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AUTHORIZATION REQUEST FOAM 8 U ..
r.? -,Amendment----New � IU Recl � ra
South Carolina Department of Health and Environmental Control I Incinerate
P ----- Land arm � Ehergy 21V,12
Bureau of Solid and Hazardous Waste (803) 734-5200 Other, / :�`� i� /i
���Authorization Number:
Generator Inforrnatior::
To be entered
•by TSD Facility
Generator ID Namel E•z DuPwr vF /V5-My11,s 16. ,1i1e.
Address I#.( Rr # 07 5-0vr11__I City 1 /344p6,u,Z_eomesti��z) awy 41'r j State U Zip Code 1�2 S 3r2_
Official Contac VI/. O1-corr JTltlel "IMR. 0009b. ITelephone 1( 9/9) 9Q3-- 463! I l
FxT 15.
SC Count
Treatment. Storage; or Disposal Facility Information:
y
(for In-state cenerator aly)
Facility EPA ID itis C D 0._7 _0 _3___7_.5-2.8_x_1, Name I GSX SERVICES OF S.C. INC.
o Lim # mis, line will wys represent this specific waste stream:) G e. I a r 0 u
%fir --e — S A , P w a. l e
Ir r L_ T_ . �. F. D. .8. ! . POND S L 'v D G F
n
Description of Hazardous.waste
Procm Pzod,dn9 ucste:
l��r.�cr.rh F'a�yvrN�t (�J�yn.a� IJ,vn
t4.vvG/Fc7 cJ.�rN i�C/Lc z PLuS DGco/A Ji iG SFW�IG£.
IJ I J T�L� IL7itii�N� G✓LPX4 IC(`1;-Y
EPAl ILU waste Codes ROT Hazard Class
Enter Quarter for One --Time Disposal: I_i / I l gtrlyr;.
I (`.Multiple ants Enter. Frequency Here: I
Pllysicp State Waste @ 70°F
1 zVol1 liquid 3.L.._.I WA
For DIUMC Dalp =J
oeceived
CHER 19 ev. (8/86}`
t
1....J (,..,J l I 1bus:
times/yr.
Handling Method:( D_ 8 11
Volume: (lbslyr. only) 1 3 Q a° o 0 01
Flash Point (cc)
1. LTJ N/A 2. U <60°F 3.1_1 60--140°F 4. L__1 > 140°F
Page 1
AUTHORIZATION REQUEST FORM I D 0 �1 'j '
e 1 II J Recl�i;n '
s.-amendment---NeW I j Incinerate
South Carolina Department of Health and Environmental Control Landfarm �EhSz�
gy Ae�ovyr
eureau of Solid and Hazardous Waste (803) 734-5200 .__..__ Other, /f�/
�"2A11-4-2
uthorization plumbers lP W.l - J p �_ � To be entered
/ _17-�„�r�
by TSD Faci I i ty
Generator lnforrnation:
Generator ID I: D o -1 -.7-1 Name _ DU Peijr yr A115: -Re) �s Ce. ,Tire. �i�yFrr'yiu /r/o�zKr
Address 07-5'o vr11 I City 113wiA)Ly�QF,'hGt.�d �dAq 4,vt I State lNc J Zip Code 1:2- S 392-
Official Contacf N/. Oz corr J Title ( �NviR 0006b. 1Telephone Y 915) 90�" 4481 f I_. 1
---T--Fxr ass
SC County
Treatment, Storage; or Disposal Facility Information: Unin-sua centretor Dilr)
Facility EPA ID #Is C D 0 7 0 -s _S 1. Name I csx SERVICES OF S.C. INC.
o # mis line will ,a_�.D.ys represent this specific waste stream:) G e. I a '^ 5 r'"' �-{� �-k 4
(,.,� Lime ( WS(( H e v c re S fc f't . Gr-2v�d �r
S A 1 p m e t S ct.0 0e - he,�� ! �
Description of Hazardous .waste
EPA/DHEC waste Codes DOT Hazard Class
Enter Quarter for One --Time Disposal: LJ / I 1 Qtrlyr. Handling Mettiod:l D 8 11
If Multiple Shipments Enter. Frequency. Here: I °_°._l times/yr. Volume: (Ibs/yr. only) 1 3 0_) o o a of
Process Prowcin9 waste:
WAs �tt,r2 Rea7rz--4-rM-FAT-
;(3vace.nTO A!avimgL: f3ajet
t- Avb F'cvo�daaRtil����
ll nr uC/FG%c%l.!/� 7,fC! Lt
Pj VS DG r41 A"ST/C S/FW�G%
Physical State of Waste @ 70°F Flash Point (cc)
solid , 2. U liquid 3.1.,,_1 WA 1. 1.1 N/A 2.1-1 <60°F 3.1-1 60--140°F 4. U >140°F
GGr.r�rNods f4rsi NG PA r�vr Fic Trig 7'Fsi
For 011EC Use DnlY:• Ebus:
Data Received-------r--� �--�
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A. EFFLUENT LIMITATION AND MONITORING REQUIREMENTS
During the period beginning on the effective date of the permit and lasting until expirati
the permittee is authorized to discharge from outfall(s) serial number(s) 002 (Cooling Wat
and Nafion Wastewater) Such discharges shall be limited and monitored by the permittee as
specified below:
ffluent Characteristics
'low
'emperature
,OD, SDay, 200C
ME
'luoride ****
THERE SHALL BE NO CH
Discharge Limitations
kg/day (lbs/day) Other Units (Specify)
Daily Avg. Daily Max. Daily Avg. Daily Max.
ROM,IU.K:: ;Z'I'N'C', OR COPPER ADDED TO THE COOLING WATER
Monitoring_ Requirements
Measurement Sample *Sample
Frequency Type Location
Continuous Recording I or E
Daily Grab E
Quarterly Composite E
Quarterly Composite E
Weekly Composite E
*Sample locations: E — Effluent, I — Influent
**The tempe ature ©f the effluent shall be such as not to cause an increase in the -temperature of the
rece0ving eam of more than 2.80C and in no case cause the ambient water temperature to exceed 320 C.
in
**ail mens ery day a discharge occurs except for Saturdays, Sundays and legal holidays.
C-3
'**;The 4amige equ fluoride must be taken downstream of the 001 discharge, unless or until, all neutralized
jNafFbn AreDLz;�streams are discharged entirely into the cooling water outfall 002.
rn ;o
TheeernAt shall obtain authorization from the Division of Environmental Management prior
to �tilzany biocide in the cooling water (See Part III of this Permit).
The yH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be
monitored''daily at the effluent by grab samples
There shall be no discharge of floating solids or visible foam in other than trace amounts.
w
A. EFFLUENT LIMITATION AND MONITORING REQUIREMENT
During the period beginning
the permittee is authorized to dischargetive fromdate outfall(s) se
rial Such discharges shall be limited and monitored b permit and lasting until expiration,
permittee as
the
below k 'dash L7ater
y the
Effluent Characteristics
-- Lischarge Limitations
Monitoring Requirements
kg/day (lbs/day) Ot4er Units
Daily Avg, Daily Max. Dail (Specify) Measurement
Y Avg. g• Daily Max. Frequency ample *Sample
Flow Type Location
Total Suspended Solids Weekly Instantaneous
30,0 m E
Settleable Solids g/1 45,0 mg/1 2/Month
Grab E
0.1 ml/1 2 ml/1
Turbidity 0.Weekly Grab
** ** E
�, _•�,M`:.,,:� Weekly
Grab
U , D
4t! p.
Y t.
*Sample locahonsll -b
„�fltient, U - Upstream, D - Downstream
**The dischar e,.sha.1.1 no'�N caw a the turbidity
If the cannot .ty ezceeds.t>hese levels due to natural background of the receiving water to exceed
level cannot c8•.,,,,e 50 NSU.
�.,..,,Ia-uY;N;.:Lncrease in the turbidity in the receiving wateiona, the discharge
Y g water .
All samples collected should be of a representative discharge.
The pH shall not be less than 6.0 standard unite nor greater than
monitored weekly at the effluent b 9.0 standard units and shall be �mr
y grab samples
There shall be no discharge of floatingr
solids or visible foam in other than trace amounts.o � F
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DUPONT FAYETTEVILLE WORKS
Waste Treatment Facilities
The existing waste water treatment facility employs
sludge treatment to handle the organic load from the
production units; Nafion@, Dymetrol@ and Butacite@.
j.
a-
actvated
sites'
The overall treatment system is shown on the attached drawing.
During the removal of the biodegradable organic load, excess
sludge is generated. This excess sludge was previously fed to
on-site lagoons for disposal. This lagooning was discontinued in
January, 1989, and temporary facilities have been used since then
to compact the -sludge and send it to an approved off-site
landfill for disposal.
In order to establish permanent sludge handling facilities, we
are proposing new facilities that will thicken, dewater and
partially dry the sludge prior to shipment to an approved
off-site landfill.
These permanent sludge handling facilities will be centrally
located in an existing enclosed ventilated building, and will
utilize commerically available equipment connected in series
to achieve the operations outlined below.
All generated waste water from the sludge facilities will be
returned to the inlet of the waste water treatment facilities
for reprocessing.
o Thickening
Excess waste sludge is taken from the waste
treatment clarifiers recycle stream and fed to a Dissolved Air
Floatation Thickener (DAF), where the solids are concentrated to
a nominal 3 % from 0.5 %. The DAF effluent is pumped to the
Digester, where it is held until it is pumped to sludge
dewatering. The Digester is an existing concrete lined basin
that was previously used as the biological treatment aeration basin
prior to 1989.
o Dewatering
The thickened sludge is mixed with a commercial
coagulant aid, and is then pumped to a Pre -Thickener, followed by
a Screw Press where the solids are concentrated to a nominal 8 %.
The dewatering system filtrate is returned to the waste treatment
equalization tank.
A standard belt conveyor is used to transport the
dewatered sludge to an intermediate 2200 gallon sludge holdup
vessel, and then conveyed to the the drying system.
o Drying D ������
Sludge drying is accomplished by using tip 28 1989
heated dryer to boil off about 70% of the water in the waste .sludge.
A blower is used to pull water vapor from the dryer to the
direct water spray type scrubber. The scrubber collecte&WMW FILE COPY
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FILTER DRUM__ROTATION TYPE
SCREW PRESS,
a new development by H I W,
■ More Advanced Treatment Capacity
■ Lower Moisture Content Ratio
■ Fully Automatic Continuous Operation
■ Economic Operation Costs
F9
DEWATERING SCREW PRESS
FOREWORD
Hyl
�Y
r'CFe'
.::isNei •
Hoilim Iron Works Co., Ltd., with over 12 years' experience in manufactur-
Ing pollution control related equipment in Korea, has also concentrated its
efforts on sludge dewatering problems encountered throughout the world.
With Its expertise and experience in this field. HIW successfully developed,
and Introduced for the first time in 1984, a Filter Drum Rotation Type Screw
Press. This dewatering press machine has been widely used at sewage treat-
ment plants, pulp and paper industries, leather and food processing facilities
and other Industrial plants throughout Korea.
The Rotation Type Screw Press, patented in Korea and designated as a new
development machine (Government Notice), has established an excellent per-
formance record in the domestic market.
The Press has also been patented in the U.S.A. and Taiwan, and patents have ..'
been applied for in Japan and Canada.
HIW has supplied more than 340 units to various industrial plants in Korea
(1981-1986), and promising negotiations are currently underway in Japan,
Taiwan and the U.S.A.
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SAVE AND COMPLY WITH
DURCO'S NEW ENVIRO-DRI'"
■ Waste Minimization
■ Decreased Liability
■ Payback Less Than 24
Months
■ Disposal Cost Savings As
High As 75%
The Durco ENVIRO-DRI'" steam
sludge dryer has been engineered with
one purpose in mind:
To slash your metal hydroxide disposal
costs while addressing current environ-
mental guidelines.
Its very design saves you money.
This low cost unit uses steam heat to
reduce sludge volumes 50 to 75%.
That makes ENVIRO-DRI'" the most
energy efficient, cost effective dryer
available. It also means simple and
easy installation with minimal mainte-
nance for further savings.
The use of inexpensive steam as its
primary heat source not only maximizes
efficiency, it reduces drying time. Typical
drying cycles average 4 hours or less
allowing 2 cycles per work shift. The
heavy duty auger assures complete
and continuous exposure of sludge to
the heat transfer surfaces of the
jacketed hopper for maximum dryness.
Volume and weight reductions of
sludge to 75% directly translate into
significant hauling and landfill disposal
cost savings. Just as important, waste
minimization decreases liability while
helping you address EPA and RCRA
guidelines. Within 12 to 24 months
ENVIRO-DRI'" will have paid for itself.
(Please see the back page of this
brochure to calculate the projected
savings and payback period when
using ENVIRO-DRI'".)
ENVIRO-DRI" is available in
capacities from 2 cubic feet to 36 cubic
feet. Its rugged all welded construction
features automatic shutoff with manual
override, highly efficient motor and
oversized gear reducer, controls, piping
and connections. Since it uses steam,
there is no open flame or electric heat-
ing elements so fire and explosion
hazards are virtually eliminated.
Field demonstrations, testing ser-
vices and the "5/10" financing plan are
all available to help you choose the
ENVIRO-DRI" that is best for your
sludge dewatering needs.
SLUDGE DRYER
■ Optional Pneumatic Fill h
Hatch For Ease Of=+�A
Operation
n-:
■ Loading Hatch Safety Interlock N
'j7
:. ■ TEFC Highly Efficient Motor ,
■ Optional Motor Starter And
71ransfomrer For Single
Electrical Connections And
Simplified Installation
Vapor Exhaust Fan
Top Loading Allows Use Of `
Forklift Tlvcks, Drums And
Location of Press Overhead
■ Adjustable And Replaceable
Wiper Blades
t Shaft Mounted Oversized
Slow Speed Gear Reducer`';
For Long Service Life And {
Low Maintenance
Electrical Panel Including On
Off Switches And Automatic
Timer For Drying Cycle
Steam Relief Valve For Safe
Operation
All Necessary Steam
Hardware Including TFaps,
Strainers And Automatic
Solenoid Valves
Optional Pneumatic Discharl
Chute
0 Optional Automatic Drum Or
Hopper Unloaders Available,i
Features
Benefits
Steam Heat Source
Reduced Operating Costs
Maximum Efficiency
Complete Operating Safety
Control Cake Dryness
And Avoid Dusting
Heavy -Duty Construction
Minimal Maintenance
Requirements
ASME Code Stamp Standard
ILow Operating Tempe tures
Eliminates Potential For
Incineration
Expander
Can Meet Future Needs While
Z -r S►
Reducing Costs Now
educe sposal is
Increased Operating Profits
justa Dryingle
Operate Off Plant Steam
r l6At
Go [It
-to -25 PSI
5=113
SLUDGE DRYER
■ Optional Pneumatic Fill h
Hatch For Ease Of=+�A
Operation
n-:
■ Loading Hatch Safety Interlock N
'j7
:. ■ TEFC Highly Efficient Motor ,
■ Optional Motor Starter And
71ransfomrer For Single
Electrical Connections And
Simplified Installation
Vapor Exhaust Fan
Top Loading Allows Use Of `
Forklift Tlvcks, Drums And
Location of Press Overhead
■ Adjustable And Replaceable
Wiper Blades
t Shaft Mounted Oversized
Slow Speed Gear Reducer`';
For Long Service Life And {
Low Maintenance
Electrical Panel Including On
Off Switches And Automatic
Timer For Drying Cycle
Steam Relief Valve For Safe
Operation
All Necessary Steam
Hardware Including TFaps,
Strainers And Automatic
Solenoid Valves
Optional Pneumatic Discharl
Chute
0 Optional Automatic Drum Or
Hopper Unloaders Available,i
HYMANUFAMING
18003542951
In Ohio 216/238.2000
Now The hapinjet
Operates
t„tib'
J• ;
1. Scrubber Outlet - to fan, / Rt
if suction system. To
exhaust stack, if blow-in.
2. Fixed Blade Mist
Eliminator -assures � _ , • � �F�\i
droplet -free air to process
or atmosphere. II
3. Access Door - permits
inspection of plates. rr.
Peepholes and quick
opening doors are
available as options.
4. Liquid Supply and Weir
(dam( - adjustable weir
provides uniform liquid
flow to plates. Recircu.
lated slurries may be used
if concentration does not
exceed 10% by weight.
Average flow 1.2 GPM/
1000 CFM. i
5. Impingement Baffle's
Plates - create interaction
of gas stream and liquid.
Additional plates (trays, j
stages( provide increased
efficiency.
q. Access Door - for
inspeftn and
mainp}ance.
Z
C�)
W u L
it r
y It.. i7
t 0 ti CJ
DRYER SCRUBBER
Plate Discharge and Seal impingement Bailie Plate
Drain -directsslurryAssuThorough snhhinp
bottom of scrubber for Yl �+
removal. Non•clogging m er
seal prevents short
circuiting of gas.
8. Spray Section - for cooling
and entrapment of larger
particles. Spray washes
under side of plate and
walls to prevent material
buildup. Sprays are non-
clogging. Recirculated
liquid may be used if
particle sizes contained
are below 3/32 inches.
twrm4i %d ifHB
Impinjet is actually two
scrubbers in one. The spray
section cools and humidifies
entering gas while simultaneously
removing larger particulate
matter. In addition, the under -
plate spray action keeps the plate
and walls clean and prevents
build-up.
Actual scrubbing is accomplished
by the jet action of
gas in the liquid,
produced by the
uniquely designed
impingement baffle
plate. This turbulent
effect assures
thorough wetting of
particles. Impinge-
ment baffle plates are
generally made of
high efficienc , found in our impingement plate
design:
1. the formation of a great number of
minute droplets of liquid at plate orifices,
and
2. the high velocity, relative to the minute
droplets, at which dust particles enter the
orifices. Few scrubbers have both high
relative velocities and form minute
droplets which in combination
give the highest efficiency
possible at any given pressure
drop.(
Greater particle collection
efficiency is attainable by
increasing relative velocity
(higher pressure drop). The net
effect is an improvement in the
relative velocity of dust arid
liquid droplets, intensifying the
variousstainless
9. Liquid Spray Inlet - uses
entrapment of dust particles by
' approximately 0.5 to 1
Of and dui laden gas ItmIg Ibrougb
pedoratedolaleand stnlungmned
GPM/1,000 CFM at 20
�+ y4�.�
yp�� _,
PSIG. Liquid con-
principle is highly effective in
sumption is greater if
"”'einem wdxet. Minute
hguiddroWelsRam lornr cneorap
cooling of gas is required.
I it,
(Combining liquid
relative velocity and small
utilized by liquid supply
(
(No. 41 and spray inlet
(No. 9) provides total
Coll act.
liquid flow.(
.a
10. Gas Inlet - if suction job,
from process; if pressure,
from blow-in fan.
twrm4i %d ifHB
Impinjet is actually two
scrubbers in one. The spray
section cools and humidifies
entering gas while simultaneously
removing larger particulate
matter. In addition, the under -
plate spray action keeps the plate
and walls clean and prevents
build-up.
Actual scrubbing is accomplished
by the jet action of
gas in the liquid,
produced by the
uniquely designed
impingement baffle
plate. This turbulent
effect assures
thorough wetting of
particles. Impinge-
ment baffle plates are
generally made of
high efficienc , found in our impingement plate
design:
1. the formation of a great number of
minute droplets of liquid at plate orifices,
and
2. the high velocity, relative to the minute
droplets, at which dust particles enter the
orifices. Few scrubbers have both high
relative velocities and form minute
droplets which in combination
give the highest efficiency
possible at any given pressure
drop.(
Greater particle collection
efficiency is attainable by
increasing relative velocity
(higher pressure drop). The net
effect is an improvement in the
relative velocity of dust arid
liquid droplets, intensifying the
variousstainless
VemunEffect resupsinlurbulentinteraction
hgmd
entrapment of dust particles by
steels, but can also
Of and dui laden gas ItmIg Ibrougb
pedoratedolaleand stnlungmned
the liquid medium. This same
be fabricated from
^nlgngemenlbattle god tEachnote has an
dv�duaI
principle is highly effective in
plastics and other
"”'einem wdxet. Minute
hguiddroWelsRam lornr cneorap
gas cooling wherein high
materials.
suepMOed manermgas omcarry,rp
AroGeismxvnlnwnerpo,��np,oss
relative velocity and small
Two /acforts "mate file
battles for ulnmale dts. 5.11 mmugh drain
Clunm
droplet size assures intimate
gas passes into mist ehn roar IM
return to nmess or almomnem
Coll act.
DZ
V_
4
n
M�
W
CID
4
:-�
DISSOLVED
AIRjFLOATATION
I
FLOATmTREAT,'c SEPARATOR
THICKENER (DAF)
PRESSURE REGULATOR. Correct pressure in maintained by
,:C7 either automatic or manual controls to assure efficient op-
erations under all flow conditions.
SCUM ur
TROUGH with accurately formed beach asses a rel-
atively
dry scum and clean discharge.
POSITIVE SCUM REMOVAL Rex Scum Removers are avail-
able In a wide variety of types and sizes. Proper materials
aro available for unusual corrosive conditions, explosive atmos-
pheres, eta ,
0 AIR LINE. Proper amount of air I. fed directly foto the
pressure tank for optimum saturation. Air feed is regu-
lated by the pressure tank liquid level controller and a solenoid
valve in the air line.
VERTICAL SCUM IIAFiLE prevents floatable solids from
pass-ing out of tank ... directs clarified effluent to outfall weir.
AD[USTARLE DL111AL1 WEIR assures uniform discharge and
controls water level In tank for optimum skimming con-
ditions.
EF[LUFNT LINE.
w[r w[Ll Integral with Float -Treat tank, provides a con-
tinuoua supply of treated effluent for recycle system even
nthough
raw flow may be interrupted.
RECTCLE [S
PRSURE PUMP withdraws portion of effluent and
9a� pumps it to pressure tank. Because only a amall portion
of effluent Is recycled, pump size and pumping costs are held to
//the minimum.
Alis PRESSURE RETENTION TANK Is designed and tested to con-
`A�44.•��' form to rigid code requirements. Positive liquid level con-
trol assures maximum saturation of pressurized flow. Tank may
/1be supplied with or without packing as conditions warrant
Ef l.'If SETTLED SLUDGE REMOVAL is obtained by any of several
Otatypes of conveyors ... from screw conveyors in smaller
tanks up to
projects. heavy-duty conveyor sludge collectors for the larger
® BOTTOM SLUDGE WITHDRAWAL LIN.
® 6LENDING AND mSTRIRUTION STSTFM. Raw flow and recycle
stream enter the Float -Treat Tank through the inlet mani-
12jd,..As the blended stream enters, it impinges on concave re-
n baMes for thorough diffusion throughout width and depth
of tank. Inlet piping and reaction Jets ars carefully sized and
located for correct velocities, proper bubble formation and
thorough blending,
RECYCLE LINE. Pressurized recycle liquid Is Introduced inFo
raw flow line Immediately downstream from pressure re-
duction valve.
/}®� SCUM WITHDRAWAL LINE.
gt i:y RAW WASTE LINE.
s
HOLDUP VESSEL
Practical design assures dependable action
Tank liner is available to retard buildup o
the sides when spreading sticky material.
Liner is also helpful in freezing conditions
when unloading very dry or fluffy material
Tank and side extensions are made from
corrosion resistant steel. Side extensions
on for easy replacement in case of damag
Cleanout door allows complete
cleanout of tank.
Expeller is located on the ric
unit for easy and natural visi
Offset paddles engage the n
motion for efficient use of pc
pattern is controlled by a slit
a hydraui' cylinder.
um
C:7
rn v �3
A'J It+•�
O�
Auger may be lifted hydraulically to break up Aggressive aug, ,roves material forward to the
bridged material or to ensure the auger isn't expeller. This niinpr ran hp rni—ri h„rf—.6-1k,
Side extensions come in two sizes, one forms a
sufficient
e extensions
3oth exten-
.nt if damaged.
indicator is easily seen by the
. .
tags reduction on auger drive eliminates
ed for a gearbox.
drive is shearbolt protected.
Optional expeller deflector assures more even Chain drive for the expeller on the Model
distribution when spreading sticky material. Optional 304 is protected by shearbolts. Belt drive for
expeller pan is available to prevent unspread the expeller on the Model 308 efficiently
material from dropping directly on the ground handles the peak torque requirements when
spreading loads of varying consistency.
Is allow easy turning
ractors. Channels carry
it.