DEQ-CFW_00062085

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fo
4M.DuPontFluoroproducts
A Fayetteville Works Plant
O22828 NC Highway 87 West
Fayetteville, NC 28306-7332
JAN 0 2 20U9
j� December 11, 2008
DENR-
JAN
N.C. Division of Water Quality D\'
Attn: Central Files KK
1617 Mail Service Center
Raleigh, NC 27699-1617 ®®0
DISCHARGE MONITORING REPORT — November 2008
Attached is E. 1. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of November 2008.
If you have any questions, please contact Robert Geddie at [phone].
RJG: jlp
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie - FW
M. E. Johnson - FW
File: F-1-3-4
E.I. du Pont de Nemours and Company
DEQ-CFW 00062085

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 11/13/08
Facility: DUPONT NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laboratory Performin Test: MERITECH, INC Comments: Dilution Water Batch
X ew�
#701 & 702 Used
ionature o perator in Resp-onsi e� arg
Signature o La oratory Supervisor
* PASSED: 9.64% Reduction
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
_Raleigh, North Carolina 27699-1621
North Carolina Ceriodaphnia Chronic Test Results
Chronic Pass/Fail Reproduction Toxicity Test Calculated t = 2.602
Tabular t = 2.508
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = 9.64
# Young Produced II28'26`27128128131`30I27I3OI27I2�
Adult (L)ive (D)ead IIL IL IL IL IL IL IL IL- IL IL IL IL
Effluent %: 3.3%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1122126118127127127I26I22I24I26128127
Adult (L)ive (D)ead IIL IL IL IL IL IL IL IL IL IL IL IL
% Mortality
Avg.Reprod.
0.00
27.67
Control
Control
0.00
25.00
Treatment 2
Treatment 2
Control Cv
7.119% PASS FAIL
% control orgs X
producing 3rd Check One
brood
100%
1st sample 1st sample 2nd sample Complete This For Either Test
Test Start Date: 11/05/08
pH
Control 7.98 7.93 7.79 7.69 7.94 7.84 Samplet1: 11/03/08 Date
2: 11/06/08
2nd
Treatment 2 7.92 7.68 7.82 7.83 7.95 7.90 Sample Type/Duration 1st P/F
s s s Grab Comp. Duration D S S
t e t e t e L A A
hrs
a n a n a n Sample 1 g 24.0 U M A
r d r d r d X 24.o hrs T P P
t t t Sample 2
1st sample 1st sample 2nd sample 40 .........
Hardness(mg/1)
D.O. .
Control 7.69 7.26 7.89 7.50 E776
7.24 Spec. Cond.(µmhos) 180 252 393
Treatment 2 7.67 7.28 7.90 7.47 6.97 Chlorine(mg/1) 0.14 0.12
LC50/Acute Toxicity Test
Sample temp. at receipt (°C) ........ 2.9 0.2
r� r ,,;,„ osrnraaaBd as W. combining replicates) Note: Please
%
%
%
%
%
%
%
%
LC50 = %
95% Con i ence Limits
Concentration Complete This
Section Also
Mortality start/end
start/end
Method of Determination Control
Moving Average Probit - Hightj7-
Spearman Karber - Other Conc.
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
DEQ-CFW 00062086

EFFLUENT
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 001 MONTH November YEAR 2008
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Ray Beard
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES �3
DIV. OF WATER QUALITY X / O''' G7'�
DENR (SIGNATURE OF OPERATO N RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
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Lb/Day
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1
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0.558
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19
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0.590
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0.572
8
0800
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0.610
9
0800
24
0.744
10
0800
24
Y
0.727
19
7.52
18.2
26.1
:11
0800
24
Y
0.632
21
7.60'
11.6
27.4
12
0800
24
Y
0.644
20
7.70
22.6
43.0
13
0800
24
Y
0.557
14
osoo
24
Y
0.631
15
'0800
" 24
0.575
16
osoo
24
0.399
17
0800
24
B
0.403
19
7.40 `
M1
18.5 .
18
osook24
Y
0.470
18
7.34
8.6
18.8
19
0800
Y
0.459
15 .
7.30
14.2:
21.120
o800
Y
0.482
21
osoo
B
0.406
22
o800
0.648
23
osoo
0.409
10.2'
16.4
24
osoo
B
0.495
15
7.27
128.0
104.4
25
0800
24
B
0.310
14
7.15
59.5
60.8:'
26
08001
24
B
0.373
12
7.19
27
0800
24
0.333
28
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24
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0.291
29
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24
0.391LL
30
0800
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0.500
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1g/L
P/F
ug/L
<5.6 ) PASS
MINIMUM 1 0.291 1 12 1 7.15 1 <9.9 1 12.8 1 <5.6 I PASS
Comp."(C) Grab:( G) G G C C G C
Monthly Limit 2.0 191.3 317.8 1 PASS
DEM Form MR -I (12/93)
DEQ-CFW 00062087

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Karen B. Wrigley - Plant Manager
Permittee (Please print or type)
(Lija . 0 '?—
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADM[)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCB's
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone] extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00062088

EFFLUENT
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 002 MONTH November YEAR 2008
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Ray Beard
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES j
DIV. OF WATER QUALITY X
DENR (SIGNATURE OF OPERATOR rN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050
00010
00400
00951
00665
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Y/N
MGD
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UNITS
Lb/Day
mg/L
mg/L
ug/L
mg/L
mgi
1
080o
24
9.248
2
0800
24
9.568
3
o800
24
Y
9.617
21
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DEM Form MR -I (12/93)
* Holiday
DEQ-CFW 00062089

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Karen B. Wrigley - Plant Manager
Permittee (Please print or type)
12
ature of Perm
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADM[)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01092
Zinc
Chlorine
01027
Cadmium
01105
Aluminum
01032
Hexavalent Chromium
01147
Total Selenium
71880 Formaldehyde
01034
Chromium
31616
Fecal Coliform
71900 Mercury
32730
Total Phenolics
81551 Xylene
01037
Total Cobalt
34235
Benzene
01042
Copper
34481
Toluene
38260
MBAS
01045
Iron
39516
PCB's
01051
Lead
50050
Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00062090

NPDES NO: NC0003573 DISCHARGE NO: 002 MONTH: November YEAR: 2008
FACILITY: DuPont - Fayetteville Works COUNTY: Bladen
STREAM: Cape Fear River STREAM: Cape Fear River
LOCATION: DuPont River Pump Station LOCATION: Boat Ramp - 4500 ft below Prospect Hall Landing
UPSTREAM DOWNSTREAM
•
DWQ Form MR-3 (Revised 7/2000)
N
ly0
v
L)
O
N
~
00010
00400
00310
00610
00530
00094
i 'y
7
V
4) 'aG
4'
F— (D
V
N
M
m
C
0
d
W
N
C
d
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U. 0
'>
U
HRS
°C
units
mg/L
mg/L
#/100ml
µmho/cm
1
3
4
5
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
Average
Maximum
Minimum
DEQ-CFW 00062091

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on currective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Karen B. Wrigley- Plant Manager
Permittee (Please print or type)
I z/ c®
re
Date
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
00010 Temperature
00076 Turbidity
00080 Color (Pt -Co)
00082 Color (ADMI)
00095 Conductivity
00300 Dissolved Oxygen
00310 BOD5
00340 COD
00400 pH
00530 Total Suspended
Residue
00545 Settleable Matter
PARAMETER CODES
00556
Oil & Grease
00951
Total Fluoride
00600
Total Nitrogen
01002
Total Arsenic
00610
Ammonia Nitrogem-
00625
Total Kjeldhal
01027
Cadmium
Nitrogen
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
01034
Chromium
00665
Total Phosphorous
00720
Cyanide
01037
Total Cobalt
00745
Total Sulfide
01042
Copper
00927
Total Magnesium
00929
Total Sodium
01045
Iron
00940
Total Chloride
01051
Lead
01067 Nickel
01077 Silver
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCB's
50050 Flow
50060 Total
Residual
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
�4 ZZ 333
DEQ-CFW 00062092