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HomeMy WebLinkAboutNC0088838_Final Permit_20180523ti ;Y Water Resources M Environmental Quality May 23, 2018 Mr. Stuart Kerkhoff Environmental Health and Safety Manager Radiator Specialty Company 600 Radiator Road Indian Trail, NC 28079 Dear Mr. Smith: ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Interim Director Subject: Final NPDES Permit Renewal Permit NCO088838 Radiator Specialty Company Union County Facility Grade I Division personnel have reviewed and approved your application for renewal of the subject permit. Accordingly, we are forwarding the attached NPDES permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 15, 2007 (or as subsequently amended). Please note that the receiving stream is listed as impaired for fish community (fair) and benthos (poor) on the North Carolina Final 2014 303(d) Impaired Waters List. Addressing impaired waters is a high priority with the Division, and instream data will continue to be evaluated. If there is noncompliance with permitted effluent limits and stream impairment can be attributed to your facility, then mitigative measures may be required. The Division received your comments in a letter dated March 14, 2018 and the following changes were made to the draft permit sent to you on February 7, 2018: 0 Monitoring frequency for TSS has been reduced from monthly to quarterly in light of reviewed effluent data showing consistent compliance with permit limits, yielding 7% detection over the span of eight years (from February 2010 through February 2018). TSS monitoring will remain in the permit as this is a pollutant of concern and a parameter routinely put in groundwater remediation NPDES permits. • Monitoring frequency for pH has been reduced from monthly to quarterly in light of reviewed effluent data showing consistent compliance with water quality standards. pH will remain in the permit as this is a pollutant of concern and a parameter routinely in groundwater remediation NPDES permits. -- Nothing Compares':--,, State of North Carolina I Environmental Quality 1611 Mail Service Center I Raleigh, North Carolina 27699-1611 919-707-9000 • The facility component list on the Supplement to Permit Cover Sheet was revised by removing "with recorder" for the effluent meter per your request after verifying that the meter does not have a chart or other recording device, but flow readings are taken manually on a daily basis. • 1,4 -Dioxane limits and monitoring will remain in the permit as this parameter does have a NC calculated surface water criterion of 80 µg/L to protect human health in Class C waters. The reopener will remain in the permit to allow for changes to address 1,4 -Dioxane monitoring, treatment and/or compliance. 1,4 -Dioxane samples shall be analyzed by a NC certified laboratory using EPA Test Method 624. 1, and results shall be reported to the lower reporting level of the procedure. In September 2017, EPA promulgated the 2017 Methods Update Rule approving test method 624.1 for 1,4 - Dioxane. All tests for parameters listed in the NPDES permit must be performed in accordance with EPA approved test methods and by a NC certified laboratory. Currently, there are several laboratories certified in NC to perform 1,4 -Dioxane testing. Radiator Specialty is required to submit effluent data results on 1,4 -Dioxane using one of these certified labs. To learn what certified labs are in your area, please contact Data Satterwhite, DWR Laboratory Certification Branch, at 919-733-3908 ext. 202 or by e-mail: dana.satterwhite(a::ncdenr.gov. The final permit maintains the following significant changes identified in the letter sent on February 7, 2018: • Removed monitoring for Chloroethane from this permit, since an evaluation of submitted effluent data found no reasonable potential to exceed the EPA criterion of 550 µg/L. • Removed monitoring 'for 1,1-Dichloroethene; 1,2-Dichloroethene (total); 1,1,1 - Trichloroethane; and 1,2-Dichloroethane have been removed from this permit. These parameters are no longer pollutants of concern, based on reasonable potential evaluation and no significant levels in the influent. • Revised daily limits for Tetrachloroethene and Vinyl Chloride. The 2015 EPA Human Health water quality criterion for these parameters was applied in this permit (technical change). • Added monitoring with limits for pH. The pH is a pollutant of concern and the freshwater standard for Class C waters was applied in this permit. • Added quarterly monitoring and a limit of 80 gg/L for 1,4 -Dioxane to the permit with provisional monitoring increase to monthly if a sample measurement is equal to or greater than the limit. Added special condition A. (3.) REOPENER 1,4 -DIOXANE in this permit. Adjacent monitoring wells data indicate potential migration of this pollutant to the groundwater remediation collection system, thus a potential for this pollutant to be present in excess of its WQBEL which may require modification of the permit to address compliance. Federal regulations require electronic submittal of all discharge monitoring reports (DMRs) and program reports. The final NPDES Electronic Reporting Rule was adopted and became effective on December 21, 2015. The requirement to begin reporting discharge monitoring data electronically using the NC DWR's Electronic Discharge Monitoring Report (eDMR) internet application has been added to this permit. [See Special Condition A. (4.)] Page 2 of 3 For information on eDMR, registering for eDMR and obtaining an eDMR user account, please visit the following web page: http://deq.nc.gov/about/divisions/water- resources/edmr. For more information on EPA's final NPDES Electronic Reporting Rule, please visit the following web site: https://www.federalregister.gov/documents/2015/10/22/2015- 24954/national-pollutant-discharge-elimination-system-npdes-electronic-reporting-rule. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699- 6714). Unless such demand is made, this decision shall be final and binding. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Resources or any other Federal, State, or Local governmental permits that may be required. If you have any questions concerning this permit, please contact Gary Perlmutter at (919) 807- 6385 or via email at gary.perlmutter@ncdenr.gov. Sincerely, Linda Culpepper. nterim Director ivision of Water Resources, NCDEQ Hardcopy: NPDES Files Central Files DWR / Winston-Salem Regional Office / Water Quality Operations e -Copy: DWR / Aquatic Toxicity Branch / Susan Meadows Page 3 of 3 Permit NC0088838 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Radiator Specialty Company is hereby authorized to discharge wastewater from a facility located at the Radiator Specialty Company 600 Radiator Road Indian Trail Union County to receiving waters designated as an unnamed tributary to South Fork Crooked Creek in the Yadkin Pee - Dee River Basin in accordance with effluent limitations, monitoring requirements, and other applicable conditions set forth in Parts I, II, III, and IV hereof. The permit shall become effective July 1, 2018. This permit and the authorization to discharge shall expire at midnight on March 31, 2023. Signed this day, May 23, 2018. Linulpepper U '- 't IntkrVi Director, Division of Water Resources By Authority of the Environmental Management Commission Pagel of 8 Permit NC0088838, SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. Radiator Specialty Company is hereby authorized to: 1. Continue to operate a 0.090 MGD Ground Water Remediation treatment facility consisting of. ■ one (1) 6,000 -gallon equalization tank ■ one (1) transfer pump • one (1) packed air stripper column with blower and overflow sump • effluent meter gravity sewer to outfall Located at Radiator Specialty Company, 600 Radiator Road, Indian Trail in Union County. 2. Discharge from said treatment works at the location specified on the attached map into unnamed tributary to the South Fork Crooked Creek, a class C water in the Yadkin River Basin. Page 2 of 8 Permit NCO088838 Part I A. (1.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS [15A NCAC .02B .0400 et seq., .02B .0500 et seq.] a. Beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge treated groundwater from Outfall 001 of this Grade I facility. Such discharges shall be limited and monitored' by the Permittee as specified below: EFFLUENT CHARACTERISTICS LIMITATIONS MONITORING REQUIREMENTS Monthly .Average 0.090 MGD Daily Maximum Measurement Frequency Sample Type Sample Location Flow 2 Continuous Recording Effluent Total Suspended Solids 30.0 mg/L 45.0 mg/L Quarterly Grab Effluent Tetrachloroethene 3.3 gg/L Monthly Grab Effluent Vinyl Chloride 2.4 Ag/l, Monthly Grab Effluent pH Between 6.0 and 9.0 S.U. Quarterly Grab Effluent 1,4 -Dioxanes 80 µg/L Quarterly 3 Grab Effluent 1,1-Dichloroethane Monitor and Report Quarterly Grab Effluent Trichloroethene Monitor and Report Quarterly Grab Effluent Benzene Monitor and Report Quarterly Grab Effluent Methyl Chloride Monitor and Report Quarterly Grab Effluent Toluene Monitor and Report Quarterly Grab Effluent Chronic Toxicity 4 Monitor and Report Quarterly Grab Effluent Footnotes: 1. The Permittee shall submit Discharge Monitoring Reports electronically using NC DWR's eDMR application system. See Special Condition A. (4.). 2. Flow shall be measured with a totalizing flow meter. 3. 1,4 -Dioxane measurement shall be conducted by a NC -certified laboratory using EPA Test Method 624. 1, and the results shall be reported to the lower reporting level of the procedure. If a measurement is equal to or greater than 80 µg/L, then monitoring shall immediately be increased to monthly. See Special Condition A. (3). 4. Chronic Toxicity (Ceriodaphnia dubia) limit at 90% with testing in January, April, July, and October; see Special Condition A. (2.). Quarterly toxicity testing shall coincide with the sampling of all the other parameters. b. There shall be no discharge of floating solids or visible foam in other than trace amounts. Page 3 of 8 Permit NC0088838• A. (2.) CHRONIC TOXICITY PERMIT LIMIT (Quarterly) [I 5A NCAC 02B .0200 et seq.] The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 90%. The permit holder shall perform at a minimum, quarter lx monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised December 2010, or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised- December 2010) or subsequent versions. The tests will be performed during the months of January, April, July, and October. These months signify the first month of each three-month toxicity testing quarter assigned to the facility. Effluent sampling for this testing must be obtained during representative effluent discharge and shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -December 2010) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR -1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP313 for the Chronic Value. Additionally, DWR Form AT - 3 (original) is to be sent to the following address: Attention: North Carolina Division of Water Resources Water Sciences Section/Aquatic Toxicology Branch 1623 Mail Service Center Raleigh, NC 27699-1623 Completed Aquatic Toxicity Test Forms shall be filed with the Water Sciences Section no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Water Sciences Section at the address cited above. Should the Permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Assessment of toxicity compliance is based on the toxicity testing quarter, which is the three-month time interval that begins on the first day of the month in which toxicity testing is required by this permit and continues until the final day of the third month. Page 4of8 Permit NCO088838 (Continued A. (2) CHRONIC TOXICITY PERMIT LIMIT) Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Resources indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. A. (3.) REOPENER 1,4 -DIOXANE [G.S. 143-215.1(b)] Upon measurement of an effluent 1,4 -Dioxane sample equal to or greater than 80 gg/L, monitoring shall be increased immediately to monthly. If deemed necessary by the Division, the permit may be reopened to modify permit requirements to address 1,4 -Dioxane monitoring, treatment and/or compliance. Page 5 of 8 Permit NC0088838, A. (4.) ELECTRONIC REPORTING OF DISCHARGE MONITORING REPORTS [G.S. 143-215.1(b)] Federal regulations require electronic submittal of all discharge monitoring reports (DMRs) and program reports. The final NPDES Electronic Reporting Rule was adopted and became effective on December 21, 2015. NOTE: This special condition supplements or supersedes the following sections within Part II of this permit (Standard Conditions for NPDES Permits): - • Section B. (11.) • Section D. (2.) • Section D. (6.) • Section E. (5.) Signatory Requirements Reporting Records Retention Monitoring Reports 1. Reporting Requirements [Supersedes Section D. (2.) and Section „E (5.) (a)i The permittee shall report discharge monitoring data electronically using the NC DWR's Electronic Discharge Monitoring Report (eDMR) internet application. Monitoring results obtained during the previous month(s) shall. be summarized for each month and submitted electronically using eDMR. The eDMR system allows permitted facilities to enter monitoring data and submit DMRs electronically using the internet. Until such time that the state's eDMR application is compliant with EPA's Cross -Media Electronic Reporting Regulation (CROMERR), permittees will be required to submit all discharge monitoring data to the state electronically using eDMR and will be required to complete the eDMR submission by printing, signing, and submitting one signed original and a copy of the computer printed eDMR to the following address: NC DEQ / Division of Water Resources / Water Quality Permitting Section ATTENTION: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 If a permittee is unable to use the eDMR system due to a demonstrated hardship or due to the facility being physically located in an area where less than 10 percent of the households have broadband access, then a temporary waiver from the NPDES electronic reporting requirements may be granted and discharge monitoring data may be submitted on paper DMR forms (MR 1, 1. 1, 2, 3) or alternative forms approved by the Director. Duplicate signed copies shall be submitted to the mailing address above. See "How to Request a Waiver from Electronic Reporting" section below. Regardless of the submission method, the first DMR is due on the last day of the month following the issuance of the permit or in the case of a new facility, on the last day of the month following the commencement of discharge. Starting on December 21, 2020, the permittee must electronically report the following compliance monitoring data and reports, when applicable: Page 6 of 8 Permit NCO088838 (Continued A. (4.) ELECTRONIC REPORTING OF DISCHARGE MONITORING REPORTS) • Sewer Overflow/Bypass Event Reports; • Pretreatment Program Annual Reports; and • Clean Water Act (CWA) Section 316(b) Annual Reports. The Permittee may seek an electronic reporting waiver from the Division (see "How to Request a Waiver from Electronic Reporting" section below). 2. Electronic Submissions In accordance with 40 CFR 122.41(1)(9), the permittee must identify the initial recipient at the time of each electronic submission. The Permittee should use the EPA's website resources to identify the initial recipient for the electronic submission. Initial recipient of electronic NPDES information from NPDES-regulated facilities means the entity (EPA or the state authorized by EPA to implement the NPDES program) that is the designated entity for receiving electronic NPDES data [see 40 CFR 127.2(b)]. EPA plans to establish a website that will also link to the appropriate electronic reporting tool for each type of electronic submission and for each state. Instructions on how to access and use the appropriate electronic reporting tool will be available as well. Information on EPA's NPDES Electronic Reporting Rule is found at: htt s://www.federalre ister. ov/documents/2015/10/22/2015-24954/national- ollutant-dischar e-elimination-system-nodes-electronic-reoortinp--rule Electronic submissions must start by the dates listed in the "Reporting Requirements" section above. 3. How to Request a Waiver from Electronic Reporting The permittee may seek a temporary electronic reporting waiver from the Division. To obtain an electronic reporting waiver, a permittee must first submit an electronic reporting waiver request to the Division. Requests for temporary electronic reporting waivers must be submitted in writing to. the Division for written approval at least sixty (60) days prior to the date the facility would be required under this permit to begin submitting monitoring data and reports. The duration of a temporary waiver shall not exceed 5 years and shall thereupon expire. At such time, monitoring data and reports shall be submitted electronically to the Division unless the permittee re -applies for and is granted a new temporary electronic reporting waiver by the Division. Approved electronic reporting waivers are not transferrable. Only permittees with an approved reporting waiver request may submit monitoring data and reports on paper to the Division for the period that the approved reporting waiver request is effective. Information on eDMR and the application for a temporary electronic reporting waiver are found on the following web page: hftp://deg..nc.gov/about/divisions/water-resources/edi-nr Page 7of8 Permit NC0088838, (Continued A. (4.) ELECTRONIC REPORTING OF DISCHARGE MONITORING REPORTS) 4. Sionatory Requirements (Supplements Section B. (11.) (b) and Supersedes Section B (11„) (d)t All eDMRs submitted to the permit issuing authority shall be signed by a person described in Part II, Section B. (I 1.)(a) or by a duly authorized representative of that person as described in Part II, Section B. (11.)(b). A person, and not a position, must be delegated signatory authority for eDMR reporting purposes. For eDMR submissions, the person signing and submitting the DMR must obtain an eDMR user account and login credentials to access the eDMR system. For more information on North Carolina's eDMR system, registering for eDMR and obtaining an eDMR user account, please visit the following web page: htti): eq.nc.gov/about/divisions/water-resources/edmr Certification. Any person submitting an electronic DMR using the state's eDMR system shall make the following certification [40 CFR 122.22]. NO OTHER STATEMENTS OF CERTIFICATION WILL BE ACCEPTED: 7 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. " 5. Records Retention [Supplements Section D. (6.)1 The permittee shall retain records of all Discharge Monitoring Reports, including eDMR submissions. These records or copies shall be maintained for a period of at least 3 years from the date of the report. This period may be extended by request of the Director at any time [40 CFR 122.41 ]. Page 8 of 8 USGS Quad: G16SW Matthews, NC Outfall Facility Latitude: 350 3' S5" W 350 3'45" W Longitude: 800 39' 14" N 800 39'3" N Stream Class: C North Facility Location Subbasin: 03-07-12 HUC: 03040105 Radiator Specialty Company NC0088838 Zeceiving Stream: UT to South Fork Crooked Creek Union Countv Fact Sheet NPDES Permit No. NCO088838 Permit Writer/Email Contact Gary Perlmutter, gary.perlmutter@ncdenr.gov Date: May 21, 2018 Division/Branch: NC Division of Water Resources/NPDES Complex Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ® Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: Radiator Specialty Company/Radiator Specialty Company Applicant Address: 600 Radiator Road. Indian Trail, NC 28709 Facility Address: 600 Radiator Road. Indian Trail, NC 28709 Permitted Flow: 0.09 MGD Facility Type/Waste: MINOR Industrial, Ground Water Remediation Facility Class: Class I Treatment Units: EQ/collection tank, air stripper, gravity flow to outfall Pretreatment Program (Y/1) No County: Union Region Mooresville Briefly describe the proposed permitting action and facility background: Radiator Specialty Company operates a 0.09 MGD ground water remediation facility at its Indian Trail site, and had applied to renew its NPDES permit in May 2013. The site is part of a 1994 RCRA post -closure remediation requirement. Initially the remediated wastewater was accepted by a local utility. However, in 2009, the local utility informed Radiator Specialty Company that it would no longer accept the wastewater. As a result, Radiator Specialty Company applied for and was issued a NPDES permit in 2009. Page 1 of 10 The Division was advised by the Hazardous Waste Section in 2012 that significant levels of 1,4 -Dioxane was being reported in the monitoring wells data, which indicated migration of the pollutant in the aquafer. This migration may result in 1,4 -Dioxane in the collected groundwater remediation influent. To assist with development of this permit and to better characterize influent pollutants of concern, the Permittee submitted a series of influent volatile organic analysis as requested by the Division. 2. Influent Volatile Organic Data Summary Influent volatile organic data is summarized below for monthly samples for the period August through December 2014. Table. Influent Volatile Organic Data Summary Parameter Unit of Measure Average Maximum Minimum Benzene µg/L 1.11 1.4 0.77 Chloroethane µg/L 13.3 15 9.4 2-Chlorotouluene µg/L 2.98 3.3 0.81 4-Chlorotouluene m/L < I < I < 0.5 1, 1 -Dichloroethane µg/L 49.0 60 41 1,2-Dichloroetheane µg/L 0.678 0.75 0.56 1, 1 -Dichloroethene µg/L 27.0 31 23 Cis-1,2-Dichlorothene µg/L 22.8 30 20 Trans-1,2-Dichloroethene µg/L 2.52 3.0 2.0 Dichlorodifluoromethane µg2 4.50 6.1 3.2 1,4 Dioxane µg/L < 80 < 80 < 80 Ethylbenzene µg/L < I < I Methyl ethyl ketone µg/L < 5 < 5 < 5 Methylene Chloride µg/L < 2 < 2 < 1 Methyl isobutyl ketone (MIBK) µg/L < 5 < 5 7<5 Tetrachloroethene µg/l, 84.4 100 70 Toluene µg/L < 1 < I < 0.5 1,1,1 -Trichloroethane µg/l, 1.98 2.6 1.7 Trichloroethene µg/L 5.94 7.4 4.4 Vinyl chloride µg/L 4.72 6.5 3.2 Xylenes (Total) µg/L < 2 < 2 < 1 Page 2 of 10 3. Receiving Waterbody Information Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001- UT to South Fork Crooked Creek Stream Segment: 13-17-20-2 Stream Classification: C Drainage Area (mi2): 2.2 Summer 7Q 10 (cfs) 0 Winter 7Q10 (cfs): 0 - 30Q2 (cfs): 0.07 Average Flow (cfs): - IWC (% effluent): 100% 303(d) listed/parameter: This segment is impaired for Benthos and Fish Community on the Final 2014 303(d) list, first listed in 1998 Subject to TMDL/parameter: No Subbasin/HUC: Yadkin Pee -Dee; 03-07-12/03040105 FuSGS Topo Quad: G16SW Matthews, NC 4. Effluent Data Summary Effluent data is summarized below for the period September 2015 through August 2017 for limited parameters and April 2014 through August 2017 for monitor only parameters. Table. Effluent Data Summary Parameter Units Average Max Min Permit Limit' Flow MGD 0.0413 0.082 0.003 MA 0.090 TSS mg/L < 6.7 6.7 < 2.5 DM 45.0 MA 30.0 Chloroethane gg/L < 5.2 5.2 < 0.5 Monitor only 1, 1 -Dichloroethane gg/L < 3.3 3.3 < 0.5 Monitor only 1, 1 -Dichloroethene gg/L < 2.5 2.5 < 0.5 Monitor only 1,2-Dichloroethene (total) gg/L All non -detects, < 0.5 to < 10 Monitor only Tetrachloroethene gg/L All non -detects, < 0.5 to < 3 DM 3.0 1,1,1 -Trichloroethane mg/L < 4 1.1 < 0.5 DM 4.0 Trichloroethene gg/L All non -detects, < 0.5 to < 4 Monitor only Benzene gg/L < 1 0.78 < 0.5 Monitor only Methylene Chloride gg/L < 3.1 3.1 < 1 Monitor only Page 3 of 10 1,2-Dichloroethane Toluene Vinyl Chloride µg/L All non -detects, < 0.5 to < 1 pgIL < 1 < 0.5 µg/L I < 2 1 2 J < 0.5 'MA = Monthly Average, WA = Weekly Average, DM = Daily Maximum. 5. Instream Data Summary Monitor only Monitor only DM 2.0 Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/l of instream standard 'at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: NA Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): NA Name of Monitoring Coalition: NA 6. Compliance Summary Summarize the compliance record with permit effluent limits (past S years): There was one reported limit exceedance: for the daily maximum Tetrachloroethane in November 2013. As a results, a Notice of Violation was issued. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past S years): Beginning in 2013 the facility had performed and passed 15 chronic toxicity tests at 90% effluent concentration. Summarize the results from the most recent compliance inspection: The last facility inspection conducted in 2016 reported that the facility was well maintained and operated. 7. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with ISA NCAC 2B. 0204(b): NA Oxygen-ConsumiLig Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits Page 4 of 10 (e.g., BOD = 30 mg/L for Municipals) may be appropriate if deemed more stringent based on dilution and model results. Ifpermit limits are more stringent than TBELs, describe how limits were developed: NA Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/1(winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 ug/l (acute impacts). Due to analytical issues, all TRC values reported below 50 gg/L are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: NA Reasonable Potential Analysis (RPA] for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d)(i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of 1/Z detection limit for "less than" values; and 4) stream flows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between August 2013 and August 2017. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria based on effluent concentrations or continue to be a major pollutant of concern, BPJ. Tetrachoroethene; Vinyl Chloride; 1,4 -Dioxane (predicted) • Monitoring Only The following parameters will not receive a limit, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was > 50% of the allowable concentration and continue to be pollutants of interest, BPJ. l , l-Dichloroetha ne; Trichloroethene.; Benzene; Methyl Chloride; Toluene • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration and are not pollutants of concern, BPJ. Chloroethane; 1,2-Dichloroethene (total), 1,1,1 -Trichloroethane; 1,1- Dichloroethene; 1,2-Dichloroethane If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits Page 5 of 10 issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Ground Water Remediation wastewater and as such is considered complex wastewater. A chronic WET limit at 90% effluent will continue on a quarterly frequency using a garb sample for testing. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (> 1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case-by-case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/1. Describe proposed permit actions based on mercury evaluation: This facility is not considered a source of mercury; thus, the TMDL does not apply. - Other TMDL/Nutrient Manage rient Strategy Considerations If applicable, describe any other TMDLs/NutrientManagement Strategies and their implementation within this permit: NA. Other WOBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special. actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H. 010 7( c) (2) (B), 40CFR 122.4 7, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA 8. Technology -Based Effluent Limitations (TBELs) NA 9. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 213.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 21-1.0105(c)(2). In all cases, Page 6 of 10 existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 10. Antibacksliding Review Sections 402(0)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA 11. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(0) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. Monitoring for TSS will be reduced from monthly to quarterly based on BPJ following review of data provided by the Permittee following draft Public Notice. For instream monitoring, refer to Section 4. 12. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 13. Summary of Proposed Permitting Actions Table. Current Permit Conditions and Proposed Changes Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 0.09 MGD No change 15A NCAC 2B .0505 Page 7 of 10 Page 8 of 10 No change in limits; MA 30.0 mg/L reduce monitoring TBEL. BPJ - reviewed data showed TSS DM 45.0 mg/L from monthly to most non -detects with highest No change quarterly detection at 21 in 2010. WQBEL. State WQ standard, 15A pH No requirement 6 — 9 SU; add NCAC 2B .0200; reviewed data concentration < 50% of WQBEL, quarterly monitoring insufficient to show seasonal or not a pollutant of concern other variation. WQBEL (correction). State WQ Tetrachloroethene DM 3.0 gg/L Technical change standard, 15A NCAC 2B, RPA concentration < 50% of WQBEL, DM 3.3 gg/L demonstrated predicted not a pollutant of concern concentration exceeds WQBEL WQBEL (correction). State WQ Vinyl Chloride DM 2.0 gg/L Technical change standard, 15A NCAC 2B, influent concentration < 50% of the 2015 DM 2.4 gg/L concentrations exceed WQBEL, EPA criterion pollutant of concern BPJ Monitor only 'Mnn;tnr I No WQBEL available; no ChInmi-41iAnP nnhi V_ c -F,-- ___;t „i.l ,. Page 8 of 10 -------- ----J �...++..+ ... ++va++ 1.. va aaaa avuuVllLLlJ1V tJVLVll L1LL1 1V LL11LL LL.7111r., EPA criterion 1, 1 -Dichloroethane Monitor only No change Pollutant of concern BPJ RPA demonstrated predicted 1, 1 -Dichloroethene Monitor only Remove from permit concentration < 50% of WQBEL, not a pollutant of concern 1,2-Dichloroethene RPA demonstrated predicted (total) Monitor only Remove from permit concentration < 50% of WQBEL, not a pollutant of concern 1.1.1- RPA demonstrated predicted Trichloroethane DM 4.0 gg/L Remove from permit concentration < 50% of the 2015 EPA criterion Trichloroethene Monitor only No change Pollutant of concern BPJ Benzene Monitor only No change Pollutant of concern BPJ Methyl Chloride Monitor only No change Pollutant of concern BPJ RPA demonstrated predicted 1,2-Dichloroethane Monitor only Remove concentration < 50% of WQBEL, not a pollutant of concern Toluene Monitor only No change Pollutant of concern BPJ Chronic limit, 90% WQBEL. No toxics in toxic Toxicity Test effluent using grab No change amounts. 15A NCAC 2B.0200 and sample 15A NCAC 2B.0500, ATU approved sampling type Add quarterly WQBEL. Pollutant of concern, monitoring with DM based on the 80 pg/1 surface water 1,4 -Dioxane No requirement 80 Ag/L, increase criterion to protect human health. monitoring to monthly Monitoring wells indicate increased once DM exceeded presence; existing treatment will not remove. Page 8 of 10 Electronic Reporting No requirement Add Electronic Reporting Special In accordance with EPA Electronic Condition Reporting Rule 2015. MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max 14. Public Notice Schedule Permit to Public Notice: January 9, 2018 Per 15A NCAC 2H .0109 & .0 111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 15. Fact Sheet Addendum (if applicable) Were there any changes made since the Draft Permit was public noticed (Yes/No): YES. Comments were received from Mr. Stuart Kerkhoff, Radiator Specialty Company, on March 19, 2018, requesting the following changes to the permit: • Removal of the recording flowmeter requirement from the draft permit, as the Supplement to the Permit Cover Sheet lists an effluent meter with recorder, which is inconsistent with a totalizing flow meter in Footnote 2; o Requested change was made (see below). • Removal of TS S monitoring requirements from the draft permit, citing low concentrations and cost of testing. o Requested change was not made, but an alternative was (see below). • Removal of pH monitoring requirements from the draft permit, citing consistent historical data and cost of testing. o Requested change was not made, but an alternative was (see below). • Removal of 1,4 -Dioxane limitation, monthly monitoring in the event of exceedance, and reopener clause from the permit; instead proposing to maintain quarterly monitoring. Mr. Kerkhoff stated that imposing 1,4 -Dioxane limits are inappropriate as there is no established federal maximum contaminant level, state water quality standard and state evaluation of 1,4 -dioxane concentrations in waterbodies is underway. o Requested change was not made, because the 80 µg/l, limit is an established NC calculated surface water criterion to protect human health for Class C waters based on fish consumption. If Yes, list changes and their basis below: The words "with recorder" were removed from "effluent meter" on the facility component list on the Supplement to the Permit Cover Sheet after verifying that the effluent meter does not have a chart or other recording device, but readings are taken manually. Manual readings are considered satisfactory by the regional inspector as long as flow data are consistent without major variations indicating operational or monitoring issues. To date, flows have been satisfactorily consistent. TSS monitoring frequency has been reduced from monthly to quarterly in light of effluent data showing consistent compliance with limits, yielding 7% detection over a span of over eight (8) Page 9 of 10 years (from February 2010 — February 2018). TSS concentrations over the past five years mostly < 2.5 mg/L with the highest detection at 6.7 mg/L. pH monitoring frequency has been adjusted from monthly to quarterly in light of effluent data provided by the Permittee that show consistent compliance with the water quality standards, ranging 7.3-8.3 (quasi -annually, from May 2008 — November 2017). However, the submitted data were collected at frequencies too low to show seasonal or other variation (if any). pH will remain in the permit as it is a parameter of concern that is put in groundwater remediation NPDES permits. 16. Fact Sheet Attachments (if applicable): • DMR data trend charts • WET Test Summary, page 90 • 2014 NC 303(d) List, page 142 • RPA Spreadsheet Summary • Public Comment letter from Permitttee Date: May 23, 2018 Permit Writer:" Page 10 of 10 - Berry, Ron From: Watson, Edward M Sent: Friday, February 09, 2018 12:06 PM To: Berry, Ron Cc: Pitner, Andrew Subject: RE: Your copy draft permit and fact sheet for Radiator Specialty Company NC0088838 Hello Ron, MRO has reviewed the DRAFT PERMIT and has no additional comment or concerns. MRO is in agreement with the draft permit. Regards, Ed From: Berry, Ron Sent: Tuesday, February 06, 2018 12:19 PM To: Watson, Edward M <edward.watson@ncdenr.gov>; Basinger, Corey <corey.basinger@ncdenr.gov> Subject: Your copy draft permit and fact sheet for Radiator Specialty Company NC0088838 See attached, comment as needed. Ron Berry Engineer Division of Water Resources/Complex Permitting North Carolina Department of Environmental Quality 919 807 6396 office 512 N. Salisbury Street 1617 Mail Service Center Raleigh, NC 27699-1617 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. PNIELA NOTq�� �y =oAGBCIG ' 2 ' Public Notice AFFP North Carolina Public Notice North Carolina Environmental Management Corir mission/NPCES Unit Affidavit of Publication 1817 Mail Service center Raleigh, NC 27699-1617 Notice of Intent to Issue a NPDES Wastewater Permit STATE OF NORTH SS CAROLINA } The North Carolina Environ - COUNTY OF UNION) mental Management Commis- sion proposes to issue a NP - Dale Morefield, being duly sworn, says: DES wastewater discharge That he is Publisher of the The Enquirer Journal, a daily permit to the person(s)-listed newspaper of general circulation, printed and published in below,. Written comments re - Monroe, Union County, North Carolina; that the garding the proposed permit publication, a copy of which is attached hereto, was will be accepted until 30 days published in the said newspaper on the following dates: .after the publish date of this February 09, 2018 notice. The Director of the NC Division of Water Resources DWR may hold a public hear- ing should there be a signific- ign f c -ant antdegree of public interest. please mall comments and/or That said newspaper was regularly issued and circulated information requests to DWR on those dates. SIGNED: at the above address. Inter- r ested persons may visit the �- DWR at 512 N. Salisbury Publisher Street; Raleigh, NC to review Subscribed to and sworn to me this 9th day of February information on file. Additional 2018. information on NP )E per- mits and this notice may be found on Our website; Pamela D. Crump, Notary, Union CoAy, North Carolina i n w r -r r w r- r s r mii W r- My commission expires: July 10, 2018 tranQht n eS-WAS WW!EV� ~iub- i or by calling (91 9) 807-6397. The Radiator Spe- cialty Company requested re- 30146484 30800478 newal of permit l CO088838 Wren Thedford for Radiator Specialty Com— Division Of Water Resources pony in Union County; this fa - 1617 Mail Service Center cility discharge is treated Raleigh, NC 27699 groundwater to unnamed tribu- tary to South Pork Crocked Creek,River Basin. y� //Yadki_n i eba 9,, f201 PNIELA NOTq�� �y =oAGBCIG ' 2 ' serp RSC Chemical Solutions a division of Radiator Specialty Company March 14, 2018 Mr. Ron Berry Environmental Engineer North Carolina Department of Environmental Quality Division of Water Resources RECEIVED/DENR/DWR NPDES Permitting Branch MAR 1 1617 Mail Service Center 9 2018 Raleigh, North Carolina 27699-1617 Water Resources Permitting Section Re: Comments to Draft NPDES Permit Permit No. NCO088838 Class I Radiator Specialty Company 600 Radiator Road, Indian Trail, Union County, North Carolina Dear Mr. Berry: Radiator Specialty Company (RSC) respectfully submits for your review this response to the February 7, 2018 draft NPDES Permit for the groundwater recovery and treatment system at the Indian Trail, North Carolina facility that RSC received on February 14, 2018. As you know, this remediation system has been in operation since 1994. Initially, the effluent was discharged to the Union County Publicly Owned Treatment Works (POTW). In 2009, RSC received a National Pollutant Discharge Elimination System (NPDES) permit to discharge the effluent to an unnamed tributary to the South Fork of Crooked Creek. During twenty-four (24) years of operation, the groundwater recovery and treatment system at RSC has accumulated a substantial volume of analytical data that indicates the effluent incorporated in this permit is very consistent. Part IA. (1) Effluent Limitations and Monitoring Requirements Page 3 of the draft permit states that flow shall be measured with a totalizing flowmeter. The Supplement to Permit Cover Sheet calls it an "effluent meter with recorder". RSC respectfully requests the requirement for a recording flow meter be removed from the draft permit. The draft Permit includes daily maximum limitations and monthly testing requirements for total suspended solids (TSS). Based on historic data (See Table 1), TSS has been detected a total of six (6) times over a period of eight (8) years 14 600 Radiator Road — Indian Trail, NC 28079-5225 — Telephone: 800-438-4532 — Fax: 704-684-1975 — www.rscbronds.com Mr. Ron Berry March 14, 2018 Page 2 at concentrations slightly above the method detection limit. These detected concentrations ranged from 3 to 21 milligrams per liter (mg/L) and are well below the Proposed Permit Limit of 45 mg/L. TSS analysis prices range from $15 to $20 per sample. Based on these costs, elimination of the parameter from the monthly sampling requirement would save RSC between $180 and $240 per year, or up to $1,200 during the life of the Permit. Based on the consistent nature of the effluent, the lack of TSS concentrations in the eight (8) years of historic effluent sampling data, and the unnecessary cost associated with these tests, RSC respectfully requests this Monitoring Requirement be removed from the draft Permit. • The draft Permit requires monthly pH testing. While pH is not a Monitoring Requirement in the expired Permit, RSC has periodically collected pH data in conjunction with the required parameters (See Table 2). This data has been collected in general accordance with North Carolina Department of Environmental Quality (DEQ) protocol, but not by a North Carolina Certified Laboratory. As indicated in Table 2, the pH samples historically collected from the effluent have consistently been between 6.0 and 9.0 Standard Units (SU). To comply with the pH sampling requirement of the draft Permit, RSC will be obligated to retain a North Carolina Certified Field Laboratory to collect the monthly effluent samples. Use of a Certified Laboratory will increase the sampling cost by up to $150 per month, or $9,000 during the life of the Permit. Based on the consistent nature and the consistent pH values documented in historic data, and the additional cost RSC will incur to implement pH testing of the monthly effluent samples, RSC respectfully requests this Monitoring Requirement be removed from the draft Permit. • The draft Permit requires quarterly testing for 1,4 -dioxane with a proposed effluent limit of 80 micrograms per liter (pg/L). This compound was not a monitoring requirement in the expired Permit. RSC understands that no federal maximum contaminant level (MCL) for drinking water has been established for 1,4 -dioxane. While North Carolina has established a Groundwater Quality Standard for 1,4 -dioxane of 3.0 pg/L. no other state or federal standards have been established. Further, RSC understands that the DEQ has no Surface Water Quality Standard for 1,4 -dioxane under North Carolina Administrative Code, Title 15A, Subchapter 2B (15A NCAC 213). North Carolina has proposed 80 gg/L as a guideline protective value for surface 14 aters for 1,4 - dioxane. It is RSC's opinion that the DEQ does not have the authority to establish an Effluent Limitation based on a regulatory guideline and not a written regulation. Mr. Ron Berry March 14, 2018 Page 3 On March 28, 2017, the DEQ, Division of Water Resources, Water Sciences Section published a paper entitled 1,4 -Dioxane and Bromide Monitoring Plan (See Attached). In this study, the DEQ outlines a sampling and analysis program underway to evaluate 1,4 -dioxane concentrations in specific surface waters of North Carolina. This study is not anticipated to be completed until June 2019. Based on the lack of a federal MCL, the lack of an established 15A NCAC 2B standard and the fact that the DEQ is in the process of conducting a study evaluating 1,4 -dioxane concentrations in surface water bodies of North Carolina, it is RSC's opinion that including an effluent limit for 1,4 -Dioxane in the draft permit is not appropriate at this time. RSC proposes to continue to sample quarterly for 1,4 -dioxane and report these results to the DEQ. RSC respectfully requests the Permit Limit for 1,4 -dioxane, the monthly Monitoring Requirement in the event of an exceedance, and the Reopener Clause be removed from the draft Permit. We appreciate your consideration of these concerns. Please call or email if you have any questions or require any additional information. Sincerely, Radiator Specialty Company Stuart Kerkhoff, CHMM Environmental Heath and Safety Manager Attachments cc: Richard L. 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Q Attachment 1 NC Division of Water Resources 1,4 -Dioxane and Bromide Monito ing Plan In Support of NFWF-Funded Project ID #8020.16.054182 ire, 'ciences section NC DWR 1.4 -Dioxane and Bromide Monitorin,. Plan 2017-2019 1,4 -dioxane is an organic compound that readily dissolves in water at all concentrations, is persistent in the environment, and is difficult to remove through standard water and wastewater treatment processes. It is used as an industrial solvent and formed as a byproduct of some industrial processes. The compound has been characterized as "likely to be carcinogenic to humans" and identified as a potentia) contaminant of concern in public drinking water by the United States Environmental Protection Agency (USEPA). 1,4 -dioxane was recently monitored in selected finished drinking water supplies nationwide under the USEPA's Third Unregulated Contaminant Monitoring Rule (UCMR3). The USEPA uses UCMR studies to determine the extent of contamination and provide data for the consideration of new drinking water regulations. UCMR3 data indicated that finished drinking water from at least 23 large (serving > 10,000 people) utilities in North Carolina contained levels of 1,4 -dioxane in excess of the NC calculated surface water criterion (0.35 pg/L) to protect human health. Nearly all of these utilities used surface water as their primary water source, and they were located in the Cape Fear, Neuse, and Yadkin River basins. Due to wide -spread presence of this constituent throughout the United States as identified through the UCMR3 study, it is possible that the USEPA will develop health -based standards for 1,4 -dioxane in the future. A North Carolina Division of Water Resources (NC DWR) study was conducted from 2014-2016 to monitor ambient concentrations of 1,4 -dioxane in the Cape Fear River and its tributaries, and to identify potential sources of the contaminant. This study garnered media attention and was the focus of several news articles. In order to fully understand and identify the sources of 1,4 -dioxane in NC, this study will be continued in the Cape Fear River basin and expanded into the other two river basins (Yadkin and Neuse) with UCMR3 1,4 -dioxane results >_ 0.35 pg/L in public drinking water. Bromide Bromide in surface water has been associated with industrial and agricultural chemicals and coal ash facilities. It is a health concern due to its contribution to the formation of trihalomethanes (THMs). THMs are disinfection byproducts (DSPs) resulting from chlorine disinfection treatment of drinking water. Several THMs are characterized by the USEPA as "likely to be carcinogenic to humans" or as having "suggestive evidence of carcinogenic potential" and are regulated under the federal Safe Drinking Water Act with Maximum Contaminant Levels (MCLS). Based on quarterly DBP monitoring, the NC DWR Public Water Supply Section (PWS) has determined that approximately 20% (27 of 138) of NC drinking water systems that utilize surface water sources have elevated DBPs containing significant amounts of brominated trihalomethane compounds. Results from these facilities included at least one sample point at which >_ 30% of DSPs were made up of brominated compounds and the amount of DBPs was >_ 50% of the MCL. Bromide samples have been collected by the NC DWR in conjunction with 1,4 -dioxane sampling in the Cape Fear River basin. Expansion and continuation of this study will involve an additional 18 months of ambient and source identification monitoring throughout the state. Initially, this will be targeted Page 1 of 6 NC DWR 1.4 -Dioxane and Bromide Monitorin Plan 2017-2019 upstream of the NC public drinking water treatment facilities identified by PWS monitoring as experiencing elevated levels of brominated DBPs. Some of these facilities utilize multiple surface water sources and/or supply water to multiple municipalities. Objective The NC DWR Public Water Supply Section protects nearly 6000 public water systems within NC, serving the homes of approximately three-fourths of the state's population, as well as workplaces, schools, restaurants, and other public facilities. The NC DWR Water Sciences Section (WSS) will monitor bromide and 1,4 -dioxane in selected surface waters used as public drinking water supply sources in order to provide data to assist the NC Department of Environmental Quality with proactively addressing areas of contamination. The long-term conservation outcome supported by these projects will be increased protection of surface water as a water supply resource and increased safety of North Carolina's drinking water. Samples will be collected in the same stream networks as public drinking water with elevated THM and/or 1,4 -dioxane concentrations. Monitoring sites will be established at current ambient stations when possible, and additional stations will be established as needed to track sources. All samples will be collected as near -surface (i.e. 0.1 -meter depth) grab samples, and will be analyzed for bromide and field parameters (pH, specific conductance, water temperature, and dissolved oxygen). Samples from stations in close proximity to power plants and/or public water treatment plants with elevated UCMR3 results will also be analyzed for 1,4 -dioxane. Sampling will occur monthly for 18 months during 2017-2018 at the stream stations indicated in the map and table below, in accordance with methods described in North Carolina's Ambient Monitoring System (AMS) Quality Assurance Project Plan (QAPP) (NCDENR, 2014). Bromide sampling will also occur once during the project period at the two lake stations in the table, in accordance with the Ambient Lakes Monitoring Program (ALMP) QAPP (NCDENR, 2012). All samples will adhere to the NC DWR Laboratories' Sample Submittal Guidelines (DWR, 2016) and further instructions provided by the NC DWR Central Laboratory for bromide and 1,4 -dioxane sample collection, processing, and preservation. Quality assurance (QA) samples, including duplicates, matrix spikes, and matrix spike duplicates will be collected per the QAPPs and laboratory guidance. Page 2 of 6 NC DWR IA -Dioxane and Bromide Monitorini Plan 2017-2019 c jb= B0210000 Haw River at SR 1551 Hub Mill Rd. - Cape Fear Central Both 2,3 60750000 South Buffalo Creek at SR 2821 at McLeansville Cape Fear Central Both 2,3 80840000 Reedy Fork at NC -87 at Ossipee Cape Fear Central Both 2,3 Bl Haw River at SR 1712 (Brooks Bridge Rd) Cape Fear Central Both 2,3 82100000 Haw River at SR 1713 near Bynum Cape Fear Central Bath 1, 2, 3 B4 Haw River at Troxler Mill Rd near Reidsville Cape Fear Central Both 2,3 B6 Reedy Fork at NC -61 near Ossipee Cape Fear Central Both 2,3 DAQBELEW S08 Belews Lake at NC 65 Roanoke Central Bromide 1,3 N0150000 Dan River at NC 704 near Francisco Roanoke Central Bromide 1,3 N1400000 Mayo River at SR 1358 near Price Roanoke Central Bromide 1,3 N2300000 Dan River at SR 2150 near Wentworth Roanoke Central Bromide 1,3 N2430000 Smith River at SR 1714 near Eden Roanoke Central Bromide 1,3 N3000000 Dan River at SR 17161 near Mayfield Roanoke Central Bromide 1 N3500OW Dan River at NC 57 at VA line at Milton Roanoke Central Bromide 1 N4250000 Hyco River below dam near McGhees Mill Roanoke Central Bromide 1 N4406000 Marlowe Creek at SR 1322 near Woodsdale Roanoke Central Bromide 1 N4590000 Mayo Creek at SR 1501 near Bethel Hill Roanoke Central Bromide 1 NCSU24 Hasketts Creek at WOW Road near Asheboro Cape Fear Central Both 1, 2, 3 Q2810000 Yadkin River at US 64 at Yadkin College Yadkin Central Both 1 Q4660000 Yadkin River at NC 150 near Spencer Yadkin Central Both 1 Q6120000 Yadkin River at SR 1002 at High Rock Yadkin Central Both 1,2 Q6810000 Uwharrie River at NC 109 near Uwharrie Yadkin Central Both 2 Q7150000 Pee Dee River at NC 731 near Shankle Yadkin Central Both 1,2 Q7330000 Rocky River at Sit 2420 near Davidson Yadkin Central Both 2 Q8090000 Irish Buffalo Creek at SR 1132 near Faggarts Yadkin Central Both 2 Q8220000 Rocky River at SR 1006 near Concord Yadkin Central Both 2 Q9400000 Pee Dee River at US 74 near Rockingham Yadkin Central Both 2 Q9916000 Pee Dee River at NC 109 near Mangum Yadkin Central Both 2 Q9940000 Marks Creek at SR 1812 near Hamlet Yadkin Central Both 2 B6370000 Cape Fear River at US -401 at Lillington Cape Fear Eastern Both 1, 2, 3 B7480000 Cape Fear River at Hoffer WTP intake at Fayetteville Cape Fear Eastern Both 2,3 B8 Cape Fear River at Harnett Cty Public Utilities intake Cape Fear Eastern Both 1, 2, 3 B8350000 Cape Fear River at Lock 1 near Kelly Cape Fear Eastern Both 2,3 /1890000 Neuse River at SR 2000 Neuse Eastern Both 2,3 /4370000 Neuse River at US 70 Business at Smithfield Neuse Eastern Both 1, 2, 3 /4510000 Neuse River at NC 42 near Clayton Neuse Eastern Both 2,3 /5970000 Neuse River at SR 1915 near Goldsboro Neuse Eastern Both 1, 2, 3 16150000 Neuse River at NC 11 at Kinston Neuse Eastern Both 1, 2, 3 16740000 Contentnea Creek at NC 581 near Lucama Neuse Eastern Bromide 3 N5000000 Nutbush Creek at SR 1317 near Henderson Roanoke Eastern Bromide 3 N7300000 Roanoke River at NC 48 at Roanoke Rapids Roanoke Eastern Bromide 3 C4380000 S. Fork Catawba River at NC 10 near Startown Catawba Western Bromide 3 C7000000 S. Fork Catawba River at SR 2524 near S. Belmont Catawba Western Bromide 1 DAQNORM AN08 Lake Norman at Reeds Creek Catawba Western Bromide 1,3 Note: Issue Types: 1- Power Plant; 2 - WTP with 1,4 -Dioxane; 3 - WTP with DBPs Page 3 of 6 NC DWR 1.4 -Dioxane and Bromide Monitoring Plan_ _2017-2019 NC Public Water Supply Source Monitoring * Proposed Monitoring Stations Q Districts e UCMR3 1,4 -Dioxane 20.35 ug/L Major Waters • Surface Water Sources w/ High DBPs River Basins ! Power Plants Maes 0 20 40 so 120 During past 1,4 -dioxane monitoring, a contract laboratory was utilized for analysis because the NC DWR Central Laboratory did not have the analytical testing capacity to measure this compound. Instrumentation improvements will enable the NC DWR to develop enhanced long-term data analysis and tracking capabilities for 1,4 -dioxane, as well as other volatile contaminants that may be identified in the future. Through the acquisition of a gas chromatography mass spectrometer (GC -MS) with an automated purge -and -trap sample preparation system, the project will build the capacity of the WSS Organic Chemistry Branch to measure concentrations of 1,4 -dioxane and other organic compounds in NC's waters. Additional funds will be utilized for the supplies and materials necessary to collect and analyze the samples described above. Laboratory instrumentation will be acquired, installed, and calibrated by lune 2017. A sampling and analysis schedule for the 2017 sampling season will be established by lune 2017, and sampling will begin by July 2017. Data will be compiled, subjected to a quality assurance process, and uploaded to the NC DWR water quality data management system on a quarterly basis during the period of sample collection and analysis. All project -related sampling and analysis activities are expected to be completed within the project timeline below. The project schedule will be monitored by the project manager, and regular reports will be made to NFWF to confirm project progress. Page 4 of 6 NC DWR I.4-Dio)(anp and RrnmirlP�onitarin Plan 2017-2019 (NCDEQ) N.C. Department of Environmental Quality, Division of Water Resources, Water Sciences Section. 2016. Sample Submittal Guidelines — DWR Water Sciences Section Chemistry Laboratories. Available as a link from http:11deco.nc.Rov,`abouticlivision / ate,r_resourceslwater-res_ources- data water -sciences -home- a e rnicrobiol❑ -inorganics-branch same le -submission. Page 6 of 6 Berry, Ron From: Sent: To: Cc: Subject: This is the full explanation... Brower, Connie Thursday, October 15, 2015 11:58 AM Berry, Ron Grzyb, Julie FW: 1,4 Dioxane - reference to rules Connie U. Brower Water Quality Standards Coordinator Classifications and Standards/ Rules Review Branch Water Planning Section, Division of Water Resources Department of Environmental Quality 919 807 6416 office 919 707 9000 main office Connie. Brower@ncdenr.gov Physical Address: 512 North Salisbury St.,Raleigh, NC, 27604 Mailing Address: 1611 Mail Service Center, Raleigh, NC, 27699-1611 Nothing Cornro, Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Brower, Connie Sent: Wednesday, September 23, 2015 11:20 AM To: Risgaard, Jon <jon.risgaard@ncdenr.gov> Subject: FW: 1,4 Dioxane - reference to rules From: Brower, Connie Sent: Wednesday, September 02, 2015 12:34 PM To: Risgaard, Jon; Ruhlman, Carrie; Gore, Deborah; Hill, Tammy; Godreau, Jessica Cc: Grzyb, Julie; Sadosky, Rebecca; Kroeger, Steve; Manning, Jeff; Ventaloro, Christopher Subject: FW: 1,4 Dioxane - reference to rules Jon - 1 This was sent to'TR— nothing has changed except that I have a number of states noting that they, too, are seeing the chemical in either finished or surface waters. In accordance with 15A NCAC 02B .0208 (a) (2) — "....the concentration of toxic substances shall not exceed the level necessary to protect human health through exposure routes of fish consumption, water consumption, or other route identified as appropriate for the water body...." The concentrations are calculated to protect from the carcinogenic effects of 1,4 Dioxane. I copied the planet — because the question arises frequently! Connie From: Brower, Connie Sent: Tuesday, January 27, 2015 10:40 AM To: Reeder, Tom; Manning, Jeff Cc: Ruhlman, Carrie Subject: RE: 1,4 Dioxane Good morning, Tom, In accordance with 15A NCAC 0213, the calculated protective values for 1,4 Dioxane (CAS # 123-91-1) are 0.35 ug/L in Water Supply classified waters, and 80 ug/L in Class C waters. 1,4 -Dioxane is a carcinogen. As we do not routinely monitor for 1, 4 Dioxane , and as Jeff noted, no waters are impaired. As WSS reported to you, our current data is limited to three months of samples. While disconcerting, I completely agree with them that it is very early to make conclusions of source or extent of the issue. You are correct that the federal government has not established an MCL for 1,4 Dioxane. We do, however, have an established groundwater standard of 3 ug/L. This number is in need of revisions, as the information on which it is based is outdated. If modified, it would be 0.35 ug/L—the same as the surface water number. Let us know if you need additional information. Connie From: Reeder, Tom Sent: Tuesday, January 27, 2015 9:57 AM To: Brower, Connie; Manning, Jeff Subject: 1,4 Dioxane Do we have an surface water quality standard for 1,4 Dioxane? If so, what is it? Are any water listed as being impaired for 1,4 Dioxane? Thanks • Berry, Ron From: Moore, Cindy Sent: Tuesday, October 13, 2015 3:24 PM To: Berry, Ron Cc: Meadows, Susan; Giorgino, John; Hollenkamp, Carol Subject: RE: Question on toxicity test for NCO088838 Per our conversation, if this is a batch discharge, then a composite sample would be hard to achieve. I would suggest a grab sample and continue use of the chronic test. From: Berry, Ron Sent: Tuesday, October 13, 2015 3:12 PM To: Moore, Cindy <cindy.a.moore@ncdenr.gov> Subject: Question on toxicity test for NCO088838 Cindy, I did not see a response to this original email. I need a decision so I can get this permit out to public notice. Thanks, Ron Cindy, Radiator Specialty Company NPDES permit NCO088838 is being renewed and is for a ground water remediation operation that began discharging under a NPDES permit in 2010. The permit requires quarterly chronic toxicity testing using a grab sample at 90% effluent test concentration. The discharge varies from months with no discharge to months with intermittent discharge to months with continuous discharge. What is the recommended test sample type and/or appropriate toxicity test application? Should we concert to acute? Thanks, Ron Ron Berry, Engineer Division of Water Resources/NCDENR Phone: (919) 807 - 6396 Email: ron.berry@ncdenr.gov Location Address - Archdale Building, Office 925K 512 N. Salibury St. Raleigh, NC 27699 Mailing Address - Archdale Building, NCDENR/DWR 1617 Mail Service Center Raleigh, NC 27669-1617 E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties. s Chernikov, Sergei From: Ulishney, Adam Sent: Monday, March 12, 2012 11:03 AM To: Chernikov, Sergei Subject: Radiator Specialty Site NCO088838 Dear Mr. Chernikov, My name is Adam Ulishney with the NCDENR Hazardous Waste Section. One of my facilities that I currently manage is Radiator Specialty located at 600 Radiator Road in Indian Trail, Union County, North Carolina. They currently maintain a RCRA Post -Closure Permit. The portal website had listed you as the contact person for the site's NPDES permit. As part of corrective action activities at the site the facility currently operates a groundwater pump and treat system for which they maintain an NPDES permit (N00088838) for discharge of treated water to an unnamed tributary to Unnamed Tributary to South Fork Crooked Creek in the Yadkin River Basin. I just wanted to make you aware that one of the constituents within groundwater at the site is 1,4 -Dioxane. During the most recent sampling event (October 2011), 1,4 -Dioxane concentrations in groundwater ranged from <150 ug/L to 1,100 ug/I. Based on the physical and chemical properties of 1,4 -Dioxane, groundwater treatment systems similar to the one operating at the RSC facility have generally proven to be ineffective in treating this constituent. I have been unsuccessful in getting Radiator Specialty to sample the effluent for the presence of 1,4 -Dioxane to ensure that via some means this constituent is being treated (possibly by dilution) prior to discharge as it is not required by their NPDES permit. They have however collected quarterly influent samples in 2010 and results for 1,4 -Dioxane ranged from <150 ug/L to 320 ug/I. Historically the NC and EPA criteria table had the limit for 1,4 -Dioxane at 110 ug/I for a Class C water, however it appears that the table is currently being updated. If you can provide me any feedback it would be appreciated. Again I just wanted to make your aware of this information, should you feel that it is necessary to incorporate the sampling of 1,4 -Dioxane in any future NPDES permits for the facility. In any case let me know what you decide for my future reference in reviewing their annual reports. Should you need additional information or have any questions, comments, or concerns please feel free to contact me at 919-707-8210. Adam Ulishney 1lvdrogeologist North Carolina Hazardous Waste Section 'hone:' (919) 707-8210 p �) o o�� Q, Eraai:: adam.ulishneN'a ncdenr.�ov NOTICE: Effective October 24, 2011 our new address will be: 0 5 1 217 West Jones St. �-� X Raleigh, NC 27603 0, 3"�c,y �L and effective October 24, 2011 my new phone number will be: 919-707-8210 '`fit? Email correspondence to and from this address is subject to the North Carolina Public Records Low and may be disclosed to third parties unless the content is exempt by statute or other regulation. Yadkin -Pee Dee River Basin 2014 AU Number: AU Name: AU Length Area: AU Units: Classification: AU Description: 13-17c3 Rocky River 34.9 FW Miles C From Anderson Creek to Lanes Creek IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) 5e EC Copper (7 pg/I, AL, FW) 2008 2008 5e EC Zinc (50 pg/I, AL, FW) 2008 2008 13-17d Rocky River 11.5 FW Miles C From the Lanes Creek to the Pee Dee River IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr: 5e EC Copper (7 pg/I, AL, FW) 2008 2008 5 EC Turbidity (50 NTU, AL, FW miles) 2012 2008 13-17b1 Rocky River 9.2 FW Miles C From Clarke Creek to Mallard Creek IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr: 5 EC Benthos Fair (Nar, AL, FW) 2003 2008 13-17-20-2a South Fork Crooked Creek 5.6 FW Miles C From source to SR 1515 IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr: 5 EC Fish Community Fair (Nar, AL, FW) 1995 1998 5 EC Benthos Poor (Nar, AL, FW) 1995 1998 13-17-20-2b South Fork Crooked Creek 8.8 FW Miles C From SR 1515 to Crooked Creek 'IRCategory: ACS: Parameter Of Interest: 5 EC Benthos Fair (Nar, AL, FW) Collection Year: 303(d) yr: 1995 1998 13-17-36-9-(1) Stewarts Creek 8.3 FW Miles WS -III From source to a point 0.4 mile downstream of mouth of Stumplick Branch IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr. - 5 r.5 EC Benthos Fair (Nar, AL, FW) 2006 2008 13-17-36-9-(4. Stewarts Creek [Lake Twitty (Lake Stewart)] 131.1 FW Acres WS-III;CA From a point 0.4 mile downstream of mouth of Stumplick Branch to Union County SR 1681 (City of Monroe water supply intake) RCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr: 5 EC Chlorophyll a (40 pg/I, AL, NC) 2012 2008 2014 NC 303(d) List -Category 5 Final December 19, 2014 Page 142 of 149 � � u c 0 U 0 ■ � E � IL C4 2 � � ■ ■ £ 2 / § O # 2 2@ g g 2 2 ! 2 CL£--£-£ 2m0 mt £ 2! M 2 2 2 , I ƒ 0 �2 / - § § C5d a �k § \ Q § % r.. 8 o c o ! E z ■ c u% 3 a u, w # - : , a 2 ) _ 3 a $ C, L$ z 0 2 M@ P.� m k k k D -i � � -i -i u � � � � � � k k k k k\ k k k k k k a LU 2 0 < ƒ ƒ ƒ ƒ 0 R Q Z o 8 E g 0 0 0 o - c a% g m m M« a G- w 00 z o z z Q 0 0 Q 0 0 ° k ) Co $ ' m \ k k\ 0\/ B§ k k $ t § o t 6 ) B § § 7 2 \ C _ # 2 2@ g g 2 2 ! 2 CL£--£-£ 2m0 mt £ 2! M 2 2 2 , I ƒ 0 �2 / - § § C5d a �k § \ Q § % r.. 8 o c o ! 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O Y U O V C N r EL 0 N N MI N v� N CL U w w z w rn rn 0 N 05a 0 V !L U) co L M O W �+ w ao Q Z cq 00 N 00 U U U Z m 6 c C c O % 0 t O � � a m �o �o fV + cl)I04 N O a U w w z w c� W rn N d a C 13 �U E E.E m O _ O O 10CL 3 IU., IN 7 IN''O I X I X crn 1 ca I� E @ 0 19 3 c IE.a U E I� U Ise IID 0 I� 0 0 M I� o IQ a o a a a 1�5 I� Ido I z0 a° I z0 a0 I a E CO) I I�v3 I I 3 I�v� Iry z l az I 3z 1 3 i s i0 i 0 a Q a I R Iv o N z z z' } r N 00 Y J yr O fV Q a v ra z Ja � y w a vi 00 .E Z R z 'a W o a a a a O~ CL w� J a a� z� O; W w x x 0 V !L U) co L M O W �+ w ao Q Z cq 00 N 00 U U U Z m 6 c C c O % 0 t O � � a m �o �o fV + cl)I04 N O a U w w z w c� W rn N d a Date Data 1 4/14/2014 < 2 7/15/2014 < 3 10/14/2014 < 4 10/13/2015 < 5 1/12/2016 < 6 4/12/2016 < 7 7/19/2016 8 10/11/2016 < 9 1/17/2017 < 10 4/4/2017 < 11 7/25/2017 < 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS Chloroethane vb1Ugh-mT-n'COPi 1,1 Dichloroethane Mommum dais pdnss zu BDL=112DL Results i 2 1 Std Dev. 1.47' 2 1 Mean 0.8364 0.5 0.25 C.V. 1.7672 0.5 0.25 n 11 0.5 0.25 0.5 0.25 0.5 0.25 Mult Factor = 3.0400 5.2 5.2 Max. Value 5.2 0.5 0.25 Max. Pred Cw 15.8 0.5 0.25 0.25 0.5 0.25 0.5 0.5 0.25 Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 10 10/11/2016 < 11 1/17/2017 < 12 4/4/2017 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 then -Cop-data 0,04"t z .S4 0.5615 1.4802 13 2.4300 3.3 ug/L 8.0 ug/L 9595 GENERIC RPA2014_32, data - 1 - 5/21 /2018 BDL=1/2DL Results 1 0.5 Std Dev. 1 0.5 Mean 1 0.5 C.V. 1 0.5 n 0.5 0.25 0.5 0.25 Mult Factor = 0.5 0.25 Max. Value 0.5 0.25 Max. Pred Cw 3.3 3.3 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 then -Cop-data 0,04"t z .S4 0.5615 1.4802 13 2.4300 3.3 ug/L 8.0 ug/L 9595 GENERIC RPA2014_32, data - 1 - 5/21 /2018 REASONABLE POTENTIAL ANALYSIS 1 1,1 Dichloroethene Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 10 10/11/2016 < 11 1/17/2017 < 12 4/4/2017 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 valour, snore -COPY" YstlmSrtrt data pelen yy 0.5000 1.2247 13 2.2000 2.5 Ng/L 5.5 Ng/L 1,2 Dichloroethene (total) Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 1/17/2017 < 10 4/4/2017 < 11 7/25/2017 < 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 BDL=1/2DL Results 1 0.5 Std Dev. 1 0.5 Mean 1 0.5 C.V. 1 0.5 n 0.5 0.25 0.5 0.25 Mult Factor = 0.5 0.25 Max. Value 0.5 0.25 Max. Pred Cw 2.5 2.5 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 valour, snore -COPY" YstlmSrtrt data pelen yy 0.5000 1.2247 13 2.2000 2.5 Ng/L 5.5 Ng/L 1,2 Dichloroethene (total) Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 1/17/2017 < 10 4/4/2017 < 11 7/25/2017 < 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Value than "CUP 7, mvitmum "to "nil x A,S 1.81320 1.6136 1.1663 11 2.3700 5.0 vg/L 11.9 Ng/L 9595 GENERIC RPA2014_32, data -2- 5121/2018 BDL=1/2DL Results 10 5 Std Dev. 1 0.5 Mean 10 5 C.V. 2 1 n 0.5 0.25 0.5 0.25 Mult Factor = 0.5 0.25 Max. Value 0.5 0.25 Max. Pred Cw 0.5 0.25 5 2.5 5 2.5 Value than "CUP 7, mvitmum "to "nil x A,S 1.81320 1.6136 1.1663 11 2.3700 5.0 vg/L 11.9 Ng/L 9595 GENERIC RPA2014_32, data -2- 5121/2018 REASONABLE POTENTIAL ANALYSIS I Tetrachloroethene I Date Data 1 8/6/2013 2 9/30/2013 3 10/1512013 4 11/14/2013 5 12/4/2013 6 4/14/2014 7 5/15/2014 8 6/16/2014 9 7/15/2014 < 10 8/21/2014 < 11 9/25/2014 < 12 10/14/2014 < 13 12/17/2014 < 14 9/8/2015 < 15 10/13/2015 < 16 11/2412015 < 17 12/15/2015 < 18 1112/2016 < 19 2/9/2016 < 20 3/8/2016 < 21 4/12/2016 < 22 5/18/2016 < 23 6/21/2016 < 24 7/19/2016 < 25 8111/2016 < 26 9/14/2016 < 27 10/11/2016 < 28 11/16/2016 < 29 12/14/2016 < 30 1/17/2017 < 31 2/16/2017 < 32 3/20/2017 < 33 4/4/2017 < 34 5/17/2017 < 35 6/19/2017 < 36 7/25/2017 < 37 8/23/2017 < 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 V61Ye1" than "COPY" Maximum dam Pon" r -m 0.91 �4� 1.5351 0.5991 37 1.1300 5.8 yg/L 6.6 Ng/L BDL=1/2DL Results 1.6 1.6 Std Dev. 2.6 2.6 Mean 2.2 2.2 C.V. 5.8 5.8 n 2.5 2.5 1.7 1.7 Mult Factor = 1.4 1.4 Max. Value 2.5 2.5 Max. Pred Cw 1 0.5 1 1 0.5 ; 5C 3 1.5 < 3 1.5 Mean 3 1.5 10/15/2013 3 1.5 0.5 3 1.5 4 3 1.5 1 3 1.5 38 3 1.5 < 3 1.5 3 1.5 4/4/2014 3 1.5 0.5 3 1.5 7 3 1.5 1 0.5 0.25 2.0 ug/L 3 1.5 < 3 1.5 Max. Pred Cw 3 1.5 7/15/2014 3 1.5 0.5 3 1.5 10 0.5 0.25 1 3 1.5 3 1.5 < 0.5 0.25 3 1.5 10/14/2014 3 1.5 2 0.5 0.25 13 3 1.5 0.5 V61Ye1" than "COPY" Maximum dam Pon" r -m 0.91 �4� 1.5351 0.5991 37 1.1300 5.8 yg/L 6.6 Ng/L 9595 GENERIC RPA2014_32, data - 3 - 5/21/2018 1,1,1 Trichloroethane Vuluva"1118"'L4PY" M�rrimum dart pekan . Sa Date Data BDL=112DL Results 1 8/6/2013 < 1 0.5 Std Dev. ; 5C 2 9/30/2013 < 1 0.5 Mean 1.3974 3 10/15/2013 < 1 0.5 C.V. 0.5488 4 11/14/2013 < 1 0.5 n 38 5 12/4/2013 < 1 0.5 6 4/4/2014 < 1 0.5 Mult Factor = 1.1100 7 5/15/2014 < 1 0.5 Max. Value 2.0 ug/L 8 6/16/2014 < 1 0.5 Max. Pred Cw 2.2 ug/L 9 7/15/2014 < 1 0.5 10 8/21/2014 < 1 0.5 11 9/25/2014 < 4 2 12 10/14/2014 < 4 2 13 11/18/2014 < 0.5 0.25 14 12/17/2014 < 4 2 15 9/8/2015 < 4 2 16 10/13/2015 < 4 2 17 11/24/2015 < 4 2 18 12/15/2015 < 4 2 19 1/12/2016 < 4 2 20 2/9/2016 < 4 2 21 3/8/2016 < 4 2 22 4/12/2016 < 4 2 23 5/18/2016 < 4 2 24 6121/2016 < 4 2 25 7/19/2016 1.1 1.1 26 8/11/2016 < 4 2 27 9/14/2016 < 4 2 28 10/11/2016 < 4 2 29 11/16/2016 < 4 2 30 12/14/2016 < 4 2 31 1/17/2017 < 0.5 0.25 32 2/16/2017 < 4 2 33 3/20/2017 < 4 2 34 4/4/2017 < 0.5 0.25 35 5/17/2017 < 4 2 36 6/19/2017 < 4 2 37 7/25/2017 < 0.5 0.25 38 8/23/2017 < 4 2 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 9595 GENERIC RPA2014_32, data - 3 - 5/21/2018 REASONABLE POTENTIAL ANALYSIS I Trichloroethene Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 9/8/2015 < 7 10/13/2015 < 8 1/12/2016 < 9 4/12/2016 < 10 7/19/2016 < 11 10/11/2016 < 12 1/17/2017 < 13 4/4/2017 < 14 7/25/2017 < 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 VaiU"- mwn -Cpvr' 41ax�data panel 0.4618 0.4464 1.0344 14 1.9400 2.0 pg/L 3.9 Ng/L Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 10 10/11/2016 < 11 1/17/2017 < 12 4/4/2017 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Benzene BDL=112DL Results 1 0.5 Std Dev. 1 0.5 Mean 1 0.5 C.V. 1 0.5 n 0.5 0.25 4 2 Mult Factor = 0.5 0.25 Max. Value 0.5 0.25 Max. Pred Cw 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 VaiU"- mwn -Cpvr' 41ax�data panel 0.4618 0.4464 1.0344 14 1.9400 2.0 pg/L 3.9 Ng/L Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 10 10/11/2016 < 11 1/17/2017 < 12 4/4/2017 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Benzene va[ti 4s' In en -C OF, Y" Maximum deli pdinei • 9E 0.ii',J 0.3677 0.4650 13 1.4400 0.8 pg/L 1.1 pg/L 9595 GENERIC RPA2014_32, data -4- 5/21 /2018 BDL=1/2DL Results 1 0.5 Std Dev. 1 0.5 Mean 1 0.5 C.V. 1 0.5 n 0.5 0.25 0.5 0.25 Mult Factor = 0.5 0.25 Max. Value 0.5 0.25 Max. Pred Cw 0.78 0.78 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 va[ti 4s' In en -C OF, Y" Maximum deli pdinei • 9E 0.ii',J 0.3677 0.4650 13 1.4400 0.8 pg/L 1.1 pg/L 9595 GENERIC RPA2014_32, data -4- 5/21 /2018 Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/1512014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 < 10 10/11/2016 < 11 1/17/2017 12 4/4/2017 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS Methyl Chloride 1 Vnlue%"them "COPY- Ma.xunum pas points _5a 0.8538 0.8372 13 1.82 3.1 pg/L 5.6 pg/L 1 1,2 Dichloroethane J Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 < 10 10/11/2016 < 11 1/17/2017 < 12 4/4/2017 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 BDL=112DL Results 2 1 Std Dev. 2 1 Mean 2 1 C.V. 2 1 n 1 0.5 1 0.5 Mult Factor = 1 0.5 Max. Value 1 0.5 Max. Pred Cw 1 0.5 1 0.5 3.1 3.1 1 0.5 1 0.5 Vnlue%"them "COPY- Ma.xunum pas points _5a 0.8538 0.8372 13 1.82 3.1 pg/L 5.6 pg/L 1 1,2 Dichloroethane J Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 < 10 10/11/2016 < 11 1/17/2017 < 12 4/4/2017 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Vniue -rn vn"COF: v'- Kazifnu Wti pa -MA �53 0.33 0.3674 13 1.3400 0.5 Ng/L 0.7 Ng/L 9595 GENERIC RPA2014_32, data - 5 - 5/21 /2018 BDL=1/2DL Results 1 0.5 Std Dev. 1 0.5 Mean 1 0.5 C.V. 1 0.5 n 0.5 0.25 0.5 0.25 Mult Factor = 0.5 0.25 Max. Value 0.5 0.25 Max. Pred Cw 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 0.5 0.25 Vniue -rn vn"COF: v'- Kazifnu Wti pa -MA �53 0.33 0.3674 13 1.3400 0.5 Ng/L 0.7 Ng/L 9595 GENERIC RPA2014_32, data - 5 - 5/21 /2018 Date Data 1 8/6/2013 < 2 10/15/2013 < 3 4/14/2014 < 4 7/15/2014 < 5 10/14/2014 < 6 10/13/2015 < 7 1/12/2016 < 8 4/12/2016 < 9 7/19/2016 10 10/11/2016 < 11 1/17/2017 < 12 4/4/1947 < 13 7/25/2017 < 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS Toluene vwwct -inen "CW,Y.. Maximum dale poorns s!4 0.126u 0.3462 0.3657 13 1.3400 0.5 Ng/L 0.7 Ng/L BDL=1/2DL Results 1 0.5 Std Dev. 1 0.5 Mean 1 0.5 C.V. 1 0.5 n 0.5 0.25 2 0.5 0.25 Mult Factor = 0.5 0.25 Max. Value 0.5 0.25 Max. Pred Cw 0.5 0.5 4 0.5 0.25 1 0.5 0.25 5 0.5 0.25 1 0.5 0.25 6 vwwct -inen "CW,Y.. Maximum dale poorns s!4 0.126u 0.3462 0.3657 13 1.3400 0.5 Ng/L 0.7 Ng/L Vnwn' then -COPY" Maximum data ppmm = 78 0.3444 0.8289 0.4154 38 1.0900 2.0 Ng/L 2.2 ug/L 9595 GENERIC RPA201432, data -6- EF/2112018 Vinyl Chloride Date Data BDL=1/2DL Results 1 8/6/2013 < 1 0.5 Std Dev. 2 9/30/2013 < 1 0.5 Mean 3 10/15/2013 < 1 0.5 C.V. 4 11/14/2013 < 1 0.5 n 5 12/4/2013 < 1 0.5 6 4/14/2014 < 1 0.5 Mult Factor = 7 5/15/2014 < 1 0.5 Max. Value 8 6/16/2014 < 1 0.5 Max. Pred Cw 9 7/15/2014 < 1 0.5 10 8/21/2014 < 2 1 11 9/25/2014 < 2 1 12 10/14/2014 < 2 1 13 11/18/2014 < 0.5 0.25 14 12/17/2014 < 2 1 15 9/8/2015 < 2 1 16 10/13/2015 < 2 1 17 11/24/2015 < 2 1 18 12/15/2015 < 2 1 19 1/12/2016 < 2 1 20 2/9/2016 < 2 1 21 3/8/2016 < 2 1 22 4/12/2016 < 2 1 23 5/18/2016 < 2 1 24 6/21/2016 < 2 1 25 7/19/2016 2 2 26 8/11/2016 < 2 1 27 9/14/2016 < 2 1 28 10/11/2016 < 2 1 29 11/16/2016 < 2 1 30 12/14/2016 < 2 1 31 1/17/2017 < 0.5 0.25 32 2/16/2017 < 2 1 33 3/20/2017 < 2 1 34 4/4/2017 < 0.5 0.25 35 5/17/2017 < 2 1 36 6/19/2017 < 2 1 37 7/25/2017 < 0.5 0.25 38 8/23/2017 < 2 1 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Vnwn' then -COPY" Maximum data ppmm = 78 0.3444 0.8289 0.4154 38 1.0900 2.0 Ng/L 2.2 ug/L 9595 GENERIC RPA201432, data -6- EF/2112018 REASONABLE POTENTIAL ANALYSIS 0 Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Fred Cw VRi[I-&- try 4n -C OVY" Mommum da[a pains c ,A NO DATA NO DATA NO DATA 0 N/A N/A N/A 9595 GENERIC RPA2014_32, data - 7 - 5/21 /2018 1.4 Dioxane Values" Mian "COPY- . �ilpmu115 tlA�A p7�lidf 58 Date Data BDL=112DL Results 1 6/21/2014 < 80 40 Std Dev. O.LULJ 1 2 9/25/2014 < 80 40 Mean 40.0000 2 3 10/14/2014 < 80 40 C.V. 0.6000 3 4 11/18/2014 < 80 40 n 5 4 5 12/17/2014 < 80 40 5 6 Mult Factor= 2.3200 6 7 Max. Value 40.0 Ng/L 7 8 Max. Pred Cw 92.8 Ng/L 8 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 f 58 0 Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Fred Cw VRi[I-&- try 4n -C OVY" Mommum da[a pains c ,A NO DATA NO DATA NO DATA 0 N/A N/A N/A 9595 GENERIC RPA2014_32, data - 7 - 5/21 /2018 REASONABLE POTENTIAL ANALYSIS vaiucs" tnnr, -CON- MAXIMUM WX POWO �x NO DATA NO DATA NO DATA 0 N/A N/A N/A 0 Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 vaiucs" tnnr, -CON- MAXIMUM WX POWO �x NO DATA NO DATA NO DATA 0 N/A N/A N/A VAfYns' than'COPY, Maximum dw4 "nt% e 5� NO DATA NO DATA 0 NIA N/A N/A 9595 GENERIC RPA2014_32, data -8- 5/21 /2018 0 Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 VAfYns' than'COPY, Maximum dw4 "nt% e 5� NO DATA NO DATA 0 NIA N/A N/A 9595 GENERIC RPA2014_32, data -8- 5/21 /2018 Date Data 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS 0 vdiU&S, man -COPS" i O Vafv"- ltwk'�COPY" MaRimum data paiF t , Mm -mw n da6a painU I BDL=1/2DL Results Date Data BDL=1/2DL Results Std Dev. NO DATA 1 Std Dev. NO DATA Mean NO DATA 2 Mean NO DATA C.V. NO DATA 3 C.V. NO DATA n 0 4 n 0 5 Mult Factor = N/A 6 Mult Factor = N/A Max. Value N/A 7 Max. Value N/A Max. Pred Cw N/A 8 Max. Pred Cw NIA 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 9595 GENERIC RPA2014_32, data - 9 - 5/21 /2018 REASONABLE POTENTIAL ANALYSIS 0 Date Data BDL=112DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Fred Cw Yltluy" Vann "COPY' M"Imm 4KU paintl a NO DATA NO DATA 0 N/A N/A N/A 9595 GENERIC RPA2014_32, data -10- 5/21 /2018 0 Volues" b)Wn "COPY- . maxlc l d*U Pwfft _m Date Data BDL=112DL Results 1 Std Dev. NO DATA 1 2 Mean NO DATA 2 3 C.V. NO DATA 3 4 n 0 4 5 5 6 Mult Factor = N/A 6 7 Max. Value N/A 7 8 Max. Pred Cw N/A 8 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 I 58 0 Date Data BDL=112DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Fred Cw Yltluy" Vann "COPY' M"Imm 4KU paintl a NO DATA NO DATA 0 N/A N/A N/A 9595 GENERIC RPA2014_32, data -10- 5/21 /2018 Date Data 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS O venNs^ men 'COPY' U valuef" lhrlt "Copy' . *mdmum dW pwft . Nlil;if im data mifaq 6! = SS BDL=1/2DL Results Date Data BDL=1/2DL Results Std Dev. Ni: DATA 1 Std Dev. NO DATA Mean NO DATA 2 Mean NO DATA C.V. NO DATA 3 C.V. NO DATA n 0 4 n 0 5 Mult Factor = N/A 6 Mult Factor = NIA Max. Value N/A 7 Max. Value N/A Max. Pred Cw N/A 8 Max. Pred Cw N/A 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 I 58 I 9595 GENERIC RPA2014_32, data 11 - 5/21 /2018 Warer. Resources ENVIRONMENTAL OUALR*Y February 26, 2016 Mr. Stuart Kerkhoff Environmental, Health and Safety Manager Radiator Specialty Company 600 radiator Road Indian Trail, NC 28079 PAT MCCROR.Y DONALD R. VAN DER VAART Secrelary S. JAY ZIMMERMAN L aed r RECENED/NCDEQ/DWR MAR 01 2016 Water Quality Permitting Section Subject: Compliance Evaluation Inspection Radiator Specialty Company Ground water remediation NPDES Permit No. NCO088838 Union County Dear Mr. Kerkhoff: Enclosed is a copy of the Compliance Evaluation Inspection for the inspection conducted at the subject facility on February 21, 2016 by Ori Tuvia and Ed Watson. Your cooperation during the site visit was much appreciated. Please advise the staff involved with this NPDES Permit by forwarding a copy of the enclosed report. As was discussed on site, please indicate in DMRs that grab sampling is used. The report should be self-explanatory; however, should you have any questions concerning this report, please do not hesitate to contact Ori Tuvia at (704) 235-2190, or at ori.tuvia @ ncde n r.p,ov. Cc: NPDES (Ron Berry) MRO Files Sincerely, Ori Tuvia, Environmental Engineer Mooresville Regional Office Division of Water Resources, DEQ Mooresville Regional Office Location: 610 East Center Ave., Suite 301 Mooresville, NC 28115 Phone: (704) 663-1699 \ Fax: (704) 663-6040 \ Customer Service: 1-877-623.6748 United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 1 2 15 1 3 1 NCO088838 [11 12I 16/02/21 117 18I, I 191 s I 20 211.11111 1111111 11 111111111 1 111111 111111111111x8 Inspection Work Days Facility Self -Monitoring Evaluation Rating 131 QA Reserved 67'1.0 701a I 71 IN 1 72 L1 N 7374 751 111 I 1 I 180 L-1 J Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time(Date Permit Effective Date POTW name and NPDES permit Number) 10:OOAM 16/02/21 09/10/01 Radiator Specialty Company 600 Radiator Rd Exit Time/Date . Permit Expiration Date Indian Trail NC 28079 11:15AM 16/02/21 13/10/31 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data /// Richard Herman/// Stuart A Kerkhoff/// Stuart A Kerkhoff/ORC/704-6841815/ Name, Address of Responsible. Official/Title/Phone and Fax Number Contacted Stuart Kerkhoff,600 Radiator Rd Indian Trail NC 28079/1704-684-181517046841868 No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit 0 Flow Measurement Operations & Maintenance Records/Reports ® Self -Monitoring Program E Facility Site Review Effluent/Receiving Waters Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Edward Watson MRO GW/// Ori A Tuvia MRO WQ//704-663-1699/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date William C Basinger MRO WQ//704-235-2194/ EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type NC0088838 11 12I 16/02/21 17 18 I C I (Cont.) Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Noted by Ed Watson: A review of historical groundwater analytical results indicate the presence of chlorinate volatile organic compounds (CVOC's) in the onsite groundwater. However, these values have been shown to be being reduced by the on-site remediation efforts. Trichloroethane and several of its various daughter products remain in concentration in exceedance of the NC 2L standards. Historic reported values indicate these constituents are moving forward with the expected degradation of chlorinated solvents. Page# Permit: NCO088838 Owner -Facility: Radiator Specialty Company Inspection Date: 0212112016 Inspection Type: Compliance Evaluation Yes No NA NE Are records kept and maintained as required by the permit? Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ❑ ❑ 0 ❑ application? Are all records maintained for 3 years (lab. reg. required 5 years)? M ❑ ❑ Is the facility as described in the permit? 0 ❑ ❑ ❑ # Are there any special conditions for the permit? ❑ 0 ❑ ❑ Is access to the plant site restricted to the general public? Dates, times and location of sampling ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? Name of individual performing the sampling ❑ ❑ ❑ Comment: Permit has expired on 10/20/2013. The facility has.. applied for a new Dermit. The en rmit renewal is in the process of being reviewed. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? ❑ ❑ ❑ ❑ Is all required information readily available, complete and current? ❑ ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? M ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? M ❑ ❑ ❑ Is the chain -of -custody complete? ■ ❑ ❑ ❑ Dates, times and location of sampling don't indicate what type of sampling method is used. Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are MRS complete: do they include all permit parameters? ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ M ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator ❑ ❑ M ❑ on each shift? Is the ORC visitation log available and current? ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? ❑ ❑ ❑ Is the backup operator certified at one grade less or greater than the facility classification? ❑ ❑ ❑ Is a copy of the current NPDES permit available on site? ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? ❑ ❑ M ❑ Comment: DMRs, COC_ ORC lops and calibration lops for the months of June 2014 -December 2015 were examined during the inspection. Records are well kept. It was discovered that MRS don't indicate what type of sampling method is used. Flow Measurement - Effluent Yes No NA NE Page# 3 Permit: NCO088838 Owner -Facility: Radiator Specialty Company Are field parameters performed by certified personnel or laboratory? ❑ ❑ Inspection Date: 02/21/2016 Inspection Type: Compliance Evaluation Are all other parameters (excluding field parameters) performed by a certified lab? ❑ Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? ■ ❑ ❑ ❑ Is flow meter calibrated annually? ■ ❑ ❑ ❑ Is the flow meter operational? ■ ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ■ ❑ ❑ ❑ Comment: Flow meter is calibrated annually b; Clearwater Inc. Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? ❑ ❑ ❑ ❑ Are all other parameters (excluding field parameters) performed by a certified lab? ❑ ❑ ❑ # Is the facility using a contract lab? 0 ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees 0 ❑ ❑ ❑ Celsius)? ❑ ❑ ❑ Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? ❑ ❑ M ❑ Incubator (BOD) set to 20.0 degrees Celsius +/-1.0 degrees? ❑ ❑ M ❑ Comment: Prism Lab is contracted to analyze samples. ETS Lab performs chronic toxicity testing, Effluent Samolin❑ Yes No NA NE Is composite sampling flow proportional? ❑ ❑ ❑ Is sample collected below all treatment units? ❑ ❑ ❑ Is proper volume collected? ■ ❑ ❑ ❑ Is the tubing clean? 0 ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees ❑ ❑ ❑ Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type ❑ ❑ ❑ representative)? Comment: The Dermit requires arab samples for all reauired Darameters. Samoles are kept on ice in a cooler until transferred to Prism Lab. Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? ■ ❑ ❑ ❑ Are the receiving water free of foam other than trace amounts and other debris? ❑ ❑ ❑ If effluent (diffuser pipes are required) are they operating properly? ❑ ❑ M ❑ Comment: The discharge was clear with no foam and did not appear to impact the receiving stream. Page# 4 Permit: NCO088838 Owner-Facility: Radiator Specialty Company Inspection Date: 02/21/2018 Inspection Type: compliance Evaluation Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? ■ ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: The facility pumps -ground water from four recovery wells. treated by an air striver tower. Page# 5 RSC Chemical Solutions a division of Radiator Specialty Company July 9, 2015 Mr. Ron Berry Engineer North Carolina Department of Environment and Natural Resources Division of Water Resources 1617 Mail Service Center Raleigh, North Carolina 27699 RE: 1,4 -Dioxane Analytical Results Radiator Specialty Company Indian Trail, Union County, North Carolina Permit No. NCO088838 Dear Mr. Berry: RECEIVED/DENROWR JUL 16 2015 Water Quality Permitiinq Sectiar Radiator Specialty Company (RSC) is responding to your June 16, 2015 email concerning the analytical results for the presence of 1,4 -Dioxane in RSC's groundwater samples. RSC understands DENR's position that it needs to see the actual measured values, not just less than values, to properly evaluate the 1,4 -Dioxane concentrations. DENR informed RSC that it would put a permit limit of eighty (80) micrograms/Liter (ug/L) in RSC's new National Pollutant Discharge Elimination System (NPDES) Permit. Based on that conversation, RSC requested its testing laboratory to report actual measured values of 1,4 -Dioxane down to eighty (80) ug/L. As it turns out, RSC's testing laboratory can only report measured values for 1,4 -Dioxane to eighty (80) ug/L. Any results at less than this concentration can only be reported as estimate concentrations. The results reported to the DENR on May 12, 2015 are below the analytical method reporting limit and therefore cannot be reported as actual measured values. RSC asked its testing laboratory if any other analytical methods were available that could provide actual measured values at less than eighty (80) ug/L. The testing laboratory advised that no accepted methods can provide actual measured values at less than eighty (80) ug/L. Since DENR has already advised that it cannot use estimated values, RSC did not request alternate analytical procedures be used. Radiator Specialty Company appreciates the North Carolina Department of Environment and Natural Resources cooperation and assistance in this matter. If you have any questions or require additional information, please call me at (704) 684-1815. 600 Radiator Road — Indian Trail, NC 28079-5225 — Telephone: 800-438-4532 — Fax: 704-684-1975 — www.rscbrands.com Mr. Ron Berry July 9, 2015 Page 2 Sincerely, Radiator Specialty Company Lap / Y Stuart A. Kerkhoff, CHMM Environmental Health and Safety Manager cc: Mr. Richard Harmon, Harmon Environmental, PA Mr. Benne Hutson, McGuireWoods LLP NPDESU A-DIOXAN ERESPONSFIDOC sorp RSC Chemical Solutions a division of Radiator Specialty Company September 25, 2014 Mr. Ron Berry Engineer North Carolina Department of Environment and Natural Resources Division of Water Resources 1617 Mail Services Center Raleigh, North Carolina 27669-1617 Re: Response To August S, 2014 E -Mail Radiator Specialty Company Indian Trail, North Carolina Permit No. NCO088838 Dear Mr. Berry: RECEIVED/DENR/DWR SEP 2 5 2014 Water Quality Permitting Section Radiator Specialty Company (RSC) appreciates this opportunity to respond to the two proposed changes to the pending National Pollutant Discharge Elimination System (NPDES) Permit renewal for Permit No. NC0088838. For ease of review, we have presented the North Carolina Department of Environment and Natural Resources (DENR) intended incorporations from your August 5, 2014 e-mail in italics followed by RSC's response. 1. Any submitted toxicity testing ",ill require a composite be taken as the test sample. We understand that composite samples are typically required for NPDES permitted facilities with either an intermittent discharge and/or the potential for variability in the waste stream over a twenty-four (24) hour period. The groundwater recovery and treatment system at Radiator Specialty Company discharges approximately 40,000 gallons of treated groundwater per day. The discharge flow is driven by the pumping of groundwater from four (4) on-site recovery wells. As a result, the system discharges continuously each day. Since the source of the water is limited to the four (4) recovery wells, the influent water quality is well documented and variability in the waste stream has not previously occurred and is not expected to occur in the future. As a result, grab samples adequately represent the water quality for toxicity testing. DENR has accepted this approach at at least one other facility with a similar discharge. A May 8, 2014 determination by Ms. Cindy Moore. Mr. Tom Belnick and Mr. Wes Bell of DENR authorized Equipment & Supply. Inc. (NPDES #0087858) to revise the toxicity sampling protocol from composite to grab. The groundwater treatment and discharge 600 Radiator Road — Indian Trail, NC 28079-5225 — Telephone: 800-438-4532 — Fax: 704-684-1975 — www.rscbrands.com ' Mr. Ron Berry September 25, 2014 Page 12 system at the Equipment & Supply, Inc. facilty is comparable to the system operated by RSC. RSC requests the toxicity sampling protocol not be revised. 2. The presence of 1,4 -dioxane in the influent and groundwater sources will require the addition of monthly 1,4 -dioxane monitoring with an 80 microgram per liter (,ug/L) daily limit to protect for the Human Health surface water quality standard RSC is aware that 1,4 -dioxane has historically been detected in groundwater samples collected from the site and is not opposed to analyzing the effluent for 1,4 -dioxane. However, this parameter is not targeted by standard method 624, the analytical method currently required by the facility's Permit. Based on an August 11, 2014 telephone conversation with you, RSC understands DENR would accept modifying the Permit during the renewal process to specify SW -846 Method 8260 instead of Standard Method 624 for targeted volatile constituents. Further, based on this conversation, RSC implemented this analytical method change during the August 2014 monthly sampling event. The Method Reporting Limit for SW -846 Method 8260 is 150 µg/L. Prism Laboratories, Inc. has indicated that a normal Method Detection Limit for SW -846 Method 8260 is -� 10.6 pg/L. Should 1,4 -dioxane be detected in the effluent sample at a concentration between the permit limit and 150 µg/L, the result would be reported as a "Y' value. Based on our telephone conversation on August 11, 2014, RSC anticipates three (3) to six (6) months will be necessary to collect and evaluate 1,4 -dioxane analytical results to determine if changes to the existing groundwater recovery system are necessary. RSC appreciates DENR allowing us to review its recommended changes prior to issuing the draft permit renewal. Please call if you have any questions or require any additional information. Sincerely, Radiator Specialty Company La" Stuart Kerkhoff Environmental, Health and Safety Manager cc: Mr. Richard L. Harmon, Harmon Environmental. PA Mr. Benne Hutson. McGuireWoods LLP NPD1-.S/1TRMI I C11AN(ili.DOCX Daily Permit Limits Parameters ug/L Flow (MGD) 0.09 Monthly Sampling Total Suspended Solids 0.045 Monthly Average 0.030 Tetrachloroethene 3.0 1,1,1 -Trichloroethane 4.0 Vinyl chloride 2.0 1,4 -Dioxane """ 80.0 Quarterly Sampling <0.50 Chloroethane -- 1,1-Dichloroethane -- 1,1-Dichloroethene -- 1,2-Dichloroethene (total) cis-1,2-Dichloroehene Trichloroethene Benzene --- Methylene chloride -- 1,2-Dichloroethane -- Toluene --- trans-1,2-Dichloroethene --- Chronic Toxicity 90% Comments: Table 2 AIR STRIPPER EFFLUENT RADIATOR SPECIALTY COMPANY NPDES PERMIT NO. NC0088838 OUTFALL 001 08/21/14 09/25/14 10/14/14 11/18114 12/17/14 0.0006 0.0317 0.0270 0.0182 0.0332 <0.0025 <0.0026 <0.0026 <0.0025 <.0026 <1.0 <1.0 <3.0 1.213 <3.0 <1.0 0.61 <4.0 <0.50 <4.0 <2.0 <0.50 <2.0 <0.50 <2.0 <80 <80 <80 <80 <80 NA NA <0.50 NA NA NA NA <0.50 NA NA NA NA <0.50 NA NA NA NA NA NA NA NA NA <0.50 NA NA NA NA <0.50 NA NA NA NA <0.50 NA NA NA NA <1.0 NA NA NA NA <0.50 NA NA NA NA <0.50 NA NA NA NA <0.50 NA NA NA NA P NA NA NA: Not Analyzed P: Pass Chronic Toxicity Flow: Flow is the reading from the flowmeter day of sample collection less flowmeter reading during last outfall inspection divided by number of days between the two. See DMR Form. 1,4 -Dioxane: New Permit will have a limit of 80 ug/L. RSC started sampling it for evaluation in August 2014. In addition, RSC swithced to SW846 Method 8260. 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As we discussed, to address your concern, RSC implemented a monthly sampling program in which both influent and effluent were sampled for 1,4 -Dioxane from August through December 2014. The results of both the influent and effluent samples throughout this sampling period were below the suggested Permit Limit of eighty (80) micrograms per liter (ug/L). The results of these sampling activities are summarized in Tables 1 and 2. Based on the results of this sampling program, RSC does not intend to modify the current treatment technology at this time. RSC proposes to continue sampling the effluent for 1,4 -Dioxane quarterly. In the event 1,4 -Dioxane concentrations in the effluent indicate exceedances, RSC will evaluate additional treatment technologies at that time. On December 19, 2014, RSC shut down the groundwater recovery system due to operational issues with the computer system that runs the groundwater recovery system. RSC has been diagnosing the situation and proposes to resume operation of the groundwater recovery system when the issues have been resolved. Radiator Specialty Company appreciates the North Carolina Department of Environment and Natural Resources cooperation and assistance in this matter. If you have any questions or require additional information, please call me at (704) 684-1815. 600 Radiator Road — Indian Trail, NC 28079-5225 — Telephone: 800-438-4532 — Fax: 704-684-1975 — www.rscbrands.com Mr. Ron Berry May 12, 2015 Page 2 Sincerely, Radiator Specialty Company ht'J a ) Stuart A. Kerkhoff, CHMM Environmental Health and Safety Manager cc: Mr. Richard Harmon, Harmon Environmental, PA Mr. Benne Hutson, McGuireWoods LLP NPDES\1.4-DI OXANERESPONSE.DOC seVP RSC Chemical Solutions a division of Radiator Speeiaity Company May 3, 2013 Mr. Charles H. Weaver North Carolina Department of Environment and Natural Resources Division of Water Quality National Pollutant Discharge Elimination System Unit 1617 Mail Service Center -- RE: National Pollutant Discharge Elimination System Permit Renewal Application Radiator Specialty Company = Indian Trail, Union County, North Carolina Permit No. NCO088838 : Dear Mr. Weaver: Radiator Specialty Company (RSC) respectfully submits fdr your review, three copies of its National Pollutant Discharge Elimination System WDES) Permit No. NCO088838 Permit Renewal Application — Short Form C r GW. This submission serves as RSC's request for renewal of NPDES Permit NC008883,8. Based on the most recent analytical results, with the exception of chloroethane, 1, 1 -dichloroethane, 1, 1 -dichloroethene and vinyl chloride, detected at concentrations of 5.9 ug/L, 2.4 ug/L, 1.5 ug/L and 2.0 ug/L, respectively, no targeted constituents were detected at concentrations exceeding the respective analytical method detection limit. Radiator Specialty Company appreciates the North Carolina Department of Environment and Natural Resources cooperation and assistance in this matter. If you have any questions or require additional information, please call me at (704^ 1815. Sincerely, y- 8 e'�' ` \ Radiator Specialty Company .� e Stuart A. Kerkhoff, CH Environmental Health and Safety Manger NPD Es LT.DOC 600 Radiator Road — Indian Trail, INC 28079-5225 — Telephone: 800-438-4532 — Fax: 704-684-1975 — www.rscbrands.com