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HomeMy WebLinkAboutNC0087947_Fact Sheet_20180316Fact Sheet NPDES Permit No. NCO087947 Permit Writer/Email Contact Bing Bai, bing.bai@ncdenr.gov: Date: March 12, 2018 Division/Branch: NC Division of Water Resources/NPDES Complex Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ❑x Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2°d species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: Columbus County/Columbus County POTW Applicant Address: 111 Washington Street, Whiteville, NC 28472 Facility Address: 1321 Old Road 87, Acme, North Carolina 28472 Permitted Flow: 0.05 MGD Facility Type/Waste: Industrial (100%) with modified pretreatment program Facility Class: Class 2 Pre Pre -Equalization Tank; Carbon Addition System, SBR, Post - Equalization Tank; Sand Filters; Activated Sludge Digester Pretreatment Program (Y/N) Yes County: Columbus Region Wilmington Briefly describe the proposed permitting action and facility background: Columbus County has applied for NPDES permit renewal, and submitted a renewal application dated June 8, 2016. This facility receives wastewater solely from a CIU — Hexion Inc. which produces Hexamethylenetramine (Hexamine). This CIU is subject to Pretreatment Standards for Existing Sources (PSES) and meeting all Page 1 of 10 the required testing criteria list in PSES. This CIU is also subject to 40 CFR 414 Subpart H — Specialty Organic Chemicals, However, these effluent guidelines specify BOD and TSS limits which are significantly less stringent than those water -quality based limits which were included in the previous permit and carried over into this proposed draft permit. 2. Receiving Waterbody Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001- Livingston Creek Stream Segment: 18-64 Stream Classification: C; Swamp Drainage Area (mi2): 94.7 Summer 7Q10 (cfs) 0.6 Winter 7Q 10 (cfs): 7 30Q2 (cfs): - Average Flow (cfs): 85 IWC (% effluent): 12 303(d) listed/parameter: No Subject to TMDL/parameter: No Subbasin/HUC: Cape Fear•, 03030005 USGS Topo Quad: J26SW 3. Effluent Data Summary Effluent data is summarized below for the period April 2012 through April 2017. Table 3. Effluent Data Summary Parameter Units Average Max Min Permit Limit Flow MGD 0.014 0.029 0.001 0.05 BOD summer mg/l 2.32 > 41.82 < 2 MA 5.0 WA 7.5 BOD winter mg/l 2.17 > 42.91 < 2 WA 10.0 WA 15.0 Page 2 of 10 NH3N summer mg/l 0.53 6.09 < 0.1 WA 2.0 WA 6.0 NH3N winter mg/l 0.8 22.3 < 0.1 MA 4.0 WA 12.0 TSS mg/l 2.46 44.7 < 1 MA 30.0 WA 45.0 pH SU 8.19 8.91 6.1 6-9 Temperature °C 20.3 32 4 Monitor only DO mg/l 9.16 16.34 6.04 > 6.0 Conductivity umhos/cm 1,085.4 1,910 8.07 Monitor only TN mg/l 15.78 41 < 0.5 Monitor only TP mg/l 4.54 27.1 0 Monitor only Fecal Coliform #/100 ml 1.95 4,300 < 1 Not required MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/1 of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The receiving water is classified as C -Swamp water and the current permit requires instream monitoring for dissolved oxygen, temperature and conductivity. Review of instream data from January 2012 to April 2017 indicates that there were no significant differences between upstream and downstream (ANOVA, p > 0.05). The average over the period analyzed indicated that upstream DO was 5.56 mg/L and downstream DO was 5.71 mg/L. During the critical summer months (April -October), minimum values of 2.04 mg/L upstream and 1.84 mg/L downstream occurred with averages between 3.94 mg/L and 3.88 mg/L respectively. This draft permit maintains the same instream monitoring requirements. Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/7V): NO Name of Monitoring Coalition: NA Page 3 of 10 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): The facility reported 13 BOD limit violations from 2013 to 2016, and 3 fecal coliform limit violations from 2013 to 2014. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 17 of 19 quarterly chronic toxicity tests as well as all 4 second species chronic toxicity tests. Summarize the results from the most recent compliance inspection: The last facility inspection conducted on August 12, 2016 reported that the facility was well maintained and operated in compliant. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with 15A NCAC 2B. 0204(b): NA Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/l for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: Limitations for BOD are based on 2000 Cape Fear River Basin plan from Lock and Dam #1 to the Lower Cape Fear River Estuary. No changes are proposed from the previous permit limits. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/1(summer) and 1.8 mg/l (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/l (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/l are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: Limitations for NH3-N are based on 2000 Cape Fear River Basin plan from Lock and Dam #1 to the Lower Cape Fear River Estuary. This facility does receive domestic wastewater so no TRC required. There are no proposed changes. Page 4 of 10 Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of/z detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between August 2012 and August 2016. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: NA • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: NA • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Total Copper, Total Lead. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: NA o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: NA If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Page 5 of 10 Describe proposed toxicity test requirement: This is a Minor POTW, and a chronic WET limit at 12% effluent will continue on a quarterly frequency. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/1) will receive an MMP requirement. Industrials are evaluated on a case-by-case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/l Table 4. Mercury Effluent Data Summary Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. This facility is < 1 MGD and no quantifiable levels of mercury (> 1 ng/1) was reported, no mercury minimization plan (MMP) is needed. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special actions (HQW or OR W) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H. 0107(c) (2) (B), 40CFR 122.4 7, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA Page 6 of 10 2012 2013 2015 # of Samples 1 1 1 Annual Average Conc. n L 0.9 0.5 0.5 Maximum Conc., n /L 0.87 0.5 0.5 TBEL, n L 47 WQBEL, n L 104.9 Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. This facility is < 1 MGD and no quantifiable levels of mercury (> 1 ng/1) was reported, no mercury minimization plan (MMP) is needed. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special actions (HQW or OR W) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H. 0107(c) (2) (B), 40CFR 122.4 7, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA Page 6 of 10 7. Technology -Based Effluent Limitations (TBELs) Municipals Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg1l BODS/TSS for Monthly Average, and 45 mg/l for BODS/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BODS/TSS included in the permit? YES If NO, provide a justification (e.g., waste stabilization pond). NA Industrials Describe what this facility produces: Hexamethylenetramine (Hexamine). List the federal effluent limitations guideline (ELG) for this facility: 40 CFR 414.Subpart H (Specialty Organic Chemicals. If the EL is based on production or flow, document how the average production/flow value was calculated: This ELG is based on process wastewater pollutant concentrations listed in the following table. Table 5. TBEL Effluent Limits per 40 CFR 414 Subpart H (Specialty Organic Chemicals) Effluent characteristics BPT limitations (mg/L) Daily Maximum Monthly Average BODS 120 45 TSS 183 57 pH 6 — 9 s.u. Both BODS and TSS specified in TBEL are less stringent than WQBEL, so limits are set based on WQBEL (See comparison table below). Table 6. Comparison of TBEL and WQBEL Pollutant TBEL (mg/L) WQBEL (mg/L) Daily Maximum Monthly Average Daily Maximum Monthly Average BODS 120 45 - 5 TSS 183 57 - 30 pH 6 — 9 S.U. 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit Page 7 of 10 must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 9. Antibacksliding Review Sections 402(0)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 213.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(0) of the Clean Water Act, and therefore anti - backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section 4 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. Page 8 of 10 12. Summary of Proposed Permitting Actions: Table 7. Current Permit Conditions and Proposed Changes Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 0.05 MGD No change 15A NCAC 2B.0505 BODS Summer: No change WQBEL. Based on protection of DO MA 5 mg/l standard. 15A NCAC 2B.0200 WA 7.5 mg/l Winter: MA 10 mg/l WA 15 mg/l NH3-N Summer: No change WQBEL. Based on protection of MA 2 mg/l State WQ criteria. 15A NCAC WA 6 mg/l 2B.0200 Winter: MA 4 mg/1 WA 12 mg/l TSS MA 30 mg/l No change TBEL. Secondary treatment WA 45 mg/l standards/40 CFR 133 / 15A NCAC 2B .0406 DO > 6 mg/l No change WQBEL. State WQ standard, 15A NCAC 2B.0200 pH 6 — 9 SU No change WQBEL. State WQ standard, 15A NCAC 2B.0200 Total Nitrogen Monitor Only No change WQBEL. State WQ standard, 15A NCAC 2B.0200 Total Phosphorus Monitor Only No change WQBEL. State WQ standard, 15A NCAC 2B.0200 Total copper Monitor quarterly Remove copper Reasonable Potential Analysis effluent monitoring based on no RP Total lead Monitor quarterly Remove lead effluent Reasonable Potential Analysis monitoring based on no RP Conductivity Monitor weekly No change WQBEL. State WQ standard, 15A NCAC 2B.0200 Toxicity Test Chronic limit, 12% No change WQBEL. No toxics in toxic effluent amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 2' Species No requirement Add requirement in 40 CFR 122 Toxicity Test permit Page 9 of 10 Fecal Coliform No requirement Add requirement for NPDES Permit Renewal permit renewal Requirement as in 2A form Total Hardness No requirement Add effluent and Required to assess dissolved metal upstream monitoring limitations based on the new 2016 dissolved metal standards Effluent Pollutant Three times per permit No change 40 CFR 122 Scan cycle Electronic No requirement Add Electronic In accordance with EPA Electronic Reporting Reporting Special Reporting Rule 2015. Condition MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max 13. Public Notice Schedule: Permit to Public Notice: 06/26/2017 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes If Yes, list changes and their basis below: 1) The facility passed all four 2nd Species Toxicity Tests performed in August, September, October and November 2017 as required by the permit renewal application. In addition, statement for multiple species toxicity tests requirement was added to the cover letter per required by Part E. Toxicity Testing Data in EPA Form 2A. 2) Statement in cover letter for fecal coliform was added per the permit renewal application requirement. 15. Fact Sheet Attachments (if applicable): • RPA Spreadsheet Summary • Dissolved Metals Implementation/Freshwater or Saltwater • Instream DO Summary • NH3-N and TRC WLA • Mercury TMDL Evaluation Page 10 of 10 Permit No. NCO087947 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Q ality Standards/A uatic Life Protection Parameter Acute FW, gg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 213.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 gg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, gg/I Cadmium, Acute WER*{1.136672-[ln hardness] (0.041838)} e^{0.9151 [ln hardness] -3.1485} Cadmium, Acute Trout waters WER*{1.136672-[ln hardness] (0.041838)} e^{0.9151[In hardness] -3.6236} Cadmium, Chronic WER*{1.101672-[ln hardness] (0.041838)} e^{0.7998[ln hardness] -4.4451} Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 e^{0.9422[ln hardness] -1.700} Copper, Chronic WER*0.960 e^{0.8545[ln hardness] -1.702} Lead, Acute WER*{1.46203-[ln hardness](0.145712)) • e^{1.273[ln hardness] -1.460) Lead, Chronic WER*{1.46203-[ln hardness](0.145712)) • e^{1.273[ln hardness] -4.705) Nickel, Acute WER*0.998 e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NCO087947 Silver, Acute WER*0.85 • e^{l.72[ln hardness] -6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case-by-case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WOBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q 10 (the spreadsheet automatically calculates the 1 Q 10 using the formula I Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site-specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site-specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NCO087947 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site-specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal I + { [Kpo] [SS(i+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/l], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site-specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q 10 + Qw) (Cwgs) — (s7Q 10) (Cb) Qw Where: Ca = allowable effluent concentration (gg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (gg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (gg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q 10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on-going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: IQ 10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0087947 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) 331.7 Average from three PPAs [Total as, CaCO3 or (Ca+Mg)] December 2012 — July 2015 Average Upstream Hardness (mg/L) 25 Default with no data [Total as, CaCO3 or (Ca+Mg)] 7Q10 summer (cfs) 0.6 NPDES files, BIMS 1 Q 10 (cfs) 0.51 Calculated from 7Q 10 summer Permitted Flow (MGD) 0.05 NPDES files, BIMS Date: Permit Writer: Page 4 of 4 All data Date Upstream Downstream Units Date Upstream )ownstrean Units 1/5/2012 7 mg/I 9/12/2016 3.88 3.83 mg/I 2/2/2012 7.5 mg/I 9/19/2016 3.81 3.9 mg/I 3/1/2012 7.8 mg/I 9/26/2016 5.71 5.51 mg/I 4/12/2012 4.1 mg/I 10/3/2016 3.77 4.31 mg/I 5/18/2012 3.3 mg/I 10/10/2016 3.53 4.01 mg/I 6/14/2012 3 mg/I 10/17/2016 5.01 4.92 mg/I 7/12/2012 2.6 mg/I 10/24/2016 2.09 1.84 mg/I 8/9/2012 2.6 mg/I 10/31/2016 3.78 3.59 mg/I 9/6/2012 3.4 mg/I 11/7/2016 4.09 4.16 mg/I 10/9/2012 4.7 mg/I 11/14/2016 7.07 8.14 mg/I 11/1/2012 4.7 mg/I 11/21/2016 9.10 8.06 mg/I 12/13/2012 8 mg/I 11/28/2016 9.11 8.09 mg/I 1/28/2013 11.5 mg/I 12/6/2016 7.06 7.07 mg/I 2/12/2013 11.2 mg/I 12/12/2016 8.77 9.9 mg/I 3/27/2013 9.9 mg/I 12/19/2016 9.16 9.43 mg/I 4/25/2013 6.6 mg/I 12/26/2016 8.07 8.51 mg/I 5/30/2013 5.4 mg/I 1/2/2017 8.28 10.69 mg/I 6/11/2013 3.9 mg/I 1/9/2017 12.04 12.51 mg/I 7/17/2013 3.5 mg/I 1/16/2017 8.91 9.16 mg/I 8/15/2013 3.5 mg/I 1/23/2017 6.80 6.47 mg/I 9/12/2013 4.3 mg/I 1/30/2017 9.27 9.41 mg/I 10/16/2013 3.4 mg/I 2/6/2017 8.22 8.39 mg/I 11/4/2013 6.5 mg/I 2/13/2017 8.15 8.04 mg/I 12/18/2013 9.5 mg/I 2/20/2017 8.25 8.14 mg/I 2/19/2014 10.6 mg/I 2/27/2017 4.93 5.26 mg/I 5/2/2016 5.91 5.45 mg/I 3/6/2017 6.72 6.62 mg/I 5/9/2016 4.43 4.19 mg/I 3/13/2017 8.34 8.03 mg/I 5/16/2016 4.86 4.48 mg/I 3/20/2017 8.72 8.48 mg/I 5/23/2016 4.61 4.75 mg/I 3/27/2017 6.09 6.03 mg/I 5/30/2016 3.87 3.26 mg/I 4/3/2017 4.63 4.45 mg/I 6/6/2016 3.34 3.03 mg/I 4/10/2017 6.46 6.97 mg/I 6/13/2016 4.08 3.67 mg/I 4/17/2017 4.24 4.17 mg/I 6/20/2016 3.85 3.35 mg/I 4/24/2017 4.59 4.33 mg/I 6/27/2016 2.41 2.22 mg/I 7/4/2016 2.04 2.11 mg/I 7/11/2016 2.32 2.12 mg/I Min 2.04 1.84 7/18/2016 3.64 3.62 mg/I Mean 5.56 5.71 7/25/2016 3.56 3.66 mg/I 8/1/2016 4.00 5.08 mg/I 8/8/2016 3.45 3.5 mg/I 8/15/2016 2.78 3.07 mg/I 8/22/2016 3.47 3.18 mg/I 8/29/2016 3.06 2.95 mg/I 9/5/2016 4.84 4.7 mg/I Anova: Single Factor SUMMARY Groups Count Sum 4verageriance Column 1 52 289.17 5.561 6 Column 2 77 439.31 5.705 7 ANOVA irce of Variate SS df MS F P -value F crit Between Gro 0.64687 1 0.647 0 0.75253123 3.915727 Within Grour 822.77817 127 6.479 Total 823.42504 128 Critical Summer Date Upstream Downstream Units Date Upstream )ownstrean 4/12/2012 4.1 mg/I 4/17/2017 4.24 4.17 5/18/2012 3.3 mg/I 4/24/2017 4.59 4.33 6/14/2012 3 mg/I 7/12/2012 2.6 mg/I Min 2.04 1.84 8/9/2012 2.6 mg/I Mean 3.94 3.88 9/6/2012 3.4 mg/I 10/9/2012 4.7 mg/I 4/25/2013 6.6 mg/I 5/30/2013 5.4 mg/I 6/11/2013 3.9 mg/I 7/17/2013 3.5 mg/I 8/15/2013 3.5 mg/I 9/12/2013 4.3 mg/I 10/16/2013 3.4 mg/I 5/2/2016 5.91 5.45 mg/I 5/9/2016 4.43 4.19 mg/I 5/16/2016 4.86 4.48 mg/I 5/23/2016 4.61 4.75 mg/I 5/30/2016 3.87 3.26 mg/I 6/6/2016 3.34 3.03 mg/I 6/13/2016 4.08 3.67 mg/I 6/20/2016 3.85 3.35 mg/I 6/27/2016 2.41 2.22 mg/I 7/4/2016 2.04 2.11 mg/I 7/11/2016 2.32 2.12 mg/I 7/18/2016 3.64 3.62 mg/I 7/25/2016 3.56 3.66 mg/I 8/1/2016 4 5.08 mg/I 8/8/2016 3.45 3.5 mg/I 8/15/2016 2.78 3.07 mg/I 8/22/2016 3.47 3.18 mg/I 8/29/2016 3.06 2.95 mg/I 9/5/2016 4.84 4.7 mg/I 9/12/2016 3.88 3.83 mg/I 9/19/2016 3.81 3.9 mg/I 9/26/2016 5.71 5.51 mg/I 10/3/2016 3.77 4.31 mg/I 10/10/2016 3.53 4.01 mg/I 10/17/2016 5.01 4.92 mg/I 10/24/2016 2.09 1.84 mg/I 10/31/2016 3.78 3.59 mg/I 4/3/2017 4.63 4.45 mg/I 4/10/2017 6.46 6.97 mg/I Units mg/I mg/I Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Proiect Information Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class Aquactic Life ❑CHECK IF HQW OR ORW WQS 150 FW Columbus County POTW 2 NCO087947 001 0.050 Livingston Creek 03030005 C, Sw ❑Apply WS Hardness WQC 7Q10s (cfs) 7Q10w (cfs) 30Q2 (cfs) QA (cfs) 1Q10s (cfs) 0.60 NC 7.00 FW 65 ug/L 85.00 Aquatic Life 0.51 1.1443 Effluent Hardness -------------------------------- Upstream Hardness --------------------------------- Combined Hardness Chronic .--------- -_ Combined Hardness Acute 331.67 mg/L (Avg) 25 mg/L (Avg) _ 60.08 m /L — — — — — — — — — — I 65.45 m 9 /L ------------- ug/L Data Source(s) ❑CHECK TO APPLY MODEL NC 230 Par01 Par02 Par03 Par04 Par05 Par06E Par07 ParOB Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 1.1443 FW 7.5022 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L_ Chromium III Aquatic Life NC 241.4144 FW 1990.7933 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 16.6704 FW 25.9337 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 7.8256 FW 220.7278 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 78.1730 FW 756.7275 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 1.5518 ug/L Zinc Aquatic Life NC 266.4001 FW 284.1325 ug/L Bis(2-etylhexyl)phthalate Human Health C 0.37 HH pg/L NCO087947 RPA, input 6/22/2017 NCO087947 RPA, input 6/22/2017 Columbus County POTW - NC0087947 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM Qw (MGD) = 0.05 1Q10S (cfs) = 0.51 7Q10S (cfs) = 0.60 7Q10W (cfs) = 7.00 30Q2 (cfs) = NO 30Q2 DATA Avg. Stream Flow, QA (cfs) = 85.00 Receiving Stream: Livingston Creek HUC 03030005 DATA POINTS = 58 WWTP/WTP Class: 2 IWC% @ 1Q10S = 13.19148936 1WC% @ 7Q10S = 11.43911439 IWC% @ 7Q10W = 1.095019428 1WC% @ 30Q2 = N/A IW%C @ QA = 0.091093415 Stream Class: C, Sw Outfall 001 Qw = 0.05 MGD COMBINED HARDNESS (m¢/L) Acute = 65.45 mg/L Chronic = 60.08 mg/L PARAMETER TYPE NC STANDARDS OR EPA CRITERIA y REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION (1)Applied C7 (L � z Chronic Acute n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 2,577.4 Arsenic C 150 FW(7QlOs) 340 ug/L 3 1 15.0 Chronic (FW): 1,311.3 No RP, Predicted Max < 50% of Allowable Cw - No Default C.V. No value Allowable Cw Monitoring required Arsenic C 10 HH/WS(Qavg) ug/L Note: n 5 9 _> Chronic (HH): 10,977.7 Limited data set No value > Allowable Cw Acute: 492.74 Beryllium NC 6.5 FW(7QIOs) 65 ug/L 3 0 NO DETECTS _ _ Note: n:5 9 Chronic: 56.82 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set Max MDL = 10 Monitoring required Acute: 56.871 Cadmium NC 1.1443 FW(7QIOs) 7.5022 ug/L 3 0 NO DETECTS Note: n < 9 .............................................. Chronic: 10.003 No RP, Predicted Max < 50of Allowable Cw - No Limited data set Max MDL = 10 Monitoring required Acute: NO WQS Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 1 141.0 1 Note: n 5 9 Default C.V. Chronic: IWC? Limited data set Acute: 121.3 Chromium VI NC 11 FW(7QIOs) 16 µg/L 0 0 N/A _ -- Chronic: ----96.2-- ------------------------- Chromium, Total NC gg/L 3 0 NO DETECTS a. No Monitoring required if all Total Chromium Note: n < 9 samples are < the Chromium VI Allowable Cw Limited data set Max MDL = 10 Acute: 196.59 Copper NC 16.6704 FW(7QlOs) 25.9337 ug/L 20 11 21.28 Chronic: 145.73 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 166.8 Cyanide NC 5 FW(7QlOs) 22 10 ug/L 3 0 NO DETECTS Note: n:5 9 Chronic: 43.7 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set Max MDL = 10 Monitoring required Acute: 1,673.259 Lead NC 7.8256 FW(7QlOs) 220.7278 ug/L 20 0 NO DETECTS ---------------------------------------------- ___________________Chronic: 68.411 Chronic: No RP, Predicted Max < 50% of Allowable Cw - No Max MDL = 15 Monitoring required NCO087947 RPA, rpa Page 1 of 2 6/22/2017 Columbus County POTW - Outfall 001 NCO087947 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 0.05 MGD NCO087947 RPA, rpa Page 2 of 2 6/22/2017 Acute: NO WQS Molybdenum NC 2000 HH(7Q10s) u,/L 0 0 N/A Chronic: 17,483.9 No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Acute (FW): 5,736.5 Nickel NC 78.1730 FW(7Q10s) 756.7275 gg/L 3 1 15.0 Chronic (FW): 683.4 No RP, Predicted Max < 50% of Allowable Cw - No Note: n:5 9 Default C.V. No value Allowable Cw Monitoring required Nickel NC 25.0000 WS(7Q10s) gg/L Limited data set _> Chronic (WS): 218.5 No value > Allowable Cw Acute: 424.5 Selenium NC 5 FW(7Q10s) 56 ug/L 3 1 15.0 Note: n < 9 Default C.V. ---------------------------------------------- ____________________Note: Chronic: 43.7 No RP, Predicted Max < 50% of Allowable Cw - No Limited data sel No value > Allowable Cw Monitoring required Acute: 11.763 Silver NC 0.06 FW(7Q10s) 1.5518 ug/L 3 0 NO DETECTS Note: n:5 9 Chronic: 0.525 All samples are less than detect. Permittee should Limited data set Max MDL = 10 lower reporting level to PQL=1.0 Acute: 2,153.9 Zinc NC 266.4001 FW(7Q10s) 284.1325 ug/L 3 0 NO DETECTS 1 Note: n < 9 .............................................. Chronic: 2,328.9 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set Max MDL = 10 Monitoring required Acute: NO WQS Bis(2-etylhexyl)phthalate c 0.37 HH(Qavg) gg/L 3 1 33.60000 _ _ Note: n:5 9 Default C.V. Chronic: 406.17645 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set No value > Allowable Cw IMonitoring required NCO087947 RPA, rpa Page 2 of 2 6/22/2017 H1 REASONABLE POTENTIAL ANALYSIS H2 Effluent Hardness Use"PASTE SPECIAL Date Data BDL=1/2DL Results 1 1210/12 125 125 Std Dev. 2 11/12/2013 520 520 Mean 3 7/28/2015 350 350 C.V. (default) 4 25 25 Std Dev. 331.6667 n 5 0.6000 3 10th Per value 6 4 n Average Value 7 10th Per value 331.67 mg/L Max. Value 8 520.00 mg/L 7 Max. Value 9 8 7/28/2015 < 10 5 10 1 4 10 11 n 11 5 12 12 25.00 mg/L 13 14 14 7 15 15 16 8 16 Max. Pred Cw 18 17 19 18 20 19 11 22 20 23 21 24 13 22 26 23 27 24 28 25 16 30 26 31 17 27 32 28 34 29 19 35 30 20 31 21 32 33 34 23 35 24 REASONABLE POTENTIAL ANALYSIS FE H2 Use"PASTE SPECIAL Use"PASTE SPECIAL "COPY" Values"Maximum Upstream Hardness .Maximum data points = 58 . Maximum data Date Data BDL=1/2DL Results 198.1372 1 25 25 Std Dev. 331.6667 2 Mean 0.6000 3 C.V. 3 4 n 170.00 mg/L 5 10th Per value 331.67 mg/L 6 Average Value 520.00 mg/L 7 Max. Value 0.0000 8 7/28/2015 < 10 5 9 1 4 10 n 11 5 12 25.00 mg/L 13 14 25.00 mg/L 7 15 Max. Value 16 8 17 Max. Pred Cw 18 19 10 20 21 11 22 23 24 13 25 26 14 27 28 29 16 30 31 17 32 33 34 19 35 FE Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 4.0333 0.6000 3 3.00 5.0 ug/L 15.0 ug/L NCO087947 RPA, data 6/22/2017 Pdr01 & Pdr02 Use"PASTE SPECIAL Values" then "COPY" Arsenic . Maximum data points = 58 Date Data BDL=1/2DL Results N/A 1 12/11/2012 < 10 5 Std Dev. 25.0000 2 11/12/2013 2.1 2.1 Mean 0.0000 3 7/28/2015 < 10 5 C.V. (default) 1 4 n 25.00 mg/L 5 25.00 mg/L 6 Mult Factor = 25.00 mg/L 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 4.0333 0.6000 3 3.00 5.0 ug/L 15.0 ug/L NCO087947 RPA, data 6/22/2017 Par03 REASONABLE POTENTIAL ANALYSIS Use"PAE SPECIAL Par04 ST Use "PASTE SPECIAL Par07 Values then COPY Values" then "COPY" Beryllium I Cadmium Total Phenolic Compounds .Maximum data . Maximum data NCO087947 RPA, data 2- 6/22/2017 points = 58 points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 12/11/2012 < 10 5 Std Dev. 2.5981 1 12/11/2012 < 10 5 Std Dev. 2.5981 1 12/13/2012 47 47 Std Dev. 2 11/12/2013 < 1 0.5 Mean 3.5000 2 11/12/2013 < 1 0.5 Mean 3.5000 2 11/12/2013 < 5 2.5 Mean 3 7/28/2015 < 10 5 C.V. (default) 0.6000 3 7/28/2015 < 10 5 C.V. (default) 0.6000 3 7/28/2015 < 8 4 C.V. (default) 4 n 3 4 n 3 4 n 5 5 5 6 Mult Factor = 3.00 6 Mult Factor = 3.00 6 Mult Factor = 7 Max. Value 5.00 ug/L 7 Max. Value 5.000 ug/L 7 Max. Value 8 Max. Pred Cw O DETECTS ug/L 8 Max. Pred Cw O DETECTS ug/L 8 Max. Pred Cw 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 17 17 17 18 18 18 19 19 19 20 20 20 21 21 21 22 22 22 23 23 23 24 24 24 25 25 25 26 26 26 27 27 27 28 28 28 29 29 29 30 30 30 31 31 31 32 32 32 33 33 33 34 34 34 35 35 35 NCO087947 RPA, data 2- 6/22/2017 REASONABLE POTENTIAL ANALYSIS Use"PASTE SPECIAL Par10 Use "PASTE SPECIAL Pall Values"then"COPY" Chromium, Total Values" then "COPY" Copper . Maximum data . Maximum data points = 58 points = 58 17.8333 0.6000 3 3.00 47.0 ug/L 141.0 ug/L Use "PASTE SPECIALPar12 Values" then "COPY" . Maximum data points = 58 r- 6.4800 0.5384 20 1.33 16.00 ug/L 21.28 ug/L Cyanide Date Data BDL=1/2DL Results BDL=1/2DL Results 1 12/11/2012 < 10 5 Std Dev. 2.3094 2 11/12/2013 < 2 1 Mean 3.6667 3 7/28/2015 < 10 5 C.V. (default) 0.6000 4 16 n 3 5 < 10 5 n 6 6/25/2013 Mult Factor = 3.00 7 6 Max. Value 5.0 Ng/L 8 4.7 Mult Factor = Max. Pred Cw O DETECTS Ng/L 9 8.9 8.9 Max. Value 8 10 9.6 9.6 Max. Pred Cw 11 2/24/2014 3.6 12 10 5/12/2014 17 13 9.6 11 8/3/2014 14 6.3 6.3 12 15 5.9 5.9 16 2/9/2015 < 10 17 14 5/18/2015 < 18 2.5 15 7/28/2015 19 10 5 16 20 < 10 5 21 11/16/2015 < 7 22 18 2/15/2016 < 23 2.5 19 5/16/2016 24 10 10 20 25 < 7 3.5 26 35 27 22 28 23 29 24 30 31 32 26 33 27 34 28 35 Use "PASTE SPECIALPar12 Values" then "COPY" . Maximum data points = 58 r- 6.4800 0.5384 20 1.33 16.00 ug/L 21.28 ug/L Cyanide Date Data BDL=1/2DL Results 1 8/27/2012 2 12 12 Std Dev. 2 11/20/2012 < 5 5 6 6 Mean 3 11/29/2012 16 16 C.V. 4 2/11/2013 < 10 5 n 5 6/25/2013 < 10 5 6 8/16/2013 4.7 4.7 Mult Factor = 7 11/4/2013 12 8.9 8.9 Max. Value 8 11/12/2013 9.6 9.6 Max. Pred Cw 9 2/24/2014 3.6 3.6 10 5/12/2014 17 9.6 9.6 11 8/3/2014 6.3 6.3 12 11/10/2014 5.9 5.9 13 2/9/2015 < 10 5 14 5/18/2015 < 5 2.5 15 7/28/2015 < 10 5 16 8/17/2015 < 10 5 17 11/16/2015 < 7 3.5 18 2/15/2016 < 5 2.5 19 5/16/2016 32 10 10 20 8/15/2016 < 7 3.5 21 35 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Use "PASTE SPECIALPar12 Values" then "COPY" . Maximum data points = 58 r- 6.4800 0.5384 20 1.33 16.00 ug/L 21.28 ug/L Cyanide NCO087947 RPA, data 3- 6/22/2017 Date Data BDL=1/2DL 1 12/10/2012 < 5 5 2 11/12/2013 < 5 5 3 7/28/2015 < 5 5 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 NCO087947 RPA, data 3- 6/22/2017 REASONABLE POTENTIAL ANALYSIS Par14 Par17 & Par18 Use"PASTESPECIAL Use"PASTE SPECIAL Values" then "COPY., Lead Values" then "COPY" Nickel . Maximum data . Maximum data points = 58 points = 58 Results Date Std Dev. 0.0000 Mean 5.00 C.V. 0.0000 n 3 Mult Factor = 1.00 Max. Value 5.0 ug/L Max. Pred Cw O DETECTS ug/L 4- Use"PASTE Ya Ply SPECIAL -Values" then "COPY". Maximum data points = 58 4.6667 0.6000 3 3.00 5.0 Ng/L 15.0 Ng/L Date Data 1 BDL=1/2DL Results 10 5 Std Dev. 1 8/27/2012 < 10 5 Std Dev. 2.4284 2 11/29/2012 < 10 5 Mean 3.1500 3 12/11/2012 < 10 5 C.V. 0.7709 4 2/11/2013 < 10 5 n 20 5 6/25/2013 < 1 0.5 6 8/16/2013 < 1 0.5 Mult Factor = 1.47 7 11/4/2013 < 1 0.5 Max. Value 7.500 ug/L 8 11/12/2013 < 1 0.5 Max. Pred Cw O DETECTS ug/L 9 2/24/2014 < 1 0.5 10 5/12/2014 < 1 0.5 11 8/3/2014 < 1 0.5 12 11/10/2014 < 1 0.5 13 2/9/2015 < 3 1.5 14 5/18/2015 < 15 7.5 15 7/28/2015 < 10 5 16 8/17/2015 < 10 5 17 11/16/2015 < 10 5 18 2/15/2016 < 10 5 19 5/16/2016 < 10 5 20 8/15/2016 < 10 5 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 4- Use"PASTE Ya Ply SPECIAL -Values" then "COPY". Maximum data points = 58 4.6667 0.6000 3 3.00 5.0 Ng/L 15.0 Ng/L Date Data BDL=1/2DL Results 1 12/11/2012 < 10 5 Std Dev. 2 11/12/2013 4 4 Mean 3 7/8/2015 < 10 5 C.V. (default) 4 n 5 8 6 Mult Factor = 7 11 Max. Value 8 Max. Pred Cw 9 14 10 16 11 17 12 19 13 20 14 22 15 23 16 25 17 26 18 28 19 29 20 31 21 32 22 34 23 35 24 25 26 27 28 29 30 31 32 33 34 35 4- Use"PASTE Ya Ply SPECIAL -Values" then "COPY". Maximum data points = 58 4.6667 0.6000 3 3.00 5.0 Ng/L 15.0 Ng/L NCO087947 RPA, data 6/22/2017 Date Data 1 12/20/2012 < 5 2 11/12/2013 1.1 3 7/8/2015 < 10 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 NCO087947 RPA, data 6/22/2017 REASONABLE POTENTIAL ANALYSIS Selenium Use "PASTE SPECIAL Values" then "COPY" Par20 Silver Use "PASTE SPECIAL Values" then "COPY" Par21 Zinc Use "PASTE SPECIAL Values" then "COPY" Part; . Maximum data . Maximum data . Maximum data points = 58 points = 58 points = 58 BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 2.5 Std Dev. 1.9757 1 12/11/2012 < 10 5 Std Dev. 2.5981 1 12/11/2012 < 10 5 Std Dev. 0.0000 1 1.1 Mean 2.8667 2 11/12/2013 < 1 0.5 Mean 3.5000 2 11/12/2013 < 10 5 Mean 5.0000 2 5 C.V. (default) 0.6000 3 7/8/2015 < 10 5 C.V. (default) 0.6000 3 7/28/2015 < 10 5 C.V. 0.0000 3 n 3 4 n 3 4 n 3 4 5 5 5 Mult Factor = 3.00 6 Mult Factor = 3.00 6 Mult Factor = 1.00 6 Max. Value 5.0 ug/L 7 Max. Value 5.000 ug/L 7 Max. Value 5.0 ug/L 7 Max. Pred Cw 15.0 ug/L 8 Max. Pred Cw O DETECTS ug/L 8 Max. Pred Cw O DETECTS ug/L 8 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 17 17 17 18 18 18 19 19 19 20 20 20 21 21 21 22 22 22 23 23 23 24 24 24 25 25 25 26 26 26 27 27 27 28 28 28 29 29 29 30 30 30 31 31 31 32 32 32 33 33 33 34 34 34 35 35 35 NCO087947 RPA, data 5- 6/22/2017 REASONABLE POTENTIAL ANALYSIS Max. Fred Cw 33.600000 gg/L NCO087947 RPA, data 6- 6/22/2017 Use"PASTE SPECIAL Bis(2-etylhexyl) phthalate Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 12/11/2012 < 5 2.5 Std Dev. 4.4792 11/12/2013 < 10 5 Mean 6.2333 7/28/2015 11.2 11.2 C.V. (default) 0.6000 n 3 Mult Factor = 3.00 Max. Value 11.200000 gg/L Max. Fred Cw 33.600000 gg/L NCO087947 RPA, data 6- 6/22/2017 NH3/TRC WLA Calculations Facility: Columbus County POTW PermitNo. NC0087947 Prepared By: Bing Bai Enter Design Flow (MGD): 0.05 Enter s7Q10 (cfs): 0.6 Enter w7Q10 cfs : 7 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 0.6 s7Q10 (CFS) 0.6 DESIGN FLOW (MGD) 0.05 DESIGN FLOW (MGD) 0.05 DESIGN FLOW (CFS) 0.0775 DESIGN FLOW (CFS) 0.0775 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 11.44 IWC (%) 11.44 Allowable Conc. (ug/1) 149 Allowable Conc. (mg/1) 7.0 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 7 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 0.05 (If DF >331; Monitor) DESIGN FLOW (CFS) 0.0775 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 8.74 Upstream Bkgd (mg/1) 0.22 IWC (%) 1.10 Allowable Conc. (mg/1) 144.5 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) oo M M M A O O d �I �I U U O O 0 m m d d L CL 06 d 06 U z CJ O � ate) Q v LL > LL Q d LL n Q Z I N Q d H H H d O O Lr? 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C) - 04/06/13 Weekly mg/I 7.5 15 100 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 04/30/13 Weekly mg/I 5 5.4 8 Monthly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 05/18/13 Weekly mg/I 7.5 8 6.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 05/25/13 Weekly mg/I 7.5 23 206.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 05/31/13 Weekly mg/I 5 11.25 125 Monthly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 06/01/13 Weekly mg/I 7.5 8 6.7 Weekly Average Proceed to NOV Concentration Exceeded BOD, 5 -Day (20 Deg. C) - 09/07/13 Weekly mg/I 7.5 41.82 457.6 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 09/28/13 Weekly mg/I 7.5 9 20 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 09/30/13 Weekly mg/I 5 13.2 164.1 Monthly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 10/05/13 Weekly mg/I 7.5 11 46.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 07/05/14 Weekly mg/I 7.5 20 166.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 05/14/16 Weekly mg/I 7.5 17 126.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case BOD, 5 -Day (20 Deg. C) - 08/13/16 Weekly mg/I 7.5 12 60 Weekly Average Proceed to Concentration Exceeded Enforcement Case Coliform, Fecal MF, MFC 06/01/13 Weekly #/100ml 400 4,300 975 Weekly Geometric Mean Proceed to NOV Broth, 44.5 C Exceeded Coliform, Fecal MF, MFC 08/10/13 Weekly #/100ml 400 4,300 975 Weekly Geometric Mean Proceed to NOV Broth, 44.5 C Exceeded MONITORING REPORT(MR) VIOLATIONS for: Permit: NCO087947I MRs Between 1 - 2012 and 6 - 2017 Region: % Facility Name: % Param Name % County: % Major Minor: % Report Date: 06/05/17 Page: 2 of 3 V7MWiolation Category:% Program Category: % Subbasin:% Violation Action: % PERMIT: NCO087947 FACILITY: Columbus County -Columbus County WWTP COUNTY: Columbus REGION: Wilmington Limit Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 07-2014 001 Effluent Coliform, Fecal MF, MFC 07/12/14 Weekly #/100ml 400 450 12.5 Weekly Geometric Mean Proceed to Broth, 44.5 C Exceeded Enforcement Case Monitoring Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 12-2016 001 Effluent Annual Pollutant Scan [126 12/31/16 Annually yes=1 no=0 Frequency Violation No Action, Invalid parameters] Permit 08-2013 001 Effluent Coliform, Fecal MF, MFC 08/17/13 Weekly #/100ml Frequency Violation Proceed to NOV Broth, 44.5 C 10-2013 001 Effluent Coliform, Fecal MF, MFC 10/12/13 Weekly #/100ml Frequency Violation Proceed to Broth, 44.5 C Enforcement Case 06-2012 001 Effluent Copper, Total (as Cu) 06/30/12 Quarterly ug/I Frequency Violation No Action, Facility Reporting Error 02-2012 001 Effluent Flow, in conduit or thru 02/29/12 Continuous mgd Frequency Violation No Action, Facility treatment plant Reporting Error 06-2012 001 Effluent Lead, Total (as Pb) 06/30/12 Quarterly ug/I Frequency Violation No Action, Facility Reporting Error 02-2012 001 Effluent Nitrogen, Ammonia Total (as 02/18/12 Weekly mg/I Frequency Violation No Action, Facility N) - Concentration Reporting Error Other Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 11-2012 11/12/12 Aquatic toxicity permit Proceed to NOV limit violation 12-2012 12/03/12 Aquatic toxicity permit Proceed to NOV limit violation 11-2013 11/04/13 Aquatic toxicity permit Proceed to NOV limit violation 12-2013 12/09/13 Aquatic toxicity permit Proceed to NOV limit violation MONITORING REPORT(MR) VIOLATIONS for: Permit: NCO087947I MRs Between 1 - 2012 and 6 - 2017 Region: % Facility Name: % Param Name % County: % Major Minor: % Report Date: 06/05/17 Page: 3 of 3 V7MWiolation Category:% Program Category: % Subbasin:% Violation Action: % PERMIT: NCO087947 FACILITY: Columbus County -Columbus County WWTP COUNTY: Columbus REGION: Wilmington Other Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 01-2014 01/20/14 Aquatic toxicity permit Proceed to limit violation Enforcement Case Reporting Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 12-2016 01/31/17 Late/Missing DMR None 6/22/17 WQS = 12 ng/L Facility Name Columbus County POTW/NC0087947 /Permit No. : Total Mercury 1631E PQL = 0.5 ng/L Date Modifier Data Entry Value 12/10/12 0.866 0.866 11/19/13 < 0.5 0.5 8/5/15 < 0.5 0.5 MERCURY WQBEL/TBEL EVALUATION V:2013-6 No Limit Required No MMP Required 7Q10s = 0.600 cfs WQBEL = 104.90 ng/L Permitted Flow = 0.050 47 ng/L 0.9 ng/L - Annual Average for 2012 0.5 ng/L - Annual Average for 2013 0.5 ng/L - Annual Average for 2015 Removal Rate Calculations Removal -rate Calculation Removal Rates Page 1 of 1 pages 6/13/2017, 8:27 AM Revision: August 1999 AMMONIA < Influent mg/L Used in Calculation < Effluent mg/L Used in Calculation Influent < mg/L Used in Calculation < Effluent mg/L Used in Calculation Sample Date Mar -17 Spreadsheet 1782.5 1782.5 1.5 1.5 < 2.6 1.3 < 2.6 1.3 Instructions: 1) Data Heavyd only in Bordered cells. Rest of worksheet is 1567.5 1182.4 1577.5 1450.6 1567.5 < 1182.4 < 1577.5 < 1450.6 < 2.0 2.0 2.0 3.0 1 1 1 1.5 < 2.6 < 2.6 < 2.6 < 2.6 1.3 < 1.3 1.3 < 1.3 2.6 4.3 2.60 2.86 1.3 4.28 1.3 2.86 Feb -17 Jan -17 Dec -16 Nov -16 protected, password is T. 2) For below 2584.0 1358.0 1246.0 2584.0 1358.0 < 1246.0 0.6 2.0 1.7 0.6 1.0 1.7 < 2.6 5.3 2.9 1.3 5.3 < 2.9 < 2.10 2.50 2.50 2.1 1.25 1.25 Oct -16 Sep -16 Aug -16 detection data, Jul -16 enter "<" in "<" column, and enter detection level in Influent or Effluent mg/I columns. 1493.0 1293.0 1740.0 1422.0 1493.0 < 1293.0 1740.0 1422.0 < 2.0 1.5 3.2 2.0 1.0 1.5 3.2 1.0 < 2.7 < 2.7 3.3 < 2.7 1.4 < 1.4 < 3.3 1.4 2.60 2.60 3.00 5.60 1.3 1.3 3 5.6 Jun -16 May -16 Apr -16 Spreadsheet will auto- a 1258.0 1488.0 1258.0 1488.0 < 1.8 2.0 1.8 1.0 < 2.7 < 2.7 1.4 1.4 3.00 1.30 3 1.3 Mar -16 Feb -16 c calcculateulate averages and removal rates using 1/2 1793.0 1640.0 1793.0 < 1640.0 2.0 1.8 1.0 1.8 < 2.8 < 2.8 1.4 1.4 < 1.80 2.70 1.8 1.35 Jan-16 Dec -15 value entered. 3) Document removal Rate choice 4) Formulas in Compre- hensive Guide HwAcnapter, Section E, 1463.0 1825.0 1740.0 1382.0 1294.0 1463.0 < 1825.0 1740.0 < 1382.0 <1 1294.0 <1 1551.405 2.0 2.3 2.0 2.0 2.0 1.0 2.3 1.0 1.0 1.0 1.33 < 2.7 3.6 < 2.8 < 2.8 3.3 1.4 < 3.6 < 1.4 < 1.4 < 3.3 1<1 1.90 2.70 2.70 2.70 2.70 2.70 1.35 1.35 1.35 1.35 1.35 1.95 Nov -15 Oct -15 Sep -15 Aug -15 Jul -15 Column Avera g es => page 1. Unpaired Site Specific RR => 99.91 % Unpaired Site Specific RR NC0087947 Literature/Default RR => 85.00 % Literature/Default RR => 85.00 Columbus County POTW 31 % of data is BDL 69 % of data is BDL 6/13/2017 Removal -rate Calculation Removal Rates Page 1 of 1 pages 6/13/2017, 8:27 AM Revision: August 1999 AMMONIA NPDES/Aquifer Protection Permitting Unit Pretreatment Information Request Form PERMIT WRITER COMPLETES THIS PART: Check all that apply PERMIT WRITERS - AFTER you pet this form back from PERCS: Notifyy PERCS if LTMP/STMP data we said should be on DMRs is not really there, so we can get it for you (or NOV POTW). - Notify PERCS if you want us to keep a specific POC in LTMP/STMP so you will have data for next permit renewal. - Email PERCS draft permit, fact sheet, RPA. - Send PERCS paper copy of permit (w/o NPDES boilerplate), cover letter, final fact sheet. Email RPA if changes. n/a 0 Date of Request 6/8/2017 municipal renewal X 2017 Requestor Bing Bai new industries Facility Name Columbus County POTW WWTP expansion Permit Number NCO087947 Speculative limits Region Wilmington stream reclass. Basin Cape Fear outfall relocation 7Q10 change I otherl other check applicable PERCS staff: 10ther Comments to PERCS: RRn (:PF (:TR FRR TAR - Sarah Racc (Rn7-R31 n1 CHO, HW, LTN, LUM, NES, NEW, ROA, YAD Monit Hassan (807-6314) Facility is permited for 0.05 MGD, with Hexion Inc. as the sole user. The facility does not receive or treat any domestic wastewater, and is running a pretreatment program. PERCS PRETREATMENT STAFF COMPLETES THIS PART: Status of Pretreatment Program (check all that apply) 1) facility has no SIU's, does have Division approved Pretreatment Program that is INACTIVE 2) facility has no SIU's, does not have Division approved Pretreatment Program X 3) facility has SIUs and DWQ approved Pretreatment Program (list "DEV" if program still under development) 3a) Full Program with LTMP X 3b) Modified Program with STMP 4) additional conditions regarding Pretreatment attached or listed below Flow, MGD Industrial Uncontrollable a a Parameter of Concern (POC) L) y Check List a BOD TSS NH3 Arsenic Cadmium Chromium Lead Molybden Nickel Silver Selenium Zinc Total Nitn Phosphor Permitted Actual ITime period for Actual I I STMP time frame: 0.029 0.013 1/1/2016 - 12/31/2016 Most recent: 2012 n/a 0 Next Cycle: 2017 POC due to Required NPDES/ Non- Required by 503 Disch Permit EPA* Sludge— dge** Limit POC due to SIU*** POTW POC STMP (Explain Effluent below)**** Freq LTMP Effluent Freq 4 = quarterly sampling one year before HWA is due X 4 N/A X 4 X 4 X 4 X 4 4 X 4 X 4 Is all data on DMRs? X 4 YES X 4 NO (attach data) X 4 X 4 4 X 4 X 4 Is data in spreadsheet YES email to writer NO *Always in the LTMP/STMP ** Only in LTMP/STMP if sludge land app or composte (dif POCs for incinerators) *** Only in LTMP/STMP while SIU still discharges to POTW **** Only in LTMP/STMP when pollutant is still of concern to POTW :omments to Permit Writer (ex., explanation of any POCs; info you have on IU related investigations into NPDES problems): emoval rate data from 2012 attached. Sampling for next HWA should have begun 2017 and should be recorded on DMRs. SIU flow from )retreatment annual report. All flow into POTW is from SIU; no uncontrollable. Columbus County NCO087947 Revised: July 24, 2007