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HomeMy WebLinkAboutNC0006190_Fact Sheet_20181221Fact Sheet NPDES Permit No. NC0006190 Permit Writer/Email Contact Bing Bai, bing.bai@ncdenr.gov: Date: December 21, 2018 Division/Branch: NC Division of Water Resources/NPDES Complex Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ® Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2" species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: South Fork Industries, Inc. / Maiden Plant Applicant Address: 100 West Pine Street, Maiden, NC 28650 Facility Address: 100 West Pine Street, Maiden, NC 28650 Permitted Flow: 1.1 MGD Facility Type/Waste: Major Industrial/100% industrial Facility Class: Class 3 Treatment Units: Manual bar screen; Heat exchanger; Aeration; Clarification; Post aeration; Sludge storage lagoon Pretreatment Program (Y/N) No County: Catawba Region Mooresville Briefly describe the proposed permitting action and facility background: Delta Apparel, Inc. submitted NPDES permit renewal application for their Maiden Plant WWTP in November 2015, six months before the current permit expiration date (May 31, 2016). In December 2016, the ownership of the Maiden Plant WWTP was transferred from Delta Apparel, Inc. to South Fork Industries, Inc., and the permit was Page 1 of 12 administratively continued based on Delta Apparel's renewal application. On May 10, 2018 South Fork Industries, Inc. submitted a revised renewal application for their 1.1 MGD Maiden Plant WWTP with updated contact information. South Fork's Maiden Plant is a major industrial textile facility for fabric dyeing and finishing. This facility discharges 100% process wastewater, and all domestic wastewater is treated at the Town of Maiden WWTP. South Fork provided actual and projected production rate from 2016 through 2020 with justifications. Due to predicted rapid production increase, tiered limits will be proposed and included in this permit renewal. The first tier limits will be calculated based on predicted average daily production of 62,000 lbs/day for 2019, and second tier limits will be calculated based on predicted average daily production of 75,000 lbs/day for 2020. Once daily average production rate reaches 95% of 62,000 lbs/day, Permittee is required to notify the Division and the second tier limits will become effective. 2. Receiving Waterbody Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 — Clark Creek Stream Segment: 11-129-5-(0.3) Stream Classification: C Drainage Area (mi2): 66 Summer 7Q10 (cfs) 12 Winter 7Q10 (cfs): 25.5 30Q2 (cfs): 34 Average Flow (cfs): 78 IWC (% effluent): 12 % 303(d) listed/parameter: No Subject to TMDL/parameter: Yes- State wide Mercury TMDL implementation. Subbasin/HUC: Catawba River Basin / 03050102 USGS Topo Quad: E14SW (Maiden NC) 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below for the period of January 2013 through December 2017. Table 3. Effluent Data Summary Outfall 001 Parameter Units Average Max Min Permit Limit Flow MGD 0.577 1.054 0.001 MA 1.1 Page 2 of 12 MA 162 BOD5 lb/day 27.6 1237.2 < 0.5 DM 325 MA 2802 COD lb/day 714.5 2740.1 32.8 DM 5604 MA 785 TSS lb/day 60.6 1229 < 2.7 DM 1853 MA NH3N mg/l 0.16 5.8 < 0.01 DM 15 MA Sulfide lb/day < 0.42 < 0.82 < 0.02 DM 16 MA Phenols lb/day 0.08 1.18 0 DM 8 Total Chromium µg/l 5.1 14 < 5 DM 402 pH S.U. 8.4 9 6.6 6-9 DO mg/l 8.2 14 5.1 DA > 5.0 Temperature ° C 21.5 30.7 3.8 Monitor only Conductivity µmhos/cm 8940 20000 1160 Monitor only Total Copper µg/l 27.6 32 23 Monitor only Total Zinc µg/l 252.3 477 25.2 Monitor only Chloride mg/1 21.7 38 13 Monitor only Sulfates mg/1 449 640 25 Monitor only TN mg/l 10.6 58.9 1.5 Monitor only TP mg/1 5.4 11.4 0.1 Monitor only Color ADMI 273 556 < 25 MA 549 MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum, DA=Daily Average 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/l of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). Page 3 of 12 If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The current permit requires instream monitoring for color, total copper, dissolved oxygen, temperature and conductivity. Review of instream data from past three years indicates that no statistical difference existed between upstream and downstream samples for all parameters (ANOVA p > 0.05). Dissolved oxygen standard of 5 mg/1 was maintained for both upstream and downstream. monitoring for total copper was added to the permit in 2002 renewal for development of copper TMDL in Clark Creek. Since this segment of receiving stream is not impaired with copper, and effluent limits for copper will be added to the Outfall 001, copper instream monitoring will be removed from this renewal. This draft permit maintains the same instream monitoring requirements for temperature, DO, conductivity and color. Table 4. Upstream Monitoring results summary Temp DO Conductivity Color Total Copper °C mg/L µmhos/cm ADMI µg/L Average 16.8 10.6 187.1 54.6 5.6 Max 25.3 16.6 1470 219 8 Min 2.4 6.7 < 0.1 22.2 < 5 Table 5. Downstream Monitoring results summary Temp DO Conductivity Color Total Copper °C mg/L µmhos/cm ADMI µg/L Average 17 10.3 277.1 56.1 6.2 Max 24.3 15.8 1170 395 8 Min 2.6 5.6 0.01 20 < 5 Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): NO Name of Monitoring Coalition: NA 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): The facility reported 6 BOD limit violations (daily maximum exceedance) in 2014, and all violations were proceeded to enforcement case. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 20 of 20 quarterly chronic toxicity tests. Summarize the results from the most recent compliance inspection: The last facility inspection conducted on February 22, 2018 reported that the facility was not in compliance due to reporting/monitoring violations and deficiencies in the Influent Sampling, Laboratory/Summary, Operation & Maintenance/Summary, Bar Screens, Aeration Basin, and Aerobic Digester. 6. Water Quality -Based Effluent Limitations (WQBELs) Page 4 of 12 Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with I5A NCAC 2B.0204(b): NA Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/1 for Municipals) may be appropriate if deemed more stringent based on dilution and model results. Ifpermit limits are more stringent than TBELs, describe how limits were developed: Limitations for BOD5 (MA 162 lbs/day, DM 325 lbs/day) was developed based on 1995 —1997 production rates following Effluent Guidelines ,40 CFR 410 Subpart E — Knit Fabric Finishing. In 1997, A Streeter Phelps (Level B) model for instream DO protection was performed and predicted an increase to 300 lbs/day BOD5 would not impact the DO downstream of the outfall. Although both level B model and 40 CFR 410 allows for increases in EGLs for BOD5, the Division has elected to freeze the ELG limits for BOD5 due to the impaired stream status and the ability of the permittee to already meet these more stringent limits. Therefore, no changes are proposed from the previous permit limits on BOD5 limits. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/1(summer) and 1.8 mg/l (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/l (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/l are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: Current limitations for ammonia (MA 3 mg/L, DM 15 mg/L) are based on 1997 Waste Load Allocation. TRC is not required for this facility since the discharge is 100% industrial. There are no proposed changes Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of/z detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of Page 5 of 12 dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between January 2015 and December 2017. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: NA Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: Copper No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Arsenic, Beryllium, Cadmium, Chloride, Chromium VI, Cyanide, Lead, Nickel, Selenium, Silver, Zinc, Sulfate. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: Chronic WET limit at 12% effluent will continue on a quarterly frequency. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/1) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/1 Page 6 of 12 Table 6. Mercury Effluent Data Summary 2018 # of Samples 1 Annual Average Conc. n L 2.4 Maximum Conc., ng/L 2.4 TBEL, ng/L 47 WQBEL, n L 771 Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. Furthermore, since this is an industrial facility discharging less than 2 MGD, no MMP is required. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 1 SA NCAC 2H. 0107(c) (2) (B), 40CFR 122. 47, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 1 SA NCAC 2B.0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Industrials (if not applicable, delete and skip to next Section) Describe what this facility produces: fabric dyeing and finishing List the federal effluent limitations guideline (ELG) for this facility: 40 CFR 410 Subpart E — Knit Fabric Finishing (BPT and BAT) Page 7 of 12 If the ELG is based on production or flow, document how the average productionfflow value was calculated: This ELG is based on production. South Fork provided yearly production data from 2016 to 2017, and projected production from 2018 through 2020 (Table 7). Table 7. Average daily production data provided by South Fork Year Daily Average (lbs/day) Increase Rate 2016 Actual 29443 - 2017 Actual 34405 16.9% 2018 Projected 50287 46.2% 2019 Projected 62000 23.3% 2020 Projected 75000 21% Since South Fork is projecting an annual increase rate of more than 20% from 2018 to 2020, tiered limits will be included in this permit. For ELG limits, document the calculations used to develop TBEL limits: Limits for first tier will be calculated using average daily production rate of 62,000 lbs/day, and limits for second tier will be calculated using average daily production rate of 75,000 lbs/day. The Permittee is required to notify the Division when daily average production rate exceeds 58,900 lbs/day (95% of 62,000 lbs/day) before Tier 2 limits become effective. Limits in Table 8 are calculated following the effluent guidelines in 40 CFR 410 Subpart E - Knit Fabric Finishing. Table 8. TBEL Development per 40 CFR 410. 52/13PT Pollutant BPT limitations (pounds per 1000 pounds of product) Tier 1 ( 62,000 lbs/day) Tier 2 (75,000 lbs/day) Calculated Limits (lbs/day) Calculated Limits (lbs/day) Daily Maximum Monthly Average Daily Maximum Monthly Average Daily Maximum Monthly Average BOD5 5 2.5 310 155 375 187.5 COD 60 30 3720 1860 4500 2250 TSS 21.8 10.9 1351.6 675.8 1635.0 817.5 Sulfide 0.2 0.1 12.4 6.2 15 7.5 Phenols 0.1 0.05 6.2 3.1 7.5 3.8 Total chromium 0.1 0.05 6.2 3.1 7.5 3.8 pH 6.0 - 9.0 s.u. A comparison of TBEL and QWBEL limits are shown in Table 9. Results show that TBEL limits for BOD5, COD, TSS, Sulfide, Phenol and Total Chromium are all stringent than WQBEL limits. Therefore, TBEL Limits will be applied and included in the permit. Although 40 CFR 410 allows for increases in EGLs based on the actual production, the Division has elected to freeze the EGL limits for BOD, TSS, Sulfide, and Phenols due to the impaired stream status and the ability of the permittee to already meet these more stringent limits. After comparing the proposed limits with the frozen limits, proposed limits Page 8 of 12 for BOD5 and TSS for Tier 2 of this permit are less stringent than the frozen limits. Therefore, limits BOD5 and TSS for Tier 2 page will remain the same as existing limits at Monthly average 162 lbs/day and Daily Max 325 lbs/day for BOD5, and Monthly average 785 lbs/day and Daily Max 1853 lbs/day for TSS. These numbers are based on 1995-1997 production rates. Table 9. Comparison of TBEL and WQBEL with permitted flow of 1.1 MGD Pollutant TBEL - Tier 1 (lbs/day) TBEL - Tier 2 (lbs/day) WQBEL (mg/L) WQBEL (lbs/day) Daily Maximum Monthly Average Daily Maximum Monthly Average Daily Maximum Monthly Average Daily Maximum Monthly Average BOD5 310 155 375 187.5 - - - - COD 3720 1860 4500 2250 - - - - TSS 1351.6 675.8 1635.0 817.5 - - - - Sulfide 12.4 6.2 15 7.5 1.43 1.43 23.8 23.8 Phenol 6.2 3.1 7.5 3.8 6.3 6.3 57.8 57.8 Total Chromium 6.2 3.1 7.5 3.8 - - - - Chromium III - - - - 8.8 1.34 80.7 12.3 Chromium VI - - - - 0.109 0.088 1.0 0.81 pH 6.0 - 9.0 s.u. Note: Bolded numbers are more stringent limits Although WQBEL for Chromium III and Chromium VI are more stringent than TBEL, according to Reasonable Potential Analysis, all reported total chromium values were < 5 µg/L, and there is no reasonable potential to exceed water quality standard for Chromium III or Chromium VI. Therefore, no limit or monitoring for Chromium III or Chromium VI will be added to the permit. If any limits are based on best professional judgement (BPJ), describe development: NA Document any TBELs that are more stringent than WQBELs: TBELs for BOD5, COD, TSS, Sulfide, Phenol, and Total Chromium are more stringent than WQBELs. Document any TBELs that are less stringent than previous permit: NA 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 213.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105( c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA Page 9 of 12 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 213.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti - backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section 4 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12.Summary of Proposed Permitting Actions: Table 10. Current Permit Conditions and Proposed Changes 1.1 MGD Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 1.1 MGD No change 15A NCAC 2B .0505 BOD5 — Tier 1 MA 162 lbs/day MA 155 lbs/day TBEL. 40 CFR 410.52BPT DM 325 lbs/day DM 310 lbs/day BOD5 Tier 2 MA 162 lbs/day MA 162 lbs/day TBEL. 40 CFR 410.52/BPT DM 325 lbs/day DM 325 lbs/day COD— Tier 1 MA 2802 lbs/day MA 1860 lbs/day TBEL. 40 CFR 410.52/BPT DM 5604 lbs/day DM 3720 lbs/day COD — Tier 2 MA 2802 lbs/day MA 2250 lbs/day TBEL. 40 CFR 410.52/BPT DM 5604 lbs/day DM 4500 lbs/day Page 10 of 12 TSS - Tier 1 MA 785 lbs/day MA 675.8 lbs/day TBEL. 40 CFR 410.52/BPT DM 1853 lbs/day DM 1351.6 lbs/da TSS - Tier 2 MA 785 lbs/day MA 785 lbs/day TBEL. 40 CFR 410.52/BPT DM 1853 lbs/day DM 1853 lbs/day Sulfide - Tier 1 MA 8 lbs/day MA 6.2 lbs/day TBEL. 40 CFR 410.52/BPT DM 16 lbs/day DM 12.4 lbs/da Sulfide - Tier 2 MA 8 lbs/day MA 7.5 lbs/day TBEL. 40 CFR 410.52/BPT DM 16 lbs/day DM 15 lbs/day Phenol - Tier 1 MA 4 lbs/day MA 3.1 lbs/day TBEL. 40 CFR 410.52/BPT DM 8 lbs/day DM 6.21bs/da Phenol - Tier 2 MA 41bs/day MA 3.8 lbs/day TBEL. 40 CFR 410.52/BPT DM 8 lbs/day DM 7.5 lbs/day Total Chromium DM 402 µg/L MA 3.1 lbs/day TBEL. 40 CFR 410.52/BPT - Tier 1 DM 6.21bs/da Total Chromium DM 402 µg/L MA 3.8 lbs/day TBEL. 40 CFR 410.52/BPT - Tier 2 DM 7.5 lbs/da WQBEL. Based on protection of NH3-N MA 3 mg/l No change State WQ criteria. 15A NCAC WA 15 mg/1 2B.0200 DO Daily Average > 5 mg/l No change WQBEL. State WQ standard, 15A (Effluent) NCAC 2B.0200 pH 6 - 9 SU No change WQBEL. State WQ standard, 15A NCAC 2B.0200 Color MA 549 ADMI No change WQBEL. State WQ standard, 15A Effluent NCAC 2B.0200 Temperature Monitor 3/Week No change WQBEL. State WQ standard, 15A (Effluent) NCAC 2B .0500 Conductivity Monitor 3/Week No change WQBEL. State WQ standard, 15A (Effluent) NCAC 2B .0500 Total Copper Monitor Quarterly No change Reasonable Potential Analysis. No (Effluent) RP With predicted C. > 50% of Ca Total Zinc Monitor Quarterly Removed from permit Reasonable Potential Analysis. No RP in RPA. Chloride Monitor Quarterly Removed from permit Reasonable Potential Analysis. No RP in RPA. Sulfates Monitor Quarterly Removed from permit Reasonable Potential Analysis. No RP in RPA. Total Nitrogen Monitor Monthly No change WQBEL. 15A NCAC 2B.0200 Total Phosphorus Monitor Quarterly No change WQBEL. 15A NCAC 2B.0200 Chronic limit 12% WQBEL. No toxics in toxic Toxicity Test effluent No change amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 Color Monitor Only No change WQBEL. State WQ standard, 15A (Instream) NCAC 2B .0500 Temperature Monitor Only No change WQBEL. State WQ standard, 15A (Instream) NCAC 2B .0500 DO Monitor Only No change WQBEL. State WQ standard, 15A (Instream) NCAC 2B .0500 Conductivity Monitor Only No change WQBEL. State WQ standard, 15A Instream NCAC 2B .0500 Page 11 of 12 Total Copper (Instream) Monitor Only Removed from permit Receiving stream not impaired with copper. Add effluent and upstream monitoring Required to assess dissolved metal Total Hardness No requirement based on the new 2016 limitations dissolved metal standards Electronic Add Electronic In accordance with EPA Electronic Reporting No requirement Reporting Special Reporting Rule 2015. Condition MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max 13. Public Notice Schedule: Permit to Public Notice: 10/31/2018 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes If Yes, list changes and their basis below: • Sample type for Total Chromium was corrected to composite in Sections A. (1) and A. (2) Effluent Limitations and Monitoring Requirements. 15. Fact Sheet Attachments (if applicable): • RPA Spreadsheet Summary • Instream DO Summary • Dissolved Metals Implementation/Freshwater or Saltwater • NH3-N and TRC WLA • Mercury TMDL Evaluation Page 12 of 12 Permit No. NC0006190 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Q ality Standards/A uatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/l (Dissolved) Acute SW, µg/l (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 213.0200 (e.g., arsenic at 10 µg/l for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*11.136672-[ln hardness] (0.04183 8)1 e^ f0.9151 [ln hardness]-3.14851 Cadmium, Acute Trout waters WER*11.136672-[ln hardness] (0.04183 8)1 e^ f0.9151[ln hardness]-3.62361 Cadmium, Chronic WER*11.101672-[ln hardness] (0.04183 8)1 e^ f0.7998[ln hardness]-4.44511 Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.72561 Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.68481 Copper, Acute WER*0.960 eA f O.9422[ln hardness]-1.7001 Copper, Chronic WER*0.960 eAtO.8545[ln hardness]-1.7021 Lead, Acute WER*11.46203-[ln hardness](0.145712)) • e^11.273[ln hardness]-1.460) Lead, Chronic WER*11.46203-[ln hardness](0.145712)) • e^11.273[ln hardness]-4.705) Nickel, Acute WER*0.998 eAtO.8460[ln hardness]+2.2551 Nickel, Chronic WER*0.997 eAtO.8460[ln hardness]+0.05841 Page 1 of 4 Permit No. NC0006190 Silver, Acute WER*0.85 • e^{l.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WOBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q 10 (the spreadsheet automatically calculates the 1 Q 10 using the formula I Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NC0006190 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal I + { [Kpo] [SS(i+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/l], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q 10 + Qw) (Cwgs) — (s7Q 10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q 10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: IQ 10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0006190 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) 26.2 Average from 5 effluent samples [Total as, CaCO3 or (Ca+Mg)] March — May 2018 Average Upstream Hardness (mg/L) 36.6 Average from 7 samples collected [Total as, CaCO3 or (Ca+Mg)] March — May 2018 7Q10 summer (cfs) 12 NPDES files, BIMS 1Q10 (cfs) 9.94 Calculated from 7Q10 summer Permitted Flow (MGD) 1.1 NPDES files, BIMS Date: June 21.2018 Permit Writer: Bing Bai Page 4 of 4 Instream DO Upstream Downstream Upstream Downstream 8/4/2015 7.4 7.7 3/31 /2016 9.7 9.1 8/5/2015 7.4 7.1 4/7/2016 9.5 9.7 8/6/2015 7.2 7.1 4/14/2016 10.5 9.9 8/11 /2015 7.3 7.2 4/21 /2016 9.3 8.5 8/12/2015 7.4 7.3 4/28/2016 7.5 7.7 8/13/2015 7.9 7.5 5/5/2016 6.7 8.7 8/18/2015 7.2 5.6 5/12/2016 8.8 8.4 8/19/2015 7.3 7.2 5/19/2016 11.2 11 8/20/2015 6.9 6.7 5/26/2016 10.9 10.7 8/25/2015 7.4 7.3 6/1/2016 9.7 9.7 8/26/2015 7.6 7.5 6/2/2016 10.3 10.1 8/27/2015 7.9 7.9 6/7/2016 10.2 9.8 9/1/2015 7.7 7.4 6/8/2016 11 10.4 9/2/2015 7.5 7.3 6/9/2016 11.1 10.7 9/3/2015 7.3 7.2 6/14/2016 10.1 9.9 9/8/2015 7.4 7.1 6/15/2016 9.9 9.3 9/9/2015 7.2 7.1 6/16/2016 9.8 9.2 9/10/2015 7.1 6.8 6/21 /2016 10.6 10.1 9/15/2015 8.9 8.8 6/22/2016 10.1 9.8 9/16/2015 8.8 8.7 6/23/2016 9.9 9.4 9/17/2015 8.8 8.5 6/28/2016 8.8 8.5 9/22/2015 8.1 8.2 6/29/2016 9.9 9.7 9/23/2015 8.2 8.3 6/30/2016 9.7 9.5 9/24/2015 8.2 8.3 7/5/2016 9.5 9.2 9/29/2015 7.7 7.6 7/6/2016 9.6 9.2 9/30/2015 7.6 7.5 7/7/2016 9.8 9.3 10/1/2015 7.7 6.5 7/12/2016 9.4 9.3 10/8/2015 8.9 8.8 7/13/2016 9.6 9.3 10/15/2015 9.1 9.1 7/14/2016 9.8 9.5 10/22/2015 10.2 10 8/9/2016 9.6 9 10/29/2015 8.5 8.3 8/10/2016 9.6 9 11 /5/2015 8.8 8.5 8/11 /2016 9.7 9.3 11 /12/2015 9.1 9.2 9/20/2016 9.8 9.8 11 /19/2015 8 8 9/21 /2016 10.1 9.3 11 /25/2015 11.2 11.4 9/22/2016 9.9 9.6 12/2/2015 10.4 10 9/27/2016 9.4 8.7 12/10/2015 10.5 10.7 9/28/2016 9.9 9.6 12/17/2015 9.9 9.8 9/29/2016 10 9.8 12/23/2015 9.8 9.6 10/6/2016 11 11.2 12/30/2015 9.5 9.4 10/13/2016 12.4 12 1 /7/2016 12.4 12.3 10/20/2016 9.5 9.4 1 /14/2016 13.2 12.6 10/27/2016 12.6 12.1 1 /21 /2016 12.8 12.6 11 /3/2016 11.5 10.6 1 /28/2016 12.2 12 11 /10/2016 12.8 13.3 2/4/2016 9.8 9.6 11/17/2016 12.9 13.5 2/11 /2016 14 13.4 11 /23/2016 15.2 14.5 2/18/2016 12.8 12.3 12/1 /2016 13.9 14 2/25/2016 11 10.8 12/8/2016 14 13.2 3/3/2016 12.6 12.1 12/15/2016 15.4 14.6 3/10/2016 10.1 9.5 12/22/2016 15.2 15.1 3/17/2016 9.8 9.7 1/5/2017 15.2 14.6 3/24/2016 10.5 10 1 /12/2017 15.1 14.9 Upstream Downstream Upstream Downstream 1/19/2017 14.1 14.3 8/24/2017 10 9.7 1 /26/2017 13.1 12.5 8/29/2017 10.5 9.9 2/2/2017 14.6 13.7 8/30/2017 10.7 10.4 2/9/2017 13.2 12.6 8/31 /2017 10.4 10.1 2/16/2017 14.8 14 9/5/2017 10.9 10.7 2/23/2017 12.9 12 9/6/2017 10.3 10 3/2/2017 12.9 12.1 9/7/2017 11.6 11.5 3/9/2017 14.3 13.6 9/12/2017 10.6 10.4 3/16/2017 16.6 13.4 9/13/2017 11.5 11.1 3/23/2017 14.3 13.4 9/14/2017 11.2 10.6 3/30/2017 12 11 9/19/2017 10.6 10.7 4/6/2017 11.3 11.4 9/20/2017 11.2 10.5 4/13/2017 12 11.4 9/21 /2017 10.7 10.6 4/20/2017 12.2 11.8 9/26/2017 10.9 10.8 4/27/2017 11.4 10.8 9/27/2017 10.7 10.1 5/4/2017 11.6 11.5 9/28/2017 10.2 9.8 5/11 /2017 11.3 10.9 10/5/2017 12.3 12.3 5/18/2017 10.9 10.4 10/12/2017 10.7 9.7 5/25/2017 10.7 10.6 10/19/2017 13.1 12.8 6/1 /2017 10.9 10.4 10/26/2017 13.2 12.6 6/6/2017 10.2 9.7 11 /2/2017 13.1 12.5 6/7/2017 10.7 10.4 11 /9/2017 13.1 13.1 6/8/2017 11.1 10.8 11 /16/2017 14 14 6/13/2017 10.4 10.4 11 /23/2017 15.3 14.5 6/14/2017 9.9 9.5 11/30/2017 15.3 15.3 6/15/2017 10.1 9.9 12/7/2017 13.9 13.8 6/20/2017 10.1 9.9 12/14/2017 16.3 15.8 6/21 /2017 10.6 10.1 12/21 /2017 13.6 13.1 6/22/2017 10.4 9.9 6/27/2017 10.9 10.5 6/28/2017 11.5 11 6/29/2017 11.2 10.8 7/11/2017 10.1 9.7 7/12/2017 10 9.5 7/13/2017 9.8 8.7 7/18/2017 9.8 9.3 7/19/2017 10.2 9.9 Anova: Single Factor 7/20/2017 9.9 10 7/25/2017 9.8 9.5 SUMMARY 7/26/2017 9.9 9.8 Groups Count Sum Average Variance 7/27/2017 9.7 9.5 Upstream 184 1948.4 10.5891304 4.369062 8/1/2017 10.8 10.2 Downstream 184 1888 10.2608696 3.976056 8/2/2017 9.7 10.1 8/3/2017 10.7 10.7 8/8/2017 9.4 9 ANOVA 8/9/2017 10.2 10.1 SS df MS P-value F crit 8/10/2017 10.7 10.3 Between Grour 9.91347826 1 9.91347826 0.124087 3.866991 8/15/2017 9.5 9 Within Groups 1527.15652 366 4.1725588 8/16/2017 9.4 9.1 8/17/2017 10.1 9.8 Total 1537.07 367 8/22/2017 10.4 9.5 8/23/2017 10.4 9.4 MONITORING REPORT(MR) VIOLATIONS for: Permit: NC0006190 MRs Between 1 - 2013 and 2 - 2018 Region: % Facility Name: % Param Name % County: % Major Minor: % Report Date: 02/12/18 Page: 1 of 2 Violation Category% Program Category: Subbasin:%41 Violation Action: % PERMIT: NC0006190 FACILITY: South Fork Industries Inc - South Fork Industries - COUNTY: Catawba REGION: Mooresville Maiden Plant Limit Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPS LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 05 -2014 001 Effluent BOD, 5-Day (20 Deg. C) - 05/13/14 3 X week Ibs/day 325 680.3 109.3 Daily Maximum Proceed to Quantity Daily Exceeded Enforcement Case 05 -2014 001 Effluent BOD, 5-Day (20 Deg. C) - 05/15/14 3 X week Ibs/day 325 1,237.2 280.7 Daily Maximum Proceed to Quantity Daily Exceeded Enforcement Case 05 -2014 001 Effluent BOD, 5-Day (20 Deg. C) - 05/20/14 3 X week Ibs/day 325 742 128.3 Daily Maximum Proceed to Quantity Daily Exceeded Enforcement Case 05 -2014 001 Effluent BOD, 5-Day (20 Deg. C) - 05/21/14 3 X week Ibs/day 325 993.4 205.7 Daily Maximum Proceed to Quantity Daily Exceeded Enforcement Case 05 -2014 001 Effluent BOD, 5-Day (20 Deg. C) - 05/22/14 3 X week Ibs/day 325 554 70.5 Daily Maximum Proceed to Quantity Daily Exceeded Enforcement Case 05 - 2014 001 Effluent BOD, 5-Day (20 Deg. C) - 05/31/14 3 X week Ibs/day 162 395.49 144.1 Monthly Average Proceed to Quantity Daily Exceeded Enforcement Case Monitoring Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPS LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 04 -2017 001 Effluent BOD, 5-Day (20 Deg. C) - 04/01/17 3 X week Ibs/day Frequency Violation No Action, BIMS Quantity Daily Calculation Error 12 -2017 001 Effluent BOD, 5-Day (20 Deg. C) - 12/02/17 3 X week Ibs/day Frequency Violation None Quantity Daily 04 -2017 001 Effluent Chromium, Total (as Cr) 04/01/17 Weekly ug/I Frequency Violation No Action, BIMS Calculation Error 04 - 2017 001 Effluent Color, Spectrophoto-Metric 04/01/17 Weekly admi unit Frequency Violation No Action, BIMS Filter Calculation Error 04 - 2017 001 Effluent Conductivity 04/01/17 3 X week umhos/cm Frequency Violation No Action, BIMS Calculation Error 12 -2017 001 Effluent Conductivity 12/02/17 3 X week umhos/cm Frequency Violation None 04 -2017 001 Effluent Nitrogen, Ammonia Total (as 04/01/17 3 X week mg/I Frequency Violation No Action, BIMS N) - Concentration Calculation Error MONITORING REPORT(MR) VIOLATIONS for: Report Date: 02/12/18 Page: 2 of 2 Permit: NC0006190 MRs Between 1 - 2013 and 2 - 2018 Region: % Violation Category:% Program Category: % Facility Name: % Param Name % County: % Subbasin:% Violation Action: Major Minor: PERMIT: NC0006190 FACILITY: South Fork Industries Inc - South Fork Industries - COUNTY: Catawba REGION: Mooresville Maiden Plant Monitoring Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 12 -2017 001 Effluent Nitrogen, Ammonia Total (as 12/02/17 3 X week mg/I Frequency Violation None N) - Concentration 04 -2017 001 Effluent Oxygen Demand, Chem. 04/01/17 Weekly Ibs/day Frequency Violation No Action, BIMS (High Level) (COD) Calculation Error 04 - 2017 001 Effluent Oxygen, Dissolved (DO) 04/01/17 3 X week mg/I Frequency Violation No Action, BIMS Calculation Error 12 - 2017 001 Effluent Oxygen, Dissolved (DO) 12/02/17 3 X week mg/I Frequency Violation None 04 - 2017 001 Effluent pH 04/01/17 3 X week su Frequency Violation No Action, BIMS Calculation Error 12 - 2017 001 Effluent pH 12/02/17 3 X week su Frequency Violation None 04-2017 001 Effluent Phenolics, Total Recoverable 04/01/17 Weekly Ibs/day Frequency Violation No Action, BIMS Calculation Error 04 - 2017 001 Effluent Solids, Total Suspended - 04/01/17 3 X week Ibs/day Frequency Violation No Action, BIMS Quantity Daily Calculation Error 12 - 2017 001 Effluent Solids, Total Suspended - 12/02/17 3 X week Ibs/day Frequency Violation None Quantity Daily 04 - 2017 001 Effluent Sulfide, Total (as S) 04/01/17 Weekly Ibs/day Frequency Violation No Action, BIMS Calculation Error 04 - 2017 001 Effluent Temperature, Water Deg. 04/01/17 3 X week deg c Frequency Violation No Action, BIMS Centigrade Calculation Error 12 - 2017 001 Effluent Temperature, Water Deg. 12/02/17 3 X week deg c Frequency Violation None Centigrade Reporting Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 09 -2016 10/31/16 Late/Missing DMR No Action, BPJ 11 -2017 001 Effluent Temperature, Water Deg. 11/30/17 3 X week deg c Sampling Location None Centigrade Missing Whole Effluent Toxicity Testing and Self Monitoring Summary Danaher (Dynapar)/004 (comb 1,2,3) NC0001121/004 County: Bladen Fthd24PF Begin: 1/1/2015 Ac P/F Monit: 90% Ft NonComp: Single J F M A M 2014 Fail Pass Pass 2015 Pass 2016 Pass Pass 2017 Pass Daniel Stowe Botanical Garden NCO088684/001 County: Gaston Ceri7dPF Begin: 5/1/2016 Chr Monit: 90% NonComp: J F M A M 2014 Fail 2015 Fail 2016 Pass 2017 Fail Dare County-/002 (RO) WTP NCO070157/002 County: Dare Mysd24PF Begin: 2/1/2009 24hr p/f ac monit: 90 NonComp: J F M A M 2014 Pass Pass 2015 Pass Pass 2016 Pass Pass 2017 Fail - Pass Davidson Water Inc. WTP NCO084425/001 County: Davidson Ceri7dPF Begin: 10/1/2017 Chr Monit: 90% NonComp: J F M A M 2014 Pass Pass 2015 Fail Fail 2016 Fail Pass 2017 Pass Pass Deer Chase Subdivision WWTP NCO063746/001 County: Wake Ceri7dPF Begin: 6/1/2008 chr lim: 90% @ 0.05 NonComp: Single J F M A M 2014 Pass Pass 2015 Pass Pass 2016 Pass - Pass 2017 Fail >100 >100 >100 Pass Delta Apparel - S. Fork NC0006190/001 Cer7dChV Begin: 5/1/2013 chr lim: 12% J F M 2014 16.97 2015 16.97 2016 16.97 2017 17 Region: FRO 7Q10: 812.5 J J Fail Fail Fail Pass Pass Pass Pass Pass Region: MRO 7Q10: 0 J J Fail Fail Pass Fail Region: WARO 7Q10: Tidal l J Pass Pass Pass Region: WSRO 7Q10: J J Region: RRO 7Q10: 0.0 J J Pass Pass Pass Fail County: Catawba Region: MRO NonComp: Single 7Q10: 12 A M J J 16.97 16.97 16.97 16.97 Basin: CPF16 Mar Jun Sep Dec PF: NA IWC: NA Freq: Q A S O Pass Fail Pass Pass Fail Pass Basin: CTB37 Mar Jun Sep Dec PF: 0.003 IWC: 100 Freq: Q A S O Fail - Fail Fail Pass - Basin: PAS56 Jan Apr Jul Oct PF: 1.42 IWC: NA Freq: Q A 5 O Pass Pass Pass Pass Basin: YAD04 Feb May Aug Nov PF: 0.3 IWC: Freq: A A S O Pass - Pass Pass Pass - Basin: NEU02 Jan Apr Jul Oct PF: 0.05 IWC: 100 Freq: Q A S O Pass Pass - - Pass >100 >100 Pass Basin: CTB35 Mar Jun Sep Dec PF: 1.1 IWC: 11 Freq: Q A 5 O 16.97 - 16.97 33.94 33.9 SOC JOC: N D Pass Fail Pass Pass SOC JOC: N D Pass Fail Pass Pass SOC JOC: N D SOC JOC: N D Pass Pass Pass Fail Fail SOC JOC: N D SOC-JOC: N D 16.97 16.97 33.94 17 Leeend: P= Fathead minnow (Pimohales oromelas). H=No Flow (facility is active). s = Split test between Certified Labs Page 29 of 105 NH3/TRC WLA Calculations Facility: South Fork Industries, Inc. PermitNo. NC0006190 Prepared By: Bing Bai Enter Design Flow (MGD): 1.1 Enter s7Q10 (cfs): 12 Enter w7Q10 cfs : 25.5 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 12 s7Q10 (CFS) 12 DESIGN FLOW (MGD) 1.1 DESIGN FLOW (MGD) 1.1 DESIGN FLOW (CFS) 1.705 DESIGN FLOW (CFS) 1.705 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 12.44 IWC (%) 12.44 Allowable Conc. (ug/1) 137 Allowable Conc. (mg/1) 6.5 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 25.5 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 1.1 (If DF >331; Monitor) DESIGN FLOW (CFS) 1.705 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 8.04 Upstream Bkgd (mg/1) 0.22 IWC (%) 6.27 Allowable Conc. (mg/1) 25.4 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) 7/26/18 WQS = 12 ng/L Facility Name South Fork Industries, Inc. / NC0006190 /Permit No. : Total Mercury 1631E PQL = 0.5 ng/L Date Modifier Data Entry Value 7/11/18 2.4 2.4 MERCURY WQBEL/TBEL EVALUATION V:2013-6 No Limit Required No MMP Required 7Q10s = 12.000 cfs WQBEL = 96.46 ng/L Permitted Flow = 1.100 47 ng/L 2.4 ng/L - Annual Average for 2018 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Proiect Information Facility Name WWTP/WTP Class NPDES Permit Outfal I Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑CHECK IF HQW OR ORW WQS South Fork Industries, Inc. 3 NC0006190 001 1.100 Clark Creek 03050102 C ❑Apply WS Hardness WQC 7Q10s (cfs) 7Q10w (cfs) 30Q2 (cfs) QA (cfs) 1Q10s (cfs) 12.00 25.50 34.00 78.00 9.94 Effluent Hardness -------------------------------- Upstream Hardness .------------ Combined Hardness Chronic Acte Combined Hardness u 26.16 mg/L (Avg) 36.64 mg/L (Avg) ---------- ----- 35.34 m /L I 35.11 m /L Data Source(s) ❑CHECK TO APPLY MODEL Par01 Par02 Par03 Par04 Par05 Par06E Par07 ParOB ParO9 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Part B Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.7664 FW 4.3575 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 156.3151 FW 1195.2608 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A Ng/L Copper Aquatic Life NC 10.5926 FW 14.4202 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 4.3381 FW 110.5097 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 49.8967 FW 446.7574 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 0.5315 ug/L Zinc Aquatic Life NC 169.9220 FW 167.6106 ug/L NC0006190 RPA, input 6/21 /2018 NC0006190 RPA, input 6/21 /2018 South Fork Industries, Inc. - NC0006190 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM Qw (MGD) = 1.10 1Q10S (cfs) = 9.94 7Q10S (cfs) = 12.00 7Q10W (cfs) = 25.50 30Q2 (cfs) = 34.00 Avg. Stream Flow, QA (cfs) = 78.00 Receiving Stream: Clark Creek HUC 03050102 DATA POINTS = 58 WWTP/WTP Class: 3 IWC% @ 1Q10S = 14.64147703 1WC% @ 7Q10S = 12.44071507 IWC% @ 7Q10W = 6.267230289 1WC% @ 30Q2 = 4.775241563 IW%C @ QA = 2.139138072 Stream Class: C Outfall 001 Qw = 1.1 MGD COMBINED HARDNESS (m¢/L) Acute = 35.11 mg/L Chronic = 35.34 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA (n REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE d � Chronic Acute Applieda n # Det. Max Pred Cw Allowable Cw (1) M Standard Acute (FW): 2,322.2 No RP, Predicted Max < 50% of Allowable Cw - No Arsenic C 150 FW(7Q10s) 340 ug/L Monitoring required 1 0 NO DETECTS Chronic (FW): 1,205.7 No RP, Predicted Max < 50% of Allowable Cw - No Max MDL = 5 Monitoring required Arsenic C 10 HH/WS(Qavg) ug/L Note: n 5 9 Chronic (HH): 467.5 Limited data set Max MDL = 5 Acute: 443.94 Beryllium NC 6.5 FW(7Q10s) 65 ug/L 1 0 NO DETECTS Note: n < 9 Chronic: 52.25 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set Max MDL = 1 Monitoring required Acute: 29.761 Cadmium NC 0.7664 FW(7Q10s) 4.3575 ug/L 1 0 No DETECTS Note: n < 9 Chronic: 6.160 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set Max MDL = 2 Monitoring required Acute: NO WQS Chlorides NC 230 FW(7Q10s) mg/L 6 6 81.3 Note: n < 9 Default C.V. _ _ _ _ _ _ _ _ _ _ _ Chronic 1,848.8 _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Limited data set No value > Allowable Cw Monitoring required Acute: NO WQS Total Phenolic Compounds NC 300 A(30Q2) ug/L 1 1 180.0 No RP, Predicted Max < 50% of Allowable Cw - No Note: n < 9 Default C.V. _ Chronic 6,282.4 Limited data se jNo value > Allowable Cw Monitoring required Acute: 8,163.5 Chromium III NC 156.3151 FW(7Q10s) 1195.2608 µg/L 0 0 N/A _ -- Chronic- - 1,256.5 - - - - - - - - - Acute: 109.3 all total chromium are < 5 ug/L Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A __ _ _ ____ _ _ Chronic: 88.4 _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Chromium, Total NC µg/L 21 0 NO DETECTS a. No Monitoring required if all Total Chromium samples are < the Chromium A Allowable Cw Max MDL = 5 Acute: 98.49 Copper NC 10.5926 FW(7Q10s) 14.4202 ug/L 5 5 74.24 Note: n < 9 Default C.V. Chronic: 85.14 No RP , Predicted Max >_ 50% of Allowable Cw - Limited data set JNo value > Allowable Cw apply Quarterly Monitoring NC0006190 RPA, rpa Page 1 of 2 8/2/2018 South Fork Industries, Inc. Outfall 001 N0000619U Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 1.1 MUD Acute: 150.3 Cyanide NC 5 FW(7Q10s) 22 10 ug L 1 1 13.0 _ _ _ _ _I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Note: n < 9 Default C.V. Chronic: 40.2 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set No value > Allowable Cw Monitoring required Acute: NO WQS Fluoride NC 1800 FW(7Q10s) ug/L 1 1 186.0 Note: n < 9 Default C.V. _ Chronic 14,468.6 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set No value > Allowable Cw Monitoring required Acute: 754.772 Lead NC 4.3381 FW(7Q10s) 110.5097 ug/L 1 0 NO DETECTS Note: n < 9 _ _ _ _ _ _ _ _ Chronic: 34.870 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set Max MDL = 5 Monitoring required Acute (FW): 3,051.3 Nickel NC 49.8967 FW(7Q10s) 446.7574 µg/L 1 0 NO DETECTS _ ------------------------------------------- Chronic (FW): 401.1 No RP, Predicted Max < 50% of Allowable Cw - No Note: n s 9 Max MDL = 5 Monitoring required Nickel NC 25.0000 WS(7Q10s) µg/L Limited data set Chronic (WS): 201.0 Max MDL = 5 Acute: 382.5 ]No Selenium NC 5 FW(7Q10s) 56 ug/L 1 0 NO DETECTS Note: n <_ 9 _ _ _ _ _ _ _ Chronic: 40.2 _ _ _ _ _ _ _ _ _ _ _ _ _ RP, Predicted Max < 50% of Allowable Cw - No Limited data sel Max MDL = 5 Monitoring required Silver NC 0.06 FW(7Q10s) 0.5315 ug/L 1 0 NO DETECTS Acute: 3.630 No detects Note: n <_ 9 Chronic: 0.482 Permittee shall sample to lower PQL at 1 ug/L, no Limited data set Max MDL = 5 limit or monitoring is required Acute: 1,144.8 Zinc NC 169.9220 FW(7Q10s) 167.6106 ug/L 12 12 648.0 Chronic:1,365.9 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required NC0006190 RPA, rpa Page 2 of 2 8/2/2018 H1 REASONABLE POTENTIAL ANALYSIS H2 Use "PASTE SPECIAL Effluent Hardness Values" then "COPY" Upstream Hardness Maximum data points = 58 Date Data BDL=1/2DL Results 1 3/29/2018 21 21 Std Dev. 2 4/4/2018 50 50 Mean 3 4/18/2018 21 21 C.V. (default) 4 5/10/2018 18.4 18.4 n 5 5/17/2018 20.4 20.4 10th Per value 6 Average Value 7 Max. Value 8 9 10 11 12 13 14 15 16 17 18 19 20 21 Date Data BDL=1/2DL Results 13.3697 1 3/29/2018 44 44.1 Std Dev. 26.1600 2 4/5/2018 21 21 Mean 0.6000 3 4/19/2018 43 43 C.V. (default) 5 4 4/26/2018 28 28.1 n 19.20 mg/L 5 5/3/2018 47 46.8 10th Per value 26.16 mg/L 6 5/10/2018 45 44.9 Average Value 50.00 mg/L 7 5/17/2018 29 28.6 Max. Value 8 9 10 11 12 13 14 15 16 17 18 19 20 21 ParO' Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 1 10.4062 36.6429 2 0.6000 3 7 4 25.26 mg/L 5 36.64 mg/L 6 46.80 mg/L 7 NC0006190 RPA, data - 1 - 8/2/2018 8 9 10 11 12 13 14 15 16 17 18 19 20 21 REASONABLE POTENTIAL ANALYSIS 1 & Par02 Use "PASTE SPECIAL Arsenic Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 8/24/2015 < 5 2.5 Std Dev. N/A Mean 2.5000 C.V. 0.0000 n 1 Mult Factor = 1.00 Max. Value 2.5 ug/L Max. Pred Cw O DETECTS ug/L NC0006190 RPA, data - 2 - 8/2/2018 Par03 REASONABLE POTENTIAL ANALYSIS Par04 Use "PASTE SPECIAL Beryllium Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 1 8/24/2015 < 1 0.5 Std Dev 2 Mean 3 C.V. 4 n 5 Cadmium Date Data BDL=1/2DL Results N/A 1 8/24/2015 < 2 1 Std Dev 0.5000 2 Mean 0.0000 3 C.V. 1 4 n 5 Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 N/A 1.0000 0.0000 1 6 Mult Factor = 1.00 6 Mult Factor = 1.00 7 Max. Value 0.50 ug/L 7 Max. Value 1.000 ug/L 8 Max. Pred Cw O DETECTS ug/L 8 Max. Pred Cw O DETECTS ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 9 10 11 12 13 14 15 16 17 18 19 20 21 ParO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 NC0006190 RPA, data -3- 8/2/2018 5 REASONABLE POTENTIAL ANALYSIS Par07 Use "PASTE SPECIAL - Chlorides Values" then "COPY". Total Phenolic Compounds Maximum data points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 12/13/2016 38 38 Std Dev. 8.7101 1 8/24/2015 180.0 180.0 Std Dev. 3/14/2017 17 17 Mean 21.7 2 Mean 6/6/2017 23 23 C.V. (default) 0.6000 3 C.V. 9/5/2017 18 18 n 6 4 n 3/18/2018 13 13 5 6/5/2018 21 21 Mult Factor = 2.1 6 Mult Factor = Max. Value 38.0 mg/L 7 Max. Value Max. Pred Cw 81.3 mg/L 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 NC0006190 RPA, data - 4 - 8/2/2018 Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 N/A 180.0000 0.0000 1 1.00 180.0 ug/L 180.0 ug/L REASONABLE POTENTIAL ANALYSIS Par10 Chromium, Total Use "PASTE SPECIAL. Values" then "COPY" Pal Copper Maximum data points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 10/25/2017 < 5 3 Std Dev. 0.0000 1 12/13/2016 29 29 Std Dev. 2 10/18/2017 < 5 3 Mean 2.5000 2 3/14/2017 32 32 Mean 3 10/11/2017 < 5 3 C.V. 0.0000 3 9/5/2017 23 23 C.V. (default) 4 10/4/2017 < 5 3 n 21 4 3/18/2018 24 24 n 5 9/27/2017 < 5 3 5 6/5/2018 30 30 6 9/20/2017 < 5 3 Mult Factor = 1.00 6 Mult Factor = 7 9/13/2017 < 5 3 Max. Value 2.5 fag/L 7 Max. Value 8 9/6/2017 < 5 3 Max. Pred Cw O DETECTS pg/L 8 Max. Pred Cw 9 8/30/2017 < 5 3 9 10 8/23/2017 < 5 3 10 11 8/16/2017 < 5 3 11 12 8/9/2017 < 5 3 12 13 8/2/2017 < 5 3 13 14 7/26/2017 < 5 3 14 15 7/19/2017 < 5 3 15 16 7/12/2017 < 5 3 16 17 6/28/2017 < 5 3 17 18 6/21 /2017 < 5 3 18 19 6/14/2017 < 5 3 19 20 6/7/2017 < 5 3 20 21 5/31 /2017 < 5 3 21 NC0006190 RPA, data -5- 8/2/2018 Par12 Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 REASONABLE POTENTIAL ANALYSIS Par13 Use "PASTE SPECIAL Cyanide Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 3.9115 1 8/26/2015 13 13 Std Dev. N/A 27.6000 2 Mean 0.6000 3 C.V. 5 4 n 5 2.32 6 Mult Factor = 32.00 ug/L 7 Max. Value 74.24 ug/L 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 I't3 13.00 0.0000 1 1.00 13.0 ug/L 13.0 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 Fluoride Date Data BDL=1/2DL Results 186 186 Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw NC0006190 RPA, data 8/2/2018 Par14 Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Lead Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results N/A 1 8/24/2015 < 5 2.5 Std Dev. N/A 186.0000 2 Mean 2.5000 0.0000 3 C.V. 0.0000 1 4 n 1 5 1.00 6 Mult Factor = 1.00 186.0 ug/L 7 Max. Value 2.500 ug/L 186.0 ug/L 8 Max. Pred Cw O DETECTS ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 -7- Par17 & Par18 Nickel Date Data BDL=1/2DL Results 1 8/24/2015 < 5 2.5 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 NC0006190 RPA, data 8/2/2018 REASONABLE POTENTIAL ANALYSIS Use "PASTE Par19 SPECIAL -Values" Use "PASTE SPECIAL then "COPY". Selenium es" then "COPY" Values" Maximum data points Maximum data - 58 points = 58 Date 1 8/24/2015 Data BDL=1/2DL Results < 5 2.5 Std Dev. N/A N/A 2.5000 2 Mean 2.5000 0.0000 3 C.V. 0.0000 1 4 n 1 5 1.00 6 Mult Factor = 1.00 2.5 pg/L 7 Max. Value 2.5 ug/L O DETECTS pg/L 8 Max. Pred Cw JO DETECTS ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 Par20 Silver Date Data BDL=1/2DL Results 1 8/24/2015 < 5 2.5 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 NC0006190 RPA, data 8/2/2018 REASONABLE POTENTIAL ANALYSIS Par21 Use "PASTE SPECIAL Use "PASTE SPECIAL - Values" then "COPY" Zinc Values" then "COPY". Maximum data Maximum data points = points = 58 1 58 1 Date 3/22/2016 Data 405 BDL=1/2DL Results 405 Std Dev. 124.0128 N/A 2.5000 2 3/4/2015 322 322 Mean 213.7667 0.0000 3 12/8/2015 303 303 C.V. 0.5801 1 4 9/1/2015 282 282 n 12 5 6/2/2015 280 280 1.00 6 12/13/2016 212 212 Mult Factor = 1.60 2.500 ug/L 7 9/27/2016 168 168 Max. Value 405.0 ug/L O DETECTS ug/L 8 3/14/2017 154 154 Max. Pred Cw 648.0 ug/L 9 9/5/2017 54 54 10 6/6/2017 48 48 11 6/21 /2016 25 25.2 12 8/24/2015 312 312 13 14 15 16 17 18 19 20 21 NC0006190 RPA, data - 9 - 8/2/2018