NC0038377_J17040240report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17040240
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:4/26/2017
Customer Address:Mayo Steam Plant
Customer Name(s):Bryan Moeller, Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy We
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 44
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2017011885 MAYO STEAM 07-Apr-17 8:35 AM Synterra SW-CB2
1 Total Samples
Duke Energy Analytical Lab
Page 2 of 44
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:4/25/2017
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
2017011885
Collection Date:07-Apr-17 8:35 AM
Site:SW-CB2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/08/2017 09:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 24 mg/L EPA 300.0 04/11/2017 13:20 BGN90340.5 5
Sulfate 18 mg/L EPA 300.0 04/11/2017 13:20 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 13:18 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 13:38 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/18/2017 11:32 SLS25600.005 1
Barium (Ba)0.028 mg/L EPA 200.7 04/18/2017 11:32 SLS25600.005 1
Boron (B)0.434 mg/L EPA 200.7 04/18/2017 11:32 SLS25600.05 1
Iron (Fe)0.048 mg/L EPA 200.7 04/18/2017 11:32N1 SLS25600.01 1
Manganese (Mn)2.18 mg/L EPA 200.7 04/18/2017 11:32 SLS25600.005 1
Strontium (Sr)0.182 mg/L EPA 200.7 04/18/2017 11:32 SLS25600.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/18/2017 11:32 SLS25600.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.4 mg/L EPA 200.7 04/17/2017 16:12 SLS25600.01 1
Magnesium (Mg)5.78 mg/L EPA 200.7 04/17/2017 16:12 SLS25600.005 1
Potassium (K)1.99 mg/L EPA 200.7 04/17/2017 16:12 SLS25600.1 1
Sodium (Na)13.0 mg/L EPA 200.7 04/17/2017 16:12 SLS25600.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.223 mg/L EPA 200.7 04/19/2017 10:42 MHH71310.005 1
Barium (Ba)0.032 mg/L EPA 200.7 04/19/2017 10:42 MHH71310.005 1
Boron (B)0.437 mg/L EPA 200.7 04/19/2017 10:42 MHH71310.05 1
Iron (Fe)2.21 mg/L EPA 200.7 04/19/2017 10:42 MHH71310.01 1
Manganese (Mn)2.25 mg/L EPA 200.7 04/19/2017 10:42 MHH71310.005 1
Strontium (Sr)0.191 mg/L EPA 200.7 04/19/2017 10:42 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/19/2017 10:42 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
2017011885
Collection Date:07-Apr-17 8:35 AM
Site:SW-CB2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Copper (Cu)4.14 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/18/2017 14:23 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR0.2 1
Vanadium (V) Low Level 0.640 ug/L EPA 200.8 04/13/2017 21:09 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 04/13/2017 15:00 MGIGANT251
Total Carbon
TOC 4.0 mg/L SM5310C/EPA9060A 04/10/2017 15:09B3 CJELLIO0.1 1
Duke Energy Analytical Lab
Page 5 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
2017011885
Collection Date:07-Apr-17 8:35 AM
Site:SW-CB2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 7 mg/L SM2540D 04/12/2017 10:00 MGIGANT51
Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than the reporting limit.
Qualifiers:
B3 Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than ½ the
reporting limit, but less than the reporting limit.
N1 See additional information listed below.
Duke Energy Analytical Lab
Page 6 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040164 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0003 mg-N/L -1-0.0003 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0008 mg-N/L -1-0.0008 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0001 mg-N/L -10.0001 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0003 mg-N/L -1-0.0003 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 99.1mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.5mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.295 3.01 97.9mg-N/L -11090102.95
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.295 3.01 97.9mg-N/L -11090102.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030150 -- 2017007407
Nitrite + Nitrate
(Colorimetric)
0.902 50 96.1mg-N/L -11090200180
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030150 -- 2017007407
Nitrite + Nitrate
(Colorimetric)
0.9 50 95.4 0.189mg-N/L -11090200180
Duke Energy Analytical Lab
Page 7 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040164 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010990
Nitrite + Nitrate
(Colorimetric)
0.176 0.25 82.8mg-N/L -1109010.176
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010990
Nitrite + Nitrate
(Colorimetric)
0.174 0.25 82 1.03mg-N/L -1109010.174
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17040122 -- 2017011346
Nitrite + Nitrate
(Colorimetric)
0.457 0.25 95.6mg-N/L -1109010.457
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17040122 -- 2017011346
Nitrite + Nitrate
(Colorimetric)
0.462 0.25 97.3 0.914mg-N/L -1109010.462
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17040122 -- 2017011357
Nitrite + Nitrate
(Colorimetric)
0.108 0.25 74.5mg-N/L -1109010.108
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17040122 -- 2017011357
Nitrite + Nitrate
(Colorimetric)
0.108 0.25 74.7 0.37mg-N/L -1109010.108
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J17040122 -- 2017011359
Nitrite + Nitrate
(Colorimetric)
0.539 0.25 98.7mg-N/L -1109010.539
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J17040122 -- 2017011359
Nitrite + Nitrate
(Colorimetric)
0.543 0.25 100 0.703mg-N/L -1109010.543
Final QualifierDilMeasuredUnits:Parameter
MS # 6
% Recovery LCL UCLSpike
Parent Sample: J17040123 -- 2017011368
Nitrite + Nitrate
(Colorimetric)
1.54 0.25 94.1mg-N/L -1109011.54
Final QualifierDilMeasuredUnits:Parameter
MSD # 6
RPD% Recovery LCL UCLSpike
Parent Sample: J17040123 -- 2017011368
Nitrite + Nitrate
(Colorimetric)
1.55 0.25 97.3 0.517mg-N/L -1109011.55
Duke Energy Analytical Lab
Page 8 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040203 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0218 mg/L -10.0218 0.1 < 1/2 RDL
Sulfate -0.0485 mg/L -1-0.0485 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.76 50 99.9mg/L -120801057.6
Sulfate 5.85 50 103mg/L -120801058.5
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.78 50 100 0.324mg/L -120801057.8
Sulfate 5.69 50 100 3.02mg/L -120801056.9
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 6.52 5 101mg/L -1208016.52
Sulfate 9.53 5 101mg/L -1208019.53
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 6.51 5 100 0.291mg/L -1208016.51
Sulfate 9.53 5 101 0.0592mg/L -1208019.53
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.07 5 101mg/L -1109015.07
Sulfate 5.06 5 101mg/L -1109015.06
Duke Energy Analytical Lab
Page 9 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040372 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.012 ug/L -10.012 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.92 20 91.9ug/L -130702018.4
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.897 20 89.7 2.48ug/L -130702017.9
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.965 1 95.3ug/L -1307010.965
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.961 1 94.9 0.421ug/L -1307010.961
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.08 2 104ug/L -1158512.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.4ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008374
Mercury (Hg) 0.995 1 98.6ug/L -1307010.995
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008374
Mercury (Hg) 1 1 99.4 0.808ug/L -1307011
Duke Energy Analytical Lab
Page 10 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040373 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.012 ug/L -10.012 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.4ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010982
Mercury (Hg) 0.962 1 95ug/L -1307010.962
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010982
Mercury (Hg) 0.955 1 94.3 0.74ug/L -1307010.955
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010991
Mercury (Hg) 0.965 1 95.3ug/L -1307010.965
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010991
Mercury (Hg) 0.961 1 94.9 0.421ug/L -1307010.961
Duke Energy Analytical Lab
Page 11 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040382 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000743 mg/L -10.000743 0.005 < 1/2 RDL
Barium (Ba) 0.000277 mg/L -10.000277 0.005 < 1/2 RDL
Boron (B) 0.000598 mg/L -10.000598 0.05 < 1/2 RDL
Iron (Fe) 0.00123 mg/L -10.00123 0.01 < 1/2 RDL
Manganese (Mn) 0.000076 mg/L -10.000076 0.005 < 1/2 RDL
Strontium (Sr) 0.000074 mg/L -10.000074 0.005 < 1/2 RDL
Zinc (Zn) 0.000735 mg/L -10.000735 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.12 2 106mg/L -1158512.12
Barium (Ba) 1.01 1 101mg/L -1158511.01
Boron (B) 2.06 2 103mg/L -1158512.06
Iron (Fe) 2 2 100mg/L -1158512
Manganese (Mn) 1.03 1 103mg/L -1158511.03
Strontium (Sr) 1.97 2 98.5mg/L -1158511.97
Zinc (Zn) 1.02 1 102mg/L -1158511.02
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010982
Aluminum (Al) 4.96 5 99.3mg/L -1307014.96
Barium (Ba) 5.16 5 102mg/L -1307015.16
Boron (B) 5 5 100mg/L -1307015
Iron (Fe) 4.77 5 95.4mg/L -1307014.77
Manganese (Mn) 5.04 5 101mg/L -1307015.04
Strontium (Sr) 5.2 5 101mg/L -1307015.2
Zinc (Zn) 5.07 5 101mg/L -1307015.07
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010982
Aluminum (Al) 4.86 5 97.1 2.22mg/L -1307014.86
Barium (Ba) 5.09 5 100 1.41mg/L -1307015.09
Boron (B) 4.93 5 98.7 1.39mg/L -1307014.93
Iron (Fe) 4.69 5 93.8 1.73mg/L -1307014.69
Manganese (Mn) 4.95 5 99 1.78mg/L -1307014.95
Strontium (Sr) 5.06 5 97.8 2.82mg/L -1307015.06
Zinc (Zn) 4.96 5 99.2 2.09mg/L -1307014.96
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010992
Aluminum (Al) 4.87 5 97.3mg/L -1307014.87
Duke Energy Analytical Lab
Page 12 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040382 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010992
Barium (Ba) 5.06 5 101mg/L -1307015.06
Boron (B) 4.9 5 97.8mg/L -1307014.9
Iron (Fe) 4.83 5 94.3mg/L -1307014.83
Manganese (Mn) 5.03 5 99.3mg/L -1307015.03
Strontium (Sr) 4.82 5 95.5mg/L -1307014.82
Zinc (Zn) 4.94 5 98.8mg/L -1307014.94
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17040035 -- 2017010992
Aluminum (Al) 4.92 5 98.1 0.88mg/L -1307014.92
Barium (Ba) 5.04 5 100 0.358mg/L -1307015.04
Boron (B) 4.88 5 97.4 0.41mg/L -1307014.88
Iron (Fe) 4.83 5 94.2 0.0849mg/L -1307014.83
Manganese (Mn) 5.03 5 99.2 0.121mg/L -1307015.03
Strontium (Sr) 4.79 5 95 0.567mg/L -1307014.79
Zinc (Zn) 4.96 5 99.2 0.424mg/L -1307014.96
Duke Energy Analytical Lab
Page 13 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040357 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca)mg/L -10.0015 0.01 < 1/2 RDL
Magnesium (Mg)mg/L -1-0.003 0.005 < 1/2 RDL
Potassium (K)mg/L -10.0002 0.1 < 1/2 RDL
Sodium (Na)mg/L -1-0.027 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.05 2 103mg/L -1158512.05
Magnesium (Mg) 2.02 2 101mg/L -1158512.02
Potassium (K) 4.02 4 100mg/L -1158514.02
Sodium (Na) 8.34 8.1 103mg/L -1158518.34
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010453
Calcium (Ca) 10.2 5 102mg/L -13070110.2
Magnesium (Mg) 6.28 5 101mg/L -1307016.28
Potassium (K) 8.41 5 102mg/L -1307018.41
Sodium (Na) 6.71 5 102mg/L -1307016.71
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010453
Calcium (Ca) 10.3 5 104 1.97mg/L -13070110.3
Magnesium (Mg) 6.33 5 102 0.93mg/L -1307016.33
Potassium (K) 8.5 5 104 1.84mg/L -1307018.5
Sodium (Na) 6.74 5 103 0.546mg/L -1307016.74
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17030451 -- 2017012164
Calcium (Ca) 54 5 90.8mg/L -13070154
Magnesium (Mg) 20 5 98.6mg/L -13070120
Potassium (K) 12.4 5 98.7mg/L -13070112.4
Sodium (Na) 23.5 5 100mg/L -13070123.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17030451 -- 2017012164
Calcium (Ca) 54.3 5 96.4 6.02mg/L -13070154.3
Magnesium (Mg) 20.2 5 102 3.1mg/L -13070120.2
Potassium (K) 12.5 5 100 1.47mg/L -13070112.5
Sodium (Na) 23.5 5 101 0.715mg/L -13070123.5
Duke Energy Analytical Lab
Page 14 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040206 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al)mg/L -10.001 0.005 < 1/2 RDL
Barium (Ba) 0.000214 mg/L -10.000214 0.005 < 1/2 RDL
Boron (B) -0.00203 mg/L -1-0.00203 0.05 < 1/2 RDL
Iron (Fe) 0.000973 mg/L -10.000973 0.01 < 1/2 RDL
Manganese (Mn) 0.00042 mg/L -10.00042 0.005 < 1/2 RDL
Strontium (Sr) 0.000798 mg/L -10.000798 0.005 < 1/2 RDL
Zinc (Zn) 0.000909 mg/L -10.000909 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al)5 95.4mg/L -1158514.77
Barium (Ba) 5 5 100mg/L -1158515
Boron (B) 4.91 5 98.2mg/L -1158514.91
Iron (Fe) 4.99 5 99.9mg/L -1158514.99
Manganese (Mn) 5.02 5 100mg/L -1158515.02
Strontium (Sr) 4.92 5 98.4mg/L -1158514.92
Zinc (Zn) 5.07 5 101mg/L -1158515.07
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008372
Aluminum (Al)5mg/L -130701Not Tested
Barium (Ba) 5.09 5 98.8mg/L -1307015.09
Boron (B) 4.92 5 98.4mg/L -1307014.92
Iron (Fe) 4.99 5 98.7mg/L -1307014.99
Manganese (Mn) 4.94 5 98.7mg/L -1307014.94
Strontium (Sr) 5.07 5 97.5mg/L -1307015.07
Zinc (Zn) 4.92 5 98.2mg/L -1307014.92
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008372
Aluminum (Al)5mg/L -130701Not Tested
Barium (Ba) 4.93 5 95.6 3.25mg/L -1307014.93
Boron (B) 4.65 5 92.9 5.73mg/L -1307014.65
Iron (Fe) 4.85 5 95.7 3.04mg/L -1307014.85
Manganese (Mn) 4.78 5 95.5 3.3mg/L -1307014.78
Strontium (Sr) 4.83 5 92.7 5.01mg/L -1307014.83
Zinc (Zn) 4.76 5 95 3.27mg/L -1307014.76
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Aluminum (Al) 5.18 5 99.1mg/L -1307015.18
Duke Energy Analytical Lab
Page 15 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040206 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Barium (Ba) 4.98 5 98.9mg/L -1307014.98
Boron (B) 5.35 5 98.2mg/L -1307015.35
Iron (Fe) 7.08 5 97.5mg/L -1307017.08
Manganese (Mn) 7.17 5 98.5mg/L -1307017.17
Strontium (Sr) 4.99 5 96mg/L -1307014.99
Zinc (Zn) 4.95 5 99mg/L -1307014.95
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Aluminum (Al) 4.92 5 93.9 5.39mg/L -1307014.92
Barium (Ba) 4.69 5 93.1 6.06mg/L -1307014.69
Boron (B) 5.07 5 92.6 5.85mg/L -1307015.07
Iron (Fe) 6.83 5 92.5 5.31mg/L -1307016.83
Manganese (Mn) 6.93 5 93.6 5.14mg/L -1307016.93
Strontium (Sr) 4.79 5 92 4.21mg/L -1307014.79
Zinc (Zn) 4.64 5 92.8 6.44mg/L -1307014.64
Duke Energy Analytical Lab
Page 16 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040356 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.035 ug/L -1-0.035 1 < 1/2 RDL
Arsenic (As) 0.014 ug/L -10.014 1 < 1/2 RDL
Beryllium (Be) -0.059 ug/L -1-0.059 1 < 1/2 RDL
Cadmium (Cd) 0 ug/L -10 1 < 1/2 RDL
Chromium (Cr) -0.007 ug/L -1-0.007 1 < 1/2 RDL
Cobalt (Co) 0.001 ug/L -10.001 1 < 1/2 RDL
Copper (Cu) 0.047 ug/L -10.047 1 < 1/2 RDL
Lead (Pb) 0.002 ug/L -10.002 1 < 1/2 RDL
Molybdenum (Mo) 0.006 ug/L -10.006 1 < 1/2 RDL
Nickel (Ni) -0.031 ug/L -1-0.031 1 < 1/2 RDL
Selenium (Se) 0.026 ug/L -10.026 1 < 1/2 RDL
Thallium (Tl) Low Level -0.032 ug/L -1-0.032 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.033 ug/L -10.033 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 48.9 50 97.7ug/L -11585148.9
Arsenic (As) 49.6 50 99.3ug/L -11585149.6
Beryllium (Be) 50.7 50 101ug/L -11585150.7
Cadmium (Cd) 49.8 50 99.7ug/L -11585149.8
Chromium (Cr) 50.1 50 100ug/L -11585150.1
Cobalt (Co) 49.2 50 98.3ug/L -11585149.2
Copper (Cu) 50.4 50 101ug/L -11585150.4
Lead (Pb) 49.5 50 99ug/L -11585149.5
Molybdenum (Mo) 51.1 50 102ug/L -11585151.1
Nickel (Ni) 49.8 50 99.6ug/L -11585149.8
Selenium (Se) 47.9 50 95.7ug/L -11585147.9
Thallium (Tl) Low Level 49 50 98ug/L -11585149
Vanadium (V) Low Level 49.7 50 99.4ug/L -11585149.7
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Antimony (Sb) 51.9 50 104ug/L -13070151.9
Arsenic (As) 51.5 50 103ug/L -13070151.5
Beryllium (Be) 51.8 50 103ug/L -13070151.8
Cadmium (Cd) 50.7 50 101ug/L -13070150.7
Chromium (Cr) 51.5 50 103ug/L -13070151.5
Cobalt (Co) 51.4 50 101ug/L -13070151.4
Copper (Cu) 55.5 50 103ug/L -13070155.5
Lead (Pb) 50.9 50 101ug/L -13070150.9
Duke Energy Analytical Lab
Page 17 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040356 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Molybdenum (Mo) 52.8 50 105ug/L -13070152.8
Nickel (Ni) 51.8 50 103ug/L -13070151.8
Selenium (Se) 48.8 50 97.4ug/L -13070148.8
Thallium (Tl) Low Level 49 50 98.1ug/L -13070149
Vanadium (V) Low Level 51.6 50 103ug/L -13070151.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Antimony (Sb) 49.4 50 98.6 4.97ug/L -13070149.4
Arsenic (As) 49.2 50 97.9 4.61ug/L -13070149.2
Beryllium (Be) 52.4 50 105 1.28ug/L -13070152.4
Cadmium (Cd) 48.4 50 96.8 4.67ug/L -13070148.4
Chromium (Cr) 49.1 50 98.1 4.92ug/L -13070149.1
Cobalt (Co) 49.1 50 96.4 4.76ug/L -13070149.1
Copper (Cu) 52.6 50 96.9 5.93ug/L -13070152.6
Lead (Pb) 48.7 50 97.1 4.43ug/L -13070148.7
Molybdenum (Mo) 50.2 50 100 5.1ug/L -13070150.2
Nickel (Ni) 49.8 50 98.8 3.86ug/L -13070149.8
Selenium (Se) 46.8 50 93.4 4.2ug/L -13070146.8
Thallium (Tl) Low Level 46.1 50 92.3 6.15ug/L -13070146.1
Vanadium (V) Low Level 49 50 97.9 5.07ug/L -13070149
Duke Energy Analytical Lab
Page 18 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040213 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.054 ug/L -10.054 1 < 1/2 RDL
Arsenic (As) 0.021 ug/L -10.021 1 < 1/2 RDL
Beryllium (Be) -0.047 ug/L -1-0.047 1 < 1/2 RDL
Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL
Chromium (Cr) -0.086 ug/L -1-0.086 1 < 1/2 RDL
Cobalt (Co) -0.002 ug/L -1-0.002 1 < 1/2 RDL
Copper (Cu) -0.015 ug/L -1-0.015 1 < 1/2 RDL
Lead (Pb) 0.002 ug/L -10.002 1 < 1/2 RDL
Molybdenum (Mo) 0.007 ug/L -10.007 1 < 1/2 RDL
Nickel (Ni) -0.301 ug/L -1-0.301 1 < 1/2 RDL
Selenium (Se) -0.01 ug/L -1-0.01 1 < 1/2 RDL
Thallium (Tl) Low Level 0.001 ug/L -10.001 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.036 ug/L -10.036 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 48.6 50 97.3ug/L -11585148.6
Arsenic (As) 47.8 50 95.6ug/L -11585147.8
Beryllium (Be) 51.9 50 104ug/L -11585151.9
Cadmium (Cd) 48.6 50 97.3ug/L -11585148.6
Chromium (Cr) 48.1 50 96.2ug/L -11585148.1
Cobalt (Co) 47.3 50 94.5ug/L -11585147.3
Copper (Cu) 47.7 50 95.4ug/L -11585147.7
Lead (Pb) 48.9 50 97.9ug/L -11585148.9
Molybdenum (Mo) 49 50 97.9ug/L -11585149
Nickel (Ni) 47.4 50 94.8ug/L -11585147.4
Selenium (Se) 45.7 50 91.4ug/L -11585145.7
Thallium (Tl) Low Level 49.3 50 98.6ug/L -11585149.3
Vanadium (V) Low Level 47.5 50 94.9ug/L -11585147.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008373
Antimony (Sb) 53.3 50 104ug/L -13070153.3
Arsenic (As) 50.1 50 99.6ug/L -13070150.1
Beryllium (Be) 54.5 50 109ug/L -13070154.5
Cadmium (Cd) 51 50 102ug/L -13070151
Chromium (Cr) 55 50 99.6ug/L -13070155
Cobalt (Co) 48.7 50 96.1ug/L -13070148.7
Copper (Cu) 51.4 50 97.5ug/L -13070151.4
Lead (Pb) 51.6 50 103ug/L -13070151.6
Duke Energy Analytical Lab
Page 19 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040213 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008373
Molybdenum (Mo) 60.2 50 105ug/L -13070160.2
Nickel (Ni) 52.5 50 97.4ug/L -13070152.5
Selenium (Se) 47.6 50 95.1ug/L -13070147.6
Thallium (Tl) Low Level 53.4 50 107ug/L -13070153.4
Vanadium (V) Low Level 52.8 50 101ug/L -13070152.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008373
Antimony (Sb) 51.2 50 99.3 4.15ug/L -13070151.2
Arsenic (As) 48 50 95.4 4.31ug/L -13070148
Beryllium (Be) 53 50 106 2.75ug/L -13070153
Cadmium (Cd) 48.9 50 97.5 4.26ug/L -13070148.9
Chromium (Cr) 53.4 50 96.3 3.31ug/L -13070153.4
Cobalt (Co) 46.6 50 92 4.33ug/L -13070146.6
Copper (Cu) 49.4 50 93.6 4.08ug/L -13070149.4
Lead (Pb) 49.6 50 98.9 3.99ug/L -13070149.6
Molybdenum (Mo) 57.7 50 99.6 4.91ug/L -13070157.7
Nickel (Ni) 50.2 50 92.7 4.89ug/L -13070150.2
Selenium (Se) 46.2 50 92.2 3.13ug/L -13070146.2
Thallium (Tl) Low Level 51.5 50 103 3.59ug/L -13070151.5
Vanadium (V) Low Level 50.9 50 97.4 3.89ug/L -13070150.9
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Antimony (Sb) 53.1 50 106ug/L -13070153.1
Arsenic (As) 51 50 101ug/L -13070151
Beryllium (Be) 54 50 108ug/L -13070154
Cadmium (Cd) 52 50 104ug/L -13070152
Chromium (Cr) 52.2 50 104ug/L -13070152.2
Cobalt (Co) 50.8 50 99.8ug/L -13070150.8
Copper (Cu) 51.1 50 101ug/L -13070151.1
Lead (Pb) 52.9 50 105ug/L -13070152.9
Molybdenum (Mo) 52.7 50 105ug/L -13070152.7
Nickel (Ni) 51 50 102ug/L -13070151
Selenium (Se) 49 50 97.8ug/L -13070149
Thallium (Tl) Low Level 54.6 50 109ug/L -13070154.6
Vanadium (V) Low Level 52.5 50 104ug/L -13070152.5
Duke Energy Analytical Lab
Page 20 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040213 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17040240 -- 2017011885
Antimony (Sb) 50.1 50 100 5.94ug/L -13070150.1
Arsenic (As) 48.3 50 95.9 5.5ug/L -13070148.3
Beryllium (Be) 51.9 50 104 3.97ug/L -13070151.9
Cadmium (Cd) 49.4 50 98.7 5.29ug/L -13070149.4
Chromium (Cr) 49.4 50 98.5 5.45ug/L -13070149.4
Cobalt (Co) 47.7 50 93.5 6.44ug/L -13070147.7
Copper (Cu) 48.1 50 95 6.06ug/L -13070148.1
Lead (Pb) 49.6 50 98.8 6.49ug/L -13070149.6
Molybdenum (Mo) 49.7 50 99 5.9ug/L -13070149.7
Nickel (Ni) 48.1 50 96 5.87ug/L -13070148.1
Selenium (Se) 53.1 50 106 8.02ug/L -13070153.1
Thallium (Tl) Low Level 51.6 50 103 5.59ug/L -13070151.6
Vanadium (V) Low Level 49.2 50 97.2 6.46ug/L -13070149.2
Duke Energy Analytical Lab
Page 21 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040293 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030095 -- 2017007164
TDS 233 0.428mg/L -1233
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030151 -- 2017007409
TDS 233 0.43mg/L -1233
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17040216 -- 2017011780
TDS 82 3.59mg/L -182
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J17040216 -- 2017011789
TDS 77 2.56mg/L -177
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 98 100 98mg/L -11090198
Duke Energy Analytical Lab
Page 22 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040217 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.022 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.052 0.1 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
TOC mg/L -10.046 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 106mg/L -1208012.32
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 103 3.1mg/L -1208012.25
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 101mg/L -1208013.37
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 100 1.04mg/L -1208013.35
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 99mg/L -1208016.02
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 91 8.37mg/L -1208015.87
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 105mg/L -1158513.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 105mg/L -1158513.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
TOC 2.87 107mg/L -1158513.08
Duke Energy Analytical Lab
Page 23 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040240
Q17040244 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030185 -- 2017007576
TSS 0.6 100mg/L -10.6
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030266 -- 2017007989
TSS 1.6 11.8mg/L -11.6
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030266 -- 2017007991
TSS 3.2 0mg/L -13.2
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J17030266 -- 2017007993
TSS 5.6 3.51mg/L -15.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50.8 50 102mg/L -11090150.8
Duke Energy Analytical Lab
Page 24 of 44
#=CL#
April 15, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92336429
92336429
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17040240
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 07, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
1(704)875-9092
Enclosures
cc:Program Manager, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 19
Duke Energy Analytical Lab
Page 25 of 44
#=CP#
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Pace Project No.:
Project:
92336429
J17040240
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West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Duke Energy Analytical Lab
Page 26 of 44
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92336429
J17040240
Lab ID Sample ID Matrix Date Collected Date Received
92336429001 2017011885 Water 04/07/17 08:35 04/07/17 13:40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Duke Energy Analytical Lab
Page 27 of 44
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92336429
J17040240
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92336429001 2017011885 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF1
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Duke Energy Analytical Lab
Page 28 of 44
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92336429
J17040240
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92336429001 2017011885
Methane 324 ug/L 04/12/17 22:3510.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)44.4 mg/L 04/12/17 16:155.0SM 2320B
Alkalinity, Total as CaCO3 44.4 mg/L 04/12/17 16:155.0SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
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Duke Energy Analytical Lab
Page 29 of 44
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92336429
J17040240
Method:
Client:Duke Energy
RSK 175 Modified
Date:April 15, 2017
Description:RSK 175 Headspace
General Information:
1 sample was analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
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Duke Energy Analytical Lab
Page 30 of 44
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92336429
J17040240
Method:
Client:Duke Energy
SM 2320B
Date:April 15, 2017
Description:2320B Alkalinity
General Information:
1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 7 of 19
Duke Energy Analytical Lab
Page 31 of 44
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92336429
J17040240
Method:
Client:Duke Energy
SM 4500-S2D
Date:April 15, 2017
Description:4500S2D Sulfide Water
General Information:
1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 356425
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92336426003,92336462002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1977383)
• Sulfide
• MSD (Lab ID: 1977384)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 8 of 19
Duke Energy Analytical Lab
Page 32 of 44
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92336429
J17040240
Method:
Client:Duke Energy
EPA 218.7
Date:April 15, 2017
Description:Hexavalent Chromium by IC
General Information:
1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 362203
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2017011885 (Lab ID: 92336429001)
• Chromium, Hexavalent
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
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Duke Energy Analytical Lab
Page 33 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92336429
J17040240
Sample:2017011885 Lab ID:92336429001 Collected:04/07/17 08:35 Received:04/07/17 13:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 324 ug/L 04/12/17 22:35 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)44.4 mg/L 04/12/17 16:155.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/12/17 16:155.0 1
Alkalinity, Total as CaCO3 44.4 mg/L 04/12/17 16:155.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/17 13:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/14/17 15:42 18540-29-9 D30.12 5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/15/2017 03:17 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 19
Duke Energy Analytical Lab
Page 34 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92336429
J17040240
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
356330
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92336429001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1976673
Associated Lab Samples:92336429001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/12/17 18:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1976674LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 342396 86 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1976675MATRIX SPIKE SAMPLE:
MSSpike
Result
92336423005
Methane ug/L 441396 109 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/15/2017 03:17 PM
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[phone]
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Duke Energy Analytical Lab
Page 35 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92336429
J17040240
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
356278
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92336429001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1976401
Associated Lab Samples:92336429001
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/12/17 11:59
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/12/17 11:59
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/12/17 11:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1976402LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.850 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1976403MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92336423008
1976404
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 107 80-120107 0 255063.6 117 117
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1976405MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92336426009
1976406
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-120102 1 255074.8 124 126
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/15/2017 03:17 PM
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[phone]
Page 12 of 19
Duke Energy Analytical Lab
Page 36 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92336429
J17040240
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
356425
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92336429001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1977379
Associated Lab Samples:92336429001
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/13/17 13:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1977380LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.49.5 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1977381MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92336426003
1977382
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 85 80-12085 0 10.5ND 0.52 0.52
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1977383MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92336462002
1977384
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 79 80-12079 0 10.5ND 0.40 0.40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/15/2017 03:17 PM
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[phone]
Page 13 of 19
Duke Energy Analytical Lab
Page 37 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92336429
J17040240
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
362203
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92336429001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1952149
Associated Lab Samples:92336429001
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 04/14/17 11:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1952150LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.078.075 103 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1952151MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92336052009
1952152
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 105 85-115103 1 20.0750.083 0.16 0.16
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1952153MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92336032009
1952154
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .12 106 85-11595 5 20.120.16 0.30 0.28
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/15/2017 03:17 PM
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Duke Energy Analytical Lab
Page 38 of 44
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92336429
J17040240
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/15/2017 03:17 PM
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[phone]
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Duke Energy Analytical Lab
Page 39 of 44
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92336429
J17040240
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92336429001 3563302017011885RSK 175 Modified
92336429001 3562782017011885SM 2320B
92336429001 3564252017011885SM 4500-S2D
92336429001 3622032017011885EPA 218.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/15/2017 03:17 PM
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Duke Energy Analytical Lab
Page 40 of 44
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Duke Energy Analytical Lab
Page 41 of 44
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Duke Energy Analytical Lab
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Duke Energy Analytical Lab
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Duke Energy Analytical Lab
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