DEQ-CFW_00086413

4
r +
('--I- Received
FAYETTEVILLE WORKS OCT 17 2007
,fir Permits Section
APPLICATION TO MODIFY
THE TITLE V AIR PERMIT
(PERMIT NO.03735T24)
TO INSTALL AND OPERATE
A PACKAGE RENTAL BOILER
FEBRUARY 16, 2004
DEQ-CFW 00086413

FORM Al
FACILITY (General Information)
REVISED 11101102 MrOr-MR/Diviginn of Air Otialitv - Anniii-ation for Air Permit to Construct/Onerata r_­A1__j
WRY
r/1 Local Zoning Consistency Determination (if required) Facility Reduction & Recycling Survey Form (Form A4) BApplication Fee
El Responsible Official/Authorized Contact Signature Appropriate Number of Copies of Application [3.E. Seal (if required)
Legal Corporate/Owner Name: E. 1. du Pont de Nemours & Company, Inc.
Site Name: DuPont Company - Fayetteville Works
Site Address (911 Address) Line 1: 22828 NC Highway 87 W
Site Address Line 2:
City: Duart 7ownship
State: North Carolina
ZiCode: 28306
Coun!x: Bladen
10 4!11
Xg, pN00%TE.
�1
. 1% IN0W1100W1 �MPermit/Technical Contact. Facilityflnspection Contact.,
Namerritle: Michael E. Johnson Environmental Manager
Name/Title: Michael E. Johnson Environmental Manager
Mailing Address Line 1: 22828 NC Highway 87 W
Mailing Address Line 1: 22828 NC Highway 87 W
Mailing Address Line 2:
Mailing Address Line 2:
City: Fayetteville State: NC Zip Code: 28306-7332
city: Fayetteville state: NC Zip Code: 28306-7332
Phone No. area code) [phone]
1 Fax No. (area code) [phone]
Phone No. (area code) [phone] Fax No. area code) [phone]
Email Address: [e-mail]
Email Address: [e-mail]
Responsible Official/Authorized Contact.
Invoice Contact.
Name/Title: Barry L. Hudson I Plant Manager
Namefritle: Michael E. Johnson / Environmental Manager
Mailing Address Line 1: 22828 NC Highway 87 W
Mailing Address Line 1: 22828 NC Highway 87 W
Mailing Address Line 2:
Mailing Address Line 2:
city: Fayetteville State: NC Zip Code: 28306-7332
city: Fayetteville state: NC Zip Code: 28306-7332
Phone No. (area code) [phone]
1 Fax No. area code) [phone]
Phone No. (area code) [phone]
Fax No. (area code) [phone]
Email Address: bar [e-mail] ont.com
Email Address: [e-mail]
N jW4 RRIP, 1,00,10,0—
❑ New Non -permitted Facility/Greenfield Modification of Facility (permitted) ❑ Renewal with Modification
❑ Renewal (TV Only)
1
1'A 1IT
�'u' g1N110 OW;"g111.
DSmall ❑ Prohibitory Small ❑ Synthetic Minor Title V
[General �
Describe nature of,lant site) operations ):
Manufacturer of chemicals, resins, plastic films, and plastic sheeting
Primary SIC/NAICS Code: 3081, 3083, 2821, 2869 lCurrent/Previous
Air Permit No. 03735T24 Expiration Date 4130/2008
Facility Coordinates: Latitude: 34 degrees 50' 00" North Longitude: 78 degrees 50'00" West
Does this application contain confidential data? ❑ YES NO
u
Person Name: Michael E. Johnson
11, 7.7 g'p
MIN;. 911i,1A
Firm Name: DuPont Company -Fayetteville Works
Mailing Address Line 1: 22828 NC Highway 87 W
Mailing Address Line 2:
City: Fayetteville
State: NC
Zip Code: 28306-7332
County: Bladen
—
Phone No. (area code [phone]
Fax No. (area code) [phone]
Email Address: michael.e.l'[e-mail]
_.m
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gIffi2mhffiUMMT TW '2ffl�m g,
Name (typed): Barry L. Hudson Title: Plant Manager
X Signature(Blue Ink): Date: February 16, 2004
L_ z2ZL� d j
Tit wai__L A--1— A— %I — — — — — — — -
DEQ-CFW-00086414

Zoning Consistency Determination
Facility Name DuPont Company — Fayetteville Works
Facility Street Address 22828 NC Highway 87 W
Facility City Duart Township, Bladen County, North Carolina
Description of Process installation and operation of a #2 fuel oil fired rental boiler
SIC Code/NAICS 2821, 2869, 3081, 3083
Facility Contact Michael E. lohnson
Phone Number (91016784155
Mailing Address 22828 NC Highway 87 W
Receive
iC
Mailing City, State Zip Fayetteville, NC 28306-7332
OCT 1 N0
Based on the information given above (please check the appropriate boxes): Xg pell"lls 5eot'o'
©have received a copy of the air permit application (draft or final) AND...
U-1he proposed operation IS consistent with applicable zoning and subdivision ordinances
Agency Bladen County Planning Department
Name of Designated Official Greg Elkins
Title of Designated Official Planning Director
SignatureJLe�
CC -
Date
include this Consistency Determination in the permit application and also mail to
following:
Attn: Major Source Review Branch Supervisor
NCDENR — Division of Air Quality
Permitting Section
1641 Mail Service Center
Raleigh, NC 276994641
Mr. Steven F. Vozzo
NCDENR — Division of Air Quality
Fayetteville Regional Office
225 Green Street, Suite 714
Fayetteville, NC 28301
DEQ-CFW 00086415

FORMS A2, A33 A4
EMISSION SOURCE LISTING FOR THIS APPLICATION - A2
112r APPLICABILITY INFORMATION - A3
SURVEY OF FACILITY REDUCTION & RECYCLING ACTIVITIES - A4
REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate A2
EMISSION SOURCE LISTING: New, Modified,
EMISSION SOURCE EMISSION SOURCE
ID NO. DESCRIPTION
Previously Unpermitted, Replaced, Deleted
CONTROL DEVICE CONTROL DEVICE
ID NO. DESCRIPTION
d'£§
PS-Temp
No. 2 Fuel Oil fired Rental Boiler
None
None
....
011 � i ay�i
�!;
tf 3Yw {
Ica 3-F f'H 'k� � £-; 00,
„'i n'.i��3 ,r. rb ,.,,if
Is your facility subject to 40 CFR Part 68 "Prevention of Accidental Releases" - Section 112(r) of the Federal Clean Air Act? 0 Yes
If No, please specify in detail how your facility avoided applicability:
If your facility, is Subject to 112(r), please complete the following:
II A. Have you already submitted a Risk Management Plan (RMP) to EPA Pursuant to 40 CFR Part 68.10 or Part 68.150?
Q Yes Specify required RMP submittal date: 21 1999 If submitted, RMP submittal date: 06/08/1999
B. Are you using administrative controls to subject your facility to a lesser 112(r) program standard?
Q No If yes, please specify:
Facility Name: DuPont Company - Fa etteville Works
Mailing Address Line 1: 22828 NC Highway 87 W
Mailing Address Line 2:
City: Fayetteville
state: NC
Zip Code: 28306 County: Bladen
Phone No. 910 678-1155
Fax No. 910 678-1247
Email Address: [e-mail]
Pollutant
Ongoing Source Reduction
Activities (Enter Code)
City, Emitted Before
Reduction (lb/yr)
Qty. Emitted After
Reduction (lb/yr)
Planned Source Reduction
Activities (Enter Code)
All
Nospecific activities
No current planned activities
For assistance with Section A4, please contact the North Carolina Division of Pollution Prevention and Environmental Assistance
at 1-800-763-0136 or [e-mail]
Attach Additional Sheets As Necessary
DEQ-CFW 00086416

its] 101 ,
SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES) ��
REVISED 12/01/01 NCDENR/Division of Air Qualitv - Application for Air Permit to Construct/Operate �_ _ o
EMISSION SOURCE DESCRIPTION: No. 2 Fuel Oil Fired Rental Boiler
EMISSION SOURCE ID NO: PS -Temp
CONTROL DEVICE ID NO(S): n/a
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S): PEP -Temp
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
This emission source is a package boiler which will be brought on -site and operated on a temporary basis as short-term
replacement boiler for one of the two permitted main boilers (PS-1 or PS-2) during periods when those boilers are taken
out of service for routine maintenance and repair.
TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES):
(] Coal,wood,oil, gas, other bumer (Form 131) ❑ Woodworking (Form B4) ❑ Manufact. of chemicals/coatings/inks (Form 137)
❑ Int.combustion engine/generator (Form B2) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form 68)
❑ Liquid storage tanks (Form B3) ❑ Storage silos/bins (Form 136) ❑ Other (Form B9)
START CONSTRUCTION DATE: Will notify OPERATION DATE: Will notify DATE MANUFACTURED: 1990 or later
MANUFACTURER / MODEL NO.: Will notify upon arrival 1EXPECTED OP. SCHEDULE: 24 HR/DAY 7 DAY/WK <12 WK/YR
IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): Dc NESHAP (SUBPART?): n/a MACT (SUBPART?): n/a
PERCENTAGE ANNUAL THROUGHPUT (%): DEC-FEB 25% MAR -MAY 25% JUN-AUG 25% SEP-Nov 25%
EXPECTED ANNUAL HOURS OF OPERATION: <2,000 STACK EMISSIONS UNDER NORMAL OPERATION: <20 % OPACITY
j�VISIBLE
.1�JFI�„ .,
r
AIR POLLUTANT EMITTED
SOURCE OF
EMISSION
FACTOR
EXPECTED ACTUAL
AFTER CONTROLS / LIMITS
POTENTIAL EMSSIONS
BEFORE CONTROLS LIMITS AFTER CONTROLS / LIMITS
Ib/hr
tons/yr
Ib/hr
I tons/yr
Ib/hr
tons/yr
PARTICULATE MATTER (PM)
AP-42
2.33
9.24
2.33
10.22
2.33
10.22
PARTICULATE MATTER<10 MICRONS (Pv110)
AP-42
0.71
2.80
0.71
3.10
0.71
3.10
PARTICULATE MATTER<2.5 MICRONS (PM2.5)
AP-42
0.18
0.70
0.18
0.77
0.18
0.77
SULFUR DIOXIDE (S02)
AP-42
10.04
39.76
10.04
43.98
10.04
43.98
NITROGEN OXIDES (NOx)
AP-42
9.19
36.40
14.14
61.95
9.19
40.26
CARBON MONOXIDE (CO)
AP-42
3.54
14.00
3.54
15.49
3.54
15.49
VOLATILE ORGANIC COMPOUNDS (VOC)
AP-42
0.14
0.56
0.14
0.62
0.14
0.62
LEAD
AP-42
0.00
0.00
0.00
0.00
1 0.00
0.00
OTHER
.. ' H4QQi1iPGi s" 11i£il`•�=
1�i[
FCi3i ry =.
HAZARDOUS AIR POLLUTANT AND CAS NO.
SOURCEOF
EMISSION
FACTOR
EXPECTED ACTUAL
AFTER CONTROLS / LIMITS
POTENTIAL EMSSIONS
BEFORE CONTROLS / LIMITS AFTER CONTROLS / LIMITS
Ib/hr
tons/yr
Ib/hr
tons/yr
Ib/hr
tons/yr
See attached NCDENR Emissions Spreadsheet
I
a-.h✓���...�.ei-zu>s����.,,����%j ����.f�t���ii,;f,'.��p�i„��'��J���Y�>�sif����l�i���/���w������3,�',
e�, "�.�e:i£� Y.,���.c?� '.Y.r.11
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO.
EF SOURCE
Ib/hr
Ib/da
Ib/ r
See attached NCDENR Emissions Spreadsheet
Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates) and
describe how these are monitored and with what frequency; and (3) describe any monitoring devices, gauges, or test ports for this source.
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE -
Attach Additional Sheets As Necessary
DEQ-CFW 00086417

Attachment 1
Supporting Documentation and Requested Permit Limits
NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate
EMISSION SOURCE DESCRIPTION: No. 2 Fuel Oil Fired Rental Boiler
EMISSION SOURCE ID NO: PS -Temp
CONTROL DEVICE ID NO(S): n/a
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S): PEP -Temp
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
This emission source is a package boiler which will be brought on -site and operated on a temporary basis as short-term
replacement boiler for one of the two permitted main boilers (PS-1 or PS-2) during periods when those boilers are taken
out of service
by , -z
� ���
The emissions shown on Form B are directly from the spreadsheet for estimating emissions from fuel oil combustion
units found on the Division of Air Quality website. A copy of that spreadsheet is attached.
���QSYZ';DrFEI,E!#1
iEtFikiE.,,
REQUESTED AVOIDANCE CONDITION FOR NCAC 2D.0530
Prevention of Significant deterioration
Tons per Year
AIR POLLUTANT
PARTICULATE MATTER PM
25
PARTICULATE MATTER <10 MICRONS (PM10)
15
SULFUR DIOXIDE S02
40
NITROGEN OXIDES NOx
40
� `��?OtiIPiASSI?IS
:...._
iFFi11ATfON T,tt0?Q
HAZARDOUS AIR POLLUTANT AND CAS NO.
SOURCE OF
EMISSION
FACTOR
EXPECTED ACTUAL
AFTER CONTROLS / LIMITS
POTENTIAL EMSSIONS
BEFORE CONTROLS / LIMITS AFTER CONTROLS / LIMITS
Ib/hr
tons/yr
Whir
tons/yr
Ib/hr
tons/yr
See attached NCDENR Emissions Spreadsheet
i+'iSmYli5vtiJYIif?✓..�.
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS ! LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO.
EF SOURCE
Ib/hr
Ib/day
Iblyr
See attached NCDENR Emissions Spreadsheet
Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates) and
describe how these are monitored and with what frequency; and (3) de
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE
Attach Additional Sheets As Necessary
DEQ-CFW 00086418

FUEL OIL COMBUSTION EMISSIONS CALCULATOR REVISION C 3/19/2003 - OUTPUT SCREEN
Instructions: Enter emission source / facility data on the "INPUT" tab/screen. The air emission results and summary of
input data are viewed / printed on the "OUTPUT" tab/screen. The different tabs are on the bottom of this screen.
f `R
This spreadsheet Is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This
spreadsheet Is subject to continual revision and updating. it is your responsibility to be aware of the most current information available. DENR is not
responsible for errors or omissions that may be contained herein.
iE7-'�-.
COMPANY: DuPont Company - Fayetteville Worki
MAX HEAT INPUT: 99.00 MMBTUJHR
FACILITY ID NO.: 0900009
FUEL HEAT VALUE: 140,000 BTU/GAL
PERMIT NUMBER: 03735T24
ACTUAL ANNUAL FUEL USAGE: 5,600,000 GAL/YR
FACILITY CITY: Fayetteville
MAXIMUM ANNUAL FUEL USAGE: 6,194,571 GAL/YR
FACILITY COUNTY: Bladen
MAXIMUM SULFUR CONTENT: 0.1 %
USER NAME: Michael E. Johnson
1;
I OXFIM7Z 1,0419FWI VQ
MAX. FUEL USAGE: 5,600,000 GAL/YR
EMISSION SOURCE DESCRIPTION: No. 2 oil -fired Rental Boiler
EMISSION SOURCE ID NO.: PS -Temp
MAX. SULFUR CONTENT: 0.1 %
TFiC3t.,,DE1tICES,_ . ' ..
NONE/OTHER
PM
NiFif3L)="Now . W&
0
NONE/OTHER
S02
0
LOW NOX BURNERS (LNB)
NOx
35
AIR POLLUTANT EMITTED
ACTUAL EMISSIONS
AFTERCONTROLS/LIMITS
POTENTIAL EMSSIONS
BEFORE CONTROLS/LIMITS AFTERCONTROLS/LIMITS
EMISSION FACTOR
Ib/103 al
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
uncontrolled
controlled
TOTAL PARTICULATE MATTER PM FPM+CPM
2.33
9.24
2.33
10.22
2.11
9.24
3.30E+00
3.30E+00
FILTERABLE PM (FPM)
1.41
5.60
1.41
6.19
1.28
5.60
2.00E+00
2.00E+00
CONDENSABLE PM (CPM)
0.92
3.64
0.92
4.03
0.83
3.64
1.30E+00
1.30E+00
FILTERABLE PM<10 MICRONS (PM1e)
0.71
2.80
0.71
3.10
0.64
2.80
1.00E+00
1.00E+00
FILTERABLE PM<2.5 MICRONS (PM2,5)
0.18
0.70
0.18
0.77
0.16
0.70
2.50E-01
2.50E-01
SULFUR DIOXIDE S02
10.04
39.76
10.04
43.98
9.08
39.76
1.42E+01
1.42E+01
NITROGEN OXIDES NOx
9.19
36.40
14.14
61.95
8.31
36.40
2.00E+01
1.30E+01
CARBON MONOXIDE CO
3.54
14.00
3.54
15.49
3.20
14.00
5.00E+00
5.00E+00
VOLATILE ORGANIC COMPOUNDS VOC
0.14
0.56
0.14
0.62
0.13
0.56
2.00E-01
2.00E-01
LEAD
0.00
0.00
0.00
0.00
0.00
0.00
1.26E-03
1.26E-03
.. �xA, ..�.... sa33CCE?t177."1tf3.Pi1#.Ef1i41#AIFi?t�#>'C�".
.-, _
,. _ • •.
TOXIC / HAZARDOUS AIR POLLUTANT
CAS
NUMBER
ACTUAL EMISSIONS
AFTERCONTROLS/LIMITS)
POTENTIAL EMISSIONS
BEFORE CONTROLS/LIMITS AFTER CONTROLS/LIMITS)
EMISSION FACTOR
Ib/103 al
Ib/hr
Ib/yr
Ib/hr
Ib/ r
Ib/hr
Ib r
uncontrolled
controlled
Antimony & compounds (H)
SBC
0.0E+00
0.0E+00
O.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
Arsenic & compounds (TH)
ASC
4.0E-04
3.1 E+00
4.0E-04
3.5E+00
3.6E-04
3.1 E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
1.9E-03
1.5E+01
1.9E-03
1.7E+01
1.8E-03
1.5E+01
2.75E-03
2.75E-03
Beryllium & compounds (H)
BEC
3.0E-04
2.4E+00
3.0E-04
2.6E+00
2.7E-04
2.4E+00
4.20E-04
4.20E-04
Cadium & compounds (TH)
CDC
3.0E-04
2.4E+00
3.0E-04 I
2.6E+00
2.7E-04
2.4E+00
4.20E-04
4.20E-04
Chromium - AlVrotal (H)
CRC
3.0E-04
2.4E+00
3.0E-04
2.6E+00
2.7E-04
2.4E+00
4.20E-04
4.20E-04
Cobalt compounds (H)
COC
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
Ethylbenzene (H)
100414
5.8E-04
4.6E+00
5.8E-04
5.1 E+00
5.2E-04
4.6E+00
8.17E-04
8.17E-04
Fluorides (sum fluoride compounds) (T)
16984488
2.6E-02
2.1 E+02
2.6E-02
2.3E+02
2.4E-02
2.1 E+02
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
3.4E-02
2.7E+02
3.4E-02
3.0E+02
3.1 E-02
2.7E+02
4.80E-02
4.80E-02
Lead and Lead compounds (H)
PBC
8.9E-04
7.1 E+00
8.9E-04
7.8E+00
8.1 E-04
7.1 E+00
1.26E-03
1.26E-03
Manganese & compounds (TH)
MNC
5.9E-04
4.7E+00
5.9E-04 I
5.2E+00
5.4E-04
4.7E+00
8.40E-04
8.40E-04
Mercury & compounds (TH)
HGC
I 3.0E-04
2.4E+00
3.0E-04
2.6E+00
2.7E-04
2.4E+00
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
1.7E-04
1.3E+00
1.7E-04
1.5E+00
1.5E-04
1.3E+00
2.36E-04
2.36E-04
Napthalene (H)
91203
2.4E-04
1.9E+00
2.4E-04
2.1 E+00
2.1 E-04
1.9E+00
3.33E-04
3.33E-04
Niche & compounds (H)
NIC
3.0E-04
2.4E+00
3.0E-04
2.6E+00
2.7E-04
2.4E+00
4.20E-04
4.20E-04
Phosphorus Metal, Yellow or White (H)
7723140
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
I 0.00E+00
0.00E+00
POM rates uncontrolled (H)
POM
2.3E-03
1.8E+01
2.3E-03
2.0E+01
2.1 E-03
1.8E+01
3.30E-03
3.30E-03
Selenium compounds (H)
SEC
1.5E-03
1.2E+01
1.5E-03 I
1.3E+01
1.3E-03
1.2E+01
2.10E-03
2.10E-03
Toluene (TH)
108883
5.6E-02
4.5E+02
5.6E-02
4.9E+02
5.1 E-02
4.5E+02
7.97E-02
7.97E-02
X lene (TH)
1330207
9.9E-04
7.8E+00
9.9E-04
8.7E+00
9.0E-04
7.8E+00
1.40E-03
1.40E-03
Total HAP (H)
1.0E-01
8.0E+02
1.0E-01
8.9E+02
9.2E-02
8.0E+02
1.4E-01
1.4E-01
Lar et HAP
5.63E-02
4.46E+02
5.63E--002
5.09E-02
4.46E+02
7.97E-02
7.97E-02
t/v(H)
A ]�4�.94E+02
WEI:, ��'i��� �+�Y��.7..�!R�{3�if� -�Q��� �':Q1� ��F%ii+!1 i��.T. i`!����}}
5�f, ...,
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
EMISSION FACTOR
Ib/103 al
TOXIC AIR POLLUTANT
CAS Num.
Ib/hr
lb/dayIb
r
uncontrolled
controlled
Arsenic & compounds (TH)
ASC
3.58E-04
8.59E-03
3.14E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
1.76E-03
4.22E-02
1.54E+01
2.75E-03
2.75E-03
Cadium & compounds (TH)
CDC
2.68E-04
6.44E-03
2.35E+00
4.20E-04
4.20E-04
Fluorides (sum fluoride compounds) (T)
169I44488
2.38E-02
5.72E-01
2.09E+02
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
3.07E-02
7.36E-01
2.69E+02
4.80E-02
4.80E-02
Manganese & compounds (TH)
MNC
5.37E-04
1.29E-02
4.70E+00
8.40E-04
8.40E-04
Mercury & compounds (TH)
HGC
2.68E-04
6.44E-03
2.35E+00
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
1.51E-04
3.62E-03
1.32E+00
2.36E-04
2.36E-04
Toluene (TH)
108883
5.09E-02
1.22E+00
4.46E+02
7.97E-02
7.97E-02
DEQ-CFW 00086419

FUEL OIL COMBUSTION EMISSIONS CALCULATOR REVISION C 3/19/2003 - OUTPUT SCREEN
Instructions: Enter emission source / facility data on the "INPUT" tab/screen. The air emission results and summary of
input data are viewed / printed on the "OUTPUT" tab/screen. The different tabs are on the bottom of this screen.
4•
This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This
spreadsheet Is subject to continual revision and updating. it is your responsibility to be aware of the most current information available. DENR is not
responsible for errors or omissions that may be contained herein.
_.... W
it
COMPANY: DuPont Company - Fayetteville Work
MAX HEAT INPUT: 99.00 MMBTU/HR
FACILITY ID NO.: 0900009
FUEL HEAT VALUE: 140,000 BTU/GAL
PERMIT NUMBER: 03735T24
ACTUAL ANNUAL FUEL USAGE: 1,100,000 GAL/YR
FACILITY CITY: Fayetteville
MAXIMUM ANNUAL FUEL USAGE: 6,194,571 GAL/YR
FACILITY COUNTY: Bladen
MAXIMUM SULFUR CONTENT: 0.5 %
USER NAME: Michael E.Johnson
rihR��tUF{�il£%I,s.
EMISSION SOURCE DESCRIPTION: No. 2 oil -fired Rental Boiler
MAX. FUEL USAGE: 1,100,000 GAL/YR
EMISSION_ SOURCE ID NO.: PS-Tem
SULFUR CONTENT: 00.5
,.„.,.. /...,....M„A.X.
.F./
_j 6
NONE/OTHER
PM
,. .;
0
NONE/OTHER
S02
0
LOW NOX BURNERS (LNB)
NOx
35
AIR POLLUTANT EMITTED
ACTUAL EMISSIONS
AFTERCONTROLS/LIMITS
POTENTIAL EMSSIONS
BEFORE CONTROLS/LIMITS AFTER CONTROLS/LIMITS
EMISSION FACTOR
Ib/103 al
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
uncontrolled
controlled
TOTAL PARTICULATE MATTER PM FPM+CPM
2.33
1.82
2.33
10.22
0.41
1.82
3.30E+00
3.30E+00
FILTERABLE PM (FPM)
1.41
1.10
1.41
6.19
0.25
1.10
2.00E+00
2.00E+00
CONDENSABLE PM (CPM)
0.92
0.72
0.92
4.03
0.16
0.72
1.30E+00
1.30E+00
FILTERABLE PM<10 MICRONS (PM,o)
0.71
0.55
0.71
3.10
0.13
0.55
1.00E+00
1.00E+00
FILTERABLE PM<2.5 MICRONS (PM2.5)
0.18
0.14
0.18
0.77
0.03
0.14
2.50E-01
2.50E-01
SULFUR DIOXIDE S02
50.21
39.05
50.21
219.91
8.92
39.05
7.10E+01
7.10E+01
NITROGEN OXIDES NOx
9.19
7.15
14.14
61.95
1.63
7.15
2.00E+01
1.30E+01
CARBON MONOXIDE CO
3.54
2.75
3.54
15.49
0.63
2.75
5.00E+00
5.00E+00
VOLATILE ORGANIC COMPOUNDS VOC
0.14
0.11
0.14
0.62
0.03
0.11
2.00E-01
2.00E-01
LEAD
0.00
0.00
0.00
0.00
0.00
0.00
1.26E-03
1.26E-03
x ,�.__,r ., Tt1FfCf_37�kfill«i},!k11CI�T,eCtI?FE91SS1�.i1VFfl/3A�ITli,e
.,,
_r_�-.,_
-,:
TOXIC / HAZARDOUS AIR POLLUTANT
CAS
NUMBER
ACTUAL
1AFTERCONTROLS
EMISSIONS
/ LIMITS
BEFORE CONTROLS
POTENTIAL
LIMITS(AFTER
EMSSIONS
CONTROLS/ LIMITS
EMISSION
Ib/103
FACTOR
al
Ib/hr
Ib/ r
Ib/hr
Ib/yr
Ib/hr
Ib/yr
uncontrolled
controlled
Antimony & compounds (H)
SEC
O.oE+00
0.0E+00
O.0E+00
0.0E+00
O.0E+00
0.0E+00
O.00E+00
O.00E+00
Arsenic & compounds (TH)
ASC
I 4.0E-04
6.2E-01
4.0E-04
3.5E+00
7.0E-05
6.2E-01
5.60E-04
5.60E-04
Benzene (TH)
71432
1.9E-03
3.0E+00
1.9E-03
1.7E+01
3.5E-04
3.0E+00
2.75E-03
2.75E-03
Beryllium & compounds (H)
BEC
3.0E-04
4.6E-01
3.0E-04
2.6E+00
5.3E-05
4.6E-01
4.20E-04
4.20E-04
Cadium & compounds (TH)
CDC
3.0E-04
4.6E-01
3.0E-04
2.6E+00
5.3E-05
4.6E-01
4.20E-04
4.20E-04
Chromium - All/Total (H)
CRC
3.0E-04
4.6E-01
3.0E-04
2.6E+00
5.3E-05 I
4.6E-01
4.20E-04
4.20E-04
Cobalt compounds (H)
CDC
0.0E+00
0.0E+00
0.0E+00
0.0E+00
O.0E+00
O.oE+00
O.00E+00
0.00E+00
Ethylbenzene (H)
100414
5.8E-04
9.0E-01
5.8E-04
5.1 E+00
1.0E-04
9.0E-01
8.17E-04
8.17E-04
Fluorides (sum fluoride compounds) (T)
16984488
2.6E-02
4.1E+01
2.6E-02
2.3E+02
4.7E-03
4.1 E+01
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
3.4E-02
5.3E+01
3.4E-02
3.0E+02
6.0E-03
5.3E+01
4.80E-02
4.80E-02
Lead and Lead compounds (H)
PBC
8.9E-04
1.4E+00
8.9E-04
7.8E+00
1.6E-04
1.4E+00
1.26E-03
1.26E-03
Manganese & compounds (TH)
MNC
5.9E-04
9.2E-01
5.9E-04
5.2E+00 I
1.1E-04
9.2E-01
8.40E-04
8.40E-04
Mercury & compounds (TH)
HGC
3.0E-04
4.6E-01
3.0E-04
2.6E+00
5.3E-05
4.6E-01
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
1.7E-04
2.6E-01
1.7E-04
1.5E+00
3.0E-05
2.6E-01
2.36E-04
2.36E-04
Napthalene (H)
91203
1 2.4E-04
3.7E-01
2.4E-04
2.1 E+00
4.2E-05
3.7E-01
3.33E-04
3.33E-04
Nickle & compounds (H)
NIC
3.0E-04
4.6E-01
3.0E-04
2.6E+00
5.3E-05
4.6E-01
4.20E-04
4.20E-04
Phosphorus Metal, Yellow or White (H)
7723140
0.0E+00
O.0E+00
O.0E+00
O.oE+00
O.oE+00
0.0E+00
O.00E+00
O.00E+00
POM rates uncontrolled (H)
POM
2.3E-03
3.6E+00
2.3E-03 I
2.0E+01
4.1 E-04
3.6E+00
3.30E-03
3.30E-03
Selenium compounds (H)
SEC
1.5E-03
2.3E+00
1.5E-03
1.3E+01
2.6E-04
2.3E+00
2.10E-03
2.10E-03
Toluene. (TH)
108883
5.6E-02
8.8E+01
5.6E-02
4.9E+02
1.0E-02
8.8E+01
7.97E-02
7.97E-02
Xylene (TH)
1330207
9.9E-04
1.5E+00
9.9E-04
8.7E+00
1.8E-04
1.5E+00
1.40E-03
1.40E-03
Total HAP (H)
1.0E-01
1.6E+02
1.0E-01 1
8.9E+02
1.8E-02 1
1.6E+02
1.4E-01
1.4E-01
Larget HAP (H)
5.63E-02 I
8.76E+01
5.63E-02
4.94E+02
1.00E-02
8.76E+01
7.97E-02 I
7.97E-02
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
EMISSION FACTOR
Ib/103 al
TOXIC AIR POLLUTANT
CAS Num.
Ib/hr
lb/day
Ib r
uncontrolled lcontroiied
Arsenic & compounds (TH)
ABC
7.03E-05
1.69E-03
6.16E-01
5.60E-04
5.60E-04
Benzene (TH)
71432
3.45E-04
8.29E-03
3.03E+00
2.75E-03
2.75E-03
Cadium & compounds (TH)
CDC
5.27E-05
1.27E-03
4.62E-01
4.20E-04
4.20E-04
Fluorides (sum fluoride compounds) (T)
16984488
4.68E-03
1.12E-01
4.10E+01
3.73E-02
3.73E-02
Formaldehyde (TH) I
50000 I
6.03E-03
1.45E-01
5.28E+01
4.80E-02
4.80E-02
Manganese & compounds (TH)
MNC
1.05E-04
2.53E-03
9.24E-01
8.40E-04
8.40E-04
Mercury & compounds (TH)
HGC
5.27E-05
1.27E-03
4.62E-01
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
2.96E-05
7.11E-04
2.60E-01 I2.36E-04
2.36E-04
Toluene (TH)
108883
1.00E-02
2.40E-01
8.76E+01 I
7.97E-02
7.97E-02
DEQ-CFW 00086420

FORM B1
EMISSION SOURCE (WOOD, COAL, OIL, GAS, OTHER FUEL -FIRED BURNER)
REVISED 12/01/01 NCDENR/Division of Air Qualitv - Annlication for Air Permit to Construct/Onerate 131
EMISSION SOURCE DESCRIPTION: No. 2 Fuel Oil Fired Rental Boiler
EMISSION SOURCE ID NO: PS -Temp
CONTROL DEVICE ID NO(S): None
OPERATING SCENARIO: OF
EMISSION POINT (STACK) ID NO(S): PEP -Temp
DESCRIBE USE. 0 PROCESS HEAT ❑ SPACE HEAT ❑ ELECTRICAL GENERATION
0 CONTINUOUS USE ❑ STAND BY/EMERGENCY ❑ OTHER (DESCRIBE):
HEATING MECHANISM: i] INDIRECT ❑ DIRECT
MAX. FIRING RATE (MMBTU/HOUR): <99
3
�5 „q a%i}„ 'Nn 3 Y
12.
WOOD TYPE. ❑ BARK ❑ WOOD/BARK ❑ WET WOOD ❑ DRY WOOD ❑ OTHER (DESCRIBE):
PERCENT MOISTURE OF FUEL:
❑ UNCONTROLLED ❑ CONTROLLED WITH FLYASH REINJECTION ❑ CONTROLLED W/O REINJECTION
FUEL FEED METHOD:
HEAT TRANSFER MEDIA: ❑ STEAM ❑ AIR ❑ OTHER
METHOD OF TUBE CLEANING:
CLEANING SCHEDULE:
TYPE OF BOILER
IF OTHER DESCRIBE:
PULVERIZED
OVERFEED STOKER
UNDERFEED STOKER
SPREADER STOKER
FLUIDIZED BED
❑ WET BED
❑ UNCONTROLLED
❑ UNCONTROLLED
❑ UNCONTROLLED
❑ CIRCULATING
❑ DRY BED
❑ CONTROLLED
❑ CONTROLLED
❑ FLYASH REINJECTION
❑ NO FLYASH REINJECTION
❑ RECIRCULATING
METHOD OF LOADING: ❑ CYCLONE ❑ HANDFIRED ❑ TRAVELING GRATE ❑ OTHER (DESCRIBE):
METHOD OF TUBE CLEANING:
CLEANING SCHEDULE:
�{ - 'Y'� -_ �9 ice-:- � ��
� 'c'k" � � � �[���ii�7'J
LTI���iY_
;S ,..'S' rY-s.,, - ✓.,,. "». J 3t
TYPE OF BOILER: ❑ UTILITY X INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL
TYPE OF FIRING: ❑X NORMAL ❑ TANGENTIAL Z LOW NOX BURNERS ❑ NO LOW NOX BURNER
METHOD OF TUBE CLEANING: Tubeblowing CLEANING SCHEDULE: At least once per day
�' �,�' ✓ sr ��" ?Z k5
���� Ful���i srl�l3 Bfl,,�I±�ER-�.. ''�s<
�� F� r -;.�'� z , _.�� ..? v'�,-���� a a,.�`'�`vs'"' '�`
�
TYPE OF FUEL: PERCENT MOISTURE:
TYPE OF BOILER: ❑ UTILITY ❑ INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL
TYPE OF FIRING: TYPE OF CONTROL (IF ANY): FUEL FEED METHOD:
METHOD OF TUBE CLEANING: CLEANING SCHEDULE:
�N1✓��5�4VPzG'AL/Ki.�'I`
EL [
._� -' .*�i-.._.,-„.�°,� .K...
MAXIMUM DESIGN
REQUESTED CAPACITY
FUEL TYPE
UNITS
CAPACITY (UNIT/HR)
LIMITATION (UNIT/HR)
No. 2 Fuel Oil
Gallons
707
707
r �IECCHR�CTI=�'tGSCUIt'L
I~`I^ AIlAf##I irk ,
..
SPECIFIC
SULFUR CONTENT
ASH CONTENT
FUEL TYPE
BTU CONTENT
(% BY WEIGHT)
(% BY WEIGHT)
No. 2 Fuel Oil
133,595 BTU per gallon
<0.1
<0.01
SAMPLING PORTS, COMPLIANT WITH EPA METHOD 1 WILL BE INSTALLED ON THE STACKS: 0 YES ❑ NO
COMMENTS: To comply with the requested PSD Avoidance conditions for the subject Rental Boiler, DuPont will
monitor the sulfur content of the No. 2 fuel oil and will determine the emissions of the criteria pollutants on a monthly
basis. These emissions will be reported to DAQ-FRO on a quarterly basis.
DEQ-CFW 00086421

DUPONT - FAYETTEVILLE WORKS
RENTAL BOILER
FLOW CHART
ATMOSPHERE
PEP -TEMP
RENTAL
BOILER
STACK
BOILER #2 l STEAM
WATER ♦ ( PS -Temp )
#2 FUEL OIL FROM
#2 FUEL OIL
STORAGE TANK
DEQ-CFW 00086422

y mkvn Folk
0
m
p
1^
l !
n
�O
0
0
00
N
W
NMI [N[rE{k pRq,
rI539815 i
•1
[ID Mod
�•
r1539815
TEVILE iORKS
HOUSE
DIAGRAM
E
PWACE----
Y W owllw.
E.I.W /011 CE ■IOM � Cd
.IMC.
FIGIIfL14Ei 61/N114Mf

FORM D1
FACILITY -WIDE EMISSIONS SUMMARY
REVISED 12/01/01 NCDENR/Divisinn of Air ouality - Anolication for Air Permit to Construct/Ooerate Di
EXPECTED ACTUAL EMISSIONS
(AFTER CONTROLS /
LIMITATIONS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS /
LIMITATIONS)
POTENTIAL EMISSIONS
(AFTER CONTROLS /
LIMITATIONS
AIR POLLUTANT EMITTED
tons/ r
tons/ r
tons/ r
PARTICULATE MATTER PM
82.86
419.51
124.04
PARTICULATE MATTER < 10 MICRONS (PM10)
41.81
134.87
56.31
PARTICULATE MATTER < 2.5 MICRONS (PM2.5)
2.78
241.16
90.31
SULFUR DIOXIDE S02
674.97
1,530.19
1,489.29
NITROGEN OXIDES NOx
104.91
308.57
271.31
CARBON MONOXIDE CO
13.84
49.67
49.67
VOLATILE ORGANIC COMPOUNDS VOC
167.34
2,092.41
444.73
LEAD
0.00
0.00
0.00
OTHER
EXPECTED ACTUAL EMISSIONS
(AFTER CONTROLS /
LIMITATIONS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS /
LIMITATIONS)
POTENTIAL EMISSIONS
(AFTER CONTROLS /
LIMITATIONS
HAZARDOUS AIR POLLUTANT EMITTED
CAS NO.
tons/ r
tons/ r
tons/ r
Hydrogen Fluoride
7664-39-3
1.32
2.64
662.02
Dimeth I formamide
68-12-2
.62
51.51
1.54
Methanol
67-56-1
3.23
161.25
3.25
Acetonitrile
75-05-8
1.44
2.35
2.35
Hydrogen chloride
7647-01-0
24.18
46.67
46.67
Dieth lene glycol ether
GLYCOLETHERS
1.93
9.63
9.63
Methylene chloride
72-09-2
1.13
11.34
11.34
Toluene
108-88-3
.25
2.54
2.54
�a,.f-.-,.-£�3.s1.5'.�°c a.�VA�F'?o-l�'4717ICii€-Li�+=SQI�
,n.
- "�
.l'.. z '+kw-. r.✓d
INDICATE REQUESTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS. EMISSIONS ABOVE THE TOXIC PERMIT EMISSION RATE (TPER) IN 15A
NCAC 2Q .0711 MAY REQUIRE AIR DISPERSION MODELING. USE NETTING FORM D2 IF NECESSARY.
ModelingRe uired ?
TOXIC AIR POLLUTANT EMITTED
CAS NO.
Ib/hr
lb/day
lb/year
Yes
No
See Comments
COMMENTS:
Pursuant to 2Q.0702(a)(18), a permit to emit toxic air pollutants is not required for combustion sources. In additi ion, this
site already has a facility -wide limit for all North Carolina Toxic Air Pollutants. This permit modification to operate a rental
boiler does not request any increase in the established TAP limits.
Attach Additional Sheets As Necessary
DEQ-CFW 00086424

FORM D2
AIR POLLUTANT NETTING WORKSHEET
Revised:12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate �2
PURPOSE OF NETTING: AIR TOXICS PSD 100/250 tons per ear) PSD SIGNIFICANT LEVELS
AIR POLLUTANT: CAS NO.:
EMISSION SOURCE ID NOS.: PS-Temp
��T1AEl������
i��i�IR ��
hc�°`d'5: .;:a.,c✓,�"mx4?s:,_. �. tea- x. i;<, .y a.-. x .. «10arvrs.. x,.. _. . � ... ..�'
EMISSIONS USE APPROPRIATE COLUMNS ONLY
LB/YEAR LB/DAY LB/HR
umrnar3z�I jai
wxlg
t[S
MODIFICATION
INCREASE
- MINUS -
- MINUS -
- MINUS -
- MINUS -
MODIFICATION
DECREASE
= EQUALS =
= EQUALS =
= EQUALS =
= EQUALS =
NET CHANGE
FROM MODIFICATION
17j
CREDITABLE
INCREASE
- MINUS -
MINUS -
MINUS -
- MINUS -
CREDITABLE
DECREASE
= EQUALS =
= EQUALS =
= EQUALS =
= EQUALS =
NET CREDITABLE
CHANGE
TOTAL FACILITY
EMISSIONS
TPER LEVELS (2Q .0711)
CHECK HERE IF AN AIR DISPERSION MODELING ANALYSIS IS REQUIRED
COMMENTS: Pursuant to 20.0702(a)(18), a permit to emit toxic air pollutants is not required for combustion sources. No
netting is needed for the criteria pollutants since a PSD Avoidance Limit is being requested for the rental boiler.
Attach Additional Sheets As Necessary
DEQ-CFW 00086425

FORM D3
MODELING REQUEST FORMS (3 pages)
REVISED: 02/20/03 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D3
If the applicant desires, the NCDAQ/AQAB will perform the initial modeling compliance demonstration using EPA approved screening and, if applicable and
where possible, refined models. If the model results indicate the facility will be unable to demonstrate compliance with applicable Acceptable Ambient Level(s)
the applicant will be notified and will be required to perform the compliance demonstration using established modeling protocol and modeling analysis
requirements as defined in the North Carolina Administrative Code 15A NCAC 2D .1100 and 2Q .0700 and in the Guidelines for Evaluating the Impacts o
Toxic Pollutants in North Carolina.
To perform the dispersion modeling compliance demonstration, the AQAB will require the following data:
Provide a brief description of the modification and/or addition necessitating the toxic modeling request:
This permit modification deals exclusively with the operation of a temporary rental boiler. Pursuant to 20.0702(a)(18), a
permit to emit toxic air pollutants is not required for combustion sources. Therefore, no modeling is required nor
requested.
3�,�Is71:�������'"T-Gi�ityH���T�� ��� �[l� 1}f t+�.(���R€Z%
`�t���Vx';3,�.�a• 5. .1�uC�. '��5��j.`... >.� :�i,.Y. �,3�:� k �"'s�n. �lRHs� � �t*�� �s'&,
TOXIC AIR POLLUTANT TAP
MAXIMUM TOXIC AIR POLLUTANT AP
I EMISSIONS After Controls
Emission Point ID
Ibs/year
Ibs/day
Ibs/hr
Attach Additional Sheets As Necessary Page 1 of 3
DEQ-CFW 00086426

FORM D3
MODELING REQUEST FORMS
REVISED: 02/20/03 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate
D3
, ,�� ��•� �� `�� � � � ��
��(� t3ATA�„ g �
�. ��` ^Z v zr' d• 'Yi # 4 T �.
�ur��a'f�.ri��telr���si �n:�� �c� �� source tass�f�tr�� Iss�os���
cuss etaas� ' � t�� ar �o voit�tteso�tr����oi��b � roc vo(�ts sout�e c�ta, ctac�t ��
� .`-!'¢ � -j. ; 8^ - i £ ?,__.= � �° .�ia' � �. v � i 3 y,.�a
POINT SOURCE
STACK DATA
Emission Point 1D
PEP -Temp
Stack Description
Boiler Stack
Stack Height (ft or m) - AGL
25 ft.
Stack Temperature (OF or OK)
650OF
Stack Exit Velocity (ft/s or m/s)
47 ft/sec
Stack Diameter (ft or m)
4 ft
Stack Base Elevation (ft) - MSL
146
Stack UTM Coordinates (m) E
NAD version 27 / 83 (circle one) N
' OR' Zone
Latitude `-- ° N
Longitude OW
340 50' 00"
780 50' 00"
Rain Cap? (Y/N)
N.
Vertical Stack? (Y/N)
Y
AREA SOURCE
(contact DAQ for clarification of
input data requirements)
AREA SOURCE DATA
(for each area source, submit a separate detailed description of the area source, to include
dimensions of the area and elevations. Also include source on site ma .
Emission Point ID
Source Description
Area Source Height (ft or m) - AGL
Area Source Length (ft or m)
Area Source Width (ft or m)
Source Base Elevation (ft) - MSL
Area Source UTM Coordinates (m) E
NAD version 27 / 83 (circle one) N
' OR ; Zone
Latitude `-- ° N
Longitude Ow
VOLUME SOURCE
(contact DAQ for clarification of
input data requirements)
VOLUME SOURCE DATA
(for each volume source, submit a separate detailed description of the volume source, to
Include dimensions of the volume source where emissions be in to dis erse.
Emission Point ID
Source Description
Volume Source Height (ft or m) - AGL
Volume Source Length (ft or m)
Volume Source Bldg Height (ft or m)
Source base Elevation (ft) - MSL
Volume Source UTM Coordinates (m) E
NAD version 27 / 83 (circle one) N
:OR ' Zone
Latitude `� ° N
Longitude Ow
ft- feet AGL- Above Ground level m/s- meters per second Kelvin (degrees)=273+((°F-32) x 5/9)
m- meters UTM- Universal Transverse Mercator MSL- Mean Sea Level
Attach Additional Sheets As Necessary Page 2 of 3
DEQ-CFW 00086427

FORM D3
MODELING REQUEST FORMS
REVISED: 02/20/03 NCDENR/Division of Air Quality- Application for Air Permit to Construct/Operate D3
�b'e'�� % ✓F t�. 3?:.: �,.4`.e"da.
..r.�v, ,. .:.�.G,i .,a�i.. .3�� 'vq`-`+.+ �,�w„�,?,n�`.', 5.._.9.. _.. �:: i•_. : ;s�� 'x w .. x .nk�.
A detailed site diagram must be submitted and should include all of the information listed below:
- Property boundaries
- Scale and true north indicator
- All existing and proposed buildings or structures on site
- Locations of all emission sources (existing and proposed) listed in Section 2, Page 1 of Form D3
- All public rights -of -way traversing the property ( e.g. roads, railroad tracks, rivers, etc.)
- UTM coordinates or latitude/longitude of at least one point (e.g. source or building corner)
A USGS Contour Map must also be submitted with the location of your facility clearly designated.
A certified plat map from County Register of Deeds or a signed survey map.
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CTA`Cl'k� �'
� ��' �3�� S*«bf Yy�l'�
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�•i" �' V�' �L���� ��1j��Tf�� cif 9'
irerghtscxr a�s{ngie< r �
,_ � E
,� r'I�J[LC��fx �
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�:`e, 2� �������'7
�x
`; �� ��g�'�k y��.����'.a'
�
Fy±.�Ar<;a"i `. '_
«: ' ., =,k��
,. �'i.��. •,xM
, ;#,�v. , , x,s,:: ,e�*m�.Yr,.'"w�s'a`
. ,3_
Building ID
Building Description
Building Height (ft or m)
Building Length (ft or m)
Building Width (ft or m)
g��
�.g �` �. ^,Ra"a� �r�.
. .. �-hiCz �x�?��-tr-� �'&.. ,$„. .�;✓7 , _vs„5:-..> Y'r'.�`�3'h .a�3�,.:. , - ,...,< N
Pursuant to 20.0702(a)(18), a permit to emit toxic air pollutants is not
Facility Operating Limits
(Operating hours, fuel limits, required for combustion sources. Therefore, no modeling is required
or other enforceable limits)
nor requested.
If an operating schedule is not given, continuous operations will be assumed (i.e. 24 hours/day,
8760 hours/year).
Note: if compliance is demonstrated using the above facility operating limits, these limits will be
imposed as a permit restriction.
Name: Michael E. Johnson
Facility Point of Contact Title: Environmental Manager
(required)
Phone: [phone]
EmailAdress: [e-mail]
DEQ-CFW 00086428

EXEMPT AND INSIGNIFICANT ACTIVITIES SUMMARY
REVISED: 12/01/01 K1f nrmDiniviainn of Air t]nalifu . Anniieatinn fnr Air Parmit to Cnnstructfnnnratn D4
,_�?, ..�! .33.a �. 3 � ' ... , ..�Y ; 'd ::k. �,. < � � t. i 33 , .,� c '». - -�X � ,H . � .... �: i -. ;;i.._s. ..i;• ,-.».<, i,,,t 4'� .. .1. �a L T. -. i�i .,
:. ➢:t d�i�'ivo.,.a,... .., ,,.. :�.: 3. �)jy�7��7jj?i�3'�3!`�q,P`� 9. ypy >i 1!;'3:�n.(3iyy. Mph .�. .. :i�. ,�. �. .,1 �,!153 ._a+Nm,.sl SvV-.i Yk.. kh-y_1. SR+ i, y� } .I ,._.fU. 3 . ,.: _ lS. F'i�1.
.. .. .'R�.'.
l
SIZE OR
PRODUCTION
BASIS FOR EXEMPTION OR
DESCRIPTION OF EMISSION SOURCE
RATE
INSIGNIFICANT ACTIVITY
1.
2.
3.
4.
5.
6.
7.
8.
9.
Comments:
This permit modification to allow for the operation of a rental boiler is neither insignificant nor exempt.
Attach Additional Sheets As Necessary
DEQ-CFW 00086429

FORM D
TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION
REVISED: 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D5
PROVIDE DETAILED TECHNICAL CALCULATIONS TO SUPPORT ALL EMISSION, CONTROL, AND REGULATORY
DEMONSTRATIONS MADE IN THIS APPLICATION. INCLUDE A COMPREHENSIVE PROCESS FLOW DIAGRAM AS
NECESSARY TO SUPPORT AND CLARIFY CALCULATIONS AND ASSUMPTIONS. ADDRESS THE
FOLLOWING SPECIFIC ISSUES ON SEPARATE PAGES:
A SPECIFIC EMISSIONS SOURCE (EMISSION INFORMATION) (FORM B) - SHOW CALCULATIONS USED, INCLUDING EMISSION FACTORS, MATERIAL
BALANCES, AND/OR OTHER METHODS FROM WHICH THE POLLUTANT EMISSION RATES IN THIS APPLICATION WERE DERIVED. INCLUDE
CALCULATION OF POTENTIAL BEFORE AND, WHERE APPLICABLE, AFTER CONTROLS. CLEARLY STATE ANY ASSUMPTIONS MADE AND PROVIDE ANY
REFERENCES AS NEEDED TO SUPPORT MATERIAL BALANCE CALCULATIONS.
B SPECIFIC EMISSION SOURCE (REGULATORY INFORMATION)(FORM E2 - TITLE V ONLY) - PROVIDE AN ANALYSIS OF ANY REGULATIONS APPLICABLE
TO INDIVIDUAL SOURCES AND THE FACILITY AS A WHOLE. INCLUDE A DISCUSSION OUTING METHODS (e.g. FOR TESTING AND/OR MONITORING
REQUIREMENTS) FOR COMPLYING WITH APPLICABLE REGULATIONS, PARTICULARLY THOSE REGULATIONS LIMITING EMISSIONS BASED ON
PROCESS RATES OR OTHER OPERATIONAL PARAMETERS. PROVIDE JUSTIFICATION FOR AVOIDANCE OF ANY FEDERAL REGULATIONS (PREVENTION
OF SIGNIFICANT DETERIORATION (PSD), NEW SOURCE PERFORMANCE STANDARDS (NSPS), NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR
POLLUTANTS (NESHAPS), TITLE V), INCLUDING EXEMPTIONS FROM THE FEDERAL REGULATIONS WHICH WOULD OTHERWISE BE APPLICABLE TO
THIS FACILITY. SUBMIT ANY REQUIRED TO DOCUMENT COMPLIANCE WITH ANY REGULATIONS. INCLUDE EMISSION RATES CALCULATED IN ITEM "A"
ABOVE, DATES OF MANUFACTURE, CONTROL EQUIPMENT, ETC. TO SUPPORT THESE CALCULATIONS.
C CONTROL DEVICE ANALYSIS (FORM C) - PROVIDE A TECHNICAL EVALUATION WITH SUPPORTING REFERENCES FOR ANY CONTROL EFFICIENCIES
LISTED ON SECTION C FORMS, OR USED TO REDUCE EMISSION RATES IN CALCULATIONS UNDER ITEM "A" ABOVE. INCLUDE PERTINENT OPERATING
PARAMETERS (e.g. OPERATING CONDITIONS, MANUFACTURING RECOMMENDATIONS, AND PARAMETERS AS APPLIED FOR IN THIS APPLICATION)
CRITICAL TO ENSURING PROPER PERFORMANCE OF THE CONTROL DEVICES). INCLUDE AND LIMITATIONS OR MALFUNCTION POTENTIAL FOR THE
PARTICULAR CONTROL DEVICES AS EMPLOYED AT THIS FACILITY. DETAIL PROCEDURES FOR ASSURING PROPER OPERATION OF THE CONTROL
DEVICE INCLUDING MONITORING SYSTEMS AND MAINTENANCE TO BE PERFORMED.
D IPROCESS AND OPERATIONAL COMPLIANCE ANALYSIS - (FORM E3 - TITLE V ONLY) - SHOWING HOW COMPLIANCE WILL BE ACHIEVED WHEN USING
PROCESS, OPERATIONAL, OR OTHER DATA TO DEMONSTRATE COMPLIANCE. REFER TO COMPLIANCE REQUIREMENTS IN THE REGULATORY
ANALYSIS IN ITEM "B" WHERE APPROPRIATE. LIST ANY CONDITIONS OR PARAMETERS THAT CAN BE MONITORED AND REPORTED TO
DEMONSTRATE COMPLIANCE WITH THE APPLICABLE REGULATIONS.
E IPROFESSIONAL ENGINEERING SEAL - PURSUANT TO 15A NCAC 2Q .0112 "APPLICATION REQUIRING A PROFESSIONAL ENGINEERING SEAL, --
A PROFESSIONAL ENGINEER REGISTERED IN NORTH CAROLINA SHALL BE REQUIRED TO SEAL TECHNICAL PORTIONS OF THIS APPLICATION FOR
NEW SOURCES AND MODIFICATIONS OF EXISTING SOURCES. (SEE INSTRUCTIONS FOR FURTHER APPLICABILITY).
attest that this application for
has been reviewed by me and is accurate, complete and consistent with the information supplied
in the engineering plans, calculations, and all other supporting documentation to the best of my knowledge. I further attest that to the best of my
knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal
package may have been developed by other professionals, inclusion of these materials under my seal signifies that I have reviewed this material
and have judged it to be consistent with the proposed design. Note: In accordance with NC General Statutes 143-215.6A and 143-215.6B, any
person who knowingly makes any false statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor which
may include a fine not to exceed $10, 000 as well as civil penalties up to $25, 000 per violation.
USE BLUE INK TO COMPLETE THE FOLLOWING) I PLACE NORTH CAROLINA SEAL
DATE:
COMPANY:
ADDRESS:
TELEPHONE:
SIGNATURE:
PAGES CERTIFIED:
(IDENTIFY ABOVE EACH PERMIT FORM AND ATTACHMENT
DEQ-CFW 00086430

SECTION D
TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION
Emission Unit ID: PS -Temp
Emission Unit Description: Rental Boiler
A. SPECIFIC EMISSIONS SOURCE — EMISSION INFORMATION (FORM B)
The emissions listed on Form B were generated from the Division of Air Quality's "Fuel Oil
Combustion Emissions Calculator Revision C 3/19/2003". A copy of the output screen from
that spreadsheet will be found behind Form B.
B. SPECIFIC EMISSION SOURCE — REGULATORY INFORMATION (FORM E2)
This emission unit is subject to the following regulations:
1. 15A NCAC 2D.0503
— Particulates From Fuel Burning Indirect Heat Exchangers;
2. 15A NCAC 2D.0516
— Sulfur Dioxide Emissions From Combustion Sources;
3. 15A NCAC 2D.0524
— New Source Performance Standards
3. 15A NCAC 2D.0521—
Control of Visible Emissions; and
4. Avoidance of 15A NCAC 2D.0530 — Prevention of Significant Deterioration;
The specific limits associated with each of these applicable regulations are as follows:
15A NCAC 2D.0503 states that allowable PM emissions from combustion units whose
maximum heat input is up to 100 MM-BTU per hour is 0.33 pounds of PM per MM-BTU.
15A NCAC 2D.0516 requires that sulfur dioxide emissions from combustion sources shall
not exceed 2.3 Ib/MM-BTU.
15A NCAC 2D.0521 requires for installations established after July 1,1971 that visible
emissions shall not be more than 20 percent opacity when averaged over a six -minute period
except that six -minute periods averaging not more than 87 percent opacity may occur not
more than once in any hour nor more than four times in any 24-hour period.
15A NCAC 2D.0524 requires that sources subject to new source performance standards
promulgated in 40 CFR Part 60 comply with emission standards, monitoring and reporting
requirements, maintenance requirements, notification and record keeping requirements,
performance test requirements, test method and procedural provisions, and any other
provisions specified in the federal regulations. Installations of small industrial steam
DEQ-CFW 00086431

SECTION D
TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION
Emission Unit ID: PS -Temp
Emission Unit Description: Rental Boiler
generating units established after June 9,1989 must comply with the requirements of Part 60
Subpart Dc of the code of Federal Regulations.
Pursuant to §60.42c, the standard for sulfur dioxide is that the discharge of sulfur dioxide
cannot exceed 0.50 lb/million Btu heat input; or, as an alternative, the fuel oil cannot contain
greater than 0.5 weight percent sulfur.
Pursuant to §60.43c, the standard for particulate matter is that the discharge of particulate
matter cannot be greater than 20 percent opacity (6-minute average), except for one 6-minute
period per hour of not more than 27 percent opacity.
15A NCAC 2D.0530 is the prevention of significant deterioration rule. lmplementation of
this rule will prevent significant deterioration of air quality. For DuPont Fayetteville -Works,
this rule requires that the emissions of the federal criteria pollutants from Boiler #2 (PS-2)
does not exceed the significant emission rates for those pollutants without a PSD review.
C. CONTROL DEVICE ANALYSIS (FORM C)
This emission unit (boiler) is equipped with a low-NOx burner and will burn exclusively
Number 2 Fuel Oil. The boiler has no other equipment to limit or control air emissions.
D. PROCESS AND OPERATIONAL COMPLIANCE ANALYSIS (FORM E3)
15A NCAC 2D.0503 — As indicated in the emissions estimate contained in this D Form, the
rental boiler will be firing exclusively No. 2 Fuel Oil. According to the AP-42 emission
factor which has an A rating (3.3 lb PM/1000 gallons based on fuel oil containing the
maximum sulfur limit of 0.1 % by weight), PM emissions are equal to approximately
0.025 lb/MM-BTU (based on 133,595 BTU/gal). NCAC 2D.0503(c) lists the particulate
matter emission limit for combustion units up to 100 MM-BTU/hr as 0.33 lb PM per MM-
BTU. Thus, the PM emissions for the Rental Boiler at full rates are less than 8% of the
allowable emissions, and therefore, no monitoring or record keeping is required because
compliance with 2D.0503 will be maintained.
15A NCAC 2D.0516 — The sulfur dioxide emissions will be below 2.3 lb/MM-BTU as long
as the sulfur content in fuel oil is below 2.2% by weight. NSPS Subpart Dc requires that the
DEQ-CFW 00086432

SECTION D
TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION
Emission Unit ID: PS -Temp
Emission Unit Description: Rental Boiler
discharge of sulfur dioxide cannot exceed 0.50 lb/MM-Btu heat input; or, as an alternative,
the fuel oil cannot contain greater than 0.5 weight percent sulfur. Therefore, compliance
with NSPS Subpart Dc will equal compliance with 2D.0516. The fuel oil sulfur content will
be obtained from the vendor and recorded in a logbook. Sulfur content will be maintained
below 0.5% by weight to ensure compliance.
15A NCAC 2D.0521 requires for sources manufactured after July 1, 1971, that visible
emissions shall not be more than 20 percent opacity when averaged over a six -minute period
except that six -minute periods averaging not more than 87 percent opacity may occur not
more than once in any hour nor more than four times in any 24-hour period.
15A NCAC 2D.0524 — Installations of small industrial steam generating units established
after June 9,1989 must comply with the requirements of Part 60 Subpart Dc of the code of
Federal Regulations. The Rental Boiler will burn exclusively Number 2 Fuel Oil with a
sulfur content of less than 0.5 weight percent. Certificates of Analysis will be obtained from
the fuel supplier as documentation of compliance of the standard set forth in §60.42c. The
boiler will be operated such that that visible emissions are not more than 20 percent opacity
when averaged over a six -minute period, except for one six -minute period per hour of not
more than 27 percent opacity.
15A NCAC 2D.0530 — A PSD avoidance limit is being requested for this permit. DuPont
will monitor the type and quantity of fuel oil consumed by Boiler #2 and will use this
information to calculate the emissions of the criteria pollutants for the previous consecutive
twelve month period using the Division of Air Quality's fuel oil combustion emissions
calculator or an equivalent.
E. PROFESSIONAL ENGINEERING SEAL
This permit modification is to allow a package rental boiler to operate at this facility and
provide supplemental steam during periods when either of the two permanent boilers are
shutdown for repairs. A PSD Avoidance limit is being requested, and the boiler will be
compliant with the requirements of 40 CFR 60 Subpart De. Due to extreme simplicity of this
requested modification, no professional engineering seal is required.
DEQ-CFW 00086433

REVISED: 12/01/01
FORM E1
TITLE V GENERAL INFORMATION
of Air Qualitv - Analication for Air Permit to Construc
Indicate here if your facility is subject to Title V by: ❑x Emissions ❑ Other
If subject to Title V by other, check or specify: ❑ NSPS ❑ NESHAPS (MACT) ❑ TITLE IV
Other, specify:
El
If you are or will be subject to any maximum achievable control technology standards (MACT) issued pursuant to section
112(d) of the Clean Air Act, specify below:
EMISSION SOURCE
EMISSION SOURCE ID
DESCRIPTION
MACT
BS-D
Butacite Tinting Process
Part 63 Subpart KK
BS-B
Butacite PVB Process
Part 63 Subpart FFFF
NS-A
Nafion HFPO Process
Part 63 Subpart FFFF
NS-B
Nafion VEN Process
Part 63 Subpart FFFF
NS-C
Nafion VIES Process
Part 63 Subpart FFFF
NS-D
Nafion RSU Process
Part 63 Subpart FFFF
NS-F
Nafion MMF Process
Part 63 Subpart FFFF
NS-G
Nafion Resins Process
Part 63 Subpart FFFF
PS-1
Industrial Boiler (Primary)
Part 63 Subpart DDDDD
PS-2
Industrial Boiler (Back-up)
Part 63 Subpart DDDDD
PS -Temp
Industrial Boiler (Rental)
Part 63 Subpart DDDDD
List any additional regulation which are requested to be included in the shield and provide a detailed explanation as to why
the shield should be granted:
REGULATION
EMISSION SOURCE (include ID)
EXPLANATION
2D.0300
All emission sources
Emergency Abatement Plan
2D.0535
All emission sources
Allowance for excess emissions and malfunctions
40 CFR Part 68
All emission sources
Risk Management Plan (accidental releases)
2D.0501 e)
All emission sources
By meeting the SIP regulations in 2D.0500, this
site will meet all standards of 2D.0400
2D.0530
PS -Temp
This application is requesting that a PSD
avoidance condition be placed in the permit for
NOx, S02, PM, and PM-10.
Comments: This permit modification is to allow for the periodic installation and operation of a package rental boiler to provide
for supplemental steam during outages of either of the two permanent boilers ( ID Nos. PS-1 and PS-2). Compliance with the
requested PSD Avoidance condition will be easily ensured do to the short duration the rental boiler will be in operation during
any given 12-month period.
Attach Additional Sheets As Necessary
DEQ-CFW 00086434

FORM E2
EMISSION SOURCE APPLICABLE REGULATION LISTING
REVISED 12/01/01 Division of Air Qualitv - ADnlication for Air Permit to Construct/Ooerate E2
EMISSION
SOURCE
ID NO.
EMISSION
SOURCE
DESCRIPTION
OPERATING SCENARIO
INDICATE PRIMARY (P)
OR ALTERNATIVE (A)
POLLUTANT
APPLICABLE
REGULATION
Eiffim,2
s e s
IWO-
z",1 ... _'4.,,. ,i ... '.i.�i....%+N==i£'.?,*„"�,
,,:...<-'Yf,'
s�i..
-'-
h
_.✓lr'_.y n a? .."
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
PM
NCAC 2D.0503
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
PM
NCAC 2D.0524
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
PM
NCAC 213.0530
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
PM
NCAC 20.0317
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
PM-10
NCAC 2D.0530
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
1310-10
NCAC 20.0317
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
S02
NCAC 2D.0516
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
S02
NCAC 2D.0524
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
S02
NCAC 2D.0530
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
S02
NCAC 20.0317
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
NOx
NCAC 213.0530
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
NOx
NCAC 2Q.0317
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
V.E.
NCAC 2D.0521(c)
PS -Temp
No. 2 Fuel Oil Fired Boiler
No. 2 Fuel Oil
V.E.
NCAC 2D.0521(d)
Attach Additional Sheets As Necessary
DEQ-CFW 00086435

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate
E3
Emission Source ID NO. PS -Temp Regulated Pollutant Particulate Matter PM
Applicable Regulation NCAC 2Q.0317
Alternative Operating Scenario (AOS) NO: ll
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
- iT a.�aw� ."�ru 2'..fit� ,y-.....uY--Y�-.-,,...�..��@�.-' ..- �-lw➢� Yam. �..r��^�-_, �o �'`.,�.i.
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes X No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes X No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): PM from the Rental Boller (PS -Temp) will be
determined using thje NCDENR DAQ fuel oil combustion emissions calculator or an equivalent.
Emissions will be tracked to ensure the 12-month moving sum does not exceed 25 tons.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
Monthly emissions determination and quarterly reporting to NCDENR Division of Air Quality.
`Ifi,a7,.;
Data (Parameter) being recording: Particulate matter emissions
Frequency of recordkeeping (How often is data recorded?):
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly. Any records
associated with that report will be available to NCDENR personnel upon request.
Generally describe what is being reported:
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly.
Frequency: MONTHLY 9 QUARTERLY EVERY 6 MONTHS
OTHER (DESCRIBE):
�' 5G p
�j�EST s
a?a.,, ar.i".�,. _, .�.,�,j�.�kz'-.- ,,b%,`acZT, ..b. � .T:lu"v� .--^£,i - Y'z:�i`�.. - ,..1b. � -, ✓:". �T. ,.--
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00086436

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate
E3
Emission Source ID NO. PS -Temp Regulated Pollutant Particulate Matter <10 4m PM-10
Applicable Regulation NCAC 20.0317
Alternative Operating Scenario (AOS) NO: n/a
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
EQE1Il Rli NT � � � w
NITO)IMG R E
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes LxJ No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes LI No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): PM-10 from the Rental Boiler (PS -Temp) will be.
determined using thje NCDENR DAQ fuel oil combustion emissions calculator or an equivalent.
Emissions will be tracked to ensure the 12-month moving sum does not exceed 15 tons.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
Monthly emissions determination and quarterly reporting to NCDENR Division of Air Quality.
Data (Parameter) being recording: Particulate matter <10 µm emissions
Frequency of recordkeeping (How often is data recorded?):
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly. Any records
associated with that report will be available to NCDENR personnel upon request.
Generally describe what is being reported:
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly.
Frequency: MONTHLY 0 QUARTERLY EVERY 6 MONTHS
OTHER (DESCRIBE):
,�.A� SM$✓F 4�i kFr9 J �i3 ,�� F ii�.. M _ r/ $ °5/a`"aR�Ti ,/Y✓hl r' 3Cb PE.: S? Y '€.z / .�.r' C✓"'
v ,,. rcx` .,. S.,3v�wf,.�r,✓ 2 i
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00086437

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCnENR/nivicinn C)f Air fluality- Anolication for Air Permit to Construct/Onerate E3
Emission Source ID NO. PS -Temp Regulated Pollutant Nitrogen Oxides NOx
Applicable Regulation NCAC 2Q.0317
Alternative Operating Scenario (AOS) NO: n/a
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes N No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes Lxg No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): NOx from the Rental Boiler (PS -Temp) will be
determined using thje NCDENR DAQ fuel oil combustion emissions calculator or an equivalent.
Emissions will be tracked to ensure the 12-month moving sum does not exceed 40 tons.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
Monthly emissions determination and quarterly reporting to NCDENR Division of Air Quality.
Data (Parameter) being recording: Nitrogen Oxides (NOx)
Frequency of recordkeeping (How often is data recorded?):
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly. Any records
associated with that report will be available to NCDENR personnel upon request.
Generally describe what is being reported:
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly.
Frequency: MONTHLY Fx1 QUARTERLY EVERY 6 MONTHS
OTHER (DESCRIBE):
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00086438

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality- Application for Air Permit to Construct/Operate
E3
Emission Source ID No. PS -Temp Regulated Pollutant Sulfur dioxide S02
Applicable Regulation NCAC 20.0317
Alternative Operating Scenario (AOS) NO: n/a
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
lstI#i
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes LxJ No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes U No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): S02 from the Rental Boller (PS -Temp) will be
determined using thje NCDENR DAQ fuel oil combustion emissions calculator or an equivalent.
Emissions will be tracked to ensure the 12-month moving sum does not exceed 40 tons.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
Monthly emissions determination and quarterly reporting to NCDENR Division of Air Quality.
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Data (Parameter) being recording: Sulfur dioxide (S02)
Frequency of recordkeeping (How often is data recorded?):
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly. Any records
associated with that report will be available to NCDENR personnel upon request.
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Generally describe what is being reported:
Emissions of this pollutant will be determined monthly and reported to NCDENR quarterly.
Frequency: MONTHLY N QUARTERLY EVERY 6 MONTHS
OTHER (DESCRIBE):
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Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00086439

FORM E4
EMISSION SOURCE COMPLIANCE SCHEDULE
Revised 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate E4
COMPLIANCE STATUS WITH RESPECT TO ALL APPLICABLE REQUIREMENTS
Will each emission source at your facility be in compliance with all applicable requirements at the time of permit issuance
and continue to comply with these requirements?
0 Yes No If NO, complete A through F below for each requirement
for which compliance is not achieved.
Will your facility be in compliance with all applicable requirements taking effect during the term of the permit and meet
such requirements on a timely basis?
0 Yes No If NO, complete A through F below for each requirement
for which compliance is not achieved.
If this application is for a modification of existing emissions source(s), is each emission source currently in compliance
with all applicable requirements?
0 Yes No If NO, complete A through F below for each requirement
for which compliance is not achieved.
A. Emission Source Description (Include ID NO.) Rental Boiler (PS -Temp)
B. Identify applicable requirement for which compliance is not achieved:
C. Narrative description of how compliance will be achieved with this applicable requirements:
D. Detailed Schedule of Compliance:
Ste s Date Expected
E. Frequency for submittal of progress reports (6 month minimum):
F. Starting date of submittal of progress reports:
Attach Additional Sheets As Necessary
DEQ-CFW 00086440

FORM E5
TITLE V COMPLIANCE CERTIFICATION (Required)
Revised 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate
In accordance with the provisions of Title 15A NCAC 20.0520 the responsible company official of.•
SITE NAME: Dupont Company - Fayetteville Works
SITE ADDRESS: 22828 NC Highway 87 W
CITY, NC: Duart Township
COUNTY: Bladen
PERMIT NUMBER: 03735T24
CERTIFIES THAT(Check the appropriate box):
0 The facility is in compliance with all applicable requirements
❑ The facility is not currently incompliance with all applicable requirements
If this box is checked, you must also complete form E4 "Emission Source Compliance Schedule"
E5
The undersigned certifies under the penalty of law, that all information and statements provided in the application, based on
information and belief formed after reasonable inquiry, are true, accurate, and complete.
Date: February 16, 2004
company official (REQUIRED, USE BLUE INK)
Barry L. Hudson - Plant Manager
Name, Title of responsible company official (Type or print)
Attach Additional Sheets As Necessary
DEQ-CFW 00086441