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NC0030210_Renewal Application_20180611
• ROY COOPER Governor MICHAEL S.REGAN Secretary Water Resources LINDA CTJLPEPPER ENVIRONMENTAL OUA.ITV Interim Director June 11, 2018 Jacqueline Jarrell, PE Charlotte Water 5100 Brookshire Blvd Charlotte, NC 28216-3371 Subject: Permit Renewal Application No. NC0030210 Mallard Creek WWTP Mecklenburg County Dear Applicant: The Water Quality Permitting Section acknowledges the June 7, 2018 receipt of your permit renewal application and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. Per G.S. 150B-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a timely manner to requests for additional information necessary to allow a complete review of the application and renewal of the permit. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https://deci.nc.gov/permits-regulations/permit-guidance/environmental-application-tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. Sincerely, _Y110/P e,,89-,3 Wren Thedford Administrative Assistant Water Quality Permitting Section ec: WQPS Laserfiche File w/application(MR0) State of North Carolina I Environmental Quality I Water Resources 1617 Mail Service Center I Raleigh,North Carolina 27699-1617 919-807-6300 Mallard Creek WRF NC0030210 Permit Renewal Application May 2018 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee FORM 2A NP FORM A A PPL. IO OVERVIEW NPDES APPLICATION OVERVIEW Form 2A has been developed in a modular format and consists of a "Basic Application Information" packet and a "Supplemental Application Information" packet. The Basic Application Information packet is divided into two parts. All applicants must complete Parts A and C. Applicants with a design flow greater than or equal to 0.1 mgd must also complete Part B. Some applicants must also complete the Supplemental Application Information packet. The following items explain which parts of Form 2A you must complete. BASIC APPLICATION INFORMATION: A. Basic Application Information for all Applicants. All applicants must complete questions Al through A.8. A treatment works that discharges effluent to surface waters of the United States must also answer questions A.9 through A.12. B. Additional Application Information for Applicants with a Design Flow z 0.1 mgd. All treatment works that have design flows greater than or equal to 0.1 million gallons per day must complete questions B.1 through B.6. C. Certification. All applicants must complete Part C(Certification). SUPPLEMENTAL APPLICATION INFORMATION: D. Expanded Effluent Testing Data. A treatment works that discharges effluent to surface waters of the United States and meets one or more of the following criteria must complete Part D(Expanded Effluent Testing Data): 1. Has a design flow rate greater than or equal to 1 mgd, 2. Is required to have a pretreatment program(or has one in place), or 3. Is otherwise required by the permitting authority to provide the information. E. Toxicity Testing Data. A treatment works that meets one or more of the following criteria must complete Part E(Toxicity Testing Data): 1. Has a design flow rate greater than or equal to 1 mgd, 2. Is required to have a pretreatment program(or has one in place), or 3. Is otherwise required by the permitting authority to submit results of toxicity testing. F. Industrial User Discharges and RCRA/CERCLA Wastes. A treatment works that accepts process wastewater from any significant industrial users(SlUs)or receives RCRA or CERCLA wastes must complete Part F(Industrial User Discharges and RCRA/CERCLA Wastes). Sills are defined as: 1. All industrial users subject to Categorical Pretreatment Standards under 40 Code of Federal Regulations(CFR)403.6 and 40 CFR Chapter I,Subchapter N(see instructions); and 2. Any other industrial user that: a. Discharges an average of 25,000 gallons per day or more of process wastewater to the treatment works(with certain exclusions);or b. Contributes a process wastestream that makes up 5 percent or more of the average dry weather hydraulic or organic capacity of the treatment plant; or c. Is designated as an SIU by the control authority. G. Combined Sewer Systems. A treatment works that has a combined sewer system must complete Part G(Combined Sewer Systems). ALL APPLICANTS MUST COMPLETE PART C (CERTIFICATION) EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 1 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee BASIC APPLICATION INFORMATION PART A. BASIC APPLICATION INFORMATION FOR ALL APPLICANTS: All treatment works must complete questions A.1 through A.8 of this Basic Application Information Packet. A.1. Facility Information. Facility Name Mallard Creek Water Reclamation Facility Mailing Address 12400 US Hwy 29 North Charlotte,NC 28262 Contact Person Henry Eudy Title Plant Supervisor Telephone Number ( 704 ) 547-0680 Facility Address 12400 US Hwy 29 North (not P.O.Box) Charlotte,NC 28262 A.2. Applicant Information. If the applicant is different from the above,provide the following: Applicant Name Charlotte Water Mailing Address 5100 Brookshire BLVD. . Charlotte,NC 28216 Contact Person Jacqueline A.Jarrell,P.E. Title Operations Chief Telephone Number ( 704 ) 336-5433 Is the applicant the owner or operator(or both)of the treatment works? X owner X operator Indicate whether correspondence regarding this permit should be directed to the facility or the applicant. 0 facility X applicant A.3. Existing Environmental Permits. Provide the permit number of any existing environmental permits that have been issued to the treatment works (include state-issued permits). NPDES NC0030210 PSD UIC Other RCRA Other W00013252-Reclaimed Water Permit A.4. Collection System Information. Provide information on municipalities and areas served by the facility. Provide the name and population of each entity and,if known,provide information on the type of collection system(combined vs.separate)and its ownership(municipal,private,etc.). Name Population Served Type of Collection System Ownership Charlotte,NC Separate Sanitary Sewer System Charlotte Water Total population served 195,951 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 2 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee A.5. Indian Country. a. Is the treatment works located in Indian Country? ❑ Yes XNo b. Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from(and eventually flows through)Indian Country? ❑ Yes XNo A.6. Flow. Indicate the design flow rate of the treatment plant(i.e.,the wastewater flow rate that the plant was built to handle). Also provide the average daily flow rate and maximum daily flow rate for each of the last three years. Each year's data must be based on a 12-month time period with the 12th month of"this year"occurring no more than three months prior to this application submittal. a. Design flow rate 12.0 mgd Two Years Aqo Last Year This Year b. Annual average daily flow rate 2016 avq-8.96 2017 avq.-9.54 1st Q 2018 avq.-9.48 c. Maximum daily flow rate 14.5 20.1 _ 12.6 A.7. Collection System. Indicate the type(s)of collection system(s)used by the treatment plant. Check all that apply. Also estimate the percent contribution(by miles)of each. X Separate sanitary sewer 100 ❑ Combined storm and sanitary sewer 0/0 A.8. Discharges and Other Disposal Methods. a. Does the treatment works discharge effluent to waters of the U.S.? X Yes 0 No If yes,list how many of each of the following types of discharge points the treatment works uses: i. Discharges of treated effluent 100% ii. Discharges of untreated or partially treated effluent iii. Combined sewer overflow points iv. Constructed emergency overflows(prior to the headworks) v. Other b. Does the treatment works discharge effluent to basins,ponds,or other surface impoundments that do not have outlets for discharge to waters of the U.S.? 0 Yes X No If yes,provide the following for each surface impoundment: Location: Annual average daily volume discharge to surface impoundment(s) mgd Is discharge 0 continuous or 0 intermittent? c. Does the treatment works land-apply treated wastewater? 0 Yes X No If yes,provide the following for each land application site: Location: Number of acres: Annual average daily volume applied to site: mgd Is land application 0 continuous or 0 intermittent? d. Does the treatment works discharge or transport treated or untreated wastewater to another treatment works? 0 Yes X No EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 3 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC003021 0 Renewal Yadkin - PeeDee If yes,describe the mean(s)by which the wastewater from the treatment works is discharged or transported to the other treatment works (e.g.,tank truck,pipe). If transport is by a party other than the applicant,provide: Transporter Name Mailing Address Contact Person Title Telephone Number ( ) For each treatment works that receives this discharge,provide the following: Name Mailing Address Contact Person Title Telephone Number ( If known,provide the NPDES permit number of the treatment works that receives this discharge Provide the average daily flow rate from the treatment works into the receiving facility. mgd e. Does the treatment works discharge or dispose of its wastewater in a manner not included in A.8.through A.8.d above(e.g.,underground percolation,well injection): ❑ Yes X No If yes,provide the following for each disposal method: Description of method(including location and size of site(s)if applicable): Annual daily volume disposed by this method: Is disposal through this method 0 continuous or 0 intermittent? EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 4 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee WASTEWATER DISCHARGES: If you answered"Yes"to question A.8.a,complete questions A.9 through A.12 once for each outfall(including bypass points)through which effluent is discharged. Do not include information on combined sewer overflows in this section. If you answered"No"to question A.8.a,go to Part B,"Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd." A.9. Description of Outfall. a. Outfall number 001 b. Location Charlotte, NC 28262 (City or town,if applicable) (Zip Code) Mecklenburg NC (County) (State) 35°19'52" 80°41'54" (Latitude) (Longitude) c. Distance from shore(if applicable) 1' ft. d. Depth below surface(if applicable) n/a ft. e. Average daily flow rate 9.28 mgd f. Does this outfall have either an intermittent or a periodic discharge? ❑ Yes X No (go to A.9.g.) If yes,provide the following information: Number f times per year discharge occurs: Average duration of each discharge: Average flow per discharge: mgd Months in which discharge occurs: g. Is outfall equipped with a diffuser? 0 Yes X No A.10. Description of Receiving Waters. a. Name of receiving water Mallard Creek b. Name of watershed(if known) Rocky River to Yadkin PeeDee Basin United States Soil Conservation Service 14-digit watershed code(if known): c. Name of State Management/River Basin(if known): Yadkin PeeDee United States Geological Survey 8-digit hydrologic cataloging unit code(if known): HUC: 03040105 Sub- basin 03-07-11 d. Critical low flow of receiving stream(if applicable) acute 0.35 cfs chronic cfs e. Total hardness of receiving stream at critical low flow(if applicable): 86 mg/I of CaCO3 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 5 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - Pee Dee A.11. Description of Treatment a. What level of treatment are provided? Check all that apply. X Primary X Secondary X Advanced 0 Other. Describe: Please see Attachment#2 b. Indicate the following removal rates(as applicable): Design BOD5 removal or Design CBOD5 removal 97 Design SS removal 97 Design P removal n/a Design N removal 40 Other c. What type of disinfection is used for the effluent from this outfall? If disinfection varies by season,please describe: UV If disinfection is by chlorination is dechlorination used for this outfall? 0 Yes 0 No Does the treatment plant have post aeration? 0 Yes X No A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum,effluent testing data must be based on at least three samples and must be no more than four and one-half years apart. Outfall number: 001 MAXIMUM DAILY VALUE AVERAGE DAILY VALUE PARAMETER ---- Value Units Value Units Number of Samples pH(Minimum) 6.5 s.u. pH(Maximum) 7.4 s.u. Flow Rate 20.1 MGD 9.28 MGD 821 Temperature(Winter) 24.0 °C 18.8 °C 264 Temperature(Summer) 27.7 °C 24.4 °C 297 *For pH please report a minimum and a maximum daily value MAXIMUM DAILY AVERAGE DAILY DISCHARGE POLLUTANT DISCHARGE ANALYTICAL ML/MDL Number of METHOD Conc. Units Conc. Units Samples CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS BIOCHEMICAL OXYGEN BOD5 DEMAND(Report one) CBOD5 9.8 mg/L 1.03 mg/L 356 SM 5210B 2.0 FECAL COLIFORM 62 CFU/100 1 CFU/100 561 SM 9222D 1.0 ml ml (MF) TOTAL SUSPENDED SOLIDS(TSS) 8.2 mg/L 1.23 mg/L 356 SM 2540D 2.5 END OF PART A. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 6 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC003021 0 Renewal Yadkin - PeeDee BASIC APPLICATION INFORMATION PART B. ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR EQUAL TO 0.1 MGD(100,000 gallons per day). All applicants with a design flow rate>_0.1 mgd must answer questions B.1 through B.6. All others go to Part C(Certification). B.1. Inflow and Infiltration. Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration. 152,000 gpd Briefly explain any steps underway or planned to minimize inflow and infiltration. Charlotte Water has been smoke testing and TVinq collection system lines to determine sources of I and I. When sources are identified,we are rehabilitating pipelines by lining the existing infrastructure, rebuilding manholes, and in some areas building relief sewer lines. Please see Attachment#3 for additional information. B.2. Topographic Map. Attach to this application a topographic map of the area extending at least one mile beyond facility property boundaries. This map must show the outline of the facility and the following information. (You may submit more than one map if one map does not show the entire area.) a. The area surrounding the treatment plant,including all unit processes. b. The major pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which treated wastewater is discharged from the treatment plant. Include outfalls from bypass piping,if applicable. c. Each well where wastewater from the treatment plant is injected underground. d. Wells,springs,other surface water bodies,and drinking water wells that are: 1)within'/mile of the property boundaries of the treatment works,and 2)listed in public record or otherwise known to the applicant. e. Any areas where the sewage sludge produced by the treatment works is stored,treated,or disposed. f. If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act(RCRA)by truck,rail, or special pipe,show on the map where the hazardous waste enters the treatment works and where it is treated,stored,and/or disposed. B.3. Process Flow Diagram or Schematic. Provide a diagram showing the processes of the treatment plant,including all bypass piping and all backup power sources or redunancy in the system. Also provide a water balance showing all treatment units,including disinfection(e.g., chlorination and dechlorination). The water balance must show daily average flow rates at influent and discharge points and approximate daily flow rates between treatment units. Include a brief narrative description of the diagram. Please see Attachments#2 and#5 B.4. Operation/Maintenance Performed by Contractor(s). Are any operational or maintenance aspects(related to wastewater treatment and effluent quality)of the treatment works the responsibility of a contractor? ❑ Yes X No If yes,list the name,address,telephone number,and status of each contractor and describe the contractor's responsibilities(attach additional pages if necessary). Name: Mailing Address: Telephone Number ( ) Responsibilities of Contractor B.5. Scheduled improvements and Schedules of Implementation. Provide information on any uncompleted implementation schedule or uncompleted plans for improvements that will affect the wastewater treatment,effluent quality,or design capacity of the treatment works. If the treatment works has several different implementation schedules or is planning several improvements,submit separate responses to question B.5 for each. (If none,go to question B.6.) a. List the outfall number(assigned in question A.9)for each outfall that is covered by this implementation schedule. 001 b. Indicate whether the planned improvements or implementation schedule are required by local,State,or Federal agencies. ❑ Yes X No EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 7 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee c. If the answer to B.5.b is"Yes,"briefly describe,including new maximum daily inflow rate(if applicable). d. Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below,as applicable. For improvements planned independently of local,State,or Federal agencies,indicate planned or actual completion dates,as applicable. Indicate dates as accurately as possible. Schedule Actual Completion Implementation Stage MM/DD/YYYY MM/DD/YYYY -Begin Construction / / / / -End Construction / / / / -Begin Discharge / / / / -Attain Operational Level / / / I e. Have appropriate permits/clearances concerning other Federal/State requirements been obtained? X Yes 0 No Describe briefly: Please see Attachment#6 B.6. EFFLUENT TESTING DATA(GREATER THAN 0.1 MGD ONLY). Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information on combine sewer overflows in this section. All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum effluent testing data must be based on at least three pollutant scans and must be no more than four and on-half years old. Outfall Number: 001 MAXIMUM DAILY AVERAGE DAILY DISCHARGE DISCHARGE ANALYTICAL POLLUTANT METHOD ML/MDL Conc. Units Conc. Units Number of Samples CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS AMMONIA(as N) 1.9 mg/L 0.03 mg/L 356 SM 4500-NH3-H-97 0.1 CHLORINE(TOTAL 0 mg/L 0 mg/L 4 SM 4500-CL-G-00 10/15 RESIDUAL,TRC) DISSOLVED OXYGEN 9.9 mg/L 8.53 mg/L 561 SM 4500-OG-01 0.1 TOTAL KJELDAHL 1.6 mg/L 0.786 mg/L 28 EPA 351.2-93 0.25 NITROGEN(TKN) NITRATE PLUS NITRITE 21 mg/L 16.2 mg/L 30 EPA 353.2—93 0.75 NITROGEN OIL and GREASE 0 mg/L 0 mg/L 29 EPA 1664 B 5.0 PHOSPHORUS(Total) 4.7 mg/L 3.61 mg/L 29 EPA 4500-H-99 0.1 TOTAL DISSOLVED SOLIDS 320 mg/L 289 mg/L 4 SM 2540 C-97 25 (TDS) OTHER END OF PART B. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 8 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC003021 0 Renewal Yadkin - PeeDee BASIC APPLICATION INFORMATION PART C. CERTIFICATION All applicants must complete the Certification Section. Refer to instructions to determine who is an officer for the purposes of this certification. All applicants must complete all applicable sections of Form 2A,as explained in the Application Overview. Indicate below which parts of Form 2A you have completed and are submitting. By signing this certification statement,applicants confirm that they have reviewed Form 2A and have completed all sections that apply to the facility for which this application is submitted. Indicate which parts of Form 2A you have completed and are submitting: X Basic Application Information packet Supplemental Application Information packet: X Part D(Expanded Effluent Testing Data) X Part E(Toxicity Testing: Biomonitoring Data) X Part F(Industrial User Discharges and RCRA/CERCLA Wastes) 0 Part G(Combined Sewer Systems) ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION. I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information,the information is,to the best of my knowledge and belief,true, accurate,and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. Name and official title Jacqueline A. Jarrell, Operations Chief Signature Telephone number ( 704) 336-5433 Date signed Upon request of the permitting authority,you must submit any other information necessary to assure wastewater treatment practices at the treatment works or identify appropriate permitting requirements. SEND COMPLETED FORMS TO: NCDENR/ DWQ Attn: NPDES Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 9 of 22 ' FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC003021 0 Renewal Yadkin - PeeDee SUPPLEMENTAL APPLICATION INFORMATION PART D. EXPANDED EFFLUENT TESTING DATA Refer to the directions on the cover page to determine whether this section applies to the treatment works. Effluent Testing: 1.0 mgd and Pretreatment Works. If the treatment works has a design flow greater than or equal to 1.0 mgd or it has(or is required to have)a pretreatment program,or is otherwise required by the permitting authority to provide the data,then provide effluent testing data for the following pollutants. Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall through which effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected through analyses conducted using 40 CFR Part 136 methods. In addition,these data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. Indicate in the blank rows provided below any data you may have on pollutants not specifically listed in this form. At a minimum,effluent testing data must be based on at least three pollutant scans and must be no more than four and one-half years old. Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE ANALYTICAL ML/MDL METHOD POLLUTANT Number Conc. Unit Mass Units Conc Units Mass Units of s Samples METALS(TOTAL RECOVERABLE),CYANIDE,PHENOLS,AND HARDNESS. ANTIMONY 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 200.8 5.0 ARSENIC 0 ug/L 0 #/day 0 ug/L 0 #/day 123 EPA 200.8 5.0 BERYLLIUM 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 200.8 2.0/5.0 CADMIUM 0 ug/L 0 #/day 0 ug/L 0 #/day 123 EPA 200.8 1.0 CHROMIUM 0 ug/L 0 #/day 0 ug/L 0 #/day 123 EPA 200.8 5.0 COPPER 8.8 ug/L 0.681 #/day 2.71 ug/L 0.209 #/day 123 EPA 200.8 2.0 LEAD 0 ug/L 0 #/day 0 ug/L 0 #/day 123 EPA 200.8 5.0 MERCURY 0.002 ug/L 0.00015 #/day 0.00063 ug/L 0.000048 #/day 29 EPA 1631 E 0.001 NICKEL 2.8 ug/L 0.216 #/day 0.95 ug/L 0.073 #Iday 123 EPA 200.8 2.0 SELENIUM 0 ug/L 0 #/day 0 ug/L 0 #/day 123 EPA 200.8 5.0 SILVER 0 ug/L 0 #/day 0 ug/L 0 #/day 123 EPA 200.8 5.0 THALLIUM 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 200.8 1.0/5.0 ZINC 53 ug/L 4.10 #/day 38 ug/L 2.94 #/day 123 EPA 200.8 10 CYANIDE 0 ug/L 0 #/day 0 ug/L 0 #/day 64 HACH 10-204- 10 00-1-x TOTAL PHENOLIC 0.039 mg/L 3.01 #/day 0.009 mg/L 0.696 #/day 4 EPA 420.2 0.005/0.0 COMPOUNDS 5 SM 2340B or HARDNESS(as CaCO3) 150 mg/L 11,609 #/day 125 mg/L 9,674 #/day 28 5.0&1.0 EPA 200.7 Use this space(or a separate sheet)to provide information on other metals requested by the permit writer EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 10 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL ML/MDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples VOLATILE ORGANIC COMPOUNDS ACROLEIN 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 100 ACRYLONITRILE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 100 BENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 BROMOFORM 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 CARBON TETRACHLORIDE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 CHLOROBENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 AODIBROMO- METHANE 0 ug/L 0 #/day 0 ug/L 0 #lday 4 EPA 624 5 METH CHLOROETHANE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 10 2-CHLOROETHYLVINYL ETHER 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 10 CHLOROFORM 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 ICHLOROBROMO- METHANE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 M 1,1-DICHLOROETHANE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 1,2-DICHLOROETHANE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 ETYS-I,2-DICHLORO- ETHHYLENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 1 HYLENE - ETTHYLENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 1,2-DICHLOROPROPANE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 YL PROPYLENEENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 PRO ETHYLBENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 METHYL BROMIDE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 10 METHYL CHLORIDE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 10 METHYLENE CHLORIDE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 TETRA- CHLOROETHANE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 CHLOR TETRACHLORO- ETHYLENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 TOLUENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 11 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL ML/MDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples 1,1,1- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 TRICHLOROETHANE 1'1'2 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 TRICHLOROETHANE TRICHLOROETHYLENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 5 VINYL CHLORIDE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 624 10 Use this space(or a separate sheet)to provide information on other volatile organic compounds requested by the permit writer ACID-EXTRACTABLE COMPOUNDS P-CHLORO-M-CRESOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 2-CHLOROPHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 2,4-DICHLOROPHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 2,4-DIMETHYLPHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 4,6-DINITRO-O-CRESOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 20 2,4-DINITROPHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 50 2-NITROPHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 4-NITROPHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PENTACHLOROPHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 20 PHENOL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 2,4,6- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 TRICHLOROPHENOL Use this space(or a separate sheet)to provide information on other acid-extractable compounds requested by the permit writer BASE-NEUTRAL COMPOUNDS ACENAPHTHENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 ACENAPHTHYLENE 0 ug/L 0 #Ida 0 ug/L 0 #Ida 4 EPA 625 10 9 Y 9 Y ANTHRACENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 BENZIDINE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 50 BENZO(A)ANTHRACENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 BENZO(A)PYRENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 12 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE ' POLLUTANT Number ANALYTICAL ML/MDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples 3,4 BENZO- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 FLUORANTHENE BENZO(GHI)PERYLENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 BENZO(K) 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 FLUORANTHENE BIS(2-CHLOROETHOXY) 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 METHANE BIS(z-CHLOROETHYL)- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 ETHER BIS(z-CHLOROISO- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PROPYL)ETHER BIS(2-ETHYLHEXYL) 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PHTHALATE 4-BROMOPHENYL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PHENYL ETHER BUTYL BENZYL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PHTHALATE 2-CHLORO- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 NAPHTHALENE 4-CHLORPHENYL 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PHENYL ETHER CHRYSENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 DI-N-BUTYL PHTHALATE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 DI-N-OCTYL PHTHALATE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 DIBENZO(A,H) 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 ANTHRACENE 1,2-DICHLOROBENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 1,3-DICHLOROBENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 1,4-DICHLOROBENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 3,3-DICHLORO- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 BENZIDINE DIETHYL PHTHALATE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 DIMETHYL PHTHALATE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 2,4-DINITROTOLUENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 2,6-DINITROTOLUENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 1,2-DIPHENYL- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 HYDRAZINE I EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 13 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee Outfall number 001 (Complete once for each outfall discharging effluent to waters of the United States.) i MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL ML/MDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples I FLUORANTHENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 FLUORENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 HEXACHLOROBENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 HExA - 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 BUTADIENE HEXACHLOROCYCLO- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PENTADIENE HEXACHLOROETHANE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 INDENO(1,2,3-CD) 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PYRENE ISOPHORONE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 NAPHTHALENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 NITROBENZENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 N-NITROSODI-N- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PROPYLAMINE N-NITROSODI- 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 METHYLAMINE N-NITR0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PHENYLAMINE PHENANTHRENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 PYRENE 0 ug/L 0 #/day 0 ug/L 0 #/day 4 EPA 625 10 1,2,4- 0 ug/L 0 #/day0 ug/L 0 #/da 4 EPA 625 10 TRICHLOROBENZENE 9 9 Y Use this space(or a separate sheet)to provide information on other base-neutral compounds requested by the permit writer , i Use this space(or a separate sheet)to provide information on other pollutants(e.g.,pesticides)requested by the permit writer END OF PART D. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. rJge 14 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin - PeeDee SUPPLEMENTAL APPLICATION INFORMATION PART E. TOXICITY TESTING DATA POTWs meeting one or more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the facility's discharge points: 1)POTWs with a design flow rate greater than or equal to 1.0 mgd;2)POTWs with a pretreatment program(or those that are required to have one under 40 CFR Part 403);or 3)POTWs required by the permitting authority to submit data for these parameters. • At a minimum,these results must include quarterly testing for a 12-month period within the past 1 year using multiple species(minimum of two species),or the results from four tests performed at least annually in the four and one-half years prior to the application,provided the results show no appreciable toxicity,and testing for acute and/or chronic toxicity,depending on the range of receiving water dilution. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. • In addition,submit the results of any other whole effluent toxicity tests from the past four and one-half years. If a whole effluent toxicity test conducted during the past four and one-half years revealed toxicity,provide any information on the cause of the toxicity or any results of a toxicity reduction evaluation,if one was conducted. • If you have already submitted any of the information requested in Part E,you need not submit it again. Rather,provide the information requested in question E.4 for previously submitted information. If EPA methods were not used,report the reasons for using alternate methods. If test summaries are available that contain all of the information requested below,they may be submitted in place of Part E. If no biomonitoring data is required,do not complete Part E. Refer to the Application Overview for directions on which other sections of the form to complete. E.7. Required Tests. Indicate the number of whole effluent toxicity tests conducted in the past four and one-half years. x chronic See Attachment#8 for all second species(Fat Head Minnow)Toxicity test data collected since Jan 1,2014,the effective date of our current permit. E.2. Individual Test Data. Complete the following chart for each whole effluent toxicity test conducted in the last four and one-half years. Allow one column per test(where each species constitutes a test). Copy this page if more than three tests are being reported. Test number: Test number: Test number: a. Test information. Test Species&test method number Age at initiation of test Outfall number Dates sample collected Date test started Duration b. Give toxicity test methods followed. Manual title Edition number and year of publication Page number(s) c. Give the sample collection method(s)used. For multiple grab samples,indicate the number of grab samples used. 24-Hour composite Grab d. Indicate where the sample was taken in relation to disinfection. (Check all that apply for each. Before disinfection After disinfection EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 15 of 22 Attachment # 1 Mallard Creek WRF-Receiving Stream Hardness Calculation MCA- Upstream of Mallard MCB- Downstream of Mallard 1/14/2016 75 1/14/2016 100 2/18/2016 70 2/18/2016 74 3/14/2016 98 3/14/2016 100 4/11/2016 77 4/11/2016 110 5/10/2016 79 5/10/2016 110 6/13/2016 77 6/13/2016 110 7/11/2016 56 7/11/2016 110 8/15/2016 86 8/15/2016 120 9/19/2016 90 9/19/2016 100 10/10/2016 58 10/10/2016 58 11/21/2016 100 11/21/2016 130 12/21/2016 84 12/21/2016 120 1/18/2017 83 1/18/2017 93 2/14/2017 82 2/14/2017 110 3/16/2017 66 3/16/2017 98 4/11/2017 77 4/11/2017 100 5/17/2017 77 5/17/2017 100 6/14/2017 29 6/14/2017 39 1 7/18/2017 67 7/18/2017 87 8/22/2017 60 8/22/2017 99 9/11/2017 64 9/11/2017 100 10/18/2017 99 10/18/2017 100 11/15/2017 63 11/15/2017 110 12/12/2017 64 12/12/2017 94 1/16/2018 76 1/16/2018 100 2/14/2018 69 2/14/2018 95 3/19/2018 38 3/19/2018 98 Average: 73 99 Count: 27 27 Receiving Stream Hardness: 86 Attachment #2 Charlotte Water Mallard Creek WRF NPDES# NC0030210 Process Flow Description Attachment#3— Description of Treatment—Additional Information OUTFALL NUMBER: 001 A.11.a Description of Treatment Treatment consists of coarse and fine mechanical bar screens; grit removal; day tanks; storm flow equalization; five primary clarifiers; three trains in parallel of activated sludge treatment; four final clarifiers; effluent traveling bridge filters; ultraviolet disinfection; reuse distribution; sludge thickening; anaerobic digesters; and sludge dewatering. B.3. Process Flow Diagram or Schematic The attached flow schematic SC-1 (Attachment 2) shows the processes of the treatment facility along with bypasses. The plant is currently permitted to treat 12.0 MGD of wastewater. Preliminary Treatment: Wastewater enters the plant through a 36-inch gravity sewer line to enter the headworks and influent pumping station. The flow entering the headworks flows through two mechanical screens where the screenings are compacted and conveyed to a dumpster. Flow from the screens is sent to two vortex grit removal basins of 30 MGD capacity. Primary Treatment: Following preliminary treatment, the wastewater splits between two cells of the flow equalization day tanks. From here, it is pumped to the distribution boxes (DB), DB-1, DB-1A, and DB-2A and is distributed to the five existing primary clarifiers (PC-1 through PC-5). After primary treatment the flow from all of the operating clarifiers is collected and discharged into DB-5 where it is combined with the collected RAS flow from all three treatment trains and then is distributed to the aeration basins. Secondary Treatment: The combined flow is combined with RAS and split equally between biological treatment trains 1, 2 and 3. It goes through anoxic zone and aeration zone with internal recycle. The activated sludge process is carried out in a series of rectangular aeration basins and, in trains 1 and 2, is followed by additional round aeration basins. Following the aeration basin, flow from the round oxic basins of trains 1 and 2 are combined in DB-9 and split to final clarifiers (FC) FC-1, FC-2 and FC-5. Flow from train 3 aeration basin is sent to FC-3 at DB-18. A portion of the flow at DB- 18 can be directed to DB-9 to mix with the flows from trains 1 and 2 and feed to FC-1, FC-2 and FC-5. This portion is determined by a modulating pinch valve that calculates an input percentage to divert. Tertiary Treatment: Combined secondary effluent from all the final clarifiers is sent to filter distribution structure (FDS) FDS-1 and FDS-2 for filtration. Filtered effluent is sent for UV disinfection and re-aeration structure where aeration takes place. The effluent is discharged through a 42" line into Mallard Creek. Solids Processing and Biosolids Management Plan at Mallard Creek WRF Mallard Creek WRF is currently operating one 1.0 MG and two .48MG primary digesters with an average detention time of 40-50 days. The average total solids of raw sludge to the primary digesters is 3.0-4.0%. Average sludge flow to the primary digesters is between 50-60k gallons/day. Mallard is currently operating one secondary digester with a volume of 480k gallons. The average total percent solids of digested sludge at Mallard is 1.5%. For thickening and dewatering purposes, Mallard uses three Humboldt/Bird and one GEA/Westfalia centrifuges—two for thickening and two for dewatering. Dewatered solids are belt conveyed out of the dewatering building into a 24 cu. yard dump truck and taken to a cover storage pad onsite where they are stored in batches and tested. The average percent solids of Mallard's cake is 20%. All biosolids produced at Mallard Creek WRF are Class B biosolids and they are land applied in both North and South Carolina per our contract with Synagro provided that they pass all required testing and are conforming solids according to 40 CFR Part 503. All non-conforming solids are hauled by Synagro and landfilled. Attachment #3 Mallard Basin Inflow and Infiltration (I&I) Reduction Practices Charlotte Water (CLTWater) has maintained an established evaluation and rehabilitation program since the early 1990's. The purpose of this program is to restore and preserve hydraulic capacity, structural integrity, and to reduce corrective maintenance costs by addressing issues that cause SSOs. This includes maintaining and implementing an on-going I/I reduction plan. Multiple construction contracts are continually in place to address these issues. Through comprehensive SSES efforts, including manhole inspections, smoke testing, CCTV, flow monitoring, etc., areas are identified for rehabilitation and work orders assigned to a contractor. The work may include manhole rehabilitation, point repairs, pipe lining and pipe replacement. Since July 2003, CLTWater's Rehabilitation Team has inspected in excess of 4,700 manholes, smoke tested at least 137,000 ft. of pipe, and performed CCTV inspection on more than 15,600 ft. of pipe, resulting in the following 670 manholes rehabbed/repaired, 750 inflow dishes installed and 3,150 ft. of pipe rehabbed/replaced throughout the collection system. This does not include similar work performed by CLTWater's Field Operation Division. CLTWater also implemented a chemical root control program in March 2005 and we continue to maintain and expand that program. CLTWater uses flow monitoring extensively to support engineering analyses, to prioritize sewer improvements, and to evaluate capacity issues and I/I loadings in the major trunk lines in the system. CLTWater currently has 52 permanent flow meters installed throughout the service area (4 permanent meters in the Mallard Creek basin) and utilizes temporary flow metering on an as-needed basis. Attachment #4 t .` .' MallardParcel Wastewater Mains g '1„ ri=l Mallard WWTP One Mile Radius ForceMain `° '., •• Well / DrinkingWater Gravity p.,:..,:-.,!..: • Biosolids Storage LowPressure • II" Sludge .- Streams •, .. _..... .Alli . I . .,\ • 1. . . t ",.452-... At- iiiii*, .,,,t.., ..74 t „ ,.. • V Y • • .. e i � r • o .r `C> " ~ • y r ` Storage , '' o y Iii a i CI) ? • a r -:.,. . . 't +.S .• µ i- 4-. i'?.. ii" -- t.tt; '''--------.:2, i) • ' / • Y :,•-4 ��. yam., 1 .A, 41 is, it . 7..,_.: , L. .. litt.,, :: , : 141Nor- i. . • 2•1'�RL..T B'rlaY 4/ - �Y ` i rfS Date: 5/31/2018 N Map Number: 1 Project: Mallard Creek wwTP CHARLOTTE WATER CHARLOTTE Scalel inch=1,786 feet .1A74' fA4• One Mile Radius ENGINEERING DIVISI®N W(6T E R .. , E charbne Water geographic data and other records are provided A-1 •��%• br general Inb,mation puryoses only.WMk Chadolte Water 5100 BROOKSHIRE BLVD Created By: akeseveryenorttownfm the accuraryolbb�ation,adoes CHARLO1 1E,NC 28216 not warrant nor guarantee Information provided Is accurate,current sclonfZrco pkle.Chan°.Waterassumes oresponsbainfor the Page 1 of 1 s consequences of mapproprale uses or neshlerprelatbns of released data. - Mallard Parcel Wastewater Mains � E. Ca6 •�• Mallard WW1? Two Mile Radius ForceMain �� ��Oc,F d,�4s • Well / Drinking Water Gravity ���64 Co • Biosolids Storage LowPressure ~9 Sludge `6►i t. �► • • • Streams iwa cT -T • . ��p c N � tl',\'.: -- .- Alli s Lis , ■ '' ` � � Biosolids ,. . / • 0 1 Storage \ • 03 1 4 ' "'tai : �;' N /y L a • o' • (.01 — . k -• r • °'o =• 9• \11.42, V •c){? . .1 Z!,1.rif 464 •vsy.... ‘'Po• (yr_41... .;.,; _- fere �' v ��' t North �I_i .•kls �a y. Date: 5/31/2018 N Map Number: 1 Project: Mallard Creek\NWTP CHARLOTTE WATER CHARLOTTE Scale:1 inch=3,573 feet '/�,� Two Mile Radius ENGINEERING DIVISION W6 T E R W��/ I cnarone waer veo9ravnip tlata ane Omar re nma a.a promaetl 5100 BROOKSHIRE BLVD �_� Created B br pereol Inbimation puryocea only.Whlk Chatlotte Waler y: makes every e o to onfim t e a« aty of nb matron,A Ecea CHARLOTTE,NC 28216 nat vro rtaM rer puararNee inlormaGon pmvkled is a«urate,current +' ompkk.CM1atlotte W4tar aceumes no reaponsbJiry for the Page 1 of 1 sclontz C leased cesol lnapproprute uses or misinterpretatkna of �J , eleautl tlaO. Attachment #5 I • GENERAL NOTES: 1. PROCESS SCHEMATIC PROVIDED FOR REFERENCE ONLY.NOT ALL EXISTING OR NEW VALVES.PIPING,EQUIPMENT OR INSTRUMENTS ARE SHOWN . /. —_.\ ------- / \ /- '-�\ • FUTURE —..— -J FUTURE I RIFER PRNARY I — FUTURE AERATION I I FINAL No.B • I BASIN No.42 CLARIFIER /' I I-..—1 F1 \ No.4 r \\ '^i?. Dg2A , �r—-- �. I-----1FUTURE AERATION ~, , Ds-is �/I \_.- '' RASIWAS ® I � I BASN N0.4.1 Ir /' PTMPING r.--, STATION No.2 RRANiY \\ Tf I-1 I CLARIFIER DB-17IhI+ 'm" No.4 I — AERATION / _ �`_ DB-19 `L, I BASIN No.3.2 I \ PRIMARY ) AERATION / �\ DB-1 ` DB-2 I CLARIFIER L BASIN Na 3.1 FINAL No.S \ X. ,. ""L" CLARE \\ �g-s \- ) I 1 --_— Na 3 —� yi J �/f 18'RAS) DB-18 FLOW SCUM PUMPS `C / CONTROL / \ STRUCTURE ` 30'SE PRNIARY MH-51 , CLARIFIER S 8• MH-57• No.3 FINAL ! id CLARI SIER - . 12 RAS TO 3'SPD s `\ a _ram ( 312 PE ( 38*SI MH S4 �O MH-56D(13 (24.RAS E- DB-10 !a • MHS6 \` RAE ` AH-3 �\ 30'ML �PRIMARY • \ I 110=11 (\JIMH-1 / ��MH,2 ` MHS CLFINAL ARIFIER 1 N0.2 \ ` AERATION ‘�J ON \J^\ No.2 ( MH-52 DBS MH33 \� N 2 M \\\ --1 BAs ; // ....../Ak • 1 1 N0.22 ',I / 36'PE O BAS No.1.1 I _.p I DB-15 / AERATION I I iv // s DB-7 I Ni i BASIN No.21V DB-4 D&12 $1e ) DBS • � N. ) 1-7):—\3... J —CO I-40 � OJ V ' MH-50 MH-58 ( ` A/) 411110 V _ AERATION \ AllAERATION BASIN _ p&g BASN y/ l ... No.1.3 O70C RECYCLE Y ANOXIC PUMPING STATION OXIC RECYCLE No.2.3 CLARIFIER PRIMARY No.1 BASIN XI 1.1 NO.1 I I ANOXIC PUMPING STATION NoPUMPING 1, CLARIFIER 1 M11-36_ , BASIN Na 21 N0.2 STATION No.1/ No.1 ) I • MN33 II 24"OR / �� rad73 I'l1 , 1 M 0X1C RECYCLE ie.- I I PUMPING STATION I ..- D&11 IA=' / TO FILTER DISTRIBUTION STRUCTURES No.1 3 2 \\—( 18'OR) / D&14 ( 16'OR (— OXIC RECYCLE PUMPING —__ I STATION NO.2A Dm, DB-13 77� DESIGNED 9 —— —' OTD -'' //� I �rw CMU MALLARD CREEK WATER RECLAMATION FACILITY VERIFY SCALES B7��u DRAWN 5 c• • JGK "_ "f�''- ` _ �c"�/ V"` T FINAL CLARIFIER AND RELATED IMPROVEMENTS oBAR IS ONE�"wNa DRAWING NO. 7 tlEGI® p �' 033586 9115 HARRIS CORNERS PARKWAY.SURE 440 'llll OTTEsw GENERAL 0®1" 00-(�7-0.9 1 - E� w CHARLOTTE,NC 28269 .■1 '+eal PHONE:(704)598-0918 FAX: DATE DATE #� (7o4)�s e876 � PROCESS SCHEMATIC IF THIS SHONE MCNON SHEET No. THIS 'FSHF)_TT,AQft/ST CT• NO:8187810 DESCRIPTION 11/2010 IZ-22_�� LICENSE No.62119 SACCORDINGLY 9 OF 103 FILENAME 6167810-00.6-0911og PLOT TIME: STIMES • ' ' I i Z Ifs•PI 1,1100.11/ PRIMARY CH gisitFIUiim111oN4I/( IUTURE 7 FUTURE \ SLUDGE g' ar FINAL AIMPUMPING CLARIFIER 1 I CLARIFR STRTION uNO. ......,:x\/ I RPNS0NR2S IENO. 2 FUTURE 1 \ / PUMPING N,. 6 / AERATION BASIN STATION FT]4.2 11 FIERA UOTNUREBRS IN I I CEO 1411WEI ,.. ,rj.3,4(---:;.......7 CLPARIFFIEYR CEP .C132:0 I 6 . ,...., 2672.1.1.16 ..0 4. 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I CELL NO. 2 11 4E20 L-- DB NO. 13 tf.III i an) . 42.10,6, At6.-if VI,6/ 110 IR 611640010,01 I °-'.`:':::;T m TO INFLUENT PUMPING STATIONs Ilk/10.03 112.SE 16.0/11.01 . CHL OR INF "":---€2> .. ! EM-124 FILTER FILTER DISTRIBUTION DISTRIBUTION Ewa 11.6 16.500,1100 1.01 t... Ion 66 10011.1 STRUCTURE STRUCTURE PRRSHRLL .1 C:::> FLUMES A NO. 1 . aZIZIa NO. P (25 MGD-----",...) ()() 1 CAP. EACH) EFFLUENT 402 <E3> GRIT •-• 111r• __ IC'" € i,.. 1,)(--) FILTERS . • e3r 3 o 0 0 i 110 REMOVAL BAS INS FLOW 0 ak 1.01,1 1,...,„...,...11......1 lar a mart., =:} / \ (30 MOD CAP. EACH) LEGENQ EQUALIZATION 'ZED • .-- I 6000 I ----J Lzw..7... ----....1 Lzz7F I CIA BASIN (=, LINE SIZE--\ r SERVICE ----- ===== 0 o il NS 16.11,20.251 ,.. ... 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UV ,.;• - MRS TAKEN FROM PREVIOUS CONSTRUCTION DRAWINGS, '11111,),..4,,,,....._ RASP-% RAS PUMP / IS FOR REFERENCE ONLY, AND SHALL BE FIELD VERIFIED. 112.it 16.0116.01 .. .1. , ,., ,,ED, .170, .1,131, ---Fam.010N BOLD (DARK) DELINEATION IS NEW WORK OR LOCATION OF niru. SCUM-S SCUM PUMPEXISTING CONSTRUCTION TO BE MODIFIED UNDER THIS filigiiir' ,,,,.. :,:......, SG-% SLUICE GATE ' R,EU,.VisEORI RS TI NFDEN sT TI ..-''\ (I ' , :RiT.,..-- ,,,, ,„ \ - ji UV .\ \ i 2NUCTRUNRDE 117,Avg P' • CONTRACT UNLESS OTHERWISE NOTED. RECORD DRAWING INFLUENT PUMPING STATION SLO-X SLIDE GATE ---'6.4321)(o il,(Vowg 0144RE/)ultErjpgD TO REFLECT WASP-% MRS PUMP 3,11.10-6.1(01.10002 00111116.1 I "" I UN 103..t .. .0 :REEDRucT 60 0 BY a ENGINEER DATE MA""" .11.42..ct, :::ReEASSEENDTATIVE I r A . 16.0, O. '..""." .....NEW UV DISINFECTION' AND RE-AERATION STRUCTURE CHARLOTTE-MECKLENBURG UTILITIES !aTGHE::!!NE!! UPON INFORMRTION AS MAT BE PROVIDED BY THE CONTRACTOR RND CONSTRUCTION OBSERVATION MU = .4411'111.1..... MALLARD CREEK WATER RECLAMATION FACILITY THIS DOCUMENT I fORIGINALLY ISSUED S C-1. , DESIGNED RNB PROJECT ND. EXPANSION TO 12 MGD RNO SERLED BY DETAILED- ALC.MOO trprO, BLACK&VEATCH- DRVID 06. PRRKER PROFESSIONAL ENGINEER, 1 N.C. REGISTRATION CHECKED APPROVED RED 5504 Cliff Cameron Drive Sulfin 164 . Charlotte, North Corollna 259252 LIQUIDS SCHEMATIC NO. 195IG ON 02/19/59 SHEET i 11006 REVISIONS AND RECORD SF TASTE an. RI YE APP DATE- ' 28269 - 1 OF 1 ' 1 Attachment #6 Filter, UV and Clarifier Improvements The purpose of this project is to provide updated and more reliable equipment for the filtration of final clarifier effluent and for UV disinfection of plant discharge flow. Additionally with this project, improvements will be made to FC-1, FC-2 and FC-3. The existing traveling bridge sand filters will be replaced with rotating disc filters with a total peak flow capacity of 32mgd. These filters will be placed in the footprint of the existing filters with modifications to the flow routing. Along with the filters the existing UV disinfection system will be replaced with an updated system also capable of flows of 32mgd. The UV system will be moved into the footprint previously used by the existing filters with flow modifications. Along with this project the interior metal structure and operating parts of FC-1, FC-2 and FC-3 will be replaced and upgraded with stainless steel structure and mechanisms to protect against corrosion and updates will be made to the drive and scum collection systems. Notice to Proceed Date July 2019 Final Completion Date March 2021 Operational Date March 2021 Generator and Power Distribution Improvements The purpose of this project is to improve reliability of power and backup generator feed to the Mallard Creek plant. A new generator building will be constructed with two 3000kW generators and related switchgear along with a new electrical substation. The new generators will replace the single active backup generator currently onsite and the new electrical substation will consolidate the existing power distribution system and make it more reliable. Notice to Proceed Date November 2018 Final Completion Date June 2020 Operational Date June 2020 Expansion Project The purpose of this project is to expand the Mallard Creek plant in order to stay ahead of increased flow projections in the service basin of the treatment plant. This project is still in its early stages but may include the expansion or replacement of the influent lift station, screening removal, primary clarifiers, aeration basins, blowers, final clarifiers and equalization basin. Notice to Proceed Date Undetermined Final Completion Date Undetermined Operational Date Undetermined Attachment #7 - - 1 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC00302 10 Month August Outfall 001 Year 2014 Facility Name Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of EFFLUENT Sampling:8/6/2014, low level mercury 8/5]14 Phone (7041 547-0680 Analytical Laboratory: CMUD Environmental Lab NC 192,Prism Lab NC 402,Access Lab NC 618 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Ammonia(as N) Composite SM 4500-NH3-H-97 0.1 Less than mg/L 2 Dissolved oxygen Grab SM4500-O-G-01 1.0 7.9 mg/L 1 Nitrate/Nitrite Composite EPA 353.2-93 1.0 18 mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2-93 0.25 0.48 mg/L 1 Total Phosphorus Composite SM 4500P-G-99 0.1 4.2 mg/L 1 Total dissolved solids Composite SM 2540C-97 25 314 mg/L 1 Hardness Composite SM 2340B-97 0.5 130 mg/L 1 Chlorine(total residual,TRC) Grab SM 4500C1-G-00 10 Less than ug/L 1 Oil and grease Grab EPA 1664B 5 Less than mg/L 1 Metals (total recoverable), cyanide and total phenols Antimony Composite 200.8 5.0 Less than ug/L 1 Arsenic Composite 200.8 5.0 Less than ug/L 2 Beryllium Composite 200.8 5.0 Less than ug/L 1 Cadmium Composite 200.8 1.0 Less than ug/L 2 Chromium Composite 200.8 5.0 Less than ug/L 2 Copper Composite 200.8 2.0 6.1 ug/L 2 Lead Composite 200.8 5.0 Less than ug/L 2 Mercury Grab EPA 1631E 1.0 Less than ng/L 1 Nickel Composite 200.8 2.0 2.3 ug/L 1 Selenium Composite 200.8 5.0 Less than ug/L 2 Silver Composite 200.8 5.0 Less than ug/L 2 Thallium Composite 200.9 1.0 Less than ug/L 1 Zinc Composite 200.8 10 41 ug/L 2 Cyanide Grab 10-204-00-1-X 10 Less than ug/L 1 Total phenolic compounds Grab EPA 420.2 0.005 0.039 mg/L 1 Volatile organic compounds Acrolein Grab EPA 624 100 Less than ug/L 1 Acrylonitrile Grab EPA 624 100 Less than ug/L 1 Benzene Grab EPA 624 5 Less than ug/L 1 Bromoform Grab EPA 624 5 Less than ug/L 1 Carbon tetrachloride Grab EPA 624 5 Less than ug/L 1 Chlorobenzene Grab EPA 624 5 Less than ug/L 1 Chlorodibromomethane (Dibromochloromethanel Grab EPA 624 5 Less than ug/L 1 Chloroethane Grab EPA 624 10 Less than ug/L 1 2-chloroethylvinyl ether Grab EPA 624 10 Less than ug/L 1 Chloroform Grab EPA 624 5 Less than ug/L 1 Dichlorobromomethane (Bromodichloromethane) Grab EPA 624 5 Less than ug/L 1 1,1-dichloroethane Grab EPA 624 5 Less than ug/L 1 1,2-dichloroethane Grab EPA 624 5 Less than ug/L 1 Trans-1,2-dichloroethylene Grab EPA 624 5 Less than ug/L 1 Form - DMR- PPA-1 Page 1 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month August Outfall 001 Year 2014 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Volatile organic compounds(Cont.) 1,1-dichloroethylene Grab EPA 624 5 Less than ug/L 1 1,2-dichloropropane Grab EPA 624 5 Less than ug/L 1 1,3-dichloropropylene Grab EPA 624 5 Less than ug/L 1 I Ethylbenzene Grab EPA 624 5 Less than ug/L 1 Methyl bromide(Bromomethane) Grab EPA 624 10 Less than ug/L 1 Methyl chloride(Chloromethane) Grab EPA 624 10 Less than ug/L 1 Methylene chloride Grab EPA 624 5 Less than ug/L 1 1,1,2,2-tetrachloroethane Grab EPA 624 5 Less than ug/L 1 Tetrachloroethylene Grab EPA 624 5 Less than ug/L 1 Toluene Grab EPA 624 5 Less than ug/L 1 1,1,1-trichloroethane Grab EPA 624 5 Less than ug/L 1 1,1,2-trichloroethane Grab EPA 624 5 Less than ug/L 1 Trichloroethylene Grab EPA 624 5 Less than ug/L 1 Vinyl chloride Grab EPA 624 10 Less than ug/L 1 Acid-extractable compounds P-chloro-m-creso (4-chloro-3-methvlahenol) Composite EPA 625 10 Less than ug/L 1 2-chlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dichlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dimethylphenol Composite EPA 625 10 Less than ug/L 1 4,6-dinitro-o-cresol (4,6- Dinitro-2-methvlphenoll Composite EPA 625 20 Less than ug/L 1 2,4-dinitrophenol Composite EPA 625 50 Less than ug/L 1 2-nitrophenol Composite EPA 625 10 Less than ug/L 1 4-nitrophenol Composite EPA 625 10 Less than ug/L 1 Pentachlorophenol Composite EPA 625 20 Less than ug/L 1 Phenol Composite EPA 625 10 Less than ug/L 1 2,4,6-trichlorophenol Composite EPA 625 10 Less than ug/L 1 Base-neutral compounds Acenaphthene Composite EPA 625 10 Less than ug/L 1 Acenaphthylene Composite EPA 625 10 Less than ug/L 1 Anthracene Composite EPA 625 10 Less than ug/L 1 Benzidine Composite EPA 625 50 Less than ug/L 1 Benzo(a)anthracene Composite EPA 625 10 Less than ug/L 1 Benzo(a)pyrene Composite EPA 625 10 Less than ug/L 1 3,4 benzofluoranthene (Benzo(b)fluoranthene) Composite EPA 625 10 Less than ug/L 1 Benzo(ghi)perylene Composite EPA 625 10 Less than ug/L 1 Benzo(k)fluoranthene Composite EPA 625 10 Less than ug/L 1 Bis (2-chloroethoxy) methane Composite EPA 625 10 Less than ug/L 1 Bis (2-chloroethyl) ether Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroisopropyl) ether Composite EPA 625 10 Less than ug/L 1 Bis (2-ethylhexyl) phthalate Composite EPA 625 10 Less than ug/L 1 4-bromophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Butyl benzyl phthalate Composite EPA 625 10 Less than ug/L 1 2-chloronaphthalene Composite EPA 625 10 Less than ug/L 1 I4-chlorophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Form - DMR- PPA-1 Page 2 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month August Outfall 001 Year 2014 ' Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Base-neutral compounds(cont.) Chrysene Composite EPA 625 10 Less than ug/L 1 Di-n-butyl phthalate Composite EPA 625 10 Less than ug/L 1 Di-n-octyl phthalate Composite EPA 625 10 Less than ug/L 1 Dibenzo(a,h)anthracene Composite EPA 625 10 Less than ug/L 1 1,2-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,3-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,4-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 3,3-dichlorobenzidine Composite EPA 625 10 Less than ug/L 1 Diethyl phthalate Composite EPA 625 10 Less than ug/L 1 Dimethyl phthalate Composite EPA 625 10 Less than ug/L 1 2,4-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 2,6-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 1,2-diphenylhydrazine Composite EPA 625 10 Less than ug/L 1 Fluoranthene Composite EPA 625 10 Less than ug/L 1 Fluorene Composite EPA 625 10 Less than ug/L 1 Hexachlorobenzene Composite EPA 625 10 Less than ug/L 1 Hexachlorobutadiene Composite EPA 625 10 Less than ug/L 1 Hexachlorocyclo-pentadiene Composite EPA 625 10 Less than ug/L 1 Hexachloroethane Composite EPA 625 10 Less than ug/L 1 Indeno(1,2,3-cd)pyrene Composite EPA 625 10 Less than ug/L 1 Isophorone Composite EPA 625 10 Less than ug/L 1 Naphthalene Composite EPA 625 10 Less than ug/L 1 Nitrobenzene Composite EPA 625 10 Less than ug/L 1 N-nitrosodi-n-propylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodimethylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodiphenylamine Composite EPA 625 10 Less than ug/L 1 Phenanthrene Composite EPA 625 10 Less than ug/L 1 Pyrene Composite EPA 625 10 Less than ug/L 1 1,2,4,-trichlorobenzene Composite EPA 625 10 Less than ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified perdonnel properly gather and evaluat the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsibel for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Authorized Representative name e;griha. , :c • -�:.�-�. ' Si: ature cilicilacikt Date 1 Form - DMR- PPA-1 Page 3 1 INFLUENT Annual Monitoring and Pollutant Scan Permit No. N C0030210 Month August Outfall 001 Year 2014 Facility Name Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of INFLUENT Sampling: 8/5/14 Phone (704) 547-0680 Analytical Laboratory: CMUD Environmental Lab NC 192,Prism Lab NC 402,Access Lab NC 618 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Ammonia(as N) Composite SM 4500-NH3-H-97 1.0 31 mg/L 2 Dissolved oxygen Grab SM4500-O-G-01 n/a n/a mg/L 0 Nitrate/Nitrite Composite EPA 353.2-93 0.05 Less than mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2-93 2.5 46 mg/L 1 Total Phosphorus Composite SM 4500P-G-99 0.2 5.7 mg/L 1 Total dissolved solids Composite SM 2540C-97 n/a n/a mg/L 0 Hardness Composite SM 2340C-97 n/a n/a mg/L 0 Chlorine(total residual,TRC) Grab SM 4500C1-G-00 n/a n/a ug/L 0 Oil and grease Grab EPA 1664B 5.0 19 mg/L 1 Metals (total recoverable), cyanide and total phenols Antimony Composite EPA 200.8 5.0 Less than ug/L 1 Arsenic Composite EPA 200.8 5.0 Less than ug/L 1 Beryllium Composite EPA 200.8 5.0 Less than ug/L 1 Cadmium Composite EPA 200.8 1.0 Less than ug/L 1 Chromium Composite EPA 200.8 5.0 Less than ug/L 1 Copper Composite EPA 200.8 2.0 24 ug/L 1 Lead Composite EPA 200.8 5.0 Less than ug/L 1 Mercury Composite EPA 245.2 0.2 Less than ug/L 1 Nickel Composite EPA 200.8 2.0 2.9 ug/L 1 Selenium Composite EPA 200.8 5.0 Less than ug/L 1 Silver Composite EPA 200.8 5.0 Less than ug/L 1 Thallium Composite EPA 200.9 1.0 Less than ug/L 1 Zinc Composite EPA 200.8 20 130 ug/L 1 Cyanide Grab 10-204-00-1-X 10 Less than ug/L 1 Total phenolic compounds Grab EPA 420.2 0.005 0.033 mg/L 1 Volatile organic compounds Acrolein Grab EPA 624 100 Less than ug/L 1 Acrylonitrile Grab EPA 624 100 Less than ug/L 1 Benzene Grab EPA 624 5 Less than ug/L 1 Bromoform Grab EPA 624 5 Less than ug/L 1 Carbon tetrachloride Grab EPA 624 5 Less than ug/L 1 Chlorobenzene Grab EPA 624 5 Less than ug/L 1 Chlorodibromomethane (Dibromochloromethanel Grab EPA 624 5 Less than ug/L 1 Chloroethane Grab EPA 624 10 Less than ug/L 1 2-chloroethylvinyl ether Grab EPA 624 10 Less than ug/L 1 Chloroform Grab EPA 624 5 Less than ug/L 1 Dichlorobromomethane (Bromodichloromethanel Grab EPA 624 5 Less than ug/L 1 1,1-dichloroethane Grab EPA 624 5 Less than ug/L 1 1,2-dichloroethane Grab EPA 624 5 Less than ug/L 1 Grans-1,2-dichloroethylene Grab EPA 624 5 Less than ug/L 1 Form - DMR- PPA-1 Page 1 INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month August Outfall 001 Year 2014 I Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Volatile organic compounds(Cont. 1,1-dichloroethylene Grab EPA 624 5 Less than ug/L 1 1,2-dichloropropane Grab EPA 624 5 Less than ug/L 1 1,3-dichloropropylene Grab EPA 624 5 Less than ug/L 1 Ethylbenzene Grab EPA 624 5 Less than ug/L 1 Methyl bromide(Bromomethane) Grab EPA 624 10 Less than ug/L 1 Methyl chloride(Chloromethane) Grab EPA 624 10 Less than ug/L 1 Methylene chloride Grab EPA 624 5 Less than ug/L 1 1,1,2,2-tetrachloroethane Grab EPA 624 5 Less than ug/L 1 Tetrachloroethylene Grab EPA 624 5 Less than ug/L 1 Toluene Grab EPA 624 5 Less than ug/L 1 1,1,1-trichloroethane Grab EPA 624 5 Less than ug/L 1 1,1,2-trichloroethane Grab EPA 624 5 Less than ug/L 1 Trichloroethylene Grab EPA 624 5 Less than ug/L 1 Vinyl chloride Grab EPA 624 10 Less than ug/L 1 Acid-extractable compounds P-chloro-m-creso (4-chloro-3-methvlohenol) Composite EPA 625 10 Less than ug/L 1 2-chlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dichlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dimethylphenol Composite EPA 625 10 Less than ug/L 1 4,6-dinitro-o-cresol J4,6-Dinitro-2-methvinhenol) Composite EPA 625 20 Less than ug/L 1 2,4-dinitrophenol Composite EPA 625 50 Less than ug/L 1 2-nitrophenol Composite EPA 625 10 Less than ug/L 1 , 4-nitrophenol Composite EPA 625 10 Less than ug/L 1 Pentachlorophenol Composite EPA 625 20 Less than ug/L 1 Phenol Composite EPA 625 10 Less than ug/L 1 2,4,6-trichlorophenol Composite EPA 625 10 Less than ug/L 1 Base-neutral compounds Acenaphthene Composite EPA 625 10 Less than ug/L 1 Acenaphthylene Composite EPA 625 10 Less than ug/L 1 Anthracene Composite EPA 625 10 Less than ug/L 1 Benzidine Composite EPA 625 50 Less than ug/L 1 Benzo(a)anthracene Composite EPA 625 10 Less than ug/L 1 Benzo(a)pyrene Composite EPA 625 10 Less than ug/L 1 3,4 benzofluoranthene fBenzofbifluoranthenei Composite EPA 625 10 Less than ug/L 1 Benzo(ghi)perylene Composite EPA 625 10 Less than ug/L 1 Benzo(k)fluoranthene Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethoxy) methane Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethyl) ether Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroisopropyl) ether Composite EPA 625 10 Less than ug/L 1 Bis (2-ethylhexyl) phthalate Composite EPA 625 10 Less than ug/L 1 4-bromophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Butyl benzyl phthalate Composite EPA 625 10 Less than ug/L 1 2-chloronaphthalene Composite EPA 625 10 Less than ug/L 1 I4-chlorophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Form - DMR- PPA-1 Page 2 INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month August Outfall 001 Year 2014 1 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Base-neutral compounds(cont.) Chrysene Composite EPA 625 10 Less than ug/L 1 Di-n-butyl phthalate Composite EPA 625 10 Less than ug/L 1 Di-n-octyl phthalate Composite EPA 625 10 Less than ug/L 1 Dibenzo(a,h)anthracene Composite EPA 625 10 Less than ug/L 1 1,2-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,3-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,4-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 3,3-dichlorobenzidine Composite EPA 625 10 Less than ug/L 1 Diethyl phthalate Composite EPA 625 10 Less than ug/L 1 Dimethyl phthalate Composite EPA 625 10 Less than ug/L 1 2,4-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 2,6-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 1,2-diphenylhydrazine Composite EPA 625 10 Less than ug/L 1 Fluoranthene Composite EPA 625 10 Less than ug/L 1 Fluorene Composite EPA 625 10 Less than ug/L 1 Hexachlorobenzene Composite EPA 625 10 Less than ug/L 1 Hexachlorobutadiene Composite EPA 625 10 Less than ug/L 1 Hexachlorocyclo-pentadiene Composite EPA 625 10 Less than ug/L 1 Hexachloroethane Composite EPA 625 10 Less than ug/L 1 Indeno(1,2,3-cd)pyrene Composite EPA 625 10 Less than ug/L 1 Isophorone Composite EPA 625 10 Less than ug/L 1 Naphthalene Composite EPA 625 10 Less than ug/L 1 Nitrobenzene Composite EPA 625 10 Less than ug/L 1 N-nitrosodi-n-propylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodimethylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodiphenylamine Composite EPA 625 10 Less than ug/L 1 Phenanthrene Composite EPA 625 10 Less than ug/L 1 I Pyrene Composite EPA 625 10 Less than ug/L 1 1,2,4,-trichlorobenzene Composite EPA 625 10 Less than ug/L 1 I I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified perdonnel properly gather and evaluat the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsibel for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. P1"10i Authorized Representative name \0 "\ Signatjhre 9/f9 /0Will Date Form - DMR- PPA-1 Page 3 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month November Outfall 001 Year 2015 acuity Name Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of EFFLUENT Sampling: 11/11/2015, low level mercury 11/10/15 Phone (704) 547-0680 Analytical Laboratory: CHARLOTTE WATER Environmental Lab NC 192, Prism Lab NC 402 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Ammonia(as N) Composite SM 4500-NH3-H-97 0.1 Less than mg/L 2 Dissolved oxygen Grab ASTM D888-09C 1.0 8.6 mg/L 1 Nitrate/Nitrite Composite EPA 353.2-93 1.0 12 mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2-93 0.25 1.2 mg/L 1 Total Phosphorus Composite SM 4500P-H-99 0.1 1.7 mg/L 1 Total dissolved solids Composite SM 2540C-11 25 220 P mg/L 1 Hardness Composite SM 2340B-11 1.0 110 mg/L 1 Chlorine(total residual,TRC) Grab SM 4500C1-G-00 15 Less than ug/L 1 Oil and grease Grab EPA 1664B 5 Less than mg/L 1 Metals(total recoverable), cyanide and total phenols Antimony Composite EPA 200.8 5.0 Less than ug/L 1 Arsenic Composite EPA 200.8 5.0 Less than ug/L 2 Beryllium Composite EPA 200.8 5.0 Less than ug/L 1 Cadmium Composite EPA 200.8 1.0 Less than ug/L 2 Chromium Composite EPA 200.8 5.0 Less than ug/L 2 Copper Composite EPA 200.8 2.0 2.1 ug/L 2 Lead Composite EPA 200.8 5.0 Less than ug/L 2 4ercury Grab EPA 1631E 1.0 Less than ng/L 1 idickel Composite EPA 200.8 2.0 Less than ug/L 2 Selenium Composite EPA 200.8 5.0 Less than ug/L 2 Silver Composite EPA 200.8 5.0 Less than ug/L 2 Thallium Composite EPA 200.8 5.0 Less than ug/L 1 Zinc Composite EPA 200.8 10 22 ug/L 2 Cyanide Grab 10-204-00-1-X 10 Less than ug/L 1 Total phenolic compounds Grab EPA 420.2 0.005 Less than mg/L 1 Volatile organic compounds Acrolein Grab EPA 624 100 Less than ug/L 1 Acrylonitrile Grab EPA 624 100 Less than ug/L 1 Benzene Grab EPA 624 5 Less than ug/L 1 Bromoform Grab EPA 624 5 Less than ug/L 1 Carbon tetrachloride Grab EPA 624 5 Less than ug/L 1 Chlorobenzene Grab EPA 624 5 Less than ug/L 1 Chlorodibro m om eth ane fDibromochloromethanel Grab EPA 624 5 Less than ug/L 1 Chloroethane Grab EPA 624 10 Less than ug/L 1 2-chloroethylvinyl ether Grab EPA 624 10 Less than ug/L 1 Chloroform Grab EPA 624 5 Less than ug/L 1 Dichlorobromomethane fBromodichloromethanel Grab EPA 624 5 Less than ug/L 1 1,1-dichloroethane Grab EPA 624 5 Less than ug/L 1 1,2-dichloroethane Grab EPA 624 5 Less than ug/L 1 'rans-1,2-dichloroethylene Grab EPA 624 5 Less than ug/L 1 Form - DMR- PPA-1 Page 1 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month November Outfall 001 Year 2015 I Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Volatile organic compounds (Cont.) 1,1-dichloroethylene Grab EPA 624 5 Less than ug/L 1 1,2-dichloropropane Grab EPA 624 5 Less than ug/L 1 1,3-dichloropropylene Grab EPA 624 5 Less than ug/L 1 Ethylbenzene Grab EPA 624 5 Less than ug/L 1 Methyl bromide(Bromomethane) Grab EPA 624 10 Less than ug/L 1 Methyl chloride(Chloromethane) Grab EPA 624 10 Less than ug/L 1 Methylene chloride Grab EPA 624 5 Less than ug/L 1 1,1,2,2-tetrachloroethane Grab EPA 624 5 Less than ug/L 1 Tetrachloroethylene Grab EPA 624 5 Less than ug/L 1 Toluene Grab EPA 624 5 Less than ug/L 1 1,1,1-trichloroethane Grab EPA 624 5 Less than ug/L 1 1,1,2-trichloroethane Grab EPA 624 5 Less than ug/L 1 Trichloroethylene Grab EPA 624 5 Less than ug/L 1 Vinyl chloride Grab EPA 624 10 Less than ug/L 1 Acid-extractable compounds P-chloro-m-creso 14-chloro-3-methvlphenoll Composite EPA 625 10 Less than ug/L 1 2-chlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dichlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dimethylphenol Composite EPA 625 10 Less than ug/L 1 4,6-dinitro-o-cresol (4,6- �initro-2-methvinhenoll Composite EPA 625 20 Less than ug/L 1 2,4-dinitrophenol Composite EPA 625 50 Less than ug/L 1 2-nitrophenol Composite EPA 625 10 Less than ug/L 1 4-nitrophenol Composite EPA 625 10 Less than ug/L 1 Pentachlorophenol Composite EPA 625 20 Less than ug/L 1 Phenol Composite EPA 625 10 Less than ug/L 1 2,4,6-trichlorophenol Composite EPA 625 10 Less than ug/L 1 Base-neutral compounds Acenaphthene Composite EPA 625 10 Less than ug/L 1 Acenaphthylene Composite EPA 625 10 Less than ug/L 1 Anthracene Composite EPA 625 10 Less than ug/L 1 Benzidine Composite EPA 625 50 Less than ug/L 1 Benzo(a)anthracene Composite EPA 625 10 Less than ug/L 1 Benzo(a)pyrene Composite EPA 625 10 Less than ug/L 1 3,4 benzofluoranthene iBenzolblfluoranthenel Composite EPA 625 10 Less than ug/L 1 Benzo(ghi)perylene Composite EPA 625 10 Less than ug/L 1 Benzo(k)fluoranthene Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethoxy)methane Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethyl) ether Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroisopropyl) ether Composite EPA 625 10 Less than ug/L 1 Bis(2-ethyihexyl) phthalate Composite EPA 625 10 Less than ug/L 1 4-bromophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 3utyl benzyl phthalate Composite EPA 625 10 Less than ug/L 1 2-chloronaphthalene Composite EPA 625 10 Less than ug/L 1 4-chlorophenyl phenyl ether Composite EPA 625 10 LeSs than ug/L 1 Form - DMR- PPA-1 Page 2 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month November Outfall 001 Year 2015 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Base-neutral compounds (cont.) Chrysene Composite EPA 625 10 Less than ug/L 1 Di-n-butyl phthalate Composite EPA 625 10 Less than ug/L 1 Di-n-octyl phthalate Composite EPA 625 10 Less than ug/L 1 Dibenzo(a,h)anthracene Composite EPA 625 10 Less than ug/L 1 1,2-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,3-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,4-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 3,3-dichlorobenzidine Composite EPA 625 10 Less than ug/L 1 Diethyl phthalate Composite EPA 625 10 Less than ug/L 1 Dimethyl phthalate Composite EPA 625 10 Less than ug/L 1 2,4-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 2,6-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 1,2-diphenylhydrazine Composite EPA 625 10 Less than ug/L 1 Fluoranthene Composite EPA 625 10 Less than ug/L 1 Fluorene Composite EPA 625 10 Less than ug/L 1 Hexachlorobenzene Composite EPA 625 10 Less than ug/L 1 Hexachlorobutadiene Composite EPA 625 10 Less than ug/L 1 Hexachlorocyclo-pentadiene Composite EPA 625 10 Less than ug/L 1 Hexachloroethane Composite EPA 625 10 Less than ug/L 1 Indeno(1,2,3-cd)pyrene Composite EPA 625 10 Less than ug/L 1 .sophorone Composite EPA 625 10 Less than ug/L 1 gaphthalene . Composite EPA 625 10 Less than ug/L 1 Nitrobenzene Composite EPA 625 10 Less than ug/L 1 N-nitrosodi-n-propylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodimethylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodiphenylamine Composite EPA 625 10 Less than ug/L 1 Phenanthrene Composite EPA 625 10 Less than ug/L 1 Pyrene Composite EPA 625 10 Less than ug/L 1 1,2,4,-trichlorobenzene Composite EPA 625 10 Less than ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified perdonnel properly gather and evaluat the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsibel for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. ----?)i- Cli-vilix L . 1-67so n Au orized Representative name '• ) 4--A.,ca,r156a, id,..7*------ ign. re /c39-4 7 4./C) /5 Date Form - DMR- PPA-1 Page 3 INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month November Outfall 001 Year 2015 'acuity Name Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of INFLUENT Sampling: 11/10/2015, additional Phenol 11/11/15 Phone (7041 547-0680 Analytical Laboratory; CHARLOTTE WATER Environmental Lab NC 192, Prism Lab NC 402 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples , Ammonia (as N) Composite SM 4500-N113-H-97 1.0 14 mg/L 2 Dissolved oxygen Grab ASTM D888-09C n/a n/a mg/L 0 Nitrate/Nitrite Composite EPA 353.2-93 0.05 0.27 mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2-93 2.5 23 mg/L 1 Total Phosphorus Composite SM 4500P-H-99 0.2 2.7 mg/I, 1 Total dissolved solids Composite SM 2540C-11 n/a n/a mg/L 0 Hardness Composite SM 2340B-11 n/a n/a mg/L 0 Chlorine (total residual, TRC) Grab SM 4500C1-G-00 n/a n/a ug/L 0 Oil and grease Grab EPA 1664B 5.0 12 mg/L 1 1 Metals (total recoverable), cyanide and total phenols Antimony Composite EPA 200.8 5.0 Less than ug/L 1 Arsenic Composite EPA 200.8 5.0 Less than ug/L 1 Beryllium Composite EPA 200.8 5.0 Less than ug/L 1 Cadmium Composite EPA 200.8 1.0 Less than ug/L 1 Chromium Composite EPA 200.8 5.0 Less than ug/L 1 Copper Composite EPA 200.8 2.0 15 ug/L 1 Lead Composite EPA 200.8 5.0 Less than ug/L 1 .lercury Composite EPA 245.1 0.2 Less than ug/l. 1 Nickel Composite EPA 200.8 2.0 3.3 ug/L 1 Selenium Composite EPA 200.8 5.0 Less than ug/L 1 Silver Composite EPA 200.8 5.0 Less than ug/L 1 Thallium Composite EPA 200.8 5.0 Less than ug/L 1 Zinc Composite EPA 200.8 10 60 ug/L 1 Cyanide Grab 10-204-00-1-X 10 Less than ug/L 1 Total phenolic compounds Grab EPA 420,2 0.050 Less than mg/L 2 Volatile organic compounds Acrolein Grab EPA 624 100 Less than ug/L . 1 Acrylonitrile Grab EPA 624 100 Less than ug/L 1 Benzene Grab EPA 624 5 Less than ug/L 1 Bromoform Grab EPA 624 5 Less than.ug/l. 1 Carbon tetrachloride Grab EPA 624 5 Less than ug/L 1 Chlorobenzene Grab EPA 624 5 Less than ug/L 1 1 Chlorodibromomethane (Dibromochlorometbane) Grab EPA 624 5 Less than ug/L 1 Chloroethane Grab EPA 624 10 Less than ug/L 1 2-ehloroethylvinyl ether Grab EPA 624 10 Less than ug/L 1 Chloroform Grab EPA 624 5 Less than ug/I, 1 Dichlorobromomethane I BromodichloromerhanGrab EPA 624 5 Less than ug/L 1 oi 1,1-dichloroethane Grab EPA 624 5 Less than ug/L 1 1,2-dichloroethane Grab EPA 624 5 Less than ug/L 1 Trans-1,2-dichloroethylene Grab EPA 624 5 Less than ug/L 1 Form - DMR- PPA-1 Page 1 INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month November Outfall 001 Year 2015 I Sample Analytical 1 Quantitation Sample Units of Number of ?arameter Type Method I Level Result Measurement samples Volatile organic compounds (Cont.) 1,1-dichloroethylene Grab EPA 624 5 Less than ug/L 1 1,2-dichloropropane Grab EPA 624 5 Less than ug/L 1 1,3-dichloropropylene Grab EPA 624 5 Less than ug/L 1 Ethylbenzene Grab EPA 624 5 Less than ug/L 1 Methyl bromide(Bromomethane) Grab EPA 624 10 Less than ug/L 1 Methyl chloride(Chloromethane) Grab EPA 624 10 Less than ug/L 1 Methylene chloride Grab EPA 624 5 Less than ug/L 1 1,1,2,2-tetrachloroethane Grab EPA 624 5 Less than ug/L 1 Tetrachloroethylene Grab EPA 624 5 Less than ug/L 1 Toluene Grab EPA 624 5 Less than ug/L 1 1,1,1-trichloroethane Grab EPA 624 5 Less than ug/L 1 11,2-trichloroethane Grab EPA 624 5 Less than ug/L 1 Trichloroethylene Grab EPA 624 5 Less than ug/L 1 Vinyl chloride Grab EPA 624 10 Less than ug/L 1 Acid-extractable compounds P-chloro-m-creso (4-chloro-3-methylphenoll Composite EPA 625 10 Less than ug/1_ 1 2-chlorophenol Composite EPA 625 10 Less than ug/I. I 2,4-dichlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dimethylphenol Composite EPA 625 10 Less than ug/L 1 4,6-dinitro-o-cresol 4,6-Dinitro-2-methylphenoll Composite EPA 625 20 Less than ug/L 1 2,4-dinitrophenol Composite EPA 625 50 Less than ug/L 1 2-nitrophenol Composite EPA 625 10 Less than ug/L 1 4-nitrophenol Composite EPA 625 10 Less than ug/L 1 Pentachlorophenol Composite EPA 625 20 Less than ug/L 1 Phenol Composite EPA 625 10 Less than ug/L 1 2,4,6-trichlorophenol Composite EPA 625 10 Less than ug/L 1 Base-neutral compounds Acenaphthene Composite EPA 625 10 Less than ug/L 1 Acenaphthylene Composite EPA 625 10 Less than ug/L 1 I - Anthracene Composite EPA 625 10 Less than ug/L 1 Benzidine Composite EPA 625 50 Less than ug/L 1 Benzo(alanthracene Composite EPA 625 10 Less than ug/L 1 Benzo(a)pyr-ene Composite EPA 625 10 Less than ug/L 1 3,4 benzofluoranthene BenzoNfluoranthenel Composite EPA 625 10 Less than ug/L 1 ( Benzo(ghi)perylene Composite EPA 625 10 Less than ug/L 1 Benzo(k)fluoranthene Composite EPA 625 10 Less than ug/L I Bis (2-chloroethoxy) methane Composite EPA 625 10 Less than ug/L 1 Bis (2-chloroethyl) ether Composite EPA 625 10 Less than ug/L 1 I Bis (2-chloroisopropyl) ether Composite EPA 625 10 Less than ug/L 1 Bis (2-ethylhexv1) phthalate Composite EPA 625 10 Less than ug/L 1 4-bromophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Butyl benzyl phthalate Composite EPA 625 10 Less than ug/L 1 2-chloronaphthalene Composite EPA 625 10 Less than ug/L 1 I 4-chlorophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Form - DMR- PPA-1 Page 2 INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month November Outfall 001 Year 2015 1 Sample Analytical Quantitation Sample Units of Number of 'arameter Type Method Level Result Measurement samples Base-neutral compounds (cont.) Chrysene Composite EPA 625 10 Less than ug/L 1 Di-n-butyl phthalate Composite EPA 625 10 Less than ug/L 1 Di-n-octyl phthalate Composite EPA 625 10 Less than ug/L 1 Dibenzo(a,h)anthracene Composite EPA 625 10 Less than ug/L 1 1,2-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,3-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,4-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 3,3-dichlorobenzidine Composite EPA 625 10 Less than ug/L 1 Diethyl phthalate Composite EPA 625 10 Less than ug/L 1 Dimethyl phthalate Composite EPA 625 10.Less than ug/L 1 2,4-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 2,6-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 1,2-diphenylhydrazine Composite EPA 625 10 Less than ug/L 1 Fluoranthene Composite EPA 625 10 Less than ug/L 1 Fluorene Composite EPA 625 10 Less than ug/L 1 Hexachlorobenzene Composite EPA 625 10 Less than ug/L 1 Hexachlorobutadiene Composite EPA 625 10 Less than ug/L 1 Hexachlorocyclo-pentadiene Composite EPA 625 10 Less than ug/L 1 Hexachloroethane Composite EPA 625 10 Less than ug/L 1 Indeno(1,2,3-cd)pyrene Composite EPA 625 10 Less than ug/L 1 [sophorone Composite EPA 625 10 Less than ug/L 1 Naphthalene Composite EPA 625 10 Less than ug/L 1 Nitrobenzene Composite EPA 625 10 Less than ug/L 1 N-nitrosodi-n-propylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodimethylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodiphenylamine Composite EPA 625 10 Less than ug/L 1 Phenanthrene Composite EPA 625 10 Less than ug/L 1 Pyrene Composite EPA 625 10 Less than ug/L 1 1,2,4,-trichlorobenzene Composite EPA 625 10 Less than ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified perdonnel properly gather and evaluat the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsibel for gathering the infoithation, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. I r II41a- t - 1--LA. ..:,-OI) Au orized Representative name r • 6{2p.... -L L Signat re /0?-47/, Date Form Form - DMR- PPA-1 Page 3 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month February Outfall 001 Year 2016 Facility Name Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of EFFLUENT Sampling: 2/10/16,low level mercury 2/9/2016 Phone (704) 547-0680 Analytical Laboratory: CHARLOTTE WATER Environmental Lab NC 192, Prism Lab NC 402 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Ammonia(as N) Composite SM 4500-NH3-H-11 0.1 Less than mg/L 2 Dissolved oxygen Grab ASTM D888-09C 1.0 9.5 mg/L 1 Nitrate/Nitrite Composite EPA 353.2-93 1.0 15 mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2-93 0.25 1.1 mg/L 1 Total Phosphorus Composite SM 4500P-G-11 0.1 2.9 mg/L 1 Total dissolved solids Composite SM 2540C-11 25 300 mg/L 1 Hardness Composite EPA 200.7 1.0 150 mg/L 1 Chlorine(total residual,TRC) Grab SM 450001-G-00 15 Less than ug/L 1 Oil and grease Grab EPA 1664B 5 Less than mg/L 1 Metals(total recoverable), cyanide and total phenols Antimony Composite EPA 200.8 5.0 Less than ug/L 1 Arsenic Composite EPA 200.8 5.0 Less than ug/L 2 Beryllium Composite EPA 200.8 5.0 Less than ug/L 1 Cadmium Composite EPA 200.8 1.0 Less than ug/L 2 Chromium Composite EPA 200.8 5.0 Less than ug/L 2 Copper Composite EPA 200.8 2.0 2.5 ug/L 2 Lead Composite EPA 200.8 5.0 Less than ug/L 2 Mercury Grab EPA 1631E 1.0 Less than ng/L 1 Nickel Composite EPA 200.8 2.0 Less than ug/L 2 Selenium Composite EPA 200.8 5.0 Less than ug/L 2 Silver Composite EPA 200.8 5.0 Less than ug/L 2 Thallium Composite EPA 200.8 5.0 Less than ug/L 1 Zinc Composite EPA 200.8 10 44 ug/L 2 Cyanide Grab 10-204-00-1-X 10 Less than ug/L 1 Total phenolic compounds Grab EPA 420.2 0.05 Less than mg/L 1 Volatile organic compounds Acrolein Grab EPA 624 100 Less than ug/L 1 Acrylonitrile Grab EPA 624 100 Less than ug/L 1 Benzene Grab EPA 624 5 Less than ug/L 1 Bromoform Grab EPA 624 5 Less than ug/L 1 Carbon tetrachloride Grab EPA 624 5 Less than ug/L 1 Chlorobenzene Grab EPA 624 5 Less than ug/L 1 Chlorodibromomethane (Dibromochloromethane) Grab EPA 624 5 Less than ug/L 1 Chloroethane Grab EPA 624 10 Less than ug/L 1 2-chloroethylvinyl ether Grab EPA 624 10 Less than ug/L 1 Chloroform Grab EPA 624 5 Less than ug/L 1 Dichlorobromomethane (Bromodichloromethanel Grab EPA 624 5 Less than ug/L 1 1,1-dichloroethane Grab EPA 624 5 Less than ug/L 1 1,2-dichloroethane Grab EPA 624 5 Less than ug/L 1 I`rans-1,2-dichloroethylene Grab EPA 624 5 Less than ug/L 1 Form- DMR- PPA-1 Page 1 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month February Outfall 001 Year 2016 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Volatile organic compounds(Cont.) 1,1-dichloroethylene Grab EPA 624 5 Less than ug/L 1 1,2-dichloropropane Grab EPA 624 5 Less than ug/L 1 1,3-dichloropropylene Grab EPA 624 5 Less than ug/L 1 Ethylbenzene Grab EPA 624 5 Less than ug/L 1 Methyl bromide(Brornomethane) Grab EPA 624 10 Less than ug/L 1 Methyl chloride(Chloromethane) Grab EPA 624 10 Less than ug/L 1 Methylene chloride Grab EPA 624 5 Less than ug/L 1 1,1,2,2-tetrachloroethane Grab EPA 624 5 Less than ug/L 1 Tetrachloroethylene Grab EPA 624 5 Less than ug/L 1 Toluene Grab EPA 624 5 Less than ug/L 1 1,1,1-trichloroethane Grab EPA 624 5 Less than ug/L 1 1,1,2-trichloroethane Grab EPA 624 5 Less than ug/L 1 Trichloroethylene Grab EPA 624 5 Less than ug/L 1 Vinyl chloride Grab EPA 624 10 Less than ug/L 1 Acid-extractable compounds P-chloro-m-creso (4-chloro-3-methylphenol) Composite EPA 625 10 Less than ug/L 1 2-chlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dichiorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dimethylphenol Composite EPA 625 10 Less than ug/L 1 4,6-dinitro-o-cresol (4,6- Dinitro-2 methvlphenol) Composite EPA 625 20 Less than ug/L 1 2,4-dinitrophenol Composite EPA 625 50 Less than ug/L 1 2-nitrophenol Composite EPA 625 10 Less than ug/L 1 4-nitrophenol Composite EPA 625 10 Less than ug/L 1 Pentachlorophenol Composite EPA 625 20 Less than ug/L 1 Phenol Composite EPA 625 10 Less than ug/L 1 2,4,6-trichlorophenol Composite EPA 625 10 Less than ug/L 1 Base-neutral compounds Acenaphthene Composite EPA 625 10 Less than ug/L 1 Acenaphthylene Composite EPA 625 10 Less than ug/L 1 Anthracene Composite EPA 625 10 Less than ug/L 1 Benzidine Composite EPA 625 50 Less than ug/L 1 Benzo(a)anthracene Composite EPA 625 10 Less than ug/L 1 Benzo(a)pyrene Composite EPA 625 10 Less than ug/L 1 3,4 benzofluoranthene (Benzo(b)fluoranthenel Composite EPA 625 10 Less than ug/L 1 Benzo(ghi)perylene Composite EPA 625 10 Less than ug/L 1 Benzo(k)fluoranthene Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethoxy)methane Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethyl) ether Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroisopropyl) ether Composite EPA 625 10 Less than ug/L 1 Bis(2-ethylhexyl) phthalate Composite EPA 625 10 Less than ug/L 1 4-bromophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Butyl benzyl phthalate Composite EPA 625 10 Less than ug/L 1 2-chloronaphthalene Composite EPA 625 10 Less than ug/L 1 I4-chlorophenyl phenyl ether Composite EPA 625 .10 Less than ug/L 1 Form- DMR- PPA-1 Page 2 EFFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month February Outfall 001 Year 2016 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Base-neutral compounds (cont.) Chrysene Composite EPA 625 10 Less than ug/L 1 Di-n-butyl phthalate Composite EPA 625 10 Less than ug/L 1 Di-n-octyl phthalate Composite EPA 625 10 Less than ug/L 1 Dibenzo(a,h)anthracene Composite EPA 625 10 Less than ug/L 1 1,2-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,3-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,4-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 3,3-dichlorobenzidine Composite EPA 625 10 Less than ug/L 1 Diethyl phthalate Composite EPA 625 10 Less than ug/L 1 Dimethyl phthalate Composite EPA 625 10 Less than ug/L 1 2,4-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 2,6-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 1,2-diphenylhydrazine Composite EPA 625 10 Less than ug/L 1 Fluoranthene Composite EPA 625 10 Less than ug/L 1 Fluorene Composite EPA 625 10 Less than ug/L 1 Hexachlorobenzene Composite EPA 625 10 Less than ug/L 1 Hexachlorobutadiene Composite EPA 625 10 Less than ug/L 1 Hexachlorocyclo-pentadiene Composite EPA 625 10 Less than ug/L 1 Hexachloroethane Composite EPA 625 10 Less than ug/L 1 Indeno(1,2,3-cd)pyrene Composite EPA 625 10 Less than ug/L 1 [sophorone Composite EPA 625 10 Less than ug/L 1 Naphthalene Composite EPA 625 10 Less than ug/L 1 Nitrobenzene Composite EPA 625 10 Less than ug/L 1 N-nitrosodi-n-propylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodimethylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodiphenylamine Composite EPA 625 10 Less than ug/L 1 Phenanthrene Composite EPA 625 10 Less than ug/L 1 Pyrene Composite EPA 625 10 Less than ug/L 1 1,2,4,-trichlorobenzene Composite EPA 625 10 Less than ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified perdonnel properly gather and evaluat the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsibel for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. AL. I -�4:k0� Au --orized Representative name \gfa0V4V12._:g.r.:Fl.PLOi'---) Signature Ta Pr) 4 ', Acs/ 6 Date Form- DMR- PPA-1 Page 3 INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month February Outfall 001 Year 2016 Facility Name Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of INFLUENT Sampling: 2/9/16 Phone (704) 547-0680 Analytical Laboratory: CHARLOTTE WATER Environmental Lab NC 192, Prism Lab NC 402 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Ammonia(as N) Composite SM 4500-NH3-H-11 1.0 30 mg/L 2 Dissolved oxygen Grab ASTM D888-09C n/a n/a mg/L 0 Nitrate/Nitrite Composite EPA 353.2-93 0.05 Less than mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2-93 2.5 40 mg/L 1 Total Phosphorus Composite SM 4500P-G-11 0.1 5.2 mg/L 1 Total dissolved solids Composite SM 2540C-11 n/a n/a mg/L 0 Hardness Composite EPA 200.7 n/a n/a mg/L 0 1 Chlorine (total residual,TRC) Grab SM 4500C1-G-00 n/a n/a ug/L 0 Oil and grease Grab EPA 1664B 5.0 28 mg/L 1 Metals(total recoverable),cyanide and total phenols Antimony Composite EPA 200.8 5.0 Less than ug/L 1 Arsenic Composite EPA 200.8 5.0 Less than ug/L 1 Beryllium Composite EPA 200.8 5.0 Less than ug/L 1 Cadmium Composite EPA 200.8 1.0 Less than ug/L 1 Chromium Composite EPA 200.8 5.0 Less than ug/L 1 Copper Composite EPA 200.8 2.0 18 ug/L 1 Lead Composite EPA 200.8 5.0 Less than ug/L 1 Mercury Composite EPA 245.1 0.2 Less than ug/L 1 Nickel Composite EPA 200.8 2.0 3.0 ug/L 1 Selenium Composite EPA 200.8 5.0 Less than ug/L 1 Silver Composite EPA 200.8 5.0 Less than ug/L 1 Thallium Composite EPA 200.8 5.0 Less than ug/L 1 Zinc Composite EPA 200.8 10 110 ug/L 1 Cyanide Grab 10-204-00-1-X 10 Less than ug/L 1 Total phenolic compounds Grab EPA 420.2 0.050 0.064 mg/L 1 Volatile organic compounds Acrolein Grab EPA 624 100 Less than ug/L 1 Acrylonitrile Grab EPA 624 100 Less than ug/L 1 Benzene Grab EPA 624 5 Less than ug/L 1 Bromoform Grab EPA 624 5 Less than ug/L 1 Carbon tetrachloride Grab EPA 624 5 Less than ug/L 1 Chlorobenzene Grab EPA 624 5 Less than ug/L 1 Chlorodibromomethane (Dibromochloromethane) Grab EPA 624 5 Less than ug/L 1 Chloroethane Grab EPA 624 10 Less than ug/L 1 2-chloroethylvinyl ether Grab EPA 624 10 Less than ug/L 1 Chloroform Grab EPA 624 5 Less than ug/L 1 Dichlorobromomethane (Bromodichloromethanel Grab EPA 624 5 Less than ug/L 1 1,1-dichloroethane Grab EPA 624 5 Less than ug/L 1 1,2-dichloroethane Grab EPA 624 5 Less than ug/L 1 [Tans-1,2-dichloroethylene Grab EPA 624 5 Less than ug/L 1 Form - DMR- PPA-1 Page 1 I INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month February Outfall 001 Year 2016 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level • Result Measurement samples Volatile organic compounds (Cont.) 1,1-dichloroethylene Grab EPA 624 5 Less than ug/L 1 1,2-dichloropropane Grab EPA 624 5 Less than ug/L 1 1,3-dichloropropylene Grab EPA 624 5 Less than ug/L 1 Ethylbenzene Grab EPA 624 5 Less than ug/L 1 Methyl bromide(Bromomethane) Grab EPA 624 10 Less than ug/L 1 Methyl chloride(Chloromethane) Grab EPA 624 10 Less than ug/L 1 Methylene chloride Grab EPA 624 5 Less than ug/L 1 1,1,2,2-tetrachloroethane Grab EPA 624 5 Less than ug/L 1 Tetrachloroethylene Grab EPA 624 5 Less than ug/L 1 Toluene Grab EPA 624 5 Less than ug/L 1 1,1,1-trichloroethane Grab EPA 624 5 Less than ug/L 1 1,1,2-trichloroethane Grab EPA 624 5 Less than ug/L 1 Trichloroethylene Grab EPA 624 5 Less than ug/L 1 Vinyl chloride Grab EPA 624 10 Less than ug/L 1 Acid-extractable compounds P-chloro-m-creso (4-chloro-3-methvinhenoll Composite EPA 625 10 Less than ug/L 1 2-chlorophenol Composite EPA 625 10 Less than ug/L 1 2,4-dichlorophenoi Composite EPA 625 10 Less than ug/L 1 2,4-dimethylphenol Composite EPA 625 10 Less than ug/L 1 4,6-dinitro-o-cresol (4,6-Dinitro-2-methvlphenol) Composite EPA 625 20 Less than ug/L 1 2,4-dinitrophenol Composite EPA 625 50 Less than ug/L 1 2-nitrophenol Composite EPA 625 10 Less than ug/L 1 4-nitrophenol Composite EPA 625 10 Less than ug/L 1 Pentachlorophenol Composite EPA 625 20 Less than ug/L 1 Phenol Composite EPA 625 10 15 ug/L 1 2,4,6-trichlorophenol Composite EPA 625 10 Less than ug/L 1 Base-neutral compounds Acenaphthene Composite EPA 625 10 Less than ug/L 1 Acenaphthylene Composite EPA 625 10 Less than ug/L 1 Anthracene Composite EPA 625 10 Less than ug/L 1 Benzidine Composite EPA 625 50 Less than ug/L 1 Benzo(a)anthracene Composite EPA 625 10 Less than ug/L 1 Benzo(a)pyrene Composite EPA 625 10 Less than ug/L 1 3,4 benzofluoranthene (Benzo(b)fluoranthenel Composite EPA 625 10 Less than ug/L 1 Benzo(ghi)perylene Composite EPA 625 10 Less than ug/L 1 Benzo(k)fluoranthene Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethoxy)methane Composite EPA 625 10 Less than ug/L 1 Bis(2-chloroethyl) ether Composite EPA 625 10 Less than ug/L 1 Bis (2-chloroisopropyl) ether Composite EPA 625 10 Less than ug/L 1 Bis(2-ethylhexyl)phthalate Composite EPA 625 10 Less than ug/L 1 4-bromophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 3utyl benzyl phthalate Composite EPA 625 10 Less than ug/L 1 2-chloronaphthalene Composite EPA 625 10 Less than ug/L 1 I4-chlorophenyl phenyl ether Composite EPA 625 10 Less than ug/L 1 Foi in- DMR- PPA-1 Page 2 INFLUENT Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month February Outfall 001 Year 2016 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Base-neutral compounds (cont.) Chrysene Composite EPA 625 10 Less than ug/L 1 Di-n-butyl phthalate Composite EPA 625 10 Less than ug/L 1 Di-n-octyl phthalate Composite EPA 625 10 Less than ug/L 1 Dibenzo(a,h)anthracene Composite EPA 625 10 Less than ug/L 1 1,2-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,3-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 1,4-dichlorobenzene Composite EPA 625 10 Less than ug/L 1 3,3-dichlorobenzidine Composite EPA 625 10 Less than ug/L 1 Diethyl phthalate Composite EPA 625 10 Less than ug/L 1 Dimethyl phthalate Composite EPA 625 10 Less than ug/L 1 2,4-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 2,6-dinitrotoluene Composite EPA 625 10 Less than ug/L 1 1,2-diphenylhydrazine Composite EPA 625 10 Less than ug/L 1 Fluoranthene Composite EPA 625 10 Less than ug/L 1 Fluorene Composite EPA 625 10 Less than ug/L 1 Hexachlorobenzene Composite EPA 625 10 Less than ug/L 1 Hexachlorobutadiene Composite EPA 625 10 Less than ug/L 1 Hexachlorocyclo-pentadiene Composite EPA 625 10 Less than ug/L 1 Hexachloroethane Composite EPA 625 10 Less than ug/L 1 Indeno(1,2,3-cd)pyrene Composite EPA 625 10 Less than ug/L 1 lsophorone Composite EPA 625 10 Less than ug/L 1 Naphthalene Composite EPA 625 10 Less than ug/L 1 Nitrobenzene Composite EPA 625 10 Less than ug/L 1 N-nitrosodi-n-propylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodimethylamine Composite EPA 625 10 Less than ug/L 1 N-nitrosodiphenylarnine Composite EPA 625 10 Less than ug/L 1 Phenanthrene Composite EPA 625 10 Less than ug/L 1 Pyrene Composite EPA 625 10 Less than ug/L 1 1,2,4,-trichlorobenzene Composite EPA 625 10 Less than ug/L 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified perdonnel properly gather and evaluat the infoi uiation submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsibel for gathering the information, the information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false infoxxuation, including the lssibility of fines and imprisonment for knowing violations. h() YL L -mon I Authorized Representative name IS Signature f -\c1 .. , ai , 1( ' Date Page 3 Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month May Outfall 001 Year 2017 Facility Name: Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of EFFLUENT sampling: 5/10/2017, 5/9 Low level mercury Phone (704) 547-0680 Analytical Laboratory: CHARLOTTE WATER Environmental Lab--NC 192; and Prism Lab NC 402 Parameter Sample Analytical Quantitation Sample Units of Parameter Code Type Method Level Result Measurement Ammonia(as N) C0610 Composite SM 4500-NH3-H-11 0.10 Less than mg/L Chlorine(total residual,TRC) 50060 Grab Hach 10014ULR 15 Less than ' ug/L Dissolved Oxygen 00300 Grab ASTM D888-09C 1.0 8.5 mg/L Nitrite plus Nitrate Total(as N) 00630 Composite EPA 353.2-93 1 13 mg/L Total Kjeldahl Nitrogen 00625 Composite EPA 351.2-93 0.25 0.6 mg/L Oil and Grease 00556 Grab EPA 1664B 5 Less than mg/L Total Phosphorus C0665 Composite SM 4500P-H-11 0.10 2.20 mg/L Total Dissolved Solids 70295 Composite SM 2540C-11 25 320 mg/L Hardness 00900 Composite EPA 200.7 1.0 130 mg/L Metals(total recoverable),cyanide and total,phenols Antimony 01097 Composite EPA 200.8 5.0 Less than ug/L Arsenic 01002 Composite EPA 200.8 5.0 Less than ug/L Beryllium 01012 Composite EPA 200.7 2.0 Less than ug/L Cadmium 01027 Composite EPA 200.8 1.0 Less than ug/L Chromium 01034 Composite EPA 200.8 5.0 Less than ug/L Copper 01042 Composite EPA 200.8 2.0 3.8 ug/L Lead 01051 Composite EPA 200.8 5.0 Less than ug/L Mercury(Method 1631E) COMER Grab EPA 1631E 1.0 Less than ng/L Nickel 01067 Composite EPA 200.8 2.0 Less than ug/L Selenium 01147 Composite EPA 200.8 5.0 Less than ug/L Silver 01077 Composite EPA 200.8 5.0 Less than ug/L Thallium 01059 Composite EPA 200.8 5.0 Less than ug/L Zinc 01092 Composite EPA 200.8 10 40 ug/L Cyanide 00720 Grab 10-204-00-1-X 10 Less than ug/L Total phenolic compounds 32730 Grab EPA 420.2 0.050 Less than mg/L Volatile organic compounds Acrolein 34210 Grab EPA 624 100 Less than ug/L Acrylonitrile 34215 Grab EPA 624 100 Less than ug/L Benzene 34030 Grab EPA 624 5 Less than ug/L Bromoform 32104 Grab EPA 624 5 Less than ug/L Carbon Tetrachloride 32102 Grab EPA 624 5 Less than ug/L Chlorobenzene 34301 Grab EPA 624 5 Less than ug/L Chlorodibromomethane 34306 Grab EPA 624 5 Less than ug/L Chloroethane 85811 Grab EPA 624 10 Less than ug/L 2-chloroethyl vinyl ether 34576 Grab EPA 624 10 Less than ug/L Chloroform 32106 Grab EPA 624 5 Less than ug/L )ichlorobromomethane 32101 Grab EPA 624 5 Less than ug/L ,1-dichloroethane 34496 Grab EPA 624 5 Less than ug/L 1,2-dichloroethane 32103 Grab EPA 624 5 Less than ug/L Trans-1,2-dichloroethylene 34546 Grab EPA 624 5 Less than ug/L Form- DMR- PPA-1 Page 1 Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month May Outfall 001 Year 2017 Parameter Sample Analytical Quantitation Sample Units of Parameter Code Type Method Level Result Measurement 1,1-dichloroethylene 34501 Grab EPA 624 5 Less than ug/L 1,2-dichloropropane 34541 Grab EPA 624 5 Less than ug/L 1,3-dichloropropylene 77163 Grab EPA 624 5 Less than ug/L Ethylbenzene 34371 Grab EPA 624 5 Less than ug/L Methyl Bromide 34413 Grab EPA 624 10 Less than ug/L Methyl Chloride 34418 Grab EPA 624 10 Less than ug/L Methylene Chloride 34423 Grab EPA 624 5 Less than ug/L 1 1,1,2,2-tetrachloroethane 81549 Grab EPA 624 5 Less than ug/L 1 Tetrachloroethylene 34475 Grab EPA 624 5 Less than ug/L Toluene 34010 Grab EPA 624 5 Less than ug/L 1,1,1-trichloroethane 34506 Grab EPA 624 5 Less than ug/L 1,1,2-trichloroethane 34511 Grab EPA 624 5 Less than ug/L Trichloroethylene 39180 Grab EPA 624 5 Less than ug/L Vinyl Chloride 39175 Grab EPA 624 10 Less than ug/L Acid-extractable compounds P-chloro-m-creso 34452 Composite EPA 625 10 Less than ug/L 2-chlorophenol 34586 Composite EPA 625 10 Less than ug/L 2,4-dichlorophenol 34601 Composite EPA 625 10 Less than ug/L 2,4-dimethylphenol 34606 Composite EPA 625 10 Less than ug/L 4,6-dinitro-o-cresol 34657 Composite EPA 625 20 Less than ug/L 2,4-dinitrophenol 34616 Composite EPA 625 50 Less than ug/L 2-nitrophenol 34591 Composite EPA 625 10 Less than ug/L 4-nitrophenol 34646 Composite EPA 625 10 Less than ug/L Pentachlorophenol 39032 Composite EPA 625 20 Less than ug/L Phenol 34694 Composite EPA 625 10 Less than ug/L 2,4,6-trichlorophenol 34621 Composite EPA 625 10 Less than ug/L Base-neutral compounds Acenaphthene 34205 Composite EPA 625 10 Less than ug/L Acenaphthylene 34200 Composite EPA 625 10 Less than ug/L Anthracene CO220 Composite EPA 625 10 Less than ug/L Benzidine 39120 Composite EPA 625 50 Less than ug/L Benzo(a)anthracene 34526 Composite EPA 625 10 Less than ug/L Benzo(a)pyrene 34247 Composite EPA 625 10 Less than ug/L 3,4 benzofluoranthene 34230 Composite EPA 625 10 Less than ug/L Benzo(ghi)perylene 34521 Composite EPA 625 10 Less than ug/L Benzo(k)fluoranthene 34242 Composite EPA 625 10 Less than ug/L Bis (2-chloroethoxy) methane 34278 Composite EPA 625 10 Less than ug/L Bis(2-chloroethyl) ether 34273 Composite EPA 625 10 Less than ug/L Bis (2-chloroisopropyl) ether 34283 Composite EPA 625 10 Less than ug/L Bis (2-ethylhexyl) phthalate 39100 Composite EPA 625 10 Less than ug/L 4-bromophenyl phenyl ether 34636 Composite EPA 625 10 Less than ug/L 3utyl benzyl phthalate 34292 Composite EPA 625 10 Less than ug/L ?-chloronaphthalene 34581 Composite EPA 625 10 Less than ug/L 4-chlorophenyl phenyl ether 34641 Composite EPA 625 10 Less than ug/L Chrysene 34320 Composite EPA 625 10 Less than ug/L Form - DMR- PPA-1 Page 2 Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month May Outfall 001 Year 2017 Parameter Sample Analytical Quantitation Sample Units of Parameter Code Type Method Level Result Measurement Di-n-butyl phthalate 39110 Composite EPA 625 10 Less than ug/L Di-n-octyl phthalate 34596 Composite EPA 625 10 Less than ug/L Dibenzo(a,h)anthracene 34556 Composite EPA 625 10 Less than ug/L 1,2-dichlorobenzene 34536 Composite EPA 625 10 Less than ug/L 1,3-dichlorobenzene 34566 Composite EPA 625 10 Less than ug/L 1,4-dichlorobenzene 34571 Composite EPA 625 10 Less than ug/L 34631 Composite EPA 625 10 Less than L ug 3,3 dichlorobenzidine p ug/L phthalate 34336 Composite EPA 625 10 Less than ug/L Dimethyl phthalate 34341 Composite EPA 625 10 Less than ug/L 1 2,4-dinitrotoluene 34611 Composite EPA 625 10 Less than ug/L 2,6-dinitrotoluene CO626 Composite EPA 625 10 Less than ug/L 1,2-diphenylhydrazine 34346 Composite EPA 625 10 Less than ug/L Fluoranthene C0376 Composite EPA 625 10 Less than ug/L Fluorene 34381 Composite EPA 625 10 Less than ug/L Hexachlorobenzene CO700 Composite EPA 625 10 Less than ug/L Hexachlorobutadiene 39702 Composite EPA 625 10 Less than ug/L Hexachlorocyclo-pentadiene 34386 Composite EPA 625 10 Less than ug/L Hexachloroethane 34396 Composite EPA 625 10 Less than ug/L Indeno(1,2,3-cd)pyrene 34403 Composite EPA 625 10 Less than ug/L Isophorone 34408 Composite EPA 625 10 Less than ug/L Naphthalene 34696 Composite EPA 625 10 Less than ug/L Nitrobenzene 34447 Composite EPA 625 10 Less than ug/L N-nitrosodi-n-propylamine 34428 Composite EPA 625 10 Less than ug/L N-nitrosodimethylamine 34438 Composite EPA 625 10 Less than ug/L N-nitrosodiphenylamine 34433 Composite EPA 625 10 Less than ug/L Phenanthrene 34461 Composite EPA 625 10 Less than ug/L Pyrene 34469 Composite EPA 625 10 Less than ug/L 1,2,4,-trichlorobenzene 34551 Composite EPA 625 10 Less than ug/L "I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system,or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations." Authorized Represeenttaative/n,,am�e Signa, re 0//5/00/ ---7 Date Form- DMR- PPA-1 Page 3 Annual Monitoring and Pollutant Scan Permit No. NCO030210 Month May Outfall 001 Year 2017 Facility Name: Mallard Creek WWTP ORC Mr. Darrell Dewitt Date of INFLUENT sampling: 5/9/2017 Phone (704J 547-0680 Analytical Laboratory: CHARLOTTE WATER Environmental Lab--NC 192; and Prism Lab NC 402 Parameter Sample Analytical Quantitation Sample Units of Parameter - Code Type Method Level Result Measurement Ammonia (as N) C0610 Composite SM 4500-NH3-H-11' 1.0 33 mg/L Chlorine(total residual,TRC) 50060 Grab Hach 10014ULR 15 N/A ug/L Dissolved Oxygen 00300 Grab ASTM D888-09C 1.0 N/A mg/L Nitrite plus Nitrate Total(as N) 00630 Composite EPA 353.2-93 0.05 Less than mg/L Total Kjeldahl Nitrogen 00625 Composite EPA 351.2-93 2.5 46 mg/L Oil and Grease 00556 Grab EPA 1664B 5.0 21 mg/L Total Phosphorus C0665 Composite SM 4500P-H-11 0.10 5.40 mg/L Total Dissolved Solids 70295 Composite SM 2540C-11 25 N/A mg/L Hardness 00900 Composite EPA 200.7 1.0 N/A mg/L Metals(total recoverable), cyanide and total phenols Antimony 01097 Composite EPA 200.8 5.0 Less than ug/L Arsenic 01002 Composite EPA 200.8 5.0 Less than ug/L Beryllium 01012 Composite EPA 200.7 5.0 Less than ug/L Cadmium 01027 Composite EPA 200.8 1.0 Less than ug/L Chromium 01034 Composite EPA 200.8 5.0 Less than ug/L Copper 01042 Composite EPA 200.8 2.0 17 ug/L Lead 01051 Composite EPA 200.8 5.0 Less than ug/L Mercury COMER Composite EPA 245.1 0.2 Less than ug/L Nickel 01067 Composite EPA 200.8 2.0 3.4 ug/L Selenium 01147 Composite EPA 200.8 5.0 Less than ug/L Silver 01077 Composite EPA 200.8 5.0 Less than ug/L Thallium 01059 Composite EPA 200.8 5.0 Less than ug/L Zinc 01092 Composite EPA 200.8 50 93 ug/L Cyanide 00720 Grab 10-204-00-1-X 10 Less than ug/L Total phenolic compounds 32730 Grab EPA 420.2 0.050 0.060 mg/L Volatile organic compounds Acrolein 34210 Grab EPA 624 100 Less than ug/L Acrylonitrile 34215 Grab EPA 624 100 Less than ug/L Benzene 34030 Grab EPA 624 5 Less than ug/L Bromoform 32104 Grab EPA 624 5 Less than ug/L Carbon Tetrachloride 32102 Grab EPA 624 5 Less than ug/L Chlorobenzene 34301 Grab EPA 624 5 Less than ug/L Chlorodibromomethane 34306 Grab EPA 624 5 Less than ug/L Chloroethane 85811 Grab EPA 624 10 Less than ug/L 2-chloroethyl vinyl ether 34576 Grab EPA 624 10 Less than ug/L Chloroform 32106 Grab EPA 624 5 Less than ug/L )ichlorobromomethane 32101 Grab EPA 624 5 Less than ug/L ,1-dichloroethane 34496 Grab EPA 624 5 Less than ug/L 1,2-dichloroethane 32103 Grab EPA 624 5 Less than ug/L Trans-1,2-dichloroethylene 34546 Grab EPA 624 5 Less than ug/L Form - DMR- PPA-1 Page 1 Annual Monitoring and Pollutant Scan . Permit No. NC0030210 Month May Outfall 001 Year 2017 Parameter Sample Analytical Quantitation Sample Units of Parameter Code Type Method Level Result Measurement 1,1-dichloroethylene 34501 Grab EPA 624 5 Less than ug/L 1,2-dichloropropane 34541 Grab EPA 624 5 Less than ug/L 1,3-dichloropropylene 77163 Grab EPA 624 5 Less than ug/L Ethylbenzene 34371 Grab EPA 624 5 Less than ug/L Methyl Bromide 34413 Grab EPA 624 10 Less than ug/L Methyl Chloride 34418 Grab EPA 624 10 Less than ug/L Methylene Chloride 34423 Grab EPA 624 5 Less than ug/L 1,1,2,2-tetrachloroethane 81549 Grab EPA 624 5 Less than ug/L Tetrachloroethylene 34475 Grab EPA 624 5 Less than ug/L Toluene 34010 Grab EPA 624 5 Less than ug/L 1,1,1-trichloroethane 34506 Grab EPA 624 5 Less than ug/L 1,1,2-trichloroethane 34511 Grab EPA 624 5 Less than ug/L Trichloroethylene 39180 Grab EPA 624 5 Less than ug/L Vinyl Chloride 39175 Grab EPA 624 10 Less than ug/L Acid-extractable_compounds P-chloro-m-creso 34452 Composite EPA 625 10 Less than ug/L 2-chlorophenol 34586 Composite EPA 625 10 Less than ug/L 2,4-dichlorophenol 34601 Composite EPA 625 10 Less than ug/L 2,4-dimethylphenol 34606 Composite EPA 625 10 Less than ug/L 4,6-dinitro-o-cresol 34657 Composite EPA 625 20 Less than ug/L 2,4-dinitrophenol 34616 Composite EPA 625 50 Less than ug/L 2-nitrophenol 34591 Composite EPA 625 10 Less than ug/L 4-nitrophenol 34646 Composite EPA 625 10 Less than ug/L Pentachlorophenol 39032 Composite EPA 625 20 Less than ug/L Phenol 34694 Composite EPA 625 10 12 ug/L 2,4,6-trichlorophenol 34621 Composite EPA 625 10 Less than ug/L Base-neutral compounds Acenaphthene 34205 Composite EPA 625 10 Less than ug/L Acenaphthylene 34200 Composite EPA 625 10 Less than ug/L Anthracene CO220 Composite EPA 625 10 Less than ug/L Benzidine 39120 Composite EPA 625 50 Less than ug/L Benzo(a)anthracene 34526 Composite EPA 625 10 Less than ug/L Benzo(a)pyrene 34247 Composite EPA 625 10 Less than ug/L 3,4 benzofluoranthene 34230 Composite EPA 625 10 Less than ug/L Benzo(ghi)perylene 34521 Composite EPA 625 10 Less than ug/L Benzo(k)fluoranthene 34242 Composite EPA 625 10 Less than ug/L Bis(2-chloroethoxy)methane 34278 Composite EPA 625 10 Less than ug/L Bis(2-chloroethyl) ether 34273 Composite EPA 625 10 Less than ug/L Bis(2-chloroisopropyl) ether 34283 Composite EPA 625 10 Less than ug/L Bis(2-ethylhexyl) phthalate 39100 Composite EPA 625 10 Less than ug/L 4-bromophenyl phenyl ether 34636 Composite EPA 625 10 Less than ug/L `3utyl benzyl phthalate 34292 Composite EPA 625 10 Less than ug/L chloronaphthalene 34581 Composite EPA 625 10 Less than ug/L 4-chlorophenyl phenyl ether 34641 Composite EPA 625 10 Less than ug/L Chrysene 34320 Composite EPA 625 10 Less than ug/L Form - DMR- PPA-1 Page 2 Annual Monitoring and Pollutant Scan Permit No. NC0030210 Month May Outfall 001 Year 2017 Parameter Sample Analytical Quantitation Sample Units of Parameter Code Type Method Level Result Measurement Di-n-butyl phthalate 39110 Composite EPA 625 10 Less than ug/L Di-n-oc ty 1 phthalate 34596 Composite EPA 625 10 Less than ug/L Dibenzo(a,h)anthracene 34556 Composite EPA 625 10 Less than ug/L 1,2-dichlorobenzene 34536 Composite EPA 625 10 Less than ug/L 1,3-dichlorobenzene 34566 Composite EPA 625 10 Less than ug/L 1,4-dichlorobenzene 34571 Composite EPA 625 10 Less than ug/L 3,3-dichlorobenzidine 34631 Composite EPA 625 10 Less than ug/L Diethyl phthalate 34336 Composite EPA 625 10 Less than ug/L Dimethyl phthalate 34341 Composite EPA 625 10 Less than ug/L 2,4-dinitrotoluene 34611 Composite EPA 625 10 Less than ug/L 2,6-dinitrotoluene C0626 Composite EPA 625 10 Less than ug/L 1,2-diphenylhydrazine 34346 Composite EPA 625 10 Less than ug/L Fluoranthene C0376 Composite EPA 625 10 Less than ug/L Fluorene 34381 Composite EPA 625 10 Less than ug/L Hexachlorobenzene C0700 Composite EPA 625 10 Less than ug/L 1 Hexachlorobutadiene39702 Composite EPA 625 , 10 Less than ug/L Hexachlorocyclo-pentadiene 34386 Composite EPA 625 10 Less than ug/L Hexachloroethane 34396 Composite EPA 625 10 Less than ug/L Indeno(1,2,3-cd)pyrene 34403 Composite EPA 625 10 Less than ug/L Isophorone 34408 Composite EPA 625 10 Less than ug/L Naphthalene 34696 Composite EPA 625 10 Less than ug/L Nitrobenzene 34447 Composite EPA 625 10 Less than ug/L N-nitrosodi-n-propylamine 34428 Composite EPA 625 10 Less than ug/L N-nitrosodimethylamine 34438 Composite EPA 625 10 Less than ug/L N-nitrosodiphenylamine 34433 Composite EPA 625 10 Less than ug/L Phenanthrene 34461 Composite EPA 625 10 Less than ug/L Pyrene 34469 Composite EPA 625 10 Less than ug/L 1,2,4,-trichlorobenzene 34551 Composite EPA 625 10 Less than ug/L "I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system,or those persons directly responsible for gathering the information,the information submitted aware that there are significantpenalties for submittingfalse the best of myknowledge and belief,true,accurate,and complete. I amw gm is,to gp information,including the possibility of fines and imprisonment for knowing violations." Authorized Representative name 4,v_____ • fri - iz ature ___12&3_4_ 7_________ Date Form- DMR- PPA-1 Page 3 Attachment #8 E"Jj'm'!'c. (864)877-6942 • Fax(864)877.6938 P n Rnx 16474,Grnenville, 3C 21161.ti 4 Craftsman Court,Greer,5C 29650 Fathead Minnow Survival and Growth Test EPA-821-R-02-013 Method 1000 Fp! Client: CHARLOTTE MECKLENBURG UTILITIES DEPT Facility:MALLARD CREEK WRF NPDES#:NC0030210 Test Date: 28-May-14 1 Laboratory ID#: T43460 P.PROMELAS 5-28 Test Reviewed and Approved By: Robert W.Kelley,Ph.D. Farhad Rostampour QA/QC Officer Laboratory Director ii - E Certification#E87819 SCDHEC Certification#23104 Test results presented in this report conform to all requirements of NELAC,conducted under NELAC Certification Number E87819 Florida Dept.of Health.Included results pertain only to provided samples. NCDENR Certification# 022 Page 1 of 8 Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test Date: 6/9/2014 Facility: CMUD Mallard Creek WRF NPDES#NC0030210 Pipe#: 001 County: Mecklenburg Laboratory: ETT Environmental,Inc. Comments x %�/� Signature of Operator in Resp i har�i'�C ORC Phone/Email x Signature of Laboratory Supervisor MAIL ORIGINAL TO: Environmental Sciences Section Division of Water Resources NC DENR 1621 Mail Sservlce Center Raleigh,NC 27699-1621 Test Initiation Date/Time 5/28/2014 1435 Avg Wt/Surv.Control 0.9245 Test Organisms %Eff. Repl. 1 2 3 4 - Cultured In-House Control Surviving# 9 9 9 9 %Survival 90% x Outside Supplier Original# 10 10 10 10 Wt/original(mg) 1.0090 0.7890 0.7160 0.8140 Avg Wt(mg) 0.8320 Hatch Date: 5/27/2014 23% Surviving# 9 10 10 9 %Survival 95% Hatch Time: 1100-1300 Original if 10 10 10 10 Wt/original(mg) 0.7900 0.9520 0.7700 0.8370 Avg Wt(mg) 0.8373 45% Surviving# 9 8 9 8 %Survival 85% • Original# 10 10 10 10 Wt/original(mg) 0.8400 0.6760 0.9460 0.9580 Avg Wt(mg) L 0.8550 60% Surviving# 8 9 9 10 %Survival 90% Original# 10 10 10 10 Wt/original(mg) 0.8140 0.8470 0.9380 0.8920 Avg Wt(mg) L 0.8728 90% Surviving# 8 9 9 9 %Survival 87.5% Original# 10 10 10 10 Wt/original(mg) 0.9480 0.4110 0.9080 1.0020 Avg Wt(mg) 0.8173 100% Surviving ft 7 7 8 8 %Survival 75.0% Original# 10 10 10 10 Wt/original(mg) 0.5870 0.7900 0.8550 0.9170 Avg Wt(mg) 0.7873 1 1 Water Quality Data Day Control 0 1 2 3 4 5 6 u pH(SU)Init/Fin 8.0/ 7.7 8.0/ 7.6 8.0/ 7.9 8.1/ 7.5 7.9/ 7.9 8.0/ 7.5 7.9/ 7.9 r DO(mg/L)Init/Fin 8.1/ 6.4 7.9/ 6.5 7.8/ 7.7 7.7/ 6.7 7.7/ 7.1 8.3/ 6.0 8.2/ 7.s i Temp©Init/Fin 24.1/ 24.6 24.3/ 24.9 24.9/ 24.8 24.8/ 24.6 24.2/ 24.7 24.7/ 24.9 24.9/ 24.8 High Concentration 0 1 2 3 4 5 6 1 pH(SU)Init/Fin 7.9/ 7.9 7.9/ 8.0 8.0/ 8.0 8.0/ 7.8 8.1/ 8.0 7.9/ 7.9 7.8/ 7.9 DO(mg/L)Init/Fin 8.1/ 6.3 8.3/ 7.1 8.4/ 6.8 8,2/ 6.5 8.1/ 6.5 8.4/ 6.8 8.1/ 7.3 Temp©Init/Fin 24.1/ 24.6 24.3/ 24.9 25.0/ 24.8 24.8/ 24.6 24.2/ 24.7 24.9/ 24.9 25.0/ 24.8 Sample 1 2 3 SurvivalGrowth Overall Result Collection Start Date 05/26/14 05/28/14 05/29/14 Normal yes no ChV 94.9% r Grab Horn.Var. no yes Composite(Duration) 24 hour 24 hour 24 hour NOEC 90% 100% Hardness(mg/L) 125.4 125.4 125.4 LOEC 100% >100% f Alkalinity(mg/L) 78.2 71.7 65.4 ChV 94.9% >100% Conductivity(umhos/cm) 495 501 507 Method Steels RS Steels RS • Chlorine(mg/L) 0.11 <0.05 <0.05 Temp.at Receipt(C) 3.4 3.3 2.6 Stats Survival Growth Conc. Critical Calculated Critical Calculated Dilution H2O Hardness(mg/L) 49.9 23% 10 22 10 19 Alkalinity(mg/L) 41.5 45% 10 14 10 19 Conductivity(umhos/cm) 205 60% 10 18 10 22 90% 10 16 10 19 r 100% 10 10 10 18 Y DWQ form AT-5 revised 2/2013 e ti Page 2 of 8 CHRONIC DEFINITIVE SURVIVAL AND REPRODUCTION/GROWTH TEST Statistical Analyses Client: Charlotte Mecklenburg/Mallard Creek Sample Identification: MALLARD Test Date: 28-May-2014 Tests for Normality and Heterogeneity of Variance Sample Use Parameter Test Used Result Sample Date Sample Used Normality N/A N/A Sample A 26-May-14 28-May-14 29-May-14 Variance N/A N/A Sample B 28-May-14 30-May-14 31-May-14 Sample C 30-May-14 01-Jun-14 02-Jun-14 03-Jun-14 Tests for Differences in Survival and Growth Concentration-Response: Survival Test Type Used: Linear Interpolation 100% W 80% %Effluent ,2 ■ ■ ■ ■ ■ ■ Effect Control 23.0% 45.0% 60.0% 90.0% 100.0% N 60% W k Survival 90.0% 95.0% 85.0% 90.0% 87.5% 75.0% 7 40% %reduction 0.0% 0.0% 0.0% 0.0% 18.9% 20% Growth 0.832 0.837 0.855 0.873 0.817 0.787 ed17Vt 230% 45 Coe 600% 900% 100.0% %reduction(smoothed) 0.0% 0.0% 0.0% 3,8% 7.3% i Test Concentration .ICU n`d`i° f ar,R. Variance 0.064 0.007 0.017 0.003 0.075 0.021 Acceptability Criteria Value Upper Limit Lower Limit Conorntrallor-R sr R / rspon rproducllonGrow h 0 0 CV:Coeff.ofVariation 26.4% 42.0% 8.9/0 PMSD: 0 0 o p 1 MS .%MSD 29.2/0 30.0% 12.0% �+ MSD:Min.Sign.Diff. 0.280 Acceptability criteria limits not exceeded t3 0.60 ■ ■ ■ e ■ e IC25 Point Estimates TEST RESULTS S 0 .60s Survival IC25->100.0% %Reduction per Linear Interpolation N 0.40 Growth IC25=>100.0% @CTC of 0.0% t Hypothesis Testing Survival effect NA a 0.20 NOEC Growth 100.0% Growth effect NA 0 Carrot 220 fpr 10.0% 90Ae6 1000% CI Moduli oChV Growth > 100.0% PASS Test Concentration f rerNJI Comments Page 3 of 8 a z 33 - 0 Q) A N (, i _ ' p O 0 U1 CJ 0 O 3 a O n 0 — 4 10 m m 0 C) m > S L) m m 0 C) m >IT C) N m 0 C) In S C) mr m 0 0 m I C) m Cil 0 0 m > I 0 m m 0 C) m > m , N N 0 0 0 0 0 0 0 - 0 0 0 - .-, 0 0 0 0 0 0 0 a 0 A A 9 en CJ ' 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0000T. IT _ o a o o -+ o -+ -. 0 0 0 0 - O -. -. 0 0 0 o a 0 a a 0 A Ut v n C) s N CD O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 = Tr'''. N N m 0 0000 0 o 0 0 0000 0 --, o 0 0 0 0 0 0 o 0 0 ¢ R A A C C i J CD'CD o 0 0 0 0 0 0 0 0 0 0 0 0 0 o c o 0 0 0 0 0 0 0 fir.. 0 0 - 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 a Fp A A r a CA n) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 coca )) O o o -• 0 0 0 0 o O _. o 0 0 -. 0 0 0 0 0 o O 0 o p yF, co ?A e n s �1 CO 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o a 0 0 0 0 0 0 0 o w rn 0 N0 NJ 0 -• 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a F ACA > - - CO O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 « rn N O N O 0 0 0 0 0 - 0 -+ 0 0 0 0 00 0 0 0 0 a O N ¢ A co 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 V 5D m m m 0 m " n) 0 _ ¢ N o j m m m m m m i, N J ()1 a V0 m -. m N 0 J d. 0 0) m > J V (O L m 0 (0 S '_''i . ns 0 O Ln c 0. O _ J 0 -\ - Co Oa m m o 0 0 o (n m CO CO m CO CO m o o 0 m o m o m A m 2-_,,i. 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J V V J -D [v (O -, O m N [O (O (O Cn CO N CD co V1 O co C7 '"' i - . ......_ • IHII.TTCHAIN OF CUSTODY RECORD __.y-tTi�•- ,.,,.,,����� - .--:*-F-"_...----:-.1-- e e 0 600• 'td �Pa>_e of I PO Box 16414,Greenvitre,SC 25606.7414 t (884)877-6942, (800)691-2325 Fax:(884)877 8938 Shipping Address:4 Craftsman Cl,Greer,SC 29650 tnVw.RrCNVIRCN.f YNYAL.GOH Client: 4/, r .1' 'U V Program Containers Preservative Parameters Facility: I{-511t--14 C-ek\t• (u c F \..----_._.....—Whale Eineeet Toxicity State: N C.. NPDLS 11: IJC VIP' u1.1(✓5 0 Acute (Ironic Tat Organisms Q `e5 Q CI (Composite only) ((tab or Composite) c r o �? c n Z v o 4.1 U _ c .n .� p Sign,and Print below 3 y e'er o e c 2-ltd J n c 5_• w 2 z w Vi C > < (j the dotted line e € �• N^p U i yQtt 5. =� 'r O E A , V' * _ , •O L n Q SA1vMPLE ID (2 C°mpo.ite Stan Dste Time Sumpl;Cdlvian Dslc Time Collected by U y v) Z� C 5 j Y u - `e - = �' fD e _ e.p,y;r F f U U U D in — U Chemical Analysis SOther In•s.c• C. 5••2 G•-i-k t3rb�. s•-. 1,-19 SSD 1 �-�{ i X X Gr QC-,lOerct X 3 X lE3 at • ry • CD 0 OD ` � _� t -- Speeiallnstrucuoss: )e 10 �cL!$'j- t Sd . \ rt! r� SAM ���C'Sl'(1. !1� OrC?J 1 te~ �G_ �-Ctrn(� ej�.'i t� t�C� r:.�loa .-4 v a.s‘� Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished By/Organization Received B7IOroanizatiou QS, \\„.„.4 c (� "eovi,e.r 1, Area Tema°C Preserved? 5-x7-ie( aa Y 1• I(\c\\e-I. .( (tpe> &. Kw-0 _i,:215 /`� �._aai:----,s�rJe3afar - - -- 'h s�y�l�T ,-2 4- P re -4.- " ,�<o�.-- ' -c124/,e /1� ttGavvi t:(rt 0� 6 ; l7/ ,•' �1 t w` 7r '/���"<<.�LS, . 2 j ' a�� - rfio.. :� .�4L &ce t� f ii,4�j35s I) - r (I (Crr ) '', 7.).Li • COMP SITE SAMPLING ROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:1 sample each hour for 24 hours.Equal roles 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample). or at minimum I sample every 4 hours over24 hours. Sample may nor be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit p(isss-t.-4,. Cam - (0.e.Th S..o......-.....,--t.,--, c-1 2%\1- —1"'a_ ETTCRA N OF CUSTODY RECORD Pam of PO Box 16414.Greenville.SC 29606-7414 (864)877-6942. (800)891-2325 Fac(864)877 6938 Shipping Address:4 Craftsman Ct,Greer,SC 29650 www.tTPCMV.0 I7 rrALCOM Client C n ti 1, rProgram Containers Preservative Parameters Facility:f A114.r /Creek PRI"' �f Whole Effluent Toxicity uu ►State: /VC— NPDES#: /V C.. n 0 3 D a pcn Acute Jhroaf0 Test Organisms U (Composite only) (Grab or Composite) rn < 7F-• 2 U _t v o _ Z U " . = 1=FL50. = = _ — t-,' ° s Sign,and Print below 3 = E. E o '-HC ^ _ = = oa z = _ >. . v the dotted line e = C O .2 .t.' -mos '_ - "� v = _ _o < Cj N O o- Vl N O 4.Naom .. C O 1• C r .I -'5" N SAMPLE ID Composite Stan Darcl Time Sample Collection Date Time Collected by U c0 r/] Z ��_ C U > 6=pdaa < < J J U 6 E 2 iTi s U = L Chemical Analysis&Other . ✓ICY - . Ar ` C.-9 ly e 5—)-5)-11 TA 5 �_k/i , , 3 X g X ) �- t ,a CD O Co • • Special Instructions: S' 4 j ,gr 5"C f-- i,v-,p 3:-6 .•c_1 - Sample Custody Transfer Record Secure Receipt Sample Date Time / Relmqu ed bYy/,IOraanization Received By/O1Eanization Area Temp°C Preserved? i7ii:P� / �, C ,�,I _i1� /7 / .� b..t I I I p t�1300 - lA>r t( 177-7;' ) to-Ltri cr J L �, COMPOSITES4MPLING ROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must fist be used within 36 hours Time Proportional:1 sample each hour for 24 hours.Equal volui 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags_ of sample collection(completion of composite sample). or at minimum I sample every 4 hours over 24 hours_ Sample may not be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit _ _ ETT „._. CHAIN OF CUSTODY RECORD J "Fu"-' 3y_ oe”:—1 !Page of 1._ PO Box 1 6414.GRLxrwrLl_r,SC 29506-7414 13541 377-5942. 13001 591-2323 F4x:128.51 577 5533 5NI1,PINS A.SDSZSS:4 Cu.5r SM14N Cr.900185.SC 29550 W 1VW.rrrtnvI RGNrg,ITF.LCON Client: /// \\\ (:,- > /J 4 ( A4 c ( 1 cc t...oe ( k'• ) Program Containers Preservative Parameters Facility: Whole Effluent Toxicity State: \'PDF.$T_ 1 Acute Chronic Test organisms e I 6 0 — 1 _ o Ti — V ` U 5. .(Comoat.-only) (Grab or Composite) < o c o .. pG - P - c 1.}5504 3 E 4oc L3.141,203 — = rnL o a zom ^ CU y S. o = ,o, o — = ` m = P C , i— , v2n O o 0 .znAe o y — T .j, t; VSAMPLE ID ✓CCempm}teStartDme Time Sample CoUu2c Docl Time Collected by U vi c. Z eto E. U > ` c-o.� v � O .. 2 w_s � �3 � Chemical Analysis&Other 5 cr c 5-xi-1L\ bs-30-1‘l 6918111 )11iNf\&9- I i 1 X I I I I IX I I I I QI I ;�v1 say I I .-vi I I I I_ co I I I I II 0. I I I CO I III VIII I I II I I I I ] IIHLL I ._ IIII I 1 Special Instructions: ` }� i j /� (� �} 1.'� Cl?c el' \` ) � ��C L`.�f� � 4(. S a cl .or .eI Sample Custody Transfer Record Somme Receipt Sample Date Time Relina - ed By/0 nation -.... -ivied By/Orga -.ti Area Temp'C Preserved? 5=10-1‘‘ bMsl .- --e� di . i �o j,:�.(,.,- I I idde 3Q 14113631 —) �� _ . i,. ' t,.i..6, GC r /14pro 1 I 0 LC-jiT) I 4 12_ COMPOSITE SAMPLING 'tI OCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TI!IT PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:I sample each hour for 24 hours-Equal volur 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample). or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Flow Proportional-As per ins-auctions in?v?DES permit. • r1 .. :q dt�' • nu€rortrtt rag 4,Iran. (8$4}877-6942 . Fax(85:)377-6938 PQ Rax 9FA14.Grer?nvttir.SC 2`dile, 4 Gran ;nan C atert.Greer,$C 290'30 • Fathead Minnow Survival and Growth Test EPA-821-R-62-513 Method 1000 Client: CHARLOTTE MYIECKLE NBURG UTILITIES DEPT Facility:MALLARD CREEK WRF NPDES#:NC0030210 Test DAte,: 10-Fob-z5- Laboratory ID#:T43642 P.PROMELAS 2-is Test Reviewed and Approved By: Robert Vt.Kelley.Ph.D. Farhad Rostampour QA/QC Officer Laboratory Director SHIPPED 6/11/14 BILLED 6/23/14 • t: 5_h �,. ,,t+„a 'k .Certification#E87819 SCDBFC Certification#23104 Test r llts presented in this report conform to all requirements of NELAC,conducted underNE.LAC Certification Number E81819 Florida Dept of Health.looluded rwalts pertain only to provided samples, NCDENR Certification# 022 Page 1 of 7 Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test Facility: CMUD Mallard Creek NPDES 6 NC00 0030210 . Pipe#: 001 County: Mecklenburg Laboratory: ETT EnvironmenjaL,Inc. - , Comments Signature of Operator inResponsibleCharge x ,pa4 W 4. Signature of Laboratory Supervisor MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh,NC 27 699-1 62 1 Test Initiation Date/Time 10-Feb-15 / 1647 Avg Wt/Surv.Control 0.8465 Test Organisms %Eff. Rept. 1 2 3 4 I rCultured In-House IControl Surviving# 10 10 10 10 %Survival! 100.0% I QX Outside Supplier Original# 10 10 10 10 Wt/original(me) 0.7140 0.9450 0.9040 0.8230 Avg Wt(mg) 0.8465 Hatch Date: 2-9-15 l 23 Surviving#b 10 10 10 10 %Survival 100.0% Hatch Time: 0730-0900 Original# 10 10 10 10 Wt/original(mg) 0.7570 0.7620 0.8120 0.7110 Avg Wt(mg) 0.7605 451 Surviving# 10 10 10 9 %Survival 100.0% Original# 10 10 10 9 Wt/original(mg) 0.6750 0.7850 0.6950 0.8000 Avg Wt(mg)l 0.7383 60 Surviving# 10 10 9 10 %Survival 100.0% Orginal# 10 10 9 10 WVoriginal(mg) 0.6750 0.6770 1 0.8411 0.7260 Avg We(ma) 0.7293 90 Surviving# 9 40 10 1 9 %Survival 100.0% Original# 9 10 10 9 WUoriglnal{mg) 0.8279 0.9730 0.9210 0.7567 Avg Wt(mg) 0.8696 100 Surviving# , 10 9 9 10 %Survival l 97,5% Original# 10 10 9 10 1 WVoriginal(mg) 0.8500 0.6510 0.9478 0.8390 Avg Wt(mg)l 0.8220 Water Quality Data Day Control 0 1 2 3 4 sti 5 6 pH(SU)InIt/FIn 8.3 I 7.6 8.0 1 7.7 18.1 1 7.3 8.0 / 7.1 8.2 / 7.9 8.1 I 7.4 8.1 / 7.3 DO(mg/L) Init/Fin 7.8 / 6.5 7.9 1 6.2 18.0 / 5.2 7.7 1 6.3 7.9 / 5.7 7.2 / 6.2 7.4 / 6.8 Temp(C)Init/Fin 24.6 / 25.0 25.0 1 25.1 1 25.1 / 25,0 24.7 / 25.7 24.5 / 24.7 24.7 1 24.9 24,1 / 25.1 High Concentration 0 1 2 3 4 5 6 pH(SU)!nit/Fin 7.8 / 7.8 7.7 / 7.6 7.3 / 7.6 7.7 / 7.2 7.2 / 7,6 7.6 / 7.5 7.4 / 7.8 DO(mg/L) !nit/Fin 7.8 / 6.7 8.0 1 6.0 8.0 / 6.1 7.9 / 6.2 8.4 1 6.3 8.0 / 5.4 8.1 / 5.3 Temp(C)lnit/Fin 25.0 / 25.0 25.0 I 24.7 24.7 1 25.0 24.5 I 25.0 24.4 I 25.0 24.5 / 24.9 24.3 I 20,8 Sample 1 2 3 Survival Growth Overall Result Collection Start Date 2-9-15 2-11-15 I 2-12-15 Normal D no I I yes Ch/ >100% Grab I Horn.Var. O no eyes Composite(Duration) _ 24 hr 24 hr 24 hr NOEC 100.0% 100.0% Hardness(mg/L) 124.0 124.0 128.0 LOEC >100% • >100% Alkalinity(mg/L) 76.0 62.3 63.6 ChV >100% >100% Conductivity(umbos/cm) 498 483 494 Method Steels Dunnetts Chiorine(mg/L) <0.05 <0.05 0.07 Temp at Receipt(C) 0.8 1,7 2.0 Stats Survival Growth Cont. Critical Calculated Critical Calculated Dilution H2O 23 10 18 2.41 1.38 Hardness(mg/L) 50.0 45 10 16 2,41 1.73 Alkalinity(mg/L) 53.80 60 10 16 2.41 t87 Conductivity(umhoslcm) 213 90 10 14 2.41 _ -0.37 100 10 14 2.41 0.39 • Page 2of7 DWQ Form AT-5(1/04) . CHRONIC DEFINITIVE SURVIVAL AND REPRODUC ION/GROWTH TEST Statistical Analyses Client Charlotte Meelclenburg/Mallard Creek Pimephales promelas Sample Identification: MALLARD Second Species Test Date: 10-Feb-2015 Tests for Normality and Heterogeneity of Variance Sample Use Parameter Tei tied Result Sample Date Sample Used Normality N/A N/A Sample A 09-Feb-IS 10-Feb-1S 11-Feb-15 Variance N/A • N/A Sample 13 11-Feb-15 12-Feb-I5 13-Feb-15 Sample C 12-Feb-15 14-Feb-15 15-Feb-15 16-Fcb-15 , Tests for Differences in Survival and Growth Conceni olt R use=Survival Test Type Used Linear Interpolation t0 l7 SI = .m 74 OM %Efluent CS ^- 37 - IS CS to - 13 G finli Effect Control 23.0% 45.0% 60.0% 90.0% 100.0% o° c w Survival 100.0% 100.0% 100.0% 100.0% 100.0% 97.4% . _1r. • %reduction 0.0% 0.0% 0.0% 0.0% 2.6% 20%. Growth 0.847 0.761 0.737 0.727 0.874 0.819 CS .ac-o y %reduction(smoothed) 0.0% 0.0% 0.0% 0.0% 7.5% Test Con eni1a n a=',TM.= Variance 0.0104 0.0017 0.0040 0.0061 0.0093 0.0154 Acce tabilty Critetsa Value Upper Limit Lower Limit CoocelttratIors•Response Reproductsrm SGsoveaz CV:Coeff of Variation 12.0% 42.0% 8.9% PMSD:%MSD 16.6% 30.0% 12.0% ,e - } a � MSD:Min.Sign.WE 0.1 Acceptability criteria limits not exceeded t• O.a? �"-� 1C25 Point Estimates TEST RESULTS f°y 020 1 Survival /c25.• >100% %Reduction per Linear Interpolation '.7.) o 45,0.40 Growth 1C25= >100% (a,CTC of 90.0% elcc hypothesis Testing Survival effect 0.0% 4' M 0 NOECGrowth 100.0% Growth effect 0.0% • 0 ,.,; :.Ca ,sx, aCg i<5.04> , o Test Ctanxntation G.", CI1V Growth > 100.0/0 PASS 3' 1Coments -- in i Page 3 of 7 • o ° $ ( W 0 2O € (0 i10 u 0 0 a o ii } II m mo0 [oDxo 'n • o W D 41 -nmO0 WDI rmO0a1D 0111M0041D247mIn00� Da -0 Ii (, L 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 g p, N n < N,Ai o .� u,b 0000 - 0001, 0000 00 00 0000000 b °: 77 Is L 7 000011 b b b d •0 0 0 0.p, O• ' V V 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 . , 0 0 0 0 0. 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1\34-'s vw U1 b1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - F', 1 ',:i' N rp c - 0 0 0 0 0 0 0 0 0 0.0 0 0 0 0 0 0 0 0 0 0 0 0 o s a N 'P o 0 L7P O 0 0 0 0 0 O� O O O Or P 0 0 0 O O O O O b o o V- o 0 0 0 O. 0 0 0 O, 0 0 0 0 O O O O O O: 0 0 0 O p, O N Iv t a' 2111 o cn .Gn U1 ' 0 0 0 0 0 0 0 10 0 0 0 0 0 0 0000 0 0 0 0 F- O O 0 P • 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r.p o w. cfl w 0 0 0 0 _ 0 0 0� 0 0 0 0 o b o 0 0 0 0.0 0 0 0 0.� 1 io 00 .,. o. - o00 0000 00001 0000 00oba O! o -1 OJ 0 0 0 0 0 0 0 -+ 0 0 -+ 0 0 0 0 0 0 0 0000 :1 CO I - ,> N w p Ol ..f 0 0fr1 N N N 0 ,p 0 A o s o 1 •` 2 9-"o —�ii . . 3 w iee' 0 0 0 0 0 0 l0 l0 0 0 0 0 0 (0 • I 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0'0 0 0 0 0 0 0 0 G — UpziavoznA mcnp.wt� 1 zu , 1 m2 s 0 . j N N 0 - N o e. Z Z r - o N O r n '-' E x O cn Y b D N -i C N N O -p P ' j = w o A N N N N N N 4,4,4s.4s.ANA o h o O �... (7�Ol U7 U1 V U1 Cr, qJ P..;-- .........._______ .. . ETTCHAOT OF CUSTODY RECORD . .Fes.r-,:-`�_%:w--•.t_. 7 ,.' 113.1t4, 1 .t eenvEo,Sc255?414 'Page �1 Dr Pa oxt84t4,Gteenvir Sc 25358-7414 (854)877.6942,(800)831.2325 Fmc(864)877 6938 Shipping Address:4 Craftsman Ct.Greer,SC 28650 W WW.LTITNVIRONM6NTA4.00M • • Client: C. �., )) j l I� �'� ztdT i / j(—t Program Containers Preservative Parameters Moto Cm°tm t Tozier State: j C.-- NPDES'; L• V I�t Q 71D aTy} Acute Chronic Test OrOsetse s g rd (Composite only) (Grab or Composite) . o 0 % ?..• n Z .r t=t�Ses - G '� Cq I Sign,and Print beloa' $ go a 2=HCI. = E. .c B.,.a' the dotted line L a U 2 E 1-AT :g 1 3'14 u ;? 'o _ d=�aOH _ v E 4-..O v 3=2nAc o a. '? til 1# SAMPLED f7 Com/mite Start Date Time SampleCot'aaonDale Time Celleetor by. U Gl GOi a ria:. C7 ? -2 b.Diy, U !],..1; Z i73 ^ U ? $ Chemical Analysis 8 Other lh- ' ' "�—t phi c l0 0�A ii4c3 3X. �a X — tu ea y V f - -- - t SpeciallnStruCtiOnS p ." OA /::. . 1 Sample Custody Transfer Record • Secure Receipt Sample JDate Time/ R iiinnjquiiss ed B /Organizati/CIJt ' Jrc J / Receiv d By/Organization Area Temp aC Preserved? i_t 017.Vii b // " / ,/ci ...--- �i•%.c.4fl.. `ir - 0- 2, -(S 1L:-k•i N , °;t .L t •-�e ' A,- kka y . . ) o LC- 40 - , ko •1 to \ 1�, ) o.3 COMPOSITE SAMPLING 'ROCEDURE TEP•PERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 35 hours Time Proportional:1 sample each hour for 24 hours,Equal yolm 0.0 and 6.0°C.Samples must not be frozen.Use water ice in seated bags. of sample collection(completion of composite sample), or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Plow Proportional:As instructions in NPDES permit. .. „ ET' q I CHAIN OF CUSTODY RECORD _. �—; ,._s; Page of—� PO Box 18414,Greenvale,SC 20606.7414 . (864)877.6942, (800)891.2325 Fex:(864)877 6938 Shipping Address:4 Craftsman Cl,Greer,SC 205550 WWW.LTTCNVIR9NMCNYALcoM •Client: CMUD i , MEM Presort atbo Parameters Faellfty: Melo Cm°ent Toxicity — I II reelm State: N C i.+rDES 1\C GCS 3 .O Test OrgnalSmS D j , E (Composite only) (Graben-Composite) • o [ 2 S • c V ISign,and Print below 2.trot ,_ m a m r the dotted line oK :2 s '2 2 . o SAMPLE�,fn7 =2ntc a '��' �.= k1. L•1 c t_i SAMPLEID Compottleswtmte Time Samp'cCOINawlDale Tame Collected by a 6=Dd r tJ C] El! 2 2 s. U i z ChemlealAnztysis&Other i` -14 ail'15 07a' -3D•-15 i1IOI11vp�1 G 1A ��tz6. cce Special Instructions: ‘,.e.Q.,,,,„.e.c t. a,c.;.Q, Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished By I Organization - / Received B�!rgan%r lion Area Temp CC Preserved? 2-i _15 J ,t-n 'i , '�,--tet. ('1 t y ,4d, alO j» ir ( �/ I- . jito (I ( I 1 CsMP'S/TESAMPLING/ROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected overa 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:l sample each hour for 24 hours,Equal voila 0.0 and 6.0°C.Samples must not be frozen.Use water ice In sealed bags. of sample collection(completion ofeomposite sample). or at minimum i sample every 4 hours over24!tours. Sample may not be used after 72 hours from sample collection. Flow Proportional:Asper instructions in NPDES permit. • ETT e. OF CUSTODY RECORD — ''''',&: 4-7.;.:::':-.i.=;£.7-2••AC rn`':"erVt-A- 1L.4„ F--.__2--o-i=---: ITIBox16414.Gra nae,SC 29806-7414 _ (884)877-6942,(800)891-2325 Fax(884)877 6938 ShIpping Address:4 Craftsman Cl,Greer,$0 29650 WWWeETTE1VIRONMCNITALCI:214 Client: CA CI HO hit i•-41 A r Program Containers Preservative Parameters - Faci"trih,,a,,,ece kV 8 1----- Illiolo Effluent Toxicity t--,...,-,.....—... State: VC- NPDES ; /1./e.- DO'? .‘. 0 'Acuto Chronic Test Organisms _ .9- ii 23 n Is n i. -t? 8 t: ti; i co i (Composile onty) (Grab orComposito) < S g ..3 o ti 13, t3 g• .p.; was oa T-.7:- '. ) .4 z .....a- .:2 ' 0 55 1 Sign,and Print below g I.- ..a. .4-a 1.14c. P. S, I. ... to. z-E .g E ti3 e' the dotted line ". F--," § rt4' Ci 0 1.1 • 342103 .c. ,--- 4. .2.,: ...6 --....-, • i ?.. .. ., •1.5 ',-5, /2 5 4.usou 71.% .9 S.2aAc g 6 ,-- ..c ._..' =,, ...,-- W ___W SAMPLE ID 13-. CompositeSzart Date Time samou Cakction asle TIM Co/faded by k-.3 to co Z 0.0 .> -. 4.tx,n < U C3 0 II: Z.r73 :4" 0 r-- 2 Chemical Analysls&Other t,....- Y\ j .-e4--- C.- M--)D-T5 OU Vds-13-1>" D)157gifT/h( fric(re A K (3, t6\-=. 144-1(01-196 i 1:1 co c•;, --4 . o " ' Z1 • i : 1 1 - - _ - -,- -, I _ --., Special InstrucAnsp ........-- 1 __o Y..- 5;1,70 7 ---r, ' Al e79-- 56efizc/ q d—EY7/.? /6.0/tuki 4-0 7/y / Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished By/Organization, Rec.'ved By!Organization , Area Temp°C Preserved? ii3Oc- ...... ''''''''''..— C...Cia...r,t,.......—.1e1- 1 ../ -.... 41 alb tow ___. , 4 / 2-13-(,- (al 7 ._..- - 4X4/ 9, G Z..- .,-- ' I \ '' / 7'.---) • - _...I . '71- i t .. ' i k Cot,'OSITESAMFUNG tOCEDURESv TEAIPERATURE AfONITORING PROCEDURES HOLD TIME PROCEDURES 1 Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:1 sample each hour for 2,1 hours.Equal volur 0.9 and 6.0°C.Samples must not be frozen.Use water ice In sealed bags. of sample collection(completion of composite sample). or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit. i anti ranmenta,Int. (ES )B77.6042.FAX(884)877,8936 P.O,Box 1 e414,Greenville,SC 29605 4 Craftsman Cana,Greer,SC 29650 Fathead Minnow Survival and Growth Test EPA-821-R-02-013 Method 1000 Client: CHARLOTTE WATER Facility:MALLARD CREEK NPDES#:NC0030210 Test Date: 02-Aug-16 Laboratory ID#:T47451 P PROMELAS Test Reviewed and Approved By: , fWT W. -`�-L�,i,.r/,r T _. Robert W.Kelley,Ph.D. Farbad Rostamppour QA/QC Officer Laboratory Director t` Certification#E87819 SCDHEC Certification#23104 Test results presented in this report conform to all requirements of NELAC,conducted under NELAC Certification Number 1387819 I Florida Dept.of Health.Included results pertain only to provided samples. NCDENR Certification# 022 Page 1 of 7 1 ' Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test Facility; Charlotte Water Mallard Creek NPDES#NC0030210 Pipe#: 001 County: Mecklenburg Laboratory: ETT Environmental,Inc. �� Comments/ x VW, I Signature of Operator in Reppo ibl-C1arg: // • •x /G( / Signature of Laboratory Supervisor MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh,NC 27699-1621 Test initiation Date/Time 8/2/16 / 1637 Avg Wt/Surv.Control 0.661 Test Organisms %Eff. Rept. 1 2 3 4 1 (Cultured In-House Control Surviving 4 10 10 10 10 %Survival 100.0% Q X Outside Supplier Original# 10 10 10 10 Wt/original(mg) 0.6900 0.7220 0.6560 0.5750 Avg Wt(mg) 0.6608 Hatch Date: 8/1-2/16 23 Surviving# 10 10 10 9 %Survival 97.5% Hatch Time:1600-1000 Original# 10 10 10 10 Wt/original(mg) 0.6330 0.6440 0.7060 0.6610 Avg Wt(mg) 0.6610 451 Surviving# 10 10 10 10 %Survival 100.0% Original# 10 10 10 10 Wt/original(mg) 0.6320 0.7080 0.6940 0.7910 Avg Wt(mg) 0.7063 60 Surviving# 10 10 9 10 %Survival 97.5% Original# 10 10 10 10 Wt/orlginal(mg) 0.6620 0.8160 0.7440 0.6560 Avg Wt(mg)r 0.7195 90 Surviving 4 8 10 10 10 %Survival 95.0% Original# 10 10 10 10 Wt/original(mg) 0.5480 0.6740 0.7130 0.6810 Avg Wt(mg) 0.6540 1 100 Surviving# 10 10 10 10 %Survival 100.0% , Original# 10 10 10 10 Wt/original(mg) 0.7220 0.6710 0.7160 0.7260 Avg Wt(mg) 0.7088 Water Quality Data Day Control 0 1 2 3 4 6 6 i pH(SU)Init/Fin 7.7 / 7.4 7.7 / 7.5 7.8 / 7.4 7.7 / 7.4 7.6 / 7.5 7.8 / 7.6 7.9 / 7.3 DO(mg/L) Intl/Fin 8.1 / 7.2 8.3 / 6.5 8.0 / 5.7 7.6 / 5.9 7.9 / 7.0 7.8 / 6.4 8.1 / 6.1 Temp(C)init/Fln 24.4 / 26.2 24.8 / 26.2 24.7 / 25.0 24.9 / 25.6 24.7 / 25.2 24.6 / 25.1 24.8 / 26.0 High Concentration 0 1 2 3 4 5 6 pH(SU)intt/Fin 7.0 / 7.7 7.8 / 7.7 7.9 / 7.6 7.8 / 7.6 7.6 I 7.8 7.7 / 7.8 7.9 / 7.6 DO(mg/L) Init/Fin 8.0 / 6.8 8.4 / 6.2 8.2 / 5.1 7.7 / 6.2 8.8 / 6.4_ 7.9 / 5.8 8.3 / 6.2 Temp(C)Init/Fin 25.0 I 25.2 24.6 / 26.2 24.7 1 25.0 24.9 1 26.6 24.7 / 25.2 24.3 / 25.1 24.4 1 25.0 Sample 1 2 3 Survival Growth Overall Result Collection Start Date 8-1-16 8-3-16 8-4-16 Normal I I no I I yes ChV >100% Grab Hom.Var. i I yes I I yes • Composite(Duration) 24 hr 24 hr 24 hr NOEC 100% 100% Hardness(mg/L) 124.5 124.6 124.0 LOEC >100% >100% Alkalinity(mg/L) 77.7 75.6 80.6 ChV >100% >100% Conductivity(umhos/cm) 506 498 504 Method Steels Dunnetts Chlorine(mg/L) <0.05 <0.05 <0.05 Temp at Receipt(C) 0.1 0.1 1.7 Stats Survival Growth Conc. Critical Calculated Critical Calculated Dilution H2O 23 10 16 2.41 -0.01 Hardness(mg/L) 48.0 45 10 18 2.41 -1.09 Alkalinity(mg/L) 31.8 60 10 16 2.41 -1.40 Conductivity(umhos/cm) 188 90 10 16 2.41 0.16 100 10 18 2.41 -1.15 } , DWQ Form AT-5(1/04) Page 2 of 7 CHRONIC DEFINITIVE SURVIVAL AND REPRODUCTION/GROWTH TEST Statistical Analyses Client: Charlotte Mecklenburg/Mallard Creek Pimephales promelas Sample Identification: MALLARD CREEK Second Species Test Date: 02-Aug-2016 Tests for Normality and Heterogeneity of Variance Sample Use Parameter Test Used Result Sample Date Sample Used Normality N/A N/A Sample 01-Aug-16 02-Aug-16 03-Aug-I6 Variance N/A N/A Sample It 03-Aug-16 04-Aug-16 05-Aug-16 Sample C 04-Aug-16 06-Aug-16 07-Aug-16 08-Aug-16 Tests for Differences in Survival and Growth Goncentrallion-Response: Survival Test Type Used: Linear Interpolation 1664 • ,._ U _. ..„40....„10 ar 164 %Bflluent 2 ■ a Ionia a Effect Control 23.0% 45.0% 60.0% 90.0% 100.0% t its G tO Survival 100.0% 97.5% 100.0% 97.5% 95.0% 100.0% 164 %reduction 1.2% 1.2% 2,5% 2.5% 2.5% i64 Growth 0.6608 0,6610 0.7063 0.7195 0.6540 0.7088 Ott Control �'; `�; . . MD% %reduction(smoothed) 0.0% 0.0% 0.0% 0.8% 0.8% Test Concentration 0`ro',ry'n"� Variance 0.0040 0.0010 0.0043 0.0058 0.0053 0.0007 Acceptability Criteria Value Upper Limit Lower Limit CV:Coeff.of Variation 9.6% 42.0% 8.9% CGrlo ntra ion•Re ner:Reproduction I Graw4h PMSD:%MSD 14.2% 30.0% 12.0% +t 010 MSD:Min.Sign.Diff, 0.094 Acceptability criteria limits not exceeded 4 a--ff"~ -t 0.00 IC25 Point Estimates TEST RESULTS -est 0,00 ■ a ■ el le ie Survival IC25= >100.0% %Reduction per Linear Interpolation i 0.10 a 0,30 Growth IC25= >100.0% @CTC of 90.0% t+ 2 020 Hypothesis Testing Survival effect 2.5% '0.10 NOEC Growth 100.0% Growth effect 0.8% 0 Control .3,04 .11.04 110,04 10,04 {k4 KOH rhmeed ChV Growth > 100.0% PASS Test Concentration •ai -„ Comments Page 3 of 7 l W m W I y m 0 v,cOhrnn�n CD 0 3 W o C ¢ ' N N N N N N Ni W W U o G q S m K r m LL p N m m C U W e g o 0 AM n= X ❑ n E m N . m o 0 . 0 LLAC > X e o 72222 o v N _ - N ' w E o.- 0 E ^o a �j i n O) ng v E 2 E m` Li . u a d a O L =C 9 * m b m e m 3 ❑7, . 022 . : E a E t . W J Y = E H Q r N M C 6 Op w z* 5 e aa a o 2 1, r a 42 m . ' " E a m Z F}}r} }wmEog oo . u o � = a : i ` mE aOZQQQQaQvmzvfmm ' rz i ocX = 7 = z - `o U-0 CI 0Ca C2❑ m 0 0 0 0 0 0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 m o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Z > LL M m(❑ m r E ❑ 01 C O 1 W Q co LL m a 0 i r _ 2o O N CO m CO Q CO N CO Q N CO Q CO CO Q N CO CO o N O M , O m M O co CC CO Q m Q I-- m N 1,- .-- N 3 E N. CO 10 CO fD N m 0 1-m N 0 0 N 0 CO CO IN 0 A [D I- P. CO 0 p o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 '0 0 0 0 — — to 0 r 3 r N Q , o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 .- 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 .1-,- . 3 87, 0 .. U 0 : N N 0 0 0 0 0 0 0 0 0 0 0 0 0 .- 0 0 0 0 0 0 0 0 0 '2 o e 27, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 M N m 3 ' 2 2 ,_ N N 1.6 ❑ m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 < 0 -„ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N.LO Q 3 > i t to m m O o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O O O O 0 0 0 0 IL LL N N ❑ a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o O 0 0 0 0 41 M 3 `o Co 0 o W 5NN ❑ 7, 000 . 00 . - 0000 0 . 0 . _ 000 00 . 0 LL LL Ci 0 0 0 0 0 0 0 0 O.0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N-N N 3 m L. m o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -Ua ' - N N 0 e 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 `0 0 0 0 N tri m U ' Z. N N ❑ m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 > z 0 c a m Q m 0 ❑ W LL 0 X Q m O ❑ W LL 0 X < o U ❑ W LL 0 2 Q CO 0 ❑ W LL O X < m U ❑ W LL O = < CO 0 W LL 0 2 > s O g P cm3 u Co P '° t1 N a Off co s z s ET _ CHAIN b�7 CUSTODY RECORD - . i - it+y�9 ,' 'Ib l'�5• t ._..:,fir', �Paae�of___z__ PO Box 16414,Greenville,SC 29926-7414 ff (864)877-6942, (800)891-2325 Fac(864)877 6938 Shipping Address 4 Craftsman Ct,Greer,SC 29650 W W W.ETTENV IRCNMENTALCO M Client: ,. C.,'r S\o.\-\-e. W e; {may Program Containers Preservative p Parameters Facility: ix A-\\-0ScC c Q.tz k State: NQ NPDES i'.',.: M(. C-23 Q I 1;rooleEmueTat TtOrg -_ n l l Acute Chronic Test4rganisms 4 i11 �' <i _ n o o' (Composite only) (Grab or Composite) < " = 5 , _ U o — U c U - — o cc a% _ = IH:504 .m _ = — _ ,•'. k•-, ✓7 Sign and Print below 3 s o 0 3a H¢ ? = 2 = St�_ = 2 _ E ;;m ?' 5 the dotted line ic c U .° _ yyyOH. = = e o = ? =' ? N N SAMPLE ID t? co p °' ,u o cp 2 o D•s=ZaAc o o s = _. = T zn —`-2 _ P Composite Time SomleCoaroinsDatc Time Collected by U cq yr Z c p > < 'C 0 U U D r=. 2 'in Z U _ y 2 Chemical Analysis8other 6�Orbe C)--' --C--C C ' -11"l(C) o-b:� ,. = -ic, ,65 Gs.-2,--3_ ,_ er_ 3y, int xY 4'7LfSf4 V Special Instructions: Ca1DC1 r,^,,}- ,N; 1>,)(3:.P'• a Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished ran' tion Received li /Organization Area Temo°C Preserved2 Ph/A' k j-'JIvi i .. _,i �.. 1 I 1 Vig, 1(173� ( � ) .' / 7T I I 1 �� 16-4.6 �� - ///,, , a^i �r 1 . _rd."' _� - - I I o. CQMLMOSITE SAMPLING OCEDURES TEITIPERATURE MONITORING PROCEDURES OLD TIME PROCEDURES Composite samples must bd collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:I sample each hour for 24 hours.Equal voler 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bas. of sample collection(completion of composite sample). or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit. ET' ' CHAIN of CUSTODY RECORD ,. ,,�, ,.;d 4Rc(.:t0 f: s.'5E:Ui: Pate d of__4 PO Box 16414,Greenville,SC 29606-7414 (864)877-6942, (800)891-2325 Fa c(864)877 6935 Shipping Addres 4 Craftsman Ct,Greer,SC 29650 W W W.ETrENVIRONMENTAL.COM Client: /� ( R k` ,telt V\�(Ur��G'tl-4a. {W -c _› Program Containers Preservative Parameters Facility: (\'if , ` 1-h•_NP—C lh Whole Effluent Toxicity State: V,€__. h NPDES# (L1Lp3O31 a . O Acute Chronic Test Organisms :i � _ _p r - o riS _ ZC (Composite only) (Grab or Composite) Q o a- u L U _ UU — y = trso4 Ih — 02Sign,and Print below w >HCI. ,p' = m m a — •^ ? c v the dotted line — ' p U vm E c . a .. 4.wti 2 go _ c a. o = N • - U' Pyo o co 8 5=z.-a. ct o c �, t E. _SAMPLE ID j Compositcaort Date Time Somple Ullman Dote Firm Collected by rn 07 Z a t7 > 6.0� G F U U Q t=. .� ;n = U _ 3 z Chemical Analysis 2.Other 1Y)—EiP e, 2 4.117--,,4 3.4_1 ._. fR _crkl... .(reli____y . 4-74s16 -k-, t2 sX 4X , a m rn O N Special Instructions: • Sample Custody Transfer Record Secure Receipt Sample • -Date Time .telin uished B !Organization Receiv=.By I Orsanization Area Temp°C Preserved? 41' Iff . ( irL22_,. /5-71--) :- . �� , ,./ COMPOSITE SA MPLIA t,PROCEDURE EMPERATURE iIJONPTORING PROCEDURES LD TIME PROCEDURES Composite samples must.e collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testine the sample must first be used within 36 hours Time Proportional:1 sample each hour for 24 hours.Equal volui 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bass. of sample collection(completion of composite sample). or at minimum I sample every 4 hours over 24 hours. Sample may not be used after Z hours from sample collection. Flow Proportional:As per instructions in NPDES permit _. ET'ALT CHAIN OF CUSTODY RECORD ,,..itl'r?,,,,,t5.7..�uto17r�t ffiv€ZT"=tebm!' Page of PO Box 16414,Greernn9le,SC 29606-7414 , (864)877-6942,(800)891-2325 Fax(864)877 6938 Shipping Address 4 Craftsman Ct.,Greer,SC 29650 W W W.L'TrENV IRONMENTALCOM CIient: ���J� i e W�� 6 Program Containers 1Prtscrvative Facility: Parameters ff)P) ,AroL Ct-Pek WR Whole Effluent Toxicity State: NC__ NPDES m; t4(? CO 3C7` 1 Q Acute Chronic Test Organisms - m TS • a! .3 c :i _ a o D a (Composite may) (Grab or Composite) E o • = U r= . o F. '• Z SiQti,and Print below 3 — = m 2=HCt. ' = = z — — z - _ c Sig,n, dotted line "^ U 3-HNo3 = ° 2 = r" n P. i, , < SAMPLE ID CampasiteStart Dam Time SampkCalltaionDate Time Collected by U0 to Z .-....• = C) > ic <6=OtF U 0 U ^ 2 iZ _ U _ 3 L Chemical Analysis E.Other G_ 4dX � � X v 0 D J D V Special Instructions: $<'rcc"r1` oc iPg ,, 4, ? s S A-c--. 5-e i••er..1) 8. E. C- s.,:,,e ck®, a'S Sample Custody Transfer Record Secure Receipt Sample Date Time 1' quished By/ /Organization Roc ped By/Organization Area Temp'C Preserved'? Al STs i.� )u �� t. 2/SAA& /- • C- l,< 5/, fr _,--,,, /1?-,- -------' L-----7-1— I I 1.-7 COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:1 sample each hour for 24 hours.Equal volus 0.0 and 6.0°C.Samples must not be frozen_Use water ice in sealed bags. of sample collection(completion of composite sample). or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit ) EEImJI . (E64)877.6942 .FAY(86d)877-6938 P.O,Box 16414,Greenv-Ile,SC 29606 4 Craftsman Cairt,Greer,SC 29650 1 t Fathead Minnow Survival and Growth Test EPA-821—R-02-013 Method 1000 Client: CHARLOTTE WATER Facility: Mallard Creek NPDES#:NC0030210 ( Test Date: 14-Nov-17 Laboratory Sample ID#:T50422 P PROMELAS Test Reviewed and Approved By: Robert W.Kelley,Ph.D. Farhad Rostampour QA/QC Officer Laboratory Director } Certification#E87819 SCDHEC Certification#23104 Test results presented in this report conform to all requirements of NELAC,conducted under NELAC Certification Number E87819 Florida Dept.ofHealth.Included results pertain only to provided samples. NCD ENR Certification# 022 Page 1 of 6 I Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test , Facility: Charlotte Water Mallard Creek NPDES# NC0030210 Pipe#: 001 County: Mecklenburg I Laboratory: ETT Environmental,Inc. Comments x i Signature of Operator s o ible,�� x Signature of Laboratory Supervisor MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh,NC 27699-1621 Test Initiation Date/Time 11/14/17 / 05:06 PM Avg Wt/Surv.Control 0.6599 Test Organisms %Eff. Repl. 1 2 4 4 _ Cultured In-House t Control Surviving# 9 10 10 10 %Survival 97.5% X Outside Supplier Original# 10 10 10 10 Wt/original(mg) 0.5640 0.6400 0.7350 0.6380 Avg Wt(mg) 0.6443 Hatch Date: 11/13/17 25.0 Surviving# 10 9 7 10 %Survival 92.3% Hatch Time: 1030-1130 N Original# 10 10 9 10 Wt/original(mg) 0.5400 0.5710 0.5578 0.6500 Avg Wt(mg) 0.5797 45.0 Surviving# 9 10 10 9 %Survival 97.4% Original# 10 10 10 9 Wt/original(mg) 0.5930 0.8190 0.6640 0.7011 Avg Wt(mg) 0.6943 60.0 Surviving# 10 9 9 10 %Survival 95.0% Original# 10 10 10 10 Wt/original(mg) 0.6390 0.6800 0.6420 0.7030 Avg Wt(mg) 0.6660 90.0 Surviving# 10 8 9 10 %Survival 94.9% Original# 10 9 10 10 Wt/original(mg) 0.5720 0.8100 0.7380 0.5550 Avg Wt(mg) 0.6688 100.0 Surviving# 10 10 10 10 %Survival 100.0% Original# 10 10 10 10 Wt/original(mg) 0.5210 0.6080 0.7910 0.8190 Avg Wt(mg) 0.6848 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH(SU)Init/Fin 7.9 / - 7.9 / 7.6 7.7 / 7.3 7.9 / 7.4 7.6 / 7.1 7.7 / 7.3 7.7 / 7.3 ----/ 7.8 DO(mg/L) !nit/Fin 7.0 / - 7.8 / 6.4 7.5 / 5.6 7.3 / 5.5 8.1 / 5.0 8.6 / 6.5 7.7 / 5.8 ----I 6.2 Temp(C)!nit/Fin 24.7 / - 24.6 / 24.8 24.6 / 24.7 24.5 / 24.5 24.4 / 24.5 24.5 / 25.1 24.6 / 25.0 ----/ 25.4 High Concentration 0 1 2 3 4 5 6 7 pH(SU)Init/Fln 7.9 / - 7.7 / 7.6 7.9 / 7.5 7.8 / 7.7 7.4 / 7.5 7.5 / 7.6 7.5 / 7.6 ---/ 7.9 DO(mg/L) Init/Fin 9.1 / - 7.8 / 5.9 7.6 / 5.9 7.7 I 6.2 8.8 / 5.7 8.7 / 6.8 8.6 / 5.5 ----/ 5.7 Temp(C)Init/Fin 25.0 / - 24.5 / 24.8 24.7 / 24.7 24.8 / 24.5 24.7 / 24.5 24.9 / 25.1 24.7 / 25.0 ----/ 25.4 Sample 1 2 Survival Growth Overall Result Collection Start Date 11/13/17 11/15/17 11/16/17 Normal yes yes ChV >100.00% Grab Horn.Var. yes yes Composite(Duration) 24 hr 24 hr 24 hr NOEC 100.0% 100.0% Hardness(mg/L) 100.0 120.0 120.0 LOEC >100.00% >100.00% Alkalinity(mg/L) 68.8 52.2 53.5 ChV >100.00% >100.00% Conductivity(umhos/cm) 502 519 523 Method T-Test T-Test Chlorine(mg/L) <0.05 <0.05 <0.05 Temp at Receipt(C) 0.0 0.0 0.1 Stats Survival Growth e not frozen not frozen Conc. Critical Calculated Critical Calculated ) e Dilution H2O 25% 2.41 1.20 2.41 0.97 Hardness(mg/L) 46.0 45% 2.41 0.00 2.41 -0.75 Alkalinity(mg/L) 29.2 60% 2.41 0.59 2.41 -0.33 s Conductivity(umhos/cm) 178 90% 2.41 0.66 2.41 -0.37 1 100% 2.41 -0.59 2.41 -0.61 DWQ Form AT-5(1/04) Page 2 of 6 1 E 1 W N LLI H 3 E , a m X w m L 10To CC 9 o Ia p U o a - a N a a ox ¢ - oYz z o m z o ❑ LL _ m XN o (7)c WLL _uSso - E orn 0 . ( roMz .- o a .-nczm e � N w E m W o E `. w ' E m U m Q Z E E _ c o 0 a m m o .eF. a 0 z E • E E _ m _ m H 4 0 a 6- 22 ti m .- ` L 6 - o z S • E o z z = ., 7, 7, - _ E m f1 U t; 2 U f V1 to of 1- c c h = v : F - c ❑ Z z O X _ _ Q r o 0 O S - m o 0 0 0 0 0 0 o m , 0 0 0 0 o m o o m 00 0000, 03000000 03000000000000 0 0 0 CO LL Q — a 0 w m m 0 . LL U N .- U O O n m h m y G N h .- m cp 1� 0 rp m V O r N N O m CO D. COY' 0 0 6 m 6r: N r` CO in o r ro ti o o � 0 0 0 0 0 0 7- 0 0 0 0 0 0 0 0 0 o 0 0 0 0 0 •V d a in 0 9 0 0 0 0 0 '7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N asa 7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 he CO . J V N V 01,, o0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 re N N Q 7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 W f m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Q Q e N N N - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 NL 0 V' V V' V N N N 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - D o m o 0 0 o O o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10 LO N a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ... 0 0 0 0 0 0 0 0 0 • -, ' N N N o 0 0 0 0 0 0 0 0 0 0 0 0 'o o 0 0 0 0 0 0 0 0 0 0 n N- CO i V V' V 0 0 0 0 0 0 0 0 0 0 0 .- 0 0 0 0 0 0 0 0 0 0'0 0 0 0 > N N N Q o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CO 00 CD a d 0 m 0 0 0 0 0 0 0 0 7 0 0 0 0 o 0 0 0 0 0 o 0 0 0 0 O -, m N N N 0 a. m Q m o ❑ W LL C9 S Q mooW LL 0 2 Q m o ❑ '.L LL O S Q m o ❑ W o U S Q m o ❑ W LL O S Q m O O W LL o' 2 ! U a' E D 2 C E N 00 rel t() CO 04 O (D D7 O a f :,1E, ETTCHAINOF CUSTODY RECORD PO Box 16414,Greenville,SC 29606-7414 Pale T Of (864)877-6942, (800)891-2325 Fatc(864)877 6938 Shipping Address:4 Craftsman Ct,Greer,SC 29650 WW W.BTTCNv1AONMEnrALCOM Client: C / Ade r-C,, Program Containers Preservative Parameters Facility /e.C- (it ;n/,O 1-. I/Y �` Whole Gfiluent Tosidh• State: NPDES#: /VC. 0 Ct 3u a /'OI Acute Chronic Tett Organisms ' n ai _ c 2 n a (Composite only) (Grab or Composite) - y ii _ o c . - S _ _ Z ti - U Sian,and Print below 3 g = ro = 2-Ct. _ = 2 a-- o _ > s � o o ,,, _ C the dotted line - - = v .n 3-t{l'o3 = z ' -"'_ _ '" -y - o = .- SAMPLE ID �? Camposiu Start Date Time sample Collection Dote lime Collected b U n rn Z C7 > a 'G. o o — y'—E JG..Olhc < < U U U ❑ t 2 rn_ _ U = 3 2 Chemical Analysis Z Ocher fil'E �, 1 l1317 _ o //-1 Y1 _ _ >XI ti z jC 5oua . ce0 Special Instructions: /_ „,r / T L C . f gZpfZt"'19 3: t /.,,r ` I hCr; CL .4 .jtn.te, ,A. /4�Jc l�CG `p• ��5 �L c �t' bGie� i n �i� �eh�'L ��rC 5 6.'7 L a /lt't� d'�ir ./ i Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished By/Organ don, p,. Re eived By/Organization Area Temp°C Preserved? #11/17O�r3 � f CI (-'fl /C, -'�-c Gi/o/e � �^• (y . J I 'L 1)-i q-1 7 9:19 ,apple: t te 4 1 Pvi /¢ 17 / 4 i �� v T ///.4//7 ) N, �(i I 10.0 no+I r,t-Dzein _ COMPOSITE SAMIPLINe PROCEDURES TEMPERATURE MONITORING PROCEDURESHOLD TIME PROCEDURES ES Composite samples m '.e collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must fintbe used within 36 hours Time Proportional:1 sample each hour for 24 hours.Equal volut 0.0 and 6.0`C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample). or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit ETCHAIN OF CUSTODY RECORD •���NNIyJ„'I JILhih^ di ;r wm� �:• J y�`-. "L, PII,.w,,:-.4.1.----_,gv)trt m6 E-4,7 'Page of PO Box 16414,Greenville,SC 29606-7414 (864)877-6942, (800)891-2325 Far(864)877 6938 Shipping Address:4 Craftsman Ct,Greer,SC 29650 WWw•ETTENVIRONMEIvrALCOM Client: C-1-‘Ac)9 e \o,\- QJ Program Containers Preservative Parameters Facility: OilAa , U .ie. Whole EMI=Toxicity nState: NPDES#: Acute Chronic Test Organisms — _ o d (Composite only) (Gab or Composite) E o o = U .Q „ Z U c i _ c = v o _ I-HCL , o' ✓; Sign,and Print below 3 = o it ,-HCL = = = _n _ ?— > -r. the dotted line = .o v F2 :-rno> o = _ �' = _ •E SAMPLE ID U Cornpos res ars nu,Time Sample Collection Dole Time Collected by U E an Z c U j 8 5.�i0 r) — ^ 2 _ • b.oth= E F U U U r_ z n _ U = 3 2 Chemical Analysis a.Other if)-E-4 C i limio cola liA6)1-7 (a7..e.--ei-Z--0,--- x .5/ 50LIP.,;3 in co to o Special Instructions: s<1(Any Ae —I(� c , ke-'r- �.,pd ' 3. 5 Sample Custody Transfer Record Secure Receipt Sample Date Time Rel' uished By/Organization ,Received By/Organization Area Temp'C Preserved? rncAl,? ca7;a. .1\p.—k • t U ci. lam' I i I-i��i'H:zcz 'p& . ! .r o ni of )o� I I ,4J,7yo ,.... ) / 16/17 J60S r - • h h a 9 (ar) ,,ti. E-r 10.0 n1- � CNIOSITES4APLIN PROCEDU TEMPERATURE MONITORING PROCEDURES1 , HOLD TIME PROCEDURES Composite samples must collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing.d1e sample must_fist be used within 36 hours Time Proportional:1 sample each hour for 24 hours.Equal volm 0.0 and 6.0°C.Samples must not be frozen_Use water ice in sealed bas. of sample collection(completion of composite sample). or at minimum 1 sample every 4 hours over 24 hours_ Sample may not be used after 72 hours from sample collettion. Flow Proportional:As per instructions in NPDES permit. ETT ___. _ CHAIN OF CUSTODY RECORD ,0 ri et kii Pace___1_of t PC Box 16414 Greenville,SC 29606-7414 (864)877-6942, (800)891-2325 Fac(864)877 6938 Shipping Address 4 Craftsman Ct,Greer,SC 29550 WWW.urrenr IRONM ENCAI—COM. Client: ` J/ r)4/- AA Ar- Program Containers 'Preservative I ParametersFacility: ry 1G //_-eJ �- /c /VO Whole Effluent Toxicity State: /V NPDES:=: C..... 00 30A/0 : Acute Chronic Test On,..nisms = n < IU (Composite only) (Grab or Composite) 4 un 0 = U SI SI Sign,and Print below 3 > o o tJ „Ha.04 _ z ^ 2 _ .a z 7 _ _ — n the dotted tine - C U _ vlAw = ❑ '' = —E 72 T - ^ = _ < c - .- S m a:AhOH _ g a c = = i `o e ? - N i - SAMPLE ID U Composite Start D°te Time Sample Collection Dene Ti e = P, sm za4c t) — s —_ y a_ - N Collected br U to Z a F. U > 0 6.,otbe Q G J U U D 2 IT) — �= 3= Chemical Analysis L Other m to c) 0 m p • Special Instructions: I Sample Custody Transfer Record Secure Receipt Sample Date Ti - I '1.. ' ted By/Organization_ Received By/Organization Area Temp°C Preserved? tk-t l� �a _ .-,,cD 5-,g\ '' ,-h�i c `ci .-► t)i-17-11 t .3� I-), 1(ri'• 1 l 1 o 1 l 1-)17 COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES /HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:1 sample each hour for 24 hours.Equal volur 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample). orat minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit EE1m1 . (E&4)B77-6942.FAX(864)877-6938 P.O.Box 1e414,GreenvIle,5G 29606 4 Craftsman Ccurt,Greer,SC 29650 Fathead Minnow Survival and Growth Test EPA-821-R-02-013 Method 1000 Client: CHARLOTTE WATER Facility:Mallard Creek NPDES#:NC0030210 Test Date: 13-Feb-18 Laboratory Sample ID#:T50955 P promelas Test Reviewed and Approved By: Ald 4(4 Robert W.Kelley,Ph.D. Farhad Rostampour QA/QC Officer laboratory Director Certification#E87819 SCDHEC Certification#23104 Test results presented in this report conform to all requirements of NELAC,conducted under NELAC Certification Number E87819 Florida Dept of Health.Included results pertain only to provided samples. NCDENR Certification# 022 Page 1 of 6 Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test Facility: Charlotte Water Mallard Creek NPDES# NC0030210 Pipe#: 001 County: Mecklenburg Laboratory: ETT Environmental,inc. Comments x - Signature of Operato -- .on='bl•,. .e x (ft / . Signature of Laboratory Supervisor MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh,NC 27699-1621 Test Initiation Dat ime e!r' 02/13/18 / 04:50 PM AvgWt/Surv.Control 0.7483 Test Organisms 9 %Eff. Repl. 1 2 3 4 Cultured In-House Control Surviving# 10 10 9 10 %Survival 97.5% X Outside Supplier Original# 10 10 10 10 Wt/original(mg) 0.6650 0.7620 0.6930 0.7960 Avg Wt(mg) 0.7290 Hatch Date: 02/12/18 25.0 Surviving# 10 10 10 10 %Survival 100.0% Hatch Time: 1000-1130M; Original# 10 10 10 10 Wt/original(mg) 0.6530 0.7010 0.7230 0.7160 Avg Wt(mg) 0.6983 45.0 Surviving# 10 10 10 10 %Survival 100.0% Original# 10 10 10 10 Wt/original(mg) 0.5300 0.6490 0.8010 0.7640 Avg Wt(mg) 0.6860 I 60.0 Surviving# 10 10 10 10 %Survival 100.0% Original# 10 10 10 10 Wt/original(mg) 0.7560 0.7910 0.8010 0.7960 Avg Wt(mg) 0.7860 I 90.0 Surviving# 9 10 10 10 %Survival 100.0% Original# 9 10 10 10 Wt/original(mg) 0.7222 0.7540 0.6260 0.8590 Avg Wt(mg) 0.7403 100.0 Surviving# 10 10 10 10 %Survival 100.0% Original# 10 10 10 10 Wt/original(mg) 0.8080 0.9430 0.8300 0.8490 Avg Wt(mg) 0.8575 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH(SU)!nit/Fin 7.4 / - 7.6 / 7.4 7.9 / 7.6 7.6 / 7.7 7.8 / 7.4 7.7 / 7.4 7.6 / 7.4 --/ 8.0 DO(mg/L) Init/Fin 8.6 / - 8.3 / 6.7 7.7 / 6.2 7.7 / 6.3 7.5 / 5.5 7.7 / 5.2 5.6 / 6.4 --/ 6.2 Temp(C)Init/Fin 24.7 / - 24.7 I 24.8 24.6 / 25.4 24.9 / 25.2 24.7 / 252 24.8 / 25.1 24.6 1 25.2 -/ 24.8 High Concentration 0 1 2 3 4 5 6 7 pH(SU)Init/Fin 7.1 / - 7.6 / 7.6 7.5 / 7.9 7.8 / 7.6 7.7 / 7.7 7.5 / 7.6 7.8 / 7.7 -1 7.9 DO(mg/L) 'nit/Fin 9.2 / - 8.0 / 6.5 8.1 / 6.8 7.5 / 5.7 7.7 / 6.4 7.4 / 5.7 7.2 I 6.1 --/ 5.9 Temp(C)Init/Fin 25.0 / - 24.7 / 24.8 24.9 / 25.4 25.0 / 25.2 24.8 1 252 24.8 / 25.1 24.7 / 25.2 -/ 24.8 Sample 1 2 Survival Growth Overall Result Collection Start Date 02/12/18 02/14/18 02/15/18 Normal no yes ChV >100.00% Grab Horn.Var. yes yes Composite(Duration) 24 hr 24 hr 24 hr NOEC 100.0% 100.0% Hardness(mg/L) 122.0 130.0 132.0 LOEC >100.00% >100.00% Alkalinity(mg/L) 82.0 58.6 68.3 ChV >100.00% >100.00% Conductivity(umhos/cm) 486 509 514 Method Steel's Test T-Test Chlorine(mg/L) <0.05 <0.05 <0.05 Temp at Receipt(C) 0.1 0.0 0.0 Stats Survival Growth not frozen not frozen Conc. Critical Calculated Critical Calculated Dilution H2O 25% 10.00 20.00 2.41 0.59 Hardness(mg/L) 46.0 45% 10.00 20.00 2.41 0.82 Alkalinity(mg/L) 28.4 60% 10.00 20.00 2.41 -1.09 Conductivity(umhos/cm) 179 90% 10.00 20.00 2.41 -0.22 100% 10.00 20.00 2.41 -2.46 DWQ Form AT-5(1/04) Page 2 of 6 W Z ,I m3 1 a 13 i a W m 0 m co co 5 i (L.' Q O C S m O cC C C m E o m m1 LL_ o a. m LL_ a 0 a E E '� n 5 3 Itaj = o U W A 40 N O U I/1 O N 10 N N m O m J )- 0 f z2 N O d z In o O N N 1 E F S i EO a Q fi m U q m E Il m z ', E E S ` 0 _ a v m N g a 2 2 0 n E E n ° ? E 5 2 E = n K a E c g 5 C C Y 0 ;32 7, _ - E i _ n' E 6 w rn o c U :21 o • u w i v E in m in F i ,= o X l= .= a r' `° 0 0 O nO e • o o m o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o o o o o o m o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 m m. ItT e1111111111111111111111111111111111111111111111111W . IL Z o 0 S a N N Rf m en ID t7 m .- b CO v- CO N C CO m CO0 m rl v f+) g CO N m N O N tri O 0 N m 0 m 6 N N IA O m a) 1 3 E to n Id n Io n n r� to cd n I: r m n I� m of I» of to GI m a o 0 0 0 0 0 0 0 0 0 0 o a a a a 7 o 0 0 a a a a CO n 3 V N O 'e o o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o a o 0 0 N CO N 3 0 n V'In .cl- U U 8 1., . . 00 0 . 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 „ N N N U o e o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 OD r W >, 3 U 0 V In V' 8 -1, o a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 , ^ N N N a p 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CO N n O 2 er to V 8 ,TLL LL1 0 0 0 0 0 0 0 0 -0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 N N (N o k n o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O N 0) m 3 In In V 0U 0 , 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 , ' N N N 0ii ▪ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 CO 0 0 0 0 0 Cr Ip na r J 0 0 > N N N O 'e 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ti N N N o I 0 ▪ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r pp o V V V a, o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 , U „ N N N 4 0 6 n Y u 2 .41000 W LL O = Q m U o W LL C9 = Q m U o W LL 0 = 0 0 0 o W LL 0 = Q m U O W LL 0 = Q m U o W LL G = = o E E £ f LI 0 - • ° _ a U u z i C O l ` s S Ii v°i V N N In 7 O /D O e LL E w o U T r 1 1 1 • i ,•_.... . ET I CHAIN OF CUSTODY RECORD --..---71-05..^—`' =m9h _0rrnie_ Page _I_of_ PO Box 16414,Greenville,SC 29606-7414 (864)877-6942, (800)891-2325 Fex_(884)877 6938 Shipping Address:4 Craftsman CI,Greer,SC 29650 W WW.ETTENVIRONMENTAL.COM Client: 11 CY\11C),6 �. W.A' s vt Program Containers Presen'afive Parameters Facility: d M.;>>P3sC1 C k 1,�1"'R +-� C� Whole Effluent Toxicity 1v State: NPDES r: Cf 030'4;1 1 Acute Chronic Test Organisms , U (Composite only) (Grab or Composite) 4 p �_ U U c n L^ t•J `_r$ a -r 1=11504 'm c ? - ^ .E rn a Sign,and Priut below = a 9 a 2=Hct. ti ' z _ m z E un '� . G' U 3=HNO3 C 2 2 •- .3 = y w o _ v the dotted line i=_ E .E _ r� H 4=NaOH =' = L o = c d -p `o o .L — O P u o o P. o o c�i 5=Za,,c u r:s ^ •• o .4 -. > c_ = t.t i_l 4 ry, 1 SAMPLE ID V CompositeStnr'Due Time SampteCollection Dntc Time Collected by U h h Z 0. 0 6.Other < < U 0 U d a: E vs = U 3 I' Chemical Analysis&Other Y Oe r(;\__ ,f z . 4. _ 1 i I • Special Instructions: s y� ,hQr&fl ( C—, Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished By/Organization Rec ived By/Organization Area . Temp°C Preserved? j 2-1 —/ ?.1g �l i'a lea �• .�, (R, l I ,. �� 1 ?-13-1`' (' _ vt� ,�13 I A gm �0 /-7r fry' J ��r' I 1 0.I I C�A OSITE SAMPLIN PROCEDUR1-4"--a LTEA PERATURE MONITORING PROCEDURES i HOLD TIME PROCEDURES Composite samples mus a collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:1 sa ple each hour for 24 hours.Equal valid 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample). i or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. 1Flow Proportional:As per instructions in NPDES permit I _ I ETCHAIN OF CUSTODY RECORD .Pose of PO Box 16414,Greenville,SC 29606-7414 (864)877-6942, (800)891-2325 Fax:(864)877 6936 Shipping Address:4 Craftsman Ct,Greer,SC 29650 W W W.STfENVIRONMENTAL.COM Client: ' kii jn�—�l lb�a �� G� Program Containers Preservative Parameters Facility: /Yvn l�et/' f C e_IC /` P. State: 1 C- Dn3� j ;;'holeGtnucntstOrga 7V NPDES R: o Acute Chronic Test OrganismsL,� L — aO U Q i e (Composite only) (Grab or Composite) < c •� U U o c a Z U b a I•HSO4 P. , _ - .❑ F . rn Sign,and Print below 3 _ m — 2=HCL ^ = i z E _ 5 ' B a e. 5,1 the dotted lint E _ ` = y a=N OH3 .2 2 o o n 7 P, =' Ti :z N p E �j u a ', o o cy u 5=ZI Ac u o .. — G :, a ^ W v 8 41 SAMPLE ID Compmise Stnrt Date Time Snmplc Collccticn Dntc Time Collected by D to t i Z a F. O > 6=0ci¢r < < J J U 0 L4 L in 2 U 3 2 Chemical Analysts 6 Other 5C956 Special instructions: 041. ercNot 4.1 AAt1)—)3 1— i -ple ct,lc;,,-�,o„ tl 3L . Tt --)i11:5,4L-:,.c.;;. • Sample Custody Transfer Record Secure Receipt Sample Date Time Relin uished By/Organization - Received By/Organization Temp`C Preserved? gii� . i .. irt2G✓R � : q ` 'ciq , ate. I I. I Mini F -.4.1M/1011/- a 1s- - ISMp - lJ /E. r � .-� E I 10.0>7D COMPOSITE SAMPLI`i PROCEDURE 'TEMPERATURE MON/TORING PROCEDURES / r HOLD TIME PROCEDURES Composite samples mus be collected over a 24(lour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional:I sample each hour for 24 hours.Equal;'olul 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample). or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Plow Proportional:As per instructions in NPDES permit ;, • . a IET1 • CHAIN OF CUSTODY RECORD I i. 3� I=(3 i•'Lu ' d'_0= Page_j_of 1 PO Box 16414,Greenville,SC 29606-7414 (864)877-6942, (800)891-2325 F5x(864)877 6938 J ;Shipping Address:4 Craftsman Ct,Greer,SC 29650 WY/W.ETTCNVIRONME TALCOM Client: r,�.i S 1Qik(J ki0 Program Containers Preservative Parameters ty: (..N A 1tl f Facility: Q_e k 1jt,(� 1 Whole Effluent Q State: {4 C., NPDES*: (V 30 )f\0 Acotc Chronic Test Organisms O to (Composite only) (Crab or Composite) - 1.1 cU �` U o p- - Z 0 i EZ Sign,and Print below 9 ca = 2-itct - ' co ,—' o - ti the dotted line a E E U ° y s=HHos `_—' ea ^ .6 y 4=NaOH = o o = >. = C w& L �j Q o o c o rj i-Zn,1c u v '� in �,_ r _ SAMPLE ID Composite Start Date Time Sample Collection Dam Time Collected by U en to Z w i1 Cl 6=0amr F U U Li 0 E 2 rn - U = 3 L Chemical Analysis 8 Other VC' a1�sh 011// r�i�1w 07a5- `'-\ `, A- �( 3X d A�#°°�.' X IS -r to 1 co o - . - Special Instructions: ' Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished By/Ornanization eceiv d By/Or° nization Area Temp'C Preserved? . i 1 el a Mciipio I I I 2-16.1'T3c ( - Well. Mitt. _________----7I I I (9)(/.[C ( (330 -,„&„„... ..,,,_ I — err 2/r6/f,g 1767 er i -- ,,,,,,,,A,, -1 II t. ( • F_l-T- I 10.01 - 'fes - r COMPOSITE SAMPLING PROCEprfICTEMPERATURE MONITORING PROCEDURES , HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours l• Time Proportional:l sample each hour far 24 hours.Equal volut 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample). or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection. Flow Proportional:As per instructions in NPDES permit. Attachment FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin Pee Dee SUPPLEMENTAL APPLICATION INFORMATION PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA,or other remedial wastes must complete part F. GENERAL INFORMATION: F.1. Pretreatment program. Does the treatment works have,or is subject ot,an approved pretreatment program? El Yes ❑ No F.2. Number of Significant Industrial Users(SIUs)and Categorical Industrial Users(CIOs). Provide the number of each of the following types of industrial users that discharge to the treatment works. a. Number of non-categorical SIUs. 0 b. Number of CIUs. 3 SIGNIFICANT INDUSTRIAL USER INFORMATION: Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and provide the information requested for each SIU. F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages as necessary. Name: See following pages for answers to F3—F8. Mailing Address: F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge. F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge. Principal product(s): Raw material(s): F.6. Flow Rate. a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. gpd ( continuous or intermittent) b. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. gpd ( continuous or intermittent) F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following: a. Local limits 0 Yes 0 No b. Categorical pretreatment standards 0 Yes 0 No If subject to categorical pretreatment standards,which category and subcategory? FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: Mallard Creek WRF, NC0030210 Renewal Yadkin Pee Dee F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g., upsets,interference)at the treatment works in the past three years? ❑ Yes ❑ No If yes,describe each episode. RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE: F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe? ❑ Yes ® No(go to F.12) F.10. Waste transport Method by which RCRA waste is received(check all that apply): ❑ Truck ❑ Rail ❑ Dedicated Pipe F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units). EPA Hazardous Waste Number Amount Units CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER: F.12. Remediation Waste. Does the treatment works currently(or has it been notified that it will)receive waste from remedial activities? ❑ Yes(complete F.13 through F.15.) 0 No F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to origniate in the next five years). F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if known. (Attach additional sheets if necessary.) F.15. Waste Treatment. a. Is this waste treated(or will be treated)prior to entering the treatment works? ❑ Yes ❑ No If yes,describe the treatment(provide information about the removal efficiency): b. Is the discharge(or will the discharge be)continuous or intermittent? ❑ Continuous 0 Intermittent If intermittent,describe discharge schedule. END OF PART F. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE SIGNIFICANT INDUSTRIAL USER INFORMATION: Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and provide the information requested for each SIU. F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages as necessary. Name: Avago Technologies Wireless(U.S.A.)Manufacturing Inc. Mailing Address: 9815 David Taylor Drive Charlotte,NC 28262 F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge. Metal Finishing—Etching of Quartz Wafer with a metal film F.S. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge. Principal product(s): Quartz Wafers Raw material(s): Quartz or silicon wafers,cleaning solvents,Etchants and addatives,photoresist coatings,polymer coating for silicon wafers,Thin film metal coating F.6. Flow Rate. a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 7544 gpd ( continuous or X intermittent) b. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 1879 gpd (X continuous or intermittent) F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following: a. Local limits ® Yes 0 No b. Categorical pretreatment standards ® Yes 0 No If subject to categorical pretreatment standards,which category and subcategory? 40 CFR 433.17 F.B. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g., upsets,interference)at the treatment works in the past three years? 0 Yes ® No If yes,describe each episode. SIGNIFICANT INDUSTRIAL USER INFORMATION: Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and provide the information requested for each SIU. F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages as necessary. Name: Carrier Corporation Mailing Address: 9701 Old Statesville Road Charlotte,NC 28269 F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge. Operation includes various metal working activities such as plasma-arc cutting,rolling,shotblasting,welding,brazing,machine,assembly, washing,insulation adhesive operation,testing(leak testing and final testing)and painting heavy and light chillers.Prior to painting,Carrier will operate two phosphating operations,which discharges continuously. F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge. Principal product(s): Large Capacity Chillers Raw material(s): Rinse Waters _ F.6. Flow Rate. a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 10000 gpd (x continuous or intermittent) b. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 19000 gpd (X continuous or intermittent) F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following: a. Local limits ® Yes 0 No b. Categorical pretreatment standards ® Yes 0 No If subject to categorical pretreatment standards,which category and subcategory? 433.17 Metal Finisher F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g., upsets,interference)at the treatment works in the past three years? 0 Yes 0 No If yes,describe each episode. SIGNIFICANT INDUSTRIAL USER INFORMATION: Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and provide the information requested for each SIU. F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages as necessary. Name: Mallard Creek Polymers Mailing Address: 2800 Morehead Road, Charlotte,NC,28262 F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge. Produce Organic chemicals,mostly styrene and butadiene polymers F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge. Principal product(s): Styrene/butadiene polymers Raw material(s): styrene, butadiene,various other chemicals F.6. Flow Rate. a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 52,833 gpd ( X continuous or intermittent) b. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 1,400 gpd ( X continuous or intermittent) F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following: a. Local limits 0 Yes ❑ No b. Categorical pretreatment standards 0 Yes 0 No If subject to categorical pretreatment standards,which category and subcategory? 40 CFR 414 subpart D F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g., upsets,interference)at the treatment works in the past three years? 0 Yes 0 No If yes,describe each episode.