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HomeMy WebLinkAboutNC0086606_Fact Sheet_20181029FACT SHEET FOR COMPLEXEXPEDITED - PERMIT RENEWAL NPDES Permit NCO086606 Table 1-- Basic Information S Permit Writer / Date Permit Number Permittee Permittee's Consultant / Contact Facility Regional Office / Contact Basin Name / Subbasin Number Receiving Stream / Verified Stream Classification in Permit / Verified Does permit need Daily Max NH3 limits? Does permit need TRC limits/lan a e? Does permit have toxicity testing? Does permit have Special Conditions? _ Does i)ermit have instream monitorin,=?_ Is the stream impaired [303(d) listed]? Any obvious compliance concerns? mods since last Current expiration date New expiration date it? BIMS Downloads and Review Summar, Joe R. Corporon, L.G. — revised 290ct2018 ioe.co orona_ncdenr. ov 919-707-3617 NCO086606 Carolina Water Service [CWS], Inc. PO Box 240908 Charlotte, NC 28224 Steve Bond, El (LandDesign) 707— 333-0325 CWS The Harbour — Well #4, Class 1 1540 Bradlev School Road MRO / [Staff Report (?)] Catawba / 03-08-32 UT Lake Norman (Catawba River) [segment 11-(75) / Yes (see BIMS Tracking Sheet). WS-IV; B; CA No Yes, limit 17 L — updated TRC footnote Yes — has WET test TGP3B in accord w/ IE WTP Yes, see Section A. 3. re -opener clause No, {removed last renewal at Permittee's No Yes — consistently fails WET test [sodium ion -exchange (IE) treatment]. Zero -flow conditions at outfall (no credit for dilution). RPA — concludes metal limits equal to standards; to receive dilution credit, the Permittee should consider outfall extension into the lake; employ an effluent diffuser w/ approved model — OR consider changing treatment technology. Renewal adds a "compliance period" of 5 years to establish possible dilution and soluble -metals treatment. No _ March 31, 2018 March 31, 2023 1. For renewal: Updated effluent page in accordance with Ion -Exchange (IE) WTP technology guidelines (2009); updated permit template, facility location, facility description, and added 8 Digit HUC to the map; Added parameter monitoring and limits based on zero flow conditions (IWC=100%) using a Reasonable Potential Analysis (RPA). The maximum monthly -average flow rate for treated wastewater effluent occurred during Jun2016 at 0.0165 MGD; this figure was used in the RPA analysis, per WTP Strategy 2009. The Permittee reported a maximum waste effluent now of 0.200 MGD (Nov2016) assumed a reporting error [outlier not considered]. Page 11 1. Flow Monitoring — Reviewed flow data (by year) noting the monitoring frequency at 2/monthly; footnote edited to require both flow rate and flow duration, log to be kept onsite for DWR review. Based on a Permittee-corrected BIMS database, DWR has confirmed that this facility's average monthly wasteflow is less than 30,000 gpd. Therefore, a composite sampler is not required. 2. Tom- The WTP failed 18 of 18 WET tests during the past 4 years. 3. CoMpliance — BIMs records indicates a Notice of Deficiency (NOD) for low pH in Feb2017, and an NOV for failure to monitor Chloride (Jun2015. 4. CWS responded to previous Special Condition A. (3.) by providing a Discharge Alternatives Evaluation (DAE) with its application to renew. The Division concurs that a surface -water discharge is the best discharge alternative based on cost, however effluent conditions have changed for this renewal may affect future costs analyses (see Effluent Data Concerns and RPA). Table 2 — Wastewater Database (Jan2014 - Aug2018) - Compared to SWQ Standards Parameter Max Reported Average Reported Water Supply (WS) Standard Sample Count (n) Flow (MGD) 0.200 0.0044 Not limited 467 Total Chloride 13,000 mg/L 4,476 mg/L 250 mg/L 57 Total Copper 50 µg/L 17.1 µg/L 7.88 µg/L 19 Total Lead 500 µg/L 14.1 µg/L 25 µg/L 55 Total Manganese 4,100 µg/L 528 µg/L 200 µg/L 55 Salinity 103.2 ppth (?) 6.18 ppth 55 TDS 24,000 mg/L 8,143 mg/L 250 mg/L 110 TSS 31 mg/L 6.37 mg/L 110 Total Zinc 820 mg/L 118.7 µg/L 50 µg/L 20 Effluent Data Concerns — Data suggest that the current treatment system is not adequate to meet NC Surface Water Quality Standards for metals, for Total Dissolved Solids (TDS), and for Total Chlorides considering a discharge under "zero -flow receiving -stream conditions to Class WS-IV; B; CA [Water Supply; swimmable; habitat -critical area]. The Permittee is admonished to consider applying a potable -water treatment technology other than sodium ion exchange (IE). Alternative: consider extending discharge into the lake and employing an effluent diffuser. After modeling, this pre -approved diffuser may allow dilution credit to be applied to parameter limits. Self -monitoring databases contained reporting errors [now corrected by the Permittee for renewal]. Discharge Monitoring Reports (DMRs/eDMRs) reported multiple parameters of concern (POCs) with confused, inconsistent units of measure. In addition, the Permittee reported parameters as "not detected" by submitting "0" instead of reporting the required laboratory minimum detection levels (MDLs). These are permit violations. Page 12 5. Reasonable Potential Analysis (RPA) — Per WTP permitting guidance, Total Iron is no longer considered a POC, and monitoring is hereby discontinued. However, data for copper, zinc, lead, chloride, manganese, Chloride and TDS continue to show reasonable potential to exceed their respective surface water -quality standards. Considering a discharge under zero -flow conditions [7Q10/30Q2 = 0.0 cfs], each metal requires a permit limit equal to its standard. In addition, future soluble -fraction metals calculations require Total Hardness monitoring of the effluent [upstream also recommended, but not possible under zero -flow receiving -stream conditions]. 6. Revised Treatment R uired — Based on DWR/CWS discussions during pre -draft review, June 22, 2018, permit Special Condition A. (3.) details permit limits and compliance deadlines as: • compliance to metals limits begins on -or -before the expiration date of this permit. • compliance to Total Chloride limits begins on -or -before September 30, 2021. DWR may reopen this permit to incorporate new data, as warranted [see A. (3)]. Table 3 -- Parameters of Concern - Renewal Summary 2018 Characteristic DWQ Action WET Testing Continue WET testing (monitoring only) per WTP Policy Total Dissolved Solids (TDS) Monitor 2/Month; Limit = 500 mg/L; no change recommended Monitor Monthly - to protect human health through water Total Chloride consumption and fish tissue consumption; Daily Max = 250 m L compliance begins on 3 OSep2O21 Ammonia [NH3 as N] Monitoring not required; this facility does not add ammonia as a disinfectant [deleted from draft]. All Metals Based on RPA, metals limits are set equal to standards; [see permit A. (1.)] Monitor Monthly — to protect human health (HH) and aquatic life (AL) considering Water Supply WS-IV; B; CA, bathing, and consumption of fish tissue. The Permittee has one (1) permit cycle to establish See Special Condition A. (3.). compliance with permit limits for soluble metals [on or before the permit expiration date 31Mar2023]. Turbidity Monitoring Monthly no limit — lake not impaired — no changes recommended Draft Permit to Public Notice: [estimate] Permit Scheduled to Issue: [estimate] September 19, 2018 November 1, 2018 Page 13 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 4 - NC Dissolved Metals Water Qualift Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness Dependent Standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 5. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, = 1 Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} e^{0.9151 [In hardness]-3.1485) Cadmium, Acute Trout waters WER*{1.136672-[In hardness](0.041838)) a^{0.9151[ln hardness]-3.6236} Cadmium, Chronic 1 WER*{1.101672-[ln hardness](0.041838)} • e^{0.7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 a^{0.8190[ln hardness]+3.7256) Chromium III, Chronic WER*0.860 e^{0.8190[In hardness]+0.6848} Copper, Acute WER*0.960 e^{0.9422[ln hardness]-1.700} Copper, Chronic WER*0.960 a^{0.8545[ln hardness]-1.7021 Lead, Acute WER*{l.46203-[In hardness](0.145712)} • e^{1.273[ln hardness]-1.460} Lead, Chronic WER*{1.46203-[ln hardness](0.145712)) • e^{1.273[ln hardness]-4.705} Nickel, Acute WER*0.998 • e^{0.8460[ln hardness]+2.255} Page 14 Nickel, Chronic WER*0.997 • e^{0.8460[ln hardness]+0.05841 Silver, Acute WER*0.85 • e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 a^{0.8473[ln hardness]+0.8841 Zinc, Chronic WER*0.986 a^{0.8473[ln hardness]+0.884) General Information on the Reasonable Potential Analysis RPA The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge - specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case - specific translators developed in accordance with established methodology. RPA Permitting GuidanceMO BELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. To establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. Page � 5 If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow. cfs *Avg. Effluent Hardness. m,,IL x (s7410_ cfs *Avg. Upstream Hardness. mu'L) (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1 Q 10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [KPo] [SS(1+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA prosram under a 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site - specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7010 + Qw) (Cwgs) — (s7Q10)(Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) Page 16 s7Q10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: IQ 10 = used in the equation to protect aquatic life from acute toxicity QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality - Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments Data Source) Average Effluent Hardness (mg/L) Total as, CaCO3 or Ca+M 25 Assumed — no data to date Average Upstream Hardness (mg/L) Total as, CaCO3 or Ca+M 25 Assumed — no data to date 7Q 10 summer cfs 0.0 1 Q 10 cfs 0.0 Permitted Flow MGD) Not limited Permit A Date: ACf0C (0O/ (!7- Page 17 n 2 C d L o !� e co f- t a m am t N C3 f6 0 LL MINGININICIN 1111111810 a)� Z m J N� 0) +0 W W W W W W W W W !6 l6 W W A A W A W W a a a a a a a a a a a a a a a a a a a coW a a a a a >_ Ln 1 1 1 I �=• cm E 0of CD co O V O Q ci Q Q' J J •O 0' 3e _ �j o o o �O o ,� 00 > 0 o 0 0 0 0 0 =IJ1 EI E °D a= a O O 0 0 0 ci N N Y m(0D Z Z O I N t I 1 d Whe N 0 0 i l i l Na . 11 1 1 I 5 1 1�1 1 1•�I m I IL1� uOl I i�la 3 t H t y 1 q y1�1c1� 0 cID1�l7E f ~2 0 I I= 0 d a z a ; 0t a a N_ Ci _cE > 2 E a w; bl CI m1 C I C *51a (% v ~ c 3 d as N O U' =10 olo0iV = ti Z 0 li w 2 y 11 r �, Wj?i 00 G. 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O U L7 J R C :e IL U cc 0 V ♦� VZ l0 aD E N N O] X G N n am U) d m a r 3 O 10 x U 28 s REASONABLE POTENTIAL ANALYSIS H1 H2 Lino ^PASTE SPECIAL Uas PASTE SPECIA! Effluent Hardness Val use ttlen'c0Pr- Upstream Hardness Yalu"'• rh°" -c°Pr m mimurn data Maximum d611 {ral,ret = 58 points - SE Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 25 Std Dev. rd,A 1 25 25 Std Dev. N/A 2 Mean 25.0000 2 Mean 25.0000 3 C.V. 0.0000 3 C.V. 0.0000 4 n 1 4 n 1 5 10th Per value 25.00 mg/L 5 10th Per value 25.00 mg/L 6 Average Value 25.00 mg/L 6 Average Value 25.00 mg/L 7 Max. Value 25.00 mg/L 7 Max. Value 25.00 mg/L 8 8 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 86606 CWS Harbor wells Updated RPA Sep2018.xlsm, data - 1 - 9/5/2018 REASONABLE POTENTIAL ANALYSIS Par05 Chlorides Ure -PASTE SPFCiAL• vy1F°o, Tncn 'COPY- Pal M ax3mum datA pk1nS+ _ Date Data BDL=1/2DL Results 1 2014 11610 11610 Std Dev. 3379.:. 1 2 2014 7900 7900 Mean 4,638.7 2 3 2014 9900 9900 C.V. 0.7284 3 4 2014 11000 11000 n 55 4 5 2014 12000 12000 5 6 2014 9900 9900 Mult Factor = 1.0 6 7 2014 13000 13000 Max. Value 13000.0 mg/L 7 8 2014 9900 9900 Max. Pred Cw 13,130.0 mg/L 8 9 2014 7600 7600 9 10 2014 6400 6400 10 11 2014 4000 4000 11 12 2014 5900 5900 12 13 2015 550 550 13 14 2015 230 230 14 15 2015 860 860 15 16 2015 2200 2200 16 17 2015 470 470 17 18 2015 2300 2300 18 19 2015 3300 3300 19 20 2015 2900 2900 20 21 2015 1400 1400 21 22 2015 2300 2300 22 23 2015 1500 1500 23 24 2016 5700 5700 24 25 2016 8300 8300 25 26 2016 2800 2800 26 27 2016 4200 4200 27 28 2016 5800 5800 28 29 2016 6300 6300 29 30 2016 4600 4600 30 31 2016 7600 7600 31 32 2016 6300 6300 32 33 2016 6900 6900 33 34 2016 5400 5400 34 35 2016 5100 5100 35 36 2017 6200 6200 36 37 2017 4000 4000 37 38 2017 6900 6900 38 39 2017 2900 2900 39 40 2017 4900 4900 40 41 2017 0.0001 41 42 2017 ^ ^^^' 42 43 2017 1700 1700 43 44 2017 4600 4600 44 45 2017 180 180 45 46 2017 1700 1700 46 47 2017 4000 4000 47 48 2017 790 790 48 49 2018 1000 1000 49 50 2018 1200 1200 50 51 2018 1000 1000 51 52 2018 2800 2800 52 53 2018 5200 5200 53 54 2018 140 140 54 55 100 100 55 56 4800 4800 56 57 4900 4900 57 58 58 ll+o ' PAS M SF Copper Vail . U" n 1444imm s pdrW -4 Date Data BDL=1/2DL Results 2014 36 36 Std Dev. 13.441;: 2014 29 29 Mean 15.0000 2014 11 11 C.V. 0.8961 2014 38 38 n 19 2015 < 10 5 2016 < 10 5 Mult Factor = 1.57 2015 < 10 5 Max. Value 50.00 2015 12 12 Max. Fred Cw 78.50 2016 12 12 2016 10 5 2016 14 14 2016 18 18 2017 < 10 5 2017 50 50 2017 11 11 2017 14 14 2017 < 10 5 2018 < 10 5 2018 < 10 5 -2- 86606 CWS Harbor wells Updated RPA Sep2018.xlsm, data 9/5/2018 REASONABLE POTENTIAL ANALYSIS Parl4 Par21 'ECWL 0" _PAM SPECKL =QPY' Lead Valwte thtn "COPY" Zinc . raa,mum 0z2 6 points = 55 Date BDL=112DL Results Date Data BDL=112DL Results 1 2014 9 9 Std Dev. 66.9512 1 2014 670 670 Std Dev. 2 2014 < 5 2.5 Mean 13.0818 2 2014 45 45 Mean 3 2014 < 5 2.5 C.V. 5.1179 3 2014 310 310 C.V. 4 2014 < 5 2.6 n 55 4 2014 820 820 n 5 2014 < 5 2.5 5 2015 250 250 6 2014 < 5 2.5 Mult Factor = 1.05 6 2015 < 30 15 Mult Factor = ug/L 7 2014 < 5 2.5 Max. Value 500.000 ug/L 7 2015 93 93 Max. Value ug/L 8 2014 < 5 2.5 Max. Pred Cw 525.000 ug/L 8 2015 190 190 Max. Pred Cw 9 2014 < 5 2.5 9 2016 290 290 10 2014 5 5 10 2016 120 120 11 2014 < 5 2.5 11 2016 140 140 12 2014 < 5 2.5 12 2016 110 110 13 2015 < 5 2.5 13 2017 270 270 14 2015 < 5 2.5 14 2017 220 220 15 2015 5 5 15 2017 120 120 16 2015 < 5 2.5 16 2017 160 160 17 2015 < 5 2.5 17 2017 140 140 18 2015 < 5 2.5 18 2017 56 56 19 2015 < 5 2.5 19 2018 150 150 20 2015 < 5 2.5 20 2018 190 190 21 2015 < 5 2.5 21 22 2015 < 5 2.5 22 23 2016 < 5 2.5 23 24 2015 < 5 2.5 24 25 2016 < 5 2.5 25 26 2016 < 5 2.5 26 27 2016 < 5 2.5 27 28 2016 5 5 28 29 2016 500 500 29 30 2016 5 5 30 31 2016 5 5 31 32 2016 5 5 32 33 2016 5 5 33 34 2016 5 5 34 35 2016 5 5 35 36 2016 1 1 36 37 2017 5 5 37 38 2017 1 1 38 39 2017 25 25 39 40 2017 5 5 40 41 2017 5 5 41 42 2017 5 5 42 43 2017 5 5 43 44 2017 2.5 2.5 44 45 2017 5 5 45 46 2017 1 1 46 47 2017 5 5 47 48 2017 5 5 48 49 2018 5 5 49 50 2018 5 5 50 51 2018 5 5 51 52 2018 5 5 52 53 2018 5 5 53 54 2018 5 5 54 55 2018 5 5 55 f 56 56 57 I 57 58 58 Use 'PASTE SF M�xlmum i Points - a 217.9500 0.9114 20 1.55 820.0 1271.0 86606 CWS Harbor wells Updated RPA Sep2018.xlsm, data -3- 9/5/2018 REASONABLE POTENTIAL ANALYSIS Par22 Par23 Tuw. U" "PASTE WECIAL "Opy- Manganese "'Iv&2" °Tan "COPY" Iron MAXImum onto K ppin% - 69 Date Data BDL=1/2DL Results Date Data BDL=112DL Results 1 2014 1380 1380 Std Dev. 668.8 1 < 100 50 Std Dev. 2 2014 410 410 Mean 520.8 2 < 100 50 Mean 3 2014 1500 1500 C.V. 1.3 3 120 120 C.V. 4 2014 650 650 n 56 4 100 100 n 5 2014 1300 1300 5 300 300 6 2014 520 520 Mult Factor = 1.02 6 330 330 Mult Factor = ug/L 7 2014 890 890 Max. Value 4100.0 ug/L 7 r 100 50 Max. Value ug/L 8 2014 490 490 Max. Pred Cw 4182.0 ug/L 8 620 620 Max. Pred Cw 9 2014 480 480 9 540 540 10 2014 540 540 10 260 260 11 2014 750 750 11 170 170 12 2014 1300 1300 12 120 120 13 2015 100 100 13 410 410 14 2015 37 37 14 500 500 15 2015 54 54 15 100 50 16 2015 83 83 16 160 160 17 2015 70 70 17 1100 1100 18 2015 47 47 18 19 2015 230 230 19 20 2015 370 370 20 21 2015 150 150 21 22 2015 59 59 22 23 2015 4100 4100 23 24 2015 110 110 24 25 2016 1500 1500 25 26 2016 1700 1700 26 27 2016 670 670 27 28 2016 880 880 28 29 2016 1200 1200 29 30 2016 860 860 30 31 2016 480 480 31 32 2016 790 790 32 33 2016 870 870 33 34 2016 920 920 34 35 2016 310 310 35 36 2016 290 290 36 37 2017 230 230 37 38 2017 81 81 38 39 2017 420 420 39 40 2017 60 60 40 41 2017 93 93 41 42 2017 62 62 42 43 2017 140 140 43 44 2017 75 75 44 45 2017 380 380 45 46 2017 93 93 46 47 2017 40 40 47 48 2017 55 55 48 49 2018 59 59 49 50 2018 140 140 50 51 2018 100 100 51 52 2018 730 730 52 53 2018 32 32 53 54 2018 86 86 54 55 2018 68 68 55 56 2018 130 130 56 57 57 58 58 86606 CWS Harbor wells Updated RPA Sep2018.xlsm, data -4- 9/5/2018 REASONABLE POTENTIAL ANALYSIS Ulm -PASTE $PEC1 vatu"- then "COP Mgzimurn Bala pvinln - 56 290.00 0.9616 17 1.70 1100 ug/L 1870 ug/L Par24 Ulia 'PASTE SPECK TDS valuac' lnan "COP, . Maximum dala Wntx = 58 Date Data BDL=112DL Results 1 2016 540 540 Std Dev. 2 2016 820 820 Mean 5383.1373 3 2016 1600 1600 C.V. 0.5670 4 2016 2200 2200 n 51 5 2016 9000 9000 6 2016 11000 11000 Mult Factor = 1.03 7 2016 9500 9500 Max. Value 14000 mg/1 8 2016 9900 9900 Max. Pred Cw 14420 mg/L 9 2016 8900 8900 10 2016 6600 6600 11 2016 6900 6900 12 2016 7100 7100 13 2016 6100 6100 14 2016 5800 5800 15 2016 1300 1300 16 2016 3900 3900 17 2016 8000 8000 18 2016 5400 5400 19 2016 4900 4900 20 2016 6000 6000 21 2016 7500 7500 22 2016 6800 6800 23 2016 7400 7400 24 2016 920 920 25 2017 4000 4000 26 2017 2800 2800 27 2017 6500 6500 28 2017 880 880 29 2017 5700 5700 30 2017 5200 5200 31 2017 5000 5000 32 2017 3300 3300 33 2017 7500 7500 34 2017 2300 2300 35 2017 6900 6900 36 2017 5100 5100 37 2017 8200 8200 38 2017 6000 6000 39 2017 7000 7000 40 2017 6800 6800 41 2017 14000 14000 42 2017 9500 9500 43 2017 3700 3700 44 2017 3800 3800 45 2017 900 900 46 2017 800 800 47 2017 6300 6300 48 2018 7100 7100 49 2018 380 380 50 2018 3200 3200 51 2018 3600 3600 52 53 54 55 56 57 I 58 86606 CWS Harbor wells Updated RPA Sep2018.xlsm, data -5- 9/5/2018