NC0038377_J17030696report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17030696
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:4/20/2017
Customer Address:Mayo Steam Plant
Customer Name(s):Bryan Moeller, Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy We
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Dissolved copper was detected both in the filter blank and associated groundwater samples in this workorder. This could
potentially be due to poor filtration apparatus flushing in the field.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 79
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2017010453 MAYO STEAM 28-Mar-17 9:45 AM Synterra MW -12S
2017010455 MAYO STEAM 28-Mar-17 9:56 AM Synterra MW-12D
2017010456 MAYO STEAM 28-Mar-17 10:53 AM Synterra MW-2
2017010457 MAYO STEAM 28-Mar-17 11:28 AM Synterra BG-1
2017010458 MAYO STEAM 28-Mar-17 1:06 PM Synterra MW-3
2017010459 MAYO STEAM 28-Mar-17 2:00 PM Synterra Filter Blank
2017010460 MAYO STEAM 28-Mar-17 2:00 PM Synterra Equipment Blank
7 Total Samples
Duke Energy Analytical Lab
Page 2 of 79
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:4/19/2017
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010453
Collection Date:28-Mar-17 9:45 AM
Site:MW -12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2017 13:06 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 0.56 mg/L EPA 300.0 03/30/2017 19:29 BGN90340.1 1
Sulfate 0.95 mg/L EPA 300.0 03/30/2017 19:29 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 12:30 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/13/2017 14:22 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.060 mg/L EPA 200.7 04/05/2017 12:16 JJMACKE0.005 1
Barium (Ba)0.012 mg/L EPA 200.7 04/05/2017 12:16 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/05/2017 12:16 JJMACKE0.05 1
Iron (Fe)5.61 mg/L EPA 200.7 04/05/2017 12:16 JJMACKE0.01 1
Manganese (Mn)0.399 mg/L EPA 200.7 04/05/2017 12:16 JJMACKE0.005 1
Strontium (Sr)0.026 mg/L EPA 200.7 04/05/2017 12:16 JJMACKE0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 04/05/2017 12:16 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.10 mg/L EPA 200.7 04/17/2017 15:39 SLS25600.01 1
Magnesium (Mg)1.25 mg/L EPA 200.7 04/17/2017 15:39 SLS25600.005 1
Potassium (K)3.29 mg/L EPA 200.7 04/17/2017 15:39 SLS25600.1 1
Sodium (Na)1.59 mg/L EPA 200.7 04/17/2017 15:39 SLS25600.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.413 mg/L EPA 200.7 03/30/2017 11:59 MHH71310.005 1
Barium (Ba)0.013 mg/L EPA 200.7 03/30/2017 11:59 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/30/2017 11:59 MHH71310.05 1
Iron (Fe)6.82 mg/L EPA 200.7 03/30/2017 11:59 MHH71310.01 1
Manganese (Mn)0.395 mg/L EPA 200.7 03/30/2017 11:59 MHH71310.005 1
Strontium (Sr)0.027 mg/L EPA 200.7 03/30/2017 11:59 MHH71310.005 1
Zinc (Zn)0.021 mg/L EPA 200.7 03/30/2017 11:59 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010453
Collection Date:28-Mar-17 9:45 AM
Site:MW -12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Arsenic (As)1.05 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Cobalt (Co)1.46 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Copper (Cu)4.99 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Molybdenum (Mo)1.79 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Nickel (Ni)1.55 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR0.2 1
Vanadium (V) Low Level 2.13 ug/L EPA 200.8 04/06/2017 20:35 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Arsenic (As)1.11 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Chromium (Cr)1.06 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Cobalt (Co)1.59 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Copper (Cu)3.73 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Lead (Pb)1.42 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Molybdenum (Mo)1.97 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Nickel (Ni)1.79 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR0.2 1
Vanadium (V) Low Level 2.80 ug/L EPA 200.8 04/06/2017 18:10 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 51 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 5 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010453
Collection Date:28-Mar-17 9:45 AM
Site:MW -12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 8.1 mg/L SM5310C/EPA9060A 04/10/2017 15:09B3 CJELLIO0.5 5
TOTAL SUSPENDED SOLIDS
TSS 17 mg/L SM2540D 03/30/2017 10:00 MGIGANT141
Duke Energy Analytical Lab
Page 6 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010455
Collection Date:28-Mar-17 9:56 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.190 mg-N/L EPA 353.2 04/07/2017 13:12 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.3 mg/L EPA 300.0 03/30/2017 19:46 BGN90340.1 1
Sulfate 1.1 mg/L EPA 300.0 03/30/2017 19:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 12:32 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/13/2017 14:25 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/05/2017 12:20 JJMACKE0.005 1
Barium (Ba)0.013 mg/L EPA 200.7 04/05/2017 12:20 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/05/2017 12:20 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/05/2017 12:20 JJMACKE0.01 1
Manganese (Mn)0.035 mg/L EPA 200.7 04/05/2017 12:20 JJMACKE0.005 1
Strontium (Sr)0.086 mg/L EPA 200.7 04/05/2017 12:20 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/05/2017 12:20 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)12.1 mg/L EPA 200.7 04/17/2017 15:52 SLS25600.01 1
Magnesium (Mg)3.20 mg/L EPA 200.7 04/17/2017 15:52 SLS25600.005 1
Potassium (K)1.41 mg/L EPA 200.7 04/17/2017 15:52 SLS25600.1 1
Sodium (Na)9.26 mg/L EPA 200.7 04/17/2017 15:52 SLS25600.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.140 mg/L EPA 200.7 03/30/2017 12:03 MHH71310.005 1
Barium (Ba)0.015 mg/L EPA 200.7 03/30/2017 12:03 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/30/2017 12:03 MHH71310.05 1
Iron (Fe)0.242 mg/L EPA 200.7 03/30/2017 12:03 MHH71310.01 1
Manganese (Mn)0.045 mg/L EPA 200.7 03/30/2017 12:03 MHH71310.005 1
Strontium (Sr)0.085 mg/L EPA 200.7 03/30/2017 12:03 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2017 12:03 MHH71310.005 1
Duke Energy Analytical Lab
Page 7 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010455
Collection Date:28-Mar-17 9:56 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Copper (Cu)2.34 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Nickel (Ni)1.12 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR0.2 1
Vanadium (V) Low Level 0.511 ug/L EPA 200.8 04/06/2017 21:04 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Chromium (Cr)1.25 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Copper (Cu)1.24 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Nickel (Ni)1.29 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR0.2 1
Vanadium (V) Low Level 0.805 ug/L EPA 200.8 04/06/2017 18:17 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 96 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 8 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010455
Collection Date:28-Mar-17 9:56 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.192 mg/L SM5310C/EPA9060A 04/10/2017 15:09B3 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 03/30/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 9 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010456
Collection Date:28-Mar-17 10:53 AM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.156 mg-N/L EPA 353.2 04/07/2017 13:16 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 03/30/2017 20:04 BGN90340.5 5
Sulfate 18 mg/L EPA 300.0 03/30/2017 20:04 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 12:35 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/13/2017 14:27 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/05/2017 12:24 JJMACKE0.005 1
Barium (Ba)0.049 mg/L EPA 200.7 04/05/2017 12:24 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/05/2017 12:24 JJMACKE0.05 1
Iron (Fe)0.333 mg/L EPA 200.7 04/05/2017 12:24 JJMACKE0.01 1
Manganese (Mn)0.515 mg/L EPA 200.7 04/05/2017 12:24 JJMACKE0.005 1
Strontium (Sr)0.178 mg/L EPA 200.7 04/05/2017 12:24 JJMACKE0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 04/05/2017 12:24 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)18.6 mg/L EPA 200.7 04/17/2017 15:56 SLS25600.01 1
Magnesium (Mg)7.66 mg/L EPA 200.7 04/17/2017 15:56 SLS25600.005 1
Potassium (K)3.68 mg/L EPA 200.7 04/17/2017 15:56 SLS25600.1 1
Sodium (Na)31.1 mg/L EPA 200.7 04/17/2017 15:56 SLS25600.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.477 mg/L EPA 200.7 03/30/2017 12:07 MHH71310.005 1
Barium (Ba)0.051 mg/L EPA 200.7 03/30/2017 12:07 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/30/2017 12:07 MHH71310.05 1
Iron (Fe)0.574 mg/L EPA 200.7 03/30/2017 12:07 MHH71310.01 1
Manganese (Mn)0.564 mg/L EPA 200.7 03/30/2017 12:07 MHH71310.005 1
Strontium (Sr)0.184 mg/L EPA 200.7 03/30/2017 12:07 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2017 12:07 MHH71310.005 1
Duke Energy Analytical Lab
Page 10 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010456
Collection Date:28-Mar-17 10:53 AM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Cobalt (Co)1.61 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Copper (Cu)2.03 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Molybdenum (Mo)2.11 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Nickel (Ni)3.70 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR0.2 1
Vanadium (V) Low Level 0.422 ug/L EPA 200.8 04/06/2017 19:44 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Cobalt (Co)1.88 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Copper (Cu)1.14 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Molybdenum (Mo)1.63 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Nickel (Ni)3.11 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR0.2 1
Vanadium (V) Low Level 0.684 ug/L EPA 200.8 04/06/2017 18:24 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 11 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010456
Collection Date:28-Mar-17 10:53 AM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.7 mg/L SM5310C/EPA9060A 04/10/2017 15:09B3 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 03/30/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 12 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010457
Collection Date:28-Mar-17 11:28 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.834 mg-N/L EPA 353.2 04/07/2017 13:17 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 03/30/2017 21:48 BGN90340.2 2
Sulfate 0.25 mg/L EPA 300.0 03/30/2017 21:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 12:37 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/13/2017 14:39 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/05/2017 12:48 JJMACKE0.005 1
Barium (Ba)0.088 mg/L EPA 200.7 04/05/2017 12:48 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/05/2017 12:48 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/05/2017 12:48 JJMACKE0.01 1
Manganese (Mn)0.007 mg/L EPA 200.7 04/05/2017 12:48 JJMACKE0.005 1
Strontium (Sr)0.166 mg/L EPA 200.7 04/05/2017 12:48 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 04/05/2017 12:48 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)12.9 mg/L EPA 200.7 04/17/2017 16:00 SLS25600.01 1
Magnesium (Mg)3.28 mg/L EPA 200.7 04/17/2017 16:00 SLS25600.005 1
Potassium (K)1.38 mg/L EPA 200.7 04/17/2017 16:00 SLS25600.1 1
Sodium (Na)12.5 mg/L EPA 200.7 04/17/2017 16:00 SLS25600.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.218 mg/L EPA 200.7 03/30/2017 12:11 MHH71310.005 1
Barium (Ba)0.087 mg/L EPA 200.7 03/30/2017 12:11 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/30/2017 12:11 MHH71310.05 1
Iron (Fe)0.137 mg/L EPA 200.7 03/30/2017 12:11 MHH71310.01 1
Manganese (Mn)0.010 mg/L EPA 200.7 03/30/2017 12:11 MHH71310.005 1
Strontium (Sr)0.173 mg/L EPA 200.7 03/30/2017 12:11 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2017 12:11 MHH71310.005 1
Duke Energy Analytical Lab
Page 13 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010457
Collection Date:28-Mar-17 11:28 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Copper (Cu)1.59 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Nickel (Ni)1.38 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR0.2 1
Vanadium (V) Low Level 3.62 ug/L EPA 200.8 04/06/2017 21:12 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Nickel (Ni)1.41 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR0.2 1
Vanadium (V) Low Level 4.00 ug/L EPA 200.8 04/06/2017 18:31 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 14 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010457
Collection Date:28-Mar-17 11:28 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.640 mg/L SM5310C/EPA9060A 04/10/2017 15:09B3 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 03/30/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 15 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010458
Collection Date:28-Mar-17 1:06 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.072 mg-N/L EPA 353.2 04/07/2017 13:18 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 50 mg/L EPA 300.0 03/30/2017 20:38 BGN9034110
Sulfate 22 mg/L EPA 300.0 03/30/2017 20:38 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 12:40 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/13/2017 14:47 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/05/2017 12:52 JJMACKE0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 04/05/2017 12:52 JJMACKE0.005 1
Boron (B)1.03 mg/L EPA 200.7 04/05/2017 12:52 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/05/2017 12:52 JJMACKE0.01 1
Manganese (Mn)1.02 mg/L EPA 200.7 04/05/2017 12:52 JJMACKE0.005 1
Strontium (Sr)0.332 mg/L EPA 200.7 04/05/2017 12:52 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/05/2017 12:52 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)29.5 mg/L EPA 200.7 04/17/2017 16:04 SLS25600.01 1
Magnesium (Mg)9.33 mg/L EPA 200.7 04/17/2017 16:04 SLS25600.005 1
Potassium (K)2.06 mg/L EPA 200.7 04/17/2017 16:04 SLS25600.1 1
Sodium (Na)23.1 mg/L EPA 200.7 04/17/2017 16:04 SLS25600.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 03/30/2017 12:15 MHH71310.005 1
Barium (Ba)0.056 mg/L EPA 200.7 03/30/2017 12:15 MHH71310.005 1
Boron (B)0.982 mg/L EPA 200.7 03/30/2017 12:15 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 03/30/2017 12:15 MHH71310.01 1
Manganese (Mn)1.28 mg/L EPA 200.7 03/30/2017 12:15 MHH71310.005 1
Strontium (Sr)0.334 mg/L EPA 200.7 03/30/2017 12:15 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2017 12:15 MHH71310.005 1
Duke Energy Analytical Lab
Page 16 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010458
Collection Date:28-Mar-17 1:06 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Copper (Cu)4.29 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Nickel (Ni)3.36 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2017 21:19 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Nickel (Ni)3.74 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2017 18:39 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 17 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010458
Collection Date:28-Mar-17 1:06 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.0 mg/L SM5310C/EPA9060A 04/10/2017 15:09B3 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 03/30/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 18 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010459
Collection Date:28-Mar-17 2:00 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/13/2017 14:49 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/05/2017 12:56 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/05/2017 12:56 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/05/2017 12:56 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/05/2017 12:56 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/05/2017 12:56 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/05/2017 12:56 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/05/2017 12:56 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Copper (Cu)2.90 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2017 21:26 PARMSTR0.3 1
Duke Energy Analytical Lab
Page 19 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010460
Collection Date:28-Mar-17 2:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2017 13:20 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 03/30/2017 20:56 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 03/30/2017 20:56 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/17/2017 12:42 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 04/17/2017 16:08 SLS25600.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/17/2017 16:08 SLS25600.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/17/2017 16:08 SLS25600.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/17/2017 16:08 SLS25600.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 03/30/2017 12:19 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 03/30/2017 12:19 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/30/2017 12:19 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 03/30/2017 12:19 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 03/30/2017 12:19 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 03/30/2017 12:19 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2017 12:19 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2017 18:46 PARMSTR0.3 1
Duke Energy Analytical Lab
Page 20 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
2017010460
Collection Date:28-Mar-17 2:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.200 mg/L SM5310C/EPA9060A 04/10/2017 15:09B3 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 03/30/2017 10:00 MGIGANT51
Qualifiers:
B3 Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than ½ the
reporting limit, but less than the reporting limit.
Duke Energy Analytical Lab
Page 21 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17040148 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0013 mg-N/L -10.0013 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0003 mg-N/L -10.0003 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0005 mg-N/L -1-0.0005 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0023 mg-N/L -10.0023 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 5
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0013 mg-N/L -10.0013 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 6
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0003 mg-N/L -1-0.0003 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.306 3.01 102mg-N/L -11090103.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.3 3.01 99.8mg-N/L -11090103
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.3 3.01 99.7mg-N/L -11090103
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.302 3.01 100mg-N/L -11090103.02
Duke Energy Analytical Lab
Page 22 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17040148 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 5
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 100mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 6
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.3 3.01 99.6mg-N/L -11090103
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020179 -- 2017004257
Nitrite + Nitrate
(Colorimetric)
0.25 0.25 97.1mg-N/L -1109010.25
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020179 -- 2017004257
Nitrite + Nitrate
(Colorimetric)
0.251 0.25 97.4 0.319mg-N/L -1109010.251
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010455
Nitrite + Nitrate
(Colorimetric)
0.432 0.25 97mg-N/L -1109010.432
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010455
Nitrite + Nitrate
(Colorimetric)
0.431 0.25 96.6 0.278mg-N/L -1109010.431
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17030643 -- 2017010150
Nitrite + Nitrate
(Colorimetric)
0.295 0.25 99.4mg-N/L -1109010.295
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17030643 -- 2017010150
Nitrite + Nitrate
(Colorimetric)
0.291 0.25 97.8 1.3mg-N/L -1109010.291
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17040036 -- 2017010999
Nitrite + Nitrate
(Colorimetric)
0.468 0.25 96.3mg-N/L -1109010.468
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17040036 -- 2017010999
Nitrite + Nitrate
(Colorimetric)
0.468 0.25 96.5 0.107mg-N/L -1109010.468
Duke Energy Analytical Lab
Page 23 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030757 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0356 mg/L -10.0356 0.1 < 1/2 RDL
Sulfate 0.0247 mg/L -10.0247 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Chloride 0.0305 mg/L -10.0305 0.1 < 1/2 RDL
Sulfate -0.017 mg/L -1-0.017 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 7.35 5000 101mg/L -1208010007350
Sulfate 6.66 5000 92.4mg/L -1208010006660
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 7.35 5000 101 0.0514mg/L -1208010007350
Sulfate 6.66 5000 92.4 0.0455mg/L -1208010006660
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 7.66 25 96.6mg/L -12080538.3
Sulfate 8.56 25 99.6mg/L -12080542.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 7.65 25 96.5 0.172mg/L -12080538.3
Sulfate 8.56 25 99.6 0.0221mg/L -12080542.8
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.19 5 104mg/L -1109015.19
Sulfate 5.25 5 105mg/L -1109015.25
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Chloride 5.11 5 102mg/L -1109015.11
Sulfate 5.23 5 105mg/L -1109015.23
Duke Energy Analytical Lab
Page 24 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17040372 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.012 ug/L -10.012 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.92 20 91.9ug/L -130702018.4
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.897 20 89.7 2.48ug/L -130702017.9
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.965 1 95.3ug/L -1307010.965
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.961 1 94.9 0.421ug/L -1307010.961
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.08 2 104ug/L -1158512.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.4ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008374
Mercury (Hg) 0.995 1 98.6ug/L -1307010.995
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030331 -- 2017008374
Mercury (Hg) 1 1 99.4 0.808ug/L -1307011
Duke Energy Analytical Lab
Page 25 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17040320 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.01 100 100ug/L -13070100101
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1 100 99.6 0.8ug/L -13070100100
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.22 2 111ug/L -1158512.22
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010457
Mercury (Hg) 0.969 1 95.9ug/L -1307010.969
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010457
Mercury (Hg) 0.919 1 90.9 5.35ug/L -1307010.919
Duke Energy Analytical Lab
Page 26 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17040082 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000031 mg/L -1-0.000031 0.005 < 1/2 RDL
Barium (Ba) 0.000062 mg/L -10.000062 0.005 < 1/2 RDL
Boron (B) 0.000228 mg/L -10.000228 0.05 < 1/2 RDL
Iron (Fe) -0.000624 mg/L -1-0.000624 0.01 < 1/2 RDL
Manganese (Mn) 0.000085 mg/L -10.000085 0.005 < 1/2 RDL
Strontium (Sr) 0.000145 mg/L -10.000145 0.005 < 1/2 RDL
Zinc (Zn) -0.000139 mg/L -1-0.000139 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.12 2 106mg/L -1158512.12
Barium (Ba) 0.998 1 99.8mg/L -1158510.998
Boron (B) 2.05 2 103mg/L -1158512.05
Iron (Fe) 2.1 2 105mg/L -1158512.1
Manganese (Mn) 0.995 1 99.5mg/L -1158510.995
Strontium (Sr) 1.92 2 95.9mg/L -1158511.92
Zinc (Zn) 1.04 1 104mg/L -1158511.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030466 -- 2017009188
Aluminum (Al) 5.41 5 108mg/L -1307015.41
Barium (Ba) 6.31 5 108mg/L -1307016.31
Boron (B) 5.63 5 110mg/L -1307015.63
Iron (Fe) 5.65 5 105mg/L -1307015.65
Manganese (Mn) 5.78 5 108mg/L -1307015.78
Strontium (Sr) 7.57 5 111mg/L -1307017.57
Zinc (Zn) 5.38 5 108mg/L -1307015.38
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030466 -- 2017009188
Aluminum (Al) 5.39 5 108 0.222mg/L -1307015.39
Barium (Ba) 6.31 5 108 0mg/L -1307016.31
Boron (B) 5.66 5 111 0.525mg/L -1307015.66
Iron (Fe) 5.66 5 105 0.0762mg/L -1307015.66
Manganese (Mn) 5.79 5 108 0.314mg/L -1307015.79
Strontium (Sr) 7.64 5 113 1.32mg/L -1307017.64
Zinc (Zn) 5.38 5 108 0.0743mg/L -1307015.38
Duke Energy Analytical Lab
Page 27 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17040357 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca)mg/L -10.0015 0.01 < 1/2 RDL
Magnesium (Mg)mg/L -1-0.003 0.005 < 1/2 RDL
Potassium (K)mg/L -10.0002 0.1 < 1/2 RDL
Sodium (Na)mg/L -1-0.027 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.05 2 103mg/L -1158512.05
Magnesium (Mg) 2.02 2 101mg/L -1158512.02
Potassium (K) 4.02 4 100mg/L -1158514.02
Sodium (Na) 8.34 8.1 103mg/L -1158518.34
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010453
Calcium (Ca) 10.2 5 102mg/L -13070110.2
Magnesium (Mg) 6.28 5 101mg/L -1307016.28
Potassium (K) 8.41 5 102mg/L -1307018.41
Sodium (Na) 6.71 5 102mg/L -1307016.71
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010453
Calcium (Ca) 10.3 5 104 1.97mg/L -13070110.3
Magnesium (Mg) 6.33 5 102 0.93mg/L -1307016.33
Potassium (K) 8.5 5 104 1.84mg/L -1307018.5
Sodium (Na) 6.74 5 103 0.546mg/L -1307016.74
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17030451 -- 2017012164
Calcium (Ca) 54 5 90.8mg/L -13070154
Magnesium (Mg) 20 5 98.6mg/L -13070120
Potassium (K) 12.4 5 98.7mg/L -13070112.4
Sodium (Na) 23.5 5 100mg/L -13070123.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17030451 -- 2017012164
Calcium (Ca) 54.3 5 96.4 6.02mg/L -13070154.3
Magnesium (Mg) 20.2 5 102 3.1mg/L -13070120.2
Potassium (K) 12.5 5 100 1.47mg/L -13070112.5
Sodium (Na) 23.5 5 101 0.715mg/L -13070123.5
Duke Energy Analytical Lab
Page 28 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030702 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00134 mg/L -10.00134 0.005 < 1/2 RDL
Barium (Ba) 0.000456 mg/L -10.000456 0.005 < 1/2 RDL
Boron (B) 0.00209 mg/L -10.00209 0.05 < 1/2 RDL
Iron (Fe) 0.00192 mg/L -10.00192 0.01 < 1/2 RDL
Manganese (Mn) 0.000488 mg/L -10.000488 0.005 < 1/2 RDL
Strontium (Sr) 0.000607 mg/L -10.000607 0.005 < 1/2 RDL
Zinc (Zn) 0.00146 mg/L -10.00146 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.76 5 95.3mg/L -1158514.76
Barium (Ba) 4.94 5 98.7mg/L -1158514.94
Boron (B) 4.89 5 97.8mg/L -1158514.89
Iron (Fe) 4.96 5 99.2mg/L -1158514.96
Manganese (Mn) 4.95 5 99mg/L -1158514.95
Strontium (Sr) 4.88 5 97.5mg/L -1158514.88
Zinc (Zn) 4.95 5 98.9mg/L -1158514.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030466 -- 2017009188
Aluminum (Al) 4.69 5 93.6mg/L -1307014.69
Barium (Ba) 5.87 5 99.1mg/L -1307015.87
Boron (B) 5.08 5 99.1mg/L -1307015.08
Iron (Fe) 5.17 5 98.1mg/L -1307015.17
Manganese (Mn) 5.08 5 97.2mg/L -1307015.08
Strontium (Sr) 6.79 5 95.8mg/L -1307016.79
Zinc (Zn) 4.83 5 96.6mg/L -1307014.83
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030466 -- 2017009188
Aluminum (Al) 4.46 5 89 5mg/L -1307014.46
Barium (Ba) 5.6 5 93.8 5.54mg/L -1307015.6
Boron (B) 4.64 5 90.3 9.35mg/L -1307014.64
Iron (Fe) 4.91 5 92.9 5.43mg/L -1307014.91
Manganese (Mn) 4.84 5 92.4 5.06mg/L -1307014.84
Strontium (Sr) 6.52 5 90.3 5.91mg/L -1307016.52
Zinc (Zn) 4.59 5 91.7 5.25mg/L -1307014.59
Duke Energy Analytical Lab
Page 29 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030753 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.031 ug/L -10.031 1 < 1/2 RDL
Arsenic (As) 0.026 ug/L -10.026 1 < 1/2 RDL
Beryllium (Be) -0.131 ug/L -1-0.131 1 < 1/2 RDL
Cadmium (Cd) 0.009 ug/L -10.009 1 < 1/2 RDL
Chromium (Cr) 0.029 ug/L -10.029 1 < 1/2 RDL
Cobalt (Co) 0.015 ug/L -10.015 1 < 1/2 RDL
Copper (Cu) 0.093 ug/L -10.093 1 < 1/2 RDL
Lead (Pb) 0.011 ug/L -10.011 1 < 1/2 RDL
Molybdenum (Mo) 0.021 ug/L -10.021 1 < 1/2 RDL
Nickel (Ni) 0.015 ug/L -10.015 1 < 1/2 RDL
Selenium (Se) 0.032 ug/L -10.032 1 < 1/2 RDL
Thallium (Tl) Low Level -0.023 ug/L -1-0.023 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.07 ug/L -10.07 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50 50 100ug/L -11585150
Arsenic (As) 50.4 50 101ug/L -11585150.4
Beryllium (Be) 50.9 50 102ug/L -11585150.9
Cadmium (Cd) 50.2 50 100ug/L -11585150.2
Chromium (Cr) 50.2 50 100ug/L -11585150.2
Cobalt (Co) 50.4 50 101ug/L -11585150.4
Copper (Cu) 50.8 50 102ug/L -11585150.8
Lead (Pb) 49.9 50 99.8ug/L -11585149.9
Molybdenum (Mo) 51.1 50 102ug/L -11585151.1
Nickel (Ni) 50.6 50 101ug/L -11585150.6
Selenium (Se) 47.9 50 95.8ug/L -11585147.9
Thallium (Tl) Low Level 54.2 50 108ug/L -11585154.2
Vanadium (V) Low Level 49.8 50 99.7ug/L -11585149.8
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010456
Antimony (Sb) 50.7 50 101ug/L -13070150.7
Arsenic (As) 50.7 50 101ug/L -13070150.7
Beryllium (Be) 51.6 50 103ug/L -13070151.6
Cadmium (Cd) 50.2 50 100ug/L -13070150.2
Chromium (Cr) 50.4 50 101ug/L -13070150.4
Cobalt (Co) 51.6 50 100ug/L -13070151.6
Copper (Cu) 52.6 50 101ug/L -13070152.6
Lead (Pb) 50.3 50 101ug/L -13070150.3
Duke Energy Analytical Lab
Page 30 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030753 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010456
Molybdenum (Mo) 54 50 104ug/L -13070154
Nickel (Ni) 54.5 50 102ug/L -13070154.5
Selenium (Se) 48.5 50 96.9ug/L -13070148.5
Thallium (Tl) Low Level 40.3 50 80.6ug/L -13070140.3
Vanadium (V) Low Level 50.9 50 101ug/L -13070150.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030696 -- 2017010456
Antimony (Sb) 46.5 50 93 8.55ug/L -13070146.5
Arsenic (As) 46.7 50 93.2 8.23ug/L -13070146.7
Beryllium (Be) 46.1 50 92.2 11.3ug/L -13070146.1
Cadmium (Cd) 46.8 50 93.5 7.09ug/L -13070146.8
Chromium (Cr) 46.6 50 93.1 7.74ug/L -13070146.6
Cobalt (Co) 48 50 92.8 7.48ug/L -13070148
Copper (Cu) 49.1 50 94.1 7.21ug/L -13070149.1
Lead (Pb) 46.5 50 93 7.84ug/L -13070146.5
Molybdenum (Mo) 49.9 50 95.5 8.22ug/L -13070149.9
Nickel (Ni) 50.6 50 93.9 7.85ug/L -13070150.6
Selenium (Se) 45.2 50 90.3 7.03ug/L -13070145.2
Thallium (Tl) Low Level 37.1 50 74.2 8.29ug/L -13070137.1
Vanadium (V) Low Level 47.3 50 93.7 7.52ug/L -13070147.3
Duke Energy Analytical Lab
Page 31 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030707 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.039 ug/L -1-0.039 1 < 1/2 RDL
Arsenic (As) 0.016 ug/L -10.016 1 < 1/2 RDL
Beryllium (Be) -0.02 ug/L -1-0.02 1 < 1/2 RDL
Cadmium (Cd) 0.006 ug/L -10.006 1 < 1/2 RDL
Chromium (Cr) 0.02 ug/L -10.02 1 < 1/2 RDL
Cobalt (Co) 0.01 ug/L -10.01 1 < 1/2 RDL
Copper (Cu) 0.049 ug/L -10.049 1 < 1/2 RDL
Lead (Pb) 0.009 ug/L -10.009 1 < 1/2 RDL
Molybdenum (Mo) 0.019 ug/L -10.019 1 < 1/2 RDL
Nickel (Ni) 0.018 ug/L -10.018 1 < 1/2 RDL
Selenium (Se) 0.013 ug/L -10.013 1 < 1/2 RDL
Thallium (Tl) Low Level -0.051 ug/L -1-0.051 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.05 ug/L -10.05 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.4 50 98.8ug/L -11585149.4
Arsenic (As) 49.2 50 98.4ug/L -11585149.2
Beryllium (Be) 48.3 50 96.7ug/L -11585148.3
Cadmium (Cd) 49.1 50 98.2ug/L -11585149.1
Chromium (Cr) 49 50 98ug/L -11585149
Cobalt (Co) 49.1 50 98.2ug/L -11585149.1
Copper (Cu) 51.1 50 102ug/L -11585151.1
Lead (Pb) 48.8 50 97.7ug/L -11585148.8
Molybdenum (Mo) 50.1 50 100ug/L -11585150.1
Nickel (Ni) 52.3 50 105ug/L -11585152.3
Selenium (Se) 48.7 50 97.4ug/L -11585148.7
Thallium (Tl) Low Level 52.8 50 106ug/L -11585152.8
Vanadium (V) Low Level 49 50 98.1ug/L -11585149
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030466 -- 2017009195
Antimony (Sb) 49.6 50 99.3ug/L -13070149.6
Arsenic (As) 50.7 50 99.5ug/L -13070150.7
Beryllium (Be) 48.6 50 97.3ug/L -13070148.6
Cadmium (Cd) 48.6 50 97.3ug/L -13070148.6
Chromium (Cr) 48.8 50 97.4ug/L -13070148.8
Cobalt (Co) 56 50 97.5ug/L -13070156
Copper (Cu) 49.5 50 98.7ug/L -13070149.5
Lead (Pb) 49.2 50 98.3ug/L -13070149.2
Duke Energy Analytical Lab
Page 32 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030707 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030466 -- 2017009195
Molybdenum (Mo) 52 50 101ug/L -13070152
Nickel (Ni) 50.1 50 98.9ug/L -13070150.1
Selenium (Se) 49.4 50 98.6ug/L -13070149.4
Thallium (Tl) Low Level 52.5 50 105ug/L -13070152.5
Vanadium (V) Low Level 49.7 50 97.9ug/L -13070149.7
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030466 -- 2017009195
Antimony (Sb) 47.6 50 95.2 4.22ug/L -13070147.6
Arsenic (As) 48.5 50 95.1 4.45ug/L -13070148.5
Beryllium (Be) 45.7 50 91.4 6.22ug/L -13070145.7
Cadmium (Cd) 47.2 50 94.3 3.09ug/L -13070147.2
Chromium (Cr) 47 50 93.8 3.78ug/L -13070147
Cobalt (Co) 54.3 50 94.1 3.55ug/L -13070154.3
Copper (Cu) 47.6 50 94.8 3.96ug/L -13070147.6
Lead (Pb) 47.6 50 95.2 3.25ug/L -13070147.6
Molybdenum (Mo) 50.1 50 97.3 3.72ug/L -13070150.1
Nickel (Ni) 48.3 50 95.3 3.65ug/L -13070148.3
Selenium (Se) 46 50 91.8 7.06ug/L -13070146
Thallium (Tl) Low Level 49.6 50 99.2 5.62ug/L -13070149.6
Vanadium (V) Low Level 48.4 50 95.2 2.82ug/L -13070148.4
Duke Energy Analytical Lab
Page 33 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030737 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030078 -- 2017007056
TDS 40 11.8mg/L -140
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030078 -- 2017007058
TDS 68 0mg/L -168
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030078 -- 2017007059
TDS 16 11.8mg/L -116
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 98 100 98mg/L -11090198
Duke Energy Analytical Lab
Page 34 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17040217 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.022 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.052 0.1 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
TOC mg/L -10.046 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 106mg/L -1208012.32
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 103 3.1mg/L -1208012.25
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 101mg/L -1208013.37
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 100 1.04mg/L -1208013.35
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 99mg/L -1208016.02
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 91 8.37mg/L -1208015.87
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 105mg/L -1158513.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 105mg/L -1158513.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
TOC 2.87 107mg/L -1158513.08
Duke Energy Analytical Lab
Page 35 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030696
Q17030729 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17020100 -- 2017003803
TSS 2 10.5mg/L -12
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 49.6 50 99.2mg/L -11090149.6
Duke Energy Analytical Lab
Page 36 of 79
#=CL#
April 07, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92335089
92335089
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17030696
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on March 29, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
1(704)875-9092
Enclosures
cc:Program Manager, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 25
Duke Energy Analytical Lab
Page 37 of 79
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92335089
J17030696
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Duke Energy Analytical Lab
Page 38 of 79
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92335089
J17030696
Lab ID Sample ID Matrix Date Collected Date Received
92335089001 2017010453 Water 03/28/17 09:45 03/29/17 13:50
92335089002 2017010455 Water 03/28/17 09:56 03/29/17 13:50
92335089003 2017010456 Water 03/28/17 10:53 03/29/17 13:50
92335089004 2017010457 Water 03/28/17 11:28 03/29/17 13:50
92335089005 2017010458 Water 03/28/17 13:06 03/29/17 13:50
92335089006 2017010460 Water 03/28/17 14:00 03/29/17 13:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
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Duke Energy Analytical Lab
Page 39 of 79
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92335089
J17030696
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92335089001 2017010453 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF1
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92335089002 2017010455 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF1
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92335089003 2017010456 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF1
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92335089004 2017010457 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF1
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92335089005 2017010458 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF1
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92335089006 2017010460 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF1
SM 4500-S2D 1 PASI-AEWS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
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Duke Energy Analytical Lab
Page 40 of 79
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92335089
J17030696
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92335089001 2017010453
Methane 273 ug/L 04/04/17 00:0510.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)22.7 mg/L 03/31/17 00:235.0SM 2320B
Alkalinity, Total as CaCO3 22.7 mg/L 03/31/17 00:235.0SM 2320B
Chromium, Hexavalent 4.4 ug/L 04/06/17 11:320.50EPA 218.7
92335089002 2017010455
Alkalinity,Bicarbonate (CaCO3)54.3 mg/L 03/31/17 00:335.0SM 2320B
Alkalinity, Total as CaCO3 54.3 mg/L 03/31/17 00:335.0SM 2320B
Chromium, Hexavalent 0.63 ug/L 04/07/17 10:140.12EPA 218.7
92335089003 2017010456
Methane 931 ug/L 04/04/17 00:3510.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)106 mg/L 03/31/17 00:455.0SM 2320B
Alkalinity, Total as CaCO3 106 mg/L 03/31/17 00:455.0SM 2320B
Chromium, Hexavalent 0.080 ug/L 04/06/17 16:570.025EPA 218.7
92335089004 2017010457
Alkalinity,Bicarbonate (CaCO3)53.0 mg/L 03/31/17 00:575.0SM 2320B
Alkalinity, Total as CaCO3 53.0 mg/L 03/31/17 00:575.0SM 2320B
Chromium, Hexavalent 0.25 ug/L 04/06/17 12:110.025EPA 218.7
92335089005 2017010458
Alkalinity,Bicarbonate (CaCO3)69.5 mg/L 03/31/17 01:095.0SM 2320B
Alkalinity, Total as CaCO3 69.5 mg/L 03/31/17 01:095.0SM 2320B
Chromium, Hexavalent 0.19 ug/L 04/06/17 12:240.025EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 41 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92335089
J17030696
Method:
Client:Duke Energy
RSK 175 Modified
Date:April 07, 2017
Description:RSK 175 Headspace
General Information:
6 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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[phone]
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Duke Energy Analytical Lab
Page 42 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92335089
J17030696
Method:
Client:Duke Energy
SM 2320B
Date:April 07, 2017
Description:2320B Alkalinity
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
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Duke Energy Analytical Lab
Page 43 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92335089
J17030696
Method:
Client:Duke Energy
SM 4500-S2D
Date:April 07, 2017
Description:4500S2D Sulfide Water
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 25
Duke Energy Analytical Lab
Page 44 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92335089
J17030696
Method:
Client:Duke Energy
EPA 218.7
Date:April 07, 2017
Description:Hexavalent Chromium by IC
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 360998
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92335161007,92335161017
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1944752)
• Chromium, Hexavalent
• MSD (Lab ID: 1944753)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 45 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335089
J17030696
Sample:2017010453 Lab ID:92335089001 Collected:03/28/17 09:45 Received:03/29/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 273 ug/L 04/04/17 00:05 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)22.7 mg/L 03/31/17 00:235.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 03/31/17 00:235.0 1
Alkalinity, Total as CaCO3 22.7 mg/L 03/31/17 00:235.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/03/17 15:45 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 4.4 ug/L 04/06/17 11:32 18540-29-90.50 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 46 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335089
J17030696
Sample:2017010455 Lab ID:92335089002 Collected:03/28/17 09:56 Received:03/29/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 04/04/17 00:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)54.3 mg/L 03/31/17 00:335.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 03/31/17 00:335.0 1
Alkalinity, Total as CaCO3 54.3 mg/L 03/31/17 00:335.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/03/17 15:45 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.63 ug/L 04/07/17 10:14 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 11 of 25
Duke Energy Analytical Lab
Page 47 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335089
J17030696
Sample:2017010456 Lab ID:92335089003 Collected:03/28/17 10:53 Received:03/29/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 931 ug/L 04/04/17 00:35 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)106 mg/L 03/31/17 00:455.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 03/31/17 00:455.0 1
Alkalinity, Total as CaCO3 106 mg/L 03/31/17 00:455.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/03/17 15:45 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.080 ug/L 04/06/17 16:57 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 48 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335089
J17030696
Sample:2017010457 Lab ID:92335089004 Collected:03/28/17 11:28 Received:03/29/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 04/04/17 00:51 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)53.0 mg/L 03/31/17 00:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 03/31/17 00:575.0 1
Alkalinity, Total as CaCO3 53.0 mg/L 03/31/17 00:575.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/03/17 15:45 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.25 ug/L 04/06/17 12:11 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 49 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335089
J17030696
Sample:2017010458 Lab ID:92335089005 Collected:03/28/17 13:06 Received:03/29/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 04/04/17 13:53 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)69.5 mg/L 03/31/17 01:095.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 03/31/17 01:095.0 1
Alkalinity, Total as CaCO3 69.5 mg/L 03/31/17 01:095.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/03/17 15:45 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.19 ug/L 04/06/17 12:24 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
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Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 50 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335089
J17030696
Sample:2017010460 Lab ID:92335089006 Collected:03/28/17 14:00 Received:03/29/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 04/04/17 14:23 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 03/31/17 01:215.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 03/31/17 01:215.0 1
Alkalinity, Total as CaCO3 ND mg/L 03/31/17 01:215.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/03/17 15:45 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
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[phone]
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Duke Energy Analytical Lab
Page 51 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92335089
J17030696
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
354936
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1968929
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/03/17 19:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1968930LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 297396 75 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1968931MATRIX SPIKE SAMPLE:
MSSpike
Result
92334975008
Methane ug/L 990396 94 70-130618
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92334975010
1968932SAMPLE DUPLICATE:
Methane ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
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Duke Energy Analytical Lab
Page 52 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92335089
J17030696
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
355127
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92335089005, 92335089006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1969905
Associated Lab Samples:92335089005, 92335089006
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/04/17 13:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1969906LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 454396 115 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92335147001
1969908SAMPLE DUPLICATE:
Methane ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
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Duke Energy Analytical Lab
Page 53 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92335089
J17030696
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
354433
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004, 92335089005, 92335089006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1966114
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004, 92335089005, 92335089006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 03/30/17 22:38
Alkalinity, Total as CaCO3 mg/L ND 5.0 03/30/17 22:38
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 03/30/17 22:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1966115LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 47.850 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1966116MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92334975020
1966117
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-12099 1 255019.8 68.9 69.3
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1966118MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335089006
1966119
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-12097 1 2550ND48.9 48.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 25
Duke Energy Analytical Lab
Page 54 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92335089
J17030696
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
354894
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004, 92335089005, 92335089006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1968725
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004, 92335089005, 92335089006
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/03/17 15:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1968726LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.49.5 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1968727MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335042008
1968728
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 108 80-120108 0 10.5ND 0.54 0.54
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1968729MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335147003
1968730
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 102 80-120103 1 10.5ND 0.51 0.52
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 25
Duke Energy Analytical Lab
Page 55 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92335089
J17030696
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
360998
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004, 92335089005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1944748
Associated Lab Samples:92335089001, 92335089002, 92335089003, 92335089004, 92335089005
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 04/06/17 10:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1944749LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.067.075 90 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1944750MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335161007
1944751
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .22 99 85-115109 10 20.22ND 0.22 0.25
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1944752MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335161017
1944753
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M6.25 119 85-115124 4 20.25ND 0.30 0.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 25
Duke Energy Analytical Lab
Page 56 of 79
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92335089
J17030696
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 25
Duke Energy Analytical Lab
Page 57 of 79
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92335089
J17030696
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92335089001 3549362017010453RSK 175 Modified
92335089002 3549362017010455RSK 175 Modified
92335089003 3549362017010456RSK 175 Modified
92335089004 3549362017010457RSK 175 Modified
92335089005 3551272017010458RSK 175 Modified
92335089006 3551272017010460RSK 175 Modified
92335089001 3544332017010453SM 2320B
92335089002 3544332017010455SM 2320B
92335089003 3544332017010456SM 2320B
92335089004 3544332017010457SM 2320B
92335089005 3544332017010458SM 2320B
92335089006 3544332017010460SM 2320B
92335089001 3548942017010453SM 4500-S2D
92335089002 3548942017010455SM 4500-S2D
92335089003 3548942017010456SM 4500-S2D
92335089004 3548942017010457SM 4500-S2D
92335089005 3548942017010458SM 4500-S2D
92335089006 3548942017010460SM 4500-S2D
92335089001 3609982017010453EPA 218.7
92335089002 3609982017010455EPA 218.7
92335089003 3609982017010456EPA 218.7
92335089004 3609982017010457EPA 218.7
92335089005 3609982017010458EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 01:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 25
Duke Energy Analytical Lab
Page 58 of 79
Page 23 of 25
Duke Energy Analytical Lab
Page 59 of 79
Page 24 of 25
Duke Energy Analytical Lab
Page 60 of 79
Page 25 of 25
Duke Energy Analytical Lab
Page 61 of 79

April 17, 2017

Anne Pridgeon
Duke Energy
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment
Work Order: 419506
SDG: J17030696

Dear Anne Pridgeon:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on March 29, 2017. This original data report has been prepared and reviewed in
accordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 5015714
Enclosures
Page 1 of 17
Chelsea Seagle for
Duke Energy Analytical Lab
Page 62 of 79
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO004 Duke Energy Carolinas, LLC <BR> (PO 5015714)
Client SDG: J17030696 GEL Work Order: 419506
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 17
Duke Energy Analytical Lab
Page 63 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1651909
1651909
1651987
1652046
1523
1947
1018
0925
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/14/17
04/14/17
04/11/17
04/14/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
419506001
Ground Water
28-MAR-17 09:45
29-MAR-17
2017010453 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.561
0.306
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000096
ND
ND
ND
ND
0.383
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"103 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 03/30/17 16519081140CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 17
Duke Energy Analytical Lab
Page 64 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1651909
1651909
1651987
1652046
1532
1956
1018
0925
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/14/17
04/14/17
04/11/17
04/14/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
419506002
Ground Water
28-MAR-17 09:56
29-MAR-17
2017010455 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.498
0.345
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000123
ND
ND
ND
ND
4.68
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"82.6 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 03/30/17 16519081140CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 17
Duke Energy Analytical Lab
Page 65 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1651909
1651909
1651987
1652046
1534
1958
1018
0925
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/14/17
04/14/17
04/11/17
04/14/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
419506003
Ground Water
28-MAR-17 10:53
29-MAR-17
2017010456 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.481
0.208
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000256
ND
ND
ND
1.85
1.61
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"85.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 03/30/17 16519081140CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 17
Duke Energy Analytical Lab
Page 66 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1651909
1651909
1651987
1652046
1535
1959
1019
0925
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/14/17
04/14/17
04/11/17
04/14/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
419506004
Ground Water
28-MAR-17 11:28
29-MAR-17
2017010457 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.318
0.366
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
0.352
2.51
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"84.8 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 03/30/17 16519081140CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 17
Duke Energy Analytical Lab
Page 67 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1651909
1651909
1651987
1652046
1537
2001
1019
0925
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/14/17
04/14/17
04/11/17
04/14/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
419506005
Ground Water
28-MAR-17 13:06
29-MAR-17
2017010458 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.403
0.437
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000954
ND
ND
ND
ND
3.41
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"84.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 03/30/17 16519081140CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 7 of 17
Duke Energy Analytical Lab
Page 68 of 79
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1651909Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Parmname
Anne PridgeonContact:
Duke Energy
13339 Hagers Ferry Road
Huntersville, North Carolina
April 17, 2017Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
Anlst Date Time
SKJ 04/14/17 19:49
04/14/17 15:25
04/14/17 15:22
04/14/17 19:46
04/14/17 19:44
04/14/17 15:20
QC
ND
ND
ND
0.0000875
0.0515
0.000508
0.000561
0.00508
ND
ND
ND
ND
NOM Sample
ND
ND
ND
0.000096
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
U
U
U
J
U
U
U
U
QC1203757922 419506001
QC1203757921
QC1203757925
QC1203757920
N/A
N/A
N/A
9.26
REC%
104
102
102
102
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
419506Workorder:
Mail Code: MGO3A2
U
U
U
J ^
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
1651909
1651987
Batch
Batch
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Parmname Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
04/14/17 15:26
04/14/17 19:50
04/14/17 19:52
04/14/17 15:28
04/11/17 10:24
04/11/17 10:18
04/11/17 10:19
QC
0.0516
0.000504
0.000569
0.00504
ND
ND
ND
ND
0.639
7.19
0.213
NOM Sample
0.000096
ND
ND
ND
ND
ND
ND
0.096
-0.0176
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
Qual
U
U
U
U
U
QC1203757923 419506001
QC1203757926 419506001
QC1203757924 419506001
QC1203758103 419504009
QC1203758104
QC1203758102
N/A
N/A
N/A
N/A
211
REC%
104
101
103
101
104
0.0496
0.0005
0.00055
0.005
6.89
MS
MS
SDILT
DUP
LCS
MB
419506Workorder:
J
U
U
U
U
U
U
J
U *
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Rad Ra-226
1652046Batch
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
MXH8 04/14/17 09:25
04/14/17 09:55
04/14/17 09:25
04/14/17 09:55
QC
3.35
20.4
0.119
124
NOM Sample
4.17
4.17
Range
(0%-20%)
(75%-125%)
(75%-125%)
Qual
U
QC1203758279 419504012
QC1203758281
QC1203758278
QC1203758280 419504012
The Qualifiers in this report are defined as follows:
22
REC%
78.7
92.2
26.0
130
DUP
LCS
MB
MS
419506Workorder:
**
<
>
BD
E
FA
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
*
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 4 of 4
Units Anlst Date TimeQCNOMSampleRangeQualREC%
419506Workorder:
U
UI
UJ
UL
X
Y
^
h
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy Carolinas, LLC
(DUPC)
SDG #: J17030696
Work Order #: 419506

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 29
Analytical Batch: 1651909

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1651908
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
419506001 2017010453
419506002 2017010455
419506003 2017010456
419506004 2017010457
419506005 2017010458
1203757920 Method Blank (MB)ICP-MS
1203757921 Laboratory Control Sample (LCS)
1203757925 Laboratory Control Sample (LCS)
1203757924 419506001(2017010453L) Serial Dilution (SD)
1203757922 419506001(2017010453D) Sample Duplicate (DUP)
1203757923 419506001(2017010453S) Matrix Spike (MS)
1203757926 419506001(2017010453S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-063 REV# 1
Analytical Batch: 1651987
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The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
419506001 2017010453
419506002 2017010455
419506003 2017010456
419506004 2017010457
419506005 2017010458
1203758102 Method Blank (MB)
1203758103 419504009(NonSDG) Sample Duplicate (DUP)
1203758104 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The sample and the
duplicate, 1203758103 (Non SDG 419504009DUP), did not meet the relative percent difference requirement;
however, they do meet the relative error ratio requirement with a value of 2.3005.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1652046
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
419506001 2017010453
419506002 2017010455
419506003 2017010456
419506004 2017010457
419506005 2017010458
1203758278 Method Blank (MB)
1203758279 419504012(NonSDG) Sample Duplicate (DUP)
1203758280 419504012(NonSDG) Matrix Spike (MS)
1203758281 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
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procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The sample and the
duplicate, 1203758279 (Non SDG 419504012DUP), did not meet the relative percent difference requirement;
however, they do meet the relative error ratio requirement with a value of 1.2239.

Miscellaneous Information

Additional Comments
The matrix spike, 1203758280 (Non SDG 419504012MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA170010
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-17-12
SC000122016-21
VT87156
460202
C780
997404
List of current GEL Certifications as of 17 April 2017
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Duke Energy Analytical Lab
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