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NC0021873_Fact Sheet_20180627
Fact Sheet NPDES Permit No. NCO021873 Permit Writer/Email Contact Qais Banihani, gais.banihani@ncdenr.gov: Date: April 23, 2018 Division/Branch: NC Division of Water Resources/NPDES Complex Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: N Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2' species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: Town of Mayodan/Mayodan WWTP Applicant Address: 210 W Main Street, Mayodan, NC 27027 Facility Address: 293 Cardwell Road, Mayodan, NC 27027 Permitted Flow: 2.5, 3.0 & 4.5 MGD Facility Type/Waste: Major Municipal; domestic and Industrial Facility Class: Class III (2.5 MGD) and IV (3.0 & 4.5 MGD) Treatment Units: Mechanical Bar Screen, Aeration Basins, Secondary Clarifiers, Chlorination, Dechlorination, Effluent flow meter, Sludge Digesters and Sludge Thickeners Pretreatment Program (Y/N) Y County: Rockingham Region Winston-Salem Page 1 of 13 Briefly describe the proposed permitting action and facility background: The Town of Mayodan Wastewater Treatment Plant (WWTP), herein called Mayodan or Permittee, applied for an NPDES permit renewal. The Permittee's 5 -year NPDES permit expired on May 31, 2017. Mayodan services 2,468 local residents and receives industrial and domestic influent flow from the Towns of Stoneville (1,042 residents) and Madison (2,205). In 2002, Mayodan applied for an expansion from 3.0 MGD to 4.5 MGD in order to add service to Stoneville and Madison. In 2007, because of loss of a major SN, Mayodan applied for a flow reduction modification to the permit to downgrade to 2.5 MGD, thereby going from a Class IV to a Class III facility with corresponding relaxed limits and monitoring conditions. The average discharge for the period of January 2014 through February 2018 was 1.05 MGD. This facility has 3 Significant Industrial Users (SIUs); Two Textile facilities and one Metal Finisher. 2. Receiving Waterbody Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 — Mayo River Stream Segment: 22-30-(10) Stream Classification: C Drainage Area (mi2): 312 Summer 7Q10 (cfs) 75 Winter 7Q 10 (cfs): 131 30Q2 (cfs): 150 Average Flow (cfs): 362 IWC (% effluent): 5% (2.5 MGD), 6% (3.0 MGD) and 9% (4.5 MGD) 303(d) listed/parameter: No Subject to TMDL/parameter: Yes- State wide TMDL for Mercury implementation Subbasin/HUC: Dan River Headwaters 03-02-02; 03010103 USGS Topo Quad: B 19 NW Page 2 of 13 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below for the period of January 2014 through February 2018. Table 1. Effluent Data Summary Outfall 001 Page 3 of 13 Permit Parameter Units Average Max Min Limit MA 2.5, 3 &4.5 Flow MGD 1.05 5.34 0.07 WA 45.0 BOD summer mg/l 6.34 49.0 < 2.0 MA 30.0 WA 45.0 BOD winter mg/l 6.04 32.0 < 2.0 MA 30.0 BOD Removal % 93.11 98.07 74.01 > 85.0 WA 45.0 TSS mg/l 7.82 83.0 < 2.0 MA 30.0 TSS Removal % 90.34 97.86 65.25 > 85.0 NH3N summer at 2.5 WA 35.0 mg/1 1.86 17.0 < 0.04 MGD MA 16.0 NH3N summer at 3.0 WA 35.0 mg/1 1.86 17.0 < 0.04 MGD MA 14.0 NH3N summer at 4.5 WA 27.0 mg/1 1.86 17.0 < 0.04 MGD MA 9.0 NH3N winter at 2.5 MGD mg/l 1.13 10.48 < 0.04 NH3N winter at 3.0 MGD mg/l 1.13 10.48 < 0.04 WA 35.0 NH3N winter at 4.5 MGD mg/l 1.13 10.48 < 0.04 MA 31.5 TRC µg/1 23.92 50.0 1 DM 28.0 (geometric) Fecal coliform #/100 ml 180.86 4280 < 1 WA 400 MA 200 6.0 > pH <9.0 pH SU 6.79 11.0 6.0 DO mg/l 7.92 16.5 1.4 Temperature °C 16.42 30 1.5 Conductivity umhos/cm 392.02 731.2 7.0 Page 3 of 13 TN mg/l 19.37 400.0 1.44 Average 7.0 TP mg/l 2.12 7.71 0.13 17.8 Total Chromium at 2.5 Min 5.3 1 5.2 23.4 P g/l 5.0 5.0 5.0 MGD Total Chromium at 3.0 DM 14,500 µg/1 5.0 5.0 5.0 MGD MA 856 Total Chromium at 4.5 DM 10,000 µg/1 5.0 5.0 5.0 MGD MA 587 Total Mercury ng/L 4.47 11.9 < 1.0 AA 47 Total Silver gg/l 1.47 < 10.0 < 1.0 Total Copper gg/l 7.42 11.0 3.0 MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum, DA=Daily Average, AA -Annual Average. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/l of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will beproposedfor this permit action: The current permit requires instream monitoring for Dissolved Oxygen (DO), Temperature, Conductivity and pH. A review of instream data from June 2016 through February 2018 indicates that the DO standard of 5 mg/L was maintained, and there were no significant differences between upstream and downstream (ANOVA, p > 0.5). The average DO for upstream and downstream were 9.5 and 9.6, respectively. Temperature readings were nearly identical between upstream and downstream sites except with only one set of measurements showing a differential greater than 2.8 degrees °C (12 °C for upstream and 15 °C for downstream) in November 2016. Effluent temperature on that day was 11 °C. On the other hand, conductivity readings between upstream and downstream locations were statistically significant (ANOVA, p < 0.05). There was no significant differences between upstream and downstream pH readings (ANOVA, p > 0.5). Instream data is summarized in tables 2 and 3. Table 2: Upstream Instream Data (June 2016 - February 2018) H SU Temperature °C DO m /L Conductivity mhos/cm Average 7.0 18.7 9.5 61.6 Max 8.2 31 17.8 89.2 Min 5.3 1 5.2 23.4 Page 4 of 13 Table 3: Downstream Instream Data (June 2016 - February 2018) Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): NO Name of Monitoring Coalition: NA 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): The facility reported a total of 5 limit violations from August 2013 to March 2018. All the violations were Fecal Coliform violations. TRC limit violations were not included since No action was required for values reported < 50 ug/L. The Fecal Coliform exceeded the weekly geometric mean twice in 2013, once in each 2014, 2015 and 2017. Fecal Coliform limit violations resulted in 2 Notices of Violation (NOVs), 2 No Actions and 1 Notice of Deficiency (NOD). Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): For the past four years, the facility passed 16 of 16 quarterly chronic toxicity tests as well as all four 2" d species chronic toxicity tests. Summarize the results from the most recent compliance inspection: The last facility inspection conducted in 2016 reported that the facility was operating properly. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following stream flows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with 15A NCAC 2B. 0204(b): NA Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/l for Municipals) may be appropriate if deemed more stringent based on dilution and model results. Ifpermit limits are more stringent than TBELs, describe how limits were developed: NA Page 5 of 13 H Temperature DO Conductivity SU °C m /L mhos/cm Average 7.0 18.8 9.6 67.2 Max 8.2 31 18.7 103.8 Min 5.2 1 5.5 45.6 Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): NO Name of Monitoring Coalition: NA 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): The facility reported a total of 5 limit violations from August 2013 to March 2018. All the violations were Fecal Coliform violations. TRC limit violations were not included since No action was required for values reported < 50 ug/L. The Fecal Coliform exceeded the weekly geometric mean twice in 2013, once in each 2014, 2015 and 2017. Fecal Coliform limit violations resulted in 2 Notices of Violation (NOVs), 2 No Actions and 1 Notice of Deficiency (NOD). Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): For the past four years, the facility passed 16 of 16 quarterly chronic toxicity tests as well as all four 2" d species chronic toxicity tests. Summarize the results from the most recent compliance inspection: The last facility inspection conducted in 2016 reported that the facility was operating properly. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following stream flows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with 15A NCAC 2B. 0204(b): NA Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/l for Municipals) may be appropriate if deemed more stringent based on dilution and model results. Ifpermit limits are more stringent than TBELs, describe how limits were developed: NA Page 5 of 13 Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/l (summer) and 1.8 mg/l (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/l (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/l are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: Wasteload Allocation (WLA) calculations resulted in a cap of 28 gg/L TRC, which is the same as in the current permit. Therefore, there are no proposed changes for TRC. The WLA calculations for ammonia resulted in the same limits as in the current permit. No changes are proposed from the current permit limits. Table 4 summarizes the NH3-N limit for each flow tier. Figure 1 shows that none of the average monthly and weekly average NH3-N results exceeded the monthly average and weekly average NH3-N limits even the more stringent limits at permitted flow of 3.0 and 4.5 MGD. Table 4. NH3-N Limit Figure 1. Effluent NH3-N data for Q = 2.5 MGD Mayodan NH, -N for Q= 2.5 MGD �- MA Limit _ WA Limit 40 35 bA 30 'Z 25 M Z 20 15 - • 10 • • W 5 • •••• t• Joe. • • 0 •• al 1/1/2014 7/20/2014 2/5/2015 8/24/2015 3/11/2016 9/27/2016 4/15/2017 11/1/2017 Date Page 6 of 13 Q=2.5MGD Q=3.0MGD Q=4.5MGD Season Monthly Average Weekly Average Monthly Average Weekly Average Monthly Avera e Weekly Average Summer 16.0 35.0 14.0 35.0 9.0 27.0 Winter No Limit No Limit No Limit No Limit 31.5 35.0 Figure 1. Effluent NH3-N data for Q = 2.5 MGD Mayodan NH, -N for Q= 2.5 MGD �- MA Limit _ WA Limit 40 35 bA 30 'Z 25 M Z 20 15 - • 10 • • W 5 • •••• t• Joe. • • 0 •• al 1/1/2014 7/20/2014 2/5/2015 8/24/2015 3/11/2016 9/27/2016 4/15/2017 11/1/2017 Date Page 6 of 13 Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of '/2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between April 2014 and December 2017. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: None • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: Lead at 4.5 MGD • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Arsenic, Cadmium, Total Chromium, Copper, Cyanide, Lead at 2.5 and 3 MGD, Molybdenum, Nickel, Selenium, Silver, and Zinc. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Page 7 of 13 Describe proposed toxicity test requirement: This is a Major POTW, and a chronic WET limit at 5% (2.5 MGD), 6% (3.0 MGD) and 9% (4.5 MGD) effluent will continue on a quarterly frequency. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/1) will receive an MMP requirement. Industrials are evaluated on a case-by-case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/1 Table 5. Mercury Effluent Data Summary- 2.5 MGD Table 6. Mercury Effluent Data Summary- 3.0 MGD 2014 2015 2016 2017 # of Samples 4 4 4 4 Annual Average Conc. n /L 3.8 4.7 4.5 4.6 Maximum Conc., n L 5.5 11.9 9.9 10.10 TBEL, n /L 47 WQBEL, n /L 244.3 Table 6. Mercury Effluent Data Summary- 3.0 MGD Table 7. Mercury Effluent Data Summary- 4.5 MGD 2014 2015 2016 2017 # of Samples 4 4 4 4 Annual Average Conc. n /L 3.8 4.7 4.5 4.6 Maximum Conc., n L 5.5 11.9 9.9 1.10 TBEL, n /L 47 WQBEL, n /L 205.5 Table 7. Mercury Effluent Data Summary- 4.5 MGD Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. However, since the facility is > 2 MGD and reported quantifiable levels of mercury (> 1 ng/1), a mercury minimization plan (MMP) remains the same as in the current permit. Page 8 of 13 2014 2015 2016 2017 # of Samples 4 4 4 4 Annual Average Conc. n /L 3.8 4.7 4.5 4.6 Maximum Conc., n L 5.5 11.9 9.9 10.10 TBEL, n /L 47 WQBEL, n /L 141.0 Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. However, since the facility is > 2 MGD and reported quantifiable levels of mercury (> 1 ng/1), a mercury minimization plan (MMP) remains the same as in the current permit. Page 8 of 13 Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special actions (HQW or OR W) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H. 010 7(c) (2) (B), 40CFR 122.4 7, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/l BODS/TSS for Monthly Average, and 45 mg/l for BODS/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BODS/TSS included in the permit? YES If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105( c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 9. Antibacksliding Review: Sections 402(0)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Page 9 of 13 Are any effluent limitations less stringent than previous permit (YES/NO): Yes If YES, confirm that antibacksliding provisions are not violated: Based on RPA, no monitoring will be required for Total Chromium, Silver and Copper. In addition, the Total Mercury limit of 47 ng/L annual average will be removed from the current permit based on the Mercury TMDL evaluation. However, the Total Mercury will continue to be monitored quarterly as in the current permit. 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(0) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12.Summary of Proposed Permitting Actions: Table 8. Current Permit Conditions and Proposed Changes 2.5, 3.0 & 4.5 MGD Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 2.5, 3.0 and 4.5 No change 15A NCAC 213.0505 MGD BODS Summer: No change TBEL. Secondary treatment MA 30 mg/1 standards/40 CFR 133 / 15A NCAC WA 45 mg/1 2B .0406 Winter: MA 30 mg/l WA 45 m /l TSS MA 30 mg/1 No change TBEL. Secondary treatment WA 45 mg/l standards/40 CFR 133 / 15A NCAC 213 .0406 Page 10 of 13 NH3-N at 2.5 Summer: No change WQBEL. Based on protection of MGD MA 16.0 mg/l State WQ criteria (WLA). 15A WA 35 mg/l NCAC 2B Winter MA No requirement WA No requirement NH3-N at 3.0 Summer: No change WQBEL. Based on protection of MGD MA 14.0 mg/l State WQ criteria (WLA). 15A WA 35 mg/l NCAC 2B Winter MA No requirement WA No requirement NH3-N at 4.5 Summer: No change WQBEL. Based on protection of MGD MA 9.0 mg/l State WQ criteria (WLA). 15A WA 27 mg/l NCAC 2B Winter MA 31.5 mg/l WA 35 m /l Total Residual DA 28 gg/L No change WQBEL. Based on protection of Chlorine State WQ criteria (WLA). 15A NCAC 2B Fecal coliform MA 200 /100ml No change WQBEL. State WQ standard, 15A WA 400 /100ml NCAC 2B pH 6 — 9 SU No change WQBEL. State WQ standard, 15A NCAC 2B DO at 2.5 MGD Monitor 3/week No change WQBEL. State WQ standard, 15A NCAC 2B DO at 3.0 and 4.5 Monitor Daily No change WQBEL. State WQ standard, 15A MGD NCAC 2B Temperature at 2.5 Monitor 3/Week No change WQBEL. State WQ standard, 15A MGD NCAC 2B Temperature at 3.0 Monitor Daily No change WQBEL. State WQ standard, 15A and 4.5 MGD NCAC 2B Conductivity at Monitor 3/Week No change 15A NCAC 2B.0500 2.5 MGD Conductivity at Monitor Daily No change WQBEL. State WQ standard, 15A 3.0 and 4.5 MGD NCAC 2B Total Nitrogen Monitor Monthly No change WQBEL. State WQ standard, 15A NCAC 2B. 0500 Total Phosphorus Monitor Monthly No change WQBEL. State WQ standard, 15A NCAC 2B. 0500 Page 11 of 13 Total Chromium at Monitor Quarterly Remove monitoring No reasonable potential (RP) found 2.5 MGD in RPA and less than Cr VI Total Chromium at MA 856 µg/L Remove effluent No reasonable potential (RP) found 3.0 MGD limitation and in RPA and less than Cr VI DM 14,500 µg/L monitoring Total Chromium at MA 587 µg/L Remove effluent No reasonable potential (RP) found 4.5 MGD limitation and in RPA and less than Cr VI DM 10,000 µg/L monitoring Total Mercury AA 47 ng/L Remove effluent Mercury TMDL Evaluation limitation and monitoring Total Silver Monitor Quarterly Remove monitoring No reasonable potential (RP) found in RPA Total Copper Monitor Quarterly Remove monitoring No reasonable potential (RP) found in RPA Lead No Requirement Monitor Quarterly at Reasonable potential (RP) found in 4.5 MGD RPA Total Hardness No Requirement Add effluent and Hardness -dependent dissolved upstream Quarterly metals water quality standards Monitoring approved in 2016 Toxicity Test Monitor Quarterly No change WQBEL. No toxics in toxic amounts. 15A NCAC 2B Effluent Pollutant Monitor and Report Three times per permit 40 CFR 122 Scan cycle Electronic No requirement Add Electronic In accordance with EPA Electronic Reporting Reporting Special Reporting Rule 2015. Condition MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max, AA - Annual Average 13. Public Notice Schedule: Permit to Public Notice: 05/01/2018 Per 15A NCAC 2H .0109 & .0 111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. Page 12 of 13 14. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): NO If Yes, list changes and their basis below: NA NC Wildlife Resources Commission (WRC) did make comments on the draft renewal permit due to the presence of rare, threatened and endangered aquatic species, including mussels and fish. Specifically they requested that we encourage the permittee to consider switching disinfection to UV or Ozone instead of Chlorine, and that we investigate developing site specific limits for ammonia -nitrogen. In response, we did agree to add language to the permit issuance cover page discussing the WRC concerns and to strongly request the permittee to consider UV or other alternate to chlorination, and to keep working on controlling ammonia -nitrogen discharges. It was pointed out that the recent TRC analysis have all been below 50 µg/L, and the facility has passed all WET tests. The existing NH3-N data was reviewed and in - stream concentrations were calculated from DMR data using 7Q10 dilution and the Division's standard background ammonia -N concentration of 0.22 mg/ L. The results showed mostly background to slightly above background ammonia -N of 0. 22 - 0.25 mg/ L. The highest in -stream concentration was 0.34 mg/ L in July 2016. See attached Ammonia -N predicted In -stream Concentrations, Mayo WWTP January 2015 - February 2018. 15. Fact Sheet Attachments (if applicable): RPA Spreadsheet Summary Dissolved Metals Implementation/Freshwater or Saltwater Page 13 of 13 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Table 1. Project Information ]CHECK IF HQW OR ORW WQS Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ]Apply WS Hardness WQC 7Q1Os (cfs) 7011 Ow (cfs) 30Q2 (cfs) QA (cfs) 1 Q1 Os (cfs) Effluent Hardness_ Upstream Hardness_ Combined Hardness Chronic_ Combined Hardness Acute Data Source(s) ❑CHECK TO APPLY MODEL Town of Mayodan WWTP III NCO021873 001 2.500 Mayo River 0301010304 C 75.00 131.00 150.00 362.00 61.34 64.74 mg/L (Avg) ------------------- 36.26 mg/L (Avg) ------------------- 37.66 mg/L ------------------- 37.95 mg/L REQUIRED DATA ENTRY Par01 Par02 Par03 Par04 Par05 Par06111111 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.8041 FW 4.6638 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 164.6657 FW 1273.9479 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 11.1837 FW 15.5177 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 4.6574 FW 120.5551 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 52.6525 FW 477.1704 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 0.6077 ug/L Zinc Aquatic Life NC 179.3216 FW 179.0388 ug/L Bromoform Human Health C 120 HH pg/L Dichlorobromomethane Human Health C 27 HH pg/L RPA_Mayodan_NCO021873_Q 2.5 mgd_More metals, input 6/27/2018 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, input 6/27/2018 REASONABLE POTENTIAL ANALYSIS 1 Effluent Hardness Use "PASTE SPECIAL Values" then "COPY" H2 Upstream Hardness Use "PASTE SPECIAL Values" then "COPY" Par01 & Par02 Arsenic . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL 1 9/9/2014 69 69 Std Dev. 20.6917 1 6/21/2016 40 40 Std Dev. 15.3601 1 4/2/2014 < 5 2.5 2 12/8/2015 44 44 Mean 64.7368 2 7/5/2016 75 75 Mean 36.2581 2 6/4/2014 < 5 2.5 3 3/15/2016 57 57 C.V. 0.3196 3 7/19/2016 52 52 C.V. 0.4236 3 9/10/2014 < 5 2.5 4 6/21/2016 68 68 n 38 4 8/2/2016 44 44 n 31 4 12/2/2014 < 5 2.5 5 7/5/2016 135 135 10th Per value 44.00 mg/L 5 8/16/2016 78 78 10th Per value 20.00 mg/L 5 3/4/2015 < 5 2.5 6 7/19/2016 84 84 Average Value 64.74 mg/L 6 9/6/2016 41 41 Average Value 36.26 mg/L 6 6/3/2015 < 5 2.5 7 8/2/2016 85 85 Max. Value 135.00 mg/L 7 9/20/2016 60 60 Max. Value 78.00 mg/L 7 9/2/2015 < 5 2.5 8 8/16/2016 78 78 8 10/4/2016 53 53 8 12/9/2015 < 5 2.5 9 9/6/2016 90 90 9 10/18/2016 32 32 9 3/9/2016 < 5 2.5 10 9/20/2016 104 104 10 12/13/2016 32 32 10 6/8/2016 < 5 2.5 11 10/4/2016 85 85 11 12/20/2016 36 36 11 9/7/2016 < 5 2.5 12 10/18/2016 68 68 12 1/10/2017 33 33 12 12/14/2016 < 5 2.5 13 12/13/2016 68 68 13 1/17/2017 36 36 13 3/8/2017 < 5 2.5 14 12/20/2016 92 92 14 1/31/2017 20 20 14 6/14/2017 < 5 2.5 15 1/10/2017 82 82 15 2/28/2017 20 20 15 9/13/2017 < 5 2.5 16 1/17/2017 76 76 16 3/7/2017 36 36 16 12/6/2017 < 5 2.5 17 1/31/2017 65 65 17 3/21/2017 24 24 17 18 2/28/2017 56 56 18 4/4/2017 20 20 18 19 3/7/2017 44 44 19 4/19/2017 28 28 19 20 3/21/2017 44 44 20 5/2/2017 24 24 20 21 4/5/2017 48 48 21 5/16/2017 56 56 21 22 4/19/2017 60 60 22 9/5/2017 20 20 22 23 5/2/2017 44 44 23 9/19/2017 20 20 23 24 5/16/2017 84 84 24 10/4/2017 28 28 24 25 6/6/2017 48 48 25 11/7/2017 24 24 25 26 6/20/2017 29 29 26 11/21/2017 28 28 26 27 8/1/2017 63 63 27 12/6/2017 28 28 27 28 8/16/2017 63 63 28 1/2/2018 24 24 28 29 9/5/2017 56 56 29 1/16/2018 36 36 29 30 9/19/2017 48 48 30 2/7/2018 36 36 30 31 10/4/2017 64 64 31 2/20/2018 40 40 31 32 11/7/2017 40 40 32 32 33 11/21/2017 52 52 33 33 34 12/6/2017 52 52 34 34 35 1/2/2018 60 60 35 35 36 1/16/2018 55 55 36 36 37 2/7/2018 60 60 37 37 38 2/20/2018 40 40 38 38 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 3- 6/27/2018 Mult Factor = 1.00 Max. Value 2.5 ug/L Max. Pred Cw 2.5 ug/L REASONABLE POTENTIAL ANALYSIS 4- RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Use"PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Results Std Dev. 0.0000 Mean 2.5000 C.V. 0.0000 n 16 Mult Factor = 1.00 Max. Value 2.5 ug/L Max. Pred Cw 2.5 ug/L REASONABLE POTENTIAL ANALYSIS 4- RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Cadmium Date Data BDL=1/2DL Results 1 4/2/2014 < 1 0.5 Std Dev. 2 6/4/2014 < 1 0.5 Mean 3 9/10/2014 < 1 0.5 C.V. 4 12/2/2014 < 1 0.5 n 5 3/4/2015 < 1 0.5 6 6/3/2015 < 1 0.5 Mult Factor = 7 9/2/2015 < 1 0.5 Max. Value 8 12/9/2015 < 1 0.5 Max. Pred Cw 9 3/9/2016 < 1 0.5 10 6/8/2016 < 1 0.5 11 9/7/2016 < 1 0.5 12 12/14/2016 < 1 0.5 13 3/8/2017 < 1 0.5 14 6/14/2017 < 1 0.5 15 9/13/2017 < 1 0.5 16 12/6/2017 < 1 0.5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Pdr10 Values" then "COPY" . Maximum data points = 58 0.5000 0.0000 16 1.00 0.500 ug/L 0.500 ug/L Chromium, Total Date Data 1 3/31/2014 < 2 4/2/2014 < 3 6/4/2014 < 4 6/10/2014 < 5 9/10/2014 < 6 12/2/2014 < 7 3/4/2015 < 8 6/3/2015 < 9 9/2/2015 < 10 12/9/2015 < 11 3/9/2016 < 12 3/15/2016 < 13 6/8/2016 < 14 9/7/2016 < 15 12/14/2016 < 16 3/8/2017 < 17 6/14/2017 < 18 6/20/2017 < 19 9/13/2017 < 20 12/6/2017 < 21 33 22 35 23 36 24 38 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Chromium, Total Date Data BDL=1/2DL Results 5 2.5 Std Dev. 5 2.5 Mean 5 2.5 C.V. 5 2.5 n 5 2.5 9 5 2.5 Mult Factor = 5 2.5 Max. Value 5 2.5 Max. Pred Cw 5 2.5 15 5 2.5 6/14/2017 5 2.5 18 5 2.5 12/6/2017 5 2.5 21 5 2.5 5 2.5 255 5 2.5 5 2.5 28 5 2.5 5 2.5 31 5 2.5 5 - Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 r 2.5000 0.0000 20 1.00 2.5 pg/L 2.5 pg/L Copper BDL=1/2DL 7 7 6 6 8 8 10 10 11 11 9 9 10 10 3 3 5 5 6 6 5 5 5 5 9 9 9 9 6 6 5 5 6 6 10 10 11 11 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Date Data 1 3/31/2014 2 4/2/2014 3 6/4/2014 4 6/10/2014 5 9/10/2014 6 12/2/2014 7 3/4/2015 8 6/3/2015 9 9/2/2015 10 12/9/2015 11 3/9/2016 12 6/8/2016 13 9/7/2016 14 12/14/2016 15 3/8/2017 16 6/14/2017 17 6/20/2017 18 9/13/2017 19 12/6/2017 20 21 22 23 24 L 255 26 27 28 29 30 31 32 33 34 35 36 37 38 Copper BDL=1/2DL 7 7 6 6 8 8 10 10 11 11 9 9 10 10 3 3 5 5 6 6 5 5 5 5 9 9 9 9 6 6 5 5 6 6 10 10 11 11 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par12 Use "PASTE SPECIAL Par14 Values" then "COPY" Cyanide Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 Results Date Std Dev. 2.4110 Mean 7.4211 C.V. 0.3249 n 19 MultFactor= 1.21 Max. Value 11.00 ug/L Max. Fred Cw 13.31 ug/L 5.00 0.0000 16 1.00 5.0 ug/L 5.0 ug/L 6 - Date 1 4/2/2014 < 2 6/4/2014 < 3 9/10/2014 < 4 12/2/2014 < 5 3/4/2015 < 6 6/3/2015 < 7 9/2/2015 < 8 12/9/2015 < 9 3/9/2016 < 10 6/8/2016 11 9/7/2016 12 12/14/2016 13 3/8/2017 < 14 6/14/2017 < 15 9/13/2017 16 12/6/2017 < 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Lead Date Data Results BDL=1/2DL Results 1 4/2/2014 < 5 5 Std Dev. 2 6/4/2014 < 5 5 Mean 3 9/10/2014 < 5 5 C.V. 4 12/2/2014 < 5 5 n 5 3/4/2015 < 5 5 6 6/3/2015 < 5 5 MultFactor= 7 9/2/2015 < 5 5 Max. Value 8 12/9/2015 < 5 5 Max. Fred Cw 9 3/9/2016 < 5 5 10 6/8/2016 < 5 5 11 9/7/2016 < 5 5 12 12/14/2016 < 5 5 13 3/8/2017 < 5 5 14 6/14/2017 < 5 5 15 9/13/2017 < 5 5 16 12/6/2017 < 5 5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 5.00 0.0000 16 1.00 5.0 ug/L 5.0 ug/L 6 - Date 1 4/2/2014 < 2 6/4/2014 < 3 9/10/2014 < 4 12/2/2014 < 5 3/4/2015 < 6 6/3/2015 < 7 9/2/2015 < 8 12/9/2015 < 9 3/9/2016 < 10 6/8/2016 11 9/7/2016 12 12/14/2016 13 3/8/2017 < 14 6/14/2017 < 15 9/13/2017 16 12/6/2017 < 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Lead Date Da BDL=1/2DL Results 5 2.5 Std Dev. 5 2.5 Mean 5 2.5 C.V. 5 2.5 n 5 2.5 6/3/2015 5 2.5 MultFactor= 5 2.5 Max. Value 5 2.5 Max. Fred Cw 5 2.5 6/8/2016 < 6 6 9/7/2016 20 20 12/13/2016 12 12 3/8/2017 < 5 2.5 6/14/2017 5 2.5 9/13/2017 10 10 12/6/2017 5 2.5 Use "PASTE SPECIAL Par15 Values" then "COPY" . Maximum data points = 58 4.8750 1.0253 16 1.80 20.000 ug/L 36.000 ug/L RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Date Da 1 4/2/2014 2 6/3/2014 3 9/10/2014 4 12/3/2014 5 3/4/2015 6 6/3/2015 7 9/2/2015 8 12/9/2015 9 3/9/2016 10 6/8/2016 < 11 9/7/2016 12 12/13/2016 13 3/8/2017 < 14 6/14/2017 15 9/13/2017 16 12/6/2017 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Mercury to BDL=1/2DL Results 1.1 1.1 Std Dev. 5.5 5.5 Mean 5.2 5.2 C.V. 3.4 3.4 n 3.3 3.3 Mean 1.4 1.4 Mult Factor = 11.9 11.9 Max. Value 2.3 2.3 Max. Pred Cw 3.5 3.5 n 1 0.5 < 9.9 9.9 4.1 4.1 < 1 0.5 Mult Factor = 3.4 3.4 < 10.1 10.1 Max. Value 4.4 4.4 < REASONABLE POTENTIAL ANALYSIS Par16 Par17 & Par18 Use "PASTE SPECIAL Use "PASTE SPECIAL Values" then "COPY" Molybdenum Values" then "COPY" Nickel . Maximum data . Maximum data points = 58 points = 58 4.4063 0.7855 16 1.62 11.9 ng/L 19.3 ng/L 7 - 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 6 6/3/2015 < 10 5 Mult Factor = 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Pred Cw 9 3/9/2016 < 10 5 10 6/8/2016 < 10 5 11 9/7/2016 < 10 5 12 12/14/2016 < 10 5 13 3/8/2017 < 10 5 14 6/14/2017 < 10 5 15 9/13/2017 < 10 5 16 12/6/2017 < 10 5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 7 - 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L Use "PASTE SF Values" then "i Maximum < points = 5 5.3125 0.2353 16 1.17 10.0 11.7 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 6 6/3/2015 < 10 5 Mult Factor = 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Pred Cw 9 3/9/2016 < 10 5 10 6/8/2016 < 10 5 11 9/7/2016 < 10 5 12 12/14/2016 < 10 5 13 3/8/2017 < 10 5 14 6/14/2017 < 10 5 15 9/13/2017 10 10 16 12/6/2017 < 10 5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Use "PASTE SF Values" then "i Maximum < points = 5 5.3125 0.2353 16 1.17 10.0 11.7 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Par19 Selenium Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 6 6/3/2015 < 10 5 Mult Factor = Ng/L 7 9/2/2015 < 10 5 Max. Value Ng/L 8 12/9/2015 < 10 5 Max. Pred Cw 9 3/9/2016 < 10 5 10 6/8/2016 < 10 5 11 9/7/2016 < 10 5 12 12/14/2016 < 10 5 13 3/8/2017 < 10 5 14 6/14/2017 < 10 5 15 9/13/2017 < 10 5 16 12/6/2017 < 10 5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Paf20 Values" then "COPY" Silver . Maximum data points = 58 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L Date Data BDL=1/2DL Results 1 3/31/2014 < 10 5 Std Dev. 2 4/2/2014 < 1 0.5 Mean 3 6/4/2014 < 1 0.5 C.V. 4 6/10/2014 < 1 0.5 n 5 9/10/2014 < 1 0.5 9/2/2015 6 12/2/2014 < 1 0.5 Mult Factor = 7 3/4/2015 < 1 0.5 Max. Value 8 6/3/2015 < 1 0.5 Max. Pred Cw 9 9/2/2015 < 1 0.5 12/14/2016 10 12/9/2015 < 1 0.5 26 11 3/9/2016 < 1 0.5 52 12 6/8/2016 < 1 0.5 16 13 9/7/2016 < 1 0.5 14 12/14/2016 < 1 0.5 15 3/8/2017 < 1 0.5 16 6/14/2017 < 1 0.5 21 17 6/20/2017 < 1 0.5 18 9/13/2017 < 1 0.5 19 12/6/2017 < 1 0.5 20 26 21 27 22 23 28 24 L 29 255 31 26 32 27 33 28 34 29 36 30 37 31 38 32 33 34 35 36 37 38 8 - Use "PASTE SPECIAL Par21 Values" then "COPY" . Maximum data points = 58 0.7368 1.4011 19 1.85 5.000 ug/L 9.250 ug/L Zinc RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL 1 4/2/2014 51 51 2 6/4/2014 59 59 3 9/10/2014 72 72 4 12/2/2014 55 55 5 3/4/2015 81 81 6 6/3/2015 37 37 7 9/2/2015 71 71 8 12/9/2015 49 49 9 3/9/2016 57 57 10 6/8/2016 23 23 11 9/7/2016 63 63 12 12/14/2016 71 71 13 3/8/2017 26 26 14 6/14/2017 52 52 15 9/13/2017 48 48 16 12/6/2017 77 77 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 6/27/2018 REASONABLE POTENTIAL ANALYSIS RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 9- 6/27/2018 Par22 Par23 Use "PASTE SPECIAL Use "PASTE SPECIAL Use "PASTE SPECIAL Values" then "COPY" Bromoform Values" then "COPY" Dlchlorobro171omethane Values" then "COPY" . Maximum data . Maximum data . Maximum data points = 58 points = 58 points = 58 Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Std Dev. 17.0000 1 9/9/2014 51.6 51.6 Std Dev. 26.4426 1 9/9/2014 15.2 15.2 Std Dev. 5.8312 Mean 55.7500 2 12/8/2015 5.8 5.8 Mean 21.0667 2 12/8/2015 15.2 15.2 Mean 11.8333 C.V. 0.3049 3 3/15/2016 5.8 5.8 C.V. (default) 0.6000 3 3/15/2016 5.1 5.1 C.V. (default) 0.6000 n 16 4 n 3 4 n 3 5 5 MultFactor= 1.23 6 MultFactor= 3.00 6 MultFactor= 3.00 Max. Value 81.0 ug/L 7 Max. Value 51.600000 pg/L 7 Max. Value 15.200000 pg/L Max. Fred Cw 99.6 ug/L 8 Max. Fred Cw 154.800000 pg/L 8 Max. Fred Cw 45.600000 pg/L 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 RPA_Mayodan_NC0021873_Q 2.5 mgd_More metals, data 9- 6/27/2018 Town of Mayodan WWTP - NC0021873 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM Qw (MGD) = 2.5000 1Q10S (cfs) = 61.34 7Q10S (cfs) = 75.00 7Q10W (cfs) = 131.00 30Q2 (cfs) = 150.00 Avg. Stream Flow, QA (cfs) = 362.00 Receiving Stream: Mayo River HUC 0301010304 DATA POINTS = 58 WWTP/WTP Class: III IWC% @ 1Q10S = 5.941884536 IWC% @ 7Q10S = 4.912836767 IWC% @ 7Q10W = 2.873030584 1WC% @ 30Q2 = 2.518277823 IW%C @ QA = 1.059104886 Stream Class: C Outfall 001 Qw = 2.5 MGD COMBINED HARDNESS (me/L) Acute = 37.95 mg/L Chronic = 37.66 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J a Applied Chronic Acute n # Det. Max Pred Cw Allowable Cw Standa Acute (FW): 5,722.1 No RP, Predicted Max < 50% of Allowable Cw - No Arsenic C 150 FW(7Q10s) 340 ug/L Monitoring required 16 0 2.5 ------------------------------------ Chronic (FW): 3,053.2 All values less than 5 ug/L Max MDL =-5 Arsenic C 10 HH/WS(Qavg) ug/L NO DETECTS Chronic (HH): 944.2 _ -------------------------- ____________Arsenic All values less than 5 ug/L Max MDL = 5 Acute: 78.491 No RP, Predicted Max < 50% of Allowable Cw - No Cadmium NC 0.8041 FW(7Q10s) 4.6638 ug/L 16 0 0.500 Monitoring required - - ----------------------------- Chronic: 16.366 no detect, all values less than 1 ug/L NO DETECTS Max MDL = 1 Acute: 269.3 Chromium VI NC 11 FW(7Q10s) 16 gg/L 0 0 N/A Chronic: -----223.9-- --------------------------- Chromium, Total NC gg/L 20 0 2.5 Max reported value = 2.5 All values less than 5 ug/L & < Cr IV NO DETECTS Max MDL = 5 Acute: 261.16 No RP, Predicted Max < 50% of Allowable Cw - No Copper NC 11.1837 FW(7Q10s) 15.5177 ug/L 19 19 13.31 Monitoring required Chronic: 227.64 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 370.3 No RP, Predicted Max < 50% of Allowable Cw - No Cyanide NC 5 FW(7Q10s) 22 10 ug/L 16 0 5.0 Monitoring required --------------------------------------------- Chronic: 101.8 All values less than 5 ug/L NO DETECTS Max MDL = 10 Acute: 2,028.904 No RP, Predicted Max < 50% of Allowable Cw - No Lead NC 4.6574 FW(7Q10s) 120.5551 ug/L 16 4 36.000 Monitoring required Chronic: 94.800 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Mercury NC 12 FW(7Q10s) 0.5 ng/L 16 14 19.3 Chronic: 244.3 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Molybdenum NC 2000 HH(7Q10s) ug/L 16 0 5.0 Chronic: 40,709.7 No RP, Predicted Max < 50% of Allowable Cw - No NO DETECTS Max MDL = 10 Monitoring required RPA_ Mayodan_NC0021873_Q 2.5 mgd_More metals, rpa Page 10 of 12 6/27/2018 Town of Mayodan WWTP - Outfall 001 NCO021873 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 2.5 MGD RPA_ Mayodan_NC0021873_Q 2.5 mgd_More metals, rpa Page 11 of 12 6/27/2018 Acute (FW): 8,030.6 No RP, Predicted Max < 50% of Allowable Cw - No Nickel NC 52.6525 FW(7Q10s) 477.1704 gg/L --------------------------------------------- Monitoring required 16 1 11.7 Chronic (FW): 1,071.7 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw ------------------------------ Monitoring required Nickel NC 25.0000 WS(7Q10s) µg /L Chronic (WS): 508.9 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 942.5 No RP, Predicted Max < 50% of Allowable Cw - No Selenium NC 5 FW(7Q10s) 56 ug/L 16 0 5.0 Monitoring required Chronic: 101.8 All values less than 10 ug/L NO DETECTS Max MDL = 10 Acute: 10.227 Silver NC 0.06 FW(7Q10s) 0.6077 ug/L 19 0 9.250 Chronic: 1.221 All values < 1 ug/L with one < 10 ug/L NO DETECTS Max MDL = 10 Acute: 3,013.2 No RP, Predicted Max < 50% of Allowable Cw - No Zinc NC 179.3216 FW(7Q10s) 179.0388 ug/L 16 16 99.6 Monitoring required Chronic: 3,650.1 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Bromoform c 120 HH(Qavg) gg/L 3 3 154.80000 Note: n:5 9 C.V. (default) Chronic: 11330.32258 No RP, Predicted Max < 50% of Allowable Cw -No Limited data set No value > Allowable Cw Monitoring required Acute: NO WQS Dichlorobromomethane c 27 HH(Qavg) gg/L 33 45.60000 Note: n <_ 9 C.V. (default) Chronic: 2549.32258 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set INo value > Allowable Cw Monitoring required RPA_ Mayodan_NC0021873_Q 2.5 mgd_More metals, rpa Page 11 of 12 6/27/2018 Date: 6/27/2018 Enter data onto "Table 1" under the Input Sheet and enter "Effluent Hardness" under the Data Sheet. In accordance with 40 CFR 122.45 (c), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). 1) Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively. 2) The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 30 mg/L is used to calculate the Translator values. 3) Pretreatment Facilities— PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations. 4) For Cadmium, Lead, Nickel, Chromium and Beryllium, if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. 5) For monitoring and compliance purposes if Total Chromium 'Y: Town of Mayodan WWTP Outfall 001 PERMIT: NCO021873 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Recelving Recewl" 9 Stream Stream su mer 7010 Hec. Jtream 1010 NHUtJ Flow Limn Total Suspende0 Solids -Fixed Value- ComDinetl Hardness chronic ComDinetl Hardness Acute Instream Wastexater ConranVatlon Instream Emu Wastewater Upstream Hardness Hartlness ConcenVaton Averege Average 7010(CFS) (MGD) MGD MGD (mg/L) (mg/L) (mg/L) (Chronic) (Acute)' (mgt) (mglL) 75.0000 1 48.3871 39.5742 2.5000 10 37.657 37.950 4.9128 5.9419 36.2580645 64.73684 Upstream Hard Avg (mg/L) = 36.25806 EFF Hard Avg (mg/L) = 64.73684 Dissolved Metals CriteriaUS EPA III Metal Criteria Tela) Metal= COMMENTS (Identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): after applying hartlness PARAMETER uaron Translators -using Default Partition Dissolved Mesa+Tansia.r Chronic Acute Coefficients Chronic I Acute 0.202 164.67 1.000 11.00 N/A 0.348 11.18 0.184 4.66 0.432 52.65 25 1.000 0.06 0.2881 179.32 =dissolved metal standard.5ee 15A NCAC 026.0211 for more information. = hardness -dependent dissolved metal standard. See 15A NCAC 02B.0211 for more information. = based upon measurement of total recaveable metal. See 15A NCAC 02B.0211 far mare informadon. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Toml Recoverable metal standard. The Human Health standard for Arsenic is 30 pg/L which is Total Recoverable metal standard. ACA H 37.95024 ACCH 37.65718 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Table 1. Project Information ]CHECK IF HQW OR ORW WQS Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ]Apply WS Hardness WQC 7Q1Os (cfs) 7011 Ow (cfs) 30Q2 (cfs) QA (cfs) 1 Q1 Os (cfs) Effluent Hardness_ Upstream Hardness_ Combined Hardness Chronic_ Combined Hardness Acute Data Source(s) ❑CHECK TO APPLY MODEL Town of Mayodan WWTP IV NCO021873 001 3.000 Mayo River 0301010304 C 75.00 131.00 150.00 362.00 61.34 64.74 mg/L (Avg) ------------------- 36.26 mg/L (Avg) ------------------- 37.92 mg/L ------------------- 38.26 mg/L REQUIRED DATA ENTRY Par01 Par02 Par03 Par04 Par05 Par06111111 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.8083 FW 4.6975 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 165.6087 FW 1282.5903 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 11.2505 FW 15.6388 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 4.6938 FW 121.6715 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 52.9640 FW 480.5146 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 0.6164 ug/L Zinc Aquatic Life NC 180.3842 FW 180.2955 ug/L Bromoform Human Health C 120 HH pg/L Dichlorobromomethane Human Health C 27 HH pg/L RPA_Mayodan_NCO021873_Q 3 mgd_More metals, input 6/27/2018 RPA_Mayodan_NC0021873_Q 3 mgd_More metals, input 6/27/2018 REASONABLE POTENTIAL ANALYSIS 1 Effluent Hardness Use "PASTE SPECIAL Values" then "COPY" H2 Upstream Hardness Use "PASTE SPECIAL Values" then "COPY" Par01 & Par02 Arsenic . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL 1 9/9/2014 69 69 Std Dev. 20.6917 1 6/21/2016 40 40 Std Dev. 15.3601 1 4/2/2014 < 5 2.5 2 12/8/2015 44 44 Mean 64.7368 2 7/5/2016 75 75 Mean 36.2581 2 6/4/2014 < 5 2.5 3 3/15/2016 57 57 C.V. 0.3196 3 7/19/2016 52 52 C.V. 0.4236 3 9/10/2014 < 5 2.5 4 6/21/2016 68 68 n 38 4 8/2/2016 44 44 n 31 4 12/2/2014 < 5 2.5 5 7/5/2016 135 135 10th Per value 44.00 mg/L 5 8/16/2016 78 78 10th Per value 20.00 mg/L 5 3/4/2015 < 5 2.5 6 7/19/2016 84 84 Average Value 64.74 mg/L 6 9/6/2016 41 41 Average Value 36.26 mg/L 6 6/3/2015 < 5 2.5 7 8/2/2016 85 85 Max. Value 135.00 mg/L 7 9/20/2016 60 60 Max. Value 78.00 mg/L 7 9/2/2015 < 5 2.5 8 8/16/2016 78 78 8 10/4/2016 53 53 8 12/9/2015 < 5 2.5 9 9/6/2016 90 90 9 10/18/2016 32 32 9 3/9/2016 < 5 2.5 10 9/20/2016 104 104 10 12/13/2016 32 32 10 6/8/2016 < 5 2.5 11 10/4/2016 85 85 11 12/20/2016 36 36 11 9/7/2016 < 5 2.5 12 10/18/2016 68 68 12 1/10/2017 33 33 12 12/14/2016 < 5 2.5 13 12/13/2016 68 68 13 1/17/2017 36 36 13 3/8/2017 < 5 2.5 14 12/20/2016 92 92 14 1/31/2017 20 20 14 6/14/2017 < 5 2.5 15 1/10/2017 82 82 15 2/28/2017 20 20 15 9/13/2017 < 5 2.5 16 1/17/2017 76 76 16 3/7/2017 36 36 16 12/6/2017 < 5 2.5 17 1/31/2017 65 65 17 3/21/2017 24 24 17 18 2/28/2017 56 56 18 4/4/2017 20 20 18 19 3/7/2017 44 44 19 4/19/2017 28 28 19 20 3/21/2017 44 44 20 5/2/2017 24 24 20 21 4/5/2017 48 48 21 5/16/2017 56 56 21 22 4/19/2017 60 60 22 9/5/2017 20 20 22 23 5/2/2017 44 44 23 9/19/2017 20 20 23 24 5/16/2017 84 84 24 10/4/2017 28 28 24 25 6/6/2017 48 48 25 11/7/2017 24 24 25 26 6/20/2017 29 29 26 11/21/2017 28 28 26 27 8/1/2017 63 63 27 12/6/2017 28 28 27 28 8/16/2017 63 63 28 1/2/2018 24 24 28 29 9/5/2017 56 56 29 1/16/2018 36 36 29 30 9/19/2017 48 48 30 2/7/2018 36 36 30 31 10/4/2017 64 64 31 2/20/2018 40 40 31 32 11/7/2017 40 40 32 32 33 11/21/2017 52 52 33 33 34 12/6/2017 52 52 34 34 35 1/2/2018 60 60 35 35 36 1/16/2018 55 55 36 36 37 2/7/2018 60 60 37 37 38 2/20/2018 40 40 38 38 RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 3- 6/27/2018 Mult Factor = 1.00 Max. Value 2.5 ug/L Max. Pred Cw 2.5 ug/L REASONABLE POTENTIAL ANALYSIS 4- RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Use"PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Results Std Dev. 0.0000 Mean 2.5000 C.V. 0.0000 n 16 Mult Factor = 1.00 Max. Value 2.5 ug/L Max. Pred Cw 2.5 ug/L REASONABLE POTENTIAL ANALYSIS 4- RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Cadmium Date Data BDL=1/2DL Results 1 4/2/2014 < 1 0.5 Std Dev. 2 6/4/2014 < 1 0.5 Mean 3 9/10/2014 < 1 0.5 C.V. 4 12/2/2014 < 1 0.5 n 5 3/4/2015 < 1 0.5 6 6/3/2015 < 1 0.5 Mult Factor = 7 9/2/2015 < 1 0.5 Max. Value 8 12/9/2015 < 1 0.5 Max. Pred Cw 9 3/9/2016 < 1 0.5 10 6/8/2016 < 1 0.5 11 9/7/2016 < 1 0.5 12 12/14/2016 < 1 0.5 13 3/8/2017 < 1 0.5 14 6/14/2017 < 1 0.5 15 9/13/2017 < 1 0.5 16 12/6/2017 < 1 0.5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Pdr09 Values" then "COPY" . Maximum data points = 58 0.5000 0.0000 16 1.00 0.500 ug/L 0.500 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Chromium VI Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw 5 - Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 r NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L Chromium, Tot; RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL 1 3/31/2014 < 5 2.5 2 4/2/2014 < 5 2.5 3 6/4/2014 < 5 2.5 4 6/10/2014 < 5 2.5 5 9/10/2014 < 5 2.5 6 12/2/2014 < 5 2.5 7 3/4/2015 < 5 2.5 8 6/3/2015 < 5 2.5 9 9/2/2015 < 5 2.5 10 12/9/2015 < 5 2.5 11 3/9/2016 < 5 2.5 12 3/15/2016 < 5 2.5 13 6/8/2016 < 5 2.5 14 9/7/2016 < 5 2.5 15 12/14/2016 < 5 2.5 16 3/8/2017 < 5 2.5 17 6/14/2017 < 5 2.5 18 6/20/2017 < 5 2.5 19 9/13/2017 < 5 2.5 20 12/6/2017 < 5 2.5 21 22 23 24 250 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 al Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Pall Use "PASTE SPECIAL Par12 Values" then "COPY" Copper Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 2.5000 0.0000 20 1.00 2.5 pg/L 2.5 pg/L 7.4211 0.3249 19 1.21 11.00 ug/L 13.31 ug/L 6 - Date Data Data BDL=1/2DL Results 1 3/31/2014 7 7 Std Dev. 2 4/2/2014 6 6 Mean 3 6/4/2014 8 8 C.V. 4 6/10/2014 10 10 n 5 9/10/2014 11 11 < 6 12/2/2014 9 9 Mult Factor = 7 3/4/2015 10 10 Max. Value 8 6/3/2015 3 3 Max. Pred Cw 9 9/2/2015 5 5 12/6/2017 10 12/9/2015 6 6 18 11 3/9/2016 5 5 12 6/8/2016 5 5 13 9/7/2016 9 9 23 14 12/14/2016 9 9 15 3/8/2017 6 6 16 6/14/2017 5 5 28 17 6/20/2017 6 6 18 9/13/2017 10 10 19 12/6/2017 11 11 33 20 34 21 36 22 37 38 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 7.4211 0.3249 19 1.21 11.00 ug/L 13.31 ug/L 6 - Cyanide Date Data 1 4/2/2014 < 2 6/4/2014 < 3 9/10/2014 < 4 12/2/2014 < 5 3/4/2015 < 6 6/3/2015 < 7 9/2/2015 < 8 12/9/2015 < 9 3/9/2016 < 10 6/8/2016 < 11 9/7/2016 < 12 12/14/2016 < 13 3/8/2017 < 14 6/14/2017 < 15 9/13/2017 < 16 12/6/2017 < 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Cyanide BDL=1/2DL Results i 5 Std Dev. i 5 Mean i 5 C.V. i 5 n i 5 i 5 Mult Factor = i 5 Max. Value i 5 Max. Pred Cw i 5 i 5 i 5 i 5 i 5 i 5 i 5 i 5 Use "PASTE SPECIAL Par14 Values" then "COPY" . Maximum data points = 58 Date 1 4/2/2014 < 2 6/4/2014 < 3 9/10/2014 < 4 12/2/2014 < 5 3/4/2015 < 6 6/3/2015 < 7 9/2/2015 < 8 12/9/2015 < 9 3/9/2016 < 10 6/8/2016 11 9/7/2016 12 12/14/2016 13 3/8/2017 < 14 6/14/2017 < 15 9/13/2017 16 12/6/2017 < 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 5.00 0.0000 16 1.00 5.0 ug/L 5.0 ug/L RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Lead BDL=1/2DL Results 5 2.5 Std Dev. 5 2.5 Mean 5 2.5 C.V. 5 2.5 n 5 2.5 6/3/2014 5 2.5 MultFactor= 5 2.5 Max. Value 5 2.5 Max. Fred Cw 5 2.5 C.V. 6 6 12/3/2014 20 20 3.4 12 12 5 5 2.5 3.3 5 2.5 n 10 10 6/3/2015 5 2.5 1.4 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par15 Use "PASTE SPECIAL Par16 Use "PASTE SPECIAL Values"then"COPY" Mercury Values" then "COPY" Molybdenum Values" then "COPY" . Maximum data . Maximum data . Maximum data points = 58 points = 58 points = 58 4.8750 1.0253 16 1.80 20.000 ug/L 36.000 ug/L 7- 4.4063 0.7855 16 1.62 11.9 ng/L 19.3 ng/L Date Data BDL=1/2DL Results 1 4/2/2014 1.1 1.1 Std Dev. 2 6/3/2014 5.5 5.5 Mean 3 9/10/2014 5.2 5.2 C.V. 4 12/3/2014 3.4 3.4 n 5 3/4/2015 3.3 3.3 n 6 6/3/2015 1.4 1.4 MultFactor= 7 9/2/2015 11.9 11.9 Max. Value 8 12/9/2015 2.3 2.3 Max. Fred Cw 9 3/9/2016 3.5 3.5 12/9/2015 10 6/8/2016 < 1 0.5 9 11 9/7/2016 9.9 9.9 12 12/13/2016 4.1 4.1 5 13 3/8/2017 < 1 0.5 10 14 6/14/2017 3.4 3.4 < 15 9/13/2017 10.1 10.1 3/8/2017 16 12/6/2017 4.4 4.4 14 17 < 10 5 18 9/13/2017 < 10 5 19 16 12/6/2017 < 10 20 17 21 18 22 19 23 24 25 21 26 22 27 23 28 24 29 30 31 26 32 27 33 28 34 29 35 36 37 31 38 32 7- 4.4063 0.7855 16 1.62 11.9 ng/L 19.3 ng/L 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 6 6/3/2015 < 10 5 MultFactor= 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Fred Cw 9 3/9/2016 < 10 5 10 6/8/2016 < 10 5 11 9/7/2016 < 10 5 12 12/14/2016 < 10 5 13 3/8/2017 < 10 5 14 6/14/2017 < 10 5 15 9/13/2017 < 10 5 16 12/6/2017 < 10 5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Par17 & Par18 Nickel REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par19 Values" then "COPY" . Maximum data points = 58 5.3125 0.2353 16 1.17 10.0 pg/L 11.7 pg/L Selenium Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 7 6 6/3/2015 < 10 5 Mult Factor = 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Fred Cw 9 3/9/2016 < 10 5 0.5 10 6/8/2016 < 10 5 13 11 9/7/2016 < 10 5 12/14/2016 12 12/14/2016 < 10 5 < 13 3/8/2017 < 10 5 1 14 6/14/2017 < 10 5 0.5 15 9/13/2017 < 10 10 19 16 12/6/2017 < 10 5 17 21 18 22 19 23 20 25 21 26 22 27 23 28 24 29 25 31 26 32 27 33 28 34 29 35 30 37 31 38 32 33 34 35 36 37 38 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par19 Values" then "COPY" . Maximum data points = 58 5.3125 0.2353 16 1.17 10.0 pg/L 11.7 pg/L Selenium 8 - Use "PASTE SPECIAL Par20 Values" then "COPY" . Maximum data points = 58 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L Silver Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 7 6 6/3/2015 < 10 5 Mult Factor = 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Fred Cw 9 3/9/2016 < 10 5 0.5 10 6/8/2016 < 10 5 13 11 9/7/2016 < 10 5 12/14/2016 12 12/14/2016 < 10 5 < 13 3/8/2017 < 10 5 1 14 6/14/2017 < 10 5 0.5 15 9/13/2017 < 10 5 19 16 12/6/2017 < 10 5 17 21 18 22 19 23 20 25 21 26 22 27 23 28 24 29 25 31 26 32 27 33 28 34 29 35 30 37 31 38 32 33 34 35 36 37 38 8 - Use "PASTE SPECIAL Par20 Values" then "COPY" . Maximum data points = 58 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L Silver RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL 1 3/31/2014 < 10 5 2 4/2/2014 < 1 0.5 3 6/4/2014 < 1 0.5 4 6/10/2014 < 1 0.5 5 9/10/2014 < 1 0.5 6 12/2/2014 < 1 0.5 7 3/4/2015 < 1 0.5 8 6/3/2015 < 1 0.5 9 9/2/2015 < 1 0.5 10 12/9/2015 < 1 0.5 11 3/9/2016 < 1 0.5 12 6/8/2016 < 1 0.5 13 9/7/2016 < 1 0.5 14 12/14/2016 < 1 0.5 15 3/8/2017 < 1 0.5 16 6/14/2017 < 1 0.5 17 6/20/2017 < 1 0.5 18 9/13/2017 < 1 0.5 19 12/6/2017 < 1 0.5 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par21 Use "PASTE SPECIAL Values" then "COPY" Zinc Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 Par22 Results Date Data Std Dev. 1.0324 Mean 0.7368 C.V. 1.4011 n 19 MultFactor= 1.85 Max. Value 5.000 ug/L Max. Fred Cw 9.250 ug/L Use "PASTE SPECIAL Par23 Date Data BDL=1/2DL Results 1 4/2/2014 51 51 Std Dev. 17.0000 1 2 6/4/2014 59 59 Mean 55.7500 2 3 9/10/2014 72 72 C.V. 0.3049 3 4 12/2/2014 55 55 n 16 4 5 3/4/2015 81 81 51.600000 pg/L 5 6 6/3/2015 37 37 MultFactor= 1.23 6 7 9/2/2015 71 71 Max. Value 81.0 ug/L 7 8 12/9/2015 49 49 Max. Fred Cw 99.6 ug/L 8 9 3/9/2016 57 57 9 10 6/8/2016 23 23 10 11 9/7/2016 63 63 11 12 12/14/2016 71 71 12 13 3/8/2017 26 26 13 14 6/14/2017 52 52 14 15 9/13/2017 48 48 15 16 12/6/2017 77 77 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 Use "PASTE SPECIAL Par23 Date Da 1 9/9/2014 2 12/8/2015 3 3/15/2016 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 9- 6/27/2018 Bromoform Values then COPY . Maximum data points = 58 Date Data BDL=1/2DL Results 9/9/2014 51.6 51.6 Std Dev. 26.4426 12/8/2015 5.8 5.8 Mean 21.0667 3/15/2016 5.8 5.8 C.V. (default) 0.6000 n 3 MultFactor= 3.00 Max. Value 51.600000 pg/L Max. Fred Cw 154.800000 pg/L Date Da 1 9/9/2014 2 12/8/2015 3 3/15/2016 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 9- 6/27/2018 MultFactor= 3.00 Max. Value 15.200000 ug/L Max. Fred Cw 45.600000 Ng/L REASONABLE POTENTIAL ANALYSIS 10- RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Use"PASTE SPECIAL Dichlorobromomethane Values" then "COPY" . Maximum data points = 58 to BDL=1/2DL Results 15.2 15.2 Std Dev. 5.8312 15.2 15.2 Mean 11.8333 5.1 5.1 C.V. (default) 0.6000 n 3 MultFactor= 3.00 Max. Value 15.200000 ug/L Max. Fred Cw 45.600000 Ng/L REASONABLE POTENTIAL ANALYSIS 10- RPA_Mayodan_NC0021873_Q 3 mgd_More metals, data 6/27/2018 Town of Mayodan WWTP NCO021873 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM Qw (MGD) = 3.0000 1Q10S (cfs) = 61.34 7Q10S (cfs) = 75.00 7Q10W (cfs) = 131.00 30Q2 (cfs) = 150.00 Avg. Stream Flow, QA (cfs) = 362.00 Receiving Stream: Mayo River HUC 0301010304 DATA POINTS = 58 WWTP/WTP Class: IV IWC% @ 1Q10S = 7.0465222 IWC% @ 7Q10S = 5.838041431 IWC% @ 7Q10W = 3.42793955 1WC% @ 30Q2 = 3.006789525 IW%C @ QA = 1.268239465 Stream Class: C Outfall 001 Qw=3 MGD COMBINED HARDNESS (m¢/L) Acute = 38.26 mg/L Chronic = 37.92 mg/L PARAMETER NC STANDARDS OR EPA CRITERIAJ U) REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE a Applied Chronic Acute n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 4,825.1 No RP, Predicted Max < 50% of Allowable Cw - No Arsenic C 150 FW(7Q10s) 340 ug/L Monitoring required 16 0 2.5 Chronic (FW): 2,569.4 All values less than 5 ug/L Max MDL =-5 Arsenic C 10 HH/WS(Qavg) ug/L NO DETECTS Chronic (HH): 788.5 _ -------------------------- ____________Arsenic All values less than 5 ug/L Max MDL = 5 Acute: 66.665 No RP, Predicted Max < 50% of Allowable Cw - No Cadmium NC 0.8083 FW(7Q10s) 4.6975 ug/L 16 0 0.500 Monitoring required - - ----------------------------- Chronic: 13.846 No detects, all less than 1 ug/L NO DETECTS = Max MDL 1 Acute: 227.1 Chromium VI NC 11 FW(7Q10s) 16 pg/L 0 0 N/A Chronic: -----188.4-- --------------------------- Chromium, Total NC pg/L 20 0 2.5 Max reported value = 2.5 All values less than 5 ug/L & < Cr VI NO DETECTS Max MDL = 5 Acute: 221.94 No RP, Predicted Max < 50% of Allowable Cw - No Copper NC 11.2505 FW(7Q10s) 15.6388 ug/L 19 19 13.31 Monitoring required --------------------------------------------- Chronic: 192.71 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 312.2 No RP, Predicted Max < 50% of Allowable Cw - No Cyanide NC 5 FW(7Q10s) 22 10 ug/L 16 0 5.0 Monitoring required --------------------------------------------- Chronic: 85.6 All values less than 5 ug/L NO DETECTS Max MDL = 10 Acute: 1,726.689 No RP, Predicted Max < 50% of Allowable Cw - No Lead NC 4.6938 FW(7Q10s) 121.6715 ug/L 16 4 36.000 Monitoring required Chronic: 80.400 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Mercury NC 12 FW(7Q10s) 0.5 ng/L 16 14 19.3 Chronic: 205.5 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Molybdenum NC 2000 HH(7Q10s)ug/L 16 0 5.0 INo Chronic: 34,258.1 RP, Predicted Max < 50% of Allowable Cw - No RPA _Mayodan_NCO021873_Q 3 mgd_More metals, rpa Page 11 of 13 6/27/2018 Town of Mayodan WWTP - Outfall 001 NCO021873 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 3 MGD RPA _Mayodan_NCO021873_Q 3 mgd_More metals, rpa Page 12 of 13 6/27/2018 NO DETECTS Max MDL— 10 Monitoring required Acute (FW): 6,819.2 No RP, Predicted Max < 50% of Allowable Cw - No Nickel NC 52.9640 FW(7Q10s) 480.5146 µg/L Monitoring required 16 1 11.7 Chronic (FW): 907.2 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Monitoring required Nickel NC 25.0000 WS(7Q10s) µg/L _Cw Chronic (WS): 428.2 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 794.7 No RP, Predicted Max < 50% of Allowable Cw - No Selenium NC 5 FW(7Q10s) 56 ug/L 16 0 5.0 Monitoring required ----------------------------- Chronic: 85.6 All values less than 10 ug/L NO DETECTS Max MDL = 10 Acute: 8.747 Silver NC 0.06 FW(7Q10s) 0.6164 ug/L 19 0 9.250 Chronic: 1.028 All values < 1 ug/L with one < 10 ug/L NO DETECTS Max MDL = 10 Acute: 2,558.6 No RP, Predicted Max < 50% of Allowable Cw - No Zinc NC 180.3842 FW(7Q10s) 180.2955 ug/L 16 16 99.6 Monitoring required Chronic: 3,089.8 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Bromoform C 120 HH(Qavg) µg/L 3 3 154.80000 Note: n:5 9 C.V. (default) Chronic: 9461.93548 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set No value > Allowable Cw Monitoring required Acute: NO WQS Dichlorobromomethane C 27 HH(Qavg) µg/L 3 3 45.60000 Note: n < 9 C.V. (default) Chronic: 2128.93548 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set No value > Allowable Cw Monitoring required RPA _Mayodan_NCO021873_Q 3 mgd_More metals, rpa Page 12 of 13 6/27/2018 Date: 6/27/2018 Enter data onto "Table 1" under the Input Sheet and enter "Effluent Hardness" under the Data Sheet. In accordance with 40 CFR 122.45 (c), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). 1) Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively. 2) The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 30 mg/L is used to calculate the Translator values. 3) Pretreatment Facilities— PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations. 4) For Cadmium, Lead, Nickel, Chromium and Beryllium, if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. 5) For monitoring and compliance purposes if Total Chromium 'Y: Town of Mayodan WWTP Outfall 001 PERMIT: NCO021873 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Recelving Recewl" 9 Stream Stream su mer 7010 Hec. Jtream 1010 NHUtJ Flow Limn Total Suspende0 Solids -Fixed Value- ComDinetl Hardness chronic ComDinetl Hardness Acute Instream Wastexater ConranVatlon Instream Emu Wastewater Upstream Hardness Hartlness ConcenVaton Averege Average 7010(CFS) (MGD) MGD MGD (mg/L) (mg/L) (mg/L) (Chronic) (Acute)' (mgt) (mglL) 75.0000 1 48.3871 39.5742 3.0000 10 37.921 36.265 5.8380 7.0465 36.2580645 64.73684 Upstream Hard Avg (mg/L) = 36.25806 EFF Hard Avg (mg/L) = 64.73684 Dissolved Metals CriteriaUS EPA III Metal Criteria Tela) Metal= COMMENTS (Identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): after applying hartlness PARAMETER uaron Translators -using Default Partition Dissolved Mesa+Tansia.r Chronic Acute Coefficients Chronic I Acute 0.202 165.61 1.000 11.00 N/A 0.348 11.25 0.184 4.69 0.432 52.96 25 1.000 0.06 0.2881 180.38 =dissolved metal standard.5ee 15A NCAC 026.0211 for more information. = hardness -dependent dissolved metal standard. See 15A NCAC 02B.0211 for more information. = based upon measurement of total recaveable metal. See 15A NCAC 02B.0211 far mare informadon. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Toml Recoverable metal standard. The Human Health standard for Arsenic is 30 pg/L which is Total Recoverable metal standard. ACA H 38.26483 ACCH 37.92067 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Table 1. Project Information ]CHECK IF HQW OR ORW WQS Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ]Apply WS Hardness WQC 7Q1Os (cfs) 7011 Ow (cfs) 30Q2 (cfs) QA (cfs) 1 Q1 Os (cfs) Effluent Hardness_ Upstream Hardness_ Combined Hardness Chronic_ Combined Hardness Acute Data Source(s) ❑CHECK TO APPLY MODEL Town of Mayodan WWTP IV NCO021873 001 4.500 Mayo River 0301010304 C 75.00 131.00 150.00 362.00 61.34 64.74 mg/L (Avg) ------------------- 36.26 mg/L (Avg) ------------------- 38.68 mg/L ------------------- 39.17 mg/L REQUIRED DATA ENTRY Par01 Par02 Par03 Par04 Par05 Par06111111 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.8205 FW 4.7939 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 168.3242 FW 1307.2705 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 11.4430 FW 15.9855 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 4.7990 FW 124.8735 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 53.8613 FW 490.0688 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 0.6415 ug/L Zinc Aquatic Life NC 183.4450 FW 183.8859 ug/L Bromoform Human Health C 120 HH pg/L Dichlorobromomethane Human Health C 27 HH pg/L RPA_Mayodan_NCO021873_Q 4.5 mgd_More metals, input 6/27/2018 RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, input 6/27/2018 REASONABLE POTENTIAL ANALYSIS 1 Effluent Hardness Use "PASTE SPECIAL Values" then "COPY" H2 Upstream Hardness Use "PASTE SPECIAL Values" then "COPY" Par01 & Par02 Arsenic . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL 1 9/9/2014 69 69 Std Dev. 20.6917 1 6/21/2016 40 40 Std Dev. 15.3601 1 4/2/2014 < 5 2.5 2 12/8/2015 44 44 Mean 64.7368 2 7/5/2016 75 75 Mean 36.2581 2 6/4/2014 < 5 2.5 3 3/15/2016 57 57 C.V. 0.3196 3 7/19/2016 52 52 C.V. 0.4236 3 9/10/2014 < 5 2.5 4 6/21/2016 68 68 n 38 4 8/2/2016 44 44 n 31 4 12/2/2014 < 5 2.5 5 7/5/2016 135 135 10th Per value 44.00 mg/L 5 8/16/2016 78 78 10th Per value 20.00 mg/L 5 3/4/2015 < 5 2.5 6 7/19/2016 84 84 Average Value 64.74 mg/L 6 9/6/2016 41 41 Average Value 36.26 mg/L 6 6/3/2015 < 5 2.5 7 8/2/2016 85 85 Max. Value 135.00 mg/L 7 9/20/2016 60 60 Max. Value 78.00 mg/L 7 9/2/2015 < 5 2.5 8 8/16/2016 78 78 8 10/4/2016 53 53 8 12/9/2015 < 5 2.5 9 9/6/2016 90 90 9 10/18/2016 32 32 9 3/9/2016 < 5 2.5 10 9/20/2016 104 104 10 12/13/2016 32 32 10 6/8/2016 < 5 2.5 11 10/4/2016 85 85 11 12/20/2016 36 36 11 9/7/2016 < 5 2.5 12 10/18/2016 68 68 12 1/10/2017 33 33 12 12/14/2016 < 5 2.5 13 12/13/2016 68 68 13 1/17/2017 36 36 13 3/8/2017 < 5 2.5 14 12/20/2016 92 92 14 1/31/2017 20 20 14 6/14/2017 < 5 2.5 15 1/10/2017 82 82 15 2/28/2017 20 20 15 9/13/2017 < 5 2.5 16 1/17/2017 76 76 16 3/7/2017 36 36 16 12/6/2017 < 5 2.5 17 1/31/2017 65 65 17 3/21/2017 24 24 17 18 2/28/2017 56 56 18 4/4/2017 20 20 18 19 3/7/2017 44 44 19 4/19/2017 28 28 19 20 3/21/2017 44 44 20 5/2/2017 24 24 20 21 4/5/2017 48 48 21 5/16/2017 56 56 21 22 4/19/2017 60 60 22 9/5/2017 20 20 22 23 5/2/2017 44 44 23 9/19/2017 20 20 23 24 5/16/2017 84 84 24 10/4/2017 28 28 24 25 6/6/2017 48 48 25 11/7/2017 24 24 25 26 6/20/2017 29 29 26 11/21/2017 28 28 26 27 8/1/2017 63 63 27 12/6/2017 28 28 27 28 8/16/2017 63 63 28 1/2/2018 24 24 28 29 9/5/2017 56 56 29 1/16/2018 36 36 29 30 9/19/2017 48 48 30 2/7/2018 36 36 30 31 10/4/2017 64 64 31 2/20/2018 40 40 31 32 11/7/2017 40 40 32 32 33 11/21/2017 52 52 33 33 34 12/6/2017 52 52 34 34 35 1/2/2018 60 60 35 35 36 1/16/2018 55 55 36 36 37 2/7/2018 60 60 37 37 38 2/20/2018 40 40 38 38 RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 3- 6/27/2018 Mult Factor = 1.00 Max. Value 2.5 ug/L Max. Pred Cw 2.5 ug/L REASONABLE POTENTIAL ANALYSIS 4- RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Use"PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Results Std Dev. 0.0000 Mean 2.5000 C.V. 0.0000 n 16 Mult Factor = 1.00 Max. Value 2.5 ug/L Max. Pred Cw 2.5 ug/L REASONABLE POTENTIAL ANALYSIS 4- RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Cadmium Date Data BDL=1/2DL Results 1 4/2/2014 < 1 0.5 Std Dev. 2 6/4/2014 < 1 0.5 Mean 3 9/10/2014 < 1 0.5 C.V. 4 12/2/2014 < 1 0.5 n 5 3/4/2015 < 1 0.5 6 6/3/2015 < 1 0.5 Mult Factor = 7 9/2/2015 < 1 0.5 Max. Value 8 12/9/2015 < 1 0.5 Max. Pred Cw 9 3/9/2016 < 1 0.5 10 6/8/2016 < 1 0.5 11 9/7/2016 < 1 0.5 12 12/14/2016 < 1 0.5 13 3/8/2017 < 1 0.5 14 6/14/2017 < 1 0.5 15 9/13/2017 < 1 0.5 16 12/6/2017 < 1 0.5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Pdr09 Values" then "COPY" . Maximum data points = 58 0.5000 0.0000 16 1.00 0.500 ug/L 0.500 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Chromium VI Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw 5 - Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 r NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L Chromium, Tot; RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL 1 3/31/2014 < 5 2.5 2 4/2/2014 < 5 2.5 3 6/4/2014 < 5 2.5 4 6/10/2014 < 5 2.5 5 9/10/2014 < 5 2.5 6 12/2/2014 < 5 2.5 7 3/4/2015 < 5 2.5 8 6/3/2015 < 5 2.5 9 9/2/2015 < 5 2.5 10 12/9/2015 < 5 2.5 11 3/9/2016 < 5 2.5 12 3/15/2016 < 5 2.5 13 6/8/2016 < 5 2.5 14 9/7/2016 < 5 2.5 15 12/14/2016 < 5 2.5 16 3/8/2017 < 5 2.5 17 6/14/2017 < 5 2.5 18 6/20/2017 < 5 2.5 19 9/13/2017 < 5 2.5 20 12/6/2017 < 5 2.5 21 22 23 24 250 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 31 Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Fred Cw REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Pal Use "PASTE SPECIAL Par12 Values" then "COPY" Copper Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 2.5000 0.0000 20 1.00 2.5 pg/L 2.5 pg/L 7.4211 0.3249 19 1.21 11.00 ug/L 13.31 ug/L 6 - Date Data Data BDL=1/2DL Results 1 3/31/2014 7 7 Std Dev. 2 4/2/2014 6 6 Mean 3 6/4/2014 8 8 C.V. 4 6/10/2014 10 10 n 5 9/10/2014 11 11 < 6 12/2/2014 9 9 MultFactor= 7 3/4/2015 10 10 Max. Value 8 6/3/2015 3 3 Max. Fred Cw 9 9/2/2015 5 5 12/6/2017 10 12/9/2015 6 6 18 11 3/9/2016 5 5 12 6/8/2016 5 5 13 9/7/2016 9 9 23 14 12/14/2016 9 9 15 3/8/2017 6 6 16 6/14/2017 5 5 28 17 6/20/2017 6 6 18 9/13/2017 10 10 19 12/6/2017 11 11 33 20 34 21 36 22 37 38 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 7.4211 0.3249 19 1.21 11.00 ug/L 13.31 ug/L 6 - Cyanide Date Data 1 4/2/2014 < 2 6/4/2014 < 3 9/10/2014 < 4 12/2/2014 < 5 3/4/2015 < 6 6/3/2015 < 7 9/2/2015 < 8 12/9/2015 < 9 3/9/2016 < 10 6/8/2016 < 11 9/7/2016 < 12 12/14/2016 < 13 3/8/2017 < 14 6/14/2017 < 15 9/13/2017 < 16 12/6/2017 < 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 Cyanide BDL=1/2DL Results i 5 Std Dev. i 5 Mean i 5 C.V. i 5 n i 5 i 5 MultFactor= i 5 Max. Value i 5 Max. Fred Cw i 5 i 5 i 5 i 5 i 5 i 5 i 5 i 5 Use "PASTE SPECIAL Par14 Values" then "COPY" . Maximum data points = 58 Date 1 4/2/2014 < 2 6/4/2014 < 3 9/10/2014 < 4 12/2/2014 < 5 3/4/2015 < 6 6/3/2015 < 7 9/2/2015 < 8 12/9/2015 < 9 3/9/2016 < 10 6/8/2016 11 9/7/2016 12 12/14/2016 13 3/8/2017 < 14 6/14/2017 < 15 9/13/2017 16 12/6/2017 < 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 5.00 0.0000 16 1.00 5.0 ug/L 5.0 ug/L RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Lead BDL=1/2DL Results 5 2.5 Std Dev. 5 2.5 Mean 5 2.5 C.V. 5 2.5 n 5 2.5 6/3/2014 5 2.5 MultFactor= 5 2.5 Max. Value 5 2.5 Max. Fred Cw 5 2.5 C.V. 6 6 12/3/2014 20 20 3.4 12 12 5 5 2.5 3.3 5 2.5 n 10 10 6/3/2015 5 2.5 1.4 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par15 Use "PASTE SPECIAL Par16 Use "PASTE SPECIAL Values"then"COPY" Mercury Values" then "COPY" Molybdenum Values" then "COPY" . Maximum data . Maximum data . Maximum data points = 58 points = 58 points = 58 4.8750 1.0253 16 1.80 20.000 ug/L 36.000 ug/L 7- 4.4063 0.7855 16 1.62 11.9 ng/L 19.3 ng/L Date Data BDL=1/2DL Results 1 4/2/2014 1.1 1.1 Std Dev. 2 6/3/2014 5.5 5.5 Mean 3 9/10/2014 5.2 5.2 C.V. 4 12/3/2014 3.4 3.4 n 5 3/4/2015 3.3 3.3 n 6 6/3/2015 1.4 1.4 MultFactor= 7 9/2/2015 11.9 11.9 Max. Value 8 12/9/2015 2.3 2.3 Max. Fred Cw 9 3/9/2016 3.5 3.5 12/9/2015 10 6/8/2016 < 1 0.5 9 11 9/7/2016 9.9 9.9 12 12/13/2016 4.1 4.1 5 13 3/8/2017 < 1 0.5 10 14 6/14/2017 3.4 3.4 < 15 9/13/2017 10.1 10.1 3/8/2017 16 12/6/2017 4.4 4.4 14 17 < 10 5 18 9/13/2017 < 10 5 19 16 12/6/2017 < 10 20 17 21 18 22 19 23 24 25 21 26 22 27 23 28 24 29 30 31 26 32 27 33 28 34 29 35 36 37 31 38 32 7- 4.4063 0.7855 16 1.62 11.9 ng/L 19.3 ng/L 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 6 6/3/2015 < 10 5 MultFactor= 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Fred Cw 9 3/9/2016 < 10 5 10 6/8/2016 < 10 5 11 9/7/2016 < 10 5 12 12/14/2016 < 10 5 13 3/8/2017 < 10 5 14 6/14/2017 < 10 5 15 9/13/2017 < 10 5 16 12/6/2017 < 10 5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Par17 & Par18 Nickel REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par19 Values" then "COPY" . Maximum data points = 58 5.3125 0.2353 16 1.17 10.0 pg/L 11.7 pg/L Selenium Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 7 6 6/3/2015 < 10 5 Mult Factor = 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Fred Cw 9 3/9/2016 < 10 5 0.5 10 6/8/2016 < 10 5 13 11 9/7/2016 < 10 5 12/14/2016 12 12/14/2016 < 10 5 < 13 3/8/2017 < 10 5 1 14 6/14/2017 < 10 5 0.5 15 9/13/2017 < 10 10 19 16 12/6/2017 < 10 5 17 21 18 22 19 23 20 25 21 26 22 27 23 28 24 29 25 31 26 32 27 33 28 34 29 35 30 37 31 38 32 33 34 35 36 37 38 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par19 Values" then "COPY" . Maximum data points = 58 5.3125 0.2353 16 1.17 10.0 pg/L 11.7 pg/L Selenium 8 - Use "PASTE SPECIAL Par20 Values" then "COPY" . Maximum data points = 58 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L Silver Date Data BDL=1/2DL Results 1 4/2/2014 < 10 5 Std Dev. 2 6/4/2014 < 10 5 Mean 3 9/10/2014 < 10 5 C.V. 4 12/2/2014 < 10 5 n 5 3/4/2015 < 10 5 7 6 6/3/2015 < 10 5 Mult Factor = 7 9/2/2015 < 10 5 Max. Value 8 12/9/2015 < 10 5 Max. Fred Cw 9 3/9/2016 < 10 5 0.5 10 6/8/2016 < 10 5 13 11 9/7/2016 < 10 5 12/14/2016 12 12/14/2016 < 10 5 < 13 3/8/2017 < 10 5 1 14 6/14/2017 < 10 5 0.5 15 9/13/2017 < 10 5 19 16 12/6/2017 < 10 5 17 21 18 22 19 23 20 25 21 26 22 27 23 28 24 29 25 31 26 32 27 33 28 34 29 35 30 37 31 38 32 33 34 35 36 37 38 8 - Use "PASTE SPECIAL Par20 Values" then "COPY" . Maximum data points = 58 5.0000 0.0000 16 1.00 5.0 ug/L 5.0 ug/L Silver RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Date Data BDL=1/2DL 1 3/31/2014 < 10 5 2 4/2/2014 < 1 0.5 3 6/4/2014 < 1 0.5 4 6/10/2014 < 1 0.5 5 9/10/2014 < 1 0.5 6 12/2/2014 < 1 0.5 7 3/4/2015 < 1 0.5 8 6/3/2015 < 1 0.5 9 9/2/2015 < 1 0.5 10 12/9/2015 < 1 0.5 11 3/9/2016 < 1 0.5 12 6/8/2016 < 1 0.5 13 9/7/2016 < 1 0.5 14 12/14/2016 < 1 0.5 15 3/8/2017 < 1 0.5 16 6/14/2017 < 1 0.5 17 6/20/2017 < 1 0.5 18 9/13/2017 < 1 0.5 19 12/6/2017 < 1 0.5 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Par21 Use "PASTE SPECIAL Values" then "COPY" Zinc Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 Par22 Results Date Data Std Dev. 1.0324 Mean 0.7368 C.V. 1.4011 n 19 MultFactor= 1.85 Max. Value 5.000 ug/L Max. Fred Cw 9.250 ug/L Use "PASTE SPECIAL Par23 Date Data BDL=1/2DL Results 1 4/2/2014 51 51 Std Dev. 17.0000 1 2 6/4/2014 59 59 Mean 55.7500 2 3 9/10/2014 72 72 C.V. 0.3049 3 4 12/2/2014 55 55 n 16 4 5 3/4/2015 81 81 51.600000 pg/L 5 6 6/3/2015 37 37 MultFactor= 1.23 6 7 9/2/2015 71 71 Max. Value 81.0 ug/L 7 8 12/9/2015 49 49 Max. Fred Cw 99.6 ug/L 8 9 3/9/2016 57 57 9 10 6/8/2016 23 23 10 11 9/7/2016 63 63 11 12 12/14/2016 71 71 12 13 3/8/2017 26 26 13 14 6/14/2017 52 52 14 15 9/13/2017 48 48 15 16 12/6/2017 77 77 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 Use "PASTE SPECIAL Par23 Date Da 1 9/9/2014 2 12/8/2015 3 3/15/2016 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 9- 6/27/2018 Bromoform Values then COPY . Maximum data points = 58 Date Data BDL=1/2DL Results 9/9/2014 51.6 51.6 Std Dev. 26.4426 12/8/2015 5.8 5.8 Mean 21.0667 3/15/2016 5.8 5.8 C.V. (default) 0.6000 n 3 MultFactor= 3.00 Max. Value 51.600000 pg/L Max. Fred Cw 154.800000 pg/L Date Da 1 9/9/2014 2 12/8/2015 3 3/15/2016 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 9- 6/27/2018 MultFactor= 3.00 Max. Value 15.200000 ug/L Max. Fred Cw 45.600000 Ng/L REASONABLE POTENTIAL ANALYSIS 10- RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Use"PASTE SPECIAL Dichlorobromomethane Values" then "COPY" . Maximum data points = 58 to BDL=1/2DL Results 15.2 15.2 Std Dev. 5.8312 15.2 15.2 Mean 11.8333 5.1 5.1 C.V. (default) 0.6000 n 3 MultFactor= 3.00 Max. Value 15.200000 ug/L Max. Fred Cw 45.600000 Ng/L REASONABLE POTENTIAL ANALYSIS 10- RPA_Mayodan_NC0021873_Q 4.5 mgd_More metals, data 6/27/2018 Town of Mayodan WWTP - NC0021873 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM Qw (MGD) = 4.5000 1Q10S (cfs) = 61.34 7Q10S (cfs) = 75.00 7Q10W (cfs) = 131.00 30Q2 (cfs) = 150.00 Avg. Stream Flow, QA (cfs) = 362.00 Receiving Stream: Mayo River HUC 0301010304 DATA POINTS = 58 WWTP/WTP Class: IV IWC% @ 1Q10S = 10.21005636 IWC% @ 7Q10S = 8.508691674 IWC% @ 7Q10W = 5.055263635 1WC% @ 30Q2 = 4.443382704 IW%C @ QA = 1.890371976 Stream Class: C Outfall 001 Qw = 4.5 MGD COMBINED HARDNESS (me/L) Acute = 39.17 mg/L Chronic = 38.68 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J a Applied Chronic Acute n # Det. Max Pred Cw Allowable Cw Standa Acute (FW): 3,330.1 No RP, Predicted Max < 50% of Allowable Cw - No Arsenic C 150 FW(7Q10s) 340 ug/L Monitoring required 16 0 2.5 Chronic 1,762.9 All values less than 5 ug/L Max MDL = 5 Arsenic C 10 HH/WS(Qavg) ug/L NO DETECTS _ _ _ _ Chronic (HH): 529.0 _-------------------------- ____________________Arsenic All values less than 5 ug/L Max MDL = 5 Acute: 46.953 No RP, Predicted Max < 50% of Allowable Cw - No Cadmium NC 0.8205 FW(7Q10s) 4.7939 ug/L 16 0 0.500 Monitoring required - - ----------------------------- Chronic: 9.643 None detects, all less than 1 ug/L NO DETECTS Max MDL = 1 Acute: 156.7 Chromium VI NC 11 FW(7Q10s) 16 Itg/L 0 0 N/A Chronic: -----129.3-- --------------------------- Chromium, Total NC VgIL 20 0 2.5 Max reported value = 2.5 All values less than 5 ug/L & < Cr IV NO DETECTS Max MDL = 5 Acute: 156.57 No RP, Predicted Max < 50% of Allowable Cw - No Copper NC 11.4430 FW(7Q10s) 15.9855 ug/L 19 19 13.31 Monitoring required --------------------------------------------- Chronic: 134.49 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 215.5 No RP, Predicted Max < 50% of Allowable Cw - No Cyanide NC 5 FW(7Q10s) 22 10 ug/L 16 0 5.0 Monitoring required --------------------------------------------- Chronic: 58.8 All values less than 5 ug/L NO DETECTS Max MDL = 10 Acute: 1,223.044 No RP, Predicted Max < 50% of Allowable Cw - No Lead NC 4.7990 FW(7Q10s) 124.8735 ug/L 16 4 36.000Monitoring required Chronic: 56.401 No RP , Predicted Max >_ 50% of Allowable Cw No value > Allowable Cw apply Quarterly Monitoring Acute: NO WQS Mercury NC 12 FW(7Q10s) 0.5 ng/L 16 14 19.3 Chronic: 141.0 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Molybdenum NC 2000 HH(7Q10s) ug/L 16 0 5.0 Chronic: 23,505.4 No RP, Predicted Max < 50% of Allowable Cw - No NO DETECTS Max MDL = 10 Monitoring required RPA_ Mayodan_NC0021873_Q 4.5 mgd_More metals, rpa Page 11 of 13 6/27/2018 Town of Mayodan WWTP - Outfall 001 NCO021873 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 4.5 MGD RPA_ Mayodan_NC0021873_Q 4.5 mgd_More metals, rpa Page 12 of 13 6/27/2018 Acute (FW): 4,799.9 No RP, Predicted Max < 50% of Allowable Cw - No Nickel NC 53.8613 FW(7Q10s) 490.0688 gg/L Monitoring required 16 1 11.7 --------------------------------------------- Chronic (FW): 633.0 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw ------------------------------ Monitoring required Nickel NC 25.0000 WS(7Q10s) µg,L Chronic (WS): 293.8 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 548.5 No RP, Predicted Max < 50% of Allowable Cw - No Selenium NC 5 FW(7Q10s) 56 ug/L 16 0 5.0 Monitoring required Chronic: 58.8 All values less than 10 ug/L NO DETECTS Max MDL = 10 Acute: 6.283 Silver NC 0.06 FW(7Q10s) 0.6415 ug/L 19 0 9.250 Chronic: 0.705 All values < 1 ug/L with one < 10 ug/L NO DETECTS Max MDL = 10 Acute: 1,801.0 No RP, Predicted Max < 50% of Allowable Cw - No Zinc NC 183.4450 FW(7Q10s) 183.8859 ug/L 16 16 99.6 Monitoring required Chronic: 2,156.0 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Bromoform c 120 HH(Qavg) gg/L 3 3 154.80000 Note: n:5 9 C.V. (default) Chronic: 6347.95699 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set No value > Allowable Cw Monitoring required Acute: NO WQS Dichlorobromomethane c 27 HH(Qavg) gg/L 33 45.60000 Note: n < 9 C.V. (default) Chronic: 1428.29032 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set INo value > Allowable Cw Monitoring required RPA_ Mayodan_NC0021873_Q 4.5 mgd_More metals, rpa Page 12 of 13 6/27/2018 Date: 6/27/2018 Enter data onto "Table 1" under the Input Sheet and enter "Effluent Hardness" under the Data Sheet. In accordance with 40 CFR 122.45 (c), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). 1) Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively. 2) The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 30 mg/L is used to calculate the Translator values. 3) Pretreatment Facilities— PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations. 4) For Cadmium, Lead, Nickel, Chromium and Beryllium, if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. 5) For monitoring and compliance purposes if Total Chromium 'Y: Town of Mayodan WWTP Outfall 001 PERMIT: NCO021873 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Recelving Recewl" 9 Stream Stream Hec. Jtream NHUtJ Total Suspende0 Solids ComDinetl Hardness ComDinetl Hardness Instream Wastexater Instream EmueM Wastewater Upstream Hardness su mer 7010 1010 Flow Limn -FNetl Value- chronic Acute ConranVatlon Hartlness ConcenVatlon Averege Average(mg4) 7010(CFS) (MGD) MGD MGD (mg/L) (mg/L) (mg/L) (Chronic) (Acute) (mglL) 75.0000 1 48.3871 39.5742 4.5000 10 38.681 39.166 8.5087 10.2101 36.2580645 64.73684 Upstream Hard Avg (mg/L) = 36.25806 EFF Hard Avg (mg/L) = 64.73684 Dissolved Metals CriteriaUS EPA III Metal Criteria Tela) Metal= COMMENTS (Identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): after applying hartlness PARAMETER uaron Translators -using Default Partition Dissolved Mega+Transia.r Chronic Acute Coefficients Chronic I Acute 0.202 168.32 1.000 11.00 N/A 0.348 11.44 0.184 4.80 0.432 53.86 25 1.000 0.06 0.2881 183.44 =dissolved metal standard.5ee 15A NCAC 026.0211 for more information. = hardness -dependent dissolved metal standard. See 15A NCAC 02B.0211 for more information. = based upon measurement of total recaveable metal. See 15A NCAC 02B.0211 far mare informadon. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Toml Recoverable metal standard. The Human Health standard for Arsenic is 30 pg/L which is Total Recoverable metal standard. ACA H 39.16576 ACCH 38.68124 LO L ;I- ui w I" M M Ln 0 \\ O N O C4 O C14 M M ri N M mIt `� M 00 i C 4-1 JO �o Q N Ct N Q Q _ Q _ Q fO � N f0 11 N C m O II L N II C C C C J Q Q Q Q co C \ \ \ \ -0 -0 ?) 000 t10 00 LJ 'a C C Cl) O c 7 L � N 00 In tD ++ cc E o M z E 0" LD J C U � z Z +' v Q 0 C Ln Ln Ln � La Lp J r\ O O O i O O Ln \ \ \ \ \ W M \ \ n N \ 00 cu J W 00 r -i N LL m lD M lD Ol M LD m II II N LD m cN-i w O O m O LL CCf OJ cr E D L a cc LU 7 r.! 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OD E / a (u/ / -- m k E k § _j t 2 > § J k E © `ca k � Ex k / Cf k -3: LD L le Ln LD I- M L!i Mrl O O. N ON O C14 O r4 N M c i tL0 L L L L- M 00 eh 12 12 .2 12 12 bo OD tio bD C ❑ Lq m m II Ln Lp O II L O! c c c c II cr w J LLI a a a a m L, a- p tko L ) � L_ cr LUM cc N 00 n Ln LD ++ I= M E o `rl° CF Z E 'A 2 ¢ca U m ZkD QJ CGC G t Ln Ln Ln Ln D LO LO O O O 1� -I Q O Ln W rl Ln q 1� rl \ rl e^ J 00 U N 0-Ct ❑ W \ m CIJ n LL lD II II Ln Q7 M l0 mrq M Or 3 Ol rl N LU -I O m C LL \ tD O F- 0) E D L U N W 7 a --I Ll1 N M �' M Ln Ln Ql rl vi t rl t j Ln Ln M M rl N M O 01 4 O M 00 tt C L rl Ln N Ct M q M L!i Mrl O. \ rl M L!) M M c i N M `i Cl R M 00 eh ~ +M C ❑ Lq II Ln Lp O II L O! cr w a- p v � a LUM E o `rl° m ZkD t Ln Ln Ln Ln LO LO LO r -I 1� -I rl H rl \ rl e^ 00 U N 0-Ct ❑ \ CIJ n LL lD M lD Q7 M l0 mrq M l0 Ol rl N +-+ \ tD O F- I c ro 0 a c� NH3/TRC WLA Calculations Facility: Mayodan WWTP PermitNo. NC0021873 Prepared By: Qais Banihani Enter Design Flow (MGD): 2.5 Enter s7Q10 (cfs): 75 Enter w7Q10 cfs : 131 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 75 s7Q10 (CFS) 75 DESIGN FLOW (MGD) 2.5 DESIGN FLOW (MGD) 2.5 DESIGN FLOW (CFS) 3.875 DESIGN FLOW (CFS) 3.875 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 4.91 IWC (%) 4.91 Allowable Conc. (ug/1) 346 Allowable Conc. (mg/1) 16.1 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 131 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 2.5 (If DF >331; Monitor) DESIGN FLOW (CFS) 3.875 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 20.35 Upstream Bkgd (mg/1) 0.22 IWC (%) 2.87 Allowable Conc. (mg/1) 55.2 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/1, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Facility: Mayodan WWTP PermitNo. NC0021873 Prepared By: Qais Banihani Enter Design Flow (MGD): 3 Enter s7Q10 (cfs): 75 Enter w7Q10 cfs : 131 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 75 s7Q10 (CFS) 75 DESIGN FLOW (MGD) 3 DESIGN FLOW (MGD) 3 DESIGN FLOW (CFS) 4.65 DESIGN FLOW (CFS) 4.65 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 5.84 IWC (%) 5.84 Allowable Conc. (ug/1) 291 Allowable Conc. (mg/1) 13.6 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 131 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 3 (If DF >331; Monitor) DESIGN FLOW (CFS) 4.65 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 17.13 Upstream Bkgd (mg/1) 0.22 IWC (%) 3.43 Allowable Conc. (mg/1) 46.3 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/1, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Facility: Mayodan WWTP PermitNo. NC0021873 Prepared By: Qais Banihani Enter Design Flow (MGD): 4.5 Enter s7Q10 (cfs): 75 Enter w7Q10 cfs : 131 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 75 s7Q10 (CFS) 75 DESIGN FLOW (MGD) 4.5 DESIGN FLOW (MGD) 4.5 DESIGN FLOW (CFS) 6.975 DESIGN FLOW (CFS) 6.975 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 8.51 IWC (%) 8.51 Allowable Conc. (ug/1) 200 Allowable Conc. (mg/1) 9.4 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 131 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 4.5 (If DF >331; Monitor) DESIGN FLOW (CFS) 6.975 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 11.75 Upstream Bkgd (mg/1) 0.22 IWC (%) 5.06 Allowable Conc. (mg/1) 31.5 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/1, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni)