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HomeMy WebLinkAboutNC0067342_EPA Facility Assessment Report 11/29/2018_20181029UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 4 Science and Ecosystem Support Division Field Services Branch 980 College Station Road Athens, Georgia 30605-2720 November 29, 2018 MEMORANDUM SUBJECT: (Revision #2) NPDES Diagnostic Evaluation Report Transmittal Northview Mobile Home Park WWTP Weaverville, North Carolina SESD Project ID: 18-0570 FROM: Chris McHugh, Environmental Engineer Enforcement Section Science and Ecosystem Support Division Athens, Georgia THRU: Mike Bowden, Chief Enforcement Section TO: Science and Ecosystem Support Division Athens, Georgia Dennis Sayre, Acting Chief Municipal and Industrial Enforcement Section Water Protection Division Atlanta, Georgia Attached is a revised copy of the NPDES Diagnostic Evaluation (DE) Report for the inspection conducted at the Northview Mobile Home Park WWTP located at Northview Park Road, Weaverville, NC. The DE was conducted from July 16-18, 2018. the recommendations included in this report reflect the operational conditions and configuration of the WWTP at the time of the EPA evaluation. Suggestions and recommendations should be reviewed and implemented applicable to the current WWTP unit processes. The report was revised to correct the clarifier volume stated in Table 9 on page 18 and to change the name of acting chief from David Apanian to Dennis Sayre. The revisions do not affect any subsequent calculations in the report. This revised report supersedes the original report. Please forward copies of the report to the appropriate parties. If you have any questions concerning the diagnostic evaluation, please call me at (706) 355-8652 or email me at Mchugh.christopher@epa.gov. Attachment: Cc (via email): Gracy Danois, USEPA, WPD, NPDES Permitting and Enforcement Branch Andrea Zimmer, USEPA, WPD, NPDES Permitting and Enforcement Branch Sara Schiff Janovitz, USEPA, WPD, State of North Carolina Pacesetter Mary Mattox, USEPA, WPD, NPDES Permitting and Enforcement Branch SESD ID: 18-0570 Final Report Page 1 of 58 Project ID: 18-0570 NPDES Diagnostic Evaluation Report (Revision 2) Northview Mobile Home Park WWTP Northview Park Road Weaverville, NC, 28787 Project Date: July 16-18, 2018 Report Date: November 29, 2018 Project Leader: Chris McHugh Environmental Engineer, EIT Enforcement Section Field Services Branch Science & Ecosystem Support Division USEPA – Region 4 980 College Station Road Athens, Georgia 30605-2720 The activities depicted in this report are accredited under the US EPA Region 4 Science and Ecosystem Support Division ISO/IEC 17025 accreditation issued by the ANSI-ASQ National Accreditation Board. Refer to certificate and scope of accreditation AT-1644. SESD ID: 18-0570 Final Report Page 2 of 58 Approvals: SESD Project Leader: Chris McHugh, Environmental Engineer Enforcement Section Field Services Branch Science and Ecosystem Support Division Date Approving Official: Mike Bowden, Chief Enforcement Section Field Services Branch Science and Ecosystem Support Division Date Requestor: Dennis Sayre, Acting Chief NPDES Permitting and Enforcement Branch Water Protection Division USEPA – Region 4 61 Forsyth Street SW Atlanta, GA, 30303-8960 Analytical Support: Science and Ecosystem Support Division U.S. EPA Region 4 980 College Station Rd Athens, GA, 30605 11/08/2018 11/08/2018 SESD ID: 18-0570 Final Report Page 3 of 58 Table of Contents 1.INTRODUCTION................................................................................................................. 4 2.BACKGROUND ................................................................................................................... 5 3.SUMMARY AND RECOMMENDATIONS ...................................................................... 5 4.FACILITY SITE REVIEW ................................................................................................. 6 5.PERMIT................................................................................................................................. 7 6.RECORDS AND REPORTS ............................................................................................... 8 7.FLOW MEASUREMENT ................................................................................................... 8 8.SLUDGE HANDLING ......................................................................................................... 9 9.SAMPLING ........................................................................................................................... 9 9.1 FACILITY SAMPLING ........................................................................................................ 9 9.2 USEPA SAMPLING ACTIVITIES ...................................................................................... 10 9.3 USEPA SAMPLING RESULTS ......................................................................................... 11 9.4 USEPA PROCESS CONTROL RESULTS............................................................................ 12 9.4 USEPA SAMPLING METHODOLOGY .............................................................................. 15 10.EFFLUENT AND RECEIVING WATERS ................................................................. 15 11.REFERENCES ................................................................................................................ 16 List of Tables TABLE 1 - INSPECTION PERSONNEL .................................................................................. 4 TABLE 2 - FLOW MEASUREMENT DEVICE COMPARISON .......................................... 8 TABLE 3 - TYPICAL CONCENTRATIONS OF UNTREATED DOMESTIC WASTEWATER** ............................................................................................................. 10 TABLE 4 - SESD SAMPLING RESULTS ............................................................................... 11 TABLE 5 - SESD IN-SITU SAMPLING RESULTS ............................................................... 12 TABLE 6 - PROCESS CONTROL RESULTS SUMMARY ................................................. 13 TABLE 7 - NEW ASB IN-SITU PROFILE ............................................................................ 14 TABLE 8 - OLD ASB IN-SITU PROFILE .............................................................................. 15 TABLE 9 - LEGEND FOR FIGURE 2 ..................................................................................... 18 TABLE 10 – OLD-ASB SETTLOMETER TEST RESULTS ................................................ 38 TABLE 11 – NEW-ASB SETTLOMETER TEST RESULTS ............................................... 38 List of Figures FIGURE 1 – NORTHVIEW MOBILE HOME PARK WWTP FLOW DIAGRAM ............ 7 FIGURE 2 - NORTHVIEW MOBILE HOME PARK WWTP TREATMENT UNIT DIMENSIONS ..................................................................................................................... 18 SESD ID: 18-0570 Final Report Page 4 of 58 NPDES Diagnostic Evaluation Northview Mobile Home Park WWTP (Permit No. NC0067342) 1. Introduction During the week of July 16, 2018, representatives of the U.S. Environmental Protection Agency (USEPA) Region 4 Science and Ecosystem Support Division (SESD) and the North Carolina Department of Environmental Quality (NCDEQ) conducted a National Pollutant Discharge Elimination System (NPDES) Diagnostic Evaluation (DE) of the Northview Mobile Home Park Wastewater Treatment Plant (WWTP) in Weaverville, North Carolina. The inspection was requested by the NCDEQ Asheville Regional Office to evaluate the plant’s treatment performance and operation, and to collect samples from the influent and effluent. The effluent samples were evaluated to determine if the treated wastewater was within permit limits. The following people listed in Table 1 participated in the inspection. Table 1 - Inspection Personnel Inspector Organization Date on site Chris McHugh USEPA Region 4 SESD 7/16/18 – 7/18/18 Louis Salguero USEPA Region 4 SESD 7/16/18 – 7/18/18 Cornell Gayle USEPA Region 4 SESD 7/17/18 – 7/18/18 Linda Wiggs NCDEQ Asheville Regional Office 7/16/18 – 7/18/18 Landon Davidson NCDEQ Asheville Regional Office 7/16/18 – 7/17/18 The diagnostic evaluation included the following tasks: •Assessing the design, operations, and management factors limiting treatment performance. •Review of operations and management of the wastewater treatment plant. •Evaluation of the unit process performance via visual observations, field measurements, sampling, data review, and process control testing. •Determination of the unit process operating parameters (e.g. TSS, TVSS, F/M, SVI, and Sludge Age). SESD ID: 18-0570 Final Report Page 5 of 58 •Evaluation of the NPDES self-monitoring program, including sampling, flow measurements, records and reports, and laboratory procedures. 2. Background The Northview Mobile Home Park WWTP is a privately-owned municipal wastewater treatment plant that serves Northview Mobile Home Park, consisting of approximately 170 mobile homes. The facility is designed to operate as an extended aeration plant that consists of an original package plant with an aeration basin, Imhoff clarifier, and digester, as well as a newer aeration basin, circular clarifier, and chlorine contact chamber. It is permitted to discharge 0.032 MGD to receiving waters designated as Flat Creek in the French Broad River Basin. Currently, the facility is under a Statutory Tap Moratorium because the NCDEQ Asheville Regional Office deemed it unable to adequately treat the volume of wastewater flow it receives daily. 3. Summary and Recommendations The purpose of this Diagnostic Evaluation was to evaluate the overall operation and maintenance of the plant’s treatment systems, review the operating records, and historical data relevant to plant operations associated with permit requirements, and provide technical recommendations to improve plant’s performance. SESD evaluated the Northview Mobile Home Park treatment processes and facility conditions, flow measurement system, sludge handling procedures, and NPDES sampling. This report reflects the operation and configuration of the WWTP at the time of the inspection. During the evaluation, two 24-hour composite influent wastewater samples were collected from the headworks of the plant. In addition, three 24-hour effluent composite samples were collected just before the outfall location. Influent and effluent samples were analyzed for Biochemical Oxygen Demand (BOD 5 ), Total Suspended Solids (TSS), Ammonia (NH 3 ), Nitrite-Nitrate (NO 3 - NO 2 ), Total Kjeldahl Nitrogen (TKN), Total Phosphorus, and Alkalinity. In-situ parameters (pH, dissolved oxygen (DO), Total Residual Chlorine, and temperature) were also measured at the effluent sampling location. Grab samples were collected from the two aeration basins and analyzed for TSS and Total Volatile Suspended Solids (TVSS) to gather more information for process control testing and operating calculations. In-situ parameters (pH, dissolved oxygen, specific conductivity, and temperature) were measured in both basins as well. The major findings were as follows: •The circular clarifier had sludge blanket depth covering 8.5 feet out of 10 feet total depth, and the polishing clarifier had 5.5 feet covering 10 feet total depth. •During the inspection, it was observed that the circular clarifier weir plates were covered in solids when the influent flow rate increased. (See photo # 7, #12). SESD ID: 18-0570 Final Report Page 6 of 58 •The dissolved oxygen levels in the aeration basins were below 1 mg/L, right after the aeration diffused blowers were turned off. The blowers are set to run 15 minutes every hour. DO levels recommended for extended aeration are 1 to 3 mg/l (Metlcalf & Eddy, 2014) •The secondary flow measurement device was showing inconsistent readings during the time of the inspection and was not within the accepted accuracy requirement of ±10 % of the primary flow measurement device. Outlined in Table 2, the facility’s secondary device was 66% – 69.4% lower than the instantaneous flow check made at the primary device. •There was no permanently installed staff gage to measure the water level above the weir plate. •The flow totalizer was not functioning properly during the inspection. •There were noticeable amounts of floating solids and debris in the chlorine contact chamber. (See photo # 9). •The effluent sample setup was not properly installed. The sample tubing dips downward over the chlorine contact chamber side wall into a PVC pipe before being routed to the automatic sampler. This creates a section of tubing that could improperly store the wastewater, adversely affecting the purging cycle of the sampler. •The Total Residual Chlorine measured at the pipe opening just before outfall was 370 µg/L, well above the permit limit of 28 µg/L. Recommendations are as follows: •Continue to monitor sludge levels throughout the plant and waste more frequently to prevent accumulation of sludge in the clarifiers. As conditions permit, sludge should not be removed more the 10 percent above previous levels during sludge wasting cycles to allow the biological system to stabilize and allow the operators to adequately assess plant conditions. •Consider modifying the aeration schedule to better balance the on/off cycle which will create a more stable environment for the microorganisms. The mixed liquor DO levels and effluent pH should be carefully monitored, more frequently if necessary to help achieve the right balance. •Install a measurement device such as a staff gage so that the water level above the weir can accurately be measured. •Have scheduled maintenance plans in place for broken equipment, such as the flow totalizer, to repair it on a timely basis. •Modify the effluent sampling tubing setup so that there are no unnecessary dips in the line that could affect the purge cycle of the sampler. •Determine the correct dosage of chlorination and dechlorination tablets required to adequately disinfect the effluent flow without exceeding the permit limits for Total Residual Chlorine. 4.Facility Site Review The WWTP is configured as an extended aerated system. Modifications to the original package plant include the addition of the new aeration basin, circular clarifier, and contact chamber. (See Figure 1). Influent wastewater enters the plant (see photo # 1) and splits between the new and old SESD ID: 18-0570 Final Report Page 7 of 58 aeration basins and the equalization basin. (See photo # 4, # 5). Following aeration, the flow from both basins is sent to the circular clarifier. Return activated sludge (RAS) is diverted back to the aeration basins, and waste activated sludge (WAS) is thickened and decanted in the digester before being hauled to a landfill. Afterwards the circular clarifier, flow is sent to a polishing clarifier (Imhoff tank). The old chlorine contact chamber serves as an additional retention unit before flow enters the new contact chamber, where tablets are used to chlorinate and dechlorinate the effluent before final discharge. The old chlorine contact chamber could be used to chlorinate the effluent, and the new contact chamber could be used to allow proper detention time for disinfection. Currently the chlorination and dechlorination is all applied in the new chlorine contact chamber seen in Figure 1. Figure 1 shows the flow diagram of the facility as determined by the facility operator and by visual observation during the inspection. Table 9 in Appendix A lists the size of each treatment unit, measured during the inspection. Figure 1 – Northview Mobile Home Park WWTP Flow Diagram 5.Permit The Northview Mobile Home Park WWTP permit (NC0067342) became effective on April 1, 2018 and will expire on March 31, 2023. The Northview Mobile Home Park and the wastewater treatment plant serving the homes are both owned by the Eaven Brice Partnership. Under the permit, the Eaven Brice Partnership can operate the existing 0.032 MGD extended aeration wastewater treatment facility, and after obtaining an Authorization to Construct permit from NCDEQ, construct and operate a 0.050 MGD facility to incorporate more wastewater from new homes. SESD ID: 18-0570 Final Report Page 8 of 58 6.Records and Reports As part of a settlement agreement with NCDEQ, the facility is required to submit monthly process control logs that show process control weekly results. The log shows dissolved oxygen and MLSS concentrations in the aeration basins, settlometer test results, clarifier sludge blanket depth, solids removed from the digester, and average flow. At the time of inspection, the facility was reporting the log each month. The facility should continue to perform the process control checks and maintain process control logs each month to help track the facility’s solids inventory and manage proper solids wasting. It was observed in the June 2018 and August 2018 logs that process control results for sludge blanket depth weren’t consistently recorded. The facility should keep track of the sludge blanket depth in the clarifiers and dissolved oxygen levels and settlometer test results for both aeration basins. This will help to provide information of possible process control adjustments to ensure that both basins are operating efficiently. 7.Flow Measurement The effluent flow measurement system is composed a of 90 ⁰ v-notch weir primary device and an ultrasonic flow meter as a secondary flow measurement device. At the time of the inspection the flow meter totalizer wheel was not recording flow. Additionally, the digital instantaneous flow reading was very inconsistent. The digital value was fluctuating from 1 gallon per minute to upwards of 40 gallons per minute in a five-minute time span. Table 2 - Flow Measurement Device Comparison Flow Device Device Type Flow (GPM) Percent Error Date and Time 90⁰ v-notch Weir Primary 17.66 (instantaneous) 66.0% 7/18/2018 12:45 pm Ultrasonic sensor Secondary 6.00 90⁰ v-notch Weir Primary 17.66 (instantaneous) 69.4% 7/18/2018 12:40 pm Ultrasonic sensor Secondary 5.4 Shown in Table 2, comparisons between the primary and secondary flow devices were made by converting the instantaneous head measurement from the 90⁰ v-notch Weir to instantaneous flow measurement and comparing that value with the secondary ultrasonic sensor instantaneous flow reading. The two comparisons between the primary and secondary flow devices indicated a flow measurement difference of 66.0% and 69.4% which is outside the USEPA accepted accuracy range of ±10% difference. SESD ID: 18-0570 Final Report Page 9 of 58 Deficiency: The facility’s flow meter is outside of the 10 % difference with the primary flow device. The flow totalizer was not recording flow on the paper wheel. Regulatory Requirement: 40 CFR, Part 122.41 (e), Proper Operation and Maintenance. The permittee shall at all times properly operate and maintain all facilities and systems of treatment and control and related appurtenances which are installed or used by the permittee to achieve compliance with the conditions of this permit. According to the “NPDES Compliance Inspection Manual, 2017,” The permittee's flow measurements should be within 10 percent of the inspector's measurements to certify accurate flow measurement. 8.Sludge Handling The Northview Mobile Home Park WWTP uses a septic tank company to dispose sludge from the digester. At the time of the inspection, the circular clarifier had a sludge blanket depth of 8.5 feet. (See photo # 11). The total depth of the clarifier is 10 feet. Additionally, the polishing clarifier (Imhoff tank) had a sludge blanket of 5.5 feet with a total depth of 10 feet. The chlorine contact chamber also had a sludge blanket of 0.25 feet with a total depth of 7.5 feet. (Note: the accumulated sludge in the chlorine contact chamber was pumped before the sludge depth measurement was taken). Typically, the sludge blanket depth should be kept to less than one- fourth of the clarifier sidewall water depth (CSU 2008). During the inspection, the digester was determined to have a storage capacity of about 3000 gallons. (See Table 9). Based on the amount of sludge build up throughout the plant, the facility should waste more sludge to the digester. On July 18, 2018, the facility had its digester pumped and the waste disposed of in a nearby landfill. (See photo # 3, # 15). Based on the sludge depth throughout the plant, it is recommended that the operator increase gradually the amount of WAS. Sludge management is a critical component to properly operate an activated sludge treatment system. 9.Sampling 9.1 Facility Sampling The permittee collected samples according to the sampling frequencies and sample types described in the permit. The facility collected the effluent flow composite samples with an automatic sampler. At the time of the inspection, it was difficult to observe the facility’s sampler collect a sample aliquot. The sampling frequency was sporadic and didn’t correlate to the flow composite sampler that the USEPA set to run at the same time as the facility. Deficiency: EPA also observed that the tubing running from the sampling location to the composite sampler did not allow the sampler to properly purge the tubing before collecting a sample aliquot. The SESD ID: 18-0570 Final Report Page 10 of 58 sample tubing should not have unnecessary bends or dips because it can store effluent wastewater during the purge cycle. Regulatory Requirement: 40 CFR, Part 122.41 (e), Proper Operation and Maintenance. The permittee shall at all times properly operate and maintain all facilities and systems of treatment and control and related appurtenances which are installed or used by the permittee to achieve compliance with the conditions of this permit. Recommendation: The facility should reconfigure the tubing setup, by removing the current PVC conduit and adjust the slope of the PVC conduit underground to avoid tubing bending. 9.2 USEPA Sampling Activities During the inspection, sampling was conducted to determine if the facility was meeting its effluent permit limits as well as to characterize the influent waste stream and to evaluate the operating parameters of the plant. On July 16, 2018, sampling equipment was setup at the facility’s influent and effluent locations to collect 24-hour composite samples. (See photos # 2, 9, and 13). After collecting the samples on July 18, 2018, the samplers were programmed to collect a second set of 24-hour composite samples. Process control samples in both the new and old aeration basins (ASB) were collected to measure the TSS and TVSS concentrations. These samples were collected as grab samples. Additionally, a third effluent composite sampler paced by constant 15-minute intervals was set up on July 17, 2018, because of difficulties using a flow meter to pace the sampling. The difficulties encountered while setting up the flow meter were because there was no staff gage to measure the water level above the weir plate and the ability to accurately determine the level using a handheld level. See photo #10. Table 3 shows a comparison of USEPA influent analytical results and typical influent wastewater concentrations. The strength of the incoming TSS, BOD 5 , NH 3 , and TKN concentrations was high. This high strength influent is typical in plants of which the only influent source are single residential areas such as mobile home parks. There are no other inflow and infiltration sources to dilute the incoming waste concentration which is typically seen at larger domestic wastewater treatment plants. Table 3 - Typical Concentrations of Untreated Domestic Wastewater** Strength in (mg/L) USEPA SAMPLING Analysis Low Medium High INF001 INF002 NH 3 14 20 41 54 48 TKN 23 35 69 88 78 NO 3 -NO 2 0* 0* 0* .077 .078 P 3.7 5.6 11 14 12 SESD ID: 18-0570 Final Report Page 11 of 58 BOD 5 133 200 400 330 300 TSS 130 195 389 780 820 *Trace concentrations **Wastewater Engineering: Treatment and Reuse 5th edition, Metcalf & Eddy, 2014. McGraw- Hill Inc. NYC 9.3 USEPA Sampling Results Table 4 highlights the USEPA sampling analytical results for the influent and effluent locations as well as process control locations. As seen in the EFF002 and EFF003 results, pacing by flow and by time provided comparable results, and the effluent being discharged met permit limits for each EFF001, EFF002, and EFF003. See Appendix D, SESD Final Analytical Results for a complete listing of analytical data. Table 4 - SESD Sampling Results Station ID EFF001 * EFF002 ** EFF003 *** INF001 INF002 NEW- ASB OLD- ASB Type Composite Composite Composite Composite Composite Grab Grab Date 7/17/18 7/18/18 7/18/18 7/17/18 7/18/18 7/17/18 7/17/18 Time 10:25 11:17 11:30 11:10 11:00 15:00 15:00 Analyte mg/L mg/L mg/L mg/L mg/L mg/L mg/L NH 3 as N 0.90 0.098 0.12 54 48 - - TKN 4.7 3.7 3.8 88 78 - - NO 3 -NO 2 0.078 0.050 U 0.050 U 0.077 0.078 - - Alkalinity 160 150 160 370 330 - - P 1.5 1.4 1.2 14 12 - - BOD 5 4.0 J, K 4.0 J, K 4.0 J, K 330 J. L 300 J, L - - TSS 5.2 5.0 U 5.0 U 780 820 4700 4100 TVSS - - - - - 3800 3300 Notes: The laboratory report includes the definition of Region 4 Analytical Data Qualifiers, which is included in Appendix D. *EFF001 Flow proportional sample finished sampling in approximately 8 hours due to average daily flow being much higher than anticipated. **EFF002 Time proportional sample run simultaneously with EFF003 to ensure 24-hour composite sample ***EFF003 Despite recalculating flow pacing volume, sampler still finished in approximately 12 hours due to average daily flow being higher than anticipated. SESD ID: 18-0570 Final Report Page 12 of 58 Table 5 - SESD In-situ Sampling Results Analysis pH Specific Conductivity Dissolved Oxygen Total Residual Chlorine Units Standard Units µs/cm mg/L µg/L Sample ID EFF002 and EFF003 6.99 660 3.21 370 Shown in Table 5, in-situ parameters were measured at the time of effluent sample collection on 7/18/18. Deficiency: The Total Residual Chlorine was 370 µg/L, which exceeds the daily maximum permit limit. Regulatory Requirement: NC0067342 Section 3.A.(1) states that the Total Residual Chlorine daily maximum is 28 µg/L. Recommendation: The facility should adjust the amount of chlorination and dechlorination to meet permit limits. 9.4 USEPA Process Control Results The following process control tests were conducted: •Settlometer test, dissolved oxygen profile in the aeration tanks, and sludge blanket depths in the clarifiers. •Microorganism evaluation of grab samples from aeration basins using a standard phase/contract microscope. (See photo # 14). •Unit process operating parameters were also calculated to determine if the hydraulic and organic loadings were within the recommended range of operation and design for an extended aeration unit. Table 6 outlines the results of the process control tests and calculations conducted during the inspection. Based on the results and visual observations, the facility is operating with excess solids. This is evident by a low F/M ratio (high concentration of microorganisms, MLVSS compared to food, BOD 5 ), high sludge blanket depths in both clarifiers, and a sludge age that is on the high range. Additionally, the dissolved oxygen profile indicates that the current blower schedule is causing the aeration basins to go into anoxic states shortly after blowers are cycled off. At the time of the inspection, the blower schedule was set to run for 15 minutes every hour. The facility should evaluate the volume of solids in its system and gradually remove more solids on a regular basis. This will lower the MLSS concentration in the aeration basin, reduce the SESD ID: 18-0570 Final Report Page 13 of 58 sludge blanket depths in the clarifiers and prevent further solids loss during peak flow events. Typically, facilities use an operating strategy for sludge wasting such as maintaining a target F/M ratio, constant MLVSS concentration, or target Mean Cell Residence Time (MCRT). Additionally, the blower on/off cycle should be evaluated to maintain the aeration basins DO levels above 1 mg/L (recommended DO levels: 1 mg/L to 3 mg/L). This will create a healthy biomass environment. A gradual reduction in the solids inventory would allow for proper DO levels with less aeration requirements and subsequently less power consumption. Careful consideration of the plant’s effluent quality should be noted when making changes to the solids inventory. Table 6 - Process Control Results Summary Process Control Parameters Results Recommended Range for Extended Aeration Comments SSV 30 New-ASB 950 mg/L 300-500 mL/L Poor/Slow settling SSV 30 Diluted New-ASB 500 mg/L <300 mL/L Poor/Slow settling Mixed Liquor Suspended Solids (MLSS) (New-ASB) 4700 mg/L 2000-5000 mg/L High end of range Mixed Liquor Volatile Suspended Solids (MLVSS) (New-ASB) 3800 mg/L 70-80% of MLSS 80.9%, high end of range Sludge Volume Index (SVI) (New-ASB) 202 mL/g 100-150 mL/g Poor Settling Dissolved Oxygen (New-ASB) See table 7* 2.0-3.0 mg/L SSV 30 Old-ASB 870 mg/L 300-500 mL/L Poor settling SSV 30 Diluted Old-ASB 450 mg/L <300 mL/L Poor settling Mixed Liquor Suspended Solids (MLSS) (Old-ASB) 4100 mg/L 2000-5000 mg/L High end of range Mixed Liquor Volatile Suspended Solids (MLVSS) (Old-ASB) 3300 mg/L 70-80% of MLSS 80.4%, at high end of range Sludge Volume Index (SVI) (Old-ASB) 212.2 mL/g 100-150 mL/g Poor Settling Dissolved Oxygen (Old-ASB) See table 8* 2.0-3.0 mg/L Low DO. SESD ID: 18-0570 Final Report Page 14 of 58 Process Control Parameters Results Recommended Range for Extended Aeration Comments Sludge Blanket Depth Circular: 8.5 ft Polishing: 5.5 ft The clarifier depths are 10 feet each High Sludge Age for entire aeration basin system 14.3 days 10 – 15 days Older sludge Hydraulic Retention Time (HRT) for entire aeration basin system 3.16 days 1-5 days Within range F/M Ratio for entire aeration basin system 0.0275 .05-.15 Low F/M, Table 7 - NEW ASB In-Situ Profile 5 Minutes After Aeration 30 Minutes After Aeration Front Middle End Front Middle End Depth pH in Standard Units 1 ft 7.12 7.18 7.23 7.1 7.05 7.17 5 ft 7.15 7.17 7.24 7.09 7.07 7.05 10 ft 7.17 7.18 7.23 7.09 7.09 7.08 Specific Conductivity in µs/cm 1 ft 675 663 660 675 665 668 5 ft 664 665 663 671 665 665 10 ft 672 661 662 670 665 665 Dissolved Oxygen in mg/L 1 ft 3.2 1.42 1.28 0.8 0.6 0.45 5 ft 2.14 1.04 1.22 0.65 0.39 0.37 10 ft 1.64 0.85 1.15 0.58 0.61 0.35 Temperature in ⁰C 1 ft 25.7 25.8 25.9 26.1 26.4 26.6 5 ft 25.7 25.8 25.8 26.0 26.0 26.2 10 ft 25.7 25.8 25.7 26.0 26.1 26.1 Where, Front is at the beginning of the basin where flow enters; Middle is approximately in the middle of the basin; End is at the other end of the basin where flow leaves SESD ID: 18-0570 Final Report Page 15 of 58 Table 8 - OLD ASB In-Situ Profile 5 Minutes After Aeration 30 Minutes After Aeration Front Middle End Front Middle End Depth pH in Standard Units 1 ft 7.29 7.26 7.26 7.13 7.12 7.14 5 ft 7.26 7.24 7.23 7.11 7.12 7.12 10 ft 7.24 7.22 7.22 7.10 7.10 7.11 Specific Conductivity in µs/cm 1 ft 688 680 674 690 679 676 5 ft 693 678 677 677 676 676 10 ft 681 674 670 675 675 674 Dissolved Oxygen in mg/L 1 ft 1.96 .85 1.3 .4 .33 .28 5 ft 1.6 .67 .77 .3 .27 .24 10 ft 1.06 .51 .60 .28 .25 .23 Temperature in ⁰C 1 ft 25.6 25.6 25.6 25.9 26.0 25.8 5 ft 25.6 25.6 25.6 25.9 25.9 25.8 10 ft 25.5 25.6 25.6 25.8 25.8 25.8 Where, Front is at the beginning of the basin where flow enters; Middle is approximately in the middle of the basin; End is at the other end of the basin where flow leaves 9.4 USEPA Sampling Methodology SESD conducted the sampling activities following the Sample Analysis Plan (SAP) prepared for the project. All USEPA sampling methods, measurements, and calibrations were conducted in accordance with USEPA Region 4 SESD procedures listed in the SAP. Samples were analyzed at the SESD laboratory in accordance with the Analytical Support Branch (ASB) Laboratory Operations and Quality Assurance Manual. The ASB laboratory is accredited under the EPA Region 4 ASB’s ISO/IEC 17025 accreditation issued by ANSI-ASQ National Accreditation Board/ACLAS. 10.Effluent and Receiving Waters The final effluent was clear; however, there were visible solids observed floating on top in the chlorine contact chamber just before the effluent weir plate. (See photo # 9). SESD ID: 18-0570 Final Report Page 16 of 58 11.References •“Aerobic Biological Wastewater Treatment Facilities: Process Control Manual.” Office of Water U.S.EPA III-A-524-77, March 1977. •“Operation of Municipal Wastewater Treatment Plants, MOP 11,” Volume 2, 5th, 1996. Water Environment Federation. •“Operation of Wastewater Treatment Plants Vol 1 and 2”, 7th Edition, CSU, Sacramento, 2008. •“Wastewater Engineering: Treatment and Reuse” 5th edition, Metcalf & Eddy, 2014. SESD ID: 18-0570 Final Report Page 17 of 58 Appendix A: Facility Diagrams SESD ID: 18-0570 Final Report Page 18 of 58 Figure 2 - Northview Mobile Home Park WWTP Treatment Unit Dimensions Table 9 - Legend for Figure 2 Figure Label Treatment Unit Volume (ft3) Volume (gallons) 1 Digester 400 3,000 2 Old Aeration Basin 3,600 26,928 3 Polishing Clarifier 1,360 10,175 4 Old Cl Contact Chamber 300 2,244 5 Equalization Basin 2,228 16,667 6 Clarifier 1,810 13,539 7 New Aeration Basin 7,140 53,411 8 New Cl Contact (unused) 900 6,732 9 New Cl Contact 900 6,732 Front End Front End Middle Middle Inner Diameter Outer Diameter SESD ID: 18-0570 Final Report Page 19 of 58 Appendix B: Photographic Log SESD ID: 18-0570 Final Report Page 20 of 58 Photo Number (1)P7170004.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.414 W82;36;19.518 Orientation East Description Influent waste stream, and manual bar screen. SESD ID: 18-0570 Final Report Page 21 of 58 Photo Number (2) P7170005.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.372 W82;36;19.524 Orientation South Description Influent waste stream splitter box. Floatable solids passing through the screen and some over the weirs into the aeration basins. SESD ID: 18-0570 Final Report Page 22 of 58 Photo Number (3) P7170006.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.378 W82;36;19.506 Orientation Downward Description Digester SESD ID: 18-0570 Final Report Page 23 of 58 Photo Number (4) P7170007.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.3778 W82;36;19.506 Orientation West Description Original package plant that now consists of a digester, aeration basin, polishing clarifier, and old contact chamber SESD ID: 18-0570 Final Report Page 24 of 58 Photo Number (5) P7170008.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.312 W82;36;19.458 Orientation West Description New aeration basin, while blowers are off SESD ID: 18-0570 Final Report Page 25 of 58 Photo Number (6) P7170010.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.120 W82;36;19.866 Orientation East Description Circular Clarifier with floating solids and grit. SESD ID: 18-0570 Final Report Page 26 of 58 Photo Number (7) P7170011.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.096 W82;36;19.992 Orientation West Description Circular clarifier weirs overflowing. SESD ID: 18-0570 Final Report Page 27 of 58 Photo Number (8) P7170013.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.138 W82;36;20.004 Orientation West Description Floating solids and grit in the old aeration basin. SESD ID: 18-0570 Final Report Page 28 of 58 Photo Number (9) P7170017.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.126 W82;36;20.334 Orientation West Description New chlorine contact chamber. Floating solids present. SESD ID: 18-0570 Final Report Page 29 of 58 Photo Number (10) P7170021.jpg Date Taken 7/17/2018 Author Chris McHugh GPS Location N35;43;15.726 W82;36;20.088 Orientation East Description New Chlorine contact chamber, effluent 90⁰ v-notch weir. Dye used to measure height of water above weir SESD ID: 18-0570 Final Report Page 30 of 58 Photo Number (11) P7170025.jpg Date Taken 7/17/2018 Author Chris McHugh GPS Location N35;43;15.294 W82;36;20.574 Orientation East Description Sludge blanket measured in circular clarifier. Sludge blanket depth was 8.5 ft. SESD ID: 18-0570 Final Report Page 31 of 58 Photo Number (12) P7170030.jpg Date Taken 7/17/2018 Author Chris McHugh GPS Location N35;43;15.294 W82;36;20.574 Orientation North Description Floatable solids over the weir plates on the circular clarifier SESD ID: 18-0570 Final Report Page 32 of 58 Photo Number (13) P7170032.jpg Date Taken 7/17/2018 Author Cornell Gayle GPS Location N35;43;15.372 W82;36;19.524 Orientation East Description Influent waste stream splitter box. Floatable solids passing through the screen and some over the weirs into the aeration basins. View of the autosampler setup at the influent location. SESD ID: 18-0570 Final Report Page 33 of 58 Photo Number (14) P7170048.jpg Date Taken 7/18/2018 Author Cornell Gayle GPS Location NA Orientation NA Description Filamentous microorganism presence in NEW-ASB grab sample. Very little microorganism activity observed. SESD ID: 18-0570 Final Report Page 34 of 58 Photo Number (15) P7180076.jpg Date Taken 7/18/2018 Author Cornell Gayle GPS Location N35;43;15 W82;36;19 Orientation South Description Digester right before being pumped. SESD ID: 18-0570 Final Report Page 35 of 58 Appendix C: Operating Parameters Calculations & Process Control Results SESD ID: 18-0570 Final Report Page 36 of 58 USEPA calculated the operating parameters using the USEPA diagnostic evaluation sampling results. Based on the difficulties verifying flow, results will be calculated using the instantaneous flow measured with surveying equipment. Hydraulic Retention Time (HRT) • 𝑉𝑉=𝑉𝑉𝑁𝑁𝑁𝑁𝑁𝑁−𝐴𝐴𝐴𝐴𝐴𝐴+𝑉𝑉𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴= .053411 𝑀𝑀𝑀𝑀+ .026828 𝑀𝑀𝑀𝑀=0.080239 𝑀𝑀𝑀𝑀 • 𝑄𝑄𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑁𝑁𝑖𝑖𝑖𝑖𝑖𝑖= 0.02543 𝑀𝑀𝑀𝑀𝑀𝑀 • 𝐻𝐻𝐻𝐻𝐻𝐻= 𝑉𝑉𝑄𝑄𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑁𝑁𝑖𝑖𝑖𝑖𝑖𝑖=0.0802390.02543 =3.16 𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑� The recommended range is 1 to 5 days (CSU, 2008). Sludge Volumetric Index (SVI) • SS30Old =Old −ASB 30 minute Settlometer Test Sludge Volume = 870 mL/L • TSSOld−ASB =4100 𝑚𝑚𝑚𝑚/𝐿𝐿 • SVIOld−ASB = SS30Old−ASB TSSOld−ASB�= 870mLL∗1000 mg/g4100 mg/L =212.2 mL/g • SS30New =New −ASB 30 minute Settlometer Test Sludge Volume = 950 mL/L • TSSNew−ASB =4700 𝑚𝑚𝑚𝑚/𝐿𝐿 • SVINEw−ASB = SS30New−ASB TSSNew−ASB�= 950mLL∗1000 mg/g4700 mg/L =202 mL/g A value of 100 mL/g is considered a good settling sludge, although SVI values below 100 are desired (Metcalf and Eddy, 2014). SESD ID: 18-0570 Final Report Page 37 of 58 Food-to-Microorganism Ratio (F/M) •𝑄𝑄𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑁𝑁𝑖𝑖𝑖𝑖𝑖𝑖= 0.02543 𝑀𝑀𝑀𝑀𝑀𝑀 •𝑉𝑉𝑁𝑁𝑁𝑁𝑁𝑁−𝐴𝐴𝐴𝐴𝐴𝐴= .053411 𝑀𝑀𝑀𝑀 •𝑋𝑋𝑁𝑁𝑁𝑁𝑁𝑁−𝐴𝐴𝐴𝐴𝐴𝐴=𝐻𝐻𝑉𝑉𝑇𝑇𝑇𝑇𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴=3800 mg/L •𝑉𝑉𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴= .026828 𝑀𝑀𝑀𝑀 •𝑋𝑋𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴=𝐻𝐻𝑉𝑉𝑇𝑇𝑇𝑇𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴=3300 mg/L •𝑇𝑇𝑖𝑖𝑎𝑎𝑎𝑎=𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝑑𝑑𝑚𝑚𝐴𝐴 𝐼𝐼𝐼𝐼𝐼𝐼𝐼𝐼𝐼𝐼𝐴𝐴𝐼𝐼𝐼𝐼 𝐵𝐵𝐵𝐵𝑀𝑀5 𝑐𝑐𝑐𝑐𝐼𝐼𝑐𝑐𝐴𝐴𝐼𝐼𝐼𝐼𝐴𝐴𝑑𝑑𝐼𝐼𝑐𝑐𝑐𝑐𝐼𝐼= 300+3302 =315 𝑚𝑚𝑚𝑚/𝐿𝐿 𝐹𝐹𝑀𝑀�=𝑄𝑄𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑖𝑁𝑁𝑖𝑖𝑖𝑖𝑖𝑖∗𝑇𝑇𝑖𝑖𝑎𝑎𝑎𝑎[(𝑉𝑉𝑁𝑁𝑁𝑁𝑁𝑁−𝐴𝐴𝐴𝐴𝐴𝐴∗ 𝑋𝑋𝑁𝑁𝑁𝑁𝑁𝑁−𝐴𝐴𝐴𝐴𝐴𝐴)+ (𝑉𝑉𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴∗ 𝑋𝑋𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴)] = (0.02543 𝑀𝑀𝑀𝑀𝑀𝑀∗315 𝑚𝑚𝑚𝑚/𝐿𝐿)[(0.053411 𝑀𝑀𝑀𝑀∗3800 𝑚𝑚𝑚𝑚/𝐿𝐿)+ (0.026828 𝑀𝑀𝑀𝑀∗3300 𝑚𝑚𝑚𝑚/𝐿𝐿) = = 0.0275 Typical design parameters for extended aeration activated sludge plants range from 0.05 to 0.15 (WEF,1996). Sludge Age •Solids Inventory = [(𝑉𝑉𝑁𝑁𝑁𝑁𝑁𝑁−𝐴𝐴𝐴𝐴𝐴𝐴∗ 𝑋𝑋𝑁𝑁𝑁𝑁𝑁𝑁−𝐴𝐴𝐴𝐴𝐴𝐴)+ (𝑉𝑉𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴∗ 𝑋𝑋𝑂𝑂𝑂𝑂𝑂𝑂−𝐴𝐴𝐴𝐴𝐴𝐴) •Sludge Age = 𝑇𝑇𝑐𝑐𝐼𝐼𝑐𝑐𝑑𝑑𝑑𝑑 𝐼𝐼𝐼𝐼𝐴𝐴𝐴𝐴𝐼𝐼𝐼𝐼𝑐𝑐𝐴𝐴𝑑𝑑𝐻𝐻𝑇𝑇𝑇𝑇𝑖𝑖𝑎𝑎𝑎𝑎𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝� = Sludge Age = 𝑇𝑇𝑐𝑐𝐼𝐼𝑐𝑐𝑑𝑑𝑑𝑑 𝐼𝐼𝐼𝐼𝐴𝐴𝐴𝐴𝐼𝐼𝐼𝐼𝑐𝑐𝐴𝐴𝑑𝑑𝐻𝐻𝑇𝑇𝑇𝑇𝑖𝑖𝑎𝑎𝑎𝑎𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝� =[(0.053411 𝑀𝑀𝑀𝑀∗3800 𝑚𝑚𝑚𝑚/𝐿𝐿) + (0.026828 𝑀𝑀𝑀𝑀∗3300 𝑚𝑚𝑚𝑚/𝐿𝐿)]800 𝑚𝑚𝑚𝑚𝐿𝐿∗ 0.02543 𝑀𝑀𝑀𝑀𝑀𝑀 = 14.3 days SESD ID: 18-0570 Final Report Page 38 of 58 Settlometer Test The settlometer test was performed to observe the settling characteristics of the mixed liquor, assess sludge quality, and approximate age. A settlometer test was conducted at the plant using an undiluted 1,000 mL sample and a 50% diluted sample collected at both the New-ASB and Old-ASB. Table 10 – Old-ASB Settlometer Test Results Time (minutes) Settled Sludge Volume 100% MLSS (mL/L) Settled Sludge Volume 50% MLSS (mL/L) 0 1000 1000 5 950 770 10 940 670 15 930 600 20 910 540 25 880 490 30 870 450 Table 11 – New-ASB Settlometer Test Results Time (minutes) Settled Sludge Volume 100% MLSS (mL/L) Settled Sludge Volume 50% MLSS (mL/L) 0 1000 1000 30 950 500 60 890 450 The recommended range for the 30 min 100% MLSS SSV test is 300 – 500 mL/L. (CSU 2008). The results from both basins indicate the sludge settled slowly. SESD ID: 18-0570 Final Report Page 39 of 58 Appendix D: SESD Laboratory Analytical Results 19 Pages D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel August 23, 2018 MEMORANDUM SUBJECT: FROM: FINAL Analytical Report Project: 18-0570, North View Mobile Home WWTP CSI Compliance Monitoring 4SESD-ASB Jeffrey Hendel ASB Inorganic Chemistry Section Chief Analytical Support Branch Danny France, ChiefTHRU: TO:Christopher McHugh Attached are the final results for the analytical groups listed below. These analyses were performed in accordance with the Analytical Support Branch's (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesd/asbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and have been qualified by this laboratory if the applicable quality control criteria were not met. Verification is defined in Section 5.2 of the ASB LOQAM. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are accurate within the limits of the method(s) and are representative only of the samples as received by the laboratory. Analyses Included in this report:Method Used:Accreditations: Classical/Nutrient Analyses (CNA) Ammonia as N ISOEPA 350.1 (Water) Ammonia/TKN ISOEPA 351.2 (Water) Classical/Nutrients ISOSM 2320B (Water) Demand ISOSM 5210B (Water) Nitrate and/or Nitrite ISOEPA 353.2 (Water) Phosphorous ISOEPA 365.1 (Water) Solids ISOSM 2540E (Water) Solids ISOUSGS I-3765-85 (Water) 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 1 of 19 SESD 18-0570 Final Report Page 40 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Sample Disposal Policy Due to limited space for long term sample storage, ASB’s policy is to dispose of samples on a periodic schedule. Air samples collected in summa canisters will be disposed of 30 days following the issuance of this report. All other sample media including original samples, sample extracts and or digestates will be disposed of, in accordance with applicable regulations, 60 days from the date of this report. This sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal investigators that case development and litigation are complete. These samples may be held in the laboratory's custody for a longer period of time. If samples require storage beyond the 60-day period, please contact the Sample Control Coordinator by e-mail at R4SampleCustody@epa.gov. 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 2 of 19 SESD 18-0570 Final Report Page 41 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Date ReceivedDate CollectedMatrixLaboratory IDSample ID SAMPLES INCLUDED IN THIS REPORT Project: 18-0570, North View Mobile Home WWTP CSI EFF001 E182912-01 Municipal Eff. Wastewater 7/17/18 10:25 7/19/18 7:10 EFF002 E182912-02 Municipal Eff. Wastewater 7/18/18 11:17 7/19/18 7:10 EFF003 E182912-03 Municipal Eff. Wastewater 7/18/18 11:30 7/19/18 7:10 INF001 E182912-04 Municipal Inf. Wastewater 7/17/18 11:10 7/19/18 7:10 INF002 E182912-05 Municipal Inf. Wastewater 7/18/18 11:00 7/19/18 7:10 NEW-ASB E182912-06 Municipal Proc. Wastewater 7/17/18 15:00 7/19/18 7:10 OLD-ASB E182912-07 Municipal Proc. Wastewater 7/17/18 15:00 7/19/18 7:10 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 3 of 19 SESD 18-0570 Final Report Page 42 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel DATA QUALIFIER DEFINITIONS U The analyte was not detected at or above the reporting limit. J The identification of the analyte is acceptable; the reported value is an estimate. K The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less than the reported value. L The identification of the analyte is acceptable; the reported value may be biased low. The actual value is expected to be greater than the reported value. ACRONYMS AND ABBREVIATIONS CAS Chemical Abstracts Service Note: Analytes with no known CAS identifiers have been assigned codes beginning with "E", the EPA ID as assigned by the EPA Substance Registry System (www.epa.gov/srs), or beginning with "R4-", a unique identifier assigned by the EPA Region 4 laboratory. MDL Method Detection Limit - The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero. MRL Minimum Reporting Limit - Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments. TIC Tentatively Identified Compound - An analyte identified based on a match with the instrument software's mass spectral library. A calibration standard has not been analyzed to confirm the compound's identification or the estimated concentration reported. ACCREDITATIONS: ISO ASB is accredited by ISO/IEC 17025, including an amplification for forensic accreditation through ANSI-ASQ National Accreditation Board. Refer to the certificate and scope of accreditation AT-1644 at: http://www.epa.gov/aboutepa/about-region-4s-science-and-ecosystem-support-division-sesd NR The EPA Region 4 Laboratory has not requested accreditation for this test. 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 4 of 19 SESD 18-0570 Final Report Page 43 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Classical/Nutrient Analyses Sample ID:Lab ID: EFF001 E182912-01 Matrix:Municipal Eff. Wastewater Date Collected:7/17/18 10:25 Project: 18-0570, North View Mobile Home WWTP CSI Station ID:EFF001 CAS Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method 0.050Ammonia as N mg/L EPA 350.10.907664-41-7 8/14/18 16:09 8/13/1810:13 0.50Total Kjeldahl Nitrogen mg/L EPA 351.24.7E17148461 8/08/1818:16 8/01/1811:14 1.0Alkalinity, Total (as CaCO3)mg/L SM 2320B160E16401927/24/18 11:25 7/24/1811:25 2.0BOD, 5 Day mg/L SM 5210B4.0 J, KE1640606 7/24/18 14:48 7/19/1810:22 0.050Nitrate/Nitrite as N mg/L EPA 353.20.078E701177 7/26/18 15:40 7/26/1815:13 0.050Total Phosphorus mg/L EPA 365.11.57723-14-0 8/07/1814:11 8/02/1810:28 5.0Total Suspended Solids mg/L USGS I-3765-855.2E1642818 7/24/18 21:15 7/23/1821:08 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 5 of 19 SESD 18-0570 Final Report Page 44 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Classical/Nutrient Analyses Sample ID:Lab ID: EFF002 E182912-02 Matrix:Municipal Eff. Wastewater Date Collected:7/18/18 11:17 Project: 18-0570, North View Mobile Home WWTP CSI Station ID:EFF001 CAS Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method 0.050Ammonia as N mg/L EPA 350.10.0987664-41-7 8/14/18 16:09 8/13/1810:13 0.50Total Kjeldahl Nitrogen mg/L EPA 351.23.7E17148461 8/08/1818:16 8/01/1811:14 1.0Alkalinity, Total (as CaCO3)mg/L SM 2320B150E16401927/24/18 11:35 7/24/1811:35 2.0BOD, 5 Day mg/L SM 5210B4.0 J, KE1640606 7/24/18 14:48 7/19/1811:28 0.050Nitrate/Nitrite as N mg/L EPA 353.20.050 UE701177 7/26/18 15:40 7/26/1815:13 0.050Total Phosphorus mg/L EPA 365.11.47723-14-0 8/07/1814:11 8/02/1810:28 5.0Total Suspended Solids mg/L USGS I-3765-855.0 UE1642818 7/24/18 21:15 7/23/1821:08 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 6 of 19 SESD 18-0570 Final Report Page 45 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Classical/Nutrient Analyses Sample ID:Lab ID: EFF003 E182912-03 Matrix:Municipal Eff. Wastewater Date Collected:7/18/18 11:30 Project: 18-0570, North View Mobile Home WWTP CSI Station ID:EFF001 CAS Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method 0.050Ammonia as N mg/L EPA 350.10.127664-41-7 8/14/18 16:09 8/13/1810:13 0.50Total Kjeldahl Nitrogen mg/L EPA 351.23.8E17148461 8/08/1818:16 8/01/1811:14 1.0Alkalinity, Total (as CaCO3)mg/L SM 2320B160E16401927/24/18 11:55 7/24/1811:55 2.0BOD, 5 Day mg/L SM 5210B4.0 J, KE1640606 7/24/18 14:48 7/19/1811:28 0.050Nitrate/Nitrite as N mg/L EPA 353.20.050 UE701177 7/26/18 15:40 7/26/1815:13 0.050Total Phosphorus mg/L EPA 365.11.27723-14-0 8/07/1814:11 8/02/1810:28 5.0Total Suspended Solids mg/L USGS I-3765-855.0 UE1642818 7/24/18 21:15 7/23/1821:08 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 7 of 19 SESD 18-0570 Final Report Page 46 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Classical/Nutrient Analyses Sample ID:Lab ID: INF001 E182912-04 Matrix:Municipal Inf. Wastewater Date Collected:7/17/18 11:10 Project: 18-0570, North View Mobile Home WWTP CSI Station ID:INF001 CAS Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method 1.2Ammonia as N mg/L EPA 350.1547664-41-7 8/14/18 16:09 8/13/1810:13 2.5Total Kjeldahl Nitrogen mg/L EPA 351.288E171484618/08/1818:16 8/01/1811:14 1.0Alkalinity, Total (as CaCO3)mg/L SM 2320B370E16401927/24/18 12:05 7/24/1812:05 2.0BOD, 5 Day mg/L SM 5210B330J, LE1640606 7/24/18 14:48 7/19/1810:45 0.050Nitrate/Nitrite as N mg/L EPA 353.20.077E701177 7/26/18 15:40 7/26/1815:13 0.25Total Phosphorus mg/L EPA 365.1147723-14-0 8/06/1816:27 8/02/1810:28 5.0Total Suspended Solids mg/L USGS I-3765-85780E16428187/24/18 21:15 7/23/1821:08 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 8 of 19 SESD 18-0570 Final Report Page 47 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Classical/Nutrient Analyses Sample ID:Lab ID: INF002 E182912-05 Matrix:Municipal Inf. Wastewater Date Collected:7/18/18 11:00 Project: 18-0570, North View Mobile Home WWTP CSI Station ID:INF001 CAS Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method 1.2Ammonia as N mg/L EPA 350.1487664-41-7 8/14/18 16:09 8/13/1810:13 2.5Total Kjeldahl Nitrogen mg/L EPA 351.278E171484618/08/1818:16 8/01/1811:14 1.0Alkalinity, Total (as CaCO3)mg/L SM 2320B330E16401927/24/18 12:11 7/24/1812:11 2.0BOD, 5 Day mg/L SM 5210B300J, LE1640606 7/24/18 14:48 7/19/1811:28 0.050Nitrate/Nitrite as N mg/L EPA 353.20.078E701177 7/26/18 15:40 7/26/1815:13 0.25Total Phosphorus mg/L EPA 365.1127723-14-0 8/06/1816:27 8/02/1810:28 5.0Total Suspended Solids mg/L USGS I-3765-85820E16428187/24/18 21:15 7/23/1821:08 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 9 of 19 SESD 18-0570 Final Report Page 48 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Classical/Nutrient Analyses Sample ID:Lab ID: NEW-ASB E182912-06 Matrix:Municipal Proc. Wastewater Date Collected:7/17/18 15:00 Project: 18-0570, North View Mobile Home WWTP CSI Station ID:PC001 CAS Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method 5.0Total Suspended Solids mg/L USGS I-3765-854700E16428187/24/18 21:15 7/23/1821:08 5.0Volatile Suspended Solids mg/L SM 2540E3800E16403747/24/18 21:18 7/23/1821:13 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 10 of 19 SESD 18-0570 Final Report Page 49 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Classical/Nutrient Analyses Sample ID:Lab ID: OLD-ASB E182912-07 Matrix:Municipal Proc. Wastewater Date Collected:7/17/18 15:00 Project: 18-0570, North View Mobile Home WWTP CSI Station ID:PC002 CAS Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method 5.0Total Suspended Solids mg/L USGS I-3765-854100E16428187/24/18 21:15 7/23/1821:08 5.0Volatile Suspended Solids mg/L SM 2540E3300E16403747/24/18 21:18 7/23/1821:13 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 11 of 19 SESD 18-0570 Final Report Page 50 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Classical/Nutrient Analyses (CNA) - Quality Control US-EPA, Region 4, SESD Batch 1807102 - C SM5210 BOD Blank (1807102-BLK1)Prepared: 07/19/18 Analyzed: 07/24/18 SM 5210B BOD, 5 Day mg/LU2.0 U LCS (1807102-BS1)Prepared: 07/19/18 Analyzed: 07/24/18 SM 5210B BOD, 5 Day mg/L238.50 2.0 198.00 QL-284.6-115.4120 LCS Dup (1807102-BSD1)Prepared: 07/19/18 Analyzed: 07/24/18 SM 5210B BOD, 5 Day mg/L213.00 2.0 198.00 1584.6-115.4108 11.3 Batch 1807116 - C 2540 Solids Blank (1807116-BLK1)Prepared: 07/23/18 Analyzed: 07/24/18 USGS I-3765-85 Total Suspended Solids mg/LU5.0 U LCS (1807116-BS1)Prepared: 07/23/18 Analyzed: 07/24/18 USGS I-3765-85 Total Suspended Solids mg/L87.200 5.0 95.100 77.1-11091.7 LCS Dup (1807116-BSD1)Prepared: 07/23/18 Analyzed: 07/24/18 USGS I-3765-85 Total Suspended Solids mg/L88.000 5.0 95.100 1077.1-11092.5 0.913 Duplicate (1807116-DUP1)Prepared: 07/23/18 Analyzed: 07/24/18 Source: E182912-01 USGS I-3765-85 Total Suspended Solids mg/L5.0000 5.0 5.2000 103.92 MRL Verification (1807116-PS1)Prepared: 07/23/18 Analyzed: 07/24/18 USGS I-3765-85 Total Suspended Solids mg/L6.1000 5.0 9.5100 MRL-257.1-13064.1 Batch 1807117 - C 2540 Solids Blank (1807117-BLK1)Prepared: 07/23/18 Analyzed: 07/24/18 SM 2540E Volatile Suspended Solids mg/LU5.0 B-3, U 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 12 of 19 SESD 18-0570 Final Report Page 51 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Classical/Nutrient Analyses (CNA) - Quality Control US-EPA, Region 4, SESD Batch 1807117 - C 2540 Solids Blank (1807117-BLK1)Prepared: 07/23/18 Analyzed: 07/24/18 LCS (1807117-BS1)Prepared: 07/23/18 Analyzed: 07/24/18 SM 2540E Volatile Suspended Solids mg/L32.900 5.0 30.400 84.9-115108 LCS Dup (1807117-BSD1)Prepared: 07/23/18 Analyzed: 07/24/18 SM 2540E Volatile Suspended Solids mg/L32.600 5.0 30.400 20084.9-115107 0.916 MRL Verification (1807117-PS1)Prepared: 07/23/18 Analyzed: 07/24/18 SM 2540E Volatile Suspended Solids mg/L5.7000 5.0 6.0800 MRL-270-13093.8 Batch 1807119 - C 2320B Alkalinity Blank (1807119-BLK1)Prepared & Analyzed: 07/24/18 SM 2320B Alkalinity, Total (as CaCO3)mg/LU1.0 U LCS (1807119-BS1)Prepared & Analyzed: 07/24/18 SM 2320B Alkalinity, Total (as CaCO3)mg/L52.022 1.0 50.000 92-115104 LCS Dup (1807119-BSD1)Prepared & Analyzed: 07/24/18 SM 2320B Alkalinity, Total (as CaCO3)mg/L51.926 1.0 50.000 1092-115104 0.185 Duplicate (1807119-DUP1)Prepared & Analyzed: 07/24/18 Source: E182912-02 SM 2320B Alkalinity, Total (as CaCO3)mg/L155.90 1.0 154.75 100.735 Duplicate (1807119-DUP2)Prepared & Analyzed: 07/24/18 Source: E183001-02 SM 2320B Alkalinity, Total (as CaCO3)mg/L71.710 1.0 72.338 100.872 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 13 of 19 SESD 18-0570 Final Report Page 52 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Classical/Nutrient Analyses (CNA) - Quality Control US-EPA, Region 4, SESD Batch 1807119 - C 2320B Alkalinity MRL Verification (1807119-PS1)Prepared & Analyzed: 07/24/18 SM 2320B Alkalinity, Total (as CaCO3)mg/L1.0820 1.0 1.0000 MRL-272-135108 Batch 1807137 - C 353.2 NO3-NO2 Blank (1807137-BLK1)Prepared & Analyzed: 07/26/18 EPA 353.2 Nitrate/Nitrite as N mg/LU0.050 U LCS (1807137-BS1)Prepared & Analyzed: 07/26/18 EPA 353.2 Nitrate/Nitrite as N mg/L0.48390 0.050 0.50050 90-11096.7 Matrix Spike (1807137-MS1)Prepared & Analyzed: 07/26/18 Source: E182901-07 EPA 353.2 Nitrate/Nitrite as N mg/L0.81180 0.050 0.50050 0.31000 90-110100 Matrix Spike (1807137-MS2)Prepared & Analyzed: 07/26/18 Source: E182912-03 EPA 353.2 Nitrate/Nitrite as N mg/L0.53370 0.050 0.50050 0.049100 90-11096.8 Matrix Spike Dup (1807137-MSD1)Prepared & Analyzed: 07/26/18 Source: E182901-07 EPA 353.2 Nitrate/Nitrite as N mg/L0.81620 0.050 0.50050 0.31000 1090-110101 0.541 Matrix Spike Dup (1807137-MSD2)Prepared & Analyzed: 07/26/18 Source: E182912-03 EPA 353.2 Nitrate/Nitrite as N mg/L0.53730 0.050 0.50050 0.049100 1090-11097.5 0.672 MRL Verification (1807137-PS1)Prepared & Analyzed: 07/26/18 EPA 353.2 Nitrate/Nitrite as N mg/L0.051800 0.050 0.050000 MRL-270-130104 Batch 1808002 - C 351.2 TKN Blank (1808002-BLK1)Prepared: 08/01/18 Analyzed: 08/06/18 EPA 351.2 Total Kjeldahl Nitrogen mg/LU0.050 U 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 14 of 19 SESD 18-0570 Final Report Page 53 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Classical/Nutrient Analyses (CNA) - Quality Control US-EPA, Region 4, SESD Batch 1808002 - C 351.2 TKN Blank (1808002-BLK1)Prepared: 08/01/18 Analyzed: 08/06/18 Blank (1808002-BLK2)Prepared: 08/01/18 Analyzed: 08/08/18 EPA 351.2 Total Kjeldahl Nitrogen mg/LU0.050 U LCS (1808002-BS1)Prepared: 08/01/18 Analyzed: 08/06/18 EPA 351.2 Total Kjeldahl Nitrogen mg/L1.1440 0.050 1.1650 90-11098.2 LCS (1808002-BS2)Prepared: 08/01/18 Analyzed: 08/08/18 EPA 351.2 Total Kjeldahl Nitrogen mg/L1.1620 0.050 1.1650 90-11099.7 Matrix Spike (1808002-MS1)Prepared: 08/01/18 Analyzed: 08/06/18 Source: E182901-06 EPA 351.2 Total Kjeldahl Nitrogen mg/L1.9360 0.050 0.99900 0.97400 90-11096.3 Matrix Spike (1808002-MS2)Prepared: 08/01/18 Analyzed: 08/08/18 Source: E182912-02 EPA 351.2 Total Kjeldahl Nitrogen mg/L4.6000 0.50 0.99900 3.7000 XM-190-11090.1 Matrix Spike Dup (1808002-MSD1)Prepared: 08/01/18 Analyzed: 08/06/18 Source: E182901-06 EPA 351.2 Total Kjeldahl Nitrogen mg/L1.9590 0.050 0.99900 0.97400 2090-11098.6 1.18 Matrix Spike Dup (1808002-MSD2)Prepared: 08/01/18 Analyzed: 08/08/18 Source: E182912-02 EPA 351.2 Total Kjeldahl Nitrogen mg/L4.5900 0.50 0.99900 3.7000 20 XM-190-11089.1 0.218 MRL Verification (1808002-PS1)Prepared: 08/01/18 Analyzed: 08/06/18 EPA 351.2 Total Kjeldahl Nitrogen mg/L0.072000 0.050 0.050000 MRL-2, QR-2 70-130144 MRL Verification (1808002-PS2)Prepared: 08/01/18 Analyzed: 08/08/18 EPA 351.2 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 15 of 19 SESD 18-0570 Final Report Page 54 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Classical/Nutrient Analyses (CNA) - Quality Control US-EPA, Region 4, SESD Batch 1808002 - C 351.2 TKN MRL Verification (1808002-PS2)Prepared: 08/01/18 Analyzed: 08/08/18 Total Kjeldahl Nitrogen mg/L0.085000 0.050 0.050000 MRL-2, QR-2 70-130170 Batch 1808007 - C 365.1 TPhos Blank (1808007-BLK1)Prepared: 08/02/18 Analyzed: 08/06/18 EPA 365.1 Total Phosphorus mg/LU0.010 U Blank (1808007-BLK2)Prepared: 08/02/18 Analyzed: 08/07/18 EPA 365.1 Total Phosphorus mg/LU0.010 U LCS (1808007-BS1)Prepared: 08/02/18 Analyzed: 08/06/18 EPA 365.1 Total Phosphorus mg/L0.37860 0.010 0.36750 90-110103 LCS (1808007-BS2)Prepared: 08/02/18 Analyzed: 08/07/18 EPA 365.1 Total Phosphorus mg/L0.37590 0.010 0.36750 90-110102 Matrix Spike (1808007-MS1)Prepared: 08/02/18 Analyzed: 08/06/18 Source: E182901-05 EPA 365.1 Total Phosphorus mg/L0.71620 0.010 0.50100 0.21820 90-11099.4 Matrix Spike (1808007-MS2)Prepared: 08/02/18 Analyzed: 08/07/18 Source: E182912-01 EPA 365.1 Total Phosphorus mg/L1.9625 0.050 0.50100 1.4685 90-11098.6 Matrix Spike (1808007-MS3)Prepared: 08/02/18 Analyzed: 08/06/18 Source: E183001-05 EPA 365.1 Total Phosphorus mg/L3.8880 0.10 0.50100 3.4160 90-11094.2 Matrix Spike Dup (1808007-MSD1)Prepared: 08/02/18 Analyzed: 08/06/18 Source: E182901-05 EPA 365.1 Total Phosphorus mg/L0.71560 0.010 0.50100 0.21820 1090-11099.3 0.0838 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 16 of 19 SESD 18-0570 Final Report Page 55 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Classical/Nutrient Analyses (CNA) - Quality Control US-EPA, Region 4, SESD Batch 1808007 - C 365.1 TPhos Matrix Spike Dup (1808007-MSD2)Prepared: 08/02/18 Analyzed: 08/07/18 Source: E182912-01 EPA 365.1 Total Phosphorus mg/L1.9675 0.050 0.50100 1.4685 1090-11099.6 0.254 Matrix Spike Dup (1808007-MSD3)Prepared: 08/02/18 Analyzed: 08/06/18 Source: E183001-05 EPA 365.1 Total Phosphorus mg/L3.8680 0.10 0.50100 3.4160 1090-11090.2 0.516 MRL Verification (1808007-PS1)Prepared: 08/02/18 Analyzed: 08/06/18 EPA 365.1 Total Phosphorus mg/L0.013000 0.010 0.010000 MRL-270-130130 MRL Verification (1808007-PS2)Prepared: 08/02/18 Analyzed: 08/07/18 EPA 365.1 Total Phosphorus mg/L0.0086000 0.010 0.010000 MRL-2, U 70-13086.0 Batch 1808049 - C 350.1 Ammonia Blank (1808049-BLK1)Prepared: 08/13/18 Analyzed: 08/14/18 EPA 350.1 Ammonia as N mg/LU0.050 U LCS (1808049-BS1)Prepared: 08/13/18 Analyzed: 08/14/18 EPA 350.1 Ammonia as N mg/L0.98100 0.050 0.99900 90-11098.2 Matrix Spike (1808049-MS1)Prepared: 08/13/18 Analyzed: 08/14/18 Source: E182912-03 EPA 350.1 Ammonia as N mg/L1.0980 0.050 0.99900 0.12500 90-11097.4 Matrix Spike (1808049-MS2)Prepared: 08/13/18 Analyzed: 08/14/18 Source: E183001-04 EPA 350.1 Ammonia as N mg/L17.570 0.50 0.99900 17.030 XM-190-11054.1 Matrix Spike Dup (1808049-MSD1)Prepared: 08/13/18 Analyzed: 08/14/18 Source: E182912-03 EPA 350.1 Ammonia as N mg/L1.0980 0.050 0.99900 0.12500 1090-11097.4 0.00 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 17 of 19 SESD 18-0570 Final Report Page 56 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Classical/Nutrient Analyses (CNA) - Quality Control US-EPA, Region 4, SESD Batch 1808049 - C 350.1 Ammonia Matrix Spike Dup (1808049-MSD2)Prepared: 08/13/18 Analyzed: 08/14/18 Source: E183001-04 EPA 350.1 Ammonia as N mg/L17.790 0.50 0.99900 17.030 10 XM-190-11076.1 1.24 MRL Verification (1808049-PS1)Prepared: 08/13/18 Analyzed: 08/14/18 EPA 350.1 Ammonia as N mg/L0.054000 0.050 0.050000 MRL-270-130108 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 18 of 19 SESD 18-0570 Final Report Page 57 of 58 D.A.R.T. Id: 18-0570 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 Project: 18-0570, North View Mobile Home WWTP CSI - Reported by Jeffrey Hendel Notes and Definitions for QC Samples U The analyte was not detected at or above the reporting limit. B-3 Level in blank does not impact data quality MRL-2 MRL verification for Non-Potable Water matrix QL-2 Laboratory Control Spike Recovery greater than method control limits QR-2 MRL verification recovery greater than upper control limits. XM-1 Sample background/spike ratio higher than method evaluation criteria 8/23/18 7:00E182912 CNA FINAL 08 23 18 0700Page 19 of 19 End of Report SESD 18-0570 Final Report Page 58 of 58