NC0038377_J17030335report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17030335
Project Name:MAYO STEAM - ABGW
Lab Contact:Anne Pridgeon
Date:4/18/2017
Customer Address:Mayo Steam Plant
Customer Name(s):J. TOEPFER, T. HUNSUCKER
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Method 2320: The matrix spike duplicate associated with CW-6 recovered outside method limits for alkalinity. Respective batch
quality checks are acceptable therefore data has been flagged and reported.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 81
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2017008411 MAYO STEAM 03-Apr-17 3:49 PM Synterra CW-1
2017008412 MAYO STEAM 03-Apr-17 4:08 PM Synterra CW-1D
2017008413 MAYO STEAM 03-Apr-17 1:00 PM Synterra CW-2
2017008414 MAYO STEAM 03-Apr-17 12:46 PM Synterra CW-2D
2017008415 MAYO STEAM 04-Apr-17 9:25 AM Synterra CW-3
2017008416 MAYO STEAM 04-Apr-17 12:40 PM Synterra CW-4
2017008417 MAYO STEAM 04-Apr-17 4:15 PM Synterra CW-5
2017008418 MAYO STEAM 03-Apr-17 2:50 PM Synterra CW-6
2017008419 MAYO STEAM 03-Apr-17 2:02 PM Synterra BG-1
2017008420 MAYO STEAM 03-Apr-17 1:05 PM Synterra BG-2
2017008421 MAYO STEAM 04-Apr-17 12:40 PM Synterra CW-4 DUP
2017008422 MAYO STEAM 04-Apr-17 3:50 PM Synterra FIELD BLANK
12 Total Samples
Duke Energy Analytical Lab
Page 2 of 81
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/18/2017
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008411
Collection Date:03-Apr-17 3:49 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 18 mg/L EPA 300.0 04/04/2017 13:23 BGN90340.5 5
Nitrate 6.6 mg/L EPA 300.0 04/04/2017 13:23 BGN90340.1 1
Nitrate as N 1.5 mg-N/L EPA 300.0 04/04/2017 13:23 BGN90340.023 1
Sulfate 9.6 mg/L EPA 300.0 04/04/2017 13:23 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:19 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.119 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.05 1
Calcium (Ca)10.0 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Iron (Fe)0.147 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.01 1
Magnesium (Mg)3.92 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Manganese (Mn)0.012 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Potassium (K)1.12 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.1 1
Sodium (Na)16.5 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.05 1
Strontium (Sr)0.071 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
Zinc (Zn)0.013 mg/L EPA 200.7 04/17/2017 09:56 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR0.2 1
Vanadium (V) Low Level 0.805 ug/L EPA 200.8 04/06/2017 22:54 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 04/04/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 4 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008411
Collection Date:03-Apr-17 3:49 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/05/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 5 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008412
Collection Date:03-Apr-17 4:08 PM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 04/04/2017 13:40 BGN90340.5 5
Nitrate 2.0 mg/L EPA 300.0 04/04/2017 13:40 BGN90340.1 1
Nitrate as N 0.44 mg-N/L EPA 300.0 04/04/2017 13:40 BGN90340.023 1
Sulfate 3.5 mg/L EPA 300.0 04/04/2017 13:40 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:21 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.065 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.05 1
Calcium (Ca)47.6 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Iron (Fe)0.069 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.01 1
Magnesium (Mg)9.55 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Manganese (Mn)0.034 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Potassium (K)2.18 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.1 1
Sodium (Na)13.9 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.05 1
Strontium (Sr)0.180 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/17/2017 10:08 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Molybdenum (Mo)23.0 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR0.2 1
Vanadium (V) Low Level 1.33 ug/L EPA 200.8 04/06/2017 22:24 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 190 mg/L SM2540C 04/04/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 6 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008412
Collection Date:03-Apr-17 4:08 PM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/05/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 7 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008413
Collection Date:03-Apr-17 1:00 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 50 mg/L EPA 300.0 04/04/2017 13:58 BGN9034110
Nitrate < 0.1 mg/L EPA 300.0 04/04/2017 13:58 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/04/2017 13:58 BGN90340.023 1
Sulfate 39 mg/L EPA 300.0 04/04/2017 13:58 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:24 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.027 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Barium (Ba)0.123 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Boron (B)0.796 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.05 1
Calcium (Ca)16.7 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Iron (Fe)0.011 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.01 1
Magnesium (Mg)8.20 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Manganese (Mn)0.119 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Potassium (K)1.92 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.1 1
Sodium (Na)16.2 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.05 1
Strontium (Sr)0.227 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 04/17/2017 10:13 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2017 23:01 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 04/04/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 8 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008413
Collection Date:03-Apr-17 1:00 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/05/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 9 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008414
Collection Date:03-Apr-17 12:46 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 04/04/2017 14:15 BGN9034220
Nitrate < 0.2 mg/L EPA 300.0 04/04/2017 14:15 BGN90340.2 2
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/04/2017 14:15 BGN90340.023 1
Sulfate 62 mg/L EPA 300.0 04/04/2017 14:15 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:26 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.129 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Barium (Ba)0.032 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Boron (B)0.303 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.05 1
Calcium (Ca)85.7 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Iron (Fe)0.240 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.01 1
Magnesium (Mg)8.49 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Manganese (Mn)0.709 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Potassium (K)4.49 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.1 1
Sodium (Na)19.5 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.05 1
Strontium (Sr)0.452 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 04/17/2017 10:17 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Molybdenum (Mo)1.03 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR0.2 1
Vanadium (V) Low Level 0.812 ug/L EPA 200.8 04/06/2017 23:08 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 04/04/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 10 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008414
Collection Date:03-Apr-17 12:46 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 6 mg/L SM2540D 04/05/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 11 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008415
Collection Date:04-Apr-17 9:25 AM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 98 mg/L EPA 300.0 04/05/2017 16:22 BGN9034220
Nitrate 1.2 mg/L EPA 300.0 04/05/2017 16:22B2, B3;BGN90340.2 2
Nitrate as N 0.26 mg-N/L EPA 300.0 04/05/2017 16:22B2, B3;BGN90340.023 1
Sulfate 17 mg/L EPA 300.0 04/05/2017 16:22 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:29 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.152 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Barium (Ba)0.017 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.05 1
Calcium (Ca)65.1 mg/L EPA 200.7 04/12/2017 12:34m4 MHH71310.01 1
Chromium (Cr)0.008 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Iron (Fe)0.176 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.01 1
Magnesium (Mg)7.48 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Manganese (Mn)0.025 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Potassium (K)4.39 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.1 1
Sodium (Na)42.3 mg/L EPA 200.7 04/12/2017 12:34m4 MHH71310.05 1
Strontium (Sr)0.322 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2017 12:34 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR0.2 1
Vanadium (V) Low Level 1.77 ug/L EPA 200.8 04/10/2017 15:21 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 360 mg/L SM2540C 04/06/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 12 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008415
Collection Date:04-Apr-17 9:25 AM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 7 mg/L SM2540D 04/07/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 13 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008416
Collection Date:04-Apr-17 12:40 PM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.5 mg/L EPA 300.0 04/05/2017 16:39 BGN90340.1 1
Nitrate 0.52 mg/L EPA 300.0 04/05/2017 16:39B2, B3;BGN90340.1 1
Nitrate as N 0.12 mg-N/L EPA 300.0 04/05/2017 16:39B2, B3;BGN90340.023 1
Sulfate 25 mg/L EPA 300.0 04/05/2017 16:39 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:31 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.188 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Barium (Ba)0.027 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.05 1
Calcium (Ca)12.7 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Iron (Fe)0.125 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.01 1
Magnesium (Mg)3.32 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Potassium (K)1.35 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.1 1
Sodium (Na)16.7 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.05 1
Strontium (Sr)0.127 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2017 12:46 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR0.2 1
Vanadium (V) Low Level 1.31 ug/L EPA 200.8 04/10/2017 14:52 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 04/06/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 14 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008416
Collection Date:04-Apr-17 12:40 PM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/07/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 15 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008417
Collection Date:04-Apr-17 4:15 PM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 42 mg/L EPA 300.0 04/05/2017 16:56 BGN9034110
Nitrate 0.11 mg/L EPA 300.0 04/05/2017 16:56B2, B3;BGN90340.1 1
Nitrate as N 0.02 mg-N/L EPA 300.0 04/05/2017 16:56B2, B3;BGN90340.023 1
Sulfate 6.4 mg/L EPA 300.0 04/05/2017 16:56 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:46 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Barium (Ba)0.046 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.05 1
Calcium (Ca)56.1 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Iron (Fe)0.390 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.01 1
Magnesium (Mg)7.45 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Manganese (Mn)0.431 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Potassium (K)5.81 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.1 1
Sodium (Na)18.7 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.05 1
Strontium (Sr)0.165 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2017 12:50 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2017 15:28 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 04/06/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 16 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008417
Collection Date:04-Apr-17 4:15 PM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/07/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 17 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008418
Collection Date:03-Apr-17 2:50 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 90 mg/L EPA 300.0 04/04/2017 14:33 BGN9034220
Nitrate < 0.2 mg/L EPA 300.0 04/04/2017 14:33 BGN90340.2 2
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/04/2017 14:33 BGN90340.023 1
Sulfate 38 mg/L EPA 300.0 04/04/2017 14:33 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:53 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.091 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Barium (Ba)0.043 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.05 1
Calcium (Ca)112 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Iron (Fe)2.44 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.01 1
Magnesium (Mg)20.3 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Manganese (Mn)1.59 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Potassium (K)9.69 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.1 1
Sodium (Na)47.7 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.05 1
Strontium (Sr)0.334 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/17/2017 10:21 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Molybdenum (Mo)3.90 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2017 23:15 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 530 mg/L SM2540C 04/04/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 18 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008418
Collection Date:03-Apr-17 2:50 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 9 mg/L SM2540D 04/05/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 19 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008419
Collection Date:03-Apr-17 2:02 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 300.0 04/04/2017 14:50 BGN90340.5 5
Nitrate 3.6 mg/L EPA 300.0 04/04/2017 14:50 BGN90340.1 1
Nitrate as N 0.82 mg-N/L EPA 300.0 04/04/2017 14:50 BGN90340.023 1
Sulfate 0.27 mg/L EPA 300.0 04/04/2017 14:50 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:55 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.046 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Barium (Ba)0.090 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.05 1
Calcium (Ca)12.9 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Iron (Fe)0.040 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.01 1
Magnesium (Mg)3.25 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Manganese (Mn)0.006 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Potassium (K)1.36 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.1 1
Sodium (Na)12.5 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.05 1
Strontium (Sr)0.176 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/17/2017 10:25 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR0.2 1
Vanadium (V) Low Level 3.89 ug/L EPA 200.8 04/06/2017 23:45 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 04/04/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 20 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008419
Collection Date:03-Apr-17 2:02 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/05/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 21 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008420
Collection Date:03-Apr-17 1:05 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 35 mg/L EPA 300.0 04/04/2017 15:07 BGN90340.5 5
Nitrate < 0.1 mg/L EPA 300.0 04/04/2017 15:07 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/04/2017 15:07 BGN90340.023 1
Sulfate 5.6 mg/L EPA 300.0 04/04/2017 15:07 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 14:58 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.100 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Barium (Ba)0.045 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.05 1
Calcium (Ca)53.3 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Iron (Fe)0.221 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.01 1
Magnesium (Mg)10.5 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Manganese (Mn)0.105 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Potassium (K)3.41 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.1 1
Sodium (Na)45.1 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.05 1
Strontium (Sr)0.296 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/17/2017 10:37 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR0.2 1
Vanadium (V) Low Level 3.87 ug/L EPA 200.8 04/06/2017 23:52 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 04/04/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 22 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008420
Collection Date:03-Apr-17 1:05 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/05/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 23 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008421
Collection Date:04-Apr-17 12:40 PM
Site:CW-4 DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.7 mg/L EPA 300.0 04/05/2017 17:14 BGN90340.1 1
Nitrate 0.52 mg/L EPA 300.0 04/05/2017 17:14B2, B3;BGN90340.1 1
Nitrate as N 0.12 mg-N/L EPA 300.0 04/05/2017 17:14B2, B3;BGN90340.023 1
Sulfate 26 mg/L EPA 300.0 04/05/2017 17:14 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 15:00 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.154 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Barium (Ba)0.027 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.05 1
Calcium (Ca)12.8 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Iron (Fe)0.101 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.01 1
Magnesium (Mg)3.35 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Potassium (K)1.30 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.1 1
Sodium (Na)16.8 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.05 1
Strontium (Sr)0.131 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2017 12:54 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR0.2 1
Vanadium (V) Low Level 1.25 ug/L EPA 200.8 04/10/2017 15:35 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 04/06/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 24 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008421
Collection Date:04-Apr-17 12:40 PM
Site:CW-4 DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/07/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 25 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008422
Collection Date:04-Apr-17 3:50 PM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/05/2017 16:04 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/05/2017 16:04B2, B3;BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/05/2017 16:04B2, B3;BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 04/05/2017 16:04 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/10/2017 15:03 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.05 1
Calcium (Ca)< 0.01 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.05 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/12/2017 12:58 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2017 15:43 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/06/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 26 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
2017008422
Collection Date:04-Apr-17 3:50 PM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/07/2017 10:00 MGIGANT51
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Duke Energy Analytical Lab
Page 27 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040031 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0326 mg/L -10.0326 0.1 < 1/2 RDL
Nitrate 0.0312 mg/L -10.0312 0.1 < 1/2 RDL
Sulfate -0.0009 mg/L -1-0.0009 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 8.44 25 97.2mg/L -12080542.2
Nitrate 6.16 25 98.7mg/L -12080530.8
Sulfate 6.82 25 97.8mg/L -12080534.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 8.45 25 97.5 0.374mg/L -12080542.3
Nitrate 6.18 25 99.2 0.592mg/L -12080530.9
Sulfate 6.84 25 98.2 0.375mg/L -12080534.2
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.54 25 98.9mg/L -12080542.7
Nitrate 25mg/L -120801Not Tested
Sulfate 6.75 25 101mg/L -12080533.7
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.53 25 98.6 0.294mg/L -12080542.6
Nitrate 25mg/L -120801Not Tested
Sulfate 6.74 25 101 0.203mg/L -12080533.7
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.03 5 101mg/L -1109015.03
Nitrate 5.05 5 101mg/L -1109015.05
Sulfate 5.06 5 101mg/L -1109015.06
Duke Energy Analytical Lab
Page 28 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040066 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0186 mg/L -10.0186 0.1 < 1/2 RDL
Nitrate 0.0621 mg/L -10.0621 0.1 > 1/2 RDL
Sulfate -0.0439 mg/L -1-0.0439 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.19 5 99.3mg/L -1208016.19
Nitrate 6.53 5 106mg/L -1208016.53
Sulfate 5.3 5 95mg/L -1208015.3
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.21 5 99.5 0.251mg/L -1208016.21
Nitrate 6.47 5 105 1.17mg/L -1208016.47
Sulfate 5.26 5 94.4 0.699mg/L -1208015.26
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 10.1 100 105mg/L -1208020203
Nitrate 5.23 100 103mg/L -1208020105
Sulfate 6.07 100 105mg/L -1208020121
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 10.1 100 105 0.21mg/L -1208020202
Nitrate 5.23 100 103 0mg/L -1208020105
Sulfate 6.08 100 105 0.0931mg/L -1208020122
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.38 5 108mg/L -1109015.38
Nitrate 5.36 5 107mg/L -1109015.36
Sulfate 5.32 5 106mg/L -1109015.32
Duke Energy Analytical Lab
Page 29 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040191 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.013 ug/L -1-0.013 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.006 ug/L -1-0.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.866 20 87.4ug/L -130702017.3
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.861 20 86.9 0.574ug/L -130702017.2
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.905 100 90.6ug/L -1307010090.5
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.912 100 91.2 0.682ug/L -1307010091.2
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
Mercury (Hg) 0.88 20 86.1ug/L -130702017.6
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.869 20 85 1.29ug/L -130702017.4
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.08 2 104ug/L -1158512.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.94 2 96.8ug/L -1158511.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008417
Mercury (Hg) 0.911 1 91.3ug/L -1307010.911
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008417
Mercury (Hg) 0.913 1 91.5 0.219ug/L -1307010.913
Duke Energy Analytical Lab
Page 30 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040075 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000412 mg/L -10.000412 0.005 < 1/2 RDL
Barium (Ba) -0.00015 mg/L -1-0.00015 0.005 < 1/2 RDL
Boron (B) -0.00221 mg/L -1-0.00221 0.05 < 1/2 RDL
Calcium (Ca) 0.000072 mg/L -10.000072 0.01 < 1/2 RDL
Chromium (Cr) -0.00093 mg/L -1-0.00093 0.005 < 1/2 RDL
Copper (Cu) 0.000226 mg/L -10.000226 0.005 < 1/2 RDL
Iron (Fe) -0.000053 mg/L -1-0.000053 0.01 < 1/2 RDL
Magnesium (Mg) -0.000262 mg/L -1-0.000262 0.005 < 1/2 RDL
Manganese (Mn) -0.000157 mg/L -1-0.000157 0.005 < 1/2 RDL
Nickel (Ni) -0.000204 mg/L -1-0.000204 0.005 < 1/2 RDL
Potassium (K) -0.0147 mg/L -1-0.0147 0.1 < 1/2 RDL
Sodium (Na) -0.0243 mg/L -1-0.0243 0.05 < 1/2 RDL
Strontium (Sr) -0.000062 mg/L -1-0.000062 0.005 < 1/2 RDL
Zinc (Zn) 0.000244 mg/L -10.000244 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.02 5 100mg/L -1158515.02
Barium (Ba) 5.07 5 101mg/L -1158515.07
Boron (B) 4.98 5 99.6mg/L -1158514.98
Calcium (Ca) 5.04 5 101mg/L -1158515.04
Chromium (Cr) 5.01 5 100mg/L -1158515.01
Copper (Cu) 5.04 5 101mg/L -1158515.04
Iron (Fe) 4.96 5 99.2mg/L -1158514.96
Magnesium (Mg) 4.99 5 99.8mg/L -1158514.99
Manganese (Mn) 5.04 5 101mg/L -1158515.04
Nickel (Ni) 5.05 5 101mg/L -1158515.05
Potassium (K) 5.01 5 100mg/L -1158515.01
Sodium (Na) 5 5 100mg/L -1158515
Strontium (Sr) 4.96 5 99.2mg/L -1158514.96
Zinc (Zn) 5.03 5 101mg/L -1158515.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008411
Aluminum (Al) 5.27 5 103mg/L -1307015.27
Barium (Ba) 5.15 5 103mg/L -1307015.15
Boron (B) 5.06 5 101mg/L -1307015.06
Calcium (Ca) 15.2 5 103mg/L -13070115.2
Chromium (Cr) 5.04 5 101mg/L -1307015.04
Copper (Cu) 5.07 5 101mg/L -1307015.07
Duke Energy Analytical Lab
Page 31 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040075 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008411
Iron (Fe) 5.19 5 101mg/L -1307015.19
Magnesium (Mg) 8.9 5 99.5mg/L -1307018.9
Manganese (Mn) 5.09 5 102mg/L -1307015.09
Nickel (Ni) 5.06 5 101mg/L -1307015.06
Potassium (K) 6.16 5 101mg/L -1307016.16
Sodium (Na) 21.8 5 106mg/L -13070121.8
Strontium (Sr) 5.1 5 101mg/L -1307015.1
Zinc (Zn) 5.03 5 100mg/L -1307015.03
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008411
Aluminum (Al) 4.76 5 92.9 10.3mg/L -1307014.76
Barium (Ba) 4.65 5 93 10.1mg/L -1307014.65
Boron (B) 4.75 5 95 6.32mg/L -1307014.75
Calcium (Ca) 14.7 5 93.4 10mg/L -13070114.7
Chromium (Cr) 4.55 5 90.9 10.4mg/L -1307014.55
Copper (Cu) 4.58 5 91.6 10.2mg/L -1307014.58
Iron (Fe) 4.77 5 92.5 8.63mg/L -1307014.77
Magnesium (Mg) 8.39 5 89.3 10.8mg/L -1307018.39
Manganese (Mn) 4.59 5 91.5 10.5mg/L -1307014.59
Nickel (Ni) 4.54 5 90.8 10.7mg/L -1307014.54
Potassium (K) 5.68 5 91.1 10.1mg/L -1307015.68
Sodium (Na) 21.3 5 97 8.59mg/L -13070121.3
Strontium (Sr) 4.72 5 93 7.85mg/L -1307014.72
Zinc (Zn) 4.53 5 90.4 10.5mg/L -1307014.53
Duke Energy Analytical Lab
Page 32 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040140 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00371 mg/L -10.00371 0.005 > 1/2 RDL
Barium (Ba) -0.000092 mg/L -1-0.000092 0.005 < 1/2 RDL
Boron (B) 0.000168 mg/L -10.000168 0.05 < 1/2 RDL
Calcium (Ca) 0.00674 mg/L -10.00674 0.01 > 1/2 RDL
Chromium (Cr) -0.00017 mg/L -1-0.00017 0.005 < 1/2 RDL
Copper (Cu) -0.000511 mg/L -1-0.000511 0.005 < 1/2 RDL
Iron (Fe) 0.000635 mg/L -10.000635 0.01 < 1/2 RDL
Magnesium (Mg) 0.00069 mg/L -10.00069 0.005 < 1/2 RDL
Manganese (Mn) -0.000089 mg/L -1-0.000089 0.005 < 1/2 RDL
Nickel (Ni) 0.000066 mg/L -10.000066 0.005 < 1/2 RDL
Potassium (K) -0.00917 mg/L -1-0.00917 0.1 < 1/2 RDL
Sodium (Na) -0.00359 mg/L -1-0.00359 0.05 < 1/2 RDL
Strontium (Sr) 0.000018 mg/L -10.000018 0.005 < 1/2 RDL
Zinc (Zn) 0.000192 mg/L -10.000192 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.91 5 98.3mg/L -1158514.91
Barium (Ba) 4.94 5 98.8mg/L -1158514.94
Boron (B) 4.8 5 96.1mg/L -1158514.8
Calcium (Ca) 4.91 5 98.2mg/L -1158514.91
Chromium (Cr) 4.86 5 97.1mg/L -1158514.86
Copper (Cu) 4.82 5 96.5mg/L -1158514.82
Iron (Fe) 4.87 5 97.4mg/L -1158514.87
Magnesium (Mg) 4.79 5 95.9mg/L -1158514.79
Manganese (Mn) 4.9 5 98.1mg/L -1158514.9
Nickel (Ni) 4.93 5 98.7mg/L -1158514.93
Potassium (K) 4.75 5 94.9mg/L -1158514.75
Sodium (Na) 4.75 5 95mg/L -1158514.75
Strontium (Sr) 4.81 5 96.2mg/L -1158514.81
Zinc (Zn) 4.95 5 99mg/L -1158514.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008415
Aluminum (Al) 5.18 5 101mg/L -1307015.18
Barium (Ba) 5.04 5 100mg/L -1307015.04
Boron (B) 4.79 5 95.8mg/L -1307014.79
Calcium (Ca) 67.8 5 54.3mg/L -13070167.8
Chromium (Cr) 4.85 5 96.8mg/L -1307014.85
Copper (Cu) 4.84 5 96.8mg/L -1307014.84
Duke Energy Analytical Lab
Page 33 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040140 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008415
Iron (Fe) 5.07 5 97.9mg/L -1307015.07
Magnesium (Mg) 12.1 5 91.7mg/L -13070112.1
Manganese (Mn) 4.92 5 98mg/L -1307014.92
Nickel (Ni) 4.84 5 96.6mg/L -1307014.84
Potassium (K) 9.26 5 97.3mg/L -1307019.26
Sodium (Na) 46.3 5 78.6mg/L -13070146.3
Strontium (Sr) 5.14 5 96.4mg/L -1307015.14
Zinc (Zn) 4.84 5 96.7mg/L -1307014.84
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008415
Aluminum (Al) 4.81 5 93.1 7.7mg/L -1307014.81
Barium (Ba) 4.66 5 92.9 7.7mg/L -1307014.66
Boron (B) 4.61 5 92.1 3.89mg/L -1307014.61
Calcium (Ca) 66.8 5 33 48.8mg/L -13070166.8
Chromium (Cr) 4.56 5 91 6.26mg/L -1307014.56
Copper (Cu) 4.55 5 91 6.17mg/L -1307014.55
Iron (Fe) 4.79 5 92.2 6.02mg/L -1307014.79
Magnesium (Mg) 11.8 5 85.7 6.74mg/L -13070111.8
Manganese (Mn) 4.57 5 90.9 7.54mg/L -1307014.57
Nickel (Ni) 4.54 5 90.8 6.25mg/L -1307014.54
Potassium (K) 8.94 5 90.9 6.85mg/L -1307018.94
Sodium (Na) 45.4 5 61.4 24.5mg/L -13070145.4
Strontium (Sr) 4.99 5 93.3 3.25mg/L -1307014.99
Zinc (Zn) 4.55 5 90.9 6.21mg/L -1307014.55
Duke Energy Analytical Lab
Page 34 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040078 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.013 ug/L -10.013 1 < 1/2 RDL
Arsenic (As) 0.037 ug/L -10.037 1 < 1/2 RDL
Beryllium (Be) -0.102 ug/L -1-0.102 1 < 1/2 RDL
Cadmium (Cd) 0.011 ug/L -10.011 1 < 1/2 RDL
Cobalt (Co) 0.017 ug/L -10.017 1 < 1/2 RDL
Lead (Pb) 0.015 ug/L -10.015 1 < 1/2 RDL
Molybdenum (Mo) 0.021 ug/L -10.021 1 < 1/2 RDL
Selenium (Se) 0.025 ug/L -10.025 1 < 1/2 RDL
Thallium (Tl) Low Level -0.008 ug/L -1-0.008 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.049 ug/L -10.049 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.3 50 98.6ug/L -11585149.3
Arsenic (As) 49.7 50 99.4ug/L -11585149.7
Beryllium (Be) 50.9 50 102ug/L -11585150.9
Cadmium (Cd) 50.1 50 100ug/L -11585150.1
Cobalt (Co) 50.1 50 100ug/L -11585150.1
Lead (Pb) 50 50 99.9ug/L -11585150
Molybdenum (Mo) 51.2 50 102ug/L -11585151.2
Selenium (Se) 48.6 50 97.2ug/L -11585148.6
Thallium (Tl) Low Level 54.2 50 108ug/L -11585154.2
Vanadium (V) Low Level 49.1 50 98.3ug/L -11585149.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008412
Antimony (Sb) 50.5 50 101ug/L -13070150.5
Arsenic (As) 50.4 50 101ug/L -13070150.4
Beryllium (Be) 49.1 50 98.4ug/L -13070149.1
Cadmium (Cd) 50.5 50 101ug/L -13070150.5
Cobalt (Co) 49.9 50 99.5ug/L -13070149.9
Lead (Pb) 50.5 50 101ug/L -13070150.5
Molybdenum (Mo) 74.5 50 103ug/L -13070174.5
Selenium (Se) 49.2 50 98.1ug/L -13070149.2
Thallium (Tl) Low Level 55 50 110ug/L -13070155
Vanadium (V) Low Level 51.6 50 101ug/L -13070151.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008412
Antimony (Sb) 47.3 50 94.6 6.65ug/L -13070147.3
Duke Energy Analytical Lab
Page 35 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040078 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008412
Arsenic (As) 47.4 50 94.5 6.2ug/L -13070147.4
Beryllium (Be) 47.7 50 95.6 2.82ug/L -13070147.7
Cadmium (Cd) 47.4 50 94.8 6.24ug/L -13070147.4
Cobalt (Co) 47.3 50 94.3 5.4ug/L -13070147.3
Lead (Pb) 47.6 50 94.9 6ug/L -13070147.6
Molybdenum (Mo) 71.5 50 97 6.07ug/L -13070171.5
Selenium (Se) 44.6 50 88.8 10ug/L -13070144.6
Thallium (Tl) Low Level 51.3 50 103 6.89ug/L -13070151.3
Vanadium (V) Low Level 49 50 95.3 5.3ug/L -13070149
Duke Energy Analytical Lab
Page 36 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040146 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.002 ug/L -10.002 1 < 1/2 RDL
Arsenic (As) 0.048 ug/L -10.048 1 < 1/2 RDL
Beryllium (Be) 0.049 ug/L -10.049 1 < 1/2 RDL
Cadmium (Cd) 0.003 ug/L -10.003 1 < 1/2 RDL
Cobalt (Co) 0.012 ug/L -10.012 1 < 1/2 RDL
Lead (Pb) 0.013 ug/L -10.013 1 < 1/2 RDL
Molybdenum (Mo) 0.017 ug/L -10.017 1 < 1/2 RDL
Selenium (Se) 0.041 ug/L -10.041 1 < 1/2 RDL
Thallium (Tl) Low Level 0.027 ug/L -10.027 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.062 ug/L -10.062 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 48.9 50 97.8ug/L -11585148.9
Arsenic (As) 50.1 50 100ug/L -11585150.1
Beryllium (Be) 50.6 50 101ug/L -11585150.6
Cadmium (Cd) 50.1 50 100ug/L -11585150.1
Cobalt (Co) 49.8 50 99.6ug/L -11585149.8
Lead (Pb) 49.5 50 99ug/L -11585149.5
Molybdenum (Mo) 51 50 102ug/L -11585151
Selenium (Se) 49 50 98.1ug/L -11585149
Thallium (Tl) Low Level 49.7 50 99.3ug/L -11585149.7
Vanadium (V) Low Level 49.3 50 98.7ug/L -11585149.3
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008416
Antimony (Sb) 51.8 50 103ug/L -13070151.8
Arsenic (As) 50.6 50 101ug/L -13070150.6
Beryllium (Be) 52.2 50 104ug/L -13070152.2
Cadmium (Cd) 52 50 104ug/L -13070152
Cobalt (Co) 50.6 50 101ug/L -13070150.6
Lead (Pb) 50.6 50 101ug/L -13070150.6
Molybdenum (Mo) 52.8 50 105ug/L -13070152.8
Selenium (Se) 49.9 50 98.9ug/L -13070149.9
Thallium (Tl) Low Level 51.5 50 103ug/L -13070151.5
Vanadium (V) Low Level 53 50 103ug/L -13070153
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008416
Antimony (Sb) 48.7 50 97.4 6.07ug/L -13070148.7
Duke Energy Analytical Lab
Page 37 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040146 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030335 -- 2017008416
Arsenic (As) 47.6 50 95 6.26ug/L -13070147.6
Beryllium (Be) 49.4 50 98.6 5.43ug/L -13070149.4
Cadmium (Cd) 48.9 50 97.8 6.11ug/L -13070148.9
Cobalt (Co) 47.6 50 95.2 6.18ug/L -13070147.6
Lead (Pb) 47.6 50 95.2 6.11ug/L -13070147.6
Molybdenum (Mo) 49 50 97.3 7.54ug/L -13070149
Selenium (Se) 46.7 50 92.6 6.63ug/L -13070146.7
Thallium (Tl) Low Level 48.6 50 97.1 5.92ug/L -13070148.6
Vanadium (V) Low Level 50.3 50 97.9 5.37ug/L -13070150.3
Duke Energy Analytical Lab
Page 38 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040032 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030335 -- 2017008411
TDS 134 0.749mg/L -1134
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030335 -- 2017008412
TDS 194 2.61mg/L -1194
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030335 -- 2017008413
TDS 159 2.48mg/L -1159
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 95 100 95mg/L -11090195
Duke Energy Analytical Lab
Page 39 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040100 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030093 -- 2017007155
TDS 199 0.504mg/L -1199
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030149 -- 2017007395
TDS 234 1.27mg/L -1234
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030335 -- 2017008415
TDS 358 0.834mg/L -1358
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J17030335 -- 2017008416
TDS 138 2.86mg/L -1138
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 104 100 104mg/L -110901104
Duke Energy Analytical Lab
Page 40 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040063 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030149 -- 2017007393
TSS 6 3.39mg/L -16
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030149 -- 2017007394
TSS 0.6 40mg/L -10.6
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030149 -- 2017007395
TSS 15.8 2.5mg/L -115.8
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J17030160 -- 2017007450
TSS 10 3.92mg/L -110
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 5
RPD
Parent Sample: J17030165 -- 2017007475
TSS 4.6 4.44mg/L -14.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 46.4 50 92.8mg/L -11090146.4
Duke Energy Analytical Lab
Page 41 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030335
Q17040124 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030098 -- 2017007173
TSS 3 6.9mg/L -13
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030098 -- 2017007175
TSS 3.2 6.06mg/L -13.2
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030108 -- 2017007204
TSS 11 1.83mg/L -111
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J17030138 -- 2017007350
TSS 10.4 0mg/L -110.4
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 5
RPD
Parent Sample: J17030138 -- 2017007351
TSS 4.2 0mg/L -14.2
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 46.4 50 92.8mg/L -11090146.4
Duke Energy Analytical Lab
Page 42 of 81
#=CL#
April 07, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92335800
92335800
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17030335
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 04, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
1(704)875-9092
Enclosures
cc:Program Manager, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 1 of 20
Duke Energy Analytical Lab
Page 43 of 81
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92335800
J17030335
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
Page 2 of 20
Duke Energy Analytical Lab
Page 44 of 81
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92335800
J17030335
Lab ID Sample ID Matrix Date Collected Date Received
92335800001 2017008411 Water 04/03/17 15:49 04/04/17 13:20
92335800002 2017008412 Water 04/03/17 16:08 04/04/17 13:20
92335800003 2017008413 Water 04/03/17 13:00 04/04/17 13:20
92335800004 2017008414 Water 04/03/17 12:46 04/04/17 13:20
92335800005 2017008418 Water 04/03/17 14:50 04/04/17 13:20
92335800006 2017008419 Water 04/03/17 14:02 04/04/17 13:20
92335800007 2017008420 Water 04/03/17 13:05 04/04/17 13:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
Duke Energy Analytical Lab
Page 45 of 81
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92335800
J17030335
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92335800001 2017008411 SM 2320B 3 PASI-AKDF1
92335800002 2017008412 SM 2320B 3 PASI-AKDF1
92335800003 2017008413 SM 2320B 3 PASI-AKDF1
92335800004 2017008414 SM 2320B 3 PASI-AKDF1
92335800005 2017008418 SM 2320B 3 PASI-AKDF1
92335800006 2017008419 SM 2320B 3 PASI-AKDF1
92335800007 2017008420 SM 2320B 3 PASI-AKDF1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
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Duke Energy Analytical Lab
Page 46 of 81
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92335800
J17030335
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92335800001 2017008411
Alkalinity,Bicarbonate (CaCO3)36.4 mg/L 04/06/17 20:225.0SM 2320B
Alkalinity, Total as CaCO3 36.4 mg/L 04/06/17 20:225.0SM 2320B
92335800002 2017008412
Alkalinity,Bicarbonate (CaCO3)165 mg/L 04/06/17 20:345.0SM 2320B
Alkalinity, Total as CaCO3 165 mg/L 04/06/17 20:345.0SM 2320B
92335800004 2017008414
Alkalinity,Bicarbonate (CaCO3)173 mg/L 04/06/17 21:155.0SM 2320B
Alkalinity, Total as CaCO3 173 mg/L 04/06/17 21:155.0SM 2320B
92335800005 2017008418
Alkalinity,Bicarbonate (CaCO3)297 mg/L 04/06/17 21:465.0SM 2320B
Alkalinity, Total as CaCO3 297 mg/L 04/06/17 21:46 M15.0SM 2320B
92335800006 2017008419
Alkalinity,Bicarbonate (CaCO3)53.4 mg/L 04/06/17 22:305.0SM 2320B
Alkalinity, Total as CaCO3 53.4 mg/L 04/06/17 22:305.0SM 2320B
92335800007 2017008420
Alkalinity,Bicarbonate (CaCO3)227 mg/L 04/06/17 22:415.0SM 2320B
Alkalinity, Total as CaCO3 227 mg/L 04/06/17 22:415.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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[phone]
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Duke Energy Analytical Lab
Page 47 of 81
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92335800
J17030335
Method:
Client:Duke Energy
SM 2320B
Date:April 07, 2017
Description:2320B Alkalinity
General Information:
7 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 355453
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92335800005,92335807008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1971866)
• Alkalinity, Total as CaCO3
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 48 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335800
J17030335
Sample:2017008411 Lab ID:92335800001 Collected:04/03/17 15:49 Received:04/04/17 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)36.4 mg/L 04/06/17 20:225.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/06/17 20:225.0 1
Alkalinity, Total as CaCO3 36.4 mg/L 04/06/17 20:225.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
Pace Analytical Services, LLC
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[phone]
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Duke Energy Analytical Lab
Page 49 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335800
J17030335
Sample:2017008412 Lab ID:92335800002 Collected:04/03/17 16:08 Received:04/04/17 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)165 mg/L 04/06/17 20:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/06/17 20:345.0 1
Alkalinity, Total as CaCO3 165 mg/L 04/06/17 20:345.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 50 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335800
J17030335
Sample:2017008413 Lab ID:92335800003 Collected:04/03/17 13:00 Received:04/04/17 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/06/17 21:055.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/06/17 21:055.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/06/17 21:055.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 51 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335800
J17030335
Sample:2017008414 Lab ID:92335800004 Collected:04/03/17 12:46 Received:04/04/17 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)173 mg/L 04/06/17 21:155.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/06/17 21:155.0 1
Alkalinity, Total as CaCO3 173 mg/L 04/06/17 21:155.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 52 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335800
J17030335
Sample:2017008418 Lab ID:92335800005 Collected:04/03/17 14:50 Received:04/04/17 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)297 mg/L 04/06/17 21:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/06/17 21:465.0 1
Alkalinity, Total as CaCO3 297 mg/L 04/06/17 21:46 M15.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
Pace Analytical Services, LLC
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[phone]
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Duke Energy Analytical Lab
Page 53 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335800
J17030335
Sample:2017008419 Lab ID:92335800006 Collected:04/03/17 14:02 Received:04/04/17 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)53.4 mg/L 04/06/17 22:305.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/06/17 22:305.0 1
Alkalinity, Total as CaCO3 53.4 mg/L 04/06/17 22:305.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
Pace Analytical Services, LLC
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[phone]
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Duke Energy Analytical Lab
Page 54 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92335800
J17030335
Sample:2017008420 Lab ID:92335800007 Collected:04/03/17 13:05 Received:04/04/17 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)227 mg/L 04/06/17 22:415.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/06/17 22:415.0 1
Alkalinity, Total as CaCO3 227 mg/L 04/06/17 22:415.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
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[phone]
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Duke Energy Analytical Lab
Page 55 of 81
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92335800
J17030335
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
355452
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92335800001, 92335800002, 92335800003, 92335800004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1971857
Associated Lab Samples:92335800001, 92335800002, 92335800003, 92335800004
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/06/17 15:16
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/06/17 15:16
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/06/17 15:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1971858LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.650 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1971859MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335589004
1971860
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 96 80-12096 0 255072.6 120 121
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1971861MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335589014
1971862
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 103 80-120102 1 255048.4 100 99.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
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Duke Energy Analytical Lab
Page 56 of 81
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92335800
J17030335
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
355453
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92335800005, 92335800006, 92335800007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1971863
Associated Lab Samples:92335800005, 92335800006, 92335800007
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/06/17 21:27
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/06/17 21:27
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/06/17 21:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1971864LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.750 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1971865MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335800005
1971866
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M15010580-120121 2 2550297349357
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1971867MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335807008
1971868
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 81 80-12082 0 2550291332332
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
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Duke Energy Analytical Lab
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92335800
J17030335
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
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Duke Energy Analytical Lab
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92335800
J17030335
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92335800001 3554522017008411SM 2320B
92335800002 3554522017008412SM 2320B
92335800003 3554522017008413SM 2320B
92335800004 3554522017008414SM 2320B
92335800005 3554532017008418SM 2320B
92335800006 3554532017008419SM 2320B
92335800007 3554532017008420SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 02:02 PM
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#=CL#
April 10, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92336004
92336004
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17030335
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 05, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
1(704)875-9092
Enclosures
cc:Program Manager, Duke Energy
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92336004
J17030335
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92336004
J17030335
Lab ID Sample ID Matrix Date Collected Date Received
92336004001 2017008415 Water 04/04/17 09:25 04/05/17 13:40
92336004002 2017008416 Water 04/04/17 12:40 04/05/17 13:40
92336004003 2017008417 Water 04/04/17 16:15 04/05/17 13:40
92336004004 2017008421 Water 04/04/17 12:40 04/05/17 13:40
92336004005 2017008422 Water 04/04/17 15:50 04/05/17 13:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92336004
J17030335
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92336004001 2017008415 SM 2320B 3 PASI-AKDF1
92336004002 2017008416 SM 2320B 3 PASI-AKDF1
92336004003 2017008417 SM 2320B 3 PASI-AKDF1
92336004004 2017008421 SM 2320B 3 PASI-AKDF1
92336004005 2017008422 SM 2320B 3 PASI-AKDF1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92336004
J17030335
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92336004001 2017008415
Alkalinity,Bicarbonate (CaCO3)140 mg/L 04/07/17 23:205.0SM 2320B
Alkalinity, Total as CaCO3 140 mg/L 04/07/17 23:205.0SM 2320B
92336004002 2017008416
Alkalinity,Bicarbonate (CaCO3)49.0 mg/L 04/07/17 23:335.0SM 2320B
Alkalinity, Total as CaCO3 49.0 mg/L 04/07/17 23:335.0SM 2320B
92336004003 2017008417
Alkalinity,Bicarbonate (CaCO3)161 mg/L 04/08/17 00:105.0SM 2320B
Alkalinity, Total as CaCO3 161 mg/L 04/08/17 00:105.0SM 2320B
92336004004 2017008421
Alkalinity,Bicarbonate (CaCO3)47.5 mg/L 04/08/17 00:415.0SM 2320B
Alkalinity, Total as CaCO3 47.5 mg/L 04/08/17 00:415.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92336004
J17030335
Method:
Client:Duke Energy
SM 2320B
Date:April 10, 2017
Description:2320B Alkalinity
General Information:
5 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92336004
J17030335
Sample:2017008415 Lab ID:92336004001 Collected:04/04/17 09:25 Received:04/05/17 13:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)140 mg/L 04/07/17 23:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/07/17 23:205.0 1
Alkalinity, Total as CaCO3 140 mg/L 04/07/17 23:205.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/10/2017 10:42 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92336004
J17030335
Sample:2017008416 Lab ID:92336004002 Collected:04/04/17 12:40 Received:04/05/17 13:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)49.0 mg/L 04/07/17 23:335.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/07/17 23:335.0 1
Alkalinity, Total as CaCO3 49.0 mg/L 04/07/17 23:335.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/10/2017 10:42 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 8 of 17
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92336004
J17030335
Sample:2017008417 Lab ID:92336004003 Collected:04/04/17 16:15 Received:04/05/17 13:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)161 mg/L 04/08/17 00:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/17 00:105.0 1
Alkalinity, Total as CaCO3 161 mg/L 04/08/17 00:105.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/10/2017 10:42 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92336004
J17030335
Sample:2017008421 Lab ID:92336004004 Collected:04/04/17 12:40 Received:04/05/17 13:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)47.5 mg/L 04/08/17 00:415.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/17 00:415.0 1
Alkalinity, Total as CaCO3 47.5 mg/L 04/08/17 00:415.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/10/2017 10:42 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92336004
J17030335
Sample:2017008422 Lab ID:92336004005 Collected:04/04/17 15:50 Received:04/05/17 13:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/08/17 00:525.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/17 00:525.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/08/17 00:525.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/10/2017 10:42 AM
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[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92336004
J17030335
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
355696
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92336004001, 92336004002, 92336004003, 92336004004, 92336004005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1973269
Associated Lab Samples:92336004001, 92336004002, 92336004003, 92336004004, 92336004005
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/07/17 20:52
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/07/17 20:52
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/07/17 20:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1973270LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.650 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1973271MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92335840008
1973272
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 102 80-120102 1 2550ND50.9 51.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1973273MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92336004002
1973274
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 110 80-120101 4 255049.0 104 99.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/10/2017 10:42 AM
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92336004
J17030335
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92336004
J17030335
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92336004001 3556962017008415SM 2320B
92336004002 3556962017008416SM 2320B
92336004003 3556962017008417SM 2320B
92336004004 3556962017008421SM 2320B
92336004005 3556962017008422SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/10/2017 10:42 AM
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[phone]
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