DEQ-CFW_00085891

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DEC ZCL
FAYETTEVILLE WORKS
APPLICATION TO MODIFY THE TITLE V AIR PERMIT
(PERMIT NO.03735T33)
TO CONSTRUCT AND OPERATE
A NATURAL GAS -FIRED OR NO.2 FUEL OIL -FIRED BOILER
0
TO PERMIT
THE HFPO PRODUCT CONTAINER DECONTAMINATION PROCESS
THE VE NORTH PRODUCT CONTAINER DECONTAMINATION PROCESS
THE VE SOUTH PRODUCT CONTAINER DECONTAMNATION PROCESS
THE ENCLOSED APPLICATION AND FEE IS PURSUANT TO
15A NCAC 2Q.0504
"OPTION FOR OBTAINING CONSTRUCTION AND OPERATION PERMIT"
DEQ-CFW 00085891

FORM Al
FACILITY (General Information)
REVISED 12/01/01 NCDENR/Division of Air Qualitv - Application for Air Permit to Construct/Operate
Al
NOTEa:APPLICATION WILL NOT BE PROCESSED WITHOUT. THE FOLLOWING:
Local Zoning Consistency Determination (if required) 0 Facility Reduction & Recycling Survey Form (Form A4) (] Application Fee
Responsible Official/Authorized Contact Signature 21 Appropriate Number of Copies of Application ❑ P.E. Seal (if required)
GENERAL INFORMATION
Legal Corporate/Owner Name: E.I. du Pont de Nemours & Company
Site Name: DuPont Company - Fayetteville Works
Site Address (911 Address) Line 1: 22828 NC Highway 87 W
Site Address Line 2:
City: Fayetteville
State: North Carolina
Zip Code: 28306-7332
County: Bladen
CONTACT INFORMATION
Permit/Technical Contact:
Facility/inspection Contact:
Name/Title: Michael E. Johnson, Environmental Manager
Name/Title: (Same as Permit/Technical Contact)
Mailing Address Line 1: 22828 NC Hwy 87 W
Mailing Address Line 1:
Mailing Address Line 2:
Mailing Address Line 2:
City: Fayetteville State: NC Zip Code: 28306
City: State: Zip Code:
Phone No. 910.678.1155
lFax No. 910.678.1247
Phone No. ( ) I
Fax No. ( )
Email Address: [e-mail]
Email Address:
Responsible Official/Authorized Contact:
Invoice Contact:
Name/Title: Karen B. Wrigley / Plant Manager
Name/Title: (Same as Permit/Technical Contact)
Mailing Address Line 1: 22828 NC Hwy 87 W
Mailing Address Line 1:
Mailing Address Line 2:
Mailing Address Line 2:
City: Fayetteville State: NC Zip Code: 28306
City: State: Zip Code:
Phone No. 910-678-1546
1 Fax No. 910-678-1247
Phone No. ( )
Fax No. ( )
Email Address: [e-mail]
Email Address:
APPLICATION IS BEING MADE FOR
❑ New (non -permitted) Facility/Greenfield 1] Modification of Facility (permitted) ❑ Renewal With Modification
❑ Renewal (TV Only)
:FACILITY CLASSIFICATION AFTER APPLICATION (Check Only One)
❑ General ❑ Small ❑ Prohibitory Small ❑ Synthetic Minor 91 Title V (Must include Form(s) E)
FACILITY (Plant Site) INFORMATION
Describe nature of (plant site) operation(s): Chemical manufacturing facility.
Primary SIC/NAICS Code: 3081, 3083, 2821, 2869
1 Current/Previous Air Permit No. 03735T33
Facility Coordinates: Latitude: 34 deg. 50 min. 30 sec. Longitude: -74 deg. 50 min. 10 sec.
Does this application contain confidential data? ❑ No 1] Yes (See Instructions)
_PERSON Olk FIRM THAT "PREPARED APPLICATION
Person Name: Michael E. Johnson
Firm Name:
Mailing Address Line 1: 22828 NC Hwy 87 W
Mailing Address Line 2:
City: Fayetteville
State: NC
Zip Code: 28306-7332
county: Bladen
Phone No. 910-678-1155
Fax No. 910-678-1247
Email Address: Michael,[e-mail]
SIGNATURE OF RESPONSIBLE OFFICIAL/AUTHORIZED
CONTACT
Name (typed): Karen B. Wrigley Title: Plant Manager
X Signature(Blue Ink): Date:
6 y ' ' 1 December 4, 2008
Attach Additional Sheets As Necessary
DEQ-CFW 00085892

Zoning Consistency Determination
Facility Name DuPont Company — Fayetteville Works
Facility Street Address 22828 NC Highway 87 W
Facility City Duart Township, Bladen County, North Carolina
Natural gas -fired or No. 2 fuel oil -fired boiler;
Description of Processes HFPO Product Container Decontamination Process;
VE North Product Container Decontamination Process;
VE South Product Container Decontamination Process; et al
SIC Code/NAICS 3081 / 326113
Facility Contact Michael E. Johnson
Phone Number [phone]
Mailing Address 22828 NC Highway 87 W
Mailing City, State Zip Fayetteville, NC 28306-7332
Based on the information given above:
Q I have received a copy of the air permit application (draft or final) AND...
C✓1 The proposed operation IS consistent with applicable zoning and subdivision ordinances
Agency
Name of Designated Official
Title of Designated Official
Signature
Date
Bladen County Planning Department
Greg Elkins
Planning Director
December 4, 2008
Please forward to the mailing address listed above and the air quality offices listed below:
Attn: Major Source Review Branch Supervisor
NCDENR — Division of Air Quality
Permitting Section
1641 Mail Service Center
Raleigh, NC 27699-1641
Mr. Steven F. Vozzo
NCDENR — Division of Air Quality
Fayetteville Regional Office
225 Green Street — Suite 714
Fayetteville, NC 28301
DEQ-CFW 00085893

FORMS A2, A3
EMISSION SOURCE LISTING FOR THIS APPLICATION - A2
112r APPLICABILITY INFORMATION - A3
REVISED 04/10/07 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate
A2
EMISSION SOURCE LISTING: New, Modified, Previously Un ermitted, Replaced, Deleted
EMISSION SOURCE
EMISSION SOURCE
I
CONTROL DEVICE
CONTROL DEVICE
ID NO.
DESCRIPTION
ID NO.
DESCRIPTION
Equipment
To Be ADDED By This Application (New, Previously;
Unpermitted, or Replacement)
Natural gas -fired or No. 2 oil -fired
PS-3
boiler, 97 million BTU per hour
None
maximum heat input
NS-N
HFPO product cylinder
NCD-Hdr1
Gaseous Absorber
decontamination process
NS-O
Vinyl Ethers North product cylinder
NCD-Hdr1
Gaseous Absorber
decontamination process
NS-P
Vinyl Ethers South product
NCD-Hdr2
Gaseous Absorber
cylinder decontamination process
Existing ;Permitted Equipment To Be MODIFIED By
This Application
Natural gas -fired or No. 2/No. 6 fuel
PS-1
oil -fired boiler, 139.4 million BTU
None
per hour maximum heat input
Natural gas -fired or No. 2/No. 6 fuel
PS-2
oil -fired boiler, 88.4 million BTU per
None
hour maximum heat input
SGS-A
SentryGlas® Plus Manufacturing
None
1-10
Abrasive blasting building
None
7-
Equipment To Be DELETED
By This Application
1,12(r) APPLICABILITY] NFORMATION.
A3
Is your facility subject to 40 CFR Part 68 "Prevention of Accidental Releases" - Section 112(r) of the Federal Clean
Yes (] No ❑
Air Act?
If No, please specify in detail how your facility avoided applicability:
If your facility is Subject to 112(r), please complete the following:
A. Have you already submitted a Risk Management Plan (RMP) to EPA Pursuant to 40 CFR Part 68.10 or Part 68.150?
Yes X❑ No ❑ Specify required RMP submittal date: June 30, 1999
If submitted, RMP submittal date: June 8, 1999 RMP resubmitted on June 3, 2004
B. Are you using administrative controls to subject your facility to a lesser 112(r) program standard?
Yes ❑ No 0 If yes, please specify:
Attach Additional Sheets As Necessary
DEQ-CFW 00085894

For assistance with FORM A4, please contact the North Carolina Division of Pollution Prevention and Environmental Assistance at 1-800-763-0136 or [e-mail]

FORM B
SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES)
REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate F B
EMISSION SOURCE DESCRIPTION:
Natural gas -fired or No. 2 oil -fired boiler
EMISSION SOURCE ID NO: PS-C
CONTROL DEVICE ID NO(S): None
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S) PEP-2
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
Natural gas -fired or No. 2 oil -fired boiler with a maxiniurn heat input of 97.0 NMM-BTU / hour.
TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES):
rx-1 Coal,wood,oil, gas, other burner (Form B1) ❑ Woodworking (Form 134) ❑ Manufact. of chemicals/coatings/inks (Form 67)
❑ Int.combustion engine/generator (Form 132) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form 68)
❑ Liquid storage tanks (Form 133) ❑ Storage silos/bins (Form B6) ❑ Other (Form 69)
START CONSTRUCTION DAT Jan 09
1OPERATION DATE Jun 09 JDATE
MANUFACTURED: Dee 2008
MANUFACTURER / MODEL NO.: n/a 1EXPECTED OP. SCHEDULE: 24 HR/DAY 7 DAY/WK 50 WK/YR
IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): DC NESHAP (SUBPART?): NO MACT (SUBPART?): No
PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25
EXPECTED ANNUAL HOURS OF OPERATION: -8400 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: <20 % OPACITY
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION
FOR THIS SOURCE
AIR POLLUTANT EMITTED
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
PARTICULATE MATTER (PM)
AP-42
2.29
9.60
2.29
10.01
2.29
10.01
PARTICULATE MATTER<10 MICRONS (PM10)
AP-42
0.69
2.91
0.69
3.03
0.69
3.03
PARTICULATE MATTER<2.5 MICRONS (PM2,5)
AP-42
0.17
0.73
0.17
0.76
0.17
0.76
SULFUR DIOXIDE (S02)
AP-42
4.92
20.66
4.92
21.55
4.92
21.55
NITROGEN OXIDES (NOx)
AP-42
9.01
37.83
9.01
60.69
9.01
39.45
CARBON MONOXIDE (CO)
AP-42
3.46
14.55
3.46
15.17
3.46
15.17
VOLATILE ORGANIC COMPOUNDS (VOC)
AP-42
0.14
0.58
0.14
0.61
0.14
0.61
LEAD
AP-42
0
0
0
O
0
0
OTHER
HAZARDOUS AIR POLLUTANT
EMISSIONS
INFORMATION FOR THIS SOURCE'
HAZARDOUS AIR POLLUTANT
AND CAS NUMBER
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons! r
Ib/hr
tons/ r
Ib/hr
tons/ r
See attached NCDENR spreadsheets
TOXIC AIR POLLUTANT EMISSIONS
INFORMATION FOR
THIS SOURCE
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO. I EF SOURCE
Ib/hr
lb/day
Ib/ r
See attached NCDENR spreadsheets_
Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission
rates) and describe how these are monitored and with what frequency; and (3) describe any monitoring devices, gauges, or test ports for this source.
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE BI THROUGH B9 FORM FOR EACH SOURCE
Attach Additional Sheets As Necessary
DEQ-CFW 00085896

FORM B
SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES)
REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate u i
EMISSION SOURCE DESCRIPTION: HFPO Product
Container Decontamination Process
EMISSION SOURCE ID NO: NS-N
CONTROL DEVICE ID NO(S): NCD-Hdrl
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S) NEP-Hdrl
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
HFPO product containers that are returned from customers must be decontaminated by venting
any residual product (hexafluoropropylene oxide) from the containers. The product containers are
vented to a gaseous absorber (NCD-Hdrl), but since the product is not water soluble, none of the
emissions are controlled and all is assumed to vent to the atmosphere.
TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-69 ON THE FOLLOWING PAGES):
❑ Coal,wood,oil, gas, other burner (Form B1) ❑ Woodworking (Form 134) ❑ Manufact. of chemicals/coatings/inks (Form B7)
❑ Int.combustion engine/generator (Form 132) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form 68)
❑ Liquid storage tanks (Form B3) ❑ Storage silos/bins (Form B6) N Other (Form B9)
START CONSTRUCTION DAT June 0$
1OPERATION DATE June 08 JDATE
MANUFACTURED: n/a
MANUFACTURER / MODEL NO.: n/a
1EXPECTED OP. SCHEDULE: 7 HR/DAY 7 DAY/INK 52 WK/YR
IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): No NESHAP (SUBPART?): No MACT (SUBPART?): No
PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25
EXPECTED ANNUAL HOURS OF OPERATION: 2628
IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: 0 % OPACITY
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION
FOR THIS SOURCE
AIR POLLUTANT EMITTED
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Iblhr
tonsl r
Ib/hr
tons/ r
tb/hr
tons! r
PARTICULATE MATTER (PM)
0
0
0
0
0
0
PARTICULATE MATTER<10 MICRONS (PMtc)
0
0
0
0
0
0
PARTICULATE MATTER<2.5 MICRONS (PM2.5)
0
0
0
0 1
0
0
SULFUR DIOXIDE (S02)
0
0
0
0
0
0
NITROGEN OXIDES (NOx)
0
0
0
0
0
CARBON MONOXIDE (CO)
0
0
0
0
0
0
VOLATILE ORGANIC COMPOUNDS (VOC)
Est.
<9.1
<40
>9.2
>40
>9.2
>40
LEAD
0
0
0
0
0
0
OTHER
0
0
1 0
0
0
0
:-' HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE'
HAZARDOUS AIR POLLUTANT
AND CAS NUMBER
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLSILIMITS) (AFTER CONTROLS/LIMITS)
Whir
tons/ r
Ib/hr
tons/ r
Whir
tons/ r
none
TOXIC AIR POLLUTANT EMISSIONS INFORMATION
FOR THIS SOURCE
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO.
EF SOURCE
Ib/hr
Ib/da
Ib/ r
none
Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates)
and describe how these are monitored and with what frequency; and (3) de
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE
Attach Additional Sheets As Necessary
DEQ-CFW 00085897

FORM B
SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES)
REVISED 12101/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate B
EMISSION SOURCE DESCRIPTION: VE North Product
Container Decontamination Process
EMISSION SOURCE ID NO: NS-®
CONTROL DEVICE ID NO(S): NCI)-Hdrl
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S) NEP-Hdrl
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
Vinyl Ethers ("VE") North product containers that are returned from customers must be
decontaminated by venting any residual product (perfluoropropyl vinyl ether, ester vinyl ether, and
perfluorinated sulfonyl vinyl ether) from the containers. The product containers are vented to a
gaseous absorber (NCD-Hdrl), but since the products are not water soluble, none of the emissions
are controlled and all is assumed to vent to the atmosphere.
TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM 131-139 ON THE FOLLOWING PAGES):
❑ Coal,wood,oil, gas, other burner (Form B1) ❑ Woodworking (Form 134) ❑ Manufact. of chemicals/coatings/inks (Form 137)
❑ Int.combustion engine/generator (Form B2) ❑ Coating/finishing/printing (Form 135) ❑ Incineration (Form 138)
❑ Liquid storage tanks (Form B3) ❑ Storage silos/bins (Form 136) ❑x Other (Form 139)
START CONSTRUCTION DAT dune 08
1OPERATION DATE .Tune 08 JDATE
MANUFACTURED: n/a
MANUFACTURER / MODEL NO.: n/a TEXPECTED OP. SCHEDULE: 1 HR/DAY 7 DAY/WK 17 WK/YR
IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): NO NESHAP (SUBPART?): NO MACT (SUBPART?): No
PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25
EXPECTED ANNUAL HOURS OF OPERATION: 374 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: 0 % OPACITY
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION'FOR
THIS SOURCE
AIR POLLUTANT EMITTED
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
PARTICULATE MATTER (PM)
0
0
0
0
0
0
PARTICULATE MATTER<10 MICRONS (PM10)
0
0
0
0
0
0
PARTICULATE MATTER<2.5 MICRONS (PM2.5)
0
0
0
0
0
0
SULFUR DIOXIDE (S02)
0
0
0
0
0
0
NITROGEN OXIDES (NOx)
0
0
0
0
0
0
CARBON MONOXIDE (CO)
0
0
0
0
0
0
VOLATILE ORGANIC COMPOUNDS (VOC)
Est.
2.4
10.3
4.7
20.6
4.7
20.6
LEAD
0
0
0
0
0
0
OTHER
0
0
0
1 0
0
0
HAZARDOUS AIR POLLUTANT EMISSIONS
INFORMATION
FOR THIS SOURCE
HAZARDOUS AIR POLLUTANT
AND CAS NUMBER
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
none
TOXIC:AIR LUTANT EMISSIONS INFORMATION
FOR THIS SOURCE
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO.
EF SOURCE
Ib/hr
Iblda
Ib! r
none
Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates)
and describe how these are monitored and with what frequency; and (3) de
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE
Attach Additional Sheets As Necessary
DEQ-CFW 00085898

FORM B
SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES)
REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate 1 B
EMISSION SOURCE DESCRIPTION: VE South Product
Container Decontamination Process
EMISSION SOURCE ID NO: NS-P
CONTROL DEVICE ID NO(S): NCD-Hdr2
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S) NEP-Hdr2
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
Vinyl Ethers ("VE") South product containers that are returned from customers must be
decontaminated by venting any residual product (perfluoromethyl vinyl ether or perfluoroethyl
vinyl ether) from the containers. The product containers are vented to a gaseous absorber (NCD-
Hdr2), but since the products are not seater soluble, none of the emissions are controlled and all is
assumed to vent to the atmosphere.
TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES):
❑ Coal,wood,oil, gas, other burner (Form 131) ❑ Woodworking (Form 134) ❑ Manufact. of chemicals/coatings/inks (Form 137)
❑ Int.combustion engine/generator (Form 132) ❑ Coating/finishing/printing (Form 135) ❑ Incineration (Form 138)
❑ Liquid storage tanks (Form 133) ❑ Storage silos/bins (Form 136) N1 Other (Form 139)
START CONSTRUCTION DAT June 08
1OPERATION DATE .tune 08 IDATE
MANUFACTURED: n/a
MANUFACTURER / MODEL NO.: n/a 1EXPECTED OP. SCHEDULE: 2 HR/DAY 7 DAY/WK 52 WK/YR
IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): NO NESHAP (SUBPART?): No MACT (SUBPART?): No
PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25
EXPECTED ANNUAL HOURS OF OPERATION: 693 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: 0 % OPACITY
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION
FOR THIS SOURCE
AIR POLLUTANT EMITTED
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons! r
lb/hr
tons/ r
PARTICULATE MATTER (PM)
0
0
0
0
0
0
PARTICULATE MATTER<10 MICRONS (PM1o)
0
0
0
0
0
0
PARTICULATE MATTER<2.5 MICRONS (PM2.5)
0
0
0
0
0
0
SULFUR DIOXIDE (S02)
0
0
0
0
0
0
NITROGEN OXIDES (NOx)
0
0
0
0
0
0
CARBON MONOXIDE (CO)
0
0
0
0
0
0
VOLATILE ORGANIC COMPOUNDS (VOC)
Est.
2.7
11.6
5.3
23.1
5.3
23.1
LEAD
0
1 0
0
0
0
0
OTHER
0
0
0
0
0
0
HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE
HAZARDOUS AIR POLLUTANT
AND CAS NUMBER
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
none
TOXIC AIR POLLUTANT EMISSIONS INFORMATION
FOR THIS SOURCE
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO.
EF SOURCE
Ib/hr
lb/day
Ib/ r
none
Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates)
and describe how these are monitored and with what frequency; and (3) de
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE B1 THROUGH B9 FORM FOR EACH SOURCE
Attach Additional Sheets As Necessary
DEQ-CFW 00085899

FORM B
SPECIFIC EMISSIONS SOURCE INFORMATION (REQUIRED FOR ALL SOURCES)
REVISED 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate I v l
EMISSION SOURCE DESCRIPTION:
Abrasive Blasting and Painting Building
EMISSION SOURCE ID NO: I-10
CONTROL DEVICE ID NO(S): None
OPERATING SCENARIO 1 OF 1
EMISSION POINT (STACK) ID NO(S) Fugitive
DESCRIBE IN DETAILTHE EMISSION SOURCE PROCESS (ATTACH FLOW DIAGRAM):
On a non -routine basis, equipment will be painted in the already identified insignificant activity
building where abrasive blasting will be conducted. Objects that do not easily fit into the current
Paint Shop (Emission Source ID No. I-7) would be painted in this open structure.
TYPE OF EMISSION SOURCE (CHECK AND COMPLETE APPROPRIATE FORM B1-B9 ON THE FOLLOWING PAGES):
❑ Coal,wood,oil, gas, other burner (Form B1) ❑ Woodworking (Form B4) ❑ Manufact. of chemicals/coatings/inks (Form 137)
❑ Int.combustion engine/generator (Form 132) ❑ Coating/finishing/printing (Form B5) ❑ Incineration (Form BB)
❑ Liquid storage tanks (Form 63) ❑ Storage silos/bins (Form B6) 21 Other (Form B9)
START CONSTRUCTION DAT Existing
OPERATION DATE June 09 JDATE
MANUFACTURED: n/a
MANUFACTURER / MODEL NO.: n/a EXPECTED OP. SCHEDULE: 4 HR/DAY 1 DAY/WK 52 WK/YR
IS THIS SOURCE SUBJECT TO? NSPS (SUBPART?): NO NESHAP (SUBPART?): NO MACT (SUBPART?): No
PERCENTAGE ANNUAL THROUGHPUT (%): JAN-MAR 25 APR-JUN 25 JUL-SEP 25 OCT-DEC 25
EXPECTED ANNUAL HOURS OF OPERATION: 200 IVISIBLE STACK EMISSIONS UNDER NORMAL OPERATION: 0 % OPACITY
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE
AIR POLLUTANT EMITTED
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Ib/hr
tons/ r
Ib/hr
tons/ r
PARTICULATE MATTER (PM)
0
0
0
0
0
0
PARTICULATE MATTER<10 MICRONS (PM10)
0
0
1 0
0
0
0
PARTICULATE MATTER<2.5 MICRONS (PM2.5)
0
0
0
0
0
0
SULFUR DIOXIDE (S02)
0
0
0
0
0
0
NITROGEN OXIDES (NOx)
0
0
0
0
0
0
CARBON MONOXIDE (CO)
0
0
0
0
0
0
VOLATILE ORGANIC COMPOUNDS (VOC)
Est.
<1
1.5
<1
1.5
<1
1.5
LEAD
0
0
0
0
0
0
OTHER
0
0
0
0
0 1
0
HAZARDOUS AIR POLLUTANT EMISSIONS INFORMATION FOR THIS SOURCE
HAZARDOUS AIR POLLUTANT
AND CAS NUMBER
SOURCE
OF
EMISSION
FACTOR
EXPECTED ACTUAL
(AFTER CONTROLS/LIMITS)
POTENTIAL EMISSIONS
(BEFORE CONTROLS/LIMITS) (AFTER CONTROLS/LIMITS)
Ib/hr
tons/ r
Whir
tons/ r
Ib/hr
tons/ r
none
TOXIC AIR POLLUTANT EMISSIONS INFORMATION
FORMS SOURCE
INDICATE EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
TOXIC AIR POLLUTANT AND CAS NO.
EF SOURCE
Ib/hr
lb/day
Ib/ r
none
Attachments: (1) emissions calculations and supporting documentation; (2) indicate all requested state and federal enforceable permit limits (e.g. hours of operation, emission rates)
and describe how these are monitored and with what frequency; and (3) de
COMPLETE THIS FORM AND COMPLETE AND ATTACH APPROPRIATE 89 THROUGH B9 FORM FOR EACH SOURCE
Attach Additional Sheets As Necessary
DEQ-CFW 00085900

FORM B1
EMISSION SOURCE (WOOD, COAL, OIL, GAS, OTHER FUEL -FIRED BURNER)
REVISED 12/01/01 NCDENR/Division of Air Qualitv - Application for Air Permit to Construct/Operate FB1
EMISSION SOURCE DESCRIPTION:
Natural gas -fired or No. 2 oil -fired boiler
EMISSION SOURCE ID NO: PS-3
CONTROL DEVICE ID NO(S): n/a
OPERATING SCENARIO: 1 OF 1
EMISSION POINT (STACK) ID NO(S): PEP-2
DESCRIBE USE: 7 PROCESS HEAT ❑ SPACE HEAT ❑ ELECTRICAL GENERATION
❑ CONTINUOUS USE ❑ STAND BY / EMERGENCY ❑ OTHER (DESCRIBE):
HEATING MECHANISM: ❑ INDIRECT DIRECT
MAX. FIRING RATE (MMBTU/HOUR): 97.0
WOOD -FIRED BURNER
WOOD TYPE: ❑ BARK ❑ WOOD/BARK ❑ WET WOOD ❑ DRY WOOD ❑ OTHER (DESCRIBE):
PERCENT MOISTURE OF FUEL:
❑ UNCONTROLLED ❑ CONTROLLED WITH FLYASH REINJECTION ❑ CONTROLLED W/O REINJECTION
FUEL FEED METHOD:
HEAT TRANSFER MEDIA: ❑ STEAM ❑ AIR ❑ OTHER
METHOD OF TUBE CLEANING:
CLEANING SCHEDULE:
COAL-FIRED BURNER
TYPE OF BOILER
IF OTHER DESCRIBE:
PULVERIZED
❑ WET BED
❑ DRY BED
OVERFEED STOKER
❑ UNCONTROLLED
❑ CONTROLLED
UNDERFEED STOKER
❑ UNCONTROLLED
❑ CONTROLLED
SPREADER STOKER
❑ UNCONTROLLED
❑ FLYASH REINJECTION
❑ NO FLYASH REINJECTION
FLUIDIZED BED
❑ CIRCULATING
❑ RECIRCULATING
METHOD OF LOADING: ❑ CYCLONE ❑ HANDFIRED ❑ TRAVELING GRATE ❑ OTHER (DESCRIBE):
METHOD OF TUBE CLEANING:
CLEANING SCHEDULE:
OIUGAS-FIRED BURNER
TYPE OF BOILER: ❑ UTILITY 0 INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL
TYPE OF FIRING: 0 NORMAL ❑ TANGENTIAL 0 LOW NOX BURNERS ❑ NO LOW NOX BURNER
METHOD OF TUBE CLEANING: Sootblowing on tube
exterior, none on interior
CLEANING SCHEDULE: When firing natural gas once
per year; when on #2 fuel oil once a week
OTHER FUEL -FIRED BURNER
TYPE OF FUEL: PERCENT MOISTURE:
TYPE OF BOILER: ❑ UTILITY ❑ INDUSTRIAL ❑ COMMERCIAL ❑ RESIDENTIAL
TYPE OF FIRING: TYPE OF CONTROL (IF ANY): FUEL FEED METHOD:
METHOD OF TUBE CLEANING: CLEANING SCHEDULE:
FUEL USAGE INCLUDE STARTUPIBACKU'P FUELS
FUEL TYPE
UNITS
MAXIMUM DESIGN
CAPACITY (UNIT/HR)
REQUESTED CAPACITY
LIMITATION (UNIT/HR)
Natural Gas
std. cubic feet
95,098
95,098
No. 2 Fuel Oil
gallons
693
693
FUEL CHARACTERISTICS
(COMPLETE ALL THAT ARE APPLICABLE)
FUEL TYPE
SPECIFIC
BTU CONTENT
SULFUR CONTENT
(% BY WEIGHT)
ASH CONTENT
(% BY WEIGHT)
Natural Gas
1,020 BTU/scf
0.05
0
No. 2 Fuel Oil
140,000 BTU/gallon
0.05
0
SAMPLING PORTS, COMPLIANT WITH EPA METHOD 1 WILL BE INSTALLED ON THE STACKS El YES ❑ NO
COMMENTS:
The low-NOx burner must achieve a NOx reduction of at least 35% to avoid the applicability of the
Prevention of Significant Deterioration rule (NCAC 2D.0530).
Attach Additional Sheets As Necessary
DEQ-CFW 00085901

FORM B5
EMISSION SOURCE (COATING/FINISHING/PRINTING)
REVISED 12/01 /01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate
g5
EMISSION SOURCE DESCRIPTION:
Abrasive blasting and painting building
EMISSION SOURCE ID NO(S): 1-10
CONTROL DEVICE ID NO(S): none
OPERATING SCENARIO: OF
EMISSION POINT (STACK) ID NO(S) Fugitive
TYPE OF OPERATION: ❑ PRINTING ❑ COATING El OTHER FINISHING (Describe in process)
IS THIS OPERATION: ❑ CONTINUOUS 21 NON -CONTINUOUS (Batch)
DESCRIBE IN DETAIL THE PROCESS (ATTACH FLOW DIAGRAM):
On a non -routine basis, equipment will be painted in the already identified insignificant activity
building where abrasive blasting will be conducted.
WHAT IS BEING PRINTED/COATED/OR FINISHEI Piping and other metal pieces and equipment
CONTINUOUS TYPE OF PRINTING/COATING ❑ FLEXOGRAPHIC ❑ ROTOGRAVURE ❑ LITHOGRAPHIC ❑ OFFSET
❑ OTHER (PLEASE SPECIFY):
NUMBER OF STATIONS:
IWEIGHT OF MATERIAL BEING PRINTED OR COATED (LB/FT2):
MAXIMUM COVERAGE OF INK/COATING (LB/FT2): IMAXIMUM
SPEAD (FT/MIN):
MAXIMUM WIDTH OF WEB BEING PRINTED OR COATED (INCHES): JACTUAL
SPEED (FT/MIN):
NON -CONTINUOUS ITYPE OF SOURCE: 0 STATION ❑ BOOTH ❑ WASH -OFF TANK ❑ OFFSET
❑ DIP TANK ❑ OTHER (PLEASE SPECIFY):
WEIGHT OF ITEM BEING COATED/PRINTED (LB/UI 1 lb. to >1000 lb.
UNIT: Piping and other metal pieces
MAXIMUM DIMENSIONS OF EACH ITEM (INCHE LENGTH: 240 WIDTH: 48 MAXIMUM COATED/PRINTED PER HOU 5
METHOD OF SPRAY: ❑ AIRLESS 7 AIR ATOMIZE ❑ ELECTROSTATIC ❑ HVLP ❑ OTHER
NUMBER OF GUNS PER STATION/SOUR( 1 TRANSFER EFFICIENCY:
EXHAUST CONTROL: 0 NONE ❑ DRY FILTER ❑ WATERWASH ❑ BAFFLES ❑ OTHER
PARTICULATE CAPTURE EFFICIENCY:
COATING/SOLVENT USE (INCLUDE MSDS FOR EACH COATING)
ACTUAL USAGE
MAXIMUM DESIGN CAPACITY
STATION NO.
COATING/SOLVENT PRODUCT NAME AND FORMU
NUMBER APPLIED AT THIS STATION/SOURCE
UNIT/HR
UNIT/YR
UNIT/HR
UNIT/YR
UNITS
DuPont Imron (2.8 lb. VOC per gallon)
<1
63
n/a
n/a
Gallon
DuPont Dulux (4.2 lb. VOC per gallon)
<1
177
n/a
n/a
Gallon
DuPont 25P (2.8 lb. VOC per gallon)
<1
108
n1a
nla
Galion
DuPont Primer (3.5 lb. VOC per gallon)
<1
50
n/a
n/a
Gallon
DuPont Thinner (8.3 lb. VOC per gallon)
<1
100
n/a
nla
Gallon
CLEAN-UP
DuPont Thinner (8.3 lb. VOC per gallon)
<1
100
n/a
n/a
Gallon
ATTACH ADDITIONAL SHEETS AS NEEDED
METHOD OF HEATING: ❑ STEAM ❑ DIRECT FIRED ❑ ELECTRIC ❑ OTHER:
FUEL USED: n/a - Building is not heated
TOTAL MAXIMUM FIRING RATE (MILLION BTU/HI
MAXIMUM ANNUAL FUEL USE UNITS
MAXIMUM HOURLY FUEL USE:
ACTUAL ANNUAL FUEL USE: UNITS
ACTUAL HOURLY FUEL USE:
COMMENTS:
Any painting activity in this building would be taking the place of current painting activities that occurs
in the site's insignificant activity Paint Shop (Emission Source ID No. 1-7). Only larger objects that do
not easily fit in the Paint Shop would be painted in this building.
Attach Additional Sheets As Necessary
DEQ-CFW 00085902

FORM B9
EMISSION SOURCE (OTHER)
REVISED: 12/01/01 MMPKIRlnivicinn of Air Otinlity - Annlicatinn for Air Permit to Construct/Ooerate B9
EMISSION SOURCE DESCRIPTION: HFPO Product
Container Decontamination Process
EMISSION SOURCE ID NO: NS-N
CONTROL DEVICE ID NO(S): NCD-Hdrl
OPERATING SCENARIO: 1 OF 1
EMISSION POINT (STACK) ID NO(S) NEP-Hdrl
DESCRIBE IN DETAIL THE PROCESS (ATTACH FLOW DIAGRAM):
HFPO product containers that are returned from customers must be decontaminated by venting
any residual product (hexafluoropropylene oxide) before the containers are reused. The
container is alternately put under vacuum and then filled with nitrogen gas several times to
expedite the removal of the residual product. The product containers are vented to a gaseous
absorber (NCD-Hdrl ), but since the product is not water soluble, none of the emissions are
controlled and all is assumed to vent to the atmosphere.
MATERIALS; ENTERING PROCESS - CONTINUOUS PROCESS
MAX. DESIGN
CAPACITY UNIT/HR
REQUESTED CAPACITY
LIMITATION UNIT/HR
TYPE
UNITS
Not applicable ("N/A"
MATERIALS ENTERING PROCESS' - =BATCH OPERATION
MAX. DESIGN
CAPACITY UNIT/BATCH
REQUESTED CAPACITY
LIMITATION UNIT/BATCH
TYPE
UNITS
NIA
MAXIMUM DESIGN BATCHES / HOUR):
REQUESTED LIMITATION (BATCHES / HOUR): (BATCHES/YR):
FUEL USED: NIA
TOTAL MAXIMUM FIRING RATE (MILLION BTU/HR): NIA
MAX. CAPACITY HOURLY FUEL USE: N/A
REQUESTED CAPACITY ANNUAL FUEL USE: N/A
COMMENTS:
Process flow diagram
Vacuum _♦ NCD- Atmosphere
System Hdrl
Nitrogen
HFPO Product
Container
Attach Additional Sheets as Necessary
DEQ-CFW 00085903

EMISSION SOURCE (OTHER)
RF\/ISFn- i2lnil N Llr`nCKIDIM Aci— ^f Ai, rl—lif- _ Annli—tinn fnr Air Pcrmit to rnnctrnrt/nnPratP B9
EMISSION SOURCE DESCRIPTION: VE North Product
Container Decontamination Proces]EMISSION
EMISSION SOURCE ID NO: NS-®
CONTROL DEVICE ID NO(S): NCD-Hdr1
OPERATING SCENARIO: 1 OF 1
POINT (STACK) ID NO(S) NEP-Hdr1
DESCRIBE IN DETAIL THE PROCESS (ATTACH FLOW DIAGRAM):
Vinyl Ethers ("VE") North product containers that are returned from customers must be
decontaminated by venting any residual product (perfluoropropyl vinyl ether, ester vinyl ether,
and perfluorinated sulfonyl vinyl ether) before the containers are reused. The container is
alternately put under vacuum and then filled with nitrogen gas several times to expedite the
removal of the residual product. The product containers are vented to a gaseous absorber (NCD-
Hdr2), but since the product is not water soluble, none of the emissions are controlled and all is
assumed to vent to the atmosphere.
MATERIALS ENTERING PROCESS - CONTINUOUS PROCESS
MAX. DESIGN
CAPACITY UNIT/HR
REQUESTED CAPACITY
LIMITATION UNIT/HR
TYPE
UNITS
Not applicable ("N/A")
MATERIALS ENTERING PROCESS - BATCH OPERATION
MAX. DESIGN
CAPACITY UNIT/BATCH
REQUESTED CAPACITY
LIMITATION UNIT/BATCH
TYPE
UNITS
NIA
MAXIMUM DESIGN BATCHES / HOUR):
REQUESTED LIMITATION (BATCHES / HOUR): (BATCHES/YR):
FUEL USED: N/A
ITOTAL MAXIMUM FIRING RATE (MILLION BTU/HR): N/A
MAX. CAPACITY HOURLY FUEL USE: NIA
REQUESTED CAPACITY ANNUAL FUEL USE: NIA
COMMENTS:
Process flow diagram
Vacuum _10 NCD- Atmosphere
System Hdr1
Nitrogen
VE North Product IF
Container
Attach Additional Sheets as Necessary
DEQ-CFW 00085904

EMISSION SOURCE (OTHER)
REVISED: 12/01/01 nICnCPJP1ni,A.in of Air rl. mlih, - Annlicnfinn fnr Air Permit to Cnnctrimt/Onarate B+`'
EMISSION SOURCE DESCRIPTION: VE South Product
Container Decontamination Process
EMISSION SOURCE ID NO: NS-P
CONTROL DEVICE ID NO(S): NCD-Hdr2
OPERATING SCENARIO: 1 OF 1
EMISSION POINT (STACK) ID NO(S) NEP-Hdr2
DESCRIBE IN DETAIL THE PROCESS (ATTACH FLOW DIAGRAM):
Vinyl Ethers ("VE") South product containers that are returned from customers must be
decontaminated by venting any residual product (perfluoromethyl vinyl ether or perfluoroethyl
vinyl ether) before the containers are reused. The container is alternately put under vacuum and
then filled with nitrogen gas several times to expedite the removal of the residual product. The
product containers are vented to a gaseous absorber (NCD-Hdr2), but since the product is not
water soluble, none of the emissions are controlled and all is assumed to vent to the atmosphere.
MATERIALS ENTERING PROCESS - CONTINUOUSPROCESS :
MAX. DESIGN
CAPACITY UNIT/HR
REQUESTED CAPACITY
LIMITATION UNIT/HR
TYPE
UNITS
Not applicable ("NIA"
MATERIALS ENTERING PROCESS - BATCH OPERATION'
MAX. DESIGN
CAPACITY UNIT/BATCH
REQUESTED CAPACITY
LIMITATION UNIT/BATCH
TYPE
UNITS
N/A
MAXIMUM DESIGN BATCHES / HOUR):
REQUESTED LIMITATION (BATCHES / HOUR): (BATCHES/YR):
FUEL USED: NIA
TOTAL MAXIMUM FIRING RATE (MILLION BTU/HR): N/A
MAX. CAPACITY HOURLY FUEL USE: N/A
REQUESTED CAPACITY ANNUAL FUEL USE: NIA
COMMENTS:
Process flow diagram
Vacuum _10 NCD- 10 Atmosphere
System Hdr2
Nitrogen
VE South Product
Container
Attach Additional Sheets as Necessary
DEQ-CFW 00085905

FORM C6
CONTROL DEVICE (GASEOUS ABSORBER)
REVISED 11/29/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate r C6
AS REQUIRED 15A NCAC 20.0112 THIS FORM MUST BE SEALED BY A PROFESSIONAL ENGINEER P.E. LICENSED /N NORTH CAROLINA.
CONTROL DEVICE ID NO: NCD-Hdr1
CONTROLS EMISSIONS FROM WHICH EMISSION SOURCE ID NO, NS-N, NS-O
EMISSION POINT ID NO(S): NEP-Hdr1
1POSITION IN SERIES OF CONTROLS: NO. 1 OF 1 UNITS
MANUFACTURER: SGL Industries
MODEL NO: DuPont Engineering Design
DATE MANUFACTURED:
PROPOSED OPERATION DATE: Already permitted and in operation
OPERATING SCENARIO:
PROPOSED CONSTRUCTION DATE: Already permitted and in operation
1 OF 1
DESCRIBE CONTROL SYSTEM:
2.2 sq. ft. cross section baffle plate tower 20 ft. high with counter -current contact of vent gases with
caustic solution. Note that scrubbers are already permitted and in operation and this application
simply documents additional possible loading from newly permitted processes.
POLLUTANT(S) COLLECTED: VOC
BEFORE CONTROL EMISSION RATE (LB/HR): <13.8
CAPTURE EFFICIENCY: 0 % % % %
CONTROL DEVICE EFFICIENCY: 0 % % % %
CORRESPONDING EFFICIENCY: 0 % % % %
EFFICIENCY DETERMINATION CODE: n/a
TOTAL EMISSION RATE (LB/HR): <13.8
PRESSURE DROP (IN. H20): MIN ~0 MAX ~8
WARNING ALARM? 17 YES ❑ NO
INLET TEMP. (OF): MIN Amb. MAX Amb.
OUTLET TEMPERATURE (OF): MIN Amb. MAX Amb.
INLET AIR FLOW RATE (ACFM): -300 (max)
GAS VELOCITY (FT/SEC): --5.25 (max)
TOTAL GAS PRESSURE (PSIG): ~0.5
IGAS DEW POINT (°F):
TYPE OF SYSTEM:
PACKED COLUMN
TYPE OF PACKING:
COLUMN LENGTH (FT):
COLUMN DIAMETER (FT):
PLATE COLUMN
IPLATE SPACING (INCHES): 9
ICOLUMN LENGTH (FT): 25
ICOLUMN DIAMETER (FT): 1.7
ADDITIVE LIQUID SCRUBBING MEDIUM: Caustic solution
PERCENT RECIRCULATED Approximately 100%
MINIMUM LIQUID INJECTION RATE (GAUMIN): >7000 k /hr
MAKE UP RATE (GAL/MIN): n/a FOR ADDITIVE (GAL/MIN): -0.1
pH RANGE: Normally >10
METHOD pH MONITORING: In -line pH meter
DESCRIBE MAINTENANCE PROCEDURES:
Generally speaking routine maintenance tasks are minimal. As necessary work is performed during
annual shutdown.
DESCRIBE ANY FIRE DETECTION DEVICES AND ANY MEANS OF FIRE SUPPRESSION:
NA
DESCRIBE ANY MONITORING DEVICES, GAUGES, TEST PORTS, ETC:
Based on testing, scrubber circulation rate is monitored to assure proper operation. Column
pressure and effluent liquid pH are also monitored.
ATTACH A DIAGRAM OF THE RELATIONSHIP OF CONTROL DEVICE TO ITS EMISSION SOURCE(S):
See process flow diagram on Form B9's in this application.
Attach Additional Sheets As Necessary
DEQ-CFW 00085906

FORM C6
CONTROL DEVICE (GASEOUS ABSORBER)
RFVISFD 11 /29/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate C6
AS REQUIRED 15ANCACIQ .0112 THIS FORM MUST BE SEALED BYA PROFESSIONAL ENGINEER P.E. LICENSED IN NORTH CAROLINA.
CONTROL DEVICE ID NO: NCD-Hdr2
ICONTROLS EMISSIONS FROM WHICH EMISSION SOURCE ID NO, NS-P
EMISSION POINT ID NO(S): NEP-Hdr2
POSITION IN SERIES OF CONTROLS: NO. 1 OF 1 UNITS
MANUFACTURER: SGL Industries
MODEL NO: DuPont Engineering Design
DATE MANUFACTURED:
PROPOSED OPERATION DATE: Already permitted and in operation
OPERATING SCENARIO:
PROPOSED CONSTRUCTION DATE: Already permitted and in operation
1 OF 1
DESCRIBE CONTROL SYSTEM:
2.2 sq. ft. cross section baffle plate tower 20 ft. high with counter -current contact of vent gases with
caustic solution. Note that scrubbers are already permitted and in operation and this application
simply documents additional possible loading from In
POLLUTANT(S) COLLECTED: VOC
BEFORE CONTROL EMISSION RATE (LB/HR): 2.4
CAPTURE EFFICIENCY: 0 % % % %
CONTROL DEVICE EFFICIENCY: 0 % % % %
CORRESPONDING EFFICIENCY: 0 % % % %
EFFICIENCY DETERMINATION CODE: n/a
TOTAL EMISSION RATE (LB/HR): 2.4
PRESSURE DROP (IN. H20): MIN ~0 MAX ~8
WARNING ALARM? I] YES ❑ NO
INLET TEMP. (°F): MIN Amb. MAX Amb.
OUTLET TEMPERATURE (°F): MIN Amb. MAX Amb.
INLET AIR FLOW RATE (ACFM): -300 (max)
GAS VELOCITY (FT/SEC): -5.25 (max)
TOTAL GAS PRESSURE (PSIG): -0.5
GAS DEW POINT (OF):
TYPE OF SYSTEM:
PACKED COLUMN
ITYPE OF PACKING:
ICOLUMN LENGTH (FT):
ICOLUMN DIAMETER (FT):
PLATE COLUMN
IPLATE SPACING (INCHES): 9
ICOLUMN LENGTH (FT). 25
ICOLUMN DIAMETER (FT): 1.7
ADDITIVE LIQUID SCRUBBING MEDIUM: Caustic Solution
PERCENT RECIRCULATED. Approximately 100%
MINIMUM LIQUID INJECTION RATE (GAUMIN): >7000 kg/hr
IMAKE UP RATE (GAL/MIN): n/a FOR ADDITIVE (GAL/MIN): -0.1
pH RANGE: Normally >10
IMETHOD pH MONITORING: In -line pH meter
DESCRIBE MAINTENANCE PROCEDURES:
Generally speaking routine maintenance tasks are minimal. As necessary work is performed during
annual shutdown.
DESCRIBE ANY FIRE DETECTION DEVICES AND ANY MEANS OF FIRE SUPPRESSION:
NA
DESCRIBE ANY MONITORING DEVICES, GAUGES, TEST PORTS, ETC:
Based on testing, scrubber circulation rate is monitored to assure proper operation. Column
pressure and effluent liquid pH are also monitored.
ATTACH A DIAGRAM OF THE RELATIONSHIP OF CONTROL DEVICE TO ITS EMISSION SOURCE(S):
See process flow diagram on Form 139's in this application.
Attach Additional Sheets As Necessary
DEQ-CFW 00085907

FORM D1
FACILITY -WIDE EMISSIONS SUMMARY
REVISED 12/01/01 NCnFNR/nivisinn of Air Onality -A Iiratinnfor Air Permit to Construct/Ooerate D1
CRITERIA AIR POLLUTANT EMISSIONS INFORMATION - FACILITY -WIDE
EXPECTED ACTUAL EMISSIONS
POTENTIAL EMISSIONS
POTENTIAL EMISSIONS
(AFTER CONTROLS !
(BEFORE CONTROLS /
(AFTER CONTROLS /
LIMITATIONS)
LIMITATIONS)
LIMITATIONS
AIR POLLUTANT EMITTED
tons/ r
tons/ r
tons! r
Unchanged (site is
Unchanged (site is
PARTICULATE MATTER (PM)
44
Major Source)
Major Source)
Unchanged (site is
Unchanged (site is
PARTICULATE MATTER < 10 MICRONS (PM10)
37
Major Source)
Major Source)
Unchanged (site is
Unchanged (site is
PARTICULATE MATTER < 2.5 MICRONS (PM2.5)
24
Major Source)
Major Source)
Unchanged (site is
Unchanged (site is
SULFUR DIOXIDE (S02)
600
Major Source)
Major Source)
Unchanged (site is
Unchanged (site is
NITROGEN OXIDES (NOx)
130
Major Source)
Major Source)
Unchanged (site is
Unchanged (site is
CARBON MONOXIDE (CO)
18
Major Source)
Major Source)
VOLATILE ORGANIC COMPOUNDS (VOC)
380
Major Source
Major Source
LEAD
OTHER
HAZARDOUS AIR POLLUTANT
EMISSIONS INFORMATION - FACILITY -WIDE
EXPECTED ACTUAL EMISSIONS
POTENTIAL EMISSIONS
POTENTIAL EMISSIONS
(AFTER CONTROLS /
(BEFORE CONTROLS /
(AFTER CONTROLS /
LIMITATIONS)
LIMITATIONS)
LIMITATIONS
HAZARDOUS AIR POLLUTANT EMITTED
CAS NO.
tons/ r
tons/ r
tons/ r
>25 (site is Major
>25 (site is Major
Total E vAPs
>25 (site is Major Source)
Source)
Source)
TOXIC AIR POLLUTANT EMISSIONS
INFORMATION - FACILITY -WIDE -
INDICATE REQUESTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS. EMISSIONS ABOVE THE TOXIC PERMIT EMISSION RATE (TPER) IN
15A NCAC 2Q .0711 MAY REQUIRE AIR DISPERSION MODELING. USE NETTING FORM D2 IF NECESSARY.
ModelingRe uired ?
TOXIC AIR POLLUTANT EMITTED
CAS NO.
Ib/hr
lb/day
lb/year
Yes
No
No TAPS will be emitted from this
X
modification.
COMMENTS:
As indicated above, the site is a major source for criteria pollutants and HAPs. The proposed operation of the
Natural Gas -Fired or No. 2 Fuel Oil -Fired Boiler (ID No. PS-C) will not change any of the current classifications.
Combustion sources are exempt from the air toxics program per 2Q.0702(a)(18). A PSD avoidance condition is
being requested for the HFPO Product Container Decontamination Process (ID No. NS-N).
Attach Additional Sheets as Necessary
DEQ-CFW 00085908

FORM D2
AIR POLLUTANT NETTING WORKSHEET
Revised:12101101 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D2
PURPOSE OF NETTING: ❑ AIR TOXICS ❑ PSD (100/250 tons per year) ❑ PSD SIGNIFICANT LEVELS
AIR POLLUTANT: None CAS NO.:
EMISSION SOURCE ID NOS.:
SECTION A -EMISSION OFFSETTING ANALYSIS'FOR MODIFIED/NEW SOURCES
Summarize in this section
using 'the;B forms
EMISSIONS - USE APPROPRIATE COLUMNS ONLY
LB/YEAR
LB/DAY
LB/HR
MODIFICATION
INCREASE
- MINUS -
MINUS -
- MINUS -
MINUS -
MODIFICATION
DECREASE
= EQUALS =
= EQUALS =
= EQUALS =
= EQUALS =
NET CHANGE
FROM MODIFICATION
S'ECTION'B
- FACILITY -WIDE EMISSION NETTING ANALYSIS
CREDITABLE
INCREASE
- MINUS -
- MINUS -
- MINUS -
MINUS -
CREDITABLE
DECREASE
= EQUALS =
= EQUALS =
= EQUALS =
= EQUALS =
NET CREDITABLE
CHANGE
SECTION C - FACILITY -WIDE EMISSIONS -
TOTAL FACILITY
EMISSIONS
TPER LEVELS (2Q .0711)
CHECK HERE IF AN AIR DISPERSION MODELING ANALYSIS IS REQUIRED ❑
Attach Additional Sheets As Necessary
DEQ-CFW 00085909

FORM D3
MODELING REQUEST FORMS (3 pages)
REVISED: 02/20/03 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D3
If the applicant desires, the NCDAQ/AQAB will perform the initial modeling compliance demonstration using EPA approved screening
and, if applicable and where possible, refined models. If the model results indicate the facility will be unable to demonstrate compliance
with applicable Acceptable Ambient Level(s) the applicant will be notified and will be required to perform the compliance demonstration
using established modeling protocol and modeling analysis requirements as defined in the North Carolina Administrative Code 15A
NCAC 2D .1100 and 2Q .0700 and in the Guidelines for Evaluating the Impacts of Toxic Pollutants in North Carolina.
To perform the dispersion modeling compliance demonstration, the AQAB will require the following data:
1 INTRODUCTION
Provide a brief description of the modification and/or addition necessitating the toxic modeling request:
The Product Container Decontamination Processes (ID Nos. NS-N, NS-O, NS-P) will have no
emissions of Toxic Air Pollutants. The natural gas -fired or No. 2 fuel oil -fired boiler (ID No. PS-3)
is exempt from the Air Toxics Program. Therefore, modeling is neither needed nor requested.
Subsequently, pages 2 and 3 of this form are not included in this application.
2. EMISSIONS.DATA - Facility -wide emissions, by source, of all modeled toxics.
TOXIC AIR POLLUTANT TAP
MAXIMUM TOXIC AIR POLLUTANT TAP EMISSIONS After Controls
Emission Point ID
Ibs/ ear
Ibs/da
Ibs/hr
I
Attach Additional Sheets As Necessary rage ! U1 a
DEQ-CFW 00085910

FORM D4
EXEMPT AND INSIGNIFICANT ACTIVITIES SUMMARY
RF\/ISFT iwn1/01 NCnFNR/nivicinn of Air Qimlity - Annliratinn for Air Permit to Construct/oDerate D�
ACTIVITIES EXEMPTED PER 2Q .0102 OR
INSIGNIFICANT ACTIVITIES PER 2Q .0503 FOR TITLE V SOURCES
DESCRIPTION OF EMISSION SOURCE
SIZE OR
PRODUCTION
RATE
BASIS FOR EXEMPTION OR
INSIGNIFICANT ACTIVITY
1.
Abrasive blasting and painting
building (ID No. 1-10)
Less than 5 tons
of VOC is emitted
per year
Based on normal painting activity for
this site, the VOC emissions from
paints is estimated to be 1.5 tons/year.
2.
3.
4.
5.
6.
7.
8.
Attach Additional Sheet As Necessary
DEQ-CFW 00085911

FORM D
TECHNICAL ANALYSIS TO SUPPORT PERMIT APPLICATION
REVISED: 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate D5
PROVIDE DETAILED TECHNICAL CALCULATIONS TO SUPPORT ALL EMISSION, CONTROL, AND REGULATORY
DEMONSTRATIONS MADE IN THIS APPLICATION. INCLUDE A COMPREHENSIVE PROCESS FLOW DIAGRAM AS
NECESSARY TO SUPPORT AND CLARIFY CALCULATIONS AND ASSUMPTIONS. ADDRESS THE
FOLLOWING SPECIFIC ISSUES ON SEPARATE PAGES:
A.
SPECIFIC EMISSIONS SOURCE (EMISSION INFORMATION) (FORM B) - SHOW CALCULATIONS USED, INCLUDING EMISSION FACTORS,
MATERIAL BALANCES, AND/OR OTHER METHODS FROM WHICH THE POLLUTANT EMISSION RATES IN THIS APPLICATION WERE DERIVED.
INCLUDE CALCULATION OF POTENTIAL BEFORE AND, WHERE APPLICABLE, AFTER CONTROLS. CLEARLY STATE ANY ASSUMPTIONS MADE
AND PROVIDE ANY REFERENCES AS NEEDED TO SUPPORT MATERIAL BALANCE CALCULATIONS.
B.
SPECIFIC EMISSION SOURCE (REGULATORY INFORMATION)(FORM E2 - TITLE V ONLY) - PROVIDE AN ANALYSIS OF ANY REGULATIONS
APPLICABLE TO INDIVIDUAL SOURCES AND THE FACILITY AS A WHOLE. INCLUDE A DISCUSSION OUTING METHODS (e.g. FOR TESTING
AND/OR MONITORING REQUIREMENTS) FOR COMPLYING WITH APPLICABLE REGULATIONS, PARTICULARLY THOSE REGULATIONS LIMITING
EMISSIONS BASED ON PROCESS RATES OR OTHER OPERATIONAL PARAMETERS. PROVIDE JUSTIFICATION FOR AVOIDANCE OF ANY
FEDERAL REGULATIONS (PREVENTION OF SIGNIFICANT DETERIORATION (PSD), NEW SOURCE PERFORMANCE STANDARDS (NSPS),
NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS (NESHAPS), TITLE V), INCLUDING EXEMPTIONS FROM THE FEDERAL
REGULATIONS WHICH WOULD OTHERWISE BE APPLICABLE TO THIS FACILITY. SUBMIT ANY REQUIRED TO DOCUMENT COMPLIANCE WITH
ANY REGULATIONS. INCLUDE EMISSION RATES CALCULATED IN ITEM "A" ABOVE, DATES OF MANUFACTURE, CONTROL EQUIPMENT, ETC.
TO SUPPORT THESE CALCULATIONS.
C.
CONTROL DEVICE ANALYSIS (FORM C) - PROVIDE A TECHNICAL EVALUATION WITH SUPPORTING REFERENCES FOR ANY CONTROL
EFFICIENCIES LISTED ON SECTION C FORMS, OR USED TO REDUCE EMISSION RATES IN CALCULATIONS UNDER ITEM "A" ABOVE. INCLUDE
PERTINENT OPERATING PARAMETERS (e.g. OPERATING CONDITIONS, MANUFACTURING RECOMMENDATIONS, AND PARAMETERS AS
APPLIED FOR IN THIS APPLICATION) CRITICAL TO ENSURING PROPER PERFORMANCE OF THE CONTROL DEVICES). INCLUDE AND
LIMITATIONS OR MALFUNCTION POTENTIAL FOR THE PARTICULAR CONTROL DEVICES AS EMPLOYED AT THIS FACILITY. DETAIL
PROCEDURES FOR ASSURING PROPER OPERATION OF THE CONTROL DEVICE INCLUDING MONITORING SYSTEMS AND MAINTENANCE TO
BE PERFORMED.
D.
PROCESS AND OPERATIONAL COMPLIANCE ANALYSIS - (FORM E3 - TITLE V ONLY) - SHOWING HOW COMPLIANCE WILL BE ACHIEVED
WHEN USING PROCESS, OPERATIONAL, OR OTHER DATA TO DEMONSTRATE COMPLIANCE. REFER TO COMPLIANCE REQUIREMENTS IN
THE REGULATORY ANALYSIS IN ITEM "B" WHERE APPROPRIATE. LIST ANY CONDITIONS OR PARAMETERS THAT CAN BE MONITORED AND
REPORTED TO DEMONSTRATE COMPLIANCE WITH THE APPLICABLE REGULATIONS.
E.
PROFESSIONAL ENGINEERING SEAL - PURSUANT TO 15A NCAC 2Q .0112 "APPLICATION REQUIRING A PROFESSIONAL ENGINEERING SEAL,"
A PROFESSIONAL ENGINEER REGISTERED IN NORTH CAROLINA SHALL BE REQUIRED TO SEAL TECHNICAL PORTIONS OF THIS
APPLICATION FOR NEW SOURCES AND MODIFICATIONS OF EXISTING SOURCES. (SEE INSTRUCTIONS FOR FURTHER APPLICABILITY).
l attest that this application for
has been reviewed by me and is accurate, complete and consistent with the
information supplied in the engineering plans, calculations, and all other supporting documentation to the best of my knowledge. I
further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations.
Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials
under my seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. Note: In
accordance with NC General Statutes 143-215.6A and 143-215.6B, any person who knowingly makes any false statement,
representation, or certification in any application shall be guilty of a Class 2 misdemeanor which may include a fine not to exceed
$10, 000 as well as civil penalties up to $25, 000 per violation.
(PLEASE USE BLUE INK TO COMPLETE THE FOLLOWING) PLACE NORTH CAROLINA SEAL HERE
NAME:
DATE:
COMPANY:
ADDRESS:
TELEPHONE:
SIGNATURE:
PAGES CERTIFIED:
(IDENTIFY ABOVE EACH PERMIT FORM AND ATTACHMENT
THAT IS BEING CERTIFIED BY THIS SEAL)
Attach Additional Sheets As Necessary -- See Attached Calculation Sheet
DEQ-CFW 00085912

W-Attachment
TECHNICAL ANALYSIS IN SUPPORT OF PERMIT APPLICATION
Emission Unit IDs: PS-3
Emission Source Description: Natural gas -fired or No. 2 fuel oil -fired boiler (97 million
Btu per hour maximum heat input)
Emission Estimation Approach:
The emissions from this boiler is determined using the emissions spreadsheet found on the
North Carolina NCDENR Division of Air Quality website. These spreadsheets are based on
AP-42 emission factors. Since either natural gas of No. 2 fuel oil will be burned in this
boiler, both the "Fuel oil combustion" spreadsheet and the "Natural gas combustion"
spreadsheet were used, and the output of both spreadsheets are attached.
The boiler will include a now-NOx burner that will control at least 35% of the potential NOx
emissions.
It is assumed that the maximum sulfur content of the No. 2 fuel oil is 0.1 % sulfur.
Potential Emissions
Fuel Type
No. 2 Fuel Oil
6,069,428 gal/yr
Natural Gas
833,060,000 scf/yr
CRITERIA AIR POLLUTANT EMITTED
Emission (ton/yr)
Emission (ton/yr)
TOTAL PARTICULATE MATTER PM FPM+CPM
10.0
3.2
FILTERABLE PM (FPM)
6.1
0.8
CONDENSABLE PM (CPM)
3.9
2.4
FILTERABLE PM<10 MICRONS (PMIO)
3.0
FILTERABLE PM<2.5 MICRONS (PM2.5)
0.8
SULFUR DIOXIDE S02
21.5
0.2
NITROGEN OXIDES NOx
39.5
20.8
CARBON MONOXIDE CO
15.2
35.0
VOLATILE ORGANIC COMPOUNDS VOC
0.6
2.3
LEAD
0.0
0.0
Fuel quantities listed is based on the rated firing capacity of the boiler (97 million BTU per
hour) and assumes the boiler is operating 8,760 hours per year.
DEQ-CFW 00085913

FUEL OIL COMBUSTION EMISSIONS CALCULATOR REVISION C 3/19/2003 - OUTPUT SCREEN
Instructions: Enter emission source I facility data on the "INPUT tabiscreen. The air emission results and summary of
input data are viewed / printed on the "OUTPUT" tab/screen. The different tabs are on the bottom of this screen.
This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information contained. This
.d&'dmmi A� spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current information available. DENR is not
NCDENRresponsible for errors or omissions that may be contained herein.
SOURCE ✓ FACILtTY7 USER INPUT SUMMARY (FROM INPUT SCREEN)
COMPANY: DuPont - Fayetteville Works
MAX HEAT INPUT: 97.00 MMBTU/HR
FACILITY ID NO.: 0900009
FUEL HEAT VALUE: 140.000 BTU/GAL
PERMIT NUMBER: 03735T33
ACTUAL ANNUAL FUEL USAGE: 6.069,428 GAL/YR
FACILITY CITY: Duart Township
MAXIMUM ANNUAL FUEL USAGE: 6.069,429 GAL/YR
FACILITY COUNTY: Bladen
MAXIMUM SULFUR CONTENT: 0.1 %
USER NAME: Michael E. Johnson
REQUESTED: PERMIT LIMITATIONS:
EMISSION SOURCE DESCRIPTION: No. 2 oil -fired Boiler
MAX. FUEL USAGE: 6,069.429 GAL/YR
EMISSION SOURCE ID NO.: PS-3
MAX. SULFUR CONTENT: 0.05 %
TYPE' OF CONTROL DEVICES =
POLLUTANT_
CONTROL EFF.
NONE/OTHER
PM
0
NONE/OTHER
S02
0
LOW NOX BURNERS (LNB)
NOx
35
CRITERIA AIR
POLLUTANT EMISSIONS INFORMATION
AIR POLLUTANT EMITTED
ACTUAL EMISSIONS
AFTER CONTROLS / LIMITS
POTENTIAL EMSSIONS
BEFORE CONTROLS / LIMITS AFTER CONTROLS / LIMITS
EMISSION FACTOR
lb/103gal)
Ib/hr
tons/ r
Ib/hr
I tons/ r
Ib/hr
tons/ r
uncontrolled 1controlled
TOTAL PARTICULATE MATTER PM FPM+CPM
2.29
10.01
2.29
10.01
2,29
10.01
3.30E+00
3.30E+00
FILTERABLE PM (FPM)
1.39
6.07
1.39
6.07
1.39
6.07
2.00E+00
2.00E+00
CONDENSABLE PM (CPM)
0.90
3.95
0.90
3.95
0.90
3.95
1.30E+00
1.30E+00
FILTERABLE PM<10 MICRONS (PM16)
0.69
3.03
0.69
3.03
0.69
3.03
1.00E+00
1.00E+00
FILTERABLE PM<2.5 MICRONS (PM2.5)
0.17
0.76
0.17
0.76
0.17
0.76
2.50E-01
2.50E-01
SULFUR DIOXIDE S02
4.92
21.55
4.92
21.55
4.92
21.55
7.10E+00
7.10E+00
NITROGEN OXIDES NOx
9.01
39.45
13.86
60.69
9.01
39.45
2.00E+01
1.30E+01
CARBON MONOXIDE CO
3.46
15.17
3.46
15.17
3.46
15.17
5.00E+00
5.00E+00
VOLATILE ORGANIC COMPOUNDS VOC
0.14
0.61
0.14
0.61
0.14
0.61
2.00E-01
2.00E-01
LEAD
0.00
0.00
0.00
0.00
0.00
0.00
1.26E-03
1.26E-03
TOXIC HAZARDOUS AIR `POLLUTANT -EMISSIONS
INFORMATION
TOXIC / HAZARDOUS AIR POLLUTANT
CAS
NUMBER
ACTUAL EMISSIONS
AFTER CONTROLS / LIMITS
POTENTIAL EMSSIONS
BEFORE CONTROLS / LIMITS AFTER CONTROLS / LIMITS
EMISSION FACTOR
lb/103 aI
Ib/hr
Ib/yr
Ib/hr
Ib/yr
Ib/hr
Ib/yr
uncontrolled
controlled
Antimony & compounds (H)
SBC
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
Arsenic & compounds (TH)
ASC
3.9E-04
3.4E+00
3.9E-04
3.4E+00
3.9E-04
3.4E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
1.9E-03
1.7E+01
1.9E-03
1.7E+01
1.9E-03
1.7E+01
2.75E-03
2.75E-03
Beryllium & compounds (H)
BEC
2.9E-04
2.5E+00
2.9E-04
2.5E+00
2.9E-04
2.5E+00
4.20E-04
4.20E-04
Cadium & compounds (TH)
CDC
2.9E-04
2.5E+00
2.9E-04
2.5E+00
2.9E-04
2.5E+00
4.20E-04
4.20E-04
Chromium - AII/rotal (H)
CRC
2.9E-04
2.5E+00
2.9E-04
2.5E+00
I 2.9E-04
2.5E+00
4.20E-04
4.20E-04
Cobalt compounds (H)
COC
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
Ethylbenzene (H)
100414
5.7E-04
5.0E+00
5.7E-04
5.0E+00
5.7E-04
5.0E+00
8.17E-04
8.17E-04
Fluorides (sum fluoride compounds) (T)
16984488
2.6E-02
2.3E+02
2.6E-02
2.3E+02
2.6E-02
2.3E+02
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
3.3E-02
2.9E+02
3.3E-02
2.9E+02
3.3E-02
2.9E+02
4.80E-02
4.80E-02
Lead and Lead compounds (H)
PBC
8.7E-04
7.6E+00
8.7E-04
7.6E+00
8.7E-04
7.6E+00
1.26E-03
1.26E-03
Manganese & compounds (TH)
MNC
5.8E-04
5.1 E+00
5.8E-04
5.1 E+00
5.8E-04
5.1 E+00
8.40E-04
8.40E-04
Mercury & compounds (TH)
HGC
2.9E-04
2.5E+00
2.9E-04
2.5E+00
2.9E-04
2.5E+00
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
1.6E-04
1.4E+00
1.6E-04
1.4E+00
1.6E-04
1.4E+00
2.36E-04
2.36E-04
Napthalene (H)
91203
2.3E-04
2.0E+00
2.3E-04
2.0E+00
2.3E-04
2.0E+00
3.33E-04
3.33E-04
Nickle & compounds (H)
NIC
2.9E-04
2.5E+00
2.9E-04
2.5E+00
2.9E-04
2.5E+00
4.20E-04
4.20E-04
Phosphorus Metal, Yellow or White (H)
7723140
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.00E+00
0.00E+00
POM rates uncontrolled (H)
POM
2.3E-03
2.0E+01
2.3E-03
2.0E+01
2.3E-03
2.0E+01
3.30E-03
3.30E-03
Selenium compounds (H)
SEC
1.5E-03
1.3E+01
1.5E-03
1.3E+01
1.5E-03
1.3E+01
2.10E-03
2.10E-03
Toluene (TH)
108883
5.5E-02
4.8E+02
5.5E-02
4.8E+02
5.5E-02
4.8E+02
7.97E-02
7.97E-02
Xylene (TH)
1330207
9.7E-04
8.5E+00
9.7E-04
8.5E+00
9.7E-04
8.5E+00
1.40E-03
1.40E-03
Total HAP (H)
9.9E-02
8.7E+02
9.9E-02
8.7E+02
9.9E-02
8.7E+02
1.4E-01
1.4E-01
Lar et HAP (H)
5.52E-02
4.84E+02
5.52E-02
4.84E+02
5.52E-02
I 4.84E+02
I 7.97E-02
7.97E-02
TOXIC AlRPOLLUTANT
EMISSIONS
INFORMATION:(FOR
PERMI:T77NCa
PURPOSES)
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
EMISSION FACTOR
Ib/10a al
TOXIC AIR POLLUTANT
CAS Num.
Whir
lb/day
Ib/ r
uncontrolled
controlled
Arsenic & compounds (TH)
ASC
3.88E-04
9.31E-03
3.40E+00
5.60E-04
5.60E-04
Benzene (TH)
71432
1.91E-03
4.57E-02
1.67E+01
2.75E-03
2.75E-03
Cadium & compounds (TH)
CDC
2.91 E-04
6.98E-03
2.55E+00
4.20E-04
4.20E-04
Fluorides sum fluoride compounds) (T)
16984488
2.58E-02
6.20E-01
2.26E+02
3.73E-02
3.73E-02
Formaldehyde (TH)
50000
3.33E-02
7.98E-01
2.91E+02
4.80E-02
4.80E-02
Manganese & compounds (TH)
MNC
5.82E-04
1.40E-02
5.10E+00
8.40E-04
8.40E-04
Mercury & compounds (TH)
HGC
2.91E-04
6.98E-03
2.55E+00
4.20E-04
4.20E-04
Methyl chloroform (TH)
71566
1.64E-04
3.92E-03
1.43E+00
2.36E-04
2.36E-04
Toluene (TH)
108883
5.52E-02
1.32E+00
4.84E+02
7.97E-02
7.97E-02
X lene (TH)
1330207
9.70E-04
2.33E-02
8.50E+00
1.40E-03
1.40E-03
DEQ-CFW 00085914

NATURAL
GAS COMBUSTION EMISSIONS CALCULATOR REVISION E 2120/03 - OUTPUT SCREEN
Aare
Instructions: Enter emission source / facility data on the 'INPUT" tab/screen. The air emission results and summary of input data
viewed / printed on the "OUTPUT" tab/screen. The different tabs are on the bottom of this screen.
.wrs-
N�DENR
This spreadsheet is for your use only and should be used with caution. DENR does not guarantee the accuracy of the information
contained. This spreadsheet is subject to continual revision and updating. It is your responsibility to be aware of the most current
information available. DENR is not responsible for errors or omissions that may be contained herein.
SOURCE I FACILITY/ USER INPUT SUMMARY (FROM INPUT SCREEN)
COMPANY: DuPont Com an Fa etteville Works
� � - �
FACILITY 0900009
PERMIT NUMBBEE R: 03735T33
EMISSION SOURCE DESCRIPTION: 97 MMBTU/HR NATURAL GAS -FIRED BOILER
FACILITY CITY: Duart Township
EMISSION SOURCE ID NO.: PS-3
FACILITY COUNTY: Bladen
CONTROL DEVICE: I LOW NOx BURNERS
POLLUTANT
CONTROL EFF.
SPREADSHEET PREPARED BY: Michael E. Johnson
NOX
CALCD AS 50%
ACTUAL FUEL THROUGHPUT: 833.06 10 SCF/YR
FUEL HEAT VALUE: 1,020 BTU/SCF
POTENTIAL FUEL THROUGHPUT: 833.06 106 SCF/YR
BOILER TYPE SMALL BOILER (<100 mmBTU/HR)
REQUESTED MAX. FUEL THRPT: 833.06 106 SCF/YR
NO SNCR APPLIED
CRITERIA AIR
POLLUTANT EMISSIONS INFORMATION
AIR POLLUTANT EMITTED
ACTUAL EMISSIONS
AFTER CONTROLS / LIMITS
POTENTIAL
EMSSIONS
EMISSION FACTOR
Ib/mmBtu
BEFORE CONTROLS / LIMITS
AFTER CONTROLS
/ LIMITS
lblhr
tons! r
lblhr
tons! r
lb/hr
tons! r
uncontrolled
controlled
PARTICULATE MATTER Total
0.72
3.17
0.72
3.17
0.72
3.17
0.007
0.007
PARTICULATE MATTER Condensable
0.54
2.37
0.54
2.37
0.541
2.37
0.006
0.006
PARTICULATE MATTER Filterable
0.18
0.79
0.18
0.79
0.18
0.79
0.002
0.002
SULFUR DIOXIDE S02
0.06
0.25
0.06
0.25
0.06
0.25
0.001
0.001
NITROGEN OXIDES NOx
4.75
20.83
9.51
41.65
4.75
20.83
0.098
0.049
CARBON MONOXIDE CO
7.99
34.99
7.99
34.99
7.99
34.99
0.082
0.082
VOLATILE ORGANIC COMPOUNDS VOC
0.52
2.29
0.52
2.29
0.52
2.29
0.005
0.005
LEAD
0.00E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
0.0E+00
- TOXIC I HAZARDOUS
AIR POLLUTANT
EMISSIONS INFORMATION
TOXIC / HAZARDOUS AIR POLLUTANT
CAS
NUMBER
ACTUAL EMISSIONS
AFTER CONTROLS/LIMITS
POTENTIAL
EMSSIONS
EMISSION FACTOR
Ib/mmBtu
BEFORE CONTROLS/LIMITS
AFTER CONTROLS/LIMITS
Ib/hr
Ibs/yr
lb/hr
Ibs/ r
lb/hr
lbsl r
uncontrolled
controlled
Arsenic & Compounds TH
ASC
0.00E+00
O.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
O.00E+oo
o.00E+oo
Benzene TH
71432
2.00E-04
1.75E+00
2.00E-04
1.75E+00
2.00E-04
1.75E+00
2.06E-06
2.06E-06
Benzo a rene T
50328
1.14E-07
1.00E-03
1.14E-07
1.00E-03
1.14E-07
1.00E-03
1.1BE-09
1.18E-09
Beryllium metal T
7440417
0.00E+00
0.09E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
Cadmium & compounds TH
CDC
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
O.00E+00
0.00E+00
O.00E+00
Chromium - AII/Total H
CRC
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
Soluble Chromate Compounds, as Chromium VI T
SoICR6
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
O.00E+00
0.00E+00
Cobalt compounds H
COC
7.99E-06
7.00E-02
7.99E-06
7.00E-02
7.99E-06
7.00E-02
8.24E-08
8.24E-08
Formaldehyde TH
50000
7.13E-03
6.25E+01
7.13E-03
6.25E+01
7.13E-03
6.25E+01
7.35E-05
7.35E-05
Hexane, n- TH
110543
1.71E-01
1.50E+03
1.71E-01
1.50E+03
1.71 E-01
1.50E+03
1.76E-03
1.76E-03
Manganese & compounds TH
MNC
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
Mercury & Compounds H
HGC
0.00E+00
0.00E+00
0.00E+00
I 0.00E+00
0.00E+00
0.00E+00
0.00E+00
O.00E+oo
Na thalene H
91203
5.80E-05
5.08E-01
5.80E-05
5.08E-01
5.80E-05
5.08E-01
5.98E-07
5.98E-07
Nickel metal T
7440020
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
O.00E+00
0.00E+00
Selenium compounds H
SEC
2.28E-06
2.00E-02
2.28E-06
2.00E-02
2.28E-06
2.00E-02
2.35E-08
2.35E-08
Toluene (TH)
IIOBB83
I 3.23E-04
2.83E+00
3.23E-04
2.83E+00
3.23E-04
2.83E+00
3.33E-06
3.33E-06
Total HAPs
I1.79E-01 1.57E+03
1.79E-01
1.57E+03
I 1.79E-01
I 1.57E+03
1.84E-03
I 1.84E-03
Highest HAP Hexane 1.71 E-01 1.50E+03 1.71 E-01 1.50E+0331 1.76E-03
TOXIC AIR POLLUTANT EMISSIONS INFORMATION (FOR PERMITTING PURPOSES)
EXPECTED ACTUAL EMISSIONS AFTER CONTROLS / LIMITATIONS
EMISSION FACTOR
Ib/mmBtu
TOXIC AIR POLLUTANT
CAS Num.
Ib/hr
lb/day
Ib/ r
uncontrolled
controlled
Arsenic & Compounds H
ASC
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
Benzene TH
71432
2.00E-04
4.79E-03
1.75E+00
2.06E-06
2.06E-06
Benzo a rene T
50328
1.14E-07
2.74E-06
1.00E-03
1.18E-09
1.18E-09
Beryllium metal T
7440417
0.00E+00
0.00E+00
0.00E+00
O.00E+00
O.00E+00
Cadmium & compounds TH
CDC
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
Soluble Chromate Compounds, as Chromium VI T
SoICR6
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
Formaldehyde TH
50000
7.13E-03
1.71E-01
6.25E+01
7.35E-05
7.35E-05
Hexane, n- TH
110543
1.71E-01
4.11E+00
1.50E+03
1.76E-03
1.76E-03
Manganese & compounds TH
MNC
0.00E+00
0.00E+00
0.00E+00
0.00E+00
O,OOE+00
Nickel metal T
7440020
0.00E+00
0.00E+00
0.00E+00
O.00E+oo
O.o0E+00
Toluene (TH)
1108883
1 3.23E-04
I 7.76E-03
I 2.83E+00
3.33E-06
3.33E-06
DEQ-CFW 00085915

FORM E1
TITLE V GENERAL INFORMATION
REVISED: 12/01/01 Division of Air Quality - Application for Air Permit to Construct/Operate E1
IF YOUR FACILITY IS CLASSIFIED AS "MAJOR FOR TITLE V YOU MUST COMPLETE
THIS FORM AND ALL OTHER REQUIRED "E" FORMS (E2 THROUGH E5 AS APPLICABLE)
Indicate here if your facility is subject to Title V by: rx7l Emissions ❑ Other
If subject to Title V by other, check or specify: ® NSPS O NESHAPS (MACT) ❑ TITLE IV
Other, specify:
If you are or will be subject to any maximum achievable control technology standards (MACT) issued pursuant
to section 112(d) of the Clean Air Act, specify below:
EMISSION EMISSION SOURCE
SOURCE ID DESCRIPTION MACT
BS-D Butacite Tinting "Printing MACT" (Part 63 Subpart KK)
Throughout Facility Facility Wide "MON MACT" (Part 63 Subpart FFFF)
List any additional regulation which are requested to be included in the shield and provide a detailed explanation
as to why the shield should be granted:
REGULATION EMISSION SOURCE (Include ID) EXPLANATION
40 CFR 60 (NSPS) Natural gas -fired / No. 2 fuel This boiler will comply with all the
Subpart Dc oil -fired boiler requirements of NSPS Subpart Dc
Comments:
Attach Additional Sheets As Necessary
DEQ-CFW 00085916

FORM E2
EMISSION SOURCE APPLICABLE REGULATION LISTING
RFVISF_D 12/C niwi�inn of Air rmnlifii - Annlinnfinn fnr Air Parmit to Cnnctrurt/Onarate E2
EMISSION
EMISSION
OPERATING SCENARIO
SOURCE
SOURCE
INDICATE PRIMARY (P)
APPLICABLE
ID NO.
DESCRIPTION
OR ALTERNATIVE (A)
POLLUTANT
REGULATION
ES 1
CoallWood Boiler
P - Coal
PM
NCA C 2D . 0503
A -Wood
PM
NCAC 2D . 0504
NCAC 2D.0524 New Source
Natural gas -fired /
as - P Natural
g
S02
Performance Standards
PS-3
No. 2 fuel oil -fired
boiler
NCAC 2D.0524 New Source
A - No. 2 fuel oil
S02
Performance Standards
NCAC 2Q.0317 -- PSD Avoidance
Natural gas -fired /
P -Natural gas
S02
(existing 702.5 TPY site -wide limit)
PS-3
No. 2 fuel oil -fired
boiler
NCAC 2Q.0317 -- PSD Avoidance
A - No. 2 fuel oil
S02
(existing 702.5 TPY site -wide limit)
NCAC 2D.0524 New Source
Natural gas -fired /
P - Natural gas
PM
Performance Standards
PS-3
No. 2 fuel oil -fired
boiler
NCAC 2D.0524 New Source
A - No. 2 fuel oil
PM
Performance Standards
NCAC 2D.0521 -- Control of visible
Natural gas -fired /
P - Natural gas
VE
emissions
PS-3
No. 2 fuel oil -fired
boiler
NCAC 2D.0521 -- Control of visible
A - No. 2 fuel oil
VE
emissions
HFPO Product
Container
NCAC 2Q.0317 -- Avoidance
NS-N
Decontamination
P
VOC
conditions for 15A NCAC 2D.0530
Process
Attach Additional Sheets As Necessary
DEQ-CFW 00085917

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01 /01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant S02
Emission Source ID NO. PS-3 Applicable Regulation NCAC'_Q.0317
Alternative Operating Scenario (AOS) NO: 1.
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes ❑X No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes ❑X No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPING REQUIREMENTS
Data (Parameter) being recording: S02 emissions from all combustion sources will be determined
via fuel consumption and AP-42 emission factors.
Frequency of recordkeeping (How often is data recorded?): Monthly
REPORTING REQUIREMENTSI
Generally describe what is being reported: Monthly S02 emissions will be determined monthly and
will be reported to N.C. Division of Air Quality every sit months.
Frequency: ❑ MONTHLY ❑ QUARTERLY M EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
..................... ... .
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085918

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant Visible emissions
Emission Source ID NO. PS-3 Applicable Regulation NCAC 2D.0521
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes ® No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes ❑X No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- No monitoring/recordlceeping/
reporting is required for visible emissions from the firing of natural gas or No. 2 fuel oil in
these sources.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPING REQUIREMENTS -
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?): Not applicable
REPORTING REQUIREMENTS'
Generally describe what is being reported: None
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085919

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01 /01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant VOC
Emission Source ID NO. NS-N Applicable Regulation NCAC 2Q.0317
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes FX-1 No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes 0 No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPING REQUIREMENTS
Data (Parameter) being recording: VOC emissions will be determined via engineering calculations
Frequency of recordkeeping (How often is data recorded?): Monthly
_REPORTING REQUIREMENTS
Generally describe what is being reported: Monthly VOC emissions will be determined monthly and
will be reported to N.C. Division of Air Quality every six months.
Frequency: ❑ MONTHLY ❑ QUARTERLY EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085920

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant Visible emissions
Emission Source ID NO. NS-N Applicable Regulation NCA.0 2D.Q-521
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes 0 No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes [X� No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- Emitted product is a colorless gas
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPING REQUIREMENTS
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?): Not applicable
REPORTING REQUIREMENTS
Generally describe what is being reported: None
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: _ Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085921

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3�
Regulated Pollutant Odor
Emission Source ID NO. NS-N Applicable Regulation NCAC 2D.1806
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes ❑X No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes ❑X No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- Emissions from this process are
odorless gases.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
REGORDKEEPING REQUIREMENTS
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?):
REPORTING 'REQUIREMENTS
Generally describe what is being reported: Not applicable
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
.,.:.TESTING:.
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: _ Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085922

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant Visible emissions
Emission Source ID NO. NS-0 Applicable Regulation NCAC 2D.0521
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING _REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes ❑X No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes ❑X No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- Emitted product is a Colorless gas
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPING REQUIREMENTS
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?): Not applicable
REPORTING REQUIREMENTS
Generally describe what is being reported: None
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085923

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant Odor
Emission Source ID NO. NS-O Applicable Regulation NCAC 2D.1806
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes 0 No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes Fx� No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- Emissions from this process az'e
odorless gases.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPING REQUIREMENTS
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?):
REPORTINGREQUIREMENTS'
Generally describe what is being reported: Not applicable
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085924

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01/01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate r E3 1
Regulated Pollutant Visible emissions
Emission Source ID NO. NS-P Applicable Regulation NCAC 2D.0521
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes ❑X No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes 0 No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- Emitted product is a Colorless gas
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPING REQUIREMENTS
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?): Not applicable
REPORTING 'REQUIREMENTS
Generally describe what is being reported: None
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085925

FORM E3
EMISSION SOURCE COMPLIANCE METHOD
REVISED 12/01 /01 NCDENR/Division Of Air Quality - Application for Air Permit to Construct/Operate E3
Regulated Pollutant Odor
Emission Source ID NO. NS-P Applicable Regulation NCAC 2D.1806
Alternative Operating Scenario (AOS) NO:
ATTACH A SEPARATE PAGE TO EXPAND ON ANY OF THE BELOW COMMENTS
MONITORING REQUIREMENTS
Is Compliance Assurance Monitoring (CAM) 40 CFR Part 64 Applicable? ❑ Yes A No
If yes, is CAM Plan Attached (if applicable, CAM plan must be attached)? ❑ Yes ❑X No
Describe Monitoring Device Type: Not applicable
Describe Monitoring Location: Not applicable
Other Monitoring Methods (Describe In Detail): Not applicable -- Emissions from this process are
odorless gases.
Describe the frequency and duration of monitoring and how the data will be recorded (i.e., every 15 minutes, 1 minute instantaneous
readings taken to produce an hourly average):
RECORDKEEPINGREQUIREMENTS
Data (Parameter) being recording: Not applicable
Frequency of recordkeeping (How often is data recorded?):
REPORTING' REQUIREMENTS
Generally describe what is being reported: Not applicable
Frequency: ❑ MONTHLY ❑ QUARTERLY ❑ EVERY 6 MONTHS
❑ OTHER (DESCRIBE):
TESTING
Specify proposed reference test method: Not applicable
Specify reference test method rule and citation: Not applicable
Specify testing frequency: Not applicable
NOTE - Proposed test method subject to approval and possible change during the test protocol process
Attach Additional Sheets As Necessary
DEQ-CFW 00085926

4 %
FORM E4
EMISSION SOURCE COMPLIANCE SCHEDULE
Revised 12/01/01 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate E4
COMPLIANCE STATUS WITH RESPECT TO ALL APPLICABLE REQUIREMENTS
Will each emission source at your facility be in compliance with all applicable requirements at the time of permit
issuance and continue to comply with these requirements?
0 Yes ❑ No If NO, complete A through F below for each requirement for
which compliance is not achieved.
Will your facility be in compliance with all applicable requirements taking effect during the term of the permit and
meet such requirements on a timely basis?
0 Yes ❑ No If NO, complete A through F below for each requirement for
which compliance is not achieved.
If this application is for a modification of existing emissions source(s), is each emission source currently in
compliance with all applicable requirements?
0 Yes ❑ No If NO, complete A through F below for each requirement for
which compliance is not achieved.
A. Emission Source Description (Include ID NO.)
B. Identify applicable requirement for which compliance is not achieved:
C. Narrative description of how compliance will be achieved with this applicable requirements:
D. Detailed Schedule of Compliance:
Ste s Date Expected
E. Frequency for submittal of progress reports (6 month minimum):
Not applicable
F. Starting date of submittal of progress reports: Not applicable
Attach Additional Sheets As Necessary
DEQ-CFW 00085927

FORM E5
TITLE V COMPLIANCE CERTIFICATION (Required)
Revised 01/01/07 NCDENR/Division of Air Quality - Application for Air Permit to Construct/Operate E5
In accordance with the provisions of Title 15A NCAC 20.0520 and .0515(b)(4),
the responsible company official of.
SITE NAME:
DuPont Fayetteville Works
SITE ADDRESS:
22828 NC Highway 87 W
CITY, NC:
Fayetteville, NC 28306
COUNTY:
Bladen
PERMIT NUMBER:
03735T33
CERTIFIES THAT (Check the appropriate statement):
0 The facility is in compliance with all applicable requirements
❑ In accordance with the provisions of Title 15A NCAC 2Q .0515(b)(4) the responsible
company official certififies that the proposed minor modification meets the criteria for using
the procedures set out in 2Q .0515 and requests that these procedures be used to process
the permit application.
❑ The facility is not currently in compliance with all applicable requirements
If this box is checked, you must also complete form E4 "Emission Source Compliance Schedule"
The undersigned certifies under the penalty of law, that all information and statements provided
in the application, based on information and belief formed after reasonable inquiry, are true,
accurate, and complete.
c
i Vi
of responsible company
Karen B. Wrigley, Plant Mai
me, Title of responsible company
IRED, USE BLUE INK)
er
cial Mix or
Date: December 4. 2008
Attach Additional Sheets As Necessary
DEQ-CFW 00085928