20140957 Ver 2_Drilling Fluid Additives - Fishing Creek_20180820 (16)

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Submit by Anonymous User 8/20/2018 4:06:35 PM (Message Start Event)
Accept by Montalvo, Sheri A 8/21/2018 11:48:39 AM (NON -DOT - Existing Project)
The task was assigned to Montalvo, Sheri A. The due date is: August 23, 2018 5:00 PM
8/20/2018 4:06 PM

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20140957
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Project Submittal Dated 8/20/2018
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ACP Drilling Fluid Additives - Fishing Creek HDD
2.25MB
Crossing.pdf
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Documentation of the composition and properties of drilling fluid additives (SDS) for the ACP Fishing Creek
HDD crossing submitted by ACP General Contractor Spring Ridge Constructors (SRC) and Subcontractor
Oz Directional Drilling (OZDD).
V By checking the box and signing box below, I certify that:
o I have given true, accurate, and complete information on this form;
o I agree that submission of this form is a "transaction" subject to Chapter 66, Article 40 of the NC General Statutes (the
"Uniform Electronic Transactions Act")
• I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes
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o I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written
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MATERIAL SAFETY DATA SHEET
Product Trade Name:BARA-KADE® PLUS BENTONITE
Revision Date:20-Dec-2011
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Trade Name:BARA-KADE® PLUS BENTONITE
Synonyms:None
Chemical Family:Mineral
Application:Additive
Manufacturer/Supplier BENTONITE Performance Minerals LLC
3000 N Sam Houston Parkway East
Houston, TX 77032
Telephone: [phone]
Fax: [phone]
Emergency Telephone: [phone]
Prepared By Chemical Compliance
Telephone: [phone]
e-mail: [e-mail]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA
Bentonite 1302-78-9 60 - 100%Not applicable Not applicable
Crystalline silica, cristobalite 14464-46-1 0 - 1%0.025 mg/m3 1/2 x 10 mg/m3
%SiO2 + 2
Crystalline silica, tridymite 15468-32-3 0 - 1% 0.05 mg/m
3 1/2 x 10 mg/m3
%SiO2 + 2
Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m
3 10 mg/m3
%SiO2 + 2
More restrictive exposure limits may be enforced by some states, agencies, or other authorities.
3. HAZARDS IDENTIFICATION
Hazard Overview CAUTION! - ACUTE HEALTH HAZARD
May cause eye and respiratory irritation.
DANGER! - CHRONIC HEALTH HAZARD
Breathing crystalline silica can cause lung disease, including silicosis and lung
cancer. Crystalline silica has also been associated with scleroderma and kidney
disease.
This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposures below
recommended exposure limits. Wear a NIOSH certified, European Standard EN
149, or equivalent respirator when using this product. Review the Material Safety
Data Sheet (MSDS) for this product, which has been provided to your employer.
BARA-KADE® PLUS BENTONITE
Page 1 of 7
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Treat symptomatically.
5. FIRE FIGHTING MEASURES
Flash Point/Range (F):Not Determined
Flash Point/Range (C):Not Determined
Flash Point Method:Not Determined
Autoignition Temperature (F):Not Determined
Autoignition Temperature (C):Not Determined
Flammability Limits in Air - Lower (%):Not Determined
Flammability Limits in Air - Upper (%):Not Determined
Fire Extinguishing Media All standard firefighting media.
Special Exposure Hazards Not applicable.
Special Protective Equipment for
Fire-Fighters
Not applicable.
NFPA Ratings:Health 0, Flammability 0, Reactivity 0
HMIS Ratings:Health 0*, Flammability 0, Physical Hazard 0 , PPE: E
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment. Avoid creating and breathing dust.
Environmental Precautionary
Measures
None known.
Procedure for Cleaning /
Absorption
Collect using dustless method and hold for appropriate disposal. Consider possible
toxic or fire hazards associated with contaminating substances and use appropriate
methods for collection, storage and disposal.
7. HANDLING AND STORAGE
Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposure below
recommended exposure limits. Wear a NIOSH certified, European Standard En 149,
or equivalent respirator when using this product. Material is slippery when wet.
Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.
Close container when not in use. Do not reuse empty container.
BARA-KADE® PLUS BENTONITE
Page 2 of 7
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits listed in Section 2.
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by
an industrial hygienist or other qualified professional based on the specific
application of this product.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (95%)
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:Solid
Color:Various
Odor:Odorless
pH:8-10
Specific Gravity @ 20 C (Water=1):2.65
Density @ 20 C (lbs./gallon):Not Determined
Bulk Density @ 20 C (lbs/ft3):50-70
Boiling Point/Range (F):Not Determined
Boiling Point/Range (C):Not Determined
Freezing Point/Range (F):Not Determined
Freezing Point/Range (C):Not Determined
Vapor Pressure @ 20 C (mmHg):Not Determined
Vapor Density (Air=1):Not Determined
Percent Volatiles:Not Determined
Evaporation Rate (Butyl Acetate=1):Not Determined
Solubility in Water (g/100ml):Insoluble
Solubility in Solvents (g/100ml):Not Determined
VOCs (lbs./gallon):Not Determined
Viscosity, Dynamic @ 20 C (centipoise):Not Determined
Viscosity, Kinematic @ 20 C (centistrokes):Not Determined
Partition Coefficient/n-Octanol/Water:Not Determined
Molecular Weight (g/mole):Not Determined
10. STABILITY AND REACTIVITY
Stability Data:Stable
Hazardous Polymerization:Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to
Avoid)
Hydrofluoric acid.
BARA-KADE® PLUS BENTONITE
Page 3 of 7
Hazardous Decomposition
Products
Amorphous silica may transform at elevated temperatures to tridymite (870 C) or
cristobalite (1470 C).
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational
sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in
experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory
passages. Breathing silica dust may not cause noticeable injury or illness even
though permanent lung damage may be occurring. Inhalation of dust may also have
serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection
below).
Skin Contact May cause mechanical skin irritation.
Eye Contact May cause eye irritation.
Ingestion None known
Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and
bronchitis, or subject to eye irritation, should not be exposed to quartz dust.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a
progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms
include cough, shortness of breath, wheezing, non-specific chest illness, and
reduced pulmonary function. This disease is exacerbated by smoking. Individuals
with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has
determined that crystalline silica inhaled in the form of quartz or cristobalite from
occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to
humans) and has determined that there is sufficient evidence in experimental
animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to
humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres
(June 1997) in conjunction with the use of these minerals. The National Toxicology
Program classifies respirable crystalline silica as "Known to be a human carcinogen".
Refer to the 9th Report on Carcinogens (2000). The American Conference of
Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints
such as scleroderma (an immune system disorder manifested by scarring of the
lungs, skin, and other internal organs) and kidney disease.
Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"
published by the American Thoracic Society Medical Section of the American Lung
Association, American Journal of Respiratory and Critical Care Medicine, Volume
155, pages 761-768 (1997).
Toxicity Tests
BARA-KADE® PLUS BENTONITE
Page 4 of 7
Oral Toxicity:Not determined
Dermal Toxicity:Not determined
Inhalation Toxicity:Not determined
Primary Irritation Effect:Not determined
Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June
1997).
Genotoxicity:Not determined
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air)Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity:TLM96: 10000 ppm (Oncorhynchus mykiss)
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity:Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
DOT
Not restricted
Canadian TDG
Not restricted
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
BARA-KADE® PLUS BENTONITE
Page 5 of 7
Sea Transportation
IMDG
Not restricted
Other Transportation Information
Labels:None
15. REGULATORY INFORMATION
US Regulations
US TSCA Inventory All components listed on inventory or are exempt.
EPA SARA Title III Extremely
Hazardous Substances
Not applicable
EPA SARA (311,312) Hazard
Class
Acute Health Hazard
Chronic Health Hazard
EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical
Release Reporting" under Section 313 (40 CFR 372).
EPA CERCLA/Superfund
Reportable Spill Quantity
Not applicable.
EPA RCRA Hazardous Waste
Classification
If product becomes a waste, it does NOT meet the criteria of a hazardous waste as
defined by the US EPA.
California Proposition 65 The California Proposition 65 regulations apply to this product.
MA Right-to-Know Law One or more components listed.
NJ Right-to-Know Law One or more components listed.
PA Right-to-Know Law One or more components listed.
Canadian Regulations
Canadian DSL Inventory All components listed on inventory or are exempt.
WHMIS Hazard Class Crystalline silica
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Not applicable
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.
BARA-KADE® PLUS BENTONITE
Page 6 of 7
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
BARA-KADE® PLUS BENTONITE
Page 7 of 7
SAFETY DATA SHEET
Product Trade Name:BAROGROUT
Revision Number: 2Revision Date:02-Jun-2015
Product Trade Name:
Internal ID Code
2.1 Classification in accordance with paragraph (d) of §1910.1200
1.3 Manufacturer's Name and Contact Details
HM008064
BAROGROUT
Manufacturer/Supplier Baroid Industrial Drilling Products
Product Service Line of Halliburton
P.O. Box 1675
Houston, TX 77251
Telephone: [phone] or 1-877-379-7412
Emergency Telephone: [phone]
Carcinogenicity Category 1A - H350
Specific Target Organ Toxicity - (Repeated Exposure)Category 1 - H372
1. Identification
Prepared By
2.2. Label Elements
Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
Synonyms:
1.2 Recommended use and restrictions on use
Hazard Pictograms
None
1.1. Product Identifier
1.4. Emergency telephone number
Application:Grouting Material
Emergency Telephone Number [phone]
Signal Word Danger
Chemical Family:
Uses Advised Against No information available
Mineral
_____________________________________________________________________________________________
2. Hazard(s) Identification
Page 1 / 10
_____________________________________________________________________________________________
BAROGROUT Revision Date: 02-Jun-2015
CAS Number PERCENT (w/w)GHS Classification - US
Crystalline silica, quartz 14808-60-7 30 - 60%Carc. 1A (H350)
STOT RE 1 (H372)
H350 - May cause cancer
H372 - Causes damage to organs through prolonged or repeated exposure
Crystalline silica, cristobalite 14464-46-1 0.1 - 1%Carc. 1A (H350)
STOT RE 1 (H372)
Contains
Substances CAS Number
Response
The exact percentage (concentration) of the composition has been withheld as proprietary.
P308 + P313 - IF exposed or concerned: Get medical advice/attention
Crystalline silica, quartz 14808-60-7
Crystalline silica, cristobalite
4. First-Aid Measures
14464-46-1
4.1. Description of first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Storage
2.3 Hazards not otherwise classified
Ingestion Under normal conditions, first aid procedures are not required.
P405 - Store locked up
None known
Prevention
4.2 Most important symptoms/effects, acute and delayed
Carcinogen. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica
has also been associated with scleroderma and kidney disease. Prolonged or repeated exposure may cause damage
to organs.
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P280 - Wear protective gloves/protective clothing/eye protection/face protection
4.3. Indication of any immediate medical attention and special treatment needed
Hazard Statements
3. Composition/information on Ingredients
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations
_____________________________________________________________________________________________
Precautionary Statements
Page 2 / 10
Substances
_____________________________________________________________________________________________
Revision Date: 02-Jun-2015BAROGROUT
See Section 8 for additional information
7.1. Precautions for Safe Handling
5. Fire-fighting measures
Handling Precautions
This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid
breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below
recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when
using this product. Material is slippery when wet.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
5.3 Special protective equipment and precautions for fire-fighters
Suitable Extinguishing Media
All standard fire fighting media
6.2. Environmental precautions
5.2 Specific hazards arising from the substance or mixture
7.2. Conditions for safe storage, including any incompatibilities
Special Protective Equipment for Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Prevent from entering sewers, waterways, or low areas.
Storage Information
Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use.
Do not reuse empty container. Store in a dry location. Store in a well ventilated area. Product has a shelf life of 12
months.
Notes to Physician
6. Accidental release measures
Special Exposure Hazards
None anticipated
8. Exposure Controls/Personal Protection
6.3. Methods and material for containment and cleaning up
Extinguishing media which must not be used for safety reasons
None known.
Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated
with contaminating substances and use appropriate methods for collection, storage and disposal.
8.1 Occupational Exposure Limits
5.1. Extinguishing media
Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA
Crystalline silica, quartz 14808-60-7 TWA: 10 mg/m3
%SiO2 + 2
TWA: 0.025 mg/m3
6.1. Personal precautions, protective equipment and emergency procedures
Crystalline silica, cristobalite 14464-46-1 TWA: 1/2 x 10 mg/m3
%SiO2 + 2
TWA: 0.025 mg/m3
Treat symptomatically.
7. Handling and storage
Use appropriate protective equipment. Avoid creating and breathing dust.
_____________________________________________________________________________________________
Page 3 / 10
_____________________________________________________________________________________________
Revision Date: 02-Jun-2015BAROGROUT
upper flammability limit No data available
Eye Protection Wear safety glasses or goggles to protect against exposure.
lower flammability limit No data available
Personal Protective Equipment
Evaporation rate No data available
If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Other Precautions
Vapor Pressure No data available
None known.
Vapor Density No data available
Specific Gravity 2.6
Water Solubility Partly soluble
Solubility in other solvents No data available
Respiratory Protection
Partition coefficient: n-octanol/water No data available
Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (N95, P2/P3)
Property
Autoignition Temperature No data available
Values
Decomposition Temperature No data available
Remarks/ - Method
Viscosity No data available
9. Physical and Chemical Properties
Explosive Properties No information available
pH:No data available
Oxidizing Properties No information available
Hand Protection Normal work gloves.
Freezing Point/Range No data available
9.2. Other information
VOC Content (%)No data available
Melting Point/Range No data available
Engineering Controls
8.3 Individual protection measures, such as personal protective equipment
10. Stability and Reactivity
Boiling Point/Range No data available
9.1. Information on basic physical and chemical properties
Skin Protection
10.1. Reactivity
Flash Point No data available
Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.
Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits.
Flammability (solid, gas)No data available
8.2 Appropriate engineering controls
Odor:Odorless
Physical State:Powder
_____________________________________________________________________________________________
Color:Gray to Blue
Page 4 / 10
Odor
Threshold:
No information available
_____________________________________________________________________________________________
Revision Date: 02-Jun-2015BAROGROUT
Principle Route of Exposure Eye or skin contact, inhalation.
10.4. Conditions to Avoid
10.6. Hazardous Decomposition Products
11.2 Symptoms related to the physical, chemical and toxicological characteristics
Not expected to be reactive.
10.3. Possibility of Hazardous Reactions
Acute Toxicity
Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
None anticipated
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational
sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence
in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory
passages. Breathing silica dust may not cause noticeable injury or illness even
though permanent lung damage may be occurring. Inhalation of dust may also
have serious chronic health effects (See "Chronic Effects/Carcinogenicity"
subsection below).
Stable
Eye Contact May cause mechanical irritation to eye.
Skin Contact May cause mechanical skin irritation. Can dry skin.
Ingestion None known.
Will Not Occur
11. Toxicological Information
10.2. Chemical Stability
10.5. Incompatible Materials
_____________________________________________________________________________________________
Page 5 / 10
11.1 Information on likely routes of exposure
Hydrofluoric acid.
_____________________________________________________________________________________________
Revision Date: 02-Jun-2015BAROGROUT
Mechanical irritation of the eyes is possible.
No data available No data available
Crystalline silica, cristobalite 14464-46-1 Mechanical irritation of the eyes is possible.
Chronic Effects/Carcinogenicity
Crystalline silica,
cristobalite
14464-46-1
Substances CAS Number Skin Sensitization
>15,000 mg/kg (Human)No data available
Crystalline silica, quartz 14808-60-7 No information available.
No data available
Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a
progressive, disabling, and sometimes-fatal lung disease called silicosis.
Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness, and reduced pulmonary function. This disease is exacerbated by smoking.
Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has
determined that crystalline silica inhaled in the form of quartz or cristobalite from
occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to
humans) and has determined that there is sufficient evidence in experimental
animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to
humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic
Fibres (June 1997) in conjunction with the use of these minerals. The National
Toxicology Program classifies respirable crystalline silica as "Known to be a
human carcinogen". Refer to the 9th Report on Carcinogens (2000). The
American Conference of Governmental Industrial Hygienists (ACGIH) classifies
crystalline silica, quartz, as a suspected human carcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints
such as scleroderma (an immune system disorder manifested by scarring of the
lungs, skin, and other internal organs) and kidney disease.
Crystalline silica, cristobalite 14464-46-1 No information available
Toxicology data for the components
11.3 Toxicity data
Substances CAS Number Respiratory Sensitization
Substances
Crystalline silica, quartz 14808-60-7 No information available
CAS Number Skin corrosion/irritation
Crystalline silica, cristobalite 14464-46-1 No information available
Substances CAS Number
Crystalline silica, quartz 14808-60-7
Substances CAS Number Mutagenic Effects
Non-irritating to the skin
LD50 Oral
Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
LD50 Dermal
Crystalline silica, cristobalite
Crystalline silica, cristobalite 14464-46-1 Not regarded as mutagenic.
14464-46-1 Non-irritating to the skin
LC50 Inhalation
Substances CAS Number Carcinogenic Effects
Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The
IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity of
crystalline silica with repeated respiratory exposure. Based on available scientific evidence, this
substance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary to
lung injury.
Crystalline silica, quartz
Substances CAS Number Eye damage/irritation
_____________________________________________________________________________________________
14808-60-7 >15,000 mg/kg (Human)
Page 6 / 10
Crystalline silica, quartz 14808-60-7
_____________________________________________________________________________________________
Revision Date: 02-Jun-2015BAROGROUT
Product Ecotoxicity Data
No data available
Crystalline silica, cristobalite
Substances CAS Number STOT - repeated exposure
Substance Ecotoxicity Data
14464-46-1 No information available
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Toxicity to Invertebrates
Crystalline silica, quartz 14808-60-7
Crystalline silica,
quartz
14808-60-7 No information available LL0 (96h) 10,000 mg/L
(Danio rerio) (similar
substance)
No information available LL50 (24h) > 10,000 mg/L
(Daphnia magna) (similar
substance)
Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Crystalline silica, cristobalite
Crystalline silica,
cristobalite
14464-46-1 No information available LL0 (96h) 10,000 mg/L
(Danio rerio) (similar
substance)
No information available LL50 (24h) > 10,000 mg/L
(Daphnia magna) (similar
substance)
Substances
Crystalline silica, cristobalite 14464-46-1 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
CAS Number Reproductive toxicity
Crystalline silica, quartz 14808-60-7 No information available
Substances CAS Number
Crystalline silica, cristobalite 14464-46-1 The methods for determining biodegradability are not
applicable to inorganic substances.
Aspiration hazard
Substances CAS Number
Crystalline silica, quartz
12.3. Bioaccumulative potential
14808-60-7 Not applicable
STOT - single exposure
14464-46-1
Substances CAS Number Log Pow
Crystalline silica, cristobalite 14464-46-1
Crystalline silica, quartz 14808-60-7 No information available
Not applicable
Crystalline silica, cristobalite 14464-46-1 No information available
Crystalline silica, quartz 14808-60-7
12.4. Mobility in soil
No significant toxicity observed in animal studies at concentration requiring classification.
Crystalline silica, quartz 14808-60-7
Substances CAS Number Mobility
12. Ecological Information
Crystalline silica, cristobalite
Crystalline silica, quartz 14808-60-7 No information available
14464-46-1
12.1. Toxicity
Crystalline silica, cristobalite 14464-46-1 No information available
No significant toxicity observed in animal studies at concentration requiring classification.
No information available
Ecotoxicity Effects
_____________________________________________________________________________________________
Page 7 / 10
Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The
IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity of
crystalline silica with repeated respiratory exposure. Based on available scientific evidence, this
substance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary to
lung injury.
_____________________________________________________________________________________________
Revision Date: 02-Jun-2015BAROGROUT
Environmental Hazards:Not applicable
UN Proper Shipping Name:Not restricted
Follow all applicable national or local regulations.
IMDG/IMO
Transport Hazard Class(es):
UN Number:Not restricted
Not applicable
No information available
UN Proper Shipping Name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
Environmental Hazards:Not applicable
14. Transport Information
IATA/ICAO
UN Number:Not restricted
UN Proper Shipping Name:Not restricted
US DOT Bulk
Transport Hazard Class(es):Not applicable
13.1. Waste treatment methods
Packing Group:Not applicable
DOT (Bulk)
Environmental Hazards:Not applicable
Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable
Special Precautions for User: None
12.5 Other adverse effects
Canadian TDG
Disposal Method
US DOT
15. Regulatory Information
UN Number:Not restricted
Bury in a licensed landfill according to federal, state, and local regulations.
US Regulations
UN Proper Shipping Name:Not restricted
US TSCA Inventory All components listed on inventory or are exempt.
UN Number:
Transport Hazard Class(es):Not applicable
Not restricted
13. Disposal Considerations
_____________________________________________________________________________________________
Packing Group:Not applicable
Page 8 / 10
Contaminated Packaging
_____________________________________________________________________________________________
BAROGROUT Revision Date: 02-Jun-2015
EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical
Release Reporting" under Section 313 (40 CFR 372).
NJ Right-to-Know Law One or more components listed.
EPA RCRA Hazardous Waste
Classification
16. Other information
If product becomes a waste, it does NOT meet the criteria of a hazardous waste
as defined by the US EPA.
Chronic Health Hazard
Preparation Information
PA Right-to-Know Law One or more components listed.
Prepared By Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
Revision Date:02-Jun-2015
EPA SARA Title III Extremely
Hazardous Substances
California Proposition 65
Reason for Revision Update to Format
SECTION:
2
The California Proposition 65 regulations apply to this product.
Additional information
For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.
EPA CERCLA/Superfund
Reportable Spill Quantity
Canadian Regulations
Not applicable.
Not applicable
MA Right-to-Know Law
_____________________________________________________________________________________________
One or more components listed.
Canadian DSL Inventory
Page 9 / 10
All components listed on inventory or are exempt.
EPA SARA (311,312) Hazard
Class
_____________________________________________________________________________________________
Revision Date: 02-Jun-2015BAROGROUT
End of Safety Data Sheet
Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.
_____________________________________________________________________________________________
Key or legend to abbreviations and acronyms
bw – body weight
CAS – Chemical Abstracts Service
EC50 – Effective Concentration 50%
ErC50 – Effective Concentration growth rate 50%
LC50 – Lethal Concentration 50%
LD50 – Lethal Dose 50%
LL50 – Lethal Loading 50%
mg/kg – milligram/kilogram
mg/L – milligram/liter
NIOSH – National Institute for Occupational Safety and Health
NTP – National Toxicology Program
OEL – Occupational Exposure Limit
PEL – Permissible Exposure Limit
ppm – parts per million
STEL – Short Term Exposure Limit
TWA – Time-Weighted Average
UN – United Nations
h - hour
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
w/w - weight/weight
d - day
Key literature references and sources for data
www.ChemADVISOR.com/
Page 10 / 10
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name MAGMA-FIBER - FINE
Version #03
Revision date 19-December-2008
Chemical name Man-Made Mineral Fiber
Chemical description Fabric/Mat
CAS #Mixture
Supplier Drilling Mud Direct, LLC
8 Inverness Drive East, Suite 245
Englewood, CO 80112
2. Hazards Identification
OSHA regulatory status This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Eyes Dust or powder may irritate eye tissue.
Skin Prolonged and/or repeated skin contact may result in mild irritation or redness. No components in
this product are known to be absorbed through the skin.
Inhalation Inhalation of dusts may cause respiratory irritation.
Ingestion No significant adverse effects are expected upon ingestion of the product.
Components CAS # Percent
3. Composition / Information on Ingredients
Non-hazardous and other components below reportable levels > 0.1
65997-17-3 90 - 100GLASS, OXIDE
4. First Aid Measures
First aid procedures
Eye contact Immediately flush eyes with plenty of water for at least 20 minutes. If irritation persists get
medical attention.
Skin contact Wash affected area with mild soap and water. Get medical attention if irritation develops or
persists.
Inhalation If exposed to excessive levels of dusts or fumes, remove to fresh air and get medical attention if
cough or other symptoms develop.
Ingestion No need for first aid is anticipated if material is swallowed.
Notes to physician Provide general supportive measures and treat symptomatically.
5. Fire Fighting Measures
Flammable properties None known.
Extinguishing media
Suitable extinguishing
media
Dry chemical, CO2, water spray or regular foam. Use any media suitable for the surrounding fires.
Hazardous combustion
products
None known.
6. Accidental Release Measures
Environmental precautions No special environmental precautions required.
Material name: MAGMA-FIBER - FINE MSDS US
1 / 4
Phone: [phone]
Methods for containment None necessary.
Methods for cleaning up Vacuum or sweep up material and place in a disposal container. Avoid the generation of dusts
during clean-up. Reduce airborne dust and prevent scattering by moistening with water.
7. Handling and Storage
Handling Keep formation of airborne dusts to a minimum. Avoid breathing dusts from this material. Provide
appropriate exhaust ventilation at places where dust is formed. Do not get this material in your
eyes, on your skin, or on your clothing.
Storage Guard against dust accumulation of this material. Keep in a dry, cool and well-ventilated place.
8. Exposure Controls / Personal Protection
Engineering controls Good general ventilation should be sufficient to control airborne levels. Use process enclosures,
local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
Personal protective equipment
Eye / face protection Wear safety glasses with side shields.
Skin protection Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory protection Use a particulate filter respirator for particulate concentrations exceeding the Occupational
Exposure Limit.
General hygeine
considerations
Use good industrial hygiene practices in handling this material. Wash hands before breaks and
immediately after handling the product. Keep working clothes separately.
9. Physical & Chemical Properties
Appearance Fibers.
Color White to tan.
Odor Slight.
Odor threshold Not available.
Physical state Solid.
Form Not available.
pH Not available.
Melting point 2102 °F (1150 °C)
Freezing point Not available.
Boiling point Not available.
Flash point Not available.
Evaporation rate Not available.
Flammability Not available.
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Vapor pressure Not available.
Vapor density Not available.
Specific gravity 2.6
Relative density Not available.
Solubility (water)Insoluble
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
VOC 0 % estimated
Percent volatile 0 % estimated
10. Chemical Stability & Reactivity Information
Chemical stability Stable at normal conditions. No hazards to be especially mentioned.
Material name: MAGMA-FIBER - FINE MSDS US
2 / 4
Conditions to avoid None known.
Incompatible materials This product reacts with acids.
Hazardous decomposition
products
Thermal decomposition can lead to release of irritating gases and vapors.
Possibility of hazardous
reactions
Will not occur.
11. Toxicological Information
Not available.
12. Ecological Information
Ecotoxicity No data available for this product. This material is not expected to be harmful to aquatic life.
Environmental effects No data available for this product. Based on the physical properties of this product, significant
environmental persistence and bioaccumulation would not be expected.
Persistence and degradability Not available.
13. Disposal Considerations
Disposal instructions Dispose in accordance with all applicable regulations.
14. Transport Information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations OSHA Process Safety Standard: This material is not known to be hazardous by the OSHA Highly
Hazardous Process Safety Standard, 29 CFR 1910.119.
CERCLA (Superfund) reportable quantity
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely
hazardous substance
No
Section 311 hazardous
chemical
No
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
NoAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
NoChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of New and Existing Chemicals (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Material name: MAGMA-FIBER - FINE MSDS US
3 / 4
Country(s) or region Inventory name On inventory (yes/no)*
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations WARNING: This product contains a chemical known to the State of California to cause cancer.
16. Other Information
Further information This safety datasheet only contains information relating to safety and does not replace any product
information or product specification.
0
0
/0
HMIS ratings
NFPA ratings Health: 0
Flammability: 0
Instability: 0
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The manufacturer expressly does not make
any representations, warranties, or guarantees as to its accuracy, reliability or completeness nor
assumes any liability, for its use. It is the user's responsibility to verify the suitability and
completeness of such information for each particular use.
Third party materials: Insofar as materials not manufactured or supplied by this manufacturer are
used in conjunction with, or instead of this product, it is the responsibility of the customer to
obtain, from the manufacturer or supplier, all technical data and other properties relating to these
and other materials and to obtain all necessary information relating to them. No liability can be
accepted in respect of the use of this product in conjunction with materials from another supplier.
Issue date 19-December-2008
Material name: MAGMA-FIBER - FINE MSDS US
4 / 4
SAFETY DATA SHEET
Product Trade Name:BORE-GROUT

Revision Date:14-Aug-2017 Revision Number: 7
1. Identification
1.1. Product Identifier
Product Trade Name:BORE-GROUT
Synonyms None
Chemical Family:Mineral
Internal ID Code HM006781
1.2 Recommended use and restrictions on use
Application:Grouting Material
Uses advised against No information available
1.3 Manufacturer's Name and Contact Details
Manufacturer/Supplier
Baroid Industrial Drilling Products
Product Service Line of Halliburton Energy Services, Inc.
P.O. Box 1675
Houston, TX 77251
Telephone: [phone] or 1-877-379-7412
Halliburton Energy Services, Inc.
645 - 7th Ave SW Suite 1800
Calgary, AB
T2P 4G8
Canada
Prepared By Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
1.4. Emergency telephone number:
Emergency Telephone Number 1-866-519-4752 or 1-760-476-3962
Global Incident Response Access Code: 334305
Contract Number: 14012
2. Hazards Identification
2.1 Classification in accordance with paragraph (d) of §1910.1200
Carcinogenicity Category 1A - H350
Specific Target Organ Toxicity - (Repeated Exposure)Category 1 - H372
2.2. Label Elements
Hazard Pictograms
_____________________________________________________________________________________________
Page 1 / 10
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
Signal Word:Danger
Hazard Statements H350 - May cause cancer by inhalation
H372 - Causes damage to organs through prolonged or repeated exposure if
inhaled
Precautionary Statements
Prevention P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P280 - Wear protective gloves/protective clothing/eye protection/face protection
Response P308 + P313 - IF exposed or concerned: Get medical advice/attention
P314 - Get medical attention/advice if you feel unwell
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations
2.3 Hazards not otherwise classified
This product contains Wyoming bentonite or other sorptive clays. Crystalline silica forms found in this particular clay are limited to
quartz. Extreme temperatures that can generate cristobalite or tridymite are not expected to occur under realistic conditions. In
addition, all quartz found in sorptive clays are considered “occluded”, i.e., strongly coated with an amorphous silica surface.
Occluded quartz has been experimentally-determined to be relatively non-toxic compared to unoccluded quartz. A lack of health
effects found in several studies examining occupational exposure to sorptive clays also suggest that chronic inhalation of sorptive
clays is not expected to result in silicosis or cancer. In light of these findings OSHA has recently exempted Wyoming bentonite and
other sorptive clays from the crystalline silica PEL in §1910.1053(a)(1)(iii).
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w)GHS Classification - US
Crystalline silica, quartz 14808-60-7 1 - 5%Carc. 1A (H350)
STOT RE 1 (H372)
The exact percentage (concentration) of the composition has been withheld as proprietary.
4. First Aid Measures
4.1. Description of first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
4.2 Most important symptoms/effects, acute and delayed
_____________________________________________________________________________________________
Page 2 / 10
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also
been associated with scleroderma and kidney disease.
4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
5. Fire-fighting measures
5.1. Extinguishing media
Suitable Extinguishing Media
All standard fire fighting media
Extinguishing media which must not be used for safety reasons
None known.
5.2 Specific hazards arising from the substance or mixture
Special exposure hazards in a fire
None anticipated
5.3 Special protective equipment and precautions for fire-fighters
Special protective equipment for firefighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Use appropriate protective equipment. Avoid creating and breathing dust.
See Section 8 for additional information
6.2. Environmental precautions
Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up
Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated
with contaminating substances and use appropriate methods for collection, storage and disposal.
7. Handling and storage
7.1. Precautions for safe handling
Handling Precautions
This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid
breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below
recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when
using this product. Material is slippery when wet.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Information
Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use.
Do not reuse empty container. Product has a shelf life of 12 months.
8. Exposure Controls/Personal Protection
_____________________________________________________________________________________________
Page 3 / 10
8.1 Occupational Exposure Limits
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA
Crystalline silica, quartz 14808-60-7 TWA: 50 µg/m3 TWA: 0.025 mg/m3
Exposures to crystalline silica that result from bentonite or other sorptive clays are exempt from the PEL in §1910.1053. The PEL
in §1910.1000 Table Z–3 (i.e., the formula that is approximately equivalent to 100 µg/m3) applies to occupational exposures to
respirable crystalline silica from sorptive clays.
8.2 Appropriate engineering controls
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits.
8.3 Individual protection measures, such as personal protective equipment
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values
Remarks/ - Method
pH:8-10
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Flammability (solid, gas)No data available
Upper flammability limit No data available
Lower flammability limit No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.6
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information
VOC Content (%)No data available
Physical State:Powder Color Tan
Odor:Mild earthy Odor
Threshold:
No information available
_____________________________________________________________________________________________
Page 4 / 10
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
10. Stability and Reactivity
10.1. Reactivity
Not expected to be reactive.
10.2. Chemical stability
Stable
10.3. Possibility of hazardous reactions
Will Not Occur
10.4. Conditions to avoid
None anticipated
10.5. Incompatible materials
Hydrofluoric acid.
10.6. Hazardous decomposition products
Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
11. Toxicological Information
11.1 Information on likely routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation.
11.2 Symptoms related to the physical, chemical and toxicological characteristics
Acute Toxicity
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational
sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence
in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory
passages. Breathing silica dust may not cause noticeable injury or illness even
though permanent lung damage may be occurring. Inhalation of dust may also
have serious chronic health effects (See "Chronic Effects/Carcinogenicity"
subsection below).
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a
progressive, disabling, and sometimes-fatal lung disease called silicosis.
Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness, and reduced pulmonary function. This disease is exacerbated by smoking.
Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has
determined that crystalline silica inhaled in the form of quartz or cristobalite from
occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to
humans) and has determined that there is sufficient evidence in experimental
animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to
humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres
(June 1997) in conjunction with the use of these minerals. The National Toxicology
_____________________________________________________________________________________________
Page 5 / 10
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
Program classifies respirable crystalline silica as "Known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American
Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline
silica, quartz, as a suspected human carcinogen (A2). There is some evidence
that breathing respirable crystalline silica or the disease silicosis is associated with
an increased incidence of significant disease endpoints such as scleroderma (an
immune system disorder manifested by scarring of the lungs, skin, and other
internal organs) and kidney disease.
This product contains Wyoming bentonite or other sorptive clays. Crystalline silica
forms found in this particular clay are limited to quartz. Extreme temperatures that
can generate cristobalite or tridymite are not expected to occur under realistic
conditions. In addition, all quartz found in sorptive clays are considered
“occluded”, i.e., strongly coated with an amorphous silica surface (Wendlandt et
al., 2007; Hochella and Muryama, 2010; SMI, 2014). Occluded quartz has been
experimentally-determined to be relatively non-toxic compared to unoccluded
quartz (Geh et al., 2006; Creutzenberg et al., 2008). A lack of health effects found
in several studies examining occupational exposure to sorptive clays also suggest
that chronic inhalation of sorptive clays is not expected to result in silicosis or
cancer (Waxweiler et al., 1988; ACGIH, 1991; USEPA, 1996; IARC, 2005). In light
of these findings OSHA has recently exempted Wyoming bentonite and other
sorptive clays from the crystalline silica PEL in §1910.1053(a)(1)(iii).
11.3 Toxicity data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human)No data available No data available
Substances CAS Number Skin corrosion/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CAS Number Serious eye damage/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the eye
Substances CAS Number Skin Sensitization
Crystalline silica, quartz 14808-60-7 No information available.
Substances CAS Number Respiratory Sensitization
Crystalline silica, quartz 14808-60-7 No information available
Substances CAS Number Mutagenic Effects
Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CAS Number Carcinogenic Effects
Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The
IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity of
crystalline silica with repeated respiratory exposure.
Substances CAS Number Reproductive toxicity
Crystalline silica, quartz 14808-60-7 No information available
Substances CAS Number STOT - single exposure
Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number STOT - repeated exposure
Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CAS Number Aspiration hazard
Crystalline silica, quartz 14808-60-7 Not applicable
_____________________________________________________________________________________________
Page 6 / 10
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
12. Ecological Information
12.1. Toxicity
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Toxicity to Invertebrates
Crystalline silica,
quartz
14808-60-7 EC50 (72 h) =440 mg/L
(Selenastrum
capricornutum)(similar
substance)
LL0 (96 h) =10000 mg/L
(Danio rerio)(similar
substance)
No information available LL50 (24 h) >10000 mg/L
(Daphnia magna)(similar
substance)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Crystalline silica, quartz 14808-60-7 The methods for determining biodegradability are not
applicable to inorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Crystalline silica, quartz 14808-60-7 No information available
12.4. Mobility in soil
Substances CAS Number Mobility
Crystalline silica, quartz 14808-60-7 No information available
12.5 Other adverse effects
No information available
13. Disposal Considerations
13.1. Waste treatment methods
Disposal methods If practical, recover and reclaim, recycle, or reuse by the guidelines of an
approved local reuse program. Should contaminated product become a waste,
dispose of in a licensed industrial landfill according to federal, state, and local
regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
US DOT
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
Canadian TDG
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
_____________________________________________________________________________________________
Page 7 / 10
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
IMDG/IMO
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
IATA/ICAO
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
US Regulations
US TSCA Inventory All components listed on inventory or are exempt.
TSCA Significant New Use Rules - S5A2
Substances CAS Number TSCA Significant New Use Rules - S5A2
Crystalline silica, quartz 14808-60-7 Not applicable
EPA SARA Title III Extremely Hazardous Substances
Substances CAS Number EPA SARA Title III Extremely Hazardous
Substances
Crystalline silica, quartz 14808-60-7 Not applicable
EPA SARA (311,312) Hazard Class
Chronic Health Hazard
EPA SARA (313) Chemicals
Substances CAS Number Toxic Release Inventory (TRI) -
Group I
Toxic Release Inventory (TRI) -
Group II
Crystalline silica, quartz 14808-60-7 Not applicable Not applicable
EPA CERCLA/Superfund Reportable Spill Quantity
Substances CAS Number CERCLA RQ
Crystalline silica, quartz 14808-60-7 Not applicable
EPA RCRA Hazardous Waste Classification
If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA.
California Proposition 65
Substances CAS Number California Proposition 65
Crystalline silica, quartz 14808-60-7 carcinogen
U.S. State Right-to-Know Regulations
Substances CAS Number MA Right-to-Know Law NJ Right-to-Know Law PA Right-to-Know Law
Crystalline silica, quartz 14808-60-7 Carcinogen
Extraordinarily hazardous
1660 Present
NFPA Ratings:Health 0, Flammability 0, Reactivity 0
HMIS Ratings:Health 0*, Flammability 0, Physical Hazard 0 , PPE: E
_____________________________________________________________________________________________
Page 8 / 10
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
Canadian Regulations
Canadian Domestic Substances
List (DSL)
All components listed on inventory or are exempt.
16. Other information
Preparation Information
Prepared By Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
Revision Date:14-Aug-2017
Reason for Revision SDS sections updated:
1
2
8
11
Additional information
For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheet
bw – body weight
CAS – Chemical Abstracts Service
d - day
EC50 – Effective Concentration 50%
ErC50 – Effective Concentration growth rate 50%
h - hour
LC50 – Lethal Concentration 50%
LD50 – Lethal Dose 50%
LL50 – Lethal Loading 50%
mg/kg – milligram/kilogram
mg/L – milligram/liter
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
NIOSH – National Institute for Occupational Safety and Health
NTP – National Toxicology Program
OEL – Occupational Exposure Limit
PEL – Permissible Exposure Limit
ppm – parts per million
STEL – Short Term Exposure Limit
TWA – Time-Weighted Average
UN – United Nations
w/w - weight/weight
Key literature references and sources for data
www.ChemADVISOR.com/
_____________________________________________________________________________________________
Page 9 / 10
Disclaimer Statement
_____________________________________________________________________________________________
BORE-GROUT Revision Date: 14-Aug-2017
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 10 / 10
Safety Data Sheet
ClayBreaker
SDS – CB - (Revision Date 5/15/15) Page 1 of 5
1. PRODUCT AND COMPANY IDENTIFICATION

PRODUCT IDENTIFIER: ClayBreaker
PRODUCT NAME: Quaternary Ammonium Compound

RECOMMENDED USE: Clay stabilizer in industrial applications

SUPPLIER: DCS Fluid Solutions, LP
P.O. Box 1027
Graham, TX 76450
[phone]

24-HOUR EMERGENCY TELEPHONE: [phone]

2. HAZARDS IDENTIFICATION

CLASSIFICATION: Acute toxicity 4, Oral

SIGNAL WORD: Warning

HAZARD STATEMENTS: Harmful if swallowed.

SYMBOLS:

PRECAUTIONARY Do not eat, drink or smoke when using this product.
STATEMENTS: Wash thoroughly after handling.
Avoid contact with eye, skin and clothing.
Wear protective gloves, splash apron, safety glasses or chemical safety goggles.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water. Wash
contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If you feel unwell, or irritation of eye/skin persists, call a POISON CENTER or physician.
Store locked up in closed containers at moderate temperatures.
Dispose of contents and container in accordance with local, state, and federal regulations.

3. COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL NAME: CAS No.: WEIGHT %:
Trade secret Trade secret 25
Water 7732-18-5 75

Safety Data Sheet
ClayBreaker
SDS – CB - (Revision Date 5/15/15) Page 2 of 5
4. FIRST-AID MEASURES

General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where
possible). If breathing has stopped, trained personnel should begin rescue breathing or, if the heart has stopped, immediately, start
cardiopulmonary resuscitation (CPR) or automated external defibrillator.

Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty
persists.

Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if
irritation develops or persists.

Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present, and easy to do. Continue rinsing.
Obtain medical attention if irritation persists.

Ingestion: Rinse mouth. Do NOT induce vomiting. Get immediate medical attention.

Note to physician: No specific treatment. Treat according to symptoms present.

5. FIREFIGHTING MEASURES

Extinguishing Media:
Suitable Extinguishing Media: Use appropriate extinguishing media for the surrounding fire. The product is not
flammable.
Unsuitable Extinguishing Media: Not applicable.
Specific Hazards:
No unusual fire or explosion hazards noted.
Special Protective Equipment and Precautions for Fire-Fighters:
Fire-fighters should wear full fire-fighting gear including self-contained breathing apparatus.
Keep containers cool using water spray or fog.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions:
Avoid contact with skin, eyes and clothing. Provide adequate ventilation. Use personal protective equipment (PPE) specified
in Section 8.
Environmental Precautions:
Prevent spilled material from entering sewers, storm drains and public waters.
Methods for Containment:
Stop spill/release if it can be done safely. Contain spills with dikes of sand, earth or other absorbents to prevent migration
and entry into the environment and waterways. Local authorities should be advised if significant spillages cannot be
contained.
Methods for Cleanup:
Clean up spills immediately. Keep area well ventilated. Flush area with water. Do NOT wash into sewer. Recover as much of
the solution as possible by vacuum. Absorb remaining solution with inert, non-combustible material. Place in suitable
salvage containers. Dispose of waste in accordance with local, state and federal regulations in a chemical waste landfill.

Safety Data Sheet
ClayBreaker
SDS – CB - (Revision Date 5/15/15) Page 3 of 5
7. HANDLING AND STORAGE

Handling Precautions:
Always wear recommended personal protection equipment. Do not get in eyes, on skin or clothing. Do not swallow. Use
with adequate ventilation. Eating, drinking and smoking in work areas is prohibited.

Hygienic Work Practices:
Use good personal hygiene practices. Wash hands and skin thoroughly after handling. Promptly remove contaminated
clothing and wash before reuse. Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.

Storage Precautions:
Keep containers tightly closed and properly labeled. Store in cool, dry, well-ventilated area away from heat, sources of
ignition and direct sunlight. Keep container closed when not in use. Keep in original container. Store containers in upright
position. Since emptied containers retain product residue, follow hazard precautions even when empty.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Limits:
No Occupational Exposure Limits (OELs) have been established for this product or its chemical components.

Appropriate Engineering Controls:
Ensure adequate ventilation.
Emergency eye wash and safety showers should be available in the immediate vicinity of any potential exposure.

Personal Protective Equipment:
Eye Protection – Wear chemical safety glasses or safety googles.
Skin Protection – Wear chemical resistant gloves and splash apron.
Respiratory Protection – Ensure adequate ventilation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colorless to amber liquid
Odor: Very faint
Odor Threshold: Not available
pH: 6.5 to 9.0
Melting Point/Freezing Point: Not available / 16° F
Boiling Point: >212° F
Flash Point: >201° F
Evaporation Rate: Not available
Flammability: Not available
Upper Flammability Limit: Not available
Lower Flammability Limit: Not available
Vapor Pressure: Not available
Vapor Density: Not available
Relative Density: 1.01 - 1.03 Specific Gravity
Solubility: Complete in water
Partition Coefficient: Not available
Auto-Ignition Temperature: Not available
Decomposition Temperature: Not available
Viscosity: Not available
Safety Data Sheet
ClayBreaker
SDS – CB - (Revision Date 5/15/15) Page 4 of 5
10. STABILITY AND REACTIVITY

Reactivity: Hazardous reactions will not occur under normal conditions.
Chemical Stability: Stable under normal conditions.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Avoid temperatures exceeding flash point and contact with incompatible material.
Incompatible Materials: Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products: Irritants. Toxic gas. Hydrogen chloride. May include oxides of carbon & nitrogen.

11. TOXICOLOGICAL INFORMATION

Routes of Exposure:
Inhalation: Prolonged inhalation may be harmful.
Ingestion: Harmful if swallowed. May cause nausea, vomiting, diarrhea or more severe symptoms.
Skin Contact: Not a dermal irritant.
Eye Contact: Not an ocular irritant.

Acute Toxicity: Harmful is swallowed
LD50 and LC50: Acute LD50: 1000 – 4000 mg/kg, Rat, Oral
Respiratory or Skin Sensitization: No data available
Carcinogenicity: Not considered a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive Toxicity: Not expected to be hazardous by OSHA criteria.
Germ Cell Mutagenicity: No data available
Specific Target Organ Toxicity – Single Exposure: No data available
Specific Target Organ Toxicity – Repeated Exposure: No data available
Aspiration Hazard: Not classified

12. ECOLOGICAL INFORMATION

Ecotoxicity: Not classified
Persistence and Degradability:
ClayBreaker has a biodegradation percentage of 85.2% and is considered to have ready biodegradability. Test of ready
biodegradability are stringent tests that provide limited opportunity for acclimation and biodegradation to occur. A positive
result in a test of ready biodegradability is an indication that the test substance will undergo rapid and ultimate
biodegradation in the environment. OECD Guideline 301B has set the standard for ready biodegradability at 60%.
ClayBreaker exceeds this standard for environmental friendliness.
Bioaccumulative Potential: Not established
Mobility in Soil: No data available
Other Adverse Effects: No adverse environmental effects are expected from this product.

13. DISPOSAL CONSIDERATIONS

Follow approved local beneficial reuse guidelines for uncontaminated spent drilling fluids. If contaminated, dispose of in a licensed
industrial landfill according to local, state and federal regulations. If released to the environment for other than its intended
purpose, this product does not meet, in its present state, the definition of a hazardous waste under 40 CFR 261. Under RCRA it is the
responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria for hazardous
waste. Waste management should be in full compliance with federal, state and local laws.
Empty containers retain product residue which may exhibit hazards of material. Do not use for other purposes. Return containers to
reclamation centers for proper cleaning and reuse.
Safety Data Sheet
ClayBreaker
SDS – CB - (Revision Date 5/15/15) Page 5 of 5
714. TRANSPORTATION INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION (DOT):
Not regulated as dangerous goods.

CANADIAN TRANSPORTATION OF DANGEROUS GOODS (TDG):
Not regulated as dangerous goods.

IMDG:
Not regulated as dangerous goods.

IATA:
Not regulated as dangerous goods.

15. REGULATORY INFORMATION

OSHA: This product is listed as a hazardous material under the criteria of Federal OSHA Hazard Communication Standard, 29 CFR
1910.1200. We request that you make all information in the Material Safety Data Sheet available to your employees.

TSCA: All components are on the TSCA Inventory List.

CERCLA: No reportable quantity.

SARA TITLE III:
Extremely Hazardous Substance (EHS): No
Section 312 (Tier II) Ratings: Immediate (acute) health hazard
Section 313: Not applicable

RCRA: No

Canada WHMIS: Not on inventory

16. OTHER INFORMATION

CURRENT ISSUE DATE: May 15, 2015
Updated to comply with new GHS standard and SDS requirements of OSHA Hazard Communication Standard 29 CFR 1910.1200.

DCS Fluids Solutions, LP believes the information contained in this material safety data sheet is accurate based on the information supplied by reputable suppliers of
our raw materials. We cannot make any assertions as to its reliability or completeness; therefore, the user may rely on it only at user’s risk. We have made no effort
to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this information and product may be used,
we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It is the obligation of each user of this product
to comply with the requirements of all applicable laws regarding use and disposal of this product. No warranty, either expressed or implied, or liability of any nature
with respect to this product or to the data herein is made or incurred hereunder.
05/01/2014Revision:
06/12/2014Printed:
Page: 1
DMD Pac LVMATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
00065Product Code:
DMD Pac LVProduct Name:
Drilling Mud Direct, LLCCompany Name:
8 Inverness Dr. E. Ste 245
Englewood, CO 80112
ChemTrecEmergency Contact:1 [phone]
International 1 [phone]
Office [phone]
Phone Number:
www.muddirect.netWeb site address:
1. Product and Company Identification
2. Hazards Identification
No specific health hazards are encountered under normal product use.Emergency Overview:
Hazard Rating System:Instability
Special Hazard
Health
FlammabilityHEALTH
FLAMMABILITY
PPE
PHYSICAL
1
01
E
1 1 0
NFPA:HMIS:
Potential Health Effects
(Acute and Chronic):
CAS # Hazardous Components (Chemical Name)
3. Composition/Information on Ingredients
Concentration
NA ( Trade Secret ) 100.0 %
In Case of Inhalation:
4. First Aid Measures
Emergency and First Aid
Procedures:
Wash with plenty of water.In Case of Eye Contact:
Wash with plenty of soap and water.In Case of Skin Contact:
Seek medical advice.In Case of Ingestion:
Ventilate the premises. The patient is to be removed from the contaminated premises.
5. Fire Fighting Measures
Flash Pt:NP Method Used: Estimate
Use protection for respiratory tract.Fire Fighting Instructions:
Flammable Properties and
Hazards:
Autoignition Pt:NP
Explosive Limits:LEL: UEL:
Water.Suitable Extinguishing Media:
None known.Unsuitable Extinguishing
Media:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
05/01/2014Revision:
06/12/2014Printed:
Page: 2
DMD Pac LVMATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
6. Accidental Release Measures
Steps To Be Taken In Case
Material Is Released Or
Spilled:
Use mask. gloves and protective clothing.Protective Precautions,
Protective Equipment and
Emergency Procedures:
In case of spill sweep up carefully. Product on contact with water creates a hazard due to
its slipperiness. If possible recover the product, otherwise collect.
Environmental Precautions:
7. Handling and Storage
The product should be used in a well ventilated place Avoid direct contact with the
product. Avoid accumulating electrostatic charge. Avoid dust formation. Do not eat or
drink while working.
Precautions To Be Taken in
Handling:
Keep containers closed. Store in a dry place away from moisture.. Adequate ventilation
in working are.
Precautions To Be Taken in
Storing:
8. Exposure Controls/Personal Protection
OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits
NA ( Trade Secret )
Use respiratory protection when there is a risk of vapors/spray/dust exposureRespiratory Equipment
(Specify Type):
Use close fitting safety gogglesEye Protection:
Use protective gloves.Protective Gloves:
No special precaution must be adopted for normal use.Other Protective Clothing:
Engineering Controls
(Ventilation etc.):
9. Physical and Chemical Properties
Physical States:[ ] Gas [ ] Liquid [ X ] Solid
Melting Point:NA
Boiling Point:NA
Autoignition Pt:NP
Flash Pt:NP Method Used: Estimate
Explosive Limits:LEL: UEL:
Specific Gravity (Water = 1):
Density:NA
Powder
Odor: None
Appearance and Odor:
Vapor Pressure (vs. Air or
mm Hg):
Vapor Density (vs. Air = 1):
Evaporation Rate:
Solubility in Water: Soluble
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
05/01/2014Revision:
06/12/2014Printed:
Page: 3
DMD Pac LVMATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
Percent Volatile:
pH: 6 - 8.5
10. Stability and Reactivity
Conditions To Avoid -
Instability:
Unstable [ ] Stable [ X ]Stability:
Incompatibility - Materials To
Avoid:
Stable under normal conditions.Hazardous Decomposition Or
Byproducts:
Will occur [ ] Will not occur [ X ]Possibility of Hazardous
Reactions:
Stable under normal conditions. As organic product, usual precaution to avoid explosion
of dust are recommended.
Conditions To Avoid -
Hazardous Reactions:
11. Toxicological Information
Skin: May cause slight irritation
Eye: May cause slight irritation
Acute oral toxicity on rates (LD50) >2000mg/kg
Toxicological Information:
Not carcinogenicCarcinogenicity/Other
Information:
12. Ecological Information
The natural polysaccharide derivatives aren't considered as Readily Biodegradable,
showing a biodegradable value<60% (OECD301) but they have no environmentally
concern due to the negligible bioaccumulation (log POw<3) and can be easily removed
in water treatment plants.
Persistence and
Degradability:
IF possible recover the product, otherwise dispose of in authorized landfill or incinerate in
accordance with local regulation. Main general legislation, when and if
applicable:91/156/EEC, 91/689/EEC, 94/62/EC and subsequent amendments.
Waste Disposal Method:
13. Disposal Considerations
14. Transport Information
Not restricted.DOT Proper Shipping Name:
DOT Hazard Class:
UN/NA Number:
LAND TRANSPORT (US DOT):
Not restricted.IMDG/IMO Shipping Name:
MARINE TRANSPORT (IMDG/IMO):
Not restricted.ICAO/IATA Shipping Name:
AIR TRANSPORT (ICAO/IATA):
Not restricted.Additional Transport
Information:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
05/01/2014Revision:
06/12/2014Printed:
Page: 4
DMD Pac LVMATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
15. Regulatory Information
[ ] Yes [X] No Acute (immediate) Health Hazard
[ ] Yes [X] No Chronic (delayed) Health Hazard
[ ] Yes [X] No Fire Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
[ ] Yes [X] No Reactive Hazard
This material meets the EPA
'Hazard Categories' defined
for SARA Title III Sections
311/312 as indicated:
16. Other Information
Additional Information About
This Product:
Although the information and recommendations set forth herein (hereinafter
"Information") are presented in good faith and believed to be correct as of the date
hereof, Drilling Mud Direct, makes no representations as to the completeness or
accuracy thereof. Information is supplied upon the condition that the person receiving
this MSDS will make own determination as to its suitability for their intended purpose
prior to use. Since the product is within the exclusive control of the user, it is the user's
obligation to determine the conditions of safe use of this product. Such conditions should
comply with all Federal Regulations concerning the Product. NO REPRESENTATIONS
OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE
HERUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH
INFORMATION REFERS.
Company Policy or
Disclaimer:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
Concrete Mix Design Submittal
Date :05/23/2017 1
L13G - 1:3 Fine GroutMix Code :Description :L13G
No.-000810 Version
Customer
Contact
Office Phone
Project Name
Project Contact
Usage/ Placement
Oz Directional Drilling
Judy Way
ASTM 476 Fine Grout
Air Content
Slump
Unit Weight
W/C Ratio
Design Tolerance
2
+/- 1
lb/ft3
9.0
0.49
142.9
3500 psiDesign Strength
Material Description Source Supplier CONCRETE Design Quantity Specific
Gravity
Volume
(ft3)Type
Cement LEHIGH TYPE I 750 lbLehigh Cement Company-EVANSVILLE 3.15C-150 3.82
Fine Aggregate PIONEER TARBURTON CONC SAND 2740 lbPioneer Materials-TARBURTON 2.62C-33 16.76
Admixture PLASTOCRETE 161 4.0 /cwtSika Corporation-NJ -C-494 -
Admixture SIKA VISCO 2100 HRWR 4.0 /cwtSika Corporation-NJ -C-494 -
Water WATER 44.0 galWATER-WATER POTABLE 1.00C-1602 5.88
Yield 3857 --27.00lb
Air Content 2.00 % --0.54

Note 1: Sika 2100 may be added to increase the slump to 8" maximim.
Note 2: Sikaset (accelerator) may be added for cold weather concreting.
Note 3: Sika Plastiment (retarder) may be added for hot weather concreting.
NOTES

Prepared By :
LISA SIMPSON Manager - Mix Development & Submittals
Approval of this mix design for use on a project
will serve as an approval for the testing agency to
send all break data to Heritage Concrete
([e-mail]) as per the
requirements in ACI 301 and ACI 318.
STRENGTH PERFORMANCE
REPORT
Period :
Mix :L13G - ASTM C 476 FINE GROUT
16 Jul 2015 30 Nov 2015To
3000 Specified Strength
Average Strength
Standard Deviation
Corrected CofV ACI Running Average of 3 Criteria
ACI Standard Deviation Criteria
3960
300
7.6 Yes
Yes
28 Day
Required Strength 3400
Compressive Test Number of Tests 30
Strength28
psi
28 Str
psi
Count
Average
STDEV
COV%
Range Min
Range Max
30 30
3960 3960
300 300
7.6 7.6
3710 3710
5440 5440
28 Str
psi
11/30/2015 60322566
10/6/2015
60236436
60236425
60236418
10/1/2015
60319622
60319613
60319599
9/29/2015
60319544
60319534
60319524
60319514
9/22/2015
60319232
60319215
60319199
9/21/2015 60319127
60319111
9/18/2015
60319055
60319039
60319015
9/17/2015 60318977
60318948
7/30/2015
60316322
60316315
60316307
7/28/2015
60316193
60316191
60316171
7/16/2015
60315559
60315546
60315536
Date Sample
5440
3820
3910
3880
3920
4000
3950
3710
3840
3800
3810
3800
3950
4010
4030
3880
4190
3790
3850
4020
4100
4120
3990
3900
3800
3770
3820
3810
3840
3980
Date : 15/23/2017 Page 1 of
Type:II and GU ASTM, II AASHTO Test Period:9/22/16
Silo:to:10/22/16
Supplier:Lehigh Cement Company LLC Source Location:Evansville Plant
Address:537 Evansville Rd
Fleetwood, PA, 19522 Contact:Sales Office
Telephone:[phone]
Item Limit Results Limit Results
SiO2 -18.95 Fineness:
Al2O3 6.0 Max 4.99 -91.21
Fe2O3 6.0 Max 4.19 150 min 395
CaO -60.87
MgO 6.0 max 2.96 0.8 max 0.106
SO3 3.43
Equivalent Alkalies 0.97 45 min 102
Loss on Ignition 3.5 max 2.65 375 max 202
Insoluble Residue 1.5 max 0.65
CO2 A 1.35 12 max 6.6
Limestone %5.0 max 3.89
CaCO3 in Limestone 70% Min 79.0
-16.03
Potential Compounds:10.0 min 25.91
C3S -52.41 17.0 min 30.71
C2S -14.84 -37.36
C3A 8 max 6.13
C4AF -12.76
Item Limit Results Limit Result
C3S+4.75*C3A 81.5 Min 50 72
Heat of Hydration 80.9 Max 0.020 0.013
October 22, 2016
Date Quality Control Manager
7-Day
28-Day
False Set
C-1038
Physical Requirements (ASTM C-150, Table 3)
Item
% Passing 45µm (No. 325)
Blaine Fineness (m2/Kg)
Autoclave Expansion (%)
Vicat Setting Time:
Final Set (minutes)
Item
Air Content (%)
Compressive Strengths Mpa:
1-Day
3-Day
Certification
Mill Test Certificate Report
General Information
Physical Requirements (ASTM C-150, Table 4)Chemical Requirements (ASTM C-150, Table 2)
Chemical Requirements (ASTM C-150, Table 1)
Test Data on ASTM "Standard" Requirements
Test Data on ASTM Optional Requirement
Initial Set (minutes)
This certifies that the described cement, at the time of shipment, meets chemical and physical requirements of the current
applicable specification for ASTM C-150, for Type II as well as AASHTO M-85 for Type II. This cement also meets the
specification for ASTM C-1157 type GU. This cement contains no organic or inorganic additions. We are not responsible
for improper use or workmanship.
January 12. 2017
Heritage Concrete
307 A Street
Wilmington, DE 19801.
Attn: Lisa Simpson
Dear Lisa
The following is a Concrete Sand gradation from our Tarburton Plant located in Dover,
Delaware, to certify A.S.T.M. C-33 gradation compliance
January
12, 2017
Sieve Size
% Passing
3/89'
100
#4
97.6
#8
93.3
#16
82.5
#30
49.9
#50
15.1
#100
2.3
#200
0.1
FM - 2.59
If you have any questions or need further information, please do not hesitate to give me a
call at 302-632-9963.
Sincerely, IZ
Pioneer Materials
Chris Tharp
Q.C. Tech Sand And Gravel Operations
Penney Supply, Central Region & Corporate Office
Penney Supply, North Region Office & Construction
McMinn Asphalt & Construction
Pioneer Materials
1001 Paxton Street Harrisburg, PA 17104 [phone]
300 Armstrong Road Pittston, PA 18640 [phone]
2743 Lancaster Road Menheim, PA 17545 [phone]
880 Long Point Road Dover, DE 19901 (302) 6985510
0
01 le
Materials

ConstructionSika® ViscoCrete® 2100
High Range Water Reducing Admixture
Description Sika ViscoCrete 2100 is a high range water reducing and superplasticizing
admixture utilizing Sika’s ‘ViscoCrete’ polycarboxylate polymer technology.
Sika ViscoCrete 2100 meets the requirements for ASTM C-494 Types A and F.
Applications Sika ViscoCrete 2100 may be used in both ready mix and precast applications, as
a plant added high range water reducer to provide excellent plasticity while main-
taining slump for up to 90 minutes. Controlled set times make Sika ViscoCrete
2100 ideal for horizontal and vertical applications.
Sika ViscoCrete 2100 is ideal for production of Self Consolidating Concrete (SCC).
Advantages Water Reduction: Sika ViscoCrete 2100 can be dosed in small amounts to obtain
water reduction from 10-15%, and will achieve water reduction up to 45% at high
dosage rates.
Sika ViscoCrete 2100 is suitable for all levels of water reduction.
High Plasticity: The superplasticizing action of Sika ViscoCrete 2100 provides
high-slump, flowing concrete that maintains excellent workability and may be
placed with minimal vibration even at very low water cement ratio’s as low as 0.25.
Sika ViscoCrete 2100 plasticized concrete is highly fluid while maintaining complete
cohesion within the concrete matrix to eliminate excessive bleeding or segregation.
Extended Slump Life and Set Control: Sika ViscoCrete 2100 has been formu-
lated to provide controlled and predictable extended slump life for periods of 60 to
90 minutes with normal set times.
The combined high range water reduction and superplasticizing action of Sika
ViscoCrete 2100 provide the following benefits in hardened concrete:
n Higher ultimate strengths allow for greater engineering design flexibility and
structural economies.
n Reduced water cement ratios produce more durable, dense concrete with
reduced permeability.
n Highly effective plasticizer reduces surface defects in concrete elements and
improves aesthetic appearance.
It has been formulated to provide maximum water reduction and extended slump
retention at low dosages.
How to Use
Dosage Dosage rates will vary according to materials used, ambient conditions and the
requirements of a specific project. Sika recommends dosage at 2-6 fl. oz. per 100
lbs. (130-390 ml/100 kg) of cementitious for conventional concrete applications.
If high slump or Self Consolidating Concrete (SCC) is required, dosage from 6-12
fl.oz./100 lbs. (390-780 ml/100 kg.) of cementitious may be used.
Dosage rates outside the recommended range may be used where specialized
materials such as microsilica are specified, extreme ambient conditions are en-
countered or unusual project conditions require special consideration. In thi case,
Please contact your local regional Sika office or Sika Technical Service
Department 1-800- 933-7452 for more information and assistance.
Product Data Sheet
Edition 12.2005
Identification no. 781-540
Sika ViscoCrete 2100
ConstructionKEEP CONTAINER TIGHTLY CLOSED • KEEP OUT OF REACH OF CHILDREN • NOT FOR INTERNAL CONSUMPTION • FOR INDUSTRIAL USE ONLY
All information provided by Sika Corporation (“Sika”) concerning Sika products, including but not limited to, any recommendations and advice
relating to the application and use of Sika products, is given in good faith based on Sika’s current experience and knowledge of its products
when properly stored, handled and applied under normal conditions in accordance with Sika’s instructions. In practice, the differences in materi-
als, substrates, storage and handling conditions, actual site conditions and other factors outside of Sika’s control are such that Sika assumes no
liability for the provision of such information, advice, recommendations or instructions related to its products, nor shall any legal relationship be
created by or arise from the provision of such information, advice, recommendations or instructions related to its products. The user of the Sika product(s) must test the product(s) for suitability for the intended application and purpose before proceeding with the full application of the product(s).
Sika reserves the right to change the properties of its products without notice. All sales of Sika product(s) are subject to its current terms and conditions of sale which are available at www.sikacorp.com or by calling 800-933-7452.
Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product’s most cur-rent Technical Data Sheet, product label and Material Safety Data Sheet which are available at www.sikaconstruction.com or
800-933-7452. Nothing contained in any Sika materials relieves the user of the obligation to read and follow the warnings and instruction
for each Sika product as set forth in the current Technical Data Sheet, product label and Material Safety Data Sheet prior to product use.
SIKA warrants this product for one year from date of installation to be free from manufacturing defects and to meet the technical properties
on the current Technical Data Sheet if used as directed within shelf life. User determines suitability of product for intended use and
assumes all risks. Buyer’s sole remedy shall be limited to the purchase price or replacement of product exclusive of labor or cost of labor.
NO OTHER WARRANTIES EXPRESS OR IMPLIED SHALL APPLY INCLUDING ANY WARRANTY OF MERCHANTIBILITY
OR FITNESS FOR A PARTICULAR PURPOSE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR
SPECIAL OR CONSEQUENTIAL DAMAGES. SIKA SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN
A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
Sika Canada Inc.
601, Delmar Avenue
Pointe-Claire, QC H9R 4A9
Phone: [phone]
Fax: [phone]
www.sika.ca
Sika Corporation
201 Polito Avenue
Lyndhurst, NJ 07071
Phone: [phone]
Fax: [phone]
www.sikaconstruction.com
1-800-933-SIKA
Regional Information and Sales Centers. For the location of your nearest Sika representative, contact your regional center.
U.S. : North East Region: Fairless Hills, PA, Phone: [phone] North Central Region: Marion, OH, Phone: [phone]
South East Region: Conyers, GA, Phone: [phone] South Central Region: Mesquite, TX, Phone: [phone]
Western Region: Santa Fe Springs, CA, Phone: [phone]
Canada: Ontario: Mississauga, ON, Phone: [phone], Alberta: Edmonton, AB, Phone: [phone]
Quality Certification Numbers: Lyndhurst: FM 69711 (ISO 9000), FM 70421 (QS 9000), Marion: FM 69715, Kansas City: FM 69107, Santa Fe Springs: FM 69408
ISO 9000:2000
Mixing For best superplasticizing results, add Sika ViscoCrete 2100 directly to freshly
mixed concrete in the concrete mixer at the end of the batching cycle.
Sika ViscoCrete 2100 may also be dispensed as an integral material during the
regular admixture batching cycle or into freshly mixed concrete in a Ready-Mix
truck at the concrete plant.
To optimize the superplasticizing effect, after the addition Sika ViscoCrete 2100
Sika recommends that the combined materials be mixed for 80-100 revolutions,
either in the concrete mixer or in the Ready-Mix truck.
Combination with other admixtures: Sika ViscoCrete 2100 is highly effective
as single admixture or in combination with other admixtures in the Sika System. If
used in combination with certain Sikament high range water reducers it may affect
the plastic properties of fresh concrete. Please contact a Sika representative for
further information.
Combination with microsilica: Sika ViscoCrete 2100 is particularly well suited
for use with microsilica because of its water reduction capability and superior
slump control.
Packaging Sika ViscoCrete 2100 is available in 55 gallon drum (208 liter), 275 gallon totes
(1040 liters) drums and bulk delivery.
Storage and Shelf-life Sika ViscoCrete 2100 should be stored at above 35°F (2°C). If frozen, thaw and
agitate thoroughly to return to normal state.
Shelf life when stored in dry warehouse conditions between 50°F and 80°F
(10°C - 27°C) is one year.
Typical Data
Appearance Light Blue liquid.
Specific Gravity Approx. 1.1
CAUTiON: iRRiTANT Contains aqueous polymer solution (CAS: Mixture). May cause eye/skin/respira-
tory irritation. May be harmful if swallowed.
Handling and Storage Avoid direct contact. Wear personal protective equipment (chemical resistant
goggles/gloves/clothing) to prevent direct contact with skin and eyes. Use only in
well ventilated areas. Wash thoroughly with soap and water after use. Remove
contaminated clothing and launder before reuse.
First Aid Eyes: Hold eyelids apart and flush thoroughly with water for 15 minutes. Skin:
Remove contaminated clothing. Wash skin thoroughly for 15 minutes with soap
and water. inhalation: Remove person to fresh air. ingestion: Do not induce
vomiting. Dilute with water. Contact physician. in all cases contact a physician
immediately if symptoms persist.
Clean Up Use personal protective equipment (chemical resistant goggles/gloves/clothing).
Without direct contact, remove spilled or excess product and place in suitable
sealed container. Dispose of excess product and container in accordance with
applicable environmental regulations.
Sika and ViscoCrete are registered trademarks. Made in USA. Printed in USA.
ConstructionPlastocrete® 161
Water Reducing Admixture
Description Plastocrete 161 is a lignin polymer-type water-reducing admixture.
Plastocrete 161 meets the requirements of ASTM C-494 Types A, B and D.
Applications Plastocrete 161 is recommended for use in all applications where high quality
concrete with superior workability is required.
Advantages Plastocrete 161 water reducing admixture provides an economical and highly
effective means of reducing the amount of mixing water required to produce
concrete of a certain slump by acting as a dispersant for the cement particles
in the mix.
Through this dispersing action more of the surface area of the cement particles
is available for early hydration. The more cement particles hydrated by contact
with the mixing water, the greater the compressive strength of the concrete.
Plastocrete 161 is formulated as a Type A water reducer to allow up to 10%
water reduction and maximize the benefits of increased hydration in both the
hardened and plastic states.
n Reduced water content required to achieve desired slump, increases
compressive and flexural strengths and allows the use of more economi-
cal mixes.
n Improved paste quality makes concrete easier to pump and finish.
n Consistent normal setting times throughout the recommended dosage.
n Lower water cement ratios provide decreased permeability and increased
durability.
n Plastocrete 161 does not contain intentionally added chlorides and will
not initiate nor promote the corrosion of steel in the concrete.
How to Use
Dosage Dosage rates will vary depending on the material used, ambient conditions
and the requirements of a specific project.
For general concreting applications, Sika recommends a dosage rate between
2-4 fl.oz./100 lbs. (130-260 ml/100 kg) of cementitious materials for normal
setting characteristics. Dosage rates of 4-6 fl.oz./100 lbs. (260-390 ml/100 kg)
of cementitious materials are recommended for applications where higher
water reduction is needed as well as extended workability and prolonged
setting times.
Dosage rates outside the recommended range may be used where
specialized materials such as microsilica are specified, extreme ambient
conditions are encountered or unusual project conditions require special con-
sideration. In this case please contact your local regional Sika office or Sika
technical service department at 1-800-933-7452 for further information.
Product Data Sheet
Edition 10.2005
Identification no. 161
Plastocrete 161
ConstructionKEEP CONTAINER TIGHTLY CLOSED • KEEP OUT OF REACH OF CHILDREN • NOT FOR INTERNAL CONSUMPTION • FOR INDUSTRIAL USE ONLY
All information provided by Sika Corporation (“Sika”) concerning Sika products, including but not limited to, any recommendations and advice
relating to the application and use of Sika products, is given in good faith based on Sika’s current experience and knowledge of its products
when properly stored, handled and applied under normal conditions in accordance with Sika’s instructions. In practice, the differences in materi-
als, substrates, storage and handling conditions, actual site conditions and other factors outside of Sika’s control are such that Sika assumes no
liability for the provision of such information, advice, recommendations or instructions related to its products, nor shall any legal relationship be
created by or arise from the provision of such information, advice, recommendations or instructions related to its products. The user of the Sika product(s) must test the product(s) for suitability for the intended application and purpose before proceeding with the full application of the product(s).
Sika reserves the right to change the properties of its products without notice. All sales of Sika product(s) are subject to its current terms and conditions of sale which are available at www.sikacorp.com or by calling 800-933-7452.
Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product’s most cur-rent Technical Data Sheet, product label and Material Safety Data Sheet which are available at www.sikaconstruction.com or
800-933-7452. Nothing contained in any Sika materials relieves the user of the obligation to read and follow the warnings and instruction
for each Sika product as set forth in the current Technical Data Sheet, product label and Material Safety Data Sheet prior to product use.
SIKA warrants this product for one year from date of installation to be free from manufacturing defects and to meet the technical properties
on the current Technical Data Sheet if used as directed within shelf life. User determines suitability of product for intended use and
assumes all risks. Buyer’s sole remedy shall be limited to the purchase price or replacement of product exclusive of labor or cost of labor.
NO OTHER WARRANTIES EXPRESS OR IMPLIED SHALL APPLY INCLUDING ANY WARRANTY OF MERCHANTIBILITY
OR FITNESS FOR A PARTICULAR PURPOSE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR
SPECIAL OR CONSEQUENTIAL DAMAGES. SIKA SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN
A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
Sika Canada Inc.
601, Delmar Avenue
Pointe-Claire, QC H9R 4A9
Phone: [phone]
Fax: [phone]
www.sika.ca
Sika Corporation
201 Polito Avenue
Lyndhurst, NJ 07071
Phone: [phone]
Fax: [phone]
www.sikaconstruction.com
1-800-933-SIKA
Regional Information and Sales Centers. For the location of your nearest Sika representative, contact your regional center.
U.S. : North East Region: Fairless Hills, PA, Phone: [phone] North Central Region: Marion, OH, Phone: [phone]
South East Region: Conyers, GA, Phone: [phone] South Central Region: Mesquite, TX, Phone: [phone]
Western Region: Santa Fe Springs, CA, Phone: [phone]
Canada: Ontario: Mississauga, ON, Phone: [phone], Alberta: Edmonton, AB, Phone: [phone]
Quality Certification Numbers: Lyndhurst: FM 69711 (ISO 9000), FM 70421 (QS 9000), Marion: FM 69715, Kansas City: FM 69107, Santa Fe Springs: FM 69408
Mixing Plastocrete 161 is added at the concrete plant. Measure required quantity
manually or by automated dispenser. Add into the water line at the batch plant
or to the mixer at the end of the batching cycle.
Combination with other Admixtures: Plastocrete 161 works effectively as a
single admixture or in combination with other admixtures in the Sika System.
When air entrained concrete is specified, Sika recommends the use of Sika air
entraining admixtures.
When used in combination with other admixtures, care must be taken to
dispense each admixture separately into the concrete. Do not mix with dry ce-
ment.
Packaging Plastocrete 161 is supplied in 55 gallon (208 liter) drums and bulk delivery.
Storage and Shelf-life Plastocrete 161 should be stored at above 40°F (5°C). If frozen, thaw and
agitate thoroughly to return to normal state before use.
Shelf life when stored in dry warehouse conditions between 50°F and 80°F
(10°C - 27°C) is one year.
Typical Data
Appearance Dark Brown liquid
Specific Gravity Approx. 1.2
Caution Skin and eye irritant; avoid contact. The use of NIOSH approved respirator,
safety goggles and rubber gloves is recommended. Avoid breathing product.
Use with adequate ventilation. Remove contaminated clothing.
Handling and Storage Avoid direct contact. Wear personal protective equipment (chemical resistant
goggles/gloves/clothing) to prevent direct contact with skin and eyes. Use
only in well ventilated areas. Wash thoroughly with soap and water after use.
Remove contaminated clothing and launder before reuse.
First Aid Eyes: Hold eyelids apart and flush thoroughly with water for 15 minutes. Skin:
Remove contaminated clothing. Wash skin thoroughly for 15 minutes with
soap and water. Inhalation: Remove person to fresh air. Ingestion: Do not
induce vomiting. Dilute with water. Contact a physician. In all cases, contact
a physician immediately if symptoms persist.
Clean Up Use personal protective equipment (chemical resistant goggles/gloves/
clothing). Without direct contact, remove spilled or excess product and place
in suitable sealed container. Dispose of excess product and container in
accordance with applicable environmental regulations.
Sika and Plastocrete are registered trademarks. Made in USA. Printed in USA.
SikaSet® NC
Accelerating Admixture
Description
SikaSet NC is a non -chloride, water reducing and accelerating admixture.
SikaSet NC meets the requirements of ASTM C-494 Types C and E.
Applications
SikaSet NC is an effective accelerator where high early strength concrete is de-
sired and the use of calcium chloride is prohibited_
Advantages
Accelerated Set Times and Strength Development: SikaSet NC may be used
to accelerate set times and increase early strength gain where job -site efficiency
is important in order to meet construction deadlines. SikaSet NC saves time and
money by allowing faster finishing and stripping of concrete surfaces.
■ Accelerated setting time across a wide range of temperatures.
Increased early and ultimate compressive and flexural strengths.
■ Insulation and heating costs during curing time are reduced.
Accelerated set times allow crews to finish concrete earlier; saving on labor
costs.
■ Earlier stripping and reuse of forms increases labor productivity.
■ Accelerated strength gain allows earlier structural use and speeds completion
time.
SikaSet NC does not contain calcium chloride or any other intentionally added
chlorides and will not initiate or promote the corrosion of steel members present in
the concrete.
Cold Weather Concreting: At the recommended dosage rate SikaSet NC will
protect concrete from freezing in most sub -freezing temperature conditions and
may reduce the need for cold weather concreting practices as specified in AC!
306 - Standard Specification for Cold Weather Concreting.
How to Use
Dosage
To accelerate set times dosage at the rate of 10-45 fl. oz. per 100 lbs.
Wxing
(650 - 2940 mill 00 kg.) of cement is recommended.
When used to protect concrete from freezing, dosage will vary with different
brands of cement and ambient temperatures and higher dosages may be nec-
essary. Sika recommends that trial mixes be performed to determine the most
efficient dosage. When using 16 fl-oz./100 lbs. or more, adjust mixing water
accordingly. Dosage rates outside the recommended range may be used where
specialized materials such as microsilica are specified, extreme ambient condi-
tions are encountered or unusual project conditions require special consideration.
in this case please contact your local regional Sika office or Sika technical service
department at 1-800-933-7452 for further information.
Add the correct amount of SikaSet NC at the concrete plant. The admixture may
be added manually or by automated dispenser directly into the sand or into the
water line at the batch plant.
When used in combination with other admixtures care must be taken to dispense
each admixture separately into the mix. Do not mix with dry cement. Field evalu-
ations should be carried out to determine the minimum ambient and concrete
temperature rewired, and the optimum dosage for the desired setting time and
strength perftx-S€anc-e_ Appropriate, sound curing practices must be followed to
protect `ras u ate from excessive heat loss in extreme weather conditions.

Commination with other admixtures:
SikaSet NC is highly effective as a single admixture or in combination with other
Sika admixtures. Add the correct amount of SikaSet NC at the concrete plant. The
admixture may be added manually or by automated dispenser directly into the
sand or into the water line at the batch plant.
Packaging Sika Set NC is available in 55 gallon drum (208 liter), 275 gallon totes (1040 liters)
drums and bulk delivery.
Storage and Shelf Life Sika Set NC should be stored at above 4WF (5°C). If frozen, thaw and
agitate thoroughly to return to normal state_ Protect from direct sunlight.
Shelf life when stored in dry warehouse conditions between 50°F and 80°F
(10'C - 27°C) is one year
Typical Data
Appearance Blue liquid -
Specific Gravity Approx. 1.4 —
CAUTION: IRRITANT Contains Sodium Salt of an Organic Acid Solution (CAS: Mixture) and Calcium
Nitrate (CAS: 10124-37-5). May cause eyelskin/respiratory irritation. May be
harmful if swallowed.
Handling and Storage Avoid direct contact. Wear personal protective equipment (chemical resistant
goggles/gloves/clothing) to prevent direct contact with skin and eyes. Use only in
well ventilated areas. Wash thoroughly with soap and water after use. Remove
contaminated clothing and launder before reuse.
First Aid Eyes: Hold eyelids apart and flush thoroughly with water for 15 minutes. Skin:
Remove contaminated clothing. Wash skin thoroughly for 15 minutes with soap
and water Inhalation: Remove to fresh air. Ingestion: Do not induce vomiting.
Dilute with water. Contact physician. In all cases contact a physician immedi-
ately if symptoms persist.
Clean Up Use personal protective equipment (chemical resistant goggles/gloves/clothing).
Without direct contact, remove spilled or excess product and place in suitable
sealed container. Dispose of excess product and container in accordance with
applicable environmental regulations -
's
r
KEEP CONTAINER TIGHTLY CLOSED -KEEP OUT OF REACH OF CHILDREN • NOT FOR INTERNAL CONSUMPTION • FOR INDUSTRIAL USE ONLY
All infonnatFon provided by Sika Corporation ("Sika') concerning Sika products, rneludirtg but not limited to, any recommendations and advice
relating to the application and use of Sika products, is given in good faith based an Sika's current experience and knowledge Of its products
when properly stored, handled and applied under normal condilions in accordance with Sikainstructions. In practice, the differences in materi-
'
als, substrates, storage and handling conditions, actual site conditions and other factors cue s of Slka's control are such that Sika assumes no
liabi3ity for the provision of such information, ativice, recommendations or instructions related to its products, nor shall any legal relationship be
created dy or arise from the provision of such information, advice, recommendations or instructions related to its protlucts, The user of the Sika
product(s) must test1he product(s) for suitability forthe intended applicalion and purpose before proceeding with the full ducts Th of theof the Sika
reserves the right to change the properties of its products without notice. All sales of Sika product(s) are sub-
Sika)ect to its current terms and conditions of sale which are available at www.sikaus� or by calling 890-933-7452_
Prior to each use of any Stka product, the user must always read and follow the warnings and instructions on the product's
duct label and Material Safety Data Sheet which are available at www.sik .com or
,most current Technical Data Sheet, preach
for each Sikalia Nothing contained in any o
00 -7 Sika materials relieves the user of the obligation to Feed and follow the wamings and instruction
product as set #Drib in the current Technical Data Sheet, product label and Material Safety Date Sheet prior to product use
SIKA warrants this product for one year from data of installation to be free from manufacturing defects and to meet the lechnicai properties
on the current Technrcal Data Sheet if used as directed within shelf tire. User determines suitability of product for intended use and
assumes ali risks. Buyer's sole remedy shalt be limited to the purchase price or replacement of product exclusive of labor or cost of tabor.
NO OTHER WARRANTIES EXPRESS OR IMPLIED SHALL APPLY INCLUDING ANY WARRANTY OF MERCHANTIBILITY
OR FITNESS FOR A PARTICULAR PURPOSE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR
SPECIAL OR CONSEQUENTIAL DAMAGES. SIKA SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN
A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
SAca Ca+Pof24on Stka Canada Inc.
2�' ? AVenue 601, DetmarAvenue
0.7871 POinte-Claire, QC H9R 4A9 9-800-933-SIKA
r '
933- W'D Phone: [phone]
az� 2Z '_:12-3-57 25 Fax: {514) 6973047
www.siks.ea
Rego" mbffiaa�wn arvd Sale, Carters. For the location of your nearest Sika representative, contact your regional crater.
>ltier East ` iegilm: Fess Hills, PA, phone: [phone] North Central Region: Marion, ON. Phone: j800) 851-1545
S"ftCC11yers. GA, Phone: (774)) 760-1300 South Central Regian: Mesquite, TX, Phone: {972) 289-6480
Western Region: Santa Fe Springs, GA, Phone: [phone]
awWWw VZ553@LC-- CN, Phdrie- {9051 795-3177, Alberta: Edmonton, AB, Phone' (780) 486$111
- >A731 V -0 90e05, FM 70421 lQS 9004 Marton: Fitt 139715, Kansas city: FM 159107, Santa Fe Sprinp: FM x9405
Sika and SikaSet are registered trademarks. Made in USA. Printed in USA

SAFETY DATA SHEET
Product Trade Name:FUSE-IT®

Revision Date:16-Aug-2016 Revision Number: 14
1. Identification
1.1. Product Identifier
Product Trade Name:FUSE-IT®
Synonyms None
Chemical Family:Anionic Polymer
Internal ID Code HM005844
1.2 Recommended use and restrictions on use
Application:Lost Circulation Material
Uses advised against No information available
1.3 Manufacturer's Name and Contact Details
Manufacturer/Supplier
Baroid Fluid Services
Product Service Line of Halliburton
P.O. Box 1675
Houston, TX 77251
Halliburton Energy Services
645 - 7th Ave SW Suite 1800
Calgary, AB
T2P 4G8
Canada
Prepared By Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
1.4. Emergency telephone number
Emergency Telephone Number:1-866-519-4752 or 1-760-476-3962
Global Incident Response Access Code: 334305
Contract Number: 14012
2. Hazard(s) Identification
2.1 Classification in accordance with paragraph (d) of §1910.1200
Specific Target Organ Toxicity - (Single Exposure)Category 3 - H336
Acute Aquatic Toxicity Category 3 - H402
Chronic Aquatic Toxicity Category 3 - H412
2.2. Label Elements
_____________________________________________________________________________________________
Page 1 / 9
_____________________________________________________________________________________________
FUSE-IT®Revision Date: 16-Aug-2016
Hazard Pictograms
Signal Word:Warning
Hazard Statements H336 - May cause drowsiness or dizziness
H402 - Harmful to aquatic life
H412 - Harmful to aquatic life with long lasting effects
Precautionary Statements
Prevention P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
Response P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position
comfortable for breathing
P312 - Call a POISON CENTER/doctor/physician if you feel unwell
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations
2.3 Hazards not otherwise classified
None known
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w)GHS Classification - US
Hydrotreated light petroleum distillate 64742-47-8 10 - 30%STOT SE 3 (H336)
Asp. Tox. 1 (H304)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 1 - 5%Skin Irrit. 2 (H315)
Eye Irrit. 2A (H319)
Aquatic Acute 2 (H401)
Aquatic Chronic 2 (H411)
The exact percentage (concentration) of the composition has been withheld as proprietary.
4. First-Aid Measures
4.1. Description of first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.
4.2 Most important symptoms/effects, acute and delayed
May cause headache, dizziness, and other central nervous system effects. Causes mild skin irritation.
_____________________________________________________________________________________________
Page 2 / 9
_____________________________________________________________________________________________
FUSE-IT®Revision Date: 16-Aug-2016
4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
5. Fire-fighting measures
5.1. Extinguishing media
Suitable Extinguishing Media
Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons
None known.
5.2 Specific hazards arising from the substance or mixture
Special exposure hazards in a fire
Spills produce extremely slippery surfaces.
5.3 Special protective equipment and precautions for fire-fighters
Special protective equipment for firefighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Use appropriate protective equipment. Spills of this product are very slippery. Avoid breathing vapors. Avoid contact
with skin, eyes and clothing.
See Section 8 for additional information
6.2. Environmental precautions
Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up
Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling
Handling Precautions
Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after
use. Material is slippery underfoot. Launder contaminated clothing before reuse. Use appropriate protective
equipment.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Information
Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use. Keep from
freezing. Store at temperatures between 40 and 90 F (5 and 35 C). Product has a shelf life of 12 months.
8. Exposure Controls/Personal Protection
8.1 Occupational Exposure Limits
Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA
Hydrotreated light petroleum
distillate
64742-47-8 Not applicable Not applicable
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 Not applicable Not applicable
_____________________________________________________________________________________________
Page 3 / 9
_____________________________________________________________________________________________
FUSE-IT®Revision Date: 16-Aug-2016
8.2 Appropriate engineering controls
Engineering Controls Use in a well ventilated area.
8.3 Individual protection measures, such as personal protective equipment
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715,
or equivalent respirator when using this product.
Hand Protection Impervious rubber gloves.
Skin Protection Normal work coveralls. Rubber apron.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values
Remarks/ - Method
pH:6-8 (0.5%)
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point > 100 °C / > 212 °F PMCC
Flammability (solid, gas)No data available
Upper flammability limit No data available
Lower flammability limit No data available
Evaporation rate No data available
Vapor Pressure 0.002 mmHg @ 20°C
Vapor Density No data available
Specific Gravity 1.25
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information
VOC Content (%)No data available
10. Stability and Reactivity
10.1. Reactivity
Not expected to be reactive.
Physical State:Liquid Color Milky white
Odor:Paraffinic Hydrocarbon Odor
Threshold:
No information available
_____________________________________________________________________________________________
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10.2. Chemical stability
Stable
10.3. Possibility of hazardous reactions
Will Not Occur
10.4. Conditions to avoid
None anticipated
10.5. Incompatible materials
Strong oxidizers.
10.6. Hazardous decomposition products
Oxides of nitrogen. Carbon monoxide and carbon dioxide.
11. Toxicological Information
11.1 Information on likely routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation. Ingestion.
11.2 Symptoms related to the physical, chemical and toxicological characteristics
Acute Toxicity
Inhalation May cause central nervous system depression including headache, dizziness,
drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and
unconsciousness.
Eye Contact May cause mild eye irritation.
Skin Contact Causes mild skin irritation.
Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,
difficulty breathing, wheezing, coughing up blood and pneumonia, which can be
fatal.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%
are chronic health hazards.
11.3 Toxicity data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Hydrotreated light
petroleum distillate
64742-47-8 >5000 mg/kg-bw (rat) (similar
substance)
>2000 mg/kg-bw (rabbit) (similar
substance)
>5.2 mg/L (rat, 4 h, vapor)
(similar substance)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydrox
y-
9016-45-9 4290 mg/kg (rat)2500 mg/kg (rabbit)No data of sufficient quality are
available
Substances CAS Number Skin corrosion/irritation
Hydrotreated light petroleum
distillate
64742-47-8 Non-irritating to the skin (similar substances)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 Causes skin irritation. (Rabbit)
Substances CAS Number Serious eye damage/irritation
Hydrotreated light petroleum
distillate
64742-47-8 Non-irritating to rabbit's eye (similar substances)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 Causes moderate eye irritation (Rabbit)
Substances CAS Number Skin Sensitization
Hydrotreated light petroleum
distillate
64742-47-8 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
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Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 Patch test on human volunteers did not demonstrate sensitization properties
Substances CAS Number Respiratory Sensitization
Hydrotreated light petroleum
distillate
64742-47-8 No information available
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 No information available
Substances CAS Number Mutagenic Effects
Hydrotreated light petroleum
distillate
64742-47-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similar
substances)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 In vivo tests did not show mutagenic effects. (similar substances)
Substances CAS Number Carcinogenic Effects
Hydrotreated light petroleum
distillate
64742-47-8 Did not show carcinogenic effects in animal experiments (similar substances)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 Did not show carcinogenic effects in animal experiments (similar substances)
Substances CAS Number Reproductive toxicity
Hydrotreated light petroleum
distillate
64742-47-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal
experiments. (similar substances)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 No data of sufficient quality are available.
Substances CAS Number STOT - single exposure
Hydrotreated light petroleum
distillate
64742-47-8 May cause disorder and damage to the Central Nervous System (CNS) (similar substances)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 No information available
Substances CAS Number STOT - repeated exposure
Hydrotreated light petroleum
distillate
64742-47-8 No significant toxicity observed in animal studies at concentration requiring classification. (similar
substances)
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number Aspiration hazard
Hydrotreated light petroleum
distillate
64742-47-8 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,
wheezing, coughing up blood and pneumonia, which can be fatal.
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 Not applicable
12. Ecological Information
12.1. Toxicity
Ecotoxicity effects
Harmful to aquatic life. Harmful to aquatic life with long lasting effects.
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Toxicity to Invertebrates
Hydrotreated light
petroleum distillate
64742-47-8 EC50 (72h) > 1,000 mg/L
(Skeletonema costatum)
ErL50 (72h) > 1000 mg/L
(Pseudokirchneriella
subcapitata)
EbL50 (72h) > 1000 mg/L
(Pseudokirchneriella
subcapitata)
NOELR (72h) 1000 mg/L
(Pseudokirchneriella
subcapitata)
LC50 (96h) > 10,000
mg/L (Scophthalmus
maximus)
LL50 (96h) > 1000 mg/L
(Oncorhynchus mykiss)
No information available LC50 (48h) > 10,000
mg/L (Acartia tonsa)
EC50 (48h) 1100 mg/L
(Daphnia pulex)
LC50 (48h) 0.12 mg/L
(Daphnia magna)
EL50 (48h) > 1000 mg/L
(Daphnia magna)
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Poly(oxy-1,2-ethandiyl)
,
a-(nonylphenyl)-w-hydr
oxy-
9016-45-9 EC50 (48 h) 12 mg/L
(Pseudokirchneriella
subcapitata)
LC50 (96 h) 1.3 mg/L
(Lepomis macrochirus)
LC50 (96 h) 5 mg/L
(Danio rerio)
LOEC (21 d) 0.05 mg/L
(Gasterosteus aculeatus)
No information available EC50 (48h) 1.821 mg/L
(Daphnia sp.) (QSAR)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Hydrotreated light petroleum distillate 64742-47-8 (40% @ 28d)
Poly(oxy-1,2-ethandiyl), a-(nonylphenyl)-w-hydroxy-9016-45-9 Readily biodegradable (98-99% @ 28d)
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Hydrotreated light petroleum distillate 64742-47-8 Log Pow Weighted Average7.5
Poly(oxy-1,2-ethandiyl), a-(nonylphenyl)-w-hydroxy-9016-45-9 3.7 @ 25°C
12.4. Mobility in soil
Substances CAS Number Mobility
Hydrotreated light petroleum distillate 64742-47-8 No information available
Poly(oxy-1,2-ethandiyl), a-(nonylphenyl)-w-hydroxy-9016-45-9 No information available
12.5 Other adverse effects
No information available
13. Disposal Considerations
13.1. Waste treatment methods
Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
US DOT
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
Canadian TDG
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
IMDG/IMO
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
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IATA/ICAO
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
US Regulations
US TSCA Inventory All components listed on inventory or are exempt.
TSCA Significant New Use Rules - S5A2
Substances CAS Number TSCA Significant New Use Rules - S5A2
Hydrotreated light petroleum distillate 64742-47-8 Not applicable
Poly(oxy-1,2-ethandiyl), a-(nonylphenyl)-w-hydroxy-9016-45-9 79 FR 59186, Oct 1, 2014
EPA SARA Title III Extremely Hazardous Substances
Substances CAS Number EPA SARA Title III Extremely Hazardous
Substances
Hydrotreated light petroleum distillate 64742-47-8 Not applicable
Poly(oxy-1,2-ethandiyl), a-(nonylphenyl)-w-hydroxy-9016-45-9 Not applicable
EPA SARA (311,312) Hazard Class
Acute Health Hazard
EPA SARA (313) Chemicals
Substances CAS Number Toxic Release Inventory (TRI) -
Group I
Toxic Release Inventory (TRI) -
Group II
Hydrotreated light petroleum distillate 64742-47-8 Not applicable Not applicable
Poly(oxy-1,2-ethandiyl),
a-(nonylphenyl)-w-hydroxy-
9016-45-9 Not applicable Not applicable
EPA CERCLA/Superfund Reportable Spill Quantity
Substances CAS Number CERCLA RQ
Hydrotreated light petroleum distillate 64742-47-8 Not applicable
Poly(oxy-1,2-ethandiyl), a-(nonylphenyl)-w-hydroxy-9016-45-9 Not applicable
EPA RCRA Hazardous Waste Classification
If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA.
California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.
MA Right-to-Know Law Does not apply.
NJ Right-to-Know Law Does not apply.
PA Right-to-Know Law Does not apply.
NFPA Ratings:Health 1, Flammability 1, Reactivity 0
HMIS Ratings:Health 1, Flammability 1, Physical Hazard 0 , PPE: C
Canadian Regulations
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Canadian Domestic Substances
List (DSL)
All components listed on inventory or are exempt.
16. Other information
Preparation Information
Prepared By Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
Revision Date:16-Aug-2016
Reason for Revision SDS sections updated:
2
Additional information
For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheet
bw – body weight
CAS – Chemical Abstracts Service
d - day
EC50 – Effective Concentration 50%
ErC50 – Effective Concentration growth rate 50%
h - hour
LC50 – Lethal Concentration 50%
LD50 – Lethal Dose 50%
LL50 – Lethal Loading 50%
mg/kg – milligram/kilogram
mg/L – milligram/liter
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
NIOSH – National Institute for Occupational Safety and Health
NTP – National Toxicology Program
OEL – Occupational Exposure Limit
PEL – Permissible Exposure Limit
ppm – parts per million
STEL – Short Term Exposure Limit
TWA – Time-Weighted Average
UN – United Nations
w/w - weight/weight
Key literature references and sources for data
www.ChemADVISOR.com/
Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
Product Trade Name:HOLEPLUG® 3/8

Revision Date:14-Aug-2017 Revision Number: 17
1. Identification
1.1. Product Identifier
Product Trade Name:HOLEPLUG® 3/8
Synonyms None
Chemical Family Mineral
Internal ID Code HM003667
1.2 Recommended use and restrictions on use
Application Fluid Loss Additive
Uses advised against No information available
1.3 Manufacturer's Name and Contact Details
Manufacturer/Supplier
Baroid Fluid Services
Product Service Line of Halliburton Energy Services, Inc.
P.O. Box 1675
Houston, TX 77251
Telephone: [phone]
Halliburton Energy Services, Inc.
645 - 7th Ave SW Suite 1800
Calgary, AB
T2P 4G8
Canada
Prepared By Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
1.4. Emergency telephone number
Emergency Telephone Number 1-866-519-4752 or 1-760-476-3962
Global Incident Response Access Code: 334305
Contract Number: 14012
2. Hazard Identification
2.1 Classification of the substance or mixture
Carcinogenicity Category 1A - H350
Specific Target Organ Toxicity - (Repeated Exposure)Category 1 - H372
2.2. Label Elements
Hazard Pictograms
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HOLEPLUG® 3/8 Revision Date: 14-Aug-2017
Signal Word:Danger
Hazard Statements H350 - May cause cancer by inhalation
H372 - Causes damage to organs through prolonged or repeated exposure if
inhaled
Precautionary Statements
Prevention P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P280 - Wear protective gloves/eye protection/face protection
Response P308 + P313 - IF exposed or concerned: Get medical advice/attention
P314 - Get medical attention/advice if you feel unwell
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations
2.3 Other hazards which do not result in classification
This product contains Wyoming bentonite or other sorptive clays. Crystalline silica forms found in this particular clay are limited to
quartz. Extreme temperatures that can generate cristobalite or tridymite are not expected to occur under realistic conditions. In
addition, all quartz found in sorptive clays are considered “occluded”, i.e., strongly coated with an amorphous silica surface.
Occluded quartz has been experimentally-determined to be relatively non-toxic compared to unoccluded quartz. A lack of health
effects found in several studies examining occupational exposure to sorptive clays also suggest that chronic inhalation of sorptive
clays is not expected to result in silicosis or cancer. In light of these findings OSHA has recently exempted Wyoming bentonite and
other sorptive clays from the crystalline silica PEL in §1910.1053(a)(1)(iii).
3. Composition/information on Ingredients
Substances CAS Number PERCENT
(w/w)
GHS Classification -
Canada
HMIRA Registry
Number
Filing Date Decision
Granted Date
Crystalline silica, quartz 14808-60-7 1 - 5%Carc. 1A (H350)
STOT RE 1 (H372)
Not applicable Not
applicable
Not
applicable
4. First aid measures
4.1. Description of first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
4.2 Most important symptoms/effects, acute and delayed
Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also
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HOLEPLUG® 3/8 Revision Date: 14-Aug-2017
been associated with scleroderma and kidney disease.
4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
5. Fire-fighting measures
5.1. Extinguishing media
Suitable Extinguishing Media
All standard fire fighting media
Extinguishing media which must not be used for safety reasons
None known.
5.2 Specific hazards arising from the substance or mixture
Special exposure hazards in a fire
Not applicable
5.3 Special protective equipment and precautions for fire-fighters
Special protective equipment for firefighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Use appropriate protective equipment. Avoid creating and breathing dust.
See Section 8 for additional information
6.2. Environmental precautions
None known.
6.3. Methods and material for containment and cleaning up
Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated
with contaminating substances and use appropriate methods for collection, storage and disposal.
7. Handling and Storage
7.1. Precautions for safe handling
Handling Precautions
This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid
breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below
recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when
using this product. Material is slippery when wet.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Information
Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use.
Do not reuse empty container. Product has a shelf life of 60 months.
8. Exposure Controls/Personal Protection
8.1 Occupational Exposure Limits
Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA
Crystalline silica, quartz 14808-60-7 TWA: 50 µg/m3 TWA: 0.025 mg/m3
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8.2 Appropriate engineering controls
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits.
8.3 Individual protection measures, such as personal protective equipment
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values
Remarks/ - Method
pH:7.5
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Flammability (solid, gas)No data available
Upper flammability limit No data available
Lower flammability limit No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.12
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information
VOC Content (%)No data available
10. Stability and Reactivity
10.1. Reactivity
Not expected to be reactive.
Physical State:Solid Color Various
Odor:Odorless Odor
Threshold:
No information available
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10.2. Chemical stability
Stable
10.3. Possibility of hazardous reactions
Will Not Occur
10.4. Conditions to avoid
None anticipated
10.5. Incompatible materials
Hydrofluoric acid.
10.6. Hazardous decomposition products
Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
11. Toxicological Information
11.1 Information on likely routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation.
11.2 Symptoms related to the physical, chemical and toxicological characteristics
Acute Toxicity
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational
sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence
in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory
passages. Breathing silica dust may not cause noticeable injury or illness even
though permanent lung damage may be occurring. Inhalation of dust may also
have serious chronic health effects (See "Chronic Effects/Carcinogenicity"
subsection below).
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a
progressive, disabling, and sometimes-fatal lung disease called silicosis.
Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness, and reduced pulmonary function. This disease is exacerbated by smoking.
Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has
determined that crystalline silica inhaled in the form of quartz or cristobalite from
occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to
humans) and has determined that there is sufficient evidence in experimental
animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to
humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres
(June 1997) in conjunction with the use of these minerals. The National Toxicology
Program classifies respirable crystalline silica as "Known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American
Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline
silica, quartz, as a suspected human carcinogen (A2). There is some evidence
that breathing respirable crystalline silica or the disease silicosis is associated with
an increased incidence of significant disease endpoints such as scleroderma (an
immune system disorder manifested by scarring of the lungs, skin, and other
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HOLEPLUG® 3/8 Revision Date: 14-Aug-2017
internal organs) and kidney disease.
This product contains Wyoming bentonite or other sorptive clays. Crystalline silica
forms found in this particular clay are limited to quartz. Extreme temperatures that
can generate cristobalite or tridymite are not expected to occur under realistic
conditions. In addition, all quartz found in sorptive clays are considered
“occluded”, i.e., strongly coated with an amorphous silica surface (Wendlandt et
al., 2007; Hochella and Muryama, 2010; SMI, 2014). Occluded quartz has been
experimentally-determined to be relatively non-toxic compared to unoccluded
quartz (Geh et al., 2006; Creutzenberg et al., 2008). A lack of health effects found
in several studies examining occupational exposure to sorptive clays also suggest
that chronic inhalation of sorptive clays is not expected to result in silicosis or
cancer (Waxweiler et al., 1988; ACGIH, 1991; USEPA, 1996; IARC, 2005). In light
of these findings OSHA has recently exempted Wyoming bentonite and other
sorptive clays from the crystalline silica PEL in §1910.1053(a)(1)(iii).
11.3 Toxicity data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human)No data available No data available
Substances CAS Number Skin corrosion/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CAS Number Serious eye damage/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the eye
Substances CAS Number Skin Sensitization
Crystalline silica, quartz 14808-60-7 No information available.
Substances CAS Number Respiratory Sensitization
Crystalline silica, quartz 14808-60-7 No information available
Substances CAS Number Mutagenic Effects
Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CAS Number Carcinogenic Effects
Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The
IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity of
crystalline silica with repeated respiratory exposure.
Substances CAS Number Reproductive toxicity
Crystalline silica, quartz 14808-60-7 No information available
Substances CAS Number STOT - single exposure
Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number STOT - repeated exposure
Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CAS Number Aspiration hazard
Crystalline silica, quartz 14808-60-7 Not applicable
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity Data
No data available
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Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Toxicity to Invertebrates
Crystalline silica,
quartz
14808-60-7 EC50 (72 h) =440 mg/L
(Selenastrum
capricornutum)(similar
substance)
LL0 (96 h) =10000 mg/L
(Danio rerio)(similar
substance)
No information available LL50 (24 h) >10000 mg/L
(Daphnia magna)(similar
substance)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Crystalline silica, quartz 14808-60-7 The methods for determining biodegradability are not
applicable to inorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Crystalline silica, quartz 14808-60-7 No information available
12.4. Mobility in soil
Substances CAS Number Mobility
Crystalline silica, quartz 14808-60-7 No information available
12.5 Other adverse effects
No information available
13. Disposal Considerations
13.1. Waste treatment methods
Disposal methods If practical, recover and reclaim, recycle, or reuse by the guidelines of an
approved local reuse program. Should contaminated product become a waste,
dispose of in a licensed industrial landfill according to federal, state, and local
regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
Canadian TDG
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
US DOT
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
IMDG/IMO
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
_____________________________________________________________________________________________
Page 7 / 9
_____________________________________________________________________________________________
HOLEPLUG® 3/8 Revision Date: 14-Aug-2017
Environmental Hazards:Not applicable
IATA/ICAO
UN Number Not restricted
UN proper shipping name:Not restricted
Transport Hazard Class(es):Not applicable
Packing Group:Not applicable
Environmental Hazards:Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
Canadian Regulations
Canadian Domestic Substances
List (DSL)
All components listed on inventory or are exempt.
US Regulations
US TSCA Inventory All components listed on inventory or are exempt.
TSCA Significant New Use Rules - S5A2
Substances CAS Number TSCA Significant New Use Rules - S5A2
Crystalline silica, quartz 14808-60-7 Not applicable
EPA SARA Title III Extremely Hazardous Substances
Substances CAS Number EPA SARA Title III Extremely Hazardous
Substances
Crystalline silica, quartz 14808-60-7 Not applicable
EPA SARA (311,312) Hazard Class
Chronic Health Hazard
EPA SARA (313) Chemicals
Substances CAS Number Toxic Release Inventory (TRI) -
Group I
Toxic Release Inventory (TRI) -
Group II
Crystalline silica, quartz 14808-60-7 Not applicable Not applicable
EPA CERCLA/Superfund Reportable Spill Quantity
Substances CAS Number CERCLA RQ
Crystalline silica, quartz 14808-60-7 Not applicable
EPA RCRA Hazardous Waste Classification
If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA.
NFPA Ratings:Health 0, Flammability 0, Reactivity 0
HMIS Ratings:Health 0*, Flammability 0, Physical Hazard 0 , PPE: At
16. Other information
Preparation Information
Prepared By Chemical Stewardship
Telephone: [phone]
e-mail: [e-mail]
Revision Date:14-Aug-2017
_____________________________________________________________________________________________
Page 8 / 9
_____________________________________________________________________________________________
HOLEPLUG® 3/8 Revision Date: 14-Aug-2017
Reason for Revision SDS sections updated:
2
8
11
Additional information
For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheet
bw – body weight
CAS – Chemical Abstracts Service
EC50 – Effective Concentration 50%
ErC50 – Effective Concentration growth rate 50%
LC50 – Lethal Concentration 50%
LD50 – Lethal Dose 50%
LL50 – Lethal Loading 50%
mg/kg – milligram/kilogram
mg/L – milligram/liter
NIOSH – National Institute for Occupational Safety and Health
NTP – National Toxicology Program
OEL – Occupational Exposure Limit
PEL – Permissible Exposure Limit
ppm – parts per million
STEL – Short Term Exposure Limit
TWA – Time-Weighted Average
UN – United Nations
h - hour
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
w/w - weight/weight
d - day
Key literature references and sources for data
www.ChemADVISOR.com/
NZ CCID
Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 9 / 9
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DMD Lubra-Star Plus
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
0003Product Code:
DMD Lubra-Star PlusProduct Name:
Drilling Mud Direct, LLCCompany Name:
8 Inverness Dr. E. Ste 245
Englewood, CO 80112
ChemTrecEmergency Contact:1 [phone]
International 1 [phone]
Office [phone]
Phone Number:
www.muddirect.netWeb site address:
1. Product and Company Identification
2. Hazards Identification
Product may be irritating to eyes, skin
Eyes: May cause slight irritation to the eyes. Contact with hot or molten material can
cause sever thermal burns.
Skin: May be irritating to the skin. Contact with hot or molten material can cause severe
thermal burns.
Ingestion: Not anticipated route or exposure. Not expected to be orally toxic.
Inhalations No adverse effects expected in normal industrial use
Emergency Overview:
Hazard Rating System:Instability
Special Hazard
Health
FlammabilityHEALTH
FLAMMABILITY
PPE
PHYSICAL
1
0
1
E
1
1
0
NFPA:HMIS:
None known. the components of this product are not known to cause target organ
effects. not listed as a carcinogen by IARC, NTP or OSHA
Potential Health Effects
(Acute and Chronic):
CAS # Hazardous Components (Chemical Name)
3. Composition/Information on Ingredients
Concentration
NA ( Trade Secret ) 0.0 -100.0 %
In Case of Inhalation:
4. First Aid Measures
Emergency and First Aid
Procedures:
Remove contact lenses if worn. Flush thoroughly with large amounts of running water for
at least 15 minutes. Get medical attention if irritations develops.
In Case of Eye Contact:
Wash exposed are with soap and water. Remove contaminated clothing and wash
before reuse. Get medical attention if irritated develops. For hot or molten product,
immediately immerse and/or flush are with large amounts of cold water. Cover with
clean cotton sheeting or gauze and get prompt medical attention.
In Case of Skin Contact:
If person is conscious, immediately rinse mouth and give large quanties of water to drink.
Get immediate medical attention. Never give anything by mouth to an unconscious
person.
In Case of Ingestion:
Remove person to fresh air. Get medical attention for any breathing difficulty.
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
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DMD Lubra-Star Plus
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
5. Fire Fighting Measures
Flash Pt:> 206.00 F
Evacuate all unnecessary personal. Wear self contained breathing apparatus and
protection for skin. Mixing water with hot molten product may cause violent splattering
due to rapid steam generation.
Fire Fighting Instructions:
Flammable Properties and
Hazards:
Autoignition Pt:
Explosive Limits:LEL: UEL:
Carbon dioxide, dry chemical or regular foam.Suitable Extinguishing Media:
6. Accidental Release Measures
Stop leak if you can do so without risk. Contain, collect by absorbing on sand, sawdust or
other available solids and place in suitable container for reuse or disposal.
Steps To Be Taken In Case
Material Is Released Or
Spilled:
Wear appropriate protective clothing to prevent skin exposure.Protective Precautions,
Protective Equipment and
Emergency Procedures:
7. Handling and Storage
Handle only in well ventilated area. Avoid eye contact. Avoid repeated or prolonged skin
contact. Use appropriate protective equipment. Unvented containers may develop
pressure. Open with caution. Wash thoroughly after handling. Eyewash stations and
safety showers should be easily accessible to area where product is used.
Precautions To Be Taken in
Handling:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep
containers closed when not in use. Store hot or molten material under an inert gas
blanket to avoid oxidative degradation. Keep away from oxidizing agents and alkalis.
Precautions To Be Taken in
Storing:
8. Exposure Controls/Personal Protection
OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits
NA ( Trade Secret )
None required under normal conditions of use. A system of local and/or general exhaust
is recommended if handled in a confined area.
Respiratory Equipment
(Specify Type):
Safety glasses with side shieldsEye Protection:
Wear long sleeved clothing and rubber or neoprene gloves. use heat resistant gloves for
hot or molten material. As appropriate for work area.
Protective Gloves:
As appropriate for work area.Other Protective Clothing:
Not applicable.Engineering Controls
(Ventilation etc.):
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
05/01/2014Revision:
06/12/2014Printed:
Page: 3
DMD Lubra-Star Plus
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
9. Physical and Chemical Properties
Physical States:[ ] Gas [ X ] Liquid [ ] Solid
Melting Point:
Boiling Point:> 375.00 F - 190.60 C
Autoignition Pt:
Flash Pt:> 206.00 F
Explosive Limits:LEL: UEL:
Specific Gravity (Water = 1):~ .91 - .94
Appearance: Black. Viscous.
Odor: sweet
Appearance and Odor:
Vapor Pressure (vs. Air or
mm Hg):
Vapor Density (vs. Air = 1):NA
Evaporation Rate:PR
Solubility in Water:
Percent Volatile:
pH:NP
10. Stability and Reactivity
Stable under normal condtions of use and storageConditions To Avoid -
Instability:
Unstable [ ] Stable [ X ]Stability:
strong oxidizers, alkalis.Incompatibility - Materials To
Avoid:
oxides of sulfurHazardous Decomposition Or
Byproducts:
Will occur [ ] Will not occur [ X ]Possibility of Hazardous
Reactions:
Conditions To Avoid -
Hazardous Reactions:
11. Toxicological Information
Toxicological Information:
No acute toxicity data is available for product or components. Cancer Status: not listed
as carcinogen by IARC, NTP or OSHA. There are no known chronic effects from
exposure to this product.
Chronic Toxicological
Effects:
No information found.General Ecological
Information:
12. Ecological Information
This product is biodegradable under aerobic and anaerobic condensationsPersistence and
Degradability:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
05/01/2014Revision:
06/12/2014Printed:
Page: 4
DMD Lubra-Star Plus
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
Please be advised that state and local requirements for waste disposal may be more
restrictive or otherwise different from federal laws and regulations. Consult state and
local regulations regarding the proper disposal of this material.
Any containers or equipment used should be decontaminated immediately after use.
Waste Disposal Method:
13. Disposal Considerations
14. Transport Information
Non-Hazardous for Air Transport: Non-hazardous for air transport.DOT Proper Shipping Name:
DOT Hazard Class:
UN/NA Number:
LAND TRANSPORT (US DOT):
15. Regulatory Information
[ ] Yes [X] No Acute (immediate) Health Hazard
[ ] Yes [X] No Chronic (delayed) Health Hazard
[ ] Yes [X] No Fire Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
[ ] Yes [X] No Reactive Hazard
This material meets the EPA
'Hazard Categories' defined
for SARA Title III Sections
311/312 as indicated:
16. Other Information
Additional Information About
This Product:
Although the information and recommendations set forth herein (hereinafter
"Information") are presented in good faith and believed to be correct as of the date
hereof, Drilling Mud Direct, makes no representations as to the completeness or
accuracy thereof. Information is supplied upon the condition that the person receiving
this MSDS will make own determination as to its suitability for their intended purpose
prior to use. Since the product is within the exclusive control of the user, it is the user's
obligation to determine the conditions of safe use of this product. Such conditions should
comply with all Federal Regulations concerning the Product. NO REPRESENTATIONS
OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE
HERUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH
INFORMATION REFERS.
Company Policy or
Disclaimer:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
05/01/2014Revision:
06/12/2014Printed:
Page: 1
DMD Soda Ash
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
00002Product Code:
DMD Soda AshProduct Name:
Drilling Mud Direct, LLCCompany Name:
8 Inverness Dr. E. Ste 245
Englewood, CO 80112
ChemTrecEmergency Contact:1 [phone]
International 1 [phone]
Office [phone]
Phone Number:
www.muddirect.netWeb site address:
1. Product and Company Identification
2. Hazards Identification
May cause eye, skin, and respiratory irritation.Emergency Overview:
Hazard Rating System:Instability
Special Hazard
Health
FlammabilityHEALTH
FLAMMABILITY
PPE
PHYSICAL
2
0
0
E
2
0
0
NFPA:HMIS:
Potential Health Effects
(Acute and Chronic):
CAS # Hazardous Components (Chemical Name)
3. Composition/Information on Ingredients
Concentration
In Case of Inhalation:
4. First Aid Measures
Emergency and First Aid
Procedures:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention if irritation persists.
In Case of Eye Contact:
Wash with soap and water. Get medical attention if irritation persists.In Case of Skin Contact:
Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical
attention. Never give anything by mouth to an unconscious person.
In Case of Ingestion:
If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becaomes difficult.
5. Fire Fighting Measures
Flash Pt:NP Method Used: Estimate
Full protective clothing and approved self-contained breathing apparatus required for fire
fighting personnel.
Fire Fighting Instructions:
Flammable Properties and
Hazards:
Autoignition Pt:NA
Explosive Limits:LEL: UEL:
Water fog, carbon dioxide, foam, dry chemical.Suitable Extinguishing Media:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
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DMD Soda Ash
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
6. Accidental Release Measures
Scoop up and remove.Steps To Be Taken In Case
Material Is Released Or
Spilled:
Use appropriate protective equipment. Avoid creating and breathing dust.Protective Precautions,
Protective Equipment and
Emergency Procedures:
7. Handling and Storage
Avoid contact with eyes, skin or clothing. Avoid creating or inhaling dust.Precautions To Be Taken in
Handling:
Store away from acids. Store in cool, dry location. Product has a shelf life 36 months.Precautions To Be Taken in
Storing:
8. Exposure Controls/Personal Protection
OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits
Dust/mist respirator. (95%)Respiratory Equipment
(Specify Type):
Dust proof goggles.Eye Protection:
Normal work gloves.Protective Gloves:
Eyewash fountains and safety showers must be easily accessible.Other Protective Clothing:
Use in a well ventilated area. Localized ventilation should be used to control dust levels.Engineering Controls
(Ventilation etc.):
9. Physical and Chemical Properties
Physical States:[ ] Gas [ ] Liquid [ X ] Solid
Melting Point:0.00 C
Boiling Point:0.00 C
Autoignition Pt:NA
Flash Pt:NP Method Used: Estimate
Explosive Limits:LEL: UEL:
Specific Gravity (Water = 1): 2.5
Appearance: White. Powder.
Odor: Odorless.
Appearance and Odor:
Bulk density: 48-62 - 20C LB/CF
Vapor Pressure (vs. Air or
mm Hg):
Vapor Density (vs. Air = 1):
Evaporation Rate:
Solubility in Water:
Percent Volatile:
pH: 11.5
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
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DMD Soda Ash
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
10. Stability and Reactivity
None anticipated.Conditions To Avoid -
Instability:
Unstable [ ] Stable [ X ]Stability:
Strong acids.Incompatibility - Materials To
Avoid:
Carbon monoxide and carbon dioxide.Hazardous Decomposition Or
Byproducts:
Will occur [ ] Will not occur [ X ]Possibility of Hazardous
Reactions:
Conditions To Avoid -
Hazardous Reactions:
11. Toxicological Information
Inhalation: May cause respiratory irritation.
Skin Contact: prolonged or repeated contact may cause skin irritation.
Eye Contact: may cause eye irritation.
Ingestion: Irritation of the mouth, throat and stomach.
Toxicological Information:
Oral: LD50: 4220 mg/kg (Rat)
Dermal: Not determined
Inhalation: Not determined.
Chronic Toxicological
Effects:
No data available to indicate product or components present at greater than 1% are
chronic health hazards.
Carcinogenicity/Other
Information:
12. Ecological Information
Acute Fish Toxicity: TLM24: 385 mg/l ( Lepomis macrochirus)
Acute Crustaceans Toxicity: Not determined
Acute Algae Toxicity: Not determined
Results of PBT and vPvB
assessment:
Bury in licensed landfill according to federal, state, and local regulations.
Follow all applicanle national and local regulations.
Waste Disposal Method:
13. Disposal Considerations
14. Transport Information
Not restricted.DOT Proper Shipping Name:
DOT Hazard Class:
UN/NA Number:
LAND TRANSPORT (US DOT):
Not restricted.IMDG/IMO Shipping Name:
MARINE TRANSPORT (IMDG/IMO):
Not restricted.ICAO/IATA Shipping Name:
AIR TRANSPORT (ICAO/IATA):
Not restricted.Additional Transport
Information:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
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DMD Soda Ash
MATERIAL SAFETY DATA SHEET
02/20/2013Supersedes Revision:
15. Regulatory Information
[ ] Yes [X] No Acute (immediate) Health Hazard
[ ] Yes [X] No Chronic (delayed) Health Hazard
[ ] Yes [X] No Fire Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
[ ] Yes [X] No Reactive Hazard
This material meets the EPA
'Hazard Categories' defined
for SARA Title III Sections
311/312 as indicated:
US TSCA : All components listed on inventory or are exempt.
EPA Sara Title III Extremely Hazardous Substances: Not applicable
EPA SARA (311,312) Hazard Class: Acute Health Hazard
EPA SARA (313) Chemicals: This product does not contain a toxic chemical for routine
annual " Toxic Chemical Release Reporting" under Section 313 (40 CFR 372).
EPA CERCLA/ Superfund Reportable Spill Quantity: Not Applicable.
EPA RECA Hazardous Waste Classification: If product becomes a waste, it does NOT
meet the criteria of a hazardous waste as defined by the US EPA.
California Proposition 65: All components listed do not apply to the California Propostion
65 Regulation.
MA Right-to-Know Law: Does not apply
NJ Right-to-Know Law Does not apply
PA: Right-to-know Law: Does not apply
Canadian Regulations
Canadian DSL Inventory All components listed on inventory.
WHMIS Hazard Class; Un-controlled
Regulatory Information:
16. Other Information
Additional Information About
This Product:
Although the information and recommendations set forth herein (hereinafter
"Information") are presented in good faith and believed to be correct as of the date
hereof, Drilling Mud Direct, makes no representations as to the completeness or
accuracy thereof. Information is supplied upon the condition that the person receiving
this MSDS will make own determination as to its suitability for their intended purpose
prior to use. Since the product is within the exclusive control of the user, it is the user's
obligation to determine the conditions of safe use of this product. Such conditions should
comply with all Federal Regulations concerning the Product. NO REPRESENTATIONS
OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE
HERUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH
INFORMATION REFERS.
Company Policy or
Disclaimer:
Licensed to NorthStar Fluid Solutions: MIRS MSDS, (c) A V Systems, Inc.ANSI Z400.1-2004
02/20/2013Revision:
02/20/2013Printed:
Page: 1
Star Plex
MATERIAL SAFETY DATA SHEET
01/25/2013Supercedes Revision:
0003Product Code:
Star PlexProduct Name:
Mixed Metal BlendTrade Name:
NorthStar Fluid SolutionsCompany Name:
PO Box 271036
Louisville, CO 80027
ChemTrecEmergency Contact:1 [phone]
International 1 [phone]
Information:
[phone]
Phone Number:
www.northstarfluids.comWeb site address:
1. Product and Company Identification
2. Hazards Identification
Product may irritate eyes, skin, mucous membranes and upper respiratory tract with
overexposure. Prolonged inhalation (chronic) of dust may result in lung damage.
Emergency Overview:
Hazard Rating System:Instability
Special Hazard
Health
FlammabilityHEALTH
FLAMMABILITY
PPE
PHYSICAL
1
0
0
E
1
0
0
Potential Health Effects
(Acute and Chronic):
Immediately flush with plenty of water for at least 15 minutes. Get medical attention.Eye Contact:
Wash material off the skin with plenty of soap and water. If redness, itching or a burning
sensation develops, get medical attention. Remove contaminated clothing.
Skin Contact:
Flush oral cavity and give one or two glasses of water. If gastrointestinal symptoms
develop., consult medical personnel. (Never give anything by mouth to an unconscious
person.)
Ingestion:
Remove victim to fresh air. Consult medical personnel.Inhalation:
CAS # Hazardous Components (Chemical Name)
3. Composition/Information on Ingredients
Concentration
NA ( Trade Secret ) < 1.0 %
4. First Aid Measures
Emergency and First Aid
Procedures:
Immediately flush with plenty of water for at least 15 minutes. Get medical attention.In Case of Eye Contact:
Wash material off the skin with plenty of soap and water. If redness, itching or a burning
sensation develops, get medical attention. Remove contaminated clothing.
In Case of Skin Contact:
Flush oral cavity and give one or two glasses of water. If gastrointestinal symptoms
develop., consult medical personnel. (Never give anything by mouth to an unconscious
person.)
In Case of Ingestion:
Remove victim to fresh air. Consult medical personnel.
In Case of Inhalation:
ANSI Z400.1-2004
02/20/2013Revision:
02/20/2013Printed:
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Star Plex
MATERIAL SAFETY DATA SHEET
01/25/2013Supercedes Revision:
5. Fire Fighting Measures
Flash Pt:NA Method Used: Estimate
Water, foam, dry chemical or carbon dioxide.Fire Fighting Instructions:
No data available.Flammable Properties and
Hazards:
Autoignition Pt:NA
Explosive Limits:LEL: No data. UEL: No data.
Suitable for all regular extinguishing materials. Do not use high pressure water jet.Suitable Extinguishing Media:
None knownUnsuitable Extinguishing
Media:
6. Accidental Release Measures
Avoid creating dust. Avoid contact with skin or eyes. Sweep or shovel into metal or
plastic container. Remove mechanically while dry.
Steps To Be Taken In Case
Material Is Released Or
Spilled:
7. Handling and Storage
DO not get in eyes. Avoid creating dust.Precautions To Be Taken in
Handling:
Normal chemical handling and storage in a cool, dry place tightly sealed. Keep dust
formation to a minimum.
Precautions To Be Taken in
Storing:
8. Exposure Controls/Personal Protection
OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits
PEL: 8825 ppm/(%SiO2+5) TLV: 0.05 mg/m3 (R) NA ( Trade Secret )
No data.
Use MSHA-NIOSH approved respirator for dust, mists and fumes whose TLV is greater
than 0.05 mg/m3
Respiratory Equipment
(Specify Type):
Chemical resistant apron or protective suit if splashing or repeated contact with solution
is likely.
Eye Protection:
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good
laboratory practices. Wash and dry hands.
Protective Gloves:
Long sleeve shirt/ApronOther Protective Clothing:
Use local exhaust, keep dust exposure to a minium.Engineering Controls
(Ventilation etc.):
Handle in accordance with good industrial hygiene and safety practice. Wash hands
before breaks and at the end of workday.
Work/Hygienic/Maintenance
Practices:
ANSI Z400.1-2004
02/20/2013Revision:
02/20/2013Printed:
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MATERIAL SAFETY DATA SHEET
01/25/2013Supercedes Revision:
9. Physical and Chemical Properties
Physical States:[ ] Gas [ ] Liquid [ X ] Solid
Melting Point:> 500.00 C
Boiling Point:NA
Autoignition Pt:NA
Flash Pt:NA Method Used: Estimate
Explosive Limits:LEL: No data. UEL: No data.
Specific Gravity (Water = 1):No data.
Density: 500 - 600 G/L
White to Gray
No apparent odor.
Solid, powder
Appearance and Odor:
Vapor Pressure (vs. Air or
mm Hg):
No data.
Vapor Density (vs. Air = 1):No data.
Evaporation Rate:No data.
Solubility in Water:No data.
Percent Volatile:No data.
10. Stability and Reactivity
None knownConditions To Avoid -
Instability:
Unstable [ ] Stable [ X ]Stability:
Reacts violently with strong acids.Incompatibility - Materials To
Avoid:
None knownHazardous Decomposition Or
Byproducts:
Will occur [ ] Will not occur [ X ]Possibility of Hazardous
Reactions:
None knownConditions To Avoid -
Hazardous Reactions:
11. Toxicological Information
No data available.Toxicological Information:
Irritation or Corrosion:
Aquatic Toxicity: Trout (Oncorhynchus mykiss) 96 hr Static Acute Test passes at
LC50-379 (PPM)
General Ecological
Information:
12. Ecological Information
Persistence and
Degradability:
ANSI Z400.1-2004
02/20/2013Revision:
02/20/2013Printed:
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Star Plex
MATERIAL SAFETY DATA SHEET
01/25/2013Supercedes Revision:
Do not allow residue to flow into drainage system. Waste disposal according to
regulations of responsible local authority.
Waste Disposal Method:
13. Disposal Considerations
14. Transport Information
Not regulatedDOT Proper Shipping Name:
DOT Hazard Class:
UN/NA Number:
LAND TRANSPORT (US DOT):
Not regulatedIMDG/IMO Shipping Name:
MARINE TRANSPORT (IMDG/IMO):
Not regulatedICAO/IATA Shipping Name:
AIR TRANSPORT (ICAO/IATA):
CAS # Hazardous Components (Chemical Name)
15. Regulatory Information
S. 302 (EHS) S. 304 RQ S. 313 (TRI)
EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists
NA ( Trade Secret ) No No No
16. Other Information
No data available.Additional Information About
This Product:
Although the information and recommendations set forth herein (hereinafter
"Information") are presented in good
faith and believed to be correct as of the date hereof, NorthStar Fluid Solutions, makes
no representations as to the completeness or accuracy thereof. Information is supplied
upon the condition that the person receiving this MSDS will make own determination as
to its suitability for their intended purpose prior to use. Since the product is within the
exclusive control of the user, it is the user's obligation to determine the conditions of safe
use of this product. Such conditions should comply with all Federal Regulations
concerning the Product. NO REPRESENTATIONS OR WARRANTIES, EITHER
EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR
PURPOSE OR ANY OTHER NATURE ARE MADE HERUNDER WITH RESPECT TO
INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.
Company Policy or
Disclaimer:
ANSI Z400.1-2004