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HomeMy WebLinkAboutNC0089729_Renewal Application_20171114Water Resources ENVIRONMENTAL QUALITY November 14, 2017 Douglas Pierotti, P G. City of Charlotte 600 E 4th St Charlotte, NC 28202 Subject: Permit Renewal Application No. NCO089729 Myrtle/Morehead Storm Drainage Improvement Mecklenburg County Dear Applicant: ROY COOPER ri -srRor XhCHAEL S- REGAN Secretory LSA. CULPEPPER hderh" Dkedor The Water Quality Permitting Section acknowledges receipt of your application for a new NPDES WW permit, including supporting documentation and your check number 089125 in the amount of $860.00 as payment of the application fee. These items were received in our offices on November 8, 2017. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. The permit writer will contact you if additional information is required to complete evaluation of your application. Your timely and direct response to any such request will help to expedite the review process. Please note that acceptance of the application does not guarantee a NPDES permit will be issued for the proposed activity. A permit will only be issued following a complete review of the application, concluding the proposed discharge is allowable per applicable statutes and rules. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https://dgg. nc.gov/permits-regulations/perm it -g uida nce/envi ronmental-a ppl ication-tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. Sincerely, 3f0i Wren The ford Administrative Assistant Water Quality Permitting Section cc: Central Files w/application ec: WQPS Laserfiche File w/application State of North Carolina I Environmental Quality I Water Resources 1617 Mail Service Center I Raleigh, North Carolina 27699-1617 919-807-6300 ENVIRONMENTAL • GEOTECHNICAL BUILDING SCIENCES • MATERIALS TESTING October 16, 2017 North Carolina Department of Environment Quality Division of Water Quality NPDES Permit Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 7606 Whitehall Executive Center Drive Suite 800 Charlotte, NC 28273 Tel 704-529-3200 Fax 704-529-3272 www atcassociates corn RE: Engineering Alternatives Analysis and NPDES Permit Application Vicinity of Caldwell Street and South Boulevard Myrtle/Morehead Storm Drainage Improvement Charlotte, Mecklenburg County, North Carolina ATC Project No. 199WO01701 Dear NPDES Permit Unit: R CE1VED/fl1C,0pQ/DVVR NOVO 2017 ftltwity Pe-ffn n,q sectio¢ On behalf of the City of Charlotte, ATC Associates of North Carolina, P.C. (ATC) is submitting three copies of the National Pollutant Discharge Elimination System (NPDES) Permit Application for the discharge of treated groundwater at the above referenced project site. Attached you will find the NPDES permit application short form C — GW and a check for payment of the NPDES permit application fee, on behalf of the City. In addition, ATC has evaluated the alternatives to surface water discharge, as required in the case of any NPDES permit application, in accordance with the Engineering Alternatives Analysis Guidance Document. If you have any questions or comments, please contact our office at (704) 529-3200. Sincerely, ATC Associates of North Carolina, P.C. Joseph G. Schold, PE Principal Engineer PC: Paul Smith, PE, Woolpert Doug Pierotti, PG, City of Charlotte David A. Hunter, PG Principal Scientist Charlotte -Mecklenburg STORM600 E Fourth Street `�T�T,�JE� Charlotte, NC 28202 ��+t�� Fax 704 336 6586 Services pco,Doq_10�9 October 25, 2017 NC Department of Environmental Quality Division of Water Resources Water Quality Permitting Section - NPDES 1617 Mail Sei vice Center Raleigh, NC 27699-1617 Re: NPDES permit application (Short Form C -GW) - request to discharge into the City of Charlotte municipal stormwater system from the Myrtle/Morehead Storm Diainage Improvement Project in Charlotte, NC Division of Water Resources: Regarding the City of Charlotte's request in their NPDES permit application C -GW to discharge treated water from a remediation system at the above -referenced location into Charlotte's stormwater system, Charlotte Mecklenburg Storm Water Sei vices (CMSWS) approves the discharge. CMSWS would like to make the permittee and NC DEQ aware of the following considerations and information: CMSWS does not guarantee adequate capacity is available to permitted dischargers to keep any property or street flee of water or harm as a result of this discharge. CMSWS takes no responsibility for backflows fi•om the public drainage system into the permitted discharger's system. CMSWS is aware of trichloroethylene (TCE) and perchloroethylene (PCE) levels above Class C surface water human health standards in Little Sugar Creek (the proposed receiving water) between E. 36th St. and N. Brevard St. in Charlotte, NC. The contaminated area is located approximately 3.6 miles upstream from where the remediation system discharge receiving tributary would enter Little Sugar Creek. The source of surface water contamination is soil and groundwater contamination at a vacant industrial property along Cullman Avenue. Kathleen Lawson with the NC DEQ Hazardous Waste Section is managing the required remediation in cooperation with the responsible party if you would like more specific information. CHARIOTTF.. To report pollution or drainage problems, call 311 http //stormwater charmeck org NC Department of Environmental Quality NPDES Permit Unit October 25, 2017 If you have any questions, please contact Craig Miller at (704) 336-7605. Sincerely, c 4 Craig Miller NPDES Program Supervisor cc: David Hunter, PG, ATC Group Services LLC Doug Pierotti, PG, City of Charlotte Environmental Services 2 Engineering Alternatives Analysis and NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement Charlotte, Mecklenburg County, North Carolina ATC Project Number 199WOO1701 Engineering Alternatives Analysis and NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement Charlotte, Mecklenburg County, North Carolina ATC Project No. 199WOO1701 Prepared by: David A. Hunter, F Principal Scientist .•`o4tN 0 ARU, VA 4� Andrew Deppensmith Project Scientist seph G. Schold, PE NC Licensed Engineer6, .•�N CAq�''1. ��' � rflEs�I •. F13 v 's,��.�v�A•Q� aOvO Submitted to: North Carolina Department of Environment and Natural Resources Division of Water Quality NPDES Permit Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 On Behalf of: The City of Charlotte 600 East Fourth Street Charlotte, North Carolma 28202 Phone: (704) 336-3602 Fax: (704) 336-4554 Submitted by: ATC Associates of North Carolina, P.C. 7606 Whitehall Executive Center Drive, Suite 800 Charlotte, North Carolina 28273 Phone: (704) 529-3200 Fax: (704) 529-3272 October 16, 2017 TABLE OF CONTENTS 1.0 SITE INFORMATION...........................................................................................................1 1.1 Site Description.............................................................................................................1 1.2 Site Background............................................................................................................2 1.3 Dewatering Conditions and Flow Projections..............................................................3 2.0 ENGINEERING ALTERNATIVES ANALYSIS................................................................5 2.1 Connection to an Existing Wastewater Treatment System...........................................5 2.2 Land Application..........................................................................................................5 2.3 Infiltration Galleries......................................................................................................6 2.4 In -Situ Groundwater Remediation Wells......................................................................6 2.5 Closed -Loop Groundwater Remediation Wells............................................................7 3.0 PROPOSED GROUNDWATER TREATMENT SYSTEM...............................................9 4.0 DISCUSSION........................................................................................................................11 ATTACHMENTS Figure 1 Site Location Map Figure 2 Environmental Site Map Figure 3 Treatment System Schematic Table 1 Maximum Concentrations of Constituents Appendix A NPDES Permit Application — Short Form C — GW Appendix B Hart & Hickman Groundwater Monitoring Report — June 2017 EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No 199WO01701 October 16, 2017 1.0 SITE INFORMATION 1.1 Site Description The remaining parts of the Myrtle/Morehead project for the City of Charlotte, Stormwater Services, will include drainage improvements to the stormwater drain system to relieve flooding in upper reaches of a tributary of Little Sugar Creek. The area that experiences flooding extends along South Boulevard between Rensselaer Avenue and Templeton Avenue and extends to areas east and southeast of that interval of South Boulevard. These areas encompass the proposed storm drainage improvement construction area, generally between South Boulevard and Euclid Avenue, and between Rensselaer Avenue and Templeton Avenue. Figure I indicates the project location on part of a United States Geological Survey, topographic quadrangle map. The project will entail trenching to depths below the expected water table elevation in unconsolidated overburden soils beneath the water table along the proposed stormwater drain alignments. Construction could also encounter bedrock and its included fractures that contain groundwater. Dewatering will therefore likely be required during project construction. The groundwater is proposed to be collected, treated, and discharged to stormwater drains which will convey the flow to a Class C surface water. Research of environmental conditions in the project vicinity and monitoring of groundwater monitoring wells were performed by Hart and Hickman. McCorkle's Cleaners, a former drycleaner, operated at 1437 South Boulevard. According to a Groundwater Monitoring Report by Hart and Hickman in April 2016, chlorinated solvent impact was identified in the site monitoring well network. Figure 2 depicts the extent of the chlorinated solvent impact superimposed on the storm drain system and easements in the affected area. According to the analytical data presented in the Groundwater Monitoring Report, potential exists for groundwater to be impacted by drycleaning solvents in this area. Other downstream/downdrain locations with anticipated improvements are through residential areas with low potential for groundwater impact. 1 ATC Associates of North Carolina, P C. EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No 199WOO1701 October 16, 2017 The NPDES Permit Application Form is provided as Appendix A, and the other attachments to include a groundwater analytical table, a USGS topographic map, and a site map with contaminant plume and discharge locations, and a proposed groundwater treatment system, as requested by the permit application form. 1.2 Site Background The former McCorkle's cleaners operation operated at 1437 South Boulevard, Charlotte, North Carolina. The former drycleaner is monitored and regulated as part of the Dry -Cleaning Solvent Cleanup Act (DSCA) Program. Figure 2 depicts the site on an aerial photograph, with pertinent site features. Hart and Hickman conducted a groundwater monitoring event in March 2016. Chlorinated solvent impact above North Carolina Groundwater and Surface Water Standards was identified in the monitoring well network for multiple chlorinated solvent constituents. Potential dewatering associated with the Myrtle/Morehead Storm Drainage Improvement project could generate groundwater that includes tetrachloroethylene (PCE), trichloroethylene (TCE), and vinyl chloride (VC) above North Carolina Class C Surface Water Quality Standards (North Carolina Administrative Code, Title 15A, Subchapter 213; 2B Standards). A summary of groundwater analytical data and other impact information is provided in the Hart and Hickman Groundwater Monitoring Report in Appendix B. Figure 2 in the attached appendix indicates the alignment of the drain construction, and subsurface impact, principally by chlorinated solvents, which the drain construction is likely to encounter. Table 1 in the attached appendix provides a summary of maximum concentrations for groundwater impact based on testing along the proposed construction alignment. Approximately 400 linear feet (STA 3+00 to 8+00) of 48 -inch RCP will be installed with trench depths up to 20 feet deep with anticipated groundwater depth as shallow as 5 feet deep. The project duration should not exceed six months. The currently available groundwater concentrations were derived from analysis of volatile organic compounds via EPA Method 8260B, which is a standard environmental analysis of environmental media specified in the EPA SW -846 manual. Testing of groundwater in impacted 2 ATC Associates of North Carolina, P.0 EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No 199WO01701 October 16, 2017 areas will be conducted prior to NPDES discharge via EPA Method 8260 to confirm conditions found by the prior analyses. Testing of NPDES-permitted treatment system conditions will also be conducted by EPA Method 8260 during discharge treatment. 1.3 Dewatering Conditions and Flow Projections The source of groundwater from dewatering will likely be primary porosity from residual soils below the water table. Although rock tunneling is not expected in the project area potential exists for limited sections of the storm drain system to encounter bedrock and for dewatering to occur from bedrock fractures. The volume of flow associated with dewatering will likely be variable based on the materials encountered and other factors; however, the estimated flow volumes are based on historic flow volumes documented during dewatering along Baxter Street on the northeastern end of the project, at prior Outfall 3, and flow at the tunnel section, which included bedrock near the intersection of Morehead Street with Oriole Street, at prior Outfall 1. This dewatering, treatment and discharge occurred under NPDES Permit NC0089443. The prior dewatering and treatment was conducted during the period of fall 2014 through the winter of 2016. Flow was variable based on construction activities and the aquifer materials that were encountered. The observed flow rates ranged from lows of approximately 0.56 to 1.0 gallons per minute (gpm) up to maximum flows approaching 14 gpm. The lowest flows were recorded in areas that involved trenching through soil overburden aquifer conditions, and the highest flows resulted during tunneling through bedrock. Based on experience with the prior trenching and tunneling at other area's of the project, as well as bedrock hydraulic testing in the Piedmont Physiographic Province, a rough range of likely flow volumes for the dewatering if groundwater is encountered could be approximately 1.0 to 50 gpm. ATC estimates an amount for this proposed permit that is less than NPDES Permit No. 0089443, based on the depth and lateral exposure of excavation that are expected to be less than the downstream parts of the construction. The actual amount of dewatering volume during construction will depend upon the length of trenching interval that is exposed to aquifer and whether the excavation occurs within residual soils or in water bearing fractures. 3 ATC Associates of North Carolma, P C EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No. 199WOO1701 October 16, 2017 The area of stormwater improvements proposed for the area approximately 400 to 800 feet to the east of the intersection of South Boulevard and Rensselaer Avenue encompasses groundwater impact by chlorinated solvents from the former McCorkle's Cleaners that exceed surface water standards. The anticipated dewatering fluids will contain PCE, TCE, and VC impact exceeding 2B Standards for Class C surface water in the area of the receiving waters. The standard for fish consumption in Class C waters is 3.3 ug/L for PCE, 30 ug/L for TCE, and 2.4 ug/L for VC. Collection of groundwater containing impact concentrations of up to 113 ug/L of PCE, 50.7 ug/L of TCE and approximately 15.2 ug/L of VC could be expected given the most recent groundwater conditions found during an April 2017 monitoring event of the apparent releases at McCorkle's Cleaners. Table I contains the maximum concentrations from the April 2017 monitoring event, and Appendix B contains the June 2017 Groundwater Monitoring Report for the April 2017 sampling data. For the purposes of treatment design, ATC has assumed a flow of up to 50 gpm, with the three regulated chlorinated solvents' concentrations indicated above, so that treatment would result in discharge concentrations that are less than the Class C surface water standards. 4 ATC Associates of North Carolina, P C. EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No. 199WO01701 October 16, 2017 2.0 ENGINEERING ALTERNATIVES ANALYSIS The North Carolina Division of Water Quality Engineering Alternatives Analysis (EAA) Guidance Document, dated June 23, 2005, requires an evaluation of wastewater disposal alternatives in addition to direct discharge. The subject discharge will be from a groundwater remediation system and the following wastewater disposal alternatives are therefore being evaluated: • Connection to an existing wastewater treatment system • Land application • Infiltration galleries • In-situ groundwater remediation wells • Closed-loop groundwater remediation wells 2.1 Connection to an Existing Wastewater Treatment System ATC contacted the Charlotte Water to determine if groundwater from the onsite treatment system could be discharged to the Charlotte Water's Publicly Owned Treatment Works (POTW). Charlotte Water did not provide permission to discharge pre-treated groundwater to the sewer system. Thus, POTW discharge for the treated water will not be an acceptable alternative for discharge of treated dewatering fluids. 2.2 Land Application Land application of groundwater through drip irrigation or spray irrigation is not a feasible alternative for disposal of dewatering fluids at the project site. The project is located in an urban area of Charlotte, and sufficient permeable land is not available in the vicinity for groundwater application. The land area requirements also entail setbacks of the land application areas from property boundaries. Additionally, the drainage construction project will be conducted in municipal roadways, and unpaved private properties would therefore need to be acquired for land application purposes. According to sales records obtained from Charlotte -Mecklenburg POLARIS (Property Ownership and Land Records Information System), private properties in the project vicinity would cost approximately $500,000 to $2,000,000. Groundwater treatment, 5 ATC Associates of North Carolina, P C EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No. 199WOO1701 October 16, 2017 which would be required prior to irrigation, would add to the expense of this alternative. Based on excessive expenses needed for property purchases, as well as lack of available permeable area, land application is not a feasible alternative. 2.3 Infiltration Galleries An infiltration gallery is a horizontal drain constructed of perforated piping and surrounded by permeable material, such as sand or gravel, which distributes treated water for infiltration to subsurface soils. An infiltration gallery should be able to store and transmit water to the subsurface at the same or greater rate that water is being added to prevent flooding. Assuming the maximum potential discharge rate of 50 gpm, the surficial silt and clay of the Piedmont would not transmit dewatering fluids at a sufficient rate to prevent flooding. ATC personnel have extensive experience with past efforts through non -discharge permitting where infiltration, in Piedmont soils with much lower flow rates were unsuccessful, even with expansion of infiltration galleries beyond original designs. The galleries would also require extensive land area for construction, which is not available at the subject site. In addition, because the proposed project area spans over 1000 feet, a stationary discharge location would not be feasible and multiple galleries would be necessary. The use of infiltration galleries for discharge of dewatering fluids is infeasible for the project. 2.4 In -Situ Groundwater Remediation Wells At least two separate classes of technologies could be interpreted to meet the definition of in-situ groundwater remediation. In one sense, in-situ groundwater remediation would be conducted by injection of materials designed to reduce contaminant concentrations in groundwater, so that water collected during construction dewatering could be directly discharged, without additional treatment, to surface waters. Such in-situ remediation usually relies upon trenches, galleries, or injection wells to infiltrate fluids that remediate dissolved contaminants and contaminants that are sorbed to the soil and aquifer matrix. Such materials either enhance natural biological processes of aerobic or anaerobic metabolism; act chemically upon the contaminants by oxidation or reduction; or provide a material, such as activated carbon, to sorb the contaminants. Combinations of the technologies are also often used. 6 ATC Associates of North Carolina, P C EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATCProiectNo 199WOO1701 October 16. 2017 In-situ groundwater remediation can be effective at reduction of impact to achieve groundwater regulatory goals; however, full remediation in the limited time before inception of the storm drain improvement project, especially to concentrations below surface water standards, would be unlikely. Property access across a much larger footprint than the project currently affects would also be necessary for effective remediation of materials that might migrate to the dewatering locations. Reactive barrier walls installed by trenching could be attempted. Again, the project footprint would be excessively expanded, and potential for impacted groundwater to migrate beneath the reactive barrier trench would be enhanced due to the dewatering. If wells were used an underground injection control (UIQ permit would also be required. Full remedial costs to render the impacted groundwater suitable for discharge would also be prohibitively expensive, if such a method were even technologically feasible, which is not certain. Another potential interpretation for in-situ groundwater remediation entails that dewatering fluids be collected, treated, and re -injected to specifically -installed, subsurface injection wells for management of the fluid. This process would require sufficient wells for the Piedmont bedrock aquifer to accept the injection of the dewatering fluid. Approval of the fluid injection would also require a UIC permit. Installation of piping to carry the fluids to the injection well locations would be needed, or contaminated water would need to be transported to a separate area for injection. An extended period of time of likely many years for chlorinated remediation, using what is essentially a pump -and -treat technology, would also be required and would constitute an unacceptable time period given the project schedule. As with other alternatives the pump and treat method with re-injection would be unnecessarily expensive. In-situ groundwater remediation is judged to be an unacceptable alternative for the project. 2.5 Closed -Loop Groundwater Remediation Wells A closed-loop groundwater remediation system, typically using recirculation well technology, collects groundwater from one aquifer interval, treats the groundwater within the well, and injects the treated water into another aquifer interval. The technology can be set up to operate in several ways. The water can be collected from a shallow zone, treated, and then inject to a deeper zone, or the opposite arrangement can be made. Hybrid setups of multiple collection and 7 ATC Associates of North Carolina, P C EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No. 199WOO1701 October 16, 2017 injection zones may also be possible. The hydraulic modeling and design of an inject well system typically strives to achieve a re -circulation cell in the local groundwater regime, so that impacted water migrating to the recirculation cell is captured and treated, with the net effect being that the recirculation cell prevents impacted water from passing the recirculation cell. As with other remedial options that require groundwater treatment, additional area and property access would be required for recirculation; pilot testing would be needed to assure that a sufficient number of wells were placed along the construction alignment; and certainty of successful cleanup could not be assured, especially because the construction alignment is through existing groundwater impact. The schedule to provide groundwater cleanup along the alignment would also be an extended period. The action of dewatering adjacent to the recirculation wells would also have uncertain consequences and could adversely affect the technology's ability to assure clean dewatering discharge. Because of the cost of $100,000 or more per recirculation well, the technology would also be likely to have very high costs. Closed- loop groundwater remediation wells would be an unacceptable alternative for achieving groundwater cleanup that would result in clean dewatering fluids collection prior to the project start. 8 ATC Associates of North Carolina, P C EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No 199WO01701 October 16, 2017 3.0 PROPOSED GROUNDWATER TREATMENT SYSTEM Appendix A contains the NPDES Permit Application, Short Form C—GW, with supporting documentation. The proposed groundwater treatment system consists of an air stripper, Carbonair STAT 80 or equivalent, with four trays and a 350 cubic feet per minute (CFM) blower with a flow capacity of up to 50 gpm to volatilize the expected chlorinated solvent impact in groundwater for atmospheric discharge. Groundwater extracted from the trenching project will be collected into an optional weir/equalization tank to reduce sediment, then into a holding and settling vessel of approximately 500 to 1,000 gallons each. Flow from the holding tank will be float switch -controlled and pumped at a maximum rate of 50 gpm through two, parallel filtration units to remove sediment, and then proceed into the air stripper. The water will then cascade downward through the ventilated air stripper trays as the air is forced upward through the air stripper. Once in the holding tank at the base of the air stripper, a set of float switches will control discharge via a second pump to the NPDES discharge location. Additionally, a second set of, redundant pumps of 50 gpm maximum capacity will be placed for pumping to the air stripper from the holding tank and after the air stripper to pump to the discharge. The second, redundant, set of pumps before and after the stripper will serve as emergency pumps to assure continued operation in case of filter clogging or other failure of one of the primary pumps. Figure 3 in the attached appendix is a proposed treatment system schematic. Two stormwater drains have been proposed for potential discharge and are located in an easement area near the intersection of Cleveland Avenue and Rensselaer Avenue and in an easement near the bend of South Caldwell Street. The final discharge point of the two storm drains is Little Sugar Creek and its tributaries. Figure 2 in the attached appendix shows the proposed discharge locations on a site plan. A maximum flow rate of 50 gpm and influent concentration maximums from Table I were used for treatment system design purposes. Table 2 provides model output for treatment by the specified air stripper or equivalent. The effluent will be sampled initially upon treatment system startup and again for the system startup after major changes in dewatering locations during the project. Once certainty regarding dewatering fluid conditions is obtained for each area of 9 ATC Associates of North Carolina, P.0 EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No 199WO01701 October 16, 2017 construction, the need for continued NPDES permitted discharge will be evaluated and communicated to the NPDES Permitting Unit. For each application, the system effluent will be sampled once per week during the first month of operation and for each month of treatment system operation thereafter. The laboratory analytical data using EPA Method 8260 for volatile organic compounds will be utilized to determine that required treatment is being met. The operator in responsible charge (ORC) will submit monthly discharge monitoring reports (DMRs). I 10 ATC Associates of North Carolina, P C. EAA & NPDES Permit Application Myrtle/Morehead Storm Drainage Improvement ATC Project No 199WO01701 October 16, 2017 4.0 DISCUSSION Consideration should be given to the overall storm drainage improvement as a rationale for requesting NPDES permitting as part of the project construction. That is, the goal of the project is limit flooding during major storm events, which, especially in urban settings, present significant contributions to adverse surface water quality conditions. The routing of the drain in its large diameter, downstream segment as proposed will aid the project schedule and limit the number of flood events affecting headwaters of the drainage during the planning and construction phases. Please note that the project design includes methods to seal the drain against impacted groundwater incursion across intervals affected by groundwater impact. Thus, the proposed NPDES permit will allow construction of a drainage improvement that will ultimately serve to increase water quality. 11 ATC Associates of North Carolina, P.C. FIGURES G _ _ 27 49 SITE AREA 27 = ' .�, \ .� CQ' ���P � ' ��C►�'�, � � ANT �� i F \�- 4v w TREMoTA 5 - v Al �, �.:, �, , c r tic oSO QQy '��•� F,o `� 3 o ; �o 0 500 1,000 2000 REFERENCE: USGS 7.5-MINUTE MAP, CHARLOTTE EAST, NORTH CAROLINA. DATED 2016 APPROXIMATE SCALE IN FEET IR TITLE FIGURE 1 SITE LOCATION MAP Iff MYRTLE AND MOREHEAD STORMWATER IMPROVEMENTS ArAkTc SOUTH BOULEVARD ASSOCIATES OF NORTH CAROLINA, P.C. CHARLOTTE, NORTH CAROLINA ChwiciftNorhCwol. 2W3 QW)52"= FAX M4)52D-W2 CAD FILE MMNPEDS I TYPE CODE I PREP BY AD REV. BY DH SCALE AS SHOWN DATE 8.28.17 PROJECT NO 1 NA y✓vA \ Ga 4 ... - c C;'J —_ z s S Vl/�y d„ rrf •�'VZ ., / At, 3 .- x ~ r Cr o c ti : '' 10 1 OAI F' Lt li�� V O 00 -� - �` Z r> 0V, C_ Oo 0 v v~ �s OJ ! �71 .; �o o 0OOH tea: M D O z (O /� \ D z J )1Z.v'-,. . � M �'� . ' rZ f MIa J 7 r 0 0 'A� o L rm Z0 o r `O '1 W O .. c y i 0 m a � � O `a. m o \�. m $ rr >y' O , j .. o n � 0 o .r m cn cn � m cn A\�� M � � X o M m m D o rn m �7 Z7 —{ n + <� m c �7 m z z �} �. C q C7 O —1 C red t* C m Aew�t m m 0Al D r �� 40 FIGURE 2 DISCHARGE LOCATIONS ARE TO EXISTING ENVIRONMENTAL SITE MAP NA DROP INLETS OFCITY DRAINAGE SYSTEM, WHICH N kT STORMWATER DCHARLOTTE MYRTLE/MOREHEAD STORM DRAINAGE IMPROVEMENTS OUTFALL TO LITTLE SUGAR CREEK. ENVIRONMENTAL SERVICES—CITY OF CHARLOTTE ASSOCIATES OF NORTH CAROLINA, P.C. CHARLOTTE, NORTH CAROLINA Charlotte, North Carolina 28273 (704)529-3200 FAX (704)529-3272 PREP. BY REV. BY SCALE DATEPROJECT NO. MMNPDES I AD DH AS SHOWN 9.5.17 199WO01701 Am v u. .D z a �j z A m m D M� M A O z U) A C Am � ADeO Z cZzz 0S(!v o rr'Z{ 61 _J 1N O O v 1140 rLs 2 O 6 z c� z x pq r m —DI D C W O ;u _ fT7 O G) D M m m Z r < m Z r- C 7 O r N z < O z ;a ;mum r N m -+ z Ln C7 0 0 0 �o D A Z 0, M O AM 0 z 1 Lt_ FIGURE 3 JW TREATMENT SYSTEM SCHEMATIC � A C MYRTLE/MOREHEAD STORM DRAINAGE IMPROVEMENTS kT ENVIRONMENTAL SERVICES -CITY OF CHARLOTTE ASSOCIATES OF NORTH CAROLINA, P.C. CHARLOTTE, NORTH CAROLINA Charlotte, North Carolina 28273 (704)529-3200 FAX (704)529-3272 FB,D Flt "I[. I'RIFP. BY REV. BY SCfV..[:. DATE PROJECT NO. MMNPDES AD/CS DH NOT TO SCALE 9.22.17 199WO01701 = D 6 go gym D M� M A O z U) A C Am � ADeO Z cZzz 0S(!v o rr'Z{ 61 _J 1N O O v 1140 rLs 2 O 6 z c� z x pq r m —DI D C W O ;u _ fT7 O G) D M m m Z r < m Z r- C 7 O r N z < O z ;a ;mum r N m -+ z Ln C7 0 0 0 �o D A Z 0, M O AM 0 z 1 Lt_ FIGURE 3 JW TREATMENT SYSTEM SCHEMATIC � A C MYRTLE/MOREHEAD STORM DRAINAGE IMPROVEMENTS kT ENVIRONMENTAL SERVICES -CITY OF CHARLOTTE ASSOCIATES OF NORTH CAROLINA, P.C. CHARLOTTE, NORTH CAROLINA Charlotte, North Carolina 28273 (704)529-3200 FAX (704)529-3272 FB,D Flt "I[. I'RIFP. BY REV. BY SCfV..[:. DATE PROJECT NO. MMNPDES AD/CS DH NOT TO SCALE 9.22.17 199WO01701 TABLES Table 1 Maximum Concentrations of Constituents Myrtle/Morehead Storm Drainage Improvement Environmental Services - City of Charlotte Charlotte. North Carolina Notes: 1. Maximum concentrations obtained from groundwater monitoring analytical data from the most recent Groundwater Monitoring Report completed by Hart & Hickman, dated June 15, 2017. 2. North Carolina 2B Standards are Class C water quality standards for surface waters (North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters). c w° c aci o a, U Z A G N U U A N U U U N fn q Maximum Concentration 10,300 113 200 50.7 15.2 3.33 20.9 2.44 1,350 43.3 2.70 3.13 NC 2B Standards NE 3.3 NE 30 2.4 NE I NE NE NE NE I NE I NE Notes: 1. Maximum concentrations obtained from groundwater monitoring analytical data from the most recent Groundwater Monitoring Report completed by Hart & Hickman, dated June 15, 2017. 2. North Carolina 2B Standards are Class C water quality standards for surface waters (North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters). Table 2 Influent/Effluent Model for Treatment System fro Ct ERVICIES (ORPORMIiION (' Customer: Date: Design Basis ATC Group Services LLC 09/26/2017 Flow rate: Water temperature CARkMR 50 Spm 55 OF (assumed) 1140 Conrad Industrial Dr. Ludington, M149431 office 231.843.2711 fax 231.843.4081 Contaminant Influent Concentration (Vg/L)(a) Effluent Criteria (µg/Qb) Cis-1,2-Dichloroethene 10,300 - Tetrachloroethene (PCE) 113 3.3 Trans-1,2-Dichloroethene (DCE) 200 - Trichloroethene (TCE) 50.7 30 Vinyl Chloride (VC) 15.2 2.4 Xylene 3.33 - 1,1-Dichloroethene 20.9 - Chloroform 2.44 - 2-Butanone (MEK) 1,350 - Tert-Butylbenzene 43.3 - 1,1-Dichloroethane (DCA) 2.7 - 1,2,4-Trimethylbenzene 3.13 - (a) Based on the given influent concentrations. (b) Based on the given NC 2B standards. Bold values indicate contaminants above discharge criteria. Recommendations: Low Profile Air Stripper STAT 80 unit with 4 trays, operated at 350 cfm • PCE is the design contaminant. • The effluent PCE concentration is predicted to be 1.9 ppb (see the modeling output below). All contaminants are predicted to be below discharge criteria. NOTICE THIS DOCUMENT AND ITS CONTENTS ARE PROPRIETARY TO CARBONAIR ENVIRONMENTAL SYSTEMS, AND MAY NOT BE COPIED, DISTRIBUTED OR USED BY ANYONE, IN WHOLE OR IN PART, WITHOUT THE EXPRESS AUTHORIZATION OF CARBONAIR. THE CONTENT OF THIS DOCUMENT HAS BEEN DEVELOPED BY CARBONAIR TO ADDRESS SPECIFIC FACTUAL INFORMATION. IT MAY BE BASED ON INFORMATION AND ASSUMPTIONS THAT ARE NOT DISCLOSED WITHIN THIS DOCUMENT, BUT REFLECT CARBONAIR'S KNOWLEDGE AND EXPERIENCE. THE INFORMATION IN THIS DOCUMENT SHOULD NOT BE USED OR RELIED UPON BY ANYONE WITHOUT THE COOPERATION OR ASSISTANCE OF CARBONAIR TO FULLY UNDERSTAND ITS INTENDED APPLICATION AND USE. Safety - Quality - Teamwork - Professionalism - Positive Attitude proact-usa.com carbonair.com CARBONAIR ENVIRONMENTAL SYSTEMS 1480 County Road C West, Roseville, MN 55113 PHONE: 800-526-4999 FAX: 651-202-2985 STAT MODEL CALCULATIONS Tue Sep 26 12:22:29 CDT 2017 UNIT MODEL: STAT 80 WATER FLOW RATE (GPM): 50.00 AIR FLOW RATE (ACFM): 350.00 AIR -TO -WATER RATIO: 52:1 WATER TEMPERATURE (F): 55.00 AIR TEMPERATURE (F): 55.00 OPERATING PRESS (ATM): 1.00 SAFETY FACTOR M: 15.00 Influent Conc. for CIS-1,2-DICHLOROETHENE 10300.00000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF 54.21330 77.93479 89.11638 94.57150 97.27749 98.63087 EFF CONC ppb 4716.03037 2272.71688 1121.01241 559.13574 280.41804 141.02010 OFF -GAS CONC ug/l 107.38403 154.37083 176.5189.9 187.32431 192.68427 195.36500 Influent Conc. for TETRACHLOROETHENE 113.00000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF 64.84055 87.39902 95.45327 98.35545 99.40465 99.78441 EFF CONC ppb 39.73018 14.23911 5.13781 1.85834 0.67275 0.24362 OFF -GAS CONC ug/l 1.40903 1.89925 2.07427 2.13734 2.16014 2.16839 AIR EMISSION lb/d 3.35186 4.81849 5.50982 5.84709 6.01440 6.09807 AIR EMISSION lb/d 0.04398 0.05928 0.06475 0.06671 0.06743 0.06768 Influent Conc. for TRANS-I,2-DICHLOROETHENE 200.00000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF 58.34519 81.84956 91.94170 96.39305 98.37966 99.27092 EFF CONC ppb 83.30961 36.30088 16.11661 7.21390 3.24068 1.45816 OFF -GAS CONC ug/l 2.24405 3.14806 3.53622 3.70743 3.78383 3.81811 Influent Conc. for TRICHLOROETHENE 50.70000 ppb NO OF REMOVAL EFF EFF CONC OFF -GAS CONC TRAY % ppb ug/l 1 63.02637 18.74563 0.61451 2 85.92917 7.13391 0.83781 3 94.58755 2.74411 0.92223 4 97.90956 1.05985 0.95462 AIR EMISSION lb/d 0.07005 0.09826 0.11038 0.11572 0.11811 0.11918 AIR EMISSION lb/d 0.01918 0.02615 0.02879 0.02980 5 99.19135 0.40999 0.96712 6 99.68700 0.15869 0.97195 Influent Conc. for VINYL CHLORIDE 15.20000 ppb NO OF REMOVAL EFF EFF CONC OFF -GAS CONC TRAY % ppb ug/l 1 73.89606 3.96780 0.21600 2 93.07166 1.05311 0.27206 3 98.15309 0.28073 0.28691 4 99.50709 0.07492 0.29087 5 99.86841 0.02000 0.29192 6 99.96487 0.00534 0.29220 Influent Conc. for XYLENES (TOTAL) 3.33000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF % 57.75230 81.57573 91.85683 96.37981 98.38643 99.27998 EFF CONC ppb 1.40685 0.61353 0.27117 0.12055 0.05373 0.02398 OFF -GAS CONC ug/l 0.03698 0.05224 0.05882 0.06172 0.06301 0.06358 Influent Conc. for 1,1-DICHLOROETHENE 20.90000 ppb NO OF REMOVAL EFF EFF CONC OFF -GAS CONC TRAY % ppb ug/l 1 72.74583 5.69612 0.29238 2 92.49504 1.56854 0.37176 3 97.92753 0.43315 0.39359 4 99.42725 0.11971 0.39962 5 99.84168 0.03309 0.40129 6 99.95623 0.00915 0.40175 Influent Conc. for CHLOROFORM 2.44000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF % 53.02738 76.79326 88.26236 93.99442 96.90932 98.40470 EFF CONC ppb 1.14613 0.56624 0.28640 0.14654 0.07541 0.03893 Influent Conc. for MEK 1350.00000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF % 1.90403 3.24246 4.19215 4.87048 5.35730 5.70786 EFF CONC ppb 1324.29554 1306.22677 1293.40601 1284.24846 1277.67642 1272.94386 OFF -GAS CONC ug/l 0.02488 0.03603 0.04142 0.04411 0.04547 0.04617 OFF -GAS CONC ug/l 0.49432 0.84179 1.08835 1.26445 1.39084 1.48185 0.03019 0.03034 AIR EMISSION lb/d 0.00674 0.00849 0.00896 0.00908 0.00911 0.00912 AIR EMISSION lb/d 0.00115 0.00163 0.00184 0.00193 0.00197 0.00198 AIR EMISSION lb/d 0.00913 0.01160 0.01229 0.01247 0.01253 0.01254 AIR EMISSION lb/d 0.00078 0.00112 0.00129 0.00138 0.00142 0.00144 AIR EMISSION lb/d 0.01543 0.02628 0.03397 0.03947 0.04341 0.04625 Influent Conc. for tert-BUTYLBENZENE 43.30000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF 0 58.57018 82.44624 92.49306 96.77697 98.61389 99.40345 EFF CONC ppb 17.93911 7.60078 3.25050 1.39557 0.60019 0.25831 OFF -GAS CONC ug/l 0.48771 0.68652 0.77018 0.80585 0.82115 0.82772 Influent Conc. for 1,1-DICHLOROETHANE 2.70000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF 58.17892 81.74715 91.89024 96.36872 98.36841 99.26577 EFF CONC ppb 1.12917 0.49283 0.21896 0.09804 0.04405 0.01982 OFF -GAS CONC ug/l 0.03021 0.04245 0.04771 0.05004 0.05108 0.05154 Influent Conc. for 1,2,4-TRIMETHYLBENZENE 3.13000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF 43.88496 67.07570 80.20557 87.93073 92.57911 95.41401 EFF CONC ppb 1.75640 1.03053 0.61957 0.37777 0.23227 0.14354 OFF -GAS CONC ug/l 0.02642 0.04037 0.04828 0.05293 0.05573 0.05743 Influent Conc. for TOTAL VOCs 12104.70000 ppb NO OF TRAY 1 2 3 4 5 6 REMOVAL EFF 0 48.65504 69.85020 79.81133 84.66836 87.08372 88.29939 STAT Modeler Disclaimer EFF CONC ppb 6215.15292 3649.54311 2443.77743 1855.84939 1563.47662 1416.32350 OFF -GAS CONC ug/l 113.26052 162.59917 185.78697 197.09328 202.71583 205.54570 AIR EMISSION lb/d 0.01522 0.02143 0.02404 0.02515 0.02563 0.02584 AIR EMISSION lb/d 0.00094 0.00132 0.00149 0.00156 0.00159 0.00161 AIR EMISSION lb/d 0.00082 0.00126 0.00151 0.00165 0.00174 0.00179 AIR EMISSION lb/d 3.53528 5.07533 5.79911 6.15202 6.32752 6.41585 Carbonair's STAT Modeler is accurate only when contaminants are completely dissolved in water in the absence of substances, which may significantly affect the stripper capabilities of contaminants, such as oil & grease, surface active and foaming agents, alcohols, ketones, and other potential Henry's constant altering contaminants. Although the effluent concentration predictions made by the STAT Modeler are accurate predictions of field performance, they do not constitute a guarantee that these concentrations will be met in the field. Please contact your Carbonair representative for a design review and confirmation. APPENDIX A NPDES PERMIT APPLICATION - SHORT FORM C - GW For discharges associated with groundwater treatment facilities Mail the complete application to: N. C. Department of Environment and Natural Resources Division of Water Quality / NPDES Unit 1617 Mail Service Center, Raleigh, NC 27699-1617 NPDES Permit Number INCOO If you are completing this form in computer use the TAB key or the up - down arrows to move from one field to the next. To check the boxes, click your mouse on top of the box. Otherwise, please print or type. 1. Contact Information: Owner Name City of Charlotte, Attn. Douglas Pierotti, P.G. Facility Name Myrtle/Morehead Storm Drainage Improvement Mailing Address 600 East Fourth St. City Charlotte State / Zip Code North Carolina / 28202 Telephone Number (704)651-4366 Fax Number (704)336-4554 e-mail Address dpierotti@charlottenc.gov 2. Location of facility producing discharge: Check here if same as above ❑ South Boulevard; South Caldwell Street; Templeton Street Address or State Road Avenue; Euclid Avenue; Rensselaer Avenue, and Cleveland Avenue City Charlotte State / Zip Code North Carolina / 28202 County Mecklenburg 3. Operator Information: Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the Operator in Responsible Charge or ORC) Name City of Charlotte Attn. Douglas Pierotti, P.G. Mailing Address 600 East Fourth St. City Charlotte State / Zip Code North Carolina / 28202 Telephone Number (704)651-4366 Fax Number (704)336-4554 4. Ownership Status: Page 1 of 3 C -GW 03/05 NPDES PERMIT APPLICATION - SHORT FORM C - GW For discharges associated with groundwater treatment facilities. Federal ❑ State ❑ Private ❑ Public 5. Products recovered: Gasoline ❑ Diesel fuel ❑ Solvents ® Other 6. Number of separate discharge points: 3 Outfall Identification number(s) #1 and #2 (Little Sugar Creek) 7. Frequency of discharge: Continuous ® Intermittent ❑ If intermittent: Days per week discharge occurs: Duration: 8. Treatment System Design flow 0.050 MGD 9. Name of receiving stream(s) (Provide a map showcng the exact location of each outfall, including latitude and longitude): Little Sugar Creek "Class C" 10. Please list all additives to the treatment system, including chemicals or nutrients, that have the potential to be discharged. No Additives 11. Is this facility located on Indian country? (check one) Yes ❑ No 12. Additional Information All applicants (including renewals): A USGS topographical map (or copy of the relevant portion) which shows all outfalls A summary of the most recent analytical results (effluent data, if available) containing the maximum values for each chemical detected NEW Applicants only: Engineering Alternative Analysis Description of remediation treatment system components, capacities, and removal efficiency for detected compounds. If the treatment system will discharge to a storm sewer, written approval from the municipality responsible for the sewer. A list of any chemicals found in detectable amounts at the site, with the maximum observed concentration reported for each chemical (the most recent sample must be collected less than one year prior to the date of this application) For petroleum -contaminated sites - Analyses for Volatile Organic Compounds (VOC) should be performed. Analyses for any fuel additives likely to be present at the site and for phenol and lead should also be performed. For sites contaminated with solvents or other contaminants - EPA Method 624/625 analysis should be performed. Page 2 of 3 C -GW 03/05 NPDES PERMIT APPLICATION - SHORT FORM C - GW For discharges associated with groundwater treatment facilities 13. Applicant Certification I certify that I am familiar with the information contained in the application and that to the best of my knowledge and belief such information is true, complete, and accurate. Douglas Pierotti, P.G. Senior Project Manager Printed name of Persop Signing Title Da North Ciro a General Statute 143-215 6 (b)(2) provides that Any person who knowingly makes any false statein t r presentation, or certification in any application, record, report, plan, or other document files or required o be maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or monitoring device or method required to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both (18 U S C. Section 1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both, for a similar offense.) Page 3 of 3 C -GW 03/05 APPENDIX B Groundwater Monitoring Report McCorkle's Cleaners DSCA ID: DC600077 1437 South Boulevard Charlotte, Mecklenburg County North Carolina Dry -Cleaning Solvent Cleanup Act Program H&H Job No. DSO -80G June 15, 2017 nuoihq .Q Ste- _ OV221 ! •, j NGINE�G. hart hickman SMARTER ENVIRONMENTAL SOLUTIONS #C-1269 Engineering #245 Geology 2923 South Tryon Street, Suite 100 3334 Hillsborough Street Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com 704.586 0007 main 1 919.847.4241 main Groundwater Monitoring Report Forms for North Carolina Dry -Cleaning Solvent Cleanup Act Program Facility Name: McCorkle's Cleaners 1437 South Blvd, Charlotte, Mecklenburg County, North Carolina DSCA ID No.: DC600077 Submittal Date: June 15, 2017 Prepared By: Hart & Hickman, PC 2923 S. Tryon Street, Suite 100, Charlotte, NC 28203 Reporting Period: April 2017 to Type of Report: One -Time Event RI Semi -Annual 0 Quaterly ❑ Annual 0 Table of Contents LVA I "Nall DSCA ID No.: DC600077 Form/Att . No. Description Check box if included Groundwater Monitoring Report Forms Form 1 Report Summary 0 Form 2 Quality Assurance/Quality Control Procedures 0 Form 3 Results Conclusions and Recommendations Groundwater Monitoring Report Attachments Aft. 1 Disposal of IDW receipts from receiving facilities, or any required harzardous p Aft. 2 Site Location Map p Att. 3 Site Map p Att. 4 Groundwater Gradient Map p Att. 5 Groundwater Isoconcentration Maps 0 Att. 6 Groundwater Concentration Trend Graphs 0 Att. 7 Laboratory Analytical Report p CA ID No.: DC600077 Dates samples were collected 4/24/2017 Number of existing monitoring wells 9 List the sampled monitoring wells MW -1, MW -2S, MW -2D, MW -3, MW -4, MW -5, MW -6, MW -7, and MW -8 List the sampled water supply wells No water supply wells sampled List surface water samples collected No surface water samples collected Date analyses were performed 4/27/2017 & 4/28/2017 Were any holding times exceeded? O Yes O No Dates monitoring/supply wells were gauged 4/24/2017 Does investigation derived waste (IDW) generated during these activities still remain at the site pending disposal9 F77 OO No Average depth to groundwater 9 07 ft - shallow wells Groundwater flow direction southeast Was the static groundwater level above the top of the well screen in any wells? OO Yes O No If Yes, indicate which wells MW -1, MW -2D, MW -4, and MW -6 Is the aquifer I O Confined (9 Unconfined O Perched Were any existing monitoring wells damaged O Yes O No If Yes, indicate which wells Has the groundwater plume been defined? O Yes O No Any ongoing assessment activities? O Yes O No If Yes. provide details in the space below Any ongoing remediation activates? I O Yes O No If Yes, provide details in the space below Any significant changes in the subsurface conditions9 If Yes, provide details in the space below- O Yes) No Quality Assurance/Quality Control Procedures DSCA ID No.: DC600077 Describe the standard quality assurance/quality control (QA/QC) procedures which are practiced in order to ensure that the samples are representative of actual conditions and that analytical results are valid The water level and water quality meters were decontaminated using Alconox detergent and distilled water after each well was gauged, measured, and/or pumped to avoid cross -contamination New nitrile gloves and purge/sample tubing (both polyethylene and silicone) were used at each well Samples were collected directly into laboratory -prepared sample containers, labeled with the site and sample identifications, time, date, sampler's initials, and analysis method Samples were secured in protective wrap or bags before being covered with ice and cooled to 4 degrees Celsius in a laboratory -supplied sample cooler A sample chain -of - custody was completed and placed in the sample cooler The cooler was picked up by a courier for delivery to TestAmerica Laboratories, Inc in Nashville, Tennessee The laboratory ran standard Type Il QC measures. Describe the specific sampling technic ue employed during the collection of all ground water samples. Standard USEPA-approved low-flow/low-stress purge techniques were employed during the collection of the groundwater samples Polyethylene tubing was installed to the middle of the well screen, secured at the top of the well, and connected to a short piece of silicone tubing at the peristaltic pump rotor A second piece of polyethylene tubing was connected to the outflow side of the silicone tubing Depth -to -water was then measured with a decontaminated water level probe, and the probe was set at the top of the water column Groundwater was drawn through the tubing by the peristaltic pump at a rate that prevented drawdown of the water column in the well (approximately 100-250 mUmm at this site) Field measurements of temperature, pH, conductivity, dissolved oxygen (DO), and oxidation-reduction potential (ORP) were collected during low flow purging Readings of each parameter were collected at 5 minute intervals After field readings stabilized, samples were collected using the EPA -approved "soda -straw method". Describe the EPA approved methods used to extract and analyze the samples submitted the laboratory. Reference the maximum holding time for each type of analysis performed Groundwater samples were analyzed for volatile organic compounds (VOCs) by EPA Method 8260B The maximum holding time for VOC analysis is 14 days from the sample collection date (when the sample is preserved in HCL). All samples were preserved with HCL and were analyzed within 14 days of collection There were no discrepancies noted on the laboratory analytical reports for the analytes detected in the samples Results, Conclusions and Recommendations DSCA ID hlo.: DC606056 Results Maximum Concentration Detected in Groundwater Most Recent Event Detected at Site To -date Chemical Sampling Concentration Sampling Concentration Date Sample ID 1mg/L1 Date Sample ID [mg/L1 Tetrachloroethylene 04/24/17 MW -3 0.113 03/09/16 MW -2S 0.622 Trichloroethylene 04/24/17 MW -3 00507 03/09/16 MW -2S 0 754 Vinyl Chloride 04/24/17 MW -2S 00152 10/20/15 MW -2S 0.097 cis-1,2-Dichloroethene 04/24/17 MW -2S 10.3 01/28/15 MW -2S 13 trans-l,2-Dichloroethene 04/24/17 MW -2S 0.200 03/09/16 MW -2S 0.348 Note Other constituents have been detected in groundwater. See Table 8 for a complete list Conclusions Instructions Discuss any trends or changes noted in analytical results Hart & Hickman, PC (H&H) conducted a groundwater sampling event on April 24, 2017, which included gauging water levels and collecting samples from all site monitoring wells The primary constituents of concern at the site are tetrachloroethene (PCE) and it's degradation products trichloroethene (TCE), cis-l,2-dichloroethene (cis-1,2-DCE), trans-l,2-dichloroethylene (trans-1,2-DCE), and vinyl chloride (VC) Other petroleum -related compounds are present in site monitoring wells (see Table 8) Graphs of concentration versus time are provided in Attachment 6 Based on review of the graphs, PCE and TCE concentrations in source area shallow monitoring well MW -2S have fluctuated dramatically over time and were not detected during the April 2017 event Concentrations of cis-1,2-DCE, trans-1,2-DCE, and VC have been more consistent in MW -2S over time Concentrations of PCE and its degradation products in deeper source area monitoring well MW -21), nearby downgradient well MW -3, and the remaining upgradient and downgradient wells (except MW -6) appear to be generally stable or decreasing However, concentrations in MW -6 (located approximately 360 ft downgradient of the source property to the southeast) appear to be increasing overtime Additional sampling is needed to further evaluate concentration trends a the site Recommendations H&H conducted a groundwater sampling event at the McCorkle's Cleaners site on April 24, 2017 to evaluate current concentrations in the site monitoring wells. The analytical results indicate a potential decreasing concentration trend for dry-cleaning related constituents in source area monitoring well MW -2S and an increasing trend in downgradient well MW -6 (located in a residential area). Concentrations in the remaining site monitoring wells appear to be stable or decreasing. H&H recommends additonal groundwater sampling to further evaluate groundwater concentration trends at the site TABLES Analytical Data Tables for North Carolina Dry -Cleaning Solvent Cleanup Act Program McCorkle's Cleaners Facility Name: 1437 South Blvd, Charlotte, Mecklenburg County, North Carolina DSCA ID No.: DC600077 Submittal Date: June 15, 2017 Hart & Hickman, PC 11 Prepared By: 2923 S. Tryon Street, Suite 100, Charlotte, NC 28203 Table of Contents • DSCA ID No.: DC600077 Table/ Att. No. Description Check box if included Tables Table 1 Site Chronology D Table 2 Analytical Data for Soil ❑ Table 3 Analytical Data for Sub -slab Gas ❑ Table 4 Analytical Data for Soil Gas ❑ Table 5 Analytical Data for Indoor and Outdoor Air ❑ Table 6 Monitoring Well Construction Data 0 Table 7 Groundwater Elevation Data O Table 8 Analytical Data for Groundwater El Table 9 Analytical Data for Surface Water ❑ Table 10 Water Well(s) Survey Data ❑ Table 11 Analytical Data for Water Supply Well(s) ❑ Table 12 Analytical Data for Natural Attenuation Parameters O Attachments Att 1 Site map showing location(s) of soil boring(s) ❑ Att 2 Soil contaminant concentration maps showing the concentration at each sampling point ❑ Att 3 Soil isoconcentration maps. ❑ Att 4 Site map showing location(s) of monitoring well(s) ❑ Att 5 Well completion diagrams and records of construction submitted to state ❑ Att 6 Groundwater gradient map for each sampling event ❑ Att 7 PCE concentration map showing the concentration at each sampling point and isoconcentration map However, if there are significant plumes for other dry- cleaning contaminants, contaminant concentration maps for each chemical of concern should be included. ❑ Att. 8 Groundwater concentration trend plots ❑ Att. 9 Map showing location(s) of surface water sample(s) (if applicable) ❑ Att 10 Surface water concentration map showing the concentration at each sampling point (if applicable) El Att 11 USGS Quad map with plotted water well location(s) within the 1,500 foot and 0 5 mile radii of the site (if applicable) 11 Att 12 Site map showing location(s) of monitoring well(s) for natural attenuation paramet ❑ Att 13 Site map showing location(s) of indoor air, outdoor air, or soil gas samples ❑ Att 14 Air and soil gas concentration map showing the concentration at each sampling point ❑ Att 15 Signed laboratory analytical reports including chain -of custody and quality assurance/quality control (QA/QC) documentation (only if not previously submitted) ❑ Att 16 ❑ Att 17 ❑ Att 18 ❑ Att 19 ❑ Att 20 ❑ Att. 21 ❑ Note. 1 All maps must include a bar scale, north arrow, site name, DSCA ID No., and date Table 1: Site Chronology DSCA ID No.: DC600077 Chronology of Events Instructions Brief description of all significant events that have occurred since a problem was Date suspected at the facility Commence with the first date a problem was suspected and continue through the most recent activity described In the current report Terracon Consultants, Inc conducted a Phase I Limited Site Assessment (LSA) of the site property The LSA revealed September 2012 that the source property building operated as an active dry-cleaner from at least the 1920s to the 1960s Remnants of the former dry-cleaning operations were found during the assessment including an old dryer located inside the back of the building and an empty, 55 -gallon drum of Perchloroethylene located outside in a cmder-block storage area Terracon Consultants, Inc conducted a Phase 11 LSA of the site property which included collecting soil and groundwater October 2012 samples from two downgradient borings and collecting one, upgradient groundwater sample The results of the assessment indicated a dry-cleaning release had occurred at the site Both petroleum (Stoddard Solvent) and tetrachloroethene (PCE) based constituents were detected in soil and groundwater samples March 8, 2013 The site is certified into the DSCA Program H&H conducted Pnontization Assessment (PA) activities at the site The PA activities included the installation and sampling of seventeen soil borings (SB -1 through SB -17), ten temporary monitoring wells (TW -1 through TW -10), four Type -II monitoring wells (MW -1, MW -3, MW -4 and MW -5) and one nested well pair (MW-2S/D) As partof the PA activities, H&H conducted vapor intrusion (VI) assessment activities which included collection of two sub -slab soil gas samples (VMP-1 and VMP-2), two indoor air samples (IAS -1 and IAS -2), and one outdoor background air sample (BAS June - August 2013 1) Both indoor air samples (IAS -1 and IAS -2) collected in June 2013 (with no HVAC system operating) had Hazard Index (HI) values above 1 H&H re -sampled indoor air in the same locations (IAS -1 and IAS -2) in August 2013 after the HVAC system had been operating for a few days The indoor air samples collected in August 2013 had HI values less than1 On September 11, 2013, H&H submitted a Vapor Intrusion Assessment letter report to the DSCA Program On September 20, 2013, H&H submitted a Priontization Assessment Report and associated attachments to the DSCA Program documenting the results of the PA activities H&H conducted additional assessment activities at the site to further delineate the extents of soil and groundwater impacts, including the collection of samples from two soil borings (SB -18 and SB -17) and twelve temporary January 2015 groundwater sampling locations (TW -11 through TW -22) H&H also collected groundwater samples from the existing site monitoring wells (MW -1, MW-2S/D, MW -3, MW -4 and MW -5) On April 30, 2015, H&H submitted a report to the DSCA Program documenting the results of the additional assessment activities H&H conducted additional vapor intrusion assessment activities at the site Initially, H&H collected near -slab, January - March subsurface soil gas samples (SGP -1 through SGP -5) on the source property and adjacent properties to the east and south 2015 Based on the results, H&H subsequently collected an indoor air sample from the adjacent Elizabeth House Flowers building located at 1431 South Blvd On April 30, 2015, H&H submitted a letter report to the DSCA Program documenting the additional vapor intrusion assessment activities H&H conducted additional groundwater assessment activities at the site to further delineate the extent of groundwater impacts downgradient of the source property The additional assessment activities included the installation of three October 2015 permanent monitoring wells (MW -6, MW -7, and MW -8) Following installation, the newly installed monitoring wells were sampled along with the existing site monitoring wells (MW -1, MW -2, MW -3, MW -4 and MW -5) On January7, 2016, H&H submitted a Monitoring Well Installation Report to the DSCA Program documenting the results of the additional groundwater assessment activities H&H conducted soil gas and groundwater sampling activities at the at the site The soil gas sampling was conducted at the Charlotte Housing Authority property located to the southeast and downgradient of the site and included the March 2016 collection of six sub -surface soil gas samples (VMP-1 through VN/IP-6) The groundwater sampling activies included the collection of groundwater samples from monitoring wells MW -2S, MW -21), MW -3, MW -6, MW -7, and MW -8 On April 7, 2016, H&H submitted a Groundwater Monitoring Report to the DSCA Program documenting the results of the groundwater sampling activities H&H conducted additional soil gas sampling activities on the Charlotte Housing Authority property located southeast (downgradient) of the McCorkles Clenaers source property Three subsurface soil gas samples (VMP-7 through VMP-9) May 2016 were collected to adjacent to the apartment tower evaluate the potential vapor intrusion risk On May 20, 2016, H&H submitted a brief letter report to the DSCA Program documenting the sampling activities and results Page 1 of 2 Table 1: Site ChronoIogy 1101 DSCA ID No.: DC600077 Chronology of Events Instructions Brief description of all significant events that have occurred since a problem was Date suspected at the facility. Commence with the first date a problem was suspected and continue through the most recent activity described in the current report. H&H conducted additional soil gas sampling activities on four residentially -zoned properties located southeast (downgradient) of the McCorkles Clenaers source property Subsurface soil gas samples were collected adjacent to each September and of the downgradient buildings to evaluate the potential vapor intrusion risk The samples were collected at 401 December 2016 Rensselaer Ave (VMP-10 and VMP-11), 323 Rensselaer Ave (VMP-12 and VMP-13), 325 Rensselaer Ave (VMP-14 and VMP-15), and 405 Rensselaer Ave (VMP-16 VMP-17, and VMP-18) On January 26, 2017, H&H submitted a brief letter report to the DSCA Program documenting the sampling activities and results H&H conducted groundwater sampling activities at the at the site The groundwater monitoring achvies included gauging April 2017 Fater levels and collecting groundwater samples from each of the site monitoring wells (MW -1, MW -2S, MW -21), and MW -3 through MW -8 On June 15, 2017, H&H submitted a Groundwater Monitoring Report to the DSCA Program documenting the sampling activities and results Page 2 of 2 Table 6:Monitoring Well Construction Data �61 11319-3 DSCA ID No.: DC600077 Well ID Date Installed (mm/dd/yy) Number of Samples Well Depth [feet] Well Diameter [inch] Screen Interval [feet] Status (Active/Inactive) MW -1 06/28/13 4 30 2 15-30 Active MW -2S 08/05/13 5 23 1 8-23 Active MW -2D 08/05/13 5 67 1 62-67 Active MW -3 08/05/13 5 25 2 10-25 Active MW -4 08/05/13 4 20 2 5-20 Active MW -5 08/06/13 4 20 2 5-20 Active MW -6 10/14/15 3 20 2 5-20 Active MW -7 10/14/15 3 25 2 10-25 Active MW -8 10/14/15 3 20 2 1 5-20 Active Page 1 of I Table 7: Groundwater Elevation Data MIWA DSCA ID No.: DC600077 Groundwater Sampling Point Sampling Date (mm/dd/yy) TOC Elevation [feet] Depth to Water [feet bgs] Groundwater Elevation [feet] Depth to NAPL NAPL Thickness Corrected* [feet bgs] [feet] Groundwater Elevation [feet] MW-1 08/07/13 73198 13 72 71826 -- - - 01/28/15 15 52 71646 - - 10/20/15 1411 71787 - -- -- 03/09/16 12 15 71983 04/24/17 13 17 718 81 MW-2S 08/07/13 72675 1252 71423 - -- -- 01/28/15 1097 715 78 -- -- 10/20/15 1190 71485 -- - -- 03/09/16 10 16 71659 -- - -- 04/24/17 1150 71525 - -- MW-2D 08/07/13 72663 1265 713 98 -- -- - 01/28/15 1172 71491 -- - -- 10/20/15 1250 714 13 -- - 03/09/16 1052 716 11 -- - 04/24/17 1203 71460 -- - MW-3 08/07/13 72797 15 14 71283 -- - - 01/28/15 1413 713 84 -- -- 10/20/15 1495 71302 -- - 03/09/16 1275 71522 -- -- -- 04/24/17 1465 71332 -- -- -- MW-4 08/07/13 723 14 497 718 17 - -- 01/28/15 3 88 71926 -- -- 10/20/15 549 71765 -- 03/09/16 3 54 71960 -- -- -- 04/24/17 301 720 13 -- -- -- MW-5 08/07/13 71847 809 71038 - -- -- 01/28/15 656 71191 - -- -- 10/20/15 766 710 81 -- -- -- 03/09/16 535 713 12 -- - -- 04/24/17 722 71125 -- -- -- MW-6 10/20/15 70872 641 70231 -- - 03/09/16 452 70420 -- - -- 04/24/17 479 703 93 -- - -- Page 1 of 2 Table 7: Groundwater Elevation Data DSCA ID No.: DC600077 Groundwater Sampling Point Sampling Date (mm/dd/yy) TOC Elevation [feet] Depth to Water [feet bgs] Groundwater Elevation [feet] Depth to NAPL NAPL Thickness [feet bgs] [feet] Corrected* Groundwater Elevation [feet] MW-7 10/20/15 716 17 1456 70161 -- -- 03/09/16 1156 70461 -- 04/24/17 1269 70348 -- MW-8 10/20/15 70397 7 11 69686 -- -- 03/09/16 457 69940 04/24/17 5 53 69844 -- Note TOC elevations for MW -1 through MW -5 were professionally surveyed by the Isaacs Group on 8/7/2013 TOC elevations for MW -6 through MW -8 were professionally surveyed by the Isaacs Group on 12/7/2015 Page 2 of 2 t 10 1 air'{ L I tZ t0 OZ00 0 S I Oz 01 81000 SZ000 Sl 8z to S -M W L900'0 9100 ZZO 0 £I LO 80 o n L I tZ/VO £L000 0 8L000 0 S I Oz Of LSO 0 0 SS000 0 100'0 S 182 10 t MIN 1000 8200 0 £ I LO 80 OLZOO 0 n L6100 0 u LOSO 0 tLtoO 0 Ell 0 o SS£'0 LI/tZ/t0 8£I00 0 zztoo 0 9LZO 0 8ZZ00 0 9L90'0 Itl'0 91 60 £0 6500 0 SS00 0 61000 01 0 I LOO 0 SZ'0 6L 0 S1 Oz of £ M W ZI O I£0 ZR0 Si 8Z IO u 1) SI 0 ZS 0 £ I £1 LO/8O Q ttZoo 0 8OZ00 0 Z6Z00 0 S8L00 0 £61 0 L I tZ t0 80£00 0 1910 0 8I£00 0 66t0O 188000 SLI 0 91 60 £0 ££o0 0 ££00 0 Sh00 0 110 0 Z10 0 SS 0 Sl OZ 01 CIZ-MW LIN0 62000 LIN0 11000 95000 96000 t'0 S1 8Z 10 oo LZ00 0 tI00 0 ZI00'O VROO 0 L£00 0 h10'0 6Z 0 £1 Lo 80 £ l £Oo 0 t9zoo 0 ££to 0 S£ 1 60ZO o £££00 o zS10 0 Ooz'o £ of Ll tZ to 961000 9tLO 0 ZbI 00 9£S00 LSZO 0 8180 tR10'0 PSL 0 Rt'£ 0 Z81 0 ZZ9 0 £ 0 91 60 £0 8£0 0 9ZO 0 ESO 0 OLO 0 L60 0 tl.0 I i SI OZ OI SZ MW E Zt0 0 SI 0 £1 SI/8Z 10 ££ 0 11'0 S£ 0 £l £1 Lo 80 L 1 tz M £zoo 0 l9 poo S1 Oz o 1 01000 L9000 SI 8Z IO I MW ZS000 0r;; £I LO 80 I-w2w] =r=r Iv tfo 0 7 N N F O LL000930 oN Qi d3SQ : I • a3)8mpuno.iq ioj e;ud Ivaq IvuV :8 alquL VJ0 Z aaed (pagsgqelsa lou piepuejS IZ_p `uoijeajuaouoD olgtmolIV iunLulXLN imJalul .io) paepuejS IZ )N agldo aouvpoa')\a ue aleoipul suorjraluaouoo P10lI I 01ON s 000 0 l 0 b 0 9000 LO 0 h LO 0 S£ 0 9 S 0 £0000 0 £00 0 1 0 90 L000 0 900 0 ZO 0 90 LO 0 100 0 P-iePLeIS -IZ DN Ll bZ M 91 60 £0 8 -MIN 68000 0 ZZ00 0 17l0'0 6900'0 Z 10 0 Sl OZ 01 L6100 0 0 11 Z00 0 L l bZ/b0 L£1700 0 91 60 £0 L -MIN ZI 00 0 6£00'0 S I OZ O f £Ll0'0 LI1000 60x0 0 OSI 0 LI bZ b0 Z 1100 88100 ZL 100 0 9L£0 0 66600 91 60 0 9 -MIN 61000 690000 8L00 0 010 0 171.0 0 S I OZ of N N n X C N N - gm CL � O .�. ? O O R' G �--V, .� "y tv � =, G S• CJ r -`Ti � O 'G G fD EF ON [77 ^ CSD O _ p '� TJ N � •�Gy � "7 LL0009DU oN QI d3SQ Mu, LUIA- aajumpuno.lq ioj Bled, lead; leUV :8 algn,L Table 8(l): Anal tical Data for Groundwater User Specified Chemicals DSCA ID No.: DC600077 c b y a E c y y v c e ti to E y u ^� ❑, Y y @ D Z T 1 o F c c c U v� 08 07 13 MW 0128 15 -1 l0/20 15 0424 17 08 07 13 01 28/15 MW -2S 10 2 15 03 09 16 0 0139 0 00616 0 0190 00133 0 0212 04/24 17 0 0149 0 00595 0 0195 0 0177 08 07 13 0128 15' MW -21) 1020 15 03 09 16 0424 17 08/07 13 0 01 28 15 MW -3 1020 15 03 09 16 0 0424 17 08 07 13 MW -4 01 28 15 10 20 15 04/24 17 08 07 13 MW 01 28 15 -5 10/20/15 0424 17 Page 3of4 Table 8(1): Anal tical Data for Groundwater ser Specified Chemicals DSCA ID No.: DC600077 c _ w � p U N O p U Q T fl 1 a O T C7 � 10/20/15 <0 00050 <0 0010 <0 00050 ,0 00050 <0 00050 MW -6 03/09/16 <0 00100 <0 00100 <0 00100 <0 00100 <0 00100 04/24/17 <0 00 Loo c0 00100 <0 00100 <0 00100 -000100 10/20/15 <0 00050 <0 001 O <0 00050 <0 00050 <0 00050 MW -7 03/09/16 <0 00100 <0 00100 <0 00100 4 00100 <0 00100 04/24/17 <0 00100 <0 00100 000100 =0 00100 000100 10/20/15 <0 00050 <0 0010 <0 00050 <0 00050 <0 00050 MW -8 03/09/16 <0 00100 <0 00100 <0 00100 <0 00100 <0 00100 04/24/17 <0 00100 <0 00100 <0 00100 -000100 <0 00100 NC 2L Standard 007 007 007 0 025 007 Note 1 Bold concentrations indicate an exceedance of the NC 2L Standard (or Interum Maximum Allowable Concentration, if 2L Standard not established) Page 4 of 4 b w b -- $ample 1D a y t5 O O A N O N _ N pC O A O N n- N W O N O N N O N O N N N O N N GO O A N O N - N 5? O C A o 00 N o 00 rn o 00 o 0 00 O o 0 00 P o �� Sampling Date. (mm/dd/Y n J Ut In W J Cn (n W J G, Vi Ut W J O, Ut Vi w J Q, Vi Ut W J Ut Ut W o d w cn w w o0 0� o, w Cro Dissolved oxygen (DO) o w o w %' A A oo z 7 7 7 '7 ? 7 x i' 1 7 7 7 Nitrate i ,� ✓ 3 % z g Sample I'D D � � N Z i � O � -- � a o o0 0 o0 02Sampling Date (nun/dd y o _ 7— w w N �o A J w A n Q Dissolved oxygen (DO) o N oo O �-- Z C 1 l du Nitrate ^ A Q—'� Sulfate m 0 0 `0 Mayor Cations s� cct\ a r cLo Methane r II—Q Ferrous Iron o �Z 0 o a. Oxidation reduction potential (ORP) f ,7 Alkahnit} r Q_C, t7' y z r -, U2� Chloride (optional) C' Conductivity 3 G1 0 o CT v Cn v V A to o C, C, o C, w A= pH J A oo O 00 0o cn O J Temperature Total organic, carbon r Z C r 7 t (TOC) as Ethane y r coL Ethene C' ATTACHMENT I IDW DISPOSAL RECEIPTS Please onnt or Noe (Form designed for use on elite (12 -aitch) tvoewnter ) Form Approved OMB No 2050-0039 EPA Form 8700-22 (Rev 3-05) Previous editions are obsolete O V1rs1 Bc�9 i ED F,/ CC 9T4: TO S'TAME-E (IF REQU9RED) UNIFORM HAZARDOUS 1. Generator ID Number 2 Page 1 of 3 Emergency Response Phone 4. Manifest Tracking Number 015460105 JJ K WASTE MANIFEST NGFO IS3459 1 800-266-3924-M1 37951 5 Generator's Name and Mailing Address Generators Site Address (if different than mailing address) Petitioner for RSCA ate DCSM77, Slaw #007 McCorkles Cleaners 1437 Soffih Blvd, DWNI-DSCA 1546 Niall Sefvtoe Center Charlotte, NC26=3Slav�0ii7 R3121gh, NG 276-99-16M USA Generator's Phone d.,c 6 Transporter 1 Company Name U S EPA ID Number A&D Environmental SeriloeS (SC), LLC SC09575-%ni 7 Transporter 2 Company Name U.S. EPA ID Number 8. Designated Facility Name and Site Address U S EPA ID Number Clean Harbors Deerpark, LP. TkD055141376 2027 Independence Parkway South La Pone, TX 77671 USA Facility's Phone. 261-930-23M 9a 9b U S. DOT Description (including Proper Shipping Name, Hazard Class, ID Number, 10. Containers 11. Total 12 Unlit 13 Waste Codes No. Type HM and Packing Group (If any)) Quantity WtNGI X 1 UNMM. w4a to Environmentally hazardous substance. Ilquid, n.o.s.,— P --- (teitaah}eraethplene), 9, PG Ill, ERG# 171, W101LU i Z 2 LU 3 I t 4 r 14 Special Handling Instructions and Additional Information 9b.1) CHO-M11 (liquids) P x 55�a1 A&D Job No. %1479 Pw -7b Transponer V i Phone. 8M-434-7750 15. GENERATOR'SIOFFEROR'S CERTIFICATION: I hereby declare that the contents of this consignment are fully and accurately described above by the proper shipping name, and are classified, packaged, marked and labeled/placarded, and are in all respects in proper condition for transport according to applicable international and national govemmental regulations If export shipment and I am the Primary Exporter, I certify that the contents of this consignment conform to the terms of the attached EPAAcknowledgment of Consent. I certify that the waste minimization statement identified in 40 CFR 262 27 ) (if I am a large quantity generator) or (b) (if I am a small quan generator) is true I r 024A,5 Signature •0.1 Month Day Year C7n behalf of Petitioner OC, 6 0000 % 7 -j f— 16 International Shipments ❑ Import to U S. ❑ Export from U S Port of entrylexit. Transporter signature (for exports only), Date leaving U S w 17 TransporterAcknowledgment of Receipt of Materials Transporter 1 Printedrryped Name f Month Day (Year / d U411-1 M ISignature ZTransporter2 PnntedlTyped Name Signature Month Day Year r- 18 Discrepancy 18a Discrepancy Indication Space ❑ Quantity ❑TypeElFull Rejection ❑ Residue ❑Partial Rejection Manifest Reference Number E�. 18b Alternate Facility (or Generator) U S. EPA ID Number V Facility's Phone W 18c. Signature of Alternate Facility (or Generator) Month Day Year 19. Hazardous Waste Report Management Method Codes ( e, codes for hazardous waste treatment, disposal, and recycling systems) W 1 2 1 3 4 20 Designated Facility Owner or Operator Certification of receipt of hazardous materials covered by the manifest except as noted In Item 1 B lTd-ntedfFyped Name Signature Month Day Year EPA Form 8700-22 (Rev 3-05) Previous editions are obsolete O V1rs1 Bc�9 i ED F,/ CC 9T4: TO S'TAME-E (IF REQU9RED) CLEAN HARBORS ENVIRONMENTAL SERVICES, INC LAND DISPOSAL RESTRICTION FORM LDR-1 MANIFEST NO a��� ':Z_ -V THE HAZARDOUS WASTES IDENTIFIED ON THE HAZARDOUS WASTE MANIFEST IDENTIFIED ABOVE AND BEARING THE EPA HAZARDOUS WASTE CODES LISTED BELOW ARE RESTRICTED WASTES WHICH ARE PROHIBITED FROM LAND DISPOSAL WITHOUT FURTHER TREATMENT UNDER THE LAND DISPOSAL RESTRICTIONS, 40 CFR PART 268.7 (3)(2), AND RCRA SECTION 3004(D). IN ACCORDANCE WITH 40 CFR 268.7(a), THE EPA WASTE CODE, WASTE SUBCATEGORY, AND TREATABILITY GROUPS, AS APPLICABLE, ARE INCLUDED BELOW INSTRUCTIONS — COMPLETE ALL SECTIONS. REFER TO PAGE 3 OF THIS FORM FOR KEY TERMS/DEFINITIONS. Column 1 - Line Item Enter the manifest line item number (e g , 11 a) that corresponds to the waste code(s). Column 2 - Waste Codes/Subcategory Check off all applicable waste codes For D001 through D043, also check applicable subcategory, for F001 through F005, check applicable constituents Column 3 - Wastewater/Non-wastewater Check off "WW" for wastewater and "Non -WW" for non -wastewaters. Column 4 - LDR Handling Code Circle the appropriate handling code, as follows 1 = The waste is a characteristic hazardous waste D001, D002, D003, D004 -D011, or D018-43 which is intended for treatment/disposal in a CWA system, CWA-equivalent system, or Class I SDWA system. Underlying Hazardous Constituents (UHC's) are NOT required to be identified. 1A= The waste is a characteristic hazardous waste D001 High TOC Ignitable Liquids Subcategory (i e , greater than or equal to 10% TOC). Pursuant to 40 CFR 268 40, the waste must be treated using organic recovery (RORGS) or combustion (CMBST) technology UHC's are NOT required to be Identified. 2 = The waste is a characteristic hazardous waste D001 (other than High TOC Ignitable Liquids), D002, D003 Explosive, Water Reactive or Other Reactive subcategory, D004 -D011, D012-17 non -wastewater, or D018-43 which is intended for treatment/disposal in a non-CWA system, non-CWA-equivalent system, or non -Class I SDWA system located in the United States All UHC's which are reasonably expected to be present must be identified, except for D001 waste that is intended to be treated using organic recovery (RORGS) or combustion (CMBST) technologies Identify UHC's by completing Sections I and IV of CHI Form LDR-1 Addendum and attach completed Addendum to this form. 3 = The waste is a characteristic (i e , D -code) or listed (i e , F-, K-, U-, or P -code) hazardous waste which is intended for export and treatment/disposal at a facility located outside the United States. LDR treatment standards do not apply to hazardous waste treated/disposed in a foreign country, and per USEPA guidance, the identification of UHC's (if applicable) is not required for hazardous waste that is intended to be exported. Note however that if the exported waste is subsequently returned for treatment/disposal in the United States, all applicable LDR regulations would apply and a revised LDR notification would be required 4 = The waste meets the definition of hazardous debris pursuant to 40 CFR 268.2(h) and is intended for treatment/ disposal in compliance with the alternate debris treatment technologies of 40 CFR 26845 In accordance with the requirements of 40 CFR 2687(a)(2) the contaminants subject to treatment (CSTT's) must be identified as part of this notification. Identify CSTT's by completing Section III and IV of the CHI Form LDR-1 Addendum and attach completed Addendum to this form These constituents are being treated to comply with 40 CFR 268 45 5 = The waste is a characteristic waste D003 Reactive Sulfide, Reactive Cyanide, or Unexploded Ordnance subcategory, a characteristic waste D012- 17 wastewater, or a listed (i e, F-, K-, U-, or P -code) hazardous waste. UHC's are NOT required to be identified 6 = The waste is a lab pack that is intended for incineration using the alternative lab pack treatment standard under 40 CFR 268 42(c). UHC's are NOT required to be identified, however, the generator must complete and attach the lab pack certification statement on CHI Form LDR-LP Note that In accordance with 40 CFR Part 268 Appendix IV, lab packs which contain waste codes D009, F019, K003, K004, K005, K006, K062, K071, K100, K106, P010, P011, P012, P076, P078, U134, and U151 are not eligible for alternative lab pack treatment standard `** NOTE: IF THE WASTE IS A SOIL CONTAMINATED WITH A LISTED OR CHARACTERISTIC WASTE AND THE GENERATOR WANTS TO USE THE ALTERNATE TREATMENT STANDARD FOR SOILS, CONTACT CORPORATE COMPLIANCE FOR THE APPROPRIATE LDR NOTIFICATION FORM. SECTION I. CHARACTERISTIC WASTES D001 THROUGH D043 COLUMN 1 COLUMN 2. COLUMN 3 LINE ITEM WASTE CODE / SUBCATEGORY WASTEWATER/ SEE MANIFEST NON -WASTEWATER [ ] D001 Ignitables, except High TOC subcategory [ ] WW [ ] Non -WW [ ] D001 High TOC Ignitable Liquids Subcategory [ ] Non -WW only (Greater than or equal to 10% TOC) [ ] D002 Corrosives [ ] WW [ 1 Non -WW [ ] D003 [ ] Reactive Sulfide, per 26123 (a)(5) [ ] WW [ ] Non -WW [ ] Reactive Cyanide, per 261.23(a)(5) [ ] WW [ ] Non -WW [ J Explosive, per 261 23(a)(6), (7) & (8) [ ] WW [ ] Non -WW [ ] Water Reactive, per 261 23(a)(2), (3) & (4) [ ] Non -WW only [ ] Other Reactive, per 261.23(a)(1) [ ] WW [ ] Non -WW [ ] Unexploded Ordnance, Emergency Response [ ] WW [ ] Non -WW [ ] D004 Arsenic [ ] WW [ ] Non -WW [ ] D005 Barium [ ] D006 [ ] Cadmium [ ] Cadmium Containing Batteries [ ] D007 Chromium (] D008 [ ] Lead [ ] Lead Acid Batteries [ ] WW [ ] Non -WW [ ] WW [ ] Non -WW [ ] Non -WW only [ J WW [ ] Non -WW [ 1 WW [ ] Non -WW [ ] Non -WW only CHI Form LDR-1, Page 1 of 3 COLUMN 4 HANDLING CODE 1 2 3 4 6 1A 3 6 1 2 3 4 6 1 3 4 5 6 1 3 4 5 6 1 2 3 4 6 1 2 3 4 6 1 2 3 4 6 1 3 4 5 6 1 3 4 5 6 1 3 4 5 6 1 2 3 4 6 2 3 6 1 2 3 4 6 1 2 3 4 6 2 3 6 [Effective 2/281001 CLEAN HARBORS ENVIRONMENTAL SERVICES, INC LAND DISPOSAL RESTRICTION FORM LDR-1 MANIFEST NO SECTION I. CHARACTERISTIC WASTES D001-43 (CONTINUED) COLUMN 1 COLUMN 2 COLUMN 3 COLUMN 4 LINE ITEM WASTE CODE / SUBCATEGORY WASTEWATER/ HANDLING CODE SEE MANIFEST NON -WASTEWATER [ ] D009 [ ] Low Mercury, less than 260 mg/kg Mercury [ ] WW [ ] Non -WW 1 2 3 4 [ ] High Mercury Organic Subcategory [ ] Non -WW only 2 3 4 (] High Mercury Inorganic Subcategory [ ] Non -WW only 2 3 4 [) D010 Selenium [ J WW [ ] Non -WW 1 2 3 4 6 [ ] D011 Silver [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D012 Endnn [ ] WW [ ] Non -WW 2 3 4 5 6 [ J D013 Lindane [ ] WW [ ] Non -WW 2 3 4 5 6 [ ] D014 Methoxychlor [ ] WW [ ] Non -WW 2 3 4 5 6 [ ] D015 Toxaphene [ ] WW [ ] Non -WW 2 3 4 5 6 [ ] D016 2,4-D [ J WW [ ] Non -WW 2 3 4 5 6 [ ] D017 2,4,5 -TP (Silvex) [ ] WW [ ] Non -WW 2 3 4 5 6 [ J D018 Benzene [] WW [ j Non -WW 1 2 3 4 6 [ ] D019 Carbon tetrachloride [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D020 Chlordane [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D021 Chlorobenzene [ ] WW [ ] Non -WW 1 2 3 4 6 [ J D022 Chloroform [] WW [ J Non -WW 1 2 3 4 6 [ ] D023 o -Cresol [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D024 m -Cresol [ ] WW [ ] Non -WW 1 2 3 4 6 [ j D025 p -Cresol [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D026 Cresol [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D027 1,4 -Dichlorobenzene [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D028 1,2-Dichloroethane [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D029 1,1-Dichloroethylene [ ] WW [ ] Non -WW 1 2 3 4 6 [ J D030 2,4-Dinitrotoluene [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D031 Heptachlor (and its epoxide) [ ] WW (] Non -WW 1 2 3 4 6 [ ] D032 Hexachlorobenzene [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D033 Hexachlorobutadiene [ ] WW [ ] Non -WW 1 2 3 4 6 [ J D034 Hexachloroethane [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D035 Methyl ethyl ketone [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D036 Nitrobenzene [ ] WW [ ] Non -WW 1 2 3 4 6 [ J D037 Pentachlorophenol [ ] WW [ ] Non -WW 1 2 3 4 6 (] D038 Pyridine [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D039 Tetrachloroethylene [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D040 Trichloroethylene [ ] WW [ j Non -WW 1 2 3 4 6 [ ] D041 2,4,5 -Trichlorophenol [ ] WW [ ] Non -WW 1 2 3 4 6 [ ] D042 2,4,6-Tnchlorophenol [ ] WW [ ] Non -WW 1 2 3 4 6 (] D043 Vinyl Chloride [ ] WW [ J Non -WW 1 2 3 4 6 SECTION II SPENT SOLVENT WASTES F001 THROUGH F005 COLUMN V COLUMN 2 COLUMN 3 COLUMN 4 LINE ITEM WASTE CODE / SUBCATEGORY WASTEWATER/ HANDLING CODE SEE MANIFEST NON -WASTEWATER [ J F001 [F002 [ ] F003 [ ] F004 [ ] F005 [ ] WW [Non -WW 3 4 (5 6 [ ] 1. ALL F001 -F005 [ ] 12 Cyclohexanone [ ] 25 Pyndine [ J 2. Acetone [ ] 13 o -Dichlorobenzene i` [ ] 26 Tetrachloroethylene [ ] 3. Benzene [ ] 14 2-Ethoxyethanol (F005) [ j 27 Toluene [ ] 4 n -Butyl alcohol only) [ ] 28. 1,1,1-Trichloro- [ ] 5 Carbon disulfide [ ] 15 Ethyl acetate ethane [ ] 6 Carbon tetrachloride [ ] 16 Ethyl benzene [ ] 29 1,1,2-Trichloro- [ ] 7 Chlorobenzene [ ] 17. Ethyl ether ethane [ ] 8 o -Cresol [ ] 18 Isobutyl alcohol [ ] 30. Trichloroethylene [ ] 9 m -Cresol (difficult to [ ] 19 Methanol [ ] 31 1,1,2-Tnchloro- distinguish from [ ] 20. Methylene chloride 1,2,2-trifluoroethane p -cresol) [ ] 21 Methyl ethyl ketone (] 32.Tnchloromonofluorc- [ ] 10 p -Cresol (difficult to [ j 22 Methyl isobutyl ketone methane distinguish from [ ] 23 Nitrobenzene [ ] 33 Xylene - mixed isomers m -cresol) [ ] 24 2-Nitropropane (F005 (sum of o-, m-, and [ ] 11 Cresol - mixed isomers only) p -xylene) (sum of o-, m- and p -cresol) CHI Form LDR-1, Page 2 of 3 [Effective 2/28/00] CLEAN HARBORS ENVIRONMENTAL SERVICES, INC LAND DISPOSAL RESTRICTION FORM LDR-1 SECTION III CALIFORNIA LIST WASTES COLUMN 1 COLUMN 2 LINE ITEM WASTE CODE / SUBCATEGORY SEE MANIFEST MANIFEST NO el -5-y6 a-,0-5- COLUMN -05 COLUMN 3 WASTEWATER/ NON -WASTEWATER Hazardous waste containing one or more of the following [ ] WW [ ] Non -WW California List constituents [ ] ALL CALIFORNIA LIST CONSTITUENTS [ J Liquids with nickel greater than or equal to 134 mgfl [ J Liquids with thallium greater than or equal to 130 mg/I [ ] Liquids with PCB's > or= 50 ppm [ ] Waste containing HOC's > or = 1,000 mg/kg COLUMN 4 HANDLING CODE 1 2 3 4 6 SECTION IV OTHER LISTED WASTES (F006-12. F019 -F028. F037-38, F039 K- U- AND P -CODES) COLUMN 1 COLUMN 2 COLUMN 3' COLUMN 4 LINE ITEM WASTE CODE / SUBCATEGORY WASTEWATER/ HANDLING CODE SEE MANIFEST NON -WASTEWATER [ ] WW [ ] Non -WW 3 4 5 6 [ ] WW [ ] Non -WW 3 4 5 6 [ ] WW [ ] Non -WW 3 4 5 6 [ ] WW [ ] Non -WW 3 4 5 6 [ ] WW [ ] Non -WW 3 4 5 6 [ ] CHECK HERE IF ADDITIONAL LISTED WASTE CODES ARE PRESENT. COMPLETE AND ATTACH LDR-1 CONTINUATION SHEET [ ] CHECK HERE IF WASTE CODE F039 (MULTISOURCE LEACHATE) IS PRESENT IDENTIFY F039 CONSTITUENTS BY COMPLETING SECTIONS II AND IV OF CHI FORM LDR-1 ADDENDUM AND ATTACH COMPLETED ADDENDUM TO THIS FORM. SECTION V. CONTACT NAME AND DATE On behalf of DSCA Petitioner S'te 000 7-7 /} Pint Name z�� Date 2-67 7 KEY TERMS/DEFINITIONS CLASS I SDWA SYSTEM means a Class I deep well facility regulated under the Safe Drinking Water Act (SDWA) CWA SYSTEM means a centralized wastewater treatment facility discharging under a Clean Water Act (CWA) permit For example, a CWA facility would treat organic or inorganic aqueous wastes and discharge the treated effluent to the local sewer system. Examples of CWA treatment systems owned and operated by Clean Harbors include the wastewater treatment operations at Baltimore (including the CES system), Bristol, Chicago, Cincinnati and Cleveland. CWA-EQUIVALENT SYSTEM means a "zero discharge system" that engages in "CWA-equivalent" treatment before land disposal Zero - discharge facilities treat hazardous wastes using "CWA-equivalent" treatment methods, but do not discharge the treatment effluent to a sewer or water body (e g., spray irrigation land farm). "CWA-equivalent" treatment methods means biological treatment for organics, alkaline chlorination, or ferrous sulfate precipitation for cyanide, precipitation/ sedimentation for metals, reduction of hexavalent chromium, or other treatment technology that can be demonstrated to perform equally or greater than these technologies. HIGH TOC IGNITABLE LIQUIDS SUBCATEGORY means an ignitable liquid hazardous waste (waste code D001) which contains greater than or equal to 10% total organic carbon (TOC) Pursuant to 40 CFR 268 40, such wastes must be treated using organic recovery (RORGS) or combustion (CMBST) technology. Examples of RORGS technologies include the CES unit at Clean Harbors of Baltimore Examples of CMBST technologies include hazardous waste fuel blending and subsequent reuse at a cement kiln, or destruction at a RCRA incinerator WASTEWATERS are wastes that contain less than 1% by weight total organic carbon (TOC) and less than 1% by weight total suspended solids (TSS). [See 40 CFR 268.2(f)] CHI Form LDR-1, Page 3 of 3 [Effective 2128/00] ATTACHMENT 2 SITE LOCATION MAP IT A l r ,h Wil• .�¢/ .^ 71 Bryan. N �I( M, `—_�+f — Oc i1 l l•4 ~� O� YVl ,.A 01 Air— fij Q� S 1 i E t �►St 1' �y_c n 4 1�N Th P�on 1., J s •:�� i £;� o :Ori anage 9 r B ` 741 '_•� bilMo/ ', f - �\o� � �1'�'. W, X10 `�\�1 •1 Q �'� z� thleh S P sx' Par 9 a • 3 / Park efk f v, .`:i, AVI APPROXIMATE N 0 2000 4000 SCALE IN FEET U.S.G.S. QUADRANGLE MAP CHARLOTTE EAST, NORTH CAROLINA (1991) QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) - E SITE LOCATION MAP PROJECT McCORKLE'S CLEANERS DSCA ID: DC600077 1437 SOUTH BOULEVARD CHARLOTTE MECKLENBURG COUNTY hart 2923 TryonSroina2re100 � hiekman Chazlotte, North Carolina 28211 Charlotte, 704-586-0007 (p) 704-586-0373 .r SMARTER ENVIRONMENTAL SOLUTIONS DATE: 6-15-2017 REVISION NO: 0 JOB NO: DSO -80 ATTACHMENT: 2 ATTACHMENT 3 SITE MAP LEGEND \ i / \ ♦ !\• ��' SOURCE PROPERTY BOUNDARY ♦`\ PROPERTY BOUNDARY SOURCE PROPERTY BUILDING BUILDING APARTMENTS TYPE II MONITORING WELL RESIDENCE RESIDENCE RESIDENCE RESIDENCE RESIDENCE RESIDENCE AWA RESIDENCE RESIDENCE *1WA RESIDENCE ex\ O RESIDENCE RES NOTES: 1. MONITORING WELLS SURVEYED IN AUGUST 2013, AND DECEMBER 2015 BY THE ISAACS GROUP. 8 APPROXIMATE \ 0 80 160 SCALE IN FEET SITE MAP ♦� PSE" McCORKLE'S CLEANERS `\ \ DSCA SITE: DC600077 1437 SOUTH BOULEVARD CHARLOTTE, MECKLENBURG COUNTY hart''` hickman 2923 South Tryon Street -Suite loo \ Charlotte, North Carolina 28203 \'\ �` i • 704586-0007(p) 704586-03730 SMARTER ENVIRONMENTAL SOLUT10N5 License # C-1269 / #C-245 Geolc y� iFDATE: 6-15-17 REVISION NO. 0 �'�JJOB N0. DSO -80 ATTACHMENT NO. 3 ATTACHMENT 4 GROUNDWATER GRADIENT MAP APARTMENTS ✓y :'FORMER MCCOI-ILE'S I i i \ f i'CLEANERS v� 0�J I ELIZABETH HOU MW -1 FLOWERS 60 A MBE E\ 2tPs '•♦ OFFICE W-4 ♦ ♦(720.13) ET NAIL \\.A B TOUE Q WESTPORT B & TAL MW 2 t/(715.25/ * 2tPs '•♦ OFFICE W-4 ♦ ♦(720.13) / 'MW -7 (703.48) ^ '�0 RESIDENCE e CE I or RESIDENCE O I• 'AO RESIDENCE ` RES RESIDENCE RESIDENCE WA (698.44) RESIDENCE RESIDENCE RESIDENCE ' \ \ \ LEGEND SOURCE PROPERTY BOUNDARY ------- PROPERTY BOUNDARY SOURCE PROPERTY BUILDING BUILDING TYPE II MONITORING WELL (711.15) GROUNDWATER ELEVATION (FT MSL) 700 �� GROUNDWATER ELEVATION CONTOUR (FT MSL) INFERRED GROUNDWATER FLOW DIRECTION NOTES 1. PERMANENT MONITORING WELLS GAUGED ON 4/24/17. 2. MONITORING WELLS SURVEYED IN AUGUST 2013 AND.DECEMBER 2015 BY THE ISAACS GROUP. a APPROXIMATE 0 80 160 SCALE IN FEET GROUNDWATER GRADIENT MAP SER McCORKLE'S CLEANERS DSCA SITE: DC600077 1437 SOUTH BOULEVARD CHARLOTTE, MECKLENBURG COUNTY hart 2121 South'l'ryon Street -Suite loll hiekman Charlotte, North Carolina 28203 704-586-0007(p) 704586-03730 SMAUER ENVIf00MAENTAL SOLUi1p05 License # C-1369 / #C-245 Geolc DATE: 6-15-17 REVISION NO. 0 JOB NO. DSO -80 ATTACHMENT NO. 4 V IOUS RETAIL r' r MW -3 t (713.32)'.v• r / 'MW -7 (703.48) ^ '�0 RESIDENCE e CE I or RESIDENCE O I• 'AO RESIDENCE ` RES RESIDENCE RESIDENCE WA (698.44) RESIDENCE RESIDENCE RESIDENCE ' \ \ \ LEGEND SOURCE PROPERTY BOUNDARY ------- PROPERTY BOUNDARY SOURCE PROPERTY BUILDING BUILDING TYPE II MONITORING WELL (711.15) GROUNDWATER ELEVATION (FT MSL) 700 �� GROUNDWATER ELEVATION CONTOUR (FT MSL) INFERRED GROUNDWATER FLOW DIRECTION NOTES 1. PERMANENT MONITORING WELLS GAUGED ON 4/24/17. 2. MONITORING WELLS SURVEYED IN AUGUST 2013 AND.DECEMBER 2015 BY THE ISAACS GROUP. a APPROXIMATE 0 80 160 SCALE IN FEET GROUNDWATER GRADIENT MAP SER McCORKLE'S CLEANERS DSCA SITE: DC600077 1437 SOUTH BOULEVARD CHARLOTTE, MECKLENBURG COUNTY hart 2121 South'l'ryon Street -Suite loll hiekman Charlotte, North Carolina 28203 704-586-0007(p) 704586-03730 SMAUER ENVIf00MAENTAL SOLUi1p05 License # C-1369 / #C-245 Geolc DATE: 6-15-17 REVISION NO. 0 JOB NO. DSO -80 ATTACHMENT NO. 4 ATTACHMENT 5 GROUNDWATER ISOCONCENTRATION MAPS APARTMENTS RMER MCCORKLE'S EANERS ,ELIZABETH HC FLOWERS 8 EVE` `CACHET NAIL BOUTIQUE ,\ WESTPORT BIG 8 TALL BENJAMIN MOORE (BASEMENT) ss 2 .001 OFFICE VARIOUS RETAIL 1 \ \ RESIDE 'MWb 0.0409 \x, \ RESIDENCE RESIDENCE RESIDENCE 7MW-7 0.00211 RESIDENCE RESIDENCE \ RESIDENCE / RESIDENCE RESIDENCE / / C .\ r'\ Z ✓ G� /f\� \ \ j i \ \ \ N' �' •' \ \ \ \ RES LEGEND SOURCE PROPERTY BOUNDARY ------- PROPERTY BOUNDARY SOURCE PROPERTY BUILDING ' BUILDING TYPE II MONITORING WELL 0.00211 PCE CONCENTRATION IN mg/L PCE ISOCONTOUR LINE IN mg/L —0.0007— (DASHED WHERE INFERRED) NOTES: 1. MONITORING WELLS SAMPLED ON 4/24/17. 2. MW -2D NOT USED IN CONTOURING a APPROXIMATE 0 80 160 immimmi SCALE IN FEET GROUNDWATER PCE ISOCONCENTRATION MAP R° `T McCORKLE'S CLEANERS DSCA SITE: DC600077 1437 SOUTH BOULEVARD CHARLOTTE, MECKLENBURG COUNTY • 7.92.3 South Tryon Street -Suite 100 hart � hickman Charlotte, North Carolina 28203 704-586-0007(p) 70+586-0373(0 SMARTER ENVIRONMENTAL SOLUTIONS license # C-1269 / #C-245 Geok DATE: 6-15-17 REVISION NO. 0 JOB NO. DSO -80 ATTACHMENT NO. 5A APARTMENTS :R MCCORKLE'S ERS VARIOUS RETAIL /r 00J I $ ELIZABETH HOUSE .�� MW -1 FLOWERS 10, -♦ / 10.,W-7 -\ ADAM &EVE` �e % \ `CACHET NAI BOUTIQUE WESTPORT BIG & TALL r BENJAMIN MOOR ` (BASEMENT) \`*W4 Q� w DO �G y�04' Z' �G j poi qv / RESIDENCE RESIOEtIFE RESIDENCE RESIDENCE RESIDENCE \ RESIDENCE RESIDENCE RESIDENCE RESIDENCE ®RESIDENCE O LEGEND SOURCE PROPERTY BOUNDARY ------- PROPERTY BOUNDARY SOURCE PROPERTY BUILDING BUILDING TYPE II MONITORING WELL TCE CONCENTRATION IN mg/L TCE ISOCONTOUR LINE IN mg/L (DASHED WHERE INFERRED) NOTES: 1. MONITORING WELLS SAMPLED ON 4/24/17. 2. MW -2D NOT USED IN CONTOURING 8 APPROXIMATE 0 80 160 SCALE IN FEET i \ GROUNDWATER TICE ISOCONCENTRATION MAP PFOJECT ` McCORKLE'S CLEANERS DSCA SITE: DC600077 O'� \ 1437 SOUTH BOULEVARD �� `•� CHARLOTTE, MECKLENBURG COUNTY �. \ ��� • 2923 South Tryon Street -Suite 100 hart hickman Chadotre, North Carolina 28203 \ / 704586-0007(p) 704586-0373(0 \,\ ••,� \\ SNWrtflt ENYNOl�YIENTAL gm- MONS License # C-1269 / #C-245 Geok ,i- DATE: 6-15-17 REVISION N0.0 JOB NO. DSO -80 ATTACHMENT NO. 5B APARTMENTS X f FORMER MCCORKLE'S /CLEANERS i eOJ I $ ELIZABETH HC Mw I 001 5 FLOWERS ,♦ ADAM & EVE` `CACHET NAIL BOUTIQU WWEESTPORT BIG & TALL BENJAMIN MOORE (BASEMENT) .per •\ tissue '•.�\ yGR < A \ \.<0.001 :l F I OFFICE VARIOUS RETAIL 0.001 \ RESIDENCE RESIDENCE RESIDENCE RESIDENCE RESIDENCE MW.6 0.150 RESIDENCE RESIDENCE RESIDENCE 1 N LEGEND SOURCE PROPERTY BOUNDARY PROPERTY BOUNDARY SOURCE PROPERTY BUILDING BUILDING -01 TYPE II MONITORING WELL 0.385 CIS-1,2-DCE CONCENTRATION IN mg/L -0.07 CIS-1,2-DCE ISOCONTOUR LINE IN mg/L (DASHED WHERE INFERRED) NOTES: 1. MONITORING WELLS SAMPLED ON 4124/17- 2 MW -2D NOT USED IN CONTOURING 9 APPROXIMATE 0 80 160 SCALE IN FEET GROUNDWATER CIS-1,2-DCE ISOCONCENTRATION MAP --T McCORKLE'S CLEANERS DSCA SITE: DC600077 1437 SOUTH BOULEVARD CHARLOTTE, MECKLENBURG COUNTY : 2923 South Tryon Street -Suite 1(0 hart hickman Chadotte,North Carolina28203 704586-0007(p) 704586-0373(1) SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geolc DATE: 6-15-17 REVISION NO. 0 JOB NO. DSO -80 ATTACHMENT NO. 5C ATTACHMENT 6 GROUNDWATER CONCENTRATION TREND GRAPHS 0.7 M. 0.5 J b,0 0.4 0.2 0.1 0 05/06/13 PCE Concentrations vs Time Monitoring Wells MW -2S and MW -3 McCorkle's Cleaners (DC6OOO77) 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 Date Note: Non -detect values are graphed as half the laboratory reporting limit. 03/06/17 09/22/17 —#E-- MW -2S MW -3 0.045 0.04 0.035 0.03 J ao E r 0.025 0 c 0.02 CU c 0 U 0.015 0.01 0.005 0 05/06/13 PCE Concentrations vs Time Monitoring Wells MW -21), MW -5, MW -6, MW -7, and MW -8 McCorkle's Cleaners (DC600077) 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 Date Note: Non -detect values are graphed as half the laboratory reporting limit. 09/22/17 MW -2D --*— M W-5 —A MW -6 —f— M W-8 0.0012 0.001 J dD E C O 0.0006 L V v 0.0004 0.0002 PCE Concentrations vs Time Monitoring Wells MWA and MW -4 McCorkle's Cleaners (DC600077) 0 05/06/13 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 Date Note: Non -detect values are graphed as half the laboratory reporting limit. --4 MW -1 BMW -4 09/22/17 ®. 0.7 Ma z, 0.5 0o E c 0 :_• 0.4 ED L c v c 0 0.3 0.2 0.1 0 05/06/13 TCE Concentrations vs Time Monitoring Wells MW -2S and MW -3 McCorkle's Cleaners (DC600077) 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 Date Note: Non -detect values are graphed as half the laboratory reporting limit. --f— MW -2S 09/22/17 I►Il�i�� 0.02 0.018 0.016 0.014 J 0.012 c 0 +'r 0.01 L f+ C c 0.008 0 v 0.006 0.004 0.002 0 05/06/13 TCE Concentrations vs Time Monitoring Wells MW -213, MW -4, MW -5, MW -6, MW -7, and MW -8 McCorkle's Cleaners (DC600077) 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 Date Note: Non -detect values are graphed as half the laboratory reporting limit. 03/06/17 09/22/17 —MW -2D —0-- MW -4 —4—MW-5 f MW -6 —0 MW -7 —*— M W -8 cis-1,2-DCE Concentrations vs Time Monitoring Wells MW -2S McCorkle's Cleaners (DC6OOO77) 14 12 10 J bb E p 8 ... C O v C v 6 v C O U 4 2 0 05/06/13 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 09/22/17 Date 1.4 1.2 1 J ba 0.8 c 0 L C Cu 0.6 c 0 u 0.4 0.2 cis-1,2-DCE Concentrations vs Time Monitoring Wells MW -213 and MW -3 McCorkle's Cleaners (DC600077) 0 05/06/13 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 09/22/17 Date MW -2D MW -3 0.16 0.14 0.1 an E c 0 'Z; 0.08 M .r c v v C 0 0.06 0.04 cis-1,2-DCE Concentrations vs Time Monitoring Wells MW -4, MW -5, MW -6, and MW -8 McCorkle's Cleaners (DC600077) 0.02 ♦''�.1 0 05/06/13 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 Date Note: Non -detect values are graphed as half the laboratory reporting limit. 09/22/17 -*-MW-4 —* MW -5 —& MW -6 --41— M W-8 0.4 0.35 0.3 0.25 na E C 0 +� 0.2 to L c v U C UO 0.15 0.1 0.05 trans-1,2-13CE Concentrations vs Time Monitoring Well MW -2S McCorkle's Cleaners (DC600077) 0 _ 05/06/13 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 09/22/17 Date MW -2S 0.012 i 0.01 J C� C C 4Z 0.006 c v U 0.004 0.002 0 05/06/13 trans-1,2-DCE Concentrations vs Time Monitoring Wells MW -21), MW -3, and MW -6 McCorkle's Cleaners (DC600077) 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 Date Note: Non -detect values are graphed as half the laboratory reporting limit. MW -3 — A MW -6 09/22/17 0.12 0.1 0.04 0.02 0 05/06/13 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 09/22/17 Date Vinyl Chloride Concentrations vs Time Monitoring Well MW -2S McCorkle's Cleaners (DC6OOO77) Note: Non -detect values are graphed as half the laboratory reporting limit. - N MW -2S Vinyl Chloride Concentrations vs Time Monitoring Wells MW -21) and MW -3 McCorkle's Cleaners (DC600077) 0.005 ,1X1 / '. J Op E c 0 0.003 L C V C 0 U 0.002 0.001 0 05/06/13 11/22/13 06/10/14 12/27/14 07/15/15 01/31/16 08/18/16 03/06/17 Date Note: Non -detect values are graphed as half the laboratory reporting limit. 09/22/17 MW -2D MW -3 ATTACHMENT 7 LABORATORY ANALYTICAL REPORT TestAmerica THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel: (615)726-0177 TestAmerica Job ID: 490-127126-1 TestAmerica Sample Delivery Group: DSO -80 Client Project/Site: McCorkles Cleaners For: Hart & Hickman, PC 2923 S Tryon Street Suite 100 Charlotte, North Carolina 28203 Attn: Shane Sisco Authorized for release by. - 413012017 y.4/30/2017 8:32:24 AM Ken Hayes, Project Manager II (615)301-5035 ken. hayes@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client Hart & Hickman, PC Project/Site McCorkles Cleaners Table of Contents TestAmenca Job ID 490-127126-1 SDG DSO -80 Cover Page ............................................. 1 Table of Contents .................................. ...... 2 Sample Summary .......................... .... ........ 3 Case Narrative ............... ...... ................... 4 Definitions ............................................... 5 Client Sample Results ........... .......... ....... ...... 6 QC Sample Results ....................................... 24 QC Association ..... ................................... 39 Chronicle ................................................ 40 Method Summary ....................... ....... .. .... 42 Certification Summary .................. ................... 43 Chain of Custody ......................................... 44 Receipt Checklists ......................................... 46 TestAmenca Nashville Page 2 of 46 4/30/2017 Sample Summary Client Hart & Hickman, PC TestAmerica Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Lab Sample ID Client Sample ID Matrix Collected Received 490-127126-1 MW -1 Water 04/24/17 08 55 04/26/17 09 20 490-127126-2 MW -2S Water 04/24/17 11 00 04/26/17 09 20 490-127126-3 MW -21D Water 04/24/17 10 25 04/26/17 09 20 490-127126-4 MW -3 Water 04/24/17 09 45 04/26/17 09 20 490-127126-5 MW -4 Water 04/24/17 12 25 04/26/17 09 20 490-127126-6 MW -5 Water 04/24/17 14 45 04/26/17 09 20 490-127126-7 MW -6 Water 04/24/17 15 30 04/26/17 09 20 490-127126-8 MW -7 Water 04/24/17 16 30 04/26/17 09 20 490-127126-9 MW -8 Water 04/24/17 17 20 04/26/17 09 20 TestAmerica Nashville Page 3 of 46 4/30/2017 Case Narrative Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Job ID: 490-127126-1 Laboratory: TestAmerica Nashville Narrative f 4 Job Narrative L --:—j 490-127126-1 Comments No additional comments Receipt The samples were received on 4/26/2017 9 20 AM, the samples arrived in good condition, properly preserved and, where required, on ice The temperature of the cooler at receipt was 1 3° C GC/MS VOA No analytical or quality issues were noted, other than those described in the Definitions/Glossary page VOA Prep No analytical or quality issues were noted, other than those described in the Definitions/Glossary page TestAmenca Nashville Page 4 of 46 4/30/2017 Definitions/Glossary Client Hart & Hickman, PC Project/Site McCorkles Cleaners Qualifiers TestAmenca Job ID 490-127126-1 SDG DSO -80 GC/MS VOA Qualifier Qualifier Description 4 MS, MSD The analyte present in the original sample is greater than 4 times the matrix spike concentration, therefore, control limits are not applicable F2 MS/MSD RPD exceeds control limits Glossa Abbreviation a %R CFL CNF DER Dil Fac DL, RA, RE, IN DLC MDA EDL MDC MDL ML NC ND PQL QC RER RL RPD TEF TEQ These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis Percent Recovery Contains Free Liquid Contains no Free Liquid Duplicate error ratio (normalized absolute difference) Dilution Factor Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample Decision level concentration Minimum detectable activity Estimated Detection Limit Minimum detectable concentration Method Detection Limit Minimum Level (Dioxin) Not Calculated Not detected at the reporting limit (or MDL or EDL if shown) Practical Quantitation Limit Quality Control Relative error ratio Reporting Limit or Requested Limit (Radiochemistry) Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin) Toxicity Equivalent Quotient (Dioxin) TestAmenca Nashville Page 5 of 46 4/30/2017 TestAmenca Nashville Page 6 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC TestAmenca Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Client Sample ID: MW -1 Lab Sample ID: 490-127126-1 Date Collected: 04/24/17 08:55 Matrix: Water Date Received: 04/26/17 09:20 Method: 82608 - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed DII Fac Acetone ND 250 ug/L 04/28/17 14 14 1 Benzene ND 100 ug/L 04/28/17 14 14 1 • Bromobenzene ND 100 ug/L 04/28/17 14 14 1 Bromochloromethane ND 100 ug/L 04/28/17 14 14 1 Bromodichloromethane ND 100 ug/L 04/28/17 14 14 1 Bromoform ND 100 ug/L 04/28/171414 1 Bromomethane ND 100 ug/L 04/28/17 14 14 1 2-Butanone (MEK) ND 500 ug/L 04/28/17 14 14 1 Carbon disulfide ND 1 00 ug/L 04/28/17 14 14 1 Carbon tetrachloride ND 1 00 ug/L 04/28/17 14 14 1 Chlorobenzene ND 100 ug/L 04/28/17 14 14 1 Chlorodibromomethane ND 100 ug/L 04/28/17 14 14 1 Chloroethane ND 100 ug/L 04/28/171414 1 Chloroform ND 100 ug/L 04/28/17 14 14 1 Chloromethane ND 100 ug/L 04/28/17 14 14 1 2-Chlorotoluene ND 100 ug/L 04/28/17 14 14 1 4-Chlorotoluene ND 100 ug/L 04/28/17 14 14 1 as-1,2-Dichloroethene ND 100 ug/L 04/28/17 14 14 1 as-1,3-Dlchloropropene ND 100 ug/L 04/28/17 14 14 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/28/17 14 14 1 1,2-Dibromoethane (EDB) ND 1 00 ug/L 04/28/17 14 14 1 Dibromomethane ND 100 ug/L 04/28/171414 1 1,2 -Dichlorobenzene ND 100 ug/L 04/28/17 14 14 1 1,3 -Dichlorobenzene ND 100 ug/L 04/28/17 14 14 1 1,4 -Dichlorobenzene ND 100 ug/L 04/28/17 14 14 1 Dichlorodifluoromethane ND 100 ug/L 04/28/17 14 14 1 1,1-Dichloroethane ND 100 ug/L 04/28/17 14 14 1 1,2-Dichloroethane ND 100 ug/L 04/28/17 14 14 1 1,1-Dichloroethene ND 100 ug/L 04/28/17 14 14 1 1,2-Dichloroethene, Total ND 1 00 ug/L 04/28/17 14 14 1 1,2-Dichloropropane ND 100 ug/L 04/28/17 14 14 1 1,3-Dichloropropane ND 100 ug/L 04/28/17 14 14 1 2,2-Dichloropropane ND 100 ug/L 04/28/17 14 14 1 1,1-Dichloropropene ND 100 ug/L 04/28/17 14 14 1 Dnsopropyl ether ND 200 ug/L 04/28/17 14 14 1 Ethylbenzene ND 100 ug/L 04/28/17 14 14 1 Hexachlorobutadiene ND 200 ug/L 04/28/17 14 14 1 2-Hexanone ND 100 ug/L 04/28/17 14 14 1 Isopropylbenzene ND 100 ug/L 04/28/17 14 14 1 Methylene Chloride ND 500 ug/L 04/28/17 14 14 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/28/17 14 14 1 Methyl tert-butyl ether ND 1 00 ug/L 04/28/17 14 14 1 Naphthalene ND 500 ug/L 04/28/17 14 14 1 n-Butylbenzene ND 100 ug/L 04/28/17 14 14 1 N-Propylbenzene ND 100 ug/L 04/28/17 14 14 1 p-Isopropyltoluene ND 100 ug/L 04/28/17 14 14 1 sec-Butylbenzene ND 100 ug/L 04/28/17 14 14 1 Styrene ND 100 ug/L 04/28/17 14 14 1 tert-Butyl benzene ND 100 ug/L 04/28/17 14 14 1 TestAmenca Nashville Page 6 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -1 Lab Sample ID: 490-127126-1 Date Collected: 04/24/17 08:55 Matrix: Water Date Received: 04/26/17 09:20 Method: 82606 - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane ND ND 100 100 ug/L ug/L 04/28/171414 04/28/17 14 14 1 1 Tetrachloroethene ND 100 ug/L 04/28/17 14 14 1 Toluene ND 100 ug/L 04/28/17 14 14 1 trans-1,2-Dichloroethene ND 100 ug/L 04/28/17 14 14 1 trans-1,3-Dichloropropene ND 100 ug/L 04/28/17 14 14 1 1,2,3-Tnchlorobenzene ND 100 ug/L 04/28/17 14 14 1 1,2,4-Tnchlorobenzene ND 100 ug/L 04/28/17 14 14 1 1,1,1 -Trichloroethane ND 100 ug/L 04/28/17 14 14 1 1,1,2 -Trichloroethane ND 100 ug/L 04/28/17 14 14 1 1,4 -Dioxane ND 200 ug/L 04/28/17 14 14 1 Trichloroethene ND 100 ug/L 04/28/17 14 14 1 Trichlorofluoromethane ND 100 ug/L 04/28/17 14 14 1 1,2,3-Tnchloropropane ND 100 ug/L 04/28/17 14 14 1 1,2,4 -Tri methyl benzene ND 100 ug/L 04/28/17 14 14 1 1,3,5 -Tri methyl benzene ND 100 ug/L 04/28/17 14 14 1 Vinyl chloride ND 1 00 ug/L 04/28/17 14 14 1 Xylenes, Total ND 300 ug/L 04/28/17 14 14 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 95 70-130 04/28/17 14 14 1 Dibromofluoromethane (Surr) 94 70-130 04/28/17 14 14 1 1,2-Dichloroethane-d4 (Surr) 98 70-130 04/28/17 14 14 1 Toluene -d8 (Surr) 103 70-130 04/28/17 14 14 1 TestAmenca Nashville Page 7 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -2S Lab Sample ID: 490-127126-2 Date Collected: 04/24/17 11:00 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac Acetone ND 250 ug/L 04/27/17 14 40 1 Benzene ND 1 00 ug/L 04/27/17 14 40 1 • Bromobenzene ND 1 00 ug/L 04/27/17 14 40 1 Bromochloromethane ND 1 00 ug/L 04/27/17 14 40 1 Bromodichloromethane ND 1 00 ug/L 04/27/17 14 40 1 Bromoform ND 1 00 ug/L 04/27/17 14 40 1 Bromomethane ND 1 00 ug/L 04/27/17 14 40 1 2-Butanone (MEK) 1350 500 ug/L 04/27/17 14 40 1 Carbon disulfide ND 1 00 ug/L 04/27/17 14 40 1 Carbon tetrachloride ND 1 00 ug/L 04/27/17 14 40 1 Chlorobenzene ND 1 00 ug/L 04/27/17 14 40 1 Chlorodibromomethane ND 1 00 ug/L 04/27/17 14 40 1 Chloroethane ND 1 00 ug/L 04/27/17 14 40 1 Chloroform ND 1 00 ug/L 04/27/17 14 40 1 Chloromethane ND 1 00 ug/L 04/27/17 14 40 1 2-Chlorotoluene ND 1 00 ug/L 04/27/17 14 40 1 4-Chlorotoluene ND 1 00 ug/L 04/27/17 14 40 1 cis-1,2-Dichloroethene 10300 500 ug/L 04/28/17 18 43 50 cis-1,3-Dichloropropene ND 100 ug/L 04/27/17 14 40 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/27/17 14 40 1 1,2-Dibromoethane(EDB) ND 100 ug/L 04/27/17 14 40 1 Dibromomethane ND 1 00 ug/L 04/27/17 14 40 1 1,2 -Dichlorobenzene ND 100 ug/L 04/27/17 14 40 1 1,3 -Dichlorobenzene ND 100 ug/L 04/27/17 14 40 1 1,4 -Dichlorobenzene ND 100 ug/L 04/27/17 14 40 1 Dichlorodifluoromethane ND 1 00 ug/L 04/27/17 14 40 1 1,1-Dichloroethane 264 1 00 ug/L 04/27/17 14 40 1 1,2-Dichloroethane ND 100 ug/L 04/27/17 14 40 1 1,1-Dichloroethene 209 1 00 ug/L 04/27/17 14 40 1 1,2-Dichloroethene, Total 2240 1 00 ug/L 04/27/17 14 40 1 1,2-Dichloropropane ND 100 ug/L 04/27/17 14 40 1 1,3-Dichloropropane ND 100 ug/L 04/27/17 14 40 1 2,2-Dichloropropane ND 1 00 ug/L 04/27/17 14 40 1 1,1-Dichloropropene ND 100 ug/L 04/27/17 14 40 1 Diisopropyl ether ND 2 00 ug/L 04/27/17 14 40 1 Ethylbenzene ND 1 00 ug/L 04/27/17 14 40 1 Hexachlorobutadiene ND 2 00 ug/L 04/27/17 14 40 1 2-Hexanone ND 100 ug/L 04/27/17 14 40 1 Isopropylbenzene 149 1 00 ug/L 04/27/17 14 40 1 Methylene Chloride ND 500 ug/L 04/27/17 14 40 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/27/17 14 40 1 Methyl tert-butyl ether ND 1 00 ug/L 04/27/17 14 40 1 Naphthalene ND 500 ug/L 04/27/17 14 40 1 n-Butylbenzene 595 1 00 ug/L 04/27/17 14 40 1 N-Propylbenzene 195 1 00 ug/L 04/27/17 14 40 1 p-Isopropyltoluene ND 1 00 ug/L 04/27/17 14 40 1 sec-Butylbenzene 177 1 00 ug/L 04/27/17 14 40 1 Styrene ND 1 00 ug/L 04/27/17 14 40 1 tert-Butylbenzene 433 1 00 ug/L 04/27/17 14 40 1 TestAmerica Nashville Page 8 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -2S Lab Sample ID: 490-127126-2 Date Collected: 04/24/17 11:00 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane ND ND 100 100 ug/L ug/L 04/27/17 14 40 04/27/17 14 40 1 1 Tetrachloroethene ND 1 00 ug/L 04/27/17 14 40 1 Toluene ND 1 00 ug/L 04/27/17 14 40 1 trans-1,2-Dichloroethene 200 1 00 ug/L 04/27/17 14 40 1 trans-1,3-Dichloropropene ND 100 ug/L 04/27/17 14 40 1 1,2,3-Tnchlorobenzene ND 100 ug/L 04/27/17 14 40 1 1,2,4-Tnchlorobenzene ND 1 00 ug/L 04/27/17 14 40 1 1,1,1 -Trichloroethane ND 100 ug/L 04/27/17 14 40 1 1,1,2 -Trichloroethane ND 100 ug/L 04/27/17 14 40 1 1,4 -Dioxane ND 200 ug/L 04/27/17 14 40 1 Trichloroethene ND 1 00 ug/L 04/27/17 14 40 1 Trichlorofluoromethane ND 1 00 ug/L 04/27/17 14 40 1 1,2,3-Trichloropropane ND 100 ug/L 04/27/17 14 40 1 1,2,4-Tnmethylbenzene 313 100 ug/L 04/27/17 14 40 1 1,3,5-Tnmethylbenzene ND 100 ug/L 04/27/17 14 40 1 Vinyl chloride 152 1 00 ug/L 04/27/17 14 40 1 Xylenes, Total 333 300 ug/L 04/27/17 14 40 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 110 70-130 04/27/17 14 40 1 4-Bromofluorobenzene (Surf) 97 70-130 04/28/17 18 43 50 Dlbromofluoromethane (Surr) 105 70-130 04/27/17 14 40 1 Dibromofluoromethane (Surr) 92 70-130 04128/17 18 43 50 1,2-Dichloroethane-d4 (Surr) 106 70-130 04/27/17 14 40 1 1,2-Dichloroethane-d4 (Surr) 100 70-130 0428/17 18 43 50 Toluene -d8 (Surr) 97 70-130 0427/17 14 40 1 Toluene -d8 (Surr) 107 70-130 0428/17 18 43 50 TestAmenca Nashville Page 9 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerica Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -2131 Lab Sample ID: 490-127126-3 Date Collected: 04/24/17 10:25 Matrix: Water Date Received: 04/26/17 09:20 Method. 82608 - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetone ND 250 ug/L 04/28/17 14 38 1 Benzene ND 1 00 ug/L 04/28/17 14 38 1 • Bromobenzene ND 1 00 ug/L 04/28/17 14 38 1 Bromochloromethane ND 1 00 ug/L 04/28/17 14 38 1 Bromodichloromethane ND 1 00 ug/L 04/28/17 14 38 1 Bromoform ND 1 00 ug/L 04/28/17 14 38 1 Bromomethane ND 1 00 ug/L 04/28/17 14 38 1 2-Butanone (MEK) ND 500 ug/L 04/28/17 14 38 1 Carbon disulfide ND 1 00 ug/L 04/28/17 14 38 1 Carbon tetrachloride ND 1 00 ug/L 04/28/17 14 38 1 Chlorobenzene ND 1 00 ug/L 04/28/17 14 38 1 Chlorodibromomethane ND 1 00 ug/L 04/28/17 14 38 1 Chloroethane ND 1 00 ug/L 04/28/17 14 38 1 Chloroform 244 1 00 ug/L 04/28/17 14 38 1 Chloromethane ND 1 00 ug/L 04/28/17 14 38 1 2-Chlorotoluene ND 1 00 ug/L 04/28/17 14 38 1 4-Chlorotoluene ND 1 00 ug/L 04/28/17 14 38 1 cis-1,2-Dichloroethene 193 1 00 ug/L 04/28/17 14 38 1 cis- 1,3-Dichloropropene ND 1 00 ug/L 04/28/17 14 38 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/28/17 14 38 1 1,2-Dibromoethane (EDB) ND 1 00 ug/L 04/28/17 14 38 1 Dibromomethane ND 1 00 ug/L 04/28/17 14 38 1 1,2 -Dichlorobenzene ND 1 00 ug/L 04/28/17 14 38 1 1,3 -Dichlorobenzene ND 1 00 ug/L 04/28/17 14 38 1 1,4 -Dichlorobenzene ND 1 00 ug/L 04/28/17 14 38 1 Dichlorodifluoromethane ND 1 00 ug/L 04/28/17 14 38 1 1,1-Dichloroethane ND 100 ug/L 04/28/17 14 38 1 1,2-Dichloroethane ND 100 ug/L 04/28/17 14 38 1 1,1-Dichloroethene ND 100 ug/L 04/28/17 14 38 1 1,2-Dichloroethene, Total 196 1 00 ug/L 04/28/17 14 38 1 1,2-Dichloropropane ND 100 ug/L 04/28/17 14 38 1 1,3-Dichloropropane ND 100 ug/L 04/28/17 14 38 1 2,2-Dichloropropane ND 1 00 ug/L 04/28/17 14 38 1 1,1-Dichloropropene ND 1 00 ug/L 04/28/17 14 38 1 Diisopropyl ether ND 2 00 ug/L 04/28/17 14 38 1 Ethylbenzene ND 1 00 ug/L 04/28/17 14 38 1 Hexachlorobutadiene ND 200 ug/L 04/28/17 14 38 1 2-Hexanone ND 100 ug/L 04/28/17 14 38 1 Isopropyl benzene ND 1 00 ug/L 04/28/17 14 38 1 Methylene Chloride ND 500 ug/L 04/28/17 14 38 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/28/17 14 38 1 Methyl tert-butyl ether ND 1 00 ug/L 04/28/17 14 38 1 Naphthalene ND 500 ug/L 04/28/17 14 38 1 n-Butylbenzene ND 1 00 ug/L 04/28/17 14 38 1 N-Propylbenzene ND 1 00 ug/L 04/28/17 14 38 1 p-Isopropyltoluene ND 1 00 ug/L 04/28/17 14 38 1 sec-Butylbenzene ND 1 00 ug/L 04/28/17 14 38 1 Styrene ND 1 00 ug/L 04/28/17 14 38 1 tert-Butylbenzene ND 1 00 ug/L 04/28/17 14 38 1 TestAmenca Nashville Page 10 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerlca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -2D Lab Sample ID: 490-127126-3 Date Collected: 04/24/17 10:25 Matrix: Water Date Received: 04/26/17 09:20 Method: 82606 - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane ND ND 100 100 ug/L ug/L 04/28/17 14 38 04/28/17 14 38 1 1 Tetrachloroethene 785 1 00 ug/L 04/28/17 14 38 1 Toluene ND 1 00 ug/L 04/28/17 14 38 1 trans-1,2-Dichloroethene 292 1 00 ug/L 04/28/17 14 38 1 trans-1,3-Dichloropropene ND 100 ug/L 04/28/17 14 38 1 1,2,3-Trichlorobenzene ND 1 00 ug/L 04/28/17 14 38 1 1,2,4-Tnchlorobenzene ND 1 00 ug/L 04/28/17 14 38 1 1,1,1 -Trichloroethane ND 100 ug/L 04/28/17 14 38 1 1,1,2-Tnchloroethane ND 100 ug/L 04/28/171438 1 1,4 -Dioxane ND 200 ug/L 04/28/17 14 38 1 Trichloroethene 2 08 1 00 ug/L 04/28/17 14 38 1 Trichlorofluoromethane ND 1 00 ug/L 04/28/17 14 38 1 1,2,3-Trichloropropane ND 100 ug/L 04/28/17 14 38 1 1,2,4 -Tri methyl benzene ND 1 00 ug/L 04/28/17 14 38 1 1,3,5 -Tri methyl benzene ND 1 00 ug/L 04/28/17 14 38 1 Vinyl chloride ND 1 00 ug/L 04/28/17 14 38 1 Xylenes, Total ND 300 ug/L 04/28/17 14 38 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Suri) 95 70-130 04/28/17 14 38 1 Dlbromofluoromethane (Surr) 93 70-130 04/28/17 14 38 1 1,2-Dichloroethane-d4 (Surr) 98 70-130 04/28/17 14 38 1 Toluene -d8 (Surr) 105 70-130 0428/17 14 38 1 TestAmerlca Nashville Page 11 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -3 Lab Sample ID: 490-127126-4 Date Collected: 04/24/17 09:45 Matrix: plater Date Received: 04/26/17 09:20 Method: 82608 - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac Acetone ND 250 ug/L 04/27/17 15 06 1 Benzene ND 1 00 ug/L 04/27/17 15 06 1 • Bromobenzene ND 1 00 ug/L 04/27/17 15 06 1 Bromochloromethane ND 1 00 ug/L 04/27/17 15 06 1 Bromodichloromethane ND 1 00 ug/L 04/27/17 15 06 1 Bromoform ND 1 00 ug/L 04/27/17 15 06 1 Bromomethane ND 1 00 ug/L 04/27/17 15 06 1 2-Butanone (MEK) ND 500 ug/L 04/27/17 15 06 1 Carbon disulfide ND 1 00 ug/L 04/27/17 15 06 1 Carbon tetrachlonde ND 1 00 ug/L 04/27/17 15 06 1 Chlorobenzene ND 1 00 ug/L 04/27/17 15 06 1 Chlorodibromomethane ND 1 00 ug/L 04/27/17 15 06 1 Chloroethane ND 1 00 ug/L 04/27/17 15 06 1 Chloroform ND 1 00 ug/L 04/27/17 15 06 1 Chloromethane ND 1 00 ug/L 04/27/17 15 06 1 2-Chlorotoluene ND 1 00 ug/L 04/27/17 15 06 1 4-Chlorotoluene ND 1 00 ug/L 04/27/17 15 06 1 cis-1,2-Dichloroethene 385 1 00 ug/L 04/28/17 15 03 1 cis-1,3-Dichloropropene ND 100 ug/L 04/27/17 15 06 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/27/17 15 06 1 1,2-Dibromoethane (EDB) ND 1 00 ug/L 04/27/17 15 06 1 Dibromomethane ND 1 00 ug/L 04/27/17 15 06 1 1,2 -Dichlorobenzene ND 100 ug/L 04/27/17 15 06 1 1,3 -Dichlorobenzene ND 1 00 ug/L 04/27/17 15 06 1 1,4 -Dichlorobenzene ND 1 00 ug/L 04/27/17 15 06 1 Dichlorodifluoromethane ND 1 00 ug/L 04/27/17 15 06 1 1,1-Dichloroethane 270 1 00 ug/L 04/27/17 15 06 1 1,2-Dichloroethane ND 1 00 ug/L 04/27/17 15 06 1 1,1-Dichloroethene 1 97 1 00 ug/L 04/27/17 15 06 1 1,2-Dichloroethene, Total 326 1 00 ug/L 04/27/17 15 06 1 1,2-Dichloropropane ND 1 00 ug/L 04/27/17 15 06 1 1,3-Dichloropropane ND 1 00 ug/L 04/27/17 15 06 1 2,2-Dichloropropane ND 1 00 ug/L 04/27/17 15 06 1 1,1-Dichloropropene ND 1 00 ug/L 04/27/17 15 06 1 Dusopropyl ether ND 200 ug/L 04/27/17 15 06 1 Ethylbenzene ND 1 00 ug/L 04/27/17 15 06 1 Hexachlorobutadiene ND 2 00 ug/L 04/27/17 15 06 1 2-Hexanone ND 100 ug/L 04/27/17 15 06 1 Isopropylbenzene ND 1 00 ug/L 04/27/17 15 06 1 Methylene Chloride ND 500 ug/L 04/27/17 15 06 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/27/17 15 06 1 Methyl tert-butyl ether ND 1 00 ug/L 04/27/17 15 06 1 Naphthalene ND 500 ug/L 04/27/17 15 06 1 n-Butylbenzene ND 1 00 ug/L 04/27/17 15 06 1 N-Propylbenzene ND 1 00 ug/L 04/27/17 15 06 1 p-Isopropyltoluene ND 1 00 ug/L 04/27/17 15 06 1 sec-Butylbenzene ND 1 00 ug/L 04/27/17 15 06 1 Styrene ND 1 00 ug/L 04/27/17 15 06 1 tert-Butylbenzene ND 1 00 ug/L 04/27/17 15 06 1 TestAmenca Nashville Page 12 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerica Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -3 Lab Sample ID: 490-127126-4 Date Collected: 04/24/17 09:45 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane ND ND 1 00 1 00 ug/L ug/L 04/27/17 15 06 04/27/17 15 06 1 1 • Tetrachloroethene 113 1 00 ug/L 04/27/17 15 06 1 Toluene ND 1 00 ug/L 04/27/17 15 06 1 trans-1,2-Dichloroethene 474 1 00 ug/L 04/27/17 15 06 1 trans-1,3-Dichloropropene ND 1 00 ug/L 04/27/17 15 06 1 1,2,3 -Tri ch lorobenzene ND 1 00 ug/L 04/27/17 15 06 1 1,2,4-Trichlorobenzene ND 1 00 ug/L 04/27/17 15 06 1 1,1,1 -Trichloroethane ND 100 ug/L 04/27/17 15 06 1 1,1,2 -Trichloroethane ND 100 ug/L 04/27/17 15 06 1 1,4 -Dioxane ND 200 ug/L 04/27/17 15 06 1 Trichloroethene 50 7 1 00 ug/L 04/27/17 15 06 1 Trichlorofluoromethane ND 1 00 ug/L 04/27/17 15 06 1 1,2,3-Tnchloropropane ND 1 00 ug/L 04/27/17 15 06 1 1,2,4-Tnmethylbenzene ND 100 ug/L 04/27117 15 06 1 1,3,5 -Tri methyl benzene ND 100 ug/L 04/27/17 15 06 1 Vinyl chloride ND 1 00 ug/L 04/27/17 15 06 1 Xylenes, Total ND 300 ug/L 04/27/17 15 06 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Sun) 99 70-130 04/27/17 15 06 1 4-Bromofluorobenzene (Sun) 95 70-130 04/28/17 15 03 1 Dibromofluoromethane (Sun) 99 70-130 04127/17 15 06 1 Dibromofluoromethane (Sun) 94 70-130 04128/17 15 03 1 1,2-Dichloroethane-d4 (Surr) 101 70-130 04127/17 15 06 1 1,2-Dichloroethane-d4 (Surr) 95 70-130 04128/17 15 03 1 Toluene -d8 (Surr) 101 70-130 04127/17 15 06 1 Toluene -d8 (Surr) 105 70-130 04128/17 15 03 1 TestAmerica Nashville Page 13 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -4 Lab Sample ID: 490-127126-5 Date Collected: 04/24/17 12:25 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac Acetone ND 250 ug/L 04/28/17 15 27 1 Benzene ND 1 00 ug/L 04/28/17 15 27 1 Bromobenzene ND 1 00 ug/L 04/28/17 15 27 1 Bromochloromethane ND 1 00 ug/L 04/28/17 15 27 1 Bromodichloromethane ND 1 00 ug/L 04/28/17 15 27 1 Bromoform ND 1 00 ug/L 04/28/17 15 27 1 Bromomethane ND 1 00 ug/L 04/28/17 15 27 1 2-Butanone (MEK) ND 500 ug/L 04/28/17 15 27 1 Carbon disulfide ND 1 00 ug/L 04/28/17 15 27 1 Carbon tetrachloride ND 1 00 ug/L 04/28/17 15 27 1 Chlorobenzene ND 1 00 ug/L 04/28/17 15 27 1 Chlorodibromomethane ND 1 00 ug/L 04/28/17 15 27 1 Chloroethane ND 1 00 ug/L 04/28/17 15 27 1 Chloroform ND 1 00 ug/L 04/28/17 15 27 1 Chloromethane ND 1 00 ug/L 04/28/17 15 27 1 2-Chlorotoluene ND 1 00 ug/L 04/28/17 15 27 1 4-Chlorotoluene ND 1 00 ug/L 04/28/17 15 27 1 cis-1,2-Dichloroethene ND 100 ug/L 04/28/17 15 27 1 as-1,3-Dichloropropene ND 100 ug/L 04/28/17 15 27 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/28/17 15 27 1 1,2-Dibromoethane(EDB) ND 100 ug/L 04/28/17 15 27 1 Dibromomethane ND 1 00 ug/L 04/28/17 15 27 1 1,2 -Dichlorobenzene ND 100 ug/L 04/28/17 15 27 1 1,3 -Dichlorobenzene ND 1 00 ug/L 04/28/17 15 27 1 1,4 -Dichlorobenzene ND 100 ug/L 04/28/17 15 27 1 Dichlorodifluoromethane ND 1 00 ug/L 04/28/17 15 27 1 1,1-Dichloroethane ND 100 ug/L 04/28/17 15 27 1 1,2-Dichloroethane ND 1 00 ug/L 04/28/17 15 27 1 1,1-Dichloroethene ND 100 ug/L 04/28/17 15 27 1 1,2-Dichloroethene, Total ND 1 00 ug/L 04/28/17 15 27 1 1,2-Dichloropropane ND 100 ug/L 04/28/17 15 27 1 1,3-Dichloropropane ND 100 ug/L 04/28/17 15 27 1 2,2-Dichloropropane ND 1 00 ug/L 04/28/17 15 27 1 1,1-Dichloropropene ND 1 00 ug/L 04/28/17 15 27 1 Diisopropyl ether ND 200 ug/L 04/28/17 15 27 1 Ethylbenzene ND 1 00 ug/L 04/28/17 15 27 1 Hexachlorobutadiene ND 2 00 ug/L 04/28/17 15 27 1 2-Hexanone ND 100 ug/L 04/28/17 15 27 1 Isopropylbenzene ND 1 00 ug/L 04/28/17 15 27 1 Methylene Chloride ND 500 ug/L 04/28/17 15 27 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/28/17 15 27 1 Methyl tert-butyl ether ND 1 00 ug/L 04/28/17 15 27 1 Naphthalene ND 500 ug/L 04/28/17 15 27 1 n-Butylbenzene ND 1 00 ug/L 04/28/17 15 27 1 N-Propylbenzene ND 1 00 ug/L 04/28/17 15 27 1 p-Isopropyltoluene ND 1 00 ug/L 04/28/17 15 27 1 sec-Butylbenzene ND 1 00 ug/L 04/28/17 15 27 1 Styrene ND 1 00 ug/L 04/28/17 15 27 1 tert-Butyl benzene ND 1 00 ug/L 04/28/17 15 27 1 TestAmenca Nashville Page 14 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -4 Lab Sample ID: 490-127126-5 Date Collected: 04/24/17 12:25 Matrix: Water Date Received: 04/26/17 09:20 Method: 82606 - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac 1,1,1,2 -Tetrachloroethane ND 1 00 ug/L 04/28/17 15 27 1 1,1,2,2 -Tetrachloroethane ND 1 00 ug/L 04/28/17 15 27 1 Tetrachloroethene ND 1 00 ug/L 04/28/17 15 27 1 Toluene ND 1 00 ug/L 04/28/17 15 27 1 trans-1,2-Dichloroethene ND 100 ug/L 04/28/17 15 27 1 trans-1,3-Dichloropropene ND 1 00 ug/L 04/28/17 15 27 1 1,2,3-Trichlorobenzene ND 1 00 ug/L 04/28/17 15 27 1 1,2,4-Trichlorobenzene ND 100 ug/L 04/28/17 15 27 1 1,1,1 -Trichloroethane ND 100 ug/L 04/28/17 15 27 1 1,1,2 -Trichloroethane ND 100 ug/L 04/28/17 15 27 1 1,4 -Dioxane ND 200 ug/L 04/28/17 15 27 1 Trichloroethene ND 1 00 ug/L 04/28/17 15 27 1 Trichlorofluoromethane ND 1 00 ug/L 04/28/17 15 27 1 1,2,3-Trichloropropane ND 1 00 ug/L 04/28/17 15 27 1 1,2,4-Tnmethylbenzene ND 100 ug/L 04/28/17 15 27 1 1,3,5-Tnmethylbenzene ND 1 00 ug/L 04/28/17 15 27 1 Vinyl chloride ND 1 00 ug/L 04/28/17 15 27 1 Xylenes, Total ND 300 ug/L 04/28/17 15 27 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dd Fac 4-Bromofluorobenzene (Surr) 96 70-130 04/28/17 15 27 1 Dibromofluoromethane (Surr) 91 70-130 04128/17 15 27 1 1,2-Dichloroethane-d4 (Surr) 98 70-130 04128/17 15 27 1 Toluene -d8 (Surr) 104 70-130 0428/17 15 27 1 TestAmenca Nashville Page 15 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerica Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -5 Lab Sample ID: 490-127126-6 Date Collected: 04/24/17 14:45 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetone ND 250 ug/L 04/27/17 15 32 1 Benzene ND 1 00 ug/L 04/27/17 15 32 1 Bromobenzene ND 1 00 ug/L 04/27/17 15 32 1 Bromochloromethane ND 1 00 ug/L 04/27/17 15 32 1 Bromodichloromethane ND 1 00 ug/L 04/27/17 15 32 1 Bromoform ND 1 00 ug/L 04/27/17 15 32 1 Bromomethane ND 1 00 ug/L 04/27/17 15 32 1 2-Butanone (MEK) ND 500 ug/L 04/27/17 15 32 1 Carbon disulfide ND 1 00 ug/L 04/27/17 15 32 1 Carbon tetrachloride ND 1 00 ug/L 04/27/17 15 32 1 Chlorobenzene ND 1 00 ug/L 04/27/17 15 32 1 Chlorodibromomethane ND 1 00 ug/L 04/27/17 15 32 1 Chloroethane ND 1 00 ug/L 04/27/17 15 32 1 Chloroform ND 1 00 ug/L 04/27/17 15 32 1 Chloromethane ND 1 00 ug/L 04/27/17 15 32 1 2-Chlorotoluene ND 1 00 ug/L 04/27/17 15 32 1 4-Chlorotoluene ND 1 00 ug/L 04/27/17 15 32 1 cis-1,2-Dichloroethene ND 1 00 ug/L 04/28/17 15 52 1 cis-1,3-Dichloropropene ND 1 00 ug/L 04/27/17 15 32 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/27/17 15 32 1 1,2-Dibromoethane (EDB) ND 1 00 ug/L 04/27/17 15 32 1 Dibromomethane ND 1 00 ug/L 04/27/17 15 32 1 1,2 -Dichlorobenzene ND 1 00 ug/L 04/27/17 15 32 1 1,3 -Dichlorobenzene ND 1 00 ug/L 04/27/17 15 32 1 1,4 -Dichlorobenzene ND 1 00 ug/L 04/27/17 15 32 1 Dichlorodifluoromethane ND 1 00 ug/L 04/27/17 15 32 1 1,1-Dichloroethane ND 1 00 ug/L 04/27/17 15 32 1 1,2-Dichloroethane ND 1 00 ug/L 04/27/17 15 32 1 1,1-Dichloroethene ND 1 00 ug/L 04/27/17 15 32 1 1,2-Dichloroethene, Total 1 91 1 00 ug/L 04/27/17 15 32 1 1,2-Dichloropropane ND 1 00 ug/L 04/27/17 15 32 1 1,3-Dichloropropane ND 1 00 ug/L 04/27/17 15 32 1 2,2-Dichloropropane ND 1 00 ug/L 04/27/17 15 32 1 1,1-Dichloropropene ND 1 00 ug/L 04/27/17 15 32 1 Dnsopropyl ether ND 2 00 ug/L 04/27/17 15 32 1 Ethylbenzene ND 1 00 ug/L 04/27/17 15 32 1 Hexachlorobutadiene ND 2 00 ug/L 04/27/17 15 32 1 2-Hexanone ND 100 ug/L 04/27/17 15 32 1 Isopropylbenzene ND 1 00 ug/L 04/27/17 15 32 1 Methylene Chloride ND 500 ug/L 04/27/17 15 32 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/27/17 15 32 1 Methyl tert-butyl ether ND 1 00 ug/L 04/27/17 15 32 1 Naphthalene ND 500 ug/L 04/27/17 15 32 1 n-Butylbenzene ND 1 00 ug/L 04/27/17 15 32 1 N-Propylbenzene ND 1 00 ug/L 04/27/17 15 32 1 p-Isopropyltoluene ND 1 00 ug/L 04/27/17 15 32 1 sec-Butylbenzene ND 1 00 ug/L 04/27/17 15 32 1 Styrene ND 1 00 ug/L 04/27/17 15 32 1 tert-Butylbenzene ND 1 00 ug/L 04/27/17 15 32 1 TestAmenca Nashville Page 16 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -5 Lab Sample ID: 490-127126-6 Date Collected: 04/24/17 14:45 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane ND ND 1 00 100 ug/L ug/L 04/27/17 15 32 04/27/17 15 32 1 1 Tetra chloroethene ND 1 00 ug/L 04/27/17 15 32 1 Toluene ND 1 00 ug/L 04/27/17 15 32 1 trans-1,2-Dichloroethene ND 1 00 ug/L 04/27/17 15 32 1 trans-1,3-Dichloropropene ND 1 00 ug/L 04/27/17 15 32 1 1,2,3-Tnchlorobenzene ND 100 ug/L 04/27/17 15 32 1 1,2,4-Trichlorobenzene ND 100 ug/L 04/27/17 15 32 1 1,1,1 -Trichloroethane ND 1 00 ug/L 04/27/17 15 32 1 1,1,2 -Trichloroethane ND 1 00 ug/L 04/27/17 15 32 1 1,4 -Dioxane ND 200 ug/L 04/27/17 15 32 1 Trichloroethene ND 1 00 ug/L 04/27/17 15 32 1 Trichlorofluoromethane ND 1 00 ug/L 04/27/17 15 32 1 1,2,3-Trichloropropane ND 100 ug/L 04/27/17 15 32 1 1,2,4-Trimethylbenzene ND 100 ug/L 04/27/17 15 32 1 1,3,5-Tnmethylbenzene ND 100 ug/L 04/27/17 15 32 1 Vinyl chloride ND 1 00 ug/L 04/27/17 15 32 1 Xylenes, Total ND 300 ug/L 04/27/17 15 32 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 102 70-130 04/27/17 15 32 1 4-Bromofluorobenzene (Surr) 95 70-130 04/28/17 15 52 1 Dibromofluoromethane (Suri) 97 70-130 04/27/17 15 32 1 Dibromofluoromethane (Surr) 94 70-130 04128/17 15 52 1 1,2-Dichloroethane-d4 (Surr) 105 70-130 04/27/17 15 32 1 1,2-Dichloroethane-d4 (Surr) 101 70-130 04/28/17 15 52 1 Toluene -d8 (Surr) 100 70-130 04/27/17 15 32 1 Toluene -d8 (Surr) 104 70-130 0428/17 15 52 1 TestAmenca Nashville Page 17 of 46 4/30/2017 TestAmenca Nashville Page 18 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC TestAmenca Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Client Sample ID: MW -6 Lab Sample ID: 490-127126-7 Date Collected: 04/24/17 15:30 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetone ND 250 ug/L 04/28/17 16 16 1 Benzene ND 100 ug/L 04/28/17 16 16 1 • Bromobenzene ND 100 ug/L 04/28/17 16 16 1 Bromochloromethane ND 100 ug/L 04/28/17 16 16 1 Bromodichloromethane ND 100 ug/L 04/28/17 16 16 1 Bromoform ND 100 ug/L 04/28/17 16 16 1 Bromomethane ND 100 ug/L 04/28/17 16 16 1 2-Butanone (MEK) ND 500 ug/L 04/28/17 16 16 1 Carbon disulfide ND 1 00 ug/L 04/28/17 16 16 1 Carbon tetrachloride ND 1 00 ug/L 04/28/17 16 16 1 Chlorobenzene ND 100 ug/L 04/28/17 16 16 1 Chlorodibromomethane ND 100 ug/L 04/28/17 16 16 1 Chloroethane ND 100 ug/L 04/28/17 16 16 1 Chloroform ND 100 ug/L 04/28/17 16 16 1 Chloromethane ND 100 ug/L 04/28/17 16 16 1 2-Chlorotoluene ND 100 ug/L 04/28/17 16 16 1 4-Chlorotoluene ND 100 ug/L 04/28/17 16 16 1 cis-1,2-Dichloroethene 150 100 ug/L 04/28/17 16 16 1 cis-1,3-Dichloropropene ND 100 ug/L 04/28/17 16 16 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/28/17 16 16 1 1,2-Dibromoethane (EDB) ND 1 00 ug/L 04/28/17 16 16 1 Dibromomethane ND 100 ug/L 04/28/17 16 16 1 1,2 -Dichlorobenzene ND 100 ug/L 04/28/17 16 16 1 1,3 -Dichlorobenzene ND 100 ug/L 04/28/17 16 16 1 1,4 -Dichlorobenzene ND 100 ug/L 04/28/17 16 16 1 Dichlorodifluoromethane ND 100 ug/L 04/28/17 16 16 1 1,1-Dichloroethane ND 100 ug/L 04/28/17 16 16 1 1,2-Dichloroethane ND 100 ug/L 04/28/171616 1 1,1-Dichloroethene ND 100 ug/L 04/28/17 16 16 1 1,2-Dichloroethene, Total 151 1 00 ug/L 04/28/17 16 16 1 1,2-Dichloropropane ND 100 ug/L 04/28/17 16 16 1 1,3-Dichloro propane ND 100 ug/L 04/28/17 16 16 1 2,2-Dichloropropane ND 100 ug/L 04/28/171616 1 1,1-Dichloropropene ND 100 ug/L 04/28/17 16 16 1 Dusopropyl ether ND 200 ug/L 04/28/17 16 16 1 Ethylbenzene ND 100 ug/L 04/28/17 16 16 1 Hexachlorobutadiene ND 200 ug/L 04/28/17 16 16 1 2-Hexanone ND 100 ug/L 04/28/17 16 16 1 Isopropylbenzene ND 100 ug/L 04/28/17 16 16 1 Methylene Chloride ND 500 ug/L 04/28/17 16 16 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/28/17 16 16 1 Methyl tert-butyl ether ND 1 00 ug/L 04/28/17 16 16 1 Naphthalene ND 500 ug/L 04/28/17 16 16 1 n-Butylbenzene ND 100 ug/L 04/28/17 16 16 1 N-Propylbenzene ND 100 ug/L 04/28/17 16 16 1 p-Isopropyltoluene ND 100 ug/L 04/28/17 16 16 1 sec-Butylbenzene ND 100 ug/L 04/28/17 16 16 1 Styrene ND 100 ug/L 04/28/17 16 16 1 tert-Butyl benzene ND 100 ug/L 04/28/17 16 16 1 TestAmenca Nashville Page 18 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -6 Lab Sample ID: 490-127126-7 Date Collected: 04/24/17 15:30 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2 -Tetrachloroethane ND 100 ug/L 04/28/17 16 16 1 1,1,2,2 -Tetrachloroethane ND 100 ug/L 04/28/17 16 16 1 Tetrachloroethene 409 1 00 ug/L 04/28/17 16 16 1 Toluene ND 100 ug/L 04/28/17 16 16 1 trans-1,2-Dichloroethene 117 100 ug/L 04/28/17 16 16 1 trans-1,3-Dichloropropene ND 100 ug/L 04/28/17 16 16 1 1,2,3-Trichlorobenzene ND 100 ug/L 04/28/17 16 16 1 1,2,4-Trichlorobenzene ND 100 ug/L 04/28/17 16 16 1 1,1,1-Tnchloroethane ND 100 ug/L 04/28/17 16 16 1 1,1,2-Tnchloroethane ND 100 ug/L 04/28/17 16 16 1 1,4 -Dioxane ND 200 ug/L 04/28/17 16 16 1 Trichloroethene 173 1 00 ug/L 04/28/17 16 16 1 Trichlorofluoromethane ND 100 ug/L 04/28/17 16 16 1 1,2,3-Trichloropropane ND 100 ug/L 04/28/17 16 16 1 1,2,4-Trimethylbenzene ND 100 ug/L 04/28/17 16 16 1 1,3,5-Tnmethylbenzene ND 100 ug/L 04/28/17 16 16 1 Vinyl chloride ND 1 00 ug/L 04/28/17 16 16 1 Xylenes, Total ND 300 ug/L 04/28/17 16 16 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Suri) 94 70-130 04/28/17 16 16 1 Dibromotluoromethane (Surr) 93 70-130 04128/17 16 16 1 1,2-Dichloroethane-d4 (Surr) 99 70-130 04/28/17 16 16 1 Toluene -d8 (Surr) 105 70-130 04128/17 16 16 1 TestAmenca Nashville Page 19 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -7 Lab Sample ID: 490-127126-8 Date Collected: 04/24/17 16:30 Matrix: Water Date Received: 04/26/17 09:20 F Method: 8260B - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier Acetone ND Benzene ND Bromobenzene ND Bromochloromethane ND Bromodichloromethane ND Bromoform ND Bromomethane ND 2-Butanone (MEK) ND Carbon disulfide ND Carbon tetrachloride ND Chlorobenzene ND Chlorodibromomethane ND Chloroethane ND Chloroform 1 97 Chloromethane ND 2-Chlorotoluene ND 4-Chlorotoluene ND cis-1,2-Dichloroethene ND as-1,3-Dichloropropene ND 1,2-Dibromo-3-Chloropropane ND 1,2-Dibromoethane (EDB) ND Dibromomethane ND 1,2 -Dichlorobenzene ND 1,3 -Dichlorobenzene ND 1,4 -Dichlorobenzene ND Dichlorodifluoromethane ND 1,1-Dichloroethane ND 1,2-Dichloroethane ND 1,1-Dichloroethene ND 1,2-Dichloroethene, Total 1 13 1,2-Dichloropropane ND 1,3-Dichloropropane ND 2,2-Dichloropropane ND 1,1-Dichloropropene ND Dusopropyl ether ND Ethylbenzene ND Hexachlorobutadiene ND 2-Hexanone ND Isopropyl benzene ND Methylene Chloride ND 4-Methyl-2-pentanone (MIBK) ND Methyl tert-butyl ether ND Naphthalene ND n-Butylbenzene ND N-Propylbenzene ND p-Isopropyltoluene ND sec -Butyl benzene ND Styrene ND tert-Butylbenzene ND RL MDL Unit D Prepared Analyzed Dd Fac 250 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 500 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/28/17 16 41 1 1 00 ug/L 04/27/17 15 58 1 100 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 200 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 2 00 ug/L 04/27/17 15 58 1 100 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 500 ug/L 04/27/17 15 58 1 100 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 5 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 1 00 ug/L 04/27/17 15 58 1 TestAmenca Nashville Page 20 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -7 Lab Sample ID: 490-127126-8 Date Collected: 04/24/17 16:30 Matrix: Water Date Received: 04/26/17 09:20 Method: 82606 - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane ND ND 100 100 ug/L ug/L 04/27/17 15 58 04/27/17 15 58 1 1 Tetrachloroethene 211 1 00 ug/L 04/27/17 15 58 1 Toluene ND 1 00 ug/L 04/27/17 15 58 1 trans-1,2-Dichloroethene ND 100 ug/L 04/27/17 15 58 1 trans-1,3-Dichloropropene ND 100 ug/L 04/27/17 15 58 1 1,2,3-Trnchlorobenzene ND 1 00 ug/L 04/27/17 15 58 1 1,2,4-Trichlorobenzene ND 1 00 ug/L 04/27/17 15 58 1 1,1,1 -Trichloroethane ND 1 00 ug/L 04/27/17 15 58 1 1,1,2 -Trichloroethane ND 1 00 ug/L 04/27/17 15 58 1 1,4 -Dioxane ND 200 ug/L 04/27/171558 1 Trichloroethene ND 1 00 ug/L 04/27/17 15 58 1 Trichlorofluoromethane ND 1 00 ug/L 04/27/17 15 58 1 1,2,3-Trichloropropane ND 1 00 ug/L 04/27/17 15 58 1 1,2,4 -Tri methyl benzene ND 100 ug/L 04/27/17 15 58 1 1,3,5-Trimethylbenzene ND 1 00 ug/L 04/27/17 15 58 1 Vinyl chloride ND 1 00 ug/L 04/27/17 15 58 1 Xylenes, Total ND 300 ug/L 04/27/17 15 58 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed D►I Fac 4-Bromofluorobenzene (Surf) 100 70-130 04/27/17 15 58 1 4-Bromofluorobenzene (Surf) 93 70-130 04128/17 16 41 1 Dibromofluoromethane (Surf) 99 70-130 04/27/17 15 58 1 Dibromofluoromethane (Surr) 92 70-130 04/28/17 16 41 1 1,2-Dichloroethane-d4 (Surr) 110 70-130 04/27/17 15 58 1 1,2-Dichloroethane-d4 (Surr) 98 70-130 04/28/17 16 41 1 Toluene -d8 (Surr) 98 70-130 04127/17 15 58 1 Toluene -d8 (Surr) 106 70-130 04/28/17 16 41 1 TestAmenca Nashville Page 21 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerica Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -8 Lab Sample ID: 490-127126-9 Date Collected: 04/24/17 17:20 Matrix: Water Date Received: 04/26/17 09:20 Method: 8260B - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetone ND 250 ug/L 04/27/17 16 24 1 Benzene ND 1 00 ug/L 04/27/17 16 24 1 m Bromobenzene ND 1 00 ug/L 04/27/17 16 24 1 Bromochloromethane ND 1 00 ug/L 04/27/17 16 24 1 Bromodichloromethane ND 1 00 ug/L 04/27/17 16 24 1 Bromoform ND 1 00 ug/L 04/27/17 16 24 1 Bromomethane ND 1 00 ug/L 04/27/17 16 24 1 2-Butanone (MEK) ND 500 ug/L 04/27/17 16 24 1 Carbon disulfide ND 1 00 ug/L 04/27/17 16 24 1 Carbon tetrachloride ND 1 00 ug/L 04/27/17 16 24 1 Chlorobenzene ND 1 00 ug/L 04/27/17 16 24 1 Chlorodibromomethane ND 1 00 ug/L 04/27/17 16 24 1 Chloroethane ND 1 00 ug/L 04/27/17 16 24 1 Chloroform ND 1 00 ug/L 04/27/17 16 24 1 Chloromethane ND 1 00 ug/L 04/27/17 16 24 1 2-Chlorotoluene ND 1 00 ug/L 04/27/17 16 24 1 4-Chlorotoluene ND 1 00 ug/L 04/27/17 16 24 1 cis-1,2-Dichloroethene ND 1 00 ug/L 04/27/17 16 24 1 cis-1,3-Dichloropropene ND 100 ug/L 04/27/17 16 24 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/27/17 16 24 1 1,2-Dibromoethane(EDB) ND 100 ug/L 04/27/17 16 24 1 Dibromomethane ND 1 00 ug/L 04/27/17 16 24 1 1,2 -Dichlorobenzene ND 1 00 ug/L 04/27/17 16 24 1 1,3 -Dichlorobenzene ND 1 00 ug/L 04/27/17 16 24 1 1,4 -Dichlorobenzene ND 100 ug/L 04/27/17 16 24 1 Dichlorodifluoromethane ND 1 00 ug/L 04/27/17 16 24 1 1,1-Dichloroethane ND 1 00 ug/L 04/27/17 16 24 1 1,2-Dichloroethane ND 1 00 ug/L 04/27/17 16 24 1 1,1-Dichloroethene ND 100 ug/L 04/27/17 16 24 1 1,2-Dichloroethene, Total ND 1 00 ug/L 04/27/17 16 24 1 1,2-Dichloropropane ND 100 ug/L 04/27/17 16 24 1 1,3-Dichloro propane ND 100 ug/L 04/27/17 16 24 1 2,2-Dichloropropane ND 1 00 ug/L 04/27/17 16 24 1 1,1-Dichloropropene ND 100 ug/L 04/27/17 16 24 1 Dnsopropyl ether ND 200 ug/L 04/27/17 16 24 1 Ethylbenzene ND 1 00 ug/L 04/27/17 16 24 1 Hexachlorobutadiene ND 200 ug/L 04/27/17 16 24 1 2-Hexanone ND 100 ug/L 04/27/17 16 24 1 Isopropylbenzene ND 1 00 ug/L 04/27/17 16 24 1 Methylene Chloride ND 500 ug/L 04/27/17 16 24 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/27/17 16 24 1 Methyl tert-butyl ether ND 1 00 ug/L 04/27/17 16 24 1 Naphthalene ND 500 ug/L 04/27/17 16 24 1 n-Butylbenzene ND 1 00 ug/L 04/27/17 16 24 1 N-Propylbenzene ND 1 00 ug/L 04/27/17 16 24 1 p-Isopropyltoluene ND 1 00 ug/L 04/27/17 16 24 1 sec-Butylbenzene ND 1 00 ug/L 04/27/17 16 24 1 Styrene ND 1 00 ug/L 04/27/17 16 24 1 tert-Butylbenzene ND 1 00 ug/L 04/27/17 16 24 1 TestAmenca Nashville Page 22 of 46 4/30/2017 Client Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerlca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -8 Lab Sample ID: 490-127126-9 Date Collected: 04/24/17 17:20 Matrix: /mater Date Received: 04/26/17 09:20 Method: 82606 - Volatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane ND ND 1 00 100 ug/L ug/L 04/27/17 16 24 04/27/17 16 24 1 1 Tetrachloroethene ND 1 00 ug/L 04/27/17 16 24 1 Toluene ND 1 00 ug/L 04/27/17 16 24 1 trans-1,2-Dichloroethene ND 100 ug/L 04/27/17 16 24 1 trans-1,3-Dichloropropene ND 1 00 ug/L 04/27/17 16 24 1 1,2,3-Tnchlorobenzene ND 100 ug/L 04/27/17 16 24 1 1,2,4 -Tri chloro benzene ND 100 ug/L 04/27/17 16 24 1 1,1,1 -Trichloroethane ND 100 ug/L 04/27/17 16 24 1 1,1,2 -Trichloroethane ND 100 ug/L 04/27/17 16 24 1 1,4 -Dioxane ND 200 ug/L 04/27/17 16 24 1 Trichloroethene ND 1 00 ug/L 04/27/17 16 24 1 Trichlorofluoromethane ND 1 00 ug/L 04/27/17 16 24 1 1,2,3-Trichloropropane ND 100 ug/L 04/27/17 16 24 1 1,2,4-Tnmethylbenzene ND 100 ug/L 04/27/17 16 24 1 1,3,5-Tnmethylbenzene ND 100 ug/L 04/27/17 16 24 1 Vinyl chloride ND 1 00 ug/L 04/27/17 16 24 1 Xylenes, Total ND 300 ug/L 04/27/17 16 24 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 109 70-130 04/27/17 16 24 1 Dibromofluoromethane (Surr) 98 70-130 04/27/17 16 24 1 1,2-Dichloroethane-d4 (Surr) 105 70-130 04/27/17 16 24 1 Toluene -d8 (Surr) 99 70-130 04/27/17 16 24 1 TestAmenca Nashville Page 23 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerica Job ID 490-127126-1 SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/MS) Lab Sample ID: MB 490-425499/7 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 425499 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetone ND 250 ug/L 04/27/17 12 56 1 Benzene ND 1 00 ug/L 04/27/17 12 56 1 Bromobenzene ND 1 00 ug/L 04/27/17 12 56 1 Bromochloromethane ND 1 00 ug/L 04/27/17 12 56 1 Bromodichloromethane ND 1 00 ug/L 04/27/17 12 56 1 Bromoform ND 1 00 ug/L 04/27/17 12 56 1 Bromomethane ND 1 00 ug/L 04/27/17 12 56 1 2-Butanone (MEK) ND 500 ug/L 04/27/17 12 56 1 Carbon disulfide ND 1 00 ug/L 04/27/17 12 56 1 Carbon tetrachloride ND 1 00 ug/L 04/27/17 12 56 1 Chlorobenzene ND 1 00 ug/L 04/27/17 12 56 1 Chlorodibromomethane ND 1 00 ug/L 04/27/17 12 56 1 Chloroethane ND 1 00 ug/L 04/27/17 12 56 1 Chloroform ND 1 00 ug/L 04/27/17 12 56 1 Chloromethane ND 1 00 ug/L 04/27/17 12 56 1 2-Chlorotoluene ND 1 00 ug/L 04/27/17 12 56 1 4-Chlorotoluene ND 1 00 ug/L 04/27/17 12 56 1 cis- 1,2-Dichloroethene ND 1 00 ug/L 04/27/17 12 56 1 cis-1,3-Dichloropropene ND 1 00 ug/L 04/27/17 12 56 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/27/17 12 56 1 1,2-Dibromoethane (EDB) ND 1 00 ug/L 04/27/17 12 56 1 Dibromomethane ND 1 00 ug/L 04/27/17 12 56 1 1,2 -Dichlorobenzene ND 1 00 ug/L 04/27/17 12 56 1 1,3 -Dichlorobenzene ND 1 00 ug/L 04/27/17 12 56 1 1,4 -Dichlorobenzene ND 100 ug/L 04/27/17 12 56 1 Dichlorodifluoromethane ND 1 00 ug/L 04/27/17 12 56 1 1,1-Dichloroethane ND 1 00 ug/L 04/27/17 12 56 1 1,2-Dichloroethane ND 1 00 ug/L 04/27/17 12 56 1 1,1-Dichloroethene ND 1 00 ug/L 04/27/17 12 56 1 1,2-Dichloroethene, Total ND 1 00 ug/L 04/27/17 12 56 1 1,2-Dichloropropane ND 1 00 ug/L 04/27/17 12 56 1 1,3-Dichloropropane ND 1 00 ug/L 04/27/17 12 56 1 2,2-Dichloropropane ND 1 00 ug/L 04/27/17 12 56 1 1,1-Dichloropropene ND 1 00 ug/L 04/27/17 12 56 1 Dnsopropyl ether ND 2 00 ug/L 04/27/17 12 56 1 Ethylbenzene ND 1 00 ug/L 04/27/17 12 56 1 Hexachlorobutadiene ND 2 00 ug/L 04/27/17 12 56 1 ° 2-Hexanone ND 100 ug/L 04/27/17 12 56 1 Isop ropylbenzene ND 1 00 ug/L 04/27/17 12 56 1 Methylene Chloride ND 500 ug/L 04/27/17 12 56 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/27/17 12 56 1 Methyl tert-butyl ether ND 1 00 ug/L 04/27/17 12 56 1 Naphthalene ND 500 ug/L 04/27/17 12 56 1 n-Butylbenzene ND 1 00 ug/L 04/27/17 12 56 1 N-Propylbenzene ND 1 00 ug/L 04/27/17 12 56 1 p-Isopropyltoluene ND 1 00 ug/L 04/27/17 12 56 1 sec-Butylbenzene ND 1 00 ug/L 04/27/17 12 56 1 Styrene ND 1 00 ug/L 04/27/17 12 56 1 TestAmenca Nashville Page 24 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC TestAmerica Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: MB 490-425499/7 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch 425499 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac tert-Butylbenzene ND 1 00 ug/L 04/27/17 12 56 1 1,1,1,2 -Tetrachloroethane ND 1 00 ug/L 04/27/17 12 56 1 1,1,2,2 -Tetrachloroethane ND 1 00 ug/L 04/27/17 12 56 1 Tetra ch loroethene ND 1 00 ug/L 04/27/17 12 56 1 Toluene ND 1 00 ug/L 04/27/17 12 56 1 trans-1,2-Dichloroethene ND 1 00 ug/L 04/27/17 12 56 1 trans-1,3-Dichloropropene ND 1 00 ug/L 04/27/17 12 56 1 1,2,3-Trichlorobenzene ND 1 00 ug/L 04/27/17 12 56 1 1,2,4-Trichlorobenzene ND 1 00 ug/L 04/27/17 12 56 1 1,1,1 -Trichloroethane ND 1 00 ug/L 04/27/17 12 56 1 1,1,2 -Trichloroethane ND 1 00 ug/L 04/27/17 12 56 1 1,4 -Dioxane ND 200 ug/L 04/27/17 12 56 1 Trichloroethene ND 1 00 ug/L 04/27/17 12 56 1 Trichlorofluoromethane ND 1 00 ug/L 04/27/17 12 56 1 1,2,3-Tnchloropropane ND 1 00 ug/L 04/27/17 12 56 1 1,2,4-Tnmethylbenzene ND 1 00 ug/L 04/27/17 12 56 1 1,3,5-Tnmethylbenzene ND 1 00 ug/L 04/27/17 12 56 1 Vinyl chloride ND 1 00 ug/L 04/27/17 12 56 1 Xylenes, Total ND 300 ug/L 04/27/17 12 56 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed D►1 Fac 4-Bromofluorobenzene (Suri) 105 70-130 04/27/17 12 56 1 Dibromofluoromethane (Surr) 100 70-130 04/27/17 12 56 1 1,2-Dichloroethane-d4 (Surr) 103 70-130 04/27/17 12 56 1 Toluene -d8 (Surr) 98 70-130 04/27/17 12 56 1 Lab Sample ID: LCS 490-425499/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 425499 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Acetone 100 98 89 ug/L 99 39-150 Benzene 200 2062 ug/L 103 70-130 Bromobenzene 200 21 96 ug/L 110 70-130 Bromochloromethane 200 2053 ug/L 103 70-130 Bromodichloromethane 200 21 63 ug/L 108 70-130 Bromoform 200 21 66 ug/L 108 70-137 Bromomethane 200 2556 ug/L 128 53-150 2-Butanone (MEK) 100 8740 ug/L 87 55-143 Carbon disulfide 200 2023 ug/L 101 64-135 Carbon tetrachloride 200 2378 ug/L 119 70-147 Chlorobenzene 200 21 34 ug/L 107 70-130 Chlorodibromomethane 200 2145 ug/L 107 70-133 Chloroethane 200 1854 ug/L 93 60-138 Chloroform 200 22 08 ug/L 110 70-130 Chloromethane 200 21 73 ug/L 109 33-150 2-Chlorotoluene 200 2211 ug/L 111 70-130 4-Chlorotoluene 200 21 83 ug/L 109 70-130 TestAmerica Nashville Page 25 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 490-425499/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 425499 Analyte Spike Added LCS LCS Result Qualifier Unit D %Rec %Rec Limits cis-1,2-Dichloroethene 200 2091 ug/L 105 70-130 cis-1,3-Dichloropropene 200 21 07 ug/L 105 70-133 1,2-Dibromo-3-Chloropropane 200 1961 ug/L 98 45-138 1,2-Dibromoethane (EDB) 200 2063 ug/L 103 70-130 Dibromomethane 200 21 02 ug/L 105 70-130 1,2 -Dichlorobenzene 200 2235 ug/L 112 70-130 1,3 -Dichlorobenzene 200 21 98 ug/L 110 70-130 1,4 -Dichlorobenzene 200 2190 ug/L 109 70-130 Dichlorodifluoromethane 200 2409 ug/L 120 48-150 1,1-Dichloroethane 200 1964 ug/L 98 70-130 1,2-Dichloroethane 200 21 51 ug/L 108 70-130 1,1-Dichloroethene 200 2096 ug/L 105 70-132 1,2-Dichloroethene, Total 400 4055 ug/L 101 70-130 1,2-Dichloropropane 200 1867 ug/L 93 70-130 1,3-Dichloropropane 200 1984 ug/L 99 70-130 2,2-Dichloropropane 200 2237 ug/L 112 60-143 1,1-Dichloropropene 200 2080 ug/L 104 70-130 Dusopropyl ether 200 1736 ug/L 87 66-142 Ethylbenzene 200 2163 ug/L 108 70-130 Hexachlorobutadiene 200 21 16 ug/L 106 70-138 2-Hexanone 100 8477 ug/L 85 54-142 Isopropyl benzene 200 2320 ug/L 116 70-131 Methylene Chloride 200 2065 ug/L 103 70-130 4-Methyl-2-pentanone (MIBK) 100 8583 ug/L 86 60-137 Methyl tert-butyl ether 200 1990 ug/L 100 70-130 Naphthalene 200 1898 ug/L 95 54-150 n-Butylbenzene 200 2222 ug/L 111 68-137 N-Propylbenzene 200 21 60 ug/L 108 70-134 p-Isopropyltoluene 200 2143 ug/L 107 66-130 sec-Butylbenzene 200 21 54 ug/L 108 70-135 Styrene 200 2270 ug/L 113 70-130 tert-Butyl benzene 200 2096 ug/L 105 70-130 1,1,1,2 -Tetrachloroethane 200 2190 ug/L 109 70-130 1,1,2,2 -Tetrachloroethane 200 2023 ug/L 101 69-131 Tetrachloroethene 200 2240 ug/L 112 70-130 Toluene 200 21 23 ug/L 106 70-130 trans-1,2-Dichloroethene 200 1964 ug/L 98 70-130 trans-1,3-Dichloropropene 200 2066 ug/L 103 63-142 1,2,3-Tnchlorobenzene 200 1897 ug/L 95 46-150 1,2,4-Tnchlorobenzene 200 1859 ug/L 93 58-147 1,1,1-Tnchloroethane 200 2333 ug/L 117 70-135 1,1,2 -Trichloroethane 200 2044 ug/L 102 70-130 1,4 -Dioxane 400 3564 ug/L 89 18-150 Trichloroethene 200 21 55 ug/L 108 70-130 Trichlorofluoromethane 200 2451 ug/L 123 59-150 1,2,3-Trichloropropane 200 1950 ug/L 98 70-131 1,2,4-Trimethylbenzene 200 2212 ug/L 111 70-130 1,3,5-Tnmethylbenzene 200 2248 ug/L 112 70-130 TestAmenca Nashville Page 26 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 490-425499/3 Matrix: Water Analysis Batch: 425499 Analyte Vinyl chloride Xylenes, Total LCS LCS Surrogate %Recovery Qualifier 4-Bromofluorobenzene (Surf) 98 Dibromofluoromethane (Surr) 99 1,2-Dichloroethane-d4 (Surr) 106 Toluene -d8 (Surr) 99 Lab Sample ID: LCSD 490-425499/4 Matrix: Water Analysis Batch: 425499 Analyte Acetone i Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene cis-1,2-Dichloroethene as-1,3-Dichloropropene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane (EDB) Dibromomethane 1,2 -Dichlorobenzene 1,3 -Dichlorobenzene 1,4 -Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethene, Total 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene TestAmerica Job ID 490-127126-1 SDG DSO -80 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS D %Rec Limits Added Result Qualifier Unit 200 19 57 ug/L 400 4465 ug/L Limits 70-130 70-130 70-130 70-130 %Rec LCSD LCSD Result Qualifier D %Rec Limits D %Rec 98 57-137 RPD 112 70-132 100 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike Added LCSD LCSD Result Qualifier Unit D %Rec %Rec Limits RPD RPD Limit 100 9697 6g/L 97 3-9-- 150 2 23 200 2081 ug/L 104 70-130 1 12 200 21 24 ug/L 106 70-130 3 16 200 2057 ug/L 103 70-130 0 16 200 21 39 ug/L 107 70-130 1 14 200 21 15 ug/L 106 70-137 2 14 200 2502 ug/L 125 53-150 2 19 100 9409 ug/L 94 55-143 7 19 200 2070 ug/L 104 64-135 2 16 200 2332 ug/L 117 70-147 2 16 200 2146 ug/L 107 70-130 1 12 200 2086 ug/L 104 70-133 3 13 200 1854 ug/L 93 60-138 0 15 200 21 56 ug/L 108 70-130 2 14 200 21 34 ug/L 107 33-150 2 20 200 2234 ug/L 112 70-130 1 15 200 2229 ug/L 111 70-130 2 15 200 2072 ug/L 104 70-130 1 15 200 21 24 ug/L 106 70-133 1 15 200 2001 ug/L 100 45-138 2 19 200 2066 ug/L 103 70-130 0 13 200 2076 ug/L 104 70-130 1 14 200 2250 ug/L 113 70-130 1 12 200 2270 ug/L 114 70-130 3 13 200 2252 ug/L 113 70-130 3 12 200 2402 ug/L 120 48-150 0 16 200 1972 ug/L 99 70-130 0 17 200 21 35 ug/L 107 70-130 1 13 200 2070 ug/L 103 70-132 1 20 400 41 10 ug/L 103 70-130 1 14 200 1870 ug/L 94 70-130 0 15 200 1967 ug/L 98 70-130 1 12 200 2228 ug/L 111 60-143 0 20 200 21 00 ug/L 105 70-130 1 16 TestAmerica Nashville Page 27 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners Method: 82608 -Volatile Organic Compounds (GC/MS) (Continued) TestAmerica Job ID 490-127126-1 SDG DSO -80 " Lab Sample ID: LCSD 490-425499/4 Client Sample ID: Lab Control Sample Dup Matrix: Water Matrix: Water Prep Type: Total/NA Prep Type: Total/NA Analysis Batch: 425499 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Spike LCSD LCSD D %Rec Limits Acetone ND %Rec 4062 RPD Analyte Benzene ND Added Result Qualifier Unit D %Rec Limits RPD Limit Dusopropyl ether ug/L 200 1753 ug/L 88 66-142 1 14 I Ethylbenzene 200 2203 ug/L 110 70-130 2 12 Hexachlorobutadiene 200 2253 ug/L 113 70-138 6 16 2-Hexanone 100 8728 ug/L 87 54-142 3 17 Isopropylbenzene 200 2273 ug/L 114 70-131 2 13 Methylene Chloride 200 2049 ug/L 102 70-130 1 15 4-Methyl-2-pentanone (MIBK) 100 8897 ug/L 89 60-137 4 21 Methyl tert-butyl ether 200 2045 ug/L 102 70-130 3 16 Naphthalene 200 2047 ug/L 102 54-150 8 15 n-Butylbenzene 200 22 87 ug/L 114 68-137 3 14 N-Propylbenzene 200 2214 ug/L 111 70-134 2 14 p-Isopropyltoluene 200 22 09 ug/L 110 66-130 3 13 sec-Butylbenzene 200 2205 ug/L 110 70-135 2 14 Styrene 200 2301 ug/L 115 70-130 1 12 tert-Butyl benzene 200 21 56 ug/L 108 70-130 3 14 1,1,1,2 -Tetrachloroethane 200 2186 ug/L 109 70-130 0 13 1,1,2,2 -Tetrachloroethane 200 2071 ug/L 104 69-131 2 15 Tetrachloroethene 200 2212 ug/L 111 70-130 1 17 „ Toluene 200 21 18 ug/L 106 70-130 0 13 trans-1,2-Dichloroethene 200 2038 ug/L 102 70-130 4 15 trans-1,3-Dichloropropene 200 2050 ug/L 103 63-142 1 13 1,2,3-Trichlorobenzene 200 1985 ug/L 99 46-150 5 16 1,2,4-Trichlorobenzene 200 1944 ug/L 97 58-147 4 15 1,1,1 -Trichloroethane 200 2382 ug/L 119 70-135 2 15 1,1,2 -Trichloroethane 200 2040 ug/L 102 70-130 0 13 1,4 -Dioxane 400 3877 ug/L 97 18-150 8 34 Trichloroethene 200 21 33 ug/L 107 70-130 1 14 Trichlorofluoromethane 200 2472 ug/L 124 59-160 1 22 1,2,3-Trichloropropane 200 2002 ug/L 100 70-131 3 14 1,2,4-Trimethylbenzene 200 2239 ug/L 112 70-130 1 13 1,3,5-Tnmethylbenzene 200 2244 ug/L 112 70-130 0 14 Vinyl chloride 200 2037 ug/L 102 57-137 4 15 Xylenes, Total 400 4496 ug/L 112 70-132 1 11 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromotluorobenzene (Surr) 92 70-130 Dibromofluoromethane (Surf) 98 70-130 I 1,2-Dichloroethane-d4 (Surr) 103 70-130 Toluene -d8 (Surr) 98 70-130 Lab Sample ID: 490-127126-1 MS Client Sample ID: MW -1 Matrix: Water Prep Type: Total/NA Analysis Batch: 425499 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Acetone ND 500 4062 ug/L 81 39-150 Benzene ND 100 1031 ug/L 103 55-147 Bromobenzene ND 100 1088 ug/L 109 60-133 TestAmerlca Nashville Page 28 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Method: 82608 - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 490-127126-1 MS Client Sample ID: MW -1 Matrix: Water Prep Type: Total/NA Analysis Batch: 425499 Analyte Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene as-1,2-Dichloroethene as-1,3-Dichloropropene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane (EDB) Dibromomethane 1,2 -Dichlorobenzene 1,3 -Dichlorobenzene 1,4 -Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethene, Total 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene Dusopropyl ether Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-Isopropyltoluene sec-Butylbenzene Styrene tert-Butylbenzene 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane Sample Sample Result Qualifier Spike Added MS BAS Result Qualifier ND 100 9805 ND 100 1038 ND 100 1037 ND 100 1197 ND 500 4351 ND 100 9446 ND 100 1221 ND 100 1061 ND 100 101 2 ND 100 8803 ND 100 1104 ND 100 9655 ND 100 1105 ND 100 1089 Nb 100 1040 ND 100 101 0 ND 100 9049 ND 100 9557 ND 100 9976 ND 100 1092 ND 100 111 1 ND 100 1085 ND 100 1095 ND 100 9902 ND 100 1026 ND 100 9783 ND 200 2034 ND 100 91 91 ND 100 9348 ND 100 1080 ND 100 1024 ND 100 8606 ND 100 1087 ND 100 1053 ND 500 3753 ND 100 1175 ND 100 1022 ND 500 3996 ND 100 9405 ND 100 8989 ND 100 1138 ND 100 1096 ND 100 1086 ND 100 1106 ND 100 1196 ND 100 1086 ND 100 1072 ND 100 9812 TestAmenca Nashville Page 29 of 46 4/30/2017 %Rec Unit D %Rec Limits ug/L 98 59-132 ug/L 104 70-140 ug/L 104 53-150 ug/L 120 30-150 ug/L 87 50-143 ug/L 94 35-150 ug/L 122 56-150 ug/L 106 70-130 ug/L 101 66-140 ug/L 88 58-141 ug/L 110 66-138 ug/L 97 10-150 ug/L 111 67-138 ug/L 109 69-138 ug/L 104 68-131 ug/L 101 70-133 ug/L 90 38-138 ug/L 96 65-137 ug/L 100 70-130 ug/L 109 70-130 ug/L 111 68-131 ug/L 108 70-130 ug/L 109 10-150 ug/L 99 61-139 ug/L 103 64.136 ug/L 98 54-150 ug/L 102 60-134 ug/L 92 67-130 ug/L 93 70-130 ug/L 108 50-146 ug/L 102 54-150 ug/L 86 56-142 ug/L 109 65-139 ug/L 105 61-141 ug/L 75 44-150 ug/L 118 70-137 ug/L 102 64-130 ug/L 80 50-140 ug/L 94 55-141 ug/L 78 32-150 ug/L 114 61-141 ug/L 107 53-150 ug/L 109 66-137 ug/L 111 55-136 ug/L 120 70-130 ug/L 109 70-138 ug/L 107 70-131 ug/L 98 56-145 TestAmenca Nashville Page 29 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 490-127126-1 MS Matrix: Water Analysis Batch: 425499 Spike Sample Sample Analyte Result Qualifier Tetrachloroethene ND Toluene ND trans-1,2-Dichloroethene ND trans-1,3-Dichloropropene ND 1,2,3-Trichlorobenzene ND 1,2,4-Trichlorobenzene ND 1,1,1 -Trichloroethane ND 1,1,2 -Trichloroethane ND 1,4 -Dioxane ND Trichloroethene ND Trichlorofluoromethane ND 1,2,3-Trichloropropane ND 1,2,4-Trimethylbenzene 797 1,3,5-Trimethylbenzene ND Vinyl chloride ND Xylenes, Total ND Spike MS MS Added Result Qualifier 100 111 1 100 1043 100 9944 100 9732 100 8748 100 8988 100 121 3 100 9922 2000 1883 100 1067 100 1222 100 9578 100 1107 100 1090 100 8999 200 2283 MS MS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 97 70-130 Dibromofluoromethane (Surr) 99 70-130 1,2-Dichloroethane-d4 (Surr) 104 70-130 Toluene -d8 (Surr) 98 70-130 Lab Sample ID: 490-127126-1 MSD Matrix: Water Analysis Batch: 425499 Analyte Sample Sample Result Qualifier Acetone ND Benzene ND Bromobenzene ND Bromochloromethane ND Bromodichloromethane ND Bromoform ND Bromomethane ND 2-Butanone (MEK) ND Carbon disulfide ND Carbon tetrachloride ND Chlorobenzene ND Chlorodibromomethane ND Chloroethane ND Chloroform ND Chloromethane ND 2-Chlorotoluene ND 4-Chlorotoluene ND as-1,2-Dichloroethene ND cis- 1,3-Dichloropropene ND 1,2-Dibromo-3-Chloropropane ND Spike MSD MSD Added Result Qualifier 500 471 1 100 1051 100 1159 100 1004 100 1080 100 1108 100 1204 500 4425 100 9884 100 1238 100 1129 100 1082 100 8878 100 1080 100 101 4 100 1157 100 1127 100 1059 100 1074 100 9728 Page 30 of 46 TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MWA Prep Type: Total/NA Client Sample ID: MW -1 Prep Type: Total/NA %Rec Unit D %Rec Limits ug/L 111 57-138 ug/L 104 64-136 ug/L 99 59-143 ug/L 97 63-142 ug/L 87 36-150 ug/L 90 47-147 ug/L 121 68-144 ug/L 99 70-130 ug/L 94 11-150 ug/L 107 63-135 ug/L 122 44-150 ug/L 96 65-131 ug/L 103 64-136 ug/L 107 69-139 ug/L 90 57-150 ug/L 114 69-132 Client Sample ID: MW -1 Prep Type: Total/NA TestAmerlca Nashville 4/30/2017 %Rec RPD Unit D %Rec Limits RPD Limit ug/L 94 39-150 15 28 ug/L 105 55-147 2 22 ug/L 116 60-133 6 18 ug/L 100 59-132 2 21 ug/L 108 70-140 4 196 ug/L 111 53-150 7 20 ug/L 120 30-150 1 44 ug/L 89 50-143 2 28 ug/L 99 35-150 5 34 ug/L 124 56-150 1 18 ug/L 113 70-130 6 15 ug/L 108 66-140 7 19 ug/L 89 58-141 1 31 ug/L 108 66-138 2 21 ug/L 101 10-150 5 43 ug/L 116 67-138 5 17 ug/L 113 69-138 3 15 ug/L 106 68-131 2 21 ug/L 107 70-133 6 19 ug/L 97 38-138 7 26 TestAmerlca Nashville 4/30/2017 CSC Sample Results Client Hart & Hickman, PC TestAmenca Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/AOS) (Continued) Lab Sample ID: 490-127126-1 MSD Client Sample ID: MW -1 Matrix: Water Prep Type: Total/NA Analysis Batch: 425499 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit 1,2-Dibromoethane(EDB) ND 100 1052 ug/L 105 65-137 10 21 Dibromomethane ND 100 1032 ug/L 103 70-130 3 19 1,2 -Dichlorobenzene ND 100 1161 ug/L 116 70-130 6 15 1,3 -Dichlorobenzene ND 100 1171 ug/L 117 68-131 5 14 1,4 -Dichlorobenzene ND 100 1130 ug/L 113 70-130 4 14 Dichlorodifluoromethane ND 100 1101 ug/L 110 10-150 1 50 1,1-Dichloroethane ND 100 9915 ug/L 99 61-139 0 23 1,2-Dichloroethane ND 100 1082 ug/L 108 64-136 5 22 1,1-Dichloroethene ND 100 9912 ug/L 99 54-150 1 24 1,2-Dichloroethene, Total ND 200 2046 ug/L 102 60-134 1 22 1,2-Dichloropro pane ND 100 9297 ug/L 93 67-130 1 19 1,3-Dichloropropane ND 100 1002 ug/L 100 70-130 7 17 2,2-Dichloropropane ND 100 1085 ug/L 108 50-146 0 20 1,1-Dichloropropene ND 100 1059 ug/L 106 54-150 3 24 Dnsopropyl ether ND 100 8721 ug/L 87 56-142 1 22 Ethylbenzene ND 100 1147 ug/L 115 65-139 5 18 Hexachlorobutadiene ND 100 1167 ug/L 117 61-141 10 26 2-Hexanone ND 500 4237 ug/L 85 44-150 12 21 Isopropylbenzene ND 100 1259 ug/L 126 70-137 7 17 Methylene Chloride ND 100 1037 ug/L 104 64-130 1 22 4-Methyl-2-pentanone (MIBK) ND 500 4378 ug/L 88 50-140 9 24 Methyl tert-butyl ether ND 100 1006 ug/L 101 55-141 7 24 Naphthalene ND 100 1005 ug/L 89 32-150 11 40 n-Butylbenzene ND 100 1200 ug/L 120 61-141 5 17 N-Propylbenzene ND 100 1137 ug/L 111 53-150 4 18 p-Isopropyltoluene ND 100 1157 ug/L 116 66-137 6 16 sec -Butyl benzene ND 100 1161 ug/L 116 55-136 5 50 Styrene ND 100 1180 ug/L 118 70-130 1 16 tert-Butylbenzene ND 100 1141 ug/L 114 70-138 5 17 1,1,1,2 -Tetrachloroethane ND 100 1128 ug/L 113 70-131 5 16 1,1,2,2 -Tetrachloroethane ND 100 1021 ug/L 102 56-145 4 19 Tetra chloroethene ND 100 1179 ug/L 118 57-138 6 17 Toluene ND 100 1100 ug/L 110 64-136 5 18 trans-1,2-Dichloroethene ND 100 9867 ug/L 99 59-143 1 25 trans-1,3-Dichloropropene ND 100 1048 ug/L 105 63-142 7 18 1,2,3-Tnchlorobenzene ND 100 9704 ug/L 97 36-150 10 43 1,2,4-Tnchlorobenzene ND 100 9765 ug/L 98 47-147 8 24 1,1,1 -Trichloroethane ND 100 1250 ug/L 125 68-144 3 17 1,1,2 -Trichloroethane ND 100 1038 ug/L 104 70-130 5 18 1,4 -Dioxane ND 2000 2001 ug/L 100 11-150 6 50 Trichloroethene ND 100 1092 ug/L 109 63-135 2 17 Tnchlorofluoromethane ND 100 1287 ug/L 129 44-150 5 32 1,2,3-Trichloropropane ND 100 1061 ug/L 106 65-131 10 19 1,2,4-Tnmethylbenzene 797 100 1161 ug/L 108 64-136 5 18 1,3,5-Tnmethylbenzene ND 100 1163 ug/L 115 69-139 6 17 Vinyl chloride ND 100 9602 ug/L 96 57-150 6 37 Xylenes, Total ND 200 2325 ug/L 116 69-132 2 17 TestAmerlca Nashville Page 31 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC TestAmenca Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Method: 6260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 490-127126-1 MSD Client Sample ID: MW -1 Matrix: Water Prep Type: Total/NA Analysis Batch: 425499 MSD MSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surf) 98 70-130 Dibromofluoromethane (Surr) 97 70-130 10 1,2-Dichloroethane-d4 (Surr) 101 70-130 Toluene -d8 (Surr) 101 70-130 Lab Sample ID: MB 490-425892/7 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch 425892 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetone ND 250 ug/L 04/28/17 13 50 1 Benzene ND 1 00 ug/L 04/28/17 13 50 1 Bromobenzene ND 1 00 ug/L 04/28/17 13 50 1 Bromochloromethane ND 1 00 ug/L 04/28/17 13 50 1 Bromodichloromethane ND 1 00 ug/L 04/28/17 13 50 1 Bromoform ND 1 00 ug/L 04/28/17 13 50 1 Bromomethane ND 1 00 ug/L 04/28/17 13 50 1 2-Butanone (MEK) ND 500 ug/L 04/28/17 13 50 1 Carbon disulfide ND 1 00 ug/L 04/28/17 13 50 1 Carbon tetrachloride ND 1 00 ug/L 04/28/17 13 50 1 Chlorobenzene ND 1 00 ug/L 04/28/17 13 50 1 Chlorodibromomethane ND 1 00 ug/L 04/28/17 13 50 1 Chloroethane ND 1 00 ug/L 04/28/17 13 50 1 Chloroform ND 1 00 ug/L 04/28/17 13 50 1 Chloromethane ND 1 00 ug/L 04/28/17 13 50 1 2-Chlorotoluene ND 1 00 ug/L 04/28/17 13 50 1 4-Chlorotoluene ND 1 00 ug/L 04/28/17 13 50 1 cis-1,2-Dichloroethene ND 100 ug/L 04/28/17 13 50 1 as-1,3-Dichloropropene ND 1 00 ug/L 04/28/17 13 50 1 1,2-Dibromo-3-Chloropropane ND 100 ug/L 04/28/17 13 50 1 1,2-Dibromoethane (EDB) ND 1 00 ug/L 04/28/17 13 50 1 Dibromomethane ND 1 00 ug/L 04/28/17 13 50 1 1,2 -Dichlorobenzene ND 1 00 ug/L 04/28/17 13 50 1 1,3 -Dichlorobenzene ND 100 ug/L 04/28/17 13 50 1 1,4 -Dichlorobenzene ND 1 00 ug/L 04/28/17 13 50 1 Dichlorodifluoromethane ND 1 00 ug/L 04/28/17 13 50 1 1,1-Dichloroethane ND 1 00 ug/L 04/28/17 13 50 1 1,2-Dichloroethane ND 1 00 ug/L 04/28/17 13 50 1 1,1-Dichloroethene ND 1 00 ug/L 04/28/17 13 50 1 1,2-Dichloroethene, Total ND 1 00 ug/L 04/28/17 13 50 1 1,2-Dichloropropane ND 1 00 ug/L 04/28/17 13 50 1 1,3-Dichloropropane ND 100 ug/L 04/28/17 13 50 1 2,2-Dichloropropane ND 1 00 ug/L 04/28/17 13 50 1 1,1-Dichloropropene ND 1 00 ug/L 04/28/17 13 50 1 Diisopropyl ether ND 200 ug/L 04/28/17 13 50 1 Ethylbenzene ND 1 00 ug/L 04/28/17 13 50 1 Hexachlorobutadiene ND 200 ug/L 04/28/17 13 50 1 2-Hexanone ND 100 ug/L 04/28/17 13 50 1 TestAmenca Nashville Page 32 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC LCS LCS Result Qualifier 100 7302 TestAmenca Job ID 490-127126-1 Project/Site McCorkles Cleaners 200 2121 200 SDG DSO -80 1835 200 1709 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) 2260 Lab Sample ID: MB 490-425892/7 70-130 ug/L 85 Client Sample ID: Method Blank Matrix: Water 113 53-150 Prep Type: Total/NA Analysis Batch: 425892 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dd Fac Isopropylbenzene ND 1 00 ug/L 04/28/17 13 50 1 Methylene Chloride ND 500 ug/L 04/28/17 13 50 1 4-Methyl-2-pentanone (MIBK) ND 100 ug/L 04/28/17 13 50 1 Methyl tert-butyl ether ND 1 00 ug/L 04/28/17 13 50 1 Naphthalene ND 500 ug/L 04/28/17 13 50 1 n-Butylbenzene ND 1 00 ug/L 04/28/17 13 50 1 N-Propylbenzene ND 1 00 ug/L 04/28/17 13 50 1 p-Isopropyltoluene ND 1 00 ug/L 04/28/17 13 50 1 sec-Butylbenzene ND 1 00 ug/L 04/28/17 13 50 1 Styrene ND 1 00 ug/L 04/28/17 13 50 1 tert-Butylbenzene ND 1 00 ug/L 04/28/17 13 50 1 1,1,1,2 -Tetrachloroethane ND 100 ug/L 04/28/17 13 50 1 1,1,2,2 -Tetrachloroethane ND 1 00 ug/L 04/28/17 13 50 1 Tetrachloroethene ND 1 00 ug/L 04/28/17 13 50 1 Toluene ND 1 00 ug/L 04/28/17 13 50 1 trans-1,2-Dichloroethene ND 1 00 ug/L 04/28/17 13 50 1 trans-1,3-Dichloropropene ND 1 00 ug/L 04/28/17 13 50 1 1,2,3-Trichlorobenzene ND 100 ug/L 04/28/17 13 50 1 1,2,4-Trichlorobenzene ND 100 ug/L 04/28/17 13 50 1 1,1,1 -Trichloroethane ND 100 ug/L 04/28/17 13 50 1 1,1,2 -Trichloroethane ND 100 ug/L 04/28/17 13 50 1 1,4 -Dioxane ND 200 ug/L 04/28/17 13 50 1 Trichloroethene ND 1 00 ug/L 04/28/17 13 50 1 Trichlorofluoromethane ND 1 00 ug/L 04/28/17 13 50 1 1,2,3-Trichloropropane ND 1 00 ug/L 04/28/17 13 50 1 1,2,4-Tnmethylbenzene ND 1 00 ug/L 04/28/17 13 50 1 1,3,5-Tnmethylbenzene ND 1 00 ug/L 04/28/17 13 50 1 Vinyl chloride ND 1 00 ug/L 04/28/17 13 50 1 Xylenes, Total ND 300 ug/L 04/28/17 13 50 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dd Fac 4-Bromofluorobenzene (Surr) 96 70-130 04/28/17 13 50 1 Dibromofluoromethane (Surr) 95 70-130 04/28/17 13 50 1 1,2-Dichloroethane-d4 (Surr) 97 70-130 04/28/17 13 50 1 Toluene -d8 (Surr) 103 70-130 04/28/17 13 50 1 Lab Sample ID- LCS 490-425892/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 425892 Analyte Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Spike Added LCS LCS Result Qualifier 100 7302 200 2144 200 2121 200 2071 200 1835 200 1709 200 2260 Unit D %Rec %Rec Limits ug/L 73 39-150 ug/L 107 70-130 ug/L 106 70-130 ug/L 104 70-130 ug/L 92 70-130 ug/L 85 70-137 ug/L 113 53-150 TestAmenca Nashville Page 33 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC TestAmerica Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 490-425892/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 425892 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 2-Butanone (MEK) 100 1076 ug/L 108 55-143 Carbon disulfide 200 1920 ug/L 96 64-135 Carbon tetrachloride 200 1897 ug/L 95 70-147 Chlorobenzene 200 2225 ug/L 111 70-130 Chlorodibromomethane 200 1947 ug/L 97 70-133 Chloroethane 200 2320 ug/L 116 60-138 Chloroform 200 2024 ug/L 101 70-130 Chloromethane 200 2379 ug/L 119 33-150 2-Chlorotoluene 200 2151 ug/L 108 70-130 4-Chlorotoluene 200 21 06 ug/L 105 70-130 cis-1,2-Dichloroethene 200 2071 ug/L 104 70-130 cis-1,3-Dichloropropene 200 2089 ug/L 104 70-133 1,2-Dibromo-3-Chloropropane 200 2047 ug/L 102 45-138 1,2-Dibromoethane (EDB) 200 21 68 ug/L 108 70-130 Dibromomethane 200 2061 ug/L 103 70-130 1,2 -Dichlorobenzene 200 2205 ug/L 110 70-130 1,3 -Dichlorobenzene 200 2180 ug/L 109 70-130 1,4 -Dichlorobenzene 200 2149 ug/L 107 70-130 Dichlorodifluoromethane 200 1959 ug/L 98 48-150 1,1-Dichloroethane 200 2049 ug/L 102 70-130 1,2-Dichloroethane 200 2065 ug/L 103 70-130 1,1-Dichloroethene 200 2209 ug/L 110 70-132 1,2-Dichloroethene, Total 400 41 73 ug/L 104 70-130 1,2-Dichloropropane 200 21 11 ug/L 106 70-130 1,3-Dichloropropane 200 2242 ug/L 112 70-130 2,2-Dichloropropane 200 2048 ug/L 102 60-143 1,1-Dichloropropene 200 2045 ug/L 102 70-130 Dnsopropyl ether 200 2006 ug/L 100 66-142 Ethylbenzene 200 21 82 ug/L 109 70-130 Hexachlorobutadiene 200 1766 ug/L 88 70-138 2-Hexanone 100 1183 ug/L 118 54-142 Isopropylbenzene 200 21 01 ug/L 105 70-131 Methylene Chloride 200 2236 ug/L 112 70-130 4-Methyl-2-pentanone(MIBK) 100 1147 ug/L 115 60-137 Methyl tent -butyl ether 200 2014 ug/L 101 70-130 Naphthalene 200 1998 ug/L 100 54-150 n-Butylbenzene 200 2010 ug/L 101 68-137 N-Propylbenzene 200 21 73 ug/L 109 70-134 p-Isopropyltoluene 200 2014 ug/L 101 66-130 sec-Butylbenzene 200 2006 ug/L 100 70-135 Styrene 200 21 61 ug/L 108 70-130 tert-Butylbenzene 200 1924 ug/L 96 70-130 1,1,1,2 -Tetrachloroethane 200 2070 ug/L 103 70-130 1,1,2,2 -Tetrachloroethane 200 2215 ug/L 111 69-131 Tetrachloroethene 200 2246 ug/L 112 70-130 Toluene 200 21 65 ug/L 108 70-130 trans-1,2-Dichloroethene 200 21 02 ug/L 105 70-130 trans-1,3-Dichloropropene 200 1949 ug/L 97 63-142 TestAmenca Nashville Page 34 of 46 4/30/2017 CSC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerica Job ID 490-127126-1 SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 490-425892/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 425892 Analyte Sample Sample Spike Added LCS LCS Result Qualifier Unit D %Rec %Rec Limits 1,2,3-Tnchlorobenzene Result Qualifier 200 2033 ug/L 102 46-150 1,2,4-Trichlorobenzene ND F2 200 2017 ug/L 101 58-147 1,1,1 -Trichloroethane ND 200 2037 ug/L 102 70-135 1,1,2 -Trichloroethane ND 200 2241 ug/L 112 70-130 1,4 -Dioxane ND 400 4256 ug/L 106 18-150 Trichloroethene ND 200 2144 ug/L 107 70-130 Tnchlorofluoromethane ND 200 21 93 ug/L 110 59-150 1,2,3-Trichloropropane ND 200 2234 ug/L 112 70-131 1,2,4-Trimethylbenzene ND 200 2062 ug/L 103 70-130 1,3,5-Tnmethylbenzene ND 200 2071 ug/L 104 70-130 Vinyl chloride ND 200 21 96 ug/L 110 57-137 Xylenes, Total ND 400 4257 ug/L 106 70-132 Chlorodibromomethane LCS LCS 1000 1000 ug/L 100 66-140 Surrogate %Recovery Qualifier Limits 1074 ug/L 107 58.141 4-Bromofluorobenzene (Surr) 99 70-130 1004 ug/L 100 66-138 Dibromofluoromethane (Surr) 94 70-130 1058 ug/L 106 10-150 1,2-Dichloroethane-d4 (Surr) 94 70-130 1118 ug/L 112 67-138 Toluene -dB (Surr) 100 70-130 1092 ug/L 109 69-138 Lab Sample ID: 490-127126-2 MS Matrix: Water Analysis Batch: 425892 Client Sample ID: MW -2S Prep Type: Total/NA TestAmerica Nashville Page 35 of 46 4/30/2017 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Acetone ND F2 5000 3668 ug/!- 73 39-150 Benzene ND 1000 1069 ug/L 107 55-147 Bromobenzene ND 1000 1077 ug/L 108 60-133 Bromochloromethane ND 1000 1013 ug/L 101 59-132 Bromodichloromethane ND 1000 9339 ug/L 93 70-140 Bromoform ND 1000 8632 ug/L 86 53-150 Bromomethane ND 1000 1045 ug/L 104 30-150 2-Butanone (MEK) ND 5000 6146 ug/L 123 50-143 Carbon disulfide ND 1000 8156 ug/L 82 35-150 Carbon tetrachloride ND 1000 9664 ug/L 97 56-150 Chlorobenzene ND 1000 1140 ug/L 114 70-130 Chlorodibromomethane ND 1000 1000 ug/L 100 66-140 Chloroethane ND 1000 1074 ug/L 107 58.141 Chloroform ND 1000 1004 ug/L 100 66-138 Chloromethane ND 1000 1058 ug/L 106 10-150 2-Chlorotoluene ND 1000 1118 ug/L 112 67-138 4-Chlorotoluene ND 1000 1092 ug/L 109 69-138 cis-1,2-Dichloroethene 10300 1000 12240 4 ug/L 191 68-131 cis- 1,3-Dichloropropene ND 1000 1057 ug/L 106 70-133 1,2-Dibromo-3-Chloropropane ND 1000 1033 ug/L 103 38-138 1,2-Dibromoethane(EDB) ND 1000 1072 ug/L 107 65-137 Dibromomethane ND 1000 1023 ug/L 102 70-130 1,2 -Dichlorobenzene ND 1000 1117 ug/L 112 70-130 1,3 -Dichlorobenzene ND 1000 1139 ug/L 114 68-131 TestAmerica Nashville Page 35 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerlca Job ID 490-127126-1 SDG DSO -80 Method: 82608 - Volatile Organic Compounds (GC/IVIS) (Continued) Lab Sample ID: 490-127126-2 MS Client Sample ID: MW -2S Matrix: Water Prep Type: Total/NA Analysis Batch- 425892 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits 1,4 -Dichlorobenzene ND 1000 1109 ug/L 111 70-130 Dichlorodifluoromethane ND 1000 9127 ug/L 91 10-150 1,1-Dichloroethane ND 1000 9822 ug/L 98 61-139 1,2-Dichloroethane ND 1000 1026 ug/L 103 64-136 1,1-Dichloroethene ND 1000 1034 ug/L 103 54-150 1,2-Dichloroethene,Total 10400 2000 13340 4 ug/L 146 60-134 1,2-Dichloropropane ND 1000 1077 ug/L 108 67-130 1,3-Dichloropropane ND 1000 1178 ug/L 118 70-130 2,2-Dichloropropane ND 1000 1051 ug/L 105 50-146 1,1-Dichloropropene ND 1000 1028 ug/L 103 54-150 Dusopropyl ether ND 1000 9576 ug/L 96 56-142 Ethylbenzene ND 1000 1130 ug/L 113 65-139 Hexachlorobutadiene ND 1000 9475 ug/L 95 61-141 2-Hexanone ND 5000 5913 ug/L 118 44-150 Isopropylbenzene ND 1000 1128 ug/L 113 70-137 Methylene Chloride ND 1000 1042 ug/L 104 64-130 4-Methyl-2-pentanone(MIBK) ND 5000 5789 ug/L 116 50-140 Methyl tert-butyl ether ND 1000 9388 ug/L 94 55-141 Naphthalene ND 1000 9928 ug/L 99 32-150 n-Butylbenzene ND 1000 1049 ug/L 105 61-141 N-Propylbenzene ND 1000 1180 ug/L 118 53-150 p-Isopropyltoluene ND 1000 1057 ug/L 106 66-137 sec -Butyl benzene ND 1000 1091 ug/L 109 55-136 Styrene ND 1000 1120 ug/L 112 70-130 tert-Butylbenzene ND 1000 1085 ug/L 107 70-138 1,1,1,2 -Tetrachloroethane ND 1000 1077 ug/L 108 70-131 1,1,2,2 -Tetrachloroethane ND 1000 1127 ug/L 113 56-145 Tetrachloroethene ND 1000 1146 ug/L 115 57-138 Toluene ND 1000 1146 ug/L 115 64-136 trans-1,2-Dichloroethene 131 1000 1102 ug/L 97 59-143 trans-1,3-Dichloropropene ND 1000 9979 ug/L 100 63-142 1,2,3-Tnchlorobenzene ND 1000 1022 ug/L 102 36-150 1,2,4-Tnchlorobenzene ND 1000 1015 ug/L 102 47-147 1,1,1 -Trichloroethane ND 1000 9960 ug/L 100 68-144 1,1,2 -Trichloroethane ND 1000 1179 ug/L 118 70-130 1,4 -Dioxane ND 20000 18870 ug/L 94 11-150 Trichloroethene ND 1000 1065 ug/L 106 63-135 Trichlorofluoromethane ND 1000 1097 ug/L 110 44-150 1,2,3-Trichloropropane ND 1000 1124 ug/L 112 65-131 1,2,4-Tnmethylbenzene ND 1000 1083 ug/L 108 64-136 1,3,5-Trimethylbenzene ND 1000 1076 ug/L 108 69-139 Vinyl chloride ND 1000 1008 ug/L 101 57-150 Xylenes, Total ND 2000 2216 ug/L 111 69-132 MS MS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 98 70-130 Dibromofluoromethane (Surr) 92 70-130 1,2-Dichloroethane-d4 (Surr) 94 70-130 TestAmenca Nashville Page 36 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmerica Job ID 490-127126-1 SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 490-127126-2 MS Client Sample ID: MW -2S Matrix. Water Prep Type: Total/NA Analysis Batch: 425892 MS MS Surrogate %Recovery Qualifier Limits Toluene -d8 (Surr) 102 70-130 Lab Sample ID: 490-127126-2 MSD Client Sample ID: MW -2S Matrix: Water Prep Type: Total/NA Analysis Batch: 425892 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Acetone ND F2 5000 5274 F2 ug/L 105 39-150 36 28 Benzene ND 1000 1105 ug/L 110 55-147 3 22 Bromobenzene ND 1000 1087 ug/L 109 60-133 1 18 Bromochloromethane ND 1000 1064 ug/L 106 59-132 5 21 Bromodichloromethane ND 1000 9680 ug/L 97 70-140 4 196 Bromoform ND 1000 8534 ug/L 85 53-150 1 20 Bromomethane ND 1000 1108 ug/L 111 30-150 6 44 2-Butanone (MEK) ND 5000 6084 ug/L 122 50-143 1 28 Carbon disulfide ND 1000 9532 ug/L 95 35-150 16 34 Carbon tetrachloride ND 1000 9977 ug/L 100 56-150 3 18 Chlorobenzene ND 1000 1145 ug/L 115 70-130 0 15 Chlorodibromomethane ND 1000 9923 ug/L 99 66-140 1 19 Chloroethane ND 1000 1190 ug/L 119 58-141 10 31 Chloroform ND 1000 1081 ug/L 108 66-138 7 21 Chloromethane ND 1000 1137 ug/L 114 10-150 7 43 2-Chlorotoluene ND 1000 1128 ug/L 113 67-138 1 17 4-Chlorotoluene ND 1000 1091 ug/L 109 69-138 0 15 cis-1,2-Dichloroethene 10300 1000 12480 4 ug/L 215 68-131 2 21 cis- 1,3-Dichloropropene ND 1000 1059 ug/L 106 70-133 0 19 1,2-Dibromo-3-Chloropropane ND 1000 1052 ug/L 105 38-138 2 26 1,2-Dibromoethane (EDB) ND 1000 1109 ug/L 111 65-137 3 21 Dibromomethane ND 1000 1066 ug/L 107 70-130 4 19 1,2 -Dichlorobenzene ND 1000 1146 ug/L 115 70-130 3 15 1,3 -Dichlorobenzene ND 1000 1135 ug/L 113 68-131 0 14 1,4 -Dichlorobenzene ND 1000 1121 ug/L 112 70-130 1 14 Dichlorodifluoromethane ND 1000 1012 ug/L 101 10-150 10 50 1,1-Dichloroethane ND 1000 1109 ug/L 111 61-139 12 23 1,2-Dichloroethane ND 1000 1039 ug/L 104 64-136 1 22 1,1-Dichloroethene ND 1000 1124 ug/L 112 54-150 8 24 1,2-Dichloroethene, Total 10400 2000 13720 4 ug/L 164 60-134 3 22 1,2-Dichloropropane ND 1000 1108 ug/L 111 67-130 3 19 1,3-Dichloropropane ND 1000 1110 ug/L 111 70-130 6 17 2,2 -Di chloro propane ND 1000 1117 ug/L 112 50-146 6 20 1,1-Dichloropropene ND 1000 1049 ug/L 105 54-150 2 24 Dusopropyl ether ND 1000 1048 ug/L 105 56-142 9 22 Ethylbenzene ND 1000 1124 ug/L 112 65-139 1 18 Hexachlorobutadiene ND 1000 9991 ug/L 100 61-141 5 26 2-Hexanone ND 5000 5700 ug/L 114 44-150 4 21 Isop ropylbenzene ND 1000 1132 ug/L 113 70-137 0 17 Methylene Chloride ND 1000 1126 ug/L 113 64-130 8 22 4-Methyl-2-pentanone (MIBK) ND 5000 5782 ug/L 116 50-140 0 24 TestAmerlca Nashville Page 37 of 46 4/30/2017 QC Sample Results Client Hart & Hickman, PC TestAmerica Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 490-127126-2 MSD Client Sample ID: MW -2S Matrix: Water Prep Type: Total/NA Analysis Batch: 425892 Sample Sample Spike MSD MSD %Rec. RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Methyl tert-butyl ether ND 1000 1025 ug/L 103 55-141 9 24 Naphthalene ND 1000 1054 ug/L 105 32-150 6 40 n-Butylbenzene ND 1000 1073 ug/L 107 61-141 2 17 N-Propylbenzene ND 1000 1178 ug/L 118 53-150 0 18 p-Isopropyltoluene ND 1000 1086 ug/L 109 66-137 3 16 sec -Butyl benzene ND 1000 1121 ug/L 112 55-136 3 50 Styrene ND 1000 1099 ug/L 110 70-130 2 16 tert-Butyl benzene ND 1000 1106 ug/L 109 70-138 2 17 1,1,1,2 -Tetrachloroethane ND 1000 1069 ug/L 107 70-131 1 16 1,1,2,2 -Tetrachloroethane ND 1000 1163 ug/L 116 56-145 3 19 Tetrachloroethene ND 1000 1119 ug/L 112 57-138 2 17 Toluene ND 1000 1118 ug/L 112 64-136 2 18 trans-1,2-Dichloroethene 131 1000 1236 ug/L 111 59-143 11 25 trans-1,3-Dichloropropene ND 1000 9677 ug/L 97 63-142 3 18 1,2,3-Tnchlorobenzene ND 1000 1079 ug/L 108 36-150 5 43 1,2,4-Tnchlorobenzene ND 1000 1046 ug/L 105 47-147 3 24 1,1,1 -Trichloroethane ND 1000 1090 ug/L 109 68-144 9 17 1,1,2 -Trichloroethane ND 1000 1131 ug/L 113 70-130 4 18 1,4 -Dioxane ND 20000 19290 ug/L 96 11-150 2 50 Trichloroethene ND 1000 1096 ug/L 110 63-135 3 17 Trichlorofluoromethane ND 1000 1139 ug/L 114 44-150 4 32 1,2,3-Trichloropropane ND 1000 1148 ug/L 115 65-131 2 19 1,2,4-Trimethylbenzene ND 1000 1095 ug/L 109 64-136 1 18 1,3,5-Tnmethylbenzene ND 1000 1080 ug/L 108 69-139 0 17 Vinyl chloride ND 1000 1086 ug/L 109 57-150 7 37 Xylenes, Total ND 2000 2179 ug/L 109 69-132 2 17 MSD MSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surf) 101 70-130 Dibromofluoromethane (Surf) 95 70-130 1,2-Dichloroethane-d4 (Surr) 97 70-130 Toluene -d8 (Surr) 101 70-130 TestAmerica Nashville Page 38 of 46 4/30/2017 QC Association Summary Client Hart & Hickman, PC Project/Site McCorkles Cleaners GC/MS VOA Analysis Batch: 425499 TestAmenca Job ID 490-127126-1 SDG DSO -80 Lab Sample ID Client Sample ID Prep Type Matrix Method 490-127126-2 MW -2S Total/NA Water 8260B 490-127126-4 MW -3 Total/NA Water 8260B 490-127126-6 MW -5 Total/NA Water 8260B 490-127126-8 MW -7 Total/NA Water 8260B 490-127126-9 MW -8 Total/NA Water 8260B MB 490-425499/7 Method Blank Total/NA Water 8260B LCS 490-425499/3 Lab Control Sample Total/NA Water 8260B LCSD 490-425499/4 Lab Control Sample Dup Total/NA Water 8260B 490-127126-1 MS MW -1 Total/NA Water 8260B 490-127126-1 MSD MW -1 Total/NA Water 8260B Analysis Batch: 425892 Lab Sample ID Client Sample ID Prep Type Matrix Method 490-127126-1 MW -1 Total/NA Water 8260B 490-127126-2 MW -2S Total/NA Water 8260B 490-127126-3 MW -2D Total/NA Water 8260B 490-127126-4 MW -3 Total/NA Water 8260B 490-127126-5 MW -4 Total/NA Water 8260B 490-127126-6 MW -5 Total/NA Water 8260B 490-127126-7 MW -6 Total/NA Water 8260B 490-127126-8 MW -7 Total/NA Water 8260B MB 490-425892/7 Method Blank Total/NA Water 8260B LCS 490-425892/4 Lab Control Sample Total/NA Water 8260B 490-127126-2 MS MW -2S Total/NA Water 8260B 490-127126-2 MSD MW -2S Total/NA Water 8260B Prep Batch Prep Batch TestAmenca Nashville Page 39 of 46 4/30/2017 Lab Chronicle Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 SDG DSO -80 Client Sample ID: MW -1 Lab Sample ID: 490-127126-6 Date Collected: 04/24/17 14:45 Lab Sample ID: 490-127126-1 Date Collected: 04/24/17 08:55 Date Received: 04/26/17 09:20 Matrix: Water Dil Initial Date Received: 04/26/17 09:20 Batch Prepared iPrep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 82606 Batch Batch 10 mL Dil Initial Final Batch Prepared 425499 04/27/17 15 32 NC TAL NSH Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab I- - LTotal/NA Analysis 8260B 1 10 mL 10 mL 425892 04/28/17 14 14 BBR TAL NSH Client Sample ID: MW -2S Lab Sample ID: 490-127126-2 Date Collected: 04/24/17 11:00 Matrix: Water Date Received: 04/26/17 09:20 Batch Batch l; Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 82606 50 10 mL 10 mL 425892 04/28/17 18 43 BBR TAL NSH L Total/NA Analysis 82608 1 10 mL 10 mL 425499 04/27/17 14 40 NC TAL NSH Client Sample ID: MW -2D Lab Sample ID: 490-127126-3 Date Collected: 04/24/17 10:25 Matrix: Water Date Received: 04/26/17 09:20 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 82606 1 10 mL 10 mL 425892 04/28/17 14 38 BBR TAL NSH Client Sample ID: MW -3 Lab Sample ID: 490-127126-4 Date Collected: 04/24/17 09:45 Matrix: Water Date Received: 04/26/17 09:20 Batch Batch Dil Initial Final Batch Prepared Ii Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 8260B 1 10 mL 10 mL 425892 04/28/17 15 03 BBR TAL NSH Total/NA Analysis 8260B 1 10 mL 10 mL 425499 04/27/17 15 06 NC TAL NSH Client Sample ID: MW -4 Lab Sample ID: 490-127126-5 Date Collected: 04/24/17 12:25 Matrix: Water Date Received: 04/26/17 09:20 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab I—Total/NA Analysis 82608 1 10 mL 10 mL 425892 04/28/17 15 27 BBR TAL NSH Client Sample ID: MW -5 Lab Sample ID: 490-127126-6 Date Collected: 04/24/17 14:45 Matrix: Water Date Received: 04/26/17 09:20 Batch Batch Dil Initial Final Batch Prepared iPrep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 82606 1 10 mL 10 mL 425892 04/28/17 15 52 BBR TAL NSH Total/NA Analysis 82608 1 10 mL 10 mL 425499 04/27/17 15 32 NC TAL NSH TestAmerica Nashville Page 40 of 46 4/30/2017 Lab Chronicle Client Hart & Hickman, PC TestAmerica Job ID 490-127126-1 Project/Site McCorkles Cleaners SDG DSO -80 Client Sample ID: MW -6 Lab Sample ID: 490-127126-7 Date Collected: 04/24/17 15:30 Matrix: Water Date Received: 04/26/17 09:20 Batch Batch Dil Initial Final Batch Prepared [Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab 1 Total/NA Analysis 8260B 1 10 mL 10 mL 425892 04/28/17 16 16 BBR TAL NSH Client Sample ID: MW -7 Lab Sample ID: 490-127126-8 Date Collected: 04/24/17 16:30 Matrix: Water Date Received: 04/26/17 09:20 Batch Batch Dd Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab 13 Total/NA Analysis 8260B 1 10 mL 10 mL 425892 04/28/17 16 41 BBR TAL NSH Total/NA Analysis 82606 1 10 mL 10 mL 425499 04/27/17 15 58 NC TAL NSH Client Sample ID: MW -8 Lab Sample ID: 490-127126-9 Date Collected: 04/24/17 17:20 Matrix: Water Date Received: 04/26/17 09:20 F Batch Batch Dd Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab I Total/NA Analysis 82608 1 10 mL 10 mL 425499 04/27/17 16 24 NC TAL NSH Laboratory References: TAL NSH = TestAmenca Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 TestAmenca Nashville Page 41 of 46 4/30/2017 Method Summary Client Hart & Hickman, PC Project/Site McCorkles Cleaners TestAmenca Job ID 490-127126-1 Y SDG DSO -80 Method Method Description Protocol Laboratory 82606 Volatile Organic Compounds (GC/MS) SW846 TAL NSH Protocol References: SW846 = 'Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates Laboratory References• TAL NSH = TestAmenca Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 TestAmenca Nashville Page 42 of 46 4/30/2017 Accreditation/Certification Summary Client Hart & Hickman, PC TestAmerlca Job ID 490-127126-1 - Project/Site McCorkles Cleaners SDG DSO -80 Laboratory: TestAmerica Nashville The accreditations/certifications listed below are applicable to this report F1 Authority Program North Carolina (WW/SV11) State Program EPA Region Identification Number Expiration Date 4 387 12-31-17 Page 43 of 46 TestAmerica Nashville 4/30/2017 €a° TestAmedca THE LEADER IN ENVIRONMENTAL TESTING Nashville, TN COOLER RECEIPT FORM ' 90-1271" Chai­9111111111111 "' 490-127126 Chain of Custody Cooler Received/Opened On 4/26/2017 Ca) 0920 Time Samples Removed From Cooler Time Samples Placed In Storage"(2 Hour Window) 1 Tracking # 663,0 (last 4dig�its, FedEx) Courier: FedEx IR Gun ID/� _160656843 pH Strip Lot � 11V Chlorine Strip Lo4Ei 2. Temperature of rep. sample or temp blank when opened: L. 3 Degrees Celsius 3. if Item #2 temperature is 0°C or less, was the representative sample or temp blank frozen? YES NO.. V�A 4. Were custody seals on outside of cooler? Y - NO.AA If yes, how many and where: "r%'7 /l 4- 5. Were the seals intact, signed, and dated correctly? YE ...NO ... NA 6. Were custody papers inside cooler?, I _ Y�E ...NO. NA I certify that 1 opened the cooler and answered questions 1-6 (Intial) t��( �• 7. Were custody seals on containers: YES( and Intact YES. .NO... A Were these signed and dated correctly? YES ... NO..4�A 8. Packing mat'I used? BubblewraG' P�asticPeanuts Vermiculite Foam Insert Paper Other None 9. Cooling process: (�/ ce Ice -pack Ice (direct contact) Dry ice /O"�ther None 10. Did all containers arrive in good condition (unbroken)? rlmt...NO.. NA 11. Were all container labels complete (#, date, signed, pres., etc)? ..NO ... NA 12. Did all container labels and tags agree with custody papers? _NO ... NA !L 13a. Were VOA vials received? e� ,ln0.&-<A b. Was there any observable headspace present in any VOA vial? YES ... NO..&, 14. Was there a Trip Blank in this cooler? YES .. O.. A If multiple coolers, sequence # I certify that 1 unloaded the cooler and answered ques ions 7-14 (Intial) 15a. On pres'd bottles, �i H test strips suggest preservation reached the correct pH level? YESA ..NA b. Did the bottle labels indicate that the correct preservatives were used ES ..NO ... NA 16 Was residual chlorine present? YES ... Nt I certifythat I checked for chlorine and PH as per SOP and answered questions 15-16 (Intial) 17. Were custody papers properly filled out (ink, signed, etc)? YE NO.. NA 18. Did you sign the custody papers In the appropriate place? 19. Were correct containers used for thianalysis requested? 20. Was sufficient amount of sample sent in each container? 21. Were there Non -Conformance issues at login? YE$ .Was a NCM generated? S .NO ... NA S NO ... NA S.. O.. NA ) BIS = Broken in shipment Cooler Receipt Form doc LF -I Revised 12/15/15 End of Form Page 44 of 46 4/30/2017 Chafttte Service Center Chan ofTestAmerica Temperature on Receipt C) Custody Record M DMA-ingWater7 Yes❑ /VoA THE LEADER IN ENVIRONMENTAL TESTING cr TAI _A1 2a n nnn client C,<-*\- 9 4 k& 2 L F-Jecl Manager SVNC,"_ S Co Date LI)Qq11:7- Cham of custody Number 287937 Address _ OLIW U Vilv� 6 y S _W_ 166 Telephone Number (Area Code)/Fax Number 40"i — _0604 Lab Number 1 Page __L_ Of 1 City StRte Zlp Code Sde ContactLab Contact wiC vA 4i4A Yk t Analysis (.4ltach /rst d more space /s needed) Specia//nstructions/ Conditions of Receipt Project Name and Location (State) AC-G cYc Can7L-r1Waybd/Number ConlracUPurdtase OMei/Quote No — C /o UV MWIN Containers & Preservatives Sample /.D. No and Descnpbon (Containers for each sample maybe combined on one line) Date Time ei 3 fV\W- qhq J r7- I �*A NtW-;)S1100 "- r � N r p (M\nr-- L —logs i5 v Ms -u t/ Poss/b/e Hazard /denbAcatlon ElNon-Hazard ❑ Flammable 1:1 slur, /mtant ElPoison B Unknown Sampla Disposal (A fee may be assessed rfsamp/es are retained ElReturn To client Dlsposa/By Lab ❑ Archive For Months longerthan 1 month) rum.arouna rime rrequueo` uG Hegmrements Ppr ecrty) ❑ 24 Hours ❑ 48 Hours ❑ 7Days ❑ MDays ❑ 21 Days A Other H} Ski \LE4i �y > Re/rngmshed By I y I p'tp 1 ReceeoIL A 1 n 1411 Date Time DISTRIBUTION. WH/TE- Returned to Client wdh Report, CANARY- Stays with the Sample, PINK- Fie/d Copy 0 m Login Sample Receipt Checklist Client Hart & Hickman, PC Login Number: 127126 List Number: 1 Creator: Vest, Laura E Question Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter The cooler's custody seal, if present, is intact True Sample custody seals, if present, are intact N/A The cooler or samples do not appear to have been compromised or True tampered with Samples were received on ice True Cooler Temperature is acceptable True Cooler Temperature is recorded True COC is present True COC is filled out in ink and legible True COC is filled out with all pertinent information True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels True Containers are not broken or leaking True Sample collection date/times are provided True Appropriate sample containers are used True Sample bottles are completely filled True Sample Preservation Verified N/A There is sufficient vol for all requested analyses, incl any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4") Multiphasic samples are not present True Samples do not require splitting or compositing True Residual Chlorine Checked N/A TestAmerica Nashville Page 46 of 46 Job Number 490-127126-1 SDG Number DSO -80 List Source: TestAmenca Nashville 4/30/2017 F3