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HomeMy WebLinkAboutNC0004978_FINAL_Marshall_CSA_Tables_2018_201801292018 Comprehensive Site Assessment Update January 2018 Marshall Steam Station TABLES SynTerra TABLE 2-1 WELL CONSTRUCTION DATA MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC IDENTIFICATION PROGRAM DATE INSTALLED MONITORING ZONE Flow Layer MATERIAL DIAMETER (INCHES) NORTHING (FEET) EASTING (FEET) MEASURING POINT TOC ELEVATION (Feet-MSL) Casing Stick Up (k) GROUND SURFACE ELEVATION (FEET- MSL) TOTAL WELL DEPTH''' (FEET BGS) MEASURED WELL DEPTH' (FEET TOC) SCREEN UPPER (BGS) SCREEN LOWER (BGS) SCREENED INTERVAL' (FEET INTERVAL' SCREEN LENGTH (FT) TOP OF SCREEN ELEVATION (FEET- MSL) BOTTOM OF SCREEN ELEVATION (FEET- MSL) MIDDLE OF SCREEN ELEVATION AB-10D CAMA 6/27/2015 Deep Transition PVC 6.0 683743.73 1415472.14 802.68 3.10 799.58 84.20 87.30 71.00 76.00 74.10 79.10 5 728.58 723.58 726.08 AB-l0BR CAMA 8/25/2016 Bedrock Bedrock PVC 2.0 683738.00 1415482.00 802.539 3.01 799.532 134.00 137.01 120.00 125.00 123.01 128.01 5 679.53 674.53 677.03 AB-30S CAMA 3/31/2015 Shallow Ash PVC 2.0 683755.48 1415452.07 802.41 2.87 799.54 27.87 30.74 9.00 24.00 11.87 26.87 15 790.54 775.54 783.04 AB-10SL CAMA 3/31/2015 Shallow Ash PVC 2.0 683751.65 1415457.75 802.52 3.00 799.52 56.00 59.00 40.00 50.00 43.00 53.00 30 759.52 749.52 754.52 AB-11D CAMA 6/30/2015 Deep Transition PVC 5.0 685049.51 1416180.09 799.95 3.11 796.84 88.11 91.22 77.00 82.00 80.11 85.11 5 719.84 714.84 717.34 AB-11S CAMA 6/23/2015 Shallow Saprolite PVC 2.0 685056.24 1416188.51 800.05 3.16 796.89 19.16 22.32 6.00 16.00 9.16 19.16 30 790.89 780.89 785.89 AB-12BR CAMA 9/1/2016 Bedrock Bedrock PVC 2.0 683502.00 1414695.00 795.428 2.84 792.589 114.60 114.60 100.50 105.50 103.34 108.34 5 692.09 687.09 689.59 AB-12D CAMA 4/30/2015 Deep Transition PVC 5.0 683503.70 1414672.93 795.45 2.89 792.56 73.69 76.58 62.00 67.00 64.89 69.89 5 730.56 725.56 728.06 AB-12S CAMA 3/26/2015 Shallow Ash PVC 2.0 683503.35 1414678.32 795.61 2.91 792.70 15.91 18.82 3.00 13.00 5.91 15.91 30 789.70 779.70 784.70 AB-12SL CAMA 3/26/2015 Shallow Ash PVC 2.0 683502.36 1414682.08 795.67 2.97 792.70 54.97 57.94 40.00 50.00 42.97 52.97 30 752.70 742.70 747.70 AB-13D CAMA 6/19/2015 Deep Transition PVC 6.0 684196.73 1413520.32 824.55 2.96 821.59 95.96 98.92 81.00 86.00 83.96 88.96 5 740.59 735.59 738.09 AB-13S CAMA 4/8/2015 Shallow Ash PVC 2.0 684180.48 1413524.42 823.73 2.52 821.21 33.52 36.04 14.80 29.80 17.32 32.32 15 806.41 791.41 798.91 AB-14D CAMA 6/8/2015 Deep Transition PVC 5.0 683676.24 1412767.69 824.11 2.66 821.45 93.76 96.42 80.00 85.00 82.66 87.66 5 741.45 736.45 738.95 AB-14S CAMA 6/4/2015 Shallow Ash PVC 2.0 683679.54 1412755.12 824.71 2.98 821.73 23.68 26.66 5.70 20.70 8.68 23.68 15 816.03 801.03 808.53 AB-15BR CAMA 6/16/2015 Bedrock Bedrock PVC 6.0 684803.85 1413514.37 823.01 2.97 820.04 118.77 121.74 107.00 112.00 109.97 114.97 5 713.04 708.04 710.54 AB-15D CAMA 6/1/2315 Deep Transition PVC 6.0 684822.45 1413524.15 823.04 2.78 820.26 77.78 80.56 64.00 69.00 66.78 71.78 5 756.26 751.26 753.76 AB-15S CAMA 4/4/2015 Shallow Ash PVC 2.0 684814.88 1413521.39 823.27 3.13 820.14 23.13 26.26 5.00 20.00 8.13 23.13 15 815.14 800.14 807.64 AB-15SL CAMA 4/3/2015 Shallow Ash PVC 2.0 684808.89 1413518.56 823.17 3.15 820.02 57.15 60.30 40.00 50.00 43.15 53.15 10 780.02 770.02 775.02 AB-16D CAMA 7/13/2015 Deep Transition PVC 6.0 685497.55 1413778.99 822.45 2.95 819.50 50.05 53.00 41.00 46.00 43.95 48.95 5 778.50 773.50 776.00 AB-16S CAMA 5/13/2015 Shallow Saprolite PVC 2.0 685490.38 1413794.53 822.08 3.06 819.02 16.66 19.72 3.20 13.20 6.26 16.26 30 815.82 805.82 810.82 AB-17D CAMA 6/16/2015 Deep Transition PVC 6.0 686446.33 1413066.01 833.56 2.98 830.58 123.98 126.96 106.00 111.00 108.98 113.98 5 724.58 719.58 722.08 AB-17S CAMA 4/6/2015 Shallow Ash PVC 2.0 686446.68 1413054.46 833.29 3.00 830.29 25.01 28.01 6.00 21.00 9.00 24.00 15 824.29 809.29 816.79 AB-18D CAMA 7/2/2015 Deep Transition PVC 6.0 685663.31 1412917.88 825.20 2.96 822.24 83.46 86.42 72.00 77.00 74.96 79.96 5 750.24 745.24 747.74 AB-185 CAMA 4/7/2015 Shallow Ash PVC 2.0 685664.48 1412929.98 825.40 3.14 822.26 16.64 1918 3.00 13.00 6.14 16.14 10 819.26 809.26 814.26 AB-1BRL CAMA 9/28/2017 Bedrock Bedrock PVC 2.0 681543.59 1417690.50 774.78 0.02 774.77 166.00 166.02 161.00 166.00 161.01 166.01 5 613.77 608.77 611.27 AB-1BR CAMA 7/8/2015 Bedrock Bedrock PVC 6.0 681572.86 1417706.31 777.21A 2.38 774.83 134.38 136.76 119.00 124.00 121.38 126.38 5 655.83 650.83 653.33 AB-11) CAMA 7/8/2015 Deep Transition PVC 6.0 681567.96 1417702.65 777.09A 2.40 774.93 99.90 102.30 91.00 96.00 93.40 98.40 5 683.69 678.69 681.19 AB -IS CAMA 7/1/2015 Shallow Saprolite PVC 2.0 681562.00 1417700.48 777.27A 2.71 774.75 23.71 26.42 5.50 20.00 8.21 23.21 15 769.06 754.06 761.56 AB-20D CAMA 6/26/2015 Deep Transition PVC 6.0 684634.94 1411519.25 892.35 3.01 889.34 147.31 150.32 139.20 144.20 142.21 147.21 5 750.14 745.14 747.64 AB-20S CAMA 5/1/2015 Shallow Ash PVC 2.0 684640.86 1411523.77 892.43 3.14 889.29 72.39 75.53 53.50 68.50 56.64 71.64 15 835.79 820.79 828.29 AB-21D CAMA 4/7/2015 Deep Transition PVC 5.0 681948.98 1414935.24 810.23 2.62 807.61 83.54 86.16 60.00 65.00 62.62 67.62 5 747.61 742.61 745.11 AB-21S CAMA 3/24/2015 Shallow Ash PVC 2.0 681953.18 1414925.09 810.66 2.71 807.95 30.71 33.42 13.00 28.00 15.71 30.71 15 794.95 779.95 787.45 AB-2D CAMA 7/8/2015 Deep Transition PVC 6.0 680479.38 1417087.65 781.44 2.96 778.48 104.06 107.02 91.00 96.00 93.96 98.96 5 687.48 682.48 684.98 AB-2S CAMA 7/2/2015 Shallow Saprolite PVC 2.0 680484.01 1417091.23 781.30 2.72 778.58 34.72 37.44 17.00 32.00 19.72 34.72 15 761.58 746.58 754.08 AB-31) CAMA 5/26/2015 Deep Transition PVC 5.0 680532.62 1415467.17 815.03 2.89 812.14 143.89 146.79 130.00 135.00 132.90 137.90 5 682.14 677.14 679.64 AB-3S CAMA 3/23/2015 Shallow Ash PVC 2.0 680539.34 1415469.71 815.08 3.08 812.00 26.58 29.66 8.00 23.50 11.08 26.08 15 804.00 789.00 796.50 AB-41) CAMA 4/14/2015 Deep Transition PVC 5.0 681015.22 1415006.25 810.01 2.84 807.17 87.44 90.28 72.00 77.00 74.34 79.34 5 735.67 730.67 733.17 AB-4S CAMA 3/20/2015 Shallow Ash PVC 2.0 681009.41 1415022.53 809.73 2.30 807.43 26.80 29.10 6.00 21.00 8.30 23.30 15 801.43 786.43 793.93 AB-4SL CAMA 3/20/2015 Shallow Ash PVC 2.0 681011.27 1415014.27 809.85 2.51 807.34 57.51 60.02 38.50 48.50 41.01 51.01 30 768.84 758.84 763.84 AB-SBR CAMA 6/20/2015 Bedrock Bedrock PVC 6.0 680719.35 1414280.82 807.55 3.10 804.45 125.60 128.70 105.00 110.00 108.10 113.10 5 699.45 694.45 696.95 AB-51) CAMA 6/3/2015 Deep Transition PVC 6.0 680714.03 1414278.89 807.52 3.05 804.47 88.05 91.10 78.00 83.00 81.05 86.05 5 726.47 721.47 723.97 AB-5S CAMA 3/24/2015 Shallow Ash PVC 2.0 680708.77 1414277.38 807.50 2.94 804.56 21.44 24.38 3.20 18.20 6.14 21.14 15 801.36 786.36 793.86 AB-6BRL CAMA 9/29/2017 Bedrock Bedrock PVC 2.0 682285.34 1412826.39 836.76 2.61 834.14 160.00 -- 155.00 160.00 157.61 162.61 5 679.14 674.14 676.64 AB-6BR CAMA 6/23/2015 Bedrock Bedrock PVC 6.0 682246.45 1412848.99 835.77 2.93 832.84 121.93 124.86 105.00 110.00 107.93 112.93 5 727.84 722.84 725.34 AB-6BRA -- -- Bedrock Bedrock -- -- 682267.38 1412842.78 -- 2.93 -- -- -- -- -- -- -- -- -- -- -- AB-61) CAMA 4/22/2015 Deep Transition PVC 5.0 682239.65 1412851.32 835.36 2.46 832.90 78.26 80.72 62.50 67.50 64.96 69.96 5 770.40 765.40 767.90 AB-6S CAMA 4/22/2015 Shallow Ash PVC 2.0 682232.33 1412854.25 835.38 2.61 832.77 24.61 27.22 7.00 22.00 9.61 24.61 15 825.77 810.77 818.27 AB-71) CAMA 5/15/2015 Deep Transition PVC 5.0 682818.72 1413214.92 834.13 2.92 831.21 95.92 98.84 79.00 84.00 81.92 86.92 5 752.21 747.21 749.71 AB-7S CAMA 3/25/2015 Shallow Ash PVC 2.0 682815.06 1413224.11 834.29 2.86 831.43 23.86 26.72 5.00 20.00 7.86 22.86 15 826.43 811.43 818.93 AB-81) CAMA 5/8/2015 Deep Transition PVC 5.0 682836.10 1414032.89 800.50 3.00 797.50 104.30 107.30 95.00 100.00 98.00 103.00 5 702.50 697.50 700.00 AB-8S CAMA 4/8/2015 Shallow Ash PVC 2.0 682831.71 1414030.28 800.33 2.91 797.42 17.94 20.85 3.00 13.00 5.91 15.91 10 794.42 784.42 789.42 AB-9BR CAMA 7/10/2015 Bedrock Bedrock PVC 4.0 683043.55 1415269.85 797.64 2.70 794.94 112.80 115.50 78.00 83.00 80.70 85.70 5 716.94 711.94 714.44 AB-91) CAMA 4/28/2015 Deep Transition PVC 5.0 683050.64 1415263.19 797.26 2.50 794.76 63.00 65.50 48.00 53.00 50.50 55.50 5 746.76 741.76 744.26 AB-9S CAMA 4/27/2015 Shallow Saprolite PVC 2.0 683044.02 1415261.07 797.78 2.40 795.38 15.40 17.80 3.00 10.00 5.40 15.40 30 792.38 782.38 787.38 AL-1BR CAMA 8/30/2016 Bedrock Bedrock PVC 2.0 683136.00 1417013.00 818.067 3.04 815.023 132.00 -- 122.00 127.00 125.04 130.04 5 693.02 688.02 690.52 AL-11) CAMA 4/30/2015 Deep Transition PVC 5.0 683144.37 1417007.50 817.94 2.89 815.05 92.29 95.18 79.60 84.60 82.49 87.49 5 735.45 730.45 732.95 AL-1S CAMA 4/2/2015 Shallow Saprolite PVC 2.0 683157.68 1417002.90 817.97 3.04 814.93 50.34 53.38 31.50 46.50 34.54 49.54 15 783.43 768.43 775.93 AL-2BRLL CAMA 9/25/2017 Bedrock Bedrock PVC 2.0 684602.98 1414853.87 914.63 2.86 911.77 345.00 -- 340.00 345.00 342.86 347.86 5 571.77 566.77 569.27 AL-2BRL -- -- -- -- -- -- -- -- 915.389 2.72 912.666 -- -- -- -- 257.30 262.30 5 658.09 653.09 655.59 AL-2BR CAMA 7/8/2015 Bedrock Bedrock PVC 6.0 684615.63 1414830.04 915.10 2.32 912.78 230.82 233.14 203.60 208.60 205.92 210.92 5 709.18 704.18 706.68 AL-21) CAMA 5/27/2015 Deep Transition PVC 6.0 684620.72 1414826.75 915.33 2.50 912.83 164.50 167.00 152.00 157.00 154.50 159.50 5 760.83 755.83 758.33 AL-2S CAMA 4/28/2015 Shallow Saprolite PVC 2.0 684610.22 1414833.97 915.41 2.88 912.53 130.18 133.06 111.70 126.70 114.58 129.58 15 800.83 785.83 793.33 AL-3BR CAMA 8/30/2016 Bedrock Bedrock PVC 2.0 685509.00 1415050.00 919.02 2.99 916.03 239.30 -- 228.50 233.50 231.49 236.49 5 687.53 682.53 685.03 AL-3D CAMA 5/29/2015 Deep Transition PVC 6.0 685495.15 1415062.57 918.69 2.70 915.99 189.70 192.40 178.50 1 183.50 181.20 186.20 5 737.49 732.49 734.99 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 2-1 Well Construction Page 1 of 3 TABLE 2-1 WELL CONSTRUCTION DATA MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC IDENTIFICATION PROGRAM DATE INSTALLED MONITORING ZONE Flow Layer MATERIAL DIAMETER (INCHES) NORTHING (FEET) EASTING (FEET) MEASURING POINT TOC ELEVATION (Feet-MSL) Casing Stick Up (k) GROUND SURFACE ELEVATION (FEET- MSL) TOTAL WELL DEPTH''' (FEET BGS) MEASURED WELL DEPTH' (FEET TOC) SCREEN UPPER (BGS) SCREEN LOWER (BGS) SCREENED INTERVAL' (FEET INTERVAL' SCREEN LENGTH (FT) TOP OF SCREEN ELEVATION (FEET- MSL) BOTTOM OF SCREEN ELEVATION (FEET- MSL) MIDDLE OF SCREEN ELEVATION AL-35 CAMA 4/28/201S Shallow Ash PVC 2.0 685501.12 1415062.23 918.59 2.82 915.77 120.42 123.24 96.80 117.60 99.62 120.42 21 818.97 798.17 808.57 AL-4BR CAMA 8/30/2016 Bedrock Bedrock PVC 2.0 685140.00 1414559.00 918.715 2.97 915.747 211.00 - 179.00 184.00 181.97 186.97 5 736.75 731.75 734.25 AL-4BRL CAMA 9/27/2017 Bedrock Bedrock PVC 2.0 685158.92 1414585.85 918.74 2.90 915.85 260.00 - 250.00 260.00 252.90 262.90 10 665.85 655.85 660.85 AL-41) CAMA 6/28/2015 Deep Transition PVC 6.0 685149.26 1414565.27 918.44 2.43 916.01 159.83 162.26 148.40 153.40 150.83 155.83 5 767.61 762.61 765.11 BG-1BR CAMA 4/18/2015 Bedrock Bedrock PVC 6.0 687812.80 1419851.83 817.94 3.09 814.85 94.09 97.18 84.00 89.00 87.09 92.09 5 730.85 725.85 728.35 BG-1BRA -- Bedrock Bedrock -- - 687823.58 1419843.84 -- 3.01 - - -- - -- -- -- -- - -- BG-SD CAMA 6/24/2015 Deep Transition PVC 6.0 687818.48 1419859.84 817.63 2.88 814.75 45.28 48.16 35.00 40.00 37.88 42.88 5 779.75 774.75 777.25 BG-IS CAMA 6/3/2015 Shallow Saprolite PVC 2.0 687816.43 1419863.84 817.35 2.56 814.79 20.06 22.62 5.20 15.20 10.06 20.06 10 807.29 797.29 802.29 BG-2BR CAMA 6/23/2015 Bedrock Bedrock PVC 6.0 686181.35 1418418.84 814.81 2.82 811.99 63.45 66.27 50.00 55.00 52.82 57.82 5 761.99 756.99 759.49 BG-2S CAMA 6/18/2015 Shallow Saprolite PVC 2.0 686177.84 1418417.96 814.33 2.51 811.82 19.53 22.04 5.80 15.80 9.51 19.51 10 804.82 794.82 799.82 BG-3BR CAMA 4/5/2015 Bedrock Bedrock PVC 6.0 686843.40 1418979.67 867.69 2.97 864.72 113.97 116.93 105.00 110.00 107.97 112.97 5 759.72 754.72 757.22 BG-3D CAMA 6/25/2015 Deep Bedrock PVC 6.0 686842.13 1419003.32 864.18 2.62 861.56 73.03 75.65 59.00 64.00 61.62 66.62 5 802.56 797.56 800.06 BG-3S CAMA 5/4/2015 Shallow Saprolite PVC 2.0 686842.99 1419015.34 863.03 2.28 860.75 42.09 44.37 22.20 32.20 24.48 34.48 10 838.55 828.55 833.55 CCR-10D CCR 5/10/2016 Deep Transition PVC 2.0 682235.68 1417522.04 796.01 3.35 792.66 73.43 76.78 65.08 70.08 68.43 73.43 5 727.58 722.58 725.08 CCR-10S CCR 4/28/2016 Shallow Saprolite PVC 2.0 682238.94 1417517.24 796.46 3.55 792.91 22.76 26.31 4.21 19.21 7.76 22.76 15 788.70 773.70 781.20 CCR-11D CCR 4/22/2016 Deep Transition PVC 2.0 682078.97 1417292.17 793.86 2.59 791.27 79.87 82.46 72.28 77.28 74.87 79.87 5 718.99 713.99 716.49 CCR-11S CCR 4/21/2016 Shallow Saprolite PVC 2.0 682082.49 1417288.44 794.24 2.68 791.56 22.81 25.49 5.13 20.13 7.81 22.81 15 786.43 771.43 778.93 CCR-12D CCR 4/27/2016 Deep Transition PVC 2.0 682446.12 1416714.27 793.84 2.75 791.09 89.66 92.41 81.91 86.91 84.66 89.66 5 709.18 704.18 706.68 CCR-12S CCR 4/26/2016 Shallow Saprolite PVC 2.0 682451.33 1416717.77 793.85 2.63 791.22 23.40 26.03 5.77 20.77 8.40 23.40 15 785.45 770.45 777.95 CCR-13D CCR 4/27/2016 Deep Transition PVC 2.0 682838.47 1416772.08 800.02 2.81 797.21 84.87 87.68 77.06 82.06 79.87 84.87 5 720.15 715.15 717.65 CCR-13S CCR 4/27/2016 Shallow Saprolite PVC 2.0 682830.07 1416766.19 799.68 2.93 796.75 74.11 77.04 56.18 71.18 59.11 74.11 15 740.57 725.57 733.07 CCR-14D CCR 5/10/2016 Deep Transition PVC 2.0 683281.01 1416626.84 796.11 2.88 793.23 64.59 67.47 56.71 61.71 59.59 64.59 5 736.52 731.52 734.02 CCR-14S CCR 5/4/2016 Shallow Saprolite PVC 2.0 683291.34 1416624.08 795.97 2.54 793.43 22.22 24.76 4.68 19.68 7.22 22.22 15 788.75 773.75 781.25 CCR-15D CCR 4/22/2016 Deep Transition PVC 2.0 683867.76 1415819.89 805.14 2.72 802.42 61.23 63.95 53.51 58.51 56.23 61.23 5 748.91 743.91 746.41 CCR-1SS CCR 4/15/2016 Shallow Saprolite PVC 2.0 683863.39 1415815.68 804.76 2.52 802.24 21.51 24.03 3.99 18.99 6.51 21.51 15 798.25 783.25 790.75 CCR-16D CCR 4/25/2016 Deep Transition PVC 2.0 684323.00 1416034.21 819.37 2.95 816.42 51.45 54.40 43.50 48.50 46.45 51.45 5 772.92 767.92 770.42 CCR-16S CCR 4/16/2016 Shallow Saprolite PVC 2.0 684327.66 1416038.12 819.32 3.17 816.15 23.70 26.87 5.53 20.53 8.70 23.70 15 810.62 795.62 803.12 CCR-1D CCR 4/21/2016 Deep Transition PVC 2.0 679956.53 1415048.41 809.32 1.90 807.42 90.89 92.79 83.99 88.99 85.89 90.89 5 723.43 718.43 720.93 CCR-IS CCR 4/13/2016 Shallow Saprolite PVC 2.0 679962.30 1415053.47 810.31 2.97 807.34 37.91 40.88 19.94 34.94 22.91 37.91 15 787.40 772.40 779.90 CCR-2D CCR 4/20/2016 Deep Transition PVC 2.0 680115.92 1415484.79 806.89 2.77 804.12 81.96 84.73 74.19 79.19 76.96 81.96 5 729.93 724.93 727.43 CCR-2S CCR 4/14/2016 Shallow Saprolite PVC 2.0 680118.48 1415490.52 806.56 2.32 804.24 34.75 37.07 17.43 32.43 19.75 34.75 15 786.81 771.81 779.31 CCR-3D CCR 5/12/2016 Deep Transition PVC 2.0 679259.37 1416472.78 780.44 3.34 777.10 101.36 104.70 93.02 98.02 96.36 101.36 5 684.08 679.08 681.58 CCR-3S CCR 5/10/2016 Shallow Saprolite PVC 2.0 679264.24 1416475.78 780.28 2.89 777.39 36.23 39.12 18.34 33.34 21.23 36.23 15 759.05 744.05 751.55 CCR-4D CCR 5/3/2016 Deep Transition PVC 2.0 679823.07 1416864.75 783.82 2.88 780.94 105.25 108.13 97.37 102.37 100.25 105.25 5 683.57 678.57 681.07 CCR-4S CCR 4/20/2016 Shallow Saprolite PVC 2.0 679816.52 1416860.48 783.66 2.81 780.85 35.24 38.05 17.43 32.43 20.24 35.24 15 763.42 748.42 755.92 CCR-SD CCR 5/5/2016 Deep Transition PVC 2.0 680244.25 1417133.74 776.97 2.73 774.24 85.14 87.87 77.41 82.41 80.14 85.14 5 696.83 691.83 694.33 CCR-SS CCR 4/19/2016 Shallow Saprolite PVC 2.0 680250.77 1417138.33 777.25 3.02 774.23 33.34 36.36 15.32 30.32 18.34 33.34 15 758.91 743.91 751.41 CCR-9D CCR 5/13/2016 Deep Transition PVC 2.0 681884.33 1417909.29 799.80 2.96 796.84 100.46 103.42 92.50 97.50 95.46 100.46 5 704.34 699.34 701.84 CCR-9DA CCR 2/14/2017 Deep Transition PVC 2.0 681903.07 1417913.56 799.77 12.93 796.84 120.25 123.18 111.17 1116.17 114.10 119.10 5 1685.67 680.67 683.17 CCR-9S CCR 4/29/2016 Shallow Saprolite PVC 2.0 681882.90 1417903.10 799.88 2.97 796.91 45.20 48.17 27.23 42.23 30.20 45.20 15 769.68 754.68 762.18 GWA-IOD CAMA 3/24/2016 Deep Transition PVC 6.0 683550.78 1417401.67 778.10 2.83 775.27 122.84 125.67 113.50 118.00 116.34 120.84 5 661.77 657.27 659.52 GWA-IOS CAMA 4/6/2016 Shallow Saprolite PVC 2.0 683558.12 1417398.84 777.65 2.34 775.32 23.34 25.67 5.00 20.00 7.34 22.34 15 770.32 755.32 762.82 GWA-11BR CAMA 3/8/2017 Bedrock Bedrock PVC 2.0 682799.86 1417430.69 810.026 3.02 807.00 155.00 158.02 150.00 155.00 153.02 158.02 5 657.00 652.00 654.50 GWA-11D CAMA 3/9/2016 Deep Transition PVC 6.0 682800.44 1417422.52 811.24 3.00 808.24 129.00 131.99 110.00 115.00 112.80 117.80 5 698.44 693.44 695.94 GWA-11S CAMA 3/11/2016 Shallow Saprolite PVC 2.0 682793.57 1417401.58 812.55 2.96 809.59 78.96 81.92 40.00 55.00 42.76 57.76 115 769.79 754.79 762.29 GWA-12BR CAMA 5/24/2016 Bedrock Bedrock PVC 6.0 682081.55 1410362.43 875.65 -0.37 876.02 147.63 147.27 113.00 118.00 112.63 117.63 5 763.02 758.02 760.52 GWA-12D CAMA 5/13/2016 Deep Transition PVC 6.0 682092.53 1410359.68 875.83 -0.46 876.29 108.54 108.08 88.00 93.00 87.54 92.54 5 788.29 783.29 785.79 GWA-12S CAMA 5/24/2016 Shallow Saprolite PVC 2.0 682077.92 1410362.36 887.87 -0.14 888.01 25.06 24.92 10.00 25.00 9.46 24.46 15 878.41 863.41 870.91 GWA-13D CAMA 5/3/2016 Deep Transition PVC 6.0 683383.12 1410266.56 888.281 0.14 888.143 198.82 198.96 133.50 138.50 133.32 138.32 5 754.96 749.96 752.46 GWA-13DA -- -- Transition Zone Deep -- - 683383.24 1410260.62 -- 0.14 -- -- -- -- -- - -- -- -- -- -- GWA-13S CAMA 5/25/2016 Shallow Saprolite PVC 2.0 683379.30 1410275.40 887.87 -0.14 888.01 31.06 30.92 14.50 29.50 14.36 29.36 15 873.51 858.51 866.01 GWA-14D CAMA 3/13/2017 Deep Transition PVC 2.0 685969.66 1410111.63 911.405 -0.08 911.481 110.00 109.92 104.50 109.50 104.42 109.42 5 1806.98 801.98 804.48 GWA-14S CAMA 3/13/2017 Shallow Saprolite PVC 2.0 685968.00 1410101.56 910.688 -0.55 911.236 50.00 - 35.00 50.00 34.45 49.45 15 876.24 861.24 868.74 GWA-15S CAMA 3/10/2017 Shallow Saprolite PVC 2.0 682858.33 1417583.58 781.387 2.86 778.525 37.00 - 20.80 35.80 23.66 38.66 15 757.73 742.73 750.23 GWA-1BR CAMA 7/6/2015 Bedrock Bedrock PVC 6.0 679326.85 1416338.18 806.10 2.95 803.15 159.95 162.90 151.50 156.40 154.45 159.45 5 651.65 646.65 649.15 GWA-11) CAMA 7/2/2015 Deep Transition PVC 6.0 679331.07 1416339.79 806.05 2.78 803.27 127.28 130.06 119.00 124.00 121.78 126.78 5 684.27 679.27 681.77 GWA-1S CAMA 6/29/2015 Shallow Saprolite PVC 2.0 679336.11 1416341.98 805.97 2.81 803.16 55.81 58.62 38.00 53.00 40.81 55.81 15 765.16 750.16 757.66 GWA-2DA CAMA 3/9/2017 Deep Transition PVC 2.0 679263.20 1414083.88 826.59 2.80 823.7935 99.00 -- 94.00 99.00 96.80 101.80 5 729.79 724.79 727.29 GWA-21) CAMA 6/2/2015 Deep Transition PVC 5.0 679252.88 1414089.34 826.69 2.93 823.76 103.93 106.86 78.00 83.00 80.93 85.93 5 745.76 740.76 743.26 GWA-2S CAMA 5/14/2015 Shallow Saprolite PVC 2.0 679246.18 1414091.25 826.97 3.06 823.91 50.06 53.12 13.50 29.50 13.50 32.56 19 813.47 794.41 803.94 GWA-31) CAMA 7/15/2015 Deep Transition PVC 5.0 685962.19 1411086.36 839.44 2.96 836.48 54.16 57.12 36.00 41.00 38.96 43.96 5 800.48 795.48 797.98 GWA-3S CAMA 7/13/2015 Shallow Soil PVC 2.0 685961.42 1411080.72 839.24 2.82 836.42 18.02 20.84 3.00 13.00 5.82 15.82 10 833.42 823.42 828.42 GWA-4D CAMA/CCR 6/12/2015 Deep Transition PVC 5.0 686783.39 1411776.91 902.45 3.07 899.38 90.07 93.14 81.00 86.00 84.07 89.07 5 818.38 813.38 815.88 GWA-4S CAMA/CCR 5/19/2015 Shallow Saprolite PVC 2.0 686776.57 1411777.34 901.97 2.99 898.98 67.99 70.98 49.20 64.20 52.19 67.19 15 849.78 834.78 842.28 GWA-SD CAMA/CCR 7/8/2015 Deep Transition PVC 5.0 686811.16 1415693.60 847.17 2.81 844.36 52.31 55.12 43.50 48.50 46.31 51.31 5 800.86 795.86 798.36 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 2-1 Well Construction Page 2 of 3 TABLE 2-1 WELL CONSTRUCTION DATA MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC IDENTIFICATION PROGRAM DATE INSTALLED MONITORING ZONE Flow layer MATERIAL DIAMETER (INCHES) NORTHING (FEET) EASTING (FEET) MEASURING POINT TOC ELEVATION (Feet-MSL) Casing Stick Up (ft) GROUND SURFACE ELEVATION (FEET- MSL) TOTAL WELL DEPTH''' (FEET BGS) MEASURED WELL DEPTH' (FEET TOC) SCREEN UPPER (BGS) SCREEN LOWER (BGS) SCREENED INTERVAL' (FEET INTERVAL' SCREEN LENGTH (FT) TOP OF SCREEN ELEVATION (FEET- MSL) BOTTOM OF SCREEN ELEVATION (FEET- MSL) MIDDLE OF SCREEN ELEVATION GWA-5S CAMA/CCR 7/2/2015 Shallow Soil PVC 2.0 686815.49 1415696.44 847.22 2.92 844.30 37.42 40.34 24.50 34.50 27.42 37.42 10 819.80 809.80 814.80 GWA-6D CAMA 7/7/2015 Bedrock Bedrock PVC 6.0 686115.40 1416996.20 845.72 2.40 843.32 117.91 120.31 102.00 107.00 104.40 109.40 5 741.32 736.32 738.82 GWA-6S CAMA 6/22/2015 Shallow Saprolite PVC 2.0 686100.74 1416987.88 845.37 2.38 842.99 52.88 55.26 37.70 47.70 40.08 50.08 10 805.29 795.29 800.29 GWA-7D CAMA 6/17/2015 Deep Transition PVC 6.0 684227.62 1416711.93 812.50 2.95 809.55 37.99 40.94 25.50 30.50 28.45 33.45 5 784.05 779.05 781.55 GWA-7S CAMA 5/21/2017 Shallow Saprolite PVC 2.0 684231.64 1416725.60 810.72 2.92 807.80 21.92 24.84 9.00 19.00 11.92 21.92 10 798.80 788.80 793.80 GWA-8D CAMA 7/12/2015 Bedrock Bedrock PVC 5.0 687478.91 1415906.06 853.68 3.09 850.59 64.29 67.38 56.00 61.00 59.09 64.09 5 794.59 789.59 792.09 GWA-8S CAMA 7/12/2015 Shallow Saprolite PVC 2.0 687474.71 1415902.00 852.90 3.15 849.75 41.15 44.30 23.00 38.00 26.15 41.15 15 826.75 811.75 819.25 GWA-9BR CAMA 7/1/2015 Bedrock Bedrock PVC 6.0 685030.13 1410459.13 848.45 2.92 845.53 110.00 112.92 84.00 89.00 86.92 91.92 5 761.53 756.53 759.03 M-23 Piezometer 5/14/2008 Deep Transition PVC 1.0 -- -- 840.24 2.51 837.73 22.00 24.51 12.00 22.00 14.51 24.51 10 825.73 815.73 820.73 M-45 Piezometer 5/14/2008 Deep Transition PVC 1.0 -- -- 848.81 2.59 846.22 34.00 36.59 24.00 34.00 26.59 36.59 10 822.22 812.22 817.22 M-6 Piezometer 11/14/2007 Shallow Saprolite PVC 2.0 -- -- 839.22 2.86 836.36 30.00 32.86 15.00 30.00 17.86 32.86 is 821.36 806.36 813.86 MS-1 Piezometer 12/3/2002 Shallow Saprolite PVC 2.0 680783.30 1413134.40 916.32 2.99 813.33 24.00 26.99 14.00 24.00 16.99 26.99 10 899.33 889.33 894.33 MS-10 Landfill -- Shallow Saprolite PVC 2.0 681027.60 1411623.00 851.29 3.00 848.29 23.34 26.34 13.34 23.34 16.34 26.34 10 834.95 824.95 829.95 MS-11 Landfill -- Shallow Saprolite PVC 2.0 680297.50 1411565.00 859.78 2.91 856.87 42.72 45.63 32.72 42.72 35.63 45.63 10 824.15 814.15 819.15 MS-12 Landfill -- Shallow Saprolite PVC 2.0 679540.10 1412087.00 835.66 2.96 832.70 31.09 34.05 21.09 31.09 24.05 34.05 10 811.61 801.61 806.61 MS-13 Landfill -- Shallow Saprolite PVC 2.0 679732.80 1412501.00 841.90 2.71 839.19 41.52 44.23 31.52 41.52 34.23 44.23 10 807.67 797.67 802.67 MS-14 Landfill -- Shallow Saprolite PVC 2.0 679968.40 1413124.00 844.07 2.80 841.27 44.38 47.18 34.38 44.38 37.18 47.18 10 806.89 796.89 801.89 MS-15 Landfill -- Shallow Saprolite PVC 2.0 680428.00 1412428.00 861.47 3.05 858.42 63.08 66.13 53.08 63.08 56.13 66.13 10 805.34 795.34 800.34 MS-16 Landfill -- Transition Zone Deep PVC 2.0 681142.30 1412485.00 836.98 2.73 834.25 37.46 40.19 27.46 37.46 30.19 40.19 10 806.79 796.79 801.79 MS-2 Piezometer 1/6/2003 Shallow Saprolite PVC 2.0 680048.90 1413358.80 823.18 3.01 820.18 29.50 32.51 19.50 29.50 22.51 32.51 30 800.67 790.67 795.67 MS-3 Piezometer 12/3/2002 Shallow Saprolite PVC 2.0 679780.70 1413390.60 814.53 3.03 811.50 20.00 23.03 10.00 20.00 13.03 23.03 10 801.50 791.50 796.50 MS-4 Piezometer 1/8/2003 Shallow Saprolite PVC 2.0 679168.90 1412970.30 847.68 3.08 844.60 46.00 49.08 36.00 46.00 39.08 49.08 10 808.60 798.60 803.60 MS-5 Piezometer 12/18/2002 Shallow Saprolite PVC 2.0 679223.20 1412595.40 842.04 2.94 839.10 38.00 40.94 28.00 38.00 30.94 40.94 10 1811.10 801.10 806.10 MS-6 Piezometer 12/17/2002 Shallow Saprolite PVC 2.0 679732.80 1412500.70 841.90 2.71 839.19 38.00 40.71 28.00 38.00 30.71 40.71 10 811.19 801.19 806.19 MS-7 Piezometer 1/3/2003 Shallow Saprolite PVC 2.0 680161.50 1412251.30 836.18 3.04 833.14 26.00 29.04 16.00 26.00 19.04 29.04 10 817.14 807.14 812.14 MS-8 Landfill 1/14/2003 Shallow Saprolite PVC 2.0 681496.00 1412015.00 872.34 2.99 869.35 51.58 54.57 20.00 30.00 22.99 32.99 30 849.35 839.35 844.35 MS-9 Landfill 1/16/2003 Shallow Saprolite PVC 2.0 681384.50 1412181.70 868.04 2.68 865.36 53.00 55.68 40.00 50.00 42.68 52.68 10 825.36 815.36 820.36 MW-1 Landfill -- Shallow Saprolite PVC 2.0 682767.00 1417125.00 823.70 2.50 821.20 78.75 81.25 67.10 77.10 69.60 79.60 10 754.10 744.10 749.10 MW-IOD NPDES 7/27/2010 Deep Transition PVC 2.0 681327.00 1418119.00 772.04 2.04 770.00 87.47 89.51 82.47 87.47 84.51 89.51 5 687.53 682.53 685.03 lVi NPDES 7/26/2010 Shallow Saprolite PVC 2.0 681328.00 1418114.00 772.05 2.31 769.74 29.21 31.52 14.21 29.21 16.52 31.52 15 755.53 740.53 748.03 MW-11D NPDES 7/29/2010 Deep Transition PVC 2.0 682060.00 1411710.00 884.67 2.72 881.95 93.10 95.82 88.10 93.10 90.82 95.82 5 793.85 788.85 791.35 MW-11S NPDES 7/30/2010 Shallow Saprolite PVC 2.0 682062.00 1411706.00 884.99 2.98 882.01 54.12 57.10 39.12 54.12 42.10 57.10 15 842.89 827.89 835.39 MW-12D NPDES 8/3/2030 Deep Transition PVC 2.0 683409.00 1410712.00 871.88 2.87 869.01 98.30 101.17 93.30 98.30 96.17 101.17 5 775.71 770.71 773.21 MW-12S NPDES 8/3/2030 Shallow Saprolite PVC 2.0 683414.00 1410714.00 871.86 2.84 869.02 25.10 27.94 10.10 25.10 12.94 27.94 15 858.92 843.92 851.42 MW-13D NPDES 8/4/2030 Deep Transition PVC 2.0 685017.00 1410464.00 847.05 2.61 844.44 48.55 51.16 43.55 48.55 46.16 51.16 5 800.89 795.89 798.39 MW-13S NPDES 8/6/2030 Shallow Saprolite PVC 2.0 685021.00 1410462.00 847.49 2.59 844.90 20.88 23.47 5.88 20.88 8.47 23.47 1s 839.02 824.02 831.52 MW-14BR CAMA -- Bedrock Bedrock PVC 5.0 683634.61 1416992.14 810.49 2.84 807.65 107.84 110.68 99.00 104.00 101.84 106.84 5 708.65 703.65 706.15 MW-14D NPDES 7/28/2010 Deep Transition PVC 2.0 683626.00 1416999.00 811.43 2.76 808.67 62.60 65.36 57.60 62.60 60.36 65.36 5 751.07 746.07 748.57 MW-14S NPDES 7/30/2010 Shallow Saprolite PVC 2.0 683629.00 1416995.00 811.29 3.06 808.23 46.87 49.93 31.87 46.87 34.93 49.93 15 776.36 761.36 768.86 MW-2 Landfill 6/28/1989 Shallow Saprolite PVC 2.0 683834.00 1415046.00 797.21 2.31 794.90 35.10 37.41 23.00 33.00 25.31 35.31 10 771.90 761.90 766.90 MW-3 Landfill 6/29/1989 Shallow Saprolite PVC 2.0 685991.00 1415309.00 813.07 2.07 811.00 28.15 30.22 15.90 25.90 17.97 27.97 10 795.10 785.10 790.10 MW-4 NPDES -- Shallow Saprolite PVC 2.0 686723.00 1414467.00 866.42 2.67 863.75 50.20 52.87 40.20 50.20 42.87 52.87 10 823.55 813.55 818.55 MW-4D NPDES 10/12/2006 Bedrock Bedrock PVC 2.0 686715.00 1414462.00 866.74 3.37 863.37 64.18 67.55 55.50 60.50 58.87 63.87 5 807.87 802.87 805.37 MW-5 Landfill 5/22/2000 Shallow Saprolite PVC 2.0 684782.00 1415744.00 822.69 2.50 820.19 30.71 33.21 18.00 28.00 20.50 30.50 10 802.19 792.19 797.19 Ni CCR 10/11/2006 Deep Transition PVC 2.0 682253.00 1417831.00 791.19 3.04 788.15 87.53 90.57 82.53 87.53 85.57 90.57 5 705.62 700.62 703.12 MW-6S CCR 10/12/2006 Shallow Saprolite PVC 2.0 682250.00 1417836.00 790.35 2.89 787.46 24.88 27.77 14.88 24.88 17.77 27.77 10 772.58 762.58 767.58 MW-7D CCR 10/9/2006 Deep Transition PVC 2.0 681379.00 1417631.00 776.85 3.95 772.90 66.44 70.39 61.44 66.44 65.39 70.39 5 711.46 706.46 708.96 MW-7S CCR 10/10/2006 Shallow Saprolite PVC 2.0 681375.00 1417629.00 775.99 2.89 773.10 20.60 23.49 10.60 20.60 13.49 23.49 10 762.50 752.50 757.50 MW-8D CCR 10/10/2006 Deep Transition PVC 2.0 680944.00 1417513.00 775.18 3.84 771.34 97.70 101.54 92.70 97.70 96.54 101.54 5 678.64 673.64 676.14 MW-85 CCR 10/10/2006 Shallow Saprolite PVC 2.0 680948.00 1417509.00 775.34 3.80 771.54 27.12 30.92 17.12 27.12 20.92 30.92 30 754.42 744.42 749.42 MW-9D CCR 10/10/2006 Deep Transition PVC 2.0 680637.00 1417358.00 777.38 3.04 774.34 95.20 98.24 90.20 95.20 93.24 98.24 5 684.14 679.14 681.64 MW-95 CCR 10/11/2006 Shallow Saprolite PVC 2.0 680639.00 1417349.00 777.34 3.12 774.22 30.78 33.90 20.78 30.78 23.90 33.90 10 753.44 743.44 748.44 OB-1(Ash Basin) CAMA -- Shallow Saprolite PVC 2.0 681741.34 1413327.90 850.57 2.98 847.59 72.51 75.49 39.70 55.50 42.68 58.48 16 807.89 792.09 799.99 OB-1(Dry Ash Landfill) Landfill - Shallow Saprolite PVC 2.0 682648.00 1417081.00 825.85 2.25 823.60 65.50 67.75 53.20 63.20 55.45 65.45 10 770.40 760.40 765.40 OB-2(MW-6) Landfill - Shallow Saprolite PVC 2.0 685227.10 1414675.00 919.65 2.47 917.18 122.14 124.61 102.50 117.50 104.97 119.97 15 814.68 799.68 807.18 OB-3(MW-7) Landfill - Shallow Saprolite PVC 2.0 685380.10 1414418.00 859.16 2.60 856.56 57.25 59.85 39.00 54.00 41.60 56.60 15 8177 6 802.56 810.06 -- Information not available 1 - Water levels taken on May 22, 2017; Well depths initially measured by Pace Analytical and updated when new wells installed. 2 - "Boring Depth" is the total depth of soil boring; 'Total Well Depth" is the depth to the bottom of the filter pack. 3 - Values measured during well installation. * Estimated until ground surface elevation is resurveyed. ^ Value does not reflect recent well modification to Flush mount Prepared by: ENK Checked by: DMY P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 2-1 Well Construction Page 3 of 3 TABLE 2-2 NPDES GROUNDWATER MONITORING REQUIREMENTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Monitoring Wells PARAMETERS Frequency Laboratory Parameters Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Cobalt Chromium Copper Iron Monitoring Lead Magnesium Manganese Molybdenum Wells: MW-4, Mercury Nickel Potassium Selenium MW-4D, MW- 10S, MW-10D, MW-11S MW- 1113, MW-12S, MW-12D, MW- 13S, MW-13D, M W-14S, M W- February, June, October Sodium Strontium Thallium Vanadium -Zinc Chloride Sulfate Alkalinity Bicarbonate Carbonate Total Dissolved Solids Total Suspended Solids Field Parameters 14D Turbidity pH Temperature Specific Conductance Oxidation Dissolved Oxygen Reduction Potential Water level Source: Marshall Steam Station Marshall WW Permit #NC0004987 Final Report, 2016. Page 1 of 1 TABLE 2-3 SUMMARY OF ONSITE ENVIRONMENTAL INCIDENTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Incident Date Location Impacted Brief Description Status # of Incident Media 8601 1988 UST Facility ID 00-0- Soil Petroleum release, Closed in 1992 0000033150 volume of release not confirmed NA June Sanitary sewage pipe Soil 8,200 gallons of Closed 2005 to lagoon waste water released 86354 2005 Vehicle fueling area, Soil Petroleum release, Closed 1,000-gallon AST volume not confirmed NA 2005 Coal handling track Soil Fuel oil release, 400 Closed area gallons NA 2005 Plant intake canal Waters of the Ash slurry water Closed US release, 100 gallons 91147 2011 Booster fan Soil Petroleum release, Closed volume not confirmed NA 2015 NPDES outfall 003 to Waters of the 900 gallons of Closed plant intake canal US lubrication oil was discharged from NPDES outfall 003 to the plant intake canal 91344 2015 No. 2 fuel oil line - Soil 1,250 gallons of Open bottom ash line fuel oil was trench released due to a broken fitting on a fuel oil delivery line at the bottom ash line trench NA 2016 Plant intake canal Waters of the Limited oil sheen on Closed US surface NA 2016 Plant intake canal Waters of the Oil sheen on Closed US surface Note: Modified from Original Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\ Table 2-3 Summary of Onsite Environmental Incidents.pdf Page 1 of 1 TABLE 3-1 SOIL/MATERIAL PROPERTIES FOR ASH MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Sample Depth (ft bgs) Mo ural Content3 Grain Sizes Estimated Effective Porosity/Specific Yield (%) % Gravel % Sand 0/6Fines Coarse? Fine$ Coarse9 Medium10 Fine" Silt12 Clay13 AL-2D 23-25 24.9 0.0 0.0 0.0 0.1 11.7 78.4 9.8 8.0 AB-3D 29-30.5 45.1 0.0 11.2 7.9 22.0 38.5 19.4 1.4 32.0 AB-4D 19-20.5 86.7 0.0 0.6 3.4 11.3 54.2 29.1 1.4 29.0 AL-4D 5-7 25.4 0.0 0.0 0.0 0.2 12.7 77.6 9.5 8.5 AL-4D 20-22 19.8 0.0 0.0 0.1 0.4 14.9 73.2 11.4 9.0 AB-6D 9-10.5 56.1 0.0 0.3 1.0 2.2 45.6 49.6 1.3 23.0 AB-7D 0-2.5 - 0.0 0.0 0.0 0.7 1 13.6 70.8 14.9 7.5 AB-12D 39-40.5 32.1 0.0 0.0 0.2 0.8 21.7 68.0 9.3 12.0 AB-15 44-45 28.7 0.0 0.0 0.3 0.9 12.2 72.4 14.2 7.5 AB-18D 9-10.5 59.8 0.0 1.2 1.7 1.1 24.0 67.4 4.6 16.0 Notes: 1. Table was modified from original CSA submittal to represent analysis of ash samples only: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. 2. ASTM Standard D 2487, Standard Practice for Classification of Soils for Engineering Purposes (Unified Soil Classification System) 3. ASTM Standard D 854, "Standard Test Methods for Specific Gravity of Soil Solids by Water Pycnometer" 4. ASTM Standard D 2216, "Standard Test Methods for Laboratory Determination of Water (Moisture) Content of Soil and Rock by Mass 5. ASTM Standard D 4318, "Standard Test Methods for Liquid Limit, Plastic Limit, and Plasticity Index of Soils 6. ASTM Standard D 422, "Standard Test Method for Particle -Size Analysis of Soils 7. ASTM Standard D 5084, "Standard Test Methods for Measurement of Hydraulic Conductivity of Saturated Porous Materials Using a Flexible Wall Permeameter" 8. Coarse Gravel: 19.Omm - 75mm 9. Fine Gravel: 4.75mm - 19.Omm 10. Coarse Sand: 2.Omm - 4.75mm 11. Medium Sand: 0.425mm - 2.Omm 12. Fine Sand: 0.075mm - 0.425mm 13. Silt: 0.005mm - 0.075mm 14. Clay: <0.005mm 15. AB-15D represented on laboratory reports as AB-15 16. GWA-3GTB represented on laboratory reports as GWA-3GT P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 3-1 Physical Properties of Ash Page 1 of 1 TABLE 3-2 ASH, ROCK, AND SOIL COMPOSITION MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Fly Ash* Bottom Ash* Rock** Soil*** Aluminum, mg/kg 70,000 - 140,000 59,000 - 130,000 9,800 - 96,000 15,000 - 100,000 Calcium, mg/kg 7,400 - 150,00 5,700 - 150,000 6,000 - 83,000 1,500 - 62,000 Iron, mg/kg 34,000 - 130,000 40,000 - 160,000 8,800 - 95,000 7,000 - 50,000 Silicon, mg/kg 160,000 - 270,000 160,000 - 280,000 57,000 - 380,000 230,000 - 390,000 Magnesium, mg/kg 3,900 - 23,000 3,400 - 17,000 700 - 56,000 1,000- 15,000 Potassium, mg/kg 6,200 - 21,000 4,600 - 18,000 4,000 - 45,000 4,500 - 25,000 Sodium, mg/kg 1,700 - 17,000 1,600 - 11,000 900 - 34,000 1,000- 20,000 Sulfur, mg/kg 1,900 - 34,000 BDL - 15,000 200 - 42,000 840 - 1,500 Titanium, mg/kg 4,300 - 9,000 4,100 - 7,200 200 - 5,400 1,000 - 5,000 Antimony, mg/kg BDL - 16 All BDL 0.08 - 1.8 BDL - 1.3 Arsenic, mg/kg 22 - 260 2.6 - 21 0.50 - 14 2.0 - 12 Barium, mg/kg 380 - 5,100 380 - 3,600 67 - 1,400 200 - 1,000 Beryllium, mg/kg 2.2 - 26 0.21 - 14 0.10 - 4.4 BDL - 2.0 Boron, mg/kg 120 - 1,000 BDL - 335 0.2 - 220 BDL - 70 Cadmium, mg/kg BDL - 3.7 All BDL 0.5 - 3.6 BDL - 0.5 Chromium, mg/kg 27 - 300 51 - 1,100 1.9 - 310 15 - 100 Copper, mg/kg 62 - 220 39 - 120 10 - 120 5.0 - 50 Lead, mg/kg 21 - 230 8.1 - 53 3.8 - 44 BDL - 30 Manganese, mg/kg 91 - 700 85 - 890 175 - 1,400 100 - 1,000 Mercury, mg/kg 0.01 - 0.51 BDL - 0.07 0.1 -2.0 0.02 - 0.19 Molybdenum, mg/kg 9.0 - 60 3.8 - 27 1.0 - 16 All BDL Nickel, mg/kg 47 - 230 39 - 440 2.0 - 220 5.0 - 30 Selenium, mg/kg 1.8- 18 BDL - 4.2 0.60 - 4.9 BDL - 0.75 Strontium, mg/kg 270 - 3,100 270 - 2,000 61 - 890 20 - 500 Thallium, mg/kg BDL - 45 All BDL 0.1 - 1.8 0.20 - 0.70 Uranium, mg/kg BDL - 19 BDL - 16 0.84 - 43 1.2 - 3.9 Vanadium, mg/kg BDL - 360 BDL - 250 19 - 330 20 - 150 Zinc, mg/kg 63 - 680 16 - 370 25 - 140 22 - 99 Notes: BDL- Below Detection Limit *Source for most fly ash data is EPRI CP-INFO Database3. Beryllium„ Thallium, Mercury (bottom ash only) and Boron (bottom ash only) are from the EPRI PISCES Database6 **Source for rock data is US Geological Survey National Geochemical database.? ***Source for most soils data is Shacklette and Boerngen (1984)8; Cadmium and Thallium data are from Smith et al (2005).9 mg/kg = miligram per kilogram Table was obtained from the EPRI Technical update- Coal Combustion Products - Environmental Issue, Coal Ash: Characteristics, management, and Environmental Issues, Table 2, pg 5, EPRI, 2009. P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\ Table 3-2 Ash, Rock, and Soil Composition (EPRI) Page 1 of 1 Table 3-3. Cation/Anion Sample Results Analyte Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Iron Lead Manganese CAS RN 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-96-5 Result Unit mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg NCDENR Industrial Health PSRG 100000 94 3 44000 460 46000 200 100000 70 9400 100000 800 5200 NCDENR Protection of Groundwater PSRG NS 0.9 5.8 580 63 45 3 360000 0.9 700 150 270 65 Sample Name Sample Date AB-31D(3-5) 5/18/2015 1990 5.3 U 10 44.6 0.26 J 13.3 U 0.64 U 3.8 5.3 U 6.3 4520 5.3 U 24.1 AB-3D(64-65.5) 5/18/2015 17400 8.8 U 50.6 444 3 33.7 1.1 U 20.2 11.1 38.3 15300 18.1 144 AB-4SL(3.5-5) 5/21/2015 5180 7.8 U 22.1 168 1.5 19.4 U 0.93 U 10 5.2 J 19.6 5400 7.7 J 30.3 AB-4D(4-5.5) 5/21/2015 1330 5.3 U 7_9 24.7 0.13 J 13.3 U 0.64 U 2.4 5.3 U 4.4 3220 5.3 U 23.1 AB-4D(9-10.5) 5/21/2015 2070 7.1 U 37.2 91.7 0.22 J 17.7 U 0.85 U 4.6 7.1 U 8.7 10000 7.1 U 41.7 AB-5D(3-5) 5/20/2015 1650 6.6 U 6.6 U 44.5 0.24 J 16.6 U 0.8 U 2.7 6.6 U 9.5 4330 6.6 U 18.5 AB-5D(38-39) 5/21/2015 24300 8.2 U 78.1 437 2.3 20.6 U 0.99 U 27.7 22.4 41.6 36900 20.3 782 AB-5D(40-42) 5/21/2015 17700 5.6 U 5.6 U 176 0.51 13.9 U 0.67 U 81.2 13 6.6 22800 5.1 J 233 AB-6BR(3-5) 5/29/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA AB-6D(44-50.5) 4/16/2015 19100 6.8 U 49.6 535 2.1 16 J 0.82 U 74.1 17.5 41.5 23100 19.8 176 AB-7D(3-5) 5/11/2015 10800 6.4 U 56.1 250 3.4 39.5 0.77 U 22.5 13.5 40.7 5050 24.7 22.9 AB-7D(19-20.5) 5/11/2015 18500 7.2 U 8 247 1.5 18 U 0.86 U 77.5 10.9 31.5 32500 17.9 174 AB-8D(3-5) 5/14/2015 4850 7.9 U 23.7 149 1.3 19.8 U 0.95 U 10.6 4.4 J 16 6540 7.4 J 32.6 AB-10D(3-5) 5/1/2015 21500 6.7 U 59.2 612 2.8 15.1 J 0.81 U 34.8 12.8 38 23900 20.9 185 AB-10D(48-49) 5/2/2015 12000 6.5 U 74 234 1.8 27.8 0.79 U 21 6.4 J 29.2 8560 14.4 64.1 AB-12D(3-5) 4/30/2015 10800 J+ 6 U 6 U 126 J+ 0.69 15.1 U 0.72 U 27.7 13.4 17 21700 J- 6.9 310 J+ AB-12D(49-50.5) 4/30/2015 6720 6.7 U 3.9 J 130 0.27 J 16.8 U 0.8 U 18.7 4.6 J 7.6 8950 5 J 87.1 AB-13D(3-5) 5/18/2015 12900 6.6 U 73 291 2.9 19.9 0.8 U 25.1 91 47.8 7780 19.7 98.4 AB-13D(59-60) 5/18/2015 5410 8.6 U 17.7 193 0.75 21.5 U 1 U 9.7 8.6 U 20.3 5330 8.6 U 39.2 AB-14D(3-5) 6/3/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA AB-14D(34-35.5) 6/4/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA AB-15D(3-5) 5/15/2015 15700 8.2 U 52.9 290 3.4 12 J 0.99 U 30.9 11.5 52.3 13900 25.9 149 AB-15D(43-44) 5/6/2015 10300 6.8 U 63.5 246 2 19.3 0.81 U 21.6 6.8 J 35.6 8650 14.2 50.9 AB-17D(22-23) 5/14/2015 8350 7.3 U 28.8 179 2.6 21.2 0.87 U 19.3 10 34.8 5840 17.2 69.4 AB-18D(3-5) 6/30/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA AB-20D(3-5) 6/3/2015 12400 6.7 U 37.6 312 3.3 56.9 0.63 J 22.2 12.4 43.7 10900 22.8 44 AB-20D(86-87) 6/4/2015 5290 6.7 U 34.5 161 0.98 11.7 J 0.8 U 10.8 4.7 J 16.8 8900 5.2 J 60.7 AB-21D(25-30) 6/23/2015 3860 10.1 U 5.1 J 131 0.54 25.1 U 1.2 U 23.5 10.1 U 11.6 5960 10.1 U 25 AL-2D(3-5) 5/13/2015 15500 6.6 U 53.7 455 4.1 21.9 0.79 U 33.5 15.4 46.5 10400 22.1 79.8 AL-2D(86-88) 5/13/2015 19800 6.4 U 113 344 6.2 174 0.56 J 42.6 20.6 78 11600 43.1 65 AL-3D(3-5) 4/29/2015 12800 7 U 35.2 145 2.8 21.3 0.84 U 24.1 11_6 36.3 7090 19.6 37.4 AL-3D(110-112) 4/30/2015 12600 6.2 U 61.2 321 2.8 50.7 0.75 U 24.2 10.3 44.3 10000 19.6 73.6 AL-4D(3-5) 5/14/2015 15000 6.2 U 44.2 470 3.8 13 J 0.74 U 41.9 12.7 42.2 11100 20.9 110 AL-4D(77-79) 5/14/2015 14200 6.7 U 88.4 268 4.6 102 0.4 J 31.3 14.9 58.6 8220 28.7 27.2 SB-2(3-5) 4/23/2015 11900 J+ 6.6 U 62.3 493 J+ 4 J+ 17.7 0.79 U 22.4 12 46.4 J+ 8890 J+ 23.2 118 J+ SB-2(58-59) 4/23/2015 8680 8.1 U 40.6 125 4.5 39.3 0.98 U 16.3 10 31 4300 18 23.4 SB-3(3-5) 3/23/2015 11900 6.3 U 54 301 3.1 19.2 0.75 U 23.3 11_4 49.9 9060 23.8 81 SB-3(72.5-74.5) 4/22/2015 18200 7.4 U 81.8 361 3.6 38 0.89 U 36.9 12.8 59.1 10100 31.3 71.3 SB-4(3-5) 4/29/2015 12400 8.5 U 35.5 197 2.9 48.6 1 U 22.6 10.3 36.7 13000 19.8 52.3 SB-4(43-45) 4/29/2015 10700 7.3 U 50.5 211 3.1 102 0.88 U 20.2 10.2 37 6990 20.5 33.5 SB-5(3-5) 4/25/2015 12900 7.4 U 70.1 224 3.4 75.6 0.89 U 31.2 13.6 41.4 9450 23.2 37.3 SB-5(45.5-46.5) 4/28/2015 12100 6.8 U 41.7 213 3.2 115 0.82 U 24.2 12 39.7 8470 22.6 35.8 SB-7(3-5) 4/30/2015 9400 6 U 53.9 303 2.8 51 0.73 U 20.5 10 36.2 7110 19.5 31.7 SB-7(53-54) 4/30/2015 8620 6.2 U 4.6 J 64 0.4 15.5 U 0.74 U 20.6 68 15.7 17500 11 105 SB-7(57.5-59.5) 4/30/2015 13100 7 U 56.7 407 4.3 44.7 0.84 U 26 16 45.4 9780 26.5 38.2 SB-8(3-5) 4/14/2015 10300 6.8 U 62.2 304 3.3 18.3 0.81 U 20.8 11.3 42 8540 23.2 46.1 SB-10(3-5) 5/15/2015 5850 8 U 30.3 188 1.4 20.1 U 0.97 U 18.3 7.4 J 16.2 13300 5.9 J 70 SB-10(17.5-19.5) 5/15/2015 20900 7.2 U 127 360 4.4 36.5 0.6 J 38.7 15.6 60.7 12600 63.8 86.6 SB-11(3-5) 5/12/2015 4810 9.4 U 18.2 126 1.4 23.4 U 1.1 U 16 6.2 J 21.7 8720 7.1 J 35.7 SB-11(28-30) 5/19/2015 1790 6.8 U 19.7 41.8 0.29 J 17 U 0.82 U 3.4 6.8 U 5.9 3560 6.8 U 11.1 SB-13(3-5) 3/19/2015 14300 2.3 J 105 279 5.8 51_9 0.53 35.8 17.6 69 6750 35.4 53 SB-13(11.4-12.1) 3/19/2015 7100 3.7 U 43.5 115 1.8 26.7 0.45 U 16.5 96 30.1 5620 16.7 27.9 SB-14(3-5) 5/4/2015 4450 8.5 U 19.1 130 0.6 21.1 U 1 U 10.8 8.5 U 9.5 9540 8.5 U 54.4 SB-14(22-24) 6/30/2015 4960 J+ 8.8 U 25.1 159 J+ 0.99 24.8 1.1 U 10.8 8.8 U 17 6380 J+ 4.9 J 41.3 SB-14(28.5-29.5) 5/19/2015 8020 10.7 U 207 168 1.4 28.9 1.3 U 16.9 6.4 J 30.8 7320 10.3 J 73.8 Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 1 of 6 Table 3--3. Cation/Anion Sample Results Analyte Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Iron Lead Manganese CAS RN 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-96-5 Result Unit mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg NCDENR Industrial Health PSRG 100000 94 3 44000 460 46000 200 100000 70 9400 100000 800 5200 NCDENR Protection of Groundwater PSRG NS 0.9 5.8 580 63 45 3 360000 0.9 700 150 270 65 Sample Name Sample Date S13-15(3-5) 5/2/2015 6830 J+ 6 U 87.7 165 J+ 1.4 11.1 J 0.72 U 31 J- 6.5 26.3 23500 J- 20.8 38.1 J+ SB-15(82.5-83.5) 5/5/2015 15500 8.3 U 39.7 390 2.2 16.4 J 1 U 21 10 36.1 13300 15 105 General Notes: mg/kg - milligrams per kilogram NA - Not analyzed or not reported by analytical laboratory Std. Units - pH units Comparison Criteria: NS - No applicable standard for this parameter Shading indicates exceedance of either applicable criteria. bold - indicates exceedance of NCDENR Industrial Health Based PSRG Italic/underline- indicates exceedance of NCDENR Protection of Groundwater PSRG North Carolina Department of Environment and Natural Resources Division of Waste Management Soil Remediation Goals Table (March 2015) - Preliminary Industrial Health Based Soil Remediation Goal (PSRG) and Protection of Groundwater PSRG. "Note: No PSRG for Total Chromium is currently available, as a surrogate the PSRG for Trivalent Chromium was used for comparison purposes only. Qualifier Notes: U -- Not detected above the reporting detection limit. J -- Estimated Concentration J+ -- Estimated concentration, biased high. J- --Estimated concentration, biased low. Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 2 of 6 Table 3-3. Cation/Anion Sample Results Analyte Mercury Molybdenum Nickel Selenium Strontium Thallium Vanadium Zinc Calcium Chloride Magnesium Nitrate Potassium CAS RN 7439-97-6 7439-98-7 7440-02-0 7782-49-2 7440-24-6 7440-28-0 7440-62-2 7440-66-6 7440-70-2 16887-00-6 7439-95-4 14797-55-8 7440-09-7 Result Unit mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg NCDENR Industrial Health PSRG 8 1200 4400 1200 100000 2.4 1200 70000 NS NS NS 100000 NS NCDENR Protection of Groundwater PSRG 1 NS 130 2.1 NS 0.28 6 1200 NS NS NS NS NS Sample Name Sample Date AB-31D(3-5) 5/18/2015 0.058 2.7 U 4.9 5.3 U 29.6 5.3 U 7_8 30.5 806 274 UJ 256 27.4 UJ 235 J AB-31D(64-65.5) 5/18/2015 0.017 4.4 U 17.8 7.6 J 370 8.8 U 57.7 28.2 8950 416 UJ 3110 41.6 UJ 2900 AB-4SL(3.5-5) 5/21/2015 0.1 3.9 U 10.7 86 73.7 7.8 U 24.2 14.4 1150 389 UJ 387 38.9 UJ 715 AB-4D(4-5.5) 5/21/2015 NA 2.7 U 2.5 5.3 U 19.1 5.3 U 4.2 J 2.7 J 674 263 UJ 210 26.3 UJ 134 J AB-4D(9-10.5) 5/21/2015 0.17 2.8 J 4.4 7.1 U 17.3 7.1 U 10 7.1 U 354 356 UJ 189 35.6 UJ 196 J AB-5D(3-5) 5/20/2015 0.0065 J 3.3 U 3 6.6 U 21.3 6.6 U 4.9 J 4 J 493 312 UJ 302 31.2 UJ 291 J AB-5D(38-39) 5/21/2015 0.2 78.5 23.7 11.5 129 8.2 U 109 92.4 2400 399 UJ 9620 39.9 UJ 8920 AB-5D(40-42) 5/21/2015 0.032 2.8 U 16.7 5.6 U 57.2 5.6 U 49.2 51.6 7240 279 UJ 15000 27.9 UJ 11100 AB-6BR(3-5) 5/29/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA AB-6D(44-50.5) 4/16/2015 NA 3.4 U 59.9 8.3 226 6.8 U 86.9 50.5 5960 352 U 8340 35.2 UJ 5280 AB-7D(3-5) 5/11/2015 0.18 8.3 24.5 17.9 168 6.4 U 76.6 42 2830 306 UJ 705 30.6 UJ 1600 AB-7D(19-20.5) 5/11/2015 0.22 3.6 U 38.3 7.2 U 102 7.2 U 103 44.8 1530 366 UJ 6950 36.6 UJ 3360 AB-8D(3-5) 5/14/2015 0.052 2.5 J 11 7.4 J 55.8 7.9 U 24.1 32.1 652 397 UJ 494 39.7 UJ 735 AB-10D(3-5) 5/1/2015 0.18 3.4 U 26.8 5.6 J 266 6.7 U 94.3 65.5 4250 342 UJ 6570 34.2 UJ 6950 AB-10D(48-49) 5/2/2015 0.099 2.4 J 14.1 7.4 156 6.5 U 48.6 30.4 2420 328 UJ 1310 32.8 UJ 2560 AB-12D(3-5) 4/30/2015 NA 3 UJ 13.1 6 U 10.7 6 U 52.1 40.9 1020 295 UJ 3500 J+ 29.5 UJ 1930 J+ AB-12D(49-50.5) 4/30/2015 NA 3.4 U 9 6.7 U 33.4 6.7 U 34.7 20.7 428 336 UJ 3090 33.6 UJ 2490 AB-13D(3-5) 5/18/2015 0.2 J- 3.3 U 19.2 6.6 U 227 6.6 U 57 38.4 3240 324 UJ 1120 32.4 UJ 2220 AB-13D(59-60) 5/18/2015 NA 4.3 U 7.2 4.4 J 90.3 8.6 U 19.9 9.7 1310 417 UJ 619 41.7 UJ 1110 AB-14D(3-5) 6/3/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA AB-14D(34-35.5) 6/4/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA AB-15D(3-5) 5/15/2015 0.12 4.1 U 21.6 6.7 J 157 8.2 U 76.1 47.6 2240 389 UJ 934 38.9 UJ 2170 AB-15D(43-44) 5/6/2015 0.2 3.4 U 14.7 13.7 146 6.8 U 47.9 30.3 1850 334 UJ 811 33.4 UJ 2010 AB-17D(22-23) 5/14/2015 NA 2 J 18.1 11_4 116 7.3 U 52.6 29.3 1330 361 UJ 601 36.1 UJ 1130 AB-18D(3-5) 6/30/2015 0.09 NA NA NA NA NA NA NA NA NA NA NA NA AB-20D(3-5) 6/3/2015 0.43 3.6 26 24.8 309 6.7 U 78.1 39.1 8050 326 U 921 32.6 UJ 1510 AB-20D(86-87) 6/4/2015 0.04 3.3 U 9.7 3.5 J 95 6.7 U 19.7 11 1760 329 U 620 32.9 UJ 923 AB-21D(25-30) 6/23/2015 0.011 J 5 U 9 10.1 U 65.2 10.1 U 12.4 5.2 J 648 494 U 850 49.4 UJ 754 AL-2D(3-5) 5/13/2015 0.19 12.7 35.4 22.7 214 6.6 U 70.7 34.8 2820 314 U 3520 31.4 UJ 3020 AL-2D(86-88) 5/13/2015 0.15 2.3 J 37.2 26.9 554 6.4 U 139 62.8 9010 322 U 2470 32.2 UJ 2740 AL-3D(3-5) 4/29/2015 0.17 10.4 19.9 17.9 106 7 U 64.2 32.1 1280 337 U 1270 33.7 UJ 1920 AL-3D(110-112) 4/30/2015 0.18 5 18.9 13.6 286 6.2 U 68.3 34.4 4500 311 U 1560 31.1 UJ 2800 AL-4D(3-5) 5/14/2015 0.14 11.2 32.4 16.8 185 6.2 U 68.6 35.3 2500 303 U 3620 30.3 UJ 3390 AL-4D(77-79) 5/14/2015 0.32 12.5 28.3 26.1 193 6.7 U 88.3 40.9 3250 322 U 1040 32.2 UJ 2030 SB-2(3-5) 4/23/2015 0.049 9.7 21.5 17.7 185 J+ 6.6 U 59.6 26.2 1120 335 UJ 977 33.5 UJ 2040 J+ SB-2(58-59) 4/23/2015 0.2 10.3 20.9 20.8 104 8.1 U 45 28.4 1380 392 UJ 752 39.2 UJ 1660 SB-3(3-5) 3/23/2015 0.29 6.6 20 17.3 165 6.3 U 67.6 35.6 1230 321 UJ 1720 32.1 UJ 2580 S13-3(72.5-74.5) 4/22/2015 0.16 3.7 U 26.5 10.5 296 7.4 U 83 54.5 3570 363 UJ 1820 36.3 UJ 3680 SB-4(3-5) 4/29/2015 NA 4.3 U 19.7 18.7 171 8.5 U 70.2 34.6 3750 402 UJ 1070 40.2 UJ 1610 S13-4(43-45) 4/29/2015 NA 9.6 21.9 22.6 179 7.3 U 55.5 34.3 3850 367 UJ 902 36.7 UJ 1710 SB-5(3-5) 4/25/2015 NA 3.7 U 25.9 22.3 299 7.4 U 76 40.7 4830 366 UJ 1140 36.6 UJ 1720 SB-5(45.5-46.5) 4/28/2015 NA 8.7 23.9 21.3 187 6.8 U 69.7 40.9 5190 338 UJ 1040 44.2 J- 1850 S13-7(3-5) 4/30/2015 0.53 3 U 20.9 21_1 194 6 U 57.9 35 4930 296 UJ 851 29.6 UJ 1390 SB-7(53-54) 4/30/2015 0.17 3.1 U 7.2 6.2 U 24.9 6.2 U 45.8 17.6 540 311 UJ 1260 31.1 UJ 1450 S13-7(57.5-59.5) 4/30/2015 0.31 13 28 25.6 264 7 U 72.6 34.1 2850 345 UJ 901 34.5 UJ 1820 SB-8(3-5) 4/14/2015 NA 9.8 20.9 21.4 166 6.8 U 68.1 33 1400 337 UJ 708 33.7 UJ 1490 SB-10(3-5) 5/15/2015 0.28 2.8 J 16.6 4.9 J 90.5 8 U 29.4 16.5 1750 389 UJ 988 38.9 UJ 1050 S13-10(17.5-19.5) 5/15/2015 0.17 J+ 3.3 J 30.7 11.9 283 7.2 U 96.8 63.8 3790 359 UJ 1720 35.9 UJ 3920 SB-11(3-5) 5/12/2015 0.057 J- 4.7 U 13.5 17.6 62.2 9.4 U 27.1 14.5 861 453 UJ 309 45.3 UJ 670 S13-11(28-30) 5/19/2015 0.026 J- 3.4 U 4.3 6.8 U 24.3 6.8 U 6.7 J 6.8 U 287 343 UJ 175 34.3 UJ 349 SB-13(3-5) 3/19/2015 0.18 1.1 26 16.1 250 4 U 113 48.2 2390 372 U 1010 37.2 UJ 2190 SB-13(11.4-12.1) 3/19/2015 0.084 6 15 10.7 101 3.7 U 53.6 24.5 1750 369 U 518 36.9 UJ 1110 S13-14(3-5) 5/4/2015 0.021 J- 7 10.7 8.5 U 59.8 8.5 U 16.4 11.1 1020 399 UJ 1080 39.9 UJ 1290 SB-14(22-24) 6/30/2015 0.053 3.2 J 8.2 6.5 J- 103 J+ 8.8 U 21.2 11.4 1600 443 UJ 530 44.3 UJ 969 J+ S13-14(28.5-29.5) 5/19/2015 0.16 J- 105 13.2 11_1 137 10.7 U 36.6 22.3 1910 507 UJ 945 50.7 UJ 1770 Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 3 of 6 Table 3-3. Cation/Anion Sample Results Analyte Mercury Molybdenum Nickel Selenium Strontium Thallium Vanadium Zinc Calcium Chloride Magnesium Nitrate Potassium CAS RN 7439-97-6 7439-98-7 7440-02-0 7782-49-2 7440-24-6 7440-28-0 7440-62-2 7440-66-6 7440-70-2 16887-00-6 7439-95-4 14797-55-8 7440-09-7 Result Unit mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg NCDENR Industrial Health PSRG 8 1200 4400 1200 100000 2.4 1200 70000 NS NS NS 100000 NS NCDENR Protection of Groundwater PSRG 1 NS 130 2.1 NS 0.28 6 1200 NS NS NS NS NS Sample Name Sample Date S13-15(3-5) 5/2/2015 0.41 J- 10.2 19.7 10.3 109 J+ 6 U 62.3 18.5 1440 288 UJ 532 28.8 UJ 1700 J+ SB-15(82.5-83.5) 5/5/2015 0.18 4.2 U 18 7.8 J 282 8.3 U 48.1 22.1 4040 405 UJ 1780 40.5 UJ 3210 General Notes: mg/kg - milligrams per kilogram NA - Not analyzed or not reported by analytical laboratory Std. Units - pH units Comparison Criteria: NS - No applicable standard for this parameter Shading indicates exceedance of either applicable criteria. bold - indicates exceedance of NCDENR Industrial Health Based PSRG Italic/underline- indicates exceedance of NCDENR Protection of Groundwater PSRG North Carolina Department of Environment and Natural Resources Division of Waste Management Soil Remediation Goals Table (March 2015) - Preliminary Industrial Health Based Soil Remediation Goal (PSRG) and Protection of Groundwater PSRG. "Note: No PSRG for Total Chromium is currently available, as a surrogate the PSRG for Trivalent Chromium was used for comparison purposes only. Qualifier Notes: U -- Not detected above the reporting detection limit. J -- Estimated Concentration J+ -- Estimated concentration, biased high. J- --Estimated concentration, biased low. Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 4 of 6 Table 3-3. Cation/Anion Sample Results Analyte Sodium Sulfate pH (field) Total Organic Carbon CAS RN 7440-23-5 14808-79-8 PH TOC Result Unit mg/kg mg/kg Std. Units mg/kg NCDENR Industrial Health PSRG NS NS NS NS NCDENR Protection of Groundwater PSRG NS NS NS NS Sample Name Sample Date AB-31D(3-5) 5/18/2015 266 U 274 UJ 6.2 J 27400 AB-31D(64-65.5) 5/18/2015 554 457 J- 9.7 J 24500 AB-4SL(3.5-5) 5/21/2015 388 U 389 UJ 5.8 J 23200 AB-4D(4-5.5) 5/21/2015 266 U 137 J- 6.8 J NA AB-4D(9-10.5) 5/21/2015 354 U 356 UJ 6.1 J 11000 AB-5D(3-5) 5/20/2015 332 U 1710 J- 3.2 J 15400 AB-5D(38-39) 5/21/2015 411 U 542 J- 6.7 J 38100 AB-5D(40-42) 5/21/2015 279 U 279 UJ 6.6 J 1140 AB-6BR(3-5) 5/29/2015 NA NA NA 56200 J AB-6D(44-50.5) 4/16/2015 171 J 352 UJ 6.5 J NA AB-7D(3-5) 5/11/2015 322 U 2960 J- 6.2 J 66500 AB-7D(19-20.5) 5/11/2015 360 U 366 UJ 5.3 J 69600 AB-8D(3-5) 5/14/2015 396 U 275 J- 4 J 37000 AB-10D(3-5) 5/1/2015 249 J 342 UJ 6.9 J 52400 AB-10D(48-49) 5/2/2015 281 J 328 UJ 8.2 J 10400 AB-12D(3-5) 4/30/2015 301 U 379 J- NA NA AB-12D(49-50.5) 4/30/2015 335 U 336 UJ 5.2 NA AB-13D(3-5) 5/18/2015 346 324 UJ 6.2 J NA AB-13D(59-60) 5/18/2015 429 U 417 UJ 7.8 NA AB-14D(3-5) 6/3/2015 NA NA NA 28500 AB-14D(34-35.5) 6/4/2015 NA NA NA 31400 AB-15D(3-5) 5/15/2015 262 J 389 UJ 5.6 J 57700 AB-15D(43-44) 5/6/2015 202 J 334 UJ 7.1 J 39500 AB-17D(22-23) 5/14/2015 363 U 189 J- 5.8 J NA AB-18D(3-5) 6/30/2015 NA NA NA 33800 AB-20D(3-5) 6/3/2015 340 5500 7.4 J 91000 AB-20D(86-87) 6/4/2015 334 U 270 J 7.1 J 25700 AB-21D(25-30) 6/23/2015 503 U 690 4.8 J 114000 AL-2D(3-5) 5/13/2015 286 J 251 J- 6.5 J 58700 AL-2D(86-88) 5/13/2015 588 9150 J- 8.2 J 42600 AL-3D(3-5) 4/29/2015 180 J 337 UJ 6.3 J 71400 AL-3D(110-112) 4/30/2015 469 4090 J- 7.8 J 27000 AL-4D(3-5) 5/14/2015 278 J 303 UJ 6.6 J 89400 AL-4D(77-79) 5/14/2015 398 4990 J- 6.4 J 50700 SB-2(3-5) 4/23/2015 201 J 335 UJ 6.3 J 82900 S13-2(58-59) 4/23/2015 251 J 2710 J- 6.2 J 95200 SB-3(3-5) 3/23/2015 190 J 321 UJ 6.3 J 56100 S13-3(72.5-74.5) 4/22/2015 497 363 UJ 8.3 J 39200 SB-4(3-5) 4/29/2015 243 J 1770 J- 7.5 J NA SB-4(43-45) 4/29/2015 369 3970 J- 7.2 J NA S13-5(3-5) 4/25/2015 369 J 2120 J- 7.5 J NA S13-5(45.5-46.5) 4/28/2015 387 5270 J- 6.9 J NA SB-7(3-5) 4/30/2015 238 J 5190 J- 7 J 78100 SB-7(53-54) 4/30/2015 310 U 171 J- 5.2 J 67100 SB-7(57.5-59.5) 4/30/2015 265 J 3900 6.2 J 80500 S13-8(3-5) 4/14/2015 338 U 337 UJ 6.3 J NA SB-10(3-5) 5/15/2015 402 U 389 UJ 7.9 J 72800 S13-10(17.5-19.5) 5/15/2015 510 359 UJ 7.6 J 35600 SB-11(3-5) 5/12/2015 469 U 453 U 4.8 J 131000 J- SB-11(28-30) 5/19/2015 340 U 205 J- 5.4 J 26400 J- S13-13(3-5) 3/19/2015 290 372 U 6.4 J- 38000 SB-13(11.4-12.1) 3/19/2015 125 897 6.4 J- 33000 S13-14(3-5) 5/4/2015 423 U 271 J- 7 J 16600 J- SB-14(22-24) 6/30/2015 1 440 U 362 J 7.8 J- 45500 SB-14(28.5-29.5) 5/19/2015 1 535 U 1 731 J- 17.9 J 1 88800 J- Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 5 of 6 Table 3-3. Cation/Anion Sample Results Analyte Sodium Sulfate pH (field) Total Organic Carbon CAS RN 7440-23-5 14808-79-8 PH TOC Result Unit mg/kg mg/kg Std. Units mg/kg NCDENR Industrial Health PSRG NS NS NS NS NCDENR Protection of Groundwater PSRG NS NS NS NS Sample Name Sample Date S13-15(3-5) 5/2/2015 299 U 1680 J- 4.5 J 73200 J- SB-15(82.5-83.5) 5/5/2015 473 405 U 7.8 J 95400 General Notes: mg/kg - milligrams per kilogram NA - Not analyzed or not reported by analytical laboratory Std. Units - pH units Comparison Criteria: NS - No applicable standard for this parameter Shading indicates exceedance of either applicable criteria. bold - indicates exceedance of NCDENR Industrial Health Based PSRG Italic/underline- indicates exceedance of NCDENR Protection of Groundwater PSRG North Carolina Department of Environment and Natural Resources Division of Waste Management Soil Remediation Goals Table (March 2015) - Preliminary Industrial Health Based Soil Remediation Goal (PSRG) and Protection of Groundwater PSRG. "Note: No PSRG for Total Chromium is currently available, as a surrogate the PSRG for Trivalent Chromium was used for comparison purposes only. Qualifier Notes: U -- Not detected above the reporting detection limit. J -- Estimated Concentration J+ -- Estimated concentration, biased high. J- --Estimated concentration, biased low. Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 6 of 6 Table 3-4. Ash Sample SPLP Results Analyte Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper CAS RN 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-47-3 7440-48-4 7440-50-8 Fraction SPLP SPLP SPLP SPLP SPLP SPLP SPLP SPLP SPLP SPLP Result Unit ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I 15A NCAC 02L STANDARD Nis 1 Nis 700 Nis 700 2 10 NS 1000 IMAC* Nis Nis 10 Nis 4 NS NS NS 1 NS Sample Name Sample Date AB-3D(64-65.5) 5/18/2015 56.1 J 5 U 5 U 290 2 U 14.1 J 0.8 U 5 U 5 U 10 U AB-5D(38-39) 5/21/2015 260 0.5 U 0.29 J 87.9 0.24 358 0.66 0.89 22.1 3.8 AB-6D(44-50.5) 4/16/2015 51500 2.7 144 1090 3.2 138 0.34 110 18.1 76.6 AB-10D(48-49) 5/2/2015 2550 3.1 480 180 0.57 160 0.2 18.1 1.6 19.8 AB-14D(34-35.5) 6/4/2015 17.2 0.93 20.1 274 0.2 U 95.4 0.12 1.4 2.5 3.2 AB-15D(43-44) 5/6/2015 2900 12.2 167 212 0.42 80.2 0.13 17 1.5 14.7 AL-2D(86-88) 5/13/2015 100 U 5.8 6.4 144 2 U 591 0.54 J 5 U 15.5 10 U AL-3D(110-112) 4/30/2015 15.1 2.4 107 182 0.2 U 1400 0.08 U 0.88 0.5 U 0.55 J SB-3(72.5-74.5) 4/22/2015 2320 9.5 189 172 0.52 155 0.13 17.9 1.5 9.2 SB-4(43-45) 4/29/2015 27.6 6.8 156 178 0.2 U 1470 0.071 J 1.9 0.2 J 0.3 J SB-7(57.5-59.5) 4/30/2015 22.1 2.5 1 225 0.1 J 710 1.2 0.83 26.1 2.7 SB-8(24-25) 4/14/2015 15.5 3.6 7.4 210 0.2 U 634 1.5 1.5 44.1 5 SB-10(17.5-19.5) 5/15/2015 48200 2.9 133 1080 3.1 130 0.33 106 16.4 75.3 General Notes: ug/I - micrograms per liter NA - Not analyzed or not reported by analytical laboratory T - Total D - Dissolved N - Fraction not applicable Comparison Criteria: NS - No applicable standard for this parameter shading + bold - indicates exceedance of NC 2L or IMAC Criteria. North Carolina Department of Environment and Natural Resources Division of Water Resources 02L Groundwater Quality Standards and Interim Maximum Allowable Concentrations (IMACs). April 2013 "NOTE: The IMAC value is shown where there is no applicable 02L standard. Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina, lists Interim Maximum Allowable Concentrations (IMACs). The IMACs were issued in 2010 and 2011, however NCDENR has not established a 02L standard for these constituents as described in 15A NCAC 02L.0202(c). For this reason, IMACs are noted in this report for reference only. Qualifier Notes: U -- Not detected above the reporting detection limit. J -- Estimated Concentration J+ -- Estimated concentration, biased high. J- --Estimated concentration, biased low. Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 1 of 3 Table 3-4. Ash Sample SPLP Results Analyte Iron Lead Manganese Mercury Molybdenum Nickel Selenium Strontium Thallium Vanadium CAS RN 7439-89-6 7439-92-1 7439-96-5 7439-97-6 7439-98-7 7440-02-0 7782-49-2 7440-24-6 7440-28-0 7440-62-2 Fraction SPLP SPLP SPLP SPLP SPLP SPLP SPLP SPLP SPLP SPLP Result Unit ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I 15A NCAC 02L STANDARD 300 15 50 1 NS 100 20 NS NS NS IMAC* NS NS NS NS NS NS NS NS 0.2 0.3 Sample Name Sample Date AB-3D(64-65.5) 5/18/2015 500 U 1 U 16.6 0.2 U 5 U 2.7 J 5 U 42.6 1 U 10 U AB-5D(38-39) 5/21/2015 50 U 0.13 150 0.2 UJ 0.5 U 29.4 1.1 5.7 0.1 U 1 U AB-6D(44-50.5) 4/16/2015 48700 43.2 239 0.085 J- 2.9 46.4 15 513 1.1 213 AB-10D(48-49) 5/2/2015 1540 3.1 37.6 0.04 J- 30.2 6.5 39 198 0.23 103 AB-14D(34-35.5) 6/4/2015 23 J 0.095 J 92.8 0.2 U 4.2 11.5 4.4 92.4 0.1 U 3.5 AB-15D(43-44) 5/6/2015 1580 2.8 34.5 0.2 UJ 23.3 5.1 39.5 128 0.37 135 AL-2D(86-88) 5/13/2015 500 U 2.3 188 0.2 U 73.9 16.2 18.5 1750 1.1 19.3 AL-3D(110-112) 4/30/2015 50 U 0.1 U 9.2 0.2 UJ 193 0.27 J 19.3 1560 0.12 183 SB-3(72.5-74.5) 4/22/2015 957 3.7 12.3 0.2 UJ 5.6 4.4 89.8 243 0.28 267 SB-4(43-45) 4/29/2015 50 U 0.1 U 8.6 0.2 UJ 209 0.7 284 876 0.15 127 SB-7(57.5-59.5) 4/30/2015 19.2 J 0.061 J 153 0.2 UJ 93.2 15.7 37.1 1660 1.1 17.5 SB-8(24-25) 4/14/2015 15.1 J 0.22 188 0.2 UJ 84.8 103 124 1110 0.25 48.3 SB-10(17.5-19.5) 5/15/2015 44700 41.4 215 0.072 J- 3 44.8 14.7 453 1.1 196 General Notes: ug/I - micrograms per liter NA - Not analyzed or not reported by analytical laboratory T - Total D - Dissolved N - Fraction not applicable Comparison Criteria: NS - No applicable standard for this parameter shading + bold - indicates exceedance of INC 2L or IMAC Criteria. North Carolina Department of Environment and Natural Resources Division of Water Resources 02L Groundwater Quality Standards and Interim Maximum Allowable Concentrations (IMACs). April 2013 "NOTE: The IMAC value is shown where there is no applicable 02L standard. Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina, lists Interim Maximum Allowable Concentrations (IMACs). The IMACs were issued in 2010 and 2011, however NCDENR has not established a 02L standard for these constituents as described in 15A NCAC 02L.0202(c). For this reason, IMACs are noted in this report for reference only. Qualifier Notes: U -- Not detected above the reporting detection limit. J -- Estimated Concentration J+ -- Estimated concentration, biased high. J- --Estimated concentration, biased low. Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 2 of 3 Table 3-4. Ash Sample SPLP Results Analyte Zinc Calcium Chloride Magnesium Nitrate Potassium Sodium Sulfate pH (field) CAS RN 7440-66-6 7440-70-2 16887-00-6 7439-95-4 14797-55-8 7440-09-7 7440-23-5 14808-79-8 PH Fraction SPLP SPLP SPLP SPLP SPLP SPLP SPLP SPLP PH Result Unit ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I Std. Units 15A NCAC 02L STANDARD 1000 NS 250000 NS 10000 NS NS 250000 8.5 IMAC* NS NS NS NS NS NS NS NS NS Sample Name Sample Date AB-3D(64-65.5) 5/18/2015 50 U 1150 J+ 7600 U 195 4200 J- 158 J 3330 J+ 8200 J+ 9.7 J AB-5D(38-39) 5/21/2015 201 2620 8100 UJ 3710 710 J- 773 4180 54800 J 6.7 J AB-6D(44-50.5) 4/16/2015 176 2570 5000 U 4150 200 UJ 2700 1700 4600 J+ 6.5 J AB-10D(48-49) 5/2/2015 58.7 5100 5000 UJ 1330 200 UJ 401 1250 6800 J+ 8.2 J AB-14D(34-35.5) 6/4/2015 78.2 1450 5000 U 664 200 UJ 309 1840 8600 J+ NA AB-15D(43-44) 5/6/2015 84.7 2980 5000 U 459 200 UJ 300 1480 5100 J+ 7.1 J AL-2D(86-88) 5/13/2015 50 U 61100 6000 U 7640 250 J+ 6780 4700 214000 J+ 8.2 J AL-3D(110-112) 4/30/2015 44.7 60800 6200 U 4610 250 UJ 8020 4320 235000 J+ 7.8 J SB-3(72.5-74.5) 4/22/2015 64.2 9330 7200 UJ 1460 290 UJ 362 369 5900 J+ 8.3 J SB-4(43-45) 4/29/2015 90.2 64200 7400 UJ 2050 780 J- 3600 4500 230000 7.2 J SB-7(57.5-59.5) 4/30/2015 144 43900 7000 UJ 7560 360 J- 9050 5800 233000 6.2 J SB-8(24-25) 4/14/2015 238 32000 5000 UJ 4320 400 J- 4090 3180 108000 NA SB-10(17.5-19.5) 5/15/2015 175 2380 7200 UJ 3800 290 UJ 2530 1660 6700 J+ 7.6 J General Notes: ug/I - micrograms per liter NA - Not analyzed or not reported by analytical laboratory T - Total D - Dissolved N - Fraction not applicable Comparison Criteria: NS - No applicable standard for this parameter shading + bold - indicates exceedance of NC 2L or IMAC Criteria. North Carolina Department of Environment and Natural Resources Division of Water Resources 02L Groundwater Quality Standards and Interim Maximum Allowable Concentrations (IMACs). April 2013 "NOTE: The IMAC value is shown where there is no applicable 02L standard. Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina, lists Interim Maximum Allowable Concentrations (IMACs). The IMACs were issued in 2010 and 2011, however NCDENR has not established a 02L standard for these constituents as described in 15A NCAC 02L.0202(c). For this reason, IMACs are noted in this report for reference only. Qualifier Notes: U -- Not detected above the reporting detection limit. J -- Estimated Concentration J+ -- Estimated concentration, biased high. J- --Estimated concentration, biased low. Marshall Steam Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Station Page 3 of 3 TABLE 4-1 PRIVATE SUPPLY WELL PROPERTY INFORMATION MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Parcel ID # Property Address Street City State 461701079593 9053 Sherrills Ford Rd Sherrills Ford NC 461701092640 8012 Gregory Rd Sherrills Ford NC 461701091165 7983 Gregory Rd Sherrills Ford NC 460802973879 8086 Sherrills Ford Rd Sherrills Ford NC 460802976151 8112 Sherrills Ford Rd Sherrills Ford NC 460802976991 7958 Sherrills Ford Rd Sherrills Ford NC 460802877922 8027 Sherrills Ford Rd Sherrills Ford NC 460804729212 3102 Beatty Rd Sherrills Ford NC 460802954293 8303 Sherrills Ford Rd Sherrills Ford NC 461801069891 8101 Island Point Rd Sherrills Ford NC 461801060991 8009 Island Point Rd Sherrills Ford NC 461801067882 8083 Island Point Rd Sherrills Ford NC 461801066339 Island Point Rd Sherrills Ford NC 461701189474 Sherrills Ford Rd Sherrills Ford NC 461701274824 8220 Mcdonald Dr Sherrills Ford NC 461803100104 8790 Sherrills Ford Rd Sherrills Ford NC 460804909334 8819 Sherrills Ford Rd Sherrills Ford NC 461701085722 8913 Sherrills Ford Rd Sherrills Ford NC 461701097362 8883 Sherrills Ford Rd Sherrills Ford NC 461701097610 8861 Sherrills Ford Rd Sherrills Ford NC 461701275536 8244 Mcdonald Dr Sherrills Ford NC 461710276302 8268 Mcdonald Dr Sherrills Ford NC 461801163483 8125 Island Point Rd Sherrills Ford NC 461802672746 8628 Island Point Rd Sherrills Ford NC 461802571932 8486 Island Point Rd Sherrills Ford NC P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 4-1—Private Well Property Information_BDW.docx Page 1 of 4 TABLE 4-1 PRIVATE SUPPLY WELL PROPERTY INFORMATION MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Parcel ID # Property Address Street City State 461802661986 8639 Island Point Rd Sherrills Ford NC 461802671120 8623 Island Point Rd Sherrills Ford NC 461802574047 8575 Island Point Rd Sherrills Ford NC 461801477637 8483 Island Point Rd Sherrills Ford NC 461802576738 8566 Island Point Rd Sherrills Ford NC 461802571365 8579 Island Point Rd Sherrills Ford NC 461801478658 8499 Island Point Rd Sherrills Ford NC 460804936011 8511 Sherrills Ford Rd Sherrills Ford NC 460804938893 8416 Sherrills Ford Rd Sherrills Ford NC 461803012756 8625 Sherrills Ford Rd Sherrills Ford NC 460804934149 8491 Sherrills Ford Rd Sherrills Ford NC 460802956932 8213 Sherrills Ford Rd Sherrills Ford NC 460802956855 8225 Sherrills Ford Rd Sherrills Ford NC 460802956736 8239 Sherrills Ford Rd Sherrills Ford NC 461801050934 8220 Sherrills Ford Rd Sherrills Ford NC 461801060328 8172 Sherrills Ford Rd Sherrills Ford NC 460802969586 8168 Sherrills Ford Rd Sherrills Ford NC 460802969613 8160 Sherrills Ford Rd Sherrills Ford NC 460802968850 8140 Sherrills Ford Rd Sherrills Ford NC 460802977061 8122 Sherrills Ford Rd Sherrills Ford NC 460804937364 8456 Sherrills Ford Rd Sherrills Ford NC 460804939276 2971 Steam Plant Rd Sherrills Ford NC 461803031102 8510 Sherrills Ford Rd Sherrills Ford NC 461803021923 8526 Sherrills Ford Rd Sherrills Ford NC 461803023743 8538 Sherrills Ford Rd Sherrills Ford NC P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 4-1—Private Well Property Information_BDW.docx Page 2 of 4 TABLE 4-1 PRIVATE SUPPLY WELL PROPERTY INFORMATION MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Parcel ID # Property Address Street City State 461803024398 8550 Sherrills Ford Rd Sherrills Ford NC 461803024371 8574 Sherrills Ford Rd Sherrills Ford NC 461803016923 8610 Sherrills Ford Rd Sherrills Ford NC 461803012498 8653 Sherrills Ford Rd Sherrills Ford NC 460804946231 8396 Sherrills Ford Rd Sherrills Ford NC 461803040535 8358 Sherrills Ford Rd Sherrills Ford NC 460804949916 8316 Sherrills Ford Rd Sherrills Ford NC 460802959184 8294 Sherrills Ford Rd Sherrills Ford NC 460802959281 Sherrills Ford Rd Sherrills Ford NC 460802959229 8288 Sherrills Ford Rd Sherrills Ford NC 461801051307 8270 Sherrills Ford Rd Sherrills Ford NC 461801051629 8238 Sherrills Ford Rd Sherrills Ford NC 461801060122 8204 Sherrills Ford Rd Sherrills Ford NC 461803426350 8320 E Nc 150 Hwy Sherrills Ford NC 461803114647 3099 Steam Plant Rd Sherrills Ford NC 461801065838 8057 Island Point Rd Sherrills Ford NC 461802760831 Island Point Rd Sherrills Ford NC 461701190186 8876 Sherrills Ford Rd Sherrills Ford NC 461803123267 3085 Steam Plant Rd Sherrills Ford NC 461803008991 8722 Sherrills Ford Rd Sherrills Ford NC 461803009512 8768 Sherrills Ford Rd Sherrills Ford NC 461803003477 8771 Sherrills Ford Rd Sherrills Ford NC 461803018064 8704 Sherrills Ford Rd Sherrills Ford NC 461803009635 8756 Sherrills Ford Rd Sherrills Ford NC 461803018230 8680 Sherrills Ford Rd Sherrills Ford NC P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 4-1—Private Well Property Information_BDW.docx Page 3 of 4 TABLE 4-1 PRIVATE SUPPLY WELL PROPERTY INFORMATION MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Parcel ID # Property Address Street City State 461802673026 8643 Island Point Rd Sherrills Ford NC 461802765694 8762 Island Point Rd Sherrills Ford NC 461802767606 8780 Island Point Rd Sherrills Ford NC 461802768607 8788 Island Point Rd Sherrills Ford NC 461802769790 8806 Island Point Rd Sherrills Ford NC 461710465516 8200 E Nc 150 Hwy Sherrills Ford NC 461710467732 8226 E Nc 150 Hwy Sherrills Ford NC 461710366766 3527 Marshall Rd Sherrills Ford NC 461710269621 8050 E Nc 150 Hwy Sherrills Ford NC 461710462450 8176 E Nc 150 Hwy Sherrills Ford NC 461710460391 8162 E Nc 150 Hwy Sherrills Ford NC 461710353913 8066 E Nc 150 Hwy Sherrills Ford NC 461802678019 8716 Island Point Rd Sherrills Ford NC 461802665916 8665 Island Point Rd Sherrills Ford NC 461802761679 8716 Island Point Rd Sherrills Ford NC 461802763617 8734 Island Point Rd Sherrills Ford NC 461802764665 8746 Island Point Rd Sherrills Ford NC 461802673466 8632 Island Point Rd Sherrills Ford NC 461801076339 8064 Island Point Rd Sherrills Ford NC 461801078346 8084 Island Point Rd Sherrills Ford NC 461801079394 8104 Island Point Rd Sherrills Ford NC 461801171313 8118 Island Point Rd Sherrills Ford NC 461801173312 8136 Island Point Rd Sherrills Ford NC 461801166752 8153 Island Point Rd Sherrills Ford NC Notes. - Modified from Original Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 4-1—Private Well Property Information_BDW.docx Page 4 of 4 Table 6-1. Soil Mineralogy Results Boring ID Lab Performing Analysis Unique Lab Identifier Sample Depth (ft bgs) Soil Mineralogical Composition (wt %) Quartz K-Feldspar Plagioclas uscovite/Illiti Biotite Kaolinite Epidote Tremolite Vermiculite Hydroxylapatite Hematite Ilmenite Magnetite Mullite Amorphous) AB-11D PMET MS-01 12.5-15.0 33.3 18.5 16.7 7.3 1.9 5.8 0.7 - - - - - - - 15.8 A13-913R PMET MS-02 10-12.0 9.5 6.4 4.3 - 6.5 3.2 - 32.2 1.1 3.5 - - - - 33.3 GWA-1S PMET MS-03 50-52 22 7.1 18.7 6.4 7.3 16.5 - - - - - - - - 22 A13-113R PMET MS-04 33-35 22.6 24.3 - 8 5.2 24.7 - - - - - - - - 15.2 GWA-113R PMET MS-05 14-15.5 35.1 10.8 - 8.3 2.1 24.3 - - - - 1 - - - 18.4 AB-16D PMET MS-06 13-15 10.8 - 19.6 5.2 9.1 6.9 - 15.3 1 - - 1.4 - - 30.7 A13-2S PMET MS-07 31-32 35.8 8.9 - 5.2 2.3 31.9 - - - - 1.1 - - - 15.4 AB-15D PMET AB-15D 20-25 9.4 - - - - - - - - - 0.9 - 1.2 20.4 68.1 A13-8D PMET A13-8D 30-32.5 6.6 23.3 16.4 8.1 0.8 4.9 - - 0.8 - 0.8 - - - 38.3 A13-613R PMET AB-613R 57.5-59 2.2 7.8 19.4 - 6.2 - - 28 1 5.3 - - - I - 1 30.1 Notes: 1. Laboratory notes that samples contain amorphous smectite clays, amorphous mica, and/or amorphous iron oxide/hydroxide, but does not distinguish between them 2. Potassium Feldspar ('K-Feldspar') is a subclass of Alkali Feldspar. 3. Chemical composition of constituent minerals is as follows: Quartz - SiO2, Potassium Feldspar - (K,Na)[AlSi3O8], Plagioclase - Na[AlSi3O8]-Ca[Al2Si2O8], Muscovite - K2Al4[Si6Al2O20](OH,F)4, Illite - Kl_1.5AI4[Si7_fi.5AI1.1.5O20](OH)4, Biotite - K2(Mg,Fe+2)6.4(Fe+3,Al,Ti)0.2[ Kaolinite - AI4[S4O10](OH)8r Epidote - Ca2Fe+3A120.OH•Si2O7•SiO4, Tremolite - Ca2Mg5Si8O22(OH)2r Vermiculite -(Mg,Ca)0.7(Mg,Fe+3,Al)61(Al,Si)80201(OH)4.8H20, Hydroxylapatite - Ca5(PO4)3OH, Hematite - a-Fe2O3, Ilmenite - FeTiO3, Magnetite - Fe+2Fe2+304, MUlli 4. ft bgs = feet below ground surface Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-2. Soil Chemistry Results, Elemental Composition and % Oxides Boring ID Unique Lab Identifier Lab Performing Analysis Sample Depth (ft bgs) Elemental Composition (ppm) As Cd Ce Co Cu Ga La Mo Ni Pb Sb Se Sn W Zn Zr AB-11D American Assay MS-01 12.5-15.0 5 <0.2 109 7 9 16 60 1 11 58 <1 <1 1 <1 22 27 AB-9BR American Assay MS-02 10-12.0 8 <0.2 162 35 48 15 86 1 202 20 <1 <1 2 <1 76 17 GWA-1S American Assay MS-03 50-52 8 <0.2 332 13 23 27 196 2 6 38 <1 <1 2 <1 88 19 AB-1BR American Assay MS-04 33-35 6 <0.2 199 10 24 25 117 2 4 57 <1 <1 2 <1 74 15 GWA-1BR American Assay MS-05 14-15.5 4 <0.2 76 11 16 22 47 1 7 37 <1 <1 2 <1 58 25 AB-16D American Assay MS-06 13-15 4 <0.2 81 42 59 23 45 4 70 24 <1 1 2 1 121 10 AB-2S American Assay MS-07 31-32 2 <0.2 62 13 7 19 32 2 4 27 <1 <1 2 <1 57 20 AB-15D American Assay AB-15D 20-25 48 0.4 328 37 139 37 67 2 75 49 4 7 7 2 1 87 AB-8D American Assay AB-8D 30-32.5 28 <0.2 274 19 48 25 164 1 32 46 <1 1 1 <1 62 23 AB-6BR American Assay AB-6BR 57.5-59 15 <0.2 304 40 37 14 147 2 152 26 <1 <1 2 <1 47 6 Notes: 1. ppm = parts per million 2. ft bgs = feet below ground surface Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-3. Soil and Ash Parameters and Analytical Methods Inorganic Compounds Units Method Antimony mg/kg EPA 6020 Aluminum mg/kg EPA 6010 Arsenic mg/kg EPA 6020 Barium mg/kg EPA 6010 Beryllium mg/kg EPA 6020 Boron mg/kg EPA 6010 Cadmium mg/kg EPA 6020 Calcium mg/kg EPA 6010 Chloride mg/kg SM4500-CI-E Chromium mg/kg EPA 6010 Cobalt mg/kg EPA 6020 Copper mg/kg EPA 6010 Iron mg/kg EPA 6010 Lead mg/kg EPA 6020 Manganese mg/kg EPA 6010 Mercury mg/kg EPA Method 7470A/7471 Molybdenum mg/kg EPA 6010 Nickel mg/kg EPA 6010 Nitrate mg/kg EPA 9056 pH SU EPA 9045 Potassium mg/kg EPA 6010 Selenium mg/kg EPA 6020 Sodium mg/kg EPA 6010 Strontium mg/kg EPA 6010 Sulfate mg/kg EPA 9056 Thallium (low level) mg/kg EPA 6020 Vanadium mg/kg EPA 6020 Zinc mg/kg EPA 6010 Total Organic Carbon Units Method TOC mg/kg EPA 9060 Notes: Soil samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH using USEPA Method 9045, as noted above. Ash samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH using USEPA Method 9045; select ash samples will also be analyzed for leaching potential using SPLP Extraction Method 1312 in conjunction with USEPA Methods 6010/6020. SPLP results to be reported in units of mg/L for comparison to 2L Standards. Samples to be analyzed for Total Organic Carbon using method EPA 9060. Sample result in concentration units of mg/kg of organic carbon on a dry weight basis. mg/kg - Milligrams per kilogram S.U. - Standard Unit Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-4. Ash Basin Surface Water, Pore Water and Seep Parameters and Analytical Methods Parameter RL Units Method Field Parameters pH NA SU Field Water Quality Meter Specific Conductance NA mmho/cm Field Water Quality Meter Temperature NA °C Field Water Quality Meter Dissolved Oxygen NA mg/L Field Water Quality Meter Oxidation Reduction Potential NA mV Field Water Quality Meter Turbidity NA NTU Field Water Quality Meter Ferrous Iron NA mg/L Field Test Kit Inorganics Aluminum 5 pg/L EPA 200.7 or 6010C Antimony 1 pg/L EPA 200.8 or 6020A Arsenic 1 pg/L EPA 200.8 or 6020A Barium 5 pg/L EPA 200.7 or 6010C Beryllium 1 pg/L EPA 200.8 or 6020A Boron 50 pg/L EPA 200.7 or 6010C Cadmium 1 pg/L EPA 200.8 or 6020A Chromium 1 pg/L EPA 200.7 or 6010C Cobalt 1 pg/L EPA 200.8 or 6020A Copper 0.005 mg/L EPA 200.7 or 6010C Iron 10 pg/L EPA 200.7 or 6010C Lead 1 pg/L EPA 200.8 or 6020A Manganese 5 pg/L EPA 200.7 or 6010C Mercury (low level) 0.012 pg/L EPA 245.7 or 1631 Molybdenum 5 pg/L EPA 200.7 or 6010C Nickel 5 pg/L EPA 200.7 or 6010C Total Combined Radium (Ra-226 and Ra-228) 4 5 pCi/L EPA 903.0 Selenium 1 pg/L EPA 200.8 or 6020A Strontium 5 pg/L EPA 200.7 or 6010C Thallium (low level) 0.2 pg/L EPA 200.8 or 6020A Vanadium (low level) 0.3 mg/L EPA 200.8 or 6020A Zinc 5 pg/L EPA 200.7 or 6010C Anions/Cations Alkalinity (as CaCO3) 20 mg/L SM 2320B Bicarbonate 20 mg/L SM 2320 Calcium 0.01 mg/L EPA 200.7 Carbonate 20 mg/L SM 2320 Chloride 0.1 mg/L EPA 300.0 or 9056A Magnesium 0.005 mg/L EPA 200.7 Nitrate as Nitrogen 0.023 mg-N/L EPA 300.0 or 9056A Potassium 0.1 mg/L EPA 200.7 Sodium 0.05 mg/L EPA 200.7 Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 2 Table 6-4. Ash Basin Surface Water, Pore Water and Seep Parameters and Analytical Methods Parameter RL Units Method Sulfate 0.1 mg/L EPA 300.0 or 9056A Sulfide (as HZS) 5 0.05 mg/L SM450OS-D Total Dissolved Solids 25 mg/L SM 2540C Total Organic Carbon 0.1 mg/L SM 5310 Total Suspended Solids 2 mg/L SM 2450D Additional Groundwater Constituents Arsenic (III) (V) Vender Specific pg/L IC-ICP-CRC-MS Chromium (IV) (VI) Vender Specific pg/L IC-ICP-CRC-MS Iron Speciation (Fe(II), Fe(III) Vendor Specific pg/L IC-ICP-CRC-MS Manganese Speciation (Mn(II), Mn(IV) Vendor Specific pg/L IC-ICP-CRC-MS Selenium (IV) (VI) Vendor Specific pg/L RP-ICP-CRC-MS Notes: 1. Select constituents will be analyzed for total and dissolved concentrations. 2. RL is the laboratory analytical method reporting limit. 3. NA indicates not applicable. 4. Sulfide (as HZS) will be analyzed for groundwater samples only. 5. All EPA methods and RLs are at or below the respective 2L or 213 Standard for constituents with standards Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 2 of 2 Table 6-5. Transition Zone Mineralogy Results Boring ID Lab Performing Analysis Unique Lab Identifier Sample Depth (ft bgs) Mineralogical Composition (wt %) Quartz Feldspars Biotite Amphibole Dolomite Gibbsite A13-71D American Assay MS-13 80.4-80.6 25.7 44.7 15.2 13.5 - - A13-41D American Assay MS-17 70.3-70.5 0.9 52 38 9 - - AB-12D American Assay MS-19 54-54.3 0.4 71.2 26.4 - 1 1 Notes: ft bgs = feet below ground surface Chemical composition of constituent minerals is as follows: Quartz - SiO2, Feldspar - (K,Na)[AlSi3O8]-Ca[Al2Si2O8], Biotite - K2(Mg,Fe+2)6_4(Fe+3,AI,Ti)0_2[Si6_,AI2_1( Amphibole -(Ca,Na,K,Mn)2_3(Mg,Fe+2,Fe+3,AI,Ti,Mn.Cr.Li,Zn)5(Si,AI)8022(OH)2, Dolomite - CaMg(CO3)2r Gibbsite - AI(OH)3 Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-6. Transition Zone Results, Elemental Composition and % Oxides Boring ID Lab Performing Analysis Unique Lab Identifier Sample Depth (ft bgs) Elemental Composition (ppm) As Cd Ce Co Cu Ga La Mo Ni Pb Sb Se Sn W Zn Zr A13-7D American Assay MS-13 80.4-80.6 8 <0.2 70 39 121 21 20 <1 39 14 <1 <1 4 <1 87 12 A13-4D American Assay MS-17 70.3-70.5 5 <0.2 324 42 129 24 134 <1 36 19 <1 <1 4 <1 87 13 AB-12D American Assay MS-19 54-54.3 7 <0.2 442 22 60 23 203 <1 13 30 <1 <1 6 <1 60 15 Notes: ft bgs = feet below ground surface ppm = parts per million Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-7. Whole Rock Chemistry Results, Elemental Composition and % Oxides Boring ID Lab Performing Analysis Unique Lab Identifier Sample Depth (ft bgs) Elemental Composition (ppm) As Cd Ce Co Cu Ga La Mo Ni Pb Sb Se Sn W Zn Zr AL-3D American Assay MS-11 186.9-187.0 8 <0.2 379 19 31 17 206 1 15 63 2 <1 1 <1 55 24 AB-6D American Assay MS-12 63.9-64 11 <0.2 290 43 71 12 127 2 182 37 2 <1 2 <1 80 13 A13-7D American Assay MS-14 88.7-89.0 3 <0.2 60 32 41 15 33 <1 58 25 3 <1 2 <1 87 17 AB-9D American Assay MS-15 51-51.2 8 <0.2 1 206 1 54 45 9 1 106 1 <1 1 392 1 16 1 5 <1 1 <1 1 69 1 19 AB-4D American Assay MS-16 79.8-80 2 <0.2 118 18 1 4 22_4 65 1 17 32 2 <1 2 <1 80 8 GWA-2D American Assay MS-18 84.5-84.8 4 <0.2 261 16 11 19 120 1 5 53 2 1 <1 1 <1 73 24 Notes: ft bgs = feet below ground surface ppm = parts per million Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-8. Petrographic Analysis Summary Boring ID Petrography By Sample ID Sample Depth Mineral Percentage by Volume' Rock Type Quartz Plagioclase Alkali Feldspar Hornblende Pyroxene Biotite Chlorite Epidote Sericite (Muscovite) Tremolite Apatite Allanite Sphene Pyrite Zircon AL-3D HDR M-AL-3D-1 186.4' TO 186.85' 18 35 25 3 - 15 - - tr' - tr 3 1 - tr Biotite Granite AB-6D HDR M-AB-6D-1 64.0'to 64.3' 5 40 - 20 5 15 10 1 1 2 tr - - - tr Meta-Andesite AB-7D HDR M-AB-7D-1 89.0'to89.4' 20 30 - 15 - 25 tr 2 1 - tr - - 6 tr Meta-Dacite AB-9D HDR M-AB-9D-1 51.2'to51.6' 10 30 5 5 - 35 Tr 1 113 - Tr - - 2 tr Meta-Andesite AB-4D HDR M-AB-4D-1 79.6'to79.8' 5 55 1 tr 20 - 15 1 3 1 - tr - tr tr tr Meta -Diorite GWA-2D HDR M-GWA-2D-1 885to89.0' 15 30 20 - - 25 tr 3 tr - tr 5 tr 1 tr Meta -Granite Vercent Mineralogy estimated using Comparison Charts for Estimating Percentage Composition. All estimates are approximate. 2tr - Trace Amounts. 3-10% Coarse Muscovite. Quartz- SiO2 Plagioclase Feldspar: NaAISi3O6 - CaAI2Si2O6 Biotite: K(Mg,Fe)3AISi3Oj6(OH)2 Pyrite: FeS2 Apatite: Ca5(PO4)3(F,CI,OH) Zircon: ZrSiO, Sericite: K2AI4[Si3AI01o]2(OH)2 Chlorite: (Mg,Fe)3(Si,AI)4Oj6(OH) 2 (Mg,Fe)3(OH)6 Epidote: Ca2Al2(Fe31;Al)(SiO4)(Si2O7)0(OH) Pyroxene (augite): (Ca,Na)(Mg,Fe,AI,Ti)(Si,AI)2O6 Pyroxene (diopside): MgCa&2O6 Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 TABLE 6-9 HISTORIC WATER LEVEL DATA MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Water Level (Feet) Screened Interval (Feet, BGS) Monitoring Zone Well 7/22/2015 9/28/2015 6/22/2016 3/10/2017 6/12/2017 6/14/2017 9/22/2017 AB-10BR --- --- --- 790.60 790.25 --- 790.14 120 125 Bedrock AB-10D 789.04 789.08 789.95 790.59 790.12 --- 790.00 71 76 Deep AB-10S 789.16 789.10 790.84 791.92 790.98 --- 790.53 9 24 Shallow AB-10SL 788.98 788.97 790.17 790.90 790.25 --- 790.10 40 50 Shallow AB-11D 795.10 793.69 797.13 795.89 794.24 --- 795.09 77 82 Deep AB-11S 793.18 792.70 795.71 795.30 795.16 --- 794.60 6 16 Shallow AB-12BR --- --- --- 794.15 794.13 --- 793.84 101 106 Bedrock AB-12D 790.85 791.09 791.52 791.11 791.02 --- 791.03 62 67 Deep AB-12S 790.76 790.48 790.29 790.22 789.97 --- 790.07 3 13 Shallow AB-12SL 790.56 790.96 790.61 790.43 789.27 --- 790.35 40 50 Shallow AB-13D 797.67 797.10 798.30 797.86 798.24 --- 797.64 81 86 Deep AB-13S 797.30 796.63 798.77 797.82 797.51 --- 801.51 15 30 Shallow AB-14D 809.46 808.04 810.81 808.41 811.40 --- 809.65 80 85 Deep AB-14S 808.65 807.17 812.80 809.45 810.60 --- 808.82 6 21 Shallow AB-15BR 804.03 804.62 807.40 807.10 806.55 --- 806.86 107 112 Bedrock AB-15D 802.75 801.56 803.52 803.39 803.88 --- 803.38 64 69 Deep AB-15S 804.25 802.86 804.56 805.17 805.79 --- 804.10 5 20 Shallow AB-15SL 800.82 800.12 801.41 801.55 801.92 --- 801.54 40 50 Shallow AB-16D 813.95 811.89 816.42 815.72 815.38 --- 815.13 41 46 Deep AB-16S 814.26 811.64 816.33 816.18 816.51 --- 815.96 3 13 Shallow AB-17D 818.96 818.10 819.51 820.00 820.37 --- 819.96 106 111 Deep AB-17S 818.41 817.72 818.79 819.22 819.59 --- 819.33 6 21 Shallow AB-18D 817.91 817.50 817.85 818.40 817.67 --- 818.77 72 77 Deep AB-18S 817.69 817.36 817.61 817.99 818.55 --- 818.64 3 13 Shallow AB-1BR 771.16 772.96 774.25 773.74 774.48 --- 774.21 119 124 Bedrock AB-1D 770.08 769.44 770.69 770.48 771.31 --- 771.10 91 96 Deep AB-1S 767.10 766.76 767.87 767.59 768.37 --- 768.02 6 20 Shallow AB-20D 827.48 827.40 826.64 826.64 826.20 --- 826.24 139 144 Deep AB-20S 829.36 828.98 828.67 828.68 828.22 --- 828.15 54 69 Shallow AB-21D 792.37 792.48 793.19 793.05 792.90 --- 792.78 60 65 Deep AB-21S 791.30 791.12 791.78 791.61 791.58 --- 791.36 13 28 Shallow AB-2D 766.60 765.49 768.10 766.62 768.12 --- 767.15 91 96 Deep AB-2S 760.71 759.53 763.30 759.88 761.91 --- 761.16 17 32 Shallow AB-3D 797.18 796.95 797.45 796.48 796.06 --- 795.17 130 135 Deep AB-3S 798.46 797.79 798.32 797.12 796.62 --- 795.67 8 24 Shallow AB-4D 799.54 793.84 794.12 793.65 793.38 --- 792.80 72 77 Deep AB-4S 799.61 799.73 799.41 798.55 798.50 --- 797.62 6 21 Shallow AB-4SL 799.36 799.35 799.15 798.35 798.17 --- 797.25 39 49 Shallow P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-9 Historical Water Level Page 1 of 4 TABLE 6-9 HISTORIC WATER LEVEL DATA MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Water Level (Feet) Screened Interval (Feet, BGS) Monitoring Zone Well 7/22/2015 9/28/2015 6/22/2016 3/10/2017 6/12/2017 6/14/2017 9/22/2017 AB-5BR 799.25 799.60 799.25 799.05 799.10 --- 798.86 105 110 Bedrock AB-5D 799.34 800.27 799.85 799.58 799.56 --- 799.36 78 83 Deep AB-5S 799.50 800.29 799.92 799.52 799.63 --- 799.39 3 18 Shallow AB-6BR 817.10 815.67 820.11 817.88 --- --- --- 105 110 Bedrock AB-6BRA --- --- --- --- 818.18 --- 816.64 --- --- Bedrock AB-6D 817.86 816.43 820.87 818.56 819.69 --- 818.09 63 68 Deep AB-6S 819.80 818.43 823.07 820.21 821.38 --- 820.16 7 22 Shallow AB-7D 813.33 811.85 816.33 814.37 815.39 --- 813.58 79 84 Deep AB-7S 814.10 812.32 817.45 815.41 816.86 --- 815.18 5 20 Shallow AB-8D 764.40 791.99 792.12 791.46 791.21 --- 790.90 95 100 Deep AB-8S 766.14 792.04 791.74 790.92 789.67 --- 791.02 3 13 Shallow AB-9BR 790.62 790.59 789.91 790.60 789.37 --- 790.41 78 83 Bedrock AB-9D 789.34 789.32 789.89 789.84 788.61 --- 789.58 48 53 Deep AB-9S 789.78 789.73 790.53 790.27 790.11 --- 790.09 3 10 Shallow AL-1BR --- --- --- 776.78 777.28 --- 776.50 122 127 Bedrock AL-1D 773.91 773.70 --- 774.31 774.36 --- 774.23 80 85 Deep AL-1S 778.74 778.45 --- 779.31 779.45 --- 779.31 32 47 Shallow AL-2BR 801.31 800.92 801.74 801.23 800.87 --- 800.68 204 209 Bedrock AL-2BRL --- --- --- 796.99 797.72 --- 796.82 --- --- Bedrock AL-2D 798.99 798.70 799.50 799.19 798.86 --- 798.73 152 157 Deep AL-2S 797.22 796.94 797.69 797.57 797.26 --- 797.19 112 128 Shallow AL-3BR --- --- --- 803.80 803.69 --- 803.22 229 234 Bedrock AL-3D 802.33 801.41 803.28 803.01 802.84 --- 802.35 179 184 Deep AL-3S 802.84 801.98 803.94 804.03 803.79 --- 793.28 97 118 Shallow AL-4BR --- --- --- 810.27 809.80 --- 809.06 179 184 Bedrock AL-4D 810.09 809.75 810.16 810.31 809.84 --- 809.41 148 153 Deep BG-1BR --- --- 799.68 --- --- --- --- 84 89 Bedrock BG-1D 802.42 801.47 804.87 797.73 773.74 --- 803.31 35 40 Deep BG-1S 805.10 801.97 805.20 805.66 807.07 --- 806.62 5 15 Shallow BG-2BR 807.21 806.38 808.85 807.57 807.84 --- 807.43 50 55 Bedrock BG-2S 811.33 807.28 809.03 809.06 809.31 --- 809.27 6 16 Shallow BG-3BR --- --- 833.07 829.10 831.13 --- 830.79 105 110 Bedrock BG-3D 836.20 833.73 837.77 832.72 1 835.30 --- 835.10 59 1 64 1 Deep BG-3S 833.39 831.21 836.12 831.28 833.85 --- 833.00 22 32 Shallow GWA-10D --- --- --- 767.48 767.50 --- 767.25 114 118 Deep P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-9 Historical Water Level Page 2 of 4 TABLE 6-9 HISTORIC WATER LEVEL DATA MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Water Level (Feet) Screened Interval (Feet, BGS) Monitoring Zone Well 7/22/2015 9/28/2015 6/22/2016 3/10/2017 6/12/2017 6/14/2017 9/22/2017 GWA-10S --- --- --- 764.60 764.62 --- 764.17 5 20 Shallow GWA-11BR --- --- --- --- 764.08 --- 762.98 150 155 Bedrock GWA-11D --- --- 764.25 762.94 764.39 --- 763.36 110 115 Deep GWA-11S --- --- 766.64 765.60 766.61 --- 765.68 40 55 Shallow GWA-12BR --- --- --- 857.81 859.12 --- 857.60 113 118 Bedrock GWA-12D --- --- --- 858.59 859.99 --- 857.11 88 93 Deep GWA-12S --- --- --- 870.33 871.75 --- 869.71 10 25 Shallow GWA-13D --- --- --- 860.01 860.86 --- --- 134 139 Deep GWA-13S --- --- --- 866.61 868.10 --- 865.70 15 30 Shallow GWA-14D --- --- --- --- --- 867.98 867.44 105 110 Deep GWA-14S --- --- --- --- --- 868.04 867.59 35 50 Shallow GWA-15S --- --- --- --- 758.57 --- 756.67 21 36 Shallow GWA-1BR 764.34 763.68 765.15 763.88 764.78 --- 764.80 152 156 Bedrock GWA-1D 760.78 760.92 762.49 761.32 762.74 --- 762.26 119 124 Deep GWA-1S 760.84 759.71 761.86 760.17 762.01 --- 781.28 38 53 Shallow GWA-2D 802.72 801.29 805.46 803.27 --- --- --- 78 83 Deep GWA-2DA --- --- --- --- 804.26 --- 803.25 94 99 Deep GWA-2S 803.12 801.65 805.83 803.63 804.80 --- 803.39 14 30 Shallow GWA-3D 832.80 832.66 833.29 833.00 832.95 --- 832.81 36 41 Deep GWA-3S 830.09 829.99 830.37 830.30 830.31 --- 830.21 3 13 Shallow GWA-4D 840.34 839.87 841.66 841.15 840.70 --- 840.29 81 86 Deep GWA-4S 843.57 842.89 844.09 843.78 843.26 --- 842.91 49 64 Shallow GWA-5D 812.79 812.23 813.39 811.09 810.84 --- 810.53 44 49 Deep GWA-5S 812.57 811.94 813.23 below pump below pump --- --- 25 35 Shallow GWA-6D 802.70 801.47 804.00 802.23 802.38 --- 801.41 102 107 Deep GWA-6S 802.94 801.69 804.22 802.38 802.56 --- 801.57 38 48 Shallow GWA-7D 799.99 798.45 803.58 800.51 801.80 --- 800.95 26 31 Deep GWA-7S 797.02 795.24 801.01 798.05 799.27 --- 798.26 9 19 Shallow GWA-8D 817.58 816.20 818.80 816.20 816.39 --- 815.78 56 61 Deep GWA-8S 818.71 817.45 819.75 817.37 817.31 --- 816.94 23 38 Shallow GWA-9BR 846.38 845.00 847.85 846.90 847.25 --- 839.03 84 89 Bedrock MS-10 dry --- --- 832.61 833.91 --- --- 13 23 Shallow MS-11 --- --- --- 825.38 825.88 --- 824.40 33 43 Shallow MS-12 --- --- 818.59 811.53 812.66 --- 811.31 21 31 Shallow MS-14 --- --- --- 806.84 807.29 --- 805.37 34 44 Shallow MS-15 --- --- --- 808.73 808.84 --- 807.53 53 63 Shallow MS-16 --- --- --- 811.17 811.40 --- 810.47 27 37 Deep MS-8 --- --- --- 826.63 826.94 --- 826.17 20 30 Shallow P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-9 Historical Water Level Page 3 of 4 TABLE 6-9 HISTORIC WATER LEVEL DATA MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Water Level (Feet) Screened Interval (Feet, BGS) Monitoring Zone Well 7/22/2015 9/28/2015 6/22/2016 3/10/2017 6/12/2017 6/14/2017 9/22/2017 MW-10D 755.24 --- --- 754.48 757.86 --- 755.78 82 87 Deep MW-10S 754.75 --- --- 757.18 757.55 --- 755.50 14 29 Shallow MW-11D 840.13 --- --- 840.45 840.76 --- 840.26 88 93 Deep MW-11S 840.12 --- --- 840.38 840.57 --- 840.25 39 54 Shallow MW-12D 855.19 --- --- 857.42 858.57 --- 855.31 93 98 Deep MW-12S 855.46 --- --- 859.08 859.84 --- 855.50 10 25 Shallow MW-13D 843.06 --- --- 843.53 843.80 --- 842.85 44 49 Deep MW-13S 841.36 --- --- 841.92 842.15 --- 841.30 6 21 Shallow MW-14BR 773.60 773.18 774.75 774.24 774.24 --- 773.89 99 104 Bedrock MW-14D 772.61 770.61 --- 773.31 773.47 --- 772.94 58 63 Deep MW-14S 773.06 771.99 --- 773.67 773.85 --- 773.31 32 47 Shallow MW-3 --- --- --- 804.68 804.54 --- 804.15 16 26 Shallow MW-4 829.99 --- --- 828.74 829.23 --- 828.60 37 47 Shallow MW-4D 829.10 832.01 830.39 828.39 829.03 --- 828.50 56 61 Deep MW-5 --- 826.73 --- 842.28 842.50 --- 840.84 18 28 Shallow MW-6 --- --- 830.73 --- --- --- --- --- --- --- MW-6D 769.00 768.47 770.59 772.60 773.95 --- 773.62 83 88 Deep MW-6S 766.31 765.82 767.96 769.86 771.45 --- 770.90 15 25 Shallow MW-7 --- --- --- 813.55 813.18 --- 812.91 --- --- --- MW-7D 768.76 768.03 769.87 769.24 770.21 --- 769.83 61 66 Deep MW-7S 761.59 760.74 762.64 761.79 763.05 --- 762.18 11 21 Shallow MW-8D 759.11 757.48 760.79 760.00 761.30 --- 759.68 93 98 Deep MW-8S 757.09 755.28 758.84 757.08 759.59 --- 757.72 17 27 Shallow MW-9D 758.16 756.30 759.93 757.58 760.47 --- 758.69 90 95 Deep MW-9S 759.41 757.19 761.79 759.64 761.36 --- 760.75 21 31 Shallow OB-1 (Ash Basin) 779.43 --- --- 778.89 779.99 --- --- 40 56 Shallow OB-1 (Dry Ash Landfill) --- --- --- 801.81 802.02 --- --- 53 63 Shallow OB-2 (MW-6) --- --- --- 103 118 Shallow OB-3 (MW-7) --- --- 812.03 1 --- I --- --- --- 39 54 Shallow Notes BGS - Below ground surface Prepared by: CAG Checked by: DMY P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-9 Historical Water Level Page 4 of 4 TABLE 6-10 HORIZONTAL GROUNDWATER GRADIENTS AND VELOCITIES MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Direction Data Points Gradient (ft per ft) Velocity (ft per yr) Ash SE AB-14S to AB-8S 0.012 31.52 SE AB-15S to AB-12S 0.008 21.75 E AB-5S to AB-3S 0.003 8.37 SE AB-7S to AB-21S 0.012 33.87 Shallow E GWA-2S to GWA-1S 0.010 22.36 SE AL-2S to AL-1S 0.007 15.60 S AL-1S to MW-6S 0.007 15.54 SE AB-11S to MW-14S 0.013 29.58 S MW-6S to MW-10S 0.016 36.42 Deep SE AB-3D to GWA-1D 0.022 129.43 E/NE AB-6D to AB-21D 0.012 70.25 SW GWA-6D to AB-11D 0.005 27.51 SE AB-16D to AB-12D 0.011 64.42 SE GWA-4D to AB-13D 0.014 79.84 SE AL-4D to AB-10D 0.012 67.76 Bedrock SE AB-5BR to GWA-1BR 0.014 87.08 SE AB-15BR to AB-9BR 0.007 42.03 SE GWA-9BR to AB-9BR 0.009 59.33 Prepared by: BDW Checked by: DMY Notes• ft = feet yr = year 1. Water level measurements used for these calculations were collected on September 22, 2017 2. Geomean of hydraulic conductivities taken from Table 6-11 for each flow zone 3. Mean effective porosity each flow zone taken from 2015 CSA, Table 11-8 (HDR, Inc) and CAP Part 2, Appendix A. Table 11-11 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\ Table 6-10 Horizontal Groundwater Gradients and Velocities Page 1 of 1 TABLE 6-11 VERTICAL HYDRAULIC GRADIENTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Well ID Potential Vertical Gradient (ft per ft) Flow Direction Shallow to Deep AB-1S to AB-11) -0.0383 Upward AB-2S to AB-21) -0.0867 Upward AB-3S to AB-31) 0.0043 Downward AB-4SL to AB-4D 0.0794 Downward AB-5S to AB-51) 0.0004 Downward AB-6S to AB-61) 0.0411 Downward AB-7S to AB-71) 0.0232 Downward AB-8S to AB-81) 0.0014 Downward AB-9S to AB-91) 0.0119 Downward AB-10S to AB-10SL 0.0151 Downward AB-10SL to AB-10D 0.0035 Downward AB-11S to AB-11D -0.0072 Upward AB-12S to AB-12D -0.0168 Upward AB-12S to AB-12SL -0.0074 Upward AB-12SL to AB-12D -0.0346 Upward AB-13S to AB-13D 0.0636 Downward AB-14S to AB-14D -0.0118 Upward AB-15S to AB-15SL 0.0786 Downward AB-15SL to AB-15D -0.0865 Upward AB-16S to AB-16D 0.0238 Downward AB-17S to AB-17D -0.0067 Upward AB-18S to AB-18D -0.0019 Upward AB-20S to AB-20D 0.0237 Downward AB-21S to AB-21D -0.0336 Upward AL-1S to AL-11) 0.1182 Downward AL-2S to AL-21) -0.0448 Upward AL-3S to AL-31) -0.1233 Upward BG-1S to BG-1D 0.1324 Downward BG-2S to BG-2BR 0.0455 Downward BG-3S to BG-3D -0.0629 Upward GWA-1S to GWA-11) -0.0275 Upward GWA-2S to GWA-2DA 0.0023 Downward GWA-3S to GWA-3 D -0.0854 Upward GWA-4S to GWA-41) 0.0186 Downward GWA-6S to GWA-61) 0.0024 Downward GWA-7S to GWA-71) -0.2196 Upward GWA-8S to GWA-81) 0.0427 Downward GWA-10S to GWA-10D -0.0298 Upward GWA-11S to GWA-11D 0.0350 Downward GWA-12S to GWA-12D 0.0066 Downward GWA-13S to GWA-13DA 0.0552 Downward GWA-14S to GWA-14D 0.0024 Downward Deep to Bedrock AB-1D to AB-1BR -0.1116 Upward AB-1BR to AB-1BRL 0.0863 Downward AB-51) to AB-5BR 0.0185 Downward AB-61) to AB-6BRA 0.0050 Downward AB-91) to AB-9BR -0.0279 Upward AB-10D to Ab-10BR -0.0029 Upward AB-12D to AB-12BR -0.0731 Upward AB-15D to AB-15BR -0.0805 Upward AL-11) to AL-1BR -0.0534 Upward AL-21) to AL-2BR -0.0378 Upward AL-2BR to AL-2BRL 0.0252 Downward AL-31) to AL-3BR -0.0174 Upward AL-41) to AL-4BR -0.0279 Upward BG-11) to BG-1BR 0.0292 Downward BG-31) to BG-3BR 0.1008 Downward GWA-11) to GWA-1BR -0.0779 Upward GWA-12D to GWA-12BR 0.4499 Downward Prepared By: ENK Checked By: BDW Notes: Water levels were collected by Pace Analytical on September 22, 2017. P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-11 Vertical Gradient Page 1 of 1 Table 6-12. Hydrostratigraphic Layer Properties - Horizontal Hydraulic Conductivity Hydrostratigraphic Unit N Geometric Mean (cm/sec) Geometric Mean + 1SD (cm/sec) Geometric Mean -1SD (cm/sec) Geometric Median (cm/sec) Minimum cm/sec Maximum cm/sec Ash 17 2.9E-04 4.5E-03 1.9E-05 3.5E-04 2.5E-06 4.3E-02 Fill 14 0.000048 0.00017 0.000013 0.000064 0.0000054 0.00039 Alluvium S 10 0.00049 0.0052 0.000046 0.001 0.0000082 0.026 M 1 31 0.00078 0.0038 0.00016 0.00053 0.0001 0.026 M2 22 0.000071 0.00053 0.0000095 0.000099 0.0000015 0.0023 Transition Zone TZ 12 0.00052 0.0031 0.000085 0.00069 0.000034 0.0058 Bedrock BR 54 0.00024 0.0012 0.00005 0.00029 0.0000076 0.0056 Notes: 1. Hydraulic Conductivity, %' values have an approximate lognormal distribution. Geometric mean, median, and standard deviation estimated by taking the log of the values and running standard statistics on the log values, then converting those values back. 2. Dataset derived from CSA Investigation and historical reports. Refer to tables 11-4 and 11-6 for historic conductivity data. 3. Fill dataset derived from CSA Investigation Sites Allen (N=5), Cliffside (N=4), Dan River (N=2), and Riverbend (N= 3) 4. Alluvium dataset derived from Riverbend CSA investigation (N=3), Allen (N=2), Cliffside (N=3), and Dan River (N=2). Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-13. Hydrostratigraphic Layer Properties - Vertical Hydraulic Conductivity Hyd rostrati graph i c Unit N Geometric Mean (cm/sec) Geometric Mean + 1SD (cm/sec) Geometric Mean - 1SD (cm/sec) Geometric Median (cm/sec) Minimum (cm/sec) Maximum (cm/sec) Ash 5 6.7E-05 2.9E-04 1.6E-05 5.6E-05 1.2E-05 5.6E-04 Fill 5 6.1 E-05 2.5E-04 1.5E-05 5.9E-05 1.6E-05 4.8E-04 Alluvium (S) 12 8.7E-06 4.6E-04 1.7E-07 8.1 E-06 4.6E-08 1.5E-02 M1 17 2.2E-05 2.2E-04 2.2E-06 4.8E-05 6.2E-07 4.1 E-04 M2 6 1.0E-04 5.5E-04 1.9E-05 7.8E-05 1.5E-05 1.6E-03 Transition Zone (TZ) 1 0 1- - - - - - Bedrock (BR) 1 0 1- - - - -I - Notes: 1. Hydraulic Conductivity, `k,' values have an approximate lognormal distribution. Geometric mean, median, and standard deviation estimated by taking the log of the values and running standard statistics on the log values, then converting those values back. 2. Dataset derived from CSA Investigation and historical reports. Refer to tables 11-6 for historic conductivity data. 3. Vertical hydraulic conductivity values for the TZ and BR could not be measured in the field or laboratory. Vertical and horizontal conductivity for these layers are unlikely to be equal. Consider to be equal as an initial assumption and adjust as necessary during flow model calibration 3. Alluvium dataset derived from Allen (N=4), Belews (N=1), Cliffside (N=3), and Dan River (N=4) CSA Investigations. Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-14. Historic Slug Test Permeability Results Borehole Category of Test Depth 1 of Test (ft bgs) Depth 2 of Test (ft bgs) Horizontal Hydraulic Conductivity, V (cm/sec) Hydrostratigraphic Layer B-3 Historic Slug 49 56 1.77E-04 M1 B-4 Historic Slug 52 59 1.57E-04 M1 B-6 Historic Slug 43 47 1.56E-04 M1 B-7 Historic Slug 47 61 2.14E-05 M2 MS-2 Historic Slug 21 30 2.26E-04 M1 / M2 MS-4 Historic Slug 39 46 5.55E-04 M1 / M2 MS-5 Historic Slug 32 38 4.56E-04 M1 MS-6 Historic Slug 27 38 1.04E-04 M1 MS-7 Historic Slug 20 26 3.07E-04 M1 MS-8 Historic Slug 27 30 1.93E-04 M1 MS-10 Historic Slug 12 20 1.42E-04 M1 MS-11 Historic Slug 27 39 1.79E-04 M1 OW-1 Historic Slug 20 26 5.78E-04 M1 OW-2 Historic Slug 18 26 3.65E-04 M1 OW-3 Historic Slug 18 27 7.19E-04 M1 MW-4S Historic Slug 39 49 3.70E-04 M1 / M2 MW-4D Historic Slug 56 61 4.02E-04 BR MW-6S Historic Slug 11 21 2.62E-02 M1 MW-6D Historic Slug 79 84 1.18E-04 M2 MW-7S Historic Slug 7 17 1.21E-02 M1 MW-7D Historic Slug 58 63 1.31E-03 BR MW-8S Historic Slug 13 23 1.13E-03 M1 / M2 MW-8D Historic Slug 89 94 7.20E-04 BR MW-9S Historic Slug 17 27 9.51E-04 M1 MW-9D Historic Slug 87 92 5.64E-04 TZ / BR MW-10S Historic Slug 12 27 7.50E-04 M1 MW-10D Historic Slug 81 86 1.13E-04 M2 MW-11S Historic Slug 37 52 1.54E-03 M1 MW-11D Historic Slug 86 91 3.43E-05 TZ MW-12S Historic Slug 7 22 1.56E-03 M1 MW-12D Historic Slug 90 95 1.34E-04 M2 MW-13S Historic Slug 3 18 2.40E-04 M1 MW-13D Historic Slug 42 47 7.92E-04 TZ MW-14S Historic Slug 28 49 9.57E-04 M1 / M2 MW-14D Historic Slug 55 60 6.02E-04 TZ Notes: 1. Refer to Appendix H for historic slug test reports. 2. Historic boring logs (Appendix H) were used in the hydrostratigraphic characterization of screen intervals. 3. Historic slug test results in which test interval bridges hydrostratigraphic layers were not used in the statistical analysis. References: 1. Hydrogeologic Study. Developed by S&ME, dated August 29, 2003. S&ME Project No. 1264-02-578 2. Ash Basin Monitoring Well Installation Report. Developed by S&ME, dated December 4, 2006. S&ME Project No. 1356-06-834 3. Ash Basin Monitoring Well Installation Report. Developed by MACTEC, dated January 31, 2010. MACTEC Project No. 6228-10-5284 Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 TABLE 6-15 IN -SITU HYDRAULIC CONDUCTIVITY RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Ash Pore Water Well ID Slug Test Slug Test Number Hydraulic Conductivity (cm/sec) Hydraulic Conductivity (ft/day) Measured Geometric Mean Measured Geometric Mean _j AB-3S Slug Out Test 2 2.12E-03 -- 6.01E+00 -- AB-4S Slug Out Test 2 3.72E-04 -- 1.05E+00 -- AB-4SL Slug In Test 1 3.75E-05 3.73E-05 1.06E-01 1.06E-01 SlugOut Test 2 3.71E-05 1.05E-01 AB-5S Slug Out Test 2 1.40E-05 -- 3.96E-02 1 AB-6S Slug In Test 1 9.46E-05 1.14E-04 2.68E-01 3.24E-01 SlugOut Test 2 1.38E-04 3.91E-01 AB-8S Slug In Test 1 7.03E-02 5.52E-02 1.99E+02 1.57E+02 Slug -Out Test 2 4.34E-02 1.23E+02 AB-10SL Slug In Test 1 2.44E-04 2,60E-04 6.92E-01 7,37E-01 SlugOut Test 2 2.77E-04 7.85E-01 AB-10S Slug Out Test 2 4.29E-04 -- 1.22E+00 -- AB-12S Sluq In Test 1 1.93E-02 2,31E-02 5.47E+01 6.55E+01 SlugOut Test 2 2.77E-02 7.85E+01 AB-12SL Sluq In Test 1 4.32E-04 4.77E-04 1.22E+00 1.35E+00 SlugOut Test 2 5.27E-04 1.49E+00 AB-13S Slug In Test 1 6.72E-05 6.15E-05 1.90E-01 1.74E-01 SlugOut Test 2 5.63E-05 1.60E-01 AB-14S Slug -In Test 1 3.33E-02 -- 9.45E+01 AB-15S Slug Out Test 2 7.81E-04 -- 2.21E+00 -- AB-15SL Sluq In Test 1 5.27E-04 5.26E-04 1.49E+00 1.49E+00 SlugOut Test 2 5.25E-04 1.49E+00 AB-17S Slug Out Test 2 7.66E-04 -- 2.17E+00 -- AB-18S Slug -In Test 1 1.46E-02 -- 4.14E+01 -- AB-20S Slug -In Test 1 2.48E-06 -- 7.03E-03 -- AL-3S Slug In Test 1 1.05E-04 7,81E-05 2.97E-01 2,21E-01 SlugOut Test 2 5.83E-05 1.65E-01 GEOMETRIC MEAN 5.05E-04 1.43E+00 HIGHEST CONDUCTIVITY 7.03E-02 1.99E+02 LOWEST CONDUCTIVITY 2.48E-06 7.03E-03 Prepared by: RAG Checked by: DMY Notes: Slug tests were analyzed using the Bouwer-Rice mathmatical model, unless where indicated. cm/sec - centimeter per second ft/day - feet per day -- No statistics necessary, when only one slug test analyzed P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-15 In -Situ Hydraulic ConductivitiesSummary Results by Unit Page 1 of 6 TABLE 6-15 IN -SITU HYDRAULIC CONDUCTIVITY RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Saprolite Well ID Slug Test Slug Test Number Hydraulic Conductivity (cm sec) Hydraulic Conductivity ft/da Measured Geometric Mean Measured Geometric I Mean I AB-1S Sluq In Test 1 2.20E-05 2.27E-05 6.23E-02 6.44E-02 SlugOut Test 2 2.34E-05 6.64E-02 AB-2S Slug In Test 1 4.92E-05 5.53E-05 1.39E-01 1.57E-01 Slug Out Test 2 6.22E-05 1.76E-01 AB-9S Slug Out Test 2 4.96E-05 -- 1.41E-01 I -- AB-11S Slug In Test 1 1.55E-04 1.86E-04 4.38E-01 5.26E-01 Slu Out Test 2 2.23E-04 6.31E-01 AB-16S Slug Out Test 2 1.64E-05 -- 4.63E-02 -- AL-1S Slug In Test 1 1.03E-03 2,10E-03 2.92E+00 5.95E+00 Slug Out Test 2 4.29E-03 1.22E+01 AL-2S Slug Out Test 1 2.10E-04 -- 5.94E-01 -- BG-2S Slug In Test 1 2.64E-05 6.37E-06 7.49E-02 1.81E-02 SlugOut Test 2 1.53E-06 4.35E-03 BG-3S Slug In Test 1 2.64E-05 2,81E-05 7.47E-02 7,97E-02 SlugOut Test 2 3.00E-05 8.51E-02 GWA-1S Slug In Test 1 7.81E-04 5.61E-04 2.21E+00 1.59E+00 Slug Out Test 2 4.03E-04 1.14E+00 GWA-2S Slug In Test 1 1.46E-02 g 87E-03 4.15E+01 2,51E+01 Slug Out Test 2 5.37E-03 1.52E+01 GWA-3S Slug In Test 1 4.84E-03 3.26E-03 1.37E+01 9.24E+00 Sluq Out Test 2 2.20E-03 6.23E+00 GWA-4S Slug In Test 1 1.29E-03 1.08E-03 3.66E+00 3.07E+00 Slug Out Test 2 9.11E-04 2.58E+00 GWA-6S Slug In Test 1 8.43E-03 4.45E-03 2.39E+01 1.26E+01 Slug Out Test 2 2.35E-03 6.66E+00 GWA-7S Slug In Test 1 2.40E-02 7,15E-03 6.80E+01 2,03E+01 Slug Out Test 2 2.13E-03 6.04E+00 GWA-8S �Slug In Test 1 3.63E-02 1.30E-01 1.03E+02 3.69E+02 Slug Out Test 2 4.68E-01 I F1.33E+03 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-15 In -Situ Hydraulic ConductivitiesSummary Results by Unit Page 2 of 6 TABLE 6-15 IN -SITU HYDRAULIC CONDUCTIVITY RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Sa rolite continued Well ID Slug Test Slug Test Number Hydraulic Conductivity cm/sec Hydraulic Conductivity ft/da Measured Geometric n Measured Geometric Mean GWA-10S Slug In Test 1 4.71E-05 -- 1.33E-01 -- GWA-11S Slug Out Test 1 1.50E-04 -- 4.25E-01 -- GWA-12S Slug Out Test 1 1.31E-04 -- 3.71E-01 -- GWA-13S Slug Out Test 1 7.35E-05 -- 2.08E-01 -- MW-4 Slug In Test 1 1.30E-04 6.98E-05 3.68E-01 1.98E-01 SlugOut Test 2 3.75E-05 1.06E-01 MW-7S Slug Out Test 1 4.83E-02 -- 1.37E+02 -- OB-1 Slug In Test 1 8.65E-04 6.75E-04 2.45E+00 1.91E+00 SlugOut Test 2 5.26E-04 1.49E+00 GEOMETRIC MEAN 4.47E-04 1.27E+00 HIGHEST CONDUCTIVITY 4.68E-01 1.33E+03 LOWEST CONDUCTIVITY 1.53E-06 4.35E-03 Prepared by: RAG Checked by: DMY Notes: Slug tests were analyzed using the Bouwer-Rice mathmatical model, unless where indicated. cm/sec - centimeter per second ft/day - feet per day -- No statistics necessary, when only one slug test analyzed P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-15 In -Situ Hydraulic ConductivitiesSummary Results by Unit Page 3 of 6 TABLE 6-15 IN -SITU HYDRAULIC CONDUCTIVITY RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Deep Zone Well ID I Slug Test Slug Test Number Hydraulic Conductivity cm/sec Hydraulic Conductivity ft/da Measured Geometric Mean Measured Geometric Mean I AB-1D Slug Out Test 2 2.42E-04 -- 6.85E-01 -- AB-2D Slug In Test 1 3.36E-03 3.40E-03 9.52E+00 9,63E+00 SlugOut Test 2 3.44E-03 9.74E+00 AB-3D Slug In Test 1 1.10E-03 1.11E-03 3.11E+00 3.16E+00 Slug Out Test 2 1.13E-03 3.21E+00 IF AB-4D Slug In Test 1 2.02E-03 2,01E-03 5.73E+00 5.71E+00 SlugOut Test 2 2.00E-03 5.68E+00 AB-5D Slug In Test 1 7.76E-04 7,52E-04 2.20E+00 2,13E+00 SlugOut Test 2 7.29E-04 2.07E+00 AB-6D Slug In Test 1 4.34E-04 2.46E-04 1.23E+00 6.96E-01 Slug Out Test 2 1.39E-04 3.94E-01 AB-7D Slug In Test 1 1.03E-03 g 87E-04 2.93E+00 2,80E+00 Slug Out Test 2 9.44E-04 2.67E+00 AB-8D Slug In Test 1 1.85E-04 1.36E-04 5.24E-01 3.86E-01 SlugOut Test 2 1.00E-04 2.84E-01 AB-9D Slug In Test 1 1.33E-04 1.37E-04 3.76E-01 3.88E-01 Slug Out Test 2 1.41E-04 4.01E-01 IFAB-10D Slug In Test 1 2.89E-03 3.05E-03 8.18E+00 8,65E+00 SlugOut Test 2 3.23E-03 9.14E+00 AB-11D Slug In Test 1 2.62E-03 2.58E-03 7.43E+00 7.33E+00 Slu Out Test 2 2.55E-03 7.23E+00 AB-12D Slug In Test 1 6.83E-07 9,75E-07 1.93E-03 2,76E-03 Slug Out Test 2 1.39E-06 3.95E-03 IFAB-13D Slug In Test 1 5.49E-04 5.43E-04 1.56E+00 1.54E+00 SlugOut Test 2 5.37E-04 1.52E+00 AB-14D Slug In Test 1 7.65E-04 -- 2.17E+00 -- AB-15D Slug In Test 1 1.06E-03 1.25E-03 3.01E+00 3.53E+00 SlugOut Test 2 1.47E-03 4.15E+00 AB-16D Slug In Test 1 3.57E-05 2.94E-05 1.01E-01 8.34E-0--l2 SlugOut Test 2 2.43E-05 6.88E-02 AB-17D Slug In Test 1 5.95E-03 5.79E-03 1.69E+01 1.64E+01 SlugOut Test 2 5.64E-03 1.60E+01 AB-18D Slug In Test 1 1.22E-02 1.16E-02 3.46E+01 3.27E+01 SlugOut Test 2 1.09E-02 3.10E+01 AB-20D Slug In Test 1 3.59E-05 3.25E-05 1.02E-01 9.23E-02 SlugOut Test 2 2.95E-05 8.37E-02 AB-21D Slug In Test 1 1.41E-03 2.14E-03 3.99E+00 6.07E+00 SlugOut Test 2 3.26E-03 9,25E+00 AL-1D Slug In Test 1 2.15E-04 1.88E-04 6.10E-01 5.32E-01 SlugOut Test 2 1.64E-04 4.64E-01 AL-2D Slug In Test 1 5.73E-04 5.15E-04H.31E+00 .62E+00 1.46E+00 SlugOut Test 2 4.62E-04 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-15 In -Situ Hydraulic ConductivitiesSummary Results by Unit Page 4 of 6 TABLE 6-15 IN -SITU HYDRAULIC CONDUCTIVITY RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Deep Zone (continued) Well ID Slug Test Slug Test Number Hydraulic Conductivity (cm sec) Hydraulic Conductivity ft/da Measured Geometric Measured Geometric AL-31D Sluq In Test 1 2.90E-05 2,60E-05 8.22E 02 7.38E-02 SlugOut Test 2 2.34E-05 6.62E-02 AL-41D Slug In Test 1 1.32E-03 1.30E-03 3.75E+00 3.68E+00 SlugOut Test 2 1.28E-03 3.61E+00 BG-3D Sluq In Test 1 2.52E-03 2,65E-03 7.15E+00 7,52E+00 SlugOut Test 2 2.79E-03 7.91E+00 GWA-11D Sluq In Test 1 5.12E-04 5.19E-04 1.45E+00 1.47E+00 SlugOut Test 2 5.26E-04 1.49E+00 GWA-21D Slug In Test 1 1.37E-05 8,00E-06 3.89E-02 2.27E-02 SlugOut Test 2 4.66E-06 1.32E-02 GWA-31D Sluq In Test 1 5.66E-03 5.85E-03 1.60E+01 1.66E+01 SlugOut Test 2 6.04E-03 1.71E+01 GWA-41D Slug Out Test 1 2.73E-07 -- 7.74E-04 -- GWA-5D Slug In slugOut Test 1 1.24E-04 8,66E-05 3.51E-01 2,46E-01 Test 2 6.05E-05 1.72E-01 GWA-6D Slug In Test 1 6.21E-04 6.61E-04 1.76E+00 1.87E+00 SlugOut Test 1 7.05E-04 2.00E+00 GWA-7D Slug In Test 1 3.14E-04 2,93E-04 8.91E-01 8,29E-01 SlugOut Test 2 2.72E-04 7.72E-01 GWA-8D Slug In Test 1 3.54E-04 3.40E-04 1.00E+00 9,64E-01 SlugOut Test 2 3.27E-04 9.26E-01 GWA-10D Slug In Test 1 6.69E-04 6.00E-04 1.90E+00 1.70E+00 SlugOut Test 2 5.38E-04 1.53E+00 GWA-11D Slug In Test 1 1.23E-03 1.20E-03 3.49E+00 3.39E+00 Slu Out Test 2 1.16E-03 3.29E+00 GWA-12D Slug IU Test 1 1.99E-03 1.71E-03 5.64E+00 4.85E+00 Slu Out Test 2 1.47E-03 4.17E+00 MW-4D Slug Out Test 1 1.74E-04 -- 4.94E-01 -- GEOMETRIC MEAN 4.23E-04 1.20E+00 HIGHEST CONDUCTIVITY 1.22E-02 3.46E+01 LOWEST CONDUCTIVITY 2.73E-07 7.74E-04 Prepared by: RAG Checked by: DMY Notes: Slug tests were analyzed using the Bouwer-Rice mathmatical model, unless where indicated. cm/sec - centimeter per second ft/day - feet per day -- No statistics necessary, when only one slug test analyzed P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-15 In -Situ Hydraulic ConductivitiesSummary Results by Unit Page 5 of 6 TABLE 6-15 IN -SITU HYDRAULIC CONDUCTIVITY RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Bedrock Well ID I Slug Test Slug Test Number Hydraulic Conductivity (cm sec) Hydraulic Conductivity ft/da Measured Geometric mean Measured Geometric Mean AB-1BR Sluq In Test 1 1.69E-03 1.65E-03 4.80E+00 4.68E+00 SlugOut Test 2 1.61E-03 4.56E+00 AB-5BR Slug In Test 1 7.44E-05 7,21E-05 2.11E-01 2,04E-01 SlugOut Test 2 6.99E-05 1.98E-01 AB-6BR Slua In Test 1 1.55E-04 1.90E-04 4.40E-01 5.38E-01 SlugOut Test 2 2.32E-04 6.57E-01 AB-9BR Sluq In Test 1 4.44E-04 4.41E-04 1.26E+00 1.25E+00 SlugOut Test 2 4.38E-04 1.24E+00 AB-15BR Slug In Test 1 2.00E-03 2,03E-03 5.68E+00 5.74E+00 SlugOut Test 2 2.05E-03 5.81E+00 AL-2BR Sluq In Test 1 3.54E-05 3.23E-05 1.00E-01 9.17E-02 SlugOut Test 2 2.95E-05 8.37E-02 BG-2BR Slug In Test 1 6.32E-05 4.26E-05 1.79E-01 1.21E-01 Slug Out Test 2 2.88E-05 --] 8.15E-02 GWA-1BR Slug In Test 1 1.35E-02 1.22E-02 3.82E+01 3.46E+01 SlugOut Test 2 1.10E-02 3.13E+01 d GWA-9BR Slug In Test 1 3.81E-04 3.29E-04 1.08E+00 9.33E-01 SlugOut Test 2 2.84E-04 8.06E-01 BG1BR Slug In Test 1 2.99E-05 2.72E-05 8.49E-02 7.72E-02 Slug Out Test 2 2.48E-05 7.03E-02 BG3BR Slug In Test 1 6.09E-05 4.60E-05 1.73E-01 1.30E-01 Slug Out Test 2 3.47E-05 --] 9.85E-02 GWA-12BR Slug In Test 1 5.64E-05 5.12E-05 1.60E-01 1.45E-01 Slug Out Test 2 4.66E-05 1.32E-01 MW-14BR Slug In Test 1 2.87E-04 2.91E-04 8.13E-01 8.25E-01 SlugOut Test 2 2.95E-04 8.36E-01 GEOMETRIC MEAN 2.15E-04 6.09E-01 HIGHEST CONDUCTIVITY 1.35E-02 3.82E+01 LOWEST CONDUCTIVITY 2.48E-05 7.03E-02 Prepared by: RAG Checked by: DMY Notes: Slug tests were analyzed using the Bouwer-Rice mathmatical model, unless where indicated. cm/sec - centimeter per second ft/day - feet per day -- No statistics necessary, when only one slug test analyzed P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 6-15 In -Situ Hydraulic ConductivitiesSummary Results by Unit Page 6 of 6 Table 6-16. Estimated Effective Porosity/Specific Yield and Specific Storage for Upper Hydrostratigraphic Units (A, F, S, M1, and M2) Effective Porosity/Specific Yield (%) Specific Storage (1/ft) Hydrostratigraphic Unit N Mean (%) Median (%) Mean + 1 SD (%) Mean - 1SD (%) Minimum (%) Maximum (%) Ash 12 14.1 % 10.5% 23.2% 5.1 % 5.0% 32.0% - Fill 17 13.9% 14.0% 19.1 % 8.6% 4.5% 27.0% 6.1 E-05 - 4.0E-05 Alluvium (S) 18 17.4% 16.5% 29.0% 5.8% 3.0% 40.0% 3.0E-04 - 1.5E-05 M1 30 22.8% 25.5% 31.9% 16.4% 5.0% 35.0% 3.0E-04 - 1.5E-05 M2 4 27.9% 27.5% 31.3% 24.5% 25.0% 31.5% 1.5E-05 - 6.2E-05 Notes: 1. Effective porosity/specific yield estimated from soil testing using Fetter/Bear Diagrams (Johnson, 1967). 2. Effective porosity and specific yield are not synonymous. For practical purposes, they may be estimated as approximately equal in value. 3. Specific Storage ranges based on published values (Domenico and Mifflin, 1965). Alluvium and M1 fall within the same range of values. 4. Initial data from Allen (N=5), Buck (N=2), Cliffside (N=2), Dan River (N=8), and Marshall (N=1) CSA Investigations were used in the statistical analysis for alluvium effective porosity/specific yield. Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-17. Total Porosity, Secondary (Effective) Porosity/Specific Yield, and Specific Storage for Lower Hydrostratigraphic Units (TZ and BR) H drostrati ra hic Unit y g p Secondary (Effective) Porosity / Total Porosity% ( ) Specific Storage 1/ft p g( ) Specific Yield % Transition Zone (TZ) 5.0 - 10.0 1.0 - 10.0 1.0E-06 - 2.1 E-05 Bedrock (BR) 2.0 - 5.0 0.01 - 1.0 < 1.0E-06 Notes: 1. Ranges based on published values (Domenico and Mifflin, 1965; Singhal and Gupta, 2010). 2. Effective porosity and specific yield are not synonymous. For practical purposes, they may be estimated as approximately equal in value. Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 Table 6-18. Field Permeability Test Results Borehole Category of Test Depth 1 of Test (ft bgs) Depth 2 of Test (ft bgs) Vertical Hydraulic Conductivity'k' (cm/sec) Horizontal Hydraulic Conductivity'k' (cm/sec) Hydrostratigraphic Layer AB-3D Falling Head, Well Point 120 126 9.01E-06 TZ/BR AB-4D Constant Head, Well Point 41.5 46.5 3.46E-04 A AB-4D Falling Head, Flush Bottom 41.5 - 3.07E-05 A AB-4D Constant Head, Well Point 50.5 55.5 4.12E-03 M1 AB-4D Falling Head, Flush Bottom 50.5 - 2.09E-05 M1 AB-5BR Falling Head, Well Point 72 77 9.43E-05 TZ AB-7D Falling Head, Flush Bottom 39 - 3.01 E-05 M2 AB-7D Falling Head, Well Point 40.5 45.5 1.18E-05 M2 AB-7D Constant Head, Well Point 75 79.7 1.90E-04 TZ AB-8D Falling Head, Well Point 85 91.3 7.98E-06 M2/TZ AB-10D Falling Head, Well Point 24.6 30 6.43E-05 A AB-10D Falling Head, Flush Bottom 24.6 - 5.60E-04 A AB-10D Constant Head, Well Point 53 58 4.75E-04 M1/M2 AB-10D Falling Head, Flush Bottom 53 - 5.22E-04 S AB-10D Constant Head, Well Point 64.5 71.1 7.78E-04 TZ/BR AB-10D Falling Head, Well Point 64.5 71.1 6.40E-04 TZ/BR AB-11D Falling Head, Well Point 14 19 1.43E-05 M1/M2 AB-11D Falling Head, Flush Bottom 14 - 1.43E-05 M1 AB-11D Constant Head, Well Point 65 70 5.61E-03 BR AB-15BR Falling Head, Well Point 60.9 65.6 8.27E-04 BR AB-15D Constant Head, Well Point 25 30 4.55E-04 A AB-15D Falling Head, Flush Bottom 25 - 5.64E-05 A AB-15D Falling Head, Well Point 50 55 2.91E-06 M2 AB-15D Falling Head, Flush Bottom 50 - 4.59E-05 M2 AB-15D Falling Head, Well Point 60 65 4.94E-04 BR AB-17D Falling Head, Well Point 16.5 22 9.28E-06 A AB-17D Falling Head, Flush Bottom 16.5 - 1.19E-05 A AB-17D Falling Head, Well Point 61 65 4.27E-06 M2 AB-17D Falling Head, Flush Bottom 61 - 1.48E-05 M2 AB-18D Constant Head, Well Point 64 69 3.17E-03 BR AB-21D Falling Head, Well Point 56.2 60.7 1.19E-04 M2 AL-2BR Falling Head, Well Point 137 142 1.30E-04 M2 AL-2BR Falling Head, Well Point 178.2 183.2 1.47E-04 BR BG-1D Falling Head, Well Point 27 31.2 3.40E-05 TZ GWA-3D Falling Head, Well Point 31 36 6.75E-05 M2 GWA-3GT Falling Head, Well Point 5 10 7.44E-05 M2 GWA-3GT Falling Head, Flush Bottom 5 - 8.34E-06 M1 GWA-3GT Falling Head, Flush Bottom 16 - 4.79E-05 M1 GWA-5D Falling Head, Well Point 34.5 39.5 1.25E-05 BR GWA-5S Falling Head, Well Point 22.3 27 3.18E-04 M1 GWA-5S Falling Head, Flush Bottom 22.3 - 7.29E-05 M1 GWA-5S Falling Head, Flush Bottom 31.5 - 1.58E-03 M2 GWA-8D Falling Head, Well Point 46.2 51.2 1.31E-04 BR GWA-8GT Falling Head, Well Point 13 18 2.17E-04 M1 GWA-8GT Falling Head, Flush Bottom 13 - 4.09E-04 M1 GWA-8GT Falling Head, Well Point 28 33 3.94E-05 M2 AB-15BR Packer Test 90 95.5 2.34E-05 BR AB-15BR Packer Test 101 106.5 BR AB-15BR Packer Test 110 115.8 3.11 E-04 BR AB-5BR Packer Test 97 103.5 BR AB-5BR Packer Test 104 110.5 5.93E-05 BR AB-5BR Packer Test 112 118.5 1.32E-05 BR AB-6BR Packer Test 85 91.5 2.39E-06 BR Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 2 Table 6-18. Field Permeability Test Results AB-6BR Packer Test 95 101.5 2.59E-05 BR AB-6BR Packer Test 103 109.5 8.16E-05 BR AB-9BR Packer Test 78.5 84 6.11 E-05 BR AB-9BR Packer Test 94 99.5 2.05E-04 BR AB-9BR Packer Test 98.9 104.4 7.64E-06 BR GWA-9BR Packer Test 78 83.5 6.64E-05 BR GWA-9BR Packer Test 84.5 90 1.35E-04 BR GWA-9BR Packer Test 93 98.5 9.94E-05 BR Notes: 1. Refer to Section 11.2.1 for discussion of field procedures 2. Refer to Appendix H for calculation worksheets 3. For the pressure test, the thickness of saturated material above a relatively impermeable bed is assumed to be 600 feet for a fractured bedrock system. Water flow at this depth or greater in such systems is well documented in the Piedmont region (Daniel et al., 1989) Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 2 of 2 Table 6-19. Laboratory Permeability Test Results Borehole Depth 1 of Test (ft bgs) Depth 2 of Test (ft bgs) Vertical Hydraulic Conductivity'k' (cm/sec) Hydrostratigraphic Layer AB-1 BR 10 12 1.68E-05 F AB-1 BR 20 22 1.12E-04 F AB-3D 76 78.2 6.52E-07 M1 AB-4D 55.5 56.5 6.42E-05 M1 AB-7D 0 2.5 1.19E-04 A AB-8D 30.5 32.1 6.23E-07 M1 AB-9BR 11 12.5 5.92E-05 F AB-11 D 9 11.5 9.73E-06 M1 AB-11 D 12.5 13.5 5.64E-05 M1 AB-14D 45 45.8 1.33E-04 M2 AB-21 D 37 39 1.68E-06 M1 GWA-3GT 14 14.5 1.48E-04 M1 GWA-5S 22.3 24 2.50E-04 M1 Notes: 1. Vertical hydraulic conductivity values from laboratory testing in accordance with ASTM Standard D 5084 2. Refer to Appendix H for laboratory reports. Marshall Steam Station Source: HDR, Comprehensive Site Assessment Report Marshall Steam Station Ash Basin, September 8, 2015. Page 1 of 1 TABLE 7-1 PROVISIONAL BACKGROUND THRESHOLD VALUES FOR SOIL MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Parameter Reporting Unit PSRG Protection of Groundwater PBTV PH* S.U. NE 4.7 - 6.1 Aluminum mg/kg NE 56,437 Antimony mg/kg 0.9 0.65 Arsenic mg/kg 5.8 4.697 Barium mg/kg 580 819 Beryllium mg/kg 63 3.9 Boron mg/kg 45 8.7 Cadmium mg/kg 3 0.11 Calcium mg/kg NE 1500 Chloride mg/kg NE 13 Chromium mg/kg 3.8 32.8 Cobalt mg/kg 0.9 53.1 Copper mg/kg 700 180 Iron mg/kg 150 78,228 Lead mg/kg 270 82.5 Magnesium mg/kg NE 32,462 Manganese mg/kg 65 2,872 Mercury mg/kg 1 0.1 Molybdenum mg/kg NE 3.5 Nickel mg/kg 130 18.6 Nitrate (as N) mg/kg NE 0.56 Potassium mg/kg NE 29,937 Selenium mg/kg 2.1 1.77 Sodium mg/kg NE 394 Strontium mg/kg NE 7.53 Sulfate mg/kg NE 36 Thallium mg/kg 0.28 1.1 Vanadium mg/kg 6 210 Zinc mg/kg 1200 125 Prepared by: JHG Checked by: HHS Notes• * - Upper and lower threshold values calculated for parameter PBTV - Provisional Background Threshold Value mg/kg - milligrams per kilogram NE - Not Established PZuke Energy CarolinasM. MARSHALMSA Update January 2018TInal\Tables7able 7-1 - Soil PBTVs Page 1 of 1 FACILITY NAME: Marshall Steam Station SPREADSHEET PREPARED BY: TDP SPREADSHEET CHECKED BY: BDW TABLE 7-2 POTENTIAL SECONDARY SOURCE SOIL ANALYTICAL RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Reporting Units PSRG Protection of Groundwater Provisional Background Threshold Values mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 5.8 580 3.8 150 NE 130 2.1 NE NE 6 4.69 819 32.8 78228 3.5 18.6 1.77 7.53 36 210 Sample ID Water Level (ft btoc) Saturated/Unsaturated Location With Repect to Groundwater Flow Direction Sample Collection Date Arsenic Barium Chromium Iron Molybdenum Nickel Selenium Strontium Sulfate Vanadium AB-01BR (24-25) 3.00 Saturated Downgradient 06/28/2015 <6.5 70 5.6 9680 <3.2 1.2 j <6.5 18.1 <304 15.8 AB-02S (6-7) 20.14 Unsaturated Downgradient 07/01/2015 2.8 j 74 5.3 10600 <2.7 1.6 <5.5 24.1 <262 21.7 AB-03D (74-75.5) 19.81 Saturated Source Area 5/19/2015 <6.3 62.3 4.7 5980 <3.2 3.6 1.4 j 8.3 <302 31.2 AB-03D (78.2-79.7) 19.81 Saturated Source Area 05/19/2015 5.8 j 226 2.5 19100 <3.8 1.6 j 5.4 j 31.4 <377 43.2 AB-04SL (53.5-55.5) 12.60 Saturated Source Area 05/21/2015 6.4 j 214 4.7 34000 <3.7 5.2 <7.4 71 <361 56.3 AB-05BR (105-105) 8.69 Saturated Source Area 07/07/2015 <5.3 97.9 11.6 10900 <2.6 7.4 <5.3 22.2 <248 22 AB-05D (54-55) 8.16 Saturated Source Area 05/21/2015 <6.2 98.3 7.8 7500 <3.1 2.7 <6.2 41 <319 19.3 AB-05D (64-66) 8.16 Saturated Source Area 05/21/2015 <5.6 164 40.4 19800 <2.8 9.6 <5.6 59.2 <287 51 AB-06BR (56-57.5) 19.13 Saturated Source Area O5/29/2015 8 1360 246 37500 <2.7 182 3.3 j 253 <277 104 AB-06BR (57.5-59) 19.13 Saturated Source Area 05/29/2015 8.5 1100 217 32000 <2.8 182 <5.7 295 <274 83.5 AB-06D (53-55) 17.27 Saturated Source Area 04/16/2015 6.2 j 942 172 36600 <3.6 141 <7.2 206 <354 77.2 AB-07D (29-30.5) 20.55 Saturated Source Area 05/11/2015 5.5 j+ 552 j+ 9 34600 j+ <4.4 21.3 <8.7 208 j+ <414 123 j+ AB-08D (24-25.5) 9.60 Saturated Source Area O5/14/2015 <6 91.3 39.4 23900 <3 11.3 <6 28 <313 53.1 AB-08D (29-30.5) 9.60 Saturated Source Area 05/14/2015 4.8 j 121 36.2 36300 <3.3 14.1 <6.6 63.4 <322 83.1 AB-09BR (10-12) 7.23 Saturated Source Area 06/30/2015 4.8 j 426 405 26200 <3 169 <6 165 <294 75.7 AB-09BR (79-79) 7.23 Saturated Source Area 07/07/2015 5.9 568 13.7 15600 <2.5 15 <5 43.5 <249 33.8 AB-10D (52-53) 12.68 Saturated Source Area 05/02/2015 <6 116 21.4 22500 <3 8.5 <6 33.1 <295 48.5 AB-10D (61-62) 12.68 Saturated Source Area 05/04/2015 <6.1 174 25.6 22800 <3 13.2 <6.1 26.7 <291 50 AB-11D (3-5) 4.86 Saturated Source Area 06/23/2015 <6.8 106 j+ 11.5 16200 j- <3.4 6.5 <6.8 22.9 j+ <324 36.1 AB-11D (12.3-13.8) 4.86 Saturated Source Area 06/23/2015 <6.7 79.9 13.4 10000 <3.3 10.3 <6.7 46.6 <326 18.9 AB-12D (49-50.5) 4.41 Saturated Source Area 04/30/2015 3.9 j 130 18.7 8950 <3.4 9 <6.7 33.4 <336 34.7 AB-13D (63-64) 26.91 Saturated Source Area 05/18/2015 4.5 j 387 115 30300 <3.2 82.4 <6.3 95.8 <316 67.5 AB-13D (70-71) 26.91 Saturated Source Area 05/19/2015 4.3 j 651 j- 28.7 j- 42500 j- <2.9 51.1 j- <5.7 100 j- <298 110 AB-14D (39-40.5) 14.41 Saturated Source Area 06/04/2015 <6.9 87.8 11.8 12000 <3.4 4.4 <6.9 11.9 <336 39 AB-14D (44-45.5) 14.41 Saturated Source Area 06/04/2015 <6.5 126 3.2 10900 <3.3 1.4 j <6.5 16.1 <322 21.2 AB-15BR (104.5-104.5) 16.15 Saturated Source Area 07/07/2015 <4.8 334 20.7 10800 <2.4 15.7 <4.8 21.7 <245 27.2 AB-15D (48-49) 19.66 Saturated Source Area 05/06/2015 4.2 j 649 81.3 90500 8.1 23.6 <7.7 44.3 <378 215 AB-15D (54-55) 19.66 Saturated Source Area O5/16/2015 18.9 479 35.8 46000 5.1 20.6 <6.6 72 160 j- 103 AB-16D (5-6) 7.32 Saturated Source Area 07/09/2015 <8 189 19.9 29300 0.48j 19.1 <8 29.6 <383 104 AB-16D (12-14) 7.32 Saturated Source Area 07/09/2015 <6.9 363 61 38900 1.4 20.1 <6.9 41.2 <338 148 AB-17D (3-5) 13.60 Unsaturated Source Area 05/13/2015 <7.5 161 10.5 25900 <3.7 5.4 <7.5 12.6 <385 75.1 AB-17D (31-32) 13.60 Saturated Source Area 5/14/2015 <7.8 472 17.3 45100 <3.9 27.2 <7.8 9.1 <374 160 AB-20D (91-92) 66.11 Saturated Source Area 06/04/2015 <7.2 239 32.9 49400 <3.6 26.6 <7.2 9.7 <352 60.8 AB-20D (96-97) 66.11 Saturated Source Area 06/04/2015 <7 492 47.8 43700 <3.5 34.1 <7 16 <342 79.9 AB-21D (14-15.5) 17.37 Saturated Source Area 05/20/2015 4.9j 397 531 28400 <3.9 203 <7.8 64.4 <362 64.1 AB-21D (14-15.5) 17.37 Saturated Source Area 06/23/2015 5.1j 131 23.5 5960 <5 9 <10.1 65.2 690 12.4 AB-21D (14-15.5) 17.37 Saturated Source Area 06/24/2015 3.8j 239 13.3 22900 <3.3 10.1 <6.6 19.4 <331 90.8 AL-01D (32-34) 43.90 Unsaturated Downgradient 06/30/2015 10.5 319 lj 26200 <2.9 1.5j 7.1 82.6 <294 54 AL-01D (38-40) 43.90 Unsaturated Downgradient 06/30/2015 3.9 j 288 1.3 j 22100 <3.8 1.3 j <7.6 71 <375 41.8 AL-01D (40-41) 43.90 Unsaturated Downgradient 06/30/2015 4.3j 402 1.9 27100 <3.7 1.9 <7.3 119 <360 52.3 AL-02BR (204-204) 112.10 Saturated Source Area 07/07/2015 3.5 j 685 21.8 29600 <2.5 12.4 <5 51 <247 73.5 AL-02D (90-92) 113.92 Unsaturated Source Area 05/13/2015 6.3 j 258 97.9 38400 <3.3 24.1 4.5 j 94.8 <318 82 AL-02D (95-97) 113.92 Unsaturated Source Area 05/13/2015 <6.1 96.5 10.1 11600 <3.1 4.4 <6.1 31.9 <305 20.4 AL-03D (118-120) 113.37 Saturated Source Area 05/01/2015 6 j 614 154 46600 <3.6 138 6 j 221 <364 95.8 AL-03D (124-126) 113.37 Saturated Source Area 05/01/2015 3.6 j 1530 348 51600 <3.2 281 <6.5 331 <316 95.4 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 7-2 Secondary Source Page 1 of 2 TABLE 7-2 POTENTIAL SECONDARY SOURCE SOIL ANALYTICAL RESULTS MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Sample ID Water Level (ft btoc) Saturated/Unsaturated Location With Repect to Groundwater Flow Sample Collection Date Arsenic Barium Chromium Iron Molybdenum Nickel Selenium Strontium Sulfate Vanadium AL-04D (81.5-82.5) 106.37 Unsaturated Source Area 05/14/2015 4.5 j 716 46.2 49000 <3.4 32.2 <6.7 183 132 AL-04D (87.5-89.5) 106.37 Unsaturated Source Area 05/14/2015 <5.9 636 19.5 45100 <3 25 <5.9 77.1 <287 100 GWA-01BR (8-10) 41.30 Unsaturated Downgradient 06/26/2015 <5.7 128 6 16000 <2.9 5.3 <5.7 19.8 <302 30.4 GWA-01BR (18-20) 41.30 Unsaturated Downgradient 06/26/2015 <6.2 118 13.4 18100 <3.1 9.5 <6.2 12.2 <297 46.7 GWA-01BR (92-94) 41.30 Saturated Downgradient 06/26/2015 <7.1 235 11.5 29000 <3.6 6.5 <7.1 37.7 <337 83.4 GWA-02D (16-17) 23.34 Unsaturated Downgradient 05/14/2015 <6.4 258 j- 16.5 30700 j- <3.2 8.9 j- <6.4 4.6 172 j- 112 GWA-02D (21-22) 23.34 Saturated Downgradient 05/14/2015 <6.6 246 14.6 36700 <3.3 12.6 5.1 <325 118 GWA-02D (46-47) 23.34 Saturated Downgradient 05/14/2015 <5.4 262 78 28600 <2.7 54 <5.4 44.9 <264 66.8 MW-14BR (31.5-33) 36.42 Unsaturated Downgradient 07/10/2015 <6.5 828 61.9 50400 3 45.2 <6.5 19.1 <329 128 MW-14BR (36.5-38) 36.42 Saturated Downgradient 07/10/2015 <6 497 39.5 57800 12.9 23.5 <6 65.5 216 j 145 MW-14BR (40-41.5) 36.42 Saturated Downgradient 07/10/2015 <5.7 401 41.7 51200 10.8 14.6 <5.7 31.8 146 j MW-14BR (53-53) 36.42 Saturated Downgradient 07/12/2015 <5.4 250 46.8 18700 0.63 22.3 <5.4 29.8 <262 37 OB-01 (42-43) 57.34 Unsaturated Source Area 05/11/2015 282 4.7 38100 <3 7.5 32 <308 65.3 OB-01 (48-49) 57.34 Unsaturated Source Area 05/11/2015 280 4.4 34200 <3 5.3 36.4 <306 55.5 OB-01 (68.5-69.5) 57.34 Saturated Source Area 05/11/2015 3.2 j 75.6 2.3 8910 <2.8 1.5 <5.7 28.4 <286 12.1 SB-01 (13.5-14.5) NM Unsaturated Source Area 06/28/2015 <6.2 170 13.6 23200 <3.1 8.1 <6.2 26.9 <301 48.2 SB-01 (33-34) NM Saturated Source Area 06/28/2015 <7.6 75.3 20.1 46300 <3.8 4.3 <7.6 30.1 <361 82.4 SB-02 (67.5-68.5) NM Saturated Source Area 04/23/2015 <6.1 85.8 14 12100 <3 4.2 <6.1 23.7 969 j- 38.4 SB-02 (73-74) NM Saturated Source Area 04/23/2015 3.2 j 120 2.3 15600 <3.1 2.6 <6.1 11.2 1040 j- 28.6 SB-03 (79-80) NM Saturated Source Area 04/22/2015 <6.2 141 16.2 13300 <3.1 5.1 <6.2 27.1 <317 56.7 SB-03 (86-87) NM Saturated Source Area 4/22/2015 <6.9 42.9 <1.7 5670 <3.5 1.23 <6.9 7.9 <332 <6.9 SB-04 (50-51) NM Saturated Source Area 04/29/2015 <6.5 101 2.9 18100 <3.2 3.9 <6.5 13 843 j- 38.7 SB-04 (57-58) NM Saturated Source Area 04/29/2015 <8.1 225 4.3 15500 <4 6.8 <8.1 13.5 221 j- 46.8 SB-07 (70-71) NM Saturated Source Area 04/30/2015 <6.2 85.3 25.3 9020 <3.1 9.5 <6.2 4.4 406 50.1 SB-08 (31-32) NM Unsaturated Source Area 04/14/2015 <6.8 284 27 40100 <3.4 26.9 <6.8 10 2950 73.3 SB-10 (25-26) NM Saturated Source Area 05/15/2015 4 j 33.7 16.9 78800 3.1 j 36.5 <6.2 11.1 <318 173 SB-10 (30-31) NM Saturated Source Area 05/15/2015 <6.3 96.9 59400 <3.2 23.7 <6.3 16.7 <316 129 SB-11 (38-40) NM Saturated Source Area 05/19/2015 <6.8 95.5 1.6 j 4370 <3.4 <1.7 <6.8 11 <341 5.5 j SB-13 (15.4-16.1) NM Saturated Source Area 03/19/2015 3.1 j 358 j- 18.7 41200 <0.78 14.5 90.4 j- 342 j 90.8 SB-13 (20-20.8) NM Saturated Source Area 03/19/2015 4.7 380 17.7 43100 <0.74 17.7 104 282 j 99.8 SB-14 (35-36) NM Saturated Source Area 05/19/2015 4.6 j 193 59.3 35800 3.5 j 47.3 <7.4 20.2 <357 77.8 SB-15 (86.5-87.5) NM Saturated Source Area 05/05/2015 3.5 j 135 18.7 24800 <3.5 8.5 <6.9 35.3 <347 57.9 SB-15 (92-93) NM Saturated Source Area 05/05/2015 187 2.2 20600 <3 2.2 5.9 j 53.2 1140 j- 48.1 Notes: lmmqConcentration greater than PSRG Protection of Groundwater, which is greater than PBTV. =Concentration greater than PBTV, which is greater than PSRG Protection of Groundwater. Water level data collected on 9/22/2017 ft btoc- feet below top of casing j- - estimated concentration, biased law j+ - estimated concentration, biased high NA- Not Available ND- Non -Detect NM- not measured; general water elevation obtained from comparison of potentiometric surface map to boring locations P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 7-2 Secondary Source Page 2 of 2 TABLE 10-1 GROUNDWATER PROVISIONAL BACKGROUND THRESHOLD VALUES MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Parameter Reporting Unit NCAC 02L Standard Background Threshold Values Shallow Deep Bedrock pH* S.U. 6.5-8.5 4.6-6.4 5.7-6.9 5.6-7.6 Alkalinity mg/L NE 63 204 108 Aluminum pg/L NE 757 128 300 Antimony pg/L 1° 0.5 0.5 0.5 Arsenic pg/L 10 0.4 0.6 0.6 Barium pg/L 700 310 127 435 Beryllium pg/L 4° 0.2 0.1 0.2 Bicarbonate m g/L NE 63 204 108 Boron ug/L 700 50 50 50 Cadmium pg/L 2 0.08 0.08 0.08 Calcium mg/L NE 10.7 13.1 15 Carbonate mg/L NE 5.0 5.0 5.0 Chloride mg/L 250 5.5 4.7 4.5 Chromium (VI) 1 pg/L 10 5.7 3.0 3.9 Chromium pg/L 10 16.5 7.6 8.3 Cobalt pg/L 1° 1.2 1.9 2.8 Copper pg/L 1000 3.8 2.8 4.2 Iron pg/L 300 744 272 792 Lead ug/L 15 0.3 0.1 0.2 Magnesium mg/L NE 1.8 14.4 13.2 Manganese pg/L 50 75.3 141 26.6 Mercury pg/L 1 0.2 0.2 0.2 Methane ug/L NE 10 10 10 Molybdenum pg/L NE 0.5 3.2 3 Nickel ug/L 100 9.9 7.5 7.2 Nitrate + Nitrite mg-N/L NE 2.7 1.4 0.4 Potassium mg/L NE 5 7.8 9.8 Selenium pg/L 20 0.5 0.5 0.5 Sodium mg/L NE 9.1 29.2 14 Strontium pg/L NE 303 665 253 Sulfate mg/L 250 4.2 17.7 18.4 Sulfide mg/L NE 0.1 0.1 0.1 TDS mg/L 500 140 183 216 Thallium pg/L 0.2" 0.1 0.1 0.1 TOC mg/L NE 1 1 1 Vanadium pg/L 0.3" 5.6 3.8 16 Zinc pg/L 1000 19.2 17 11.9 Radium (Total) pCi/L NE 3.0 2.8 5.7 Uranium (Total) pg/mL NE 0.0005 0.0005 0.0005 Prepared by: JHG Checked by: MCM Notes: * - Upper and lower tolerance limits calculated for parameter - Interim Maximum Allowable Concentrations (IMACs) of 15A NCAC .021- Standard, Appendix 1, April 1, 2013 Provisional; dataset contains less than 10 valid samples - Hexavalent chromium does not have a NC 2L/IMAC standard; therefore, the NC 21 standard for total chromium is relied upon as a surrogate. pg/L - micrograms per liter pg/mL - micrograms per milliliter mg - N/L - Milligrams nitrogen per liter mg/L - milligrams per liter NA - Not available; dataset contains zero valid samples NE - Not Established pCi/L - picocuries per liter Radium (Total) - Radium-226 and Radium-228 combined S.U. - Standard Unit TDS - Total Dissolved Solids Uranium (Total) - Uranium-233, Uranium-234, Uranium-236, and Uranium-238 combined P:\Duke Energy Carolinas\38. MARSHALL\CSA Update January 2018\Final\Tables\Table 10-1 - GW PBTVs Page 1 of 1 TABLE 10-2 CHARGE BALANCE SUMMARY MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Marshall Sample Locations Anions me L 'M4.37 % Difference AB-01BR 7.71 3.02 AB-01D 7.83 2.26 AB-01S 9.51 8.37 AB-02D 4.98 3.10 AB-02S 0.25 12.98 AB-03D 3.85 6.39 AB-03S 11.00 10.30 3.31 AB-04D 1.49 1.57 2.42 AB-04S 1.42 1.51 3.08 AB-04SL 2.35 2.51 3.33 AB-05BR 6.52 7.12 4.38 AB-05D 4.05 4.59 6.25 AB-05S 31.20 13.10 40.76 AB-06BRA 9.81 7.81 11.36 AB-06D 4.62 5.13 5.30 AB-06S 15.30 16.60 3.88 AB-07D 1.52 1.81 8.64 AB-07S 37.20 40.30 3.96 AB-08D 3.74 4.01 3.53 AB-08S 5.43 5.16 2.56 AB-09BR 2.46 2.83 7.01 AB-09D 1.76 12.10 74.66 AB-09S 0.70 0.81 6.92 AB-10BR 5.99 6.94 7.39 AB-10D 4.98 5.51 5.05 AB-10S 23.30 24.70 2.98 AB-10SL 17.90 19.60 4.43 AB-11D 1.32 1.48 5.71 AB-11S 0.41 0.46 5.78 AB-12BR 4.69 5.45 7.53 AB-12D 10.70 11.40 3.17 AB-12S 94.20 100.00 3.19 AB-12SL 9.73 10.20 2.22 AB-13D 2.85 3.30 7.28 AB-13S 5.65 6.32 5.58 AB-14D 1.69 1.79 2.81 AB-14S 24.20 24.70 1.10 AB-15BR 3.97 4.45 5.64 AB-15D 3.85 4.22 4.48 AB-15S 9.53 10.80 6.41 AB-15SL 6.55 6.66 0.83 AB-16D 2.44 3.01 10.37 AB-16S 1.62 1.88 7.32 AB-17D 1.01 1.15 6.63 AB-17S 15.00 14.70 1.13 AB-18D 1.11 1.22 4.97 AB-18S 5.76 6.55 6.38 AB-20D 1.84 2.02 4.42 AB-20S 73.80 76.70 1.92 AB-21D 2.60 2.68 1.39 AB-21S 23.70 14.60 23.82 AL-01 BR 5.67 6.01 2.94 AL-01D 8.57 8.68 0.62 AL-015 1 8.11 8.12 0.05 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 10-2 Anion - Cation Marshall Page 1 of 3 TABLE 10-2 CHARGE BALANCE SUMMARY MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Marshall Sample Locations Anions me L ' Cations me L ' % Difference AL-02BR 5.59 5.53 0.54 AL-02BRL 3.80 0.00 100.00 AL-02D 19.80 21.50 4.13 AL-02S 31.20 0.17 96.38 AL-03BR 4.73 5.16 4.33 AL-03D 10.20 10.50 1.33 AL-03S 62.00 65.00 2.34 AL-04BR 4.23 4.51 3.18 AL-04D 21.60 22.90 2.89 BG-01BRA 1.90 2.20 7.30 BG-01D 1.54 1.82 8.26 BG-01S 0.68 0.76 5.72 BG-02BR 1.61 1.95 9.62 BG-02S 1.21 1.47 9.72 BG-03BR 2.09 2.51 9.17 BG-03D 2.06 2.44 8.61 BG-03S 1.37 1.61 7.93 GWA-01BR 1.81 1.94 3.59 GWA-01D 5.65 6.18 4.48 GWA-01S 0.42 0.49 7.50 GWA-02DA 2.51 1.96 12.37 GWA-02S 1.28 1.39 1.41 GWA-03D 0.94 1.01 3.42 GWA-03S 0.60 0.67 5.59 GWA-04D 2.69 3.09 6.94 GWA-04S 0.32 0.48 18.97 GWA-05D 0.31 0.40 12.84 GWA-05S 0.28 0.31 5.50 GWA-06D 1.10 1.24 5.65 GWA-06S 0.43 0.43 0.27 GWA-07D 1.69 2.10 10.77 GWA-07S 1.31 1.62 10.50 GWA-08 D 0.74 0.83 6.08 GWA-08S 0.70 0.75 3.62 GWA-09BR 0.26 1.00 58.86 GWA-10D 5.41 5.72 2.82 GWA-10S 1.39 1.43 1.18 GWA-11BR 2.49 2.71 4.30 GWA-11D 3.02 3.39 5.81 GWA-11S 5.59 6.23 5.37 GWA-12BR 1.11 1.29 7.43 GWA-12D 2.70 2.23 9.53 GWA-12S 0.18 0.25 16.26 GWA-13DA 1.91 1.94 0.67 GWA-13S 0.15 0.16 3.41 GWA-14D 0.74 0.85 7.39 GWA-14S 0.18 0.20 4.91 GWA-15S 6.58 6.66 0.58 MRl 0.71 0.15 65.44 MR10 0.40 0.11 58.39 MR11 0.66 0.11 71.57 MR12 0.62 0.18 55.18 MR13 0.87 1.51 26.66 M R 14 0.60 0.94 21.51 MR16 1.44 0.44 52.83 MR17 0.67 0.22 49.77 MR18 0.81 0.23 54.97 MR2 Office 1.05 0.42 43.18 MR2 Plant 1.53 0.40 58.69 MR20 1.19 0.34 55.19 MR21 0.12 0.14 9.74 MR22 0.33 0.16 34.50 MR23 1.62 0.55 49.35 MR25 0.95 0.29 53.88 MR26 0.68 0.28 42.29 MR28 1.03 0.26 59.42 MR29 0.32 0.11 48.87 MR30 0.13 0.23 26.56 MR31 0.36 0.11 52.80 MR32 0.55 0.19 48.74 MR33 0.35 0.10 55.71 P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 10-2 Anion - Cation Marshall Page 2 of 3 TABLE 10-2 CHARGE BALANCE SUMMARY MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Marshall Sample Locations Anions me L ' Cations me L ' % Difference MR35 1.03 0.32 52.75 MR36 1.08 0.00 99.27 MR37 0.29 0.10 48.57 MR38 0.27 0.15 29.73 MR4 2.95 1.11 45.28 M R40 0.84 0.20 61.67 MR42 0.37 0.09 60.88 MR43 0.52 0.25 35.25 M R44 0.69 0.22 51.56 MR45 0.33 0.14 38.59 MR46 0.53 0.10 68.60 M R47 0.26 0.09 48.20 MR48 0.40 0.09 62.78 MR6 0.75 0.26 47.83 MR8 0.57 0.17 54.85 MR9 0.45 0.12 58.53 MS-08 0.38 0.44 7.07 MS-09 0.79 0.90 6.64 MS-10 0.07 0.12 27.18 MS-11 0.34 0.32 3.89 MS-12 0.17 0.17 1.50 MS-13 0.35 0.46 14.11 MS-14 0.53 0.58 4.78 MS-15 1.53 1.81 8.20 MS-16 0.94 1.06 6.34 MW-01 4.37 4.47 1.12 MW-02 3.86 3.91 0.62 MW-03 0.31 0.69 37.72 M W-04 0.46 0.51 5.04 M W-04D 0.72 0.82 6.25 MW-05 0.29 0.36 10.17 M W-06D 4.02 4.25 2.83 M W-06S 2.57 2.48 1.75 M W-07D 6.02 6.19 1.41 M W-07S 7.72 6.70 7.09 M W-08D 4.68 4.96 2.86 M W-08S 7.99 9.11 6.54 M W-09D 4.36 4.71 3.85 M W-09S 5.00 6.31 11.58 MW-10D 0.52 0.59 6.00 VW-10S 0.12 0.16 14.15 M W-11 D 0.45 0.52 7.70 M W-11S 0.49 0.60 9.68 MW-12D 0.50 0.54 3.78 MW-12S 0.21 0.24 6.51 MW-13D 0.73 0.94 12.31 MW-13S 0.70 0.90 12.39 MW-14BR 2.34 2.44 1.94 MW-14D 6.32 5.62 5.87 MW-14S 10.30 8.03 12.37 OB-01 Ash Basin 7.03 7.58 3.78 OB-01 (Dry Ash Landfill -- -- -- OB-02 OB-03 Prepared by: MMS Checked by: TDP Notes: Information not available 1 meq/L = milliequivalents per liter P:\Duke Energy Carolinas\18. MARSHALL\CSA Update January 2018\Final\Tables\Table 10-2 Anion - Cation Marshall Page 3 of 3 TABLE I1-1 DATA INVENTORY SUMMARY MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC PARALLEL TO TRANSECT/CENTERLINE OF FLOW PERPENDICULAR TO TRANSECT/CENTERLINE OF FLOW DATE INVENTORY QUEDNS TAKEN FROM MMA GUIDANCE STI DOCUMENT-SECTION 4.3 TRANSECT 1 (WEST) - ALONG CENTERLINE OF PLUME TRANSECT 2 (CENTRAL) - ALONG CENTERLINE OF PLUME TRANSECT 3 (EAST)- ALONG CENTERLINE OF PLUME WELLS PERPENDICULAR TO TRANSECT 1 (WEST) WELLS PERPENDICULAR TO TRANSECT 2 (CENTRAL) WELLS PERPENDICULAR TO TRANSECT 3 (EAST) Have background concentrations been formally established PBTV concentrations are included in the Comprehensive Data Table (Appendix B) and the Proposed Background Threshold Values for Naturally Occuring Concentrations in Groundwater and Soil PBTV concentrations are included in the Comprehensive Data Table (Appendix B) and the Proposed Background Threshold Values for Naturally Occuring Concentrations in Groundwater and Soil (a) for all COIs In soil and groundwater? (Appendix H) (Appendix H) For each source area, how many wells within each Flow 1 Ash Pore 2 Ash Pore 2 Shallow 3 Shallow 2 Ash Pore 4 Ash Pore (b) systems are located along the contaminant plume 3 Shallow 3 Deep 2 Deep 7 Shallow 5 Shallow 7 Shallow centerline? Along a transact that is perpendicular to the 4 Deep 3 Bedrock 1 Bedrock 8 Deep 7 Deep 6 Deep plume centerline? 1 Bedrock 1 Bedrock Lower 1 Bedrock 1 Bedrock 2 Bedrock How many wells In (b) above are screened across the Boron In Deep Boron In Shallow Boron In Shallow Boron in Deep Boron In Shallow Boron in Shallow (c) most contaminated vertical interval of a given Flow unit or 4 Deep 2 Shallow 3 Shallow 7 Deep 5 Shallow 7 Shallow are screened across the full thickness of the Flow unit?' No wells are screened across the full thickness of an aquifer. No wells are screened across the full thickness of an aquifer. No wells are screened across the full thickness of an aquifer. No wells are screened across the full thickness of an aquifer. No wells are screened across the full thickness of an aquifer. No wells are screened across the full thickness of an aquifer. AB-5S* (9; 7/14/2015 - 9/25/2017) AB-12S* (10; 7/8/2015 - 9/25/2017) CCR-13S (9; 5/18/2016 - 8/7/2017) GWA-2S (7; 7/16/2015 - 9/25/2017) MW-7S (12; 11/8/2007 - 9/26/2017) MW-14S (24; 2/7/2011 - 10/2/2017) AB-5D (8; 10/1/2015 - 9/26/2017) AB-12SL* (9; 7/8/2015 - 9/25/2017) CCR-13D (9; 5/18/2016 - 8/7/2017) s GWA-2D (0; NA) MW-7D (14; 11/8/2007 - 9/26/2017) MW-14D (28; 2/7/2011 - 10/2/2017) AB-5BR (9; 7/17/2015 - 9/25/2017) AB-12D (9; 7/8/2015 - 9/25/2017) GWA-15S (3; 5/1/2017 - 9/28/2017) GWA-2DA (0; NA) AB-21S* (8; 7/15/2015 - 9/25/2017) MW-14BR (9; 7/19/2015 - 9/25/2017) AB-3S* (9; 7/9/2015 - 9/25/2017) AB-12BR (3; 3/13/2017 - 9/25/2017) GWA-11S (7; 4/27/2016 - 9/26/2017) GWA-1S (7; 9/29/2015 - 9/26/2017) AB-21D (8; 7/15/2015 - 9/25/2017) GWA-10S (7; 4/27/2016 - 9/28/2017) AB-313 (8; 7/11/2015 - 9/25/2017) AB-9S (9; 7/16/2015 - 9/25/2017) GWA-11D (7; 4/12/2016 - 9/26/2017) GWA-ID (6; 4/12/2016 - 9/26/2017) AB-8S* (8; 7/15/2015 - 9/25/2017) GWA-lOD (7; 4/11/2016 - 9/28/2017) AB-2S (8; 7/18/2015 - 9/26/2017) AB-91) (8; 9/29/2015- 9/25/2017) GWA-11BR (2; 4/27/2017 - 6/14/2017) GWA-1BR (7; 7/19/2015 - 9/26/2017) AB-8D (7; 9/28/2015 - 9/25/2017) MW-6S (10; 8/28/2008 - 9/26/2017) AB-213 (7; 4/12/2016 - 9/26/2017) AB-9BR (6; 6/22/2016 - 9/25/2017) MW-8S (11; 2/12/2008 - 9/26/2017) MW-2 (34; 8/9/2000 - 9/27/2017) MW-6D (10; 8/10/2009 - 9/26/2017) MW-9S (14; 11/8/2007 - 9/26/2017) AB -IS (6; 7/17/2015 - 9/28/2017) MW-8D (11; 2/16/2009 - 9/26/2017) AS-10S* (7; 9/28/2015 - 9/22/2017) MW-1 (30; 8/9/2000 - 9/28/2017) MW-9D (14; 11/8/2007 - 9/26/2017) AB -ID (7; 9/28/2015 - 9/27/2017) AB-4S* (8; 7/14/2015 - 9/25/2017) AB-10SL* (8; 9/28/2015 - 9/22/2017) CCR-12S (9; 5/18/2016 - 8/7/2017) What is the length of record and how many valid samples AB-IBR (7; 9/28/2015 - 9/27/2017) AS-4SL* (7; 7/9/2015 - 9/25/2017) AS-10D (9; 5/17/2015 - 9/22/2017) CCR-12D (9; 5/18/2016 - 8/7/2017) (d) vents are available for wells listed in (b) and (c)?2 AB-1BRL (1; 10/17/2017) AB-4D (8; 7/14/2015 - 9/25/2017) AB-lOBR (4; 12/1/2016 - 9/22/2017) CCR-145 (9; 5/18/2016 - 8/7/2017) CCR-1S (9; 5/18/2016 - 8/7/2017) CCR-9S (9; 5/18/2016 - 8/7/2017) CCR-14D (9; 5/18/2016 - 8/7/2017) CCR-1D (1; 6/12/2017) s CCR-9D (0; NA) AL -IS (8; 7/16/2015 - 9/25/2017) CCR-2S (9; 5/17/2016 - 8/7/2017) CCR-9DA (1; 4/18/2017) AL-1D (9; 7/16/2015 - 9/25/2017) CCR-2D (9; 5/17/2016 - 8/7/2017) CCR-11S (9; 5/18/2016 - 8/7/2017) AL-1BR (4; 12/6/2016 - 9/25/2017) CCR-4S (9; 5/19/2016 - 8/7/2017) CCR-I1D (9; 5/18/2016 - 8/7/2017) CCR-4D (8; 5/18/2016 - 8/7/2017) CCR-15S (9; 5/17/2016 - 8/7/2017) CCR-SS (8; 5/18/2016 - 8/7/2017) CCR-15D (9; 5/17/2016 - 8/7/2017) CCR-5D (9; 5/18/2016 - 8/7/2017) Total Record Date Range: Total Record Date Range: Total Record Date Range: Total Record Date Range: Total Record Date Range: Total Record Date Range: 11/8/2007 - 9/26/2017 7/8/2015 - 10/17/2017 4/12/2016 - 9/28/2017 2/12/2008 - 9/26/2017 8/9/2000 - 9/27/2017 8/9/2000 - 10/2/2017 Does turbidity, well construction (for example, grout 86 valid samples 75 valid samples 37 valid samples 134 valid samples 165 valid samples 182 valid samples (a) contamination, etc.), o well "break in" issues preclude the or 94 total samples 84 total samples 38 total samples 172 total samples 210 total samples 225 total samples e of data in (b), (c) (or) (d)?J 8 samples omitted 9 samples omitted 1 sample omitted 38 samples omitted 45 samples omitted 43 samples omitted Source area: # Samples; Flaw Layer = # Samples in Layer Ash Basin: 164 solid phase samples; Ash = 64, Fill = 11, Shallow = 49, Deep = 35, Bedrock = 5 For each source area and within each flow unit, how many Dry Ash Landfill (Phase I & 11): 24 solid phase samples; Ash = 12, Shallow = 0, Deep = 12, Bedrock = 0 spatial locations were sampled for solid phase chemistry PV Structural Fill: 15 solid phase samples; Ash = 9, Shallow = 5, Deep = 1, Bedrock = 0 (O and were these locations associated with "end member" (maximum and minimum) groundwater concentrations for Yes, spatial locations include maximum and minimum groundwater concentrations. each contaminant? How many of these spatial locations e associated with (b) or (c) above?4 14 samples total 10 samples total 0 samples 14 samples total 11 samples total 3 samples collected S Deep 2 Shallow 2 Deep 4 Shallow 1 shallow Given that Iron hydroxide (HFO) content Is a good (g) Indicator of retention capacity for most metal 2 samples collected 5 samples collected 1 sample collected 4 sample collected 1 sample collected 0 samples collected contaminants, how man locations In f y ()was HFO 1 In deep 2 in deep 0 In deep 3 In Deep 1 In deep measured? weapon. w these y—mna rene<t me data <one<ted as or o<rober U11, Lam)I.— Ph. m«t<anwmmacea now �Nt witmnaace<ih<rmw boron pl---Pnmarym,� M1o.—. h<,ea,p,.p,..I,--pl—froth- CCa <o—d—d. are e: (d-,xi below). ' - PH ssuespare definedsaz w er r vH-1.Turbiaip issues are denned as turbidity — Wp, replaced with an adj—t well typically ending In an'A' (e.g., GWA-21) --placed with GWA-21DA). A. [ the end of a well ID Indicates th.t the well Is an azM1 pore well. NCDEQ. (2017, 0—r). MP 1— Natural Atte"paoo" ror -rg 1, Coawmm— m Gr—d—r. omma<e for D—lo CPRer A P, via": wr: t W Nue 1sA.0106m. NC. oml,lo" 0 water s P:\D—Energy Cam11nast18. MARSHALgCSA UpdateJanuary 2018\Flnal 11-1 Marshall-DataI -r, summary TABLE 13-1 SUMMARY OF Kd VALUES FROM BATCH AND COLUMN STUDIES MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Batch Study Sample Site and Depth (feet) Arsenic Boron Cadmium Chromium Molybdenum Selenium Thallium Vanadium AB-SBR (33-35) Trial- 1 469.0 IDNA 21.0 296.0 1897.0 898.0 108.0 2488.0 Trial - 2 460.0 IDNA 20.0 305.0 1928.0 IDNA 103.0 2469.0 AB -SS (20-25) Trial - 1 1.0 IDNA 894.0 6.0 IDNA IDNA 192.0 IDNA Trial - 2 1.0 IDNA 881.0 4.0 IDNA IDNA 224.0 IDNA AB-2S (31-32) Trial - 1 496.0 2.0 62.0 874.0 3346.0 1290.0 75.0 984.0 Trial - 2 496.0 IDNA 63.0 IDNA 2541.0 IDNA 76.0 IDNA AB-413 (69.3-70.3) Trial - 1 12.0 IDNA 108.0 IDNA 0.3 IDNA 121.0 6.0 Trial - 2 11.0 IDNA 76.0 IDNA 0.2 IDNA 86.0 6.0 AB-6BR (57.5-59) Trial - 1 33.0 IDNA 149.0 32.0 3.0 14.0 611.0 228.0 Trial- 2 37.0 IDNA 149.0 IDNA 3.0 IDNA 678.0 238.0 AB-813 (30-32.5) Trial- 1 343.0 IDNA 429.0 874.0 594.0 507.0 565.0 1633.0 Trial - 2 337.0 IDNA 429.0 IDNA IDNA IDNA 546.0 1425.0 AB-1113 (12.5-15) Trial - 1 340.0 1.0 297.0 1334.0 36.0 84.0 1629.0 525.0 Trial - 2 356.0 IDNA 331.0 IDNA 35.0 IDNA 1860.0 547.0 AB-16D (13-15) Trial- 1 399.0 1.0 1241.4 519.0 36.0 89.0 804.0 194.0 Trial - 2 402.0 1.0 1092.3 438.0 36.0 IDNA 795.0 191.0 AS-113 (46) Trial - 1 52.0 IDNA 52.0 7.0 13.0 IDNA 522.0 52.0 Trial - 2 48.0 IDNA 49.0 4.0 13.0 IDNA 480.0 48.0 GWA-IS (50-52) Trial - 1 316.0 1.0 194.0 549.0 66.0 147.0 694.0 511.0 Trial - 2 336.0 1.0 197.0 380.0 68.0 IDNA 729.0 493.0 GWA-213 (83.5 -84.5) Trial - 1 37.0 IDNA 171.0 IDNA 1.0 IDNA 678.0 24.0 Trial - 2 34.0 IDNA 173.0 IDNA 1.0 IDNA 673.0 23.0 Geometric Mean 88.3 1.1 172.7 117.3 30.1 190.3 374.2 207.1 Median 326.0 1.0 172.0 342.5 36.0 147.0 555.5 238.0 Lower Quartile (exclusive) 1 33.8 1.0 62.8 6.8 0 84.0 117.8 48.0 Column Study AB-1BR (33-35) 1 Trial Only 65.0 IDNA 107.0 IDNA 90.0 65.0 235.0 120.0 AB -IS (20-25) 1 Trial Only 40.0 IDNA 625.0 IDNA IDNA 12.0 625.0 15.0 AB-25 (31-32) 1 Trial Only 60.0 IDNA 70.0 IDNA 70.0 80.0 100.0 185.0 A13-4D (69.3-70.3) 1 Trial Only 12.0 IDNA 105.0 IDNA IDNA 7.0 110.0 12.0 A13-61311 (57.5-59) 1 Trial Only 85.0 IDNA 500.0 IDNA NA 35.0 500.0 75.0 A13-81) (30-32.5) 1 Trial Only 90.0 IDNA 400.0 IDNA 25.0 90.0 375.0 240.0 AB-11D (12.5-15) 1 Trial Only 90.0 IDNA 275.0 IDNA 40.0 60.0 350.0 150.0 AB-12D (53.5-54) 1 Trial Only 70.0 IDNA 325.0 IDNA 25.0 40.0 425.0 100.0 AB-16D (13-15) 1 Trial Only 380.0 IDNA 400.0 IDNA 40.0 160.0 425.0 370.0 AS-11) (46) 1 Trial Only 55.0 IDNA 275.0 IDNA 15.0 15.0 300.0 60.0 GWA-1S (50-52) 1 Trial Only 85.0 IDNA 300.0 IDNA 30.0 60.0 320.0 160.0 GWA-21) (83.5-84.5) Trial A 35.0 IDNA 120.0 IDNA IDNA 12.0 330.0 30.0 Trial B 30.0 IDNA 160.0 IDNA IDNA 12.0 315.0 24.0 Trial C 25.0 IDNA 150.0 IDNA IDNA 10.0 300.0 20.0 Geometric Mean 57.4 IDNA 224.7 IDNA 36.0 30.8 303.9 69.0 Median 62.5 IDNA 275.0 IDNA 35.0 37.5 325.0 87.5 Ower Quartile (exclusive) 33.8 IDNA 116.8 IDNA 25.0 12.0 283.8 3.0 Notes: Prepared by: EMB Checked by: ALA IDNA = isotherm data not available Units reported in milliliters per gram (mUg) Column Kd values are from the Soil Sorption Evaluation Report (Langley, W.G. & Oza, S., 31 Oct. 2015). Batch sorption Kdvalues were taken from the linear isotherm (So= 0) values from the Addendum to Soil Sorption Evaluation (Langley, W.G. & Dongwook, K., 2 Feb. 2016). AB-12D (53.5-54) was omitted from the Kd Addendum. NA - Not analyzed P:\Duke Energy Carolinas\38. MARSHALL\CSA Update January 2018\Final\Tables\Table 13-1 Summary of Kd Values from Batch Page 1 of 1 Table 15-1 Sampling Parameters and Analytical Methods Analytical Method Chemical Analyte Bottle Requirement Preservative EPA 200.7 Total/Dissolved Metals - Alluminum, Barium, Boron, Calcium (total only), Iron, Lead, Magnesium (total only), Manganese, Potassium (total only), Sodium (total only), Strontium, Zinc 2 - 250 mL HDPE Nitric Acid, Ice EPA 200.8 Total/Dissolved Metals - Antimony, Arsenic, Beryllium, Cadmium, Chromium, Cobalt, Copper, Molybdenum, Nickel, Selenium, Thallium (low level), Vanadium (low level) 2 - 250 mL HDPE Nitric Acid, Ice EPA 245.1 Total/Dissolved Mercury 2 - 250 mL HDPE Nitric Acid, Ice EPA 300 Chloride/Sulfate 250 mL PET Ice EPA 350.1 Ammonia 250 mL PET Sulfuric Acid, Ice EPA 353.2 Nitrate/Nitrite 125 mL PET Sulfuric Acid, Ice RSK 175 Methane 2-20 mL VOA Ice SM 2540C/D TDS/TSS 2 - 1,000 mL PET Ice SM 4500 - S2D Sulfide 125 mL PET Zinc Acetate plus Sodium Hydroxide, Ice SM 5310B TOC 3 - 40 mL glass VOA Phosphoric Acid, Ice SM2320B Alkalinity (Total, Bicarbonate, and Carbonate) 500 mL PET Ice EPA 903.1 Modified Radium 226 1 L PET Nitric Acid, Ice EPA 904.0/SW846 9320 Modified Radium 228 1 L PET Nitric Acid, Ice SW846 6020A Total Combined Uranium 250 mL PET Nitric Acid, Ice EPA 218.7 Hexavalent Chromium 125 mL PET Sodium Hydroxide, Ice Marshall Steam Station Source: HDR, Corrective Action Plan Part 2 Marshall Steam Station Ash Basin, March 3, 2016 Page 1 of 1 TABLE 15-2 INTERIM MONITORING PROGRAM LIST MARSHALL STEAM STATION DUKE ENERGY CAROLINAS, LLC, TERRELL, NC Wells to be Sampled Radionuclide Sample Requested (X) AB-lOBR AB-10D AB-10S AB-10SL AB-11 D AB-11S AB-12BR X AB-12D X AB-12S X AB-12SL X AB-13D AB-13S AB-14D AB-14S AB-15BR AB-15D AB-15S AB-15SL AB-16D AB-16S AB-17D AB-17S AB-18D AB-18S AB-1BR X AB -ID X AB -IS X AB-20D AB-20S AB-21 D AB-21S AB-2D X AB-2S X AB-3D AB-3S AB-4D AB-4S AB-4SL AB-5BR X AB-5D X AB-5S X AB-6BRA AB-6D AB-6S AB-7D AB-7S AB-8D AB-8S AB-9BR AB-9D AB-9S AL-1BR X AL-1D X AL-1S X AL-2BRL AL-2D AL-2S AL-3BR AL-3D AL-3S AL-4BR AL-4D BG-1BRA X BG-1D X BG-1S X Wells to be Sampled Radionuclide Sample Requested (X) BG-2BR X BG-2S X BG-3BR X BG-3D X BG-3S X GWA-1BR X GWA-ID X GWA-IS X GWA-2DA GWA-2S GWA-3 D GWA-3S GWA-4D GWA-4S GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8D GWA-8S GWA-9BR GWA-10D GWA-SOS GWA-11BR X GWA-11D X GWA-11S X GWA-12BR X GWA-12D GWA-12S X GWA-13DA GWA-13S GWA-14D GWA-14S GWA-15S X MS-8 MS-10 X MS-11 MS-13 MW-1 MW-10D X MW-10S X MW-11D MW-11S MW-12D MW-12S MW-13D MW-13S MW-14BR X MW-14D X MW-14S X MW-2 MW-3 MW-4 X MW-4D X MW-5 MW-6D X M W-6S X MW-7 MW-7D X MW-7S X MW-8D X M W-8S X MW-9D X MW-9S X 013-1 (Dry Ash Basin) 013-1 (Dry Ash Landfill Prepared by: MP Checked by: 1L P:\Duke Eneryy Carolinas\18. MARSHALL\CSA Up -January 2018\Final\Tab1es\Ta1b1e 15-2 Interim Monitoring Program Sample Locations Page 1 of 1