NC0038377_J17050532report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17050532
Project Name:MAYO STEAM - NPDES - AOW
Lab Contact:Mary Ann Ogle
Date:6/2/2017
Customer Address:Mayo Steam Plant
Customer Name(s):Ross Hartfield, Jerry Wylie, Tim Hunsucker, Kathy Webb, Brandon Russo, Chris
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 62
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2017016892 MAYO STEAM 17-May-17 9:32 AM Ashley Booth S-06
2017016894 MAYO STEAM 17-May-17 9:47 AM Ashley Booth S-09
2017016895 MAYO STEAM 17-May-17 10:49 AM Ashley Booth S-03
2017016896 MAYO STEAM 17-May-17 11:22 AM Ashley Booth S-02B
2017016897 MAYO STEAM 17-May-17 11:34 AM Ashley Booth S-02
2017016898 MAYO STEAM 17-May-17 12:30 PM Ashley Booth S-01
2017016899 MAYO STEAM 17-May-17 4:41 PM Ashley Booth FIELD BLANK
2017016900 MAYO STEAM 17-May-17 4:41 PM Ashley Booth Trip Blank
2017016901 MAYO STEAM 17-May-17 10:49 AM Ashley Booth S-03 Duplicate
9 Total Samples
Page 2 of 62
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:6/2/2017
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016892
Collection Date:17-May-17 9:32 AM
Site:S-06
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 05/19/2017 09:00 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.13 mg-N/L EPA 353.2 05/25/2017 13:34 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 9.3 mg/L EPA 300.0 05/18/2017 19:36 BGN90340.5 5
Fluoride 0.14 mg/L EPA 300.0 05/18/2017 19:36 BGN90340.1 1
Sulfate 6.0 mg/L EPA 300.0 05/18/2017 19:36 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.068 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.005 1
Barium (Ba)0.024 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.05 1
Calcium (Ca)11.5 mg/L EPA 200.7 05/30/2017 10:36B2 MHH71310.01 1
Iron (Fe)0.412 mg/L EPA 200.7 05/30/2017 10:36B2 MHH71310.01 1
Magnesium (Mg)4.35 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.005 1
Manganese (Mn)0.168 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.005 1
Potassium (K)1.46 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.1 1
Sodium (Na)12.0 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.05 1
Total Hardness (Ca and Mg)46.7 mg/L
(CaCO3)
EPA 200.7 05/30/2017 10:36 MHH71310.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/30/2017 10:36 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/26/2017 23:59 CWSPEN30.2 1
Page 4 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016892
Collection Date:17-May-17 9:32 AM
Site:S-06
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 7.30 SI Units Field Work1
Temperature 16.7 °C Field Work1
Specific Conductance 146 uS/cm Field Work1
Turbidity 6.46 NTU Field Work1
Flow 0.0660 cfs Field Work1
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 05/22/2017 15:00 MGIGANT251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/19/2017 10:00 MGIGANT51
Page 5 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016894
Collection Date:17-May-17 9:47 AM
Site:S-09
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 05/19/2017 09:00 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.01 mg-N/L EPA 353.2 05/25/2017 13:35 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 300.0 05/18/2017 19:54 BGN90340.5 5
Fluoride 0.17 mg/L EPA 300.0 05/18/2017 19:54 BGN90340.1 1
Sulfate 9.0 mg/L EPA 300.0 05/18/2017 19:54 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.005 1
Barium (Ba)0.065 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.05 1
Calcium (Ca)25.6 mg/L EPA 200.7 05/30/2017 10:49B2 MHH71310.01 1
Iron (Fe)11.9 mg/L EPA 200.7 05/30/2017 10:49B2 MHH71310.01 1
Magnesium (Mg)9.27 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.005 1
Manganese (Mn)2.19 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.005 1
Potassium (K)1.04 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.1 1
Sodium (Na)24.8 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.05 1
Total Hardness (Ca and Mg)102 mg/L
(CaCO3)
EPA 200.7 05/30/2017 10:49 MHH71310.19 1
Zinc (Zn)0.007 mg/L EPA 200.7 05/30/2017 10:49 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Nickel (Ni)6.91 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/26/2017 23:27 CWSPEN30.2 1
Page 6 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016894
Collection Date:17-May-17 9:47 AM
Site:S-09
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.13 SI Units Field Work1
Temperature 16.6 °C Field Work1
Specific Conductance 347 uS/cm Field Work1
Turbidity 1.34 NTU Field Work1
Flow 0.0110 cfs Field Work1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 05/22/2017 15:00 MGIGANT251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/19/2017 10:00 MGIGANT51
Page 7 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016895
Collection Date:17-May-17 10:49 AM
Site:S-03
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 05/19/2017 09:00 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.07 mg-N/L EPA 353.2 05/25/2017 13:37 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 53 mg/L EPA 300.0 05/18/2017 20:12 BGN9034110
Fluoride 0.12 mg/L EPA 300.0 05/18/2017 20:12 BGN90340.1 1
Sulfate 30 mg/L EPA 300.0 05/18/2017 20:12 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.025 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.005 1
Barium (Ba)0.045 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.005 1
Boron (B)1.17 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.05 1
Calcium (Ca)27.8 mg/L EPA 200.7 05/30/2017 10:53B2 MHH71310.01 1
Iron (Fe)0.174 mg/L EPA 200.7 05/30/2017 10:53B2 MHH71310.01 1
Magnesium (Mg)9.71 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.005 1
Manganese (Mn)0.873 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.005 1
Potassium (K)2.02 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.1 1
Sodium (Na)20.7 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.05 1
Total Hardness (Ca and Mg)109 mg/L
(CaCO3)
EPA 200.7 05/30/2017 10:53 MHH71310.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/30/2017 10:53 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/27/2017 00:06 CWSPEN30.2 1
Page 8 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016895
Collection Date:17-May-17 10:49 AM
Site:S-03
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.77 SI Units Field Work1
Temperature 16.9 °C Field Work1
Specific Conductance 343 uS/cm Field Work1
Turbidity 1.69 NTU Field Work1
Flow 0.0530 cfs Field Work1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 05/22/2017 15:00 MGIGANT251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/19/2017 10:00 MGIGANT51
Page 9 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016896
Collection Date:17-May-17 11:22 AM
Site:S-02B
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 05/19/2017 09:00 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.24 mg-N/L EPA 353.2 05/25/2017 13:39 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 62 mg/L EPA 300.0 05/18/2017 20:35 BGN9034110
Fluoride < 0.1 mg/L EPA 300.0 05/18/2017 20:35 BGN90340.1 1
Sulfate 27 mg/L EPA 300.0 05/18/2017 20:35 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.005 1
Barium (Ba)0.032 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.005 1
Boron (B)1.66 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.05 1
Calcium (Ca)34.1 mg/L EPA 200.7 05/30/2017 10:58B2 MHH71310.01 1
Iron (Fe)0.074 mg/L EPA 200.7 05/30/2017 10:58B2 MHH71310.01 1
Magnesium (Mg)12.5 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.005 1
Manganese (Mn)2.84 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.005 1
Potassium (K)2.08 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.1 1
Sodium (Na)16.9 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.05 1
Total Hardness (Ca and Mg)136 mg/L
(CaCO3)
EPA 200.7 05/30/2017 10:58 MHH71310.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/30/2017 10:58 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/27/2017 00:38 CWSPEN30.2 1
Page 10 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016896
Collection Date:17-May-17 11:22 AM
Site:S-02B
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.54 SI Units Field Work1
Temperature 16.7 °C Field Work1
Specific Conductance 361 uS/cm Field Work1
Turbidity 3.69 NTU Field Work1
Flow NM cfs Field Work1
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 05/22/2017 15:00 MGIGANT251
TOTAL SUSPENDED SOLIDS
TSS 7 mg/L SM2540D 05/19/2017 10:00 MGIGANT51
Page 11 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016897
Collection Date:17-May-17 11:34 AM
Site:S-02
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 6.02 mg/L EPA 1664B 05/19/2017 09:00 CJELLIO6.02 1.204
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.01 mg-N/L EPA 353.2 05/25/2017 13:40 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 63 mg/L EPA 300.0 05/18/2017 20:51 BGN9034110
Fluoride < 0.1 mg/L EPA 300.0 05/18/2017 20:51 BGN90340.1 1
Sulfate 42 mg/L EPA 300.0 05/18/2017 20:51 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.005 1
Barium (Ba)0.122 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.005 1
Boron (B)1.58 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.05 1
Calcium (Ca)24.2 mg/L EPA 200.7 05/30/2017 11:02B2 MHH71310.01 1
Iron (Fe)4.32 mg/L EPA 200.7 05/30/2017 11:02B2 MHH71310.01 1
Magnesium (Mg)11.6 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.005 1
Manganese (Mn)2.17 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.005 1
Potassium (K)2.31 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.1 1
Sodium (Na)18.0 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.05 1
Total Hardness (Ca and Mg)108 mg/L
(CaCO3)
EPA 200.7 05/30/2017 11:02 MHH71310.19 1
Zinc (Zn)0.009 mg/L EPA 200.7 05/30/2017 11:02 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Nickel (Ni)1.83 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/27/2017 00:45 CWSPEN30.2 1
Page 12 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016897
Collection Date:17-May-17 11:34 AM
Site:S-02
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.24 SI Units Field Work1
Temperature 18.3 °C Field Work1
Specific Conductance 362 uS/cm Field Work1
Turbidity 5.56 NTU Field Work1
Flow 0.0050 cfs Field Work1
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 05/22/2017 15:00 MGIGANT251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/19/2017 10:00 MGIGANT51
Page 13 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016898
Collection Date:17-May-17 12:30 PM
Site:S-01
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5.17 mg/L EPA 1664B 05/19/2017 09:00 CJELLIO5.17 1.034
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.01 mg-N/L EPA 353.2 05/25/2017 13:41 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 57 mg/L EPA 300.0 05/18/2017 21:07 BGN9034110
Fluoride 0.14 mg/L EPA 300.0 05/18/2017 21:07 BGN90340.1 1
Sulfate 45 mg/L EPA 300.0 05/18/2017 21:07 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.005 1
Barium (Ba)0.139 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.005 1
Boron (B)1.85 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.05 1
Calcium (Ca)23.6 mg/L EPA 200.7 05/30/2017 11:06B2 MHH71310.01 1
Iron (Fe)14.7 mg/L EPA 200.7 05/30/2017 11:06B2 MHH71310.01 1
Magnesium (Mg)8.72 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.005 1
Manganese (Mn)3.15 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.005 1
Potassium (K)1.63 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.1 1
Sodium (Na)34.6 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.05 1
Total Hardness (Ca and Mg)94.8 mg/L
(CaCO3)
EPA 200.7 05/30/2017 11:06 MHH71310.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/30/2017 11:06 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Arsenic (As)2.24 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Nickel (Ni)1.09 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/27/2017 00:53 CWSPEN30.2 1
Page 14 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016898
Collection Date:17-May-17 12:30 PM
Site:S-01
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.40 SI Units Field Work1
Temperature 22.4 °C Field Work1
Specific Conductance 426 uS/cm Field Work1
Turbidity 4.99 NTU Field Work1
Flow 0.0080 cfs Field Work1
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 05/22/2017 15:00 MGIGANT251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/19/2017 10:00 MGIGANT51
Page 15 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016899
Collection Date:17-May-17 4:41 PM
Site:FIELD BLANK
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
Page 16 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016900
Collection Date:17-May-17 4:41 PM
Site:Trip Blank
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
Page 17 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016901
Collection Date:17-May-17 10:49 AM
Site:S-03 Duplicate
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 05/19/2017 09:00 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.07 mg-N/L EPA 353.2 05/25/2017 13:38 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 52 mg/L EPA 300.0 05/18/2017 21:23 BGN9034110
Fluoride 0.13 mg/L EPA 300.0 05/18/2017 21:23 BGN90340.1 1
Sulfate 30 mg/L EPA 300.0 05/18/2017 21:23 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.039 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.005 1
Barium (Ba)0.047 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.005 1
Boron (B)1.19 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.05 1
Calcium (Ca)28.5 mg/L EPA 200.7 05/30/2017 11:11B2 MHH71310.01 1
Iron (Fe)0.295 mg/L EPA 200.7 05/30/2017 11:11B2 MHH71310.01 1
Magnesium (Mg)9.93 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.005 1
Manganese (Mn)0.910 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.005 1
Potassium (K)2.06 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.1 1
Sodium (Na)21.2 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.05 1
Total Hardness (Ca and Mg)112 mg/L
(CaCO3)
EPA 200.7 05/30/2017 11:11 MHH71310.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/30/2017 11:11 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/27/2017 01:01 CWSPEN30.2 1
Page 18 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
2017016901
Collection Date:17-May-17 10:49 AM
Site:S-03 Duplicate
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 05/22/2017 15:00 MGIGANT251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/19/2017 10:00 MGIGANT51
Qualifiers:
B2 Target analyte was detected in Method Blank(s) at a concentration greater than ½ the reporting limit but less
than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Page 19 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050492 1664_SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Oil and Grease mg/L -10.183 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Oil and Grease 37.2439 87.5mg/L -11478132.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040278 -- 2017012051
Oil and Grease 33.5768 87.2mg/L -11478129.3
Page 20 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050637 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0002 mg-N/L -10.0002 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0002 mg-N/L -1-0.0002 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0001 mg-N/L -10.0001 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.305 3.01 101mg-N/L -11090103.05
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.324 3.01 108mg-N/L -11090103.24
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.318 3.01 106mg-N/L -11090103.18
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040260 -- 2017011969
Nitrite + Nitrate
(Colorimetric)
0.274 0.25 96.2mg-N/L -1109010.274
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040260 -- 2017011969
Nitrite + Nitrate
(Colorimetric)
0.274 0.25 96.2 0.0729mg-N/L -1109010.274
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17050012 -- 2017014343
Nitrite + Nitrate
(Colorimetric)
0.419 0.25 103mg-N/L -1109010.419
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17050012 -- 2017014343
Nitrite + Nitrate
(Colorimetric)
0.418 0.25 102 0.406mg-N/L -1109010.418
Page 21 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050637 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17050519 -- 2017016838
Nitrite + Nitrate
(Colorimetric)
0.368 0.25 102mg-N/L -1109010.368
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17050519 -- 2017016838
Nitrite + Nitrate
(Colorimetric)
0.368 0.25 102 0.0815mg-N/L -1109010.368
Page 22 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050458 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0405 mg/L -10.0405 0.1 < 1/2 RDL
Fluoride 0.0431 mg/L -10.0431 0.1 < 1/2 RDL
Sulfate 0.0053 mg/L -10.0053 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5mg/L -120801Not Tested
Fluoride 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5mg/L -120801Not Tested
Fluoride 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 5mg/L -120801Not Tested
Fluoride 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 5mg/L -120801Not Tested
Fluoride 5mg/L -120801Not Tested
Sulfate 5mg/L -120801Not Tested
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.98 5 99.6mg/L -1109014.98
Fluoride 5 5 99.9mg/L -1109015
Sulfate 4.96 5 99.3mg/L -1109014.96
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016892
Chloride 7.03 25 103mg/L -12080535.1
Fluoride 5.21 25 104mg/L -12080526.1
Sulfate 6.41 25 104mg/L -12080532
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016892
Chloride 7.04 25 104 0.28mg/L -12080535.2
Page 23 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050458 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016892
Fluoride 5.23 25 104 0.221mg/L -12080526.1
Sulfate 6.42 25 104 0.313mg/L -12080532.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17050536 -- 2017016943
Chloride 8.34 2500 105mg/L -120805004170
Fluoride 5.28 2500 106mg/L -120805002640
Sulfate 6.98 2500 106mg/L -120805003490
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17050536 -- 2017016943
Chloride 8.36 2500 105 0.439mg/L -120805004180
Fluoride 5.31 2500 106 0.591mg/L -120805002660
Sulfate 7.02 2500 107 0.581mg/L -120805003510
Page 24 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050634 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000962 mg/L -10.000962 0.005 < 1/2 RDL
Barium (Ba) 0.000142 mg/L -10.000142 0.005 < 1/2 RDL
Boron (B) -0.0256 mg/L -1-0.0256 0.05 < 1/2 RDL
Calcium (Ca) 0.00783 mg/L -10.00783 0.01 > 1/2 RDL
Iron (Fe) 0.00783 mg/L -10.00783 0.01 > 1/2 RDL
Magnesium (Mg) 0.000633 mg/L -10.000633 0.005 < 1/2 RDL
Manganese (Mn) 0.000343 mg/L -10.000343 0.005 < 1/2 RDL
Potassium (K) 0.00403 mg/L -10.00403 0.1 < 1/2 RDL
Sodium (Na) 0.0169 mg/L -10.0169 0.05 < 1/2 RDL
Zinc (Zn) -0.000252 mg/L -1-0.000252 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.92 5 98.5mg/L -1158514.92
Barium (Ba) 5 5 100mg/L -1158515
Boron (B) 5.01 5 100mg/L -1158515.01
Calcium (Ca) 5.03 5 101mg/L -1158515.03
Iron (Fe) 5.05 5 101mg/L -1158515.05
Magnesium (Mg) 5.03 5 101mg/L -1158515.03
Manganese (Mn) 5.04 5 101mg/L -1158515.04
Potassium (K) 4.94 5 98.8mg/L -1158514.94
Sodium (Na) 4.97 5 99.3mg/L -1158514.97
Zinc (Zn) 5.07 5 101mg/L -1158515.07
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016892
Aluminum (Al) 5.02 5 99mg/L -1307015.02
Barium (Ba) 4.98 5 99.1mg/L -1307014.98
Boron (B) 4.97 5 99.8mg/L -1307014.97
Calcium (Ca) 16.5 5 101mg/L -13070116.5
Iron (Fe) 5.42 5 100mg/L -1307015.42
Magnesium (Mg) 9.25 5 97.9mg/L -1307019.25
Manganese (Mn) 5.14 5 99.4mg/L -1307015.14
Potassium (K) 6.41 5 98.9mg/L -1307016.41
Sodium (Na) 16.8 5 96.7mg/L -13070116.8
Zinc (Zn) 4.99 5 99.6mg/L -1307014.99
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016892
Aluminum (Al) 4.84 5 95.4 3.74mg/L -1307014.84
Page 25 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050634 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016892
Barium (Ba) 4.79 5 95.3 3.95mg/L -1307014.79
Boron (B) 4.71 5 94.5 5.54mg/L -1307014.71
Calcium (Ca) 16.3 5 96.2 4.51mg/L -13070116.3
Iron (Fe) 5.23 5 96.3 3.87mg/L -1307015.23
Magnesium (Mg) 9.04 5 93.6 4.45mg/L -1307019.04
Manganese (Mn) 4.95 5 95.6 3.84mg/L -1307014.95
Potassium (K) 6.23 5 95.4 3.66mg/L -1307016.23
Sodium (Na) 16.6 5 93.3 3.6mg/L -13070116.6
Zinc (Zn) 4.79 5 95.8 3.95mg/L -1307014.79
Page 26 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050639 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.013 ug/L -10.013 1 < 1/2 RDL
Arsenic (As) -0.001 ug/L -1-0.001 1 < 1/2 RDL
Cadmium (Cd) -0.001 ug/L -1-0.001 1 < 1/2 RDL
Chromium (Cr) 0.033 ug/L -10.033 1 < 1/2 RDL
Copper (Cu) -0.047 ug/L -1-0.047 1 < 1/2 RDL
Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL
Molybdenum (Mo) 0.006 ug/L -10.006 1 < 1/2 RDL
Nickel (Ni) -0.022 ug/L -1-0.022 1 < 1/2 RDL
Selenium (Se) -0.011 ug/L -1-0.011 1 < 1/2 RDL
Thallium (Tl) Low Level 0.013 ug/L -10.013 0.2 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 48.9 50 97.8ug/L -11585148.9
Arsenic (As) 47.9 50 95.8ug/L -11585147.9
Cadmium (Cd) 48.8 50 97.5ug/L -11585148.8
Chromium (Cr) 49.7 50 99.4ug/L -11585149.7
Copper (Cu) 50 50 100ug/L -11585150
Lead (Pb) 48.7 50 97.3ug/L -11585148.7
Molybdenum (Mo) 49.3 50 98.5ug/L -11585149.3
Nickel (Ni) 48.5 50 97ug/L -11585148.5
Selenium (Se) 46.5 50 92.9ug/L -11585146.5
Thallium (Tl) Low Level 47.2 50 94.5ug/L -11585147.2
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016894
Antimony (Sb) 50.3 50 100ug/L -13070150.3
Arsenic (As) 48.9 50 96.1ug/L -13070148.9
Cadmium (Cd) 49.3 50 98.5ug/L -13070149.3
Chromium (Cr) 50 50 99.2ug/L -13070150
Copper (Cu) 47.4 50 94.8ug/L -13070147.4
Lead (Pb) 48.7 50 97.4ug/L -13070148.7
Molybdenum (Mo) 50 50 99.4ug/L -13070150
Nickel (Ni) 51 50 88.2ug/L -13070151
Selenium (Se) 46.6 50 93.1ug/L -13070146.6
Thallium (Tl) Low Level 44.3 50 88.5ug/L -13070144.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016894
Antimony (Sb) 46.9 50 93.5 7.08ug/L -13070146.9
Page 27 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050639 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17050532 -- 2017016894
Arsenic (As) 45.6 50 89.5 7.09ug/L -13070145.6
Cadmium (Cd) 45.9 50 91.7 7.19ug/L -13070145.9
Chromium (Cr) 46 50 91.2 8.43ug/L -13070146
Copper (Cu) 44.2 50 88.4 6.91ug/L -13070144.2
Lead (Pb) 45.1 50 90.3 7.58ug/L -13070145.1
Molybdenum (Mo) 46.5 50 92.3 7.37ug/L -13070146.5
Nickel (Ni) 47.1 50 80.3 9.36ug/L -13070147.1
Selenium (Se) 43.4 50 86.6 7.24ug/L -13070143.4
Thallium (Tl) Low Level 41.6 50 83.1 6.32ug/L -13070141.6
Page 28 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050525 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17040141 -- 2017011490
TDS 17700 0.113mg/L -117700
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17040141 -- 2017011491
TDS 303 0mg/L -1303
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17050012 -- 2017014343
TDS 44 4.65mg/L -144
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 103 100 103mg/L -110901103
Page 29 of 62
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17050532
Q17050493 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 50 100mg/L -11090150
Final QualifierDilMeasuredUnits:Parameter
LCSD # 1
RPD% Recovery LCL UCLSpike
TSS 49.6 50 99.2 0.803mg/L -11090149.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TSS 50.4 50 101mg/L -11090150.4
Final QualifierDilMeasuredUnits:Parameter
LCSD # 2
RPD% Recovery LCL UCLSpike
TSS 48 50 96 4.88mg/L -11090148
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
TSS 49.6 50 99.2mg/L -11090149.6
Final QualifierDilMeasuredUnits:Parameter
LCSD # 3
RPD% Recovery LCL UCLSpike
TSS 49.6 50 99.2 0mg/L -11090149.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
TSS 48.4 50 96.8mg/L -11090148.4
Final QualifierDilMeasuredUnits:Parameter
LCSD # 4
RPD% Recovery LCL UCLSpike
TSS 48.8 50 97.6 0.823mg/L -11090148.8
Page 30 of 62
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
SE22003Lot Number:
J17050532Project Number:
Mayo NPDES AOWProject Name:
05/30/2017Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 20
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: SE22003
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: Mayo NPDES AOW
Project Number: J17050532
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Low Level Mercury Analysis - Method 1631E
Samples -002, -006: The samples were analyzed at a 4X dilution due to the presence of particulate matter. The reporting limits were raised
accordingly.
Page: 2 of 20
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: SE22003

Project Name: Mayo NPDES AOW
Project Number: J17050532
Sample Number Sample ID Matrix Date Sampled Date Received
001 05/17/2017 09322017016892Aqueous 05/19/2017
002 05/17/2017 09472017016894Aqueous 05/19/2017
003 05/17/2017 10492017016895Aqueous 05/19/2017
004 05/17/2017 11222017016896Aqueous 05/19/2017
005 05/17/2017 11342017016897Aqueous 05/19/2017
006 05/17/2017 12302017016898Aqueous 05/19/2017
007 05/17/2017 10492017016901Aqueous 05/19/2017
008 05/17/2017 16412017016899Aqueous 05/19/2017
009 05/17/2017 16412017016900Aqueous 05/19/2017
(9 samples)
Page: 3 of 20
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: SE22003

Project Name: Mayo NPDES AOW
Project Number: J17050532
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2017016892 Aqueous Alkalinity SM 2320B-53 mg/L 5
001 2017016892 Aqueous Bicarbonate Alkalinity SM 2320B-53 mg/L 5
001 2017016892 Aqueous Mercury (CVAFS)1631E 1.3 ng/L 6
002 2017016894 Aqueous Alkalinity SM 2320B-130 mg/L 7
002 2017016894 Aqueous Bicarbonate Alkalinity SM 2320B-130 mg/L 7
003 2017016895 Aqueous Alkalinity SM 2320B-58 mg/L 9
003 2017016895 Aqueous Bicarbonate Alkalinity SM 2320B-58 mg/L 9
003 2017016895 Aqueous Mercury (CVAFS)1631E 2.5 ng/L 10
004 2017016896 Aqueous Alkalinity SM 2320B-61 mg/L 11
004 2017016896 Aqueous Bicarbonate Alkalinity SM 2320B-61 mg/L 11
004 2017016896 Aqueous Mercury (CVAFS)1631E 1.96 ng/L 12
005 2017016897 Aqueous Alkalinity SM 2320B-27 mg/L 13
005 2017016897 Aqueous Bicarbonate Alkalinity SM 2320B-27 mg/L 13
006 2017016898 Aqueous Alkalinity SM 2320B-53 mg/L 15
006 2017016898 Aqueous Bicarbonate Alkalinity SM 2320B-53 mg/L 15
007 2017016901 Aqueous Alkalinity SM 2320B-58 mg/L 17
007 2017016901 Aqueous Bicarbonate Alkalinity SM 2320B-58 mg/L 17
007 2017016901 Aqueous Mercury (CVAFS)1631E 2.49 ng/L 18
(18 detections)
Page: 4 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016892
SE22003-001
05/17/2017 0932
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 05/30/2017 1242 BWS 42988
1 (Bicarbonate ) SM 2320B-2011 1 05/30/2017 1242 BWS
1 (Carbonate Al) SM 2320B-2011 1 05/30/2017 1242 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 53 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 53 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 5 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016892
SE22003-001
05/17/2017 0932
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 05/25/2017 0103 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 1.3 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 6 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016894
SE22003-002
05/17/2017 0947
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 05/30/2017 1254 BWS 42988
1 (Bicarbonate ) SM 2320B-2011 1 05/30/2017 1254 BWS
1 (Carbonate Al) SM 2320B-2011 1 05/30/2017 1254 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 130 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 130 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 7 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016894
SE22003-002
05/17/2017 0947
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 4 05/25/2017 0116 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L2.00
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 8 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016895
SE22003-003
05/17/2017 1049
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 05/30/2017 1259 BWS 42988
1 (Bicarbonate ) SM 2320B-2011 1 05/30/2017 1259 BWS
1 (Carbonate Al) SM 2320B-2011 1 05/30/2017 1259 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 58 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 58 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 9 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016895
SE22003-003
05/17/2017 1049
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 05/25/2017 0121 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 2.5 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 10 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016896
SE22003-004
05/17/2017 1122
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 05/30/2017 1305 BWS 42988
1 (Bicarbonate ) SM 2320B-2011 1 05/30/2017 1305 BWS
1 (Carbonate Al) SM 2320B-2011 1 05/30/2017 1305 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 61 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 61 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 11 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016896
SE22003-004
05/17/2017 1122
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 05/25/2017 0134 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 1.96 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 12 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016897
SE22003-005
05/17/2017 1134
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 05/30/2017 1310 BWS 42988
1 (Bicarbonate ) SM 2320B-2011 1 05/30/2017 1310 BWS
1 (Carbonate Al) SM 2320B-2011 1 05/30/2017 1310 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 27 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 27 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 13 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016897
SE22003-005
05/17/2017 1134
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 05/25/2017 0139 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 14 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016898
SE22003-006
05/17/2017 1230
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 05/30/2017 1315 BWS 42988
1 (Bicarbonate ) SM 2320B-2011 1 05/30/2017 1315 BWS
1 (Carbonate Al) SM 2320B-2011 1 05/30/2017 1315 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 53 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 53 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 15 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016898
SE22003-006
05/17/2017 1230
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 4 05/25/2017 0143 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L2.00
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 16 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016901
SE22003-007
05/17/2017 1049
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 05/30/2017 1321 BWS 42988
1 (Bicarbonate ) SM 2320B-2011 1 05/30/2017 1321 BWS
1 (Carbonate Al) SM 2320B-2011 1 05/30/2017 1321 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 58 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 58 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 17 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016901
SE22003-007
05/17/2017 1049
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 05/25/2017 0148 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 2.49 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 18 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016899
SE22003-008
05/17/2017 1641
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 05/25/2017 0152 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 19 of 20
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2017016900
SE22003-009
05/17/2017 1641
05/19/2017
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J17050532
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 05/25/2017 0156 SLS 05/23/2017 2320 42729
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 20 of 20
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QC Summary
QC Data for Lot Number: SE22003
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Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:SQ42988-001
42988
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 05/30/2017 123010mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: SE22003
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Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:SQ42988-002
42988
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 97 05/30/2017 12379710090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: SE22003
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Shealy Environmental Services, Inc.

Inorganic non-metals - Duplicate
Batch:
Sample ID:SE22003-001DU
42988
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q Analysis Date% RPD
% RPD
Limit
Sample
Amount
Dil(mg/L)(mg/L)
Alkalinity 53 05/30/2017 12480.57 20531
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: SE22003
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - MB
Batch:Prep Method:
Prep Date:
Sample ID:SQ42729-001
42729 1631E
05/23/2017 2320Analytical Method:1631E
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Mercury (CVAFS)ND 05/25/2017 00520.500 ng/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: SE22003
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - LCS
Batch:Prep Method:
Prep Date:
Sample ID:SQ42729-002
42729 1631E
05/23/2017 2320Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ng/L)(ng/L)
Mercury (CVAFS)4.77 05/25/2017 0058955.00 75-1251
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: SE22003
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - MS
Batch:Prep Method:
Prep Date:
Sample ID:SE22003-001MS
42729 1631E
05/23/2017 2320Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(ng/L)(ng/L)(ng/L)
Mercury (CVAFS)5.72 05/25/2017 0107885.00 71-1251.3 1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: SE22003
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - MSD
Batch:Prep Method:
Prep Date:
Sample ID:SE22003-001MD
42729 1631E
05/23/2017 2320Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
Limit
Sample
Amount
Dil(ng/L)(ng/L)(ng/L)
Mercury (CVAFS)5.72 05/25/2017 0112885.00 71-1250.052 241.3 1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: SE22003
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Chain of Custody
and
Miscellaneous Documents
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

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