WQ0000020_Return of Application Package_20120905

A&ms,
NCDENR
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Beverly Eaves Perdue Charles Wakild, P.E.
Governor Director
September 5, 2012
Mitchell C. Griggs, Vice President — Environmental Services
Duke Energy Corporation
P.O. Box 1006
Charlotte, NC 28201-1006
Dear Mr. Griggs:
Dee Freeman
Secretary
Subject: Return of Application Package
Permit Number W00000020
Progress Energy Ash Distribution
Program
Mecklenburg County
The Aquifer Protection Section has reviewed the permit renewal request submitted on August 24, 2012
for the above referenced facility. Mr. John Toepfer (Duke Energy Corporation) was contacted via
telephone on August 27, 2012 and was informed that the subject permit is affected by Session Law 2009-
406 and 2010-177 which extend coverage of certain government permits and approvals and added
additional years to the permit expiration date. Therefore, permit number W00000020 is extended until
February 28, 2015.
Your application is being returned as indicated by Mr. Toepfer that no further action is required from the
Division at this time. However, if it is determined by Duke Energy Corporation later that a permit
modification to change some permit language is needed, the applicant can re -submit a permit
modification request to the Division.
If you have any question regarding this letter, please feel free to contact me at [phone] or
Chonticha McDaniel at [phone].
Sincerely,
4Jonisgaard
Land Application Unit Supervisor
Enc: Permit Application
cermit Application File W0000002lF'
AQUIFER PROTECTION SECTION
1636 Mali Service Center, Ralegh, North Carolina 27699-1636
Location: 512 N. Salisbury Street, Raleigh, North Carolina 27604
Phone: 9IM07-64641 FAX 1:919.807.6496
Internet: www.ncwatemuality.org
An Equal Opportunity 1 Affirm d" Action Employer
Noae hCarolim
Xturallt,

P51,Duke
Energy@
August 24, 2012
Mr. Jon Risgaard
Unit Supervisor — Land Application Unit
NCDENR/DWQ
1636 Mail Service Center
Raleigh, NC 27699-1636
Aquifer Protection Section
DUKE ENERGY CORPORATION
526 South Church St.
Charlotte, NC 28202
Mailing Address:
PO Box 1006
Charlotte, NC 28201-1006
RE: Carolina Power & Light Company d/b/a/ Progress Energy Carolinas, Inc. (PEC), an Indirect
Subsidiary of Duke Energy Corporation, Request for Extension of Permit WQ0000020 Dated
February 17, 2006
Dear Mr. Risgaard:
In the process of generating electricity, coal-fired plants generate Coal Combustion Residuals (CCRs). As
part of our ongoing commitment to the environment, Carolina Power & Light Company d/b/a/ Progress
Energy Carolinas, Inc. (PEC) seeks to handle these products in the safest,, most responsible manner
possible, either through beneficial reuse or storage. The Ash Distribution Program Permit WQ0000020
issued to PEC is set to expire on February 28, 2013. This letter constitutes a request for an extension of
the subject permit. Attached are the Toxicity Characteristic Leaching Procedure (TCLP) results for each
source generating facility as required by Condition 111.3. of the permit. We also offer the following
comments for your consideration in drafting the permit renewal:
General Comment for Permit WQ0000020 dated February 17. 2006:
• When discussing structural fill in,the permit, we recommend the following wording: "structural
fill shall mean an engineered fill constructed using CCRs that are properly placed and
compacted. This shall include fill used for embankments, greenscapes, foundations,
construction foundations, and for bases/sub-bases under a structure or a footprint of a paved
road, parking lot, sidewalk, walkway or similar structure." -This wording is slightly different than
that in our current permit but more reflective of structural fill projects we encounter and that of
15A NCAC 02T.1202.
Condition Specific Comments for Permit WQ0000020 dated February 17, 2006:
• We request the removal of Condition 11.2. regarding an operator to be in responsible charge
(0 RC). This activity is not classified by the Water Pollution Control System Operators
Certification Commission (WPCSOCC) and therefore, does not require an ORC.
• Under Condition 11.3.b. we request a modification in wording for the approved uses for bottom
ash as the Department of Transportation can not approve the use of bottom ash in areas it does
not have jurisdiction. The permit presently reads, "Overlay for secondary roads, residential
driveways, farm roads and high -traffic farm areas as approved by the NC Department of
Transportation". We request a modification that reads: "Overlay for roads as approved by the
NC Department of Transportation, residential driveways, private roads, farm roads and high -
traffic farm areas".
www. duke -energy. com

,DENR Letter—Risgaard
August 24; 2012
• Under Condition 11.3.b., we request the following uses be approved for consistency with other
permits issued by the Land Application Unit:
Bottom Ash:
Material for traction control during snow and ice events as approved by the NC
Department of Transportation. Approval by the NC Department of Transportation is not
required for use on private roads.
Flowable fill for the backfill of trenches for potable water mains as approved by the NC
Division of Environmental Health, sanitary sewers, storm drainage structures and other
trenching uses.
Soil nutrient additive, amendment, or other agricultural purpose as approved by the NC
Department of Agriculture and Consumer Services.
Raw product for the stabilization of wastewater residuals.
Fly Ash:
Flowable fill for the backfill of trenches for potable water mains as approved by the NC
Division of Environmental Health, sanitary sewers, storm drainage structures and other
trenching uses.
Overlay for roads as approved by the NC Department of Transportation, residential
driveways, private roads, farm roads and high -traffic farm areas
• We request the language in Condition 11.5 be changed to the following' -for consistency with
other permits issued by the Land Application Unit:
"Except as exempted by the condition, the Leachate Concentrations during the performance of a
Toxicity Characteristic Leaching Procedure (TCLP), the Ceiling Concentrations (i.e., dry weight
basis) and the Pollutant Monthly Average Concentrations (i.e., dry weight basis) shall be
maintained at levels less than the values listed in the table below for ash to be distributed
throughout the ash distribution program:
Parameter
Leachate Concentration
(milligrams per liter)
Ceiling Concentration
(milligrams per kilogram)
Monthly Average
Concentration
(milligrams per kilogram)
Arsenic
5.0 .
75
41
Barium
100.0
n/a
n/a
Cadmium
1.0
85
39
Chromium
5.0
n/a
n/a
Copper
n/a
4,300
1,500
Lead
5.0
840
300
Mercury
0.2
57
17
Molybdenum-
n/a
75
n/a
2

DENR Letter—Risgaard
August 24, 2012
Parameter
Leachate Concentration
(milligrams per liter)
Ceiling Concentration
(milligrams per kilogram)
Monthly Average
Concentration
(milligrams per kilogram)
Nickel
n/a
420
420
Selenium
1.0
100
100
Silver
5.0
n/a
n/a
Zinc
n/a
7,500
2,800
The following uses approved for distributed ash under the ash distribution program in
accordance with this permit shall be exempt from meeting the requirements of this condition
provided the activity does not result in any violations of water quality.standards, and there is no
direct discharge to surface waters:
a. Structural/engineered fill (i.e. engineered fill that is properly placed and compacted) for
embankments, greenscapes, foundations, construction foundations, and for bases/sub-
bases under a structure or a footprint of a paved road, parking lot, sidewalk, walkway or
similar structure. For CCRs used as fill, this exemption shall be limited to individually
permitted sites, as stipulated in Condition IVA.a, and the Permittee shall meet the
performance standard stipulated in Condition 1.5. to ensure that the applicable surface
water quality standards and groundwater quality standards are not contravened.
b. Fuel for combustion in boilers, furnaces, etc. for energy recovery.
c. Material for manufacturing of concrete products, asphalt products, brick products,
lightweight aggregate, roofing materials, insulation products, plastics, paints, bowling balls,
cosmetics, and other manufactured products in which the CCRs are encapsulated.
d. Daily, intermediate and final cover as well as any other use at a landfill as approved by the
NC Division of Waste Management.
e. Overlay for roads as approved by the NC Department of Transportation, residential
driveways, private roads, farm roads and high -traffic farm areas.
f. Material for traction control during snow and ice events, provided that the CCRs do not
exceed the leachate concentrations of concern specified in this Condition.:
g. Substitute for blasting grit, roofing granules and filter cloth precoat for residuals dewatering,
provided that the CCRs do not exceed the leachate concentrations of concern specified in
this Condition.
h. Flowable fill for backfill of trenches for potable water mains as approved by the NC Division
of Environmental Health, sanitary sewers, storm drainage structures, and other trenching
uses, provided that the CCRs do not exceed the leachate concentrations of concern specified
in this Condition.
L Raw product for the stabilization of residuals.
3

DENR Letter — Risgaard
August 24, 2012
j. Base or subbase under a structure or footprint (i.e. engineered fill that is properly placed
and compacted) of a paved road, parking lot, sidewalk, or similar structure as long as the
total depth of the CCRs does not exceed one foot."
• Under Condition 11.6. and 11.7., we request removal of reference to PEC document EVC-FGDC-
00101 "Ash Utilization Plan".
• Also at Condition 11.7., we request modification of the wording to read, "Adequate provisions
shall be taken to prevent wind erosion and surface water runoff from conveying ash from active
structural fill stockpile/storage areas onto adjacent property or into any surface waters prior to
distribution and use. This condition does not apply to ash storage facilities regulated by another
permit (e.g. NPDES permit)".
Since the CCRs are generated and stored on our applicable generation sites, this provision
conflicts and overlaps with other regulations and permits that are issued to the site by DENR.
Details are explained below:
CCRs accumulate within PEC ash ponds which are permitted wastewater treatment units that
operate under an NPDES wastewater permit. Ash ponds serve as the treatment units for
separation of ash from sluice water and are not stockpile or storage areas. Each plant's
individual NPDES wastewater permit prohibits the discharge of untreated effluent, prescribes
the conditions under which a discharge may occur and specifically regulates storm water runoff
from each plant property, including storm water runoff from any and all stockpiles.
Air emissions, including fugitive dust, at each individual plant site are regulated by Title V of the
Clean Air Act with air permits containing specific language that addresses fugitive dust emissions
from coal, coal conveyances, CCRs and on=site roads. Avoidance of nuisance conditions from
CCRs is specifically included in each plant's individual Title V permit.
Therefore, the language and intent of regulating storm water and fugitive dust emissions from
CCRs and on-site roads under Condition 11.7. are already addressed within each plant's individual
NPDES wastewater permit issued by the NC Division of Water Quality and each plant's individual
Title V air permit issued by the NC Division of Air Quality. Additional regulation of storm water
and fugitive dust emissions by the Aquifer Protection Section is duplicative of regulatory
permitting already administered by State agencies whose directive is specialized for storm water
control and air quality protection.
• We request that Condition 11.9. be updated to be consistent with 15A NCAC 02T.1206.
• Condition 111.3, states that reach source generating facility must complete a TCLP test for the
eight RCRA metals only if ash was reused during that calendar year. However, once a permit
cycle, each source generating facility must complete a TCLP test for all 40 TCLP parameters.
The TCLP test comprises eight RCRA metals (arsenic, barium, cadmium, chromium, lead,
mercury, selenium and silver), pesticides and herbicides (chlordane, endrin, heptachlor (and its
hydroxide), lindane, methoxychlor, toxaphene, 2,4-D and 2,4,5 -TP) along with volatile and semi -
volatile organics (benzene, carbon tetrachloride, chlorbenzene, chloroform, cresol, o -cresol, m-
2

DEN Letter —Risgaard
August 24, 2012
cresol, p -cresol, 1,4 -dichlorobenzene, - 1i2-dichloroethane, 1,1-dichloroethylene, 2,4-
dinitrotoluene, hexachlorobenzene, hexachloro-1,3-butadiene, hexachloroethane, methyl ethyl
ketone, nitrobenzene, pentachlorophenol, pyridine, tetrachloroethylene, trichloroethylene,
2,4,5-trichlorphenol, 2,4,6 -trichlorophenol and vinyl chloride).
Coal does not contain pesticides and herbicides and therefore, coal ash does not contain
pesticides and herbicides. Any volatile or semi -volatile constituents of coal have been
combusted in the boiler at temperatures of 1,900 T for three to five seconds and therefore,
volatile and semi -volatile organic constituents are not present in coal ash. Our past three permit
renewals (including this one) confirm that pesticides and herbicides along with volatile and
semi -volatile organics are not present in coal ash.
As such, we request that this requirement be modified such that each source generating facility
completes and annual TCLP test on a representative ash sample once per year for only the eight
RCRA metals if.that facility uses ash during the calendar year. During a permit cycle, the TCLP
test should also be required for only the eight RCRA metals.
Condition 111.4. requires sampling up to 12 times per year. However, the permit allows for a
reduction in frequency of this monitoring. We propose a monitoring frequency as shown in the
following table:
Amount of Product
Distributed
(metric tons per 365 -day
period)
Amount of Product
Distributed
(short tons per 365 -day
period)
Monitoring Frequency
mDT/yr = 0
DT/yr = 0
No Monitoring Required
0 < mDT/yr < 1,500
0 < DT/yr < 1,650
Once Per Year
1,500<_ mDT/yr < 15,000
1,650< DT/yr < 16,500
Two Times Per Year
15,000:5 mDT/yr
16,500!5 DT/yr
Six Times Per Year
In addition, we request that calcium, magnesium, manganese, phosphorous, potassium, pH and
sodium only be monitored for if the coal ash is used as a soil nutrient additive, amendment or
for other agricultural purpose as approved by the NC Department of Agricultural and Consumer
Services to be consistent with other permits issued by the Land Application Unit.
• For Condition V.1., we request removal of the reference to PEC document EVC-FGDC-00101
"Ash Utilization Plan".
5

DENR Letter — Risgaard
August 24, 2012
We appreciate your consideration of our comments and operations in renewing this permit because
beneficial reuse of CCRs is both environmentally sound and cost-effective solution. We request an
opportunity to meet with you at a date and time of your convenience to discuss our comments and the
extension of this permit. Note that PEC is closing some of our smaller coal-fired facilities but we do not
plan to remove any source generating facility from this permit as future reuse opportunities may arise.
Please contact John Toepfer at 919-546-7863 if you have any questions concerning this information.
Sincerely,
C� r�
tchell C. Griggs
Vice President — Environmental Services
Attachment
MCG/jt
M

•DENR Letter-Risgaard
August 24, 2012'
Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc.
Permit Condition 111.3 Permit Cycle TCLP Test
7
Asheville
Cape Fear
Roxboro
Sutton
Weatherspoon
Parameter/(Limit
Lee Plant
Mayo Plant
plant
Plant
plant
Plant
Plant
mg/I)
05/10/2012
05/10/2012
05/02/2012
01/24/2012
05/10/2012
06/08/2012
05/03/2012
Arsenic (5)
0.09
<0.05
<0.05
<0.025
<0.025
<0.1
0.2
Barium (100)
2.8
1.24
<1
<0.5
0.52
3
1.4
Benzene (0.5)
<0.19
<0.005
<0.005
<0.19
<0.19
<0.01
<0.05
Cadmium (1)
<0.005
<0.01
<0.01
<0.005
<0.005
<0.1
<0.05
Carbon
<0.19
<0.005
<0.005
<0.19
<0.19
<0.01
<0.05
Tetrachloride (0.5)
Chlordane (0.03)
<0.003
<0.0002
<0.0002
<0.003
<0.003
<0.0005
<0.005
Chlorobenzene
<0.19
<0.005
<0.005
<0.19
<0.19
<0.01
<0.05
(100)
Chloroform (6)
<0.19
<0.005 '
<0.005
<0.19
<0.19
<0.01
<0.25` _
Chromium (5)
<0.025
<0.05
<0.05
0.027
<0.025
<0.1
<0.05
m-Cresol(200)
<0.05
<0.1
<5
<0.05
<0.05
<0.005
<0.1
o-Cresol(200)
<0.05
<0.05
<5
<0.05
<0.05
<0.005
<0.1
p-Cresol(200)
<0.05
<0.1
<5
<0.05
<0.05
<0.005
<0.1
Cresol(200)
<0.05
<0.1
<5
<0.05
<0.05
<0.005
<0.1
2,4-D (10)
<0.01
<0.5
<5
<0.01
<0.01
<0.0133
<0.002
1,4 -
Dichlorobenzene
<0.19
<0.05
<0.05
<0.05
<0.19
<0.005
<0.1
(7.5)
1,2-Dichloroethane
<0.19
<0.005
<0.005
<0.19
<0.19
<0.01
<0.05
(0.5)
1,1-
Dichloroethylene
<0.19
<0.005
<0.005
<0.19
<0.19
<0.01
<0.05
(0.7)
2,4-Dinitrotoluene
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
(0.13)
Endrin (0.02)
<0.0005
<0.00006
<0.00006
<0.0005
<0.0005
<0.00015
<0.005
Hexachlorobenzene
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
(0.13)
Heptachlor (0.008)
<0.0005
<0.00005
<0.00005
<0.0005
<0.0005
<0.00015
<0.005
Hexachloro-1,3-
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
7

,DENR Letter - Risgaard
August 24, 2012
butadiene (0.5)
Hexachloroethane
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
(3.0)
Lead (5)
<0.025
<0.05
<0.05
<0.025
<0.025
<0.1
<0.05
Lindane (0.4)
<0.0005
<0.00005
<0.00005
<0.0005
<0.0005
<0.00015
<0.005
Mercury (0.2)
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
<0.001
Methoxychlor (10)
<1
<0.0005
<0.0005
<1
<1
<0.00015
<0.005
Methyl ethyl ketone
(200)
<0.38
<0.05
<0.05
<0.38
<0.38
<0.05
<0.5
Asheville
Cape Fear
Roxboro
Sutton
Weatherspoon
Parameter/(Limit
Lee Plant
Mayo Plant
plant
Plant
plant
Plant
Plant
mg/I)
05/02/2012
01/24/2012
05/10/2012
05/10/2012
05/10/2012
06/08/2012
05/03/2012
Nitrobenzene (2)
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
Pentachlorophenol
<0.1
<0.25
<0.25
<0.1
<0.1
<0.025
<0.1
(100)
Pyridine (5)
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
Selenium (1)
0.13
0.203
0.116
<0.1
<0.1
<0.1
0.058
Silver(5)
<0.025
<0.05
<0.05
<0.025
<0.025
<0.1
<0.05
Tetrachloroethylene
<0.19
<0.005
<0.005
<0.19
<0.19
<0.01
<0.05
(0.7)
Toxaphene (0.5)
<0.003
<0.0024
<0.0024
<0.003
<0.003
<0.0005
<0.01
Trichloroethylene
<0.19
<0.005
<0.005
<0.19
<0.19
<0.01
<0.05
(0.5)
2,4,5 -
Trichlorophenol
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
(400)
2,4,6-
<0.05
<0.05
<0.05
<0.05
<0.05
<0.005
<0.1
Trichlorophenol (2)
2,4,5 -TP (1)
<0.01
<0.5
<0.5
<0.01
<0.01
<0.00333
<0.002
Vinyl chloride (0.2)
<0.19
<0.01
<0.01
<0.19
<0.19
<0.01
<0.05

Slliing information.
T B L Environmental
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AnalySlercontelnerrPreaervetive
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Received by: (Signal Bottles Received:
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Date:
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Laboratory , Inc.
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Relinquished by: ( R iB}'.y
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2401 W. 5th St
pH Checked: NCF:
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Lumberton, NG 28358
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Collected by signatu(e}: Ruah2 (Lab MUST Be Notified)
�J' {$bl;',�l
bate Resulto Needcd:
IS-
No.
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A Some Day .......
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TemplelelPrelogin
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Shipped Via:
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Sample ID ComplGrab Matrix'
Depth
Dale Time
RernaftMonteminant Semple p gab only)
4414 1; u o Gt SS
S-3 12 vZ3a
1ti -
L 3 -
'Mantic 8S- Soll/Solk) GW- Groundwater WW- WastsWatar DW - Drinking Wa►er OT- Oft pH Temp
Remarks: 7rjQr+.�t ) r'C7tZ/ ? , O
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CoC Seals lnfficl Y N NA
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Received for lab by: (Signa re) Dale: lime:
pH Checked: NCF:
577�-12 1 69(x

BDL - Below Detection Limit
Det. Limit - Estimated Quantitation LimitMQL)
Limit - Maximum Contaminant Level as established by the US EPA
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval f6 4 ESC.
Reported: 05/15/12 17:46 Printed: 05/15/12 17:46
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REPORT OF ANALYSIS
Pam Hester
May 15,2012
TSL Laborsto ry
P.O. Box 589
Lumberton, NC 28359
ESC Sample
0
L573351-01
Desa Received may 04, 2012
Description PLocess Energy WS PN ABH
POND
Site
ID
Sample IO ASN POND
Project
TB
23644
Collected By Steve Davis
Collection Dace 05/03/12 07:30
Paramatec
Result
Dec. Limit
Units
Limit
Method
Da
/Time
By Dil
2,4,5 -TP (Sllvex)
BDL
0.0020
mg/1
1.0
8151A
05/
/12 2228
KLM 1
2,4-D
BDL
0.0010
mg/l
10.
8151A
05/
/12 2228
KLM 1
Surrogate Recovery
2,4-Dichl0rophenyl Acetic acid
80.2
4 Ret.
8151A
05/
/12 2228
KLM 1
TCLP Semi-Volatilea
1,4 -Dichlorobenzene
BOL
0.10
mg/1
7,5
0270C
05/
/12 1327
ADF 1
2,4-Dinicrotoluene
)SDL
0.10
mg/l
0.13
82700
05/
/12 1327
ADF 1
Hexachlorobenzene
BDL
0.10
mg/1
0.13
82700
05/
/12 1327
ADF 1
Rexachloro-1,3-butadiene
BDL
0.10
mg/1
0.50
8270C
05/
/12 1327
AOF 1
Nexachloroethane
BDL
0.10
mg/l
3.0
82700
05/
/12 1327
ADF 1
Nltrobanrene
BDL
0.10
mg/1
2.0
82700
05/
/12 1327
ADF 1
Pyridine
BDL
0.10
mg/1
5.0
82700
05/
/12 1327
ADF 1
364-0ethyl Phenol
BDL
0.10
mg/1
400
8270C
05/
/12 1327
ADF 1
2-Methylphenol
BDL
0.10
mg/l
200
8270C
OS/
/12 1327
ADF 1
Pentachlorophenol
PDL
0.10
mg/i
100
82700
05/
/12 1327
ADF 1
2,4,5 -Trichlorophenol
BDL
0.10
mg/l
400
8270C
05/
/12 1327
ADP 1
2,4,6 -Trichlorophenol
BOL
0.10
mg/l
2.0
8270C
05/
/12 1327
ADF 1
Surrogate Recovery
2-Fluorophenol
45.8
S Rea.
87.0
8270C
05/
/12 1327
ADF 1
Phenol -d5
35.0
9 Rac.
67.0
0270C
05/
./12 1321
ADF 1
Nitrobenzene -d5
72.3
E Rec.
120.
0270C
05/
/12 1327
ADF 1
2-Fluorobiphenyl
89.9
4 Rec.
122.
8270C
05/
/12 1327
ADF 1
2.4,6-Tribromophenol
84.8
4 Rec.
148.
82700
DS/
/12 1327
ADF 1
p-Terphdnyl-dl4
100.
4 Rec.
149.
8270C
05/
/12 1327
ADF i
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation LimitMQL)
Limit - Maximum Contaminant Level as established by the US EPA
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval f6 4 ESC.
Reported: 05/15/12 17:46 Printed: 05/15/12 17:46
Pao 3 of 3

Po, 2 of 3
2065 Lebanpn Rd.
t. Julio, TN 37122
*ESCj�
/1
��ljl' V
G(
615) 758-5858
-800-767-5859
��Q�
ax (615)
756-5859
L -A-8 3•C-I-E-N-C•a's
ax I.D.
62-0814289
•
it. 1970
REPORT OF ANALYSIS
Pam Hester
May
15,2012
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
ESC
Sample
0
L573351-01
Date Received May
04, 201::
Description Process
Energy WS -,'N ASH POND
Site
IO
Sample 10 ASH POND
Project
,:
'L-23644
Collected By Steve Davis
Collection Date 05/03/12
07:30
Parameter
Result
Dec. Limit
Units
Limit
Method
to/Time By Dil
TCL? Extraction
-
1311
0
06/12
0807 MVE i
Mercury
BDL
0.0010
mg/l
0.20
7470A
O.
08/12
0953 MDC 1
Arsenic
0,20
0.050
mg/l
5.0
6010B
0:
77/12
2150 JWH 1
Barium
1.4
0.15
mg/1
100
6010£
0°:07/12
2150 JWM ]
Cadmium
BDL
0.050
mg/l
1.0
60108
0.
07/12
2150 JWM 1
Chromium
HDL
0.050
mg/1
5.0
6010B
0;
07/12
2150 JWM 1
Lead
BDL
0.050
mg/l
5.0
6010E
0;.
07/12
2150 JWH 1
Selenium
0.058
0.050
mg/1
1.0
6010B
OL
`07/12
2150 JWM I
Silver
BDL
0.050
mg/1
5.0
6010B
0r
)3 /12
2150 JWM 1
TCLP 2HE Extraction
-
1311
0?
37/12
0802 LJN 1
TCLP Volatiles
Benzene
BDL
0,050
mg/l
0.50
8260E
0::)7/12
1855 RTW 1
Carbon tetrachloride
BDL
0.050
mg/l
0.50
82608
0;
07/12
1855 RTW 1
Chlorobenzene
BDL
0.050
mg/l
100
S260B
Ow
)7/12
1855 RTW 1
Chloroform
BDL
0.25
mg/l
6.0
6260B
Of
J7/12
1855 RTW 1
1,2-Dichloroethane
BDL
0.050
mg/l
0.50
82608
0!,
)7/12
1855 RTW 1
1,1-Dichloroethane
BDL
0.050
mg/l
0.70
8260B
OE:
?7/12
1955 RTW 1
2-Butanone (MEK)
BDL
0,50
0.050
mg/1Z00
mg/1
0.70
8260E
8260E
0,&
0`')7/12
)7/12
1855 RTW 1
1855 RTW 1
Tetrachloroethene
Trichloroethene
BDL
BDL
0.050
mg/]
0.50
8260B
0,"'..
)7/12
1855 RTW I
vinyl chloride
EDL
0.050
mg/l
0.20
82608
0;-
)7/12'1855
RTW i
Surrogate Recovery
Toluene -d8
103.
6 Rec.
114.
8260B
05
]7/12
1855 RTW 1
Dibromofluoromethane
103.
t Rae.
125.
8260E
01,
17/12
1855 RTW I
a, a,a-TrifWere toluene
1,05.
s Ree.
Rec.
114.
128.
8260E
8260B
0
0 k,
17/12
17/12
1855 RTW 1
1855 RTW 1
4-Bromofluorobenmeno
92.7
TCLP Pesticides
Chlordane
8DL
0.0050
mg/l
0.030
8081A
0;.
19/12.1408
1
Endrin
BDL
0.0050
mg/1
0.020
8081A
05
19/12
1408 ]
Heptachlor
HDL
0.0050
mg/l
0.0080
8081A
OS
-19/12
1408 1
Lindane8DL
0.0050
mg/l
0.40
0081A
0:.°;9/12
1408 1
Methoxychlor
BDL
BDL
0.0050
0.010
mg/l
mg/l
10.
0.50
8081A
8081A
0 r
05
119/12
°9/12
1408 1
1408 1
Toxaphene
Surrogate Recovery
Decachlorobiphenyl
55.0
n Rec.
123.
8081A
045
9/12
'9/12
1408 1
Tetrachloro-m-xylene
75.4
8 Rec.
114,
8081A
0.,
1406 1
TCLP Herbicides
Po, 2 of 3

(';`t
N. t
FNN11RONf1N.A1,V VE'
(:111 11'715 INC
060U, (ff(;IY
r1f,I)KNII: Wyn C' Wiliflingiml, i",F(
ol & DI.S cn-cA07729
'liull I : ::;;;r._, I-%(it 11)) Ill
-Sutton-Sutton Plnnt, 8ol Sutton Steam Plant Rd, Wilmington,Fax: (1)1(1)
13,1 :. "-- --- NC 284ol
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Coiltc6ol
liFivalion 'S1
1'111� -,'RVjkTION
Salllplv Idg-J) 7& v
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By:- Z-
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..tet,'{ E }v., th
3XI � Environmental Chemists, Inc..
6602 Windmill Way • Wilmington, NC 28405
[phone] (1 -ab) o [phone] (Fax)
710 Dowsertown.Road • Manteo, NC 27954
ANALYTICAL & CONSULTING i [phone]
CHEMISTS NCDENR: DWQ CERTIFICATE it94. DLS CERTII'fCATI.i 1137729
Progress Energy - L.V. Sutton Plant
Date of Report: Jun 28, 2012
801 Sutton Plant Road
Customer PO #:
Wilmington NC 28401
Report #: 2012-06128
Attention: R. Kent Tyndall
Report to: R. Kent Tyndall
Project ID:
Chlorobenzene
SWW Method 8260/5030
< 0.01 mg/L
6/19/2012
Chloroform
SW848 Method 826015030
< 0.01 mg/L
6/19/2012
Methyl ethyl ketone
SW8M Method 8260/5030
< 0.05 mg/L
6/19/2012
Tetrachloroethylene
SWW Method 8280/5030
< 0.01 mg/L
6/19/2012
Trichloroethylene
SWW Method 8260/5030
< 0.01 mg/L
6/19/2012
Vinyl Chloride
SW848 Method 8260/5030
< 0.01 mg/L
6/19/2.012
TCLP Metals
Arsenic
EPA 200.7
<0.100 mg/L
06/14/2012
Barium
EPA 200.7
3.00 mg/L
06/14/2012
Cadmium
EPA 200.7
<0.100 mg/L
06/14/2012
Chromium
EPA 200.7
<0.100 mg/L
06/14/2012
Lead
EPA 200.7
<0.100 mg/L
06/14/2012
Selenium
EPA 200.7
<0.100 mg/L
06/14/201.2
Silver
EPA 200.7
<0.100 mg/L
06/14/2012
Mercury
EPA 245.1
<0.002 mg/L
06/28/201.2
Comment:
Reviewed by: /
Report #:: 2012-06128 Pana 2 of 7

Environmental Chemists, Inc.
g i s r 8 6602 Windmill Wav • Wilmington, NC 28405
[phone] (Lab) • [phone] (Pax)
sM
710 Bowsertown Road • Manteo, NC 27954
�( 4(M � � [phone]
CHEMISTS
ANALYTICAL&CONSULTING P1t
NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Progress Energy - L.V. Sutton Plant Date of Report: Jun 28, 2012
801 Sutton Plant Road Customer PO #:
Wilmington NC 28401 Report #: 2012-06128
Attention: R. Kent Tyndall Report to: R. Kent Tyndall
Project ID:
Lab ID Sample ID:
12-14940 Site: Ash Sample
Test
Collect Date/Time
6/8/2012 2:00 PM
Method
Matrix
Solid/Sludge
Results
Sampled by
Greg Brown
Date Analyzed
Total Solids (%)
SM 2540 B
61.2 %
06/12/2012
Chlordane
SW 848 Method 80818/3610
<0.0005 mg/L
06/21/2012
Endrin
SW Us Method 60819/3510
<0.00015 mg/L
06/21/2012
Heptachlor
SW 846Method 808IM510
<0.00015 mg/L
06/21/2012
Heptachlor epoxide
SW 646 Method 80818/3510
<0.00015 mg/L
06/21/2012
Lindane
SW 646 Method8081BI3510
<0.00015 mg/L
06/21/2012
Methoxychlor
SW 846 Method 60818/3510
<0.00015 mg/L
06/21/2012
Toxaphene
SW 846Method 80818/3510
<0.0005 mg/L
06/21/2012
1,4-Dichlorobenzene(TCLP)
SW 846 method 8270/3510
<0.005 mg/L
06/11/2012
2,4,5-Trichlorophenol(TCLP)
SW 846Method 8270r3510
<0.005 mg/L
06/11/2012
2,4,6-Trichlorophenol(TCLP)
SW 848 method 8270/3510
<0.005 mg/L
06/11/2012
2,4-Dinitrotoluene (TCLP)
SW 846 method 8270/3510
<0.005 mg/L
06/11/2012
Cresol (TCLP)
SW 846 method 8270/3510
<0.005 mg/L
06/11/2012
Hexachloro-1,3-butadiene(TCLP)
SW 846me4hod827013510
<0.005 mg/L
06/11/2012
Hexachlorobenzene(TCLP)
SW SMMethod $27013510
<0.005 mg/L
06/11/2012
Hexachloroethane(TCLP)
SW 846medod8270/3510
<0.005 mg/L
06/11/2012
m + p Cresol (TCLP)
SW 848 method 8270/3510
<0.005 mg/L
06/11/2012
Nitrobenzene (TCLP)
SW 846 method 8270/3510
<0.005 mg/L
06/11/2012
o-Cresol(TCLP)
SW 846 method 8270/3510
<0.005 mg/L
06/11/2012
Pentachlorophenol (TCLP)
SW 948method 827013510
<0.025 mg/L
06/11/2012
Pyridine (TCLP)
SW 846 method 8270/3510
<0.005 mg/L
06/11/2012
2,4,5 -TP
SW646 Method 8151A
<0.00333 mg/L
06/25/2012
2,4-0
SW946 Method 8151A
<0.0133 mg/L
06/25/2012
1,1-Dichloroethylene
Sw646Method 82W/5030
<0.01 mg/L
6/19/2012
1,2-Dichloroethane
SWW Method 826015030
<0,01 mg/L
6/19/2012
Benzene
SW846 Method 8280/5030
< 0.01 mg/L
6/19/2012
Carbon Tetrachloride
SW646 Method 8260/5030
< 0.01 mg/L
6/19/2012
Report #:: 2012-08128
c.— , -,I

�ceAnalyfical-
CHAIN-OF-CUSTODY
/ Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C
Page: of
Required Client Information: Required Project Information: Invoice Information -
Company. Progress Energy- Roxboro Plant Report To: Dana Newcomb Attention:
Address: 1700 Dunnaway Road copy To: Amber Ramey. Bill Milam Company Name:
REGULATORY AGEbICF i± �` k c' -
.�r�
Semora, NC 27343 Address:
r NODES r GROUND WATER r~ DRINKING WATER
(' UST r RCRA �'" OTHER
Email To: dana.newcombCfponmail.com Purchase Order No.- Pace Quota
Reference:
Phone: [phone]a— 336-598-4096 Project Name: Ash.Reuse PaceP Dietl
t'$If LOCatI0I1
' Manager.
'' x,j. tx
NC
Requested Due Date/TAT: 5DAYSProject Number Pace Profile #:.
IRe�uested,''Analy�isdFdt�red��/t��<
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m
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'Important Note: By signing this form you era accepting Paces NET 30 day payment terms and agreeing to late charges of 1.5% per month for any invoices not paid Within 30 days. FALL-Q-020rev.08, 12 -Oct 2007 '

Project: ROX-Ash Reuse 5/10
Pace Project No.: 92118902
Sample: Ash Reuse TCLP Lab ID: 92118902002 Collected: 05/10/1210:00 Received: 05/17/12 17:04 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
8270 MSSV TCLP Sep Funnel
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 05/23/12 14:15
2,4,5-Tdchlorophenol
NO ug/L
50.0
1
®
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Serviced, Inc.
ace Analytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
8800 Kincey Ave. Sufte 100
www0018es,c.
Eden, NC 27288
Asheville, NC 28804
Huntersvllle, NC 28078
NRrobenzene-d5 (S)
[phone]
(628)254^-/7176
[phone]
05130/12 08:30 06/30/12 16:24 4165-60-0
2-Fluorobiphenyl(S)
Roy �Vy-6
n /"4
1
ANALYTICAL RESULTS
Terphenyl-d`14(S)
!"
Project: ROX-Ash Reuse 5/10
Pace Project No.: 92118902
Sample: Ash Reuse TCLP Lab ID: 92118902002 Collected: 05/10/1210:00 Received: 05/17/12 17:04 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
8270 MSSV TCLP Sep Funnel
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 05/23/12 14:15
2,4,5-Tdchlorophenol
NO ug/L
50.0
1
05!30/1208:30 05/30/1216:24 95.95-4
2,4,6-Tdchlorophenol
NO ug/L
50.0
1
05130/12 08:30 05/30/12 16:24 88-06-2
Surrogates
05/22/12 15:07 56.23-5
ND ug/L
190
38
NRrobenzene-d5 (S)
65%
12-102
1
05130/12 08:30 06/30/12 16:24 4165-60-0
2-Fluorobiphenyl(S)
66 %
13-107
1
05130112 08:30 05/30/12 16:24 321-60-8
Terphenyl-d`14(S)
74 %
21-132
1
05/3011208:30 05/30/1216:24 1718-51-0
Phenol -d6 (S)
31 %
10-110
1
05/30112 08:30 05/30/12 16:24 13127-88-3
2-Fluorophenol (8)
41 %
10-110
1
05/30112 08:30 06/30/12 16:24 367-12-4
2,4,6-Tdbromophenol (S)
69 %
27-108
1
05/30112 08:30 05/30112 18:24 118-79-6
8260 MSV TCLP
Benzene
2-Butanone (MEI)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4 -Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
1,2-Dichloroelhane-d4 (S)
Toluene -d8 (S)
4-BromoBuorobenzene (S)
Dibromo0uoromethane (S)
Date: 06/01/2012 10:47 AM
Analytical Method: EPA 8260
NO ug/L
190
38
06/22112 15:07 71-43-2
ND ug/L
380
38
05/22/12 15:07 78-93-3
ND ug/L
190
38
05/22/12 15:07 56.23-5
ND ug/L
190
38
05/2211215:07 108-90-7
ND ug/L
190
38
05/22/12 15:07 67-66-3
NO ug/L
190
38
05/22/1215:07 10646-7
NO ug/L
190
38
05122/1215:07 107-06-2
ND ug/L
190
38
05/22/12 15:07 75-35-4
NO ug/L
190
38
05122/1215:07 127-18-4
NO ug/L
190
38
05122/12 15:07 79-01-6
NO ug/L
190
38
05/22/12 15:07 75.01.4
110 %
70-130
38
05/22/12 15:07 17060-07-0 19
102 %
67-135
38
05/22/12 15:07 2037-26-5
100 %
70-130
38
05/22/1215:07 460-00-4
104 %
70-130
38
05/22/12 15:07 1868-53-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 23

n Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2I+eAP1 ]ll /�Il+a' 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
C11� I IG[ i l� Eden, NC 27288 Asheville, NC 28804' Huntersville, N628078
www.pecslabs.com [phone] [phone] [phone]
ANALYTICAL RESULTS Aclxcr 6m AA. +
Project: ROX-Ash Reuse 5/10
Pace Project No.: 92118902
Sample: Ash Reuse TCLP Lab ID: 92118902002 Collected: 05/10/12 10:00 Received: 05/17/12 17:04 Matrix: z3olio
Results reported on a "dry -weight' basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8081 GCS Pesticides, TCLP SPE Analytical Method: EPA 8081 Preparation Method: EPA 3535
Leachate Method/Date: EPA 1311; 05/23/12 14:15
gamma -BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
0.50 1
3.0 1
0.50 1
0.50 1
0.50 1
1000 1
3.0 1
05/24/12 13:00 05/26/12 00:36 58-89-9
05124/12 13:00 05/26/12 00:36 57-74-9
05124/12 13:00 05/26/12 00:36 72-20-8
05/24/12 13:00 05/26/12 00:36 76-44-8
05/24/1213:00 05/26/12 00:36 1024-57-3
05/24/12 13:00 05/26/12 00:36 72-43-5
05/24/12 13:00 05/26/12 00:36 8001-35-2
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
89 %
77 %
10-138 1
10-110 1
05/24/12 13:00 05/26/12 00:36 2051-24-3
05/2411213:00 05/26/12 00:36 877-09-8
8151 Chlorinate Herbicide TCLP
Analytical Method: EPA 8151
2,4-D
2,4,5 -TP (Silvex)
ND mg/L
ND mg/L
0.010 1
0.010 1
05123/12 08:00 05/24/12 07:53 94-75-7
05/23/12 08:00 05/24/12 07:53 93-72-1
Surrogates
o
70-130 1
05/23/12 08:00 05/24/12 07:53 19719-28-9
6010 MET ICP, TCLP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311; 05/24/12 18:25
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
ND mg/L
0.52 mg/L
ND mg/L
ND mg/L
ND mg/L
ND mg/L
ND mg/L
0.025 1
0.50 1
0.0050 1
0.025 1
0.025 1
0.10 1
0.025 1
05125/1215:00 05/27/1214:58 7440-38-2
05125/1215:00 .05/27/1214:58 7440-39-3
05125/1215:00 05/27/1214:58 7440-43-9
05125/1215:00 05/27/1214:58 7440-47-3
05125/1215:00. 05/27/1214:58 7439-92-1 .
05125/1215:00 05/27/1214:58 7782-49-2
05125/1215:00 05/27/1214:58 7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311;
05/24/12 18:25
Mercury
ND mg/L
0.00020 1
05129/1212;45 05/3011210:26 7439-97-6
8270 MSSV TCLP Sep Funnel
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311;
05/23/12 14:15
1,4 -Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
50.0 1
50.0 1
50.0 1
50.0 1
50.0 1
50.0 1
50.0 1
50.0 1
100 1
50.0 1
05130/1208:30 05/30/1216:24 106-46-7
05130/12 08:30 05/30/12 16:24 121-14-2
05/30/1208:30 05/30/1216:24 87-68-3
05130/12 08:30 05/30/12 16:24 118-74-1.
05130/12 08:30 05/30/12 16:24 67-72-1
05130/12 08,30 05/30/12 16:24 95-48-7
05130/12 08:30 05/30/1216:24
05130/12 08:30 05/30/12 16:24 98-95-3
05130/12 08:30 05/30/1216:24 87-86-5
05130/12 08:30 05/30/12 16:24 110-86-1
Date: 06/01/2012 10:47 AM REPORT OF LABORATORY ANALYSIS Page 6 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

11�2cieAnaocal"
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'aMudaM Nalc By sgnaq MMfens Yeu an saepWq Pena'a NEr3odry prymaalemvaM yesra bkb dwaea Wl.e%pr monNar myunvlw natpaM tMaftl as tlayu. F -ALL -Q 20rw.07. ls-MaY-2007
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;I�AceAnaljftal
www.pacelabs.com
r
Project: 8270 ReRun
Pace Project No.: 92120068
i
Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS YoCp-p Pf etJ
Sample: Bottom Ash Lab ID: 92120068001
Results reported on a "dry -weight' basis
Parameters Results Units
Collected: 05/10/12 00:00
Report Limit DF
Received: 05/14/12 13:40 Matrix: Solid
Prepared Analyzed CAS No.
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 06/06/12 14:20
1,4 -Dichlorobenzene
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 106-46-7
2,4-Dinitrotoluene
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 121-14-2
Hexachloro-1,3-butadiene
ND ug/L
50.0
1
0610711209:00 06/07/1217:13 87-68-3
Hexachlorobenzene
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 118-74-1
Hexachloroethane
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 67-72-1
2-Methylphenol(o-Cresol)
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 95-48-7
3&4-Methylphenol(m&p Cresol)
ND uglL .
50.0
1
06107/12 09:00 06/07/12 17:13
Nitrobenzene
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 98-95-3
Pentachlorophenol
ND ug/L
100
1
06107/12 09:00 06/07/12 17:13 87-86-5
Pyridine
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 110-86-1
2,4,5 -Trichlorophenol
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 95-95-4
2,4,6 -Trichlorophenol
ND ug/L
50.0
1
06107/12 09:00 06/07/12 17:13 88-06-2
Surrogates
Nitrobenzene -d5 (S)
62 %
12-102
1
06107/12 09:00 06/07/12 17:13 4165-60-0
2-Fluorobiphenyl (S)
66 %
13-107
1
06107/12 09:00 06107/1217:13 321-60-8
Terphenyl-d14 (S)
98 %
21-132
1
06107/12 09:00 06/07/12 17:13 1718-51-0
Phenol -d6 (S)
34 %
10-110
1
06107/12 09:00 06/07/12 17:13 13127-88-3
2-Fluorophenol (S)
44 %
10-110
1
06107/12 09:00 06/07/12 17:13 367-12-4
Qual
H2
Date: 06/20/2012 02:30 PM REPORT OF LABORATORY ANALYSIS Page 3 of 7
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 05/21/12 14:10
2,4,5 -Trichlorophenol
NO ug/L
2500
10
® ce
Analytical Services, Sermices, Inc.
Pace Analyti225Rverside
PaAnalytical9800
aceAnalytical 205EastMeadow Road Suite A
Dr.
Kncey Ave. Suite 100
l wxwpacefaDs.com
Eden, NC 27288
Asheville, NC 211804
Hunters0e, NC 28078
190
[phone]
(828)254-71�/�7�6
[phone]
Nitrobenzene -d5 (S)
ANALYTICAL RESULTS
{/� r0-xy)
f n l(ak+
Project: Mayo -Ash TCLP 5/10/12
4165-60-0 D3,133,
Chloroform
NO ug/L
Pace Project No.: 92118502
38
05/16/1213:41
S4
Sample: Composite Bottom Ash Lab ID:
92118602001 Collected: 05/10/1200:00
Received: 05/14/1213:40
Matrix: Solid
Results reported on a "dry -weight" basis
321-60-8
Terphenyl-d14 (S)
0 %
Parameters Results
Units Report Limit OF
Prepared Analyzed
CAS No. Qua[
8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 05/21/12 14:10
2,4,5 -Trichlorophenol
NO ug/L
2500
10
05/22112 13:00 05/23/12 19:27
95-954
2,4,6 -Trichlorophenol
NO ug/L
2500
10
05/2211213:00 05/23/1219:27
88-06-2
Surrogates
NO ug/L
190
38
05/16/12 13:41
56-23-5
Nitrobenzene -d5 (S)
0 %
12-102
10
05/22/12 13:00 05/23/12 19:27
4165-60-0 D3,133,
Chloroform
NO ug/L
190
38
05/16/1213:41
S4
2-Fluorobiphenyl(S)
0 %
- 13-107
10
05/22112 13:00 05/23/12 19:27
321-60-8
Terphenyl-d14 (S)
0 %
21-132
10
05/2211213:00 05/23/12 19:27
1718-51-0
Phenol -0 (S)
0 %
10-110
10
05/22112 13:00 05/23112 19:27
13127-88-3
2-Fluorophenol(S)
0 %
10-110
10
05122112 13:00 05/23/1219:27
387-12-4
2,4,6-Tdbromophenol (S)
0 %
27-108
10
05/22112 13:00 05/23112 19:27
118-7"
8260 MSV TCLP Analytical Method: EPA 8260
Benzene
NO ug/L
190
38
05/16/1213:41
7143-2
2-Butanone (MEK)
NO ug/L
380
38
05/16/1213:41
7&93-3
Carbon tetrachloride
NO ug/L
190
38
05/16/12 13:41
56-23-5
Chlorobenzene
NO ug/L
190
38
05/16/1213:41
108-90-7
Chloroform
NO ug/L
190
38
05/16/1213:41
67-66-3
1,4 -Dichlorobenzene
NO ug/L
190
38
05/16/1213:41
10646-7
1,2-Dichloroethane
NO ug/L
190
38
05/16/12 13:41
107-06-2
1,1-Dichloroethene
NO ug/L
190
38
05/16/1213:41
75-354
Telrachloroethene
NO ug/L
190
38
05/16/1213:41
127-18-4
Trichloroethene
NO ug/i-
190
38
05/16/12 13:41
79-01-6
Vinyl chloride
NO ug/L
190
38
05/16/12 13:41
75-01-4
Surrogates
1,2-Dichloroetharte-d4 (S)
95%
70-130
38
05/16/12 13:41
17060-07-0
Toluene-till(S)
101 %
67-135
38
05/16/12 13:41
2037-26.5
4-Bromolluorobenzene (S)
103 %
70-130
38
05/16/12 13:41
460-00-4
Dibromo6uoromethane (S)
102%
70-130
38
05/16/12 13:41
1868-53-7
Date: 05/29/201203:51 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of PaceAnalyfical Services, Inc..
1g
Page 5 of 14

aceAnalytical
/ www.pacelabs.com
Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
205 East Meadow Road - SuiteA 2225 Riverside Dr. 9800 KinceyAve. Suite 100
Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS )446L9 D P"+
Project: Mayo -Ash TCLP 5/10/12
Pace Project No.: 92118502
Sample: Composite Bottom Ash Lab ID: 92118502001 Collected: 05/10/12 00:00
Results reported on a "dry -weight' basis
Parameters Results Units Report Limit DF
Received: 05/14/12 13:40 Matrix: Solid
Prepared Analyzed CAS No. Quaff
8081 GCS Pesticides, TCLP SPE
Analytical Method: EPA 8081 Preparation Method: EPA 3535
Leachate Method/Date: EPA 1311; 05/21/12 14:10
gamma -BHC (Lindane)
ND ug/L
0.50 1
05/24/12 13:00 05/26/12 00:01 58-89-9
Chlordane (Technical)
ND ug/L
3.0 1
05/24/12 13:00 05/26/12 00:01 57-74-9
Endrin
ND ug/L
0.50 1
05/24/12 13:00 05/26/12 00:01 72-20-8
Heptachlor
ND ug/L
0.50 1
05/24/12 13:00 05/26/12 00:01 76-44-8
Heptachlor epoxide
ND ug/L
0.50 1
05/24112 13:00 05/26/12 00:01 1024-57-3
Methoxychlor
ND ug/L
1000 1
05/24112 13:00 05/26/12 00:01 72-43-5
Toxaphene
ND ug/L
3.0 1
05/24112 13:00 05/26/12 00:01 8001-35-2
Surrogates
Decachlorobiphenyl (S)
87 %
10-138 1
05/24112 13:00 05/26/12 00:01 2051-24-3
Tetrachloro-m-xylene (S)
66 %
10-110 1
05/24112 13:00 05/26/12 00:01 877-09-8
8151 Chlorinate Herbicide TCLP
Analytical Method: EPA 8151
2,4-D
ND mg/L
0.010 1
05/18/12 14:10 05/19/12 08:36 94-75-7
2,4,5 -TP (Silvex)
ND mg/L
0.010 1
05/18112 14:10 05/19/12 08:36 93-72-1
Surrogates
2,4-DCAA (S)
97 %
70-130 1
05/18112 14:10 05/19/12 08:36 19719-28-9
6010 MET ICP, TCLP
Analytical Method: EPA 6010
Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311;
05/23/12 16:35
Arsenic
ND mg/L
0.025 1
05/24/12 11:10 05/24/1217:46 7440-38-2
Barium
ND mg/L
0.50 1
05/24/12 11:10 05/24/1217:46 7440-39-3
Cadmium
ND mg/L
0.0050 1
05/24/12 11:10 05/24/1217:46 7440-43-9
Chromium
0.027 mg/L
0.025 1
05/24112 11:10 05/24/1217:46 7440-47-3
Lead
ND mg/L
0.025 1
05/24112 11:10 05/24/1217:46 7439-92-1
Selenium
ND mg/L
0.10 1
05/24/12 11:10 05/24/1217:46 7782-49-2
Silver
ND mg/L
0.025 1
05/24112 11:10 05/24/1217:46 7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470
Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311;
05/23/12 16:35
Mercury
ND mg/L
0.00020 1
05/25/12 10:55 05/25/1215:25 7439-97-6
8270 MSSV TCLP Sep Funnel
Analytical Method: EPA 8270
Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 05/21/12 14:10
1,4 -Dichlorobenzene
ND ug/L
2500 10
05/22112 13:00 05/23/1219:27 106-46-7
2,4-Dinitrotoluene
ND ug/L
2500 10
05/22112 13:00 05/23/1219:27 121-14-2
Hexachloro-1,3-butadiene
ND ug/L
2500 10
05/22/12 13:00 05/23/1219:27 87-68-3
Hexachlorobenzene
ND ug/L
2500 10
05/22/12 13:00 05/23/1219:27 118-74-1
Hexachloroethane
ND uglL
2500 10
05/22112 13:00 05/23/1219:27 67-72-1
2-Methylphenol(o-Cresol)
ND ug/L
2500 10
05/2211213:00 05/23/1219:27 95-48-7
3&4-Methylphenol(m&p Cresol)
ND ug/L
2500 10
05/22112 13:00 05/23/12 19:27
Nitrobenzene
ND ug/L
2500 10
05/22112 13:00 05/23/1219:27 98-95-3
Pentachlorophenol
ND ug/L
5000 10
05/22112 13:00 05123/1219:27 87-86-5 IR
Pyridine
ND ug/L
2500 10
05/22112 13:00 05/23/1219:27 110-86-1
Date: 05/29/2012 03:51 PM REPORT OF LABORATORY ANALYSIS Page 4 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

TRITEST ' n
6701 Conference Drive, Raleigh, -6 27607 Chani of Custody -2s
Ph: (919) 67, NC 84 fax: [phone] Tritest W O #
NCWW CenY87, NCDW Cenpa7731
Report Results To: Bill To:
Company:64?veSs�h1�,tTr1lv-,([ 'L� %era a e9 - Project Reference:
Address:
../,6'7,7 Project Number:
A6 7 % 41121 51911 r e%( Purchase Order #:
Attn: _Arc kY
/ ��— L� Standard Report Delivery
Phone(�1kj!— ,398 Fax; GO/Gls 16aro G• ❑ Rush Report Delivery _ � � P (w/ wrcharge)
Sampled by (signature):X90 * WO�JWWe� te
IbyftkbwR
Requested Due Date
.g--� ., r_ M1.. ,c.;3 f.
i.,�€ �:.+r •. rh'i
•.- rr ,c.,.. sr;
_ _. �„ .�.a,,'�Y7'd. i
. '.' -;u..i 4+x r ..-
� 9'�5 �w � .,r'�
-
, •�
•r-er+� d n =-i Y r
: .' ��,r..r��,..'' ; - ..�1
L@C
57lL`llL
Parameter/(Limit
Methyl ethyl ketone
,..)
110041WCIASy
(200)
J1,2-Dichloroethane''
Arsenic (5)
(0 5)-
um (100)
NRrobenzene (2)
1,1-3"`-.e%
ene (0 5)
Pentachlorophenol
0¢hloroethylene '
(0 7)
-
mm (1)
(100)
J 2,4-D)nrtrot0luenearbon
Pyndme (5)
(013)loride
(0.5)
Selenium
J Endrin (0 02)ane(003)
t(30)
Hexachlorobenzenebenzene
Tetrachloroethylene(013)100)
(07)Heptachlor
(o 008)form
(6)
J Toxaphene(0 5)
✓ HexachlOrO-1,3-ium
5
O
✓7nchloroethylene
butadiene (o s) n
7 Hexachloroethanein-Cresol
(200)
(0 5)
2'4'5-
(3 0)
10
o-Cresol(200)
Trichlorophenol
Lead (5)
Ip
p -Cresol (200)
(400)
J Lindane(04)
-
Cresol (200)
2.4,6-
Mercury (0 2)
2,4-0(10)
Tnchlorophenol (2)
J 2,4,5
Methoxychlor (10)
1,4-
-TP (1)
,4Dichlorobenzene
Dichlorobenzene
J Vinyl chloride (0 2)
.�
R�equWtad by (egnewre)
R by Isrynatwe)
(7 5)
nate Tina
-
'�-/36v
Receipt conditions (Lab Use Only)
Rnup6'—�snee M (siA�etwo)
s-��"-1z
1:14±2°C 0—Temp: �•� •C
Recanatl M (e5nature)
Daze rime
Res Chlorine ❑Absent ❑Present❑n/a.
Reloquehetl by 1s'eeetbre)
Reoervetl by (s'9naase)
Date Time
Acid preserv. <27 ❑ Yes ❑ No ❑ Na
Bess preserv.>12? ❑ Yes ❑ No ❑ n/a

6701 Conference Drive
Raleigh, NC 27607
Telephone: [phone]
Fax: [phone]
I'aQ
Page 2 of 2
NCNM Cert. #: 067
NC/DW Cert. #: 37731
Laboratory Report
Work Order #: 1205-00757
No. Sample ID Date Sampled Time Sampled Matrix Sample Type Condition
001 LEE PLANT ASH POND 5/10/2012 0:00 OT Grab Ambient
Analyzed
Test Performed Method Results Date Time Qualifier
Tetrachloroethene
EPA 8260B
<5 ug/L
5/17/12
12:16
Trichloroethene
EPA 82608
<5 ug/L
5117/12
12:16
Vinyl chloride
EPA 82608
<10 ug/L
5/17/12
12:16
TCLP Herbicides by 8151
EPA 8151
5/25112
0:00
2,4-D
EPA 8150
<5.0# mg/L
5/25112
0:00
2,4,5 -TP (Siivex)
EPA 8150
<0.5# mg/L
5/25112
0:00
Cresols
EPA 1311
<5# mg/L
5/25/12
0:00
#ANALYZED BY SUMMIT EVIRONMENTAL TECHNOLOGIES, INC. IN CUYAHOGA
FALLS, OH.
Reviewed by:
for Tritest, Inc.

_-, ace Ana/ytica/W
6701 Conference Drive
Raleigh, NC 27607
Telephone: [phone]
Fax: [phone]
Laboratory Report
--- Prepared for ---
Ricky Miller / Tommy Hare
Progress Energy- H.F. Lee
1677 Old Smithfield Rd.
Goldsboro, INC 27530
Report Date:
Date Received:
Work Order #:
Com- PlyJ
Page 1 of 2
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
6/6/2012
611012012
1205-00757
Project No.: 01 Gust. Code: CP9052
Project ID: LEE PLANT ASH POND Ceet. P.O.#: 5900
No. Sample ID
001 LEE PLANT ASH POND
Date Sampled Time Sampled Matrix Sample Type Condition
511012012 0:00 OT Grab Ambient
Test Performed
Method
Results
Analyzed
Date Time Qualifier
Metals TCLP Package
EPA 1311
5/16/12
15:37
TCLP Arsenic
EPA 200.8
<0.060 mg/L
5116112
15:37
TCLP Barium
EPA 200.8
<1.00 mglL
5116112
15:37
TCLP Cadmium
EPA 200.8
<0.010 mg/L
5116112
15:37
TCLP Chromium
EPA 200.8
<0.050 mg/L
5116112
15:37
TCLP Lead
EPA 200.8
<0.050 mg/L
5/16/12
15:37
TCLP Selenium
EPA 200.8
0.116 m9IL
5/16112
15:37
TCLP Sliver
EPA 200.8
<0.050 mg/L
5/16112
15:37
TCLP Mercury Analysis
EPA 245.1
<0.2 ug/L
5/14112
15:29
TCLP Pesticides; Liquids
EPA 8081A
5/16112
14:00
gamma -BHC (Lindane)
EPA 8081A
<0.05 uglL
5116112
14:00
Chlordane
EPA 8081A
<0.2 ug/L
5116/12
14:00
Endrin
EPA 8081A
<0.06 ug/L
5/16112
14:00
Heptachlor
EPA 8081A
<0.05 ug/L
5/16112
14:00
Methoxychlor
EPA 8081A
<0.5 ug/L
5/16/12
14:00
Toxaphene
EPA 8081A
<2.4 ug/L
5/16/12
14:00
TCLP 8270
EPA 8270C
5/16112
14:00
1,4 -Dichlorobenzene
EPA 8270C
<0.050 mg/L
5/16112
14:00
2,4-Dinitrotoluene
EPA 8270C
<0.050 mg/L
5/16112
14:00
Hexachlorobenzene
EPA 8270C
<0.050 mg/L
5/16112
14:00
Hexachlorobutadiene
EPA 8270C
<0.050 mg/L
5/16/12
14:00
Hexachloroethane
EPA 8270C
<0.050 mg/L
5116/12
14:00
Nitrobenzene
EPA 8270C
<0.050 mg/L
5/16/12
14:00
Pentachlorophenol
EPA 8270C
<0.250 mg/L
5116/12
14:00
Pyrldine
EPA 8270C
<0.050 mglL
5/16112
14:00
2,4,5 -Tris hlorophenot
EPA 8270C
<0.050 mg/L
5/16112
14:00
2,4,6 -Trichlorophenol
EPA 8270C
<0.050 mg/L
5116112
14:00
TCLP Volatiles by 8260B
EPA 82608
5117112
12:16
Benzene
EPA 8260B
<5 ug/L
5117112
12:16
Carbon tetrachloride
EPA 82608
<5 uglL
5117112
12:16
Chlorobenzene
EPA 8260B
<5 ug/L
5/17112
12:16
Chloroform
EPA 82608
<5 ui lL
5117/12
12:16
1,2.Dichloroethane
EPA 82608
<5 ug/L
5/17/12
12:16
1,1-Dichloroethene
EPA 82608
<5 uglL
5/17/12
12:16
Methyl ethyl ketone (MEK)
EPA 8260B
<50 ug/L
5117112
12:16

TRITEST
6791 Cuuteetue Drive, Rate-gh, NC 27697 �� � � ` ti � �� s 1iftest W Uil__-, �—
;tit: ((,19) 834.4984 tax. (419) 93-:641)7-
NCV:'1N Cerift67 NCDW Cert837Td 1
Report Results To: Bill To:
Company: rov YeSS'
Address. �-b6 Til_. �1�f
Alt:
Ph
Sa
Project Reference.
Project Number: _
Purchase Order #:
❑ St rd Report Delivery
ush Report Delivery (w/ surcharge)
' Rush projects are subject tb pnor apWova by ibe �ralm
Requested Due Date %Li/
Sample Description
C ear
Gin
Sta Date
Start
End Date
End Time
Matrix
DIV I"
w
Analyses Requested
Truest
Sample#
/
J�"
Time
ed by (signature) /
Re�inctu,
S
Rod by (s to p)
Relinquished by (Stonaiure)
Received by signaune -
fC3
Received by (sign lure /
Received by (siynatme)
'
Date
Date
Dale
lime
Receipt Conditions (Lab Use Only)
4-12°C PdTemp"� °C
Res Chlorine ❑ Absent ❑ Present ❑ nla
Acid presets <2? ❑Yes ❑ No ❑ n/a
Base presets >129 El Yes 0 No Eln/a
Time
Time

Telephone: [phone]
Fax: [phone]
0
e
TU TE ST
6701 Conference Drive
Raleigh, NC 27607
Telephone: [phone]
Fax: [phone]
Laboratory Report
Cqq rbt q -t-�
Page 2 of 2
NC[WW Cert. #: 067
NCIDW Cert. #: 37731
Work Order* 1201-02102
No. Sample ID Date Sampled Time Sampled Matrix Sample Type Condition
001 EAST ASH POND ASH 1/2412012 10:00 OT Grab Ambient
Test Performed
Method
Results
Lab Loc
DalZed Time Qualifier
Hexachlorobutadiene
EPA 8270C
<0.050 mgIL
R
1/30112
11:00
Hexachloroethane
EPA 8270C
<0.050 mgIL
R
1130112
_11:00
2-Methylphenol
EPA 8270C
<0.050 mgIL
R
1/30/12
11:00
3-&4-Methylphenol
EPA 8270C
<0.100 mgIL
R
1/30112
11:00
Nitrobenzene
EPA 8270C
<0.050 mgIL
R
1130/12
11:00
Pentachlorophenol
EPA 8270C
<0.250 mgIL
R
1130112
11:00
Pyridine
EPA 8270C
<0.050 mgIL
R
1130112
11:00
2,4,6 -Trichlorophenol
EPA 8270C
<0.060 mgIL
R
1130112
11:00
2,4,6 -Trichlorophenol
EPA 8270C
<0.050 mgIL
R
1130112
11:00
TCLP Herbicides by 8151
EPA 8151
R
211112
0:00
2,4-D
EPA 8150
<0.5# mgIL
R
211112
0:00
2,4,5 -TP (Silvex)
EPA 8160
<0.5# mgIL
R
211112
0:00
#ANALYZED BY SUMMIT EVIRONMENTAL TECHNOLOGIES, INC. IN CUYAHOGA
FALLS,OH.
Reviewed by:
i
for Tritest, Inc.

I
an TE ST
Page 1 of 2
Labo.ratory Report
Lab Location W' Lab Location 'C'
NCNVW Cert.#: 067 NC/DW Cert.#: 37731 NC/WW Cert.#: 103 NC/DW Cert.#: 37733
6701 Conference Dr, Raleigh, NC 27607 6300 Ramada Dr, Suite C2, Clemmons, NC 27012 ,
Ph: [phone] Fax: [phone] r Ph: [phone] Fax: [phone]
Project No.: 01 Report Date: 2/10/2012
Project ID: FULL TCLP ANALYSIS Date Received: 1/25/2012
--- Prepared for ---
Danny Hedgepeth
Progress Energy - Cape Fear
500 CP&L Rd.
Moncure, NC 27559
Work Order #: 1201-02102
Cust. Code: CP4625
Cust. P.O.#: 5900
No. Sample ID Date Sampled Time Sampled Matrix Sample Type Condition
001 EAST ASH POND ASH 1/24/2012 10:00 OT Grab Ambient
analyzed --- --
Test Performed Method Results Lab Loc Date Tlme Qualifier
Metals TCLP Package
EPA 1311
R
2/6/12
15:51
TCLP Arsenic
EPA 200.8
<0.050 mg/L
R
2/6/12
15:51
TCLP Barium
EPA 200.8
1.24 mg/L
R
2/6112
15:51
TCLP Cadmium
EPA 200.8
<0.010 mg/L
R
216/12
15:51
TCLP Chromium
EPA 200.8
<0.050 mg/L
R
216112
15:51
TCLP Lead
EPA 200.8
<0.050 mg1L
R
216112
15:51
TCLP Selenium
EPA 200.8
0.203 mg1L
R
216112
15;51
TCLP Silver
EPA 200.8
<0.050 mg/L
R
216/12
15:51
TCLP Mercury Analysis
EPA 245.1
<0.2 ug/L
R
2/1112
15:27
TCLP Pesticides; Liquids
EPA 8081A
R
1/26112
12:00
gamma -BHC (Lindane)
EPA 8081A
50.05 uglL
R
1126/12
12:00
Chlordane
EPA 8081A
<0.2 ug/L
R
1/26/12
12:00
Endrin
EPA 8081A
<0.06 uglL
R
1126/12
12:00
Heptachlor
EPA 8081A
<0.05 uglL
R
1126/12
12:00
Heptachlor Epoxide
EPA 8081A
<0.8 ug/L
R
1126/12
12:00
Methoxychlor
EPA 8081A
<0.5 ug/L
R
1126112
12:00
Toxaphene
EPA 8081A
<2.4 ug/L
R
1/26112
12:00
TCLP Volatiles by 8260B
EPA 82608
R
1/30112
12:24
Benzene
EPA 8260B
<5 ug/L
R
1/30112
12:24
Carbon tetrachloride
EPA 8260B
<5 ug/L
R
1/30112
12:24
Chlorobenzene
EPA 8260B
<5 ug/L
R
1130112
12:24
Chloroform
EPA 8260B
<5 ug/L
R
1/30112
12:24
1,2-Dichloroethane
EPA 82608
<5 ug/L
R
1/30112
12:24
1,1-Dichloroethene
EPA 8260B
<5 ug/L
R
1/30/12
12:24
Methyl ethyl ketone (MEK)
EPA 8260B
<60 ug/L
R
1/30/12
12:24
Tetrachloroethene
EPA 82608_
<5 ug/L
R
1130112
12:24
Trichloroethene
EPA 8260B
<5 ug/L
R
1/30/12
12:24
Vinyl chloride
EPA 8260B
<10 ug/L
R
1130112
12:24
TCLP 8270
EPA 8270C
R
1/30112
11:00
1,4 -Dichlorobenzene
EPA 8270C
<0.050 mg/L
R
1/30/12
11:00
2,4-Dinitrotoluene
EPA 8270C
<0.050 mg/L
R
1/30/12
11:00
Hexachlorobenzene
EPA 8270C
<0.050 mg/L
R
1130112
11:00

aceAnalydcal
Required Client Information: Section A Required Client Information: Section B
Company: Progress Energy Carolinas, Inc. Report To: Crystal Diedrich & Laurie Mooi
Address: 200 CP&L Drive Copy To: Crvstal.Diedrichd pgrimail.com
Arden. NC 26704 Invoice To: Crystal Diedrich
Phone: Fax: P.O.
[phone] ($28)667-5204 Project Name: Ponded Ash for Reuse Pe
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain-of-Castodyis a LEGAL DOCUMENT. All relevant fields must be completed accurately
Page: 1 of'" 1
Client Information (Check quotelcontract): To Be Completed by Pace Analytical Client: Section C
Requested Due Date:
Quote Reference:
'TAT:
Project Manager.
SectionRequired Client Information: •
Lip
• Tum around times less than 14 days subject
Project 0: '
laboratory and contractual oblgaWna and may
Profile lk
in a Rush Tumaround Surcharge.
Tum Around Time (rAT) h calender days.
SAMPLE ID • _ character per box.)
•
r
15E
I
■ ■' 3009■"■�■T :■�`■r��r■I{
1
00z8■�■ra+Fb■ r� ■1.tv■ j ypa■ ■
n: [■
:■1
■ W 0 101■ ■ ■T ■R■ME t■
ERE1
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain-of-Castodyis a LEGAL DOCUMENT. All relevant fields must be completed accurately
Page: 1 of'" 1
Client Information (Check quotelcontract): To Be Completed by Pace Analytical Client: Section C
Requested Due Date:
Quote Reference:
'TAT:
Project Manager.
Lip
• Tum around times less than 14 days subject
Project 0: '
laboratory and contractual oblgaWna and may
Profile lk
in a Rush Tumaround Surcharge.
Tum Around Time (rAT) h calender days.
SAMPLE CONDITION: SAMPLE NOTES:
Temp in C NA
Received on Ice
Sealed Cooler �
Sample Intact PRINT Name of SAMPLE
Additional Comments: (SIGNATURE of SAMPLE(
Total Metals: As, Ba, Cd, Ca, Cr, Cu, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Zn, Hg
TCLP Leach Metals: See Attached
Diedrich
Analysis
;EMARKKS / Lab ID
qA li7raya�
Y

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
® 205 East Meadow Road - Suite A 2225 Riverside Dr.
`ceAnalytical
Eden, NC 27288 Asheville, NC 28804
wwwpacelabs.crom
[phone] [phone]
ANALYTICAL RESULTS
Project: PONDED ASH REUSE 5/1
Pace Project No.: 92117624
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: ASH FROM ASH POND Lab ID: 92117624002 Collected: 05/01/12 12:36 Received: 05/02/12 09:bU Matrix: soca
Results reported on a "dry -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
8270 MSSV TCLP Sep Funnel
2,4,5 -Trichlorophenol
2,4,6 -Trichlorophenol
Surrogates
Nitrobenzene -d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol -d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4 -Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene -d8 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Date: 05/16/2012 03:14 PM
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 05/07/12 14:00
ND ug/L
50.0
1
05/08/12 09:00
05/08/12 22:00 95-95-4
ND ug/L
50.0
1
05/08/12 09:00
05/08/12 22:00 88-06-2
73 %
12-102
1
05108/12 09:00
05/08/12 22:00 4165-60-0
81 %
13-107
1
05108/12 09:00
05/08/12 22:00 321-60-8
96 %
21-132
1
05108/12 09:00
05/08/12 22:00 1718-51-0
23 %
10-110
1
05108/12 09:00
05/08/12 22:00 13127-88-3
16 %
10-110
1
05108/12 09:00
05/08/12 22:00 367-12-4
26 %
27-108
1
05108112 09:00
05/08/12 22:00 118-79-6 SO
Analytical Method: EPA 8260
ND ug/L
190
38
05/08/1220:59 71-43-2 1g
ND ug/L
380
38
05/08/12 20:59 78-93-3
ND ug/L
190
38
05/08/12 20:59 56-23-5
ND ug/L
190
38
05/08/12 20:59 108-90-7
ND ug/L
190
38
05/08/12 20:59 67-66-3
ND ug/L
190
38
05/08/12 20:59 106-46-7
ND ug/L
190
38
05/08/12 20:59 107-06-2
ND ug/L
190
38
05108/1220:59 75-35-4
ND ug/L
190
38
05/08/12 20:59 127-18-4
ND ug/L
190
38
05/08/12 20:59 79-01-6
ND ug/L
190
38
05/08/12 20:59 75-01-4
123 %
70-130
38
05/08/12 20:59 17060-07-0
100 %
67-135
38
05108/12 20:59 2037-26-5
97 %
70-130
38
05/08/12 20:59 460-00-4
103 %
70-130
38
05/08/12 20:59 1868-53-7
REPORT OF LABORATORY ANALYSIS Page 6 of 21
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

ANALYTICAL RESULTS 01,,c�
Project: PONDED ASH REUSE 511
Pace Project No.: 92117624
Sample: ASH FROM ASH POND Lab ID: 92117624002 Collected: 05/01/12 12:36 Received: 05/02/12 09:50 Matrix: Solid
Results reported on a "dry -weight' basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8081 GCS Pesticides, TCLP SPE
gamma -BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
8151 Chlorinate Herbicide TCLP
2,4-D
2,4,5 -TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury, TCLP
Mercury
8270 MSSV TCLP Sep Funnel
1,4 -Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachloro benzene
Hexachloroethane
2-M ethylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
Date: 05/16/2012 03:14 PM
Analytical Method: EPA 8081 Preparation Method: EPA 3535
Leachate Method/Date: EPA 1311; 05/07/12 14:00
ND ug/L
0.50 1
05/08/12 14:30 05/15/12 23:35
58-89-9
®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services; Inc.
aceAnalytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com
Eden, NC 27288.
Asheville, NC 28804
Huntersville, NC 28078
ND ug/L
[phone]
[phone]
[phone]
ANALYTICAL RESULTS 01,,c�
Project: PONDED ASH REUSE 511
Pace Project No.: 92117624
Sample: ASH FROM ASH POND Lab ID: 92117624002 Collected: 05/01/12 12:36 Received: 05/02/12 09:50 Matrix: Solid
Results reported on a "dry -weight' basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8081 GCS Pesticides, TCLP SPE
gamma -BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
8151 Chlorinate Herbicide TCLP
2,4-D
2,4,5 -TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury, TCLP
Mercury
8270 MSSV TCLP Sep Funnel
1,4 -Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachloro benzene
Hexachloroethane
2-M ethylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
Date: 05/16/2012 03:14 PM
Analytical Method: EPA 8081 Preparation Method: EPA 3535
Leachate Method/Date: EPA 1311; 05/07/12 14:00
ND ug/L
0.50 1
05/08/12 14:30 05/15/12 23:35
58-89-9
ND ug/L
3.0 1
05/08/12 14:30 05/15/12 23:35
57-74-9
ND ug/L
0.50 1
05/08/12 14:30 05/15/12 23:35
72-20-8
ND ug/L
0.50 1
05/08/12 14:30 05/15/12 23:35
76-44-8
ND ug/L
0.50 1
05/08/12 14:30 05/15/12 23:35
1024-57-3
ND ug/L
1000 1
05/08112 14:30 05/15/12 23:35
72-43-5
ND ug/L
3.0 1
05/08112 14:30 05/15/12 23:35
8001-35-2
107 %
10-138 1
05/08112 14:30 05/15/12 23:35
2051-24-3
80 %
10-110 1
05/08/12 14:30 05/15/12 23:35
877-09-8
Analytical Method: EPA 8151
ND mg/L
0.010 1
05/08112 08:00 05/09/12 20:10
94-75-7 M1
ND mg/L
0.010 1
05/08/12 08:00 05/09/12 20:10
93-72-1 M1
111 %
70-130 1
05/08/12 08:00 05/09/12 20:10
19719-28-9
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311; 05/11/12 16:15
0.090 mg/L
0.025 1
05/12112 13:05 05/13/12 17:38
7440-38-2
2.8 mg/L
0.50 1
05/12/12 13:05 05/13/12 17:38
7440-39-3
ND mg/L
0.0050 1 .
05/12/12 13:05 05/13/12 17:38
7440-43-9
ND mg/L
0.025 1
05/12112 13:05 05/13/12 17:38
7440-47-3
ND mg/L
0.025 1
05/12/12 13:05 05/13/12 17:38
7439-92-1
0.13 mg/L
0.10 1
05/12/12 13:05 05/13/12 17:38
7782-49-2
NO mg/L
0.025 1
05/12112 13:05 05/13/12 17:38
7440-22-4
Analytical Method: EPA7470 Preparation Method:-EPA7470
Leachate Method/Date: EPA 1311; 05/11/12 16:15
ND mg/L
0.00020 1
05/14/12 12:15 05/15/12 11:26
7439-97-6
Analytical Method: EPA8270 Preparation Method: EPA3510
Leachate Method/Date: EPA 1311;
05/07/12 14:00
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
106-46-7
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
121-14-2
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
87-68-3
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
118-74-1
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
67-72-1
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
95-48-7
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
98-95-3
ND ug/L
100 1
05/08/12 09:00 05/08/12 22:00
87-86-5
ND ug/L
50.0 1
05/08/12 09:00 05/08/12 22:00
110-86-1
REPORT OF LABORATORY
ANALYSIS
Page 5 of 21
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