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HomeMy WebLinkAboutNC0003425_Appx H - Background Statistical Evaluation Report_201710312017 Comprehensive Site Assessment Update October 2017 Roxboro Steam Electric Plant SynTerra APPENDIX H BACKGROUND STATISTICAL EVALUATION REPORT synTerra PROPOSED BACKGROUND THRESHOLD VALUES FOR NATURALLY OCCURRING CONCENTRATIONS IN GROUNDWATER AND SOIL ROXBORO STEAM ELECTRIC PLANT 1700 DUNNAWAY ROAD SEMORA,, NORTH CAROLINA 27343 OCTOBER 2017 PREPARED FOR DUKE ENERGY PROGRESS, LLC 410 S. WILMINGTON STREET / NC 15 RALEIGH, NORTH CAROLINA 27601 DUKE ENERGY , Jess Gilmer Project Scientist Craig D. Eady, NC LG 1599 Project Manager Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra TABLE OF CONTENTS SECTION PAGE 1.0 INTRODUCTION.........................................................................................................1-1 2.0 BACKGROUND DATASETS.................................................................................... 2-1 2.1 Groundwater................................................................................................................. 2-1 2.1.1 Transition Zone....................................................................................................... 2-2 2.1.2 Bedrock..................................................................................................................... 2-2 2.2 Soil...................................................................................................................................2-2 3.0 PRELIMINARY DATA ANALYSIS..........................................................................3-1 3.1 Descriptive Statistics.....................................................................................................3-1 3.2 Management of Non -Detect Data...............................................................................3-1 3.3 Graphical Analysis........................................................................................................3-2 3.4 Screening Datasets for Outliers...................................................................................3-2 3.5 Autocorrelation............................................................................................................. 3-3 3.6 Evaluation of Dataset Distribution.............................................................................3-3 4.0 PROPOSED PROVISIONAL BACKGROUND THRESHOLD VALUES ......... 4-1 5.0 REFERENCES................................................................................................................ 5-1 Page i P: \ Duke Energy Progress.1026 \ Statistics_CAMA \ BTV Reports for CSAs \ Roxboro \ DRAFT \ Roxboro _BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil Roxboro Steam Electric Plant LIST OF FIGURES Figure 1 Background Groundwater Sample Locations Figure 2 Background Soil Sample Locations Figure 3 Example of Concentration Trend Figure 4 Example of Shifting Concentration LIST OF TABLES October 2017 Table 1 Chemical Parameters Analyzed in Groundwater and Soil Table 2 Background Groundwater Results Through January 2017 Table 3 Unsaturated Background Soil Data Summary Table 4 Statistical Analysis Results - Transition Zone Table 5 Statistical Analysis Results - Bedrock Table 6 Statistical Analysis Results - Background Soil Table 7 Groundwater Provisional Background Threshold Values Table 8 Soil Provisional Background Threshold Values LIST OF APPENDICES Appendix A Box -and -Whisker and Q-Q Plots: Transition Zone Appendix B Box -and -Whisker and Q-Q Plots: Bedrock Appendix C Box -and -Whisker and Q-Q Plots: Soil Appendix D Outlier Test Results: Transition Zone (ProUCL Output) Appendix E Outlier Test Results: Bedrock (ProUCL Output) Appendix F Outlier Test Results: Soil (ProUCL Output) Appendix G GOF Test Results: Transition Zone (ProUCL Output) Appendix H GOF Test Results: Bedrock (ProUCL Output) Appendix I GOF Test Results: Soil (ProUCL Output) Appendix J UTL Results: Transition Zone (ProUCL and NCSS Output) Appendix K UTL Results: Bedrock (ProUCL and NCSS Output) Appendix L UTL Results: Soil (ProUCL and NCSS Output) Page ii SynTerra P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil Roxboro Steam Electric Plant LIST OF ACRONYMS CAMA Coal Ash Management Act CAP Corrective Action Plan CCR Coal Combustion Residuals CSA Comprehensive Site Assessment Report DWR Division of Water Resources GOF Goodness -of -Fit KM Kaplan-Meir NCDEQ North Carolina Department of Environmental Quality NCDWQ North Carolina Division of Water Quality NCAC North Carolina Administrative Code NTU Nephelometric Turbidity Units PBTV Provisional Background Threshold Value POG Protection of Groundwater PSRG Preliminary Soil Remediation Goal Q-Q Quantile-Quantile ROS Regression on Order Statistics SU Standard Units Site Roxboro Steam Electric Plant USEPA United States Environmental Protection Agency UTL Upper Tolerance Limit Page iii October 2017 SynTerra P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra 1.0 INTRODUCTION Provisional background threshold values (PBTVs) for naturally occurring concentrations in groundwater and soil at the Roxboro Steam Electric Plant (Roxboro or Site) and surrounding areas in Person County, North Carolina, are presented in this report. These PBTVs are necessary for comparison to data generated during the Comprehensive Site Assessment (CSA) of the Roxboro site. North Carolina General Assembly Session Law 2014-122, the Coal Ash Management Act (CAMA) of 2014, requires submittal of a Comprehensive Site Assessment Report for each facility that has a coal combustion residuals (CCR) impoundment. Companies that own multiple facilities with CCR impoundments must submit a CSA for each such facility. The purposes of the CSAs are to: ,61P Characterize the extent of impact resulting from storage of coal ash at regulated facilities ,67 Evaluate the chemical and physical characteristics of detected constituents 07 Investigate site geology and hydrogeology 07 Determine factors that are related to contaminant transport 07 Examine risk to potential receptors and exposure pathways To meet specific North Carolina Administrative Code (NCAC) requirements, CSAs were conducted in accordance with a conditionally approved Groundwater Assessment Plan. Those requirements, defined in 15A NCAC 02L .0106(g), include an assessment of the horizontal and vertical extent of constituents present in groundwater at concentrations exceeding groundwater quality standards. Regulations regarding North Carolina groundwater quality standards (T15A NCAC 02L .0202. Section (b)(3)) state the following: Where naturally occurring substances exceed the established standard, the standard shall be the naturally occurring concentration as determined by the Director. That sentence underscores the importance of determining the naturally occurring concentrations of constituents present in groundwater and soil. Such determination is essential in fully characterizing the extent of impacts resulting from the storage of coal ash. Page 1-1 P:\Duke Energy Progress.1026\Statistics_ CAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra Methodology for determining background concentrations in groundwater and soil at coal ash facilities is presented in the technical memorandum Revised Statistical Methods for Developing Reference Background Concentrations for Groundwater and Soil at Coal Ash Facilities (HDR Engineering, Inc. and SynTerra Corporation, May 2017). That document was based on the US Environmental Protection Agency "Unified Guidance' report (USEPA, 2009), USEPA's Guidance for Comparing Background and Chemical Concentrations in Soil for CERCLA Sites (USEPA, 2002), USEPA ProUCL Technical Guide (USEPA, 2015), and the North Carolina Division of Water Quality technical assistance document for Evaluating Metals in Groundwater at DWG Permitted Facilities (NCDWQ, 2012). The North Carolina Department of Environmental Quality (NCDEQ) Division of Water Resources (DWR) has conditionally approved the methodology presented in the statistical methods memorandum/technical guidance document. On July 7, 2017, NCDEQ provided a response letter to Duke Energy (Zimmerman to Draovitch) requiring that background constituent concentrations (referred to herein as provisional background threshold values [PBTVs]) in groundwater and soil at the Roxboro Plant be determined and submitted within 30 days from receipt of the letter. The response letter also identified groundwater and soil data appropriate for use in the statistical determination of PBTVs for the Site. PBTVs for the Roxboro Plant were subsequently submitted to NCDEQ on August 4, 2017 and August 28, 2017. Additionally, revised PBTVs for constituents in soil were resubmitted to NCDEQ on September 5, 2017 (Draovitch to Zimmerman) in response to comments from NCDEQ dated September 1, 2017 (Zimmerman to Draovitch). This report provides documentation of the procedures, evaluations, and calculations used to determine PBTVs for submittal to NCDEQ. All procedures were performed in accordance with the Revised Statistical Methods for Developing Reference Background Concentrations for Groundwater and Soil at Coal Ash Facilities (HDR Engineering, Inc. and SynTerra Corporation, May 2017) technical memorandum. Page 1-2 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant 2.0 BACKGROUND DATASETS SynTerra Groundwater samples have been collected from a background monitoring well, BG-01, since 2010 and at more recently established background locations since 2015. Soil samples were initially collected at background locations during the 2015 CSA (SynTerra 2015a). Additional soil samples were collected at background locations in 2017 to augment the background dataset for establishing PBTVs for constituents in soil. The following section describes background groundwater and soil datasets that were used to establish site PBTVs. Details regarding background datasets have also been provided in the CSA (SynTerra, 2015a), Corrective Action Plan (CAP) 1 (SynTerra 2015b), CAP 2 (SynTerra, 2016), supplemental reports, and monthly electronic data submittals. 2.1 Groundwater Groundwater samples were collected from monitoring wells using low -flow sampling techniques in accordance with the USEPA Region 1 Purging and Sampling Procedure for the Collection of Groundwater Samples from Monitoring Wells (revised January 19, 2010) and in accordance with the Groundwater Monitoring Program, Low Flow Sampling Plan, Duke Energy Facilities, Ash Basin Groundwater Assessment Program, North Carolina (June 10, 2015). Groundwater samples were analyzed for constituents listed in Table 1. Groundwater across the Site is unconfined and found within the ash basins and three flow systems - residuum/saprolite, transition zone, and fractured bedrock. However, saturated conditions are not evident within the residuum/saprolite units in background locations due to the nature of the former natural drainage features in which the ash basins were created. The current background monitoring well network at the Roxboro Plant (Figure 1) consists of wells installed within two hydrogeologic flow layers: 17 Transition zone ,67 Bedrock The background dataset for each flow layer consists of sample data pooled across background monitoring wells monitoring that flow zone. PBTVs were statistically determined for constituents using total (non -filtered) sample results obtained from background wells through the first quarter of 2017. Data were omitted from the background datasets if one or more of the following conditions were encountered: H pH was greater than 8.5 standard units (S.U.) during the time of sample collection, unless the regional NCDEQ office determined an alternate pH threshold for the Site Page 2-1 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra 167 Groundwater turbidity was greater than or equal to 10 Nephelometric Turbidity Units (NTUs) at the time of sample collection 17 Groundwater turbidity and/or pH were not recorded at the time of sample collection ,67 Result was identified as a statistical outlier ,67 Sample collection occurred less than 60 days after the previous sampling event (referred to herein as autocorrelated samples) ,67 Non -detected result was greater than 15A NCAC .02L (2L) standard or Interim Maximum Concentration (IMAC) of 15A NCAC .02L Appendix 1, April 1, 2013 The background dataset for each flow layer used to statistically determine PBTVs for constituents in groundwater are provided in Table 2. The following sections of this report summarize the background dataset for the transition zone and fractured bedrock. 2.1.1 Transition Zone Three wells (BG-01, MW-15D, and MW-18D) are used to monitor background groundwater quality within the transition zone. Through the first quarter of 2017, the background dataset for the transition zone contained more than 10 valid samples for all constituents. Additional samples were collected from BG- 01, MW-15D, and MW-18D during the second and third quarters of 2017. Those wells will be sampled again the fourth quarter. 2.1.2 Bedrock Six wells (BG-01BR, MW-10BR, MW-14BR, MW-15BR, MW-18BR, and MW- 19BRL) are used to monitor background groundwater quality within the fractured bedrock. As of the first quarter of 2017, the background dataset for fractured bedrock contained more than 10 valid samples for all constituents. Additional samples were collected from BG-01BR, MW-10BR, MW-14BR, MW- 15BR, MW-18BR and MW-19BRL during the second and third quarters of 2017. Those wells will be sampled again in the fourth quarter. 2.2 Soil Discrete soil samples were collected from multiple depth intervals at background locations during the 2015 CSA. Additional samples were collected from background locations in 2017 to augment the background dataset for use in establishing PBTVs. Soil sample locations are presented in Figure 2. Soil samples were analyzed for constituents listed in Table 1. The background soil dataset for the Roxboro Plant consists of background soil sample data pooled across varying depths and non -impacted locations. Page 2-2 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra Soil samples that did not meet the following criteria were omitted from the background dataset: ,67 Sample was collected from a location impacted by CCRs or coal -associated materials ,67 Sample was collected from a depth of less than 0.5 foot below ground surface ,67 Sample was collected from a location that was impacted by other potential anthropogenic sources of constituents ,67 Sample was collected less than 1 foot above the seasonal high water table elevation H Non -detected result was greater than the North Carolina Preliminary Soil Remediation Goal (PSRG) Protection of Groundwater (POG) Background soil data used to statistically establish PBTVs for naturally occurring inorganic constituents in soil are provided in Table I Page 2-3 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra 3.0 PRELIMINARY DATA ANALYSIS Preliminary analysis of background datasets was performed before calculating PBTVs for constituents in groundwater and soil at the Roxboro Plant. That preliminary analysis included: ,67 Calculating descriptive statistics ,67 Graphical analysis ,67 Screening datasets for statistical outliers and autocorrelated sample results 07 Assessing the distribution of constituent data 3.1 Descriptive Statistics Descriptive statistics are useful for characterizing data, increasing dataset understanding, and assessing information quality. The following descriptive statistics were calculated for the background groundwater and soil datasets: 07 Sample size ,67 Number of non -detects 07 Percentage of non -detects Those statistics were calculated for constituents within each groundwater flow layer (Tables 4 and 5). Descriptive statistics for constituents in soil are provided in Table 6. 3.2 Management of Non -Detect Data Concentrations between the lowest achievable value that can be quantitatively obtained by laboratory analytical procedures or technology (referred to as the reporting limit) and zero are called non -detects. A high degree of uncertainty is associated with non - detected values. During statistical analysis of groundwater and soil data, non -detected values within each background dataset were adjusted accordingly using the statistics software ProUCL version 5.1.002 (USEPA, 2015). The manner in which non -detects were adjusted was determined by the proportion of non -detects present within a dataset. For cases in which datasets were comprised of 50 percent or fewer non -detects, algorithms in ProUCL were applied using either the Kaplan-Meir (KM) method or robust regression on order statistics (ROS) to address non -detects. If datasets contained from 50 percent to 90 percent non -detects, PBTVs were estimated using non -parametric statistical methods, which do not make a distinction between detected and non -detected Page 3-1 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra concentrations. For instances in which datasets contained 90 percent or more non - detects or less than three detected concentrations, the non -detect value with the highest frequency of occurrence was used to represent the PBTV. 3.3 Graphical Analysis Background groundwater data was graphically portrayed using scatter plots, box -and - whisker plots, and quantile-quantile (Q-Q) plots, while background soil data was illustrated using box -and -whisker plots and Q-Q plots. The use of scatter plots of concentration versus time for constituent within each background monitoring well assisted in identifying outliers and potential trends or seasonality within datasets. Box - and -whisker plots and Q-Q plots were constructed for each constituent within each background well and for each groundwater flow layer. That was done to assess dataset distributions, identify possible outliers, and identify sub -groups. Box -and -whisker and Q-Q plots for groundwater constituents are provided in Appendices A and B. Box -and - whisker plots and Q-Q plots were also produced for constituents in soil to identify outliers, assess dataset distributions, and capture any spatial variability across boring depths. Box -and -whisker plots and Q-Q plots produced for soil are provided in Appendix C. Graphical analysis was also used to provide information regarding a steady-state baseline period free of trending or shifting background concentrations (Figures 3 and 4). Graphical analysis was used to determine if background data were valid for use in establishing PBTVs or if historical data warranted removal from the dataset due to trending or shifting concentrations. 3.4 Screening Datasets for Outliers Outliers are values that do not reside within the range of values that represent the bulk distribution of a dataset. Background groundwater and soil datasets were screened for potential outliers in accordance with methodology outlined in the Revised Statistical Methods for Developing Reference Background Concentrations for Groundwater and Soil at Coal Ash Facilities (statistical methods document) (HDR Engineering, Inc. and SynTerra Corporation, May 2017) technical memorandum. During the screening of datasets for outliers, autocorrelated values were retained to help determine whether suspected outliers are a result of pure chance (i.e., very low probability of occurrence) or in fact are representative of constituent concentrations at a given point in time. Autocorrelated values represent real data representative of a given location at a given report in time; therefore, this data should be retained for outlier screening to strengthen decision making. Omission of autocorrelated values is Page 3-2 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra warranted only during the assessment of data distributions and calculation of PBTVs, which make an underlying assumption that data are independent from one another with respect to time. Only extreme outliers and data resulting from laboratory, sampling, or reporting errors were omitted from statistical evaluations. Mild outliers were retained for statistical evaluations, as those values might be a result of "natural fluctuations and variability" in constituent concentrations (USEPA, 2009; USEPA, 2015). Results for quantitatively screening groundwater and soil datasets for potential outliers using either Dixon's or Rosner's Outlier test are provided in Appendices D through F. Statistical outliers omitted from groundwater and soil datasets prior to the estimation of PBTVs are identified in Tables 2 and 3. 3.5 Autocorrelation Autocorrelation occurs when measurements collected at different points in time correlate with one another. Sources of autocorrelation in groundwater data can be caused by seasonality, trends, or a lack of adequate time between sample collections. For the estimation of PBTVs for constituents in groundwater and soil, NCDEQ requested (Technical Memorandum: Zimmerman to Draovitch, April 2017) that Duke Energy use a minimum 60-day interval between groundwater sampling events, and that samples collected less than 60 days apart be omitted from statistical evaluations. Sample data omitted from statistical evaluations as a result of autocorrelation are identified in Table 2. 3.6 Evaluation of Dataset Distribution Upon completion of screening background datasets for outliers and autocorrelated sample results, the distribution of background groundwater and soil data were assessed following the methodology provided in the Revised Statistical Methods for Developing Reference Background Concentrations for Groundwater and Soil at Coal Ash Facilities (statistical methods document) (HDR Engineering, Inc. and SynTerra Corporation, May 2017) technical memorandum. Background constituent data were evaluated for fit with normal, lognormal, and gamma distribution models. If one of the three distribution models did not describe the dataset adequately, non -parametric (distribution -free) statistical methods were used. Rather than relying only on the text statement provided in ProUCL goodness -of -fit (GOF) test results output to determine which distribution model most accurately described the background dataset for a constituent, the significance level (i.e., Page 3-3 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra probability level or P-value), test value, critical value, and censored and uncensored Q- Q GOF plots were assessed. The distributions of background constituent data for groundwater and soil are provided in Tables 4, 5, and 6. ProUCL GOF test result outputs for groundwater and soil are provided in Appendices G through I. Page 3-4 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra 4.0 PROPOSED PROVISIONAL BACKGROUND THRESHOLD VALUES PBTVs were determined by calculating the upper tolerance limit (UTL) for each constituent. Upper and lower tolerance limits were calculated for pH. UTLs were calculated for constituents in groundwater and soil at the Roxboro Plant using methodology outlined the Revised Statistical Methods for Developing Reference Background Concentrations for Groundwater and Soil at Coal Ash Facilities (statistical methods document) (HDR Engineering, Inc. and SynTerra Corporation, May 2017) technical memorandum. Statistical analysis software UTL outputs are provided in Appendices J through L. The proposed groundwater and soil PBTVs for the Roxboro Plant submitted to NCDEQ in August 2017 and resubmitted in September 2017 are provided in Tables 7 and 8. Page 4-1 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant SynTerra 5.0 REFERENCES NCDEQ DWR, 2012. Evaluating Metals in Groundwater at DWQ Permitted Facilities: A Technical Assistance Document for DWQ Staff. http://digital.ncdcr.gov/cdm/ref/collection/p 16062co119/id/251181. SynTerra, 2015a. Comprehensive Site Assessment, Roxboro Steam Electric Plant, September 2, 2015. SynTerra, 2015b. Corrective Action Plan, Roxboro Steam Electric Plant, December 1, 2015. SynTerra, 2016. Corrective Action Plan 2, Roxboro Steam Electric Plant, February, 29, 2016. USEPA, 2002. Guidance for Comparing Background and Chemical Concentrations in Soil for CERCLA Sites. EPA 540-R-01-003. USEPA, 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities — Unified Guidance, March 2009. EPA 530-R-09-007. USEPA, 2015. Statistical Software ProUCL 5.1.002 for Environmental Applications for Data Sets with and without Nondetect Observations. EPA/600/R07/041. Page 5-1 P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant FIGURES SynTerra P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx 120 0- erd z o 10o up'�'a�d�r so ~ 60 N w Z V 40 O 20 0 3/3/2010 5/11/2012 7/20/2014 9/27/2016 DATE 120 Z OZ 100 D°inward w Q Pre end H Z 60 O O O Z UJ V 40 0 0 O Ov 20 O ., O 0 3/3/2010 5/11/2012 7/20/2014 9/27/2016 DATE 148 RIVER STREET, SUITE 220 FIGURE 3 ,tip =NE8ILLE, SOUTH 64421 gggg CAROLINA29601 EXAMPLE OF CONCENTRATION TREND ww�nr.s nterracor .com DRAWN BY: J. GILMER DATE: October2017 ROXBORO STEAM ELECTRIC PLANT synTerra[PAD.le PROJECT MANAGER C. Eady DUKE ENERGY PROGRESS LAYOUT: T. Plating , LLC Energy Progress. 10261Statistics_CAMA\B1 SEMORA NORTH CAROLINA Reports for CSAs\Roxboro\DRAFT\Figures 450 — —I 400 .� 350 Z I New Background Dataset I I W 300 D � 250 � I I (A W 200 Z V I I Ov ZO 150 V 100 I 50 � I 0 _ T -- 1/1/2010 8/24/2011 4/15/2013 12/6/2014 7/28/2016 DATE 148 RIVER STREET, SUITE 220 FIGURE 4 GREENVILLE, SOUTH CAROLINA 29601 PHONE EXAMPLE OF CONCENTRATION SHIFT 864-421 -9999 WWJJ.S nterracor .com ROXBORO STEAM ELECTRIC PLANT DRAWN BY: J. GILMER DATE: October 2017 PROJECT MANAGER C. Eady DUKE ENERGY PROGRESS, LLC synTerra LA: T.Rating SEMORA NORTH CAROLINA FYOIT \Duke Energy Progress.1026\Statistics_CAMA\BTV Reports /r CSAs\Roxboro\DRAFT\Figures Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant TABLES SynTerra P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx TABLE 1 CHEMICAL PARAMETERS ANALYZED IN GROUNDWATER AND SOIL ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC FIELD PARAMETERS pH*t Specific Conductance* Temperature* Dissolved Oxygen* Oxidation Reduction Potential* Eh* Turbidity* INORGANICS Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Iron Lead Manganese Mercury Molybdenum Nickel Selenium Strontium Thallium (low level) Vanadium (low level) Zinc NOTES: * = Indicates parameter analyzed in groundwater only. t = Indicates parameters analyzed in soil only. RADIONUCLIDES Radium 226* Radium 228* Uranium 233, 234, 236, 238 * ANIONS/CATIONS/OTHER Alkalinity (as CaCO3)* Bicarbonate* Calcium Carbonate* Chloride Magnesium Nitrate (as N)t Nitrate + Nitrite* Potassium Percent Moisturet Methane* Sodium Sulfate Sulfide* Total Dissolved Solids* Total Organic Carbon Total Suspended Solids* Metals in groundwater were analyzed for total and dissolved concentrations. Soil pH measured at 25 degrees C. Analysis of groundwater and soil samples for Chromium (VI) began after initial samples were collected as part of CSA. P:\Duke Energy Progress. 1026\Statistics_CAMA\BTV Reports for CSAs\Roxboro\DRAFT\Tables\ Table 1 - Chemical Parameters analyzed in Groundwater and Soil.xlsx Page 1 of 1 Sample ID nsition Zone BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 BG-01 MW-15D MW-15D MW-15D MW-15D MW-15D MW-15D MW-15D MW-18D MW-18D MW-18D MW-18D TABLE 2 BACKGROUND GROUNDWATER RESULTS THROUGH JANUARY 2017 ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Bi- Carbonate Chromium Analytical Parameter pH Turbidity Alkalinity Aluminum Antimony Arsenic Barium Beryllium carbonate Boron Cadmium Calcium Alkalinity (VI) Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Alkalinity Reporting Units S.U. NTUs mg/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L mg/L mg/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L 15A NCAC 02L Standard 6.5-8.5 NE NE NE 1* 10 700 4* NE 700 2 NE NE 250 10 10 1* 1000 300 15 NE 50 1 Sample Field Parameters Collection Date Analytical Results 11/30/2010 6.8 8.56 - 713 <0.5 <5 69.7 - - <50 <0.08 - - 14.2 - 11.1 - 11.2 881 <3 - 27.2 <0.2 04/20/2011 6.4 9.92 - 330 <0.5 <5 73.1 - - <50 <0.08 - - 13.4 - 15 - 11.4 499 <3 - 18.5 <0.2 07/13/2011 6.4 9.58 - <100 <0.5 <5 84 B - - <50 <0.08 - - 12.7 B - 42.7z - <5 752 <3 - 25.8 B <0.2 11/02/2011 6.6 9.42 - 201 <0.5 <5 75.6 - - <50 <0.08 - - 13.4 - 16.8 - <5 307 <3 - 7.8 <0.2 04/02/2012 6.4 9.8 - 301 <0.5 <5 72.3 - - <50 <0.08 - - 15.5 - 8.8 - <5 286 <3 - 6.5 <0.2 07/11/2012 6.3 8.57 - 734 <0.5 <5 81 - - <50 <0.08 - - 14.5 - <5 - 6.4 866 <3 - 18.7 <0.2 11/06/2012 6.4 7.91 - 438 <0.5 <5 84.2 - - <50 <0.08 - - 15 - 16.1 - <5 532 <3 - 11.1 <0.2 04/08/2013 6.3 5.24 - 110 <1 <1 79 - - <50 <1 - - 14 - <5 - <5 113 <1 - 5 <0.05 07/08/2013 6.3 6.79 - 300 <1 <1 83 - - <50 <1 - - 15 - 10 - <5 368 <1 - 9 <0.05 11/11/2013 6.4 9.8 - 438 <1 <1 83 - - <50 <1 - - 14 - 7 - <5 507 <1 - 11 <0.05 04/03/2014 6.4 6.6 - 311 <1 <1 86 - - <50 <1 - - 17 - 6 - <5 370 <1 - 8 <0.05 07/15/2014 6.3 4.4 - 205 <1 <1 81 - - <50 <1 - - 16 - <5 - <5 218 <1 - 6 <0.05 11/12/2014 6.5 7.45 - 373 <1 <1 87 - - <50 <1 - - 16 - 6 - <5 437 <1 - 9 <0.05 04/16/2015 6.6 7.86 209 278 <1 <1 95 <1 209 <50 <1 46.7 <5 16 - 13 -2-34 <5 283 <1 25.9 54 <0.05 09/16/2015 6.5 9.81 220 801 <1 <1 91 <1 220 <50 <1 40.4 <i9 16 - 6.77 <1 3.19 811 <1 24.5 M4 21 <0.05 -_, -_, _--_ 6-.4 9-3 2-28 319 �9.5 <E9.S 46 <-0-2 228 <58 F0:08 44.2 <3 6-2 3-.6 9.62 3 369 <-0-1 254 <0.2 01/05/2016 6.4 8.46 231 434 <1 <1 91 <1 231 <50 <1 43.4 <5 18 4.5 9.02 <1 2.49 484 <1 20.6 17 <0.05 04/07/2016 6.5 8.12 233 i559 <1 <1 97 <1 233 <50 <1 44.6 <5 21 10.2 18 i.85 10 i769 <1 26.1 34 <0.05 07/12/2016 6.3 9.78 243 323 <1 <1 90 <1 243 <50 <1 43.8 Bl <5 20 6.1 M6 6 <1 <5 322 <1 27.2 9 <0.05 09/08/2016 6.5 8.68 229 830 <1 <1 91 <1 229 <50 <1 41.7 <5 18 7.6 8.46 <1 3.94 766 <1 24.9 14 <0.05 11,91,2916 6.8S 6..- 2-3-7 4-& -<4- S9 2-3-7 <38 -<-I- 4z`-4 <3 - 4 <4 <3 333 <4 2-5-.3 ze.05 11/10/2016 6.6 S 9.85 235 346 <1 <1 87 <1 235 <50 <1 42.5 <5 18 4.4 7.24 <1 2.87 356 <1 23.4 13 <0.05 11/16/2016 6.4 8.73 - - - - - - - - - - - - - - - - - - - - - 01/26/2017 6.6 4.49 244 224 <1 <1 91 <1 244 <50 <1 43.1 <5 19 13.1 8.74 <1 1.8 227 <1 25.1 M4 5 <0.05 05/30/2015 6.4 2.57 230 121 <1 <1 10 <1 230 <50 <1 67.8 <i9 43 - 1.26 4.91 <1 163 <1 26.6 316 <0.05 09/12/2015 7.1 6.59 240 588 <1 <1 9 <1 240 <50 <1 66.6 <4B 43 - 2.4 1.11 1.42 671 <1 27.7 80 <0.05 -_, __, __-_ 6_.7z 9.z4 <5 <i98 ge.5 ge.5 ge.-2 <5 <54 f9-93 66 <5 44-.2 3.4 44 ge.5 -.4 5& go.! 26.6 4-5 E9.2 01/05/2016 6.4 3.29 233 201 <1 <1 8 <1 233 1 <50 <1 60.4 <5 40 1.5 M6 1.77 <1 <1 240 <1 24.3 48 <0.05 06/23/2016 6.6 3.04 237 45 <1 <1 7 <1 237 <50 <1 65.5 <5 44 2.7 2.56 <1 <1 48 <1 28 23 <0.05 n 6 yy 3.25 2-54 36 <4 <i <4 2-54 -<59 <4 68.1 <5 46 2-5 -2-.-8 <4 <4 43 <4 2-8-.7 2-;L Q.05 09/08/2016 6.9 3.46 240 125 <1 <1 6 <1 240 <50 <1 63.7 <5 44 2.7 2.81 <1 <1 146 <1 26.7 18 <0.05 11/09/2016 6.6 8.87 240 331 <1 <1 7 <1 240 <50 <1 63.1 <5 46 9.4 4.53 <1 1.66 371 <1 25.6 18 <0.05 01/25/2017 6.6 1.27 233 55 <1 <1 6 <1 233 <50 <1 65.8 <5 45 2.8 2.66 <1 <1 72 <1 27.7 8 <0.05 12/06/2015 _.4 7.16 213 P41,R1 29G 0.64 <045 Q.2 24-3 <59 Q.08 103 �,o _<5 i8i P46 54 9.56 -1-.3 499 9A1 49.6 M, 82B <0.2 01/05/2016 7.2 1.25 237 31 <1 <1 19 <1 237 <50 <1 85.3 <5 170 0.78 2 <1 <1 334 <1 42.3 978 <0.05 nc 6 _7�4 6r.43 2 -G 71 <4 <4 -<-I- 24-8 <5B <4 42 <5 339 3i.2 i9.5 <4 <4 456 <4 4i.9 io Q Q 05 07/14/2016 7.4 9.71 275 21 <1 <1 33 <1 275 <50 <1 106 <5 150 0.26 5.42 <1 1.57 298 <1 44.5 632 <0.05 09/13/2016 7.6 2.44 226 38 <1 <1 45 <1 226 <50 <1 104 <5 150 2.1 7.73 <1 <1 186 1 <1 40.4 405 <0.05 01/25/2017 6.9 0.63 198 60 <1 <1 29 <1 198 <50 <1 108 M4 <5 190 12.2 14.8 <1 1.13 193 1 <1 1 39.7 M4 305 <0.05 P:\Duke Energy Progress.1026\Statistics_CAMA\BTVReports for CSAs\Roxboro\DRAFT\Tables\Table 2- Background Groundwater Dataset_ROX.xlsx Page 1 of 6 Analytical Parameter Methane Molybdenum Nickel Reporting Units ug/L ug/L ug/L 15A NCAC 02L Standard NE NE 100 Sample ID Sample Collection Date Transition Zone BG-01 11/30/2010 - - <5 BG-01 04/20/2011 - - 17.4 BG-01 07/13/2011 - - 45.5 - BG-01 11/02/2011 - - 12 BG-01 04/02/2012 - - <5 BG-01 07/11/2012 - - <5 BG-01 11/06/2012 - - 6.2 BG-01 04/08/2013 - - <5 BG-01 07/08/2013 - - 6 BG-01 11/11/2013 - - <5 BG-01 04/03/2014 - - <5 BG-01 07/15/2014 - - <5 BG-01 11/12/2014 - - 7 BG-01 04/16/2015 - 3.04 <5 BG-01 09/16/2015 <10 <1 1.96 BG 01 12/es/291-5 ---- <}B 9.65 33 BG-01 01/05/2016 <10 <1 2.96 BG-01 04/07/2016 <10 <1 5 BG-01 07/12/2016 <10 P2,CL <1 <5 BG-01 09/08/2016 <10 <1 1.91 BGG 91 --• --• 29-- - f1 <5 BG-01 11/10/2016 <10 N2 <1 2.59 BG-01 11/16/2016 - - - BG-01 01/26/2017 <10 N2 <1 1.61 MW-15D 05/30/2015 <10 1.11 20.8 MW-15D 09/12/2015 <10 <1 16.7 --•__,-___ ge.5 i3..3 MW-15D 01/05/2016 <10 <1 15.2 MW-15D 06/23/2016 <10 <1 11.5 ,- W 15o ^ v �B E1 ii.9 MW-15D 09/08/2016 <10 <1 10.9 MW-15D 11/09/2016 <10 N2 1.56 11.1 MW-15D 01/25/2017 <10 N2 1.78 9.12 Mw i8D 12/06/2015 E1B 8.4 4 MW-18D 01/05/2016 <10 6.08 <1 w i8D 06/23/2919 �1B 7.03 2.96 MW-18D 07/14/2016 <10 1.44 4.13 MW-18D 09/13/2016 <10 4.17 <1 MW-18D 01/25/2017 <10 N2 34.9 <1 TABLE 2 BACKGROUND GROUNDWATER RESULTS THROUGH JANUARY 2017 ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Nitrate + Potassium Selenium Sodium Strontium Sulfate Nitrite mg-N/L mg/L ug/L mg/L ug/L mg/L 11 NE 20 NE NE 250 Analytical Results Total Total Organic Sulfide Thallium Dissolved Carbon Vanadium Zinc Solids mg/L ug/L mg/L mg/L ug/L ug/L NE 0.2* 500 NE 0.3* 1000 Radium (Total) pCi/L NE Uranium (Total) ug/mL NE - - - - 12.5 - <0.1 299 - - 12.3 --- --- - 11.7 - <0.1 282 - - i .9 --- --- - 11.6 B - <0.1 248 B - - <10 --- --- - - F1B - - 12.4 - <0.1 263 B - - <10 --- --- - - f1B - - 11.7 - <0.1 298 - - <10 --- -- - - F14 - - 14.2 - <0.1 312 - - <10 --- --- - - 14.3 - <0.1 300 - - <10 --- --- - - <1 - - 11 - <0.2 310 - - <5 --- --- - - <1 - - 12 - <0.2 330 - - <5 --- --- - - <1 - - 12 - <0.2 320 - - 12 --- --- - - <1 - - 13 - <0.2 320 - - <5 --- --- - - <1 - - 14 - <0.2 330 - - <5 --- --- - - <1 - - 13 - <0.2 310 - - 11 --- --- - 3.44 3.57 35.4 - 40 - <0.2 370 - - 7 --- --- 1.9 1.52 1.44 30.5 414 27 <0.1 9.23i 320 0.672 22.7 14 --- --- 23 <5 3:2 32. i 449 29% < 1 re.1 331 <4 445 -<-1B 2.6 1.87 1.01 31.6 445 23 <0.1 <0.2 350 0.579 17.5 <5 --- --- 2.7 1.65 1.78 31.5 436 24 <0.1 <0.2 330 0.704 24.4 <5 5.45 0.000661 2.6 1.94 <1 31.8 442 21 <0.1 <0.2 330 0.682 18.3 <5 2.23 0.000674 2.6 1.79 <1 30.4 443 19 <0.1 <0.2 330 0.73 19.8 6 2.14 0.000637 - 4-86 32. i 442 29 - �0.2 349 - 38.8 - - 2.3 1.92 <1 30.3 457 19 <0.1 <0.2 340 0.764 15.8 <5 --- --- - - - - - - - - - - - - 2 0.000624 2.4 1.81 <1 30.8 456 18 <0.1 <0.2 320 0.735 18.7 <5 2 0.00035 2.9 1.09 <1 28.4 243 29 <0.1 <0.2 410 1.1 4.96 <5 --- --- 3.4 1.11 <1 29.2 241 28 <0.1 <0.2 400 0.925 7.66 <5 --- --- 33 <5 <e.5 29.2 24B 24.3 E9.1 <0.1 424 4.1 6 5- 3 <1 <1 26.3 231 24 <0.1 M1 <0.2 430 0.935 8.03 <5 --- --- 3.6 1.05 <1 28.9 239 29 <0.1 <0.2 430 1.1 9.15 <5 2 0.000823 3-5 3$8 <--l- 30.4 24 & 31 E-0.1 Q.2 428 4-1 9.56 <5 0.000855 3 1.04 <1 28.1 241 29 <0.1 <0.2 410 1 9.36 <5 3.762 0.000831 3.2 1.02 <1 27.1 242 30 <0.1 <0.2 400 H1 1 9.73 <5 1.773 0.000915 3.4 1.11 <1 28.4 246 29 <0.1 <0.2 420 1.1 9.4 132 <5 1.221 0.000898 0.2-7 5.48 ! 1-.-2 32.6 578 45.1 <0.1 <.1 554 2.1 R4 4-.7 -- a - - 0.198 2.96 1.64 21.9 629 39 <0.1 <0.2 610 2.4 1.1 8 --- --- 0.207 4.12 1.25 27.5 7-6-7 37 Q.1 <.2 64G 3.8 3.33 2i.2 0.00449 0.102 4.28 <1 27.9 730 37 <0.1 <0.2 540 1.9 0.551 <5 3.36 0.00516 0.125 3.87 <1 25.8 760 31 <0.1 <0.2 540 1.7 1.23 <5 2.183 0.00396 0.209 4.13 <1 28.3 767 33 <0.1 <0.2 600 1.7 1.35 132 <5 1.535 0.00402 P:\Duke Energy Progress.1026\Statistics_CAMA\BTVReports for CSAs\Roxboro\DRAFT\Tables\Table 2- Background Groundwater Dataset_ROX.xlsx Page 2 of 6 TABLE 2 BACKGROUND GROUNDWATER RESULTS THROUGH JANUARY 2017 ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Analytical Parameter pH Turbidity Alkalinity Aluminum Antimony Arsenic Barium Beryllium Bi- carbonate Alkalinity Boron Cadmium Calcium Carbonate Alkalinity Chloride Chromium (VI) Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Reporting Units S.U. NTUs mg/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L mg/L mg/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L 15A NCAC 02L Standard 6.5-8.5 NE NE NE 1* 10 700 4* NE 700 2 NE NE 250 10 10 1* 1000 300 15 NE 50 1 Sample ID Sample Collection Date Field Parameters Analytical Results Bedrock BG-01BR 06/10/2015 6.8 8.4 240 174 <1 <1 21 <1 240 <50 <1 65.5 <10 15 - <1 1.44 <1 225 <1 16.8 690 <0.05 BG-01BR 07/09/2015 6.9 5.6 - - - - - - - - - - - - - - - - - - - - - BG-01BR 09/12/2015 7.0 2.3 230 19 <1 <1 27 <1 230 <50 <1 58.1 <10 13 - <1 <1 <1 374 <1 14.4 614 <0.05 BG 0113 12 9:5 ---- 8 5.83 234 B8 <9.5 30 �EO.2 234 <39 FB:98 39.3 <3 ii.7 FB:93 8.71 �E 9. S _<4 389 �Ee.f 34.6 429 EO.2 BG-01BR 01/05/2016 6.8 7.91 227 118 <1 <1 33 <1 227 <50 <1 58.2 <5 12 <0.03 1.96 <1 <1 375 <1 13.5 445 <0.05 BG-01BR 04/07/2016 6.9 9.86 259 19 <1 <1 29 <1 259 <50 <1 60.3 <5 13 0.035 <1 <1 <1 139 <1 14.3 398 <0.05 BG-01BR 07/14/2016 6.9 9.78 236 181 <1 <1 37 <1 236 <50 <1 61.3 <5 14 <0.03 2.15 <1 1.27 460 <1 13.8 473 <0.05 96 BI BR 0 0 Fro 8.68 2-3-5 74 -<4- � -33 23-S <S9 -<4- .7 P4 4 <S 4-2 0.864 3.89 � _<4- 493 _<4- 34.3 43-1 Q.05 5 BG-01BR 11/09/2016 6.8 9.51 235 19 <1 <1 31 <1 235 <50 <1 58.9 <5 13 4 2 <1 <1 <1 52 <1 14.5 341 <0.05 13G-0113R 01/25/2017 6.9 4.77 250 12 <1 <1 33 <1 250 <50 <1 60.9 <5 13 0.086 <1 <1 <1 43 <1 15.3 369 <0.05 MW-1013R 05/27/2015 7.1 2.5 240 24 <1 <1 93 <1 240 <50 <1 60 <10 17 - <1 8.2 4. r57 33 <1 20.6 478 <0.05 MW-1013R 09/12/2015 7.0 1.18 260 25 <1 <1 107 <1 260 <50 <1 58.6 <10 16 - <1 5.97 <1 46 <1 20.8 840 <0.05 12 _ , _--_ 7.4 9.65 2-54 43 E4- 4&-7 234 <59 EI- 57.f E5 - E9.93 <4 S. i 5 -.4 6§ E} 49 834 Q.05 MW-1013R 01/06/2016 6.8 0.61 250 8 <1 <1 120 <1 250 <50 <1 57.7 <5 18 <0.03 <1 6.38 <1 87 <1 19.8 752 <0.05 MW-1013R 04/07/2016 7.0 0.39 268 6 <1 <1 112 <1 268 <50 <1 52.4 <5 18 <0.03 <1 6.45 <1 91 <1 18.1 481 <0.05 MW-1013R 07/14/2016 7.1 0.61 264 <5 <1 <1 131 <1 264 <50 <1 57.4 <5 19 <0.03 <1 6.4 <1 50 <1 19.7 518 <0.05 MW-10BR 09/14/2016 7A S 1.99 240 6 <1 <1 135 <1 240 <50 <1 52.6 <5 18 0.096 M1 <1 33-8 <1 54 <1 18.3 446 <0.05 . r., 10B 'pro 7,2 3.73 236 8 <47 <47 42B 236 <S9 <47 49.6 <3 49 4_1 <47 i3 1 <47 34 <47 37.7 36--2 <0.05 MW-10BR 01/26/2017 7.0 0.43 249 7 <1 <1 145 <1 249 <50 <1 51 <5 18 0.15 <1 33-3 <1 17 <1 18.1 333 <0.05 MW-14BR 06/10/2015 7.0 4 250 12 <1 <1 32 <1 250 <50 <1 71.2 <10 40 - <1 1.1 1.69 898 <1 29.3 328 <0.05 12 -_, _--_ 7.4 6.28 246 E}$9 EB:S EB:S 34 2-7-6 E69 EB 98 74.3 E3 4i.9 Q.93 2-8 9.94 4-9 2299 EBB z�.8 44B E9.2 MW-14BR 01/06/2016 7.0 6.18 269 57 <1 <1 38 <1 269 <50 <1 67.6 <5 43 <0.03 1.98 1.25 2.16 1780 <1 27.2 291 <0.05 MW-14BR 04/08/2016 7.2 8.75 273 15 <1 <1 32 <1 273 <50 <1 65.3 <5 41 <0.03 M1 2.11 1.86 <1 1160 <1 29.4 286 <0.05 MW-14BR 07/14/2016 7.3 9.5 293 53 <1 <1 37 <1 293 <50 <1 69.2 <5 42 <0.03 4&-9 <1 <1 1150 <1 28.6 281 <0.05 9,98,29-6 7.2 8.;Z8 272 69 <4 33 272 E39 <4 64.6 <5 41- E9.93 3.41 3.89 4:69 4969 E4 273 339 Q.05 MW-14BR 11/10/2016 7A S 5.88 273 19 <1 <1 34 <1 273 <50 <1 64.4 <5 40 43 4.16 3.13 <1 1340 <1 26 348 <0.05 MW-14BR 01/26/2017 7.2 3.75 282 16 <1 <1 33 <1 282 <50 <1 66.7 <5 41 0.22 <1 2.02 <1 1220 <1 29.7 304 <0.05 MW-15BR 09/12/2015 8.3 3 170 377 <1 <1 19 <1 170 <50 <1 48.7 <10 34 - <1 <1 <1 456 <1 10.6 30 <0.05 -2-_,_--_ 83 249 449 299 EB:S 9.5 46 E .2 444 E69 E9$$ 4i.4 E3 33-.2 E9$3 E9.6 Q.5 <4 EE}4 8.52 49 E9.2 MW-15BR 01/05/2016 7.6 2.26 145 164 <1 <1 16 <1 145 <50 <1 38 <5 34 <0.03 <1 <1 <1 262 <1 7.76 10 <0.05 MW-15BR 04/07/2016 7.7 7.3 178 343 <1 <1 18 <1 178 <50 <1 48.1 <5 37 <0.03 1.01 <1 <1 637 <1 8.44 29 <0.05 MW-15BR 07/12/2016 8.0 2.15 168 131 <1 <1 15 <1 168 <50 <1 46.5 <5 37 0.038 3.62 <1 <1 399 <1 8.71 25 <0.05 _, _ _, _ _ - _ 713 ;Z.93 489 48 <4 46 484 E39 <4 343 <5 _37z 9.933 pqj -<4 -<4 -.4 369 E4 49.8 3-5 Q.05 MW-15BR 11/09/2016 7.7 4.66 243 169 <1 <1 19 <1 240 <50 <1 70.8 M4 <5 38 0.67 1.49 <1 <1 982 <1 16.6 47 <0.05 MW-15BR 01/25/2017 7.6 4.16 217 146 <1 <1 20 <1 217 <50 <1 65.5 <5 39 0.19 1.07 <1 <1 838 <1 15.2 49 <0.05 MW-18BR 06/02/2015 7.5 9.6 180 55 <1 <1 77 <1 180 <50 <1 95.4 <10 120 - <1 2&4 <1 95 <1 19.7 789 <0.05 MW-18BR 09/14/2015 8.0 6.55 140 44 <1 <1 52 <1 140 <50 <1 82 <10 130 - 2.23 1.03 <1 363 <1 19.5 475 <0.05 P:\Duke Energy Progress.1026\Statistics_CAMA\BTVReports for CSAs\Roxboro\DRAFT\Tables\Table 2- Background Groundwater Dataset_ROX.xlsx Page 3 of 6 TABLE 2 BACKGROUND GROUNDWATER RESULTS THROUGH JANUARY 2017 ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Analytical Parameter Methane Molybdenum Nickel Nitrate + Nitrite Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Vanadium Zinc Radium (Total) Uranium (Total) Reporting Units ug/L ug/L ug/L mg-N/L mg/L ug/L mg/L ug/L mg/L mg/L ug/L mg/L mg/L ug/L ug/L pCi/L ug/mL 15A NCAC 02L Standard NE NE 100 11 NE 20 NE NE 250 NE 0.2* 500 NE 0.3* 1000 NE NE Sample ID Sample Collection Date Analytical Results Bedrock BG-0113R 06/10/2015 <10 16.5 1.86 8333 5.36 <1 36.4 183 28 <0.2 <0.2 350 1.3 1.94 --- --- 13G-0113R 07/09/2015 - - - - - - - - - - - - - - - 2.41 0.00137 BG-0113R 09/12/2015 <10 5.36 1.3 0.089 5.51 <1 24.6 160 20 <0.1 <0.2 300 1 0.425 23 --- --- BG 0113 __• __• ____ E}B 3.2 4- 9.34 543 �E-&§ 2-3 3-68 33 f E0.1 297 33.6 -<4 BG-0113R 01/05/2016 <10 9.26 2.1 0.295 5.09 <1 21.9 163 21 <0.1 <0.2 330 0.693 1.25 --- - - BG-01BR 04/07/2016 29.6 7.42 1.45 0.192 5.18 <1 23.5 166 20 <0.1 <0.2 300 0.703 1.23 6 346 0.001082 BG-01BR 07/14/2016 1120 4.18 1.08 0.229 5.54 <1 20.5 162 20 <0.1 <0.2 300 0.795 1.67 7 2 0.001111 BG 01B 0 08/20iv 618 7.38 33AS 0.39 5.23 22.4 r 4 ill -20 <0.1 Q.2 2-619 8777 -1-.7 <- 2 0�4�73 BG-01BR 11/09/2016 569 N2 5.11 1.34 0.381 5.1 <1 21.8 169 19 <0.1 <0.2 330 0.773 1.79 <5 2.09 0.00099 13G-0113R 01/25/2017 367 N2 7.57 1.1 0.43 5.29 <1 24.2 183 19 <0.1 <0.2 330 0.849 2.34 132 <5 2 0.00137 MW-lOBR 05/27/2015 <10 24.1 2.44 0.225 9.05 <1 36.5 194 40 <0.1 <0.2 350 1.1 2.09 <5 --- --- MW-10BR 09/12/2015 <10 24.3 <1 0.083 9.28 <1 37.6 201 40 <0.1 <0.2 350 1 1.34 <5 --- --- _ _• _ • _ _ _ _ E1B 233 Fl 9. 97z9 329 32•.3 496 44 E 9.2 E 0.2 339 9.992 4�3 F - MW-10BR 01/06/2016 <10 22.7 <1 0.049 9.21 <1 36.7 196 42 <0.1 <0.2 370 0.902 1.28 <5 --- --- MW-10BR 04/07/2016 <10 19 <1 0.136 8.41 <1 37.2 181 41 <0.1 <0.2 330 0.952 1.51 33 3.771 0.00324 MW-10BR 07/14/2016 <10 19.2 <1 0.082 10 <1 40 191 41 <0.1 <0.2 340 0.993 1.68 <5 2.49 0.00316 MW-10BR 09/14/2016 <10 18.4 <1 0.152 9.11 <1 36.7 188 41 <0.1 <0.2 3229 1.1 2.04 <5 1.621 0.00293 W 10B/^9'2() 9 <10 N2 19.6 El 0.2-51 7.5l Fl 35.6 3-&9 42 <0.1 .2 238 0.992 2.68 <3 3.736 0.08383 MW-10BR 01/26/2017 <10 N2 16.3 <1 0.213 8.1 <1 37 176 40 <0.1 <0.2 330 0.966 2.91 <5 2 0.00324 MW-14BR 06/10/2015 <10 1.43 <1 <0.01 5.52 <1 22 165 15 <0.1 <0.2 370 1 0.444 34 --- --- --•__•-_-_ 22.8 4- 23 E9.92 7.93 g&5 23-4 484 3i.3 E9.1 E9.1 338 4.4 fl 44 - - MW-14BR 01/06/2016 25.8 1.44 1.8 0.014 7.19 <1 22.1 175 12 <0.1 <0.2 390 0.943 0.362 45 --- --- MW-14BR 04/08/2016 <10 1.39 2.72 <0.01 6.53 <1 22.2 159 13 <0.1 <0.2 380 0.944 <0.3 5 s'- 0.000298 MW-14BR 07/14/2016 <10 4.84 <1 <0.01 8.52 <1 24.7 181 11 <0.1 <0.2 360 1.1 0.745 12 3.01 0.000313 _ • _ _• _ _ _ _ 446 3:49 2.96 E 9.91 7.2-3 22.7 326 43 E9.1 Q.2 364 4-4- 9-423 42 8 B89398 MW-14BR 11/10/2016 129 N2 1.44 4.92 <0.01 M2 6.7 <1 21.6 175 12 <0.1 <0.2 360 1 132 <0.3 7 2.18 0.0003 MW-14BR 01/26/2017 71.3 N2 1.53 1.57 <0.01 6.52 <1 22.2 165 13 <0.1 <0.2 350 1.1 0.43 <5 2.076 0.000332 MW-15BR 09/12/2015 <10 10.8 1.42 0.027 7.88 <1 32.9 110 26 <0.1 <0.2 300 1.6 0.369 <5 --- --- 12,195,129475 E1B 4� 9.61 Q.92 844 g9.5 364 99 i9.7 9.428 E9.1 23� 4-.;L -<1- MW-15BR 01/05/2016 <10 13.8 <1 0.01 7.58 <1 35.3 92 22 <0.1 <0.2 280 0.694 <0.3 <5 --- --- MW-15BR 04/07/2016 <10 9.14 1.24 <0.01 6.05 <1 34.1 72 25 <0.1 <0.2 300 0.755 0.441 <5 3.64 0.00062 MW-15BR 07/12/2016 <10 20.9 <1 <0.01 5.51 <1 41.9 64 30 <0.1 <0.2 300 0.77 0.354 <5 2 0.000435 _ • _ _, _ _ - _ 1B 9 q;z � 1 f .91 5.03 32.6 2g 22 9.36 Q.2 33A &753 Q.3 2 9-999633 MW-15BR 11/09/2016 <10 N2 16.8 1.86 <0.01 4.59 <1 24.9 140 28 <0.1 <0.2 360 0.782 0.488 <5 2.16 0.000895 MW-15BR 01/25/2017 <10 N2 11.4 1.18 <0.01 5.03 <1 28.2 141 29 <0.1 <0.2 350 0.776 0.456 132 <5 1.611 0.000685 MW-18BR 06/02/2015 14 7.62 <1 <0.01 4.59 <1 19 224 16 <0.1 <0.2 530 1.7 0.931 --- --- MW-18BR 09/14/2015 21 10.5 <1 <0.01 5.75 <1 20 209 3.7 -*G-2 <0.2 540 11 <0.3 <5 --- --- P:\Duke Energy Progress.1026\Statistics_CAMA\BTVReports for CSAs\Roxboro\DRAFT\Tables\Table 2- Background Groundwater Dataset_ROX.xlsx Page 4 of 6 TABLE 2 BACKGROUND GROUNDWATER RESULTS THROUGH JANUARY 2017 ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Analytical Parameter pH Turbidity Alkalinity Aluminum Antimony Arsenic Barium Beryllium Bi- carbonate Alkalinity Boron Cadmium Calcium Carbonate Alkalinity Chloride Chromium (VI) Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Reporting Units S.U. NTUs mg/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L mg/L mg/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L 15A NCAC 02L Standard 6.5-8.5 NE NE NE 1* 10 700 4* NE 700 2 NE NE 250 10 10 1* 1000 300 15 NE 50 1 Sample ID Sample Collection Date Field Parameters Analytical Results Bedrock Continued --• -_, _--_ 1L. 9 7Z.64 4-68 49Q E0.5 49 E9.2 4-69 ESA Q.98 89.9999i F5 4-24 E9.93 9.99 4-3 E} <94 -28 6H9 EO% MW-18BR 01/05/2016 7.6 5.56 195 71 <1 <1 62 <1 195 <50 <1 94.5 <5 120 <0.03 4.24 1.63 <1 1260 <1 21.7 874 <0.05 MW-18BR 04/08/2016 8.3 4.68 191 10 <1 <1 51 <1 191 <50 <1 89.3 <5 120 <0.03 <1 <1 <1 1060 <1 22.7 819 <0.05 MW-18BR 11/09/2016 7.7 1.26 211 7 <1 <1 47 <1 211 <50 <1 97.2 <5 120 4:4 <1 <1 <1 1510 <1 22.1 871 <0.05 MW-18BR 01/25/2017 7.7 0.88 183 9 <1 <1 50 <1 183 1 <50 <1 89.7 <5 140 <1 I <1 <1 1250 <1 22.9 902 <0.05 MW-19BRL 06/16/2016 7.5 6.34 190 M1 120 <1 1.39 79 <1 190 <50 <1 58.1 <5 59 <0.03 <1 2.03 <1 2890 <1 13 1180 <0.05 PqW igBnz •- •---- 1L.2 9.98 2-34 4€4 _ 4 -2-Ej $5 2-34 EBB -<4 654 Bi E5 43 E9.93 -<4 4.z� i.ei 5939 E4 i4 42$B Q.95 MW-19BRL 09/28/2016 7.2 7.18 244 225 <1 2.39 73 <1 244 <50 <1 73.8 M4 <5 68 .3 <1 1.33 <1 6220 <1 14.3 M4 1050 <0.05 -, - -, _ - - _ -7-.2 r. S 47L6 4.5 E4- 2.77Z §✓ 2-7-6 E4G EI- 7Z8.7Z Bi E5 4$ Q.5 93 4. B4 E} E} S(} E} }S-Bi 4$iB Q.9 5 MW 19BRL 01/26/2017 7.2 2.64 284 44 <1 2.9 60 <1 284 <50 <1 92.3 <5 74 0. <1 <1 <1 5570 <1 17 1110 <0.05 Prepared by:JHG Checked by: RHJ Notes: 34 Indicates value omitted from dataset. - Indicates parameter not measured or analyzed. Indicates data removed/identified as an outlier Indicates data removed due to autocorrelation < - concentration not detected at or above the adjusted reporting limit. pCi/L - picocuries per liter mg - N/L - Milligrams nitrogen per liter S.U. - Standard Unit mg/L - Milligrams per liter ug/L - Micrograms per liter NE - Not established ug/mL - micrograms per milliliter NTU - Nephelometric turbidity unit * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. B - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to blank contamination. Bl - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample was greater than 10X the concentration in the method blank. Analyte concentration in sample is not affected by blank contamination. 132 - Target analyte was detected in blank(s) at a concentration greater than 1/2 the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. CH - The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. CL - The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased low. D3 - Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H1 - Analysis conducted outside the EPA method holding time. j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. L3 - Analyte recovery in the laboratory control sample (LCS) exceeded quality control (QC) limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. M1 - Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable. M2 - Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. M4 - The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. M6 - Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 - The lab does not hold accreditation for this parameter. P2 - Re -extraction or re -analysis could not be performed due to insufficient sample amount. RI - Relative Percent Difference (RPD) value was outside control limits. S - Associated calibration check did not meet specified criteria. P:\Duke Energy Progress.1026\Statistics_CAMA\BTVReports for CSAs\Roxboro\DRAFT\Tables\Table 2- Background Groundwater Dataset_ROX.xlsx Page 5 of 6 TABLE 2 BACKGROUND GROUNDWATER RESULTS THROUGH JANUARY 2017 ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Analytical Parameter Methane Molybdenum Nickel Nitrate + Nitrite Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Vanadium Zinc Radium (Total) Uranium (Total) Reporting Units ug/L ug/L ug/L mg-N/L mg/L ug/L mg/L ug/L mg/L mg/L ug/L mg/L mg/L ug/L ug/L pCi/L ug/mL 15A NCAC 02L Standard NE NE 100 11 NE 20 NE NE 250 NE 0.2* 500 NE 0.3* 1000 NE NE Sample ID Sample Collection Date Analytical Results Bedrock Continued --• -_, _-__ i2.3 63 8.4 E9.92 _3 .5 444 2-3G E1- E94 443 8.4 _<4 f1G - - MW-18BR 01/05/2016 11.7 4.92 2.11 <0.01 4.52 <1 18.8 232 5 <0.1 <0.2 530 3 <0.3 7 --- --- MW-18BR 04/08/2016 <10 2.98 <1 <0.01 10.4 <1 20.3 213 11 <0.1 <0.2 480 3.6 <0.3 <5 6.14 0.000574 MW-18BR 11/09/2016 17.7 N2 3.23 <1 <0.01 6.1 <1 17.4 249 13 <0.1 <0.2 530 1.8 <0.3 <5 1.703 0.001134 MW-18BR 01/25/2017 173 N2 4.67 <1 <0.01 8.74 <1 1 19.9 252 4.5 <0.1 <0.2 460 3.1 <0.3 132 1<5 1.344 0.00032 MW-19BRL 06/16/2016 -584 5.08 <1 <0.01 6.49 <1 36.7 189 7.7 <0.1 <0.2 380 -2-9 0.602 <5 2.39 0.000482 pqW 19BR6 • - • ---- 5.98 � fB 91 ;Z.31 34 442 9.83 E94 Q.2 388 �6 8.74 4 8 888234 MW-19BRL 09/28/2016 37200 5.41 <1 <0.01 6.46 <1 34.1 200 0.18 <0.1 <0.2 430 9.6 0.75 <5 1.517 0.00035 --• --, _--_ 8.54 -*4- fB 92 3.96 39.2 B2 2-14 23 1 Q.1 9.2 44B 3.3 9.488 i.68 8-898387Z MW-19BRL 01/26/2017 7.39 <1 <0.01 6.28 <1 31.1 1 230 1 5 1 <0.1 <0.2 440 1.9 <0.3 <5 2.84 0.00035 Prepared by: JHG Checked by: CDE Notes: 34 Indicates value omitted from dataset. - Indicates parameter not measured or analyzed. Indicates data removed/identified as an outlier Fmm� Indicates data removed due to autocorrelation < - concentration not detected at or above the adjusted reporting limit. pCi/L - picocuries per liter mg - N/L - Milligrams nitrogen per liter S.U. - Standard Unit mg/L - Milligrams per liter ug/L - Micrograms per liter NE - Not established ug/mL - micrograms per milliliter NTU - Nephelometric turbidity unit * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. B - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to blank contamination. Bl - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample was greater than 10X the concentration in the method blank. Analyte concentration in sample is not affected by blank contamination. 132 - Target analyte was detected in blank(s) at a concentration greater than 1/2 the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. CH - The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. CL - The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased low. D3 - Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H1 - Analysis conducted outside the EPA method holding time. j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. L3 - Analyte recovery in the laboratory control sample (LCS) exceeded quality control (QC) limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. M1 - Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable. M2 - Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. M4 - The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. M6 - Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 - The lab does not hold accreditation for this parameter. P2 - Re -extraction or re -analysis could not be performed due to insufficient sample amount. RI - Relative Percent Difference (RPD) value was outside control limits. S - Associated calibration check did not meet specified criteria. P:\Duke Energy Progress.1026\Statistics_CAMA\BTVReports for CSAs\Roxboro\DRAFT\Tables\Table 2- Background Groundwater Dataset_ROX.xlsx Page 6 of 6 TABLE 3 UNSATURATED BACKGROUND SOIL DATA SUMMARY ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Analytical Parameter pH Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel itrate N) Potassium Selenium Sodium Strontium Sulfate Thallium Vanadium Zinc Reporting Units S.U. mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg PSRG Protection of Groundwater NE NE 0.9 5.8 580 63 45 3 NE NE 360000 0.9 700 150 270 NE 65 1 NE 130 NE NE 2.1 NE NE NE 0.28 6 1200 Sample ID Sample Collection Date Analytical Results MW-08 (14-16) 04/27/2015 7.6 4110 --- ESz 49.3 0.23 j E13.1 E0-63 1830 E263 0.82 j 4.6 j 2.4 10200 <5.2 2910 222 <0.0086 <2.6 1.4 E26.3 836 --- 221 j 13.7 E263 --- 21.6 41.4 MW-08(21-23) 04/27/2015 7.3 14800 --- F5.7 128 i-4- E142 E9.63 ii200 E283 il-4 0.78j 20500 6 <0.0092 <2.8 34-7 5680 --- 211j E283 --- 43.1 MW-13BR (22-24) 03/04/2015 8.0 6730 --- E1.2 102 0.14 L 9-' E814 3898 E299 8.7 8.1 41 13100 <1.2 4020 132 <0.01 <0.6 4.4 E29.4 2320 389 13.2 E299 --- 59.3 25.1 MW-14BR(1-1.25) 02/25/2015 -:: 11000 --- 71.3 0.14j <3.1 E9.15 593 E300 4.1 5.3 11.1 16100 4.8 4960 79.4 0.011 <0.62 3.4 E30 1110 183 20.4 E300 --- 45.2 26.6 MW-14BR(31-31.5) 02/25/2015 8.8 8590 --- <1 170 0.11j <2.6 E812 2810 E254 9 8.6 23.1 12600 <1 6490 238 <0.0084 <0.51 6.5 E25..4 4830 <1 383 22.4 E254 --- 31 37.9 MW-14BR(37.5-38) 02/25/2015 8.0 12300 --- <1.1 198 0.25 <2.8 E0:}3 6340 E286 54 17.7 15200 <1.1 290 <0.0089 <0.55 5-33.7 E28.6 3860 <1.1 174 E286 --- 33.3 49.6 MW-17 (29-31) 04/21/2015 8.4 8530 --- 84.3 0.32 E861 5300 E250 4.8 5.7 5.7 19800 <5.1 5920 315 <0.0081 <2.5 7.9 E25 857 --- 183 j 18.8 E258 --- 23 56.4 MW-18 (31-33) 05/16/2015 7.3 3420 --- --- 31.3 0.22 j E0.2 581 E292 1.9 --- 4.8 7000 <6 686 353 <0.0092 <3 <1.5 E29.2 731 --- 222 j 8 E292 --- 3.1 j 18.7 MW-18 (37-38) 05/16/2015 7.3 3600 --- --- 18.4 0.18 j F<2.:5 Eg,�3 670 1.3 j --- 22.4 3410 <6.1 708 175 <0.0098 <3.1 <1.5 E29.6 486 --- <306 6.7 E296 --- --- 16.2 BGSB-02(4-5) 07/18/2017 6.78 31000 M <0.48 M 1.1 110 M 0.51 <0.024 2000 M 3j 39-P9 74 -. 5.1 ttd09 200 M <0.092 0.63 j,M i8-M 0.16j 1900 M 1.2j 790 29 M <11 0.093j 51 M BGSB-02(7-8) 07/18/2017 7.43 9000 <0.44 0.5 33 0.29 <0.022 460 7.2j 4.5 5.5 11 7100 2.3 1600 46 <0.087 <2 2.1 0.12j 540 0.3j 220j 7.9 <11 0.062j 31 11 BGSB-14(2-3) 07/19/2017 6.03 25000 <0.53 1.1 48 0.4 2.7 <0.026 720 6j 22 3.9 15 21000 960 78 0.03j 0.58j 3.3 0.32 260j 0.31j E530 11 64 19 BGSB-14(4-5) 07/19/2017 5.4 27000 <0.53 0.39j 97 0.26 1.2j <0.026 590 9 6.6 69 22000 4.5 5100 97 <0.084 0.61j 4.2 0.47 1600 0.53j 180j 16 IL 0.049j 54 31 BGSB-14(7-8) 07/19/2017 6.1 24000 <0.52 0.45j 160 0.34 1.1j <0.026 1100 2.8j 7.4 8.5 32 19000 2.1 5400 120 <0.089 <2 4.4 0.066j 3000 0.57j 320 31 <11 0.1j 48 31 BGSB-14(9-10) 07/19/2017 6.54 13000 <0.47 0.13j 110 0.59 <2.1 <0.024 2000 2.2j 3.8 8 69 15000 1.1 4300 110 <0.084 <1.7 3.4 0.095j 2300 0.74j 330 29 <10 0.04j 45 34 BGSB-18(2-3) 07/19/2017 7.18 18000 <0.5 0.91 48 0.31 <2.7 <0.025 610 7.1j i5 5 14 15000 5.3 1800 47 <0.08 <2.1 4 0.28 440 0.65j 110j 9.9 7.6j 0.1j 47 23 BGSB-18(4-5) 07/19/2017 7.11 9300 0.21 j,B 0.49 23 0.37 <1.9 <0.019 230 1.8j 6.9 2.2 10 9700 3.6 950 39 <0.086 <1.5 1.3j 0.057j 430 0.37j 120j 4.6 <11 0.055j 19 16 BGSB-18(7-8) 07/19/2017 6.98 11000 0.096 j,B 0.58 29 0.55 <2.9 <0.02 580 2.2j 4.3 3.3 13 12000 5 1400 82 <0.088 <2.3 1.6j 0.071j 560 0. 38j 210j 9 <12 0.05j 20 39 BGSB-18(9-10) 07/19/2017 7.69 8400 <0.47 0.71 22 <2.4 <0.024 660 5.3j 5.2 4.3 19 9900 3.4 960 73 <0.076 <1.9 1.8j 0.14j 360 0.74j 270 8.6 <11 0.045j 30 40 BGSB-18 (12-13) 07/19/2017 8.76 4600 <0.4 0.24 j 26 0.4 <2.1 <0.02 480 2.7 j 1.8 1.6 5.6 7200 2.7 980 61 <0.084 <1.7 <1.7 0.065 j 600 1 150 j 10 <10 0.03 j 9.6 27 BGSB-112(2-3) 07/19/2017 5.53 28000 <0.59 0.44j 130 0.5 1.4j <0.03 160j 7.9j 4.3 4.6 38 21000 3.8 4000 160 <0.1 0.62j 1.7j 0.47 3000 0.35j 91j 7.7 13 0.1j 43 53 BGSB-112(4-5) 07/19/2017 5.65 31000 <0.56 0.6 120 0.57 1.3j <0.028 250j llj 4.1 29 21000 5.6 4100 360 <0.097 <2.1 1.9j 0.08j 2500 1.1j 130j 10 <12 0.083j 36 54 BGSB-112(7-8) 07/19/2017 5.3 16000 0.27 j,B 0.4j 77 <2.4 <0.024 460 45 4.1 8.7 60 14000 2.4 2700 110 <0.091 <1.9 2 0.35 1400 1.1j 98j 14 <11 0.047j 39 23 BGSB-112(9-10) 07/19/2017 7.63 21000 <0.56 0.42j 220 0.74 1.2j <0.028 1100 5.5j 2 _. 23000 1.9 5900 310 <0.095 <2.2 <2.2 0.064j 5500 0.99j 90j 21 <12 0.12j 36 43 BGSB-112(14-15) 07/19/2017 7.55 19000 <0.54 0.12j 130 0.71 <2.8 <0.027 1200 3.9j 7.3 8.9 6.6 17000 1.4 6600 230 <0.095 <2.2 3.3 0.054j 6500 0.33j 100j 23 <12 0.1j 37 36 BGSB-112 (19-20) 07/19/2017 6.42 14000 <0.43 0.2j 130 0.54 0.98j <0.022 850 1.3j 3 7.1 2.5 15000 1.2 5000 270 <0.083 <1.8 2.2 0.038j 5300 0.49j 96j 18 <11 0.11 32 35 Prepared by: JHG Checked by: BDR Notes: 54 - Indicates values omitted from dataset. --- - Value removed; non -detect concentration exceeding PSRG Protection of Groundwater. - Indicates data removed /identified as an outlier. < - concentration not detected at or above the adjusted reporting limit. B - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to blank contamination. j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. M - Matrix spike / matrix spike duplicate failure mg/kg - milligrams per kilogram NE - Not established PSRG Protection of Groundwater - NCDEQ IHSB Preliminary Soil Remediation Goals Table - October 2016 S.U. - Standard Units P:\Duke Energy Progress. 1026\Statistics_CAMA\BTV Reports for CSAs\Roxboro\DRAFT\Tables\Table 3 - Background Soil Dataset_ROX.xlsx Page 1 of 1 TABLE 4 STATISTICAL ANALYSIS RESULTS - TRANSITION ZONE ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Parameter Reporting Unit Nuber of Background Wells Number of Samples Number of NDs Percent NDs Distribution Coverage (%) Confidence Level (%) UTL PH S.U. 3 33 0 0 Non -Parametric 85 95 6.3 - 7.6 Alkalinity mg/L 3 19 0 0 Non -Parametric 85 95 244 Aluminum pg/L 3 31 1 3 Normal 95 95 807 Antimony pg/L 3 32 32 100 NA NA NA 1 Arsenic pg/L 3 25 25 100 NA NA NA 1 Barium pg/L 3 32 0 0 Non -Parametric 85 95 91 Beryllium pg/L 3 19 19 100 NA NA NA 1 Bicarbonate mg/L 3 19 0 0 Non -Parametric 85 95 244 Boron pg/L 3 32 32 100 NA NA NA 50 Cadmium pg/L 3 32 32 100 NA NA NA 1 Calcium mg/L 3 19 0 0 Non -Parametric 85 95 106 Carbonate mg/L 3 16 16 100 NA NA NA 5 Chloride mg/L 3 32 0 0 Non -Parametric 85 95 150 Chromium (VI) pg/L 3 15 0 0 Normal 95 95 16.1 Chromium pg/L 3 31 3 10 Normal 95 95 18.1 Cobalt pg/L 3 16 15 94 NA NA NA 1 Copper pg/L 3 32 19 59 Non -Parametric 85 95 10 Iron pg/L 3 31 0 0 Gamma 95 95 1173 Lead pg/L 3 25 25 100 NA NA NA 1 Magnesium mg/L 3 19 0 0 Non -Parametric 85 95 42.3 Manganese pg/L 3 32 0 0 Non -Parametric 85 95 405 Mercury pg/L 3 32 32 100 NA NA NA 0.05 Methane pg/L 3 18 18 100 NA NA NA 10 Molybdenum pg/L 3 18 11 61 Non -Parametric 85 95 4.17 Nickel pg/L 3 31 12 39 Normal 95 95 5.22 Nitrate + Nitrite mg-N/L 3 18 0 0 Non -Parametric 85 95 3.4 Potassium mg/L 3 19 1 5 Normal 95 95 4.69 Selenium pg/L 3 25 20 80 Non -Parametric 85 95 1.78 Sodium mg/L 3 19 0 0 Normal 95 95 36 Strontium pg/L 3 18 0 0 Non -Parametric 85 95 760 Sulfate mg/L 3 32 0 0 Non -Parametric 85 95 37 Sulfide mg/L 3 18 18 100 NA NA NA 0.1 TDS mg/L 3 32 0 0 Non -Parametric 85 95 540 Thallium pg/L 3 31 31 100 NA NA NA 0.2 TOC mg/L 3 18 0 0 Lognormal 95 95 2.72 Vanadium pg/L 3 18 0 0 Normal 95 95 30.2 Zinc pg/L 3 31 24 77 Non -Parametric 85 95 12 Radium (Total) pCi/L 3 12 0 0 Non -Parametric 85 95 5.45 Uranium (Total) pg/mL 3 12 0 0 Non -Parametric 85 95 0.00516 Prepared by:JHG Checked by: Notes: Background wells: BG-1, MW-15D, and MW-18D S.U. = Standard Units mg/L = milligrams per liter TDS = Total Dissolved Solids mg - N/L = Milligrams nitrogen per liter TOC = Total Organic Carbon NA = Not applicable; dataset contains >90 percent NDs pg/L = micrograms per liter NO = Non -detect concentration pg/mL = micrograms per milliliter pCi/L = picocuries per liter UTL = Upper Tolerance Limit Radium (Total) = Radium-226 and Radium-228 combined Uranium (Total) = Uranium-233, Uranium-234, Uranium-236, and Uranium-238 combined P:\Duke Energy Progress. 1026\Statistics_CAMA\BTV Reports for CSAs\Roxboro\DRAFT\Tables\ Table 4 - Statistical Analysis Results - Transition Zone_ROX.xlsx Page 1 of 1 TABLE 5 STATISTICAL ANALYSIS RESULTS - BEDROCK ZONE ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Parameter Reporting Unit Number of Background Wells Number of Samples Number of NDs Percent NDs Distribution Coverage (%) Confidence Level (%) UTL pH S.U. 6 36 0 0 Non -Parametric 85 95 6.8 - 8.3 Alkalinity mg/L 6 35 0 0 Normal 95 95 317 Aluminum pg/L 6 35 1 3 Gamma 95 95 378 Antimony pg/L 6 35 35 100 NA NA NA 1 Arsenic pg/L 6 35 32 91 NA NA NA 1 Barium pg/L 6 35 0 0 Lognormal 95 95 185 Beryllium pg/L 6 35 35 100 NA NA NA 1 Bicarbonate mg/L 6 35 0 0 Normal 95 95 317 Boron pg/L 6 35 35 100 NA NA NA 50 Cadmium pg/L 6 35 35 100 NA NA NA 1 Calcium mg/L 6 35 0 0 Gamma 95 95 102 Carbonate mg/L 6 35 35 100 NA NA NA 5 Chloride mg/L 6 35 0 0 Non -Parametric 85 95 120 Chromium (VI) pg/L 6 20 13 65 Non -Parametric 85 95 0.19 Chromium pg/L 6 34 23 68 Non -Parametric 85 95 3.61 Cobalt pg/L 6 32 17 53 Non -Parametric 85 95 6.4 Copper pg/L 6 34 31 91 NA NA NA 1 Iron pg/L 6 34 0 0 Gamma 95 95 4268 Lead pg/L 6 35 35 100 NA NA NA 1 Magnesium mg/L 6 35 0 0 Normal 95 95 31.5 Manganese pg/L 6 35 0 0 Normal 95 95 1198 Mercury pg/L 6 35 35 100 NA NA NA 0.05 Methane pg/L 6 32 20 63 Non -Parametric 85 95 367 Molybdenum pg/L 6 35 0 0 Gamma 95 95 35.2 Nickel pg/L 6 34 18 53 Non -Parametric 85 95 2.11 Nitrate + Nitrite mg-N/L 6 34 18 53 Non -Parametric 85 95 0.295 Potassium mg/L 6 35 0 0 Non -Parametric 85 95 9.28 Selenium pg/L 6 35 35 100 NA NA NA 1 Sodium mg/L 6 35 0 0 Non -Parametric 85 95 37.6 Strontium pg/L 6 35 0 0 Non -Parametric 85 95 232 Sulfate mg/L 6 35 0 0 Gamma 95 95 73.5 Sulfide mg/L 6 34 34 100 NA NA NA 0.1 TDS mg/L 6 34 0 0 Non -Parametric 85 95 530 Thallium pg/L 6 35 35 100 NA NA NA 0.2 TOC mg/L 6 34 0 0 Non -Parametric 85 95 3.6 Vanadium pg/L 6 35 9 26 Normal 95 95 2.5 Zinc pg/L 6 29 22 76 Non -Parametric 85 95 7 Radium (Total) pCi/L 6 21 0 0 Lognormal 95 95 5.21 Uranium (Total) pg/mL 6 23 0 0 Non -Parametric 85 95 0.00324 Notes: Background wells: BG-1BR, MW-10BR, MW-14BR, MW-15BR, MW-18BR, and MW-19BRL mg/L = milligrams per liter mg - N/L = Milligrams nitrogen per liter NA = Not applicable; dataset contains >90 percent NDs NO = Non -detect concentration pCi/L = picocuries per liter Radium (Total) = Radium-226 and Radium-228 combined Uranium (Total) = Uranium-233, Uranium-234, Uranium-236, and Uranium-238 combined Prepared by:JHG Checked by: S.U. = Standard Units TDS = Total Dissolved Solids TOC = Total Organic Carbon pg/L = micrograms per liter pg/mL = micrograms per milliliter UTL = Upper Tolerance Limit P:\Duke Energy Progress. 1026\Statistics_CAMA\BTV Reports for CSAs\Roxboro\DRAFT\Tables\ Table 5 - Statistical Analysis Results - Bedrock_ROX.xlsx Page 1 of 1 TABLE 6 STATISTICAL ANALYSIS RESULTS - BACKGROUND SOIL ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Parameter Reporting Unit Number of Samples Number of NDs Percent NDs Distribution Coverage (0/0) Confidence Level (%) UTL PH S.U. 25 0 0 Normal 95 95 4.4 - 9.7 Aluminum mg/kg 26 0 0 Normal 95 95 34,353 Antimony mg/kg 17 14 82 NA NA NA 0.56 Arsenic mg/kg 19 2 11 Gamma 95 95 1.56 Barium mg/kg 26 0 0 Normal 95 95 222 Beryllium mg/kg 23 0 0 Normal 95 95 0.801 Boron mg/kg 19 12 63 Non -Parametric 85 95 2.9 Cadmium mg/kg 17 17 100 NA NA NA 0.024 Calcium mg/kg 22 0 0 Gamma 95 95 3,113 Chloride mg/kg 15 0 0 Normal 95 95 11.8 Chromium mg/kg 21 0 0 Normal 95 95 10.7 Cobalt mg/kg 19 0 0 Normal 95 95 11.3 Copper mg/kg 25 0 0 Gamma 95 95 114 Iron mg/kg 25 0 0 Normal 95 95 27,147 Lead mg/kg 25 7 28 Normal 95 95 6.89 Magnesium mg/kg 23 0 0 Non -Parametric 85 95 6,490 Manganese mg/kg 25 0 0 Gamma 95 95 532 Mercury mg/kg 26 24 92 NA NA NA 0.084 Molybdenum mg/kg 26 22 85 Non -Parametric 85 95 2.8 Nickel mg/kg 23 4 17 Normal 95 95 6.87 Nitrate (as N) mg/kg 17 0 0 Lognormal 95 95 0.945 Potassium mg/kg 26 0 0 Gamma 95 95 9,465 Selenium mg/kg 19 2 11 Gamma 95 95 1.63 Sodium mg/kg 24 1 4 Gamma 95 95 456 Strontium mg/kg 24 0 0 Gamma 95 95 39.2 Sulfate mg/kg 15 13 87 NA NA NA 11 Thallium mg/kg 16 0 0 Normal 95 95 0.148 Vanadium mg/kg 24 1 4 Normal 95 95 68.7 Zinc mg/kg 25 0 0 Normal 95 95 63.4 Prepared by: ]HG Checked by: Notes: mg/kg = milligrams per kilogram NA = Not applicable; dataset contains <4 detected concentrations ND = Non -detect concentration S.U. = Standard Unit UTL = Upper Tolerance Limit P:\Duke Energy Progress.1026\Statistics_CAMA\BTV Reports for CSAs\Roxboro\DRAFT\Tables\ Table 6 - Statistical Analysis Results_Soil_ROX.xlsx Page 1 of 1 TABLE 7 GROUNDWATER PROVISIONAL BACKGROUND THRESHOLD VALUES ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Parameter Reporting Unit NCAC 02L Standard Provisional Background Threshold Values Transition Zone Bedrock PH* S.U. 6.5-8.5 6.3 - 7.6 6.8 - 8.3 Alkalinity mg/L NE 244 317 Aluminum lag/L NE 807 378 Antimony lag/L 18 1 1 Arsenic lag/L 10 1 1 Barium lag/L 700 91 185 Beryllium lag/L 48 1 1 Bicarbonate mg/L NE 244 317 Boron lag/L 700 50 50 Cadmium lag/L 2 1 1 Calcium mg/L NE 106 102 Carbonate mg/L NE 5 5 Chloride mg/L 250 150 120 Chromium (VI) lag/L 10 16.1 0.19 Chromium lag/L 10 18.1 3.61 Cobalt lag/L 18 1 6.4 Copper lag/L 1000 10 1 Iron lag/L 300 1173 4268 Lead lag/L 15 1 1 Magnesium mg/L NE 42.3 31.5 Manganese lag/L 50 405 1198 Mercury lag/L 1 0.05 0.05 Methane lag/L NE 10 367 Molybdenum lag/L NE 4.17 35.2 Nickel lag/L 100 5.22 2.11 Nitrate + Nitrite mg-N/L NE 3.4 0.295 Potassium mg/L 11 4.69 9.28 Selenium lag/L 20 1.78 1 Sodium mg/L NE 36 37.6 Strontium lag/L NE 760 232 Sulfate mg/L 250 37 73.5 Sulfide mg/L NE 0.1 0.1 TDS mg/L 500 540 530 Thallium lag/L 0.2° 0.2 0.2 TOC mg/L NE 2.72 3.6 Vanadium lag/L 0.3° 30.2 2.49 Zinc lag/L 1000 12 7 Radium (Total) pCi/L NE 5.45 5.21 Uranium (Total) lag/mL NE 0.00516 0.00324 Notes: * - Upper and lower tolerance limits calculated for parameter t, - Interim Maximum Allowable Concentrations (IMACs) of 15A NCAC .021 Standard, Appendix 1, April 1, 2013 mg/L - milligrams per liter mg - N/L - Milligrams nitrogen per liter NE - Not Established pCi/L - picocuries per liter Radium (Total) - Radium-226 and Radium-228 combined Uranium (Total) - Uranium-233, Uranium-234, Uranium-236, and Uranium-238 combined Prepared by: JH(, Checked by: MC:M S.U. - Standard Unit TDS - Total Dissolved Solids TOC - Total Organic Carbon pg/L - micrograms per liter pg/mL - micrograms per milliliter P:\Duke Energy Progress.1026\Statistics_CAMA\BTV Reports for CSAs\Roxboro\DRAFT\Tables\ Table 7 - Provisional Background Groundwater Threshold Values_ROX.xlsx Page 1 of 1 TABLE 8 SOIL PROVISIONAL BACKGROUND THRESHOLD VALUES ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, SEMORA, NC Parameter Reporting Unit PSRG Protection of Groundwater BTV pH* S.U. NE 4.4 - 9.7 Aluminum mg/kg NE 34353 Antimony mg/kg 0.9 0.56 Arsenic mg/kg 5.8 1.56 Barium mg/kg 580 222 Beryllium mg/kg 63 0.801 Boron mg/kg 45 2.9 Cadmium mg/kg 3 0.024 Calcium mg/kg NE 3113 Chloride mg/kg NE 11.8 Chromium mg/kg 3.8 10.7 Cobalt mg/kg 0.9 11.3 Copper mg/kg 700 114 Iron mg/kg 150 27147 Lead mg/kg 270 6.89 Magnesium mg/kg N E 6490 Manganese mg/kg 65 532 Mercury mg/kg 1 0.084 Molybdenum mg/kg NE 2.8 Nickel mg/kg 130 6.87 Nitrate (as N) mg/kg NE 0.945 Potassium mg/kg NE 9465 Selenium mg/kg 2.1 1.63 Sodium mg/kg NE 456 Strontium mg/kg NE 39.2 Sulfate mg/kg NE 11 Thallium mg/kg 0.28 0.148 Vanadium mg/kg 6 68.7 Zinc mg/kg 1200 63.4 Prepared by: ]HG Checked by: MCM N otes * - Upper and lower threshold values calculated for parameter BTV - Background Threshold Value mg/kg - milligrams per kilogram NE - Not Established PSRG Protection of Groundwater - NCDEQ IHSB Preliminary Soil Remediation Soil Remediation Goals Table — October 2016 P:\Duke Energy Progress.1026\Statistics_CAMA\BTV Reports for CSAs\Roxboro\DRAFTJables\Table 8 -Provisional Background Soil Threshold Values_ROX.xlsx Page 1 of 1 Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant APPENDIX A SynTerra BOX AND Q-Q - PLOTS TRANSITION ZONE P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 1 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS Normal Probability Plot Section 8.0 • 7.5 • • 7.0 CL 6.5 6.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 1 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 280 • 260 240 ••• • • c M Q 220 • 200 • 180 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 2000 1500 • • E .E 1000 Q •• • 500 Ono 0 •• 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 1 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 1.0 «N ��••• • • • • 0.9 >, 0.8 O E c Q 0.7 0.6 0.5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 1 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 5- 4- 3- 2- 0- 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 1 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 100 s0 r • 60 E m 40 • • 20 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 1.0 • • • ••••• •• • • • • • 0.8 0.6 a� m 0.4 0.2 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 1 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 280 • 260 • 240 ••� m 220 • 200 • 180 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 51.0 50.5 c 0 50.0 f m 49.5 49.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 1.0 �••• • • • • 0.8 E 0.6 .E U 0.4 0.2 0.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.' 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 120 • • • 100 • E • z 80 C) N• 60 • • •• • 40 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.' 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 10 • • • 9 $ c� L U 7- 6- 5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 200 150 ••• • as .p 100 t U 50 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 15 • • • _ 10 • > • EI .E O L • V 5 • • 0 • 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 50 40 E 30 .E 0 V 20 10 i 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 5- 4- • • 3- �a 0 2 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 15 10 •• CL CL U • 5 • • • 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 2000 1500 0 1000 • 500 0 • •• 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 5 •••• • • • 4 3 M J 2- 0- 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 50 • • 45 • • 40 •• E .N = 35 c� 30 • 25 • • ••• • 20 • 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 1500 1000 • • as as ca 500 • • 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.' 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 0.20 •.•••• • • • 0.15 v m 0.10 0.05 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 11.0 10.5 m c s 10.0 f 9.5 9.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 15 , 10 E as o • • � 5 • • 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 50 40 30 v Z 20 • • 10• 0 • • • •• 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 4 • • • • 3 • • Z �I 2- 0 • 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 6 • 5 • • E 4 •• .N • cNa • a 3 2 • 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 10 N• • • • • E 6 ._ as m W 4 2 • r 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 40 • 35 • E 30 Cnn 25 • 20 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 800 • 700 • 600 E 500 400 300 200 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 50 • 40 • 30 � w • 20 w 10 • 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.' 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 0.20 0.18 0.16 a� 0.14 0.12 0.10 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.' 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 0.25 0.20 •• • • E t H 0.15 0.10 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 800 700 • 600 • • • N p 500 H N~ 400 N~ • 300 ••• • • • 200 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 2.5 • • 2.0 • C) p 1.5 • H 1.0 ••• N • 0.5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 30 25 • • 20 15 N 10 5 • 0- 1Ll 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 20 • 15 • v N •• • 10 • • • 5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 25 20 to • • N 15 NI E M 10 5 • • • • 0- 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 2.0 1.5 00 N NI E _M • 0.5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 '/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 25 20 �a 0 15 ~I E 10 5 • • • • • •• 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 1.0 0.8 M N 0.6 EI M 7 CT 0.4 0.2 0.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 1.0 0.8 N 0.6 EI M 7 'T 0.4 0.2 0.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0.4 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 1.0 0.8 cc N 0.6 EI M 7 'T 0.4 0.2 0.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 0.006 0.005 • • 0.004 00 • • M • NI 0.003 M 0.002 0.001 • 0.000 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX A NCSS 11.0. 7/10/2017 12:59:11 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_TZ_no ND column.NCSS 0.006 0.005 • • 0.004 • • H EI 0.003 0.002 0.001 • 0.000 1 5 10 25 50 75 90 95 99 Percent of Data Proposed Background Threshold Values for Naturally Occurring Concentrations in Groundwater and Soil October 2017 Roxboro Steam Electric Plant APPENDIX B BOX AND Q-Q PLOTS - BEDROCK SynTerra P:\Duke Energy Progress.1026\Statistics LAMA\BTV Reports for CSAs\Roxboro\DRAFT\Roxboro_BTV Report Text_CSA2_DRAFT.docx ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS Normal Probability Plot Section 8.5 • 8.0 ••• Q 7.5 • • 1� 7.0 6.5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 300 • • 250 SIP 200 � 150 • • 100 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0. 7/10/2017 1:43:43 PI\ Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 400 • • 300 E 200 • Q •• • 100 �r I • 0 • • ••• 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 1.0 ••«�••• • • • • 0.9 >, 0.8 _ 0 E Q 0.7 0.6 0.5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 3.0 2.5 • • t •• t 2.0 v .(D 1.5 L • • Q 1.0 • • 0.5 • • • 0.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 150 • • • • 100 • • E M m � 50 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 1.0 ••«�••• • • • • 0.8 E 0.6 aD m 0.4 0.2 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 300 • • 250 as 1 c 200 v � 150 • • 100 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 nign17 1-a3:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 51.0 50.5 0 50.0 t 0 m 49.5 49.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 1.0 ••« ---- • • • • 0.8 E 0.6-ZZ .E U 0.4 0.2 0.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 120 100 • • • •••• 80 • �a V 60 • •• • 40 • • 20 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 10 «"• • • • • 9- 8- 0 L U 7- 6- 5- 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 150 • • • 100 (D • L _o V • • 50 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 2.0 1.5 >I • E • .E 1.0 0 t t� 0.5 • r 0.0 • • •• 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 15 10 E 0 L U 5 • • • 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 25 20 • • 15 • • �a • • 0 U 10 5 M • • 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 5 4 L CCL 3 0 U 2 • • 1 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0. 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 8000 6000 • • • o 4000 2000 • • 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 1.0 ••« ---- • • • • 0.8 0.6 c� CD J 0.4 0.2 0.0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 30 • • M• • 25 20 E 'N = 15 ca 5. 10 • 5 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0. 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 1500 • 1000 : •• as • � M• 500 • 0 • • ••~ 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0. 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 0.20 • • • • 0.15 L C� G 0.10 0.05 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 30000 25000 • • 20000 • • t 15000 5 10000 5000 • 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM �T Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 30 25 • 20 •• • c � 15 0 10 map • 5 0 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 5 • • 4 3 • • m • v •• Z 2- 0- 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 0.60 • 0.45 • L 4)I 0.30 • c�a • Z i 0.15 • • • 0.00 • • • •• 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 12 10 • E .� 8 • 0 a 6 • 4 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 1.0 ••«�••• • • • • 0.9 E 0.8 m a� U) 0.7 0.6 0.5 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 50 • 40 • • • • E • 30 • 0 20 • 10 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 300 250 • • E 200 c 0 L Cl) 150 N • 100 50 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.' 7/10/2017 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 50 40 «�••• • • • 30 m Cn 20 • 10 • 0 • •• 1 5 10 25 50 75 90 95 99 Percent of Data ROXBORO STEAM ELECTRIC PLANT APPENDIX B NCSS 11.0.4 7/1 n/gel 7 1:43:43 PM Normal Probability Plots Dataset ...\Roxboro_BG GW Analytical Results thru 2017-06_Bedrock_no ND column.NCSS 0.5 0.4 aD 0.3 U) 0.2 •• • • 0.1 1 5 10 25 50 75 90 95 99 Percent of Data