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NC0024244_Fact Sheet_20181025
Fact Sheet NPDES Permit No. NCO024244 Permit Writer/Email Contact: Gary Perlmutter, gary.perlmutter@ncdenr.gov Date: October 25, 2018 Division/Branch: NC Division of Water Resources/NPDES Compliance and Expedited Permitting Unit Fact Sheet Template: Version 08Sept2016 Permitting Action: ❑ Renewal ® Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2' species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: City of Albemarle / Long Creek WWTP Applicant Address: P.O. Box 190, Albemarle, NC 08002 Facility Address: 1040 Coble Avenue, Albemarle, NC 08001 Permitted Flow: 12 MGD and 16 MGD Facility Type/Waste: MAJOR Municipal; 81 % domestic, 19% industrial' Facility Class: Grade IV Treatment Units: Bar screen, Grit removal, Activated sludge, Secondary clarifiers, Tertiary filters, Chlorination, Dechlorination, Sludge dewatering, Digesters. Pretreatment Program (Y/N) Yes County: Stanly Region Mooresville 'Percentages calculated from 2015 actual industrial and total average daily flows (1.28 and 6.62 MGD, respectively). Permitted industrial flow is 2.0 MGD or 16.7% of total current permitted flow (12 MGD). Briefly describe the proposed permitting action and facility background.• The City ofAlbemarle has applied for NPDES permit renewal, and submitted a renewal application dated April 9, 2014. At the time of application submission, the facility served a population of 17,733 residents and operated a pretreatment Page 1of19 program with 1 Significant Industrial User (SILT). The average industrial flow rate was 1.28 MGD of the 2.0 MGD permitted industrial flow for 2015. This facility has one SIU, and has a full pretreatment program with Long Term Monitoring Program (LTMP). 2. Receiving Waterbody Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 / Long Creek Stream Segment: 13-17-31 Drainage Area (mi2): 64 Summer 7Q 10 (cfs) 1.6 Winter 7Q10 (cfs): 9.5 Average Flow (cfs): 64 IWC (% effluent): 92.08% atl2 MGD and 93.94% atl6 MGD 303(d) listed/parameter: This segment is listed as impaired for Copper on the final 2016 303(d) list. Subject to TMDL/parameter: Statewide Mercury TMDL Subbasin/HUC: 03-07-13 / 0304010504 USGS Topo Quad: F18SW Albemarle 3. Effluent Data Summary Effluent data are summarized below for the period January 2014 through February 2018. The plant was operating under SOC WQ S10-010 from August 2011 until April 1, 2016, with modified limits in effect until February 1, 2016. Summary data are in two tables: one under SOC limits (Table 1), and one under permit limits (Table 2). Table 1. Effluent Data Summary under SOC-modified limits (January 1, 2014 - January 31, 2016). Parameter Units Average Max Min Limits ' BOD summer mg/L 20.9 < 2.0 MA 15.0 mg/L WA 35.0 mg/L BOD winter mg/L 6.6 30.2 < 2.0 MA 25.0 mg/L WA 35.0 mg/L BOD removal % 96.3 99.1 88.6 > 70 TSS mg/L 19.4 75 4.4 MA 35.0 mg/L WA 50.0 mg/L TSS removal % 83.3 87.2 65.9 > 70 N113-N mg/L - 5 0.1 MA 5.0 mg/L WA 15.0 mg/L ' MA = Monthly Average; WA = Weekly Average; DM = Daily Maximum. Page 2 of 19 Table 2. Effluent Data Summary under permit limits post SOC (February 1, 2016 - February 28, 2018). Parameter ' Units Average Max Min Limits 1 Flow MGD 76 __ _ _ _ 2.25 12.0 MGD BOD summer mg/L < 2,8 14.0 < 2 0 MA 10.0 mg/L WA 15.0 mg/L BOD winter mg/L < 7.4 36.0 < 2.0 MA 20.0 mg/L WA 30.0 mg/L BOD removal % 96.2 99.1 83.1 > 85 TSS mg/L 15.0 108 3.2 MA 30.0 mg/L WA 45.0 mg/L TSS removal % 88.8 94.6 76.9 > 85 NH3-N summer mg/L 0.6 2.5 n , MA 2.0 mg/L WA 6.0 mg/L NH3-N winter mg/L 1.0 7.8 0.2 MA 4.0 mg/L WA 12.0 mg/L DO mg/L 9.0 12.8 6.8 5.0 mg/L Fecal Coliform (Geomean) #/100 mL 19 4200 < 1 MA 200/100 mL WA 400/100 mL Total Residual Chlorine (TRC) µg/L 23 49 10 DM 18 µg/L Temperature °C 18 28 4 Monitor only Total Nitrogen mg/L 13.71 33.90 5.68 Monitor only Total Phosphorus mg/L 2.0 4.6 0.9 Monitor only Total Cadmium µg/L < 1.1 1.8 0.1 MA 2.2 µg/L DM 16.0 µg/L Total Chromium µg/L 24.5 55.1 8.6 MA 53.5 µg/L DM 1093 µg/L Total Lead µg/L < 2.55 3.8 < 2.5 Monitor only Total Mercury ng/L 7.2 26.6 < 1.0 MA 12.0 ng/L DM 36.0 ng/L Total Nickel µg/L 3.7 9.0 0.006 MA 27.2 µg/L DM 279 µg/L Total Selenium µg/L 4.8 6.2 0.005 MA 5.4 µg/L DM 59.9 µg/L Total Copper µg/L 69.0 135.0 29.5 Monitor only Total Silver µg/L < 2.5 2.8 < 1.9 Monitor only Total Zinc µg/L 55.1 110.0 5.2 Monitor only Page 3 of 19 Color ADMI < 50.9 155.7 < 20.0 Monitor only Between 6 and 9 pH SU 6.6 7.2 6.0 standard units 1 MA = Monthly Average; WA = Weekly Average; DM = Daily Maximum. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/l of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will beproposedfor this permit action: The current permit requires instream monitoring for Dissolved Oxygen (DO), Temperature, Conductivity, Copper, and Color from one upstream (U) and three downstream (D1, D2 and D3) locations, all in Long Creek. U is located upstream of the discharge; D1 is located at —2620 ft below the discharge; D2 is 3.9 mi. downstream at NCSR 1967 Sides Rd; and D3, for Color only, is located —200 ft below the discharge. D1 was moved from its original location at the end of NCSR 1960 to its current location in a permit modification in December 2012 due to safety concerns. Instream monitoring data were reviewed from DMRs with concurrent effluent data for evaluation of potential stream impacts. Instream DO remains in the permit as a parameter of concern for aquatic life. Reviewed instream DMR data from January 2015 through February 2018 was shown to be above the DO standard of 5.0 mg/L consistently at all locations, except for U, which had five occurrences below the standard. Overall trends show seasonal patterns with summer minima and winter maxima; among the data sets, U showed the widest seasonal variation and effluent showed the least. The DO at D1 was found to be significantly lower than upstream, D2 and the effluent DO. Further, Effluent DO was significantly higher than that at D2. Averages over the entire period analyzed were: U = 8.2 mg/L; D I = 7.6 mg/L; and D2 = 8.1 mg/L. During the critical summer months (April -October), minimum values were: U = 4.4 mg/L; D 1= 5.7 mg/L; and D2 = 6.6 mg/L; concurrent summer effluent minimal DO was 6.9 mg/L. Instream Temperature remains in the permit as a parameter of concern for aquatic life. Temperature averages for the period analyzed were: U = 19.2 °C, D1 = 21.1 °C, and D2 = 21.2 °C; and all data were below the standard of 32°C for lower piedmont and coastal plain waters. There were no significant differences among the instream locations and the effluent throughout all seasons (one-way ANOVA, F = 2.14, p = 0.09). Instream Conductivity remains in the permit as a parameter of concern due to an industrial discharger. There were significant differences between upstream, downstream (DI) and downstream (132) locations. The average conductivity values for the period analyzed were: U =187, DI = 304, and D2 = 281 µmhos/cm. The higher downstream conductivity suggests impact from the effluent, which is not currently being monitored. Because of this, the facility's receiving industrial wastewater, and monitoring requirements in NCAC 15A 2B .0500, effluent conductivity monitoring will be added to the permit. Instream Color remains in the permit as a parameter of concern due to the presence of an industrial discharger. There was clear evidence of an impact from the effluent on instream color as data among the Page 4of19 effluent, upstream and downstream waters all tested different (one-way ANOVA: F = 3.04, p < 0.0001) with effluent highest at an average of 53.0 ADMI. Downstream color averaged 42.8 ADMI, significantly higher than the upstream average of 36.3 ADMI (t-test: t = -2.12, p = 0.017). Instream Copper remains in the permit as a parameter of concern due to the stream's current listing for copper impairment on the Final 2016 303(d) list; however, there is no TMDL for copper. Significant differences were found among the three instream sites and concurrent effluent samples (one-way ANOVA: F = 90.36, p < 0.0001). The average copper values for the period analyzed were: U = 4.34, D 1= 27.33, and D2 = 18.53 µg/L; concurrent effluent data averaged 59.9 µg/L. D2 had significantly lower copper concentrations than did D1 (t-test: t = 2.22, p = 0.03). The above analysis excluded a set of unusually high instream concentrations (all > 200 µg/L) from March 1, 2017, with the highest value from the upstream sampling location. Copper loading was analyzed from the 303(d)-listing year of 2008 through 2017. Yearly average loadings decreased from 3.1 lb/day in 2008 to 2.61b/day in 2009, then increased to a peak of 4.8 lb/day in 2013, then decreased again to 2.7 lb/d in 2017. See Stream Impairment Analysis Loading of Copper in the Fact Sheet attachments for data and graphs. Copper instream monitoring frequencies in the current permit are weekly in summer months (June through September) and monthly during the rest of the year, less frequent than those under NC 15A NCAC 2B .0500 (3/week in summer, weekly in winter). These monitoring frequencies have been in the permit dating back to 1992, and were likely set in a previous permit. A review of permit files dating as far back as 1989 revealed no explanation for the monitoring frequencies, and consultation with regional office personnel also yielded no explanation. Copper instream monitoring frequencies will be maintained in the permit due to the receiving stream's continued impairment, despite a lack of a TMDL for the stream segment. Copper limits are added to the permit from a reasonable potential analysis, to further address the stream impairment by further reductions in copper loading. Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): NO Name of Monitoring Coalition: NA 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): From April 2013 through March 2018 there have been 11 violations reported, including two Notices ofDeficiency (NOD), one Notice of Violation (NOV), and seven enforcement cases. These violations involved mostly mercury and TSS exceedences (6 and 4, respectively) and one pH value below the minimum. The facility had been operating under an SOC since 2011 with modified limits for BOD, TSS, NH3-N, plus BOD and TSS removal rates. The SOC expired on April 30, 2016 with a compliance date to meet permit limits of February 1, 2016. Since the compliance date, there was one TSS weekly average exceedance, in January 2018, but no action was taken. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 20 of 24 quarterly chronic toxicity tests, as well as all 4 second species chronic Page 5of19 toxicity tests. All subsequent tests following test failures had passed. Second species tests were sampled on 10/6/2013, 11/3/2013, 12/1/2103 and 1/5/2014. Summarize the results from the most recent compliance inspection: The most recent facility inspection (compliance evaluation), conducted on February 18, 2018, found the plant to be compliant. The Long Creek WWTP SOC expired in April 2016 after construction activities/upgrades were complete. There have been four technical assistance visits from 2012-2013 for nutrient removal, aeration basins, grit removal, and influent pump station compliance issues. A compliance evaluation conducted on August 12, 2014 found issues with influent sampling tubing, corrosion of bar screens, a hole in the drying bed, and with standby power unable to supply all surface aerators. An evaluation on January 20, 2016 found the facility well operated and maintained. Repairs had been made to fix the hole in the drying bed found during the previous inspection. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMLXmodel results): If applicable, describe any mixing zones established in accordance with 15A NCAC 2B.0204(b): NA Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD = 30 mg/L for Municipals) may be appropriate if deemed more stringent based on dilution and model results. Ifpermit limits are more stringent than TBELs, describe how limits were developed: Limitations for BOD are based on a Streeter Phelps model (Level B) for instream DO protection. No changes are proposed from the previous permit limits. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 µg/L (acute impacts). Due to analytical issues, all TRC values reported below 50 µg/L are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: There are proposed changes to decrease the NH3-N limit for both the 12 MGD flow phase (winter to 2.6 mg/L monthly average and 7.8 mg/L weekly average; summer to 1.1 mg/L monthly average and 3.3 mg/L weekly average) and the 16 MGD flow phase (winter to 2.4 mg/L monthly average and 7.2 mg/L weekly average; summer to 1.1 mg/L monthly average and 3.3 mg/L weekly average) based on the ammonia criteria of 1.0/1.8 mg/L Page 6of19 summer/winter, and the ammonia -nitrogen waste load allocation (WLA) calculation to protect against ammonia toxicity. The WLA resultant TRC limits will remain at 18 µg/L daily maximum. Reasonable Potential Analysis RPA for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of '/2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between January 2014 through February 2018 for the current 12 MGD and the 16 MGD expansion flows. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: Cadmium, Chromium VI, Copper at both the 12 and 16 MGD flow tiers. o Cadmium will receive more stringent limits than in the current permit at both the 12 and 16 MGD flow tiers, along with a compliance schedule at the 12 MGD tier. Current limits will be maintained as interim limits for the duration of the compliance schedule. o Chromium VI and Copper will also receive a compliance schedule with interim monthly monitoring. Monitoring -only for Copper is in the current permit and will be maintained; monitoring -only for Chromium VI will be added. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was > 50% of the allowable concentration: Total Chromium and Silver at both flow scenarios. o Silver will receive a quarterly monitoring requirement since this metal is currently reported at levels < 2.5 µg/L, which is > the PQL of 1 µg/L and > the Cw of 0.065 µg/L at 12 MGD and 0.064 µg/L at 16 MGD, with only one detect at 2.8 µg/L. Total Silver should be sampled using "clean" sampling techniques and shall be analyzed to the lower reporting level of the procedure. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration: Arsenic, Beryllium, Total Phenolic Compounds, Cyanide, Nickel, Lead, Molybdenum, Selenium and Zinc at both flow tiers. POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: Bis (2-ethylhexyl) phthalate at 12 MGD and 16 MGD. o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None o Dichlorobromomethane and Chlorodibromomethane were detected in the pollutant scans. Neither pollutant will receive a limit or monitoring, since they did not demonstrate Page 7of19 reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration. As part of the NC 2007-2014 Water Quality Standard (WQS) Triennial Review the total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium (Cr-VI) Water Quality Standards. The RPA using the city's Total Chromium effluent data showed reasonable potential to violate the new hexavalent chromium standard. Total Chromium is made up of hexavalent and trivalent chromium. Therefore, Total Chromium limits were removed and Cr-VI limits were added to this permit, with Total Chromium quarterly monitoring maintained as part of the pretreatment Long Term Monitoring Plan. Sampling for Cr-VI will ascertain if hexavalent chromium is present in the Total Chromium samples and thus the effluent. If hexavalent chromium is present, the City will be given time to comply with the new standard per the compliance schedule added to the permit. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Major POTW, and a chronic WET limit at 90% effluent will continue with a quarterly monitoring frequency. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (^-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (> 1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/L) and/or if any individual value exceeds a TBEL value of 47 ng/L. Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL at either the 12 or the 16 MGD flow scenario, and no individual mercury sample exceeded the TBEL (Table 3), no mercury limit is required. However, since the facility is > 2 MGD and reported quantifiable levels of mercury (> 1 ng/L), a mercury minimization plan (MMP) has been added to the permit. Page 8of19 Table 3. Mercury Effluent Data Summary 2014 2015 2016 2017 2018 # of Samples 17 14 12 12 2 Annual Average Conc. ng/L 10.2 7.8 4.8 4.6 6.8 Maximum Conc., ng/L 26.60 14.00 11.00 7.20 8.90 TBEL, ng/L 47 WQBEL, ng/L at 12 MGD 13.03 WQBEL, ng/L at 16 MGD 12.77 Other TMDL/Nutrient Man ement Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA Other WQBEL Considerations- Permit Limit Development The current total chromium limitations were maintained in the interim effluent sheet until hexavalent chromium levels can be assessed. The reasonable potential analysis using the city's total chromium effluent data showed reasonable potential to violate the new hexavalent chromium standard. As a result, hexavalent chromium limitations were added to this permit. Sampling for hexavalent chromium will ascertain if hexavalent chromium is present in the total chromium samples and thus the effluent. If applicable, describe any other parameters of concern evaluated for WQBELs: Chromium VI If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c)(2)(B), 40CFR 122.47, and EPA May 2007Memo: A seven (7) year compliance schedule has been added to allow time and effort for the Permittee to comply with the new Cadmium, Chromium VI and Copper limits, resulting from their reasonable potential to exceed water quality standards and/or implementation of the new dissolved metal standards. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B.0226for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg1L BOD5/TSS for Monthly Average, and 45 mg/L for BOD5/TSS for Weekly Average). YES If NO, provide a justification. for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD5/TSS included in the permit? YES. A variance to the 85% TSS removal rate was added to the permit in 2005, with minimum limits of 82% removal in summer (from April 1 through October 31) and 68% in winter (from November 1 through March 31). This variance was carried over in the 2011 (current) permit without note of its evaluation, nor a request to continue the variance by the Permittee. In August 2011, an SOC (WQ S10-010) was issued for noncompliance with TSS, BOD and Page 9of19 NHA-N limits. Interim limits for BOD, TSS and NH3-N less stringent than those in the permit were placed into the SOC with an initial compliance date of December 1, 2013. This SOC was amended twice with a final scheduled permit limit compliance date of February 1, 2016, and a final expiration date of April 30, 2016. The permit limit for TSS removal listed in the SOC is 85%, so placed because the SOC writer was unaware of the variance. No request to continue the variance was found in the current permit renewal application received in 2014. Review of effluent TSS data since the SOC's compliance date (from February 2016 through January 2018) found one exceedance of the weekly average limit in January 2018 (67.0 mg/L) and no exceedances of the monthly average limit. Compliance with current permit limits (under variance) for TSS removal are also mostly met with one monthly average of 80.5% removal April 2016. Comparisons with the standard removal rate of 85% found seasonal noncompliance with one monthly average below in winter months — substantially fewer than before the SOC expiration. An evaluation of eligibility for continuation ofthe TSS removal limit variance was made through consulting 40 CFR 133.103(d), which lists the following criteria: 1. The treatment works is consistently meeting, or will consistently meet, its permit effluent concentration limits but cannot meet its percent removal limitations because of less concentrated influent wastewater. Not met: Post-SOC effluent TSS concentrations are consistently meeting limits, as the calculated of 95te percentile of monthly averages is 23.9 mg/L, below the 30.0 mg/L TBEL. Post-SOC effluent TSS removal rates are also consistently meeting the 85% minimum, as the calculated 951 percentile is 94.5% removal. 2. To meet the percent removal requirements, the treatment works would have to achieve significantly more stringent limitations than would otherwise be required by the concentration -based standards. NA. Percent removal requirements are found to be consistently met (see above). 3. The less concentrated influent wastewater is not the result of excessive H. NA. The SOC addressed problems in the City's collection system, which experienced considerable VI during rain events. From this evaluation, the facility does not qualify for a TSS removal limit variance. Therefore, TSS removal rate limits will be changed to 85%. If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA Page 10 of 19 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or W QBELs may be less stringent based on updated RPA or dilution). Are anv effluent limitations less .stringent than previous permit (YESINn): NO If YES, confirm that antibacksliding provisions are not violated: NA 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10122/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. No effluent parameters are sampled at reduced monitoring frequencies For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was fmalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions: Current permit conditions and proposed changes are presented in three tables: one for 12 MGD with interim limits, one for 12 MGD with final limits, and one for 16 MGD expansion flow (Tables 4, 5 and 6). The 12.0 MGD conditions have been split into interim and final tiers to address compliance schedules for Cadmium, Chromium VI and Copper limits. Table 4. Current Permit Conditions and Proposed Changes at 12 MGD - Interim Parameter Current Permit 1 Proposed Change Basis for Condition/Change Flow MA 12.0 MGD No change 15A NCAC 2B .0505 Page 11 of 19 Parameter Current Permit Proposed Change Basis for Condition/Change Summer: MA 10.0 mg/L . WA 150 mg/L WQBEL. Based on 1993 WLA BODS Winter: No change model and protection of DO MA mg/L standard. 15A NCAC 2B.0200 WA 30 mg/L Summer: Summer: MA 2.0 mg/L MA 1.1 mg/L N113-N WA 6.0 mg/L WA 3.3 mg/L WQBEL. WLA results, for Winter: Winter: protection from toxicity. MA 4.0 mg/L MA 2.6 mg/L WA 12.0 mg/L WA 7.8 mg/L WQBEL. 15A NCAC 2B.0200. DO DA > 5.0 mg/L No change Based on 1993 WLA and for the protection of water quality. MA 30 mg/L WA 45 mg/L No change in mg/L TBEL. Secondary treatment TSS removal rate 82% limits; standards / 40 CFR 133 / 15A TSS summer, 68% winter TSS removal rate NCAC 2B .0406. Removal rates do (variance granted in changed to 85% year- not meet criteria for limit variance 2005) round [40 CFR 133.103(d)]. Fecal Coliform MA 200 /100 mL WA 400 /100 mL No change WQBEL. 15A NCAC 2B.0200 TRC DM 18 µg/L No change WQBEL. 15A NCAC 2B.0200; WLA results Total Nitrogen Monitor only No change 15A NCAC 2B.0500 Total Phosphorus Monitor only No change 15A NCAC 2B.0500 Temperature Monitor only No change 15A NCAC 2B.0500 Conductivity Monitor instream only Add daily effluent 15A NCAC 2B.0500 monitoring WQBEL. 15A NCAC 2B.0200. MA 2.2 µg/L Reasonable potential to exceed Total Cadmium DM 16.0 µg/L No change WQS. Delayed implementation of lower limits via compliance schedule. MA 53.5 µg/L NPDES permitting guidance for Total Chromium DM 1093 µg/L Remove from permit dissolved metals; monitoring maintained WQBEL. 15A NCAC 2B.0200. Reasonable potential to exceed Chromium VI No requirement Monitor monthly WQS. Delayed implementation of lower limits via compliance schedule. Page 12of19 Parameter Current Permit 1 Proposed Change Basis for Condition/Change WQBEL. 15A NCAC 2B.0200. Reasonable potential to exceed Total Copper Monitor monthly No change WQS. Delayed implementation of lower limits via compliance schedule. Total Lead Monitor Quarterly Remove from permit WQBEL. 15A NCAC 2B.0200. No reasonable potential to exceed WQS. Total Mercury MA 12 ng/L Remove limits; add ury minimization Statewide mercury TMDL, based on DM 36 ng/L plan plant size Total Nickel MA 27.2 µg/L Remove from permit WQBEL. 15A NCAC 2B.0200. No DM 279 µg/L reasonable potential to exceed WQS. Total Selenium MA 5.4 µg/L Remove from permit WQBEL. 15A NCAC 2B.0200. No DM 59.9 µg/L reasonable potential to exceed WQS. Add monthly WQBEL. 15A NCAC 2B.0200. Total Silver Monitor Quarterly monitoring, report to RPA results; DWR Dissolved the lower level of the Metals guidance. 15A NCAC procedure 2B.0500 Total Zinc Monitor Quarterly Remove from permit WQBEL. 15A NCAC 2B.0200. No reasonable potential to exceed WQS. WQBEL. EPA Nationally Recommended WQ Criteria. RPA Bis (2-ethylhexyl) No requirement Add quarterly did not show reasonable potential to phthalate monitoring exceed criteria; the projected max was > 50% of allowable discharge concentration Color (ADMI) Monitor Instream and No change WQBEL. WQ Narrative Criteria. at the Effluent, 2/month 15A NCAC 2B.0200 Chronic Toxicity Chronic limit, 90% WQBEL. No toxics in toxic Test effluent No change amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 pH Between 6 and 9 SU No change WQBEL. 15A NCAC 2B.0200 Total Hardness No requirement Add effluent and Revised WQS and EPA's guidelines upstream monitoring on hardness -dependent metals. Effluent Pollutant Annual Reduce to three times 40 CFR 122 Scan per permit cycle Color Reopener and Monitoring Special condition No change NCGS.143-215.66, NCGS 143- Requirements 215.1 (b) Electronic No requirement Add Electronic Reporting Special In accordance with EPA Electronic Reporting Condition Reporting Rule 2015. Page 13 of 19 'MGD = million gallons per day, MA = monthly average, WA = weekly average, DM = daily maximum, DA = daily average. Table 5. Current Permit Conditions and Proposed Changes at 12 MGD — Final Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 12.0 MGD No change 15A NCAC 2B .0505 Summer: MA 10.0 mg/L WA 15.0 mg/L WQBEL. Based on 1993 WLA BOD5 Winter: No change model and protection of DO MA 20 mg/L standard. 15A NCAC 2B.0200 WA 30 mg/L Summer: MA 1.1 mg/L N113-N WA 3.3 mg/L No change e WQBEL. WLA results, for Winter: protection from toxicity. MA 2.6 mg/L WA 7.8 mg/L WQBEL. 15A NCAC 2B.0200. DO DA > 5.0 mg/L No change Based on 1993 WLA and for the protection of water quality. MA 30 mg/L WA 45 mg/L No change in mg/L TBEL. Secondary treatment TSS removal rate 82% limits; standards / 40 CFR 133 / 15A TSS summer, 68% winter TSS removal rate NCAC 2B .0406. Removal rates do (variance granted in changed to 85% year- not meet criteria for limit variance 2005) round [40 CFR 133.103(d)]. Fecal Coliform MA 200 /100 mL WA 400 /100 mL No change WQBEL. 15A NCAC 2B .0200 TRC DM 18 µg/L No change WQBEL. 15A NCAC 2B.0200. WLA results Total Nitrogen Monitor only No change 15A NCAC 2B.0500 Total Phosphorus Monitor only No change 15A NCAC 2B.0500 Temperature Monitor only No change 15A NCAC 2B.0500 Conductivity Monitor instream only Add effluent monitoring 15A NCAC 2B.0500 MA 2.2 µg/L MA 1.12 µg/L WQBEL. 15A NCAC 2B.0200. Total Cadmium DM 16.0 µg/L DM 6.62 µg/L Reasonable potential to exceed WQS. Total Chromium MA 53.5 µg/L Remove limits; maintain monthly NPDES permitting guidance for DM 1093 µg/L monitoring dissolved metals Page 14 of 19 Parameter Current Permit 1 Proposed Change Basis for Condition/Change MA 11.9 µg/L WQBEL. 15A NCAC 2B.0200. Chromium -VI No requirement DM 17.2 µg/L Reasonable potential to exceed WQS. MA 16.09 µg/L WQBEL. 15A NCAC 2B.0200. Total Copper Monitor monthly DM 22.52 µg/L Reasonable potential to exceed WQS. Total Lead Monitor Quarterly Remove from permit WQBEL. 15A NCAC 2B.0200. No reasonable potential to exceed WQS. Total Mercury MA 12 ng/L Add mercury Statewide mercury TMDL, based on DM 36 ng/L minimization plan plant size Total Nickel MA 27.2 µg/L Remove from permit WQBEL. 15A NCAC 2B.0200. No DM 279 µg/L reasonable potential to exceed WQS. Total Selenium MA 5.4 µg/L Remove from permit WQBEL. 15A NCAC 2B.0200. No DM 59.9 µg/L reasonable potential to exceed WQS. No limit, monitor RPA results; DWR Dissolved Total Silver Monitor Quarterly monthly; report to the lower level of the Metals guidance. 15A NCAC procedure 2B.0500 Total Zinc Monitor Quarterly No monitoring WQBEL. 15A NCAC 2B.0200. No reasonable potential to exceed WQS. WQBEL. EPA Nationally Recommended WQ Criteria. RPA Bis (2-ethylhexyl) No requirement Quarterly monitoring did not show reasonable potential to phthalate exceed criteria; the projected max was > 50% of allowable discharge concentration Color (ADMI) Monitor Instream and No change WQBEL. WQ Narrative Criteria. at the Effluent 15A NCAC 2B.0200 Chronic Toxicity Chronic limit, 90% WQBEL. No toxics in toxic Test effluent No change amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 pH Between 6 and 9 SU No change WQBEL. WQ standard, 15A NCAC 2B .0200 Added effluent and Revised water quality standards and Total Hardness No requirement upstream monitoring EPA's guidelines on hardness dependent metals. Effluent Pollutant Annual Reduce to three times 40 CFR 122 Scan per permit cycle Color Reopener and Monitoring Special condition No change NCGS.143-215.66, NCGS 143- Requirements 215.1 (b) Page 15of19 Electronic No requirement Add Electronic Reporting Special In accordance with EPA Electronic Reporting Condition Reporting Rule 2015. 'MGD = million gallons per day, MA = monthly average, WA = weekly average, DM = daily maximum, DA = daily average. Table 6. Current Permit Conditions and Proposed Changes at 16 MGD Parameter Current Permit 1 Proposed Change Basis for Condition/Change Flow MA 16.0 MGD No change 15A NCAC 2B .0505 Summer: MA 10.0 mg/L WA 15.0 mg/L WQBEL. Based on 1993 WLA BOD5 Winter: No change model and protection of DO MA 20 mg/L standard. 15A NCAC 2B.0200 WA 30 mg/L Summer: Summer: MA 2.0 mg/L MA 1.1 mg/L NH3-N WA 6.0 mg/L WA 3.3 mg/L WQBEL. WLA results, for Winter: Winter: protection from toxicity. MA 4.0 mg/L MA 2.4 mg/L WA 12.0 mg/L WA 7.2 mg/L DO DA > 5.0 mg/L No change WQBEL. Based on 1993 WLA and — for the protection of water quality. MA 30 mg/L WA 45 mg/L No change in mg/L TBEL. Secondary treatment TSS removal rate limits- standards / 40 CFR 133 / 15A TSS summer, 68%winteter r TSS removal rate NCAC 2B .0406. Removal rates do (variance granted in changed to 85% year- not meet criteria for limit variance 2005) round [40 CFR 133.103(d)]. Fecal Coliform MA 200 /100 mL No change WQBEL. WQ standard, 15A NCAC WA 400 /100 mL 2B .0200 TRC DM 18.0 µg/L No change WQBEL. WLA results. 15A NCAC 2B.0200 Total Nitrogen Monitor only No change 15A NCAC 2B.0500 Total Phosphorus Monitor only No change 15A NCAC 2B.0500 Temperature Monitor only No change 15A NCAC 2B.0500 Conductivity Monitor instream only Add effluent monitoring 15A NCAC 2B.0500 WQBEL. 15A NCAC 2B.0200. Total Cadmium M 15.8 µg/L DM 6.5 µg/L Reasonable potential to exceed WQS. Page 16 of 19 Parameter Current Permit 1 Proposed Change Basis for Condition/Change Total Chromium MA 52.6 µg/L Remove limits; maintain monthly NPDES permitting guidance for DM 1076 µg/L dissolved metals monitoring MA 11.7 µg/L WQBEL. 15A NCAC 2B.0200. Chromium -VI No monitoring DM 16.9 µg/L Reasonable potential to exceed WQS. MA 15.78 µg/L WQBEL. 15A NCAC 2B.0200. Total Copper Monitor monthly DM 22.15 µg/L Reasonable potential to exceed WQS. Total Lead Monitor Quarterly No monitoring WQBEL. 15A NCAC 2B.0200. No reasonable potential to exceed WQS. Total Mercury MA 12 ng/L Add mercury Statewide mercury TMDL, based on DM 36 ng/L minimization plan plant size Total Nickel MA 26.6 µg/L No limit or monitoring WQBEL. 15A NCAC 2B.0200. No DM 275 µg/L reasonable potential to exceed WQS. Total Selenium MA 5.3 µg/L No limit or monitoring WQBEL. 15A NCAC 2B.0200. No DM 58.9 µg/L reasonable potential to exceed WQS. Monitor only; report to WQBEL. 15A NCAC 2B.0200. Total Silver Monitor Quarterly the lower level of the RPA results and NPDES permitting procedure guidance for dissolved metals. 15A NCAC 2B.0500 Total Zinc Monitor Quarterly No monitoring No reasonable potential to exceed WQS. WQBEL. EPA Nationally Recommended WQ Criteria. RPA Bis (2-ethylhexyl) No requirement Add quarterly did not show reasonable potential to phthalate monitoring exceed criteria; the projected max was > 50% of allowable discharge concentration Color (ADMI) Monitor Instream and No change WQBEL. WQ Narrative Criteria. at the Effluent 15A NCAC 2B.0200 Chronic Toxicity Chronic limit, 90% WQBEL. No toxics in toxic Test effluent No change amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 pH Between 6 and 9 SU No change WQBEL. WQ standard, 15A NCAC 2B .0200 Add effluent and Revised water quality standards and Total Hardness No requirement upstream monitoring EPA's guidelines on hardness dependent metals. Effluent Pollutant Annual Reduce to three times 40 CFR 122 Scan per permit cycle Page 17of19 Parameter Current Permit' Proposed Change Basis for Condition/Change Color Reopener and Monitoring Special condition No change NCGS.143-215.66, NCGS 143- Requirements 215.1 (b) Electronic requirement Add Electronic Reporting Special accordance with EPA Electronic InNo Reporting Condition Reporting Rule 2015. ' MGD = million gallons per day, MA = monthly average, WA = weekly average, DM = daily maximum, DA = daily average. 13. Public Notice Schedule: Permit to Public Notice: 03/07/2017, 05/16/2018 (second Public Notice for extended compliance schedules) Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): YES, only after the first public notice. No comments were received after the second public notice. If Yes, list changes and their basis below: Input was received from the City of Albemarle concerning the compliance schedule for Cadmium, Copper, and Chromium -VI limits. Their concerns were outlined in a March 22, 2017 letter. They anticipate that the study phase to identify major contributing sources of target metals could take up to two years, since they will need to locate and understand SIU usage pattern changes throughout the year. They will also have to revise pre-treatment agreement(s) and evaluate treatment systems at SIUs since treatment additions at Long Creek W WTP may not be feasible or effective from both the cost and treatment perspective. The City anticipates that they will need to work with local industries to meet pre-treatment goals, and compliance and water quality standards. Thus, additional time will be needed to secure funding assistance programs to help the SIUs which necessitate the extension of the compliance schedule to include the requested 24 months (2 years). The special condition A. (8.) Schedule of Compliance for Cadmium, Copper, and Chromium -VI Limits in A. (2.) was revised to include a 2-year extension based on anticipated timeline of activities needed to achieve compliance with the limits contained in the permit. The Permittee shall now achieve compliance with Chromium -VI, Copper, and Cadmium limits in section A. (2) within 7 years of the effective date of this permit. As a result of the more relaxed limits via the compliance schedule extension, the draft permit will have to go to a second Public Notice. Effluent monitoring for Conductivity has been added to the permit per 15A NCAC 2B .0500. An instream analysis found higher conductivity downstream, suggesting effluent impact. Further, conductivity is an indication of industrial sources, and the facility is receiving industrial wastewater. Page 18of19 TSS removal rates were reverted to the standard 85% from evaluation of the data post-SOC permit compliance date. These data failed to meet variance criteria in 40 CFR 133.103(d). 15. Fact Sheet Attachments (if applicable): • Completed Pretreatment Information Request Form • Final 2016 NC 303(d) List, page 191 • Effluent Data Analysis — charts • Instream data analysis • Instream Impairment Analysis for Copper • Monitoring Report Violations • WET Testing Summary, page 1 • Compliance Evaluation Inspection report, February 22, 2018 - • Waste load allocations for TRC and NH3-N - 12 and 16 MGD • RPA Spreadsheet Summaries and dissolved to total metal calculator - 12 and 16 MGD • Dissolved to Total Metals Calculator - 12 and 16 MGD • Dissolved Metals Implementation/Freshwater • Mercury WQBEL/TBEL evaluation - 12 and 16 MGD Page 19 of 19 Yf- I I u NPDES/A uifer Protection Permitting Unit Pretreatment Information Request Form PERMIT WRITER COMPLETES THIS PART: PERMIT WRITERS - AFTER you n., th. Check all that apply Trom rtitc;,: - Notify PERCS if LTMP/STMP data we said should be, Date of Request 7/28/2016 _ municipal renewal X on DMRs is not really there, so we can get it for you Requestor Ron Be new industries (or NOV POTW). Facility Name Lo Greek WWTP WWTP expansion - Notify PERCS if you want us to keep a specific POC Permit Number NCO024244 Speculative limits in LTMP/STMP so you will have data for next permit Re i.on Mooresville stream reclass. renewal. Email PERCS draft permit, fact sheet, RPA. Basin Yadkin outfall relocation - Send PERCS paper copy of permit (w/o NPDES I 7Q10 khan a boilerplate), cover letter, final fact sheet. Email RPA ifother changes. check applicable PERCS staff: Other Comments to PERCS: _ ..I BIRD, CPF, CTB, FRB, TAR - Sarah Morrison 163105 X CHO, HIM, LTN, LUM, NES, NEW, ROA, YAD - Mon -it Hassan (6314) PERCS PRETREATMENT STAFF COMPLETES THIS PART: Status of Pretreatment Program (check all that apply) 1) facility has no SIU's, does have Division approved Pretreatment Program that is INACTIVE 2) facility has no SIU's, does not have Division approved Pretreatment Program 3) facility has SIUs and DWQ approved Pretreatment Program (list "DEV" if program still under development) 3a) Full Program with LTMP Me, Si t t T�/t 3b) Modifies! Program with STMP ) tJ 4) additional conditions regarding Pretreatment attached or listed below Flow, MGD Permitted I Time period for Actual STMP time frame: Industrial Most recent: Uncontrollable n/a Next C cle: g a Parameter of POC due to NPDES/ Non- Required by Re wired POTIN POC STMP LTMP POC due Concern (POC) y . Check List Dlsch Permit EPA* by b03 .+* y to SIU (Explain Effluent Effluent °a Limit Sludge- below)**** Freq Freq BOD 4 Q M TSS 4 Q M I Q = Quarterly H3 4 Q M : M = Monthly Arsenic 4 Q M �l Cadmium 4 Q M Chromium 4 Q M Dpper 4 Q M Cyanide 4 Q M Is all data on DMRs? Lead ,1 4 Q M YES ercury 4 Q M I NC {attach data) Mol bdenum 4 Q M Nickel 4 Q M Silver 4 Q M Selenium �/- 4 I Q M Znc ti+ 4 Q M Is data in spreadsheet' Total Nitrogen 4 Q M YES (emalwie Phosphorus 4 Q M NO 4 Q M 4 Q M 4 Q M 4 Q M *Always In the LTMP/STMP ** Only in LTMP/STMP if sludge land app or composte (dif POCs for incinerators) *** Only in LTMP/STMP while SIU still discharges to POTW **** Only in LTMP/STMP when pollutant is still of concern to POTW PERC NPDESPretreatment.request.form.july2007.xlsx Revised: July &, 2007 AC_ Final 2016 Category 5 Assessments-303(d) List Rocky River subbasin Yadkin -Pee Dee River Basin Assessment Unit Name Assessment Unit Description Assessment Unit Number Irish Buffalo Creek Water Quality Classification Length/Area Units From Kannapolis Water Supply Dam to Rocky River 13-17-9-(2) C 16.7 FW Miles sessment Criteria Status Reason for Rating Parameter of Interest 1R Category 9 rY Exceeding Criteria > 10% and < 90% conf Copper (7 jig/I, AL, FW) 5e Lanes Creek From source to Marshville Water Supply Dam (located 0.1 mile downstream of Beaverdam Creek) 13-17-40-(1) !Assessment Criteria Status exceeding Criteria Lanes Creek 13-17-40-(12) WS-v Treason for Rating Parameter of Interest Fair Benthos (Nar, AL, FW) 27.4 FW Miles IR Category 5 From Marshville Water Supply Dam (located 0.1 mile downstream of Beaverdam Creek) to Rocky River C 27.1 FW Miles sessment Criteria Status Reason for Rating Parameter of Interest IR Category, Exceeding Criteria Fair Benthos (Nar, AL, FW) 5 Little Richardson Creek (Lake Monr From source to a point 0.6 mile upstream of Buck Branch 13-17-36-4-(0.5) WS-Iv 77.1 FW Acres Assessment Criteria Status Reason for Rating Data Inconclusive > 10% and >90 conf N<10 Parameter of Interest IR Category Chlorophyll a (40 µg/I, AL, NC) 5 Little Richardson Creek (Lake Monr From a point 0.6 mile upstream of Buck Creek to Richardson Creek 13-17-36-4-(2) WS-IV;CA Lessment Criteria Status�Reas�and RatingParameter of Interest iR Cate ol;r rY Inconclusive 0 conf N�<10Chlorophyll a (40 µg/I, AL, NC) 5 Long Creek From Little Long Creek to Rocky River 13-17-31b r= — Hssessment criteria Status Reason for Rating Exceeding Criteria > 10% and >90 conf Parameter of Interest Copper (7 µg/i, AL, FW) 38 7 FW Acres 2.2 FW Miles IR Category 3/23/2018 Final 2016 NC Category 5 Assessments Page 191 of 196 City of Albermarle / Long Creek WWTP Effluent Data Review NCO02424 14 12 10 0 ♦�� 8 � 6 2 0 oti� oti°` 1y\ryti\ti 6\1o\ti W k Avg Long Creek WWTP - Flow Mo Avg MA Limit 4A A AAA .AA oa pyh p,6 p'y�O p'y� p'y� 01� `b\tip\� � 9\~�\� Long Creek WWTP - BOD Mo. Avg WA Limit MA Limit 40 35 30 J 25 � l f n 20 E ■ f . 15 10 • 0 91� �01a � �01y b �oyo "O,yA 440, �oy'1 , 'LOy'b \�o\ titi\y1\ 1\,'�\ y�,�1\ �b\,y`b\ A\,yp\ Long Creek WWTP - BOD Removal Effluent Limit 110 100 90 t.,r a 80 70 60 f� 50 L�- ti� ti°` tia by do y� y1 ti� y� Ion >o� �e� �J� �a� PJQv lac• 5�Q PQc Summary Statistics N 1519 Mean 5.76 SD 2.71 Min 2.25 Max 23.48 Summary Statistics Summer - SOC Post SOC N 299 297 Mean 3.2 2.8 SD 2.4 1.5 Min 2.0 2.0 Max 20.9 14.0 Winter SOC Post SOC N 218 221 Mean 6.6 7.4 SD 4.5 6.7 Min 2.0 2.0 Max 30.2 36.0 Summary Statistics _ SOC Post SOC N 25 25 Mean 96.3 96.2 SD 2.8 4.2 Min 88.6 83.1 Max 99.1 99.1 Page 1 G.B. Perlmutter, rev. 4/16/2018 City of Albermarle / Long Creek WWTP Effluent Data Review NC002424- Long Creek WWTP - TSS Wk Avg • Mo. Avg WA Limit MA Limit 80 70 60 J 50 — "■ zoUAA o s �s 10 j1r 0 ro A O,y O oy� OArv\ O O,� Long Creek WWTP - TSS Removal -+-Effluent Limit 100 95 - 90 85 r 80 y V 9 75 70 65 60 55 50 y3 I,'4b off. p ���, • ,J� lac �,$ �`a� �Q PQ� Long Creek WWTP - NH3-N a Wk Avg Mo. Avg WA Limit MA Limit 16 14 12 J 10 0 8 E 6 — - - - - - - - - - - - - 1 2 0 '1\y111 y\p \�y\�Oti(O \1�\�Oti(O 41 J\ 011 \ry�\1 cNIP 0 NVy Summary Statistics SOC Post-SOC N 517 526 Mean 19.4 15.0 SD 8.7 9.2 Min 4.4 3.2 Max 75.0 108.0 Summa Statistics SOC Post-SOC N 25 25 Mean 83.3 88.8 SD 4.4 5.2 Min 65.9 76.9 Max 87.2 94.6 Summar-; Statistics SOC N _ T 517 Mean 0.6 SD 0.5 Min 0.1 Max 7.7 Post SOC Summer Winter N 297 222 Mean 0.6 1.0 SD 0.2 1.2 Min 0.1 0.2 Max 2.5 7.8 Page 2 G.B. Perlmutter, rev. 4/16/2018 City of Albermarle / Long Creek WWTP Effluent Data Review NCO02424 Long Creek WWTP - DO Effluent Limit 14 12 10 8 no E 6 4 2 0 O,3 Oda rJN 6N \y�\1 titi\~�\~\yh\� y\3ti\ti 44' _IX 4"p,ti a\1o\ti Long Creek WWTP - Fecal Coliform Wk Avg Mo. Avg WA Limit MA Limit 1000 ♦ Ems"'► « �• Q ,ff c, 10 4 ��%*4� +ate � � � �tiR`� ,r *f � t! o'� i 1 • 013 o1a 5V o1h 010 010 011 011 01� 400\T\�~\ry\141 Long Creek WWTP - TRC Effluent Daily Max Compliant 60 50 40 t 30 r A114% 20 • 10 0 010 010 O,y'1 011 1\01\�\13\O\T \��\� 10\, of t Summary Statistics N 1037 Mean 9.03 SD 1.34 Min 6.8 Max 12.8 Summa Statistics N 1032 Geometric Mean 19 Min 1 Max 4200 Summary Statistics N 1037 Mean 23 SD 8 Min 10 Max _ _ _ _49 Page 3 G.B. Perlmutter, rev. 4/16/2018 City of Albermarle / Long Creek WWTP Effluent Data Review NCO02424 30 25 u 20 Icu � 15 CLO 10 5 0 Long Creek WWTP - Temperature Effluent O(0 O,b O,A OyA Oyu -Ot y\'b `b\y�\'L oi\"�\'L txyp Long Creek WWTP - Total Nitrogen Effluent 40 35 30 J 25 to 20 E 15 10 5 0 O,3 Oyu O,� Oyy O,� Oyu ON ON 6\yo�ti y�\\yy�ti y\\y��ti �\��ti 9\�ti�ti\yo�ti Long Creek WWTP - Total Phosphorus Effluent 5.0 4.5 4.0 3.5 3.0 to 2.5 E 2.0 1.5 1.0 0.5 00 \~Oy'S 'y \y0\�OyD ti���\�O,yA y 1�y�\~O,yh y\�y\�O,y�o \yam\�Oy�o 3`O\"O,y'1 \��\�Oy'1 °� b�y0\~O,y'b Summary Statistics N 1037 Mean 18 SD 6 Min 4 Max 28 Summ?iaLptatistics N 50 Mean 13.71 SD 5.32 Min 5.68 Max 33.90 Summary Statistics N 50 Mean 2.0 SD 0.9 Min 0.9 Max 4.6 Page 4 G.B. Perlmutter, rev. 4/16/2018 City of Albermarle / Long Creek WWTP Effluent Data Review Long Creek WWTP - Total Cadmium Effluent MA Limit 2.5 J 1.5 = 1 0.5 0 01� Q) 01; 5V QN. 01A 0100 1\�1\1 \1�\� �\o\ti o\31 a\10\~ Long Creek WWTP - Total Chromium Effluent MA Limit 60 50 f 40 w 30 20 10 0 A\01° oti`' ti O,O O,� O,A O,^ ONE y\�ti�ti 4\�1�ti �\o\ti o\,V U\1oKti Long Creek WWTP - Total Mercury Effluent MA Limit DM Limit 40 r 35 _ 30 25 �tkb 20 15 10 - 5 0 01 01� O,A O,a O,y O,O O,� 01A rill.- L yy\�,L�'L O\10�ti 1�\ry,`�'L \1y�'L 1\�ti�'ti \y��'L 3\O�'L \���'L D\.'9 Summary Statistics N 50 Mean 1.1 SD 0.3 Min 0.1 Max 1.8 Summary Statistics N 54 Mean 24.5 SD 10.9 Min 8.6 Max 55.1 Summary Statistics N 57 Mean 7.2 SD 4.5 Min 1.0 Max 26.6 NC002424, Page 5 G.B. Perlmutter, rev. 4/16/2018 City of Albermarie / Long Creek WWTP Effluent Data Review NCO02424 Long Creek WWTP - Total Nickel Effluent MA Limit 30 25 Summary Statistics 20 N 50 J 15 Mean 3.7 10 SD 1.8 Min 0.0 5 Max 9.0 0 y\~~\~Oyu 7, to\y�\�Oya \~�\�Oy� \yy\�Oyh \1y\~Oy6 \�~\�Oy1 \y�\~Oyu yti 1 y 4� A Long Creek WWTP - Total Copper Effluent 160 140 120 100 J n 80 60 40 20 0 � oy° Oyu 4SP Oyu C) oy10 Oy^ oy00 yti\� 1\y�\'L y\�y\'L \y�\'L 'bx \~O, a\yO\'L Long Creek WWTP - Total Zinc Effluent 120 100 80 J own 60 40 20 0 O,6 yy\0, ' IO\yO\`y y�\ry,`\� 1\yy \�\'L KII,L\'L I.K1O\'L Summary Statistics N 51 Mean 69.0 SD 24.6 Min 29.5 Max 135.0 Summary Statistics N 50 Mean 55.1 SD 19.5 Min 5.2 Max 110.0 Page 6 G.B. Perlmutter, rev. 4/16/2018 City of Albermarle / Long Creek WWTP Effluent Data Review NC002424- 180 160 140 Y 120 100 80 ra 60 40 20 0 Long Creek WWTP - Color Effluent Summary Statistics N 100 Mean 50.9 SD 24.1 Min 20.0 Max 155.7 (I\N titi\~A\T '�\y�\~ ti\3y\� `�\1�\� -O\�\� 9\�~\~ a\1�\� Page 7 G.B. Perlmutter, rev. 4/16/2018 Albermarle / Long Cr WWTP Dissolved Oxygen (DO) NCO024244 001 001 A Month Day Year Date Effluent Upstream Dnstream Dnstream Standard D1 D2 1 6 2015 1 /6/2015 10.8 11.3 10.9 10.9 5.0 1 21 2015 1/21/2015 10.7 11.5 5.0 2 4 2015 2/4/2015 11.5 12.8 11.9 11.8 5.0 2 18 2015 2/18/2015 11.8 11.8 5.0 3 2 2015 3/2/2015 11.4 12.1 11.9 11.5 5.0 3 17 2015 3/17/2015 9.9 9.6 5.0 4 1 2015 4/1 /2015 9.8 10.9 10 10.4 5.0 4 21 2015 4/21 /2015 8.8 8.8 5.0 5. 4 2015 514/201.5 9.2 8.4 7.9 8.9 5.0 5 19 2015 ' 5/19/2015 8.2 6.8 5.0 6 2 2015 6/21201.5 7.7 5.7 6.2 7.7 5.0 6 11 2015 6/11/2015 7.6 5.8 6.1 7.1 5.0 6 16 2015 6/16/2015 7.5 4.4 6.5 .6.7 5.0 6 23 2015 6/23/2015 7.4 4.7 6.2 6.6 5.0 6 29 2015 6/29/2015 7.8 4.7 6.4 7.1 5.0 7 7 2015 7/7/2015 7.4 6.4 6 7.4 5.0 7 14 2015 7/14/2015 7.6 5.6 6.3 7.4 5.0 7 22 2015 7/22/2015 7.3 5.7 6.2 7.6 5.0 7 29 2015 7/29/2015 7.3 5.2 6.2 7.1 5.0 8 5 2015 8/5/2015 T3 4.5 6.5 7 5.0 8 12 2015 8/12/2015 7.3 5.7 6.4 7.1 5.0 .8 19 2015 8/19/2015 7.6 6.4 6.5 7.2 5.0 8 26 2015 8/26/2015 7.6 5.6 6.4 7.4 5.0 9 2 2015 9/2/2015 7.5 6.5 6.4 7.2 5.0 9 8 2015 9/8/2015 7.7 5.6 6.4 7.3 5.0 9 16 2015 9/16/2015 8.4 5.9 7.5 8.7 5.0 9 23 2015 9/23/2015 7.9 5.8 7 7.8 5.0 10 7 2015 10/7/2015 8.1 8.5 8.2 8.4 5.0 10 20 2015 10/20/2015 9.9 10.2 5.0 11 .5 2015 11 /5/2015 8.9 8.8 8.7 8.5 5.0 11 16 2015 11 /16/2015 10.6 10.9 5.0 12 3 2015 12/3/2015 9.5 11.5 10.9 10.8 5.0 12 15 2015 12/15/2015 9.7 10.3 5.0 1 6 2016 1 /6/2016 11.4 12.1 11.8 11.9 5.0 1 20 2016 1 /20/2016 11.2 12 5.0 2 2 2016 2/2/2016 9.9 13.2 11.4 11.5 5.0 2 18 2016 2/18/2016 10.9 12.3 5.0 3 1 2016 3/1/2016 10.2 11.7 10.7 10.7 5.0 3 15 2016 3/15/2016 8.5 9.2 5.0 4 4 201.6 4/4/2016 9.9 9.8 8.8 6.6 5.0 4 18 2016 4/18/2016 9.9 9.4 5.0 5 3 2016 5/3/2016 8.6 7.6 , 7.3 7.5 5.0 5 17 2016 5/17/2016 8.8 7.9 5.0 6 .2 2016 6/2/2016 7.7 6.8 6.8 7.4 5.0 6 8 2016 6/8/2016 7.8 7.1 6.6 7.5 5.0 6 15 2016 6/15/2016 7.6 7.5 7.1 7.5 5.0 .6 22 2016 6/22/2016 7.6 6.8 6.6 7.5 5.0 6 29 2016 6/29/2016 7.5 5.4 6.4 7.1 5.0 7 5 2016 7/5/2016 7.0 7.9 5.7 7.2 5.0 7 12 2016 7/12/2016 7.4 7.0 6.6 7.0 5.0 7 20 2016 7/20/2016 7.2 6,3 6.1 7,2 5.0 7 28 2016 7/28/2016 6.9 6.1 5.9 6.7 5.0 Page 39 G.B. Perlmutter, rev. 4/16/2018 Albermarle / Long Cr WWTP Dissolved Oxygen (DO) NCO024244 8 4 2016 8/4/2016 7.2 5.7 6.5 7.1 5.0 8 10 2016 8/10/2016 7.3 7.1 6.6 7.4 5.0 8 17 2016 8/17/201.6 7.1 6.6 63 6.9 5.0 8 24 2016 8/24/2016 7.6 7.3 6.7 7.6 5.0 8 30 2016 8/30/2016 7.5 6.5 6.4 7.3 5.0 9 6 2016 9/6/2016 8.0 7.5 6.7 8.2 5.0 9 13 2016 9/13/2016 7.6 7.1 6.7 7.7 5.0 9 22 2016 9/2212016 7.8 4.8 6.8 7.4 5.0 9 28 2016 9/28/2016 8.0 7.7 7.6 7.9 5.0 10 3 2016 10/3/2016 8.4 7.8 7.4 8.5 5.0 10 18 2016 10/18/2016 8.6 8.6 5.0 11 2 2016 11 /2/2016 8.9 7.5 7.4 8.3 5.0 11 16 2016 11/16/2016 9.7 9.3 5.0 12 1 2016 12/1 /2016 8.7 7.2 7.3 7.8 5.0 12 14 2016 12/14/2016 10.0 10.0 5.0 1 5 2017 1 /512017 10.5 11.8 11.0 10.6 5.0 1 18 2017 1 /18/2017 9.4 10.3 '5.0 2 2 2017 2/2/2017 10.2 10.9 10.2 10.5 5.0 2 14 2017 2/14/2017 9.7 11.6 5.0 3 1 2017 3/1/2017 8.9 12.0 9.2 10.0 5.0 3 20 2017 3/20/2017 10.4 10.8 5.0 4 3 2017 .4/3/2017 9.1. 10.6 8.5 9.2 5.0 4 17 2017 4/17/2017 8.5 7.4 5.0 5 3 .2017 5/3/2017 8.3 7.9 7.2 8.1 5.0 5 15 2017 5/15/2017 8.6 7.9 5.0 6 8 2017 6/8/2017 8.4 7.9 7.4 8.0 5.0 6 14 2017 6/14/2017 7.7 7.1 7.0 7.9 5.0 6 21 2017 6/21 /2017 7.7 7.4 7.5 7.8 5.0 6 27 2017 6/27/2017 7.7 7.2 7.0 8.3 5.0 7 5 2017 7/5/2017 7.5 7.0 6.9 7.3 5.0 7 11 2017 7/11/2017 7.5 6.9 6.5 7.3 5.0 7. 18 2017 7/18/2017 7.2 6.7 6.4 7.4 5.0 7 25 2017 7/25/2017 7.3 6.6 6.4 7.3 5.0 8 1 2017 8/1 /2017 7.5 7.3 6.7 7.5 5.0 8 9 2017 8/9/2017 7.8 5.0 7.0 7.7 5.0 8 15 2017 8/15/2017 7.3 6.3 6.4 7.1 5.0 8 23 2017 8/23/2017 7.1 5.6 6.3 7.1 5.0 8 30 2017 8/30/2017 8.0 7.4 7.4 8.2 5.0 9 5 2017 9/5/2017 8.2 8.0 7.5 8.3 5.0 9 13 2017 9/13/2017 8.3 8.2 7.8 8.5 5.0 9 •19 2017 9/19/2017 8.0 7.3 6.9 8.0 5.0 9 - 26 2017 9/26/2017 7.8 6.1 6.8 7.4 5.0 10 5 2017 10/5/2017 8.4 6.4 7.7 8.0 5.0 10 17 2017 10/17/2017 8.5 6.1 5.0 11 1 2017 11/1/2017 9.4 9.0 8.5 9.6 5.0 11 14 2017 11/14/2017 9.8 9.4 5.0 12 4 2017 12/4/2017 10.2 9.6 9.8 12.0 5.0 12 19 2017 12/19/2017 10.4 10.9 5.0 1 9 2018 1 /9/2018 12.5 12.8 11.1 11.7 5.0 1 22 2018 1 /22/2018 11.3 12.8 5.0 2 6 2018 2/6/2018 10.6 11.8 11.2 11.1 5.0 2 20 2018 _ 2/20/2018 9.4 10.4 5.0 Page 40 G.B. Perlmutter, rev. 4/16/2018 Albermarle / Long Cr WWTP Dissolved Oxygen (DO) NCO024244 Statistic Effluent Upstream Dnstream Dnstream D1 D2 N - 104 104 78 78 Mean 8.7 8.2 7.6 8.2 SD 1.3 2.3 1.7 1.5 Min 6.9 4.4 5.7 6.6 Max 12.5 13.2 11.9 12.0 Long Creek WWTP - Instream DO Effluent Upstream Dnstream DI A Dnstream D2 14 12 10 8 t E 6 ! 4 4 2 0 Standard y� \� ti~\�01� 6\yO\�O1b � ,ti �1�\~O1y '1 �3 ti �� C yo\�oy� Anova: Single Factor SUMMARY Groups Count Sum Amerage Variance Effluent 104 901.6 8.6692308 1.780403 Upstream 104 853.9 8.2105769 5.409693 Dnstream 1 78 592.1 7.5910256 2.872516 Dnstream 1 78 642.9 8.2423077 2.189745 ANOVA rce of Variation SS df MS F P-value F crit Between Groups 51.88674 3 17.29558 5.508273 0.001042 2.6297069 Within Groups 1130.374 360 3.139928 Total 1182.261 363 Page 41 G.B. Perlmutter, rev. 4/16/2018 Albermarle / Long Cr WWTP Dissolved Oxygen (DO) NC0024244 t-Test: Two -Sample Assuming Unequal Variances t-Test: Two -Sample Assuming Unequal Variancf Upstream D1 Mean 8.210577 7.5910256 Variance 5.409693 2.8725158 Observations 104 78 Hypoth. Mean Differen 0 df 180 t Stat 2.07857 P(T<=t) one -tail 0.019538 t Critical one -tail 1.653363 P(T<=t) two -tail 0.039075 t Critical two -tail 1.973231 Conclusion: Upstream DO is higher than D1 DO Upstream D2 Mean 8.2105769 8.242308 Variance 5.4096929 2.189745 Observations 104 78 Hypothesized Mean Difl 0 df 176 t Stat -0.112122 P(T<=t) one -tail 0.4554271 t Critical one -tail 1.6535574 P(T<=t) two -tail 0.9108543 t Critical two -tail 1.9735344 Conclusion: no difference between U and D2 DC t-Test: Two -Sample Assuming Unequal Variances t-Test: Two -Sample Assuming Unequal Variancf Effluent DJ Effluent D2 Mean 8.669231 7.591026 Mean 8.6692308 8.2423077 Variance 1.780403 2.872516 Variance 1.7804033 2.1897453 Observatio 104 78 Observatior 104 78 Hypothesiz 0 Hypothesize 0 df 142 df 156 t Stat 4.642161 t Stat 2.0082345 P(T<=t) on, 3.89E-06 P(T<=t) one 0.0231721 t Critical or 1.655655 t Critical on, 1.65468 P(T<=t) twc 7.77E-06 P(T<=t) twc 0.0463442 t Critical tw 1.976811 t Critical twr 1.9752875 _ _ Conclusion: Effluent DO is higher than D1 DO Conclusion: Effluent DO is higher than D2 DO Page 42 G.B. Perlmutter, rev. 4/16/2018 Albermarle / Long Creek WWTP Temperature NCO024244 001 001 A Day Year Date Effluent Upstream Dnstream Dnstream U-DI Diff U-D2 Diff Std D1 D2 6 2015 1 /6/2015 12 9 10 9 1 0 32 21 2015 1/21/2015 11 7 32 4 2015 2/4/2015 9 6 8 7 2 1 32 18 2015 2/18/2015 7 4 32 2 2015 3/2/2015 9 9 10 9 1 0 32 17 2015 3/17/2015 13 11 32 1 2015 4/1 /2015 14 15 17 16 2 1 32 21 2015 4/21 /2015 18 16 32 4 2015 5/4/2015 17 20 22 20 2 0 32 19 2015 5/19/2015 23 23 32 2 2015 6/2/2015 24 24 25 24 1 0 32 11 2015 6/11/2015 25 25 27 25 2 0 32 16 2015 6/16/2015 26 25 26 26 1 1 32 23 2015 6/23/2015 26 27 27 27 0 0 32 29 2015 6/29/2015 24 23 24 23 1 0 32 7 2015 7/7/2015 26 28 28 27 0 -1 32 14 2015 7/14/2015 26 26 26 25 0 -1 32 22 2015 7/22/2015 27 26 26 26 0 0 32 29 2015 7/29/2015 27 26 26 26 0 0 32 5 2015 8/5/2015 27 27 28 27 1 0 32 12 2015 8/12/2015 26 26 27 25 1 -1 32 19 2015 8/19/2015 26 25 25 25 0 0 32 26 2015 8/26/2015 25 23 25 24 2 1 32 2 2015 9/2/2015 25 27 28 25 1 -2 32 8 2015 9/8/2015 25 26 26 26 0 0 32 16 2015 9/16/2015 21 19 20 18 1 -1 32 23 2015 9/23/2015 22 20 22 20 2 0 32 30 2015 9/30/2015 24 23 24 23 1 0 32 7 2015 10/7/2015 19 16 19 18.5 32 20 2015 10/20/2015 14 9 32 5 2015 11 /5/2015 20 19 20 19 1 0 32 16 2015 11 /16/2015 12 12 32 3 2015 12/3/2015 16 11 12 12 1 1 32 15 2015 12/1512015 17 14 32 6 2016 1/6/2016 10 7 7 7 0 0 32 20 2016 1 /20/2016 9 5 32 2 2016 2/2/2016 13 12 13 12 1 0 32 18 2016 2/18/2016 10 8 32 1 2016 3/1 /2016 13 13 15 13 2 0 32 15 2016 3/15/2016 18 18 32 4 2016 4/4/2016 14 17 17 16 0 -1 32 18 2016 4/18/2016 14 14 32 3 2016 5/3/2016 22 22 22 22 0 0 .32 17 2016 5/17/2016 19 18 32 2 2016 6/2/2016 24 24 24 24 0 0 32 8 2016 6/8/2016 24 26 26 25 0 -1 32 15 2016 6/15/2016 25 27 28 26 1 -1 32 22 2016 6/22/2016 24 24 25 24 1 0 32 29 2016 6/29/2016 25 24 25 24 1 0 32 5 2016 7/5/2016 27 29 29 28 0 -1 32 12 2016 7/12/2016 26 28 28 26 0 -2 32 20 2016 7/20/2016 27 26 26 26 0 0 32 Page 39 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Temperature NCO024244 28 2016 7/28/2016 28 27 28 27 1 0 32 4 2016 8/4/2016 27 25 26 26 1 1 32 10 2016 8/10/2016 27 28 28 27 0 -1 32 17 2016 8/17/2016 28 27 27 27 0 0 32 24 2016 8/24/2016 25 25 25 24 0 -1 32 30 2016 8/30/2016 26 26 26 25 0 -1 32 6 2016 9/6/2016 23 25 25 23 0 -2 32 13 2016 9/13/2016 25 25 26 25 1 0 32 22 2016 9/22/2016 25 23 23 23 0 0 32 28 2016 9/28/2016 24 25 25 25 0 0 32 3 2016 10/3/2016 21 21 22 21 1 0 32 18 2016 10/18/2016 20 19 32 2 2016 11/2/2016 19 19 18 17 -1 -2 32 16 2016 11 /16/2016 14 9 11 2 32 1 2016 12/l /2016 18 14 15 14 1 0 32 14 2016 12/14/2016 12 8 9 1 32 5 2017 1 /5/2017 13 8 9 9 1 1 32 18 2017 1 /18/2017 15 13 14 1 32 2 2017 2/2/2017 13 11 12 10 1 -1 32 14 2017 2/14/2017 13 10 10 0 32 1 2017 3/l/2017 17 17 18 17 1 0 32 20 2017 3/20/2017 12 11 32 3 2017 4/3/2017 18 18 19 18 1 0 32 17 2017 4/17/2017 20 19 19 0 32 3 2017 5/3/2017 21 21 23 23 2 2 32 15 2017 5/15/2017 20 21 21 0 32 8 2017 6/8/2017 22 21 24 22 1 32 14 2017 6/14/2017 24 24 24 26 0 2 32 21 2017 6/21/2017 25 25 25 25 0 0 32 27 2017 6/27/2017 24 25 24 -1 32 28 2017 6/28/2017 23 26 32 5 2017 7/5/2017 26 27 27 27 0 0 32 11 2017 7/11/2017 26 29 30 28 1 -1 32 25 2017 7/25/2017 27 28 28 28 0 0 32 1 2017 8/l/2017 24 25 26 25 1 0 32 9 2017 8/9/2017 25 23 24 24 1 1 32 15 2017 8/15/2017 27 26 26 26 0 0 32 23 2017 8/23/2017 27 29 29 27 0 -2 32 30 2017 8/30/2017 23 24 24 23 0 -1 32 5 2017 9/5/2017 23 24 25 24 1 0 32 13 2017 9/13/2017 22 22 22 21 0 -1 32 19 2017 9/19/2017 23 24 25 23 1 -1 32 26 2017 9/26/2017 24 25 25 23 0 -2 32 5 2017 10/5/2017 20 20 22 19 2 -1 32 17 2017 10/17/2017 19 16 18 2 32 1 2017 11 /l /2017 15 14 17 13 -1 32 14 2017 11 /14/2017 14 10 12 2 32 4 2017 12/4/2017 13 11 13 11 2 0 32 19 2017 12/19/2017 11 8 10 2 32 9 2018 1 /9/2018 5 4 7 4 0 32 22 2018 1 /22/2018 8 6 8 2 32 6 2018 2/6/2018 10 8 9 7 1 -1 32 20 2018 2/20/2018 14 13 14 1 32 Page 40 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Temperature NCO024244 Statistic Effluent Upstream Dnstream Dnstream U-D1 Diff U-D2 Diff DI N 105 104 89 78 88 78 Mean 20.0 19.2 21.1 21.2 0.9 (0.2) SD 6.1 7.2 6.5 6.2 0.9 0.9 Min 5.0 4.0 7.0 4.0 (1.0) (2.0) Max - _ 28.0 _ ^ _ 29.0_ 30.0 28.0 3.0 2.5 Long Creek WWTP - Instream Temperatures Effluent Upstream Dnstream D1 ♦ Dnstream D2 Std 35 30 u 25 w 20 NOD aa, 15 10 5 ♦ ® __ !! 0 'y4\�016 'l1\"� ,�0\��y� �y1\��1� \tit\�01t'\~O1� 3\�°\T01� O\ 1 ' Anova: Single Factor SUMMARY 3ros -YE-- - Effluent Upstream Dnstream D1 Dnstream D2 ANOVA of Variation Between Groups Within Groups Total Count 105 104 89 78 Sum_ Average Variance 2095 19.952381 36.815018 1995 19.182692 52.364358 1882 21.146067 42.603422 1656.5 21.237179 38.400808 df MS F P-value F crit 274.68677 3 91.562257 2.1384114 0.0949714 2.628903 15928.254 372 42.817887 16202.941 375 Page 41 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Instream Conductivity NCO024244 00094 - Conductivity (umhos/cmil Month Day Year Date Upstream D1 D2 1 6 2015 1/6/2015 203 234 218 2 4 2015 2/4/2015 168.9 227 226 3 2 2015 3/2/2015 154 163.6 158.4 4 1 2015 4/l /2015 161.7 227 201 5 4 2015 5/4/2015 149.3 227 192.3 6 2 2015 6/2/2015 134.8 258 285 6 11 2015 6/11/2015 155.6 329 263 6 16 2015 6/16/2015 177.3 377 359 6 23 2015 6/23/2015 141.5 356 267 6 29 2015 6/29/2015 155 396 425 7 7 2015 7/7/2015 128.7 297 236 7 14 2015 7/14/2015 72.3 220 297 7 22 2015 7/22/2015 130.3 328 247 7 29 2015 7/29/2015 107.3 274 295 8 5 2015 8/5/2015 167.5 421 399 8 12 2015 8/12/2015 145.1 448 407 8 19 2015 8/19/2015 76.5 226 467 8 26 2015 8/26/2015 148.2 435 425 9 2 2015 9/2/2015 160.5 456 442 9 8 2015 9/8/2015 107.7 433 304 9 16 2015 9/16/2015 162.5 501 482 9 23 2015 9/23/2015 190 537 522 9 30 2015 9/30/2015 152 436 364 10 7 2015 10/7/2015 168 243 211 11 5 2015 11 /5/2015 145.1 166.7 152.2 12 3 2015 12/3/2015 185.9 222 199 1 6 2016 1 /6/2016 149.7 165.4 221 2 2 2016 2/2/2016 159.9 192.4 182.5 3 1 2016 3/l /2016 124.7 162.7 165.8 4 4 2016 4/4/2016 145.2 186 167.3 5 3 2016 5/3/2016 169.2 224 213 6 2 2016 6/2/2016 186.3 259 253 6 8 2016 6/8/2016 189.7 250 255 6 15 2016 6/15/2016 216 324 307 6 22 2016 6/22/2016 220 314 301 6 29 2016 6/29/2016 198 363 362 7 5 2016 7/5/2016 184.8 352 286 7 12 2016 7/12/2016 212 236 113 7 20 2016 7/20/2016 225 293 276 7 28 2016 7/28/2016 232 380 329 8 4 2016 8/4/2016 152.9 315 182.6 8 10 2016 8/10/2016 286 314 298 8 17 2016 8/17/2016 243 370 344 8 24 2016 8/24/2016 253 382 384 8 30 2016 8/30/2016 211 361 224 9 6 2016 9/6/2016 256 323 253 9 13 2016 9/13/2016 252 406 389 9 22 2016 9/22/2016 269 405 382 9 28 2016 9/28/2016 320 316 281 10 3 2016 10/3/2016 307 321 .285 11 2 2016 11/2/2016 237 353 335 12 1 2016 12/l/2016 268 332 354 1 5 2017 1 /5/2017 212 217 201 Page 1 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Instream Conductivity NCO024244 2 2 2017 2/2/2017 161 223 199 3 1 2017 3/l /2017 206 275 281 4 3 2017 4/3/2017 232 276 258 5 3 2017 5/3/2017 134.1 177.8 162 6 8 2017 6/8/2017 135.2 174.5 154.4 6 14 2017 6/14/2017 137.4 181.2 181 6 21 2017 6/21 /2017 167.6 183.1 146.4 6 27 2017 6/27/2017 197.7 251 219 7 5 2017 7/5/2017 204 227 214 7 11 2017 7/11/2017 215 254 235 7 18 2017 7/18/2017 214 292 235 7 25 2017 7/25/2017 223 358 324 8 1 2017 8/l /2017 239 436 417 8 9 2017 8/9/2017 116.1 297 364 8 15 2017 8/15/2017 157.9 300 333 8 23 2017 8/23/2017 154.9 436 239 8 30 2017 8/30/2017 177 353 284 9 5 2017 9/5/2017 176 261 217 9 13 2017 9/13/2017 152 208 161 9 19 2017 9/19/2017 177 285 238 9 26 2017 9/26/2017 190 380 392 10 5 2017 10/5/2017 204 380 356 11 1 2017 11 /l /2017 213 366 331 12 4 2017 12/4/2017 338 361 367 1 9 2018 1 /9/2018 368 381 359 2 6 2018 2/6/2018 158 168 164 600 500 u 400 o 300 L E 200 100 0 ,yb `o\yO\,y0 Statistic Upstream Dnstream Dnstream D1 D2 N 79 79 T 79 Mean 187.0 304.3 281.3 SD 55.2 89.4 90.5 Min 72.3 162.7 113.0 Max 368.0 537.0 522.0 Long Creek WWTP - Instream Conductivity Upstream D1 D2 O,yA oyh cj 5V 'ON cjA 0§1 -Ox titi���\� 1�1y\ry 4", ��1�\� .10, 0\1,P Page 2 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Instream Conductivity NCO024244 Anova: Single Factor SUMMARY Groups _Count Average Variance Upstream 79 _Sum 14776 187.038 3043.827 D1 79 24039.4 304.2962 7998.668 D2 79 22218.9 281.2519 8194.181 ANOVA Source of Variation SS df MS F P-value F crit Between Groups 609795.6 2 304897.8 47.54945 4.69E-18 3.034414 Within Groups 1500461 234 6412.225 Total 2110256 236 Differences detected among sites. t-Test: Paired Two Sample for Means Upstream D1 Mean 187.038 304.2962 Variance 3043.827 7998.6675 Observations 79 79 Pearson Correlation 0.290284 Hypothesized Mean Di 0 df 78 t Stat -11.5249 P(T<=t) one -tail 8.12E-19 t Critical one -tail 1.664625 P(T<=t) two -tail 1.62E-18 t Critical two -tail 1.990847 t-Test: Paired Two Sample for Means r D1 D2 Mean 304.2962 281.2519 Variance 7998.668 8194.1812 Observations 79 79 Pearson Correlation 0.828971 Hypothesized Mean Di 0 df 78 t Stat 3.891382 P(T<=t) one -tail 0.000104 t Critical one -tail 1.664625 P(T<=t) two -tail 0.000209 t Critical two -tail 1.990847 t-Test: Paired Two Sample for Means Upstream �D2 ....._. _... _ Mean 187,038 281.2519 Variance 3043.827 8194.181 Observations 79 79 Pearson Correlation 0.198995 Hypothesized Mean Di 0 df 78 t Stat-8.7066 P(T<=t) one -tail 2E-13 t Critical one -tail 1.664625 P(T<=t) two -tail 4E-13 t Critical two -tail 1.990847 Page 3 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Color NCO024244 Month Day Year Date Effluent 1 6 2015 1/6/2015 1 7 2015 1/7/2015 27.9 1 21 2015 1/21/2015 1 22 2015 1 /22/2015 40.5 2 4 2015 2/4/2015 2 5 2015 2/5/2015 42.7 2 18 2015 2/18/2015 2 19 2015 2/19/2015 33.2 3 2 2015 3/2/2015 26.3 3 17 2015 3/17/2015 3 18 2015 3/18/2015 40.5 4 1 2015 4/1 /2015 4 2 2015 4/2/2015 34.51 4 21 2015 4/21/2015 4 22 2015 4/22/2015 46.39 5 4 2015 5/4/2015 5 5 2015 5/5/2015 46.81 5 19 2016 5/19/2015 5 20 2015 5/20/2015 68.68 6 2 2015 6/2/2015 6 3 2015 6/3/2015 66.6 6 16 2015 6/16/2015 6 17 2015 6/17/2015 78.6 7 7 2015 7/7/2015 7 8 2015 7/8/2015 59.84 7 22 2015 7/22/2015 7 23 2015 7/23/2015 78.81 8 5 2015 8/5/2015 8 6 2015 8/6/2015 100.29 8 19 2015 8/19/2015 8 20 2015 8/20/2015 67.96 9 2 2015 9/2/2015 9 3 2015 9/3/2015 103.47 9 16 2015 9/16/2615 9 17 2015 9/17/2015 74.76 10 7 2015 10/7/2015 10 8 2015 10/8/2015 63.5 10 20 2015 10/20/2015 10 21 2015 10/21 /2015 112 11 5 2015 11 /5/2015 155.71 11 16 2015 11 /16/2015 27.36 12 3 2015 12/3/2015 12 4 2015 12/4/2015 33.7 12 15 2016 12/15/2016 12 16 2016 12/16/2016 49.3 1 6 2016 1/6/2016 1 7 2016 1 /7/2016 20.25 1 20 2016 1 /20/2016 1 21 2016 1/21/2016 154 2 2 2016 2/2/2016 2 3 2016 2/3/2016 110.61 2 18 2016 2/18/2016 2 19 2016 2/19/2016 57.52 Upstream Dnstream (D3) 41.8 32.07 36.63 34.16 27.14 35.42 17.44 33.39 41.01 35.69 30.81 23.02 34.1 34.66 60.34 51.7 30.17 35.52 41.8 51.38 47.1 62.38 41.29 66.85 47.65 53.23 41.44 60.93 33.69 97.64 45.53 52.96 27.11 93.59 32.59 69.38 61.94 49.82 25.2 89.6 138 49.5 142.1 39.8 21.22 31.15 25.2 27.11 27.03 25.13 56.8 64.98 38.1 66.49 Page 9 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Color NCO024244 3 1 2016 3/1 /2016 53.65 26.8 45.3 3 15 2016 3/15/2016 47.76 26.64 24.3 4 4 2016 4/4/2016 30.07 32.7 4 5 2016 4/5/2016 44.7 4 18 2016 4/18/2016 20 34.7 4 19 2016 4/19/2016 36.5 5 3 2016 5/3/2016 36.31 49.84 5 4 2016 5/4/2016 70 5 17 2016 5/17/2016 34.34 45.06 5 18 2016 5/18/2016 58.4 6 2 2016 6/2/2016 54.02 35.38 38.13 6 15 2016 6/15/2016 82.06 38.96 78.36 7 5 2016 7/5/2016 20 43.82 7 6 2016 7/6/2016 65.2 7 20 2016 7/20/2016 20 24.28 7 21 2016 7/21 /2016 58.7 8 4 2016 8/4/2016 80.97 45.45 54.79 8 17 2016 8/17/2016 26.59 43.19 8 18 2016 8/18/2016 56.5 9 6 2016 9/6/2016 31.1 35.16 9 12 2016 9/12/2016 48.1 9 22 2016 9/22/2016 22.56 61.28 9 23 2016 9/23/2016 66.9 10 3 2016 10/3/2016 20 32.24 10 4 2016 10/4/2016 35.23 10 18 2016 10/18/2016 41.08 39.5 10 19 2016 10/19/2016 45.17 11 2 2016 11 /212016 22.43 53.82 11 3 2016 11 /3/2016 67.57 11 16 2016 11 /16/2016 20 20 11 17 2016 11/17/2016 30.08 12 1 2016 12/1/2016 32.4 35.31 12 2 2016 12/2/2016 47.74 12 14 2016 12/14/2016 20.73 24.5 12 15 2016 12/15/2016 42.13 1 5 2017 1/5/2017 54.34 47.01 1 6 2017 1 /6/2017 26.22 1 18 2017 1 /18/2017 20 20 1 19 2017 1 /19/2017 26.65 2 2 2017 2/2/2017 37.88 32.91 2 3 2017 2/3/2017 29.05 2 14 2017 2/14/2017 20 20 2 15 2017 2/15/2017 22.56 3 1 2017 3/1/2017 20 31.38 3 2 2017 3/2/2017 55.75 3 20 2017 3/20/2017 26.31 20.84 3 21 2017 3/21 /2017 37.87 4 3 2017 4/3/2017 20 20 4 4 2017 4/4/2017 35.81 4 17 2017 4/17/2017 20.73 35.09 4 18 2017 4/18/2017 36.6 5 3 2017 5/3/2017 35.16 39.16 5 4 2017 5/4/2017 36.43 5 15 2017 5/15/2017 34.37 37.47 5 16 2017 5/16/2017 35.98 Page 10 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Color NCO024244 6 8 2017 6/8/2017 71.44 51.99 6 9 2017 6/9/2017 36.31 6 21 2017 6/21 /2017 39.42 37.17 6 22 2017 6/22/2017 28.01 7 5 2017 7/5/2017 33.44 24.68 7 6 2017 7/6/2017 30.37 7 18 2017 7/18/2017 28.81 34.96 7 19 2017 7/19/2017 48.84 8 1 2017 8/1/2017 28.33 63.1 8 2 2017 8/2/2017 50.49 8 15 2017 8/15/2017 27.68 36.36 8 16 2017 8/16/2017 49.58 9 5 2017 9/5/2017 34.29 31.32 9 6 2017 9/6/2017 45.06 9 19 2017 9/19/2017 45 48 9 20 2017 9/20/2017 45 10 5 2017 10/5/2017 26.47 43.73 10 6 2017 10/6/2017 45.36 10 17 2017 10/17/2017 42.01 49.67 10 18 2017 10/18/2017 40.07 11 1 2017 11/1/2017 49.6 39.97 11 2 2017 11 /2/2017 42.34 11 14 2017 11/14/2017 33.82 44.5 11 15 2017 11 /15/2017 49.17 12 4 2017 12/4/2017 25.26 38.12 12 5 2017 12/5/2017 56.64 12 19 2017 12/19/2017 20.84 23.42 12 20 2017 12/20/2017 31.29 1 9 2018 1 /9/2018 20 35.24 1 10 2018 1 /10/2018 49.2 1 22 2018 1 /22/2018 32.92 41.5 1 23 2018 1 /23/2018 37.13 2 6 2018 2/6/2018 51.48 38.94 2 7 2018 2/7/2018 21.68 2 20 2018 2/20/2018 35.75 38.79 2 21 2018 2/21 /2018 61.43 Statistic Effluent U stream D3 N 44 44 44 Mean 45.9 31.9 38.7 SD 14.8 11.3 12.5 Min 21.7 20.0 20.0 Max 82.1 71.4 78.4 Page 11 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Color NC0024244 Long Creek WWTP - Instream Color Effluent Upstream A, Dnstream (D3) 180 160 140 120 g 100 a 8060 •a��'! 4X 0 20�1�F�� i ! 0 -b O,yR O,yR D.yh �.yro oye oyA oyA O,y y�\ry,`K 1�1y`~ 1`�4V �\1��1. �\b�ti 0�~�V R�yO`� yoo,'1. Anova: Single Factor SUMMARY Groups Count Sum Average Variance Effluent 76 4024.04 52.95 688.69 Upstream 75 2719.42 36.26 428.53 Dnstream ( 75 3209.15 42.79 281.57 ANOVA Source of Variation SS df MS F P-value _F crit Between Groups 10688.96 2 5344.4782 11.43782 1.87E-05 3.036339 Within Groups 104199.8 223 467.26365 Total 114888.7 225 r t-Test: Two -Sample Assuming Unequal Variances Upstream Dnstream (D3) Mean 36.25893 42.78866667 Variance 428.5349 281.573682 Observations 75 75 Hypothesized Mean Di 0 df 142 t Stat -2.12209 P(T<=t) one -tail 0.017783 t Critical one -tail 1.655655 P(T<=t) two -tail 0.035566 t Critical two -tail 1.976811 t-Test: Two -Sample Assuming Unequal Variai Effluent astr+eam ID: _ Mean 52.94789 42.78867 Variance 688.6901 281.5737 Observations 76 75 Hypothesized Mean Di 0 df 128 t Stat 2.837814 P(T<=t) one -tail 0.002642 t Critical one -tail 1.656845 P(T<=t) two -tail 0.005284 t Critical two -tail 1.978671 Page 12 G.B. Perlmutter, rev. 4/17/2018 Albermarle / Long Creek WWTP Instream Copper NCO02424 01042 - Copper, Total (as Cu) 001 001A Month Day Year Date Effluent Upstream D1 D2 1 6 2015 1 /6/2015 2 16.9 11 1 20 2015 1/20/2015 57.8 2 3 2015 2/3/2015 66.2 2 4 2015 2/4/2015 2.5 12 10 3 2 2015 3/2/2015 2.8 8.9 5.8 3 10 2015 3/10/2015 52.1 4 1 2015 4/l /2015 2 19 13 4 7 2015 4/7/2015 72.3 5 4 2015 5/4/2015 3.3 32 16 5 5 2015 5/5/2015 83.5 6 2 2015 6/2/2015 5 46 41 6 4 2015 6/4/2015 88.8 7 7 2015 7/7/2015 91.4 2.9 54 21 8 4 2015 8/4/2015 83.9 8 5 2015 8/5/2015 2.8 73 43 9 1 2015 9/1 /2015 105 9 2 2015 9/2/2015 3.1 83 51 10 7 2015 10/7/2015 4 21 13 10 8 2015 10/8/2015 63 11 5 2015 11 /5/2015 5.3 12.2 9.3 11 17 2015 11/17/2015 35.1 12 3 2015 12/3/2015 2.4 12 8.5 12 8 2015 12/8/2015 52 1 6 2016 1 /6/2016 38.6 3.38 9.77 8.3 2 2 2016 2/2/2016 59.7 2.4 17 13 3 1 2016 3/1 /2016 32.6 3.6 8.6 8 4 4 2016 4/4/2016 2.8 14 10 4 7 2016 4/7/2016 64.4 5 3 2016 5/3/2016 51.7 13 9.5 6.3 6 2 2016 6/2/2016 2.8 24 14 6 9 2016 6/9/2016 67 7 5 2016 7/5/2016 2.8 44 25 7 12 2016 7/12/2016 62.8 8 2 2016 8/2/2016 47.5 8 4 2016 8/4/2016 2.7 33 11 9 6 2016 9/6/2016 2.57 30.2 13.7 9 13 2016 9/13/2016 66 10 3 2016 10/3/2016 3 22 17 10 4 2016 10/4/2016 56.4 11 1 2016 11/1/2016 62.5 11 2 2016 11 /212016 3 49 45 12 1 2016 12/1 /2016 2.5 28 28 12 8 2016 12/8/2016 72.6 1 5 2017 1 /5/2017 3.3 13 11 1 12 2017 1/12/2017 50.1 2 2 2017 2/2/2017 3.7 21 20 2 9 2017 2/9/2017 73 3 1 2017 3/1 /2017 250 225 204 3 7 2017 3/7/2017 59.6 4 3 2017 4/3/2017 11 21.5 19 4 5 2017 4/5/2017 52.8 5 3 2017 5/3/2017 39.1 3 20 13 6 8 2017 6/8/2017 29.5 5 14 9 Pagel G.B. Perlmutter, rev. 4/18/2018 Albermarle / Long Creek WWTP Instream Copper NCO02424 7 5 2017 7/5/2017 2 4 4.7 7 6 2017 7/6/2017 35.9 8 1 2017 8/1 /2017 2 62 31 8 3 2017 8/3/2017 55.1 9 5 2017 9/5/2017 2.5 75 14 9 7 2017 9/7/2017 86.8 10 3 2017 10/3/2017 55.6 10 5 2017 10/5/2017 3.3 5.8 30 11 1 2017 11/1/2017 3.3 47 19 11 2 2017 11 /2/2017 48 12 4 2017 12/4/2017 2 25 22 12 5 2017 1 2/5/2017 66 1 9 2018 1 /9/2018 32 15 43 1 11 2018 1/11/2018 59 2 6 2018 2/6/2018 5 9 8 2 7 2018 2/7/2018 33 *Data excluded from statistical analysis as outliers. Dnstream Statistic Effluent Upstream Dnstream D1 D2 N 22 _ 22 22 22 Mean 55.9 16.4 36.2 27.6 SD 13.9 52.6 46.0 40.9 Min 29.5 2.0 4.0 4.7 Max 86.8 250.0 _ _ 225.0 204.0 Long Creek WWTP - Instream Copper Effluent Upstream D1 D2 300 250 200 J o�0 150 100 50 A. A, A Page 2 G.B. Perlmutter, rev. 4/18/2018 Albermarle / Long Creek WWTP Instream Copper NC002424 Anova: Single Factor SUMMARY Groups Count Sum Average Variance Effluent 38 2276.4 59.905263 312.8681 Upstream 37 160.75 4.3445946 26.79766 D1 37 1011.37 27.334324 430.1705 D2 37 685.6 18.52973 153.1599 ANOVA Me of Variation SS df MS F P-value F crit Between Groups 62711.48 3 20903.83 90.36938 5.01E-33 2.667006 Within Groups 33540.73 145 231.3154 Total 96252.21 148 t-Test: Two -Sample Assuming Unequal Variances Upstream D2 Mean 4.344595 18.52973 Variance 26.79766 153.15992 Observations 37 37 Hypothesized Mean Di 0 df 48 t Stat -6.43205 P(T<=t) one -tail 2.73E-08 t Critical one -tail 1.677224 P(T<=t) two -tail 5.47E-08 t Critical two -tail 2.010635 t-Test: Two -Sample Assuming Unequal Variances D1 D2 Mean 27.33432 18.52973 Variance 430.1705 153.1599 Observations 37 37 Hypothesized Mean Di 0 df 59 t Stat 2.217445 P(T<=t) one -tail 0.015229 t Critical one -tail 1.671093 P(T<rt) two -tail 0.030457 t Critical two -tail 2.000995 Page 3 G.B. Perlmutter, rev. 4/18/2018 Stream Impairment Analysis Loading of Copper Long Creek WWTP Copper Copper monthly monthly average Value average value Date ug/L mg/L Jan-08 Feb-08 Mar-08 Apr-08 May-08 Jun-08 Jul-08 Aug-08 Sep-08 Oct-08 Nov-08 Dec-08 MY- - Jan-09 Feb-09 Mar-09 Apr-09 May-09 Jun-09 Jul-09 Aug-09 Sep-09 Oct-09 Nov-09 Dec-09 'AVERAGE uJan-10 Feb-10 Mar-10 Apr-10 May-10 Jun-10 Jul-10 Aug-10 Sep-10 Oct-10 Nov-10 Dec-10 AVERAGE _ Jan-11 Feb-11 Mar-11 Apr-11 May-11 Jun-11 Jul-11 113.333 0.113333333 Ibs/day= Long Creek rhgrijF,�` , WWTP AVGaverag� monthly Flow Ibs�d--- 85.000 0.085 6.30862069['r ,,4472 62.667 0.062666667 7.087096774". 66.000 0.066 7.666333333V :42199 45.000 0.045 5.867419355 ': " 2 2620 65.000 0.065 4.067 - 22047° 50.000 0.05 3.847096774 ; =` . '1.6042 70.000 0.07 4.779032258, -2.7900" 50.000 0.05 5.4473333331..;: ;,. '--2.2-715. 85.000 0.085 4.656451613'`'= :3 3610 61.333 0.061333333 4.884333333;'. "; k. 2:4984 55.500 0.0555 5.878387097 ` -2,3209 67 4(i3�„=Q 057402778 i 5 5 4873617E 5 1057 10.000 0.01 5.796774194'q' ; ` OASIS 90.000 0.09 5.260714286! ` .39487 58.200 0.0582 9.093548387;€ .:.4:413S: 56.900 0.0569 6.123333333 2.9058 49.233 0.049233333 5.606451613! " '' 2.3020 17.400 0.0174 4.486666667 f' 0,6511 35.000 0.035 4.887096774' . 3.4265, 21.500 0.0215 5.061290323` 0.9075 52.000 0.052 5.844666667 15347 101.000 0.101 4.8383870971, 4.0756 80.000 0.08 7.081333333 '.4J247 50.000 0.05 8.824193548 3.6797 51.7 0 U.51769444 6.0_75371352, j Z 6231, 60.000 0.06 8.113225806 � 4.0599 55.000 0.055 9.527142857 4.3701 55.000 0.055 7.697666667: 3.5309 60.000 0.06 5.506333333 i , . •2.7554 68.500 0.0685 5.168387097, 269526, 50.000 0.05 6.007666667, 2,5052 44.500 0.0445 4.557096774 1.6913 47.500 0.0475 4.966774194 1.9676 61.500 0.0615 4.583333333: , . 2.3508 50.000 0.05 4.214516129 1.7575 77.500 0.0775 3.981333333. 2.5738 93.667 0.093666667 4.123225806. 3*2132 ' 60 264 0 Q602_63889 -`f 5 7U30_585 _ 2; 8664: 126.500 0.1265 _ 4.692580645 4.9507 144.500 0.1445 5.813571429 -' _ 7.0061 98.333 0.098333333 7.113548387 5:8338 77.500 0.0775 6.227: .4.0248 88.667 0.088666667 5.030967742 3.7203 50.000 0.05 4.898 2.0425 57.000 0.057 4.711290323 ` 2:2397 Monthly Flow(MGD))*8.34 2008 K110": 2010 Aug-11 67.000 0.067 4.547096774FI-1 � r2 54d�1 Sep-11 113.000 0.113 4:547666667r. y 2$ Oct-11 180.000 0.18 5.163870968 ` .-2' Nov-11 75.000 0.075 5.290666667 �,�' Dec,11 121.000 0.121 5.2358064521k i 5 2837 Jan-12 134.600 0.1346 6.340322581 j 71� 74 Feb-12 47.250 0.04725 6.042413793 Mar-12 106.909 0.106909091 6.1754838711 ': 5 5062 Apr-12 101.000 0.101 4.737333333 3 9064° May-12 91.091 0.091090909 4.783870968 i - ,, r - 36343. Jun-12 137.814 0.137814286 3.744 t :!' = ... 4 3Q32. Jul-12 157.905 0.157904762 3.894516129 ` 5A289 Aug-12 149.857 0.149857143 5.0674193554 ` 6 33-33 Sep-12 93.000 0.093 5.838666667 . �... ;o,: 4:5286 Oct-12 105.739 0.10573913 5.316129032t'+ 4:6881 Nov-12 130.000 0.13 3.814333333' 4.11355, Dec-12 86.000 0.086 4.081290323 z 2:9273 111;7i 011"76779 4986314549 Jars-13 _ 97,500 0.0975 5.509032258' 4.4797 Feb-13 108.000 0.108 6.918571429 6.2317 Mar-13 67.200 0.0672 7.038064516 3.9445 Apr-13 61.900 0.0619 6.751666667; 3.4855 May-13 50.000 0.05 6.082903226 2.5366 Jun-13 65.700 0.0657 9,087 4.9791 Jul-13 25.000 0,025 10.09 2.1038 Aug-13 76.000 0.076 5,268064516 3,3391 Sep-13 138.000 0.138 4.241666667 4.8818 Oct-13 160,000 0.16 3.953548387 5.2756 Nov-13 148.000 0.148 4.243666667' 5.2380 Dec-13 118.000 0,118 6.267741935 6,1682 AVERAGE 92.942- 0.092941667 6.287660522 4.8739 Jan-14 50.100 0.0501 7.581612903 3.1679 Feb-14 110.000 0.11 8.713214286 7.9935 Mar-14 89.800 0.0898 8.832580645 6.6150 Apr-14 96.300 0.0963 9.077 7.2901 May-14 90.800 0.0908 5.470967742. 4.1430 Jun-14 102.000 0.102 4.264. 9.6239 Jul-14 104.000 0.104 4.485483871 3.18905 Aug-14 69.400 0.0694 4.932903226; 2.8551 Sep-14 111.000 0.111 4.732333333 � 4.3809 Oct-14 135.000 0.135 4.007741935 ' 4.5123 Nov-14 110.000 0.11 4.938 4S301 Dec-14 63.900 0.0639 5.789354839i 3.0853 AVERAGE 94,3 0 094358 :33 6 068432732x 4 7755: _ y r.._ _ ...__ Jan-15 57.800 0.0578 7.276451613:.., 3.5076 Feb-15 66.200 0.0662 7.257142857; 4:0067 Mar-15 52.100 0.0521 8.018064516 3.4840• Apr-15 72.300 0.0723 6.741 40647 May-15 83.500 0.0835 4.602580645, 31052 Jun-15 88.800 0.0888 4.804333333, 3.5581 2011 2012 2013 2014 Jul-15 91.400 0.0914 4.32483871: Aug-15 83.900 0.0839 4.058064516 _ ;2 839 Sep-15 105.000 0.105 4 4.308333333 r, ;:Pi 3 7728 Oct-15 63.000 0.063 7.252580645 t' 3 81D Nov-15 35.100 0.0351 10 165 �,: 2 9756 Dec 15 52 000 0 052 10 65645161 •� 4 6215 6 62?-0 �1. 8.9' Jan-16 38.600 0.0386 7.959677419 2 5624 Feb-16 59.700 0.0597 8.550689655 4.2574 Mar-16 32.600 0.0326 6.352580645 4-7272 Apr-16 64.400 0.0644 5.547666667 2.9796 May-16 51.700 0.0517 5.030322581 2:1690 Jun-16 67.000 0.067 4.159333333 23242 Jul-16 62.800 0.0628 4.341612903 r= 12739 Aug-16 47.600 0.0476 4.937419355 "` `,:. 1.9601 Sep-16 66.000 0.066 4.602666667 i 25335: Oct-16 56.400 0.0564 4.82516129 - - 2.2696 Nov-16 62.500 0.0625 3.87' _ 2.6112 Dec-16 72.600 0.0726 4.603870968. ;. 47876 (AVERAGE _, ��. 56 825 0 05fi825 5 39841_679 1-2 5584= Jan-17 50.100 0.0501 - 7.324193548-1 3.0603 Feb-17 91.500 0.0915 5.305357143 ' 4:0486 Mar-17 59.600 0.0596 5.191612903' z.5806 Apr-17 52.800 0.0528 6.322333333 17841 May-17 39.100 0.0391 6.052 1.9735 Jun-17 29.500 0.0295 5.962666667' 1.4670 ;AUfRAGE 53 767 0053766667 6026360599 Zr7023, _ *If the value was <PQL, 1/2 the PQL was used for analysis STATISTICAL ANALYSIS FOR COPPER FOR 2008 COLLECTION YEAR, 2008 303(d) listing year, and present 2015 2016 2017 Copper Yearly Averagelbs/day Year 3.1057 2008 2.6231 2009 j 2.8664 Zulu 4.3919 2011 4.6478 2012 4.8738 2013 4.7755 2014 i 3.9171 2015 D.0000 ....... __ .... ..:. ... _._._ ,. ._.._.. _._.. .._ .. _ _....... ...__.._._. 2.5584 2016 2008 2005 2010 2011 2012 2013 2014 2015 2016 2017 2.7023 2017 Year Month 20M 2009 2010 2011 2012 2013 2014 2015 2016 2017 January 5.491002 0.483451 4.059858 4.95072 7.117417877 4.47967 3.167856 3.507628 2.562411 3.060297087 February 4.472181 3.948692 4.3701 7.006109 2.381103791 6.231696 7.993503 4.006727 4.257371 4.048571089 March 3.7D4 4.413899 3.53092 5.833821 5.506296257 3.944469 6.615002 3.483961 1.727165 2.580563876 April 4.219857 2.905903 2.755369 4.024821 3.99044536 3.485521 7.29012 4.064702 2.97963 2.784052128 May 2.202042 2.302043 2.952648 3.7203 3.634298076 2.536571 4.143011 3.205191 2.168964 1.973520898 June 2.204721 0.651087 2.505197 2.042466 4.303245559 4.979213 3.623897 3.558051 2.324152 1.46699488 July 1.604239 1.426544 1.691275 2.239653 5.128788435 2.103765 3.890529 3.296721 2.273928 - AuBust 2.789999 0.90754 1.967588 2.540827 6.333304145 3.33911 2.855145 2.839533 1.960D76 - September 2.271538 2.534715 2.350938 4.285812 4.52858664 4.881819 4.38091 3.772808 2.533492 - October 3.300959 4.075567 1.757453 7.752003 4.688104662 5.275615 4.512317 3.810651 2.26964 - November 2.498434 4.724666 2.573335 3.309312 4.1355002 5.238043 4.530121 2.975641 2.017238 - December 2.720929 3.679689 3.22317 5.283662 2.927264671 6.16821 3.085298 4.62249 2.78757 - Anova: Single Factor Groups Count Sum Average Variance 2008 12 37.4799 3.123325 1.307791 2009 12 32.0537 2,671141 2.328338 2010 12 33.72775 2.810646 0.739133 2011 12 52.98951 4.415792 3.331974 2012 12 54.67426 4.556188 1.796534 2013 12 52.6636 4.388633 1.767031 2014 12 56.08771 4.673976 2.896599 2015 12 43.1431 3.595259 0.248957 2016 12 29.86164 2.48847 0.433732 ANOVA Source of Variation SS Between Groups 75.50586 Within Groups 163.351 f Ms F 8 9.438232 5.720107 99 1.65001 Total 238.8568 107 Month 2008 - 2016 January 5.491002 2.562411 February 4.472181 4.257371 March 3.704 1.727165 April 4.219957 2.97963 May 2.202042 2.168964 June 2.204721 2.324152 July 1.604239 2.273928 August 2.789999 1.960076 September 2.271538 2.533492 October 3.300959 2.26964 November 2.498434 2.017238 December 2.720929 2.78757 303(d) Listing Year Collection Year P-value F crit 5.56111E-06 2.033295 Anova: Single Factor SUMMARY Groups Count Sum Average Variance 2008 12 37.4799 3.123325 1.307791 2016 12 29.86164 2.48847 0.433732 ANOVA Source of Variation SS df Ms F P-value F crit Between Groups 2.418247 1 2.418247 2.7771641 0.109793038 4.30095 Within Groups 19.15675 22 0.870761 Total 21.575 23 0 ui rn Qf IL a0+ G W 0 7 a 0 i Ig m U U z> zUo m U" 0� O go; -0 c $ g c E O c g pg � II v c E c E c 0c E Q o° Q a a e£ a a a e Zo z z g 42 g Q Q -CO3 S W We W` W` a a W` We w E E i& a & a & a Z m m o m E m E m $ m IR'S m m m 0 � E E 0 m 0 m m z m m Q Q Q y my Q Q Q m E u Q m Q m Q II q Y £ C1 p O o u'S Q W p pul p W 0 C T m o W N i, M q N m n A r M W a N r M 10 M N 10 m m C4 a w 3 O N O C h r N co I^O fr O O1 O 7 N N ; pp 7 m � ui ri ^ W A U i J F $FFFj N cli Of C%j r to o N vi M Sri M ui O LL w 0 ( J 7 C a > C > j C c C c C c C C C z w c c c w E E E E E z m d cwy 3 3 t L LL w X X O O O O O O X X X X X N IA N N In 1D 10 O H lU Gom Cl)M m M st T M � W g QO wi o _z ' O o m � O O O tJ i r O r O O O •- O O II x CD x x x a = II II m II II L r v y v A vgo = v v O v p m a p a F CL tu CDm i �° E m .'O- '� o m 0 �° SOS. a� 2 O O * O C _A O O O O O O O c O 5 ►- F F- F- h e F c r$ o$ Gi a c z O t 0 2 Z� o 2 0 6 o O ►- O o F o O O U � U > > U U U U N U UJ U U ,q -0 _0 g �i v v 0 ,v_ II U U -6 to' N { 0 C C C c c c C C C C C C C 7 3 7 3g0) 7 7 3 7 7 7 7 7 7 W W W W W W W W . 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EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code ' NPDES yr/mo/day Inspection Type Inspector Fee Type 1 IN 2 15 1 3 NCO024244 111 12 18/02/22 117 18 UC 19 i I 201 I Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 OA — --- Reserved I 67 70 [ I 71 I I 72 L ti j 731 I 174 75I I I I I I I 180 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES permit Number) Long Creek WWTP 1040 Coble Ave Extension Albemarle NC 28002 Name(s) of Onsite Representative(sy itles(s)/Phone and Fax Number(s) Brandon Wesley Plyler/ORC/704-984-9630/ Name, Address of Responsible Official/Tide/Phone and Fax Number Entry Time/Date Permit Effective Date 10:23AM 18/02/22 1 13/01/01 Exit Time/Date Permit Expiration Date 12:20PM 18/02/22 1 14/02/28 Other Facility Data Michael Fertis,190 PO Box Albemarle NC 28002/City Contacted Manager/704-984-9410/7049849406 No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Flow Measurement Operations & Maintenance 0 Records/Reports Self -Monitoring Program Sludge Handling Disposal Facility Site Review t Effluent/Receiving Waters Laboratory I Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) I (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Roberto Schaller MRO WO//252-946-6481/ Signature of Management O A Reviewer Agency/Office/Phone and' Fax Numbers Date W. Corey Basinger MRO WQ/a704-235-2194/ EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# 1 NPDES yr/mo/day Inspection Type NCO0242" �11 12L 18/02/22 17 18 I C I Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Page# Permit: NCO024244 Inspection Date: 0212PJ2018 Owner -Facility: Long Creek WWTP Inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ® ❑ ❑ ❑ application? Is the facility as described in the permit? ❑ ❑ ❑ # Are there any special conditions for the permit? ❑ ❑ ❑ Is access to the plant site restricted to the general public? E ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? ❑ ❑ ❑ Comment: Permit expired February 28. 2014 with draft permit sent out for review. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? ■ ❑ ❑ ❑ Is all required information readily available, complete and current? ■ ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? ❑ ❑ ❑ Is the chain -of -custody complete? ❑ ❑ ❑ Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator ❑ ❑ ❑ on each shift? Is the ORC visitation log available and current? ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? ❑ 110 Is the backup operator certified at one grade less or greater than the facility classification? ❑ ❑ ❑ Is a copy of the current NPDES permit available on site? ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? ® ❑ ❑ ❑ Comment: Records were current and available for review. Facility has in house lab for rocess control and conducts field analyses under certification #5648. All other analyses are performed b Statesville Analytical Inc.. ETS Inc., Environmental 1. Operations & Maintenance Yes No NA NE Page# 3 Permit: NCO024244 Owner -Facility: Long Creek W WTP Inspection Date: 02/22/2018 Inspection Type: Compliance Evaluation Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? 0 ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable IR ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Treatment processes appeared to be well operated. Bar Screens Yes No NA NE Type of bar screen a.Manual ❑ b.Mechanical Are the bars adequately screening debris? ❑ ❑ ❑ Is the screen free of excessive debris? ❑ ❑ ❑ Is disposal of screening in compliance? ❑ ❑ ❑ Is the unit in good condition? ❑ ❑ ❑ Comment: Facilty is fitted with mechanical and manual by -Gass bar screens Grit Removal Yes No NA NE Type of grit removal a.Manual ❑ b.Mechanical Is the grit free of excessive organic matter? ❑ ❑ ❑ Is the grit free of excessive odor? ❑ ❑ ❑ # Is disposal of grit in compliance? ❑ ❑ ❑ Comment: Grit removal appeared to be operating properly at time of inspection. Influent Sarrtollntt Yes No NA NE # Is composite sampling flow proportional? Ir ❑ ❑ ❑ Is sample collected above side streams? ❑ ❑ ❑ Is proper volume collected? ❑ ❑ ❑ Is the tubing clean? ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees+ ❑ ❑ ❑ Celsius)? Is sampling performed according to the permit? �l ❑ ❑ ❑ Comment: Influent samples collected at headworks of treatment oplant. Influent._s� was noted at 3 decrees Celsius at time of inspection. Page# 4 Permit: NCO024244 Inspection Date: 02/22/2018 Pum Station -Influent Is the pump wet well free of bypass lines or structures? Is the wet well free of excessive grease? Are all pumps present? Are all pumps operable? Are float controls operable? Is SCADA telemetry available and operational? Is audible and visual alarm available and operational? Owner -Facility: Long CreekWWTP Inspection Type: Compliance Evaluation Yes .No NA NE ■❑❑❑ ■❑❑❑ 0111111 ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ N ❑ ❑ ❑ ■ ❑ Comment: Influent is pumped over to aeration basins b use of influent screw Pumps. One of the four screw gumps did not apoera to be in good condition but was re ooed as operational, Aeration Basins Yes. No NA NE Mode of operation Ext. Air Type of aeration system Surface Is the basin free of dead spots? ❑ ❑ ❑ Are surface aerators and mixers operational? ❑ ❑ ❑ Are the diffusers operational? ❑ ❑ t ❑ Is the foam the proper color for the treatment process? ❑ ❑ ❑ Does the foam cover less than 25% of the basin's surface? ❑ ❑ ❑ Is the DO level acceptable? ❑ ❑ ❑. Is the DO level acceptable?(1.0 to 3.0 mg/1) ❑ ❑ ❑ Comment: Aeration basins have the abilitv to steD feed influent. It was noted that 2 of the 4 aeration_ basins had white foam on the surface as if basins were in start-up. Secondary Clarifier Yes No NA NE Is the clarifier free of black and odorous wastewater? E❑ ❑ ❑ Is the site free of excessive buildup of solids in center well of circular clarifier? E❑ ❑ ❑ Are weirs level? ■ ❑ ❑ ❑ Is the site free of weir blockage? ■ ❑ ❑ ❑ Is the site free of evidence of short-circuiting? E❑ ❑ ❑ Is scum removal adequate? ❑ ❑ ❑ Is the site free of excessive floating sludge? ■ ❑ ❑ ❑ Is the drive unit operational? a❑ ❑ ❑ Is the return rate acceptable (low turbulence)? 2 ❑ ❑ ❑ Is the overflow clear of excessive solids/pin floc? E ❑ ❑ ❑ Page# 5 Permit: NCO024244 Inspection Date: 02/22/2018 Owner -Facility: Long Creek WWTP Inspection Type: Compliance Evaluation Secondary Clarifier Yes No NA NE Is the sludge blanket level acceptable? (Approximately Y4 of the sidewall depth) ff ❑ ❑ ❑ Comment: Secondar , clarifiers anheared to be in 000d operational condition. D_ urina_ inspection it was noted that weirs on secondary clarifiers were exceptionally clean. Pum#xs-RAS-WAS Yes No NA NE Are pumps in place? ❑ ❑ ❑ Are pumps operational? ❑ ❑ ❑ Are there adequate spare parts and supplies on site? ❑ ❑ ❑ 0 Comment: Filtration (High Rate Tertiary) Yes No NA NE Type of operation: Cross flow Is the filter media present? ■ ❑ ❑ ❑ Is the filter surface free of clogging? N ❑ ❑ ❑ Is the filter free of growth? t ❑ ❑ ❑ Is the air scour operational? ❑ ❑ ❑ a Is the scouring acceptable? ❑ ❑ ❑ Is the clear well free of excessive solids and filter media? ❑ ❑ F ❑ Comment: Review of Total Suspended Solids TSS data reported on DMR's for the year 2017 indicated that TSS is unusually high for this facility._ It is therefore recommended that tertiary_ filters be inspected for damage and repaired as necessary. It was noted at time of inspection that new replacement filter material has been received at WWTP. Disinfection -Gas Yes No NA NE Are cylinders secured adequately? ❑ ❑ ❑ Are cylinders protected from direct sunlight? ❑ ❑ ❑ Is there adequate reserve supply of disinfectant? ❑ ❑ ❑ Is the level of chlorine residual acceptable? ❑ ❑ ❑ Is the contact chamber free of growth, or sludge buildup? ❑ ❑ ❑ Is there chlorine residual prior to de -chlorination? ❑ ❑ ❑ a Does the Stationary Source have more than 2500 Ibs of Chlorine (CAS No. 7782-50-5)? ❑ ❑ ❑ If yes, then is there a Risk Management Plan on site? ❑ ❑ If yes, then what is the EPA twelve digit ID Number? (1000- -_) 1000-0012-3092 If yes, then when was the RMP last updated? 10/14/2013 Comment: Page# 6 Permit: NC0024244 Owner - Facility: Long Creek WWTP Inspection Date: 02/2212018 Inspection Type: Compliance Evaluation Disinfection -Gas Yes No NA NE De -chlorination Yes No NA NE Type of system ? Liquid Is the feed ratio proportional to chlorine amount (1 to 1)? [loom Is storage appropriate for cylinders? ❑ ❑ a ❑ # Is de -chlorination substance stored away from chlorine containers? a ❑ ❑ ❑ Are the tablets the proper size and type? ❑ ❑ ❑ Comment: Facility is using Sodium Bisulfite for dechlorination. Are tablet de -chlorinators operational? ❑ ❑ ❑ Number of tubes in use? Comment: Drying Beds Yes No NA NE Is there adequate drying bed space? ❑ ❑ 2 ❑ Is the sludge distribution on drying beds appropriate? ❑ ❑ F ❑ Are the drying beds free of vegetation? ❑ ❑ ❑ # Is the site free of dry sludge remaining in beds? ❑ ❑ ❑ Is the site free of stockpiled sludge? ir: ❑ ❑ ❑ Is the filtrate from sludge drying beds returned to the front of the plant? ❑ ❑ ❑ # Is the sludge disposed of through county landfill? ❑ ❑ ❑ ❑ # Is the sludge land applied? ❑ ❑ ❑ (Vacuum filters) Is polymer mixing adequate? ❑ ❑ ❑ Comment: Drying beds are being used to dry alum sludge from water treatment plant. Standby Power Yes No NA NE Is automatically activated standby power available? ❑ ❑ ❑ Is the generator tested by interrupting primary power source? ❑ ❑ ❑ Is the generator tested under load? ❑ ❑ ❑ Was generator tested & operational during the inspection? ❑ a ❑ ❑ Do the generator(s) have adequate capacity to operate the entire wastewater site? ❑ ❑ ❑ Is there an emergency agreement with a fuel vendor for extended run on back-up power? ❑ ❑ ❑ Is the generator fuel level monitored? ❑ ❑ ❑ Comment: Generators are maintained by Kraft Power Equipment. Page# 7 Permit: NCO024244 Inspection Date: 02l2=018 Standby- Power Effluent Sampling Is composite sampling flow proportional? Is sample collected below all treatment units? Owner - Facility: Long Creek W WTP Inspection Type: Compliance Evaluation Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type representative)? Comment: It was noted at time of inspection that effluent sampler was 1 degree Celsius. Flow Measurement - Influent # Is flow meter used for reporting? Is flow meter calibrated annually? Is the flow meter operational? (If units are separated) Does the chart recorder match the flow meter? Comment: Flaw meter was last calibrated on January 16. 2018. Yes No NA NE Yes No NA NE ❑ ❑ ❑ L-MMMMMEl Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ M ❑ ❑ ❑ ■ ❑ ❑ ❑ Page# 8 NH3/TRC WLA Calculations Facility: Albermarle - Long Creek WWTP PermitNo. NCO024244 Prepared By: Gary Perlmutter Enter Design Flow (MGD): _ 12 Enter s7Q10 (cfs): 1.6 Enter w7Q10 (cfs): 9.5 I Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/1) IWC (%) Allowable Conc. (ug/1) Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) Ammonia (Summer) Monthly Average Limit (mg NH3-NA) 1.6 s7Q10 (CFS) 1.6 12 DESIGN FLOW (MGD) 12 18.6 DESIGN FLOW (CFS) 18.6 17.0 STREAM STD (MG/L) 1.0 0 Upstream Bkgd (mg/1) 0.22 92.08 IWC (%) 92.08 18 Allowable Conc. (mg/1) 1.1 t.i1 A 7313 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) w7Q10 (CFS) 9.5 200/100ml DESIGN FLOW (MGD) 12 DESIGN FLOW (CFS) 18.6 STREAM STD (MG/L) 1.8 1.09 Upstream Bkgd (mg/l) 0.22 IWC (%) 66.19 Allowable Conc. (mg/1) 2.6 P1 A _31 OA Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia [as NH3-N] 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Facility: Albermarle - Long Creek WWTP PermitNo. NCO024244 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 16 Enter s7010 (cfs): 1.6 Enter w7Q10 (cfs): 9.5 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/l) IWC (%) Allowable Conc. (ug/1) Fecal Coliform Monthly Average Limit (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) Ammonia (Summer) Monthly Average Limit (mg NH3-N/i) 1.6 s7Q10 (CFS) 1.6 16 DESIGN FLOW (MGD) 16 24.8 DESIGN FLOW (CFS) 24.8 17.0 STREAM STD (MG/L) 1.0 0 Upstream Bkgd (mg/1) 0.22 93.94 IWC (%) 93.94 18 Allowable Conc. (mg/1) 1.1 M,4 3.3 0A Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) w7Q10 (CFS) 9.5 200/100m1 DESIGN FLOW (MGD) 16 DESIGN FLOW (CFS) 24.8 STREAM STD (MG/L) 1.8 1.06 Upstream Bkgd (mg/1) 0.22 IWC (%) 72.30 Allowable Conc. (mg/1) 2.4 tAA 1,1 ►,JA Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/l to protect for acute toxicity Ammonia (as NH3-N1 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) L �i C �d V 0 d m LV if N _0 73 m H I f C 47 O co co co � m r- O Z •� N N r pp O m 1-11 N tG r lj. r w N ��cq FX O O N r Z �~fJ• N C7 r N ate- Qp f0 N O N f} i] C�. 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IN �, b � v N v1 I of a I O a N N a>• Q I `d I z � d In 7, Q d Q z I$ a z 11p 9d lv 1 tu iu;� n!t A g a .a ry a� i.Q�, :3 i•p a� i•p i.Q, a z IU z°IU z I I I z I z I z I z I A N 00 R n O N 4 O z N d en ON ON en v eq e Oen h In 7 IOf1 M C M C -� en O V za z� = O a, t- a O � '° N hN o 0 0 0 a a a a a a a a a a 3a d o N m 00 �p o -n N O ,000 M N N V L 2 Z Z Z 2 Z Z V V V I I CL E _ c R V J d C4 V N O O 0 Z 0 u c ? rc Y Y = z z m N U) 2 f _ I V N G Ci m N 0 N REASONABLE POTENTIAL ANALYSIS Effluent Hardness "PASTE SPECl/LL� ifs' then'COPY", aMjWMUn% data Po istp ='SS. Date Data BDL=1/2DL Results 1 12/4/2014 53 53 Sid Dev. 5.3979 2 12/8/2015 62 62 Mean 51.3329 3 7/29/2016 51.25 51.25 C.V. (default) 0.6000 4 8/1/2016 46.28 46.28 n 7 5 8/2/2016 52.1 52.1 10th Per value 46.65 mgA 6 8/3/2016 46.9 46.9 Average Value 51.33 mg/I 7 8/4/2016 47.8 47.8 Max. Value 62.00 mg/I 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23, 24 25 26 27 28 29 30 31 32 33 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Upstream Hardness Date Data BDL=1/2DL Results 1 7/29/2016 70.65 70.65 Std Dev. 2 8/1/2016 62.63 62.63 Mean 3 8/2/2016 62.2 62.2 C.V. (default) 4 8/3/2016 25.6 25.6 n 5 8/4/2016 35.5 35.5 10th Per value 6 Average Value 7 Max. Value 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use 'PASTE SP" vj lt'", dun'Cdf . WA-JM em Ebtx 51.3160 0.6000 5 29.56 mg/ 51.32 rnW 70.65 mg/I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 'tilt 24244 RPA 12MGD, data 4/18/2018 REASONABLE POTENTIAL ANALYSIS 1 & Par02 U" 'PASTE SPEri4L 1 Arsenic v&W*X- mfn •C❑p,-I Msr�m4+n only y4PLs=5! a D D t3DL- / te ata -12DL 6/34014 < 5 2.5 7/1/2014 < 5 2.5 8/6/2014 < 5 2.5 9/4/2014 < 5 2.5 1017/2014 < 5 2.5 11/4/2014 < 5 2.5 12/2/2014 < 5 2.5 12/4/2014 < 5.4 2.7 1/20/2015 < 5 2.5 3/10/2015 < 5 2.5 4/7/2015 < 5 2.5 5/5/2015 < 5 2.5 6/4/2015 < 5 2.5 7/7/2015 < 5 2.5 8/4/2015 < 5 2.5 9/1/2015 < 5 2.5 10/812015 < 5 2.6 11 /17/2015 < 5 2.5 12/8/2015 < 6.8 3.4 12/8/2015 < 5 2.5 1/6/2016 < 6.8 3.4 2/2/2016 < 5 2.5 3/1/2016 < 5 2.5 4/7/2016 < 5 2.5 5/3/2016 < 5 2.5 6/9/2016 < 5 2.5 7/12/2016 < 5 2.5 8/2/2016 < 5 2.5 9/13/2016 < 6.8 3.4 10/4/2016 < 5 2.5 11/1/2016 < 5 2.5 12/8/2016 < 5 2.5 8/3/2017 < 5 2.5 9/7/2017 < 5 2.5 16/312017 < 2.5 1.25 11/212017 < 2.5 1.25 12/5/2017 < 2.5 1.25 1/11/2018 < 2.5 1.25 2/7/2018 < 2.5 1.25 Results Results Std Dev. 0.6'2t Mean 2.4141 C.V. 0.2124 n 39 Mult Factor = 1.04 Max. Value 3.4 ug/L Max. Pred Cw O DETECTS ug/L 24244 RPA-12MGD, data 2 - 4/18/2018 REASONABLE POTENTIAL ANALYSIS Beryllium Date Data BDL=1/2DL Results 1 12/8/2015 < 0.1 0.05 Std Dev. 2 12/4/2014 < 0.1 0.05 Mean 3 C.V. 4 n 5. Par04 uaa'PAS tF $pECiai va!uvb" ti,an'COPI . ,V asrmum a�fa Date Data 0.009-1 1 1/14/2014 0.0500 2 2/5/2014 0.0000 3 W412014 < 2 4I 4/2/2014 < 5 5/6/2014 < 6 Mu@ Factor = 1.00 6 6/3/2014 < 7 Max. Value 0.05 ug/L 7 7/1/2014 8 Max. Pred Ow 0 DETECTS ug/L 8 L 8/612014 < 9 9 9/4/2014 10 10 10/7/2014 < 11 11 ` 11/4/2014 < 12 12' 1212/2014 < 13 13 1/20/2015 < 14 14 2/312016 15 15 3/10/2015 < 16 16 4/7/2015 < 17 17 5/5/2015 < 18 18 6/4/2015 < 19 19 7/7/2015 < 20. 20 8/4/2015 < 21 21 9/1/2015 22 22 10/8/2015 < 23 23, 11/17/2015 < 24 24 12/8/2015 25 25 1/6/2016 < 26 26 2/212016 < 27 27 3/1/2016 < 28 28 4l7/2016 < 29 29 5/3/2016 < 30 30 6/9/2016 < 31 31 7/12/2016 < 32 32 8/2/2016 < 33 33 9/13/2016 < 34 34 10/4/2016 35 35 11/1/2016 < 36 36 12/8/2016 < 37 37 1/12/2017 38 38 2/9/2017 39 39 317/2017 40 40 4/5/2017 41 41 5/3/2017 42 42 6/8/2017 43 43 7/6/2017 44 44 8/3/2017 45 45 9/7/2017 46 46 10/3/2017 < 47 47 11/2/2017 < 48 48 12/5/2017 49 49 1/11/2018 < 50 50 2/7/2018 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Cadmium 0.36 BDL=112DL Results 1 1 Std Dev. 1.4 1.4 Mean 1 0.5 C.V. 1 0.5 n 1 0.5 1 0.5 Mult Factor = 1.1 1.1 Max. Value 1 0.5 Max. Pred Cw 1_2 1.2 1 0.5 1 0.5 1 0.5 1 0.5 0.1 0.1 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1.4 1.4 1 0.5 1 0.5 1.8 1.8 0.36 0.18 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 0.18 1.6 1.6 1 0.5 1 0.5 1.4 1.4 1.5 1.5 1 1 1.2 1.2 1.2 1.2 1.3 1.3 1.1 1.1 1.3 1.3 1.1 1.1 1 0.5 1 0.5 1.2 1.2 1 0.5 1.2 1.2 - � Urr 'PA ZTE SPECMFParO: . varuas' nn+f,'Copv- pans = % I� 0.7592 0.5533 50 1.04 1.800 ug/L 1.872 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 .17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 24244 RPA_12MGD, data - 3 4/18/2018 REASONABLE POTENTIAL ANALYSIS Total Phenolic Compounds I IJ"'PA,STE WE Valuaa" Shan `Cei . Yar}m"m data µUITAN a " Date Data BDL=112DL Results L _ v 12/8/2015 < 30 15 Std Dev. O.�bG0 12/4/2014 < 30 15 Mean 15.0000 C.V. 0.0000 n 2 Mult Factor = 1.00 Max. Value 15.0 ug/l Max. Pred Cw 0 DETECTS ug/l usa 'PASIE SPECIAL Chromium, Total Valol1 fto G°r MaxNuM data jw tbts ,� .% Date Data BDL=1/2DL 1 1/1412614 21.7 21.7 2; 2/5/2014 28 28 3 3/412014 13.6 13.6 4 4/2/2014 21.8 21.8 5 5/6/2014 20.4 20.4 6 6/312014 22.5 22.5 7 7/1/2014 25.8 25.8 8 8/6/2014 20.8 20.8 9 9/4/2014 27 27 10 10/7/2014 36.3 36.3 W 11/4/2014 45.1 45.1 12 12/2/2014 20.9 20.9 13 1/20/2015 12.5 12.5 14 2/3/2015 21.5 21.5 15 3/10/2015 13.9 13.9 16 4/7/2015 22.6 22.6 17 5/5/2015 30.7 30.7 18 6/4/2015 27.2 27.2 19 7/7/2015 36.4 36.4 20 8/4/2D15 43 43 21 9/1/2015 5&1 55.1 22 9/14/2015 40 40 23 9/29/2015 43.7 43.7 24 9/30/2015 47.4 47.4 25 10/8/2015 27 27 26 11/17/2015 20.1 20.1 27 12/8/2015 19.8 19.8 28 1/6/2016 14.9 14.9 29 2/2/2016 24.6 24.6 30 3/1/2016 13.8 13.8 31 4/7/2016 55 55 32 4/27/2016 23.5 23.5 33 5/3/2016 21.3 21.3 34 6/9/2016 26.4 26.4 35 7/12/2016 19.2 19.2 36 8/2/2016 20 20 37 9/13/2016 26.1 26.1 38 10/4/2016 22.8 22.8 39 11/1/2016 23.2 23.2 40 12/8/2016 31.1 31.1 41 1/12/2017 18.7 18.7 42 2/9/2017 21.1 21.1 43 3/7/2017 15.8 15.8 44 4/5/2017 20 20 45 5/3/2017 12.6 12.6 46 6/8/2017 15 15 47 7/6/2017 11.1 11.1 48 8/3/2017 17.4 17.4 49 9/7/2017 11.3 11.3 50 10/3/2017 12.2 12.2 51 11/2/2017 18 18 52 12/5/2017 20 20 53 1/11/2018 35 35 54 2/7/2018 8.6 8.6 55 56 57 58 Results Std Dev. 10.8905 Mean 24.5093 C.V. 0.4443 n 54 Mull Factor = 1.02 Max. Value 55.1 ug/L Max. Pred Cw 56.2 vg/L Date Da 1 1114/2014 2 2/5/2014 3 3/4/2014 44/2/2014 5 5/6/2014 6 6/3/2014 7 7/1/2014 8 8/6/2014 9 9/4/2014 10 10/7/2014 11 11/4/2014 12 12/2/2014 13 1/20/2015 14 2/312015 15 3/10/2015 16 4/7/2015 17 5/5/2015 18 6/4/2015 19 71712015, 20 8/4/2015 21, 9/1/2015 22 10/8/2015 23 11/17/2015 24 12/8/2015 25 1/6/2016 26 2/212016 27 3/1/2016 28 4/7/2016 29 5/312016 30 6/9/2016 31 7/12/2016 32 8/2/2016 33 9/13/2016 34 10/4/2016 35 11/1/2016 36 12/8/2016 37 1/12/2017 38 219/2017 39 2/15/2017 40 37/2017 41 4/5/2017 42 513/2017 43 6/8/2017 44 7/6/2017 45 8/3/2017 46 9/7/2017 47 10/3/2017 48 11 /2/2017 49 12/5/2017 50 1 /11 /2018 51 2/7/2018 52 53 54 55 56 57 58 24244 RPA_12MGD, data - 4 - 4/18/2018 REASONABLE POTENTIAL ANALYSIS Copper to BDL=1/2DL Results 50.1 50.1 Std Dev. 110 110 Mean 89.8 89.8 C.V. 96.3 96.3 n 90.8 90.8 102 102 Mult Factor= 104 104 Max. Value 69A 69.4 Max. Pred Cw 111 111 135 135 110 110 63.9 63.9 57.8 57.8 66.2 66.2 52.1 52.1 72.3 72.3 83.5 83.5 88.8 88.8 91.4 91.4 83.9 83.9 105 105 63 63 35.1 35.1 52 52 38.6 38.6 59.7 59.7 32.6 32.6 64.4 64.4 51.7 51.7 67 67 62.8 62.8 47.6 47.6 66 66 56.4 56.4 62.5 62.5 72.6 72.6 50.1 50.1 73 73 110 110 59.6 59.6 52.8 52.8 39.1 39.1 29.5 29.5 35.9 35.9 55.1 55.1 86.8 86.8 55.6 55.6 48 48 66 66 59 59 33 33 live *PASTE Spsct Valune than •COP ML in+um data paints = 56 68.9961 0.3564 51 1.02 135.00 ug/L 137.70 ug/L Cyanide Date Data BDL=1/2DL Results 1 6/3/2014 < 5 5 Sid Dev. 2 7/1/2014 < 5 5 Mean 3 8/6/2014 < 5 5 C.V. 4 9/4/2014 < 5 5 n 5 10/7/2014 < 5 5 6 11/4/2014 < 5 5 Mult Factor = 7 12/2/2014 < 5 5 Max. Value 8 12/4/2014 < 5 5 Max. Pred Cw 9 1/20/2015 < 5 5 10 2/3/2015 < 5 5 11 3/10/2015 < 5 5 12 4/7/2015 < 5 5 13 5/5/2015 < 5 5 14 6/4/2015 < 5 5 15 7/7/2015 < 5 5 16 8/4/2015 < 5 5 17 9/1/2015 < 5 5 18 10/8/2015 < 5 5 19 11/1712015 < 5 5 20 12/8/2015 < 5 5 21 12/8/2015 < 5 5 22 1/6/2016 < 5 5 23 2/2/2016 < 5 5 24 3/1/2016 < 5 5 25 4/7/2016 < 5 5 26 5/3/2016 < 5 5 27 6/9/2016 < 5 5 28 7/12/2016 < 5 5 29 8/2/2016 < 5 5 30 9/13/2016 < 5 5 31 10/4/2016 < 5 5 32 11/1/2016 < 5 5 33 12/8/2016 < 5 5 34 3/7/2017 < 5 5 35 4/5/2017 < 5 5 36 6/8/2017 < 5 5 37 1/11/2018 9 5 38 2/7/2018 < 5 5 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 We 'BASTE $P f CI VdutV thtn "COP maxinum dmta pain1a - 59 5.00 0.0000 38 Date 1 1/14/2014 < 2 2/5/2014 < 3 3/4/2014 < 4 4/2/2014 < 5 5/6/2014 < 1.00 6 6/3/2014 < 5.0 ug/L 7 7/1/2014 < 5.0 ug/L 8 8/6/2014 < 9 9/4/2014 < 10 10/7/2014 < 11 11/4/2014 < 12 12/2/2014 < 13 1 /20/2015 < 14 2/3/2015 < 15 3/10/2015 < 16 4/7/2015 < 17 5/5/2015 < 18 6/4/2015 < 19 7/7/2015 20 8/4/2015 < 21 9/1/2015 < 22 10/8/2015 < 23 11/17/2015 < 24 12/8/2015 < 25 1 /6/2016 26 2/2/2016 < 27 3/1/2016 < 28 4/7/2016 < 29 5/3/2016 < 30 6/912016 < 31 7/12/2016 < 32 8/2/2016 < 33 9/13/2016 34 10/4/2016 < 35 11 /1 /2016 < 36 12/8/2016 < 37 1/12/2017 < 38 2/9/2017 < 39 3/7/2017 < 40 4/5/2017 < 41 513/2017 < 42 6/8/2017 < 43 7/6/2017 < 44 8/3/2017 < 45 9/7/2017 < 46 10/3/2017 < 47 11 /2/2017 < 48 12/5/2017 < 49 1/11/2018 < 50 2/7/2018 < 51 52 53 54 55 56 57 58 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2Z 2.5 2.5 2.5 2.5 3.8 2.5 2.5 2.5 2.5 2.5 3.1 2.5 2.5 2.5 2.5 2.5 2.5 2.5 3.1 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 -5- 24244 RPA_12MGD, data 4/18/2018 REASONABLE POTENTIAL ANALYSIS Lead BDL=1/2DL Results 1.25 Std Dev. 1.25 Mean 1.25 C.V. 1.25 n 1.25 1.25 Mu14Factor = 1.25 Max. Value 1.25 Max. Pred Ow 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.25 3.8 1.25 1.25 1.25 1.25 1.25 3.1 1.25 1.25 1.25 1.25 1.25 1.25 1.25 3.1 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.26 1.25 1.25 1.25 1.25 1.25 1.25 Par16 usr -PASTE SPEWL vImu.I- ui.n •car'v` Molybdenum J/aalmum oat& aema = ae Date Data BDL=1/2DL Results _ 0.5064 1 6/3/2014 < 2.5 1.25 Std Dev. 1.3750 2 7/1/2014 < 5 2.5 Mean 0.3683 3 816/2014 < 2.5 1.25 C.V. 50 4 9/4/2014 < 2.5 1.25 n 5 10/712014 < 2.5 1.25 1.03 6 11/4/2014 < 2.5 1.25 Mult Factor = 3.800 ug/L 7 12/2/2014 < 2.5 1.25 Max. Value 3.914 ug/L 8 1/20/2015 < 2.5 1.25 Max. Pred Cw 9 2/3/2015 < 2.5 1.25 10 3/10/2015 < 2.5 1.25 11 4/7/2015 < 2.5 1.25 12 5/5/2015 < 2.5 1.25 13 6/4/2015 2.7 2.7 14 7/7/2015 < 2.5 1.25 15 8/4/2015 2.9 2.9 16 9/1/2015 2.8 2.8 IT 10/8/2015 < 2.5 1.25 18 11/17/2015 < 2.5 1.25 19 12/8/2015 < 2.5 1.25 20 1/6/2016 < 2.5 1.25 21 2/2/2016 < 2.5 1.25 22 3/1/2016 < 2.5 1.25 23 4/7/2016 < 2.5 1.25 24 5/3/2016 < 2.5 1.25 25 6/9/2016 < 2.5 1.25 26 7/12/2016 < 2.5 1.25 27 8/2/2016 < 2.5 1.25 28 9/13/2016 < 2.5 1.25 29 10/4/2016 < 2.5 1.25 30 11/1/2016 < 2.5 1.25 31 1/12/2017 < 2.5 1.25 32 2/9/2017 < 2.5 1.25 33 7/6/2017 < 2.5 1.25 34 8/3/2017 < 2.5 1.25 35 1/11/2018 .< 2.5 1.25 36 2/7/2018 < 2.5 1.25 37 38 39 1 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Ws 'PRSYV SPEC vai"I"V-4Et";0 *��fft�h,JA.0 ;�Mu.66 OAT20 1.4139 0.3344 36 1.08 2.9 ug/L 3.1 ug/L L Par17 8 Par18 Nickel Date Data BDL=l/2DL 1 1/14/2014 4 4 2 2/5/2014 4.5 4.5 3 3/4/2014 4.3 4.3 4 4/2/2014 7.8 7.8 5 5/612014 5.9 5.9 6 6/3/2014 3.2 3.2 7 7/1/2014 8.6 8.6 8 8/6/2014 2.8 2.8 9 9/4/2014 4 4 10 10/7/2014 5 5 11 11/4/2014 3.6 3.6 12 12/2/2014 2.6 2.6 13 1/20/2015 0.1 0.1 14 2/3/2015 0.4 DA 15 3/10/2015 3.5 3.5 16 4/7/2015 5.3 5.3 17 5/5/2015 6.5 6.5 18 6/4/2016 6.1 6.1 19 7/7/2015 5 5 20 8/4/2015 6.1 6.1 21 9/1/2015 5.2 5.2 22 10/8/2015 3.4 3.4 23 11/17/2015 < 2.5 1.25 24 12/8/2015 3.5 3.5 25 1/6/2016 < 1.8 0.9 26 2/2/2016 2.9 2.9 27 3/1/2016 2.8 2.8 28 4/7/2016 2.6 2.6 29 5/3/2016 < 2.5 1.25 30 6/9/2016 < 2.5 1.25 31 7/12/2016 < 2.5 1.25 32 8/2/2016 < 2.5 1.25 33 9/13/2016 2.3 2.3 34 10/412016 3.5 3.5 35 11/1/2016 2.6 2.6 36 12/8/2016 2.7 2.7 37 1/12/2017 < 2.5 1.25 38 2/9/2017 3 3 39 3/7/2017 < 2.5 1.25 40 4/5/2017 < 2.5 1.25 41 5/3/2017 3.5 3.5 42 6/8/2017 < 2.5 1.25 43 7/6/2017 < 2.5 1.25 44 8/3/2017 3.1 &1 45 9/7/2017 3.2 3.2 46 10/3/2017 5.3 5.3 47 11/2/2017 4.6 4.6 48 12/5/2017 3.1 3.1 49 1/11/2018 9 9 50 2/7/2018 2.6 2.6 51 52 53 54 55 56 57 58 -6- 24244 RPA 12MGD, data 4/18/2018 REASONABLE POTENTIAL ANALYSIS u.c 'PA$TE SPC0 Va+uea' man'ClDf Maxlmym dela mints s 5., Parl9 Selenium Results ' Date Data BDL=1/2DL Std Dev. 2.0504 1 1/14/2014 < 5 2.5 Mean 3.4320 2 2/5/2014 < 5 2.5 C.V. 0.5974 3 314/2014 < 5 2.5 n 50 4 4/2/2014 < 5 2.5 5 5/6/2014 < 5 2.5 Mult Factor = 1.04 6 6/3J2014 < 5 2.5 Max. Value 9.0 ug/L 7 1/1/2014 < 5 2.5 Max. Pred Cw 9.4 Ng/L 8' 802014 < 5 2.5 9 9/4/2014 < 5 2.5 W 10/7/2014 < 5 2.5 11 - 11l4l2014 < 5 2.5 12 12/2/2014 < 5 2.5 13 1/20/2015 < 0.1 0.05 14 213/2015 < 0.5 0.25 15 3/10/2015 < 5 2.5 16; 417/2015 < 5 2.5 17 5/5/2015 < 5 2.5 18 6/4/2015 < 5 2.5 19 7/7/2015 < 5 2.5 20 8/4/2015 < 5 2.5 21 9/1/2015 < 5 2.5 22 10/8/2015 < 5 2.5 23 11/17/2015 < 5 2.5 24 12/8/2015 < 5 2.5 25 1/6/2016 < 5 2.5 26 2/2/2016 < 5 2.5 27 3/1/2016 < 5 2.5 28 4/7/2016 < 5 2.5 29 5/3/2016 < 5 2.5 30 6/9/2016 < 5 2.5 31 7/12/2016 < 5 2.5 32 8/2/2016 < 5 2.5 33 9/13/2016 < 6.2 3.1 34 10/4/2016 < 5 2.5 35 11l1/2016 < 5 2.5 36 12/8/2016 < 5 2.5 37 1/12/2017 < 5 2.5 38 219/2017 < 5 2.5 39 3/7/2017 < 5 2.5 40 4/5/2017 < 5 2.5 41 5/312017 < 5 2.5 42 6/8/2017 < 5 2.5 43 7/6/2017 < 5 2.5 44 8/3/2017 < 5 2.5 45 917/2017 < 5 2.5 46 10/3/2017 < 5 2.5 47 11/2/2017 < 5 2.5 48 12/5/2017 < 5 2.5 49 1/11/2018 < 5 2.5 50 217/2018 < 5 2.5 51 52 53 54 55 56 57 58 Results SW Dev. Mean C.V. n use "PASTE aPECtALII Par20 Vl71M!' thrd 'COPY- MasRhU�uau Silver Crtsilih = 5K Date Data BDL=1/2DL 0.4757 1 1/14/2014 < 2.4180 2 5/6/2014 < 0.1967 3 61312014 < 50 4` 7/1/2014 < 5 8/6/2014 < Mult Factor = 1.01 6 9/4/2014 < Max. Value 3.1 ug/L 7 10R/2014 < Max. Pred Cw O DETECTS ug/L 8 12/2/2014 < 9 1/20/2015 < 10 3/10/2015 < 11 5/5/2015 < 12 6/4/2015 13 7/7/2015 < 14 8/4/2015 < 15 9/1/2015 < 16 10/8/2015 < 17 11/17/2015 < 18 1/6/2016 < 19 2/2/2016 < 20 3/112016 < 21 4/7/2016 < 22, 5/3/2016 < 23 6/9/2016 < 24 7/12/2016 < 25 8/2/2016 < 26 11/1/2016 < 27 12/8/2016 < 28 1/12/2017 < 29 2/9/2017 < 30 3/7/2017 < 31 5/3/2017 < 32 6/8/2017 < 33 7/6/2017 < 34 8/3/2017 < 35 9/7/2017 < 36 10/3/2017 < 37 11/2/2017 < 38 12/5/2017 < 39 1/11/2018 < 40. 2/7/2018 < 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 4 56 1 57 58 1.9 0.95 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.8 2.8 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 1,9 0.95 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 2.5 1.25 -7- 24244 RPA_12MGD, data 4/18/2018 REASONABLE POTENTIAL ANALYSIS Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Uw -PASTE SPECIAL-' "'',ql' c�rr Zinc stnrmum wts pni.+ts • 56 Date Data BDL=1/2DL Results _ 0.2=:C== 1 1/14/2014 < 50 25 Std Dev. 1.2738 2, 2/5/2014 70 70 Mean 0.2011 3 3/4/2014 < 50 25 C.V. 40 4 4/2/2014 70 70 n 5 516/2014 110 110 1.04 6; 6/3/2014 90 90 Mult Factor = 2.800 ug/L 7 7/1/2014 70 70 Max. Value 2.912 ug/L 8 8/6/2014 35 35 Max. Pred Cw 9 9/4/2014 70 70 10 10/7/2014 77 77 11: 11/4/2014 5.2 5.2 12 12/2/2014 50 50 13 1/2012015 < 50 25 14 2/3/2015 c 50 25 15 3/10/2015 58 58 16 417/2015 60 60 17 5/5/2015 79.3 79.3 18 6/4/2015 93.1 93.1 19 7/7/2015 71.6 71.6 20 8/4/2015 50 50 21 9/1/2015 < 50 25 22 10/8/2015 < 50 25 23 11/17/2015 < 50 25 24 12/8/2015 < 50 25 25 1/6/2016 29.9 29.9 26 2/2/2016 55 55 27 3/1/2016 40 40 28 4/7/2016 50 50 29 5/3/2016 53 53 30 6/9/2016 34 34 31 7/12/2016 50 50 32 8/2/2016 < 50 25 33 9/13/2016 33.9 33.9 34 10/4/2016 • 50 25 35 11/1/2016 < 50 25 36 12/8/2016 40 40 37 1/12/2017 50 50 38 2/9/2017 70 70 39 3/7/2017 72 72 40 4/5/2017 50 50 41 5/3/2017 40 40 42 6/8/2017 25 25 43 _ 7/6/2017 50 50 44 8/3/2017 41 41 45 9/7/2017 100 100 46 10/3/2017 60 60 47 11/2/2017 38 38 48 12/5/2017 70 70 49 1/11/2018 65 65 50 2/7/2018 27 27 51 52 53 54 55 56 57 58 u04 -PATE S-PECIA�.�Par22 valuet'tnrn'Cdpri Ells (2-ethyihexyQ phthalate Mnknum pip ownn = sa i Date Data BDL=1/2DL Results 23.3493 1 12/8/2015 < 1.7 0.85 Std Dev. 49.5600 2 12/4/2014 < 1.7 0.85 Mean 0.4711 3 9/18/2013 2.6 2.6 C.V. (default) 50 4 n 5 1.03 6 Mult Factor = 110.0 ug/L 7 Max. Value 113.3 ug/L 8( Max. Pred Cw 9 10; 11 12, 13. 14. 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 -8- 24244 RPA_12MGD, data 4/1812018 REASONABLE POTENTIAL ANALYSIS Um 'PASTE 5PUCAL�ar23 use "PAS Tr spEcua1 Par24 v■ruraa' thy" ^cdrv- Dichlorobromomethane va uea' darn -Copy . Maxrmum da>'a . WA11friu n data points = SE I pWnta • 58 Date Data 1 12/8/2015 < 1.4333 I 2 12/4/2014 0.6000 + 3 9/18/2013 3 4. 5 3.00 6 2.600000 Ng/L 7 7.800000 Ng/L 8' 9 10 11 12 13 14! 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 BDL=1/2DL Results 0.17 0.085 Std Dev. 2.0317 1.1 1.1 Mean 1.72. 4 4 E.V. (default) 0.6000 n 3 Mutt Factor = 3.00 Max. Value 4.000000 ug/L Max. Pred Cw 12.000000 pg/L 1 2- 3 4 5 6 7 8 9 10 11' 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 `PASTE Sc Chlorodibromomethane '•" " ' _ IAlfifnurn R Date Data BDL=1/2DL Results 12/8/2015 1.1 1.1 Std Dev. 17 12/4/2014 < 0.17 0.085 Mean 1.7283 9/18/2013 4 4 C.V. (default) 0.6000 n 3 Mult Factor = 3.00 Max. Value 4.000000 Max. Pred Cw 12.000000 -9- 24244 RPA_12MGD, data 4/1812018 REASONABLE POTENTIAL ANALYSIS Par25 res' "n 'C 4 {sprnts = 58 I - Date Data 1 BDL=1/2DL Results Std Dev. NO DATA 2 Mean NO DATA 3' C.V. NO DATA 4 n 0 5 6 Mull Factor = NIA pg/L 7 Max. Value N/A yg/L 8 Max. Pred Cw NIA 9 10 11' 12 13 14 15 16 17 18, 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 24244 RPA_12MGD, data - 10 - 4/18/2018 kk �§ ,\ /f Iƒ UP 2I ELL U- §w ! 2 _k a 0 k� C, kU u .. /Lu o %a �2 Q IL LLZ / cv 2^048 $$R 8; QCD0 R° .f)a 22 CDa0 //» �... 2 § d ` mm2� 0 &-o � kf�e r w �0 I$ I A o go .. LU E 2 � ju- z �2$�s I� ; SRC4°� , §C,C4o §§ ■�,E _ ■ ME Ell� e Lna t°\2 2IZ;I$I Iq Rl§R IkI© §)f) a-ff/ / k �j(k k§§k/ `mlt� j\k\/ §/ e■kk §$I§e §k�5) 21{2a /)=J7 ) ,13 I[§22 ■§|�§ 2 o 21 §� k ��§§ =7 -=//r m R@\ Permit No. NCO024244 NPDES Im lementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Onality Standards/An»Atir T.ifa Prntartinn Parameter Acute FW,'µg/1 (Dissolved) Chronic-FW, µg/l Acute SW, µg11 (Dissolved) (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Be Ilium 65 6.5 --- --- Cadmium Calculation'.-. " Calculation . 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Co er Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 18.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation:. Calculation. 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 213.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[In hardness](0.041838)) e^{0.9151 [In hardness]-3.1485) Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)) a"{0.9151[In hardness]-3.6236) Cadmium, Chronic WER*{1.101672-[In h4rdness](0.041838)) a^{0:7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.7256) Chromium III,. Chronic WER*0.860 e^{0.8190[In hardness]+0.6848) Copper, Acute WER*0.960 e^{0.9422[In hardness]-1.700) Copper, Chronic WER*0.960 - eNO.8545[ln hardness]-1.702) Lead, Acute WER*{1.46203-[In hardness](0.145712)) • e^{1.213[ln hardness]-1.460) Lead, Chronic WER* I 1.46203-[In hardness](0.145712)) • e^{1.273[In hardness]4.7051 Nickel, Acute WER*0.998 - e^{0.8460[In hardness]+2.255) Page 1 of 4 Permit No. NC0024244 General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/W BELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs)1.11 Effluent hardness and upstream hardness, site -specific data is preferred Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. Page 2 of 4 Permit No. NCO024244 If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = Permitted Flow. cfs *Av . Effluent Hardness m rI + (s7Q 10 cfs *Av . U stream Hardness m (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator.. Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation; Sdiss= 1. Ctotal 1 + { [W.[sst1+e>] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Ow) (Cwgs) — (s7010) (Cb) Qv, Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) Page 3 of 4 Permit No. NC0024244 s7Q10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: IQ 10 = used in the equation to protect aquatic life from acute toxicity QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Average Effluent Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] Average Upstream Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 7Q10 summer (cfs) 1 Q 10 (cfs) Permitted Flow (MGD) Date: Permit Writer: & .A (L I If(",, 11- -'-I ' �� Value Comments (Data Source) 51.33 PPAs, DMRs, and Samples from July and August 2016 from Statesville Analytical services 51.32 Samples from July and August 2016 from Statesville Analytical services 1.6 BIMS and projectfiles 1.34 RPA, calculations mem2/4/2010 12/16 BIMS and project files Page 4 of 4 Long Creek WWTP/ NCO024244 Mercury Data Statistics (Method 1631 E) 2014 2015 2016 2017 2018 # of Samples 17 14 12 12 2 Annual Average, ng/L 10.2 7.8 4.8 4.6 6.8 Maximum Value, ng/L 26.60 14.00 11.00 7.20 8.90 TBEL, ng/L 47 WQBEL, ng/L r 1 r1 G 9 13.0 4/18/18 WQS = 12 ng/L Facility Name Long Creek WWTP/ NC0024244 /Permit No.: Total Mercury 1631E PQL = 0.5 ng/L Date Modifier Data Entry Value 1/22/14 6.78 6.78 2/6/14 8.92 8.92 3/5/14 5.83 5.83 4/2/14 7.81 7.81 5/1/14 5.33 5.33 6/3/14 11.4 11.4 7/1/14 13 13 7/21/14 22 22 7/25/14 12 12 7/31/14 11.4 11.4 8/6/14 4.94 4.94 9/4/14 8.45 8.45 10/7/14 10 10 11/4/14 26.6 26.6 11/21/14 4.7 4.7 11/30/14 6.4 6.4 12/15/14 7.4 7.4 1/20/15 1.25 1.25 2/10/15 6.2 6.2 3/9/15 4.8 4.8 4/6/15 11.6 11.6 5/5/15 13 13 5/29/15 5.2 5.2 6/4/15 6.2 6.2 7/1/15 8.5 8.5 8/4/15 12 12 9/1/15 14 14 9/30/15 6.4 6.4 10/8/15 6.8 6.8 11/17/15 5.4 5.4 12/8/15 8.2 8.2 1/7/16 4.9 4.9 2/2/16 5.5 5.5 3/1/16 4.6 4.6 4/6/16 6 6 5/3/16 4.3 4.3 6/9/16 1 0.5 7/7/16 5.4 5.4 8/2/16 5.2 5.2 9/8/16 3.2 3.2 10/4/16 11 11 11/1/16 3.5 3.5 12/12/16 3.8 3.8 1/19/17 5.2 5.2 2/10/17 5.4 5.4 MERCURY WQBEL/TBEL EVALUATION No Limit Required MMP Required 7Q10s = 1.600 cfs WQBEL = Permitted Flow = 12.000 V:2013-6 13.03 ng/L 47 ne/L 10.2 ng/L - Annual Average for 2014 7.8 ng/L - Annual Average for 2015 4.8 ng/L - Annual Average for 2016 3/7/17 5.9 5.9 4/5/17 3.5 3.5 5/3/17 2.8 2.8 6/8/17 3 3 7/6/17 4.28 4.28 8/3/17 2.4 2.4 9/7/17 2.9 2.9 10/3/17 5 6 11/2/17 7.2 7.2 12/12/17 6.1 6.1 4.6 1/11/18 8.9 8.9 2/7/18 4.7 4.7 6.8 ng/L - Annual Average for 2017 ng/L - Annual Average for 2018