Marshall_NEBA_CommunityImpactAnalysis_2018115

Community Impact Analysis
of Ash Basin Closure Options
at the Marshall Steam Station

1805955.000 - 1990

Community Impact Analysis of
Ash Basin Closure Options at the
Marshall Steam Station

Prepared on behalf of Duke Energy Carolinas,
LLC

Prepared by

Dr. Ann Michelle Morrison
Exponent
1 Mill & Main Place, Suite 150
Maynard, MA 01754

November 15, 2018

 Exponent, Inc.

1805955.000 - 1990 iii
Contents
Page
List of Figures v
List of Tables vi
Acronyms and Abbreviations viii
Limitations x
Executive Summary xi
1 Qualifications 1
2 Assignment and Retention 3
3 Reliance Materials 4
4 Introduction 5
4.1 Site Setting 6
4.2 Closure of the Ash Impoundments at Marshall 11
5 Approach to Forming Conclusions 16
5.1 Net Environmental Benefit Analysis 18
5.2 Linking Stakeholder Concerns to NEBA 20
5.3 NEBA Risk Ratings 26
5.4 Risk Acceptability 27
6 Summary of Conclusions 29
7 Conclusion 1: All closure options for the MSS ash basin are protective of human
health. 31
7.1 Private water supply wells pose no meaningful risk to the community around
MSS. 31
7.2 CCR constituents from the Marshall ash basin pose no meaningful risk to human
populations. 33
7.3 NEBA – Protection of Human Health from CCR Exposure 38

1805955.000 - 1990 iv
8 Conclusion 2: All closure options for the MSS ash basin are protective of
ecological health. 39
8.1 No meaningful risks to ecological receptors from CCR exposure exist under
current conditions or any closure option. 39
8.2 NEBA – Protection of Environmental Health from CCR Exposure 43
9 Conclusion 3: CIP and hybrid closure options limit the duration of community
disturbance. 45
9.1 There is no meaningful risk from diesel emissions to people living and working
along the transportation corridor. 47
9.2 All closure options produce comparable risk and disturbance from transportation
activities on a daily or annual basis, but excavation closure produces these impacts for
substantially longer than CIP or hybrid closures. 50
9.2.1 Noise and Congestion 50
9.2.2 Traffic Accidents 51
9.3 NEBA – Minimize Human Disturbance 52
10 Conclusion 4: All closure options for the MSS ash basin create environmental
disturbance. 56
10.1 Excavation closure results in a greater net loss of environmental services
than CIP or hybrid closure. 58
10.2 NEBA – Minimize Environmental Disturbance 62
11 Conclusion 5: Hybrid closure maximizes environmental services. 65
12 References 68

Appendix A Curriculum vitae of Dr. Ann Michelle Morrison, Sc.D.
Appendix B Human Health and Ecological Risk Assessment Summary Update for Marshall
Steam Station
Appendix C Exposure Modeling and Human Health Risk Assessment for Diesel Emissions
Appendix D Habitat Equivalency Analysis
Appendix E Net Environmental Benefit Analysis

1805955.000 - 1990 v
List of Figures
Page
Figure 4-1. Map of MSS. Reproduced and adapted from Figure 2-1 of the 2018 CSA
Supplement (SynTerra 2018a). 8
Figure 4-2. Images of various habitat types at MSS, September 5, 2018. 10
Figure 4-3. Elemental composition of bottom ash, fly ash, shale, and volcanic ash. 12
Figure 8-1. Exposure areas evaluated in the 2018 ecological risk assessment update
(SynTerra 2018b) 42
Figure 9-1. Normalized differences between all offsite transportation activities under
CIP, excavation, and hybrid closure options. 47
Figure 10-1. Map of habitat types currently present at Marshall. 57

1805955.000 - 1990 vi
List of Tables
Page
Table 4-1. Ash basin closure options provided by Duke Energy (2018b) 13
Table 4-2. Overview of some key logistical differences between closure options for the
MSS ash basin. Data provided by Duke Energy (2018b). 14
Table 5-1. Relationships between environmental services and concerns to the local
community associated with CCR and ash basin closure hazards 22
Table 5-2. Associations between objectives for closure and remediation of the Marshall
ash basins and environmental services 23
Table 5-3. Matrix of key environmental services, attributes, and comparative metrics
applied in the NEBA 24
Table 5-4. Risk-ranking matrix for impacts and risk from remediation and closure
activities. Darker shading/higher codes indicate greater impact 27
Table 7-1. Summary of human health risk assessment hazard index (HI) and excess
lifetime cancer risk (ELCR) from SynTerra (2018b) 35
Table 7-2. Summary of relative risk ratings for attributes that characterize potential
hazards to humans from CCR exposure in drinking water, surface water,
groundwater, soil, sediment, food, and through recreation 38
Table 8-1. Summary of relative risk ratings for attributes that characterize potential
hazards to ecological resources from CCR exposure in surface water, soil,
sediment, and food 43
Table 9-1. Summary of offsite transportation logistics associated with each closure
option (Duke Energy 2018b) 46
Table 9-2. Hazard indices (HI) and excess lifetime cancer risk (ELCR) from exposure
to diesel exhaust emissions along transportation corridors in northern North
Carolina. Results are for the maximum exposures modeled. 49
Table 9-3. Comparative metrics for increased noise and congestion and traffic accidents 52
Table 9-4. Summary of relative risk ratings for attributes that characterize potential
hazards to communities during remediation activities. 54
Table 10-1. Summary of NPP DSAYs for CIP and excavation closure options 62
Table 10-2. Percent impact of ash basin closure options 63
Table 10-3. Summary of relative risk ratings for habitat changes that affect provision of
environmental services. 63

1805955.000 - 1990 vii
Table 11-1. NEBA for closure of the ash basin at Marshall. 67

1805955.000 - 1990 viii
Acronyms and Abbreviations
AADT annual average daily traffic
AOW area of wetness
ASOS Automated Surface Observing S ystem
BCF bioconcentration factor
CAMA North Carolina Coal Ash Management Act
CAP corrective action plan
CCR coal combustion residuals
CCR Rule EPA Coal Combustion Residuals Rule of 2015
CERCLA Comprehensive Environmental Response, Compensation, and Liability
Act
CIP cap in place
COI constituent of interest
COPC chemical of potential concern
CSA comprehensive site assessment
DPM diesel particulate matter
Duke Energy Duke Energy Carolinas, LLC
DSAY discounted service acre-year
ELCR excess lifetime cancer risk
EPA U.S. Environmental Protection Agency
EPC exposure point concentration
ERA ecological risk assessment
FGD flue gas desulfurization
GIS geographic information system
HEA habitat equivalency analysis
HHRA human health risk assessment
HI hazard index
HQ hazard quotient
LOAEL lowest-observed-adverse-effects level
MOVES Mobile Vehicle Emissions Simulator
MSS Marshall Steam Station
NEBA net environmental benefit analysis
NCDEQ North Carolina Department of Environmental Quality
NCDOT North Carolina Department of Transportation
NOAA National Oceanic and Atmospheric Administration
NOAEL no-observed-adverse-effects level
NPDES National Pollutant Discharge Elimination System
NPP net primary productivity
NRDA natural resource damage assessment
OSAT-2 Operational Science Advisory Team-2
PBTV provisional background threshold value
PV Photovoltaic
RCRA Resource Conservation and Recovery Act
REL reference exposure level

1805955.000 - 1990 ix
RfD reference dose
SOC Special Order by Consent
TRV toxicity references value
TVA Tennessee Valley Authority

1805955.000 - 1990 x
Limitations
This report sets forth my conclusions, which are based on my education, training, and
experience; field work; established scientific methods; and information reviewed by me or
under my direction and supervision. These conclusions are expressed to a reasonable degree of
scientific certainty. The focus of this report is on local community impacts. I have, therefore, not
attempted to evaluate broader environmental impacts, such as impacts from greenhouse gas
emissions, that would be associated with each closure option.
The conclusions in this report are based on the documents made available to me by Duke
Energy or collected as part of my investigation. I reserve the right to supplement my
conclusions if new or different information becomes available to me.

1805955.000 - 1990 xi
Executive Summary1
In 2015, the U.S. Environmental Protection Agency (EPA) issued a rule called the “Hazardous
and Solid Waste Management System; Disposal of Coal Combustion Residuals [CCR] from
Electric Utilities” (CCR Rule), which, among other things, regulates closure of coal ash
impoundments in the United States. Closure of coal ash impoundments in North Carolina is
further regulated by the North Carolina Coal Ash Management Act of 2014 (CAMA) as
amended by H.B. 630, Sess. L. 2016-95. Under both the North Carolina CAMA and the federal
CCR Rule, there are two primary alternatives for closure of an ash impoundment:
 “Cap in place” (CIP) closure involves decanting the impoundment and
placing a low-permeability liner topped by appropriate cap material, soil, and
grass vegetation over the footprint of the ash to restrict vertical transport of
water through the ash, as well as a minimum of 30 years of post-closure care,
which requires the implementation of corrective action measures if and as
necessary;
 Excavation closure involves decanting the impoundment, excavating all ash
in the basin, transporting the ash to an appropriate, permitted, lined landfill,
and restoring the site.
Duke Energy Carolinas, LLC’s (Duke Energy’s) Marshall Steam Station (MSS) has one unlined
inactive ash basin. CCR associated areas that lie partially or completely within the ash basin
waste boundary include the Dry Ash Landfill (Phase II), the Industrial Landfill No. 1, and the
Photovoltaic (PV) Farm Structural Fill. Other landfill areas located beyond the ash basin waste
boundary include the Dry Ash Landfill (Phase I), the flue gas desulfurization (FGD) landfill, the
demolition landfill, and the asbestos landfill (SynTerra 2018a).
Duke Energy has evaluated three representative types of closure for the ash basin at MSS—CIP,
excavation, and hybrid closure—the latter of which involves excavating and consolidating ash

1 Note that this Executive Summary does not contain all of the technical evaluations and analyses that support the
conclusions. Hence, the main body of this report is at all times the controlling document.

1805955.000 - 1990 xii
within the basin footprint to reduce the spatial area of CIP closure. The administrative process
for selecting an appropriate closure plan for the ash basin is ongoing.
The purpose of my report is to examine how the local community’s environmental health and
environmental services2 are differently affected by each closure option as currently defined and
to evaluate these differences in a structured framework that can support decision-making in this
matter.
Environmental Decision-Making
Environmental decision-making involves understanding complex issues that concern multiple
stakeholders. Identifying the best management alternative often requires tradeoffs among
stakeholder values. These tradeoffs necessitate a transparent and systematic method to compare
alternative actions and support the decision-making process. My analyses in this matter have
used a net environmental benefit analysis (NEBA) framework (Efroymson et al. 2003, 2004) to
compare the relative risks and benefits from CIP closure, excavation closure, or a hybrid CIP
and excavation closure of the ash basin at MSS. The NEBA framework relies on scientifically
supported estimates of risk to compare the reduction of risk associated with chemicals(s) of
potential concern (COPCs)3 under different remediation and closure alternatives alongside the
creation of any risk during the remediation and closure, providing an objective, scientifically
structured foundation for weighing the tradeoffs between remedial and closure alternatives.
Despite the scientific basis of the risk characterization process used in NEBA, stakeholders in
any environmental decision-making scenario may place different values on different types of
risk (i.e., stakeholders may have different priorities for the remediation and closure). NEBA
does not, by design, elevate, or increase the value of, any specific risk or benefit in the
framework. The purpose of NEBA is to simultaneously and systematically examine all tradeoffs

2 Environmental services, or ecosystem services, are ecological processes and functions that provide value to
individuals or society (Efroymson et al. 2003, 2004).
3 COPCs are “any physical, chemical, biological, or radiological substance found in air, water, soil or biological
matter that has a harmful effect on plants or animals”
(https://ofmpub.epa.gov/sor_internet/registry/termreg/searchandretrieve/glossariesandkeywordlists/search.do?de
tails=&glossaryName=Eco%20Risk%20Assessment%20Glossary).

1805955.000 - 1990 xiii
that affect the services provided to humans and the ecosystem by the environment under
remediation and closure, allowing decision-makers to more fully understand all potential
benefits and risks of each alternative.
NEBA and similar frameworks have been used extensively by regulatory agencies such as the
National Oceanic and Atmospheric Administration (NOAA) and EPA to support evaluating
tradeoffs in mitigation (e.g., NOAA 1990), remediation (e.g., U.S. EPA 1988, 1994), and
restoration (e.g., NOAA 1996). The National Environmental Policy Act (40 CFR § 1502) relies
on a structured framework to conduct environmental assessments and produce environmental
impact statements; these analyses evaluate potential adverse effects from development projects
and identify alternatives to minimize environmental impacts and/or select mitigation measures.
Natural resource damage assessment (NRDA) utilizes a structured process to estimate
environmental injury and lost services and identify projects that restore the impacted
environment and compensate the public for the lost environmental services (e.g., NOAA 1996).
The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
remedial investigation/feasibility study process uses a set of evaluation criteria to identify
remediation projects for contaminated Superfund sites that meet remediation objectives for
effectiveness, implementability, and cost (U.S. EPA 1988). Within the Superfund Program, EPA
has also recognized the importance of remediation that comprehensively evaluates cleanup
actions “to ensure protection of human health and the environment and to reduce the
environmental footprint of cleanup activities to the maximum extent possible” (U.S EPA 2010).
The Tennessee Valley Authority (TVA) recently used a structured framework to compare the
impacts and benefits of ash basin closure alternatives at ten of its facilities (TVA 2016).
Through a NEBA-like analysis, the TVA identified “issue areas,” such as air quality,
groundwater, vegetation, wildlife, transportation, and noise and created a summary table that
provided a side-by-side comparison of the impacts of “no action,” “closure-in-place,” and
“closure-by-removal” actions. As a result of this analysis, TVA identified “closure-in-place” as
“its preferred alternative” for all ten facilities stating, “[t]his alternative would achieve the
purpose and need for TVA’s proposed actions and compared to Closure-by-Removal with less
environmental impact, shorter schedules, and less cost” (TVA 2016). The Marshall ash basin

1805955.000 - 1990 xiv
closure presents similar “issue areas” that can benefit from a similar, systematic analysis of net
benefits resulting from closure activities.
Linking Stakeholder Concerns to NEBA
To better understand stakeholder concerns related to closure of the ash basin at MSS, I reviewed
written communications about ash pond closure plans for MSS submitted to and summarized by
the North Carolina Department of Environmental Quality (NCDEQ 2016). From this review, I
identified the following categories of stakeholder concerns:
 Drinking water quality
 Groundwater quality
 Surface water quality
 Fish and wildlife
 Maintaining property value
 Preservation of natural beauty
 Recreational value
 Swimming safety
 Failure of the ash impoundment
 Risk created by the closure option outweighing risk from contamination.
The primary concerns expressed in this matter involve perceived risks from exposure to CCR
constituents that could negatively affect environmental services that benefit the local
community: provision of safe drinking water and food, safe recreational enjoyment (hunting,
fishing, swimming), and protection of natural beauty and biodiversity.4 Potential hazards to the
community associated with closure activities include physical disturbance of existing habitats;
air pollution from diesel emissions resulting from transportation activities; and traffic, noise,
and accidents that could result in property damage, injuries, and fatalities. Table ES-1 links
concerns over CCR exposure and potential hazards created by ash basin closure to
environmental services that could be affected by closure activities.

4 Biodiversity is the variety of plants and animals present at a location. Protection of biodiversity refers to
provision of habitat and related functions capable of sustaining biological populations.

1805955.000 - 1990
xv
Table ES-1. Relationships between environmental services and concerns to the local community associated with CCR
and ash basin closure hazards
Environmental Services
Safe drinking
water quality
Safe surface
water quality
Safe air
quality
Safe food
quality
Protection of
biodiversity
Recreation Natural
beauty
Safe community
environment
CCR Concerns
Drinking water
contamination
X X X
Groundwater contamination X X X
Surface water
contamination
X X X X X X X
Fish/wildlife contamination X X X X X
Contamination impacting
property value
X X X X X X X
Contamination impacting
natural beauty
X X X
Contamination impacting
recreational enjoyment
X X X X X
Contamination impacting
swimming safety
X X X X
Failure of the ash
impoundment
X X X X X X X
Closure Hazards
Habitat loss X X X X X
Contamination of air X X X X
Noise, Traffic, Accidents X X

1805955.000 - 1990 xvi
In recognition of the potential discrepancy between stakeholder priorities and the broad and
balanced treatment of service risks and benefits in NEBA, I organized the NEBA analysis
around the following five objectives for ash basin closure that recognize local stakeholder
concerns while being consistent with the methods and purpose of NEBA:
1. Protect human health from CCR constituent exposure
2. Protect ecological health from CCR constituent exposure
3. Minimize risk and disturbance to humans from closure
4. Minimize risk and disturbance to the local environment from closure
5. Maximize local environmental services.
In my analysis, I linked environmental services to the local community that could be potentially
impacted by ash basin closure and the identified objectives of ash basin closure, and I identified
attributes and comparative metrics5 that characterize the condition of the environmental services
(Efroymson et al. 2003, 2004).
I used human health attributes (e.g., risk to onsite construction workers, risk to offsite
swimmers) and risk quotients (hazard index [HI], excess lifetime cancer risk [ELCR]) to
evaluate whether there would be a potential impact to environmental services related to safe
water, air, and food under each ash basin closure option. I also used human health attributes to
evaluate whether there would be an impact to air quality during closure activities. I used
ecological health attributes (e.g., risk to birds, mammals) and risk quotients (hazard quotients
[HQs]) to evaluate whether there would be a potential impact to environmental services related
to safe surface water and food and protection of biodiversity and natural beauty under the ash
basin closure options. I evaluated risk and disturbance associated with traffic and accidents
using transportation metrics and trucking logistics (e.g., number of truck miles driven)
associated with each closure option to evaluate potential impacts to community safety. I used
net primary productivity (NPP)6 and discounted service acre-years (DSAYs)7 to characterize

5 For purposes of this analysis, an attribute is a feature that characterizes environmental services and may be
impacted by a closure option. Comparative metrics are features of the attribute (e.g., risk quotients, acreage of
habitat) that can be measured and compared between closure options.
6 NPP represents the mass of chemically fixed carbon produced by a plant community during a given time
interval. It reflects the rate at which different ecosystems are able to sequester carbon, which is related to
mitigating climate change (https://earthobservatory.nasa.gov/GlobalMaps/view.php?d1=MOD17A2_M_PSN).

1805955.000 - 1990 xvii
differences in the environmental services that derive from habitats (e.g., protection of
biodiversity, natural beauty) and that would be impacted by ash basin closure activities. Finally,
I assembled all attributes, services, and objectives within a full NEBA to examine which of the
closure options best maximizes environmental services for the local community. The metrics I
used are scientifically appropriate and commonly applied metrics to evaluate risk to humans and
the environment (U.S. EPA 1989, 1997, 2000b; NHTSA 2016) and to quantitatively measure
differences in environmental services associated with impact and restoration (Dunford et al.
2004; Desvousges et al. 2018; Penn undated; Efroymson et al. 2003, 2004).
Of note, my analysis did not consider the risks involved with onsite construction activities. For
example, I did not attempt to evaluate occupational accidents created by onsite construction and
excavation. Nor did I attempt to evaluate emissions associated with onsite construction
activities. Finally, I did not attempt to consider the risk created by disturbing the ash basin and
exposing it to the elements during excavation activities.
Some stakeholders also expressed concern over safety of the ash impoundment dam (NCDEQ
2016). The most recent dam safety report produced by Amec Foster Wheeler and submitted to
NCDEQ indicates “the construction, design, operation, and maintenance of the CCR surface
impoundments have been sufficiently consistent with recognized and generally accepted
engineering standards for protection of public safety and the environment” (Browning and
Thomas 2018).
Three possible options for closure of the ash basin at Marshall were identified by Duke Energy
(2018b) and summarized in (Table ES-2). I used these options in the NEBA to examine how
different closure possibilities impact environmental services to the local community.

7 DSAYs are derived from habitat equivalency analysis (HEA). HEA is an assessment method that calculates
debits based on services lost and credits for services gained from a remediation action (Dunford et al. 2004;
Desvousges et al. 2018; Penn undated). A discount rate is used to standardize the different time intervals in
which the debits and credits occur, and in doing so, present the service debits and credits at present value. The
present value of the services is usually expressed in terms of discounted service acre-years of equivalent habitat,
or DSAYs, which provide a means to compare the different service levels of affected habitat acres (Dunford et
al. 2004; Desvousges et al. 2018; Penn undated).

1805955.000 - 1990 xviii
Table ES-2. Ash basin closure options provided by Duke Energy (2018b)
Closure Option Description
Closure
Duration
(years)a
Construction
Duration
(years)b
CIP CIP 15 13
Excavation Excavate to current onsite landfill and create
new landfill within the excavated basin
32 28
Hybrid Partially excavate to consolidate ash and
CIP consolidated ash
15 12
a Includes pre-design investigation, design and permitting, site preparation, construction, and site restoration.
b Includes only site preparation, construction, and site restoration.
NEBA Risk Ratings
NEBA organizes environmental hazard and benefit information into a unitless metric that
represents the degree and the duration of impact from remediation and closure alternatives. One
approach to structure this analysis is to create a risk-ranking matrix that maps the proportional
impact of a hazard (i.e., risk) with the duration of the impact, which is directly related to the
time to recovery (Robberson 2006). The risk-ranking matrix used for this application of NEBA
is provided in Table ES-3. In this application, the matrix uses alphanumeric coding to indicate
the severity of an impact: higher numbers and higher letters (e.g., 8F) indicate a greater extent
and a longer duration of impact. Shading of cells within the matrix supports visualization of the
magnitude of the effect according to the extent and duration of impact.8 When there is no
meaningful risk, the cell is not given an alphanumeric code. Relative risk ratings for each
attribute and scenario examined were assembled into objective-specific summaries to compare
the net benefits of the closure options. All closure options in the NEBA were evaluated against
current conditions as a “baseline” for comparison.

8 Categories and shading as defined in the risk-ranking matrix are based on best professional judgment and used
for discussion of the relative differences in relative risk ratings. Alternative risk matrices and re sulting NEBA
classifications are explored in Appendix E.

1805955.000 - 1990 xix
Table ES-3. Risk-ranking matrix for impacts and risk from closure activities.
Darker shading and higher codes indicate greater impact.

Duration of Impact (years)
>50
(8)
35–50
(7)
26–35
(6)
16–25
(5)
10–15
(4)
5–9
(3)
1–4
(2)
<1
(1) % Impact No meaningful risk -- -- -- -- -- -- -- --
<5 % (A) 8A 7A 6A 5A 4A 3A 2A 1A
5–19% (B) 8B 7B 6B 5B 4B 3B 2B 1B
20–39% (C) 8C 7C 6C 5C 4C 3C 2C 1C
40–59% (D) 8D 7D 6D 5D 4D 3D 2D 1D
60–79% (E) 8E 7E 6E 5E 4E 3E 2E 1E
>80% (F) 8F 7F 6F 5F 4F 3F 2F 1F
NEBA analysis of possible closure options for the ash basin at MSS helps both Duke Energy
and other stakeholders understand the net environmental benefits from the closure option
configurations that were examined. If a closure option that is preferred for reasons not
considered in the NEBA does not rate as one of the options that best maximizes environmental
services to the local community, closure plans for that option can be re-examined, and
opportunities to better maximize environmental benefits can be identified (e.g., including an
offsite habitat mitigation project to offset environmental services lost from habitat alteration).
The NEBA can then be re-run with the updated plan to compare the revised closure plan with
other closure options.
The following is a summary of my conclusions and supporting analyses, which are structured
around the five objectives identified above.
Conclusion 1: All closure options for the MSS ash basin are
protective of human health.
The first objective for ash basin closure, to protect human health from CCR constituent
exposure, is represented by environmental services that provide safe drinking water, safe
groundwater, safe surface water, safe food consumption, and safe recreation. For purposes of the
NEBA, these safety considerations were evaluated based on the following:

1805955.000 - 1990 xx
1. Provision of permanent alternative drinking water supplies to private well
water supply users within a 0.5-mile radius of the MSS ash basin compliance
boundary (Holman 2018);
2. Concentrations of CCR constituents of interest (COIs)9 in drinking water
wells that could potentially affect local residents and visitors, as characterized
by HDR (2015a, 2016b) and SynTerra (2018a) in the Comprehensive Site
Assessment (CSA); and
3. Risk to various human populations from CCR exposure, as characterized in
the updated human health and ecological risk assessment conducted by
SynTerra (2018b; Appendix B).
Based on these analyses, no CCR impacts to drinking water and no meaningful risk to humans
from CCR exposure were found under current conditions10 or under any closure option. Using
the NEBA framework and relative risk ratings, these results are summarized in Table ES-4
within the objective of protecting human health from exposure to CCR constituents.

9 COIs are constituents relevant to analysis of potential exposure to CCR constituents but are not necessarily
associated with risk to human or ecological receptors.
10 SynTerra’s updated human health risk assessment (HHRA) considered only potential exposure pathways that
currently exist and could remain after ash basin closure under any closure option. Any potential risk currently
associated with seeps (or areas of wetness [AOWs]) at MSS was not evaluated in the HHRA or considered in this
analysis because any risk resulting from seeps will be eliminated, reduced, or mitigated per the court-enforceable
Special Order by Consent (SOC) that Duke Energy entered with the North Carolina Environmental Management
Commission on April 18, 2018 (EMC SOC WQ S17-009; See Section 4.2). The SOC requires Duke Energy to
accelerate the schedule for decanting the ash basin to “substantially reduce or eliminate” seeps that may be
affecting state or federal waters; the SOC also requires Duke Energy to take appropriate corrective actions for any
seeps remaining after decanting is complete to ensure the remaining seeps are managed “in a manner that will be
sufficient to protect public health, safety, and welfare, the environment, and natural resources” (EMC SOC WQ
S17-009).

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Table ES-4. Summary of relative risk ratings for attributes that characterize potential
hazards to humans from CCR exposure in drinking water, surface water,
groundwater, food, and recreation
Objective Protect Human Health from CCR
Hazard Exposure to CCR Potentially Affected Populations Local Residents/Visitors Onsite Construction Workers Offsite Recreational Swimmers Offsite Recreational Waders Offsite Recreational Boaters Offsite Recreational Fishers Offsite Subsistence Fishers Scenario
Baseline -- -- -- -- -- -- --
CIP -- -- -- -- -- -- --
Excavation -- -- -- -- -- -- --
Hybrid -- -- -- -- -- -- --
“--” indicates “no meaningful risk.”
Current conditions and conditions under all closure options support provision of safe drinking
water, safe surface water, safe food, and safe recreation, satisfying the first objective of ash
basin closure—to protect human health from CCR constituent exposure.
Conclusion 2: All closure options for the MSS ash basin are
protective of ecological health.
The second objective for ash basin closure, to protect ecological health from CCR constituent
exposure, is represented by environmental services that provide safe surface water, safe food
consumption, and protection of biodiversity and natural beauty. For purposes of the NEBA,
these considerations were evaluated based on the following:
1. Risk to ecological receptors from CCR exposure, as characterized by
SynTerra (2018b; Appendix B) in the updated human health and ecological
risk assessment; and

1805955.000 - 1990 xxii
2. Aquatic community health in Lake Norman as reported in the Lake Norman
Maintenance Monitoring Program summary report for 2016 (Duke Energy
2018a).
From my review of these analyses, no evidence of impacts to ecological receptors from CCR
exposure was identified under current conditions11 or under any closure option, and Lake
Norman continues to support a healthy aquatic community (Duke Energy 2018a). Using the
NEBA framework and relative risk ratings, these results are summarized in Table ES-5 within
the objective of protecting environmental health from exposure to CCR constituents.
Current conditions and conditions under all closure options support provision of safe surface
water, safe food consumption, and protection of biodiversity and natural beauty, satisfying the
second objective of ash basin closure—to protect ecological health from CCR constituent
exposure.

11 SynTerra’s updated ecological risk assessment (ERA) considered only potential exposure pathways that currently
exist and could remain after ash basin closure under any closure option. Any potential risk currently associated
with seeps (or AOWs) at MSS was not evaluated in the ERA or considered in this analysis because any risk
resulting from seeps will be eliminated, reduced, or mitigated per the court-enforceable SOC that Duke entered
with the North Carolina Environmental Management Commission on April 18, 2018 (EMC SOC WQ S17-009;
See Section 4.2). The SOC requires Duke Energy to accelerate the schedule for decanting the ash basin to
“substantially reduce or eliminate” seeps that may be affecting state or federal waters; the SOC also requires Duke
Energy to take appropriate corrective actions for any seeps remaining after decanting is complete to ensure the
remaining seeps are managed “in a manner that will be sufficient to protect public health, safety, and welfare, the
environment, and natural resources” (EMC SOC WQ S17-009).

1805955.000 - 1990 xxiii
Table ES-5. Summary of relative risk ratings for attributes that characterize potential
hazards to ecological resources from CCR exposure in surface water, soil,
sediment, and food
Objective Protect Ecological Health
from CCR
Hazard Exposure to CCR Potentially Affected Populations Fish Populations Aquatic Omnivore Birds (mallard) Aquatic Piscivore Birds (great blue heron) Aquatic Carnivore Birds (bald eagle) Aquatic Herbivore Mammals (muskrat) Aquatic Piscivore Mammals (river otter) Scenario
Baseline -- -- -- -- -- --
CIP -- -- -- -- -- --
Excavation -- -- -- -- -- --
Hybrid -- -- -- -- -- --
“--” indicates “no meaningful risk.”
Conclusion 3: CIP and hybrid closure options limit the duration
of community disturbance.
The third objective for ash basin closure, to minimize risk and disturbance to humans from
closure, is represented by environmental services that provide safe air quality and a safe
community environment. For purposes of the NEBA, these considerations were evaluated based
on the following:
1. Health risks from diesel exhaust emissions to the community living and
working along transportation corridors during trucking operations to haul
materials to and from the ash basin, as evaluated through the application of
diesel truck air emissions modeling and human health risk assessment; and

1805955.000 - 1990 xxiv
2. The relative risk for disturbance and accidents resulting from trucking
operations affecting residents living and working along transportation
corridors during construction operations, as evaluated by comparing the
relative differences in trucking operations among the closure options.
From these analyses, no meaningful health risk is expected from diesel exhaust emissions under
any closure option, but all the closure options are expected to produce different levels of
community disturbance in the form of noise and traffic congestion and risk of traffic accidents.
I used the number of trucks per day passing12 a receptor along a near-site transportation corridor
to examine the differences in noise and traffic congestion under the closure options. I compared
the increase in the average number of trucks hauling earthen fill, geosynthetic material, and
other materials under the closure options13 to the current number of truck passes for the same
receptor. I specified a baseline level of truck passes14 on the transportation corridor under
current conditions of 153 passes per day. Based on the assumed 153-truck-per-day baseline
level and the number of truck trips per day from Duke Energy’s projections (Duke Energy
2018b), the closure options would have similar impacts to the communities through which the
trucks pass on a daily basis (CIP = 7%, excavation = 4%, hybrid = 7%). I input these percent
impacts to the risk-ranking matrix (Table ES-3) along with the total duration of construction
activities (13 years CIP; 28 years excavation; 12 years hybrid) to evaluate which of the closure
options best minimizes human disturbances.
I also evaluated risk of traffic accidents by comparing the average number of annual offsite road
miles driven between closure options relative to an estimate of the current road miles driven in
Catawba County, North Carolina. I specified a current, or baseline, level of annual road miles

12 Truck passes per day resulting from closure activities are calculated as the total number of loads required to
transport earthen fill, geosynthetic materials, and other materials multiplied by two to account for return trips.
The resulting total number of passes is then divided evenly among the total number of months of construction
time multiplied by 26 working days per month.
13 Truck trips to haul ash were not included in the estimate for MSS ash basin closure because trucks hauling ash
would not leave MSS property and would not affect community receptors along the transportation corridors.
14 A baseline estimate of trucking passes per day for transportation corridors near MSS was derived from North
Carolina Department of Transportation (NCDOT) data of annual average daily traffic (AADT) at thousands of
locations across the state and the proportion of road miles driven by large trucks in North Carolina (See
Appendix E for details).

1805955.000 - 1990 xxv
driven along the transportation corridor near Marshall of 129 million miles,15 and the road miles
driven under the closure options are from the trucking projections provided by Duke Energy
(2018b). Using the 129-million-truck-miles baseline assumption, CIP has a 0.04% impact;
excavation has a 0.02% impact; and hybrid closure has a 0.04% impact. All closure options
have a relative risk rating of <5%. These relative risk ratings appear to be insensitive to lower
assumed baseline annual truck miles (Appendix E).
Table ES-6 summarizes the NEBA relative risk ratings based on the trucking projections and
implementation schedules provided by Duke Energy (2018b) for the objective of minimizing
disturbance to humans during closure. All closure options create a level of risk and disturbance
to human populations over baseline conditions. While the excavation closure option produces
comparable, if slightly lower, impacts to CIP and hybrid closures on a daily or annual basis (risk
rating of A), the impacts occur for more than twice as long as those for CIP or hybrid closure,
resulting in a greater cumulative impact (risk rating 6 compared to 4) from excavation closure
based on the trucking projections and implementation schedules provided by Duke Energy
(2018b).

15 To estimate the number of baseline truck miles, I multiplied the number of total vehicle miles traveled in
Catawba County (NCDMV 2017) by the Catawba County average 6.6% contribution of trucks to total AADT
(NCDOT 2015).

1805955.000 - 1990 xxvi
Table ES-6. Summary of relative risk ratings for attributes that characterize
potential hazards to communities during closure activities.
Darker shading and higher codes indicate greater impact.
Objective Minimize Human Disturbance
Hazard Noise and Traffic
Congestion
Traffic
Accidents
Air
Pollution Potentially Affected Populations Local Residents/Visitors Local Residents/Visitors Reasonable Maximum Exposure Scenario Baseline baseline baseline baseline
CIP 4B 4A --
Excavation 6A 6A --
Hybrid 4B 4A --
“--” indicates “no meaningful risk.”
All closure options support safe air quality from diesel truck emissions along the transportation
routes, and each creates comparable levels of disturbance and risk on a daily or annual basis that
could adversely impact community safety; however, these impacts occur for a substantially
longer period under the excavation closure option (28 years for excavation closure compared to
13 and 12 years for CIP and hybrid closures, respectively). Thus, CIP and hybrid closure
options better satisfy the third objective of ash basin closure—to minimize risk and disturbance
to humans from closure.
Conclusion 4: All closure options for the MSS ash basin create
environmental disturbance.
The fourth objective for ash basin closure, to minimize risk and disturbance to the local
environment from closure, is represented by two environmental services: protection of
biodiversity and natural beauty. For purposes of the NEBA, these considerations were evaluated

1805955.000 - 1990 xxvii
based on differences in the NPP of impacted habitats under the closure options, as estimated by
the number of DSAYs calculated by a habitat equivalency analysis (HEA).
The results of the HEA indicate that all closure options will result in a net loss of environmental
services due primarily to loss of forest habitat for borrow and landfill areas, reduced NPP
services provided by a grass cap (cap and landfill areas),16 and the long delay for restoration of
forested habitat in the ash basin (excavation and hybrid closures) and borrow pit (all options).
These factors, collectively, adversely affect environmental services provided by the impacted
habitat such that environmental services produced after closure will not compensate for the
service losses resulting from the closure, with hybrid closure creating the least NPP service loss.
These differences are summarized in Table ES-7. A full description of the methods,
assumptions, results, and sensitivity analyses for the HEA are provided in Appendix D and E.

16 An open field provides a relatively lower NPP service level than forest habitat (40% of forest NP P; Ricklefs
2008), and since a grass cap requires periodic maintenance mowing, for purposes of the HEA it was assumed
never to reach a level of NPP service equivalent to an open field. Grass cap was assigned a post-closure service
level of 8%, with full service attained in 2 years.

1805955.000 - 1990 xxviii
Table ES-7. Summary of NPP DSAYs for closure options
CIP Excavation Hybrid
Ash basin losses Open Field −8 −8 −8

Grass Cap −324 −306 −324

Open Water −253 −239 −253

Wetland −89 −84 −89
Broadleaf Forest −1,757 −1,645 −1,757
Needle Leaf Forest −1 −1 −1

Scrub/Shrub −1,542 −1,453 −1,542

Wetland Forest −25 −24 −25

Total losses −4,002 −3,758 −4,002
Ash basin post-closure gains Open Field 89 111
Grass Cap 784 164 495

Open Water 329 541

Wetland 12 15

Broadleaf Forest 1,627 1,033
Needle Leaf Forest 122 77
Scrub/Shrub 309 384
Wetland Forest 49 80

Total gains 784 2,704 2,737
Landfill/borrow losses Forest −1,508 −5,286 −754

Open Field
Grass Cap −9

Total losses −1,508 −5,295 −754
Landfill/borrow post-closure gains Forest 823 1,022 424

Grass cap 126
Total gains 823 1,148 424
Net Gain/Loss per Option −3,903 −5,202 −1,594
Note: DSAYs for specific habitat types are reported here rounded to the nearest whole number. As such, the net
gain/loss per option differs slightly from the sum of the individual DSAYs reported in the table.

The impact of the closure options on environmental services was computed as the percentage
difference in net DSAYs produced by the closure option and the baseline DSAYs (or the

1805955.000 - 1990 xxix
absolute value of the DSAY losses). The DSAY losses represent the NPP services that would
have been produced by the ash basin, borrow areas, and landfills but for the project closure. The
DSAY gains represent the NPP services restored after project closure plus any future gains
realized from existing habitats before remediation begins. The sum of DSAY losses and gains
represents the net change of NPP services for the project resulting from closure. Dividing the
closure option net DSAYs by the absolute value of the DSAY losses provides a percentage of
the impact. From these calculations, CIP closure will have a 71% impact, excavation closure
will have a 57% impact, and hybrid closure will have a 34% impact. 17 These percent impacts
were input to the risk-ranking matrix (Table ES-3) along with the duration of the closure
activities (13 years CIP; 28 years excavation; 12 years hybrid) to visualize, within the NEBA
framework, which of the closure options best minimizes environmental disturbances (Table ES-
8).
Table ES-8. Summary of relative risk ratings for habitat changes that
affect protection of biodiversity and natural beauty.
Darker shading and higher codes indicate greater impact.
Objective
Minimize Environmental
Disturbance
Hazard Habitat Change
Attribute DSAYs
Scenario
Baseline baseline
CIP 4E
Excavation 6D
Hybrid 4C
Within the objective of minimizing environmental disturbance from closure, my analyses
indicate that all closure options adversely impact habitat-derived environmental services;
however, hybrid closure best minimizes impacts to the protection of biodiversity and natural
beauty, better satisfying the fourth objective of ash basin closure—to minimize risk and
disturbance to the local environment from closure.

17 As discussed below, this habitat impact could be offset with an appropriate reforestation project.

1805955.000 - 1990 xxx
Conclusion 5: Hybrid closure maximizes environmental services.
Identifying environmental actions that maximize environmental services (the fifth objective for
ash basin closure) is a function of NEBA (Efroymson et al. 2003, 2004) and the overarching
objective that encompasses each of the other four objectives and all of the environmental
services that have been considered to this point.
I organized my analyses around the following five objectives for ash basin closure, and I found
the following:
1. Protect human health from CCR constituent exposure
All closure options for the MSS ash basin are protective of human health.
2. Protect ecological health from CCR constituent exposure
All closure options for the MSS ash basin are protective of ecological health.
3. Minimize risk and disturbance to humans from closure
CIP and hybrid closure options limit the duration of community disturbance.
4. Minimize risk and disturbance to the local environment from closure
All closure options for the MSS ash basin create environmental disturbance.
5. Maximize environmental local services
Hybrid closure maximizes environmental services.
Table ES-9 summarizes the relative risk ratings for all attributes and objectives that have been
considered. From this analysis, which is based on a scientific definition of risk acceptability and
includes no value weighting, the hybrid closure option best maximizes environmental benefits
compared to the CIP and excavation closure options because it offers equivalent protection of
human and ecological health from CCR exposure, results in less disturbance to the local
community over time compared to excavation closure, and produces the least disturbance to the
environment. Thus, hybrid closure best satisfies the fifth objective of ash basin closure—to
maximize local environmental services.
As noted previously, NEBA analysis provides an opportunity to better understand the net
environmental benefits of possible closure options. If Duke Energy’s preferred closure option
for reasons not considered in the NEBA does not best maximize environmental services to the

1805955.000 - 1990 xxxi
local community as currently defined, the NEBA results provide insight into how environmental
services could be improved for that closure option. For instance, if Duke Energy’s preferred
closure option for MSS is CIP closure but the HEA results for the currently defined CIP closure
option estimate a net environmental service loss of 3,903 DSAYs, Duke Energy could consider
incorporating into an updated CIP closure plan for MSS a mitigation project that compensates
for the net environmental service losses projected from the currently defined CIP closure option.
As an example, if Duke Energy started a reforestation project outside of the ash basin in 2022
(when onsite preparation of the ash basin begins), the reforestation project would gain 24.3
DSAYs/acre over the lifetime of the site (150 years in the HEA), requiring an approximate 160
acre project to compensate for the 3,903 DSAY loss projected in the HEA. Re-analysis of the
HEA component of the NEBA for the updated possible closure options would then result in no
net environmental losses (as NPP services) from habitat alteration of the basin for CIP closure,
but net losses would remain under the hybrid and excavation closure options.
By looking at a wide variety of attributes that represent a number of different environmental
services that directly link to local stakeholder concerns for the MSS ash basin, I conclude, with
a reasonable degree of scientific certainty, that the hybrid closure option for the MSS ash basin
provides greater net environmental services and less disturbance to the community and the
environment than the excavation and CIP closure options evaluated.

1805955.000 - 1990
xxxii
Table ES-9. NEBA for closure of the ash basins at Marshall.
Darker shading and higher alphanumeric codes indicate greater impact.
Objective Protect Human Health from
CCR
Protect Ecological Health
from CCR Minimize Human Disturbance
Minimize
Environmental
Disturbance
Hazard Exposure to CCR Exposure to CCR Noise and Traffic
Congestion
Traffic
Accidents Air Pollution Habitat Change Potentially Affected Populations Local Residents/Visitors Onsite Construction Workers Offsite Recreational Swimmers Offsite Recreational Waders Offsite Recreational Boaters Offsite Recreational Fishers Offsite Subsistence Fishers Fish Populations Aquatic Omnivore Birds (mallard) Aquatic Piscivore Birds (great blue heron) Aquatic Carnivore Bird (bald eagle) Aquatic Herbivore Mammals (muskrat) Aquatic Piscivore Mammals (river otter) Local Residents/Visitors Local Residents/Visitors Reasonable Maximum Exposure DSAYs
Scenario
Baseline -- -- -- -- -- -- -- -- -- -- -- -- -- baseline baseline baseline baseline
CIP -- -- -- -- -- -- -- -- -- -- -- -- -- 4B 4A -- 4E
Excavation -- -- -- -- -- -- -- -- -- -- -- -- -- 6A 6A -- 6D
Hybrid -- -- -- -- -- -- -- -- -- -- -- -- -- 4B 4A -- 4C
“--” indicates “no meaningful risk.”

1805955.000 - 1990 1
1 Qualifications
I am a senior managing scientist in the Ecological and Biological Sciences Practice at Exponent,
a scientific and engineering consulting firm. I am a professional ecologist, toxicologist, and
biologist with more than 20 years of experience studying the relationship between human
activities and effects on natural resources and people. I have Doctor of Science and Master of
Science degrees in environmental health from the Harvard University School of Public Health. I
have a Bachelor of Science degree in biology from Rhodes College. My academic and
professional training includes a broad background in topics ranging from biology, ecology,
toxicology, epidemiology, pollution fate and transport, and statistical analysis. Key areas of my
practice involve the use of structured frameworks for evaluating multiple lines of evidence to
assess causation of environmental impacts and to weigh the benefits and consequences of
decisions that affect ecological and human health.
Decision support projects I have conducted include the following:
 Net environmental benefit analysis (NEBA) to facilitate the selection of a
remediation plan for a lead contaminated river and to support closure option
analysis of coal ash basins;
 Developing beach management tools to improve public advisories related to
elevated fecal bacteria from sewage contamination at recreational beaches;
 Selecting cleanup thresholds for sediment remediation that quantitatively
weigh the tradeoff between sensitivity and specificity of potential thresholds
to meet cleanup objectives;
 Natural resource damage assessment (NRDA) to support injury quantification
and restoration selection; and
 Review and testimony on the sufficiency of environmental impact analysis to
support development planning.
Projects I have been involved in have concerned coal ash basin closures, oil spills, sewage
releases, heavy metal contamination, development planning, and various industrial and
municipal facilities that have generated complex releases to the aquatic environment. A list of

1805955.000 - 1990 2
my publications, presentations, and cases for which I have written expert reports, been deposed,
and/or provided trial testimony is provided in my curriculum vitae, included as Appendix A of
this report.

1805955.000 - 1990 3
2 Assignment and Retention
I was asked to examine how local environmental health and environmental services are
differently affected under potential closure options for the coal ash basin at Duke Energy
Carolinas, LLC’s (Duke Energy’s) Marshall Steam Station (MSS) and to evaluate these
differences in a structured framework that can support decision-making. My assignment
included review of the comprehensive site assessment (CSA) and corrective action plan (CAP)
documents for Marshall, as well as documents available through the North Carolina Department
of Environmental Quality’s (NCDEQ’s) website and documents prepared as part of Duke
Energy’s National Pollutant Discharge Elimination System (NPDES) permitting. I visited MSS
on September 5, 2018, and I reviewed expert reports prepared for related matters involving
MSS. A list of the primary documents I relied upon is provided in Section 3 of this report.

1805955.000 - 1990 4
3 Reliance Materials
In the process of conducting my analyses, I have reviewed many documents. Of those, I have
relied most on the following reports and documents. Technical (scientific literature) references
are cited in subsequent sections of this report and listed in Section 12.
 Comprehensive Site Assessment (CSA) for the Marshall Steam Station (HDR 2015a,
2016b) and SynTerra (2018a)
 Corrective Action Plan (CAP) for the Marshall Steam Station (HDR 2015b, 016a)
o Baseline Human Health and Ecological Risk Assessment for the Marshall Steam
Station (HDR 2016c [Appendix F of CAP 2])
 Lake Norman Maintenance Monitoring Program summary report for 2016 (Duke Energy
2018a)
 NCDEQ Marshall Meeting Officer Report (NCDEQ 2016)
o Attachment V. Written Public Comments Received
o Attachment VIII. Public Comment Summary Spreadsheet
 Updated Baseline Human Health and Ecological Risk Assessment (SynTerra 2018b;
Appendix B)
 Closure logistics estimates (Duke Energy 2018b).

1805955.000 - 1990 5
4 Introduction
In 2015, the U.S. Environmental Protection Agency (EPA) issued a rule called the “Hazardous
and Solid Waste Management System; Disposal of Coal Combustion Residuals [CCR] from
Electric Utilities” (CCR Rule), which, among other things, regulates closure of coal ash
impoundments in the United States. Closure of coal ash impoundments in North Carolina is
further regulated by the North Carolina Coal Ash Management Act of 2014 (CAMA), as
amended by H.B. 630, Sess. L. 2016-95. Under both the North Carolina CAMA and the federal
CCR Rule, there are two primary alternatives for closure of an ash impoundment:
 “Cap in place” (CIP) closure involves decanting the impoundment and
placing a low permeability liner topped by appropriate cap material, soil, and
grass vegetation over the footprint of the ash to restrict vertical transport of
water through the ash, as well as a minimum of 30 years of post-closure care,
which requires the implementation of corrective action measures if and as
necessary;
 Excavation closure involves decanting the impoundment, excavating all ash
in the basin, transporting the ash to an appropriate, permitted, lined landfill,
and restoring the site.
Duke Energy has evaluated three representative types of closure for the ash basin at MSS—CIP,
excavation to a new onsite landfill at MSS, and hybrid closure—the latter of which involves
excavating and consolidating ash within the basin footprint to reduce the spatial area of CIP
closure. The administrative process for selecting an appropriate closure plan is ongoing.
The purpose of my report is to examine how the local community’s environmental health and
environmental services18 are differently affected by each closure option as currently defined and
to evaluate these differences in a structured framework that can support decision-making in this
matter.

18 Environmental services, or ecosystem services, are ecological processes and functions that provide value to
individuals or society (Efroymson et al. 2003, 2004).

1805955.000 - 1990 6
4.1 Site Setting
MSS is a four-unit coal-fired power plant located on the west bank of Lake Norman near
Terrell, North Carolina, in Catawba County and is approximately 1,446 acres in area (Figure
4-1; SynTerra 2018a).
Marshall began operations in 1965 with Unit 1; Unit 2 was added in 1966; Unit 3 in 1969; and
Unit 4 in 1970 (SynTerra 2018a). Marshall has one unlined active ash basin that is
approximately 394 acres in size and was formed by constructing an earthen dike at the
confluence of Holdsclaw Creek and Lake Norman (an impounded segment of the Catawba
River). The ash basin has “a dendritic shape consisting of coves of deposited ash, dikes that
impound ash in portions of the basin, and four main areas of ponded water” (SynTerra 2018a).
Historically, fly ash and bottom ash were wet sluiced to the ash basin; however, since 1984, fly
ash has been disposed of in the onsite dry ash landfills, and bottom ash is currently wet-sluiced
to a concrete pit where the overlying water decants to the ash basin and the remaining ash is
excavated and sold for offsite beneficial reuse or used for road maintenance at MSS (SynTerra
2018a). In addition to the overlying water from bottom ash recovery, contact stormwater and
leachate from the flue gas desulfurization (FGD) landfill and FGD wastewater treatment system
effluent are routed to the ash basin. The active ash basin contains approximately 16.7 million
tons of CCR (SynTerra 2018a), and effluent from the ash basin discharges to Lake Norman
through National Pollutant Discharge Elimination System (NPDES) Outfall 002 (Figure 4-1).
MSS has two unlined ash landfill units on the eastern edge of the ash basin—Ash Landfill Phase
I19 and Ash Landfill Phase II. The Phase I landfill contains approximately 280,000 tons of fly
ash, and the Phase II landfill contains approximately 4.9 million tons of fly ash (SynTerra
2018a).
Other waste management areas at MSS include additional landfills and a structural fill. The
FGD landfill is a single-liner system located to the west of the ash basin that is permitted to
receive FGD residue (gypsum), clarifier sludge, fly ash, bottom ash, construction and

19 The ash basin footprint underlies a portion of the Phase I landfill.

1805955.000 - 1990 7
demolition waste, asbestos waste, mill rejects (pyrites), waste limestone, land clearing and inert
debris, boiler slag, ball mill rejects, sand blast material, and coal waste; however, the FGD
landfill is currently in interim closure with a 12 in. soil cover system in place and a geosynthetic
clay liner planned to be installed by the end of 2018 (SynTerra 2018a). The Industrial Landfill
No. 1,20 which has been historically permitted to receive the same inputs as the ash landfills
noted above, is located along the northern portion of the ash basin and has a three-component
liner system and a leachate collection and removal system (SynTerra 2018a). The unlined
Photovoltaic (PV) Farm Structural Fill21 located along the northwestern portion of the ash basin
is constructed of fly ash and contains a solar panel field on the south portion of the structural fill
unit (see Figure 4-2); the PV Farm Structural Fill was closed with a soil cover in 2013
(SynTerra 2018a). A demolition landfill and asbestos landfill are also located at MSS and were
closed with soil caps in 2008 (SynTerra 2018a).

20 The Industrial Landfill No. 1 is partially located above the ash basin.
21 The PV Farm Structural Fill is partially located above the ash basin.

1805955.000 - 1990
8

Figure 4-1. Map of MSS. Reproduced and adapted from Figure 2-1 of the 2018 CSA Supplement (SynTerra 2018a).
The location of ash basin discharge to Lake Norman was added (NPDES Outfall 002).

1805955.000 - 1990 9
MSS is located in an ecological transitional zone between the Appalachian Mountains and the
Atlantic coastal plain.22 Historically, much of the region was transformed from oak-hickory-pine
forests to farmland and more recently from farmland back to woodlands characterized by
successional pine and hardwood forest (Griffith et al. 2002). Current aerial imagery and onsite
observations show that approximately 68% of MSS property is forested,23 and I observed forest,
scrub/shrub,24 open water, wetland, and mowed grass habitat areas onsite during my September
5, 2018 visit (Figure 4-2).

22 Marshall is located in the Southern Outer Piedmont based on EPA’s ecoregion classification system.
https://www.epa.gov/eco-research/ecoregions
23 Based on interpretation of aerial satellite imagery and geographic information system (GIS) layers provided by
Duke Energy for Marshall.
24 Scrub/shrub habitat is characterized by low, woody plants.

1805955.000 - 1990 10

Figure 4-2. Images of various habitat types at MSS, September 5, 2018.
(a) Forest, shrub/scrub, and open water habitat looking north through a heron
rookery adjacent to the ash basin. (b) Forest, shrub/scrub, and mowed grass
habitat looking north toward the Industrial Landfill No. 1. (c) Forest and mowed
grass habitat visible from the PV Farm Structural Fill. (d) Open water and forest
around Lake Norman at NPDES Outfall 002 from the ash basin to Lake Norman;
N.B., osprey nest can be seen on top of the street light adjacent to the outfall.
The area surrounding MSS generally includes residential properties, undeveloped land, and
Lake Norman (SynTerra 2018a). Lake Norman was formed in 1963 when the Catawba River
was dammed during construction of Cowan’s Ford Hydroelectric Station, creating the largest
man-made body of water in the state of North Carolina (Duke Energy 2018a). Lake Norman is a
popular recreational destination for fishing, swimming, and boating.25 Known as a “bass fishing
haven,” anglers catch channel catfish (Ictalurus punctatus), flathead catfish (Pylodictis olivaris),
blue catfish (Ictalurus furcatus), black crappie (Promoxis nigro-maculatus), bluegill (Lepomis

25 https://www.visitlakenorman.org/things-to-do/lake-activities/

1805955.000 - 1990 11
macrochirus), largemouth bass (Micropterus salmoides), striped bass (Morone saxatilis),
spotted bass (Micropterus punctulatus), white bass (Morone chrysops), and yellow perch (Perca
flavescens) from Lake Norman.26 “Visit Lake Norman” hosts “several national fishing
tournaments annually, a testament to the fishing opportunities available here.”27 In addition to
the abundant and diverse fish in Lake Norman, a variety of wildlife can be found around the
lake, including numerous species of songbirds as well as larger species such as great blue heron
(Ardea herodias), osprey (Pandion haliaetus), bald eagle (Haliaceetus leucocepbalus), black
vulture (Coragyps atratus), turkey vulture (Catbartes aura), great egret (Ardea alba), red Tail
hawk (Buteo jamaicensis), mute swan (Cygnus olor), and black swan (Cygnus atratus);28
eastern wild turkey (Meleagris gallopavo silvestris) are also found in the terrestrial habitat
around Lake Norman.29 A great blue heron rookery is located at MSS adjacent to the ash basin,
and osprey nests are also found on site, including one built atop the street lamp next to NPDES
Outfall 002 (Figure 4-2).
4.2 Closure of the Ash Impoundments at Marshall
Coal ash, or CCR, includes fly ash, bottom ash, boiler slag, and FGD material (U.S. EPA
2017c). CCR are derived from the inorganic minerals in coal, which include quartz, clays, and
metal oxides (EPRI 2009). Fine-grained, amorphous particles that travel upward with flue gas
are called fly ash, while the coarser and heavier particles that fall to the bottom of the furnace
are called bottom ash (EPRI 2009). The chemical composition of coal ash is similar to natural
geologic materials found in the earth’s crust, but the physical and chemical properties of coal
ash vary depending on the coal source and the conditions of coal combustion and cooling of the
flue gas (EPRI 2009). The majority of both fly ash and bottom ash are composed of silicon,
aluminum, iron, and calcium, similar to volcanic ash and shale (Figure 4-3). Trace elements
such as arsenic, cadmium, lead, mercury, selenium, and chromium generally constitute less than

26 https://www.aa-fishing.com/nc/nc-fishing-lake-norman.html
27 https://www.visitlakenorman.org/things-to-do/lake-activities/fishing-guides/
28 http://www.bestoflakenorman.com/about_lake_norman/wildlife/birds_waterfowl/index.php
29 http://www.lakenormanpublications.com/herald_weekly/wildlife-of-all-kinds-found-around-lake-
norman/article_ac62daf8-1a2e-11e7-8871-c3a109ab9daf.html

1805955.000 - 1990 12
1% of total CCR composition (EPRI 2009; USGS 2015). CCR are classified as a non-hazardous
solid waste under the Resource Conservation and Recovery Act (RCRA).30

Figure 4-3. Elemental composition of bottom ash, fly ash, shale, and volcanic ash.
Excerpt from EPRI (2009).
EPA’s 2015 CCR Rule (40 CFR §§ 257 and 261) requires groundwater monitoring31 of CCR
landfills and surface impoundments and for corrective action, including closure, of CCR sites
under certain circumstances. Owners and operators of CCR landfills and impoundments that are
required to close under the regulation must conduct an analysis of the effectiveness of potential
corrective measures (a corrective measures assessment) and select a strategy that involves either
excavation or capping the “waste-in-place.” Per § 257.97(b), the selected strategy must at a
minimum be protective of human health and the environment, attain groundwater protection
standards, control the source of releases so as to reduce or eliminate further releases of certain
CCR constituents into the environment, remove from the environment as much of the

30 https://www.epa.gov/coalash/coal-ash-rule
31 Groundwater must be evaluated for boron, calcium, fluoride, pH, sulfate, and total dissolved solids, which are
defined as the constituents for detection monitoring in Appendix III. When a statistically significant increase in
Appendix III constituents over background concentrations is detected, monitoring of assessment monitoring
constituents (Appendix IV) is required. Assessment monitoring constituents are antimony, arsenic, barium,
beryllium, cadmium, chromium, cobalt, fluoride, lead, lithium, mercury, molybdenum, selenium, t hallium, and
radium 226 and 228, combined.

1805955.000 - 1990 13
contaminated material that was released from the CCR unit as is feasible, taking into account
factors such as avoiding inappropriate disturbance of sensitive ecosystems, and comply with the
standards for management of wastes in § 257.98(d).
The CCR Rule does not provide criteria for selecting between these closure alternatives because
they are both considered effective closure methods. The CCR Rule states both methods of
closure “can be equally protective, provided they are conducted properly.” Hence, the final CCR
Rule allows the owner or operator to determine whether excavation or closure in place is
appropriate for their particular unit (80 FR 21412).
For the last several years, Duke Energy has been evaluating all of its ash impoundments and
remains in the midst of further evaluating each one, including at MSS, under the CCR Rule and
pursuant to the administrative process set forth in CAMA. Ultimately, a final closure plan will
be approved by NCDEQ.
Three possible options for closure of the ash basin at MSS were identified by Duke Energy and
are summarized in (Table 4-1). These options were used in the NEBA to examine how different
closure possibilities impact environmental services to the local community.
Table 4-1. Ash basin closure options provided by Duke Energy (2018b)
Closure Option Description Closure Duration
(years)a
Construction Duration
(years)b
CIP CIP 15 13
Excavation Excavate into existing and new
onsite landfills.
32 28
Hybrid Partially excavate to consolidate
ash and CIP consolidated ash
15 12
a Includes pre-design investigation, design and permitting, site preparation, construction, and site restoration.
b Includes only site preparation, construction, and site restoration.
Table 4-2 provides a summary of some of the logistical differences between the closure options.
Key among these are the following: (1) a substantially longer period is necessary to complete
excavation closure and (2) substantially more deforestation is required under an excavation
closure for new landfill space and provision of barrow material. Considering logistics alone,

1805955.000 - 1990 14
however, does not provide a complete understanding of the potential benefits and hazards
associated with each closure option, and an integrated analysis is necessary to place stakeholder
concerns regarding risk from CCR in the larger context of risks and benefits to environmental
services.
Table 4-2. Overview of some key logistical differences between
closure options for the MSS ash basin. Data provided by
Duke Energy (2018b).
Closure Option Closure Completion
Time (years)a
Deforested
Acresb
Average truck
trips/dayc
Total truck
milesd
CIP 15 50 5 588,009
Excavation 32 303 3 832,249
Hybrid 15 25 6 535,753
a Includes pre-design investigations, design and permitting, site preparation, construction, and site restoration.
b Includes areas deforested to create borrow pits and/or landfill.
c Includes the total number of offsite roundtrip truck trips to haul earthen and geosynthetic material to and from the
ash basin.
d Includes the total number of truck miles driven over the duration of construction operations to haul material to
and from the ash basin.
Closure of the ash basin at MSS involves decanting any overlying water in the basin and
excavating or capping in place the underlying ash, as specified under CAMA and the federal
CCR Rule. Additional activities related to, but separate from, closure under CAMA and the
CCR Rule concern constructed32 and non-constructed33 seeps associated with the ash basin.34 A
Special Order by Consent (SOC; EMC SOC WQ S17-009) was signed by the North Carolina
Environmental Management Commission and Duke Energy on April 18, 2018, to “address
issues related to the elimination of seeps” from Duke Energy’s coal ash basins. The SOC
requires Duke Energy to accelerate the schedule for decanting the ash basin to “substantially
reduce or eliminate” seeps that may be affecting state or federal waters; the SOC also requires
Duke Energy to take appropriate corrective actions for any seeps remaining after decanting is

32 Constructed seeps are features within the dam structure, such as toe drains or filter blankets, that collect seepage
of liquid through the dam and discharge the seepage through a discrete, identifiable point source to a receiving
water; there are no constructed seeps at MSS to incorporate into the MSS NPDES permit NC0004987 and
managed as part of the wastewater treatment system at MSS (NCDEQ 2018).
33 Non-constructed seeps are not on or within the dam structure and do not convey liquid thro ugh a pipe or
constructed channel; non-constructed seeps at MSS that require monitoring (and potentially action if they are
not eliminated after ash basin decanting) are listed in the SOC (EMC SOC WQ S17-009).
34 In 2014, Duke Energy provided a comprehensi ve evaluation of all areas of wetness (AOWs or seeps) on Duke
Energy property and formally applied for NPDES coverage for all seeps (EMC SOC WQ S17 -009).

1805955.000 - 1990 15
complete to ensure the remaining seeps are managed “in a manner that will be sufficient to
protect public health, safety, and welfare, the environment, and natural resources” (EMC SOC
WQ S17-009). Given the court-enforceable requirement for Duke Energy to remediate any
seeps remaining after decanting the ash basin to meet standards for the protection of public and
environmental health, for purposes of my analyses, seeps (or areas of wetness [AOWs]) are
assumed to contribute no meaningful risk to humans or the environment following any closure
option since all closure options will entail decanting the basins and remediating any risk
associated with remaining seeps as required by the SOC (EMC SOC WQ S17-009).

1805955.000 - 1990 16
5 Approach to Forming Conclusions
Environmental decision-making involves understanding complex issues that concern multiple
stakeholders. Identifying the best management alternative often requires tradeoffs among
stakeholder values. For example, remediation management alternatives can decrease potential
risks to human health and the environment from contaminants, but such benefits can also have
unintended consequences, such as adverse impacts to other functions of the environment (e.g.,
destruction of habitat) or create other forms of risk (e.g., contamination of other environmental
media). These tradeoffs between existing and future environmental services necessitate a
transparent and systematic method to compare alternative actions and support the decision-
making process.
Structured frameworks or processes are commonly used to weigh evidence and support
requirements for environmental decision-making. Examples include:
 Environmental assessment (EA) and environmental impact statement (EIS)
process that supports National Environmental Policy Act requirements for
evaluating impacts from development projects and selecting mitigation
measures (40 CFR § 1502);
 Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA) remedial investigation/feasibility study process that characterizes
risk from contaminants at a site and then evaluates remediation alternatives
(U.S. EPA 1988);
 RCRA corrective measures study that supports identification, development,
and evaluation of potential remedial alternatives for corrective action (U.S.
EPA 1994);
 EPA’s causal analysis/diagnosis decision information system (CADDIS) that
supports stressor identification and selection of appropriate mitigation actions
under the Clean Water Act (Cormier et al. 2000);

1805955.000 - 1990 17
 NRDA that characterizes injury and lost human services to support selection
of restoration projects under a number of environmental laws, including
CERCLA and the Oil Pollution Act of 1990 (e.g., NOAA 1996); and
 NEBA that evaluates the tradeoffs in environmental impacts and benefits
from remediation alternatives (NOAA 1990; Efroymson et al. 2003, 2004).
These frameworks have different regulatory origins and somewhat different approaches to
accomplishing their specific objectives, but they all rely on a common core of analyses,
including characterization of exposures, identification of adverse effects, definition of complete
pathways between exposures and effects, characterization of risk or impact to exposed receptors
(i.e., human and ecological populations), and weight-of-evidence analysis.
My analyses in this matter have used a NEBA framework to compare the relative risks and
benefits derived from the closure options under consideration for the ash basin at MSS. NEBA
was originally developed to examine impacts and benefits to ecological resources and habitats
excluding impacts and risk to humans (Efroymson et al. 2004); however, as noted by EPA
(2009), remediation and closure actions can also have both direct and indirect consequences to
humans. To support a more thorough analysis of the net benefits of each closure option in this
matter, I have included comparative analyses in the NEBA that consider environmental health
more broadly, including risks and benefits to both ecological and human populations in the
vicinity. My analyses draw on the core principles of the environmental decision support
frameworks discussed above and follow a pragmatic and transparent process.
In assembling information for the NEBA and forming my conclusions, I have relied on analyses
reported in the CSA and CAP documents, as well as information provided by Duke Energy.
Because a NEBA of environmental health necessarily encompasses a variety of scientific
disciplines, I assembled a team of professionals within Exponent with expertise in ecological
risk assessment (ERA), human health risk assessment (HHRA), contaminant fate and transport,
decision support analysis, remediation, and statistics to review documents and, where indicated,
conduct analyses at my direction. The results of these efforts are included in this report and have
been reviewed by me.

1805955.000 - 1990 18
5.1 Net Environmental Benefit Analysis
Net environmental benefits are defined as, “the gains in environmental services or other
ecological properties attained by remediation or ecological restoration, minus the environmental
injuries caused by those actions” (Efroymson et al. 2003, 2004). Environmental services, or
ecosystem services, are ecological processes and functions that produce value to individuals or
society. A NEBA, as discussed above, is a structured framework for comparing impacts and
benefits to environmental services and support decision-making (Efroymson et al. 2003, 2004).
NEBA can be useful in evaluating and communicating the short-term and long-term impacts of
remedial alternatives but does not make a determination of which alternative is best; that
decision must be made by stakeholders and decision-makers and may ultimately involve
weighing or prioritizing some values or objectives over others (Efroymson et al. 2003, 2004).
NEBA relies on scientifically supported estimates of risk to compare the reduction of risk
associated with the chemicals of potential concern (COPCs)35 under different remediation and
closure alternatives alongside the creation of any risk during the remediation and closure,
providing an objective, scientifically structured foundation for weighing the tradeoffs among
remedial and closure alternatives. Despite the scientific basis of the risk characterization
process, however, stakeholders in any environmental decision-making scenario may place
different values on different types of risk. In other words, stakeholders may have different
priorities for the remediation and closure. NEBA does not, by design, elevate, or increase the
value of, any specific risk or benefit in the framework. The purpose of NEBA is to
simultaneously and systematically examine all tradeoffs that affect the services (e.g., provision
of safe drinking water, protection of biodiversity36) provided to humans and the ecosystem by
the environment under remediation and closure, allowing decision-makers to more fully
understand all potential benefits and risks of each alternative.

35 COPCs are “any physical, chemical, biological, or radiological substance found in air, water, soil or biological
matter that has a harmful effect on plants or animals”
(https://ofmpub.epa.gov/sor_internet/registry/termreg/searchandretrieve/glossariesandkeywordlists/search.do?de
tails=&glossaryName=Eco%20Risk%20Assessment%20Glossary).
36 Biodiversity is the variety of plants and animals present at a location. Protection of biodiversity refers to
provision of habitat and related functions capable of sustaining biological populations.

1805955.000 - 1990 19
EPA supports the use of NEBA (U.S. EPA 2009) as a means to compare remediation and
redevelopment alternatives “based on their contributions to human well-being.” EPA and the
National Oceanic and Atmospheric Administration (NOAA) also use NEBA to support oil spill
response decision-making (Robberson 2006; NOAA 1990). Examples of NEBA in oil-spill
decision-making include:
 Exxon Valdez Oil Spill: NEBA was first applied to weigh the net
environmental benefits of rock-washing to remove beached oil versus leaving
the oil in place to naturally degrade (NOAA 1990).
 Deepwater Horizon Oil Spill: NEBA was used by the Operational Science
Advisory Team-2 (OSAT-2) to “compare the environmental consequences of
the defined cleanup endpoints for the oil and beach types considered, and the
consequences of cleanup beyond those endpoints,” specifically noting, “It is
at this juncture that the concept of continued remedial efforts doing ‘more
harm than good’ becomes a concern” (OSAT 2011).
I have personally applied NEBA to evaluate the net environmental benefits associated with two
alternative sediment remediation cleanup goals for lead contamination in a tidal river. At that
site, the river had been contaminated with lead from a battery manufacturing facility, and the
state required removal of contaminated sediment that could potentially pose a health risk to
people and the environment. The responsible party conducted human and ecological risk
assessments, toxicity tests, and benthic community analyses to support the selection of an
appropriate cleanup threshold for lead that would be protective of humans and the natural
environment. Uncertainty in the results, however, led to two different remediation threshold
concentrations being proposed by the state and by the responsible party. The NEBA was
conducted to examine the tradeoffs in environmental impacts associated with the two cleanup
thresholds. For one segment of the river, the footprint of remediation, including the size and
types of habitat impacted, was substantially different under the alternative cleanup goals. The
lower remediation threshold caused much greater impacts to submerged aquatic vegetation and
riparian (shoreline) habitat that had cascading consequences to animals that rely on those
environments. NEBA was able to demonstrate that remediation to the lower threshold would
cause greater ecological harm and disturbance to the local community with little or no decrease

1805955.000 - 1990 20
in risk to benthic invertebrates (the ecological receptor at issue).37 Consequently, the higher
remediation goal was applied to that segment of the river.
These examples of NEBA are particularly relevant to the issues at Marshall. Remediation and
closure of coal ash basins is specifically addressed in CAMA and the CCR Rule, and both CIP
and excavation closure satisfy defined cleanup endpoints. At issue is whether removal of the
coal ash under an excavation closure crosses the “juncture,” as noted by OSAT-2, where the
action would do more harm than good (OSAT 2011).
5.2 Linking Stakeholder Concerns to NEBA
To better understand stakeholder concerns related to closure of the ash basin at MSS, I reviewed
written communications about ash basin closure plans for MSS submitted to and summarized by
NCDEQ (2016). From this review, I identified the following categories of stakeholder concerns:
 Drinking water quality
 Groundwater quality
 Surface water quality
 Fish and wildlife
 Maintaining property value
 Preservation of natural beauty
 Recreational value
 Swimming safety
 Failure of the ash impoundment
 Risk created by the closure option outweighing risk from contamination.
The primary concerns expressed by community stakeholders involve perceived risks from
exposure to CCR constituents that could negatively affect environmental services that benefit
the community: provision of safe drinking water and food, safe recreational enjoyment (e.g.,
hunting, fishing, swimming), protection of natural beauty, and biodiversity. Potential hazards to

37 Both remediation goals were found to be protective of human, fish, bird, and mammal health. Uncertainty in
toxicity test results and concern for protection of benthic macroinvertebrates (e.g., insect larvae and
crustaceans) led the state to propose a lower remediation threshold for lead.

1805955.000 - 1990 21
the community associated with closure activities include physical disturbance of existing
habitats; air pollution from diesel emissions; and traffic, noise, and accidents that could result in
property damage, injuries, and fatalities. Table 5-1 links concerns over CCR exposure and
potential hazards created by ash basin closure to environmental services that could be affected
by closure activities.

1805955.000 - 1990
22
Table 5-1. Relationships between environmental services and concerns to the local community associated with CCR
and ash basin closure hazards
Environmental Services
Safe drinking
water quality
Safe surface
water quality
Safe air
quality
Safe food
quality
Protection of
biodiversity
Recreation Natural
beauty
Safe community
environment
CCR Concerns
Drinking water
contamination
X X X
Groundwater contamination X X X
Surface water
contamination
X X X X X X X
Fish/wildlife contamination X X X X X
Contamination impacting
property value
X X X X X X X
Contamination impacting
natural beauty
X X X
Contamination impacting
recreational enjoyment
X X X X X
Contamination impacting
swimming safety
X X X X
Failure of the ash
impoundment
X X X X X X X
Closure Hazards
Habitat alteration X X X X X
Contamination of air X X X X
Noise, Traffic, Accidents X X

1805955.000 - 1990 23
In recognition of the potential discrepancy between stakeholder priorities and the broad and
balanced treatment of service risks and benefits in NEBA, I organized the NEBA in this matter
around the following five objectives for ash basin closure that recognize stakeholder concerns
while being consistent with the methods and purpose of NEBA:
1. Protect human health from CCR constituent exposure
2. Protect ecological health from CCR constituent exposure
3. Minimize risk and disturbance to humans from closure
4. Minimize risk and disturbance to the local environment from closure
5. Maximize local environmental services.
Associations between environmental services to the local community that could be potentially
impacted by ash basin closure and the identified objectives of ash basin remediation are shown
in Table 5-2.
Table 5-2. Associations between objectives for closure and remediation of the
Marshall ash basins and environmental services
Ash Basin Closure Objectives
Environmental
Services
Protect
human health
from CCR
constituent
exposure
Protect
ecological health
from CCR
constituent
exposure
Minimize risk
and
disturbance
to humans
from closure
Minimize risk
and disturbance
to the local
environment
from closure
Maximize local
environmental
services
Safe drinking
water quality X X X
Safe surface
water quality X X X
Safe air quality X X
Safe food quality X X X
Recreation X X
Natural beauty X X X
Protection of
biodiversity X X X
Safe community
environment X X

1805955.000 - 1990 24
NEBA relies on comparative metrics for specific attributes of the environment to examine the
potential impacts and benefits from remediation and closure alternatives (Efroymson et al. 2003,
2004). NEBA methodology is not, however, prescriptive in defining attributes or comparative
metrics because each application of NEBA is unique to contaminant exposure, remediation and
closure alternatives, available data, and stakeholder concerns. NEBA is an extension of the risk
assessment process (Efroymson et al. 2004). As a result, receptors, exposure pathways, and risks
identified in a site risk assessment are key inputs to a NEBA. The links between key
environmental services, attributes that represent those services, and comparative metrics used in
this NEBA are summarized in Table 5-3.
Table 5-3. Matrix of key environmental services, attributes, and comparative metrics
applied in the NEBA
Attributes
Environmental Services Human Health
Risk
Ecological Health
Risk
Net Primary
Productivity
Transportation
Metrics
Safe ground water quality HI/ELCR -- --
Safe surface water quality HI/ELCR HQ
Safe soil and sediment quality HI/ELCR HQ --
Safe air quality HI/ELCR -- --
Safe food quality HI/ELCR HQ --
Protection of biodiversity HQ DSAYs
Recreation HI/ELCRa -- DSAYs
Natural beauty HQ DSAYs
Safe community environment -- Trucking
Logistics
Notes:
DSAYs – discounted service acre-years
ELCR – excess lifetime cancer risk
HI – hazard index
HQ – hazard quotient
a Estimated from health risks from consumption of fish.
I used human health attributes (e.g., risk to onsite construction workers, risk to offsite
swimmers) and risk quotients (hazard index [HI], excess lifetime cancer risk [ELCR]) to
evaluate whether there would be a potential impact to environmental services related to safe
water, air, and food under the ash basin closure options. I also used human health attributes to
evaluate whether there would be an impact to air quality during closure activities. I used

1805955.000 - 1990 25
ecological health attributes (e.g., risk to birds, mammals) and risk quotients (hazard quotient
[HQ]) to evaluate whether there would be a potential impact to environmental services related to
safe surface water and food and protection of biodiversity and natural beauty under the ash basin
closure options. I evaluated risk and disturbance associated with traffic and accidents using
transportation metrics and trucking logistics (e.g., number of truck miles driven) associated with
each closure option to evaluate impacts to community safety. I used net primary productivity
(NPP)38 and discounted service acre-years (DSAYs)39 to characterize differences in the
environmental services that derive from habitats (e.g., protection of biodiversity, natural beauty)
and that would be impacted by ash basin closure activities. Finally, I assembled all attributes,
services, and objectives within a full NEBA to examine which of the closure options best
maximizes environmental services to the local community. These metrics represent
scientifically appropriate and commonly applied metrics to evaluate risk to humans and the
environment (U.S. EPA 1989, 1997, 2000b; NHTSA 2016) and to quantitatively measure
differences in environmental services associated with impact and restoration (Dunford et al.
2004; Desvousges et al. 2018; Penn undated; Efroymson et al. 2003, 2004).
Of note, my analysis did not consider the risks involved with on-site construction activities. For
example, I did not attempt to evaluate occupational accidents created by on-site construction
and excavation. Nor did I attempt to evaluate emissions associated with on-site construction
activities. Finally, I did not attempt to consider the risk created by disturbing the ash basin and
exposing it to the elements during excavation activities.
Some stakeholders also expressed concern over safety of the ash impoundment dam (NCDEQ
2016). The most recent dam safety report produced by Amec Foster Wheeler and submitted to
NCDEQ indicates “the construction, design, operation, and maintenance of the CCR surface

38 NPP represents the mass of chemically fixed carbon produced by a plant community during a given time
interval. It reflects the rate at which different ecosystems are able to sequester carbon, which is related to
mitigating climate change (https://earthobservatory.nasa.gov/GlobalMaps/view.php?d1=MOD17A2_M_PSN).
39 DSAYs are derived from habitat equivalency analysis (HEA). HEA is an assessment method that calculates
debits based on services lost and credits for services gained from a remediation action (Dunford et al. 2004;
Desvousges et al. 2018; Penn undated). A discount rate is used to standardize the different time intervals in
which the debits and credits occur, and in doing so, present the service debits and credits at present value. The
present value of the services is usually expressed in terms of discounted service acre-years of equivalent habitat,
or DSAYs, which provide a means to compare the different service levels of affected habitat acres (Dunford et
al. 2004; Desvousges et al. 2018; Penn undated).

1805955.000 - 1990 26
impoundments have been sufficiently consistent with recognized and generally accepted
engineering standards for protection of public safety and the environment” (Browning and
Thomas 2018).
5.3 NEBA Risk Ratings
NEBA organizes environmental hazard and benefit information into a unitless metric that
represents the degree and the duration of impact from a remediation and closure alternative
(Efroymson et al. 2003, 2004). One approach to structure this analysis is to create a risk-ranking
matrix that maps the proportional impact of a hazard (i.e., risk) with the duration of the impact
(Robberson 2006). The risk-ranking matrix used for this application of NEBA is provided in
Table 5-4. The matrix uses alphanumeric coding to indicate the severity of an impact: higher
numbers and higher letters (e.g., 8F) indicate a greater extent and a longer duration of impact,
respectively. Shading of cells within the matrix supports visualization of the magnitude of the
effect according to the extent and duration of an impact.40 When there is no meaningful risk, the
cell is not given an alphanumeric code. Risk ratings generated from the risk-ranking matrix for
each attribute and closure option examined were assembled into objective-specific summaries to
compare the net benefits of the closure options. All closure options in the NEBA were evaluated
against current conditions as a “baseline” for comparison.

40 Categories and shading as defined in the risk-ranking matrix are based on best professional judgment and used
for discussion of the relative differences in relative risk ratings. Alternative risk matrices and resulting NEBA
classifications are explored in Appendix E.

1805955.000 - 1990 27
Table 5-4. Risk-ranking matrix for impacts and risk from remediation and closure
activities. Darker shading/higher codes indicate greater impact

Duration of Impact (years)
>50
(8)
35–50
(7)
26–35
(6)
16–25
(5)
10–15
(4)
5–9
(3)
1–4
(2)
<1
(1) % Impact No meaningful risk -- -- -- -- -- -- -- --
<5 % (A) 8A 7A 6A 5A 4A 3A 2A 1A
5–19% (B) 8B 7B 6B 5B 4B 3B 2B 1B
20–39% (C) 8C 7C 6C 5C 4C 3C 2C 1C
40–59% (D) 8D 7D 6D 5D 4D 3D 2D 1D
60–79% (E) 8E 7E 6E 5E 4E 3E 2E 1E
>80% (F) 8F 7F 6F 5F 4F 3F 2F 1F
NEBA analysis of possible closure options for the ash basin at MSS helps both Duke Energy
and other stakeholders understand the net environmental benefits from the closure option
configurations that were examined. If a closure option that is preferred for reasons not
considered in the NEBA does not rate as one of the options that best maximizes environmental
services to the local community, closure plans for that option can be re-examined, and
opportunities to better maximize environmental benefits can be identified (e.g., including an
offsite habitat mitigation project to offset environmental services lost from habitat alteration).
The NEBA can then be re-run with the updated plan to compare the revised closure plan with
other closure options.
5.4 Risk Acceptability
Selecting any remediation, mitigation, restoration, or closure alternative involves considerations
of risk—risk posed by contamination in place, risk created by the action, risk remaining after the
action—and all of these risk considerations must be placed in some contextual framework if
informed decisions are to be made. Hunter and Fewtrell (2001) state, “The notion that there is
some level of risk that everyone will find acceptable is a difficult idea to reconcile and yet,
without such a baseline, how can it ever be possible to set guideline values and standards, given
that life can never be risk free?”

1805955.000 - 1990 28
EPA defines risk as “the chance of harmful effects to human health or to ecological systems
resulting from exposure to an environmental stressor” (U.S. EPA 2017a). In accordance with
EPA guidance for conducting ERAs (U.S. EPA 1997) and HHRAs (U.S. EPA 1989), risk to a
receptor (e.g., person, animal) exists when exposure to a stressor or stressors occur(s) at some
level of effect; however, because not all exposures produce adverse effects in humans or
ecological species, the exposure concentrations need to overlap with adverse effect thresholds
for there to be the potential for meaningful risk. The science supporting individual benchmarks
or levels of concern differs by the specific exposure at issue and the receptor at risk; however,
such benchmarks are considered by regulatory authorities to represent the best scientific
information available to create a baseline for risk (U.S. EPA 2017b).
The potential for risk associated with contamination is often evaluated using HQs, HIs, and
ELCRs to screen environmental media (e.g., water, soil) and identify the potential risk
associated with contamination (U.S. EPA 1989, 1997, 2000b). The HQ is the ratio of an
exposure point (EPC) concentration41 divided by an appropriate toxicity benchmark for the
receptor, chemical, and exposure scenario. An HI, which is used in HHRA, is the sum of the
HQs for several chemicals that share the same target organ. If the HQ or HI is less than 1,
exposure to that chemical (HQ) or group of chemicals (HI) is expected to result in no adverse
effects to even the most sensitive receptors. Cancer risk to humans is typically evaluated using a
probabilistic approach that considers an acceptable risk benchmark range of 10-4 to 10-6,
meaning that a person’s ELCR from the exposure being assessed is less than 1 in 10,000 to 1 in
1,000,000 (U.S. EPA 1989, 2000b).
NEBA relies on scientifically supported estimates of risk; however, regardless of the scientific
acceptability of the risk characterization process, stakeholders may place different values on
different types of risk.

41 A conservative estimate of the chemical concentration available from a particular media and exposure pathway.

1805955.000 - 1990 29
6 Summary of Conclusions
Based on my review and analyses, I developed the following conclusions, which are structured
around the five objectives identified previously:
Conclusion 1: All closure options for the MSS ash basin are protective of human health.
Current conditions and conditions42 under all closure options support provision of safe drinking
water, safe surface water, safe food, and safe recreation, satisfying the first objective of ash
basin closure—to protect human health from CCR constituent exposure.
Conclusion 2: All closure options for the MSS ash basin are protective of ecological health.
Current conditions43 and conditions under all closure options support provision of safe surface
water, safe food consumption, and protection of biodiversity and natural beauty, satisfying the
second objective of ash basin closure—to protect ecological health from CCR constituent
exposure.
Conclusion 3: CIP and hybrid closure options limit the duration of community
disturbance. All closure options support safe air quality from diesel truck emissions along the
transportation routes, and each creates comparable levels of disturbance and risk that could
adversely impact community safety on a daily or annual basis; however, these impacts occur for
a substantially longer period under the excavation closure option (28 years for excavation
closure compared to 13 and 12 years for CIP and hybrid closures, respectively). Thus, CIP and
hybrid closure options better satisfy the third objective of ash basin closure—to minimize risk
and disturbance to humans from closure.

42 SynTerra’s updated HHRA considered only potential exposure pathways that currently exist and could remain
after ash basin closure under any closure option. Any potential risk currently associated with seeps at MSS was not
evaluated in the HHRA or considered in this analysis because any risk resulting from seeps will be eliminated,
reduced, or mitigated per the court-enforceable SOC that Duke entered with the North Carolina Environmental
Management Commission on April 18, 2018 (EMC SOC WQ S17-009; See Section 4.2).
43 SynTerra’s updated ERA considered only potential exposure pathways that currently exist and could remain after
ash basin closure under any closure option. Any potential risk currently associated with seeps at MSS was not
evaluated in the ERA or considered in this analysis because any risk resulting from seeps will be eliminated,
reduced, or mitigated per the court-enforceable SOC that Duke entered with the North Carolina Environmental
Management Commission on April 18, 2018 (EMC SOC WQ S17-009; See Section 4.2).

1805955.000 - 1990 30
Conclusion 4: All closure options for the MSS ash basin create environmental disturbance.
All closure options adversely impact habitat-derived environmental services, with hybrid
closure creating the least NPP service loss and best satisfying the fourth objective of ash basin
closure—to minimize risk and disturbance to the local environment from closure.
Conclusion 5: Hybrid closure maximizes environmental services. The hybrid closure option
best maximizes environmental benefits compared to the excavation and CIP closure options
because it offers equivalent protection of human and ecological health from CCR exposure,
results in less disturbance to the community over time compared to excavation closure, and
produces the least disturbance to the environment.44 Thus, hybrid closure best satisfies the fifth
objective of ash basin closure—to maximize local environmental services.
Each will be discussed in detail in the following sections.

44 As noted in Section 5 and further discussed in Section 11, the loss of habitat-derived environmental services
could be offset with an appropriate reforestation project.

1805955.000 - 1990 31
7 Conclusion 1: All closure options for the MSS ash
basin are protective of human health.
The first objective for ash basin closure, to protect human health from CCR constituent
exposure, is represented by environmental services that provide safe drinking water, safe
groundwater, safe surface water, safe food consumption, and safe recreation. For purposes of the
NEBA, these safety considerations were evaluated based on the following:
1. Provision of permanent alternative drinking water supplies to private well
water supply users within a 0.5-mile radius of the MSS ash basin
compliance boundary (Holman 2018);
2. Concentrations of CCR constituents of interest (COIs) in drinking water
wells that could potentially affect local residents and visitors, as
characterized by HDR (2015a, 2016b) and SynTerra (2018a) in the
Comprehensive Site Assessment (CSA); and
3. Risk to various human populations from CCR exposure, as characterized
in the updated human health and ecological risk assessment conducted by
SynTerra (2018b; Appendix B).
Through these lines of evidence, I evaluated whether CCR constituents are currently impacting
drinking water wells, whether they will in the future, and whether other exposures to CCR
constituents pose a risk to human populations now or with ash basin closure.
7.1 Private water supply wells pose no meaningful risk to the
community around MSS.
Per H.B. 630, Sess. L. 2016-95, all residents with drinking water supply wells within a 0.5-mile
radius of the MSS ash basin compliance boundary have been provided with permanent
alternative drinking water supplies (i.e., filter systems or connection to public drinking water

1805955.000 - 1990 32
supplies; Draovitch 2018),45 eliminating drinking water as a potential CCR exposure pathway
for local residents or visitors
Additionally, the available data indicate that public and private well water conditions are not
impacted by CCR constituents and that groundwater flow paths from the ash basin are generally
away from residential areas (SynTerra 2018a; HB630 Residential Well Data - Sept 24
2018.xlsx).
According to the 2018 CSA, four public wells are within a 0.5-mile radius of the ash basin,
three of which are likely currently in use (SynTerra 2018a). These wells are likely not impacted
by CCR COIs as groundwater does not flow from the ash basin toward the wells, and the 2018
CSA found no evidence of risk to users of any of the public wells (SynTerra 2018a).
Fifty-seven private wells have been identified within a 0.5-mile radius of the ash basin
compliance boundary, and 17 others were assumed to be present at residences within the same
radius (SynTerra 2018a). Based on the available data, groundwater does not generally flow from
the ash basin compliance boundary toward the private wells. A few possible exceptions can be
found to the southwest of the site’s compliance boundary, along Sherrills Ford Road; however,
the chemistry data for the two wells sampled in this area showed no evidence of CCR impacts.
The only parameters exceeding North Carolina Groundwater Quality Standards (2L)46 in these
wells (MR47 and MR1004) were pH and vanadium, both of which commonly exceeded 2L in
the other private wells sampled (see below). Boron, an indicator of CCR impacts, was below the
provisional background threshold value (PBTV) in both wells (Marshall_Comprehensive All
Media thru 2018-06.xlsx).
Thirty-eight private wells were sampled by the NCDEQ in 2015, and 10 more wells were
sampled by Duke Energy in 2016 and 2017. All well concentration data were compared to
PBTVs for bedrock, 2L standards, or interim maximum allowable concentrations (IMACs)
(SynTerra 2018b). Several COIs exceeded 2L or IMAC levels, including vanadium (39 wells),

45 NCDEQ determined Duke Energy had satisfactorily completed the permanent alternative water provision under
CAMA General Statute (G.S.) 130A-309.21 l(cl) on October 12, 2108 (Holman 2018).
46 North Carolina Administrative code 15A NCAC 02L Groundwater Rules.

1805955.000 - 1990 33
pH (33), iron (5), manganese (2), total dissolved solids (1), and zinc (1). Importantly, however,
these COIs were generally below their respective PBTVs for bedrock (including vanadium in all
samples). Eleven COIs exceeded PBTVs in at least one sample, with the most frequently being
chloride (13 wells), cadmium (6 wells), and strontium (6 wells). Other PBTV exceedances were
sporadic. Constituents that were not identified as COIs at Marshall also exceeded bedrock
PBTVs in some samples. These included aluminum, calcium, hexavalent chromium, copper,
lead, sodium, and zinc (SynTerra 2018a). Exceedances of PBTVs do not by themselves
constitute evidence of CCR impacts. PBTVs were developed from a limited number of samples
at the site and may not provide a complete representation of natural background conditions in
the surrounding area encompassing the sampled wells (SynTerra 2018a). The lack of
exceedances for indicator COIs like boron supports the conclusion that private wells are not
impacted by CCR, and that sporadic PBTV exceedances for other COIs are the result of natural
variability or due to components used in well constructions (SynTerra 2018a). Based on
comparison to the downgradient groundwater and background conditions, the water in the
sampled private wells is consistent with background bedrock wells and reflects natural
background conditions (SynTerra 2018a). This conclusion is supported by the fact that
groundwater does not generally flow from the ash basin towards the private wells (SynTerra
2018a).
Since the sampling for the 2018 CSA, an additional 11 samples have been collected from 4
private wells not previously sampled (HB630 Residential Well Data - Sept 24 2018.xlsx). 2L
exceedances were detected for vanadium (in all 11 samples) and pH (in 2 samples). All samples
were below 2L and PBTV levels for both boron and sulfate. The frequency and magnitudes of
the exceedances were similar to those in the previous sampling campaigns and lend further
support to the conclusion that private well water chemistry is not impacted by CCR.
7.2 CCR constituents from the Marshall ash basin pose no
meaningful risk to human populations.
To assess potential risk to humans both onsite and offsite using the most recent and
comprehensive data available, SynTerra updated the HHRA (SynTerra 2018b) that was
originally conducted by HDR (2016c) as a component of the CAP part 2 (HDR 2016a). The

1805955.000 - 1990 34
updated HHRA included updates47 to the conceptual site model, EPCs for human receptors with
complete exposure pathways, screening level risk assessments for human receptors with
complete exposure pathways, and hazard calculations (HI, ELCR) for receptors and COPCs
with plausible complete exposure pathways.
Consistent with the 2016 Baseline Human Health and Ecological Risk Assessment (HDR
2016c), the updated HHRA (SynTerra 2018b) examined CCR constituent exposure to a range of
human populations, including construction workers; swimmers; waders; boaters; and
recreational and subsistence fishers under different pathways (i.e., exposure to sediment, surface
water, groundwater, or fish tissue). HIs and ELCRs were estimated for scenarios with plausible
complete exposure pathways.
Complete CCR exposure pathways evaluated in the updated HHRA included the following
(SynTerra 2018b):
 Onsite construction workers via groundwater48
 Offsite recreational swimmers via offsite surface water and sediment
 Offsite recreational waders via offsite surface water and sediment
 Offsite recreational boaters via offsite surface water
 Offsite recreational fishers via offsite surface water and fish tissue
 Offsite subsistence fishers via fish tissue.
Since all households with drinking water supply wells within a 0.5-mile radius of the MSS ash
basin compliance boundary have received permanent alternative water supplies (Holman 2018),
and since no potable water wells are located downgradient of MSS, drinking water risks from
groundwater were not further evaluated because there is no complete exposure pathway
(SynTerra 2018b).

47 Updates to risk assessments are a natural part of the risk analysis pro cess. EPA guidance for ecological risk
assessment notes, “The [risk assessment] process is more often iterative than linear, since the evaluation of new
data or information may require revisiting a part of the process or conducting a new assessment As more
information about a site is gained through site investigations, the risk assessment must be updated to reflect the
best knowledge of potential risk at a site” (U.S. EPA 1998). EPA similarly describes human health risk
characterization as an iterative process (U.S. EPA 2000b).
48 Groundwater exposure to onsite construction workers was evaluated in the updated HHRA, though a pathway
for exposure was considered incomplete by SynTerra (2018b).

1805955.000 - 1990 35
A summary of the risk assessment results from the updated HHRA (SynTerra 2018b) is
provided in Table 7-1.
Table 7-1. Summary of human health risk assessment hazard index (HI) and excess
lifetime cancer risk (ELCR) from SynTerra (2018b)
Media Receptor HI ELCR
Groundwater Construction Worker 0.001 NC
Sediment Recreational Swimmer 0.003 NC
Surface Water Recreational Swimmer 0.04 2.6×10-6
Sediment Recreational Wader 0.003 NC
Surface Water Recreational Wader 0.03 6.2×10-7
Surface Water Recreational Boater 0.002 5.3×10-8
Surface Water Recreational Fisher 0.002 5.3×10-8
Biota (fish) Recreational Fisher 2 3.8×10-6
Biota (fish) Subsistence Fisher 57 2.9×10-4
Notes:
NC – Risk-based concentration based on non-cancer HI.
The majority of exposure scenarios assessed by SynTerra (2018b) indicated that exposure to
CCR poses no meaningful risks to humans. The HI associated with recreational fishers and the
HI and ELCR associated with subsistence fishers were, however, estimated by SynTerra
(2018b) to be greater than 1 and 1×10-4, respectively.
Risk assessment is subject to a number of uncertainties, including the representativeness of
sample data, the degree to which exposure assumptions approximate actual exposure, estimation
of chemical toxicity, and characterization of background concentrations. Risk assessment
typically addresses these uncertainties by including conservative assumptions that tend to
overestimate exposure and risk. For example, to evaluate potential risk to subsistence fishers in
the MSS HHRA, SynTerra (2018b) used a fish consumption rate of 170 g/day, which represents
the highest level of consumption (95th percentile) in a high consuming subsistence Native
American population living in an area with plentiful fish resources that can support such high
fish consumption (Columbia River Tribes in Oregon) (U.S. EPA 2000a, 2011a).49 SynTerra
(2018b) further assumes this rate of fish consumption would continue for many years using only

49 In the case of MSS, SynTerra has not identified any populations of subsistence fishers in the area.

1805955.000 - 1990 36
fish from a single water body with fish tissue COPC concentrations estimated using a
conservative uptake model (bioconcentration factors [BCFs]) from the highest surface water
COPC concentrations. Each exposure pathway in the HHRA uses similarly conservative
assumptions to address uncertainty. While this serves to ensure a health protective assessment,
results that exceed target risk levels should be examined in more depth to understand the
context. Therefore, I examined the foundation for each exceedance in more detail.
Risk to fishers was modeled by SynTerra (2018b) by estimating fish tissue concentrations from
surface water sample data. The cumulative HIs from these exposures, 2 for recreational fishers
and 57 for subsistence fishers, were driven by concentrations of cobalt. Similar risks were noted
previously in the baseline HHRA (HDR 2016c), and HDR (2016c) attributed this estimated risk
to the use of onsite surface water as a surrogate for offsite conditions as well as conservative
uptake assumptions and bioaccumulation models, which likely overestimate metals
concentrations in fish tissue. While SynTerra (2018) used offsite water data to update EPCs in
the updated HHRA, other conservative assumptions were retained by SynTerra (2018b). The
cumulative ELCR of 2.9×10-4 for subsistence fishers from these exposures was driven by
concentrations of chromium (VI). This risk was not identified in the previous HHRA (HDR
2016c), as more recent samples were included in the 2018 analysis.
Examining these COPCs individually, for cobalt, the EPA provisional oral reference dose (RfD)
of 0.3 µg/kg/day may be considered unnecessarily conservative.50 Other government agencies
have derived higher guidance values for cobalt, including the Dutch National Institute of Public
Health and the Environment (tolerable daily intake of 98 µg/day, or 1.4 µg/kg/day for a 70 kg
adult) and the European Food Safety Authority (EFSA) (600 µg/day, or 8.6 µg/kg/day) (Schoof
2017). A recent reanalysis of relevant human and animal studies involving oral exposure to
cobalt proposed a new RfD for cobalt of 30 µg/kg/day, which is 100 times higher than what is
currently recommended by EPA (Finley et al. 2012; Schoof 2017). If the recent cobalt RfD
reported in Finley et al. (2012) were applied instead of the current EPA RfD for cobalt, the HIs
for cobalt exposure to recreational and subsistence fishers would be 0.02 and 0.57, respectively.

50 The RfD is an estimate of a daily exposure to the human population that is likely to be without an appreciable
risk of deleterious effects during a lifetime. The cobalt RfD was developed in 2008 (U.S. EPA 20 08).

1805955.000 - 1990 37
SynTerra (2018) notes that concentrations of cobalt in background samples were of the same
order of magnitude as the EPC used in risk calculations and would predict a comparable
background level of risk unassociated with CCR exposure. Given the conservative use of a BCF
to estimate fish tissue concentration and the low likelihood that the water body would be used as
a sole subsistence fish source, I conclude there is no meaningful risk to recreational or
subsistence fishers from exposure to cobalt.
For chromium (VI), the ELCR of 2.9×10-4 is less than an order of magnitude above the upper
end of EPA’s target ELCR range of 10-6 to 10-4 (U.S. EPA 1989, 2000a). This ELCR was
determined using a BCF for chromium (VI) of 200, based on a 1996 report from the National
Council on Radiation Protection and Management (NCRP 1996). However, a more recent
review by the Office of Environmental Health Hazzard Assessment (OEHHA, a part of the
California EPA) evaluated chromium uptake in fish and derived a lower BCF for chromium
based primarily on studies of chromium (VI). OEHHA (2012) states that chromium (VI) is not
well taken up into edible fish tissue and recommends a BCF of 20 (OEHHA 2012). Had a BCF
of 20 been used, the resulting ELCR would be 2.9×10-5, within EPA’s range of acceptable risk.
Synterra (2018) also notes that concentrations of chromium in background samples were as
much as four times higher than the EPC used in risk calculations, and would predict a
comparable level of risk unassociated with CCR exposure. Based on the conservative uptake
assumptions and bioaccumulation factors used in this model, and the very limited exceedance of
acceptable ELCR, I conclude there is no meaningful risk to subsistence fishers from exposure to
chromium (VI).
Given the lack of meaningful risk under current conditions,51 there is also no meaningful risk to
humans from CCR exposure under any of the ash basin closure options since all options reduce
or eliminate exposure pathways following closure. Thus, all closure options are protective of
public health.

51 SynTerra’s updated HHRA considered only potential exposure pathways that currently exist and could remain
after ash basin closure under any closure option. Any potential risk currently associated with seeps at MSS was not
evaluated in the HHRA or considered in this analysis because any risk resulting from seeps will be eliminated,
reduced, or mitigated per the court-enforceable SOC that Duke entered with the North Carolina Environmental
Management Commission on April 18, 2018 (EMC SOC WQ S17-009; See Section 4.2).

1805955.000 - 1990 38
7.3 NEBA – Protection of Human Health from CCR Exposure
There is no CCR risk from drinking water supplies, no evidence of CCR impacts to drinking
water wells, and no meaningful risk to humans from CCR exposure under current conditions or
under any closure option. Using the NEBA framework and relative risk ratings, these results are
summarized in Table 7-2 within the objective of protecting human health from CCR constituent
exposure.
Table 7-2. Summary of relative risk ratings for attributes that characterize potential
hazards to humans from CCR exposure in drinking water, surface water,
groundwater, soil, sediment, food, and through recreation
Objective Protect Human Health from CCR
Hazard Exposure to CCR Potentially Affected Populations Local Residents/Visitors Onsite Construction Workers Offsite Recreational Swimmers Offsite Recreational Waders Offsite Recreational Boaters Offsite Recreational Fishers Offsite Subsistence Fishers Scenario
Baseline -- -- -- -- -- -- --
CIP -- -- -- -- -- -- --
Excavation -- -- -- -- -- -- --
Hybrid -- -- -- -- -- -- --
“--” indicates “no meaningful risk.”
Current conditions and conditions under all closure options support provision of safe drinking
water, safe surface water, safe food, and safe recreation, satisfying the first objective of ash
basin closure—to protect human health from CCR constituent exposure.

1805955.000 - 1990 39
8 Conclusion 2: All closure options for the MSS ash
basin are protective of ecological health.
The second objective for ash basin closure, to protect ecological health from CCR constituent
exposure, is represented by environmental services that provide safe surface water, safe food
consumption, and protection of biodiversity and natural beauty. For purposes of the NEBA,
these considerations were evaluated based on the following:
1. Risk to ecological receptors from CCR exposure, as characterized by
SynTerra (2018b; Appendix B) in the updated human health and ecological
risk assessment; and
2. Aquatic community health in Lake Norman as reported in the Lake Norman
Maintenance Monitoring Program summary report for 2016 (Duke Energy
2018a).
Through these two lines of evidence, I evaluated whether CCR constituents pose a risk to
ecological populations now or after ash basin closure.
8.1 No meaningful risks to ecological receptors from CCR
exposure exist under current conditions or any closure
option.
To assess potential risk to ecological receptors both on-site and off-site using the most recent
and comprehensive data available, SynTerra (2018b) updated the Baseline Human Health and
Ecological Risk Assessment that was originally conducted by HDR (2016c) as a component of
the CAP part 2 (HDR 2016a). The updated ERA included updates to the conceptual site model,
EPCs for receptors with potentially complete exposure pathways, and screening level risk
assessments for ecological receptors with potentially complete exposure pathways. Updated
HQs were estimated for ecological receptors with plausible complete exposure pathways to
CCR related COPCs (SynTerra 2018b).
The ecological receptors evaluated in the ERA are common representatives of particular groups
of organisms inhabiting different habitats and aspects of the food web. Key receptors in

1805955.000 - 1990 40
SynTerra’s updated ERA (SynTerra 2018b) and their pathways for exposure included the
following:
 Birds: Avifauna species may be exposed by ingestion of food and surface
water and by incidental ingestion of sediment and soil. Aquatic/wetland
species included were mallard duck (omnivore) and great blue heron
(piscivore), and bald eagle (carnivore).52
 Mammals: Aquatic/wetland or terrestrial species may be exposed by
ingestion of food and surface water and by incidental ingestion of sediment
and soil. Aquatic/wetland species included were muskrat (omnivore) and
river otter (piscivore).
Ecological risk for these indicator species was characterized by SynTerra (2018b) using a risk-
based screening approach that compared exposure levels to toxicity references values (TRVs) to
calculate HQs for COPCs. TRVs in the ERA included no-observed-adverse-effects levels
(NOAELs)53 and lowest-observed-adverse-effects levels (LOAELs)54 derived from the literature
for each COPC.
HQ results for the site were evaluated for one exposure area at MSS55 (Figure 8-1). HQs less
than 1 indicate no meaningful risk to an ecological receptor species associated with exposure to
the COPCs evaluated.
 Exposure Area 1: All HQs <1, indicating no meaningful risk to receptors in
this area.

52 The bald eagle was added to this risk assessment model because the species is federally protected and represents
a raptor that preys upon fish, primarily, HQ calculations for the bald eagle include hypothetical consumption of
fish and terrestrial vertebrates that inhabit adjacent areas.
53 A NOAEL is a concentration below which no adverse effects have been observed for a specific receptor and
pathway of exposure. NOAELs are typically estimated from laboratory toxicity tests.
54 A LOAEL is a concentration associated with the lowest concentration level at which adverse effects have been
observed for a specific receptor and pathway of exposure. LOAELs are typically estimated from laboratory
toxicity tests.
55 The baseline ecological risk assessment conducted by HDR in 2016 (HDR 2016c) included two exposure areas.
Exposure Area 2, which is northwest of the ash basin, was not evaluated for the updated ERA becau se it was
considered representative of background conditions (SynTerra 2018b).

1805955.000 - 1990 41
Based on the updated ecological risk assessment (SynTerra 2018b), there are currently no
meaningful risks to ecological receptors associated with CCR exposure at MSS.
Additionally, the 2018 Lake Norman Maintenance Monitoring Program56 summary report for
2016 reported results from biological sampling (phytoplankton,57 zooplankton,58 fish) and water
chemistry analyses conducted in 2016 (Duke Energy 2018a). The report concluded that
phytoplankton and zooplankton density and diversity, and phytoplankton biomass were within
historical ranges in 2016 and represent a balanced indigenous community, with no discernable
impacts from Duke Energy operations (Duke Energy 2018a). The 2016 fishery data “indicate
that the Lake Norman fish community is balanced and is composed mostly of indigenous
species expected from a reservoir located in the NC piedmont,” with the proportions of pollution
tolerant fish species comparable throughout all zones in the lake and no indication of negative
effects as a result of Duke Energy operations (Duke Energy 2018).
Given the lack of meaningful ecological risk from CCR exposure under current conditions based
on the lines of evidence evaluated, all closure options would be protective of ecological
receptors since all closure options reduce or eliminate potential exposure pathways.

56 Duke Energy operates two power generation facilities on Lake Norman. MSS is located in the mid -lake region
of Lake Norman, and the McGuire Nuclear Station is located on the s outhern end of Lake Norman. Both
facilities have NPDES permitted discharges to the lake, and the Maintenance and Monitoring Program is an
annual lake-wide assessment of in-lake productivity, fish populations, and physicochemical characteristics of
the lake.
57 Phytoplankton are microscopic plants that require sunlight to grow and form the base of the aquatic food web.
58 Zooplankton are microscopic organisms that consume phytoplankton or other zooplankton and are a key
component of the aquatic food web,

1805955.000 - 1990
42
Figure 8-1. Exposure areas evaluated in the 2018 ecological risk assessment update (SynTerra 2018b)

1805955.000 - 1990 43
8.2 NEB A – Protection of Environmental Health from CCR
Exposure
Based on these analyses, no meaningful risk to ecological receptors from CCR exposure was
found under current conditions59 or under any closure option. Using the NEBA framework and
relative risk ratings, within the objective of protecting ecological health from exposure to CCR
constituents, these results are summarized in Table 8-1.
Table 8-1. Summary of relative risk ratings for attributes that characterize potential
hazards to ecological resources from CCR exposure in surface water, soil,
sediment, and food
Objective Protect Ecological Health
from CCR
Hazard Exposure to CCR Potentially Affected Populations Fish Populations Aquatic Omnivore Birds (mallard) Aquatic Piscivore Birds (great blue heron) Aquatic Carnivore Birds (bald eagle) Aquatic Herbivore Mammals (muskrat) Aquatic Piscivore Mammals (river otter) Scenario
Baseline -- -- -- -- -- --
CIP -- -- -- -- -- --
Excavation -- -- -- -- -- --
Hybrid -- -- -- -- -- --
“--” indicates “no meaningful risk.”
Current conditions and conditions under all closure options support provision of safe surface
water, safe food consumption, and protection of biodiversity and natural beauty, satisfying the

59 SynTerra’s updated ERA considered only potential exposure pathways that currently exist and could remain after
ash basin closure under any closure option. Any potential risk currently associated with seeps at MSS was not
evaluated in the ERA or considered in this analysis because any risk resulting from seeps will be eliminated,
reduced, or mitigated per the court-enforceable SOC that Duke entered with the North Carolina Environmental
Management Commission on April 18, 2018 (EMC SOC WQ S17-009; See Section 4.2).

1805955.000 - 1990 44
second objective of ash basin closure—to protect ecological health from CCR constituent
exposure.

1805955.000 - 1990 45
9 Conclusion 3: CIP and hybrid closure options limit
the duration of community disturbance.
The third objective for ash basin closure, to minimize risk and disturbance to humans from
closure, is represented by environmental services that provide safe air quality and a safe
community environment. For purposes of the NEBA, these considerations were evaluated based
on the following:
1. Health risks from diesel exhaust emissions to the community living and
working along transportation corridors during trucking operations to haul
materials to and from the ash basin, as evaluated through the application of
diesel truck air emissions modeling and HHRA; and
2. The relative risk for disturbance and accidents resulting from trucking
operations affecting residents living and working along transportation
corridors during construction operations, as evaluated by comparing the
relative differences in trucking operations between the closure options.
All closure options require increased trucking activity to haul materials to the site (e.g., transport
cap material to the ash basin). These activities involve the use of diesel-powered dump trucks,
which increase local diesel exhaust emissions and traffic, both of which present potential
hazards to local populations in the form of air pollution and roadway hazards. Table 9-1
summarizes the transportation logistics associated with each of the closure options Duke Energy
is considering for MSS (Duke Energy 2018b). From this summary, the amount of offsite
trucking involved is comparable between CIP and excavation closures, but excavation closure
requires more truckloads of cap and fill material and more miles driven.

1805955.000 - 1990 46
Table 9-1. Summary of offsite transportation logistics associated with each closure
option (Duke Energy 2018b)
Logistics CIP Excavation Hybrid
Closure Duration (years)a 15 32 15
Construction Duration (years)b 13 28 12
Offsite truckloads to haul cap & fill
materialc 20,582 29,303 20,459
Offsite miles driven to haul cap &
fill materialc 588,009 832,249 535,753
a Includes design and permitting, decanting, site preparation, construction, and site restoration.
b Includes site preparation, construction, and site restoration.
c Includes cover soil, top soil, and geosynthetic material.
Costs to society associated with trucking include accidents (fatalities, injuries, and property
damage), emissions (air pollution and greenhouse gases), noise, and the provision, operation,
and maintenance of public roads and bridges (Forkenbrock 1999). Generally, the magnitude of
these impacts scales with the frequency, duration, and intensity of trucking operations
(Forkenbrock 1999). Figure 9-1 illustrates the normalized differences between offsite
transportation activities under the excavation and hybrid options relative to CIP. From these
results, it is clear that risk and disturbance associated with transportation activities will be
relatively comparable between CIP and hybrid closure options. However, excavation closure has
a greater total potential for risk and disturbance from the increased number of offsite truckloads
and total miles driven; excavation closure also requires a substantially longer duration for
closure activities.

1805955.000 - 1990 47

Figure 9-1. Normalized differences between all offsite transportation
activities under CIP, excavation, and hybrid closure options.
Bars represent the relative activity of each closure option
compared to CIP.
9.1 There is no meaningful risk from diesel emissions to
people living and working along the transportation
corridor.
The types of large dump trucks that will be used in closure activities at MSS are generally diesel
powered, and diesel exhaust includes a variety of different particulates and gases, including
more than 40 toxic air contaminants.60 North Carolina does not have a diesel-specific health-
based toxicity threshold because diesel exhaust is not currently regulated as a toxic air pollutant.
North Carolina also does not regulate PM2.5 or PM1061 as toxic air pollutants. North Carolina
defers to EPA’s chronic non-cancer reference concentration (RfC) for diesel particulate matter
of 5 µg/m3 based on diesel engine exhaust to estimate risk from diesel emissions.62 California is,
to my knowledge, the only state that currently regulates diesel as a toxic air contaminant and has
identified both an inhalation non-cancer chronic reference exposure level (REL)63 of 5 µg/m3

60 https://oehha.ca.gov/air/health-effects-diesel-exhaust
61 PM2.5 and PM10 are airborne particulate matter sizes. PM2.5 is particulate matter that is 2.5 µm or less in size;
PM10 is particulate matter that is 10 µm or less in size.
62 Integrated Risk Information System (IRIS). U.S. EPA. Diesel engine exhaust.
63 A chronic REL is a concentration level (expressed in units of micrograms per cubic meter [µg/m3]) for
inhalation exposure at or below which no adverse health effects are anticipated following long -term exposure.

1805955.000 - 1990 48
and a range of inhalation potency factors indicating that a “reasonable estimate” for the
inhalation unit risk is 3.0×10-4 (µg/m3)-1 “until more definitive mechanisms of toxicity become
available” (OEHHA 2015). California bases the non-cancer and cancer health factors on the
whole (gas and particulate matter) diesel exhaust and uses PM10 as a surrogate measure.
As PM10 is the basis for both the non-cancer and inhalation risk factors for diesel exhaust
exposure in California, I relied on a PM10 exposure model to evaluate potential non-cancer and
cancer health risks from diesel exhaust.64
A representative segment of road was simulated using EPA’s AERMOD model65 to quantify air
concentrations at set distances away from the road (U.S. EPA 2016). Diesel truck emissions
were configured in the model in a manner consistent with the recommendations from EPA’s
Haul Road Working Group (U.S. EPA 2011b). The emission rate for diesel trucks was
calculated using the U.S. EPA Mobile Vehicle Emissions Simulator (MOVES) model (U.S.
EPA 2015).66 Emission factors were then applied to the average number of anticipated offsite
truck trips each year to define the average annual amount of diesel particulate matter emitted
along the representative road segment, and these exposures were then summed over seventy
years.67 AERMOD simulations were run for four transportation orientation directions and used
five years of local meteorological data to estimate EPCs at regular intervals from 10 to 150 m
perpendicular to either side of the road. The results of the model were translated into average
PM10 exposure (µg/m3) and excess cancer risk over a 70-year period using reasonable maximum

EPA has defined long-term exposure for these purposes as at least 12% of a lifetime, or about eight years for
humans.
64 California regulations and guidance indicate that when comparing whole diesel exhaust to speciated
components of diesel (e.g., polycyclic aromatic hydrocarbons, metals) the cancer risk from inhalation of whole
diesel exhaust will outweigh the multi-pathway analysis for speciated components.
65 AERMOD will calculate both the downwind transport and the dispersion of pollutants emitted from a source.
Both transport and dispersion are calculated based on the observed meteorology and characteristics of the
surrounding land. AERMOD is maintained by EPA and is the regulatory guideline model for short-range
applications (transport within 50 km).
66 The MOVES model allows a user to determine fleet average emission factors (in units of grams of pollutant per
mile traveled) for specific classes of vehicles and specific years. In this application, factors defined by MOVES
for single-unit short-haul diesel trucks were used.
67 For the cancer risk analysis, emissions were calculated as an average over the regulatory default 70-year
residential exposure duration. If the truck activity for a closure option occurs over a shorter period, the duration
of the truck activity exposure is factored into the 70-year averaging time (OEHHA 2015).

1805955.000 - 1990 49
exposure.68 Results of the exposure modeling are provided in Table 9-2. Full results and a more
detailed description of the model are provided in Appendix C.
Table 9-2. Hazard indices (HI) and excess lifetime cancer risk (ELCR) from exposure
to diesel exhaust emissions along transportation corridors in northern
North Carolina. Results are for the maximum exposures modeled.
Perpendicular
distance to road
CIP

Excavation

Hybrid
ELCR HI ELCR HI ELCR HI
10 m 4.59E-09 0.0000

3.78E-09 0.0000

4.11E-09 0.0000
20 m 3.95E-09 0.0000

3.25E-09 0.0000

3.54E-09 0.0000
30 m 3.07E-09 0.0000

2.53E-09 0.0000

2.75E-09 0.0000
40 m 2.55E-09 0.0000

2.10E-09 0.0000

2.28E-09 0.0000
50 m 2.17E-09 0.0000

1.78E-09 0.0000

1.94E-09 0.0000
60 m 1.88E-09 0.0000

1.55E-09 0.0000

1.69E-09 0.0000
70 m 1.66E-09 0.0000

1.37E-09 0.0000

1.49E-09 0.0000
80 m 1.49E-09 0.0000

1.22E-09 0.0000

1.33E-09 0.0000
90 m 1.34E-09 0.0000

1.10E-09 0.0000

1.20E-09 0.0000
100 m 1.22E-09 0.0000

1.00E-09 0.0000

1.09E-09 0.0000
110 m 1.12E-09 0.0000

9.19E-10 0.0000

1.00E-09 0.0000
120 m 1.03E-09 0.0000

8.47E-10 0.0000

9.23E-10 0.0000
130 m 9.54E-10 0.0000

7.85E-10 0.0000

8.54E-10 0.0000
140 m 8.87E-10 0.0000

7.30E-10 0.0000

7.95E-10 0.0000
150 m 8.28E-10 0.0000 6.81E-10 0.0000 7.42E-10 0.0000
Based on the assumptions applied in the air model, no meaningful risk from diesel emissions
associated with ash basin closure trucking operations was identified for people living and
working along the transportation corridor. The exposure model and risk assessment applied here
represent a simple approach to estimate risk. A more refined estimate of risk could be computed
with a more sophisticated air and risk model; however, it is unlikely to change the conclusion
that there is no meaningful risk to people living and working along the transportation corridor
from diesel emissions associated with ash basin closure construction operations.

68 Long-term exposure was incorporated into the air simulation as the average exposure given estimated trucking
rates for 12 hours per day—7am to 7 pm—6 days a week for the duration of the project trucking time.

1805955.000 - 1990 50
9.2 All closure options produce comparable risk and
disturbance from transportation activities on a daily or
annual basis, but excavation closure produces these
impacts for substantially longer than CIP or hybrid
closures.
Increased trucking increases noise and traffic congestion and creates a statistically based risk for
increased traffic accidents that could result in fatalities, injuries, and/or property damage
(Forkenbrock 1999; NHTSA 2016). MSS is located on a peninsula of Lake Norman and the
region consists primarily of sparse lakeside communities and rural forest and farmland. North
Carolina Highway 150 transects the peninsula immediately south of MSS providing the only
east-west bridge crossing of Lake Norman. There will be an increase in trucking traffic hauling
topsoil and/or geosynthetic material under all closure options along this corridor, with a
statistically increased likelihood of traffic accidents (NHTSA 2016). These accidents and
associated risks to life, health, and property will generally scale with the frequency and duration
of trucking in the region, total number of truckloads, number of roundtrip truck trips per day,
and duration of the closure.
For purposes of the NEBA, two attributes of offsite truck traffic that create disturbance to local
communities were considered: (1) noise and congestion and (2) accidents. Noise and congestion
were evaluated by comparing the number of times a construction truck would be expected to
pass a given location along the transportation corridor during closure construction activities, and
the difference in the likelihood of traffic accidents between the closure options was assumed to
be a function of the number of offsite road miles driven by construction trucks (NHTSA 2016).
9.2.1 Noise and Congestion
Regardless of the option, closure of the ash basin at MSS will result in an increased number of
large trucks69 on local roads (Table 9-1). Noise from these trucks includes engine and braking
noise, which can be disruptive to the communities through which they are passing,70 and trucks

69 Twenty-ton dump trucks, or similar vehicles for bulk transport, are assumed to be the primary vehicles that will
be involved in transporting materials during closure construction activities.
70 A typical construction dump truck noise level is approximately 88 decibels 50 ft. from the truck.
(https://www.fhwa.dot.gov/ENVIRONMENT/noise/construction_noise/handbook/handbook09.cfm)

1805955.000 - 1990 51
frequently passing through rural communities may pose additional disturbance from roadway
congestion. To compare the disturbance of trucking noise and congestion between closure
options, I used the average daily number of truck passes for trucks carrying earthen fill and
geosynthetic material to the construction site (Table 9-1). The number of passes of trucks
hauling ash from the ash basin to the landfill was not considered because these trucks do not
leave MSS. For the CIP option, it is estimated that a total of 41,164 truck passes would occur at
locations along the transportation corridor within 11 miles of the facility over the 13-month
course of trucking activities, for an average of 11 passes per day, or about one truck every hour,
assuming a 10-hour work day71. The excavation option has 58,605 total truck passes and
averages 7 truck passes per day for 28 months, or one truck every 90 minutes. For the hybrid
option, there would be 40,919 total truck passes hauling cover material along the transportation
corridor for 12 months for an average of 11 passes per day, or one truck every hour. These
results and their relative differences (as the ratio to CIP closure) are summarized in Table 9-3.
9.2.2 Traffic Accidents
Traffic accidents are assumed to be a function of the total number of offsite road miles driven by
construction trucks (NHTSA 2016). As with noise and congestion, only the miles driven hauling
earthen fill and cap materials were considered because ash-hauling vehicles will not leave MSS.
CIP closure requires a total of approximately 588,000 miles of driving; excavation closure
requires approximately 832,000 miles of driving; and hybrid closure requires approximately
536,000 miles of driving. The difference in distances driven between the hybrid and excavation
option is equivalent to twelve trips around the earth. Table 9-3 summarizes the results for all
disturbances considered.

71 All closure option assume 10-hour work days, 6-day work weeks, and 26 working days per month.

1805955.000 - 1990 52
Table 9-3. Comparative metrics for increased noise and congestion and traffic
accidents

Months of
trucking
Noise and congestion Traffic Accidents
Average truck
passes per day
Ratio to
CIP Total offsite
road miles driven Ratio to CIP
CIP 150 11 1 588,009 1
Excavation 335 7 0.64 832,249 1.4
Hybrid 138 11 1.1 535,753 0.9
9.3 NEB A – Minimize Human Disturbance
From these analyses, no meaningful health risk is expected from diesel exhaust emissions under
any closure option, but all the closure options are expected to produce different levels of
community disturbance in the form of noise and traffic congestion and risk from traffic
accidents.
I used the number of trucks per day passing72 a receptor along a near-site transportation corridor
to examine the differences in noise and traffic congestion under the closure options. I compared
the increase in the average number of trucks hauling earthen fill, geosynthetic material, and
other materials under the closure options to the current number of truck passes for the same
receptor. I specified a baseline, or current, level of truck passes on the transportation corridor,
and the number of truck passes per day under the closure options derive directly from the
trucking projections and implementation schedules provided by Duke Energy (2018b).
A baseline estimate of trucking passes per day for transportation corridors near MSS was
derived from North Carolina Department of Transportation (NCDOT) data of annual average
daily traffic (AADT) at thousands of locations across the state73 and the proportion of road miles

72 Truck passes per day is calculated as the total number of loads required to transport earthen fill, geosynthetic
material, and other materials multiplied by two to account for return trips. The resulting total number of passes
is then divided evenly among the total number of months of trucking time multiplied by 26 working days per
month.
73 Annual average daily traffic (AADT) values are derived from counts of axle pairs in every lane travel ling in
both directions using a pneumatic tube counter. At each monitoring station, raw data are collected for two days,
and these raw counts are adjusted using axle and seasonal correction factors to estimate the AADT. AADT

1805955.000 - 1990 53
driven by large trucks in Catawba County.74 Based on the assumed 153-trucks-per-day baseline
level and the number of truck trips per day from Duke Energy’s projections, all options would
have a less than 10% impact (CIP = 7%, excavation = 4%, hybrid = 7%) on noise and
congestion. I input these percent impacts to the risk-ranking matrix (Table 5-4) along with the
total duration of trucking activities (13 years CIP; 28 years excavation; 12 years hybrid) to
evaluate which of the closure options best minimizes human disturbances (Table 9-4).
I evaluated risk from traffic accidents by comparing the average number of annual offsite road
miles driven between closure options relative to a baseline estimate of the current road miles
driven.75 I chose a baseline of 129 million annual road miles for Catawba County, North
Carolina, based on the reported total vehicle miles traveled in Catawba County (NCDMV 2017)
multiplied by the county average 6.6% contribution of trucks to total AADT (NCDOT 2015). I
used the increase in truck miles driven over baseline in the closure options as a surrogate for the
potential increase in traffic accidents.
Using the 129-million-truck-miles baseline assumption, CIP has a 0.04% impact; excavation has
a 0.02% impact; and hybrid closure has a 0.04% impact. All closure options have a relative risk
rating of <5%. These relative risk ratings appear to be insensitive to lower assumed baseline
annual truck miles (see Appendix E for sensitivity analysis); reducing the baseline assumption
to the statewide minimum number of truck miles driven per year (6.2 million miles in Hyde
County) does not increase the expected percent impact for any option above 1% or increase the
relative risk rating and, by extension, the risk of traffic accidents. Results are summarized in the
NEBA framework (Table 9-4) within the objective of minimizing disturbance to humans during
closure.

results are compared to historical values at the same location and values at nearby stations to provide temporal
and spatial quality assurance. AADT data and a mapping application user interface are available online
(http://ncdot.maps.arcgis.com/apps/webappviewer/index.html?id=5f6fe58c1d90482ab9107ccc03026280 )
74 A value of 2,300 AADT was chosen as a baseline value for all vehicle traffic by identifying potential
transportation routes to and from the MSS ash basin and selecting the AADT station along the route that
currently has the lowest traffic and would experience the greatest proportional increase in trucking traffic from
ash basin closure. The baseline AADT value (2,300) was then multiplied by the county average of large truck
traffic volume (6.6%) to derive an estimated 153 passes per day along the most sensitive portion of the
transportation corridor to and from MSS (Appendix E).
75 The difference of baseline miles and closure option miles was divided by the baseline miles and multiplied by
100 to get a percent impact.

1805955.000 - 1990 54
Table 9-4. Summary of relative risk ratings for attributes that characterize
potential hazards to communities during remediation activities.
Darker shading and higher codes indicate greater impact.
Objective Minimize Human Disturbance
Hazard Noise and Traffic
Congestion
Traffic
Accidents
Air
Pollution Potentially Affected Populations Local Residents/Visitors Local Residents/Visitors Reasonable Maximum Exposure Scenario Baseline baseline baseline baseline
CIP 4B 4A --
Excavation 6A 6A --
Hybrid 4B 4A
“--” indicates “no meaningful risk.”
All closure options create some level of risk and disturbance to human populations. While the
excavation closure option produces comparable impacts to CIP and hybrid closures on a daily or
annual basis (risk rating of A)76, the impacts occur for more than twice as long as those for CIP
or hybrid closure, resulting in a greater cumulative impact (risk rating 6 compared to 4) from

76 The “A” risk rating for excavation closure is based on an estimated <5% impact on noise and congestion, as
calculated from the estimated increase in the number of truck passes per day over baseline conditions. 5% is the
upper limit of the “A” risk rating category (see Table 5-3). CIP and hybrid closures are estimated to have a 7%
impact on noise and congestion, which is very close to the low limit of the “B” risk rating category (see Table
5-3) and functionally similar to the 4% risk for excavation closure for noise and traffic congestion on a daily
basis. Therefore, while the risk ratings and shading in Table 9-4 suggest differences between the closure options
in terms of magnitude of impact (alphabetic rating), these ratings are sensitive to the category ranges defined in
the matrix because excavation closure rates at the upper limit of the “A” risk rating category and CIP and hybrid
closures rate at the low limit of the “B” risk rating category. The numeric rating, which corresponds to the
duration of impact, is the distinguishing factor between the impacts to noise and congestion under the closure
options.

1805955.000 - 1990 55
excavation closure based on the trucking projections and implementation schedules provided by
Duke Energy (2018b).77
All closure options support safe air quality from diesel truck emissions along the transportation
routes, and each creates comparable levels of disturbance and risk that could adversely impact
community safety on a daily or annual basis; however, these impacts occur for a substantially
longer period under the excavation closure option (28 years for excavation closure compared to
13 and 12 years for CIP and hybrid closures, respectively). Thus, CIP and hybrid closure
options best satisfy the third objective of ash basin closure—to minimize risk and disturbance to
humans from closure.

77 Sensitivity analyses exploring different assumptions and subsequent effects to relative risk ratings are provided
in Appendix E.

1805955.000 - 1990 56
10 Conclusion 4: All closure options for the MSS ash
basin create environmental disturbance.
Environmental services are derived from ecological processes or functions that have value to
individuals or society, with provision of a healthy environment to humans being one of the most
essential environmental services. Environmental services that support human health include
functions to purify freshwater, provide food, supply recreational opportunities, and contribute to
cultural values (MEA 2005). For example, forests provide habitat for deer that are hunted for
food; surface water supports fish populations that are food for bald eagles, a previously
threatened and endangered species highly valued by our society;78 and soil and wetlands purify
groundwater and surface water, respectively, by adsorbing contaminants. Central to weighing
the net environmental benefits of the closure options under consideration here is understanding
how they differentially impact the variety of environmental services at the site and in the area.
MSS, though an industrial site, supports a diversity of habitats that provide environmental
services. Figure 10-1 illustrates the types of habitats at the site. The ash impoundment provides
habitat that supports birds and mammals; the open water habitat of the impoundment also
removes solids from surface water by providing a low-flow environment in which ash particles
and other solids can settle into the sediment before the treated water can enter Lake Norman.
The onsite forest provides biodiversity protection in the form of foraging, shelter, and breeding
habitat for birds and mammals, among other types of organisms; watershed protection;
landscape beauty; and carbon sequestration (Bishop and Landell-Mills 2012). Beyond MSS, the
Catawba River and Lake Norman provide aquatic habitat that supports a variety of fish and
aquatic life (Duke Energy 2018a), which then provide food for birds and mammals.

78 Bald eagles were taken off the federal list of threatened and endangered species in 2007
(https://www.fws.gov/midwest/eagle/).

1805955.000 - 1990
57
Figure 10-1. Map of habitat types currently present at Marshall.
Reproduced from CAP-2 Appendix F, Figure 2-6 (HDR 2016a).

1805955.000 - 1990 58
Plants serve a vital ecosystem role by converting solar energy and carbon dioxide into food (for
themselves) and oxygen. Plants then become food for other organisms. As such, “plants provide
the energy and air required by most life forms on Earth.”79 NPP represents a measure of the
mass of chemically fixed carbon produced by a plant community during a given period and
reflects the rate at which different ecos ystems are able to sequester carbon. Given the
foundational role of primary production in supporting ecological food webs and healthy air,
NPP is a good surrogate for environmental services provided by different habitat types
(Efroymson et al. 2003). For example, the annual NPP of a temperate forest habitat is
approximately 2.5 times higher than for temperate grasslands or freshwater ecosystems
(Ricklefs 2008). By multiplying the acres of habitat type by NPP, NPP becomes a single metric
by which to compare the different levels of environmental services impacted by ash basin
closure.80
The fourth objective for ash basin closure, to minimize environmental disturbance, is
represented by the environmental services protection of biodiversity and natural beauty. For
purposes of the NEBA, these considerations were evaluated based on differences in habitat-
derived services estimated from the NPP of impacted habitat acres under the closure options.
10.1 Excavation closure results in a greater net loss of
environmental services than CIP or hybrid closure.
Regardless of the closure option, habitat, and habitat-derived environmental services, will be
altered. CIP closure requires removing existing habitat within the footprint of the ash basin,
possible temporary removal of forest habitat to create a borrow pit to source earthen materials
for the cap, and restoring the ash basin with grass cap habitat. Excavation closure requires
temporary loss and future modification of existing habitats within the footprint of the ash basin;
permanent conversion of some forest habitat to create additional landfill capacity; temporary
removal of forest habitat to create a borrow pit to source earthen materials for fill material for
the landfill cap; restoring the ash basin with a mixture of grass cap, open field, and forest

79 https://earthobservatory.nasa.gov/GlobalMaps/view.php?d1=MOD17A2_M_PSN
80 I used rates of NPP by stand age from He et al. (2012, Figure 2c.) for mixed forests as the basis for establishing
NPP of on-site wooded habitats and used relative rates of NPP from Ricklefs (2008) to scale NPP for other
habitat types.

1805955.000 - 1990 59
habitat; and restoring the new landfill capacity with grass cap. The hybrid option requires
temporary loss and future modification of existing habitats within the footprint of the ash basin,
temporary removal of forest habitat to create a borrow pit to source earthen materials for the
cap, and restoring the reduced area of ash in the basin with a mixture of grass cap, open field,
and forest habitat. All closure options include restoration of the ash basin footprint, but the
collateral losses of habitat, the differences in service levels of restored habitat, and the timelines
for recovery of the habitats vary substantially. This makes it challenging to appreciate the net
gain or loss of environmental services. To address this challenge, I used HEA to quantify the
differences in environmental services resulting from each closure option.
HEA is an assessment method widely used in NRDA to facilitate restoration scaling for
environmental services (Dunford et al. 2004; Desvousges et al. 2018; Penn undated). Numerous
damage assessment restoration plans based on the use of HEA can be found on the U.S. Fish
and Wildlife Service81 and NOAA82 websites and include sites such as the St. Lawrence River
near Massena, New York; Onondaga Lake near Syracuse, New York; and LaVaca Bay in Texas.
As Desvousges et al. (2018) describe, use of HEA has expanded in recent years beyond its
original applications for NRDA to address environmental service losses from other causes such
as forest fires and climate change. As the authors note, HEA has also been used as an
assessment tool in NEBA applications, such as evaluating the effects of transmission line
routing on habitats of greater sage-grouse (Centrocercus urophasianus), a proposed threatened
species.
The objective of HEA is to estimate the amount of compensatory services necessary to equal the
value of the services lost because of a specific release or incident. The method calculates debits
based on services lost because of resource losses and credits for services gained due to resource
gains. The latter are often scaled to compensate for, or offset, the loss in services. A discount
rate is used to standardize the different time intervals in which the debits and credits occur, so
the services are usually expressed in terms of discounted acre-years of equivalent habitat, or
DSAYs (Dunford et al. 2004; Desvousges et al. 2018; Penn undated).

81 www.doi.gov/restoration
82 www.darrp.noaa.gov

1805955.000 - 1990 60
The HEA methodology was used here to estimate changes in environmental service levels that
will accrue under closure options. Environmental services currently provided by the site will be
eliminated when the ash basin is closed. After closure is complete, there will be a new level of
environmental services provided as habitat is restored. Since post-closure habitats may differ
from those that currently occur onsite, future services could be greater or less than what occurs
at present. Similarly, land used as a borrow area or converted to landfill, as per the closure
options, will also impact the net level of services, as services currently provided by those
habitats may be reduced or eliminated. The environmental service losses and gains from onsite
and offsite habitats must be considered together when determining the overall net effect of a
closure option.
A common ecological metric is required to make comparisons between service gains and losses
from various habitat types. For purposes of this evaluation, I used annual NPP as the metric to
standardize across habitat types. In terms of habitats currently occurring on the site, wooded
areas have the highest NPP, so that is used as the basis for defining service level, and the service
levels for other habitat types (open fields, open water) are expressed as a proportion of that
baseline service. Based on He et al. (2012), and assuming a tree stand age of 50 years, NPP
would be approximately 6.4 tons of carbon per hectare per year (6.4 t C/ha/yr) in wooded areas
onsite. Based on relative rates of NPP from Ricklefs (2008), the NPP for open field and open
water habitats would be approximately 40% of the temperate forest rate. To prevent
overestimation of NPP in open water areas of the ash basin that may not provide the same level
of NPP as natural freshwater habitats (perhaps from limited abundance or diversity of
vegetation), I assumed that open water areas of the ash basin produce NPP that is 25% that of
natural ecosystems.83 Therefore, I applied a four-fold habitat quality factor to scale NPP at these
open water areas of the ash basin to approximately 10% of the rate for wooded habitats.
Deforested land for borrow areas was assumed to be reforested after closure was complete, and

83 I observed open water areas of the ash basin that supported aquatic vegetation but do not know the extent of
vegetation in the open water areas of the ash basin. Thus, I made a conservative assumption (i.e., one that
reduces the present value of the habitat) that these areas of the ash basin provide a reduced level of NPP
compared to natural open freshwater areas.

1805955.000 - 1990 61
landfill areas were assumed to recover to grass cap. The grass cap on landfill was given a
service value of 8%,84 as was done for CIP.
For each closure option, I used the acreage of existing habitat types and the level of service of
that habitat type to establish a baseline level of service. Based on the timelines for the various
closure options, a HEA was conducted to calculate the net change in service flow of the closure
area over the next 150 years at a 3% discount rate.85 Similarly, a HEA was run to calculate the
net change in environmental services deriving from areas used either as borrow or for landfill
expansion. Because NPP standardizes service levels across habitat types, the DSAY estimates
for all affected habitats can be summed to calculate the net service gain/loss associated with
each closure option. In addition to the assumptions identified above, several other assumptions
were made to support the HEA, which are described in Appendix D.
Results of the HEA are presented in Table 10-1.86 The results indicate that all closure options
will result in a net loss of environmental services due primarily to temporary or permanent loss
of forest habitat for borrow and landfill areas, reduced NPP services provided by a grass cap
(cap and landfill areas), and the long delay for restoration of forested habitat in the ash basin
(excavation and hybrid options) and borrow pit (all options). These factors, collectively,
adversely affect environmental services provided by the ash-impacted habitat acres such that
environmental services produced after closure will not compensate for the service losses
resulting from the closure. There are net losses for all closure options, with hybrid closure
creating the least NPP service loss. 87

84 An open field provides a relatively lower NPP service level than forest habitat (40% of forest NPP; Ricklefs
2008), and since a grass cap requires periodic maintenance mowing, for purposes of the HEA it was assumed
never to reach a level of NPP service equivalent to an open field. Grass cap was assumed to have 20% of the
NPP service level for open field, which is 8% of forest NPP.
85 Environmental services in future years are discounted, which places a lower value on benefits that will take
longer to accrue. The basis for this is that humans place greater value on services in the present and less value
on services that occur in the future.
86 A full description of the methods, assumptions, results, and sensitivity analyses for the HEA are provided in
Appendix D.
87 Note, however, that the environmental services lost due to the currently defined CIP closure could be offset (see
discussion in Section 11) by a suitable reforestation project that would then result in the CIP closure option
producing no net loss of habitat-derived environmental services in the HEA model.

1805955.000 - 1990 62
Table 10-1. Summary of NPP DSAYs for CIP and excavation closure options
CIP Excavation Hybrid
Ash basin losses Open Field −8 −8 −8

Grass Cap −324 −306 −324

Open Water −253 −239 −253

Wetland −89 −84 −89
Broadleaf Forest −1,757 −1,645 −1,757
Needle Leaf Forest −1 −1 −1

Scrub/Shrub −1,542 −1,453 −1,542

Wetland Forest −25 −24 −25

Total losses −4,002 −3,758 −4,002
Ash basin post-closure gains Open Field 89 111
Grass Cap 784 164 495

Open Water 329 541

Wetland 12 15

Broadleaf Forest 1,627 1,033
Needle Leaf Forest 122 77
Scrub/Shrub 309 384
Wetland Forest 49 80

Total gains 784 2,704 2,737
Landfill/borrow losses Forest −1,508 −5,286 −754

Open Field
Grass Cap −9

Total losses −1,508 −5,295 −754
Landfill/borrow post-closure gains Forest 823 1,022 424

Grass cap 126
Total gains 823 1,148 424
Net Gain/Loss per Option −3,903 −5,202 −1,594
Note: DSAYs for specific habitat types are reported here rounded to the nearest whole number. As such, the net
gain/loss per option differs slightly from the sum of the individual DSAYs reported in the table.
10.2 NEBA – Minimize Environmental Disturbance
The impact of the closure options on environmental services was computed as the percentage
difference in DSAYs produced by the closure option and the absolute value of the DSAY losses.
The DSAY losses represent the NPP services that would have been produced by the site, borrow
areas, and landfills but for the project closure. The DSAY gains represent the NPP services

1805955.000 - 1990 63
restored after project closure plus any future gains realized from existing habitats before
remediation begins. The sum of DSAY losses and gains represents the net change of NPP
services for the project resulting from closure. Dividing the net DSAYs by the absolute value of
the DSAY losses provides a percentage of the impact. From these calculations, the CIP closure
will have a 71% impact; excavation closure will have a 57% impact; and hybrid closure will
have a 34% impact (Table 10-2). These percent changes were input to the risk-ranking matrix
(Table 5-4) along with the duration of the closure activities (13 years CIP; 28 years excavation;
12 years hybrid) to evaluate, within the NEBA construct, which of the closure options best
minimizes environmental disturbances (Table 10-3).
Table 10-2. Percent impact of ash basin closure options
CIP Excavation Hybrid
DSAY Lossesa 5,509 9,053 4,756
DSAY Gains 1,607 3,851 3,161
Percent Impact (%) 71% 57% 34%
a Absolute value of DSAY losses is equivalent to baseline services of the
affected habitat, but for the closure.
Table 10-3. Summary of relative risk ratings for habitat changes that
affect provision of environmental services.
Darker shading and higher codes indicate greater impact.
Objective
Minimize Environmental
Disturbance
Hazard Habitat Change
Attribute DSAYs
Scenario
Baseline baseline
CIP 4E
Excavation 6D
Hybrid 4C
CIP closure, as currently defined, though having a lower net DSAY loss than excavation closure
has a higher percent impact because the net NPP services lost are a larger fraction of the NPP
services that would have existed but for closure of the ash basin, which is a consequence of the
low level of NPP services provided by the 502 acres of grass cap after closure (8% of forest
NPP). Conversely, the greater net NPP service loss under excavation closure is a smaller
fraction of the services that would have existed but for the closure because the excavation

1805955.000 - 1990 64
closure option can lead to the creation of forest in a large proportion of the footprint of the ash
basin and the land for landfilling (and loss of forest habits that are ultimately replaced with low
NPP grass cap). Hybrid closure has the least net NPP service loss of the options considered, and
it also has the lowest percent impact from the closure because the net NPP services lost are a
smaller fraction of the NPP services that would have existed but for closure of the ash basin,
which results from the larger forest habitat gained and smaller grass cap footprint compared to
CIP.
Within the objective of minimizing environmental disturbance from closure, my analyses
indicate that all closure options adversely impact habitat-derived environmental services and
produce comparable decreases in net NPP services; however, the lower impact and shorter
duration of hybrid closure better satisfies the fourth objective of ash basin closure—to minimize
risk and disturbance to the local environment from closure.

1805955.000 - 1990 65
11 Conclusion 5: Hybrid closure maximizes
environmental services.
Identifying environmental actions that maximize environmental services (the fifth objective for
ash basin closure) is a function of NEBA (Efroymson et al. 2003, 2004) and the overarching
objective that encompasses each of the other four objectives and all of the environmental
services that have been considered to this point. Table 11-1 summarizes the relative risk ratings
for all attributes and objectives. Impacts to environmental services considered in this NEBA
focused on key community-relevant concerns. Risk to construction workers from construction
operations, risks to local and global populations from increased greenhouse gas emissions, and
“wear-and-tear” damage to roadways from trucking were not estimated. Each of these risks,
however, would scale with the duration, frequency, and intensity of construction operations.
Sensitivity analyses of the specifications of the NEBA framework show that the specific relative
risk ratings presented in this NEBA can change depending on how baseline is defined (see
Appendix E). The purpose of the risk matrix, and the risk ratings that result from it, is to
consolidate the results from a variety of different analyses for a variety of different data types
and attributes into a single framework for comparative analysis. It is imperative, however, to
consider the underlying information used to develop the risk ratings to interpret the differences
between closure options, particularly when percent impacts or durations of closure options are
similar but receive different risk ratings.
As noted in Section 5, NEBA analysis provides an opportunity to better understand the net
environmental benefits of possible closure options. If Duke Energy’s preferred closure option
for reasons not considered in the NEBA does not best maximize environmental services to the
local community as currently defined, the NEBA results provide insight into how environmental
services could be improved for that closure option. For instance, if Duke Energy’s preferred
closure option for MSS is CIP closure but the HEA results for the currently defined CIP closure
option estimate a net environmental service loss of 3,903 DSAYs, Duke Energy could consider
incorporating into an updated CIP closure plan for MSS a mitigation project that compensates
for the net environmental service losses projected from the currently defined CIP closure option.

1805955.000 - 1990 66
As an example, if Duke Energy started a reforestation project outside of the ash basin in 2022
(when onsite preparation of the ash basin begins), the reforestation project would gain 24.3
DSAYs/acre over the lifetime of the site (150 years in the HEA), requiring an approximate 160
acre project to compensate for the 3,903 DSAY loss projected in the HEA. Re-analysis of the
HEA component of the NEBA for the updated possible closure options would then result in no
net environmental losses (as NPP services) from habitat alteration of the basin for CIP closure,
but net losses would remain under the hybrid and excavation closure options.
From the closure options considered and the analyses presented in this report, which are based
on a scientific definition of risk acceptability and include no value weighting, all closures as
currently defined provide equivalent protection of human and ecological health from CCR
exposure; however, the hybrid closure option best satisfies the fifth objective of ash basin
closure—to maximize local environmental services—because it results in less disturbance to the
local community over time compared to excavation closure and produces the least disturbance
to the environment.

1805955.000 - 1990
67
Table 11-1. NEBA for closure of the ash basin at Marshall.
Darker shading and higher alphanumeric codes indicate greater impact.
Objective Protect Human Health from
CCR
Protect Ecological Health
from CCR Minimize Human Disturbance
Minimize
Environmental
Disturbance
Hazard Exposure to CCR Exposure to CCR Noise and Traffic
Congestion
Traffic
Accidents Air Pollution Habitat Change Potentially Affected Populations Local Residents/Visitors Onsite Construction Workers Offsite Recreational Swimmers Offsite Recreational Waders Offsite Recreational Boaters Offsite Recreational Fishers Offsite Subsistence Fishers Fish Populations Aquatic Omnivore Birds (mallard) Aquatic Piscivore Birds (great blue heron) Aquatic Carnivore Birds (bald eagle) Aquatic Herbivore Mammals (muskrat) Aquatic Piscivore Mammals (river otter) Local Residents/Visitors Local Residents/Visitors Reasonable Maximum Exposure DSAYs
Scenario
Baseline -- -- -- -- -- -- -- -- -- -- -- -- -- baseline baseline baseline baseline
CIP -- -- -- -- -- -- -- -- -- -- -- -- -- 4B 4A -- 4E
Excavation -- -- -- -- -- -- -- -- -- -- -- -- -- 6A 6A -- 6D
Hybrid -- -- -- -- -- -- -- -- -- -- -- -- -- 4B 4A -- 4C
“--” indicates “no meaningful risk.”

1805955.000 - 1990 68
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Appendix A

Curriculum Vitae of
Dr. Ann Michelle Morrison, Sc.D.

Ann Michelle Morrison, Sc.D.
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Professional Profile
Dr. Morrison has over 20 years of experience evaluating the relationship between anthropogenic
contamination and health effects to aquatic life and humans. Dr. Morrison specializes in natural resource
damage assessment (NRDA), environmental causal analysis, and assessments of water quality
conditions. Dr. Morrison has provided scientific consultation regarding the design of field studies for
NRDA, and she has worked closely with legal counsel during scientific assessments and settlement
negotiations with state and federal trustees. Dr. Morrison has performed detailed technical assessments
of injuries to aquatic resources, including vegetation, benthic infauna, fishes, shellfishes, and corals. She
has also developed site-specific sediment toxicity thresholds based on the empirical r elationships of
chemical concentrations to biological effects. She has provided expert testimony concerning injury to
aquatic resources and the net environmental benefits of remediation alternatives .

Projects she has been involved with have concerned oil spills, sewage releases, heavy metal
contamination, and various industrial and municipal facilities that have generated complex releases to the
environment. Dr. Morrison applies statistical tools and weight-of-evidence approaches to delineate
exposure zones, predict the likelihood of contamination events, evaluate net environmental benefits, and
assess causation. She uses a broad knowledge of aquatic life and human health to assess risk and injury
to these populations.
Academic Credentials & Professional Honors
Sc.D., Environmental Health, Harvard University, 2004

M.S., Environmental Health, Harvard University, 2001

B.S., Biology, Rhodes College, 1997
Prior Experience
Senior Scientist, Sole Proprietor, Morrison Environmental Data Services, 2004 –2007

Data Analyst, ETI Professionals, 2005

Scientist, NIH Toxicology Training Grant, Harvard School of Public Health, 2000 –2004

Guest Student, Woods Hole Oceanographic Institution, Stegeman Lab, 2001–2004

Science Intern, Massachusetts Water Resources Authority, 03-05/2000, 10/2000-10/2001

Ann Michelle Morrison, Sc.D.
Senior Managing Scientist | Ecological & Biological Sciences
1 Mill and Main Place, Suite 150 | Maynard, MA 01754
[phone] tel | [e-mail]

Ann Michelle Morrison, Sc.D.
12/17 | Page 2
Research technician, Bermuda Biological Station for Research, Inc., Benthic Ecology Research Program
(BERP), Bermuda, 01/1998-09/1999, 06-08/2000

Research Intern, Bermuda Biological Station for Research, Inc., Benthic Ecol ogy Research Program
(BERP), Bermuda, 05/1997-12/1997

NSF Research Experience for Undergraduates Fellowship, Bermuda Biological Station for Research, Inc.,
Benthic Ecology Research Program (BERP), Bermuda, 08-11/1996
Professional Affiliations
American Chemical Society — ACS

Society for Risk Analysis — SRA

Society of Environmental Toxicology and Chemistry — SETAC

North Atlantic Chapter of SETAC
Publications
Mearns AJ, Reish DJ, Bissell M, Morrison AM, Rempel-Hester MA, Arthur C, Rutherford N, Pryor R.
Effects of pollution on marine organisms. Water Environment Research 2018; 90(10):1206–1300.
Mearns AJ, Reish DJ, Oshida PS, Morrison AM, Rempel-Hester MA, Arthur C, Rutherford N, Pryor R.
Effects of pollution on marine organisms. Water Environment Research 2017; 89(10):1704–1798.

Morrison AM, Edwards M, Buonagurio J, Cook L, Murray K, Boehm P. Assessing the representativeness
and sufficiency of water samples collected during an oil spill. Proceedings, 2017 International Oil Spill
Conference, Vol 2017, No 1.

Mearns AJ, Reish DJ, Oshida PS, Morrison AM, Rempel-Hester MA, Arthur C, Rutherford N, Pryor R.
Effects of pollution on marine organisms. Water Environment Research 2016; 88(10):1693–1807.

Morrison AM, Kashuba R, Menzie CA. Evaluating alternative causes of environmental change.
Environmental Perspectives 2016; 1.

Boehm PD, Morrison AM, Semenova S, Kashuba R, Ahnell A, Monti C. Comprehensive oil spill liability
estimation. Environmental Perspectives 2016; 1.

Boehm PD, Morrison AM. Oil spill liability modeling: helping to manage existential risks. Oil & Gas Insight,
2016; 4.

Morrison AMS, Goldstone JV, Lamb DC, Kubota A, Lemaire B, Stegeman JJ. Identification, modeling and
ligand affinity of early deuterostome CYP51s, and functional characterization o f recombinant zebrafish
sterol 14α-demethylase. Biochimica et Biophysica Acta, 2014; 1840:1825 –1836.

Menzie C, Kane Driscoll SB, Kierski M, Morrison AM. Advances in risk assessment in support of sediment
risk management. In: Processes, Assessment and Remediation of Contaminated Sediments. Reible DD
(ed), SERDP ESTCP Environmental Remediation Technology, Vol. 6, pp. 107–130, 2014.

Mudge S, Morrison AM. Tracking sources of sewage in the environment. Environmental Forensic Notes,
2010; 9.

Ann Michelle Morrison, Sc.D.
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Pietari J, Bigham G, Morrison AM. Source tracking for identification of microbial pollution sources.
Environmental Forensic Notes, 2009; 6.

Goldstone JV, Goldstone HMH, Morrison AM, Tarrant AM, Kern SE, Woodin BR, Stegeman JJ.
Cytochrome P450 1 genes in early deuterostomes (tunicates and sea urchins) and vertebrates (chicken
and frog): Origin and diversification of the CYP1 gene family. Molecular Biology and
Evolution 24(12):2619–31, 2007.

Morrison AM. Receiver Operating Characteristic (ROC) Curve Analysis of Antecedent R ainfall and the
Alewife/Mystic River Receiving Waters. Boston: Massachusetts Water Resources Authority. Report
ENQUAD 2005-04, 2005. 26 p.

Morrison AM, Coughlin K. Results of intensive monitoring at Boston Harbor beaches, 1996–2004. Boston,
Massachusetts Water Resources Authority, Report ENQUAD 2005-05, 76 pp., 2004.

Morrison AM, Coughlin K, Shine JP, Coull BA, Rex AC. Receiver operating characteristic curve analysis
of beach water quality indicator variables. Applied and Environmental Microbiology, 2003 ; 69:6405–6411.

Coughlin K, Stanley AM. Boston Harbor beach study suggests a change in beach management.
Coastlines, 2001; Issue 11.6.

Coughlin K, Stanley AM. Water quality at four Boston Harbor beaches: Results of intensive monitoring
1996–2000. Boston, Massachusetts Water Resources Authority, Report ENQUAD 2001-18, 46 pp., 2001.

Published Abstracts

Stegeman J, Handley-Goldstone H, Goldstone J, Tarrant A, Morrison AM, Wilson J, Kern S. Pantomic
studies in environmental toxicology answers, questions and extrapolation. Journal of Experimental
Zoology Part a-Comparative Experimental Biology, 2006; 305A:181.

Goldstone JV, Goldstone HMH, Morrison AM, Tarrant A, Kern SE, Woodin BR, Stegeman JJ. Functional
evolution of the cytochrome P450I gene family: Eviden ce of a pre-vertebrate origin. Marine Environmental
Research, 2006; 62: S47

Handley HH, Goldstone JV, Morrison AM, Tarrant, Wilson JY, Godard CA, Woodin BR, Stegeman JJ.
Abstracts from the 12th International Symposium on Pollutant Responses in Marine Orga nisms (PRIMO
12) — Receptors and Regulation of Cytochrome P450. Marine Environmental Research, 2004; 58:131+.

Morrison AM, Stegeman JJ. Abstracts from the Twelfth International Symposium on Pollutant Responses
in Marine Organisms (PRIMO 12) — Cloning, Expression and Characterization of Cytochrome P450 51:
An investigation of CYP51 azole sensitivity in aquatic animals. Marine Environmental Research, 2004;
58:131+.

Morrison AM, Stegeman JJ. CYP51 azole sensitivity in lower vertebrates and invertebrate. Drug
Metabolism Reviews: Biotransformation and Disposition of Xenobiotics, 2003; 35(2):179.

Presentations

Morrison AM, Ma J, Gard N, Palmquist K, Lin C, Deines A. Ecosystem services accounting in support of
corporate environmental stewardship in a changing climate. Society of Environmental Toxicology and
Chemistry (SETAC) North America 39th Annual Meeting, Sacramento, CA. November 5–8, 2018.
Pietari J, Morrison AM, Kashuba R, Boehm PD. Incorporating a framework for risk assessment, risk
management, and risk mitigation of extreme weather events at Superfund sites. Society of Environmental

Ann Michelle Morrison, Sc.D.
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Toxicology and Chemistry (SETAC) North America 39th Annual Meeting, Sacramento, CA. November 5–
8, 2018.
Deines AM, Palmquist K, Morrison AM. Global Status and Risk of Non-Native Fish Aquaculture. 148th
Annual Meeting of the American Fisheries Society, Atlantic City, NJ. August 19–23, 2018.
Morrison AM, Palmquist K, Kashuba R. Baseline in the Open-Access and “Big Data” Era. Law Seminars
International. Washington, D.C. March 1, 2018.
Palmquist K, Morrison AM, Edwards ME. Addressing white hat bias: Lessons from environmental
litigation. Society of Environmental Toxicology and Chemistry (SETAC) North America 38th Annual
Meeting, Minneapolis, MN. November 12–16, 2017.

Palmquist KR, Ginn TC, Morrison AM, Boehm PD. 2017. Addressing Spatial Data Gaps in Deep-sea
Benthic Sediment Sampling Following a Large-Scale Oil Spill. Battelle Sediment Conference in New
Orleans, LA.

Morrison AM. The Science. Natural Resource Damages 101. Law Seminars International. Washington,
D.C. March 9, 2016.

Morrison AM, Murray KJ, Cook LC, Boehm PD. Spatial and Temporal Extent of PAHs Associated with
Surface Oil Distributions (Anomalies). Gulf of Mexico Research Initiative Conference. Tampa, F L.
February 1–4, 2016.

Boehm PD, Morrison AM. The Interplay of Data Needs and Data Analysis Frameworks to Optimize the
Collection and Use of Data from Oil Spills. Gulf of Mexico Research Initiative Conference. Tampa, F L.
February 1–4, 2016.

Whaley JE, Morrison AM, Savery LC. Using the Causal Analysis Framework to Investigate Marine
Mammal Unusual Mortality Events (poster), Society of Marine Mammalogy Biennial Conference, San
Francisco, CA. December 2015.

Kashuba R, Morrison AM, Menzie C. The Application and Misapplicat ion of Directed Acyclic Graphs for
Causal Inference in Ecology. Society of Environmental Toxicology and Chemistry (SETAC) North America
36th Annual Meeting, Salt Lake City, UT. November 1–5, 2015.

Kierski M, Morrison AM, Kane Driscoll S, Menzie C. A Refined Multi-Site Model to Estimate the Toxicity of
PAH-Contaminated Sediments at MGP Sites. Society of Environmental Toxicology and Chemistry
(SETAC) North America 36th Annual Meeting, Salt Lake City, UT. November 1–5, 2015.

Morrison AM, McArdle M, Menzie C. A Tiered Approach to Causal Analysis in Natural Resource Damage
Assessment. 35th Annual Society of Environmental Toxicology and Chemistry (SETAC) Meeting,
Vancouver, BC, Canada. November 9–13, 2014.

Morrison AM, Kane Driscoll S, McArdle M, Menzie C. Integrated environmental benefit analysis of
sediment remediation thresholds. 32nd Annual Society of Environmental Toxicology and Chemistry
(SETAC) Meeting, Boston, MA. November 14–17, 2011.

Kierski M, Morrison AM, Kane Driscoll S, Menzie C. A multi-site model to estimate the toxicity of PAH
contaminated sediments at MGP sites. 32nd Annual Society of Environmental Toxicology and Chemistry
(SETAC) Meeting, Boston, MA. November 14–17, 2011.

Kierski M, Morrison AM, Kane Driscoll S, Menzie C. Use of receiver operating characteristic curve
analysis to estimate ecological risk zones as part of an ecological risk assessment. 31st Annual Society

Ann Michelle Morrison, Sc.D.
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of Environmental Toxicology and Chemistry (SETAC) Meeting, Portland, OR. November 7–11, 2010.

Morrison AM, Coughlin K, Rex A. Bayesian network predictions of Enterococcus exceedances at four
Boston Harbor beaches. Water Resources Conference 2008, Amherst, MA . April 8, 2008.

Stegeman J, Handley-Goldstone H, Goldstone J, Tarrant A, Morrison AM, Wilson J, Kern S. Pantomic
studies in environmental toxicology answers, questions and extrapolation. 15th International Congress of
Comparative Endocrinology, Boston, MA. 2005.

Goldstone JV, Goldstone HMH, Morrison AM, Tarrant A, Kern SE, Woodin BR, Stegeman JJ. Functional
evolution of the cytochrome P450I gene family: Evidence of a pre-vertebrate origin. 13th International
Symposium on Pollutant Responses in Marine Organisms (PRIMO 13), Alessandria, Italy, June 2005.

Morrison AM, Stegeman JJ. CYP51 azole sensitivity in lower vertebrates and invertebrate. 12th North
American Meeting of the International Society for the Study of Xenobiotics, Providence, RI . October 12–
16, 2003.

Morrison AM, Stegeman JJ. Cloning, expression and characterization of Cytochrome P450 51: An
investigation of CYP51 azole sensitivity in aquatic animals. 12th International Symposium, Pollutant
Responses in Marine Organisms, Tampa, FL. May 2003.

Handley HH, Goldstone JV, Morrison AM, Tarrant AM, Wilson JY, Godard CA, Woodin BR, Stegeman JJ.
12th International Symposium, Pollutant Responses in Marine Organisms, Tampa, FL. May 2003.

Morrison AM, Coughlin KA, Shine JP, Coull BA, Rex AC. Receiver operating characteristic curve analysis
of beach water quality indicator variables. Pathogens, Bacterial Indicators, and Watersheds: Treatment,
Analysis, Source Tracking, and Phase II Stormwater Issues. New England Watershed Association,
Milford, MA. May 14, 2003.

Stanley AM, Coughlin KA, Shine JP, Coull BA, Rex AC. Receiver operating characteristic analysis is a
simple and effective tool for using rainfall data to predict bathing beach bacterial water quality. 102nd
General Meeting, American Society for Microbiology, Salt Lake City, UT . May 2002.

Coughlin K, Stanley AM. Five years of intensive monitoring at Boston harbor beaches: Overview of beach
water quality and use of the Enterococcus standard to predict water quality. Massachusetts Coastal Zone
Marine Monitoring Symposium, Boston, MA. May 2001.

Smith SR, Grayston LM, Stanley AM, Webster G, McKenna SA. CARICOMP coral reef monitoring: A
comparison of continuous intercept chain and video transect techniques. Scientific Aspects of Coral Reef
Assessment, Monitoring and Management, National Coral Reef Institute (NCRI), Nova Southeastern
University, Ft. Lauderdale, FL. 1999.
Project Experience
Dr. Morrison has been involved in numerous complex projects relating to environmental contamination
and potential risk to humans and biological resources in the affected environment.

Risk Assessments and Natural Resource Assessments

Expert witness concerning net environmental benefits from coal ash closure alternatives at two coal ash
plants in North Carolina. Roanoke River Basin Association v. Duke Energy Progress, LLC, United States
District Court, Middle District of North Carolina, Case No. 1:16-cv-607 and Roanoke River Basin
Association v. Duke Energy Progress, LLC, United States District Court, Middle District of North Carolina,
Case No. No. 1:17-cv-452.

Ann Michelle Morrison, Sc.D.
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Expert witness concerning potential damages to terrestrial and aquatic resources, including coral reefs,
endangered sea turtles, fish and shellfish, and seagrass beds, resulting from a coastal development
project on the Caribbean island of Nevis. Anne Hendricks Bass vs. Director of Physical Planning,
Development Advisory Committee, and Caribbean Development Consultant Limited. Eastern Caribbean
Supreme Court, in the High Court of Justice Saint Christopher and Nevis, Nevis Circuit, Civil Case No.
NEVHCV2016/0014.

Expert witness concerning potential impacts to California fishery populations from the Refugio oil spill.
Andrews et al. v. Plains All American Pipeline, L.P. et al. United States District Court, Central District of
California, Wester Division, Case No. 2:15-cv-04113-PSG-JEM.

Provided analysis and technical support in Florida v. Georgia United States Supreme Court case that
considered questions of causation relative to alleged adverse ecological changes in downstream river
and bay populations.

Conducted a comprehensive review of an environmental impact assessment of potential impacts to coral
reefs from a proposed dairy farm development in Hawaii.

Provided scientific support for the Deepwater Horizon NRDA in the Gulf of Mexico.

Developed a cooperative NRDA field study in the offshore waters of the Gulf of Mexico to collect
sediment samples for analysis of chemistry, toxicology, and benthic infauna.

Expert witness concerning alleged injuries to aquatic resources from disposal of bauxite ore processing
wastes for the case: Commissioner of the Department of Planning and Natural Resources, Alicia V.
Barnes, et al. v. Virgin Islands Alumina Company et al. District Court of the Virgin Islands, Division of St.
Croix, Civil Case No. 2005-0062.

Developed decision management products for beach water quality stakeholders using statistical data
analysis tools such as receiver operating characteristic (ROC) curves and Bayesian networks to improve
public beach advisories related to elevated fecal bacteria.

Developed net environmental benefit analysis (NEBA) for a lead contaminated river. This analysis used
site-specific data to evaluate the costs and benefits of two different remediation options that were being
considered. The NEBA was successfully used by the client to negotiate a higher remediation goal than
original proposed by the state Department of Environmental Protection.

Performed ROC curve analyses of site-specific polycyclic aromatic hydrocarbon (PAH) toxicity data to
assess the relationship between PAH concentration and toxicity at three ecological risk assessment
projects in Wisconsin. The curves were used to identify site-specific toxicity thresholds for PAH
concentration in sediment that were indicative of various zones of toxicity (no toxicity, low tox icity, and
high toxicity), with very limited misidentification of sediments.

Provided research support to calculate site-specific no-observed-adverse-effect level (NOAEL) and
lowest-observed-adverse-effect level (LOAEL) concentrations for mammals and birds for use in a
baseline ecological risk assessment in Wisconsin.

Performed ROC curve analysis of national mercury toxicity data to assess the relationship between
mercury concentration and toxicity. The curves were also used to identify a threshold mercur y
concentration for sediment that indicates likely toxicity, with very limited misidentification of sediments that
are not toxic.

Assembled and analyzed data and reviewed remedial investigations to conduct a screening-level

Ann Michelle Morrison, Sc.D.
12/17 | Page 7
ecological risk assessment for sediment, surface water, and groundwater for a site in Connecticut. The
chemicals considered were total petroleum hydrocarbons (TPH), metals, and PAHs.

Reviewed species lists and created summary descriptions of organisms that could be potentially impacted
by dam construction on a high-altitude river in the Caribbean. This information was important to develop
the risk assessment from dam construction.

Researched the toxicity of malathion to fish to support a technical review of the National Marine Fisherie s
biological opinion for the registration of pesticides containing malathion.

Ecological and Toxicity Studies

Conducted surveys to assess the health of coral reefs, seagrass beds, and mangrove swamps in the
nearshore environment of Bermuda. Projects included area-wide habitat surveys as well as targeted sites
potentially impacted by a heavy metals dump, hot water effluent from an incinerator, sedimentation from
cruise ship traffic, and chronic release of raw sewage. In addition to ecological surveys, wate r quality was
assessed through measurements of trace metals in water, sediment, and coral tissue.

Surveyed juvenile coral recruitment in the Florida Keys to evaluate if marine protected areas (MPA s)
provide a benefit to coral recruitment.

Studied cytochrome P450 family enzymes, including CYP51 and CYP1, examining their sensitivity to
environmental chemicals and their evolution through molecular biology and biochemistry approaches.

Environmental Forensics Projects

Performed document review, information m anagement, and technical writing for numerous complex
projects that dealt with historical petroleum contamination and multiple site owners in several types of
environmental media.

Reviewed documents, assembled data, and researched metal concentrations associated with crude oil
and railroads in support of a Superfund project in Oklahoma.

Examined the correlation of multiple contaminants (PAHs, metals) with polychlorinated biphenyl (PCB)
congeners at a historically contaminated site in Alabama to identify the likely origins of the PCB
contamination.

Performed statistical analysis to determine source contribution in a chemical fingerprinting case at a
Superfund site in Washington that involved hydrocarbons in water, sediment, and groundwater.

Human Health Projects

Organized, managed, and simplified a complex database of field sampling reports for a litigation case in
Louisiana regarding human air exposure to PAHs.

Performed data analysis and document review for a Superfund site in Oklahoma. The analyses us ed
hydrocarbon chromatograms and limited PAH and metal data to identify the likely sources of
contamination.

Researched and compiled screening-level human health inhalation toxicity values for refinery-related
gases for an overseas project.

Developed a questionnaire and related database for industrial hygiene surveys to support regulatory
compliance for a highly specialized industry.

Appendix B

Human Health and Ecological
Risk Assessment Summary
Update for Marshall Steam
Station

Matt Huddleston, Ph.D.
Senior Scientist
Heather Smith
Environmental Scientist

HUMAN HEALTH AND
ECOLOGICAL RISK ASSESSMENT
SUMMARY UPDATE
For

MARSHALL STEAM STATION
8320 EAST CAROLINA HIGHWAY 150
TERRELL, NORTH CAROLINA 28682
NOVEMBER 2018
PREPARED FOR
DUKE ENERGY CAROLINAS, LLC
526 SOUTH CHURCH STREET
CHARLOTTE, NORTH CAROLINA 28202

Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

Page 1
1.0 INTRODUCTION
This update to the Marshall Steam Station (MSS or Site) human health and ecological
risk assessment incorporates results from sampling events conducted August 1989
through July 2018. The samples were collected from surface water, sediment, and
groundwater. This update was performed in support of a Net Environmental Benefits
Analysis. As set forth below in detail, this updated risk assessment concludes that: (1)
the MSS ash basin does not cause any material increase in risks to human health for
potential human receptors located on-Site or off-Site; and (2) the MSS ash basin does not
cause any material increase in risks to ecological receptors.
The original 2016 risk assessment was a component of the Corrective Action Plan Part 2
pertaining to MSS (HDR, 2016). To assist in corrective action decision making, the risk
assessment characterized potential effects on humans and wildlife exposed to naturally
occurring elements, often associated with coal ash, present in environmental media.
Corrective action is to be implemented with the goal of ensuring future site conditions
remain protective of human health and the environment, as required by the 2014 North
Carolina General Assembly Session Law 2014-122, Coal Ash Management Act (CAMA).
The risk assessment was updated as part of the 2018 Comprehensive Site Assessment
(CSA) Update report (SynTerra, 2018). This update follows the methods of the 2016 risk
assessment (HDR, 2016) and is based on U.S. Environmental Protection Agency
(USEPA) risk assessment guidance (USEPA, 1989; 1991; 1998).
Areas of wetness (AOWs), or seeps, are not subject to this risk assessment update.
AOWs associated with engineered structures, also referred to as “constructed seeps,”
have been addressed in a National Pollutant Discharge Elimination System (NPDES)
permit. Other AOWs (non-constructed seeps) are now addressed under a Special Order
by Consent (SOC) issued by the North Carolina Environmental Management
Commission (EMC SOC WQ S17-009). Many AOWs are expected to reduce in flow or
be eliminated after decanting (i.e., removal of the free water). The SOC requires that
any seeps remaining after decanting must be addressed with a corrective action plan
that must ”protect public health, safety, and welfare, the environment, and natural
resources” (EMC SOC WQ S17-009, 2. d.).
This risk assessment update includes results from samples of surface water, sediment,
and groundwater collected since the 2018 CSA update. New information regarding
groundwater flow and the treatment of source areas other than the ash basin has
resulted in refinement of exposure pathways and exposure areas. The Conceptual Site
Models (CSMs) (Figures 1 and 2) reflect potentially complete exposure pathways with
potential risks, and ecological exposure areas are depicted in Figure 3. Human health
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

Page 2
risks were evaluated Site-wide and in adjacent areas, so no exposure area figure is
provided. Changes to the CSMs include:
• Exposure to coal combustion residual (CCR) constituents by Site workers is
considered incomplete, because Duke Energy maintains strict health and safety
requirements and training. The use of personal protective equipment (e.g., boots,
gloves, safety glasses) and other safety behaviors exhibited by Site workers limits
exposure to CCR constituents. Following conservative risk assessment practices,
the initial risk assessment report considered CCR constituent exposure pathways
for Site workers to be potentially complete. Further information has revealed
that on-Site worker exposure pathways are incomplete, and this risk assessment
update has been revised to reflect this change.
• Surface water sampling and sediment sampling of Lake Norman allows for
direct assessment of those areas, rather than using AOW data as a surrogate.
Results from samples of surface water, sediment, and groundwater were compared
with human health and ecological screening values (Attachments 1 and 2) to identify
constituents of potential concern (COPCs) for further review. Exposure point
concentrations (EPCs) were calculated for COPCs (Attachments 3 and 4) to incorporate
into human health and ecological risk models. Results of risk estimates (Attachments 5
and 6) are summarized below.
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

Page 3
2.0 SUMMARY OF RISK FINDINGS
2.1 Human Health
There is no exposure to residential receptors at MSS because no one lives on-Site or near
enough to the Site to be affected by groundwater migration from the ash basin.
Potential receptors off-Site are recreational users of Lake Norman, including swimmers,
waders, boaters, and fishers. However, background concentrations of the same
elements are greater or also present similar risks to the same potential receptors. Those
risks are not associated with the ash basin.
• There is no increase in cancer risks attributable to the ash basin associated with
the boater, swimmer, and wader exposure scenarios.
o There is no increase in cancer risks for the boater, swimmer, and wader
exposure scenarios attributable to the ash basin. Incorporating hexavalent
chromium concentrations in surface water samples collected since the
2018 CSA update produced modeled potential carcinogenic risks under
the boater, swimmer, and wader scenarios. However, surface water
hexavalent chromium concentrations detected in background surface
water samples (locations SW-7 and SW-8) were as much as 2.1 µg/L,
compared to the EPC calculated from sampling data for use in the risk
assessment of 0.5 µg/L.
o No evidence of non-carcinogenic risks for the recreational swimmer,
wader, or boater exposure scenarios associated with Lake Norman was
identified.
• There is no increase in cancer risks attributable to the ash basin associated with
the fisher exposure scenario.
o There is no increase in cancer risks for the fisher exposure scenario
attributable to the ash basin. Hexavalent chromium concentrations in
surface water produced modeled results of potential carcinogenic risks
under the recreational and subsistence fishing exposure scenarios.
However, surface water hexavalent chromium concentrations collected
from the upgradient stream (sample locations SW-7 and SW-8) were as
much as 2.1 µg/L, compared to the EPC calculated from sampling data for
use in the risk assessment of 0.5 µg/L. There is, therefore, no increase in
cancer risks due to the ash basin. Moreover, risk estimates from fish
consumption are based on CCR constituent concentrations in fish tissue
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

Page 4
modeled from concentrations detected in surface water. Thus, the
modeled concentration of hexavalent chromium in fish tissue is likely
overestimated. 1
o There is no material increase in non-carcinogenic risks for the fisher
exposure scenarios attributable to the ash basin. Potential non-
carcinogenic risks were modeled for the recreational and subsistence
fisher potentially exposed to cobalt detected in Lake Norman. Subsistence
fishing, defined by USEPA (2000) as ingestion of 170 grams (0.375 pounds)
of fish per day, has not been identified on Lake Norman.2 But even if
there were subsistence fishers using the water body, there would be no
material increase in risks to them posed by the ash basin. Concentrations
of cobalt in upgradient surface water (sample locations SW-7 and SW-8)
were as much as 3.5 µg/L, compared to the EPC used in the risk
assessment of 10 µg/L. When substituted into the risk model, the
background cobalt concentration would also result in estimated risks.
Moreover, risk estimates from fish consumption are based on CCR
constituent concentrations in fish tissue modeled from concentrations
detected in surface water. The modeled concentration of cobalt in fish
tissue is likely overestimated, due to conservative assumptions concerning
bioconcentration rates. This, together with conservative assumptions on
fish consumption rates, tends to overestimate risks.
• The updated risk assessment found no evidence of risks associated with
exposure to groundwater by Site workers. Trespasser exposure to AOWs was
not evaluated because AOWs are addressed in the SOC. There is therefore no
material increase in risks associated with onsite exposure scenarios.

1 For conservative estimation of hexavalent chromium concentrations in fish tissue, the recreational and
subsistence fisher exposure models used in this risk assessment assume a hexavalent chromium
bioconcentration factor (BCF) of 200 (NRCP, 1996). Bioconcentration is the process by which a chemical is
absorbed by an organism from the ambient environment through its respiratory and dermal surfaces
(Arnot and Gobus, 2006). The degree to which bioconcentration occurs is expressed as the BCF.
Published BCFs for hexavalent chromium in fish can be as low as one, suggesting that potential
bioconcentration in fish is low (USEPA, 1980; 1984; Fishbein, 1981; ATSDR, 2012). The conservative BCF
of 200 used here likely overestimates the hexavalent chromium concentration in fish tissue.
2 To put the fish ingestion rate into context, a 170 gram per day fish meal is approximately equal to six
ounces or approximately five fish sticks per meal (see http://gortons.com/product/original-batter-
tenders); it is assumed that the subsistence fisher catches this amount of fish in the local water body and
has such a fish meal once per day, every day for years.
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

Page 5
In summary, there is no material increase in risks to human health attributable to the
MSS ash basin.
2.2 Ecological
There is no evidence of ecological risks associated with Lake Norman and a tributary
(Exposure Area 1).
• In practice, ecological risks are quantified by comparing an average daily dose
(ADD) of a constituent to a toxicity reference value (TRV) for a given wildlife
receptor. The ratio of the ADD and TRV is the hazard quotient (HQ), where an
HQ less than unity (1) indicates no evidence of risks. TRVs are generally no-
observed-adverse-effects-levels (NOAEL) or a lowest-observed-adverse-effects-
levels (LOAEL) from toxicity studies published in scientific literature.
• No HQs that were based on NOAELs and LOAELs exceeded unity for the
wildlife receptors (mallard duck, great blue heron, bald eagle, muskrat, and river
otter) exposed to surface water and sediments.
In summary, there is no evidence of ecological risks attributable to the MSS ash basin.
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

Page 6
3.0 REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR). (2012). Toxicological
Profile for Chromium. Atlanta, GA: U.S. Department of Health and Human
Services, Public Health Service.
Arnot, J.A. and F.A.P.C. Gobus. (2006). A review of bioconcentration factor (BCF) and
bioaccumulation factor (BAF) assessments for organic chemicals in aquatic
organisms. Environmental Reviews 14: 257–297.
Fishbein, L. (1981). Sources, transport and alterations of metal compounds: an
overview. I. Arsenic, beryllium, cadmium, chromium, and nickel.
Environmental Health Perspectives 40: 43-64.
HDR. (2016). Corrective Action Plan Part 2 - Marshall Steam Station Ash Basin, March 3,
2016.
National Council on Radiation Protection and Measurements (NCRP). (1996).
Screening Models for Releases of Radionuclides to Atmosphere, Surface Water
and Ground. NCR Report No. 123. Cited in:
https://www.tn.gov/assets/entities/health/attachments/Screen.pdf
SynTerra. (2018). 2018 Comprehensive Site Assessment Update, January 31, 2018.
United States Environmental Protection Agency. (1980). Ambient water quality criteria
for chromium. Washington, D.C. EPA 440/5-80-035.
United States Environmental Protection Agency. (1984). Health assessment document
for chromium. Research Triangle Park, NC. EPA 600/8-83-014F.
United States Environmental Protection Agency. (1989). Risk Assessment Guidance for
Superfund: Volume 1 - Human Health Evaluation Manual (Part A). Office of
Emergency and Remedial Response, Washington, D.C. EPA/540/1-89/002.
United States Environmental Protection Agency. (1991). Risk Assessment Guidance for
Superfund: Volume 1 - Human Health Evaluation Manual (Part B, Development
of Risk-based Preliminary Remediation Goals). Office of Emergency and
Remedial Response, Washington, D.C. EPA/540/R-92/003.
United States Environmental Protection Agency. (1998). Guidelines for Ecological Risk
Assessment. Washington, D.C. EPA/630/R-95/002F.
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

Page 7
United States Environmental Protection Agency. (2000). Guidance for Assessing
Chemical Contaminant Data for Use in Fish Advisories. Volume 1, Fish
Sampling and Analysis, Third Edition. Office of Science and Technology, Office
of Water, Washington, D.C. EPA 823-B-00-007.
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

FIGURES
š(g)
š(g)
Active Coal Ash
Basin Post Excavation
Soil
AOWs (a)
Groundwater
Dust Outdoor Air
Soil Remaining
Post-Excavation
(b)
Surface Water
(Off-site)
(d)
Surface Water
(On -site)
(d)
Sediment
(Off-site)
(c)
Fish Tissue
(c)
Groundwater
Migration to
Surface Water
and Sediment
Inhalation
Incidental
Ingestion
Dermal Contact
Drinking Water
Use (e)
Incidental
Ingestion
Incidental
Ingestion
Dermal Contact
Incidental
Ingestion
Dermal Contact
Ingestion
Drinking Water
Use
Dermal Contact
Incidental
Ingestion
Potential
Exposure
Route
Current/
Future Off-Site
Resident
Adult/Child
Current/
Future On-Site
Recreational
Trespasser
Current/
Future Off-Site
Recreational
Swimmer
Current/
Future Off-Site
Recreational
Wader
Current/
Future Off-Site
Recreational
Boater
Current/
Future Off-Site
Recreational /
Subsistence
Fisher
Current/
Future On-site
Commercial/
Industrial
Worker
Current/
Future On-Site
Construction
Worker
š š š š
šš š š š
š š š š š
šš š š š
š š š
š š š š š š
š š š š š š
š š š š š š š
š š š š ˜š š
š š š
š š š š š
š š š š
Primary
Sources
Primary
Release
Mechanisms
Secondary
Sources
Secondary
Release
Mechanisms
Potential
Exposure
Media
Human Receptors
(g)
Incidental surface water ingestion assumed only to occur for receptors for the swimming and wading
scenarios.
Infiltration/
Leaching
Runoff/Flooding
Infiltration/
Leaching
Dermal Contact š š š ˜˜
AOW Water
(On -site)Dermal Contact š š š š
AOW Soil
(On -site)Dermal Contact
Sediment
(On -site)
(d)
Incidental
Ingestion
Dermal Contact
š š š š š
š š
š ˜(f)š š
˜
š
š
š
š
š š š š š
š š š š š
š š š š š
(e)
š
š
˜(f)
š
š
š š
š š
š
š
š
š
š š
š
š
š
š
š
š š š
š
(a)
Lake Norman is a source of public drinking water i.e., WS-IV , water is treated before use . There
are no private residences located hydraullically downgradient of on -site groundwater.
Areas of wetness (AOWs) are addressed in the Special Order by Consent (SOC ) and not
evaluated in the risk assessment update at this time .
(b)Pathway incomplete as long as ash remains in place ; re -evaluation upon excavation (if
conducted ) may be warranted.
(d)Site-wide data are used to evaluate on-site exposure.
(c)Concentration of COPC in fish tissue modeled from surface water concentration .
FIGURE 1
HUMAN HEALTH RISK ASSESSMENT
CONCEPTUAL SITE MODEL
MARSHALL STEAM STATION
TERRELL, NORTH CAROLINA
š š
š š
š
š
š
š
š
š
˜
(f)
Groundwater exposure evaluated in the risk assessment update , although an incomplete
exposure pathway for construction worker.
š
š
š š
š
š
š
Pathway evaluated and found incomplete /insignificant.
Potentially complete exposure pathway based on results of 2018 risk assessment
update.
š
˜
NOTES
š š š š
š š š š
š š š š š
š
š
š
š š š š
š
˜
š
š
š
š
š
š
š
š
š
š
MammalMammal
š š
˜˜
Red Fox
(Carnivore)
š
š
š
š
š
š
River Otter
(Piscivore )
š
š
š
š
š
Robin
(Omnivore)
š
š
š
š
š
š
š
š
š
š
Avian
š
TERRESTRIAL RECEPTORS (e)
Inhalation
Plant/Incidental
Ingestion
Direct Contact
Ingestion
Ingestion
Direct Contact
Plant/Incidental
Ingestion
Direct Contact
Ingestion
Direct Contact
Ingestion
Potential
Exposure Route Fish
š
š
Primary Sources Primary Release
Mechanisms
Secondary
Sources
Secondary Release
Mechanisms
Potential
Exposure Media
AQUATIC RECEPTORS
Direct Contact ˜(d)
Ingestion š
Plant/Incidental
Ingestion
Plant/Incidental
Ingestion
Direct Contact
š
š
š
š
š
š
š
š
š
Active Coal
Ash Basin Post Excavation
Soil
AOWs (a)
Groundwater
Dust Outdoor Air
Soil Remaining
Post-Excavation
(b)
Surface Water
(Off-site )
Surface Water
(On-site)
Sediment
(Off-site)
Fish Tissue
(c)
Groundwater
Migration to
Surface Water
and Sediment
Infiltration/
Leaching
Runoff/Flooding
Infiltration/
Leaching
AOW Water
(On-site)
AOW Soil
(On-site)
Sediment
(On-site)
˜
š
Potentially complete exposure pathways based on results o 2018 risk assessment
update.
Pathway evaluated and found incomplete/insignificant.
Benthic
Invertebrates Mallard
(Omnivore)
Great Blue
Heron
(Piscivore)
Muskrat
(Herbivore)
š š š
š š š š
š š š š
š š
š
˜(d)
˜(d)
š š
š š š
š š
š š š
š
š š š š
š š š š
š š š
š š š
š
š
š
š
š
Avian (f)
Meadow Vole
(Herbivore)
š
š
š š
˜˜˜š š
š
š
š
š
š
š
š
š
Red-Tailed
Hawk
(Carnivore)
š
š
˜
š
š
š
š
š
š
š
š
š
š
š š
˜˜š š
š
š
NOTES
(d)
(e)
š š š
š š š
š š
š š
š
FIGURE 2
ECOLOGICAL RISK ASSESSMENT
CONCEPTUAL SITE MODEL
MARSHALL STEAM STATION
TERRELL, NORTH CAROLINA
š š š š
š
š š
š š
Bald eagle (carnivore) included as a receptor associated with aquatic habitat.(f)
Areas of wetness (AOWs) are addressed in the Special Order by Consent (SOC) and not
evaluated in the risk assessment update at this time.
Pathway incomplete as long as ash remains in place; re-evaluation upon excavation (if
conducted) may be warranted.
Concentration of COPC in fish tissue modeled from surface water concentration.
Based on screening against aquatic life criteria.
Exposure to terrestrial receptors was not evaluated because AOWs are addressed in the SOC.
(a)
(b)
(c)
")
")
")
")
")
")
")
")
")
")
")
")
")
")
")
")
")
")
H_2_HCA
SW-6
H_2_UP
H_2_DN
F_2_DN
SW-12
FG D RESIDUELANDFILL
PV STRU CTURALFILL
IND USTRIALLANDFILL #1
C&DLANDFILL
AS H LA NDFILL(PH AS E II)
ASH LA NDFILL(PH ASE I)
ASBESTOSLANDFILL
ACC ES S ROADSTRUCTURALFILL
ASH BASIN
LA KE N ORMAN
MARSHALL RD
GREENWOOD RDBEATTY RDSHERRI
LLS FORD RDS T A T E H W Y 1 5 0
S T A T E H W Y 1 5 0
R A ILR O ADR
A
IL
R
OA
D
EXPOSUREAREA 1
EXPOSUREAREA 2(SEE NOTE 3)
SW-5
SW-1(LAN DFILL)
SW-4
SW-3
SW-11
SW-8
SW-7
SW-9
SW-10
SW-1(CA MA)
SW-2
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community
NOTES:
1. GENERA LIZED AREAL E XTENT OF MIGRATION REPRESENTED BY NCAC 02LEXCEEDANCES OF MULTIPL E CONS TITUENTS IN MULTIPLE FLOW ZONES.
2. TWO E XPOSURE AREAS WERE DEVELOPED TO EVALUATE ECOLOGICALEXPOSURE TO SURFACE WATER AND SEDIMENT. THE EXPOSURE AREASCONSIDER ECOL OGICA L HABITATS, NE ARBY WATER BODIES, AND WET AREAS.
3. ECOL OGICAL EXPOSURE ARE A 2 IS CONSIDERED BACKGROUND AND WAS NOTEVALUATED.
4. NATURAL RESOURCES TECHNICAL REPORT (NRTR) PREPARED BY AMEC FOSTERWHEELER, INC., JUNE 19, 2015.
5. WETLA ND DE LIN EATION SURVEY CONDUCTED BY MCKIM AND CREED, MARCH2016.
6. PROPE RTY BOUNDARY PROVIDED BY DUKE ENERGY CAROLINAS.
7. AERIAL PHOTOGRAPHY OBTAINE D F ROM GOOGLE EARTH PRO ON SEPTEMBER12, 2017. IMAGE COLLECTED ON OCTOBER 8, 2016.
8. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATEPLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011).
FIGURE 3HUMAN HEALTH ANDECOLOGICAL EXPOSURE AREASMARSHALL STEAM STATIONDUKE ENERGY CAROLINAS, LLCTERRELL, NORTH CAROLINADRAWN BY: A. FEIGLPROJECT MANAGER: B. WILKERCHECKED BY: C. PONCE
DATE: 11/06/2018
148 RIVER STREET, SUITE 220GREENVILLE, SOUTH CAROLINA 29601PHONE [phone]www.synterracorp.com
P:\Duke Energy Progress.1026\00 GIS B ASE DATA\Marshall\Mapdocs\MISC\RiskAssessment\Fig03_Marshall_ExposureAreas.mxd
900 0 900 1,800450
GRAP HIC S CALE IN FEET
")SU RFACE WATER LOCATION
EXPOSURE AREA 1
EXPOSURE AREA 2
AR EA OF CONCENTRATION IN GROUNDWATERABOVE NC2L (SEE NOTES)ASH BASIN WASTE BOUNDARY
ASH BASIN C OMPLIANCE BOUNDARY
LANDFILL BOUNDARYSTRUCTURAL FILL BOUNDARY
LANDFILL COMPLIANCE BOUNDARY
DUKE ENERGY CAROLINAS MARSHALL PLANTSITE BOUNDARY
<STREAM (AMEC NRTR 2015)
WETLAND (MCKIM AND CREED 2016)
LEGEND
Risk Assessment Summary Update November 2018
Marshall Steam Station SynTerra

ATTACHMENTS
TABLE 1-1
HUMAN HEALTH SCREENING - GROUNDWATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Min.Max.
Aluminum 7429-90-5 997 573 6 54,500 54,500 NA NA 3,500 50 to 200 (i)4,000 3,500 Y
Antimony 7440-36-0 1,438 299 0.1 9.7 9.7 1 NA 1 6 1.56 (m)1 Y
Arsenic 7440-38-2 1,854 1,158 0.04 973 973 10 NA 10 10 0.052 (h,jj)10 Y
Barium 7440-39-3 1,855 1,855 8.3 2,830 2,830 700 NA 700 2,000 760 700 Y
Beryllium 7440-41-7 1,308 662 0.01 9.9 9.9 NA 4 4 4 5 4 Y
Boron 7440-42-8 1,753 844 3.3 30,900 30,900 700 NA 700 NA 800 700 Y
Cadmium 7440-43-9 1,855 335 0.024 7.5 7.5 2 NA 2 5 1.84 2 Y
Chromium (Total)7440-47-3 1,855 1,375 0.091 202 202 10 NA 10 100 4,400 (n)10 Y
Chromium (VI)18540-29-9 781 605 0.0087 142 142 NA NA 0.07 NA 0.035 (jj)0.07 Y
Cobalt 7440-48-4 1,308 1,127 0.01 216 216 NA 1 1 NA 1.2 1 Y
Copper 7440-50-8 1,568 913 0.11 1,700 1,700 1,000 NA 1,000 1,300 (k)160 1,000 Y
Lead 7439-92-1 1,855 677 0 18.61 18.61 15 NA 15 15 (l)15 (jj)15 Y
Lithium 7439-93-2 470 445 0.16 748 748 NA NA NA NA 8 8 Y
Manganese 7439-96-5 1,568 1,393 0 12,900 12,900 50 NA 200 50 (i)86 50 Y
Mercury 7439-97-6 1,855 145 0.007 1.2 1.2 1 NA 1 2 1.14 (o)1 Y
Molybdenum 7439-98-7 1,284 854 0.081 103 103 NA NA 18 NA 20 18 Y
Nickel 7440-02-0 1,465 944 0.13 173 173 100 NA 100 NA 78 (p)100 Y
Selenium 7782-49-2 1,855 671 0.092 119 119 20 NA 20 50 20 20 Y
Strontium 7440-24-6 987 979 3.7 18,700 18,700 NA NA 2,100 NA 2,400 2,100 Y
Thallium 7440-28-0 1,438 407 0.015 3.6 3.6 0.2 NA 0.2 2 0.04 (q)0.2 Y
Vanadium 7440-62-2 1,011 870 0.069 57.5 57.5 NA NA 0.3 NA 17.2 0.3 Y
Zinc 7440-66-6 1,568 833 0 315 315 1 NA 1 5,000 (i)1,200 1 Y
Notes:
AWQC - Ambient Water Quality Criteria DENR - Department of Environment and Natural Resources NC - North Carolina su - Standard units
CAMA - Coal Ash Management Act DHHS - Department of Health and Human Services NCAC - North Carolina Administrative Code µg/L - micrograms/liter
North Carolina Session Law 2014-122, ESV - Ecological Screening Value ORNL - Oak Ridge National Laboratory USEPA - United States Environmental Protection Agency
HH - Human Health PSRG - Preliminary Soil Remediation Goal WS - Water Supply
/Senate/PDF/S729v7.pdf HI - Hazard Index Q - Qualifier < - Concentration not detected at or above the reporting limit
CAS - Chemical Abstracts Service IMAC - Interim Maximum Allowable Concentration RSL - Regional Screening Level j - Indicates concentration reported below Practical Quantitation Limit
CCC - Criterion Continuous Concentration MCL - Maximum Contaminant Level RSV - Refinement Screening Value (PQL) but above Method Detection Limit (MDL) and therefore concentration is estimated
CMC - Criterion Maximum Concentration mg/kg - milligrams/kilogram SMCL - Secondary Maximum Contaminant Level
COPC - Constituent of Potential Concern NA - Not Available SSL - Soil Screening Level
Concentration
Used for
Screening
(µg/L)
15A NCAC 02L
.0202 Standard
(e)
(µg/L)
15A NCAC
02L .0202
IMAC (e)
(µg/L)
DHHS
Screening
Level (d)
(µg/L)
Federal MCL/
SMCL (c)
(µg/L)
Tap Water RSL
HI = 0.2 (a)
(µg/L)
Screening
Value Used
(µg/L)
Number of
Samples
Frequency of
Detection
Range of Detection
(µg/L)COPC?Analyte CAS
http://www.ncleg.net/Sessions/2013/Bills
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted Prepared by: HEG Checked by: HES
Page 1 of 2
TABLE 1-1
HUMAN HEALTH SCREENING - GROUNDWATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
(a) - USEPA Regional Screening Levels (May 2018). Values for Residential Soil, Industrial Soil, and Tap Water. HI = 0.2. Accessed October 2018.
https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables
(b) - USEPA National Recommended Water Quality Criteria. USEPA Office of Water and Office of Science and Technology. Accessed October 2018.
https://www.epa.gov/wqc/national-recommended-water-quality-criteria-human-health-criteria-table
USEPA AWQC Human Health for the Consumption of Organism Only apply to total concentrations.
(c) - USEPA 2018 Edition of the Drinking Water Standards and Health Advisories. March 2018. Accessed October 2018.
https://www.epa.gov/sites/production/files/2018-03/documents/dwtable2018.pdf
(d) - DHHS Screening Levels. Department of Health and Human Services, Division of Public Health, Epidemiology Section, Occupational and Environmental
Epidemiology Branch. http://portal.ncdenr.org/c/document_library/get_file?p_l_id=1169848&folderId=24814087&name=DLFE-112704.pdf
(e) - North Carolina 15A NCAC 02L .0202 Groundwater Standards & IMACs. http://portal.ncdenr.org/c/document_library/get_file?uuid=1aa3fa13-2c0f-45b7-ae96-5427fb1d25b4&groupId=38364
Amended April 2013.
(f) - North Carolina 15A NCAC 02B Surface Water and Wetland Standards. Amended January 1, 2015.
http://reports.oah.state.nc.us/ncac/title%2015a%20-%20environmental%20quality/chapter%2002%20-%20environmental%20management/subchapter%20b/subchapter%20b%20rules.pdf
WS standards are applicable to all Water Supply Classifications. WS standards are based on the consumption of fish and water.
Human Health Standards are based on the consumption of fish only unless dermal contact studies are available.
For Class C, use the most stringent of freshwater (or, if applicable, saltwater) column and the Human Health column.
For a WS water, use the most stringent of Freshwater, WS and Human Health. Likewise, Trout Waters and High Quality Waters must adhere to the most stingent of all applicable standards.
(g) - USEPA Region 4. 2018. Region 4 Ecological Risk Assessment Supplemental Guidance. March 2018 Update.
https://www.epa.gov/sites/production/files/2018-03/documents/era_regional_supplemental_guidance_report-march-2018_update.pdf
(h) - Value applies to inorganic form of arsenic only.
(i) - Value is the Secondary Maximum Contaminant Level.
https://www.epa.gov/dwstandardsregulations/secondary-drinking-water-standards-guidance-nuisance-chemicals
(j) - Value for Total Chromium.
(k) - Copper Treatment Technology Action Level is 1.3 mg/L.
(l) - Lead Treatment Technology Action Level is 0.015 mg/L.
(m) - RSL for Antimony (metallic) used for Antimony.
(n) - Value for Chromium (III), Insoluble Salts used for Chromium.
(o) - RSL for Mercuric Chloride used for Mercury.
(p) - RSL for Nickel Soluble Salts used for Nickel.
(q) - RSL for Thallium (Soluble Salts) used for Thallium.
(r) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(s) - Value for Inorganic Mercury.
(t) - Acute AWQC is equal to 1/[(f1/CMC1) + (f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated as selenite and selenate, respectively, and
CMC1 and CMC2 are 185.9 µ/gL and 12.82 µ/gL, respectively. Calculated assuming that all selenium is present as selenate, a likely overly conservative assumption.
(u) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(v) - Chloride Action Level for Toxic Substances Applicable to NPDES Permits is 230,000 µ/gL.
(w) - Applicable only to persons with a sodium restrictive diet.
(x) - Los Alamos National Laboratory ECORISK Database. http://www.lanl.gov/community-environment/environmental-stewardship/protection/eco-risk-assessment.php
(y) - Long, Edward R., and Lee G. Morgan. 1991. The Potential for Biological Effects of Sediment-Sorbed Contaminants Tested in the National Status and Trends Program.
NOAA Technical Memorandum NOS OMA 52. Used effects range low (ER-L) for chronic and effects range medium (ER-M) for acute.
(z) - MacDonald, D.D.; Ingersoll, C.G.; Smorong, D.E.; Lindskoog, R.A.; Sloane, G.; and T. Bernacki. 2003. Development and Evaluation of Numerical Sediment Quality Assessment Guidelines for
Florida Inland Waters. Florida Department of Environmental Protection, Tallahassee, FL. Used threshold effect concentration (TEC) for the ESV and probable effect concentration (PEC) for the RSV.
(aa) - Persaud, D., R. Jaagumagi and A. Hayton. 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario. Ontario Ministry of the Environment. Queen's Printer of Ontario.
(bb) - Los Alamos National Laboratory ECORISK Database. September 2017. http://www.lanl.gov/environment/protection/eco-risk-assessment.php (µg/kg dw)
(cc) - Great Lakes Initiative (GLI) Clearinghouse resources Tier II criteria revised 2013. http://www.epa.gov/gliclearinghouse/
(dd) - Suter, G.W., and Tsao, C.L. 1996. Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota: 1996 Revision. ES/ER/TM-96/R2.
http://www.esd.ornl.gov/programs/ecorisk/documents/tm96r2.pdf
(ee) - USEPA. Interim Ecological Soil Screening Level Documents. Accessed October 2018. http://www2.epa.gov/chemical-research/interim-ecological-soil-screening-level-documents
(ff) - Efroymson, R.A., M.E. Will, and G.W. Suter II, 1997a. Toxicological Benchmarks for Contaminants of Potential Concern for Effects on Soil and Litter Invertebrates and Heterotrophic Process:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-126/R2. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm126r21.pdf)
(gg) - Efroymson, R.A., M.E. Will, G.W. Suter II, and A.C. Wooten, 1997b. Toxicological Benchmarks for Screening Contaminants of Potential Concern for Effects on Terrestrial Plants:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-85/R3. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm85r3.pdf)
(hh) - North Carolina Preliminary Soil Remediation Goals (PSRG) Table. HI = 0.2. September 2015. http://portal.ncdenr.org/c/document_library/get_file?uuid=0f601ffa-574d-4479-bbb4-253af0665bf5&groupId=38361
as part of a risk assessment based on potential toxic effects, therefore; pH was not investigated further as a category 1 COPC. Water quality relative to pH will be addressed as a component of water quality monitoring programs for the site.
(jj) - Hazard Index = 0.1
(ii) - As part of the water quality evaluation conducted under the CSA, pH was measured and is reported as a metric data set. The pH comparison criteria are included as ranges as opposed to single screening values. pH is not typically included
Page 2 of 2
TABLE 1-2
HUMAN HEALTH SCREENING - SEDIMENT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Min.Max.
Aluminum 7429-90-5 1 1 NA 12,900 12,900 15,000 15,400 100,000 220,000 15,000 100,000 N N
Antimony 7440-36-0 1 0 ND ND ND 6.2 (m)6.2 (m)94 (m)94 (m)6.2 94 N N
Arsenic 7440-38-2 1 0 ND ND ND 0.68 (h)0.68 (h, jj)3 (h)3 (h, jj)0.68 3 N N
Barium 7440-39-3 1 1 NA 128 128 3,000 3,000 44,000 44,000 3,000 44,000 N N
Beryllium 7440-41-7 1 1 NA 0.93 0.93 32 32 460 460 32 460 N N
Boron 7440-42-8 1 0 ND ND ND 3,200 3,200 46,000 46,000 3,200 46,000 N N
Cadmium 7440-43-9 1 0 ND ND ND 14 14.2 200 196 14 200 N N
Chromium (III)16065-83-1 1 1 NA 45.6 45.6 24,000 24,000 100,000 360,000 24,000 100,000 N N
Cobalt 7440-48-4 1 1 NA 11.3 11.3 4.6 4.6 70 70 4.6 70 Y N
Copper 7440-50-8 1 1 NA 11.4 11.4 620 620 9,400 9,400 620 9,400 N N
Lead 7439-92-1 1 1 NA 9.2 9.2 400 400 (jj)800 800 (jj)400 800 N N
Manganese 7439-96-5 1 1 NA 115 115 360 360 5,200 5,200 360 5,200 N N
Mercury 7439-97-6 1 1 NA 0.021 0.021 4.6 (o)4.6 (o)3.1 (o)70 (o)4.6 3.1 N N
Molybdenum 7439-98-7 1 0 ND ND ND 78 78 1,200 1,160 78 1,200 N N
Nickel 7440-02-0 1 1 NA 18.7 18.7 300 (p)300 (p)4,400 (p)4,400 (p)300 4,400 N N
Selenium 7782-49-2 1 1 NA 4.1 4.1 78 78 1,200 1,160 78 1,200 N N
Strontium 7440-24-6 1 1 NA 38 38 9,400 9,400 100,000 140,000 9,400 100,000 N N
Thallium 7440-28-0 1 0 ND ND ND 0.16 (q)0.156 (q)2.4 (q)2.4 (q)0.16 2.4 N N
Vanadium 7440-62-2 1 1 NA 59.7 59.7 78 78 1,160 1,160 78 1,160 N N
Zinc 7440-66-6 1 1 NA 32.8 32.8 4,600 4,600 70,000 70,000 4,600 70,000 N N
Notes:
AWQC - Ambient Water Quality Criteria DENR - Department of Environment and Natural Resources NC - North Carolina su - Standard units
CAMA - Coal Ash Management Act DHHS - Department of Health and Human Services NCAC - North Carolina Administrative Code µg/L - micrograms/liter
North Carolina Session Law 2014-122, ESV - Ecological Screening Value ORNL - Oak Ridge National Laboratory USEPA - United States Environmental Protection Agency
HH - Human Health PSRG - Preliminary Soil Remediation Goal WS - Water Supply
/Senate/PDF/S729v7.pdf HI - Hazard Index Q - Qualifier < - Concentration not detected at or above the reporting limit
CAS - Chemical Abstracts Service IMAC - Interim Maximum Allowable Concentration RSL - Regional Screening Level j - Indicates concentration reported below Practical Quantitation Limit
CCC - Criterion Continuous Concentration MCL - Maximum Contaminant Level RSV - Refinement Screening Value (PQL) but above Method Detection Limit (MDL) and therefore concentration is estimated
CMC - Criterion Maximum Concentration mg/kg - milligrams/kilogram SMCL - Secondary Maximum Contaminant Level
COPC - Constituent of Potential Concern NA - Not Available SSL - Soil Screening Level
(a) - USEPA Regional Screening Levels (May 2018). Values for Residential Soil, Industrial Soil, and Tap Water. HI = 0.2. Accessed October 2018.
https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables
(b) - USEPA National Recommended Water Quality Criteria. USEPA Office of Water and Office of Science and Technology. Accessed October 2018.
https://www.epa.gov/wqc/national-recommended-water-quality-criteria-human-health-criteria-table
USEPA AWQC Human Health for the Consumption of Organism Only apply to total concentrations.
(c) - USEPA 2018 Edition of the Drinking Water Standards and Health Advisories. March 2018. Accessed October 2018.
https://www.epa.gov/sites/production/files/2018-03/documents/dwtable2018.pdf
(d) - DHHS Screening Levels. Department of Health and Human Services, Division of Public Health, Epidemiology Section, Occupational and Environmental
Epidemiology Branch. http://portal.ncdenr.org/c/document_library/get_file?p_l_id=1169848&folderId=24814087&name=DLFE-112704.pdf
Analyte CAS
Number
of
Samples
Frequency
of
Detection
Concentration
Used for
Screening
(mg/kg)
Range of Detection
(mg/kg)
NC PSRG
Residential Health
Screening Level
(hh)
(mg/kg)
Residential Soil
RSL (a)
HI = 0.2
(mg/kg)
NC PSRG
Industrial Health
Screening Level
(hh)
(mg/kg)
Industrial Soil
RSL (a)
HI = 0.2
(mg/kg)
Residential
Screening
Value Used
(mg/kg)
Industrial
Screening
Value Used
(mg/kg)
http://www.ncleg.net/Sessions/2013/Bills
Industrial
COPC?
Residential
COPC?
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted Prepared by: HEG Checked by: HES
Page 1 of 2
TABLE 1-2
HUMAN HEALTH SCREENING - SEDIMENT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
(e) - North Carolina 15A NCAC 02L .0202 Groundwater Standards & IMACs. http://portal.ncdenr.org/c/document_library/get_file?uuid=1aa3fa13-2c0f-45b7-ae96-5427fb1d25b4&groupId=38364
Amended April 2013.
(f) - North Carolina 15A NCAC 02B Surface Water and Wetland Standards. Amended January 1, 2015.
http://reports.oah.state.nc.us/ncac/title%2015a%20-%20environmental%20quality/chapter%2002%20-%20environmental%20management/subchapter%20b/subchapter%20b%20rules.pdf
WS standards are applicable to all Water Supply Classifications. WS standards are based on the consumption of fish and water.
Human Health Standards are based on the consumption of fish only unless dermal contact studies are available.
For Class C, use the most stringent of freshwater (or, if applicable, saltwater) column and the Human Health column.
For a WS water, use the most stringent of Freshwater, WS and Human Health. Likewise, Trout Waters and High Quality Waters must adhere to the most stingent of all applicable standards.
(g) - USEPA Region 4. 2018. Region 4 Ecological Risk Assessment Supplemental Guidance. March 2018 Update.
https://www.epa.gov/sites/production/files/2018-03/documents/era_regional_supplemental_guidance_report-march-2018_update.pdf
(h) - Value applies to inorganic form of arsenic only.
(i) - Value is the Secondary Maximum Contaminant Level.
https://www.epa.gov/dwstandardsregulations/secondary-drinking-water-standards-guidance-nuisance-chemicals
(j) - Value for Total Chromium.
(k) - Copper Treatment Technology Action Level is 1.3 mg/L.
(l) - Lead Treatment Technology Action Level is 0.015 mg/L.
(m) - RSL for Antimony (metallic) used for Antimony.
(n) - Value for Chromium (III), Insoluble Salts used for Chromium.
(o) - RSL for Mercuric Chloride used for Mercury.
(p) - RSL for Nickel Soluble Salts used for Nickel.
(q) - RSL for Thallium (Soluble Salts) used for Thallium.
(r) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(s) - Value for Inorganic Mercury.
(t) - Acute AWQC is equal to 1/[(f1/CMC1) + (f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated as selenite and selenate, respectively, and
CMC1 and CMC2 are 185.9 µg/L and 12.82 µg/L, respectively. Calculated assuming that all selenium is present as selenate, a likely overly conservative assumption.
(u) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(v) - Chloride Action Level for Toxic Substances Applicable to NPDES Permits is 230,000 µg/L.
(w) - Applicable only to persons with a sodium restrictive diet.
(x) - Los Alamos National Laboratory ECORISK Database. http://www.lanl.gov/community-environment/environmental-stewardship/protection/eco-risk-assessment.php
(y) - Long, Edward R., and Lee G. Morgan. 1991. The Potential for Biological Effects of Sediment-Sorbed Contaminants Tested in the National Status and Trends Program.
NOAA Technical Memorandum NOS OMA 52. Used effects range low (ER-L) for chronic and effects range medium (ER-M) for acute.
(z) - MacDonald, D.D.; Ingersoll, C.G.; Smorong, D.E.; Lindskoog, R.A.; Sloane, G.; and T. Bernacki. 2003. Development and Evaluation of Numerical Sediment Quality Assessment Guidelines for
Florida Inland Waters. Florida Department of Environmental Protection, Tallahassee, FL. Used threshold effect concentration (TEC) for the ESV and probable effect concentration (PEC) for the RSV.
(aa) - Persaud, D., R. Jaagumagi and A. Hayton. 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario. Ontario Ministry of the Environment. Queen's Printer of Ontario.
(bb) - Los Alamos National Laboratory ECORISK Database. September 2017. http://www.lanl.gov/environment/protection/eco-risk-assessment.php (µg/kg dw)
(cc) - Great Lakes Initiative (GLI) Clearinghouse resources Tier II criteria revised 2013. http://www.epa.gov/gliclearinghouse/
(dd) - Suter, G.W., and Tsao, C.L. 1996. Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota: 1996 Revision. ES/ER/TM-96/R2.
http://www.esd.ornl.gov/programs/ecorisk/documents/tm96r2.pdf
(ee) - USEPA. Interim Ecological Soil Screening Level Documents. Accessed October 2018. http://www2.epa.gov/chemical-research/interim-ecological-soil-screening-level-documents
(ff) - Efroymson, R.A., M.E. Will, and G.W. Suter II, 1997a. Toxicological Benchmarks for Contaminants of Potential Concern for Effects on Soil and Litter Invertebrates and Heterotrophic Process:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-126/R2. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm126r21.pdf)
(gg) - Efroymson, R.A., M.E. Will, G.W. Suter II, and A.C. Wooten, 1997b. Toxicological Benchmarks for Screening Contaminants of Potential Concern for Effects on Terrestrial Plants:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-85/R3. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm85r3.pdf)
(hh) - North Carolina Preliminary Soil Remediation Goals (PSRG) Table. HI = 0.2. September 2015. http://portal.ncdenr.org/c/document_library/get_file?uuid=0f601ffa-574d-4479-bbb4-253af0665bf5&groupId=38361
as part of a risk assessment based on potential toxic effects, therefore; pH was not investigated further as a category 1 COPC. Water quality relative to pH will be addressed as a component of water quality monitoring programs for the site.
(jj) - Hazard Index = 0.1
(ii) - As part of the water quality evaluation conducted under the CSA, pH was measured and is reported as a metric data set. The pH comparison criteria are included as ranges as opposed to single screening values. pH is not typically included
Page 2 of 2
TABLE 1-3
HUMAN HEALTH SCREENING - SURFACE WATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Min.Max.
Aluminum 7429-90-5 22 17 57.5 701 701 NA NA NA NA NA NA 50 to 200 (i)4,000 50 Y
Antimony 7440-36-0 23 14 0.11 0.75 0.75 1 NA NA NA 5.6 640 6 1.56 (m)1 N
Arsenic 7440-38-2 28 23 0.16 2.4 2.4 10 NA 10 10 0.018 (h)0.14 (h)10 0.052 (h, jj)10 N
Barium 7440-39-3 28 28 12.7 140 140 700 NA 1,000 NA 1,000 NA 2,000 760 700 N
Beryllium 7440-41-7 23 10 0.014 0.17 0.17 NA 4 NA NA NA NA 4 5 4 N
Boron 7440-42-8 28 24 46.1 3,500 3,500 700 NA NA NA NA NA NA 800 700 Y
Cadmium 7440-43-9 28 5 0.028 0.086 0.086 2 NA NA NA NA NA 5 1.84 2 N
Chromium (Total)7440-47-3 28 20 0.12 1.1 1.1 10 NA NA NA NA NA 100 4,400 (n)10 N
Chromium (VI)18540-29-9 20 12 0.016 1.1 1.1 NA NA NA NA NA NA NA 0.035 (jj)0.035 Y
Cobalt 7440-48-4 23 21 0.068 24.6 24.6 NA 1 NA NA NA NA NA 1.2 1 Y
Copper 7440-50-8 28 26 0.13 7.4 7.4 1,000 NA NA NA 1,300 NA 1,300 (k)160 1,000 N
Lead 7439-92-1 28 14 0.053 0.73 0.73 15 NA NA NA NA NA 15 (l)15 (jj)15 N
Lithium 7439-93-2 4 2 0.56 0.59 0.59 NA NA NA NA NA NA NA 8 8 N
Manganese 7439-96-5 23 23 18.4 1,600 1,600 50 NA 200 NA 50 100 50 (i)86 50 Y
Mercury 7439-97-6 28 27 4.39E-04 0.0082 0.0082 1 NA NA NA NA NA 2 1.14 (o)1 N
Molybdenum 7439-98-7 23 17 0.09 2.6 2.6 NA NA NA NA NA NA NA 20 20 N
Nickel 7440-02-0 28 13 0.24 12.7 12.7 100 NA 25 NA 610 4,600 NA 78 (p)100 N
Selenium 7782-49-2 28 8 0.25 2 2 20 NA NA NA 170 4,200 50 20 20 N
Strontium 7440-24-6 23 23 25.7 1,800 1,800 NA NA NA NA NA NA NA 2,400 2,400 N
Thallium 7440-28-0 28 8 0.018 0.11 0.11 0.2 NA NA NA 0.24 0.47 2 0.04 (q)0.2 N
Vanadium 7440-62-2 23 21 0.23 2.4 2.4 NA NA NA NA NA NA NA 17.2 17 N
Zinc 7440-66-6 28 12 2.7 9.2 9.2 1 NA NA NA 7,400 26,000 5,000 (i)1,200 1 Y
Notes:
AWQC - Ambient Water Quality Criteria DENR - Department of Environment and Natural Resources NA - Not Available SMCL - Secondary Maximum Contaminant Level
CAMA - Coal Ash Management Act DHHS - Department of Health and Human Services NC - North Carolina SSL - Soil Screening Level
North Carolina Session Law 2014-122, ESV - Ecological Screening Value NCAC - North Carolina Administrative Code su - Standard units
http://www.ncleg.net/Sessions/2013/Bills/Senate/PDF/S729v7.pdf HH - Human HealtH ORNL - Oak Ridge National Laboratory µg/L - micrograms/liter
CAS - Chemical Abstracts Service HI - Hazard Index PSRG - Preliminary Soil Remediation Goal USEPA - United States Environmental Protection Agency
CCC - Criterion Continuous Concentration IMAC - Interim Maximum Allowable Concentration Q - Qualifier WS - Water Supply
CMC - Criterion Maximum Concentration MCL - Maximum Contaminant Level RSL - Regional Screening Level < - Concentration not detected at or above the reporting limit
COPC - Constituent of Potential Concern mg/kg - milligrams/kilogram RSV - Refinement Screening Value
Screening
Value Used
(µg/L)
15A NCAC 02B
Water Supply
(WS) (f)
(µg/L)
COPC?Analyte CAS Number of
Samples
Frequency of
Detection
Prepared by: HEG Checked by: HES* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted.
15A NCAC 02B
Human Health
(HH) (f)
(µg/L)
USEPA AWQC
Consumption
of Water and
Organism (b)
(µg/L)
USEPA AWQC
Consumption
of Organism
Only (b)
(µg/L)
Range of
Detection
(µg/L)
15A NCAC 02L
.0202 Standard
(e)
(µg/L)
15A NCAC 02L
.0202 IMAC
(e)
(µg/L)
Federal MCL/
SMCL (c)
(µg/L)
Tap Water RSL
HI = 0.2 (a)
(µg/L)
Concentration
Used for
Screening (µg/L)
Page 1 of 2
TABLE 1-3
HUMAN HEALTH SCREENING - SURFACE WATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
(a) - USEPA Regional Screening Levels (May 2018). Values for Residential Soil, Industrial Soil, and Tap Water. HI = 0.2. Accessed October 2018.
https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables
(b) - USEPA National Recommended Water Quality Criteria. USEPA Office of Water and Office of Science and Technology. Accessed October 2018.
https://www.epa.gov/wqc/national-recommended-water-quality-criteria-human-health-criteria-table
USEPA AWQC Human Health for the Consumption of Organism Only apply to total concentrations.
(c) - USEPA 2018 Edition of the Drinking Water Standards and Health Advisories. March 2018. Accessed October 2018.
https://www.epa.gov/sites/production/files/2018-03/documents/dwtable2018.pdf
(d) - DHHS Screening Levels. Department of Health and Human Services, Division of Public Health, Epidemiology Section, Occupational and Environmental
Epidemiology Branch. http://portal.ncdenr.org/c/document_library/get_file?p_l_id=1169848&folderId=24814087&name=DLFE-112704.pdf
(e) - North Carolina 15A NCAC 02L .0202 Groundwater Standards & IMACs. http://portal.ncdenr.org/c/document_library/get_file?uuid=1aa3fa13-2c0f-45b7-ae96-5427fb1d25b4&groupId=38364
Amended April 2013.
(f) - North Carolina 15A NCAC 02B Surface Water and Wetland Standards. Amended January 1, 2015.
http://reports.oah.state.nc.us/ncac/title%2015a%20-%20environmental%20quality/chapter%2002%20-%20environmental%20management/subchapter%20b/subchapter%20b%20rules.pdf
WS standards are applicable to all Water Supply Classifications. WS standards are based on the consumption of fish and water.
Human Health Standards are based on the consumption of fish only unless dermal contact studies are available.
For Class C, use the most stringent of freshwater (or, if applicable, saltwater) column and the Human Health column.
For a WS water, use the most stringent of Freshwater, WS and Human Health. Likewise, Trout Waters and High Quality Waters must adhere to the most stingent of all applicable standards.
(g) - USEPA Region 4. 2018. Region 4 Ecological Risk Assessment Supplemental Guidance. March 2018 Update.
https://www.epa.gov/sites/production/files/2018-03/documents/era_regional_supplemental_guidance_report-march-2018_update.pdf
(h) - Value applies to inorganic form of arsenic only.
(i) - Value is the Secondary Maximum Contaminant Level.
https://www.epa.gov/dwstandardsregulations/secondary-drinking-water-standards-guidance-nuisance-chemicals
(j) - Value for Total Chromium.
(k) - Copper Treatment Technology Action Level is 1.3 mg/L.
(l) - Lead Treatment Technology Action Level is 0.015 mg/L.
(m) - RSL for Antimony (metallic) used for Antimony.
(n) - Value for Chromium (III), Insoluble Salts used for Chromium.
(o) - RSL for Mercuric Chloride used for Mercury.
(p) - RSL for Nickel Soluble Salts used for Nickel.
(q) - RSL for Thallium (Soluble Salts) used for Thallium.
(r) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(s) - Value for Inorganic Mercury.
(t) - Acute AWQC is equal to 1/[(f1/CMC1) + (f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated as selenite and selenate, respectively, and
CMC1 and CMC2 are 185.9 µg/L and 12.82 µg/L, respectively. Calculated assuming that all selenium is present as selenate, a likely overly conservative assumption.
(u) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(v) - Chloride Action Level for Toxic Substances Applicable to NPDES Permits is 230,000 µg/L.
(w) - Applicable only to persons with a sodium restrictive diet.
(x) - Los Alamos National Laboratory ECORISK Database. http://www.lanl.gov/community-environment/environmental-stewardship/protection/eco-risk-assessment.php
(y) - Long, Edward R., and Lee G. Morgan. 1991. The Potential for Biological Effects of Sediment-Sorbed Contaminants Tested in the National Status and Trends Program.
NOAA Technical Memorandum NOS OMA 52. Used effects range low (ER-L) for chronic and effects range medium (ER-M) for acute.
(z) - MacDonald, D.D.; Ingersoll, C.G.; Smorong, D.E.; Lindskoog, R.A.; Sloane, G.; and T. Bernacki. 2003. Development and Evaluation of Numerical Sediment Quality Assessment Guidelines for
Florida Inland Waters. Florida Department of Environmental Protection, Tallahassee, FL. Used threshold effect concentration (TEC) for the ESV and probable effect concentration (PEC) for the RSV.
(aa) - Persaud, D., R. Jaagumagi and A. Hayton. 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario. Ontario Ministry of the Environment. Queen's Printer of Ontario.
(bb) - Los Alamos National Laboratory ECORISK Database. September 2017. http://www.lanl.gov/environment/protection/eco-risk-assessment.php (µg/kg dw)
(cc) - Great Lakes Initiative (GLI) Clearinghouse resources Tier II criteria revised 2013. http://www.epa.gov/gliclearinghouse/
(dd) - Suter, G.W., and Tsao, C.L. 1996. Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota: 1996 Revision. ES/ER/TM-96/R2.
http://www.esd.ornl.gov/programs/ecorisk/documents/tm96r2.pdf
(ee) - USEPA. Interim Ecological Soil Screening Level Documents. Accessed October 2018. http://www2.epa.gov/chemical-research/interim-ecological-soil-screening-level-documents
(ff) - Efroymson, R.A., M.E. Will, and G.W. Suter II, 1997a. Toxicological Benchmarks for Contaminants of Potential Concern for Effects on Soil and Litter Invertebrates and Heterotrophic Process:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-126/R2. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm126r21.pdf)
(gg) - Efroymson, R.A., M.E. Will, G.W. Suter II, and A.C. Wooten, 1997b. Toxicological Benchmarks for Screening Contaminants of Potential Concern for Effects on Terrestrial Plants:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-85/R3. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm85r3.pdf)
(hh) - North Carolina Preliminary Soil Remediation Goals (PSRG) Table. HI = 0.2. September 2015. http://portal.ncdenr.org/c/document_library/get_file?uuid=0f601ffa-574d-4479-bbb4-253af0665bf5&groupId=38361
as part of a risk assessment based on potential toxic effects, therefore; pH was not investigated further as a category 1 COPC. Water quality relative to pH will be addressed as a component of water quality monitoring programs for the site.
(jj) - Hazard Index = 0.1
(ii) - As part of the water quality evaluation conducted under the CSA, pH was measured and is reported as a metric data set. The pH comparison criteria are included as ranges as opposed to single screening values. pH is not typically included
Page 2 of 2
TABLE 2-1
ECOLOGICAL SCREENING - SEDIMENT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Min.Max.ESV RSV
Aluminum 7429-90-5 1 1 NA 12,900 12,900 25,000 (x)58,000 (x)25,000 N
Antimony 7440-36-0 1 0 ND ND ND 2 (y)25 (y)2 N
Arsenic 7440-38-2 1 0 ND ND ND 9.8 (z)33 (z)10 N
Barium 7440-39-3 1 1 NA 128 128 20 (z)60 (z)20 Y
Beryllium 7440-41-7 1 1 NA 0.93 0.93 NA NA NA N
Boron 7440-42-8 1 0 ND ND ND NA NA NA N
Cadmium 7440-43-9 1 0 ND ND ND 1 (z)5 (z)1 N
Chromium (Total)7440-47-3 1 1 NA 45.6 45.6 43.4 (z)111 (z)43 Y
Cobalt 7440-48-4 1 1 NA 11.3 11.3 50 (aa)NA (aa)50 N
Copper 7440-50-8 1 1 NA 11.4 11.4 31.6 (z)149 (z)31.6 N
Lead 7439-92-1 1 1 NA 9.2 9.2 35.8 (z)128 (z)35.8 N
Manganese 7439-96-5 1 1 NA 115 115 460 (bb)1,100 (bb)460 N
Mercury 7439-97-6 1 1 NA 0.021 0.021 0.18 (z)1.1 (z)0.18 N
Molybdenum 7439-98-7 1 0 ND ND ND NA NA NA N
Nickel 7440-02-0 1 1 NA 18.7 18.7 22.7 (z)48.6 (z)22.7 N
Selenium 7782-49-2 1 1 NA 4.1 4.1 0.8 (bb)1.2 (bb)0.8 Y
Strontium 7440-24-6 1 1 NA 38 38 NA NA NA N
Thallium 7440-28-0 1 0 ND ND ND NA NA NA N
Vanadium 7440-62-2 1 1 NA 59.7 59.7 NA NA NA N
Zinc 7440-66-6 1 1 NA 32.8 32.8 121 (z)459 (z)121 N
Notes:
AWQC - Ambient Water Quality Criteria DENR - Department of Environment and Natural Resources su - Standard units
CAMA - Coal Ash Management Act DHHS - Department of Health and Human Services µg/L - micrograms/liter
North Carolina Session Law 2014-122, ESV - Ecological Screening Value USEPA - United States Environmental Protection Agency
HH - Human Health WS - Water Supply
/Senate/PDF/S729v7.pdf HI - Hazard Index < - Concentration not detected at or above the reporting limit
CAS - Chemical Abstracts Service IMAC - Interim Maximum Allowable Concentration j - Indicates concentration reported below Practical Quantitation Limit
CCC - Criterion Continuous Concentration MCL - Maximum Contaminant Level (PQL) but above Method Detection Limit (MDL) and therefore concentration is estimated
CMC - Criterion Maximum Concentration mg/kg - milligrams/kilogram
COPC - Constituent of Potential Concern NA - Not Available
Prepared by: HEG Checked by: ARD
http://www.ncleg.net/Sessions/2013/Bills
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted
Concentration
Used for
Screening
(mg/kg)
USEPA Region 4 Sediment
Screening Values (g)
(mg/kg)
Screening
Value
Used
(mg/kg)
COPC?Analyte CAS Number of
Samples
Frequency
of
Detection
Range of
Detection
(mg/kg)
TABLE 2-1
ECOLOGICAL SCREENING - SEDIMENT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
(a) - USEPA Regional Screening Levels (May 2018). Values for Residential Soil, Industrial Soil, and Tap Water. HI = 0.2. Accessed October 2018.
https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables
(b) - USEPA National Recommended Water Quality Criteria. USEPA Office of Water and Office of Science and Technology. Accessed October 2018.
https://www.epa.gov/wqc/national-recommended-water-quality-criteria-aquatic-life-criteria-table
USEPA AWQC Human Health for the Consumption of Organism Only apply to total concentrations.
(c) - USEPA 2018 Edition of the Drinking Water Standards and Health Advisories. March 2018. Accessed October 2018.
https://www.epa.gov/sites/production/files/2018-03/documents/dwtable2018.pdf
(d) - DHHS Screening Levels. Department of Health and Human Services, Division of Public Health, Epidemiology Section, Occupational and Environmental
Epidemiology Branch. http://portal.ncdenr.org/c/document_library/get_file?p_l_id=1169848&folderId=24814087&name=DLFE-112704.pdf
(e) - North Carolina 15A NCAC 02L .0202 Groundwater Standards & IMACs. http://portal.ncdenr.org/c/document_library/get_file?uuid=1aa3fa13-2c0f-45b7-ae96-5427fb1d25b4&groupId=38364
Amended April 2013.
(f) - North Carolina 15A NCAC 02B Surface Water and Wetland Standards. Amended January 1, 2015.
http://reports.oah.state.nc.us/ncac/title%2015a%20-%20environmental%20quality/chapter%2002%20-%20environmental%20management/subchapter%20b/subchapter%20b%20rules.pdf
WS standards are applicable to all Water Supply Classifications. WS standards are based on the consumption of fish and water.
Human Health Standards are based on the consumption of fish only unless dermal contact studies are available.
For Class C, use the most stringent of freshwater (or, if applicable, saltwater) column and the Human Health column.
For a WS water, use the most stringent of Freshwater, WS and Human Health. Likewise, Trout Waters and High Quality Waters must adhere to the most stingent of all applicable standards.
(g) - USEPA Region 4. 2018. Region 4 Ecological Risk Assessment Supplemental Guidance. March 2018 Update.
https://www.epa.gov/sites/production/files/2018-03/documents/era_regional_supplemental_guidance_report-march-2018_update.pdf
(h) - Value applies to inorganic form of arsenic only.
(i) - Value is the Secondary Maximum Contaminant Level.
https://www.epa.gov/dwstandardsregulations/secondary-drinking-water-standards-guidance-nuisance-chemicals
(j) - Value for Total Chromium.
(k) - Copper Treatment Technology Action Level is 1.3 mg/L.
(l) - Lead Treatment Technology Action Level is 0.015 mg/L.
(m) - RSL for Antimony (metallic) used for Antimony.
(n) - Value for Chromium (III), Insoluble Salts used for Chromium.
(o) - RSL for Mercuric Chloride used for Mercury.
(p) - RSL for Nickel Soluble Salts used for Nickel.
(q) - RSL for Thallium (Soluble Salts) used for Thallium.
(r) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(s) - Value for Inorganic Mercury.
(t) - Acute AWQC is equal to 1/[(f1/CMC1) + (f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated as selenite and selenate, respectively, and
CMC1 and CMC2 are 185.9 µg/L and 12.82 µg/L, respectively. Calculated assuming that all selenium is present as selenate, a likely overly conservative assumption.
(u) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(v) - Chloride Action Level for Toxic Substances Applicable to NPDES Permits is 230,000 µg/L.
(w) - Applicable only to persons with a sodium restrictive diet.
(x) - Los Alamos National Laboratory ECORISK Database. http://www.lanl.gov/community-environment/environmental-stewardship/protection/eco-risk-assessment.php
(y) - Long, Edward R., and Lee G. Morgan. 1991. The Potential for Biological Effects of Sediment-Sorbed Contaminants Tested in the National Status and Trends Program.
NOAA Technical Memorandum NOS OMA 52. Used effects range low (ER-L) for chronic and effects range medium (ER-M) for acute.
(z) - MacDonald, D.D.; Ingersoll, C.G.; Smorong, D.E.; Lindskoog, R.A.; Sloane, G.; and T. Bernacki. 2003. Development and Evaluation of Numerical Sediment Quality Assessment Guidelines for
Florida Inland Waters. Florida Department of Environmental Protection, Tallahassee, FL. Used threshold effect concentration (TEC) for the ESV and probable effect concentration (PEC) for the RSV.
(aa) - Persaud, D., R. Jaagumagi and A. Hayton. 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario. Ontario Ministry of the Environment. Queen's Printer of Ontario.
(bb) - Los Alamos National Laboratory ECORISK Database. September 2017. http://www.lanl.gov/environment/protection/eco-risk-assessment.php (µg/kg dw)
(cc) - Great Lakes Initiative (GLI) Clearinghouse resources Tier II criteria revised 2013. http://www.epa.gov/gliclearinghouse/
(dd) - Suter, G.W., and Tsao, C.L. 1996. Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota: 1996 Revision. ES/ER/TM-96/R2.
http://www.esd.ornl.gov/programs/ecorisk/documents/tm96r2.pdf
(ee) - USEPA. Interim Ecological Soil Screening Level Documents. Accessed October 2018. http://www2.epa.gov/chemical-research/interim-ecological-soil-screening-level-documents
(ff) - Efroymson, R.A., M.E. Will, and G.W. Suter II, 1997a. Toxicological Benchmarks for Contaminants of Potential Concern for Effects on Soil and Litter Invertebrates and Heterotrophic Process:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-126/R2. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm126r21.pdf)
(gg) - Efroymson, R.A., M.E. Will, G.W. Suter II, and A.C. Wooten, 1997b. Toxicological Benchmarks for Screening Contaminants of Potential Concern for Effects on Terrestrial Plants:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-85/R3. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm85r3.pdf)
(hh) - North Carolina Preliminary Soil Remediation Goals (PSRG) Table. HI = 0.2. September 2015. http://portal.ncdenr.org/c/document_library/get_file?uuid=0f601ffa-574d-4479-bbb4-253af0665bf5&groupId=38361
TABLE 2-2
ECOLOGICAL SCREENING - SURFACE WATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Min.Max.Total Dissolved Total Dissolved Total Dissolved Total Dissolved Total Dissolved Total
Aluminum 7429-90-5 22 17 57.5 701 701 NA NA NA NA 750 (b)NA 87 (b)NA 750 NA 87 NA 87 Y
Antimony 7440-36-0 23 14 0.11 0.75 0.75 NA NA NA NA 900 (cc)NA 190 (cc)NA NA NA NA NA 190 N
Arsenic 7440-38-2 24 23 0.16 2.4 2.4 NA 340 NA 150 340 (b, h)NA 150 (b, h)NA 340 (h)NA 150 (h)NA 150 N
Barium 7440-39-3 24 24 12.7 140 140 NA NA NA NA 2000 (cc)NA 220 (cc)NA NA NA NA NA 220 N
Beryllium 7440-41-7 23 10 0.014 0.17 0.17 NA 65 NA 6.5 31 (r, cc)NA 3.6 (r, cc)NA NA NA NA NA 4 N
Boron 7440-42-8 24 24 46.1 3500 3,500 NA NA NA NA 34,000 (cc)NA 7,200 (cc)NA NA NA NA NA 7200 N
Cadmium 7440-43-9 24 5 0.028 0.086 0.086 NA NA NA NA 1.1 (r)NA 0.16 (r)NA NA 1.8 (r)0.27 (r)NA 0.16 N
Chromium (Total)7440-47-3 24 20 0.12 1.1 1.1 NA NA 50 NA 1,022 (n, r)NA 48.8 (n, r)NA NA NA NA NA 50 N
Chromium (VI)18540-29-9 20 12 0.016 1.1 1.1 NA 16 NA 11 16 NA 11 NA NA 16 NA 11 11 N
Cobalt 7440-48-4 23 21 0.068 24.6 24.6 NA NA NA NA 120 (cc)NA 19 (cc)NA NA NA NA NA 19 Y
Copper 7440-50-8 24 22 0.13 7.4 7 NA NA NA NA 7.3 (r)NA 5.16 (r)NA NA NA NA NA 5.16 Y
Lead 7439-92-1 24 13 0.053 0.73 0.73 NA NA NA NA 33.8 (r)NA 1.32 (r)NA NA 65.0 (r)NA 2.5 (r)1 N
Lithium 7439-93-2 4 2 0.56 0.59 0.59 NA NA NA NA 910 (cc)NA 440 (cc)NA NA NA NA NA 440 N
Manganese 7439-96-5 23 23 18.4 1600 1,600 NA NA NA NA 1,680 (cc)NA 93 (cc)NA NA NA NA NA 93 Y
Mercury 7439-97-6 24 23 4.39E-04 0.0082 0.0082 NA NA 0.012 NA 1.4 (b, s)NA 0.77 (b, s)NA NA 1.4 (s)NA 0.77 (s)0.012 N
Molybdenum 7439-98-7 23 17 0.09 2.6 2.6 NA NA NA NA 7,200 (cc)NA 800 (cc)NA NA NA NA NA 800 N
Nickel 7440-02-0 24 13 0.24 12.7 12.7 NA NA NA NA 261 (r)NA 29 (r)NA NA 470 (r)NA 52 (r)29 N
Selenium 7782-49-2 24 8 0.25 2 2 NA NA 5 NA 20 (cc)NA 5 (cc)NA NA NA NA NA 5 N
Strontium 7440-24-6 23 23 25.7 1800 1800 NA NA NA NA 48,000 (cc)NA 5,300 (cc)NA NA NA NA NA 5300 N
Thallium 7440-28-0 24 8 0.018 0.11 0.11 NA NA NA NA 54 (cc)NA 6 (cc)NA NA NA NA NA 6 N
Vanadium 7440-62-2 23 21 0.23 2.4 2.4 NA NA NA NA 79 (cc)NA 27 (cc)NA NA NA NA NA 27 N
Zinc 7440-66-6 24 10 2.7 9.2 9.2 NA NA NA NA 67 (r)NA 67 (r)NA 120 (r)NA 120 (r)NA 67 N
Notes:
AWQC - Ambient Water Quality Criteria DENR - Department of Environment and Natural Resources su - Standard units
CAMA - Coal Ash Management Act DHHS - Department of Health and Human Services µg/L - micrograms/liter
North Carolina Session Law 2014-122, ESV - Ecological Screening Value USEPA - United States Environmental Protection Agency
HH - Human Health WS - Water Supply
/Senate/PDF/S729v7.pdf HI - Hazard Index < - Concentration not detected at or above the reporting limit
CAS - Chemical Abstracts Service IMAC - Interim Maximum Allowable Concentration j - Indicates concentration reported below Practical Quantitation Limit
CCC - Criterion Continuous Concentration MCL - Maximum Contaminant Level (PQL) but above Method Detection Limit (MDL) and therefore concentration is estimated
CMC - Criterion Maximum Concentration mg/kg - milligrams/kilogram
COPC - Constituent of Potential Concern NA - Not Available
Prepared by: HEG Checked by: ARD
Range of
Detection
(µg/L)
Concentration
Used for
Screening
(µg/L)
15A NCAC 2B
Freshwater Aquatic
Life Acute (f)
(µg/L)
15A NCAC 2B
Freshwater Aquatic Life
Chronic (f)
(µg/L)
http://www.ncleg.net/Sessions/2013/Bills
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted
USEPA Region 4
Freshwater Acute Screening
Values (g)
(µg/L)
USEPA Region 4
Freshwater Chronic
Screening Values (g)
(µg/L)
USEPA
AWQC (b)
CMC (acute)
(µg/L)
USEPA
AWQC (b)
CCC (chronic)
(µg/L)
Dissolved
Screening
Value Used
(µg/L)
COPC?Analyte CAS
Number
of
Samples
Frequency
of
Detection
Page 1 of 2
TABLE 2-2
ECOLOGICAL SCREENING - SURFACE WATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
(a) - USEPA Regional Screening Levels (May 2018). Values for Residential Soil, Industrial Soil, and Tap Water. HI = 0.2. Accessed October 2018.
https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables
(b) - USEPA National Recommended Water Quality Criteria. USEPA Office of Water and Office of Science and Technology. Accessed October 2018.
https://www.epa.gov/wqc/national-recommended-water-quality-criteria-aquatic-life-criteria-table
USEPA AWQC Human Health for the Consumption of Organism Only apply to total concentrations.
(c) - USEPA 2018 Edition of the Drinking Water Standards and Health Advisories. March 2018. Accessed October 2018.
https://www.epa.gov/sites/production/files/2018-03/documents/dwtable2018.pdf
(d) - DHHS Screening Levels. Department of Health and Human Services, Division of Public Health, Epidemiology Section, Occupational and Environmental
Epidemiology Branch. http://portal.ncdenr.org/c/document_library/get_file?p_l_id=1169848&folderId=24814087&name=DLFE-112704.pdf
(e) - North Carolina 15A NCAC 02L .0202 Groundwater Standards & IMACs. http://portal.ncdenr.org/c/document_library/get_file?uuid=1aa3fa13-2c0f-45b7-ae96-5427fb1d25b4&groupId=38364
Amended April 2013.
(f) - North Carolina 15A NCAC 02B Surface Water and Wetland Standards. Amended January 1, 2015.
http://reports.oah.state.nc.us/ncac/title%2015a%20-%20environmental%20quality/chapter%2002%20-%20environmental%20management/subchapter%20b/subchapter%20b%20rules.pdf
WS standards are applicable to all Water Supply Classifications. WS standards are based on the consumption of fish and water.
Human Health Standards are based on the consumption of fish only unless dermal contact studies are available.
For Class C, use the most stringent of freshwater (or, if applicable, saltwater) column and the Human Health column.
For a WS water, use the most stringent of Freshwater, WS and Human Health. Likewise, Trout Waters and High Quality Waters must adhere to the most stingent of all applicable standards.
(g) - USEPA Region 4. 2018. Region 4 Ecological Risk Assessment Supplemental Guidance. March 2018 Update.
https://www.epa.gov/sites/production/files/2018-03/documents/era_regional_supplemental_guidance_report-march-2018_update.pdf
(h) - Value applies to inorganic form of arsenic only.
(i) - Value is the Secondary Maximum Contaminant Level.
https://www.epa.gov/dwstandardsregulations/secondary-drinking-water-standards-guidance-nuisance-chemicals
(j) - Value for Total Chromium.
(k) - Copper Treatment Technology Action Level is 1.3 mg/L.
(l) - Lead Treatment Technology Action Level is 0.015 mg/L.
(m) - RSL for Antimony (metallic) used for Antimony.
(n) - Value for Chromium (III), Insoluble Salts used for Chromium.
(o) - RSL for Mercuric Chloride used for Mercury.
(p) - RSL for Nickel Soluble Salts used for Nickel.
(q) - RSL for Thallium (Soluble Salts) used for Thallium.
(r) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(s) - Value for Inorganic Mercury.
(t) - Acute AWQC is equal to 1/[(f1/CMC1) + (f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated as selenite and selenate, respectively, and
CMC1 and CMC2 are 185.9 µg/L and 12.82 µg/L, respectively. Calculated assuming that all selenium is present as selenate, a likely overly conservative assumption.
(u) - Criterion expressed as a function of total hardness (mg/L). Value displayed is the site-specific total hardness of mg/L.
(v) - Chloride Action Level for Toxic Substances Applicable to NPDES Permits is 230,000 µg/L.
(w) - Applicable only to persons with a sodium restrictive diet.
(x) - Los Alamos National Laboratory ECORISK Database. http://www.lanl.gov/community-environment/environmental-stewardship/protection/eco-risk-assessment.php
(y) - Long, Edward R., and Lee G. Morgan. 1991. The Potential for Biological Effects of Sediment-Sorbed Contaminants Tested in the National Status and Trends Program.
NOAA Technical Memorandum NOS OMA 52. Used effects range low (ER-L) for chronic and effects range medium (ER-M) for acute.
(z) - MacDonald, D.D.; Ingersoll, C.G.; Smorong, D.E.; Lindskoog, R.A.; Sloane, G.; and T. Bernacki. 2003. Development and Evaluation of Numerical Sediment Quality Assessment Guidelines for
Florida Inland Waters. Florida Department of Environmental Protection, Tallahassee, FL. Used threshold effect concentration (TEC) for the ESV and probable effect concentration (PEC) for the RSV.
(aa) - Persaud, D., R. Jaagumagi and A. Hayton. 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario. Ontario Ministry of the Environment. Queen's Printer of Ontario.
(bb) - Los Alamos National Laboratory ECORISK Database. September 2017. http://www.lanl.gov/environment/protection/eco-risk-assessment.php (µg/kg dw)
(cc) - Great Lakes Initiative (GLI) Clearinghouse resources Tier II criteria revised 2013. http://www.epa.gov/gliclearinghouse/
(dd) - Suter, G.W., and Tsao, C.L. 1996. Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota: 1996 Revision. ES/ER/TM-96/R2.
http://www.esd.ornl.gov/programs/ecorisk/documents/tm96r2.pdf
(ee) - USEPA. Interim Ecological Soil Screening Level Documents. Accessed October 2018. http://www2.epa.gov/chemical-research/interim-ecological-soil-screening-level-documents
(ff) - Efroymson, R.A., M.E. Will, and G.W. Suter II, 1997a. Toxicological Benchmarks for Contaminants of Potential Concern for Effects on Soil and Litter Invertebrates and Heterotrophic Process:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-126/R2. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm126r21.pdf)
(gg) - Efroymson, R.A., M.E. Will, G.W. Suter II, and A.C. Wooten, 1997b. Toxicological Benchmarks for Screening Contaminants of Potential Concern for Effects on Terrestrial Plants:
1997 Revision. Oak Ridge National Laboratory, Oak Ridge, TN. ES/ER/TM-85/R3. (Available at http://www.esd.ornl.gov/programs/ecorisk/documents/tm85r3.pdf)
(hh) - North Carolina Preliminary Soil Remediation Goals (PSRG) Table. HI = 0.2. September 2015. http://portal.ncdenr.org/c/document_library/get_file?uuid=0f601ffa-574d-4479-bbb4-253af0665bf5&groupId=38361
Page 2 of 2
TABLE 3-1
SUMMARY OF EXPOSURE POINT CONCENTRATIONS
HUMAN HEALTH - GROUNDWATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Constituent Reporting
Units
Number of
Samples
Frequency of
Detection
Minimum
Detected
Concentration
Maximum
Detected
Concentration
Mean of
Detected
Concentration
UCL Selected UCL Exposure Point
Concentration
Exposure Point
Concentration
(mg/L)
Aluminum µg/L 997 573 6 54,500 535.9 95% KM (Chebychev) UCL 587.7 587.7 0.5877
Antimony µg/L 1,438 299 0.1 9.7 0.602 95% KM (Chebychev) UCL 0.372 0.372 0.000372
Arsenic µg/L 1,854 1,158 0.04 973 9.468 95% KM (Chebychev) UCL 12.23 12.23 0.01223
Barium µg/L 1,855 1,855 8.3 2,830 142.1 95% Chebychev (Mean, Sd) UCL 165 165 0.165
Beryllium µg/L 1,308 662 0.01 9.9 0.503 95% KM (Chebychev) UCL 0.389 0.389 0.000389
Boron µg/L 1,753 844 3.3 30,900 1,983 95% KM (Chebychev) UCL 1212 1212 1.212
Cadmium µg/L 1,855 335 0.024 7.5 0.368 95% KM (Chebychev) UCL 0.148 0.148 0.000148
Chromium µg/L 1,855 1,375 0.091 202 4.628 95% KM (Chebychev) UCL 4.798 4.798 0.004798
Chromium (VI)µg/L 781 605 0.0087 142 1.734 95% KM (Chebychev) UCL 2.582 2.582 0.002582
Cobalt µg/L 1,308 1,127 0.01 216 8.225 95% KM (Chebychev) UCL 10.01 10.01 0.01001
Copper µg/L 1,568 913 0.11 1,700 4.446 95% KM (Chebychev) UCL 7.7 7.7 0.0077
Lead µg/L 1,855 677 0 18.61 0.581 99% KM (Chebychev) UCL 0.486 0.486 0.000486
Lithium µg/L 470 445 0.16 748 13.6 95% KM (Chebychev) UCL 24.09 24.09 0.02409
Manganese µg/L 1,568 1,393 0 12,900 413.8 99% KM (Chebychev) UCL 660.5 660.5 0.6605
Mercury µg/L 1,855 145 0.007 1.2 0.166 95% KM (Chebychev) UCL 0.0442 0.0442 0.0000442
Molybdenum µg/L 1,284 854 0.081 103 2.849 95% KM (Chebychev) UCL 2.756 2.756 0.002756
Nickel µg/L 1,465 944 0.13 173 7.576 95% KM (Chebychev) UCL 6.685 6.685 0.006685
Selenium µg/L 1,855 671 0.092 119 9.189 95% KM (Chebychev) UCL 4.771 4.771 0.004771
Strontium µg/L 987 979 3.7 18,700 1,444 95% KM (Chebychev) UCL 1730 1730 1.73
Thallium µg/L 1,438 407 0.015 3.6 0.205 95% KM (Chebychev) UCL 0.118 0.118 0.000118
Vanadium µg/L 1,011 870 0.069 57.5 2.618 95% KM (Chebychev) UCL 2.879 2.879 0.002879
Zinc µg/L 1,568 833 0 315 15.74 99% KM (Chebychev) UCL 14.95 14.95 0.01495
Notes:
---: Calculations were not performed due to lack of samples ND - Not Determined
Mean - Arithmetic mean UCL - 95% Upper Confidence Limit
mg/L - milligrams per liter
µg/L - micrograms per liter
(c) - 0 is defined as a number of samples analyzed or the frequency of detection among samples.
(a)- Mean calculated by ProUCL using the Kaplan-Meier (KM) estimation method for non-detect values: only given for datasets with FOD less than 100% and that met the minimum sample size and FOD requirements for use with
ProUCL; see note (b).
(b)- Sample size was greater than or equal to 10 and the number of detected values was greater than or equal to 6, therefore, a 95% UCL was calculated by ProUCL. The UCL shown is the one recommended by ProUCL. If more than one
UCL was recommended, the higher UCL was selected. ProUCL, version 5.0
(d) - The 95% UCL values are calculated using the ProUCL software (V. 5.0; USEPA, 2013a). The ProUCL software performs a goodness-of-fit test that accounts for data sets without any non-detect observations, as well as data sets with non-detect observations.
The software then determines the distribution of the data set for which the EPC is being derived (e.g., normal, lognormal, gamma, or non-discernable), and then calculates a conservative and stable 95% UCL value in accordance with the framework described in
“Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites” (USEPA, 2002b). The software includes numerous algorithms for calculating 95% UCL values, and provides a recommended UCL value based on the algorithm that
is most applicable to the statistical distribution of the data set. ProUCL will calculate a 95% UCL where there are 3 or more total samples with detected concentrations. Where too few samples or detects are available, the maximum detected concentration is used
as the EPC.
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted Prepared by: HEG Checked by: ARD
TABLE 3-2
SUMMARY OF EXPOSURE POINT CONCENTRATIONS
HUMAN HEALTH - SEDIMENT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Constituent Reporting
Units
Number of
Samples
Frequency of
Detection
Minimum
Detected
Concentration
Maximum
Detected
Concentration
Mean Detected
Concentration UCL Selected UCL
Exposure Point
Concentration
(mg/kg)
Cobalt mg/kg 1 1 NA 11.3 NA ------11.3
Prepared by: HEG Checked by: ARD
Notes:
---: Calculations were not performed due to lack of samples ND - Not Determined
Mean - Arithmetic mean UCL - 95% Upper Confidence Limit
mg/kg - milligrams per kilogram
(c) - 0 is defined as a number of samples analyzed or the frequency of detection among samples.
(a)- Mean calculated by ProUCL using the Kaplan-Meier (KM) estimation method for non-detect values: only given for datasets with FOD less than 100% and that met the minimum sample size and FOD requirements for use with ProUCL; see
note (b).
(b)- Sample size was greater than or equal to 10 and the number of detected values was greater than or equal to 6, therefore, a 95% UCL was calculated by ProUCL. The UCL shown is the one recommended by ProUCL. If more than one UCL
was recommended, the higher UCL was selected. ProUCL, version 5.0
(d) - The 95% UCL values are calculated using the ProUCL software (V. 5.0; USEPA, 2013a). The ProUCL software performs a goodness-of-fit test that accounts for data sets without any non-detect observations, as well as data sets with non-
detect observations. The software then determines the distribution of the data set for which the EPC is being derived (e.g., normal, lognormal, gamma, or non-discernable), and then calculates a conservative and stable 95% UCL value in
accordance with the framework described in “Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites” (USEPA, 2002b). The software includes numerous algorithms for calculating 95% UCL values, and
provides a recommended UCL value based on the algorithm that is most applicable to the statistical distribution of the data set. ProUCL will calculate a 95% UCL where there are 3 or more total samples with detected concentrations. Where
too few samples or detects are available, the maximum detected concentration is used as the EPC.
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted
TABLE 3-3
SUMMARY OF EXPOSURE POINT CONCENTRATIONS
HUMAN HEALTH - SURFACE WATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Constituent Number of
Samples
Frequency of
Detection
Minimum
Detected
Concentration
Maximum
Detected
Concentration
Mean Detected
Concentration UCL Selected UCL Exposure Point
Concentration
Exposure Point
Concentration
(mg/L)
Aluminum 22 17 57.5 701 216.9 95% KM H-UCL 263.9 263.9 0.2639
Boron 28 24 46.1 3,500 549.9 95% KM (Chebyshev) UCL 1,148 1,148 1.148
Chromium(VI)20 12 0.016 1.1 0.389 95% Gamma Adjusted KM-UCL 0.517 0.517 0.000517
Cobalt 23 21 0.068 24.6 3.298 95% Gamma Adjusted KM-UCL 6.483 6.483 0.006483
Manganese 23 23 18.4 1,600 378.1 95% Student's-t UCL 501 501 0.501
Zinc 28 12 2.7 9.2 5.305 95% KM (t) UCL 5.891 5.891 0.005891
Notes:
---: Calculations were not performed due to lack of samples ND - Not Determined
Mean - Arithmetic mean UCL - 95% Upper Confidence Limit
mg/L - milligrams per liter
µg/L - micrograms per liter
(c) - 0 is defined as a number of samples analyzed or the frequency of detection among samples.
(a)- Mean calculated by ProUCL using the Kaplan-Meier (KM) estimation method for non-detect values: only given for datasets with FOD less than 100% and that met the minimum sample size and FOD requirements for use with ProUCL; see note (b).
(b)- Sample size was greater than or equal to 10 and the number of detected values was greater than or equal to 6, therefore, a 95% UCL was calculated by ProUCL. The UCL shown is the one recommended by ProUCL. If more than one UCL was
recommended, the higher UCL was selected. ProUCL, version 5.0
(d) - The 95% UCL values are calculated using the ProUCL software (V. 5.0; USEPA, 2013a). The ProUCL software performs a goodness-of-fit test that accounts for data sets without any non-detect observations, as well as data sets with non-detect observations. The software then
determines the distribution of the data set for which the EPC is being derived (e.g., normal, lognormal, gamma, or non-discernable), and then calculates a conservative and stable 95% UCL value in accordance with the framework described in “Calculating Upper Confidence Limits
for Exposure Point Concentrations at Hazardous Waste Sites” (USEPA, 2002b). The software includes numerous algorithms for calculating 95% UCL values, and provides a recommended UCL value based on the algorithm that is most applicable to the statistical distribution of the
data set. ProUCL will calculate a 95% UCL where there are 3 or more total samples with detected concentrations. Where too few samples or detects are available, the maximum detected concentration is used as the EPC.
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted Prepared by: HEG Checked by: HES
TABLE 4-1
SUMMARY OF EXPOSURE POINT CONCENTRATIONS
ECOLOGICAL - SEDIMENT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Constituent Reporting
Units
Number of
Samples
Frequency of
Detection
Minimum
Detected
Concentration
Maximum
Detected
Concentration
Mean
Detected
Concentration
UCL Selected UCL
Exposure Point
Concentration
(mg/kg)
Barium mg/kg 1 1 NA 128 ---------128
Chromium (Total)mg/kg 1 1 NA 45.6 ---------45.6
Selenium mg/kg 1 1 NA 4.1 ---------4.1
Notes:
---: Calculations were not performed due to lack of samples µg/L - micrograms per liter
Mean - Arithmetic mean UCL - 95% Upper Confidence Limit
mg/kg - milligrams per kilogram
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted
(c) - The 95% UCL values are calculated using the ProUCL software (V. 5.0; USEPA, 2013a). The ProUCL software performs a goodness-of-fit test that accounts for data sets without any non-detect observations, as well as data sets with non-
detect observations. The software then determines the distribution of the data set for which the EPC is being derived (e.g., normal, lognormal, gamma, or non-discernable), and then calculates a conservative and stable 95% UCL value in
accordance with the framework described in “Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites” (USEPA, 2002b). The software includes numerous algorithms for calculating 95% UCL values, and
provides a recommended UCL value based on the algorithm that is most applicable to the statistical distribution of the data set. ProUCL will calculate a 95% UCL where there are 3 or more total samples with detected concentrations. Where
too few samples or detects are available, the maximum detected concentration is used as the EPC.
(a)- Sample size was greater than or equal to 10 and the number of detected values was greater than or equal to 6, therefore, a 95% UCL was calculated by ProUCL. The UCL shown is the one recommended by ProUCL. If more than one UCL
was recommended, the higher UCL was selected. ProUCL, version 5.0
(b) - 0 is defined as a number of samples analyzed or the frequency of detection among samples.
Prepared by: HEG Checked by: ARD
TABLE 4-2
SUMMARY OF EXPOSURE POINT CONCENTRATIONS
ECOLOGICAL - SURFACE WATER
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Constituent Reporting
Units
Number of
Samples
Frequency of
Detection
Minimum
Detected
Concentration
Maximum
Detected
Concentration
Mean
Detected
Concentration
UCL Selected UCL Exposure Point
Concentration
Exposure Point
Concentration
(mg/L)
Aluminum µg/L 22 17 57.5 701 216.9 95% KM H-UCL 263.9 263.9 0.2639
Cobalt µg/L 23 21 0.068 24.6 3.298 95% Gamma Adjusted KM-UCL 6.483 6.483 0.006483
Copper µg/L 24 22 0.13 7.4 1.5 95% KM (Chebychev) UCL 2.696 2.696 0.002696
Manganese µg/L 23 23 18.4 1600 378.1 95% Student's-t UCL 501 501 0.501
Prepared by: HEG Checked by: ARD
Notes:
---: Calculations were not performed due to lack of samples µg/L - micrograms per liter
Mean - Arithmetic mean UCL - 95% Upper Confidence Limit
mg/L - milligrams per liter
(b) - 0 is defined as a number of samples analyzed or the frequency of detection among samples.
* Data evaluated includes data from 2015 to 2nd quarter 2018, unless otherwise noted
(a)- Sample size was greater than or equal to 10 and the number of detected values was greater than or equal to 6, therefore, a 95% UCL was calculated by ProUCL. The UCL shown is the one recommended by ProUCL. If more than one UCL was recommended, the
higher UCL was selected. ProUCL, version 5.0
(c) - The 95% UCL values are calculated using the ProUCL software (V. 5.0; USEPA, 2013a). The ProUCL software performs a goodness-of-fit test that accounts for data sets without any non-detect observations, as well as data sets with non-detect observations. The
software then determines the distribution of the data set for which the EPC is being derived (e.g., normal, lognormal, gamma, or non-discernable), and then calculates a conservative and stable 95% UCL value in accordance with the framework described in
“Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites” (USEPA, 2002b). The software includes numerous algorithms for calculating 95% UCL values, and provides a recommended UCL value based on the algorithm that is
most applicable to the statistical distribution of the data set. ProUCL will calculate a 95% UCL where there are 3 or more total samples with detected concentrations. Where too few samples or detects are available, the maximum detected concentration is used as the
EPC.

Risk-Based Concentration Ash Basin-
Groundwater
Non-Cancer Cancer Final Exposure Point
Concentration
(mg/L)(mg/L)(mg/L)(mg/L)
Aluminum 7429-90-5 9.6E+04 nc 9.6E+04 nc 0.6 0.00001 nc
Antimony 7440-36-0 1.7E+01 nc 1.7E+01 nc 0.0004 0.00002 nc
Arsenic 7440-38-2 2.9E+01 4.5E+02 2.9E+01 nc 0.01 0.0004 nc
Barium 7440-39-3 5.0E+03 nc 5.0E+03 nc 0.2 0.00003 nc
Beryllium 7440-41-7 4.8E+02 nc 4.8E+02 nc 0.0004 0.000001 nc
Boron 7440-42-8 1.9E+04 nc 1.9E+04 nc 1 0.00006 nc
Cadmium 7440-43-9 1.0E+01 nc 1.0E+01 nc 0.0001 0.00001 nc
Chromium, Total 7440-47-3 8.6E+03 nc 8.6E+03 nc 0.005 0.0000006 nc
Chromium (VI)18540-29-9 2.8E+01 7.6E+01 2.8E+01 nc 0.003 0.00009 nc
Cobalt 7440-48-4 3.3E+02 nc 3.3E+02 nc 0.01 0.0000 nc
Copper 7440-50-8 3.8E+03 3.8E+03 nc 0.008 0.0000 nc
Lead (a,b)7439-92-1 0.0005 NC nc
Lithium 7439-93-2 0.02 NC nc
Manganese 7439-96-5 2.2E+03 nc 2.2E+03 nc 0.7 0.000 nc
Mercury 7439-97-6 5.0E+01 5.0E+01 nc 0.00004 0.000 nc
Molybdenum 7439-98-7 4.8E+02 nc 4.8E+02 nc 0.003 0.00001 nc
Nickel 7440-02-0 1.0E+03 nc 1.0E+03 nc 0.007 0.00001 nc
Selenium 7782-49-2 4.8E+02 nc 4.8E+02 nc 0.005 0.00001 nc
Strontium 7440-24-6 1.9E+05 nc 1.9E+05 nc 2 0.000009 nc
Thallium 7440-28-0 0.0001 NA nc
Vanadium 7440-62-2 9.6E+02 nc 9.6E+02 nc 0.003 0.000003 nc
Zinc 7440-66-6 3.1E+04 nc 3.1E+04 nc 0.01 0.000000 nc
Cumulative Risk 0.001 0.00E+00
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern NA - No toxicity value available; remedial goal not calculated
c - Remedial goal based on cancer risk NC - Not Calculated
nc - Remedial goal based on non-cancer hazard index
(a) USEPA has an action level of 15 ug/L for lead in drinking water (USEPA, 2012b). Refer to Attachment D, Section 2.5 of the Marshall Steam Station CAP (HDR 2015).
(b) Lead was not included in the cumulative risk calculation, as risk for lead is typically evaluted using biokinetic models. Lead concentrations are less than the conservative action level of 15 ug/L.
Groundwater at the site is not used for drinking water.
Exposure Routes Evaluated
Incidental Ingestion Yes
Dermal Contact Yes
Ambient Vapor Inhalation No
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
NA
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
TABLE 5-1
SUMMARY OF ON-SITE GROUNDWATER EPC/RBC COMPARISON
CONSTRUCTION - CONSTRUCTION WORKER (ADULT)
MARSHALL STEAM STATION
Risk Ratio
Non-Cancer Cancer
COPC CAS
Basis
NA
NA
Page 1 of 1
Sediment
Non-Cancer Cancer Final
Exposure
Point
Concentration
(mg/kg)(mg/kg)(mg/kg)(mg/kg)
Cobalt 7440-48-4 3.7E+03 nc 3.7E+03 nc 11 0.003 nc
0.003 0.00E+00
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern
c - Remedial goal based on cancer risk
nc - remedial goal based on non-cancer hazard index
Exposure Routes Evaluated
Incidental Ingestion Yes
Dermal Contact Yes
Particulate Inhalation No
Ambient Vapor Inhalation No
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
TABLE 5-2
SUMMARY OF OFF-SITE SEDIMENT EPC/RBC COMPARISON
RECREATIONAL SWIMMER - CHILD, ADOLESCENT, and ADULT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Risk-Based Concentration
Basis
COPC CAS
Non-Cancer Cancer
Risk Ratio
Cumulative Risk
Page 1 of 1
Surface Water
Non-Cancer Cancer Final Exposure Point
Concentration
(mg/L)(mg/L)(mg/L)(mg/L)
Aluminum 7429-90-5 1.1E+03 nc 1.1E+03 nc 0.3 0.0002 nc
Boron 7440-42-8 2.2E+02 nc 2.2E+02 nc 1 0.01 nc
Chromium (VI)18540-29-9 3.3E-01 2.0E-02 2.0E-02 c 0.0005 0.002 2.6E-02
Cobalt 7440-48-4 3.5E-01 nc 3.5E-01 nc 0.01 0.02 nc
Manganese 7439-96-5 4.1E+01 nc 4.1E+01 nc 0.5 0.01 nc
Zinc 7440-66-6 3.4E+02 nc 3.4E+02 nc 0.006 NC nc
Cumulative Risk 0.04 2.6E-02
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern NA - No toxicity value available; remedial goal not calculated
c - Remedial goal based on cancer risk NC - Not Calculated
Exposure Routes Evaluated
Incidental Ingestion Yes
Dermal Contact Yes
Ambient Vapor Inhalation No
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
TABLE 5-3
SUMMARY OF OFF-SITE SURFACE WATER EPC/RBC COMPARISON
RECREATIONAL SWIMMER - CHILD, ADOLESCENT, and ADULT
MARSHALL STEAM STATION
nc - Remedial goal based on non-cancer hazard index
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Basis
Risk-Based Concentration
COPC CAS
Cancer
Risk Ratio
Non-Cancer
Page 1 of 1
Sediment
Non-Cancer Cancer Final Exposure Point
Concentration
(mg/kg)(mg/kg)(mg/kg)(mg/kg)
Cobalt 7440-48-4 3.7E+03 nc 3.7E+03 nc 11 0.003 nc
Cumulative Risk 0.003 0.00E+00
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern
c - Remedial goal based on cancer risk
Exposure Routes Evaluated
Incidental Ingestion Yes
Dermal Contact Yes
Particulate Inhalation No
Ambient Vapor Inhalation No
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
nc - Remedial goal based on non-cancer hazard index
TABLE 5-4
SUMMARY OF OFF-SITE SEDIMENT EPC/RBC COMPARISON
RECREATIONAL WADER - CHILD, ADOLESCENT, and ADULT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Risk-Based Concentration
Basis
COPC CAS
Risk Ratio
Non-Cancer Cancer
Page 1 of 1

Risk-Based Concentration Surface Water
Non-Cancer Cancer Final
Exposure
Point
Concentration
(mg/L)(mg/L)(mg/L)(mg/L)
Aluminum 7429-90-5 1.2E+03 nc 1.2E+03 nc 0.3 0.0002 nc
Boron 7440-42-8 2.4E+02 nc 2.4E+02 nc 1 0.005 nc
Chromium (VI)18540-29-9 9.5E-01 8.3E-02 8.3E-02 c 0.0005 0.001 6.2E-03
Cobalt 7440-48-4 3.6E-01 nc 3.6E-01 nc 0.01 0.02 nc
Manganese 7439-96-5 9.0E+01 nc 9.0E+01 nc 0.5 0.01 nc
Zinc 7440-66-6 3.6E+02 nc 3.6E+02 nc 0.006 0.00002 nc
Cumulative Risk 0.03 6.2E-03
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern NC - Not Calculated
c - Remedial goal based on cancer risk
Exposure Routes Evaluated
Incidental Ingestion Yes
Dermal Contact Yes
Ambient Vapor Inhalation No
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
Basis
nc - Remedial goal based on non-cancer hazard index
COPC CAS
Cancer
Risk Ratio
Non-Cancer
NA - No toxicity value available; remedial goal not calculated
TABLE 5-5
SUMMARY OF OFF-SITE SURFACE WATER EPC/RBC COMPARISON
RECREATIONAL WADER - CHILD, ADOLESCENT, and ADULT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Page 1 of 1

Surface
Water
Non-Cancer Cancer Final
Exposure
Point
Concentration
(mg/L)(mg/L)(mg/L)(mg/L)
Aluminum 7429-90-5 5.6E+04 nc 5.6E+04 nc 0.3 0.000005 nc
Boron 7440-42-8 1.1E+04 nc 1.1E+04 nc 1 0.0001 nc
Chromium (VI)18540-29-9 2.1E+00 9.8E-01 9.8E-01 c 0.0005 0.0005 5.3E-04
Cobalt 7440-48-4 4.2E+01 nc 4.2E+01 nc 0.01 0.0002 nc
Manganese 7439-96-5 3.1E+02 nc 3.1E+02 nc 0.5 0.002 nc
Zinc 7440-66-6 2.8E+04 nc 2.8E+04 nc 0.006 0.0000002 nc
Cumulative Risk 0.0024 5.3E-04
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern NA - No toxicity value available; remedial goal not calculated
c - Remedial goal based on cancer risk
Exposure Routes Evaluated
Incidental Ingestion No
Dermal Contact Yes
Ambient Vapor Inhalation No
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
Risk-Based Concentration
Basis
nc - Remedial goal based on non-cancer hazard index
NC - Not Calculated
COPC CAS
Cancer
Risk Ratio
Non-Cancer
TABLE 5-6
SUMMARY OF OFF-SITE SURFACE WATER EPC/RBC COMPARISON
RECREATIONAL BOATER - RECREATIONAL BOATER (ADULT)
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Page 1 of 1

Surface Water
Non-Cancer Cancer Final Exposure Point
Concentration
(mg/L)(mg/L)(mg/L)(mg/L)
Aluminum 7429-90-5 5.6E+04 nc 5.6E+04 nc 0.3 0.000005 nc
Boron 7440-42-8 1.1E+04 1.1E+04 nc 1 0.0001 nc
Chromium (VI)18540-29-9 2.1E+00 9.8E-01 9.8E-01 c 0.0005 0.0005 5.3E-04
Cobalt 7440-48-4 4.2E+01 nc 4.2E+01 nc 0.01 0.0002 nc
Manganese 7439-96-5 3.1E+02 nc 3.1E+02 nc 0.5 0.002 nc
Zinc 7440-66-6 2.8E+04 nc 2.8E+04 nc 0.006 0.0000002 nc
Cumulative Risk 0.002 5.3E-04
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern NA - No toxicity value available; remedial goal not calculated
c - Remedial goal based on cancer risk
Exposure Routes Evaluated
Incidental Ingestion No
Dermal Contact Yes
Ambient Vapor Inhalation No
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
Risk-Based Concentration
Basis
nc - Remedial goal based on non-cancer hazard index
NC - Not Calculated
COPC CAS
Cancer
Risk Ratio
Non-Cancer
TABLE 5-7
SUMMARY OF OFF-SITE SURFACE WATER EPC/RBC COMPARISON
RECREATIONAL FISHER - RECREATIONAL FISHER (ADULT)
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Page 1 of 1

Non-Cancer Cancer Final Non-Cancer Cancer Final Non-Cancer Cancer Final
Exposure
Point
Concentration
(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/L)(mg/L)(mg/L)(mg/L)
Aluminum 7429-90-5 4.6E+03 nc 4.6E+03 nc 5.8E+03 nc 5.8E+03 nc 4.6E+03 nc 2.7 1.7E+03 nc 1.7E+03 nc 0.3 0.0002 nc
Boron 7440-42-8 9.1E+02 nc 9.1E+02 nc 1.2E+03 nc 1.2E+03 nc 9.1E+02 nc 0.3 3.0E+03 nc 3.0E+03 nc 1 0.000 nc
Chromium (VI)18540-29-9 1.4E+01 6.4E+00 6.4E+00 c 1.7E+01 2.7E+00 2.7E+00 c 1.4E+01 2.7E+00 200 6.9E-02 1.4E-02 1.4E-02 c 0.0005 0.0 0.04
Cobalt 7440-48-4 1.4E+00 nc 1.4E+00 nc 1.7E+00 nc 1.7E+00 nc 1.4E+00 nc 400 3.4E-03 nc 3.4E-03 nc 0.01 1.9 nc
Manganese 7439-96-5 6.4E+02 nc 6.4E+02 nc 8.1E+02 nc 8.1E+02 nc 6.4E+02 nc 2.4 2.7E+02 nc 2.7E+02 nc 0.5 0.002 nc
Zinc 7440-66-6 1.4E+03 nc 1.4E+03 nc 1.7E+03 nc 1.7E+03 nc 1.4E+03 nc 2059 6.7E-01 nc 6.7E-01 nc 0.006 0.01 nc
Cumulative Risk 1.9 3.8E-02
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern NA - No toxicity value available; remedial goal not calculated BCF - Bioconcentration Factor
c - Remedial goal based on cancer risk NC - Not Calculated Surface water RBC = Fish Tissue RBC / BCF
nc - Remedial goal based on non-cancer hazard index
Exposure Routes Evaluated
Ingestion Yes
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
Lowest
Non-
Cancer
RBC
Value
Lowest
Cancer
RBC
Value
Adult Adolescent
Basis
Surface Water Risk Ratio
Non-Cancer Cancer
TABLE 5-8
SUMMARY OF FISH TISSUE EPC/RBC COMPARISON
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
FISHER - RECREATIONAL (ADULT AND ADOLESCENT)
COPC CAS
Basis
Risk-Based Concentration - Surface Water
Basis
BCF
(unitless)
Risk-Based Concentration - Fish Tissue
Page 1 of 1

Non-Cancer Cancer Final Non-Cancer Cancer Final Non-Cancer Cancer Final Exposure Point
Concentration
(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/L)(mg/L)(mg/L)(mg/L)
Aluminum 7429-90-5 4.7E+02 nc 4.7E+02 nc 1.5E+02 nc 1.5E+02 nc 1.5E+02 nc 2.7 5.7E+01 nc 5.7E+01 nc 0.3 0.005 nc
Boron 7440-42-8 9.4E+01 nc 9.4E+01 nc 3.1E+01 nc 3.1E+01 nc 3.1E+01 nc 0.3 1.0E+02 nc 1.0E+02 nc 1 0.01 nc
Chromium (VI)18540-29-9 1.4E+00 6.6E-01 6.6E-01 c 4.6E-01 3.6E-02 3.6E-02 c 4.6E-01 3.6E-02 200 2.3E-03 1.8E-04 1.8E-04 c 0.0005 0.23 2.872
Cobalt 7440-48-4 1.4E-01 nc 1.4E-01 nc 4.6E-02 nc 4.6E-02 nc 4.6E-02 nc 400 1.1E-04 nc 1.1E-04 nc 0.01 56 nc
Manganese 7439-96-5 6.6E+01 nc 6.6E+01 nc 2.1E+01 nc 2.1E+01 nc 2.1E+01 nc 2.4 8.9E+00 nc 8.9E+00 nc 0.5 0.06 nc
Zinc 7440-66-6 1.4E+02 nc 1.4E+02 nc 4.6E+01 nc 4.6E+01 nc 4.6E+01 nc 2059 2.2E-02 nc 2.2E-02 nc 0.006 0.3 nc
Cumulative Risk 57 2.87E+00
Prepared by: HHS Checked by: TCP
Notes:
COPC - Chemical of potential concern NA - No toxicity value available; remedial goal not calculated BCF - Bioconcentration Factor
c - Remedial goal based on cancer risk NC - Not Calculated Surface water RBC = Fish Tissue RBC / BCF
nc - remedial goal based on non-cancer hazard index
There is no evidence of subsistence fishing occuring in the waterbody evaluated.
Exposure Routes Evaluated
Ingestion Yes
Target Hazard Index (per Chemical)1E+00
Target Cancer Risk (per Chemical)1E-04
Risk-Based Concentration - Fish Tissue
Lowest
Non-
Cancer
RBC
Value
Lowest
Cancer
RBC
Value
Adult Child
Risk Ratio
Non-Cancer Cancer
TABLE 5-9
SUMMARY OF FISH TISSUE EPC/RBC COMPARISON
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
FISHER - SUBSISTENCE (ADULT AND CHILD)
COPC CAS
Basis Basis
Surface WaterRisk-Based Concentration - Surface Water
Basis
BCF
(unitless)
Page 1 of 1
Source Table
(PRG Tables)Media Exposure Pathway Risk Ratio -
Non- cancer
Risk Ratio -
cancer
TABLE 5-1 Groundwater-On-Site CONSTRUCTION - CONSTRUCTION WORKER (ADULT)0.001 0.00E+00
TABLE 5-2 Sediment- Off-Site OFF-SITE RECREATIONAL SWIMMER - CHILD, ADOLESCENT, and ADULT 0.003 0.00E+00
TABLE 5-3 Surface Water- Off-Site OFF-SITE RECREATIONAL SWIMMER - CHILD, ADOLESCENT, and ADULT 0.04 2.62E-02
TABLE 5-4 Sediment- Off-Site OFF-SITE RECREATIONAL WADER - CHILD, ADOLESCENT, and ADULT 0.003 0.00E+00
TABLE 5-5 Surface Water- Off-Site OFF-SITE RECREATIONAL WADER - CHILD, ADOLESCENT, and ADULT 0.03 6.22E-03
TABLE 5-6 Surface Water- Off-Site OFF-SITE RECREATIONAL BOATER - OFF-SITE RECREATIONAL BOATER (ADULT)0.002 5.27E-04
TABLE 5-7 Surface Water- Off-Site OFF-SITE RECREATIONAL FISHER (ADULT)0.002 5.27E-04
TABLE 5-8 Biota (fish)- Off-Site
OFF-SITE FISHER - RECREATIONAL
(ADULT AND ADOLESCENT)2 3.83E-02
TABLE 5-9 Biota (fish)- Off-Site OFF-SITE RECREATIONAL FISHER (ADULT)57 2.87E+00
Prepared by: HHS Checked by: TCP
TABLE 5-10
SUMMARY OF EXPOSURE POINT CONCENTRATION COMPARISON TO RISK-BASED CONCENTRATION
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Page 1 of 1
Plants Mammal/Terr.
Vertebrates Fish Invertebrates Birds Soil
BW IRF IRW PF AM AF AI AB SF HR SUF
kg kg/kg BW/day L/kg BW/day %%%%%%hectares unitless
Meadow Volea 0.033 0.33 0.21 97.6%0%0%0%0%2.4%0.027 1
Muskratb 1.17 0.3 0.97 99.3%0%0%0%0%0.7%0.13 1
Mallard Duckc 1.134 0.068 0.057 48.3%0%0%48.3%0%3.3%435 1
American Robind 0.08 0.129 0.14 40%0%0%58%0%2%0.42 1
Red-Tailed Hawke 1.06 0.18 0.058 0%91.5%0%0%8.5%0%876 1
Bald Eaglef 3.75 0.12 0.058 0%28%58%0%13.5%0.5%2199 1
Red Foxg 4.54 0.16 0.085 6%89%0%2%0%3%1226 1
River Otterh 6.76 0.19 0.081 0%0%100%0%0%0%348 1
Great Blue Heroni 2.229 0.18 0.045 0%0%90%9.5%0%0.5%227 1
NOTES:
SUF - Seasonal Use Factor
PF - Plant Matter Ingestion Percentage
AM - Mammal/Terrestrial Vertebrate ingestion percentage
AF - Fish Ingestion Percentage
AB - Bird Ingestion Percentage
SF - Soil Ingestion Percentage
f BW, PF, AF, AM, AB, HR from USEPA 1993 (sections 2-91 and 2-97); IRF from Nagy 2001
g BW, PF, AF, AI, HR from USEPA 1993 (sections 2-224 and 2-225); SF from Beyer et al. 1994
h BW, IRw, AF, HR from USEPA 1993 (sections 2-264 and 2-266); SF from Sample and Suter 1994; IRF from Nagy 2001
i BW, PF, AF, AI, HR from USEPA 1993 (sections 2-8 and 2-9); SF from Sample and Suter 1994; IRF from Nagy 2001
j Seasonal Use Factor is set to a default of 1 to be overly conservative and protective of ecological receptors.
Table 1
Seasonal Use
Factorj
Home
RangeBody Weight Food Ingestion Rate Water Ingestion
Rate
Dietary Composition
Algorithm ID
Units
Parameter
Exposure Parameters for Ecological Receptors
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
Ecological ReceptorsBW - Body Weight
kg - Kilograms
IR - Ingestion Rate
HR - Home Range
HERBIVORE
OMNIVORE
CARNIVORE
PISCIVORE
kg/kg BW/day - Kilograms Food per Kilograms Body Weight per Day
L/kg BW/day - Liters Water per Kilogram Body Weight per Day
a BW, IRf, IRw, PF, HR from USEPA 1993 (sections 2-328 and 2-329); SF from Sample and Suter 1994
b BW, IRf, IRw, PF, HR from USEPA 1993 (sections 2-340 and 2-341); SF from TechLaw Inc. 2013; IRF from Nagy 2001
c BW, PF, AI, HR from USEPA 1993 (sections 2-43 and 2-45); SF from Beyer et al. 1994; IRF from Nagy 2001
d BW, PF, AI, HR from USEPA 1993 (sections 2-197 and 2-198); SF from Sample and Suter 1994; IRF from Nagy 2001
e BW, PF, AM, AB, IRF, HR from USEPA 1993 (sections 2-82 and 2-83)
Table 2
Toxicity Reference Values for Ecological Receptors
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
Mallard Duck
(mg/kg/day)
Great Blue
Heron
(mg/kg/day)
Bald Eagle
(mg/kg/day)
Muskrat
(mg/kg/day)
River Otter
(mg/kg/day)
American
Robin
(mg/kg/day)
Red-Tailed
Hawk
(mg/kg/day)
Meadow Vole
(mg/kg/day)
Red Fox
(mg/kg/day)
Aluminuma 110 110 110 1.93 1.93 110 110 1.93 1.93
Antimonya NA NA NA 0.059 0.059 NA NA 0.059 0.059
Arsenicb 2.24 2.24 2.24 1.04 1.04 2.24 2.24 1.04 1.04
Bariumc 20.8 20.8 20.8 51.8 51.8 20.8 20.8 51.8 51.8
Berylliuma NA NA NA 0.532 0.532 NA NA 0.532 0.532
Borona, b 28.8 28.8 28.8 28 28 28.8 28.8 28 28
Cadmiuma 1.47 1.47 1.47 0.77 0.77 1.47 1.47 0.77 0.77
Calcium EN EN EN EN EN EN EN EN EN
Chromium, Totald 1 1 1 2740 2740 1 1 2740 2740
Chromium VI (hexavalent)a NA NA NA 9.24 9.24 NA NA 9.24 9.24
Chromium IIIa 2.66 2.66 2.66 2.4 2.4 2.66 2.66 2.4 2.4
Cobalta 7.61 7.61 7.61 7.33 7.33 7.61 7.61 7.33 7.33
Coppera 4.05 4.05 4.05 5.6 5.6 4.05 4.05 5.6 5.6
Iron EN EN EN EN EN EN EN EN EN
Leadb 1.63 1.63 1.63 4.7 4.7 1.63 1.63 4.7 4.7
Magnesium EN EN EN EN EN EN EN EN EN
Manganesea 179 179 179 51.5 51.5 179 179 51.5 51.5
Mercurye 3.25 3.25 3.25 1.01 1.01 3.25 3.25 1.01 1.01
Molybdenuma, d 3.53 3.53 3.53 0.26 0.26 3.53 3.53 0.26 0.26
Nickela 6.71 6.71 6.71 1.7 1.7 6.71 6.71 1.7 1.7
Potassium EN EN EN EN EN EN EN EN EN
Seleniuma 0.29 0.29 0.29 0.143 0.143 0.29 0.29 0.143 0.143
Sodium EN EN EN EN EN EN EN EN EN
Strontiuma, d NA NA NA 263 263 NA NA 263 263
Thalliuma NA NA NA 0.015 0.015 NA NA 0.015 0.015
Titanium NA NA NA NA NA NA NA NA NA
Vanadiuma 0.344 0.344 0.344 4.16 4.16 0.344 0.344 4.16 4.16
Zinca 66.1 66.1 66.1 75.4 75.4 66.1 66.1 75.4 75.4
Nitrated NA NA NA 507 507 NA NA 507 507
Analyte
Aquatic
TRVs (NOAEL)
Terrestrial
Mallard Duck
(mg/kg/day)
Great Blue
Heron
(mg/kg/day)
Bald Eagle
(mg/kg/day)
Muskrat
(mg/kg/day)
River Otter
(mg/kg/day)
American
Robin
(mg/kg/day)
Red-Tailed
Hawk
(mg/kg/day)
Meadow Vole
(mg/kg/day)
Red Fox
(mg/kg/day)
Aluminuma 1100 1100 1100 19.3 19.3 1100 1100 19.3 19.3
Antimonya NA NA NA 0.59 0.59 NA NA 0.59 0.59
Arsenicb 40.3 40.3 40.3 1.66 1.66 40.3 40.3 1.66 1.66
Bariumc 41.7 41.7 41.7 75 75 41.7 41.7 75 75
Berylliuma NA NA NA 6.6 6.6 NA NA 6.6 6.6
Borona, b 100 100 100 93.6 93.6 100 100 93.6 93.6
Cadmiuma 2.37 2.37 2.37 10 10 2.37 2.37 10 10
Calcium EN EN EN EN EN EN EN EN EN
Chromium, Totald 5 5 5 27400 27400 5 5 27400 27400
Chromium VI (hexavalent)a NA NA NA 40 40 NA NA 40 40
Chromium IIIa 2.66 2.66 2.66 9.625 9.625 2.66 2.66 9.625 9.625
Cobalta 7.8 7.8 7.8 10.9 10.9 7.8 7.8 10.9 10.9
Coppera 12.1 12.1 12.1 9.34 9.34 12.1 12.1 9.34 9.34
Iron EN EN EN EN EN EN EN EN EN
Leadb 3.26 3.26 3.26 8.9 8.9 3.26 3.26 8.9 8.9
Magnesium EN EN EN EN EN EN EN EN EN
Manganesea 348 348 348 71 71 348 348 71 71
Mercurye 0.37 0.37 0.37 0.16 0.16 0.37 0.37 0.16 0.16
Molybdenuma, d 35.3 35.3 35.3 2.6 2.6 35.3 35.3 2.6 2.6
Nickela 11.5 11.5 11.5 3.4 3.4 11.5 11.5 3.4 3.4
Potassium EN EN EN EN EN EN EN EN EN
Seleniuma 0.579 0.579 0.579 0.215 0.215 0.579 0.579 0.215 0.215
Sodium EN EN EN EN EN EN EN EN EN
Strontiuma, d NA NA NA 2630 2630 NA NA 2630 2630
Thalliuma NA NA NA 0.075 0.075 NA NA 0.075 0.075
Vanadiuma 0.688 0.688 0.688 8.31 8.31 0.688 0.688 8.31 8.31
Zinca 66.5 66.5 66.5 75.9 75.9 66.5 66.5 75.9 75.9
Nitrated NA NA NA 1130 1130 NA NA 1130 1130
TRV - Toxicity Reference Value
Table 2 (Cont.)
NOTES:
NOAEL - No Observed Adverse Effects Level
LOAEL - Lowest Observed Effects Level
EN - Essential nutrient
NA - Not available
b USEPA 2005 EcoSSL
c Only a single paper (Johnson et al., 1960) with data on the toxicity of barium hydroxide to one avian species (chicken) was identified by USEPA (2005); therefore, an avian TRV could not
be derived and an Eco-SSL could not be calculated for avian wildlife (calculation requires a minimum of three results for two test species). Johnson et al. (1960) reports a subchronic
NOAEL of 208.26 mg/kg/d. The NOAEL was multiplied by an uncertainty factor of 0.1 to derive a very conservative TRV of 20.8 mg/kg/d.
d Sample et al. 1996
a CH2M Hill. 2014. Tier 2 Risk-Based Soil Concentrations Protective of Ecological Receptors at the Hanford Site. CHPRC-01311. Revision 2. July.
Http://pdw.hanford.gov/arpir/pdf.cfm?accession=0088115
Analyte Aquatic
TRVs (LOAEL)
Terrestrial
Table 3
Exposure Area and Area Use Factors for Ecological Receptors
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
Mallard
Duck
Great Blue
Heron Muskrat River
Otter
Bald
Eagle
American
Robin
Red-Tailed
Hawk
Meadow
Vole Red Fox
Ecological Exposure Area 1 14.6 3.36%6.43%100%4.20%0.66%100%1.667%100%1.19%
NOTES:
Area Use Factor (AUF)
Exposure Point Exposure Areaa
(hectares)
a Ecological Exposure Area 1 is east of the active ash basin. It includes the shore of Lake Norman and a feeder stream as well as some open water habitat in
Lake Norman.
Table 4
EPCs for Use in the Risk Assessment
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
COPC CASRN
Sediment EPC Used in
Risk Assessmentc
(mg/kg)
Surface Water EPC Used
in Risk Assessment
(mg/L)
Aluminum 7429-90-5 0.2639
Barium 7440-39-3 128
Chromium, Total 7440-47-3 45.6
Cobalt 7440-48-4 0.006483
Copper 7440-50-8 0.002696
Manganese 7439-96-5 0.501
Selenium 7782-49-2 4
Aquatic EPCsa, b
a EPCs for surface water are based on 95% UCLs. EPCs for sediment are based on maximum values.
b Surface water and sediment EPCs are used to evaluate aquatic receptors.
c Analysis of solids (i.e., soil and sediment) was reported as dry weight.
NOTES:
COPC - Constituent of Potential Concern
CASRN - Chemical Abstracts Service Registration Number
EPC - Exposure Point Concentration
Table 5
Calculation of Average Daily Doses for Mallard Duck
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
EPCw EPCs EPCp EPCi NIRw ADDW Pf NIRf NIRp ADDp Af NIRa ADDa Sf NIRs ADDs BF ADDt SUF AUF ADDtot
Analyte COPEC in Water
(mg/L)
COPEC in Solid
(mg/kg)
Slope, or Plant
Uptake (BAF)Intercept
Estimated1
Concentration
in Vegetation
(mg/kg dry)
Slope, or
Invertebrate
Uptake (BAF)
Intercept
Estimated2
Concentration
in
Invertebrates
(mg/kg dry)
Water
Ingestion Rate
(L/kg BW/day)
Unadjusted
Average Daily
Dose Water
(mg/kg/day)
Fraction Diet
Plant Matter
(percent)
Food Ingestion
Rate, Wet
(kg/kg BW/day)
Plant Ingestion
Rate, Dry
(kg/kg BW/day)
Unadjusted
Average Daily
Dose Plant
(mg/kg/day)
Fraction Diet
Invertebrates
(percent)
Invertebrates
Ingestion Rate
(kg dry/kg
BW/day)
Unadjusted
Average Daily
Dose
Invertebrates
(mg/kg/day)
Fraction Diet
Soil (percent)
Soil Ingestion3
Rate (kg dry/kg
BW/day)
Unadjusted
Average Daily
Dose Soil
(mg/kg/day)
Bioavailability3
(percent)
Omnivore
Intake
(mg/kg/day)
Seasonal Use
Factor
(unitless)
Area Use Factor
(Exposure
Area/Home
Range)
Adjusted Total
Omnivore
Average Daily
Dose
(mg/kg/day)
Aluminum 0.2639 0.0008 0 1 0 0.057 0.015 48%0.068 0.0049 0 48%0.007 0 3.3%0.00029 0 100%0.02 1 0.034 0.000505
Barium 128 0.03 3.84 1 128 0.057 0 48%0.068 0.0049 0.018918 48%0.007 0.9249 3.3%0.00029 0.03734 100%0.9811 1 0.034 0.032930
Chromium, Total 45.6 0.0015 0.0684 0.1 4.56 0.057 0 48%0.068 0.0049 0.000337 48%0.007 0.0329 3.3%0.00029 0.01330 100%0.04659 1 0.034 0.001564
Cobalt 0.0065 0.004 0 1 0 0.057 0.0004 48%0.068 0.0049 0 48%0.007 0 3.3%0.00029 0 100%0.0004 1 0.034 0.000012
Copper 0.0027 0.057 0.00015 48%0.068 0.0049 0 48%0.007 0 3.3%0.00029 0 100%0.0002 1 0.034 0.000005
Manganese 0.501 0.057 0.029 48%0.068 0.0049 0 48%0.007 0 3.3%0.00029 0 100%0.03 1 0.034 0.000958
Selenium 4.1 1.104 -0.678 2.4102 0.7 2.87 0.057 0 48%0.068 0.0049 0.011874 48%0.007 0.0207 3.3%0.00029 0.00120 100%0.033808081 1 0.034 0.001135
NOTES:
EPC - Exposure Point Concentration BF - Bioavailability Factor SUF - Seasonal Use Factor
NIR - Normalized Ingestion Rate BAF - Bioaccumulation Factor AUF - Area Use Factor
ADD - Average Daily Dose BCF - Bioconcentration Factor
AVERAGE DAILY DOSE VIA:
WATER
1 Bechtel Jacobs Company 1998a; Baes et al. 1984 (Mo); Environmental Restoration Division - Manual ERD-AG-003 1999; default value of 1 is used for constituents for which a BAF could not be found.
2 Bechtel Jacobs Company 1998b, Table 2, median BAFs for sediment to benthic invertebrates for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn; Sample et al. 1998b (earthworms) for Mn; default value of 1 is used for constituents for which a BAF could not be found.
PLANTS/VEGETATION INVERTEBRATES SOIL
3 Bioavailability is set to a default of 100% to be conservative and protective of ecological receptors.
Table 6
Calculation of Average Daily Doses for Great Blue Heron
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
EPCw EPCs EPCfish EPCi NIRw ADDw Af NIRf NIRa ADDa Af NIRa ADDa BF ADDt SUF AUF ADDtot
Analyte COPEC in
Water (mg/L)
COPEC in Solid
(mg/kg)
Fish Uptake
(BCF)
Estimated1
Concentration
in Fish (mg/kg)
Slope, or
Invertebrate
Uptake (BAF)
Intercept
Estimated2
Concentration
in
Invertebrates
(mg/kg dry)
Water
Ingestion Rate
(L/kg BW/day)
Unadjusted
Average Daily
Dose Water
(mg/kg/day)
Fraction Diet
Animal Matter
(percent)
Food Ingestion
Rate, Wet
(kg/kg
BW/day)
Fish Ingestion
Rate (kg/kg
BW/day)
Unadjusted
Average Daily
Dose
(mg/kg/day)
Fraction Diet
Invertebrates
(percent)
Invertebrates
Ingestion Rate
(kg dry/kg
BW/day)
Unadjusted
Average Daily
Dose
Invertebrates
(mg/kg/day)
Bioavailability3
(percent)
Piscivore Intake
(mg/kg/day)
Seasonal Use
Factor
(unitless)
Area Use
Factor
(Exposure
Area/Home
Range)
Adjusted Total
Piscivore Average
Daily Dose
(mg/kg/day)
Aluminum 0.2639 0.1 0.03 1 0.26 0.045 0.012 90%0.18 0.162 0.004 10%0.004 0.001 100%0.02 1 0.064 0.001
Barium 128 4 0 1 0 0.045 0 90%0.18 0.162 0 10%0.004 0 100%0 1 0.064 0
Chromium, Total 45.6 200 0 0.1 0 0.045 0 90%0.18 0.162 0 10%0.004 0 100%0 1 0.064 0
Cobalt 0.006483 300 1.94 1 0.01 0.045 0.0003 90%0.18 0.162 0.315 10%0.004 0.00002 100%0.32 1 0.064 0.020
Copper 0.002696 50 0.13 1.556 0.004 0.045 0.0001 90%0.18 0.162 0.022 10%0.004 0.00002 100%0.022 1 0.064 0.001
Manganese 0.501 400 200.40 0.682 -0.809 0.28 0.045 0.023 90%0.18 0.162 32.465 10%0.004 0.001 100%32.49 1 0.064 2.090
Selenium 4.1 8 0.00 0.7 0 0.045 0.000 90%0.18 0.0405 0.000 10%0.004 0.0000 100%0.000 1 0.064 0.000
NOTES:
EPC - Exposure Point Concentration BF - Bioavailability Factor SUF - Seasonal Use Factor
NIR - Normalized Ingestion Rate BAF - Bioaccumulation Factor AUF - Area Use Factor
ADD - Average Daily Dose BCF - Bioconcentration Factor
WATER FISH INVERTEBRATES
AVERAGE DAILY DOSE VIA:
1 Al (Voigt et al. 2015), mean of fish tissue BAFs; Cu (USEPA 1980); Environmental Restoration Division - Manual ERD-AG-003 1999.
3 Bioavailability is set to a default of 100% to be conservative and protective of ecological receptors.
2 Bechtel Jacobs Company 1998b, Table 2, median BAFs for sediment to benthic invertebrates for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn; Sample et al. 1998b (earthworms) for Mn; default value of 1 is used for constituents for which a BAF could not be found.
Table 7
Calculation of Average Daily Doses for Bald Eagle
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
EPCw EPCs EPCmb EPCfish NIRw ADDw Pfish Pmb NIRf NIRfish NIRmb ADDa Sf NIRs ADDs BF ADDt SUF AUF ADDTOT
Analyte COPEC in
Water (mg/L)
COPEC in Solid
(mg/kg)
Slope, or
Vertebrate
Uptake (BAF)
Intercept
Estimated1
Concentration in
Mammals and
Birds (mg/kg)
Fish
Uptake
(BCF)
Estimated2
Concentration
in Fish (mg/kg)
Water
Ingestion Rate
(L/kg
BW/day)
Unadjusted
Average Daily
Dose Water
(mg/kg/day)
Fraction of
Diet Fish
(percent)
Fraction of
Diet Mammal
+ Birds
(percent)
Food
Ingestion
Rate, Wet
(kg/kg
BW/day)
Fish Ingestion
Rate (kg/kg
BW/Day
Mammal/Bird
Ingestion Rate
(kg/kg BW/day)
Unadjusted
Average Daily
Dose
(mg/kg/day)
Fraction Diet
Soil (percent)
Soil Ingestion
Rate (kg
dry/kg
BW/day)
Unadjusted
Average Daily
Dose Soil
(mg/kg/day)
Bioavailability3
(percent)
Carnivore
Intake
(mg/kg/day)
Seasonal Use
Factor
Area Use
Factor
(Exposure
Area/Home
Range)
Adjusted Total
Carnivore
Average Daily
Dose (mg/kg/day)
Aluminum 0.2639 1 0 0.1 0.02639 0.058 0.02 58%42%0.12 0.0696 0.0498 0.002 0.5%0.0006 0 100%0.02 1 0.00664 0.0001
Barium 128 0.7 -1.412 7.27 4 0 0.058 0 58%42%0.12 0.0696 0.0498 0.36 0.5%0.0006 0.00998 100%0.3723 1 0.00664 0.002472
Chromium, Total 45.6 0.1444 -1.4599 0.40 200 0 0.058 0 58%42%0.12 0.0696 0.0498 0.02 0.5%0.0006 0.00356 100%0.02364 1 0.00664 0.00015693
Cobalt 0.006483 300 1.9449 0.058 0.0004 58%42%0.12 0.0696 0.0498 0.14 0.5%0.0006 0 100%0.136 1 0.00664 0.000901
Copper 0.002696 50 0.1348 0.058 0.0002 58%42%0.12 0.0696 0.0498 0.01 0.5%0.0006 0 100%0.01 1 0.00664 0.000
Manganese 0.501 0.004 0 400 200.4 0.058 0.03 58%42%0.12 0.0696 0.0498 13.95 0.5%0.0006 0 100%13.98 1 0.00664 0.093
Selenium 4.1 0.3764 -0.4158 1.12 8 0 0.058 0.00 58%42%0.12 0.0696 0.0498 0.06 0.5%0.0006 0.00032 100%0.06 1 0.00664 0.0003732
NOTES:
EPC - Exposure Point Concentration BF - Bioavailability Factor SUF - Seasonal Use Factor
NIR - Normalized Ingestion Rate BAF - Bioaccumulation Factor AUF - Area Use Factor
ADD - Average Daily Dose BCF - Bioconcentration Factor
3 Bioavailability is set to a default of 100% to be conservative and protective of ecological receptors.
AVERAGE DAILY DOSE VIA:
WATER VERTEBRATE PREY SOIL
1 Sample et al. 1998a; EPA 2007 EcoSSLs, Att 4-1, Table 4a
2 Al (Voigt et al. 2015), mean of fish tissue BAFs; Cu (USEPA 1980); Environmental Restoration Division - Manual ERD-AG-003 1999.
Table 8
Calculation of Average Daily Doses for Muskrat
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
EPCw EPCs EPCp NIRW ADDw Pf NIRf NIRp ADDp Sf NIRs ADDs BF ADDt SUF AUF ADDtot
Analyte COPEC in Water
(mg/L)
COPEC in Solid
(mg/kg)
Slope, or Plant
Uptake (BAF)Intercept
Estimated1
Concentration
in Vegetation
(mg/kg dry)
Water Ingestion
Rate (L/kg
BW/day)
Unadjusted
Average Daily
Dose Water
(mg/kg/day)
Fraction Diet
Plant Matter
(percent)
Food Ingestion
Rate, Wet
(kg/kg BW/day)
Plant Ingestion
Rate, Dry
(kg/kg/day)
Unadjusted
Average Daily
Dose Plant
(mg/kg/day)
Fraction Diet
Soil (percent)
Soil Ingestion
Rate (kg dry/kg
BW/day)
Unadjusted
Average Daily
Dose Soil
(mg/kg/day)
Bioavailability2
(percent)
Herbivore
Intake
(mg/kg/day)
Seasonal Use
Factor (unitless)
Area Use Factor
(Exposure
Area/Home
Range)
Adjusted Total
Herbivore
Average Daily
Dose
(mg/kg/day)
Aluminum 0.2639 0.0008 0 0.97 0.26 99%0.3 0.045 0 1%0.000273 0 100%0.26 1 1 0.26
Barium 128 0.03 3.8400 0.97 0 99%0.3 0.045 0.17159 1%0.000273 0.00454 100%0.18 1 1 0.18
Chromium, Total 45.6 0.0015 0.0684 0.97 0 99%0.3 0.045 0.00306 1%0.000273 0.00162 100%0.005 1 1 0.005
Cobalt 0.006483 0.004 0 0.97 0.01 99%0.3 0.045 0 1%0.000273 0 100%0.01 1 1 0.01
Copper 0.002696 0.97 0.003 99%0.3 0.045 0 1%0.000273 0 100%0.003 1 1 0.003
Manganese 0.501 0.05 0 0.97 0.49 99%0.3 0.045 0 1%0.000273 0 100%0.49 1 1 0.49
Selenium 4.1 1.104 -0.678 2.4102 0.97 0.00 99%0.3 0.045 0.10770 1%0.000273 0.00015 100%0.11 1 1 0.11
NOTES:
EPC - Exposure Point Concentration BF - Bioavailability Factor SUF - Seasonal Use Factor
NIR - Normalized Ingestion Rate BAF - Bioaccumulation Factor AUF - Area Use Factor
ADD - Average Daily Dose BCF - Bioconcentration Factor
AVERAGE DAILY DOSE VIA:
WATER PLANTS / VEGETATION SOIL
1 Bechtel Jacobs Company 1998a; Baes et al. 1984 (Mo); Environmental Restoration Division - Manual ERD-AG-003 1999; default value of 1 is used for constituents for which a BAF could not be found.
2 Bioavailability is set to a default of 100% to be conservative and protective of ecological receptors.
Table 9
Calculation of Average Daily Doses for River Otter
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
EPCw EPCs EPCPREY NIRw ADDw Pf NIRf NIRa ADDa BF ADDt SUF AUF ADDtot
Analyte
COPEC in
Water (mg/L)
COPEC in Solid
(mg/kg)
Fish Uptake
(BCF)
Estimated1
Concentration
in Fish (mg/kg)
Water
Ingestion Rate
(L/kg BW/day)
Unadjusted
Average Daily
Dose Water
(mg/kg/day)
Fraction Diet
Animal Matter
(percent)
Food Ingestion
Rate, Wet
(kg/kg BW/day)
Fish Ingestion
Rate (kg/kg
BW/day)
Unadjusted
Average Daily
Dose
(mg/kg/day)
Bioavailability2
(percent)
Piscivore
Intake
(mg/kg/day)
Seasonal Use
Factor
(unitless)
Area Use
Factor
(Exposure
Area/Home
Range)
Adjusted Total
Piscivore
Average Daily
Dose
(mg/kg/day)
Aluminum 0.2639 0.1 0.03 0.081 0.021 100%0.19 0.19 0.005 100%0.026 1 0.042 0.001107
Barium 128 4 0 0.081 0 100%0.19 0.19 0 100%0 1 0.042 0
Chromium, Total 45.6 200 0 0.081 0 100%0.19 0.19 0 100%0 1 0.042 0
Cobalt 0.006483 300 1.94 0.081 0.001 100%0.19 0.19 0.37 100%0.37 1 0.042 0.015525
Copper 0.002696 50 0.13 0.081 0.0002 100%0.19 0.19 0.026 100%0.026 1 0.042 0.001084
Manganese 0.501 400 200.4 0.081 0.041 100%0.19 0.19 38.08 100%38.117 1 0.042 1.59914
Selenium 4.1 8 0.00 0.081 0.000 100%0.19 0.19 0.000 100%0.000 1 0.042 0.000000
NOTES:
EPC - Exposure Point Concentration BF - Bioavailability Factor SUF - Seasonal Use Factor
NIR - Normalized Ingestion Rate BAF - Bioaccumulation Factor AUF - Area Use Factor
ADD - Average Daily Dose BCF - Bioconcentration Factor
AVERAGE DAILY DOSE VIA:
DRINKING WATER FISH
1 Al (Voigt et al. 2015), mean of fish tissue BAFs; Cu (USEPA 1980); Environmental Restoration Division - Manual ERD-AG-003 1999.
2 Bioavailability is set to a default of 100% to be conservative and protective of ecological receptors.
Table 10
Hazard Quotients for COPCs - Aquatic Receptors
Ecological Exposure Area 1
Baseline Ecological Risk Assessment
Duke Energy
Marshall Steam Station - Terrell, NC
Mallard Duck Great Blue Heron Bald Eagle1 Muskrat River Otter
Aluminum 4.59E-06 1.00E-05 6.04E-05 1.33E-01 5.74E-04
Barium 1.58E-03 0.00E+00 3.19E-04 3.40E-03 0.00E+00
Chromium, Total 1.56E-03 0.00E+00 6.64E-03 1.71E-06 0.00E+00
Cobalt 1.63E-06 2.67E-03 8.72E-04 8.58E-04 2.12E-03
Copper 1.27E-06 3.49E-04 1.64E-03 4.67E-04 1.94E-04
Manganese 5.35E-06 1.17E-02 3.71E-05 9.44E-03 3.11E-02
Mallard Duck Great Blue Heron Bald Eagle1 Muskrat River Otter
Aluminum 4.59E-07 1.00E-06 6.04E-06 1.33E-02 5.74E-05
Barium 7.90E-04 0.00E+00 1.59E-04 2.35E-03 0.00E+00
Chromium, Total 3.13E-04 0.00E+00 1.33E-03 1.71E-07 0.00E+00
Cobalt 1.59E-06 2.60E-03 8.51E-04 5.77E-04 1.42E-03
Copper 4.26E-07 1.17E-04 5.49E-04 2.80E-04 1.16E-04
Manganese 2.75E-06 6.00E-03 1.91E-05 6.84E-03 2.25E-02

Hazard Quotients greater than or equal to 1 are highlighted in gray and in boldface.
1 The bald eagle was added to this risk assessment model because the species is federally protected and represents a raptor that preys upon fish,
primarily, while the Red-Tailed Hawk primarily preys upon small terrestrial vertebrates (e.g., rodents, snakes, etc.). Hazard quotient calculations for
the Bald Eagle include hypothetical consumption of fish that inhabit adjacent surface water areas in addition to terrestrial vertebrates that inhabit
adjacent areas.
Wildlife Receptor Hazard Quotient Estimated using the 'No Observed Adverse Effects Level'
AquaticAnalyte
Analyte
Wildlife Receptor Hazard Quotient Estimated using the 'Lowest Observed Adverse Effects Level'
Aquatic
NOTES:
NM - Not measured due to lack of a Toxicity Reference Value

Appendix C

Exposure Modeling and
Human Health Risk
Assessment for Diesel
Emissions

1805955.000 - 1990 C-1
Air Dispersion Modeling for Marshall Ash Basin Closure
I used screening models to evaluate the potential for both cancer and non-cancer risks from
diesel exhaust emissions due to increased trucking operations related to the closure of the coal
ash basin at the Duke Energy Marshall Steam Station (MSS). The calculated cancer and non-
cancer risks are associated with increased diesel trucking activity near residential properties that
lie along transportation corridors near MSS. Modelling was conducted for the cap in place (CIP)
closure option, the excavation closure option, and the hybrid option. Details of these closure
options are provided in the main body of the report.
Emission rates for the fleet of diesel trucks operating as part of closure activities were calculated
based on truck activity and emission factors representative of the region from the U.S.
Environmental Protection Agency (EPA) Mobile Vehicle Emissions Simulator (MOVES). I
estimated airborne concentrations of emitted pollutants using the EPA model AERMOD for
atmospheric dispersion and transport. AERMOD is a Gaussian plume model that accounts for
the impacts of meteorology and land characteristics on airborne pollutants. Together these tools
allowed for the estimation of airborne concentrations of diesel particulate matter (DPM) emitted
from passing trucks and subsequent calculation of potential non-cancer health impacts (hazard
index [HI]) and cancer risk estimates (excess lifetime cancer risk [ELCR]).
The following sections detail the data and models used in this evaluation, including the
meteorological data, trucking operations, emissions calculations, and dispersion modeling. I also
include additional discussion of the results and associated uncertainties.

1805955.000 - 1990 C-2
Methodology
Meteorological Data
AERMOD-ready five-year 1 meteorological data sets of hourly surface meteorological data for
the years 2012–2016 were generated from the National Weather Service (NWS) Automated
Surface Observing System (ASOS) station at the Statesville Regional Airport (KSVH) in
Statesville, North Carolina.2 The Statesville Regional Airport is located approximately 18 km
from Duke Energy’s MSS. I judged this station to be representative of the meteorology in the
region of MSS. Surface parameters applied to the modeling study included wind speed and
direction, temperature, pressure, relative humidity, and cloud cover. Twice daily rawinsonde 3
observations of upper air winds and temperatures were taken from Piedmont Triad International
Airport (KGSO), which at 107 km from MSS is the closest upper air sounding site.
The meteorological data were processed using AERMET (v16216) with default options.4
AERSURFACE 5 was used to define the land-use characteristics in the region around the surface
observational site (i.e., Statesville Regional Airport). The surface characteristics, which are
important when calculating the level of atmospheric dispersion in meteorological modeling,
include surface roughness, albedo,6 and Bowen ratio.7

1 Use of five years of meteorological data is standard in regulatory application of AERMOD (EPA Guideline on
Air Quality Models, Section 8.3.1, 2005).
2 Integrated surface hourly weather observations are available at ftp://ftp.ncdc.noaa.gov/pub/data/noaa/.
3 A rawinsonde is a device typically carried by weather balloons that collects meteorological and atmospheric
data, especially regarding winds.
4 AERMET is an EPA program that will read standard recorded meteorological observations, calculate boundary
layer meteorological parameters, and output the data in a format readable by the AERMOD model (U.S. EPA
2016).
5 AERSURFACE is the EPA model used to calculate average land-use characteristics. It can read standard
databases and calculate the average values of surface roughness, albedo, and Bowen ratios, consistent with EPA
recommended methods.
6 Albedo is the ratio of reflected flux density to incident flux density. It indicates how much incoming energy is
absorbed by the land surface. Light surfaces (such as snow) will reflect higher levels of incoming energy.
7 Bowen ratio is the ratio of sensible to latent heat fluxes from the earth’s surface up into the air. Lower Bowen
ratio indicates greater water content in the land surface.

1805955.000 - 1990 C-3
Trucking Operations
Diesel emissions estimates from trucking are based on the number of trucks passing a given
receptor location along transportation corridors used during ash basin closure. The total number
of truckloads required for transporting ash, earthen fill, and geosynthetic materials under the
MSS closure options were projected by Duke Energy (2018b). These truckloads equate to
41,164 total truck passes for the CIP options, 58,605 total truck passes for the excavation option,
and 40,919 truck passes for the hybrid option. Additional loads of onsite ash-hauling trucks
were not included. I included only loads hauling earthen fill, geosynthetic materials, and other
materials in transportation emissions estimates for all options because trucks hauling ash in the
excavation and hybrid closure options do not leave MSS. Trucks hauling earthen fill are
assumed to travel 11 miles one way from the site, and trucks hauling geosynthetic material are
assumed to travel from Georgetown, South Carolina. Air modeling is conducted for a receptor
along the transportation route within the 11-mile radius traveled both by trucks hauling earthen
fill and by trucks hauling geosynthetic material. Trucks are assumed to travel in round trips, so
the number of material loads was doubled to represent the number of truck passes.
AERMOD
The AERMOD modeling system (U.S. EPA 2016) is a steady-state plume model that
incorporates air dispersion based on planetary boundary layer turbulence structure and scaling
concepts, including treatment of surface and elevated sources. EPA’s “Guideline on Air Quality
Models” (U.S. EPA 2016) identifies AERMOD as the preferred refined dispersion modeling
technique for receptors within 50 km of a modeled source.
The latest version of AERMOD (v16216r) was used with default options to conduct the
modeling.
Modeled Source and Receptors
AERMOD was configured to simulate an approximately 1-km stretch of road. This road
segment was assumed representative of any segment along the proposed transportation
corridors. The road emission source was modeled as a continuous distribution of emission along
the road due to the passage of multiple trucks. In the cross-road direction, the emissions drop off

1805955.000 - 1990 C-4
based on a normal (or Gaussian) distribution. The road emissions were represented using a line
of closely spaced volume sources running down the center of the road. Volume sources define
the initial pollutant distribution based on an initial release height and the standard deviation of
the normal distribution in both the vertical and horizontal directions (sigma-y and sigma-z). The
appropriate values for the release height and standard deviations were calculated based on
guidance in EPA’s Haul Road Working Group Final Report (U.S. EPA 2010).
Transport and dispersion of pollutants away from the road segment may be sensitive to the
predominant wind directions at the site and the orientation of the road compared to those
predominant wind directions. To fully evaluate the impacts of any road segment, four
orientations of the road were considered. Modeled orientations included roads running
north/south, east/west, northeast/southwest, and northwest/southeast. For each modeled road
orientation, receptors were included on both sides of the road to represent impacts at distances
between 10 and 150 m from the edge of the road. The representative road segments and
sampling receptor locations are shown in Figure C-1.
AERMOD was run for the five-year period (2012–2016) defined by the meteorological data.
The resulting five-year average dispersion factors were assumed representative of long-term
average dispersion of truck roadway emissions along roads in this region.

1805955.000 - 1990 C-5

Figure C-1. Location of road sources (blue) and sampling receptors (red) for each of 4 road
orientations

1805955.000 - 1990 C-6
Source Emission Rates
Emission rates for mobile sources are typically calculated based on a combination of emission
factors and activity rates. The emission factors define the amount of pollutant emitted per unit
distance traveled (grams of pollutant per kilometer traveled), and the activity rates define how
much activity occurs (i.e., the number of kilometers driven by the vehicles). Emission factors
will be specific to the type of vehicle being considered, the model year, the age of the vehicle,
and the local climate. For this evaluation, EPA’s MOVES model was used to define fleet
average emission factors for various years between 2018 and 2050 (2050 is the last year
simulated by MOVES) (U.S. EPA 2015). The 2050 emission factors were retained for all years
after 2050. These emission factors are specific to North Carolina and have been selected to
represent large, single unit diesel trucks.
Tailpipe emissions from diesel trucks (DPM) are the subset of PM10 of particular interest when
evaluating the cancer and non-cancer risk estimates in this analysis. The DPM emission factors
generated by MOVES were multiplied by the expected number of trucks under each of the
considered closure options to calculate emission rates for each option.
For the cancer risk analysis, emissions were calculated as an average over the regulatory default
70-year residential exposure duration. If the truck activity for a closure option occurs over a
shorter period, the duration of the truck activity exposure is factored into the 70-year averaging
time (OEHHA 2015). These average emission rates were multiplied by the dispersion factors
calculated by AERMOD to predict airborne concentrations. The resulting values were then
multiplied by the cancer unit risk factor 8 to quantify cancer risk.

8 A “reasonable estimate” for the inhalation unit risk of 3.0×10-4 (µg/m3)-1 was applied based on California
guidelines (OEHHA 2015).

1805955.000 - 1990 C-7
For the non-cancer analysis, airborne concentrations of DPM were calculated and compared to
the non-cancer risk threshold of 5 µg/m3.9 In this case, the average concentrations are not tied to
a 70-year period and are calculated over the period of operation for each closure option.

9 North Carolina defers to the EPA’s chronic non-cancer reference concentration (RfC) for DPM of 5 µg/m3
based on diesel engine exhaust to estimate risk from diesel emissions (Integrated Risk Information System
[IRIS]. U.S. EPA. Diesel engine exhaust).

1805955.000 - 1990 C-8
Uncertainties
A number of uncertainties should be considered when evaluating the modeled results. First, air
dispersion modeling is a mathematical calculation of pollutant transport and dispersion and may
differ from real world conditions. Typically, for regulatory applications, air dispersion models
are expected to predict concentrations within a factor of two (40 CFR Part 51). Longer
averaging periods, such as those used in this study, would often have lower uncertainties as
compared with shorter average periods such as 1-hour or 24-hour averages.
The calculation of emission factors is meant to represent fleet average characteristics. The fleet
of trucks used at this specific site may differ from the average values included in MOVES. This
may result in higher or lower actual emission rates. Additionally, MOVES includes predictions
of future year emission factors based on typical patterns of vehicle turnover and any regulations
scheduled to be implemented in future years. Not all future regulations are presently known and
future conditions may vary from these estimates.
For the non-cancer risk, an evaluation of the average concentrations was calculated over the
actual period of activity, which varies between closure options. For this portion of the
evaluation, there was no accounting for how long the emissions were present. The non-cancer
risk value is generally considered applicable over a period of approximately eight years. For
activities that occur for less than eight years, comparison with this risk value may overstate the
actual risk. Correspondingly, for activities that run significantly longer than eight years, there
may be sub-periods with higher average concentrations and higher associated non-cancer risk.

1805955.000 - 1990 C-9
Results
Worst-case impacts were calculated for each distance from the modeled road. The worst-case
result represents the highest value calculated over the four road orientations. This may not be
the same orientation for all distances. For example, a road that runs northeast/southwest aligns
with the predominant wind direction. This results in higher concentrations for receptors close to
the road. For receptors farther away from the edge of the road, the worst case occurs for a
northwest/southeast road where winds are perpendicular to the road. Worst-case results are
reported in Table 9-2 of the main report. The following sections include results for all road
orientations and distances from both sides of the road.
Model-estimated cancer risk
ELCR results for the four road orientations and both sides of the road are provided in Table C-1.

1805955.000 - 1990 C-10
Table C-1. ELCR estimates from DPM exposure due to trucking operations
associated with closure of MSS under a CIP closure, an excavation
closure, and a hybrid closure. Results for each road orientation and
distances from both sides of the road (ELCR columns per orientation).
E-W Run NE-SW Run N-S Run NW-SE Run
CIP
10 m 3.7E-09 4.3E-09 4.6E-09 4.5E-09 4.1E-09 3.8E-09 3.4E-09 3.5E-09
20 m 3.3E-09 3.9E-09 3.9E-09 3.8E-09 3.8E-09 3.4E-09 3.4E-09 3.5E-09
30 m 2.6E-09 3.1E-09 3.1E-09 2.9E-09 3.1E-09 2.6E-09 2.7E-09 2.8E-09
40 m 2.1E-09 2.5E-09 2.5E-09 2.3E-09 2.5E-09 2.1E-09 2.2E-09 2.3E-09
50 m 1.8E-09 2.1E-09 2.1E-09 1.9E-09 2.2E-09 1.8E-09 1.9E-09 2.0E-09
60 m 1.5E-09 1.8E-09 1.8E-09 1.7E-09 1.9E-09 1.5E-09 1.6E-09 1.7E-09
70 m 1.3E-09 1.6E-09 1.5E-09 1.4E-09 1.7E-09 1.3E-09 1.4E-09 1.5E-09
80 m 1.2E-09 1.4E-09 1.4E-09 1.3E-09 1.5E-09 1.2E-09 1.3E-09 1.3E-09
90 m 1.1E-09 1.3E-09 1.2E-09 1.1E-09 1.3E-09 1.0E-09 1.2E-09 1.2E-09
100 m 9.5E-10 1.2E-09 1.1E-09 1.0E-09 1.2E-09 9.5E-10 1.0E-09 1.1E-09
110 m 8.7E-10 1.1E-09 1.0E-09 9.1E-10 1.1E-09 8.6E-10 9.6E-10 1.0E-09
120 m 8.0E-10 9.9E-10 9.3E-10 8.3E-10 1.0E-09 7.9E-10 8.9E-10 9.4E-10
130 m 7.4E-10 9.2E-10 8.6E-10 7.6E-10 9.5E-10 7.3E-10 8.3E-10 8.7E-10
140 m 6.8E-10 8.6E-10 7.9E-10 7.0E-10 8.9E-10 6.7E-10 7.7E-10 8.1E-10
150 m 6.4E-10 8.0E-10 7.4E-10 6.4E-10 8.3E-10 6.3E-10 7.2E-10 7.6E-10
Excavation
10 m 3.0E-09 3.5E-09 3.8E-09 3.7E-09 3.4E-09 3.1E-09 2.8E-09 2.9E-09
20 m 2.7E-09 3.2E-09 3.2E-09 3.1E-09 3.2E-09 2.8E-09 2.8E-09 2.9E-09
30 m 2.1E-09 2.5E-09 2.5E-09 2.4E-09 2.5E-09 2.2E-09 2.2E-09 2.3E-09
40 m 1.7E-09 2.1E-09 2.0E-09 1.9E-09 2.1E-09 1.8E-09 1.8E-09 1.9E-09
50 m 1.5E-09 1.7E-09 1.7E-09 1.6E-09 1.8E-09 1.5E-09 1.5E-09 1.6E-09
60 m 1.3E-09 1.5E-09 1.5E-09 1.4E-09 1.6E-09 1.3E-09 1.3E-09 1.4E-09
70 m 1.1E-09 1.3E-09 1.3E-09 1.2E-09 1.4E-09 1.1E-09 1.2E-09 1.2E-09
80 m 9.7E-10 1.2E-09 1.1E-09 1.0E-09 1.2E-09 9.6E-10 1.0E-09 1.1E-09
90 m 8.7E-10 1.1E-09 1.0E-09 9.2E-10 1.1E-09 8.6E-10 9.5E-10 1.0E-09
100 m 7.8E-10 9.7E-10 9.1E-10 8.3E-10 1.0E-09 7.8E-10 8.6E-10 9.1E-10
110 m 7.1E-10 8.9E-10 8.3E-10 7.5E-10 9.2E-10 7.1E-10 7.9E-10 8.4E-10
120 m 6.6E-10 8.2E-10 7.6E-10 6.8E-10 8.5E-10 6.5E-10 7.3E-10 7.7E-10
130 m 6.1E-10 7.6E-10 7.0E-10 6.2E-10 7.8E-10 6.0E-10 6.8E-10 7.2E-10
140 m 5.6E-10 7.1E-10 6.5E-10 5.7E-10 7.3E-10 5.5E-10 6.3E-10 6.7E-10
150 m 5.2E-10 6.6E-10 6.1E-10 5.3E-10 6.8E-10 5.1E-10 5.9E-10 6.3E-10
Hybrid
10 m 3.3E-09 3.8E-09 4.1E-09 4.1E-09 3.7E-09 3.4E-09 3.0E-09 3.2E-09
20 m 3.0E-09 3.5E-09 3.5E-09 3.4E-09 3.4E-09 3.1E-09 3.0E-09 3.1E-09
30 m 2.3E-09 2.8E-09 2.7E-09 2.6E-09 2.8E-09 2.4E-09 2.4E-09 2.5E-09
40 m 1.9E-09 2.3E-09 2.2E-09 2.1E-09 2.3E-09 1.9E-09 2.0E-09 2.1E-09
50 m 1.6E-09 1.9E-09 1.9E-09 1.7E-09 1.9E-09 1.6E-09 1.7E-09 1.8E-09
60 m 1.4E-09 1.6E-09 1.6E-09 1.5E-09 1.7E-09 1.4E-09 1.5E-09 1.5E-09
70 m 1.2E-09 1.4E-09 1.4E-09 1.3E-09 1.5E-09 1.2E-09 1.3E-09 1.3E-09
80 m 1.1E-09 1.3E-09 1.2E-09 1.1E-09 1.3E-09 1.1E-09 1.1E-09 1.2E-09
90 m 9.4E-10 1.2E-09 1.1E-09 1.0E-09 1.2E-09 9.4E-10 1.0E-09 1.1E-09
100 m 8.5E-10 1.1E-09 9.9E-10 9.0E-10 1.1E-09 8.5E-10 9.4E-10 9.9E-10
110 m 7.8E-10 9.7E-10 9.1E-10 8.2E-10 1.0E-09 7.7E-10 8.6E-10 9.1E-10
120 m 7.1E-10 8.9E-10 8.3E-10 7.4E-10 9.2E-10 7.1E-10 8.0E-10 8.4E-10
130 m 6.6E-10 8.3E-10 7.7E-10 6.8E-10 8.5E-10 6.5E-10 7.4E-10 7.8E-10
140 m 6.1E-10 7.7E-10 7.1E-10 6.3E-10 7.9E-10 6.0E-10 6.9E-10 7.3E-10
150 m 5.7E-10 7.2E-10 6.6E-10 5.8E-10 7.4E-10 5.6E-10 6.5E-10 6.8E-10

1805955.000 - 1990 C-11
Model-estimated non-cancer risk
HI results for the four road orientations and both sides of the road are provided in Table C-2.
Table C-2. HI estimates from DPM exposure due to trucking operations associated
with closure of MSS under a CIP closure, an excavation closure, and a
hybrid closure. Results for each road orientation and distances from both
sides of the road (HI columns per orientation).
E-W Run NE-SW Run N-S Run NW-SE Run
CIP
10 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
70 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
80 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
90 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
100 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
110 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
120 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
130 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
140 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
150 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Excavation
10 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
70 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
80 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
90 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
100 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
110 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
120 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
130 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
140 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
150 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Hybrid
10 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
70 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
80 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
90 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
100 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
110 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
120 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
130 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
140 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
150 m 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

Appendix D

Habitat Equivalency Analysis

1805955.000 - 1990 D-1
Habitat Equivalency Analysis
Habitat equivalency analysis (HEA) was used to estimate changes in environmental service
levels under different closure options for the Duke Energy Marshall Steam Station (MSS). The
extent of environmental service flows currently provided by ash basin habitats (wooded areas,
open field, open water, etc.) and associated sites (borrow/landfill areas) was calculated and
compared to service flows provided by post-closure habitats in these areas.
The HEA proceeded in four steps:
1. Estimate habitat areas: The acres of different habitat types (e.g., forest,
open field, open water, wetland) that would be affected by closure under each
closure option (i.e., cap in place [CIP], excavation, and hybrid closures) were
estimated from aerial imagery.
2. Evaluate environmental service levels: The relative level of environmental
services provided by these habitats was estimated in terms of net primary
productivity (NPP).
3. Apply discounting for future services: The relative levels of environmental
services were calculated over time according to the construction
implementation schedule developed by Duke Energy (2018) and expressed in
units of discounted service acre-years (DSAYs).
4. Calculate discounted environmental services: DSAYs were summed
across the gains and losses of each habitat type to produce a net gain or loss
in environmental service levels for each closure option.
Estimate Habitat Areas
Acreages of current habitat types were calculated from geographic information system (GIS)
files provided by Duke Energy that included spatial representations of the current acreage of
open field, wetland, wooded area, and open water habitats surrounding the ash basin. The
acreages of ash basin to be closed and land converted to landfill or borrow pit were based on
information provided by Duke Energy (2018b) according to the assumptions below. For the

1805955.000 - 1990 D-2
excavation and hybrid options, the closure-by-removal portions of the ash basin were assumed
to be restored to historical, pre-basin conditions. Historical acreage of forested, open field, and
stream habitat types were estimated by measuring 1964 aerial photographs retrieved using the
U.S. Geological Service’s Earth Explore (earthexplorer.usgs.gov). Unclassified current habitat
areas in the ash basin footprint were assumed to be bare ground and to have a 0% service value.
Historical habitat types were broadly classified into forest, open water, and open-unclassified
areas since not all currently measured habitat types (e.g., scrub-shrub) could be resolved from
historical images. Historical areas of forest sub-habitat types not resolved in the historical
imagery were estimated by assuming the current (non-basin) site-wide percentages of broadleaf
forest (91%), needleleaf forest (8.3%), and wetland forest (<1%) were applied to the historical
forest areas within the ash basin footprint. Historical areas of open-unclassified (as forest or
open water) habitat types were estimated by assuming the current site-wide percentages of
scrub-shrub (72%), emergent wetland (3%), and open field (25%) applied to these areas within
the historical ash basin footprint. It is important to note that not all closure options impacted all
basin habitat areas, thus different closure options may be modeled in the HEA using different
total areas.
Additional assumptions used to calculate habitat areas included:
• Stream habitats in the ash basin were not indicated for MSS in historical
imagery and not included in the NPP services in ash basin restoration.
• Fill material for closure was assumed to be derived from excavation of basin
dam features and new onsite borrow pits. The areal extent of these borrow
pits was calculated from the volume (cubic yards) of required earthen fill
material, assuming borrow pits would be dug to 15 ft.
• Area lost to borrow pit excavation was assumed to contain forest habitat,
which is the predominant non-basin habitat type on the MSS property.
• Borrow material required for CIP closure of the Unit 5 basin was assumed to
not be available from closure activities in the active ash basin.

1805955.000 - 1990 D-3
Evaluate Environmental Services
NPP was used to standardize environmental services across habitat types. NPP is a measure of
how much photosynthesis occurs in an area greater than the amount required by the plants for
immediate respiration needs. Fundamentally, NPP is a measure of the energy available to
perform environmental services and is a useful currency for comparing habitats (Efroymson et
al. 2003). NPP is often referred to in terms of carbon fixation or carbon storage, as the removal
of carbon from the atmosphere is a primary reaction of photosynthesis.
Of the habitats currently occurring on the site, broadleaf, needleleaf, and mixed forested areas
have the highest NPP; that is, per acre of forest, photosynthesis fixes more carbon/produces
more energy for environmental services (Ricklefs 2008). As such, NPP service levels for all
habitat types were normalized to the NPP service level of forested habitat. Specifically, the
service levels for all habitat types were expressed as a proportion of the maximum wooded area
service level (He et al. 2012).
To compare results between the different closure options, a set of assumptions was used for all
options evaluated.
• Figure 22.12 from Ricklefs (2008) was used as the basis for determining
relative rates of NPP for different ecosystem types. For this evaluation,
temperate forest (woodland) was considered the base habitat with a relative
NPP of 100%. Other habitat types were normalized as a proportion of that
value based on the relative levels of NPP shown in Ricklefs’ Figure 22.12
(2008), using temperate grassland as representative of open fields and
freshwater environments as representative of open water.
− Based on Ricklefs’ Figure 22.12 (2008), NPP values for open field
and open water habitats were assumed to be 40% of the forest value.
However, because aquatic habitats of the ash basin may not be
functionally equivalent to naturally occurring freshwater ecosystems
(e.g., less abundant or diverse vegetation), a habitat quality

1805955.000 - 1990 D-4
adjustment factor of 4 was applied, lowering the relative NPP value
for ash basin open water habitat to 10% of temperate forest NPP.
• Figure 2c from He et al. (2012) was used to estimate NPP of woodland areas
based on stand age.
− The NPP functions for the three forest types (broadleaf, needleleaf,
mixed) from Figure 2c of He et al. (2012) were digitized to allow
calculation of NPP by stand age. For example, for mixed forests this
function shows rapidly increasing NPP up to a maximum at 45 years,
after which the NPP declines slightly to level off at approximately
85% of the maximum.
− All wooded areas currently occurring in the ash basin or on borrow or
landfill areas were assumed to be 50 years old, which, based on He et
al. (2012), provide approximately 97% of maximum NPP function in
the case of broadleaf and mixed forests and 84% for needleleaf
forests. Other habitats were normalized from the higher value using
the relative rates of NPP described above.
• Baseline levels of service (NPP) in the absence of closure activities were
assumed to continue at the current rate for 150 years, accounting for slight
changes in wooded area NPP by age as calculated from the NPP function of
He et al. (2012).
Apply Discounting for Future Services
HEA applies a discounting function when calculating the amount of environmental services
derived from an acre over a year and uses as its metric a discounted service acre-year, or DSAY.
Discounting is necessary because environmental services occurring in the future are assumed to
be less valuable to people than the same services performed now (Dunford et al. 2004;
Desvousges et al. 2018; Penn undated). This allows the environmental services occurring far in
the future to be considered on par with contemporary services. Thus, factors determining when

1805955.000 - 1990 D-5
closure and remediation begin and the duration of these processes are important parameters of
the final DSAY estimate.
I used the closure schedule provided by Duke Energy (2018b) to develop timelines for habitat
loss and gain under each closure option. For purposes of the HEA, only site preparation,
construction, and site restoration times were included. Pre-design and design permitting periods
were assumed to have no effect on environmental services. The closure schedule estimated
duration of each activity in months; however, since the HEA model calculates DSAYs on an
annual basis, the activity durations were rounded up the nearest full year. This has a negligible
impact on DSAY estimates.
The following assumptions were then used to standardize timing of activities among the closure
options:
• For all closure options, removal of existing onsite habitats was assumed to
occur in the year that construction begins and was assumed to be completed
the same year such that no environmental service is provided by the end of
the first construction year.
• Environmental services of areas used for borrow or as landfill were assumed
to be lost in the year construction starts, and borrow/landfill site preparation
was assumed to be complete the same year such that no environmental
service is provided by the end of the first construction year.
• Environmental service gains from restoration (ash basin and borrow area)
were assumed to begin in the year following completion of construction
activities.
• Post-closure habitats were presumed eventually to provide the same level of
service as equivalent pre-closure habitats with the following conditions:
− Forests would be age 0 in the year when restoration was completed
and would generate an increasing level of NPP as they grow,

1805955.000 - 1990 D-6
following the rates calculated from the NPP curves of He et al.
(2012).
− Restored open field habitat would take five years (based on
professional judgement) to reach the baseline relative to forest NPP of
40%, with service levels increasing linearly over that time.
− Restored wetland and stream habitat would be functionally equivalent
to natural freshwater ecosystems and would provide an NPP relative
to forests of 40% after five years (based on professional judgement),
increasing linearly over that time.
− Periodic mowing is required to maintain a grass cap, so grass cap was
assumed never to reach a level of service equivalent to an open field.
Grass cap was assumed to have 20% of the NPP service level for open
field, which is 8% of forest NPP. Grass cap was assigned a post-
closure service level of 8%, with full service attained in 2 years.
− Bare ground was assumed to provide no environmental service.
• The base year for discounting is 2019 for all closure options.
• A discount rate of 3% is applied for all closure options.
• The HEA is run for 150 years for all closure options.
Calculate Discounted Environmental Services
Calculation of DSAYs is a summation of the discounted losses and gains in service values
across habitat types. The net DSAYs calculated for each closure option are reported in Table 10-
1 of the main body of this report.
A sensitivity analysis of key parameters (based on professional experience) and assumptions
used in the HEA was conducted to evaluate how sensitive the HEA results are to changes in (1)
the duration over which the services were evaluated (i.e., 150 years), (2) the assumed relative
NPP of ash basin open water and open fields, and (3) habitat created by restoration of borrow

1805955.000 - 1990 D-7
areas. The results are discussed in the context of uncertainty in the net environmental benefit
analysis (NEBA) in Appendix E.

Appendix E

Net Environmental Benefit
Analysis

1805955.000 - 1990 E-1
Net Environmental Benefit Analysis
Net environmental benefit analysis (NEBA) is a structured framework for comparing impacts
and benefits to environmental services to support decision-making (Efroymson et al. 2003,
2004). In the NEBA application for the Marshall Steam Station (MSS) ash basin closure, a risk-
ranking approach, based on that described by Robberson (2006), was applied. The risk-ranking
approach develops alphanumerical estimates of relative risk by closure option and by attribute
(e.g., risk to a receptor, change in environmental services), which allows comparison of the
relative differences in impact between closure options to a variety of attributes. In this way,
tradeoffs can be visualized to inform decision-making.
Risk-Ranking Matrix
The risk-ranking matrix includes two axes that characterize risk. The y-axis shows the level of
impact, or risk, to an attribute, and the x-axis shows the duration of the impact (which is directly
related to the time to recovery). Both are important to evaluate the relative differences in risk
posed by closure options. A moderate level of impact over a long duration can potentially have
an overall greater negative impact on the environment than a higher impact over a very short
period (Robberson 2006). The pattern of shading of the risk matrix conveys this general
principle, though the exact shading of the cells is based on best professional judgement.
Robberson (2006) describes darker shading as indicating a higher level of concern over the level
of impact to a resource or environmental service. The NEBA matrix developed by the
Operational Science Advisory Team-2 (OSAT 2011) used a similar color coding approach to
compare risk from further cleanup of oil on beaches of the Gulf of Mexico following the
Deepwater Horizon oil spill. The risk-ranking matrix used in the NEBA of closure options for
the MSS ash basin is shown in Table E-1.

1805955.000 - 1990 E-2
Table E-1. Risk-ranking matrix for impacts and risk from closure activities. Darker
shading and higher codes indicate greater impact.

Duration of Impact (years)
>50
(8)
35–50
(7)
26–35
(6)
16–25
(5)
10–15
(4)
5–9
(3)
1–4
(2)
<1
(1) % Impact No meaningful risk -- -- -- -- -- -- -- --
<5 % (A) 8A 7A 6A 5A 4A 3A 2A 1A
5–19% (B) 8B 7B 6B 5B 4B 3B 2B 1B
20–39% (C) 8C 7C 6C 5C 4C 3C 2C 1C
40–59% (D) 8D 7D 6D 5D 4D 3D 2D 1D
60–79% (E) 8E 7E 6E 5E 4E 3E 2E 1E
>80% (F) 8F 7F 6F 5F 4F 3F 2F 1F
The percent impact levels (e.g., <5%, 5–19%) were defined based on best professional
judgement and regulatory precedent. A <5% impact characterizes a very minor potential or
expected impact that may be functionally indistinct from baseline conditions due to uncertainty
in metrics or the estimated effects. As such, this level of impact was given no shading,
regardless of the duration of impact. Impacts between 5–19% are considered low in the NEBA
framework (Efroymson et al. 2003). This impact level was shaded to reflect this low risk. Levels
of impact >20% were separated at intervals of 20% based on best professional judgement and
consistent with the risk-ranking approach used by Robberson (2006).
Similarly, the categories used to define duration of impact were based on best professional
judgment and regulatory precedent. Robberson (2006) defines recovery in <1 year as “rapid,”
with shading that indicates a generally low level of concern across the levels of impact. The
remaining time categories in the risk-ranking matrix were divided to separate relatively short
duration and time to recovery (e.g., 1–4 years, 5–9 years) from longer periods (e.g., 26–35
years). Approximately five-year periods were used to divide duration categories up to 15 years;
after 15 years, approximately 10-year periods were used. This reflects that smaller differences in
time are more important to distinguishing impacts from closure activities that last for shorter
periods; however, as impact duration increases differences in a few years are a diminishing
fraction of the total duration of the closure activities.

1805955.000 - 1990 E-3
As Robberson (2006) notes, the exact size of the risk matrix is a function of decisions made
about scaling the matrix, which is a function of the closure and remediation being considered
and the attributes included in the NEBA. For example, the duration of impact categories could
have been expanded to twelve (e.g., <1 year, 1–3 years, 3–6 years, 6–9 years, 9–12 years, 12–15
years, 15–20 years, 20–25 years, 26–35 years, 36–50 years, and >50 years) which would have
changed the alphanumeric risk ratings and perhaps some of the shading of attributes evaluated
in the NEBA. The purpose of the risk matrix, and the risk ratings that result from it, is to
consolidate the results from a variety of different analyses for a variety of different data types
and attributes into a single framework for comparative analysis. It is imperative, however, to
consider the underlying information used to develop the risk ratings to interpret the differences
between closure options, particularly when percent impacts or durations of closure options are
similar but receive different risk ratings. It is inappropriate to assume a risk rating for one
attribute is scientifically equivalent to the risk rating of another attribute because the
comparative metrics that form the foundation of the risk ratings can be fundamentally different
(e.g., a hazard quotient for risk to a bird species is different from discounted service acre-years
[DSAYs] for environmental services from a habitat). Thus, the risk ratings in the NEBA matrix
permit a relative comparison of impacts between closure options within attributes. Decision-
makers can use the NEBA framework to identify the relative impacts of closure options across
many different attributes, but the NEBA matrix does not, by design, elevate, or increase the
value of, any specific risk or benefit in the framework.
Risk Rating Sensitivity
Uncertainty in a NEBA can be evaluated by examining the uncertainty in the assumptions and
analyses used as inputs to the risk-ranking matrix. The following sections examine how
differences in assumptions could affect relative risk ratings in the NEBA framework for
attributes found to have levels of impact. Attributes for which no meaningful risk was found
(e.g., human health risk assessments, ecological health risk assessments) are not included in the
following discussion.

1805955.000 - 1990 E-4
Noise and congestion from trucking traffic
I used the number of trucks per day passing 1 a receptor along a near-site transportation corridor
as a metric to examine the differences in noise and traffic congestion under the closure options. I
compared the increase in truck passes due to hauling earthen fill, geosynthetic material, and
other materials under the closure options 2 to the current number of truck passes for the same
receptor.
The current (or baseline) number of truck passes was estimated from North Carolina
Department of Transportation (NCDOT) annual average daily traffic (AADT) data collected at
thousands of locations across the state and the proportion of road miles driven by large trucks in
North Carolina. AADT is an estimated daily traffic volume at a specific location, which
captures traffic in all lanes traveling in both directions and is assumed to represent typical traffic
volume for a year.3 Not all AADT data, however, differentiate between large trucks such as
those to be used in ash basin closure and other traffic such as cars, which is a relevant
distinction when considering impacts to communities from increased noise. NCDOT performs
vehicle classification 4 on trucking routes to estimate annualized truck percentage to apply to
AADT to determine truck AADT (NCDOT 2015). The average annualized truck percentage for
Catawba County is 6.6%.
The precise transportation corridor for trucks travelling to and from MSS during ash basin
closure is unknown; however, likely corridors in the communities local to MSS can be identified
by examining road maps and AADT statistics. MSS is located on a peninsula of Lake Norman

1 Truck passes per day resulting from trucking activities is calculated as the total number of loads required to
transport earthen fill, geosynthetic materials, and other materials multiplied by two to account for return trips.
The resulting total number of passes is then divided evenly among the total number of months of trucking time
multiplied by 26 working days per month.
2 Truck trips to haul ash were not included in the estimate for MSS ash basin closures because trucks hauling ash
would not leave the MSS property and would not affect community receptors along the transportation corridors.
3 AADT is calculated from two days of traffic counts at each station during weekdays, excluding holidays. Raw
monitoring data consists of counts of axle pairs made by pneumatic tube counters that are converted to traffic
volume by applying axle correction factors and expanded to annual estimates by seasonal correction factors.
Derived AADT values are checked for quality against nearby stations and historical station-specific values
(NCDOT 2014).
4 Vehicle classification is assigned based on number of axles, space between axles, weight of the first axle, and
total weight of the vehicle.

1805955.000 - 1990 E-5
that consists primarily of sparse lakeside communities and rural forest and farmland. The
peninsula is crossed by NC Highway (NC) 150, which transects the peninsula immediately
south of MSS providing the only east-west bridge crossing of Lake Norman in this area (Figure
E-1). NC 150 is heavily traveled, and the NCDOT traffic stations nearest the main plant
entrance road report 18,000 AADT (NCDOT Station ID 1700756 in 2017) and 17,000 AADT
(NCDOT Station ID 1700802 in 2017). Heavy trucks are likely to use this section of road when
hauling construction material for ash basin closure; however, they are unlikely to use the main
plant entrance for construction activities. The northern end of the ash basin is adjacent to Island
Point Rd (North Carolina State Road [SR] 1838), which is the most likely path for construction
traffic from the basin to SR 1848 (Sherrills Ford Rd) and connecting with NC 150. This section
of Island Point Rd serves a community of lakeside homes, and traffic monitoring stations on
Island Point Rd near the basin report 2,300 AADT in 2017 (NCDOT Station ID 1701940 and
NCDOT Station ID 1703452). To best capture trucking related impacts to sensitive communities
along the transportation corridor, I assumed a baseline truck passes per day of 153, which was
computed by multiplying 2,300 AADT (2017 estimate from Island Point Rd NCDOT Station ID
1701940) by the average percent of truck AADT for Catawba counties (6.6%; NCDOT 2015).5

5 AADT data are not available for every road or every location along a road. It is possible during closure of the
MSS ash basin that trucks will utilize less traveled roads (i.e., with lower AADT), which would have a lower
baseline truck passes per day estimate and result in a higher percent impact from ash basin closure for these
sensitive communities; however, by choosing the lowest available AADT estimate from roads within 10 miles
of MSS along the most likely transportation corridors to and from MSS to a major road (e.g., highway), my
analyses have considered sensitive communities that would be more affected by traffic noise and congestion
from ash basin closure trucking.

1805955.000 - 1990 E-6

Figure E-1. NCDOT annual average daily traffic (AADT) measurement stations near MSS.
Traffic stations and AADT values considered when determining the baseline
number of truck passes are indicated as squares.
The sensitivity of the NEBA relative risk ratings to the baseline assumption of 153 trucks per
day was evaluated by calculating relative risk ratings for a range of baseline truck traffic levels,
based on the minimum and maximum AADT values for any NCDOT station within a 50-mile
radius of the MSS ash basin, using AADT from the most recent year that data are available for a
particular station, and assuming 6.6% truck traffic as previously described. Figure E-2 plots the
resulting percent impact for closure options along with the resulting relative risk rating across
the range of 2 to 12,113 truck passes per day.

1805955.000 - 1990 E-7

Figure E-2. Sensitivity of NEBA relative risk rating for noise and congestion impacts from
trucking operations. The vertical line indicates the assumed baseline 153 truck
passes per day. The y-axis is plotted on a log10 scale and the X axis is
truncated at 500 to improve visualization.
Using a baseline truck passes per day of 153, the CIP and hybrid closure options fall into the
second lowest relative risk rating (B, 5–19%), while the excavation closure option has the
lowest risk rating (A, <5%) for traffic-induced noise and congestion during closure of the MSS
ash basin (Figure E-2). The relative risk rating for CIP and hybrid closure options could be
reduced to the lowest rating (A) if the baseline traffic assumption was increased to at least 221
truck passes per day. Higher risk ratings would result from a lower baseline truck traffic
assumption; decreasing the baseline truck traffic assumption to 55 raises the risk rating to C for
the CIP and hybrid closure options. At 153 truck passes per day, the risk rating for the
excavation closure option is near the baseline threshold. A decrease in the assumed baseline
from 153 to 140 truck passes per day would increase the risk rating for the excavation closure
option from A to B.

1805955.000 - 1990 E-8
Traffic accidents
I evaluated risk of traffic accidents by comparing the average number of annual offsite road
miles driven between closure options relative to a baseline estimate of the current annual road
miles driven.6 I chose a baseline of 129 million annual truck road miles based on the reported
total vehicle miles traveled in Catawba County, North Carolina (NCDOT 2017), multiplied by
the county average 6.6% contribution of trucks to total AADT (NCDOT 2015).
The sensitivity of the NEBA relative risk ratings to the baseline assumption of 129 million truck
miles per year was evaluated by calculating relative risk ratings for alternative baseline truck
mile assumptions derived from the counties in North Carolina with the minimum (Hyde County)
and maximum (Mecklenburg County) reported vehicle miles driven, resulting in a sensitivity
range estimated from 6.2 million to 641 million truck miles per year. Figure E-3 plots the
resulting percent impact for the closure options, along with the resulting relative risk ratings
across this range of truck miles per year.

6 The difference between the baseline miles assumption and the closure assumption was divided by the baseline
miles assumption and multiplied by 100 to get a percent impact.

1805955.000 - 1990 E-9

Figure E-3. Sensitivity of NEBA relative risk rating for traffic accidents due to trucking
activities. The vertical line indicates the assumed baseline 129 million truck
miles per year. The y-axis is plotted on a log10 scale to improve visualization.
Using the 129-million-truck-miles baseline assumption, all closure options have an impact of
less than 0.1%. All closure options have a relative risk rating of A (<5%). These relative risk
ratings do not appear to be sensitive to lower assumed baseline annual truck miles. The vertical
lines in Figure E-3 indicate the location of the baseline assumption. Reducing the baseline
assumption to the 6.2 million truck miles minimum does not increase percent impact to greater
than 0.8% for any option and the risk ratings remain unchanged.
Habitat Equivalency Analysis
Uncertainty in the habitat equivalency analysis (HEA) that examined disruption of
environmental services from ash basin closure was explored through sensitivity analyses of key
assumptions in the HEA. To test sensitivity, I re-ran HEA models with the following changes:
1. Running the HEA for 100 years instead of 150 years.

1805955.000 - 1990 E-10
2. Assuming the open water habitats of the ash basin provide environmental
services at 40% of wooded areas instead of 10%.
3. Assuming open field habitats provide environmental services at 20% of
wooded areas instead of 40%.
4. Assuming borrow area under the CIP option for the inactive basin is restored
to open field, not reforested.
For each sensitivity analysis, all parameters in the base model were held constant except the one
parameter varied to understand the sensitivity of the model to each assumption (Table E-2).
Table E-2. Change in DSAYs from base modela for key HEA assumptions
Closure Option 100-year
modelb
Ash basin
water 40%c
Borrow
becomes fieldd
Open Field
20%e
CIP 128 −760 −449 4
Excavation −28 −716 −558 −38
Hybrid −1 −760 −231 −48
a Base models were run for 150 years with ash basin open water NPP services at 10%, borrow fields
were assumed to become forest (CIP and hybrid) or mixed forest/grass cap (excavation), and open
field NPP services at 40%.
b Base models except the HEA was run for 100 years.
c Base models except ash basin open water NPP service at 40%.
d Base models except forested areas of borrow pits were assumed to become open field for all
options.
e Base models except open field NPP services decreased to 20%.
Running HEAs for 100 years increased net DSAYs slightly for the CIP option and decreased net
DSAYs slightly for the two other closure options. Increasing the ash basin open water service
level to 40% resulted in similar net negative DSAYs for all options. Assuming borrow areas
would be returned to open field resulted in a decrease in net DSAYs for all closure options.
Assuming open field NPP at 20% slightly increased CIP DSAYs and slightly decreased DSAYs
for the other two options.
Looking at the change in net DSAYs between the sensitivity models and their base models, the
changes in assumptions have relatively consistent effects on net DSAYs. For example, changing
ash basin open water services from 10 percent to 40 percent affects all closure options similarly,
since the same level of service change is applied over the same area for all closure options, with

1805955.000 - 1990 E-11
the slight difference due to the year when remediation starts and hence services are lost.
Assuming open field services at 20% results in a small net loss for the hybrid and CIP options
since the level of service provided by restored open fields is halved. Assuming that borrow
acreage is restored to open field and not forest habitat after borrow is complete results in a net
loss for all three options since all include reforestation of at least part of the borrow area.
However, since the directionality of net NPP services provided by the closure options does not
change under this sensitivity analysis (i.e., the hybrid option still results in the least net loss),
this demonstrates that the model can differentiate between relative differences in NPP service
level changes with consistency.
Changes in net DSAYs with changing assumptions may change the relative risk rating applied
to a closure option in the NEBA. However, the relative similarity in the way DSAYs change
with assumptions between the various closure options and the result that the hybrid option
results in the least net NPP services losses under any sensitivity analysis support the relative risk
ratings for decision support in the NEBA.
Closure Option Assumptions
The following assumptions were used to calculate NEBA input values related to trucking
activities and habitat acreages.
• The density of ash was assumed to be 1.2 ash tons/CY.
• Borrow pit acreage required to supply earthen fill and cover material was
assumed to be dug to a depth of 15 ft to meet volume requirements. Borrow
pits not specifically identified were assumed to contain a mixed forest habitat
that would be restored upon closure completion.
• Excavation was assumed to proceed at a rate of 1,000,000 CY/year for all
types of excavation material combined including ash, underlying over-
excavated or residual soil, and dam and embankment material.
• CIP cover systems were assumed to require two layers of geosynthetic
material. New landfill areas were assumed to require seven layers of

1805955.000 - 1990 E-12
geosynthetic material. Geosynthetic material was assumed to be transported
from Georgetown, South Carolina, at a rate of six loads per day and 3 acres
per load.
• Covers/caps for both CIP and landfills were assumed to receive 18 in. of
cover soil plus 6 in. of topsoil. New landfills also were assumed to receive 2
ft of liner soil. Topsoil was assumed to come from an offsite commercial
facility requiring no additional borrow area.
• Unless otherwise specified, offsite borrow material and topsoil were assumed
to be from sources 11 miles away (one way).
• Offsite truck capacity was assumed to be 20 CY of ash or earthen material.
• Working hours were assumed to be 10 hr/day, 6 days/week, and 26
days/month.
• Earthen fill material was assumed to be hauled in at a rate based on 1,000,000
CY/year.
• In excavated areas, 1 ft of over-excavation of residual soil was assumed.
When restoring these areas, 6 in. of top soil addition was assumed necessary
to establish vegetative stabilization over the total area.