WQ0035595_Annual Report_20130301

GRANVILLE FARMS, INC.
2012 ANNUAL LAND APPLICATION OF
RESIDUAL BIO-SOLIDS REPORT
CLASS B PROGRAM
WQ0035595
Submitted by:
Soil Plus
208 Williams Street
Greenville, North Carolina 27858
February 25, 2013
SOIL PLUS
RECEIVEMBRIM
MAR 01 2013
"r Pro**n Seft

,OIL PLUS
February 25, 2013
NCDENR-DWQ
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Re: 2012 LAND APPLICATION ANNUAL REPORT
Granville Farms, Inc. "Class $" Program
NC Permit No.: WQ0035595
Soil Plus Project No. 200705.A10
Information Processing Unit:
Soil Plus, LLC (Soil Plus) is submitting all monitoring and reporting requirements as
specified in the above referenced permit for Granville Farms, Inc. Soil Plus compiled this
report using data gathered during the compliance year. This data includes (1) certification
form, (2) residual sampling, (3) field loading calculations, (4) pathogen and vector attraction
reduction documentation, (5) standard soil fertility nutrient analysis.
Granville Farms, Inc. conducted application events on permitted fields in Edgecombe
County during 2012. A total of 516.89 Dry Tons or 4,048,961 gallons of permitted residual
bio-solids were land applied to permitted fields.
If there is any further information required or questions regarding this annual report please
do not hesitate to contact me or the Granville Farms, Inc. (919-690-8000) for further
assistance.
Respectfully,
v
C. Scott Carpenter, L.S. .
North Carolina Nutrient Management Planner
Andy Smith, Granville Farms
Jason Smith, Granville Farms
208 Williams St.
Greenville, NC 27858
t [phone]
f [phone]
www.soilplus.net

Granville Farms
2012 Annual Land
Application of
Residual Bio-Soilds
Report
WQ0035595
Edgecombe
County, NC
l
ANNUAL
CERTIFICATION FORM
Source Summary
Field Loading Summary
FIELD SUMMAW
PATHOGEN & VECTOR
REDUCTION FORM
Ahoskie WLW T?
Contentnea MSD WWII'
Neuse River VA=
Town of Tarboro WW TP
Williamston WW P
aAVERY READY INDEX $00083

ANNUAL LAND APPLICATION CERTIFICATION FORM
PermitNumber FacilityName Land Application Operator County Phone Number
WQ0035595 Granville Farms, Inc. Granville Farms Granville [phone]
Year: 2012
Land application of residuals as allowed by the permit occurred during the past calendar year? If No, skip Part A, and Part Yes No
B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the a
residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit: 28
Total number of fields utilized for land application during the year: 13
Total amount of dry tons applied during the year for all application sites: 876.44
Total number of acres utilizes for land application during the year: 185.91
Part B - Annual Compiance Statement:
Facility was compliant during calendar year with all conditions of the land application permit? Yes No
Including but not limited to items 1-13 below) issued by the Division of Water Quality W - 12
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory
results are attached
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of
certified laboratory results are attached
6.The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T
7. All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilit
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilitie
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was
received from the Division of Water Quality
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to
include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations."
Jason Smith, Vice President
Permittee Name and Title (type or print): Signature of Permittee
JWX &M;L
February 18, 2013Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)
Monday, February 18, 2013

Source Summary
WWTP Volume Applied Dxy Tons
Ahoskie WWII'
Contentnea MSD VA=
Neuse River WWl'P
Town of Tarboro WWTP
WAamston W VTP
Grand Total
1,742,500
201.27
385,000
25.85
83,581
13.47
1,512,880
238.62
325,000
37.68
4,048,961
516.89
Monday, February 18, 2013 Page 1 of 1

YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN
Crop 2 PAN
Total P
Crop 1
PAN 1
Crop 2
PAN 2
Field
Used
T Applied
Total DT
lbs/Ac.
lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used
Crop 2 Name
PAN
Used
Site# JBS
10
2.35
7,000
0.49
0.59
5.32
Annual Ryegrass -
83
0.7%
Soybeans, Full
50
Hay
Season - Manured
11
10.73
168,000
11.48
19.05
25.00
Annual Ryegrass -
125
15.2%
Soybeans, Full
50
Hay
Season - Manured
12
12.3
133,000
29.91
35.11
16.67
Annual Ryegrass -
116
30.3%
Soybeans, Fuli
50
Hay
Season - Manured
13
24.6
931,000
142.23
115.21
40.84
136,99
Soybeans, Full
176
65.5%
Annual Ryegrass -
50
81.7%
Season - Manured
Hay
14
4.01
65,000
7.54
115.83
107.11
Annual Ryegrass -
125
92.7%
Milo
50
Hay
15
7.61
14,000
0.98
0.36
3.28
Annual Ryegrass -
83
0.4%
Soybeans, Full
50
Hay
Season - Manured
17
29.51
906,000
95.92
91,13
112.81
Annual Ryegrass -
125
72.9%
Soybeans, Full
50
Hay
Season - Manured
18
7.53
293,000
25.01
85.90
114.27
Annual Ryegrass -
91
94.4%
Soybeans, Full
Hay
Season - Manured
19
11.36
344,000
31.85
10936
125.79
Annual Ryegrass -
121
90.4%
Soybeans, Full
50
Hay
Season - Manured
20
17.32
371,009
42.08
71,93
18.97
85.52
Soybeans, Full
176
40.9%
Rye, Grain
50
37.9%
Season - Manured
Monday, February 18, 2013 Page 1 of 2

YEAR TO DATE FIELD
LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING
RATES
Acres
Volume Crop 1 PAN Crop 2 PAN
Total P
%0
Crop 1 PAN 1
%
Crop 2 PAN 2
Field Used
Applied Total DT lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name PAN Used
Crop 2 Name
PAN Used
21 31.7
553,480 106..27 119.33 0.68
168.44
.annual Ryegrass - 121 98.6%
Soybeans, Full
50 1.4%
Hay
Season
22 16.49
143,240 1693 94.11
168.89
Annual Ryegrass - 106 88.8%
Corn, Grain
50
Hay
32 10.4
120,232 16.19 109.72
232.90
Annual Ryegrass - 125 87.8%
Corn, Grain
50
Hay
Total 4,048,961
Monday, February 18, 2013 Page 2 of 2

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. W(N035595 Facility Name Granvi➢c Farms, Tne, Source Pcxmit No. NC0088561 Suurce Name: Ahmkie \YAVTP
Laboratory 1
Laboratory 2
Sample or CompositeDate
Parameter (mg/Kg) C12ea A Clan B
A&L E trm
1abr, Inc.
2/21/21112
Aluminum
N/A
N/A
24,gpp
Ammonia Nitrogen
N/A
N/A
6,140
Arsenic
Cadmium
41
39
7S
85
5
2
Calcium
N/A
N/A
16,200
Copper
1,500
4,300
840
N/A
461
38—
4,790
— Lcad
Magnesium
300
N/A
Mercury
17
57
❑0
Molybdenum
N/A
75
it
Mickel
420
420
17
Ninare-NitriteNitrugen
N/A
N/A
112
Percent Solids
N/A
N/A
III
pH (no unite)
Phosphurus
Potassium
N/A
N/A
N/A
N/A
1.34
5,3cao
N/A
N/A
PAN {Inj./1ne)
-._
PAN (-S-urf—
N/A
—
—ace) N/A—
N/A
N// A
19,260
_ ...._
tfi,190
Selenium
100
100
6
I Sodium
N/A
N/A
N/A
6,710
SAX
— N/A
TKN
N/A
N/A
�9,ia0
Zinc
2,800
7,500
Iwo
^I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted, I am aware that there are significant penalties for
submitting false information, includes the possibility of fines and imprisonment for knowing violations."
iignature of Prepare, * pate
*Pmparcr is defined in 40 CPR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Ahoskie WWTP
Sampling Date 2/21/2012
Solids 2.77
Mineralization Rate 0.30
Gallons per DT 8,657.33
pH 7.34
Sodium Absorpotion 1.98 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 49,500 lbs./1,000 gal 11.44
Ammonia Nitrogen (mg/Kg) 6,140.00 lbs./1,000 gal 1.42
Nitrate -Nitrite (mg/Kg) 112.00 lbs,/1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 16,190 lbs./1,000 gal 3.74
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED .APPLIED
PAN (mg/Kg) 19,260 lbs./1,000 gal 4.45
Volatization Rate 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Potassium lbs./1,000 gal
1.22
Phosphorus lbs./1,000 gal
5.29
Calcium lbs./1,000 gal
3.74
Magnesium lbs./1,000 gal
1.10
Manganese lbs./1,000 gal
0.07
Sulfur tbs. /1,000gal
L84
Molybdenum lbs./1,000 gal
0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
5.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
461.00
Copper lbs./1,000 gal
0.11
Lcad (mg/Kg)
38.00
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.90
Mercury lbs./1,000 gal
0,00
NT;CI-1 / IV-'%
. ..,. V- S, ._rj
17 nn
1.�7-1-1 iu- /1 nnn �
.. a., ., v ga
n
�.00
Selenium (mg/Kg)
6,00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1000.00
Zinc lbs./1,000 gal
0.23
RESIDUAL NITROGEN CALCULATION
Surface Application
injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKl�T
(mg/kg) (lbs/DT)
(mg/Kg)
49,500
16,190
32.38
33,310
49,500
19,260 38.52
30,240
33,310
4,997
9,99
28,314
30,240
4,536 9.07
25,704
2B,314
2,124
4,25
26,190
25,704
1,928 3.86
23,776
26,190
982
1,96
25,208
23,776
892 1.78
22,8B5
25,208
473
0.95
24,735
22,885
429 0.86
22,456
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NI13))} (VR x NI13)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr.'I'KN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. 'I'KN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 24,765 49.53
Total 27,044 54.09

Page: 1 of 2
Report Number: 12-053-0205
Account Number: 45691
Submitted By: SCOTT CARPENTER
Send To: GRANVILLE FARMS INC
POB 1396
OXFORD, NC 27565
Lab Number: 86491
Sample Id : A022112
A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 (804) 743540f Fax (MAI271.6446
wwwaloasterri.com
Project: 201201.A10-AHOSKIE WWTP
NC CERT#257
REPORT OF ANAL YSIS Date Sampled: 2/21/2012 13:00:00
Date Received: 02/22/2012 00:00
Elate Reported: 02/27/2012
Total Solids *
2.77
27700
100.0
JM
02/22/2012 13:50
SM-254OG
Moisture *
97.23
100.0
JM
02/22/2012 13:50
SM-2540G
Total Kjeldahl Nitrogen
4.95
49500
10.0
JM
02/23/2012 07:50
SM-4500-NH3C-TKN
Total Phosphorus
2.29
22900
100
KM
02/23/2012 12:24
SW 6010C
Total Potassium
0.53
5300
100
KM
02/23/2012 12:24
SW 6010C
Total Sulfur
0.80
7980
100
KM
02/23/2012 12:24
SW 6010C
Total Calcium
1,62
16200
100
KM
02/23/2012 12:24
SW 6010C
Total Magnesium
0,48
4780
100
KM
02/23/2012 12:24
SW 6010C
Total Sodium
0.67
6720
100
KM
02/23/2012 12:24
SW 6010C
Total Iron
1.50
15000
1
KM
02/23/2012 12:24
SW 6010C
Total Aluminum
2.43
24300
10
KM
02/23/2012 12:24
SW 6010C
Total Manganese
0.03
306
1
KM
02/23/2012 12:24
SW 6010C
Total Copper
0.05
461
1
KM
02/23/2012 12:24
SW 6010C
Total Zinc
0.10
1000
1
KM
02/23/2012 12:24
SW 6010C
Ammonia Nitrogen
0.61
6140
10.0
JM
02/23/2012 07:50
SM-4500-NH3C
Organic N
4.34
43360
10.0
02/23/2012 07:50
CALCULATION
Nitrate+Nitrite-N
112
1.00
JM
02/23/2012 07:50
SM-450ONO3F
Total Cadmium
2.0
1.0
KM
02/23/2012 12:24
SW 6010C
All values are on a dry weight basis except as noted by asterisk.
Detection limit on
all N series is on a wet basis.
Our reports and let,ers ;re .`,r th• excfusiva nri conficlentw
use of our clients, and may not
be reproduced in
or l-A. n ar ln. y any
reference be made
•to
i• the wk, if .� resultsr th
oe co.oa
pany +n any dvertising,nc
s release, orotherpublic anc3cn—,—nients �+ ithout
cbt,nning ourprior r ritten
„uthorization4'4U6��
Debbie Holt

Page: 2 of 2
Report Number: 12-053-0205
Account Number: 45691
Submitted By: SCOTT CARPENTER
Send To: GRANVILLE FARMS INC
POB 1396
OXFORD, NC 27565
Lab Number: 86491
Sample Id : A022112
A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax (M) 271-6446
www,aleastem,com
Project: 201201.A10-AHOSKIE WWTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 2/21/2012 13.00:00
Date Received: 02/22/2012 00:00
Date Reported: 02/27/2012
Total Chromium
46
5
KM
02/23/2012 12:24
SW 6010C
Total Nickel
17
5
KM
02/23/2012 12:24
SW 6010C
Total Lead
38
5
KM
02/23/2012 12:24
SW 6010C
Total Arsenic
5.0
1.0
KM
02/23/2012 12:24
SW 6010C
Total Mercury
0.9
0.4
KM
02/24/2012 09:00
SW-7471 B
Total Selenium
6.0
1.0
KM
02/23/2012 12:24
SW 6010C
pH (Standard Units) *
7.34
0.01
MW
02/23/2012 09:20
SW-9045D
Total Molybdenum
11
5
KM
02/23/2012 12:24
SW 6010C
Comments:
TCLP AND ICR TO FOLLOW
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al", "Ca", "P", AND "Se". ALL OTHER QC DATA IS ACCEPTABLE -
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our report; and •leers art far the exclusi.•e and coof-'ential a >-: of our; Bents. and may not to rep: eciuc:- 1 it? -• ,.1e or part, nor m_iy xiy re`-wooce be niao;
to the v..rk, tha roe u4s. Dr th rornpanyin any advertising, news release, or othernL`,,,c announ.emeots .._:•)ct r':ralr'nJ ow pi. arrrtlen authoriaal'nn
Debbie Holt

I _„s Pace aServices, Inc.
I� 205 East
Meadow
Road -Suite A
srsrascabbamm Eden, NC 27288
(336)6236921
March 27, 2012
P�ce Ans"cai Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Anatydcal Services, Inc.
9800 KDnceyAve. Suite 100
Huntersville. NC 28078
[phone]
7
92-0222
GRANVILLE FARMS INC
201201.A10-AHOSKIE WWTPITCLP/ICR
24
13:08:00
45691
GRANVILLE FARMS INC
POB 1396
Ms. Trisha Stoss OXFORD NC 27565
A&L Eastern Laboratories
7621 Whitepine Rd
Richrtlo d WA 23237
n, ,
RE: Project: 86518
Pace Project No.: 92112744 4 ozi-) 12—
Dear Ms. Stoss., !
Enclosed are the analytical results for sample(s) received by the laboratory on February 23, 2012.
The results relate only to the samples included in this report. !Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assulrance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services loc�tion indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Charles Hardin
[e-mail]
Project Manager
Enclosures
E
cc: Tuts. Cathy Amend. A&L Eastern Laboratories
Ms. Kathy Scott, A&L Eastern Laboratories
REPORT OF LABO RATO OY A NA LYSIS Page 1 of 20
This report shall not 6e reproduced, except in full,
IV i
without the written consent of Pace Analytical Services, Inc..

A* l*
iraw:paoeb8taan
i
Pace Analytical Services, Inc,
205 East Meadow Road - Suite A
Eden, NC 2728E
[phone]
C,
Project: 86518
Pace Project No.: 92112744
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 4132 0
Arizona Certification #: AZ0735
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH 0216
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC; Reciprocity
)Alnois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FL01264
Massachusetts Certification #: M-FL1264
Michigan Certification P. 9911
Mississippi Certification: FL NELAC Reciprocity
Kansas Certification lDs
9608 Loiret Boulevard, Lenexa. KS 66219
A21-ACertfication #: 2456.01
Arkansas Certification #: 05-008-0
Illinois Certification #: 001191
Iowa Certification #: 116
Kansas(NELAP Certification #: E-10116
Charlotte Certification IDs
9800 KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Virginia Drinking Water Certification #: 00213
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification* E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #; 40
Analytical Services, Inc.
2225 Riverside Dr,
AshavfIfe, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincay Ave. Suite 100
Huntersville, NC 28078
[phone]
Missouri Cer$ficatlon #: 236
Montana C01Fication #: Cert 0074
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Oertification #: FL765
New York Crifcation #: 11608
North Carols a Environmental Certificate #: 667
North Caroiiria Certification #: 12710
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
Tennessee gertificabon #: TN02974
Texas Certifi tion: FL NELAC Reciprocity
U.S.Virgin Is nds Certification: FL NELAC Reciprocity
Virginia Certification #: 00432
Virginia Envi orlmental Certificate #: 460165
Washington ertification #: C955
Wyoming Ceertification: FL NELAC Reciprocity
Wyoming (EPA Region 8), FL NELAC Reciprocity
Louisiana C rtification #: 03055
Nevada Ce cation #; KS000212008A
Oklahoma Clertiflcation #: 9205/9935
Texas Certifi tlon #: T104704407-08-TX
Utah Certification #: 9135995665
Connecticut lCertification #: PH-0104
Florida/NE P Certification #: E87627
Kentucky U T Certification #: 84
Louisiana D H Drinking Water # L4100031
West MrginiO Certification #: 357
Virginia/VELAP Certl1raiion #: 460144
South Carol na Certification #: 99030001
Virginia Certification #: 00072
West Vrginlo Certification #: 356
Virgina/VE P Certification C 460147
REPORT OF LASORATO JY ANALYSIS
This report shall not be reproduce except in full,
without the written consent of Pace AnA�bcal Services, Inc_.
Page 2 of 20

kOft f
f rascpoodmbLwm
Project: 86518
Pace Project No.: 92112744
Lob ID Sample ID
92112744001 86618
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
205 East Meadow Road - Suite A 2225 Riverside Dr.
Eden. NC 27288 Asheville, NC 28804
[phone] [phone]
SAMPLE ANALYTE COUNT
EPA 8 81
EPA 8 51
EPA 6at}10
EPA 7470
EPA U70
ASTM D2 74-8
EPA 1 J10
SW446 .3.4,2
EPA 5
SW-846 .3.3.2
REPORT OF LABORATORY�ANALYSIS
This repro shaft not be reproduced, a cept in full,
without the written consent of pace Analytic al Services, Inc..
Analysts
RES
LJM
JMW
DMB
Bpi
KJM
DWC
SMW
OIL
EWS
OL
Pace Analytical Services, Inc.
98001dnceyAve, Suite 100
Huntemille, NC 28078
[phone]
Analytes
Raported Laboratory
8
PASI-C
3
PASI-O
7
PASI-A
1
PASI-A
18
PASI-C
15
PASI-C
1
PASI-K
1
PASI-A
1
PASI-K
1
PASI-A
1
PASI-K
Page 3 of 20

f1�2cekwcale
IY1rn'pei'ebbRCirR
i
Project: 86518
Pace Project No_: 92112744
Pace Analytieal Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL.
Pico Analyt}eaI Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pate Analytical Services, Inc.
98D0 Kincey Ave. SuRe iD0
Huntersville, NC 28078
(7D4)875-9092
Sample: 86518 Lab ID: 92112744001 Collected: =1112 13;00 Received: 02/23/12 09:30 Matrix: Solid
Results reported on a "wet-welght" basis 1
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua]
8081 GCS Pesticides, TCLP SPE Analytical Method: EPA 8081 Preparation Method: EPA3535
Leachate MethodIDate: EPA 1311; 02J27112 15:00
gamma-BHC (Undane)
ND ug/L
2.5
5
02/28/12 09:00 03/03/12 09:24 58-89-9
Chlordane (Technical)
NO ug/L
15.0
5
02/28/12 09:00 03/03/12 09:24 57-74-9
Endrin
ND ug/L
2,5
1 5
02/28/12 09.00 03/03/12 09:24 72-20-8
Heptachlor epoxide
NO ug/L
2.5
5
02/28/12 09:00 03/03/12 09:24 1024-57-3
Methoxyehlor
NO ug/L
5000
5
02/28/12 09:00 03/03/12 09:24 72-43-5
Toxaphene
ND ug/L
15.0
5
02/28/12 09:00 03/03/12 09:24 8001-35-2
Surrogates
Derachlorobiphenyl (S)
0 %
10-138
5
02/28/12 09:00 03/03/12 09;24 2051-24-3 D3,S4
Tetrachloro-m-xylene (S)
0 %
10-110
5
02l28112 09:00 03/03/12 09:24 877-09-8 94
81S1 Chiorinate Herbicide TCLP
Analytical Method: EPA 6151
2,4-D
ND mg/L
0.010
1
03105/12 08:00 03/07/12 06:57 94-75-7
2,4,5-TP (Silvex)
NO mg/L
0.010
1
03/05/12 08:00 03/07/12 08:57 93-72-1
Surrogates
2,4-DCAA (S)
91 %
70.130
1
03/05/12 08:00 03/07/12 06:57 19719-28-9
6010 MET ICP, TCLP
Analytical Method: EPA 6010 Preparation Meth�d: EPA 3010
Leachate Method/Date: EPA 1311;
02129/12 16:t0
Arsenic
ND mg/L
0,025
' 1
03/01/12 12:25 03/02/12 02:48 7440-38-2
Barium
0.S4 mg/L
0.50
1
03/01/12 12:25 03/02/12 02:48 7440-39-3
Cadmium
ND mg/L
0.0050
1
03/01112 12:25 03/02/12 02:48 7440-43-9
Chromium
ND mg/L
0.025
1
03/01/12 12:25 03/02/12 02:48 7440-47-3
Lead
ND mg/L
0,025
1
03/01/1212:25 03102/1202:48 7439-92-1
Selenium
ND mg/L
0.10
', 1
03/01/12 12:25 03/02/12 02:48 7782.49-2
Silver
ND mg/L
0,025
1
03101/1212:25 03fO211202:48 744(1-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470 Preparation
Method: EPA 7470
Leachate Method/Date: EPA 1311;
02129112 16:ia0
Mercury
8270 MSSV TCLP Sep Funnel
ND ug/L 0.20 ' 1 03101/1216:40 03/02112 12:57 7439-97-6
Analytical Method-, EPA8270 Preparation MethdlId: EPA3510
Leachate Method/Date: EPA 1311: (12127/12 15:QD
1,4-Dichlorobenzene
ND ug/L
50.0
2,4-Dinitrotoluene
ND ug/L
50.0
Hexachloro-1,3-butadiene
ND ug/L
50.0
Hexachlorobenzene
NO ug/L
50.0
Hexachloroethane
ND ug/L
50.0
2-Me"phenol(o-Cresol)
ND ug/L
50.0
3&4-Methylphenol(m&p Cresol)
ND ug/L
50.0
Nitrobenzene
ND ug/L
50.0
Pentachlorophenol
ND ug/L
100
Pyridine
ND ug/L
50.0
2,4,5-Trichlorophenol
ND ug/L
50.0
Date: 03/27/2012 01:02 PM
REPORT OF LABORATORY
1 02/28/12 08:00
03/01/12 00A0 10646-7
1 02/28/12 08:00
03/01112 00:40 121-14-2
1 02/28/12 0&00
03/01/12 00:40 87-68-3
1 02/28/12 08:00
03/01/12 00.40 118-74-1
1 02/28/12 08:00
03/01/12 00:40 67 72-1
1 02/28/12 08:00
03/01/12 00.40 95-48-7
1 02/28112 08:00
03/01/12 00:40
1 02/28/12 08:00
03/01/12 00:40 98-95-3
1 02/28/12 08:00
03/01/12 00:40 87-86-5
1 02/28/12 08:00
03101/12 00:40 110-Wl
1 02/28/12 08:00
03/01/12 00:40 95-95-4
LYSIS
This report shall not be reproduced, a cept in full,
without the written consent of Pace Analyticol Services, Inc..
Page 4 of 20

Pace Analytical Services, Irtc,
206 East Meadow Road - Suite A
Eden. NC 27289
[phone]
ANALYTICAL
Project: 86518
Pace Project No.: GIV12744
Pic* Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC Naas
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvills, NC 28078
[phone]
Sampla: $6518 Lab 10: 92112744001 Collected: 0212111 13:00 Received: 02/23/12 09:30 Matrix: Solid
Rasuits reported on a 'wet -weight" basis
Parameters Results Units Report Limit
8270 M83V TCLP Sep Funnel
Analytical Method: EPA8270 Preparation Methi
Leachate Method/Date: EPA 1311;
02/27/12 15a
2,4,6-Tdchlorophenol
ND ug/L
50.0
Surrogates
Nitrobenzene-d5 (S)
50 %
12-102
2-Fluorobiphenyl (S)
40 %
13-107
Terphenyi-dl4 (S)
88 %
21-132
PhenoW8(S)
19 %
10-110
2-Fluorophenol (S)
25 %
10-110
2,4,6-THbromophenol (S)
47 %
27-108
9260 MSV TCLP
Analytical Method: EPA 8260
Benzene
ND ug/L
100
2-Butanone (MEK)
ND ug/L
200
Carbon tetrachloride
ND ug/L
100
Chlorobenzene
ND ug/L
100
Chloroform
ND ug/L
100
1,4-Dichlorobenzene
ND ug/L
100
1,2-Dichloroethane
ND ug/L
100
11-Dichloroethene
ND ug/L
100
Tetra chloroethene
ND ug/L
100
Trfchloroethene
ND ug/L
100
Vinyl chloride
ND ugiL
100
Surrogates
1,2-Dichloroethane-64 (S)
101 %
70-130
Toluene-d8 (S)
95 %
67-135
4-Bromofluorobenzene (S)
101 %
70-130
Dibromofluoromethane (S)
100 %
70-130
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 97.2 % 0.50
1010 Flashpolnt,Closed Cup Analytical Method: EPA 1010
Flashpoinl >200 deg F 70.0
Reactive Sulfide Analytical Method: SW-846 7.3.4.2
Sulfide, Reactive ND mg/kg 100
9049 pH Soil Analytical Method: EPA 9045
pH at 25 Degrees C 6.6 Sid. Units 0.10
733C S Reactive Cyanide Analytical Method: SW-848 7.3.3.2
Cyanide, Reactive ND mg/kg 0.025
DF Prepared Analyzed CAS No.
xi: EPA 3510
10
1 02/28/12 08:00 03/01112 00:40 88-06-2
1 02/28/12 08:00 03/01/12 00:40 416"0-0
1 02/28/12 08:00 03/01/12 00:40 321-60-8
1 02/28/12 W00 03/01/12 00:40 1718-51-0
1 02/28/12 08:00 03/01/12 00:40 13127-8"
1 02128/12 08:00 03/01/12 00;40 367-12-4
1 02/28/12 08.00 03/01/12 00;40 118-79-6
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
1
1
1
1
1
02/28/12 22A3 71-43-2
02/28/12 22.43 78-93-3
02/28112 22:43 56-23-5
02/28/12 22:43 108-90-7
02/28/12 22;43 67-86-3
02/28/12 22:43 106-46-7
02/28/12 22:43 107-06-2
02/28/12 22:43 75-35-4
02/28/12 22,43 127-18-4
02/28/12 22:43 79-01-6
02/28/12 22:43 75-01-4
02/28/12 22:43 17060-07-0
02/28/12 22:43 2037-26-5
02/28/12 22:43 460-00.4
02/28112 22:43 1868-53-7
02/29112 00:00
03/0V12 10:00
03/06/12 13:00
03/05/12 13:00
03/06/12 16:56
Qual
Date: 03/27/2012 01:02 PM REPORT OF LABORATORY NALYSIS Page 5 of 20
This report shall not be reproduced, a cept in full,
without the written consent of Pace Analyti l Services, Inc..

aAaWical
a�rs�6sasnr
Project: 86518
Pace Project No,: 92112744
Pace Analytical Services, Inc. Pkea Analytical Services, Inc.
205 East Meadow Road - Suite A 2225 Riverside or.
Eden. NC 27208 Asheville, NC 28804
(336)62"921 (828i254-7176
QUALITY CONTROL DATA
QC Batch: GCSVl7689 Analysis Method: JEPA 8151
QC Batch Method: EPA 8151 Analysis Description: 8151 GCS Herbicides TCLP
Associated Lab Samples: 92112744001
METHOD BLANK: 350821
Associated Lab Samples: 92112744001
Parameter Units
2,4,5-TP (Silvex) mg1L
2,4-D mglL
2,4-DCAA (S) %
Matrix: Water
Blank Reporting
Result -- Limit I Analyzed
ND 0.010 03/07/12 02:50
ND 0.010 03/07/12 02:50
93 70-1 0 03/07112 02:50
Qualifiers
Pace Ans"cal Services, Inc.
9900 Kincey Ave. Suite 100
Huntersville, NC 26078
[phone]
LABORATORY CONTROL SAMPLE: 350822
Spike
LCS
LCS
% Rec
Parameter Units
Conc.
Result
°/G Rec
Limits Qualifiers
2,4,5-TP (Silvex) mglL
.012
.0094J l
78
7C-130
2,4-0 mg1L
.06
0.052
86
70-130
2,4-DCAA (S) °%
91
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 351479
351480
MS
MSD
92112764001
Spike
Spike MS
MSD
MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result
% Rec % Rec
Limits RPD Qual
2,4,5-TP (Silvex) mg1L ND
.012
.012 0.01
.0084J
93 70
70-130
2,4-D mglL ND
.06
.06 0.06
0.052
101 87
70-130 14
2,4-DCAA (S) %
1
82 66
70-130 SO
Date: 03/272012 01:02 PM REPORT OF LABORATORY NALYSIS Page 6 of 20
This report shall not be reproduced, except in full,
without the written consentof PaCeA00"cal Services, Inc,.

Pace Analytical Services, Inc. dace Analytical Services, Inc. Pace Analytical Services, Inc.
Ce Pc'
205 Eesi Meadow Road - Suite A
2225 Riverside Or.
8800 Kinray Ave. Suite loo
J' ww on
Eden, NC 27288
Asheville, NC 28604
Huntersville, NC 28078
[phone]
(828)2547176
[phone]
QUALITY CONTROL DATA
Project: 86518
Pace Project No.: 92112744
QC Batch: MERP14082
Analysis Method:
EPA 7470
QC Batch Method: EPA 7470
Analysis Description:
7470 Mercury TCLP
Associated Lab Samples: 92112744001
METHOD BLANK: 729496
Matrix: Water
Associated Lab Samples: 92112744001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
ug1L
NO 0.
0 0310211212:12
F
LABORATORY CONTROL SAMPLE:
729497
Spike LC5
!I LCS % Rec
Parameter
Units
Conc. Result
i % Rec Limits Qualifiers
Mercury
ug/L
2.5 2.4
98 80-120
MATRIX SPIKE SAMPLE:
729498
92112580001 Spike
MS MS
% Rec
Parameter
Units
Result Conic,
Result % Rec
Limits Qualifiers
Mercury
ug/L
NO 2.51
2.2 90
I
75-125
SAMPLE DUPLICATE: 729499
92112591001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Mercury ug/L NO N
Date: 03/27/2012 01:02 PM REPORT OF LABORATORY
This report shall not be reproduced,
without the written consent of Pace Analy
NALYSIS
}pt in full,
Services, Inc..
Page 7 of 20

i
iil• Pace Analytical Services, Inc. lace Analytical Services, Inc.
Ana"cal
UG "UW 205 East Meadow Road - Suite A 2225 Riverside Dr,
weaperabbcaonr Eden, NC27288 Asheville, NC 28804
[phone] [phone]
QUALITY CONTROL DATA
Project: 86518
Pace Project No.: 92112744
QC Batch: MPRP110014 Analysis Method: EPA 6D10
QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92112744001
Pace Analytical Services, Inc.
9800 lGnceyAve. Suite 100
Huntersviile, NC 28078
(704)875_9(192
METHOD BLANK: 729391
Matrix: Water
Associated Lab Samples: 92112744001
Blank Reporting I
Parameter
Units
Result Limit
Anatyzed
Qualifiers
Arsenic
mg/L
ND 0.0
5 03/02/12 01:36
Barium
mg/L
NO 0.10
03/02/12 01:36
Cadmium
mg/L
NO 0,00
0 03/02/12 01:36
Chromium
mg/L
ND 0,0
5 03/02/12 01:35
Lead
mg1L
ND 0.0�5
03/02/12 01:36
Selenium
mg1L
ND O.D
03/02/12 01:36
Silver
mg/L
ND 0.0
I
5 03/02/12 01:36
LABORATORY CONTROL SAMPLE:
729392
Spike LCS
LCS %
Rec
Parameter
Units
Cone. Result
% Rea Limits Qualifiers
Arsenic
mg1L
2.5 2.6
103
M120
Barium
mglL
2.5 2.2
89
M120
Cadmium
mglL
2.5 2.3
93
80-120
Chromium
mg/L
2.5 2.4
95
80-120
Lead
mglL
2.5 2.1
85
80-120
Selenium
mg1L
2.5 2.6
103
80-120
Silver
mg1L
1.2 1.3
100
80-12D
MATRIX SPIKE SAMPLE:
729394
92112680001 Spike
MS
MS
% Rea
Parameter
Units
Result Cone,
Result
% Roe
Limits Qualifiers
Arsenic
mg/L
NO 2.5
2.6
104
75-125
Barium
mg1L
NO 2.5
2.3
92
75-125
Cadmium
mg/L
NO 2.5
2.3
93
75-125
Chromium
mg/L
ND 2,51
2.4
95
75-125
Lead
mg1L
NO 2.5
2.2
87
75-125
Selenium
mg/L
NO 2.51
2.6
105
75.125
Silver
mg/L
ND 1.21
1.3
1
101
75-125
SAMPLE DUPLICATE: 729393
92112467001 Dup
Parameter
Units
Result Result
RPD
Qualifiers
<n 09F
Barium
mg1L
1.3 1.2 10
Cadmium
mg/L
<0.0050 ND
Chromium
mg1L
0.026 .0220
Lead
Date: 03/2712012 D1:02 PM
mg1L
<0.025 NO
REPORT OF LABORATORY )jIMALYSIS
This report shall not be reproduced, e� eept in full,
without the written consent of Pace Analytic` Services, tnc..
Page 8 of 20

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
i 205 East Meadow Road • Suds A 2225 Riverside Dr.
'J" Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
QUALITY CONTROL FA
Project: 86518
Pace Project No.: 92112744
SAMPLE DUPLICATE: 729393
92112467001 Dup
Parameter Units Result Result
Selenium mg/L <0.10
Silver mg/L <0.025 .0(
RP❑ Qualifiers
Date: 03/27Ml2 01:02 PM REPORT OF LABORATORY NALYSIS
This report shall not be reproduced, e II cept in full,
without the written consent of Pace Analvtiepl Services, Inc„
Pace Analytiaai Services, Ine.
9800 Kincey Ave. Suits 100
HuntersvR)e, NC 28078
[phone]
Page 9 of 20

aeArxalyfical
i rrrpspslsbr.osm
I
Project_ 86518
Pace Project No,: 92112744
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
race Aniytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch: MSVI18329 Analysis Method: IEPA8260
QC Batch Method: EPA 8260 Analysis Description: 18260 MSV TCLP
Associated Lab Samples: 92112744001
Associated Lab Samples:
Parameter
92112744001
Units
Blank
Result
Reporting
Limit
Analyzed
1,1-Dichforoethene,
ug/L
ND
5
0 02/28/12 15:37
1,2-Dichioroethane
ug/L
ND
50
02/28/12 15:37
1,4-Dichlorobenzene
ug/L
ND
50
02/28/1215:37
2-Butanone (MEK)
ug/L
ND
10J0
02128/12 15:37
Benzene
ug/L
ND
50
02/28112 15:37
Carbon tetrachloride
ug/L
ND
610
02128/12 15:37
Chlorobenzene
ug/L
ND
5
0 02/28/12 15:37
Chloroform
ug/L
ND
5,0
02/28/12 15:37
Tetrachloroethene
ug/L
NO
6.0
02/28/12 15:37
Trichloroethene
ug/L
ND
5P
02/26/12 15:37
Vinyl chloride
ug/L
ND
5
02/28/12 15,37
1,2-Dichloroethane-d4 (S)
%
109
70-1
02128/12 15:37
4-Bromofluorobenzene (S)
%
101
70-13-I0-
02/28/12 15:37
Dibromoftuorom ethane (S)
%
100
70-1*
02129/12 15:37
Toluene-d8 (S)
%101
67-1
02128/12 15:37
LABORATORY CONTROL SAMPLE: 727874
Parameter
Units
Spike
Cone.
LCS
Result
1,1-Dichloroethene
ug/L
50
46.2
1,2-Dichloroethane
ug1L
50
46,3
II A-Dfchlorobenzene
ug/L
50
47.7
2-Butanone (MEK)
ug/L
100
85.6
Benzene
ug1L
50
49.2
Carbon tetrachloride
ug/L
50
50,4
Chlorobenzene
ug/L
50
49.7
Chloroform
ug/L
50
50.3
Tetrachloroethene
ug/L
50
49.6
Trichloroethene
ug/L
50
51.2
Vinyl chloride
ug/L
50
45.4
1,2-Dichloroethane-d4 (S)
%
4-Bromoftuorobenzene (S)
°%
Dibromofluoromethane (S)
°%
Toluene-d8 (S)
°%
LCS
% Ree
Qualifiers
% Rec
Limits
92 70-141
93 70-139
95 70-141
86 63-150
98 70-132
101 70-150
99 70-134
101 70-130
99 70-137
102 70-131
91 56-144
91 70-130
99 70-130
91 70-130
101 67-135
Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 10o
Huntersvilie, NC 28078
[phone]
Qualifiers
Date: 03/27/2012 01:02 PM REPORT OF LABORATORY ANALYSIS Page 10 of 20
This report shall not be reproduced, sicept in full,
without the written consent of Pace Analytic i Services, Inc,.
i

���� Pace Analytical Services, Inc. Pace Analytical Services, Inc.
1'1if
J M 205 East Meadow Road - Suite A 2225 Riverside Dr.
M!>e��b:,aCrlr. Eden, NC 27288 Asheville, NO 2BB04
j {336)623-8921 [phone]
QUALITY CONTROL DATA
Project: 86518
Pace Project No.: 92112744
QC Batch: OEXT116575 Analysis Method: EPA8081
QC Batch Method: EPA 3535 Analysis Description; 8081 GCS TCLP Pesticides
Associated Lab Samples: 92112744001 j
METHOD BLANK: 728274
Associated Lab Samples:
92112744001
Parameter
Chlordane (Technical)
ug/L
Endrin
ug/L
gamma-BHC (Lindane)
ug1L
Heptachlor epoxide
ug/L
Methoxychlor
UA
Toxaphene
ug/L
Decaehlorobiphenyl (8)
%
Tetrachlaro-m-xylene (S)
%
Matrix: Water
Blank
Reporting
Units Result
Limit
Analyzed Qualifiers
ND
30
03l01112 11:14
ND
0.10
0310111211:14
ND
0.�0
0310111211:14
ND
0.�0
0310111211:14
ND
10
0 03/D1l12 11 a4
NO
3
0 03/01112 11:14
98
10-1
8 03101112 1114
83
10-11,0
03/0111211:14
LABORATORY CONTROL SAMPLE; 728275
Parameter Units
Endrin
ug/L
gamma-BHC (Lindane)
ug/L
Heptachlor epoxide
4L
Methoxychlor
ug1L
Decachlorobiphenyl (S)
%
Tetrachloro-m-xylene (S)
%
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1.2
1.3
103
20-134
1.2
1.3
102
20-118
1.2
1.2
100
22-133
3.7
ND
113
44-150
95
10-13B
84
10-110
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE:
728276
MS
92112402001
Spike
Parameter
Units
Result
Cane.
Endrin
uglL
ND
1.2
gamma-BHC (L]ndane)
LVL
ND
1.2
Heptachlor epoxide
ug/L
NO
1.2
Methoxychlor
ug/L
ND
3.7
Decachlorobiphenyl (S)
°%
Tetrachloro-m-xyiene (S)
%
728277
MSD
Spike MS
Conc. Result
1.2 1.
1.2 0,8
1.2 0.8
3.7 N
Pace Analytical Services, Inc.
9800 t9ncey Ave. Suke 100
Huntersville, NO 28078
[phone]
Qualifiers
MSD
M5
MSD
% Rec
Result
°% Rec
% Rec
Limits
RPD
1A
84
87
21-133
4
0.96
70
77
24-119
10
1.0
71
83
50-150
15
N❑
95
97
50-150
81
84
10-138
51
52
10-110
Qua]
Date: 03/2712012 01:02 PM REPORT OF LABORATORY ANALYSIS Page 11 of 20
This report shall not be reproduced, except in full,
without the written consent of Pace AnalytiI Services, Inc.,
I

AM •
r ssnrprcat+bRcsm
I
Project: 86518
Pace Project No.: 92112744
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL
Fine* Ans"cal Services, Inc,
2225 Riverside Dr.
Asheville, NC 28804
[phone]
OC Batch: 0EXT116574 Analysis Method: IEPA8270
QC Batch Method: EPA 3610 Analysis Description: 8270 TCLP MSSV
Associated Lab Samples: 92112744001
METHOD BLANK: 728270
Associated Lab Samples: 92112744001
Matrix: Water
Parameter
Units
Blank
Result
1,4-Dichlorobenxene
ug/L
NO
2,4,5-Trichlorophenol
ug/L
NO
2,4,6-Trichlorophenol
ug/L
NO
2,4-Dinitrotoluene
ug/L
NO
2-Methyiphenot(o-Cresol)
ug1L
NO
3&4-Methylphenol(rn&p Cresol)
ug/L
NO
Hexachloro-1,3-butadiene
ug/L
NO
Hexachlorobenzene
ug/L
NO
Hexachloroethane
ug/L
NO
Nitrobenzene
ug/L
NO
Pentachloro phenol
ug/L
NO
Pyridine
ug/L
NO
2,4,6-Tribromophenol (S)
%
75
2-Fluorobiphenyt(S)
%
70
2-Fiuorophenot (S)
%
42
Nitrobenzene -dB (S)
%
69
Phenol-d6 (S)
%
26
Terphenylkd14(S)
%
85
LABORATORY CONTROL SAMPLE: 728271
Reporting
Limit
o! (S)
Spike LCS
Parameter Units Conic. Result
eruene ug/L 5000
ophenol ug1L 0
ophenol ug/L 500
ene ug/L 500
al(o-Cresol) ug/L 500
henal(m&p Cresol) ug)L 500
3-butadlene ug/L 500
nzene ug/L 501)
Thane ug/L 500
ug/L 500
henol ug/L
ug/L
ophenol(S) %
nyl (S) `Yo
%
e-d5 (S)
o�
%
1,4-Dlchlorob
2,4,5-Trichlor
2,4,6-Trichlor
2,4-Dinitrotolu
2-Methylphen
3&4-Methy1p
Hexachloro-1,
Hexachlorobe
Hexachloroe
Nitrobenzene
Pentachlorop
Pyridine
2,4,6-Tribrom
2-Fluorobiphe
2-Fluorophen
Nitrobenzen
Phenol-d6 (S)
Terphenyl-d14 {S )
Date: 03/27/2012 01;02 PM
Ana"d
02/29112 18:58
02/29/12 1 &58
02/29/12 18:58
02/29112 18:58
02/29/12 18:58
02/29/12 18:58
02/29/12 18:58
02J29112 18:58
02/29/12 18:58
02/29/12 18:58
02129/12 18!58
02/29/12 18:58
02/29/12 t8:58
02/29/12 1 &58
02)29112 18:58
02J29/12 18:58
02/29/12 18:58
02129/12 18:58
Qualifiers
LCS % Re
c
% Rec Limits
351 70 10-110
357 71 39-108
424 85 40-104
393 79 42-109
303 61 31-110
277 55 30-110
357 71 10-110
423 85 39-121
342 fib 10-110
394 79 32 101
1000 771 77 18-108
500 207 41 10-110
86 27-108
74 13-107
49 10-110
75 12-102
31 10-110
90 21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, a cept in futt,
without the written consent of Pace Analytial Services, Inc..
I
PaceAnaiytical Services, Int,
9800 KinceyAve. Suite 100
Huntersvi le, NC 28078
[phone]
Qualifiers
Page 12 o120
1,4-Dlchlorob
2,4,5-Trichlor
2,4,6-Trichlor
2,4-Dinitrotolu
2-Methylphen
3&4-Methy1p
Hexachloro-1,
Hexachlorobe
Hexachloroe
Nitrobenzene
Pentachlorop
Pyridine
2,4,6-Tribrom
2-Fluorobiphe
2-Fluorophen
Nitrobenzen
Phenol-d6 (S)
Terphenyl-d14 {S )
Date: 03/27/2012 01;02 PM
Ana"d
02/29112 18:58
02/29/12 1 &58
02/29/12 18:58
02/29112 18:58
02/29/12 18:58
02/29/12 18:58
02/29/12 18:58
02J29112 18:58
02/29/12 18:58
02/29/12 18:58
02129/12 18!58
02/29/12 18:58
02/29/12 t8:58
02/29/12 1 &58
02)29112 18:58
02J29/12 18:58
02/29/12 18:58
02129/12 18:58
Qualifiers
LCS % Re
c
% Rec Limits
351 70 10-110
357 71 39-108
424 85 40-104
393 79 42-109
303 61 31-110
277 55 30-110
357 71 10-110
423 85 39-121
342 fib 10-110
394 79 32 101
1000 771 77 18-108
500 207 41 10-110
86 27-108
74 13-107
49 10-110
75 12-102
31 10-110
90 21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, a cept in futt,
without the written consent of Pace Analytial Services, Inc..
I
PaceAnaiytical Services, Int,
9800 KinceyAve. Suite 100
Huntersvi le, NC 28078
[phone]
Qualifiers
Page 12 o120
1000 771 77 18-108
500 207 41 10-110
86 27-108
74 13-107
49 10-110
75 12-102
31 10-110
90 21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, a cept in futt,
without the written consent of Pace Analytial Services, Inc..
I
PaceAnaiytical Services, Int,
9800 KinceyAve. Suite 100
Huntersvi le, NC 28078
[phone]
Qualifiers
Page 12 o120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, a cept in futt,
without the written consent of Pace Analytial Services, Inc..
I
PaceAnaiytical Services, Int,
9800 KinceyAve. Suite 100
Huntersvi le, NC 28078
[phone]
Qualifiers
Page 12 o120

NM1'WpIRA60LWM
Project: 86518
Pace Project No.: 92112744
Pace Analytical Services, Inc. Pace Analytcal Services, Ine-
205 East Meadow Road - Suite A 2225 Riverside or,
Eden, NC 27288 Asheville, NG 288D4
[phone] (828)2$4-7176
QUALITY CONTROL 6ATA
Pace Analytical Services, Inc.
9800 leincey Ave. Suite 100
Huntersvfle, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
728272
728273'
MS
MSD
92112563D02
Spike
Spike
MS
MSD
MS
MSD
% Ree
Parameter
Units
Result
Cone,
Cone,
Result
Result
°% Rec
% Rae
Limits
RPD Clual
1,4-Dichlor0enzene
uglL
ND
500
500
19
206
38
41
30-150
7
2,4,5-Trichlorophenot
ug1
ND
500
Soo
30
277
61
55
30-150
10
2,4,6-Tdchlorophenol
ug]L
NO
500
500
30
283
60
57
30-150
6
2,4-0Initrotoluene
uglL
ND
Soo
Soo
40
350
80
70
30-150
13
2-Methylphenol(o-Cresol)
uglL
NO
500
500
170
182
34
36
30-150
7
3&4-Methy1phenol(m&p
uglL
NO
500
500
17
178
34
36
30-150
5
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
19
216
38
43
30-150
12
Hexachlorobenzene
ug/L
ND
Soo
500
32
267
65
53
30-150
2D
Hexachloroethane
ug/L
ND
500
Soo
19�
218
39
44
30-150
11
Nitrobenzene
ug/L
ND
500
500
28V
308
57
62
30-150
7
Pentachlorophenol
ug/L
NO
1000
1000
880
772
89
77
30-150
14
Pyridine
ug/L
NO
500
Soo
106
114
21
23
30450
7 M0,M1
2,4,6-Tribromophenol (S)
°%
71
83
27-108
2-Ftuorobiphenyl (S)
°%
41
41
13-107
2-Fluorophenol(S)
%
25
25
10-110
Nitrobenzene-d5 (S)
%
51
57
12-102
Phenol E (S)
°%
17
19
10-110
Terphenyl-d14 (S)
%
82
74
21-132
Date: 03/27/2012 01:02 PM REPORT OF LABORATORY ANALYSIS Page 13 of 20
This report shall not be reproduced, .kept in full,
without the written consent of Pace Analyti Services, Inc..

f rww,psosh6+.asre
I
Project: 86518
Pace Project No.: 92112744
Pace Anslytical 8 mvices, Inc,
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL
Analytical Services, Inc.
2225 Riverside Or.
Asheville, NC 28804
[phone]
OC Batch: PMSTf7017 Analysis Method: �STM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: bry Weight/Percent Moisture
Associated Lab Samples: 92112744001
i
METHOD BLANK: 957662
Associated Lab Samples: 92112744001
Parameter Units
Percent Moisture %
SAMPLE DUPLICATE: 957663
Parameter Units
Percent Moisture %
Date: 03/27/2012 01:02 PM
Matrix: Solid
Blank Reporting
Result �Limit
Analyzed Qualifiers
ND 0.51E 02/29/12 00:00
60116050003 Dup
Result Result
6.5
RPD Qualifiers
67
REPORT OF LABORATORY NALYSIS
This report shall not be reproduced, a cept In full,
without the written consent of Pace Analyti pl Services, Inc..
i
Pace Analytical Services, Inc.
9800 Klncey Ave. Suite 1 o0
Huntersville, NC 28078
[phone]
Page 14 of 20

•
eJ��
srwpoehbr.00m
Project: 86518
Pace Project No.: 92112744
Pace AnaWleal Services, Inc,
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL
Anatytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: WET/19985 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92112744001
SAMPLE DUPLICATE: 731321
Parameter
Flashpoint
92112744001 Dup
Units Result Result RPD
deg F >200 >200
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 1 Do
Nuntersville, NC 28078
[phone]
Date: 03/27/2012 01:02 PM REPORT OF LABORATORY NALYSIS Page 15 of 20
This report shall not be reproduced, a oept in full,
without the written consent of Pace Analytical Services. Inc„

wkgo Pace Analytical Services, Inc. Poes Analytical Services, Inc.
205 East Meadow Road - Suite A 2225 Riverside dr.
a,
We,pMambbL om Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
Project: 86518
Pace Project No.: 92112744
OC Batch: WET133797
QC Batch Method: SW 846 7.3.4.2
Associated Lab Samples: 92112744001
METHOD BLANK: 960268
Associated Lab Samples: 92112744001
Parameter Units
Sulfide, Reactive mgtkg
LABORATORY CONTROL SAMPLE:
960269
Parameter
Units
Sulfide, Reactive
mog
MATRIX SPIKE SAMPLE:
960270
Parameter
Units
Sulfide, Reactive
mg/kg
SAMPLE DUPLICATE: 960271
Parameter
Units
Sulfide, Reactive
mglkg
QUALITY CONTROL 6ATA
Analysis Method: PW-846 7.3.4.2
Analysis Description: Reactive Sulfide
Matrix: Solid
Blank Reporting
Result Limit Analyzed
ND 10b 0310611213:00
Spike LCS LCS
Conc. Result i % Rec
200 182 91
I
92112591001 Spike MS
Result Conc. Result
ND 500 455
Qualifiers
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
% Rec
Limits Qualifiers
77-110
MS
% Rec
91
92112744001 Dup
Result Result I RPD Qualifiers
ND N6
% Rec
Limits Qualifiers
67-116
Date: 03/27/2012 01:02 PM REPORT OF LABORATORY ANALYSIS Page 16 of 20
This report shall not be reproduced, e,loept in full,
without the written consent of Pace Analyticsl Services, Inc..

�r •
kwc l
a�pawwbe.own
I
Project: 86518
Pace Project No.: 92112744
Pace Analytical Service@, Inc. Pico Analytical Services, Inc.
205 East Meadow i7aad- SufteA 2225 Riverside Or.
Eden, NC 27288 ! Asheville, NO 2aiiu
[phone] [phone]
QUALITY CONTROL DATA
OC Batch: VVET119962 Analysis Method: EPA 9045
Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Nuntersville, NO 28078
[phone]

MG /7 tR"w1 0
f rma%peoalaha..rom
i
Project: 86518
Pace Project No.: 92112744
DEFINITIONS
Pao* Analytical Servioes,Inc.
205 Cast Meadow Road - Suite A
Eden. NC 27288
[phone]
QUALIFIERS
Analytical Service$, toe.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 10o
Hanters0le, NC28078
OF - Dilution Factor, if reported, represents the factor applied to the reported data que to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
NO - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below ll`e adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270listed analyte) decomposes toAzobenzene.
Consistent w€th EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and l2PD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel -Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenytamine decomposes and cannot be separated from Diphenylam€ne using Method 8270
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, andl Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited anatytes,
TNI - The NELAC Institute. i
LABORATORIES
PAST -A
Pace Analytical Services • Asheville
PASI-C
Pace Analytical Services - Charlotte
PAST-K
Pace Analytical Services - Kansas City
PASI-Q
Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target ar
M0 Matrix spike recovery andlor matrix spike duplicate recovery was outsi
Mt Matrix spike recovery exceeded OC limits. Batch accepted based an I
So Surrogate recovery outside laboratory control limits.
S4 Surrogate recovery not evaluated against control limits due to sample
The result reported for
4es or other matrix interference.
laboratory control limits.
aralory control sample (LCS) recovery.
Date: 03/2712012 01:02 PM REPORT OF LABORATORY ANALYSIS
This report shaft not be reproduced, except in full,
without the written consent of Pace Analytic1�l Services, Inc..
4
[phone]
Page 19 of 20

eft*a(
w�r.�eoebAcosm
f
Project: 86518
Pace Project No.: 92112744
Pace Anstytkal Services, Inc. P ace Analytical Services, Inc.
205 East Meadow Road - Suite A 2225 Riverside Or.
Eden, NO 27288 Asheville, NO 28804
[phone] [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Lab ID
Sample 10
QC Batch Method
92112744001
$6518
EPA 3535
92112744001
86519
EPA 8151
92112744001
86618
EPA 3010
92112744001
86518
EPA 7470
92112744001
86518
EPA 3510
92112744001
86618
EPA 8260
92112744001
86518
ASTM D2974-87
92112744001
86518
EPA1010
92112744001
86518
SW-846 7.3.4.2
92112744001
$6518
EPA9045
92112744001
86518
SW-846 7,3.3.2
PaceAn&Vkal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NO 28078
[phone]
QC Batch Analytical Method
OEXTI16575
EPA 8081
GCSV/7689
EPA 8151
MPRP/10014
EPA6010
MERP14082
EPA7470
0EXT116574
EPA 8270
MSV/18329
PMST/7017
WET/19986
WET/33797
WET119962
WETAI19399
Analytical
Batch
GCSV/11472
GCSV/5507
ICP/9223
MERCf4006
MSSV/6018
Date: 03/27/2012 01:02 PM REPORT OF LABORATORY �NALYSIS Page 20 of 20
This report shall not be reproduced, elcept in full,
without the written consent of Pace Analyticki Services, Inc..

A & L Eastern Laboratories
7621 Whftepim* Rmd, Rkkmon4 VA 23237-Tol- W-743-W-Fam 804-271-6446-RianU: Offitsoal-labw4neftmeom
"IFIF A-t LF 17-1
r7w". m;lll
I
ISM" mmamm w bmm:
la med forml WavaUN&

Document Name:
Document Revised: Janur 30, 2012
crrArlalyt�cai•
Sample Condition Upon Receipt SCULtL
Page 1 of 2 -
///
Document Number:
issuing Authority:
F-CHR-CS-03-rev.06
Pace Huntersville Quality Office
Client Name: A Project
Where Received: [�Huntersvllle ❑ Asheville ❑ Eden
Courier: 21Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial❑ Pacol Other ,
Custody Seat on Cooler/Box Present: ❑ yes Q! no Seals intact: ❑ yes ❑ no
Packing Material: ❑ Bubble Wrap [?"'Bubble Bags ❑ None ❑ Other
Thermometer Used: iR Gun 11{) T1182 Type of Ice: et Blue !None Q�gamples on Ice, cooling process has begun
i
Temp Correction Factor T1101., No Correction T1102: Subtract 1.2'C
1
Corrected Cooler Temp.: C
Temp should be above freezing to 6'C
Biologics! Tissue Is Frozen; Yes No WA
Comments:
Date and 1 s pera ning
contents:
Chain of Custody Present:
es ❑No
❑NrA
1,
Chain of Custody Filled Out:
Oees ❑No
❑wA
2.
Chain of Custody Relin uished:
X. ❑No
❑wA
3.
Sampler Name b Signature on COC:
Des ON.
❑WA
4.
Samples Arrived within Hold Time:
RlYes ONO
❑NrA
5.
Short Had Time Analysis <72hr :
Dyes CK
❑WA
B,
Rush Turn Around Time R uested:
Dyes 2<
ONIA
7.
Sufficient Volume:
&Sw ❑No
❑WA
B. I
Correct Containers Used:
-Pace Containers Used:
Yes ON.
Dyes 1'JNo
❑WA
DNA
9.
Containers Intact:
12fes l-]w
❑wA
10.
Filtered volume received for Dissolved tests
Oyes ONO
PICA
11.
Sample labels match COC:
-Includes datatfimelID/Anal sis Matrix:
es ON.
❑NrA
12.
All contak► a needing preservation have been checked.
All contalners needing preservation are found to be in
compliance with EPA recommendation.
exceptions: VOA, oolNorm, TOC. OrsG, WI-DRO (water)
L Yes OW A
©Yes ❑Nq!A
©Yes ❑No
13.
V401 wren
completed
Samples checked for deehlorinabon:
Dyes ❑No
wA
14,
Head ace in VOA Vials >&mm :
❑Yes ©No
04
16.
j
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # if purchased):
Dyes ❑No
Dyes ©No
04
O-WA
1&.
Client ldotiticatlonl Resolution:
Person Contacted:
Commentst Resolution:
DatefTime:
Field Data Required? Y 1 N
i
i
SCURF Ravievar:l aj�ff bate: J SRF Revieiwl �" Date: �3 /
Note: Whenevw there is a discrepancy affecting North Carotins oompt€once samples, a c:o�y of this fonn will be sent to the North Carotirsa CEHNR
Certification Offsce (€.e out of hold, boorrecl preservative, out of temp, incorrect containers)

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ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit i m "35595 FwAty Name Gmvme Vatmb, Inc. Soorce PCVMA140. WQOI);tiW } f Caawntt-cs MSD WWVTP
Lab"amy 2
I
Sampk OFcompositeDsse
Pammeter(aWKII) CAMS A Cbm B
karirooerart
i, Tac.
3Jt3}k0t2
Ahrmirmaf, MIA
NIA
t6,331
Aammria Nitsogea, N/A
Ancum; 41
— — Gmdnlnm, 39
f
NIA
7$
85
L,4M
is
F 2
C*kimm, NIA
N/A
16,243
Capper I,W
4,W
3t17
Lead•, 300 `
840
to
MaWaimmi NIA
r
NIA
3.744
1liercttry� 17
37
a34
%*lbtlen N/A
75
5
NicW 420
420
39
Ma>�-Nmdw NaograT-NIA
fiJA
Z3.75
Perceff[SaW NIA
N/A
1.61
pH (so uttifis) NIA
MIA
6.45
— Plaoapb°sm1i NIA
Poussi.l R/A
NIA
NIA
16A95
6,+
PAN (!u}/Eafc ?, NIA
MIA
iS,196
PAN--(5>ej N/A
NIA
t�,�&^~
Sdrcadam 100
Sudium! N/A
m
NIA
5
4772
SAWNIA
1 NIA
1.11
THY, NIA
NIA
39-M
Moc' ZAW I
_i _
,3m
31-91
'g cetti r, andcr pemky of kw, dwt skis docamt of was pmpared under my d3acation or ampervisiao in &Dmdaa,00 with a rystcm designed to
amearc that gmf ed pmoaoel pmpetiy gatketed sod evahmwd the iwtmmadaa submiuod. 1 am aware that awn me a[gm6caat penatoks bar
lahm t iog Use i-fimmadon, ketudiag the poeabibhy of fines sad impnmamcot for kwwing vdoktiam:'
34pw m of Prepare. • I?ate
s'Ptepsaer is dt:tSaed is 40 CFB Pan W& 9(r) and 19A NCAC 2T .1102 ('S6)

AmAGMAN FIELD LOADING ESTIMATES
Facility Contentnea MSD WWTP
Sampling Date 3/13/2012
% Solids 1.61
Mineralization Rate 0.30
Gallons per DT 14,894.92
pH 6.65
Sodium Absorpotion 1.11 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 39,506 lbs./1,000 gal 5.30
Potassium lbs./1,000 gal
0.87
Ammonia Nitrogen (mg/Kg) 1,428,00 lbs./1,000 gal 0.19
Phosphorus lbs./1,000 gal
1.46
Nitrate -Nitrite (mg/Kg) 2,344.64 lbs./1,000 gal 0.31
Calcium lbs./1,000 gal
2.18
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs_/1,000 gal
0.50
PAN (mg/Kg) 14,482 lbs./1,000 gal 1.94
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 15,196 lbs./1,000 gal 2.04
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling Class B Ceiling
Limits (mg/Kg) Limits (mg/Kg)
41 75
39 85
1,500 4,300
300 840
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
a00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
307.00
Copper lbs./1,000 gal
0.04
Lead (mg/Kg)
18.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.34
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
39.00
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1291.00
Zinc lbs./1,000 gal
0.17
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN
PAN
Nitrogen
TKN
(mg/kg) (Ibe/DT)
(mg/Kg)
T
(mg/kg) (]bs/DT)
(mg/Kg)
39,506
14,482
28.96
25,024
39,506
15,196
30,39
24,310
25,024
3,754
7.51
21,270
24,310
3,646
7.29
20,663
21,270
1,595
3,19
19,675
20,663
1,550
3.10
19,114
19,675
738
1.48
18,937
19,114
717
1.43
19,397
18,937
355
0.71
18,582
18,397
345
0.69
18,052
Equations
1st Yr. PAN (mg/Kg)=(MR x CFKN-N113))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr, TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 20,924 41.85
Total 21,454 42.91

a
IT
P.O BOX 7085, 114 OAKMONT DRIVE
GREENVILLE. N.0 27835-7085
C.M.S.D. (SLUDGE & WELLS ACCT)
CONTENTNEA METRO. SEWAGE DIST.
MS. RENEE PRIDGEN
P.D. BOX 477
GRIFTON ,NC 28530
Sludge
Analysis
Method
PARAMETERS
Sample
Date
Analyst
Code
Aluminum, (dry wt. basis), mg/kg
16431
03120/12
LFJ
HPA200.7
Arsenic (dry wt. basis), mgikg
<2.5
03/20/12
CMF
SM3113B
Calcium (dry wt, basis), mgikg
16243
03/20/12
LFJ
E.PA200,7
Cadmium (dry wt. basis), mg/kg
2
03/22/12
CMF
SM3113B
Copper (dry wt. basis), mg/kg
307
03/20/12
LFJ
EPA200.7
Chromium, T,(dry wt. basis),mg/kg
80
03/20/12
LFJ
EPA200.7
Lead (dry weight basis), mg/kg
18
03/21/12
CMF
SM3113B
Magnesium (dry wt. basis), mg/kg
3744
03/20/12
LFJ
EPA200.7
Mercury (dry wt. basis), mg/kg
0.34
03/26/12
ADD
EPA245.1
Nickel (dry wt. basis), mg/kg
39
03/20/12
LFJ
EPA200.7
Potassium (dry wt. basis), mg/kg
6467
03/20/12
LFJ
HPA200.7
Selenium (dry wt. basis), mg/kg
<510
03/23/12
CMF
SM3113B
Sodium (dry wt. basis), mg/kg
4774
03/28/12
ADD
SM3111B
Zinc (dry wt. basis), mg/kg
1291
03130/12
ADD
SM3111B
Total Nitrogen, mglkg
39506
03/2I112
SEJ
Total Solids, %
1.61
03/15/12
MEL
SM2540G
TKN (dry Nvt.), mg/l;g
37161
03/19/12
BJC
FPA351.2
Ammonia Nitrogen (dry wt.),mg/kg
1428
03/I5/12
ANO
FPA350.1
Nitrate Nitrogen(dry wt.), mg/kg
2341
03/16/12
ANO
E?PA353.2
Nitrite Nitrogen(dry wt.), mg/kg
3.64
03/16/12
ANO
EPA353.2
Phosphorus, T. (dry wt.), mg/kg
10895
03/19/12
SEJ
EPA365.4
Molybdenum (dry wt, basis), mg/kg
<5.0
03/20/12
LFJ
EPA200.7
PHONE [phone]
FAX [phone]
ID#: 416
DATE COLLECTED: 03/13/12
DATE REPORTED : 03/30/12
REVIEWED BY:

SGS,�
r-Results of Sludge Sample
Client Sample ID: Sludge Sample
Client Project ID: 416 C.M.S.D.(SludgeMellsAect)
Lab Sample ID: 31200704001-A
Lab Project ID: 31200704
Results by SW-846 826OB-TCLP
Parameter
Result Qual
1,1-Dichloroethene
ND
1,2-Dichloroethane
ND
1,4-Dichlorobenzene
ND
2-Butanone
ND
Benzene
ND
Carbon tetrachloride
ND
Chlorobenzene
ND
Chloroform
ND
Tetrachloroelhene
ND
Trichloroethene
ND
Vinyl chloride
ND
Surrogates
1,2-Dichloroethane-d4
109
4-Bromofluorobenzene
104
Toluene d8
101
;Batch Information
Analyfrcal Balch: VMS2040
Analytical Method: SW-846 B264B-TCLP
Instrument: MSD8
Analyst: DVO
Analytical DalelTirne: 03121/2012 13:57
Print Date: 0312012012
Collection Date: 03/13/2012 09:00
Received Date: 03/16/2012 10:35
Matrix: Water
LQQ/CL
Units
DF
Date Analyzed
10.0
ug1L
10
03/21/2012 13:57
10.0
ug1L
10
03/21/2012 13:57
10.0
uglL
10
03/21/2012 13:57
250
ug/L
10
0312112012 13:57
10.0
ug1L
10
03/21/2012 13:57
10.0
ug1L
10
03/21/2012 13:57
10.0
ug1L
10
03121/2012 13:57
MO
ug1L
10
03/21/2012 13:57
10.0
ug1L
10
03/21/2012 13:57
10.0
ug1L
10
03/21/2012 13:57
10.0
ug1L
10
03121/2012 13:57
64.0-140
%
10
03121/2012 1157
85.0-115
%
10
03/21/2012 1157
82.0-117
%
10
03121/2012 13:57
Prep Dalr-h: LCH1'198
Prep Method: SW-846 1311
Prep DaielTime: 03121120-12 11:09
Prel7 Initial WI,Nni 40 rnt-
Prep Extras! Val: 40 mt-
North llmerica Lx.1%55500 Business Drive, Wilmington, NC 29405
_ t,910.350,1903 f 910 350-1551 www.ussgs.com
N C Certific Lion # 481
Member of SGS Group
Page 4 of 11

E
I
Results of Sludge Sample
t... _ --�
Client Sample ID: '5ludge Sample Collection Date: 03/1312012 09:00
Client Prgject ID:.416 C.M.S.D.(Sludge&WeltsAcct) Received. Date:.03/1612012 10.35
Lab Sample ID: 31200704001-A INatrix: Water
Laba?rojecHl): 31200704
ILI
RestlltS by 0W-0A6 $270t]-TCLP
— - -- ---� -
-- —
-
Parameter
Result Qual
LO=L
Units
DF
IA-Dichlorobenzene
ND
0.0500
mg1L
1
2,4,5-Trict lorophonol
ND
0.0500
mg1L
f
2,4,6-TrinhlorophenO
NO
0.0500
mglL
1
2,4-Dinitrotoluene
ND
0.0500
mg1L
1
s 2-Methylphenot
NO
0.0500
mg1L
1
3 and/or 4-Melhylphenol
ND
0.0500
mg1L
1
Hexachlorobenzene
ND
0.0500
mg1L
1
Hexachlorobutadiene
ND
0.0500
mg1L
1
Hexachloroethane
ND
0.0500
mglL
1
Nitrobenzene
NO
0,0500
mglL
1
Pentachtoro phenol
ND
0.0500
mglL
1
Pyridine
ND
0.0500
mg1L
1
Surrogates
2,4,6-Tribromophenol
94.0
29.3-152
%
1
2-Ffuorobiphenyl
92.1
50.0-107
%
1
2-Fluorophenol
72.2
33.1-118
%
1
Nitrobenzene-d5
91.9
46.0-118
%
1
Phenol-d6
91.3
49.0.120
%
1
Terphenyl-dl4
114
22.1-142
%
1
'Batch Information
_..-.... ,.:...- ._
Analytical Batch, XNiS1459
Prep Batr)i: XXX2370
Analytical Method: SVV-846 8270D-TCLP
Prep Method: S1N-84G 3620C TCLP
Inslnrtnenl: MSDi3
Prep DalelTiirie: 0312.21.2012
'14:49
Anatyst. CtMP
Prep Initial WI.Nol.:
10o m1_
Analytical Dalefiinle' 03127120.12 03:22
i
Prep Extracl Vol: 61nL.
Date Analyzed
03/27/2012 3:22
03/27/2012 3:22
03/27/2012 3,22
03/2712012 3:22
03/27/2012 3:22
03/2712012 3:22
03/27/2012 3:22
03/27/2012 3:22
03/27/2012 3:22
03/27/2012 3:22
03/27/2012 3:22
03/27/2012 3:22
03/27/2012 3:22
03/27/2012 3:22
03127/2012 3:22
03/27/2012 3:22
03/2712012 3:22
03/2712012 3:22
Prit) tDa1e: 0312W2012 tLC Corfifcaiianiddtii
SGS;dnr,I;Amcricilnr,
5500 Basiness 0rKe, Wilmington, NC 28405
t 103 .1403f910.350.1557 wwwu. rom,�„_
Member of SGS Group
Page 5 of 11

i
'Results of Sludge Sample
Client Sample ID: S!1096 Sample Collect€on.Date: 03/1312012 09:00
Client Project ID::414 iC'MS.D,(Studge&Well&Aect), Received Date: :0311612012 •10,35
.1 pmple 1D:.312U0704001 A " Matrix: Wafer
Lab Prnlent; I D: 31200704 .1.
Results by SW-846 6010C -TCLP
Parameter _ �., Result f i LO /CL Units DF DateAnalvzed
Arsenic ND 0.100 mg/L 1 03123/2012 18:13
Barium ND 1.00 mg/L 1 03/23/2012 18:13
Cadmium ND 0.0500 mg1L 1 03/2612012 13:22
Chromium ND 0.100 mg/L 1 03/23/2012 18:13
Lead ND 0.100 mglL 1 03/2612012 13,22 i
Selenium ND 0.200 rng/L 1 03/23/2012 18:13
Silver ND GA00 mg/L 1 0312MO12 18:13 '
Batch Information
Analytical Batch: MIP1473
Analy€ical ivleihod: SW-046 601UC -TCLP
Inslrunenl: ICP-1
Analyst: PSW
Aslalytioal bale/Time: a312312012 18:13
Analytical Hatch: MIP1474
Analytical Method: 5W-1146 6MG -TCLP
InSlrumen€: iGN
Analyst: PSW
Analytical Dalefrinie: (13126120-12 13.22
Prep Batch: MXX-1083
Prep Method: SW-846 3010A TUP
Prej) Dater€me: 0312212012 10:18
Prep Initial W[.IVol.: 5 n-rt.
Preto Extract Vol: 50 mL
Prep Ralah: MXX1983
Prep Niietfi0d: SVY-846 30-IflA TCLP
Prep Bale/Time: 03122/2012 io:9a
P rep Initial WLIVol.: 6 mt.
Prep Extract Vol: 50 mL
S
1
Prim tale. 03/2W2012 M G. Ce]fiSr- for) /t 481
SGS hdor[h amet ir.� tilt. Business Drive, Wilmington, K 28405
,♦� ��17 �� 1 f g10 3 01557 s sns.com _ _ _
wWMber of SGS GMUP
Page 6 of 11

S.GS
r Results of Sludge Sample
Client Sample ID: Sludge Sample
Client Project ID: 416 C.M.S.D.(Sludge&WellsAcct)
Lab Sample ID: 31200704001-A
Lab Project ID: 31200704
,Results by SW-846 7470A-TCLP
Parameter Result Qual
Mercury ND
;Batch Information
Analylical galch: MHG1218
Analytical Methnd: SW-846 7470A-TCLP
Instrument: HG2
Anafyst NTM
Analylical Date/Time: 03/2312012 15:33
i
Collection Date: 03/13/2012 09:00
Received Date: 03/16/2012 10.35
Matrix: Water
LOQICL Units OF Date Analyzed
0.000300 mglL 1 03/2312012 15:33
Prep Baich: MXX1889
Prep Mclhad: SW-846 7470A PREP TCLP
Prep DatnfTinne: 03/2312012 10:19
Prep Initial WI./Val.: 20 rnL
Prep Fxlraal vat. .57 rnL
Print r3ale 03/2912012
5500 Business prive, Wilmington, NC 28405
5G5 Nsrth firm rira Inc, _ t 10350,1903 f.910�3`01553 www,ussgs,[om �____
NC Certiricalion # 01
Member of SG5 Group
Page 7 of 11

sil
SG,
..-
. .. ... ... . .... ......
lResults of Sludge Sample w
Client Sample ID; -Sludge 5atnple Collection Date: 03/13/2012.09,00
Client Project ID 416 C,M.S.D,�Sludge&Vlfglls,4ccty :Received Date: 03116C1012 10:35
`Lab Sample ID::3120070400.1-A Matrix.:Water
Laf�'Project ID. 3120Q704
................... ... :..
Results by SW-846 8081 E-TCLP
Parameter Result Qual L_ QQ1CL Units DF Date Analyzed
Chlordane ND 0.0100 mglL 1 03/28/2012 19:46
Endrirt NU 0.00300 mg11- 1 03128t2012 19:46
j
Heptachlor ND 0.00300 rng/L 1 03128/2012 19.46
Heptachlor epoxide ND 0.00300 rng1L 1 03/28/2012 19:46 ':
Methoxychlor ND 0.00300 mg/L 1 03/28/2012 19:46
i Tozapherle N€} 0.0100 mg/L 1 03/28/2012 19:46
gamma-SHC (Lindane) NU 0.00300 mg1L 1 03/28/2012 19:46
Surrogates
Dibutylchlorendate 89.0 30.0-139 % 1 03128/2012 19:46
a_ ;Batatr Information
�Analyl€col Ballot: XGC2038 Prep Batch: XXX2382 i
' Analylicat Method: SW-846 8081t3-TCLP Prep Metho& SW4446 35200 TCLP
1 instrunienC E1703 Prep Daterrime: 03126/2012 14- 44
t AnalysL DTF Prep InitiM lA t.Noi.: 50 mL i
Analytical Date/Time: 03/2812012 M46 Prep Extract Vol: G mL
s
I ,
t
4
a
h.
Print Dale: 03/2912012
5500 Bus€Hess ArWe, Mmington, NC 28405
Sc>5 North rinierfs:i inr, 0.3 M f 9Y0.350 7 u
Member of 5Gi Group
Page 8 of 11

i
I
E
i
i
1
Results of Sludge Sample-
Client:5arnple ID :Sludge Sample mCollection Date: 03/13/2012.09:00
A. Client PrajectlD:: 416C,M.S,D.(Sludge&WellsAeCt). Received: ate: 03/{612012 10:35..
Lab Sarnpie ID.:31200704001-R Mz.atrix:'Watec
.,... . .
:.Lab Project ID::31200704
_....................... .
-iResuIts by SW$46 8151A -TCLP
aramefer It Quaff L ni s DF Date Analyzed
2,4'-D N.D 400 uglL 1 03/26/2012 12:10
2,4,5-TP(Silvex) N.D 100 uo1911n
Surrogates
DCAA
93.0
Latch Information
Analytical Batch: XGC2028
Analytical Method: SW-8498151A -TCLP
Instrumenl: EC04
Analysi: DTF
Anaivticat DaWTirrme: OM2.612012 42-1ff
Prml Date: 03/29/2012
i
i
35.0-135 % 1 0312612012 12:10
Peep Batch: XXX2374
Prep Metlsad: SW-846 3510C -rCf.p
Prep Date/Tile: 03/2312012 -11;23
Prep Initial Wt.1VOL. 6 FIA, i
Prep Extract Vo[: 5 rnL
i
i
i
SC;S Narllt AFnerica Inc.
5S00 Business Drive, Wilmington, NC 28405
MemberolSGS Group
I
a
Page 9 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WL Peril No. WQW35595 Facility Name (ir<inville ]arms, Inc, Source Pen -nit No. NCIHI29033
Laboratory tj tJrrsc Rivrr A1uL H—t,
IC'lC''i'P[ah Iabs, Inc
Lahoratory 2
Sam pie
Parameter (mg/Kg)
orCompositeDaic
Class A Clas D
N/A .- N/A
1/17/2012
- - 13,R37
12/5/2RI2
17,5Q9)
�- Aluminum
Ammonia Nitrogen
N/A N/A
R,51)9
10211
Arsenic
41 75
4.3
5
Cadmium
39 85
1
2
Calcium
N/A N/A
15,102
Ispill
Copper
1,500 4,300
2523
369
Lead
300 840
17.2
2e
Magnesium
N/A I N/A
51)47
4,970
Mercury
17 57
L25
L2
Molyhdenum
N/A 75
4.6
11
Nickel
420 420
1,14
32
Nitrate -Nitrite Nitrogen
N/A N/A
15
11,1 u11
Percent Solids
N/A N/A
3,7R
3.9R
pH (no units)
N/A N/A
6 d5
4.94
Phosphorus
N/A N/A
15,162
52,IW1
Potassium
N/A N/A
G55)
G9811
PAN (Surface)
N/A N/A
13,977
77.32.1
PAN (Inj./Inc.)
N/A N/A
9,423
25,114
Selenium
Io0 109
5
5
Sodium
N/A N/A
3,87.1
11,7041
SAR
N/A N/A
1.31
5.93
Total Nitrogen
N/A N/A
26,353
$-ijuo
Zinc
2,800 7,500
.13R.I
I R15
"I certify, under penalty
of law, that
this document
was prcpai
assure that qualified
personnel properly
gathered
and CVAIt12tt
submitting False information,
l" 1
incI d''�ig
/1 . //
the possibility
of fines
Soorec Namc NL'LISC River WWII
ed under my direction nr supervision in accordance with a system designed to
d the information submitted. I am aware that (here are significant penalties for
and imprisonment for knowing violations,"
Signature of Prepiref;' Date
*Preparer is defined in 40 CFR Part 503.9(r) and I5A NCAC 2T A102 (26)

AGMAN FIELD LOADING ESTIMATES
d
Facility Neuse River VA I`P
Sampling Date 1/17/2012
% Solids 3.78
Mineralization Rate 0.3
Gallons per DT 6,344.13
PH 6.46
Sodium Absorpotion L31 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 26,353 lbs./1,000 gal 8.31
Potassium lbs./1,000 gal
2.07
Ammonia Nitrogen (mg/Kg) 8,509.00 lbs./1,000 gal 2,68
Phosphorus lbs./1,000 gal
14.24
Nitrate -Nitrite (mg/Kg) 15.00 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
4.76
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
1.87
PAN (mg/Kg) 9,623 lbs./1,000 gal 3.03
Manganese lbs./1,000 gal
0.25
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 13,877 lbs./1,000 gal 4.37
Molybdenum lbs./1,000 gal
0,00
Volatization Rate= 0.5 Surface application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
4!
1 St Year
2nd Year
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.30
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
252.30
Copper lbs./1,000 gal
0.08
Lead (mg/Kg)
17.20
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
1.25
Mercury tbs. /1,000 gal
0.00
Nickel (mg/Kg)
13.40
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
438.10
Zinc lbs./1,000 gal
0.14
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
76,353
9,62-3 19.25
16,730
26,353
13,877 27.75
12,476
16,730
2,510 5.02
14,221
12,476
1,871 3.74
10,604
14,221
1,067 2.13
13,154
10,604
795 1.59
9,809
13,154
493 0.99
12,661
9,809
368 0.74
9,441
17,661
237 0.47
12,424
9,441
177 0.35
9,264
Equations
1st Yr. PAN (mg/Kg)=(MR x (1'KN-N1I3))+(VR x N143)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4tb Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5tb Yr. TKN x (MR/ 16)
Total 13,929 27.86
Total 17,089 34.18

City of Raleigh Neuse River VI►W Lab
WW Certification # 51/ EPA Lab Code NC01029
Laboratory Report of Analysis
Sample Origination: Covered Aerobic Di ester
L;,
. I. I I1,„f-ii`i
1 I' it I Ir II
,. , 'I 'll�,;•,
C'i �, ,.I
[lsl
Ia'r'I'''IdmJ �- l Z.�., '- -:h:I
G
,
I U' III
'II'l!li I. Il ail 1
I. ''
` ,l;P `
,•I'. [
, wlE I
r.l :I
1.
Z
r _ i.' I' , 'f
II"' 1.
,
,:ik-�i II' •
''
;
;-_F-'� II
'
,..;;.
a I
'I
I
I;:i'
I,I
+
fN�.�,''V
O
-„'ON�t, , ' I .,
�5
- ..;
� V I
it ;I I' l•:l�l�"a ;, VR !V .i,'Z lII III�;, ar' i0
lr41+i ,I
•r��,LE•fl'.
�In. ai.�l�.�il,
I it 'f I, ••I .
Mg
mglkg`L
;I
R►99 i
rR9�-
msftS�L.'
`!i99R'jr4m91L
•
I mgllig
111120'12
I
1 ry2a1'2 � I
I r r
I
�.I
I
I
i
I LI
113/2012
1� 4�Q;1�2 ,
I rl ' I ',;I;
_ I; `i ; :j
3's
i
� i •
, ,I
,.
,,`
:, '� ..I
I• I
I rig I''! , ` .
1/5/2012
,11� +.D�2 I�I
.,i `
,[ I' I
I:'
I
1 3.,
I •' I
'!- _ I
' I
.! 1.�
•,
1/712012
1/912012
,111112012
?l1lGiF.V,�� ,I
I,
..II
�
'•I.:
�' I I"' 141� I
1 I '
I I.. �I
I''' '.
I •
i
'
11112012
1 /1
y5,QO122
171;.1 V/201.2..
1.. J
''I' '
''• Li
'.II ICI �'
' i ' I
II'- ' ' I '
, � ' , I1
I, . I
�
,
I ,
„
" -
,,I _ ,,
�', - ji.
1/1712012
AD4C801182012
3.78
996
26,353
1,707
45,162
322
8,509
1
15
364
9,623
525
13,877
I '
1119/2012
1/20j2012;•
{
;
G
,
1/21/2012
i1727�2412
I
�
I
,
112312D12
1124l2012
AD3C801182012
;,.,' '`4:06
;i ,1:566
38,57;1:
`' 1`,915
47,17;7
:: 391
9;639.
' 29
I . 718
577.
'1�t;2:1:7
-.773
15;037:
1125 /2012
1/27/2012
1/2912012
1i3012012;
1/31/2012
Minimum
3.78
996
26,353
1,707
46,162
322
8,509
1
151
364
9,623
525
13,877
nrlaximu' '
rnr..
1
.. r
406:
1 566
.I, �38;571
, 1,!, 91,5,
`.: 47;477
: 391
"'I 9:639
29
718
` 577
'' 14 21"7
. - 77.3
' f9 037
Average
3.921
1,281
32,462
1,811
46,169
356
9,074
151
366
470
11.920
649
16,457
Darrell Crews Date
Laboratory Supervisor

City of Raleigh Neuse River 1NWTP Lab
WW Certification # 51/ EPA Lab Code NC01029
Darrell Crews date
Laboratory Supervisor
Laboratory Report of Analysis
Sample Origination Covered Aerobia Dlaestefi

City of Raleigh Neuee River WVVTP Lab
VVW Certification # 51/ EPA Lab Code NCO1029
mOg
_ . m t4
1/112012
-
1/3/2012
.114
1/512012
1/7/2012
1181202--""_
-
1/9/2012
111.R12412
-
-
111//2012
- -
1/1312012
-
_- -
—_ -
----- --
1/1512012
!A-8/2012
1/1712012
AD4CB01182012
6.600
13.400
6,558.600
8700
3,874.300
IM912012
112072012
112112012
112312012
1124/2012 :- -
AMBUT182072
-
`= 6'900
_ 1E4`200
7,387:040
9.400
4;656.900
1/25/20121/27/2012
1126124'I2-_
12
1/29/2012
---_
-
-
1/3112012
Minimum
6.600
13.400
6,558.600
8.700
3,874,300
6 900
4.200
7. 07.�00
9 400
. 4,$5ti 900
Average
13.750
13.800
6,972,800
9.050
4,265.600
503 Gelting Conc -.-
=--'
_ -75
503 EQ
17
420
% 503 EQ
39.71
3.29
Darrell Craws Date
Laboratory Supervisor

Page: i of 2
Report Number: 12-341-0209
Account Number: 45691
Submitted By: SCOTT CARPENTER
Send To: GRANVILLE FARMS INC
POB 1396
OXFORD, NC 27565
Lab Number: 90728
Sample Id : NR120512
A &L Eastem Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax (804) 271-SW
www,aleastem.com
Project: 200708.A10-NEUSE RIVER WWTP CLASS B
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 12/5/2012 00:00:00
Date Received: 12/06/2012 00:00
Date Reported: 12/13/2012
Total Solids
3.98
39800
100.0
JM
12/06/2012 15:29
SM-254OG
Moisture "
96.02
100.0
JM
12/06/2012 15:29
SM-254OG
Total Kjeldahl Nitrogen
4.47
44700
10.0
JM
12/07/2012 07:50
SM-4500-NH3C-TKN
Total Phosphorus
5.21
52100
100
BW
12/07/2012 08:15
SW 6010C
Total Potassium
0.70
6980
100
BW
12/07/2012 08:15
SW 6010C
Total Sulfur
1.16
11600
100
BW
12/07/2012 08:15
SW 6010C
Total Calcium
1.56
15600
100
BW
12/07/2012 08:15
SW 6010C
Total Magnesium
0.50
4970
100
BW
12/07/2012 08:15
SW 6010C
Total Sodium
1.67
16700
100
BW
12/07/2012 08:15
SW 6010C
Total Iron
73700
100
BW
12/07/2012 08:15
SW 6010C
Total Aluminum
17500
100
BW
12/07/2012 08:15
SW 6010C
Total Manganese
1170
5
BW
12/07/2012 08:15
SW 6010C
Total Copper
369
5
BW
12/07/2012 08:15
SW 6010C
Total Zinc
815
5
BW
12/07/2012 08:15
SW 6010C
Ammonia Nitrogen
0.40
4020
10.0
JM
12/07/2012 07:50
SM-4500-NH3C
Organic N
4.07
40680
10.0
12/07/2012 07:50
CALCULATION
Nitrate+Nitrite-N
11100
2.00
JM
12/07/2012 07:50
SM-450ONO3F
Total Cadmium
2.0
2.0
BW
12/07/2012 08:15
SW 6010C
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters er: for the excitesive and confidential fir , _f our clients. and may not be reproduced in whole cr part. i. w n i y ;ny i of rer t, mach
to the work. the results, or the ccmpany in any aciv . rti. ;nn new ratea<:�, r other public enrounc ;inonts H.thout nhtahwng our prior written authorb gtion.
Debbie Holt

Page: 2 of 2
Report Number: 12-341-0209
Account Number: 45691
Submitted By: SCOTT CARPENTER
Send To: GRANVILLE FARMS INC
POB 1396
OXFORD, NC 27565
Lab Number: 90728
Sample Id: NR120512
L A &L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 (804) 743-S401 Fax {804) 271-6446
www aleastem.com
Project: 200708.A10-NEUSE RIVER WWTP CLASS B
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 12/5/2012 00:00:00
Date Received: 12/06/2012 00:00
Date Reported: 1211312012
Total Chromium
85
5
BW
12/07/2012 08:15
SW 601 OC
Total Nickel
32
5
BW
12/07/2012 08:15
SW 601 OC
Total Lead
26
5
BW
12/07/2012 08:15
SW 601 OC
Total Arsenic
5.0
3.0
BW
12/07/2012 08:15
SW 601 OC
Total Mercury
1.2
0.4
KM
12/07/2012 09:00
SW-7471 B
Total Selenium
<5.0
5.0
BW
12/07/2012 08:15
SW 601 OC
pH (Standard Units) *
4.94
2.00
JM
12/07/2012 07:50
SW-9045D
Total Molybdenum
11
5
BW
12/07/2012 08:15
SW 601 OC
Soluble Phosphorus
0.49 4900
100
JM
12/07/2012 12:20
SOLUBLE P IN MANURE
Comments:
SULFUR, SOLUBLE PHOSPHORUS AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
THE MATRIX SPIKE WAS OUT OF LIMITS FOR "N031NO2-Wand "Fe". ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our fepnrfs and letters are for the exclusive an , conffdenfisf us: of our clients. and may net be reproduced in wh :le or part: not may my reference be made
to tb - work, the rewits• or th s r mpany in day advertisin nsw•s rale.se; or other public announcements without oblaininj our prior irritten authorization.
Debbie Holt

*ESC
1
Emily Fentress
City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
Report Summary
Thursday March 01, 2012
Report Number: L562159
Samples Received: 02/24/12
Client Project:
Descri
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have any
questions regarding this data package, please do not hesitate to call.
Entire Report Reviewed By:
'Linda Cashman ESC Representative
Laboratory Certification Numbers
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197,
FL - E87497, GA - 923, IN C--TN-01, KY - 90010, KYUST - 0016,
NC - ENV375/DW21704/BI0041, ND - R-140, NJ - TN002, NJ NELAP - TN002,
SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612,
MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1,
TX - T104704245-11-3, OK - 9915, PA - 68-02979
Accreditation is only applicable to the test methods specified on each scope of accreditation held
by ESC Lab Sciences.
Note: The use of the preparatory EPA Method 3511 is not approved or endorsed by the CA ELAP.
This report may not be reproduced, except in full, without written approval from HSC Lab Sciences.
Where applicable, sampling conducted by EEC is performed per guidance provided
in laboratory standard operating procedures: 060302, 060303, and 060304.
Page 1 of 9

REPORT OF ANALYSIS
Emily Fentress
City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
12065 Lebanon Rd.
Mt. auliet, TN 37122
[phone]
I-800-767-5859
Fax [phone]
Tax I.D. 62-0614289
Est. 1970
March 01,2D12
ESC Sample
# L562159-01
Date Received February 24,
2012
Description
Site SD
Sample ID DEWATERE➢ PRIMARY
Project
Collected By E. Fentress
Collection Date 02/23/12 09c05
Parameter
Result Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Corrosivity
Non-Ccrrosiv
9045D
02/28/12
1130
DJD
1
Ignitability
See Footnote
Deg. F
D93/101
02/27/12
1303
CJM
1
Reactive CN (SW846 7.3.3.2)
BDL
0.125
mg/kg
9012B
02/28/12
1517
1
Reactive Sulf.(SW846 7.3.4.1)
BDL
25.
mg/kg
9034/90
02/26/12
1530
MCG
1
TCLP Extraction
1311
02/26/12
0704
MVE
I
Mercury
BDL
0.0010
mg/1
0.20
7470A
02/28/12
1004
MDC
1
Arsenic
BDL
0.050
mg/1
5.0
6010B
02/27/12
0040
ZCS
1
Barium
BDL
0.15
mg/1
100
6010E
02/27/12
0040
ZCS
1
Cadmium
BDL
0.050
mg/1
1.0
6010B
02/27/12
0040
ZCS
1
Chromium
BDL
0.050
mg/1
5.0
6010E
02/27/12
0040
ZCS
1
Lead
BDL
0.050
mg/1
5.0
6010B
02/27/12
0040
ZCS
1
Selenium
BDL
0,050
mg/1
1.0
6010E
02/27/12
0040
ZCS
1
Silver
BDL
0.050
mg/1
5.0
6010E
02/27/12
0040
ZCS
1
TCLP ZHE Extraction
1311
02/27/12
0900
LJN
1
TCLP Volatiles
Benzene
BDL
0.050
mg/1
0.50
8260E
02/27/12
1930
DP
1
Carbon tetrachloride
BDL
0.050
mg/1
0.50
8260E
02/27/12
1930
DP
1
Chlorobenzene
BDL
0.050
mg/1
100
8260E
02/27/12
1930
DP
1
Chlcro€orm
BDL
0.25
mg/1
6.0
8260B
02/27/12
1930
DP
1
1,2-Dichloroethane
BDL
0.050
mg/1
0.50
8260B
02/27/12
1930
DP
1
l,I-Dichloroethene
BDL
0.050
mg/1
0.70
B26013
02/27/12
1930
DP
1
2-Butanone (MEK)
BDL
0.50
mg/1
200
8260E
03/01/12
0335
DAH
1
Tetrachloroethene
BDL
0.050
mg/1
0.70
8260E
03/01/12
0335
DAH
1
Trichloroethene
BDL
0.050
mg/1
0.50
8260E
03/01/12
0335
DAH
1
vinyl chloride
BDL
0.050
mg/1
0.20
8260B
02/27/12
1930
DP
I
Surrogate Recovery
Toluene-d8
103.
e Rec.
114.
8260B
02/27/12
1930
DP
I
Dibromoflucromethane
98.7
% Rec.
125.
8260E
02/27/12
1930
DP
1
a,a,a-Trifluorotoluene
105.
& Rec.
114.
8260E
02/27/12
1930
DP
1
4-Bromofluorobenzene
102.
%, Rec.
128.
8260B
02/27/12
1930
DP
1
TCLP Pesticides
Chlordane
BDL
0.0050
mg/1
0.030
8081A
02/23/12
1117
ADF
1
Endrin
BDL
0.0050
mg/1
0.020
8081A
02/29/12
1117
ADF
1
Heptachlor
BDL
0.0050
mg/1
0.0080
8081A
02/29/12
1117
ADF
1
L562159-01 (IGNITABILITY) - Did Not Ignite G 170 F
Page 2 of 5