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HomeMy WebLinkAboutDEQ-CFW_00073908Facility Total CY 2011 Emission Summary Recorded in ED Facility ID #: 0900009 Facility Name: Chemours Company Fayetteville Works Permit #(s): 03735T43 Green House Gases Pollutants (GHG) Actual Emissions Tons/Yr Pollutant CAS Change CY 2011 CY 2010 Demini- from ED from Fees mus Hydrofluorocarbons (HFCs 8.05 HFC Not Not N/A Reported Reported HFC-23 (Tr fluoromethane) 75467 8.05 7.57 0.05 6.3% Carbon Dioxide (CO2) 124389 37,731.18 42,199.10 5,000.0 -10.6% Methane (CH4) 74-82-8 10.10 1.66 10.0 509.5% Nitrous Oxide (N20) 10024972 1.49 0.325300 1.0 357.1% CO2 equivalent (sum of individual GHG pollutant emissiot 120,284.84 metric tons times their 1995 IPCC Global Warming Potential (GAT), converted to metric tons) Criteria Pollutants Actual Emissions (Tons/Year) Pollutant CAS % CY 2011 CY 2010 Demini- from ED from Fees mus Change CO CO 31.42 13.12 0.5 139.5% NOx NOx 73.06 43.89 0.5 66.5% PM(TSP) TSP 11.60 13.29 0.5 -12.7% PM10 PM10 11.31 9.25 0.5 22.3% PM2.5 PM2.5 11.22 7.93 0.5 41.5% S02 SO2 2.74 2.04 0.5 34.3% VOC vOC 271.17 296.10 0.5 -8.4% Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants (TAPs) (Pounds/Year) CY 2011 CY 2010 Demini- Pollutant CAS % from ED from Fees mus Change Antimony & Compounds (total mass, inc elemental SB) Not 0.000000 10.0 N/A Reported Antimony Unlisted Compounds - Specify Compounc SBC-Other Not Not 10.0 N/A (Component of SBC) Reported Reported 08/30/2017 Page 1 of 6 DEQ-CFW 00073908 Facility Total CY 2011 Emission Summary Recorded in ED Facility ID #: 0900009 Facility Name: Chemours Company - Fayetteville Works Permit #(s): 03735T43 Hazardous Air Pollutants (HAPs) Actual Emissions and/or Toxic Air Pollutants (TAPs) (Pounds/Year) CY 2011 CY 2010 Demini- Pollutant CAS % from ED from Fees mus Change Arsenic & Compounds (total mass of elemental AS, arsine and 0.232000 1.93 0.01 -88.0% all inorganic compounds) Arsenic Unlisted Compounds - Specify Compound ASC-other 0.232000 1.93 0.01 -88.0% (Component of ASC) Beryllium & compounds (Total mass) 0.106000 1.50 L0 -92.9% Beryllium Metal (unreacted) (Component of BEC) 7440-41-7 0.106000 1.50 1.0 -92.9% Beryllium Unlisted Compounds - Specify Compounc BEC-Other Not Not 1.0 N/A (Component of BEC) Reported Reported Cadmium & compounds (total mass includes elemental metal) 0.603000 1.50 1 0.1 1-59.8% Cadmium Metal, elemental, unreacted (Component 4 7440-43-9 0.603000 1.50 0.1 -59.7% CDC) Cadmium Unlisted Compounds - Specify Compounc CDC -Other Not Not 0.1 N/A (Component of CDC) Reported Reported Chromium - AII/Total (includes Chromium (V1) categories, 0.739000 1 1.50 1 0.1 1-50.7% metal and others) Chromic acid (VI) (Component of So1CR6 & CRC) 7738-94-5 0.739000 1.50 0.01 -50.7% Chromium Unlisted Compounds - Specify Compoun CRC -Other Not Not 0.1 N/A (Component of CRC) Reported Reported Chromium (VI) Soluble Chromate Compounds (Component of 0.739000 1.50 1 0.01 1-50.7% CRC) Chromic acid (VI) (Component of SolCR6 & CRC) 7738-94-5 0.739000 1.50 0.01 -50.7% Cobalt & compounds 0.138000 0.003660 1.0 N/A Cobalt Unlisted Compounds - Specify Compound COC-other 0.138000 0.003660 1.0 N/A (Component of COC) Glycol ethers (total all individual glycol ethers -See Not 0.000000 100.0 NIA http://d`aq.state. nc. usAoxics/glycolq Reported Glycol Ethers, Unlisted - Specify Compound GLYET-Other Not Not 100.0 N/A (component of GLYET) (See Reported Reported http://daq.state.nc.us/toxics Lead & compounds 0.312000 7 4.10 1.0 -92.4% 08/30/2017 Page 2 of 6 DEQ-CFW 00073909 Facility Total CY 2011 Emission Summary Recorded in ED Facility ID #: 0900009 Facility Name: Chemours CompgM - Fayetteville Works Permit #(s): 03735T43 Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPS) Pollutant CAS Actual Emissions (Pounds/Year) % Change CY 2011 from ED CY 2010 from Fees Demini- mus Lead Unlisted Compounds - Specify Compound PBC-other (Component of PBC) 0.312000 4.10 10.0 -92.4% Manganese & compounds 0.383000 3.00 10.0 -87.2% Manganese Unlisted Compounds - Specify Compoui MNC-Other (Component of MNC) 0.383000 3.00 10.0 -87.2% Mercury & Compounds - all total mass includes Hg Vapor 0.224000 L50 0.001 -85.1 % Mercury Unlisted Compounds - Specify Compound HGC-Other (Component of HGC) Not Reported Not. Reported 0.001 N/A Mercury, vapor (Component of HGC) 7439-97-6 0.224000 1.50 0.001 -85.0% Nickel & Compounds, sum total mass includes elemental 1.06 1.50 1,0 1-2-9. % Nickel metal (Component of NIC) 7440-02-0 1.06 1.50 1.0 -29.0% Nickel Unlisted Compounds (Component of NIC - NIC-Other Specify) Not Reported Not Reported 1.0 N/A Nickel, soluble compounds as nickel (Component of NICKSOLCPDs NIC) Not Reported Not Reported 1.0 N/A Polycyclic Organic Matter (7 PAH Compounds for NIF) 0.001000 0.000050 1.0 N/A Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8 56553/7PAH) 0.001000 0.000050 1.0 N/A Polycyclic Organic Matter (Specific Compounds from OAQPS or TV) 0.438000 1.20 1.0 -63.5% Benzo(a)pyrene (Component of 83329/POMTV & 50-32-8 56553/7PAH) 0.001000 0.000050 1.0 N/A Naphthalene (Component of 83329/POMTV) 91-20-3 0.437000 1.20 1.0 -63.7% Total Reduced Sulfur (TRS as total mass) 180.60 180.60 0.0% Dimethyl sulfide 75-18-3 37.50 37.50 1.0 0.0% Hydrogen sulfide 7783-06-4 140.00 140.00 1.0 0.0% Methyl mercaptan 74-93-1 3.10 3.10 1.0 0.0% Acetic acid 64-19-7 1,447.00 1,226.00 100.0 1 18.0% 08/30/2017 Page 3 of 6 DEQ-CFW 00073910 Facility Total CY 2011 Emission Summary Recorded in ED Facility ID #: 0900009 Facility Name: Chemours Company - Fayetteville Works Permit #(s): 03735T43 Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) Pollutant CAS Actual Emissions (Pounds/Year) % Change CY 2011 from ED CY 2010 from Fees Demini- mus Acetonitrile 75-05-8 2,939.00 19,491.00 100.0 -84.9% Acrolein 107-02-8 1.00 1.00 10.0 0.0% Ammonia (as NH3) 7664-41-7 20,836.50 20,834.50 100.0 0.0% Benzene 71-43-2 10.50 17.61 1.0 -40.4% Bromine 7726-95-6 26.00 26.00 10.0 0.0% CFC- 113(1,1,2-trichloro-1,2,2-trifluoroethane) 76-13-1 2,099.00 1,505.00 100.0 39.5% CFC-12 (Dichlorodifluoromethane) 75-71-8 Not Reported Not Reported 100.0 N/A Chlorine 7782-50-5 1,244.00 1,281.00 100.0 -2.9% Chloroform 67-66-3 1.00 1.00 100.0 0.0% Dimethyl formamide 68-12-2 Not Reported Not Reported 1.0 N/A Dioxane, 1,4- 123-91-1 Not Reported Not Reported 0.01 N/A Ethyl acetate 141-78-6 17.00 17.00 10.0 0.0% Ethyl benzene 100-41-4 385.20 387.89 100.0 -0.7% Ethylene dichloride (1,2-dichloroethane) 107-06-2 541.00 541.00 1.0 0.0% Ethylene glycol 107-21-1 10.00 10.00 100.0 0.0% Fluorides (sum of all fluoride compounds as mass of 16984-48-8 ion) 9.29 128.70 10.0 -92.8% Formaldehyde 50-00-0 55.66 174.27 10.0 -68.1 % Hexamethylene-1,6-diisocyanate 822-06-0 2.00 2.00 1.0 0.0% Hexane, n- 110-54-3 1,140.17 173.40 100.0 557.5% Hydrogen chloride (hydrochloric acid) 7647-01-0 12.92 38.50 100.0 -66.4% Hydrogen fluoride (hydrofluoric acid as mass of HF) 7664-39-3 (Component of 16984488/Fluorides) 3,195.69 3,374.10 100.0 -5.3% MEK (methyl ethyl ketone, 2-butanone) 78-93-3 88.00 88.00 100.0 0.0% FMethanol (methyl alcohol) 67-56-1 35,028.00 34,976.00 1,000.0 0.10/6 08/30/2017 Page 4 of 6 DEQ-CFW 00073911 . Facility Total CY 2011 Emission Summary Recorded in ED Facility ID #: 0900009 Facility Name: Chemours Company - Fayetteville Works Permit #(s): 03735T43 Hazardous Air Pollutants (HAPs) and/or Toxic Air Pollutants (TAPs) Pollutant CAS Actual Emissions (Pounds/Year) % Change CY 2011 from ED CY 2010 from Fees Demini- mus Methyl chloroform 71-55-6 0.059000 0.825000 100.0 -92.8% Methylene chloride 75-09-2 10,284.00 7,960.00 1.0 29.2% Nitric acid 7697-37-2 109.00 109.00 100.0 0.0% Phosphorus Metal, Yellow or White 7723-14-0 Not Reported Not Reported 1.0 N/A Polycyclic Organic Matter (Inc PAH, dioxins, etc. N Pom & AP 42 historic) 0.824000 11.77 1.0 -93.0% Selenium Compounds SEC 0.539000 7.39 10.0 -92.7% Sulfur trioxide 7446-11-9 158.20 152.50 100.0 3.7% Sulfuric acid 7664-93-9 273.20 230.90 100.0 18.3% Toluene 108-88-3 2,837.58 5,482.15 100.0 -48.2% Vinylidene chloride 75-35-4 Not Reported Not Reported 0.1 N/A Xylene (mixed isomers) 1330-20-7 1,088.35 1,092.93 100.0 -0.4% Largest Individual HAP Methanol (methyl alcohol) 35,028.00 lbs Total HAP Emissions 58,781.72 lbs Largest Individual CAP VOC 271.17 tons Total CAP Emissions 389.70 tons Total TAP Emissions 45,463.12 lbs Total Aggregate Emissions 408.62 tons 08/30/2017 Page 5 of 6 DEQ-CFW 00073912 DAO's Comments Regarding Inventory CO, NOx increased in 2011 due to use of natural gas in boilers in lieu of #2 fuel oil. PM, PM10, and PM2.5 changes due to specific product mix changes from previous year. S02 increase due to increased production throughput of the polymer processing aids Metal HAPs decreased due to increased use of natural gas and decreased use of #2 fuel oil in boilers. Most other HAP/TAP emissions changes are due to varying product production rates throughout the plant VOC calculations appear valid, with extensive engineering calculations for support. Process emission factors appear valid. 08/30/2017 Page 6 of 6 DEQ-CFW 00073913