NC0039578_More Information Received_20181025

TUCKASEIGEE WATER &SEWER AUTHORITY
SERVING JACKSON COUNTY
1246 West Main Street
Sylva, NC 28779
Phone:[phone] • Fax: [phone]
Oct 25, 2018
Attn:Nicholas Coco
NPDES Complex Permitting Unit
NC DEQ/DWR/WQ Permitting
1617 Mail Service Center
Raleigh NC 27699-1617 RECEIVED/DENRIDWR
NOV 01 2018
Subject: Priority Pollutant Analysis
Permit#NC0039578 Water Resources
TWSA Plant#1 Permitting Section
Jackson County
Dear Mr. Coco,
Here are the most recent PPA analysis as requested.
Please let me know if there is anything further I can do to help with your review.
Sincerely,
tan Bryson
Wastewater Plant Operations Superintendent
Tuckaseigee Water and Sewer Authority
xc: Mr Dan Harbaugh,Executive Director, TWSA
This institution is an equal opportunity provider and employer.

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®' . Pace Analytical Services,Inc.
a 2225 Riverside Dr
'aceAnalytical Asheville,NC 28804
ww✓pacelabs corn [phone]
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November 19, 2014
Mr. Stan Bryson
Tuckaseigee Water&Sewer Co.
1246 West Main Street
Sylva, NC 28779
RE: Project: TWSA PPA 11/4
Pace Project No.: 92224008
Dear Mr. Bryson:
Enclosed are the analytical results for sample(s) received by the laboratory on November 04, 2014.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
i Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
4_-_ 2 ,
Chris Derouen
[e-mail]
Project Manager
Enclosures
•
.2 `,Jc REPORT OF LABORATORY ANALYSIS
'k7n'N1�," This report shall not be reproduced,except in full,
.._,1_,--BOwithout the written consent of Pace Analytical Services,Inc. Page 1 of 33
1

C07 Pace Analytical Services,Inc.
(__ 2225 Riverside Dr
�FaceAnalytical® Asheville,NC 28804
wwwpacelabs com [phone]
CERTIFICATIONS
Project: TWSA PPA 11/4
Pace Project No.: 92224008
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 West Virginia Certification#:357
North Carolina Wastewater Certification#.12 VirginiaNELAP Certification#:460221
South Carolina Certification#:99006001
Asheville Certification IDs
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 West Virginia Certification#:356
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
(
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 2 of 33

r Pace Analytical Services,Inc.
Dr.
' _ f aceAnalytical® Asheville,2225 RiversideNC28804
/ NC
(/ wwwpacelabs.com
[phone]
ANALYTICAL RESULTS
Project: TWSA PPA 11/4
Pace Project No.: 92224008
Sample: TWSA#1 EFF Lab ID: 92224008001 Collected: 11/04/14 08.00 Received: 11/04/14 11:16 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664B
Oil and Grease ND mg/L 5.0 1 11/06/14 07:42
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ug/L 5.0 1 11/04/14 19:30 11/06/14 08:54 7440-36-0
Arsenic ND ug/L 10.0 1 11/04/14 19:30 11/06/14 08:54 7440-38-2
Beryllium ND ug/L 1.0 1 11/04/1419:30 11/06/14 08:54 7440-41-7
Cadmium ND ug/L 1.0 1 11/04/14 19:30 11/06/14 08:54 7440-43-9
Calcium 10000 ug/1_ 100 1 11/04/14 19:30 11/06/14 08:54 7440-70-2
Chromium ND ug/L 5.0 1 11/04/14 19:30 11/06/14 08:54 7440-47-3
Copper ND ug/L 5.0 1 11/04/14 19:30 11/06/14 08:54 7440-50-8
Lead ND ug/L 5.0 1 11/04/14 19:30 11/06/1415:06 7439-92-1
Magnesium 2220 ug/L 100 1 11/04/1419:30 11/06/14 08:54 7439-95-4
Nickel ND ug/L 5.0 1 11/04/14 19:30 11/06/14 08:54 7440-02-0
Selenium ND ug/L 10.0 1 11/04/14 19:30 11/06/14 08:54 7782-49-2
Silver ND ug/L 5.0 1 11/04/14 19:30 11/06/14 08:54 7440-22-4
Thallium ND ug/L 10.0 1 11/04/14 19:30 11/06/14 08:54 7440-28-0
Hardness,Total(SM 2340B) 34200 ug/L 662 1 11/04/14 19:30 11/06/14 08:54
Zinc 116 ug/L 10.0 1 11/04/14 19:30 11/06/14 08:54 7440-66-6
E-- 1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method.EPA 1631E
Mercury 2.20 ng/L 0.50 1 11/04/1415.00 11/05/14 13:41 7439-97-6
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Acenaphthene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 83-32-9
Acenaphthylene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 208-96-8
Anthracene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 120-12-7
Benzidine ND ug/L 50.0 1 11/07/14 09.53 11/10/14 01:51 92-87-5
Benzo(a)anthracene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 11/07/14 09.53 11/10/14 01:51 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 101-55-3
Butylbenzylphthalate ND ug/L 5.0 -1 11/07/14 09:53 11/10/14 01:51 85-68-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 11/07/14 09:53 11/10/14 01:51 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 111-44-4
bis(2-Chloroisopropyl)ether ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 108-60-1
2-Chloronaphthalene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 91-58-7
2-Chlorophenol ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 95-57-8
4-Chlorophenyiphenyl ether ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 7005-72-3
Chrysene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 53-70-3
1,2-Dichlorobenzene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 95-50-1
1,3-Dichlorobenzene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 541-73-1
1,4-Dichlorobenzene ND ugh 5.0 1 11/07/14 09:53 11/10/14 01:51 106-46-7
3,3'-Dichlorobenzidine ND ug/L 25.0 1 11/07/14 09:53 11/10/14 01:51 91-94-1 F
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/19/2014 10:58 AM without the written consent of Pace Analytical Services,Inc.. Page 4 of 33
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(� i Pace Analytical Services,Inc.
-PaceAnalytical2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs corn
[phone]
f ANALYTICAL RESULTS
Project: TWSA PPA 11/4
Pace Project No.. 92224008
Sample: TWSA#1 EFF Lab ID: 92224008001 Collected. 11/04/14 08.00 Received" 11/04/14 11:16 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
2,4-Dichlorophenol ND ug/L 5.0 1 11/07/14 09.53 11/10/14 01:51 120-83-2
Diethylphthalate ND ug/L 5 0 1 11/07/14 09:53 11/10/14 01.51 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 11/07/14 09 53 11/10/14 01:51 105-67-9
Dimethylphthalate ND ug/L 5.0 1 11/07/14 0953 11/10/14 01:51 131-11-3
Di-n-butylphthalate ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20 0 1 11/07/14 09:53 11/10/14 01:51 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 11/07/14 09:53 11/10/14 01:51 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 11/07/14 09.53 11/10/14 01:51 121-14-2
2,6-Dinitrotoluene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 117-84-0
1,2-Diphenylhydrazine ND ug/L 5 0 1 11/07/14 09.53 11/10/14 01:51 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5 0 1 11/07/14 09.53 11/10/14 01:51 117-81-7
Fluoranthene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 206-44-0
Fluorene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 86-73-7
Hexachloro-1,3-butadiene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 87-68-3
Hexachlorobenzene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 118-74-1
Hexachlorocydopentadiene ND ug/L 10.0 1 11/07/14 09:53 11/10/14 01.51 77-47-4
Hexachloroethane ND ug/L 5.0 1 11/07/14 09.53 11/10/14 01:51 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 193-39-5
(. Isophorone ND ug/L 10.0 1 11/07/14 09.53 11/10/14 01.51 78-59-1
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 11/07/14 09:53 11/10/14 01:51
Naphthalene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 91-20-3
Nitrobenzene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01.51 98-95-3
2-Nitrophenol ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 88-75-5
4-Nitrophenol ND ug/L 50.0 1 11/07/14 09:53 11/10/14 01.51 100-02-7
N-Nitrosodimethylamine ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 11/07/14 09.53 11/10/14 01:51 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 11/07/14 09.53 11/10/14 01:51 86-30-6
Pentachlorophenol ND ug/L 10.0 1 11/07/14 09:53 11/10/14 01:51 87-86-5
Phenanthrene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 85-01-8
Phenol ND ug/L 5 0 1 11/07/14 09-53 11/10/14 01:51 108-95-2
Pyrene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 129-00-0
1,2,4-Trichlorobenzene ND ug/L 5.0 1 11/07/14 09:53 11/10/14 01:51 120-82-1
2,4,6-Trichlorophenol ND ug/L 10.0 1 11/07/14 09-53 11/10/14 01:51 88-06-2
Surrogates
Nitrobenzene-d5(S) 51 % 10-120 1 11/07/14 09:53 11/10/14 01.51 4165-60-0
2-Fluorobiphenyl(S) 52 % 15-120 1 11/07/14 09:53 11/10/14 01:51 321-60-8
Terphenyl-d14(S) 88 % 11-131 1 11/07/14 09:53 11/10/14 01.51 1718-51-0
Phenol-d6(S) 19 % 10-120 1 11/07/14 09:53 11/10/14 01.51 13127-88-3
2-Fluorophenol(S) 26 % 10-120 1 11/07/14 09:53 11/10/14 01:51 367-12-4
2,4,6-Tribromophenol(S) 64 % 10-137 1 11/07/14 09:53 11/10/14 01.51 118-79-6
624 Volatile Organics Analytical Method:EPA 624
Acrolein ND ug/L 5.0 1 11/09/14 00.25 107-02-8
Acrylonitrile ND ug/L 50.0 1 11/09/14 00:25 107-13-1
Benzene ND ug/L 2.0 1 11/09/14 00:25 71-43-2
Bromodichloromethane ND ug/L 2.0 1 11/09/14 00 25 75-27-4 F
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/19/2014 10:58 AM without the wntten consent of Pace Analytical Services,Inc. Page 5 of 33
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f
® Pace Analytical Services,Inc.
0 2225 Riverside Dr
race Analytical Asheville,NC 28804
7 wwwpacelabs corn [phone]
ANALYTICAL RESULTS
Project: TWSA PPA 11/4
Pace Project No.: 92224008
Sample: TWSA#1 EFF Lab ID: 92224008001 Collected: 11/04/14 08:00 Received: 11/04/14 11:16 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
624 Volatile Organics Analytical Method:EPA 624
Bromoform ND ug/L 2.0 1 11/09/14 00.25 75-25-2
Bromomethane ND ug/L 2.0 1 11/09/14 00.25 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 11/09/14 00:25 56-23-5
Chlorobenzene ND ug/L 2.0 1 11/09/14 00 25 108-90-7
Chloroethane ND ug/L 2.0 1 11/09/14 00:25 75-00-3
2-Chloroethylvinyl ether ND ug/L 5 0 1 11/09/14 00:25 110-75-8
Chloroform ND ug/L 2.0 1 11/09/14 00:25 67-66-3
Chloromethane ND ug/L 2.0 1 11/09/14 00-25 74-87-3
Dibromochloromethane ND ug/L 2.0 1 - 11/09/14 00:25 124-48-1
1,1-Dichloroethane ND ug/L 2.0 1 11/09/14 00:25 75-34-3
1,2-Dichioroethane ND ug/L 2.0 1 11/09/1400.25 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 11/09/14 00:25 75-35-4
trans-1,2-Dichloroethene ND ug/L 2.0 1 11/09/14 00:25 156-60-5
1,2-Dichloropropane ND ug/L 2.0 1 11/09/14 00.25 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 11/09/14 00:25 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 11/09/14 00:25 10061-02-6
Ethylbenzene ND ug/L 2.0 1 11/09/14 00:25 100-41-4
Methylene Chloride ND ug/L 2.0 1 11/09/14 00:25 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 11/09/14 00:25 79-34-5
," Tetrachloroethene ND ug/L 2.0 1 11/09/14 00:25 127-18-4
k - Toluene ND ug/L 2.0 1 11/09/14 00:25 108-88-3
1,1,1-Tnchloroethane ND ug/L 2.0 1 11/09/14 0025 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 11/09/14 00:25 79-00-5
Trichloroethene ND ug/L 2.0 1 11/09/14 00:25 79-01-6
Vinyl chloride ND ug/L 2.0 1 11/09/14 00:25 75-01-4
Surrogates
4-Bromofluorobenzene(S) 104 % 70-130 1 11/09/14 00:25 460-00-4
Toluene-d8(S) 98 % 70-130 1 11/09/14 00:25 2037-26-5
1,2-Dichloroethane-d4(S) 91 % 70-130 1 11/09/14 0025 17060-07-0
1010 Flashpoint,Closed Cup Analytical Method:EPA 1010
Flashpoint >200 deg F 70.0 1 11/12/14 14:15
2540C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 236 mg/L 25 0 1 11/05/14 07:02
9040 pH Analytical Method:EPA 9040
pH 6.9 Std.Units 0.10 1 11/05/14 12:36 H6
350.1 Ammonia Analytical Method-EPA 350.1
Nitrogen,Ammonia 0.11 mg/L 0.10 1 11/14/14 03:07 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method.EPA 351.2
Nitrogen,Kjeldahl,Total 0.97 mg/L 0.50 1 11/16/14 12:13 7727-37-9
REPORT OF LABORATORY ANALYSIS
(
This report shall not be reproduced,except in full,
Date:11/19/2014 10:58 AM without the written consent of Pace Analytical Services,Inc. Page 6 of 33

Pace Analytical Services,Inc.
®� ® 2225 Riverside Dr
'aceAnalytical Asheville,NC 28804
/ www pacelabs.com [phone]
ANALYTICAL RESULTS
Project: TWSA PPA 11/4
Pace Project No.: 92224008
Sample: TWSA#1 EFF Lab ID: 92224008001 Collected. 11/04/14 08:00 Received: 11/04/14 11:16 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
353.2 Nitrogen,NO2/NO3 pres. Analytical Method:EPA 353.2
Nitrogen,NO2 plus NO3 2.0 mg/L 0.020 1 11/13/14 19:36
365.1 Phosphorus,Total Analytical Method:EPA 365.1
Phosphorus 1.2 mg/L 0.050 1 11/17/14 11:01 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA 420.4
Phenol 0.010 mg/L 0.010 1 11/18/14 19:12 108-95-2
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide ND mg/L 0.0050 1 11/15/14 15:14 57-12-5
Sample: TWSA#1 EFF FIELD BLK Lab ID: 92224008002 Collected: 11/04/14 08:00 Received: 11/04/14 11:16 Matrix:Water
LLHG
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Niercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury ND ng/L 0.50 1 11/04/1415.00 11/05/14 14:06 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/19/2014 10.58 AM without the wntten consent of Pace Analytical Services,Inc. Page 7 of 33
_ t

Pace Analytical Services,Inc./iPiceAnaIyticaI®
2225 Riverside Dr
Asheville,NC 28804
wwipacelabs corn
[phone]
I
December 29, 2015
Mr. Stan Bryson
Tuckaseigee Water& Sewer Co.
1246 West Main Street
Sylva, NC 28779
RE: Project: Priority Pollutant Scan 12/15
Pace Project No.: 92279826
Dear Mr. Bryson:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely, -
I
Chris Derouen
[e-mail]
Project Manager
Enclosures ,
C
f
�e PCCRfO'%
_, .-:N = 0 REPORT OF LABORATORY ANALYSIS
,,--,TNI
m This report shall not be reproduced,except in full,
a a�,,
l48011-A16\
'�Q without the wntten consent of Pace Analytical Services,Inc Page 1 of 35
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Pace Analytical Services,Inc.
• 7ceAnaIytfcaI® 2225 Riverside Dr.
Asheville,NC 28804
wwwpacelabs com [phone]
I
t-
CERTIFICATIONS
Project Priority Pollutant Scan 12/15
Pace Project No: 92279826
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#.37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 West Virginia Certification#:357
North Carolina Wastewater Certification#:12 VirginiaNELAP Certification#.460221
South Carolina Certification#.99006001
Asheville Certification IDs
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification# 40
Florida/NELAP Certification#•E87648 South Carolina Certification#:99030001
Massachusetts Certification#.M-NC030 West Virginia Certification# 356
North Carolina Dnnking Water Certification#:37712 VirginiaNELAP Certification# 460222
REPORT OF LABORATORY ANALYSIS
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. Pace Analytical Services,Inc.
2225 Riverside Dr
aceAnalytical Asheville,NC 28804
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�T—
SAMPLE ANALYTE COUNT
Project* Priority Pollutant Scan 12/15
Pace Project No.. 92279826
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92279826001 TWSA#1 EFF EPA 16646 JMS 1 PASI-C
EPA 200 7 CDF,JMW 15 PASI-A
EPA 1631E HVK 1 PASI-A
EPA 625 RES 64 PASI-C
EPA 624 GAW 32 PASI-C
EPA 1010 TEP 1 PASI-A
SM 2540C SAM 1 PASI-A
EPA 9040 MLS 1 PASI-A
EPA 350.1 SER 1 PASI-A
EPA351.2 AES2 1 PASI-A
EPA 353.2 DMN 1 PASI-A
EPA 365.1 SER 1 PASI-A
EPA 420 4 DMN 1 PASI-A
SM 4500-CN-E AES2 1 PASI-A
92279826002 TWSA#1 EFF Blank EPA 1631E HVK 1 PASI-A
_ I
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e
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services,Inc.
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Pace Analytical Services,Inc.
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aceAnalytical Asheville,2225
e,NC 2e 0
le,NC 28804
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1
ANALYTICAL RESULTS
Project- Priority Pollutant Scan 12/15
Pace Project No.: 92279826
Sample: TWSA#1 EFF Lab ID: 92279826001 Collected 12/15/15 11.30 Received. 12/15/15 13.52 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method-EPA 1664B
Oil and Grease ND mg/L 5 0 1 12/24/15 06:00
200.7 MET ICP Analytical Method-EPA 200 7 Preparation Method-EPA 200.7
Antimony ND ug/L 5.0 1 12/16/15 17.30 12/18/15 14 07 7440-36-0
Arsenic ND ug/L 10.0 1 12/16/15 17-30 12/18/15 14 07 7440-38-2
Beryllium ND ug/L 10 1 12/16/15 17:30 12/18/15 14:07 7440-41-7
Cadmium ND ug/L 1 0 1 12/16/15 17 30 12/18/15 14:07 7440-43-9
Calcium 10500 ug/L 100 1 12/16/15 17.30 12/18/15 14 07 7440-70-2
Chromium ND ug/L 5 0 1 12/16/15 17.30 12/18/15 14:07 7440-47-3
Copper ND ug/L 5.0 1 12/16/15 17:30 12/18/15 14:07 7440-50-8
Lead ND ug/L 5 0 1 12/16/15 17:30 12/18/15 14:07 7439-92-1
Magnesium 2520 ug/L 100 1 12/16/15 17:30 12/18/15 14 07 7439-95-4
Nickel ND ug/L 5.0 1 12/16/15 17:30 12/21/15 11 30 7440-02-0
Selenium ND ug/L 10.0 1 12/16/1517.30 12/18/15 14:07 7782-49-2
Silver ND ug/L 5.0 1 12/16/151730 12/18/15 14:07 7440-22-4
Thallium ND ug/L 10.0 1 12/16/15 17:30 12/21/15 11:30 7440-28-0
Hardness,Total(SM 2340B) 36600 ug/L 662 1 12/16/15 17:30 12/18/15 14.07
Zinc 79.3 ug/L 10 0 1 12/16/15 17:30 12/18/15 14.07 7440-66-6
f _631E Mercury,Low Level Analytical Method.EPA 1631E Preparation Method:EPA 1631E
Mercury 1.85 ng/L 0 50 1 12/18/15 13:00 12/18/15 17.00 7439-97-6
625 MSSV Analytical Method:EPA 625 Preparation Method.EPA 625
Acenaphthene ND ug/L 5.0 1 12/18/15 10 30 12/22/15 01:13 83-32-9
Acenaphthylene ND ug/L 5 0 1 12/18/15 10-30 12/22/15 01:13 208-96-8
Anthracene ND ug/L 5 0 1 12/18/15 10:30 12/22/15 01:13 120-12-7
Benzidine ND ug/L 50.0 1 12/18/15 10:30 12/22/15 01 13 92-87-5 L2
Benzo(a)anthracene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01-13 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01.13 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 12/18/15 10 30 12/22/15 01:13 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01.13 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01.13 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 12/18/15 10-30 12/22/15 01:13 101-55-3
Butylbenzylphthalate ND ug/L 5 0 1 12/18/15 10.30 12/22/15 01.13 85-68-7
4-Chloro-3-methylphenol ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01-13 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 12/18/15 10.30 12/22/15 01:13 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01:13 111-44-4
bis(2-Chloroisopropyl)ether ND ug/L 5 0 1 12/18/15 10:30 12/22/15 01.13 108-60-1
2-Chloronaphthalene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01:13 91-58-7
2-Chlorophenol ND ug/L 5.0 1 12/18/15 10 30 12/22/15 01:13 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01:13 7005-72-3
Chrysene ND _ ug/L 5.0 1 12/18/15 10:30 12/22/15 01 13 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01.13 53-70-3
1,2-Dichlorobenzene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01:13 95-50-1 E
1,3-Dichlorobenzene ND ug/L 5 0 1 12/18/15 10:30 12/22/15 01.13 541-73-1
1,4=Dichlorobenzene ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01:13 106-46-7
i
REPORT OF LABORATORY ANALYSIS
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4(2 Pace Analytical Services,Inc.
® 2225 Riverside Dr
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f-
ANALYTICAL RESULTS
Project: Priority Pollutant Scan 12/15
Pace Project No.: 92279826
Sample: TWNSA#1 EFF Lab ID: 92279826001 Collected: 12/15/15 11.30 Received: 12/15/15 13:52 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
625 MSSV Analytical Method.EPA 625 Preparation Method.EPA 625
3,3'-Dichlorobenzidine ND ug/L 25.0 1 12/18/15 10 30 12/22/15 01 13 91-94-1
2,4-Dichlorophenol ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01.13 120-83-2
Diethylphthalate ND ug/L 5 0 1 12/18/15 10 30 12/22/15 0113 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 12/18/15 10'30 12/22/15 01:13 105-67-9
Dimethylphthalate ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01:13 131-11-3
Di-n-butylphthalate ND ug/L 5 0 1 12/18/15 10:30 12/22/15 01:13 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20 0 1 12/18/15 10.30 12/22/15 01.13 534-52-1
2,4-Dinitrophenol ND ug/L 50 0 1 12/18/15 10 30 12/22/15 01:13 51-28-5
2,4-Dinitrotoluene ND - ug/L 5.0 1 12/18/15 10:30 12/22/15 01 13 121-14-2
2,6-Dinitrotoluene ND ug/L 5 0 1 12/18/15 10-30 12/22/15 01.13 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 12/18/15 1030 12/22/15 01:13 117-84-0
1,2-Diphenyihydrazine ND ug/L 5.0 1 12/18/15 10:30 12/22/15 0113 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 12/18/15 10:30 12/22/15 0113 117-81-7
Fluoranthene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01:13 206-44-0
Fluorene ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01:13 86-73-7
Hexachloro-1,3-butadiene ND ug/L 5 0 1 12/18/15 10 30 12/22/15 01:13 87-68-3
Hexachlorobenzene ND ug/L 5 0 1 12/18/15 10-30 12/22/15 0113 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 12/18/15 10 30 12/22/15 01:13 77-47-4
'exachloroethane ND ug/L 5 0 1 12/18/15 10:30 12/22/15 0113 67-72-1
indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01:13 193-39-5
Isophorone ND ug/L 10 0 1 12/18/15 10:30 12/22/15 01.13 78-59-1
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 12/18/15 10:30 12/22/15 01:13
Naphthalene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01.13 91-20-3
Nitrobenzene ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01.13 98-95-3
2-Nitrophenol ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01.13 88-75-5
4-Nitrophenol ND ug/L 50.0 1 12/18/15 10 30 12/22/15 01 13 100-02-7
N-Nitrosodimethylamine ND ug/L 5 0 1 12/18/15 10:30 12/22/15 01.13 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01:13 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 12/18/15 10:30 12/22/15 01:13 86-30-6
Pentachlorophenol ND ug/L 10.0 1 12/18/15 10:30 12/22/15 01:13 87-86-5
Phenanthrene ND ug/L 5.0 1 12/18/15 10.30 12/22/15 01:13 85-01-8
Phenol ND ug/L 5 0 1 12/18/15 10.30 12/22/15 01:13 108-95-2
Pyrene ND ug/L 5.0 1 12/18/15 10:30 12/22/15 01:13 129-00-0
1,2,4-Trichlorobenzene ND ug/L 5 0 1 12/18/15 10:30 12/22/15 01.13 120-82-1
2,4,6-Trichlorophenol ND ug/L 10.0 1 12/18/15 10 30 12/22/15 01:13 88-06-2
Surrogates
Nitrobenzene-d5(S) 49 % 10-120 1 12/18/15 10:30 12/22/15 01:13 4165-60-0
2-Fluorobiphenyl(S) 42 % 15-120 1 12/18/15 10:30 12/22/15 01:13 321-60-8
Terphenyl-d14(S) 50 % 11-131 1 12/18/15 10:30 12/22/15 01:13 1718-51-0
Phenol-d6(S) 18 % 10-120 1 12/18/15 10.30 12/22/15 0113 13127-88-3
2-Fluorophenol(S) 28 % 10-120 1 12/18/15 10:30 12/22/15 01.13 367-12-4
2,4,6-Tribromophenol(S) 51 % 10-137 1 12/18/15 10:30 12/22/15 01.13 118-79-6
624 Volatile Organics Analytical Method:EPA 624
L
Acrolein ND ug/L 5.0 1 12/29/15 03:38 107-02-8
Acrylonitnle ND ug/L 50 0 1 12/29/15 03:38 107-13-1
Benzene ND ug/L 2 0 1 12/29/15 03.38 71-43-2
REPORT OF LABORATORY ANALYSIS
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40.= 2) Pace Analytical Services,Inc.
. P ceAnalytical® 2225 Riverside Dr
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wvnvpacelabs com [phone]
ANALYTICAL RESULTS
Project Priority Pollutant Scan 12/15
Pace Project No.: 92279826
Sample: TWSA#1 EFF Lab ID: 92279826001 Collected: 12/15/15 11:30 Received' 12/15/15 13:52 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method.EPA 624
Bromodichloromethane 2.4 ug/L 2 0 1 12/29/15 03:38 75-27-4
Bromoform ND ug/L 2.0 1 12/29/15 03:38 75-25-2
Bromomethane ND ug/L 2.0 1 12/29/15 03:38 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 12/29/15 03:38 56-23-5
Chlorobenzene ND ug/L 2.0 1 12/29/15 03.38 108-90-7
Chloroethane ND ug/L 2.0 1 12/29/15 03:38 75-00-3
2-Chloroethylvinyl ether ND ug/L 5 0 1 12/29/15 03:38 110-75-8 c2
Chloroform 9.7 ug/L 2.0 1 12/29/15 03:38 67-66-3
Chloromethane ND ug/L 2.0 1 12/29/15 03.38 74-87-3
Dibromochloromethane ND ug/L 2.0 1 12/29/15 03:38 124-48-1
1,1-Dichloroethane ND ug/L 2.0 1 12/29/15 03:38 75-34-3
1,2-Dichloroethane ND ug/L 2 0 1 12/29/15 03.38 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 12/29/15 03.38 75-35-4
trans-1,2-Dichloroethene ND ug/L 2 0 1 12/29/15 03.38 156-60-5
1,2-Dichloropropane ND ug/L 2 0 1 12/29/15 03:38 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 12/29/15 03:38 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 12/29/15 03.38 10061-02-6
Ethylbenzene ND ug/L 2 0 1 12/29/15 03:38 100-41-4
lethylene Chloride ND ug/L 2.0 1 12/29/15 03.38 75-09-2
- i,1,2,2-Tetrachloroethane ND ug/L 2 0 1 12/29/15 03.38 79-34-5
Tetrachloroethene ND ug/L 2.0 1 12/29/15 03:38 127-18-4
Toluene ND ug/L 2.0 1 12/29/15 03:38 108-88-3
1,1,1-Trichloroethane ND ug/L 2.0 1 12/29/15 03:38 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 12/29/15 03.38 79-00-5
Tnchloroethene ND ug/L 2 0 1 12/29/15 0338 79-01-6
Vinyl chlonde ND ug/L 2.0 1 12/29/15 03:38 75-01-4
Surrogates
4-Bromofluorobenzene(S) 104 % 70-130 1 12/29/15 03:38 460-00-4
Toluene-d8(S) 106 % 70-130 1 12/29/15 03:38 2037-26-5
1,2-Dichloroethane-d4(S) 94 % 70-130 1 12/29/15 03.38 17060-07-0
1010 Flashpoint,Closed Cup Analytical Method:EPA 1010
Flashpoint >200 deg F 70 0 1 12/28/15 1310
2540C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 154 mg/L 25 0 1 12/17/15 09 19
9040 pH Analytical Method.EPA 9040
pH 7.2 Std.Units 0.10 1 12/16/15 13:05 H6
350.1 Ammonia Analytical Method-EPA 350.1
Nitrogen,Ammonia ND mg/L 0 10 1 12/18/15 03:55 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method EPA 351.2
Nitrogen,Kjeldahl,Total 0.74 mg/L 0.50 1 12/18/15 12:34 7727-37-9
REPORT OF LABORATORY ANALYSIS
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4's' Pace Analytical Services,Inc.
ac'eArelytical® 2225 Riverside Dr
Asheville,NC 28804
" www pacelabs corn
[phone]
ANALYTICAL RESULTS
Project: Priority Pollutant Scan 12/15
Pace Project No.: 92279826
Sample: TWSA#1 EFF Lab ID: 92279826001 Collected: 12/15/15 11 30 Received. 12/15/15 13.52 Matrix Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
353.2 Nitrogen,NO2/NO3 pres. Analytical Method EPA 353.2
Nitrogen,NO2 plus NO3 2.3 mg/L 0.020 1 12/23/15 14.51
365.1 Phosphorus,Total Analytical Method:EPA 365.1
Phosphorus 0.26 mg/L 0 050 1 12/19/15 05:58 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA 420 4
Phenol ND mg/L 0 010 1 12/17/15 15:36 108-95-2
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide ND mg/L 0 0080 1 12/19/15 13'10 57-12-5
Sample: TVI/SA#1 EFF Blank Lab ID: 92279826002 Collected. 12/15/15 11:30 Received: 12/15/15 13:52 Matrix Water
Parameters Results- Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631 E
`4ercury ND ng/L 0.50 1 12/18/15 13:00 12/18/15 17:54 7439-97-6
r
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,Inc.
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'aeAnalyfrcal Asheville,NC 28804
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[phone]
I
QUALIFIERS t
Project: Priority Pollutant Scan 12/15
Pace Project No.: 92279826
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit
PQL-Practical Quantitation Limit.
RL-Reporting Limit
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
C _ Method 8260
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited Contact your Pace PM for the current list of accredited analytes
TNI-The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services-Asheville
PASI-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
D6 The relative percent difference(RPD)between the sample and sample duplicate exceeded laboratory control limits.
H6 Analysis initiated outside of the 15 minute EPA recommended holding time
LO Analyte recovery in the laboratory control sample(LCS)was outside QC limits.
L2 Analyte recovery in the laboratory control sample(LCS)was below QC limits. Results for this analyte in associated
samples may be biased low.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
R1 RPD value was outside control limits.
c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether.
REPORT OF LABORATORY ANALYSIS
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I Pace Analytical Services,Inc.
Dr
- __ ace Analytical Asheville,Riverside 2e 04
NC 28804
wv,w pacelabs corn
[phone]
August 18, 2016
Mr. Stan Bryson
Tuckaseigee Water& Sewer Co.
1246 West Main Street
Sylva, NC 28779
RE: Project: TWSA PPA 8/2
Pace Project No.: 92307463
Dear Mr. Bryson:
Enclosed are the analytical results for sample(s) received by the laboratory on August 02, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless -
otherwise noted in the body of the report.
r
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this'report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
Project Manager
Enclosures
�` t'�rE `a REPORT OF LABORATORY ANALYSIS
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!9 y without the written consent of Pace Analytical Services,Inc Page 1 of 34
�ORASO

Pace Analytical Services,Inc.
© 2225 Riverside Dr
-aceAnalytical Asheville,NC 28804
wwwpacelabs corn
[phone]
CERTIFICATIONS
Project TWSA PPA 8/2
Pace Project No 92307463
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#.99006001
North Carolina Dnnking Water Certification# 37706 Florida/NELAP Certification t E87627
North Carolina Field Services Certification#•5342 Kentucky UST Certification#:84
North Carolina Wastewater Certification#.12 VirginiaNELAP Certification#.460221
Asheville Certification IDs
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification# 40
Florida/NELAP Certification#.E87648 South Carolina Certification#•99030001
Massachusetts Certification# M-NC030 VirginiaNELAP Certification#.460222
North Carolina Drinking Water Certification#.37712
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,Inc.
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SAMPLE ANALYTE COUNT
Project' TWSA PPA 8/2
Pace Project No.: 92307463
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92307463001 TWSA#1 EFF COMP EPA 1664B JMS 1 PASI-C
EPA200.7 SH1 15 PASI-A
EPA 1631E ANB 1 PAST-A
EPA 625 BPJ 63 PAST-C
EPA 624 GAW 32 PASI-C
SM 2540C CB 1 PAST-A
EPA 9040 ALC 1 PAST-A
EPA 350 1 1993 Rev 2 0 _ AES2 1 PAST-A
EPA 351.2 BRJ 1 PAST-A
EPA 353 2 DMN 1 PAST-A
EPA 365 1 WRC 1 PAST-A
EPA 4204 DMN 1 PAST-A
SM 4500-CN-E AES2 1 PAST-A
92307463002 TWSA#1 EFF COMP LLHG BLK EPA 1631E ANB 1 PAST-A
REPORT OF LABORATORY ANALYSIS
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1
Pace Analytical Services,Inc.
Dr
t-? ce Analytical Asheville,
eiv C 28ide 0
lle,NC 28804
www pacelabs corn
[phone]
ANALYTICAL RESULTS
Project. TWSA PPA 8/2
Pace Project No• 92307463
Sample: TWSA#1 EFF COMP Lab ID: 92307463001 Collected. 08/02/16 08.00 Received: 08/02/16 13:49 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
HEM,Oil and Grease Analytical Method.EPA 1664B
Oil and Grease ND mg/L 5.0 1 08/12/16 0446
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method.EPA 200.7
Antimony ND ug/L 5 0 1 08/04/16 19 30 08/06/16 01 52 7440-36-0
Arsenic ND ug/L 10 0 1 08/04/16 19 30 08/06/16 01.52 7440-38-2
Beryllium ND ug/L 1.0 1 08/04/16 19 30 08/06/16 01:52 7440-41-7
Cadmium ND ug/L 1 0 1 08/04/16 1930 08/06/16 01.52 7440-43-9
Calcium 10200 ug/L 100 1 08/04/16 19 30 08/06/16 01.52 7440-70-2
Chromium ND ug/L 5.0 1 08/04/16 19 30 08/06/16 01 52 7440-47-3
Copper ND ug/L 5.0 1 08/04/16 19 30 08/06/16 01.52 7440-50-8
Lead ND ug/L 5.0 1 08/04/16 19.30 08/06/16 01.52 7439-92-1
Magnesium 1900 ug/L 100 1 08/04/16 19.30 08/06/16 01:52 7439-95-4
Nickel ND ug/L 5.0 1 08/04/16 19:30 08/06/16 01 52 7440-02-0
Selenium ND ug/L 10.0 1 08/04/16 19 30 08/06/16 01.52 7782-49-2
Silver ND ug/L 5.0 1 08/04/16 19:30 08/06/16 01.52 7440-22-4
Thallium ND ug/L 10 0 1 08/04/16 19:30 08/06/16 01.52 7440-28-0
Hardness,Total(SM 2340B) 33300 ug/L 662 1 08/04/16 19 30 08/06/16 01:52
Zinc 87.4 ug/L 10 0 1 08/04/16 1930 08/06/16 01:52 7440-66-6
i
1631E Mercury,Low Level Analytical Method EPA 1631E Preparation Method.EPA 1631E
Mercury 2.42 ng/L 0 50 1 08/04/16 08:45 08/05/16 11:32 7439-97-6
625 MSSV Analytical Method EPA 625 Preparation Method:EPA 625
Acenaphthene ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21:29 83-32-9 M1
Acenaphthylene ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21 29 208-96-8
Anthracene ND ug/L 5.0 1 08/08/16 17.00 08/10/16 21 29 120-12-7
Benzidine ND ug/L 50.0 1 08/08/16 17.00 08/10/16 21 29 92-87-5 M1
Benzo(a)anthracene ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21:29 56-55-3
Benzo(a)pyrene ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21 29 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 08/08/16 17:00 08/10/16 2129 205-99-2
Benzo(g,h,i)perylene ND ug/L 5 0 1 08/08/16 1700 08/10/16 21 29 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21.29 207-08-9
4-Bromophenylphenyl ether ND ug/L 5 0 1 08/08/16 17:00 08/10/16 21.29 101-55-3 M1
Butylbenzylphthalate ND ug/L 5 0 1 08/08/16 17 00 08/10/16 21:29 85-68-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 08/08/16 17:00 08/10/16 21.29 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 08/08/16 17.00 08/10/16 21.29 111-44-4
2-Chloronaphthalene ND ug/L 5.0 1 08/08/16 17:00 08/10/16 21.29 91-58-7 M1
2-Chlorophenol ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21:29 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21.29 7005-72-3
Chrysene ND ug/L 5.0 1 08/08/16 17.00 08/10/16 21:29 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21:29 53-70-3
1,2-Dichlorobenzene ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21.29 95-50-1 M1
1,3-Dichlorobenzene ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21:29 541-73-1
1,4-Dichlorobenzene ND ug/L 5.0 1 08/08/16 17.00 08/10/16 21-29 106-46-7 M1
3,3'-Dichlorobenzidine ND ug/L 25.0 1 08/08/16 17.00 08/10/16 21:29 91-94-1
2,4-Dichlorophenol ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21:29 120-83-2
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project TWSA PPA 8/2
Pace Project No.. 92307463
Sample: TWSA#1 EFF COMP Lab ID: 92307463001 Collected: 08/02/16 08:00 Received: 08/02/16 13-49 Matrix Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
625 MSSV Analytical Method EPA 625 Preparation Method.EPA 625
Diethylphthalate ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21 29 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 08/08/16 17.00 08/10/16 21 29 105-67-9
Dimethylphthalate ND ug/L 5 0 1 08/08/16 17:00 08/10/16 21:29 131-11-3
Di-n-butylphthalate ND ug/L 5 0 1 08/08/16 17:00 08/10/16 21 29 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 08/08/16 1700 08/10/16 21 29 534-52-1
2,4-Dinitrophenol ND ug/L 50 0 1 08/08/16 17 00 08/10/16 21:29 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 08/08/16 17.00 08/10/16 21 29 121-14-2
2,6-Dinitrotoluene ND ug/L 5 0 1 08/08/16 17:00 08/10/16 21.29 606-20-2 M1
Di-n-octylphthalate ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21.29 117-84-0
1,2-Diphenylhydrazine ND ug/L 5 0 1 08/08/16 17 00 08/10/16 21.29 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 08/08/16 17:00 08/10/1621.29 117-81-7
Fluoranthene ND ug/L 5.0 1 08/08/16 17:00 08/10/16 21.29 206-44-0
Fluorene ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21.29 86-73-7 M1
Hexachloro-1,3-butadiene ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21.29 87-68-3
Hexachlorobenzene ND ug/L 5 0 1 08/08/16 17 00 08/10/16 21:29 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 08/08/16 17.00 08/10/16 21.29 77-47-4 M1
Hexachloroethane ND ug/L 5 0 1 08/08/16 17:00 08/10/16 21:29 67-72-1 M1
Indeno(1,2,3-cd)pyrene ND ug/L 5 0 1 08/08/16 17 00 08/10/16 21:29 193-39-5
( sophorone ND ug/L 10.0 1 08/08/16 17:00 08/10/16 21 29 78-59-1
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 08/08/16 17.00 08/10/16 21-29
Naphthalene ND ug/L 5 0 1 08/08/16 17:00 08/10/16 21:29 91-20-3
Nitrobenzene ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21 29 98-95-3 M1
2-Nitrophenol ND ug/L 5 0 1 08/08/16 17 00 08/10/16 21.29 88-75-5
4-Nitrophenol ND ug/L " 50.0 1 08/08/16 17:00 08/10/16 21.29 100-02-7
N-Nitrosodimethylamine ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21 29 62-75-9 M1
N-Nitroso-di-n-propylamine ND ug/L 5 0 1 08/08/16 17 00 08/10/16 21.29 621-64-7
N-Nitrosodiphenylamine ND ug/L 10 0 1 08/08/16 17:00 08/10/16 21.29 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 08/08/16 17.00 08/10/16 21.29 108-60-1 M1
Pentachlorophenol ND ug/L -10 0 1 08/08/16 17 00 08/10/16 21.29 87-86-5
Phenanthrene ND ug/L 5.0 1 08/08/16 17 00 08/10/16 21.29 85-01-8
Phenol ND ug/L 5 0 1 08/08/16 17.00 08/10/16 21 29
Pyrene ND ug/L 5 0 1 08/08/16 17 00 08/10/16 21.29 129-00-0
1,2,4-Trichlorobenzene ND ug/L 5.0 1 08/08/16 17.00 08/10/16 21.29 120-82-1 M1
2,4,6-Trichlorophenol ND ug/L 10 0 1 08/08/16 17.00 08/10/16 21.29 88-06-2
Surrogates
Nitrobenzene-d5(S) 19 % 10-120 1 08/08/16 17.00 08/10/16 21.29 4165-60-0
2-Fluorobiphenyl(S) 19 % 15-120 1 08/08/16 17.00 08/10/16 21:29 321-60-8
Terphenyl-d14(S) 39 % 11-131 1 08/08/16 1700 08/10/16 21 29 1718-51-0
Phenol-d6(S) 8 % 10-120 1 08/08/16 17.00 08/10/16 21 29 13127-88-3 SO
2-Fluorophenol(S) 12 % 10-120 1 08/08/16 17 00 08/10/16 21.29 367-12-4
2,4,6-Tribromophenol(S) 27 % 10-137 1 08/08/16 17.00 08/10/16 21.29 118-79-6
624 Volatile Organics Analytical Method'EPA 624
Acrolein ND ug/L 5 0 1 08/08/16 22:25 107-02-8
Acrylonitrile ND ug/L 50.0 1 08/08/16 22:25 107-13-1
Benzene ND ug/L 2.0 1 08/08/16 22.25 71-43-2
Bromodichloromethane 3.3 ug/L 2 0 1 08/08/16 22.25 75-27-4
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project TWSA PPA 8/2
Pace Project No.: 92307463
Sample: TWSA#1 EFF COMP Lab ID: 92307463001 Collected: 08/02/16 08.00 Received: 08/02/16 13 49 Matrix.Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method EPA 624
Bromoform ND ug/L 2.0 1 08/08/16 22 25 75-25-2
Bromomethane ND ug/L 2.0 1 08/08/16 22.25 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 08/08/16 22.25 56-23-5
Chlorobenzene ND ug/L 2 0 1 08/08/16 2225 108-90-7
Chloroethane ND ug/L 2.0 1 08/08/16 22:25 75-00-3
2-Chloroethylvinyl ether ND ug/L 5 0 1 08/08/16 22 25 110-75-8 M1,c2
Chloroform 8.1 ug/L 2.0 1 08/08/16 22.25 67-66-3
Chloromethane ND ug/L 2 0 1 08/08/16 22.25 74-87-3
Dibromochloromethane ND ug/L 2.0 1 08/08/16 22:25 124-48-1
1,1-Dichloroethane ND ug/L 2 0 1 08/08/16 22.25 75-34-3
1,2-Dichloroethane ND ug/L 2 0 1 08/08/16 22:25 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 08/08/16 22 25 75-35-4
trans-1,2-Dichloroethene ND ug/L 2.0 1 08/08/16 22.25 156-60-5
1,2-Dichloropropane ND ug/L 2 0 1 08/08/16 22 25 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 08/08/16 2225 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 08/08/162225 10061-02-6
Ethylbenzene ND ug/L 2 0 1 08/08/16 22 25 100-41-4
Methylene Chlonde ND ug/L 2.0 1 08/08/16 22.25 75-09-2
-1,1,2,2-Tetrachloroethane ND ug/L 2 0 1 08/08/16 22 25 79-34-5
-- Tetrachloroethene ND ug/L 2 0 1 08/08/16 2225 127-18-4
Toluene ND ug/L 2 0 1 08/08/16 22:25 108-88-3
1,1,1-Trichloroethane ND ug/L 2.0 1 08/08/1622.25 71-55-6
1,1,2-Trichloroethane ND ug/L 2 0 1 08/08/16 22:25 79-00-5
Trichloroethene ND ug/L 2.0 1 08/08/16 22 25 79-01-6
Vinyl chloride ND ug/L 2.0 1 08/08/16 22:25 75-01-4
Surrogates
4-Bromofluorobenzene(S) 100 % 70-130 1 08/08/16 22.25 460-00-4
Toluene-d8(S) 102 % 70-130 1 08/08/16 2225 2037-26-5
1;2-Dichloroethane-d4(S) 94 % 70-130 1 08/08/16 22 25 17060-07-0
2540C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 192 mg/L 25.0 1 08/09/16 12 28
9040 pH Analytical Method EPA 9040
pH 7.4 Std.Units 0 10 1 08/08/16 15.59 H6
350.1 Ammonia Analytical Method.EPA 350.1 1993 Rev 2 0
Nitrogen,Ammonia ND mg/L 0.10 1 08/10/16 0831 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method EPA 351 2
Nitrogen,Kjeldahl,Total 0.83 mg/L 0 50 1 08/12/16 01.50 7727-37-9
353.2 Nitrogen,NO2/NO3 pres. Analytical Method:EPA 353 2
Nitrogen,NO2 plus NO3 4.1 mg/L 0.020 1 08/12/16 15 59
REPORT OF LABORATORY ANALYSIS
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- ANALYTICAL RESULTS
Project' TWSA PPA 8/2
Pace Project No.: 92307463
Sample: TWSA#1 EFF COMP Lab ID: 92307463001 Collected: 08/02/16 08.00 Received' 08/02/16 13:49 Matrix. Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
365.1 Phosphorus,Total Analytical Method EPA 365 1
Phosphorus 0.97 mg/L 0 050 1 08/18/16 02:06 7723-14-0
420.4 Phenolics,Total Analytical Method EPA 420.4
Phenol 0.016 mg/L 0 010 1 08/09/16 10:31
4500CNE Cyanide,Total Analytical Method'SM 4500-CN-E
Cyanide ND mg/L 0.0080 1 08/05/1611.29 57-12-5
Sample: TWSA#1 EFF COMP Lab ID: 92307463002 Collected: 08/02/16 08.00 Received. 08/02/16 13 49 Matrix:Water
LLHG BLK
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method EPA 1631E Preparation Method EPA 1631E
Mercury ND ng/L 0.50 1 08/04/16 08 45 08/05/16 12 02 7439-97-6
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