NC0038377_J17020082report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17020082
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:3/1/2017
Customer Address:Mayo Steam Plant
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, Kim Witt
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Metals via 200.8: The instrument calibration blank recovered above the detection limit for low level thallium but less than the
reporting limit. There is no adverse impact to data, however results have been flagged accordingly.
Metals 200.7: The matrix spike and spike duplicate associated with MW-2 recovered above method limits for aluminum.
Respective batch quality checks were acceptable and data has been flagged accordingly.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 113
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2017003712 MAYO STEAM 02-Feb-17 1:45 PM Alex Lefitz CW-3
2017003725 MAYO STEAM 02-Feb-17 2:35 PM Alex Lefitz CW-4
2017003726 MAYO STEAM 02-Feb-17 11:40 AM Alex Lefitz CW-5
2017003727 MAYO STEAM 02-Feb-17 2:06 PM Alex Lefitz MW-3BR
2017003728 MAYO STEAM 02-Feb-17 12:03 PM Alex Lefitz MW-5BR
2017003729 MAYO STEAM 02-Feb-17 10:16 AM Alex Lefitz MW-8BR
2017003730 MAYO STEAM 02-Feb-17 11:46 AM Alex Lefitz MW-10BR
2017003731 MAYO STEAM 02-Feb-17 9:01 AM Alex Lefitz MW-14BR
2017003732 MAYO STEAM 02-Feb-17 1:34 PM Alex Lefitz MW-2
2017003733 MAYO STEAM 02-Feb-17 3:26 PM Alex Lefitz MW-13BR
2017003734 MAYO STEAM 02-Feb-17 1:46 PM Alex Lefitz MW-11BR
2017003735 MAYO STEAM 02-Feb-17 2:45 PM Alex Lefitz Filter Blank
2017003736 MAYO STEAM 02-Feb-17 2:45 PM Alex Lefitz Equipment Blank
13 Total Samples
Duke Energy Analytical Lab
Page 2 of 113
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:3/1/2017
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003712
Collection Date:02-Feb-17 1:45 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.316 mg-N/L EPA 353.2 02/14/2017 14:47 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 93 mg/L EPA 300.0 02/06/2017 17:33 GHUTCHI220
Sulfate 15 mg/L EPA 300.0 02/06/2017 17:33 GHUTCHI220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:01 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 13:48 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 11:12 JJMACKE0.005 1
Barium (Ba)0.013 mg/L EPA 200.7 02/16/2017 11:12 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 11:12 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/16/2017 11:12 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/16/2017 11:12 JJMACKE0.005 1
Strontium (Sr)0.305 mg/L EPA 200.7 02/16/2017 11:12 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 11:12 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)59.6 mg/L EPA 200.7 02/20/2017 11:08 JJMACKE0.01 1
Magnesium (Mg)7.54 mg/L EPA 200.7 02/20/2017 11:08 JJMACKE0.005 1
Potassium (K)4.27 mg/L EPA 200.7 02/20/2017 11:08 JJMACKE0.1 1
Sodium (Na)40.9 mg/L EPA 200.7 02/20/2017 11:08 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.210 mg/L EPA 200.7 02/20/2017 13:59 MHH71310.005 1
Barium (Ba)0.013 mg/L EPA 200.7 02/20/2017 13:59 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 13:59 MHH71310.05 1
Iron (Fe)0.173 mg/L EPA 200.7 02/20/2017 13:59 MHH71310.01 1
Manganese (Mn)0.010 mg/L EPA 200.7 02/20/2017 13:59 MHH71310.005 1
Strontium (Sr)0.312 mg/L EPA 200.7 02/20/2017 13:59 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 13:59 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003712
Collection Date:02-Feb-17 1:45 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 21:17N1 CWSPEN30.2 1
Vanadium (V) Low Level 1.40 ug/L EPA 200.8 02/22/2017 21:17 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR0.2 1
Vanadium (V) Low Level 1.81 ug/L EPA 200.8 02/22/2017 16:19 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 390 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 5 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003712
Collection Date:02-Feb-17 1:45 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.9 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 6 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003725
Collection Date:02-Feb-17 2:35 PM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.148 mg-N/L EPA 353.2 02/14/2017 14:48 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.3 mg/L EPA 300.0 02/06/2017 19:48 GHUTCHI110
Sulfate 23 mg/L EPA 300.0 02/06/2017 19:48 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:03 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 13:50 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.052 mg/L EPA 200.7 02/16/2017 11:15 JJMACKE0.005 1
Barium (Ba)0.028 mg/L EPA 200.7 02/16/2017 11:15 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 11:15 JJMACKE0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 02/16/2017 11:15 JJMACKE0.01 1
Manganese (Mn)0.016 mg/L EPA 200.7 02/16/2017 11:15 JJMACKE0.005 1
Strontium (Sr)0.135 mg/L EPA 200.7 02/16/2017 11:15 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 11:15 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)12.8 mg/L EPA 200.7 02/20/2017 11:20 JJMACKE0.01 1
Magnesium (Mg)3.47 mg/L EPA 200.7 02/20/2017 11:20 JJMACKE0.005 1
Potassium (K)1.43 mg/L EPA 200.7 02/20/2017 11:20 JJMACKE0.1 1
Sodium (Na)16.8 mg/L EPA 200.7 02/20/2017 11:20 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.655 mg/L EPA 200.7 02/20/2017 14:11 MHH71310.005 1
Barium (Ba)0.028 mg/L EPA 200.7 02/20/2017 14:11 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:11 MHH71310.05 1
Iron (Fe)0.474 mg/L EPA 200.7 02/20/2017 14:11 MHH71310.01 1
Manganese (Mn)0.023 mg/L EPA 200.7 02/20/2017 14:11 MHH71310.005 1
Strontium (Sr)0.132 mg/L EPA 200.7 02/20/2017 14:11 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 14:11 MHH71310.005 1
Duke Energy Analytical Lab
Page 7 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003725
Collection Date:02-Feb-17 2:35 PM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 21:46N1 CWSPEN30.2 1
Vanadium (V) Low Level 1.32 ug/L EPA 200.8 02/22/2017 21:46 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR0.2 1
Vanadium (V) Low Level 1.99 ug/L EPA 200.8 02/22/2017 15:48 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 8 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003725
Collection Date:02-Feb-17 2:35 PM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.459 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 9 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003726
Collection Date:02-Feb-17 11:40 AM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 14:49 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 40 mg/L EPA 300.0 02/06/2017 17:55 GHUTCHI110
Sulfate 5.4 mg/L EPA 300.0 02/06/2017 17:55 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:06 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 13:53 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 11:19 JJMACKE0.005 1
Barium (Ba)0.055 mg/L EPA 200.7 02/16/2017 11:19 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 11:19 JJMACKE0.05 1
Iron (Fe)0.374 mg/L EPA 200.7 02/16/2017 11:19 JJMACKE0.01 1
Manganese (Mn)0.706 mg/L EPA 200.7 02/16/2017 11:19 JJMACKE0.005 1
Strontium (Sr)0.160 mg/L EPA 200.7 02/16/2017 11:19 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 11:19 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)52.8 mg/L EPA 200.7 02/20/2017 11:24 JJMACKE0.01 1
Magnesium (Mg)7.95 mg/L EPA 200.7 02/20/2017 11:24 JJMACKE0.005 1
Potassium (K)6.17 mg/L EPA 200.7 02/20/2017 11:24 JJMACKE0.1 1
Sodium (Na)18.8 mg/L EPA 200.7 02/20/2017 11:24 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.041 mg/L EPA 200.7 02/20/2017 14:15 MHH71310.005 1
Barium (Ba)0.053 mg/L EPA 200.7 02/20/2017 14:15 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:15 MHH71310.05 1
Iron (Fe)0.588 mg/L EPA 200.7 02/20/2017 14:15 MHH71310.01 1
Manganese (Mn)0.766 mg/L EPA 200.7 02/20/2017 14:15 MHH71310.005 1
Strontium (Sr)0.170 mg/L EPA 200.7 02/20/2017 14:15 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 14:15 MHH71310.005 1
Duke Energy Analytical Lab
Page 10 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003726
Collection Date:02-Feb-17 11:40 AM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 21:53N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 21:53 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 16:27 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 11 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003726
Collection Date:02-Feb-17 11:40 AM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.1 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 12 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003727
Collection Date:02-Feb-17 2:06 PM
Site:MW-3BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 14:50 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 200 mg/L EPA 300.0 02/06/2017 18:40 GHUTCHI10100
Sulfate 10 mg/L EPA 300.0 02/06/2017 18:40 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:08 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 13:55 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 11:31 JJMACKE0.005 1
Barium (Ba)0.040 mg/L EPA 200.7 02/16/2017 11:31 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 11:31 JJMACKE0.05 1
Iron (Fe)0.258 mg/L EPA 200.7 02/16/2017 11:31 JJMACKE0.01 1
Manganese (Mn)0.576 mg/L EPA 200.7 02/16/2017 11:31 JJMACKE0.005 1
Strontium (Sr)0.399 mg/L EPA 200.7 02/16/2017 11:31 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 11:31 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)135 mg/L EPA 200.7 02/20/2017 13:11 JJMACKE0.1 10
Magnesium (Mg)11.2 mg/L EPA 200.7 02/20/2017 13:11 JJMACKE0.005 1
Potassium (K)7.48 mg/L EPA 200.7 02/20/2017 13:11 JJMACKE0.1 1
Sodium (Na)19.9 mg/L EPA 200.7 02/20/2017 13:11 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.027 mg/L EPA 200.7 02/20/2017 14:19 MHH71310.005 1
Barium (Ba)0.039 mg/L EPA 200.7 02/20/2017 14:19 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:19 MHH71310.05 1
Iron (Fe)0.399 mg/L EPA 200.7 02/20/2017 14:19 MHH71310.01 1
Manganese (Mn)0.601 mg/L EPA 200.7 02/20/2017 14:19 MHH71310.005 1
Strontium (Sr)0.404 mg/L EPA 200.7 02/20/2017 14:19 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 14:19 MHH71310.005 1
Duke Energy Analytical Lab
Page 13 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003727
Collection Date:02-Feb-17 2:06 PM
Site:MW-3BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 22:01N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 22:01 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR0.2 1
Vanadium (V) Low Level 0.305 ug/L EPA 200.8 02/22/2017 16:34 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 690 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 14 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003727
Collection Date:02-Feb-17 2:06 PM
Site:MW-3BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 15 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003728
Collection Date:02-Feb-17 12:03 PM
Site:MW-5BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 14:51 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 67 mg/L EPA 300.0 02/06/2017 20:57 GHUTCHI220
Sulfate < 2 mg/L EPA 300.0 02/06/2017 20:57 GHUTCHI220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:11 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 13:58 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 02/16/2017 11:34 JJMACKE0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 02/16/2017 11:34 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 11:34 JJMACKE0.05 1
Iron (Fe)8.24 mg/L EPA 200.7 02/16/2017 11:34 JJMACKE0.01 1
Manganese (Mn)1.64 mg/L EPA 200.7 02/16/2017 11:34 JJMACKE0.005 1
Strontium (Sr)0.211 mg/L EPA 200.7 02/16/2017 11:34 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 11:34 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)90.6 mg/L EPA 200.7 02/20/2017 11:31 JJMACKE0.01 1
Magnesium (Mg)7.05 mg/L EPA 200.7 02/20/2017 11:31 JJMACKE0.005 1
Potassium (K)5.76 mg/L EPA 200.7 02/20/2017 11:31 JJMACKE0.1 1
Sodium (Na)17.3 mg/L EPA 200.7 02/20/2017 11:31 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.023 mg/L EPA 200.7 02/20/2017 14:23 MHH71310.005 1
Barium (Ba)0.037 mg/L EPA 200.7 02/20/2017 14:23 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:23 MHH71310.05 1
Iron (Fe)11.7 mg/L EPA 200.7 02/20/2017 14:23 MHH71310.01 1
Manganese (Mn)1.99 mg/L EPA 200.7 02/20/2017 14:23 MHH71310.005 1
Strontium (Sr)0.226 mg/L EPA 200.7 02/20/2017 14:23 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 14:23 MHH71310.005 1
Duke Energy Analytical Lab
Page 16 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003728
Collection Date:02-Feb-17 12:03 PM
Site:MW-5BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Molybdenum (Mo)1.91 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 22:08N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 22:08 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Molybdenum (Mo)1.54 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 16:42 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 410 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 17 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003728
Collection Date:02-Feb-17 12:03 PM
Site:MW-5BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.9 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 22 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 18 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003729
Collection Date:02-Feb-17 10:16 AM
Site:MW-8BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.252 mg-N/L EPA 353.2 02/14/2017 14:53 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 130 mg/L EPA 300.0 02/06/2017 21:20 GHUTCHI550
Sulfate 39 mg/L EPA 300.0 02/06/2017 21:20 GHUTCHI550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:13 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 14:00 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 12:29 JJMACKE0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 02/16/2017 12:29 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 12:29 JJMACKE0.05 1
Iron (Fe)0.024 mg/L EPA 200.7 02/16/2017 12:29 JJMACKE0.01 1
Manganese (Mn)0.311 mg/L EPA 200.7 02/16/2017 12:29 JJMACKE0.005 1
Strontium (Sr)0.343 mg/L EPA 200.7 02/16/2017 12:29 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 02/16/2017 12:29 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)90.3 mg/L EPA 200.7 02/20/2017 11:35 JJMACKE0.01 1
Magnesium (Mg)7.04 mg/L EPA 200.7 02/20/2017 11:35 JJMACKE0.005 1
Potassium (K)5.74 mg/L EPA 200.7 02/20/2017 11:35 JJMACKE0.1 1
Sodium (Na)17.3 mg/L EPA 200.7 02/20/2017 11:35 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.275 mg/L EPA 200.7 02/20/2017 14:27 MHH71310.005 1
Barium (Ba)0.023 mg/L EPA 200.7 02/20/2017 14:27 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:27 MHH71310.05 1
Iron (Fe)0.396 mg/L EPA 200.7 02/20/2017 14:27 MHH71310.01 1
Manganese (Mn)0.253 mg/L EPA 200.7 02/20/2017 14:27 MHH71310.005 1
Strontium (Sr)0.342 mg/L EPA 200.7 02/20/2017 14:27 MHH71310.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 02/20/2017 14:27 MHH71310.005 1
Duke Energy Analytical Lab
Page 19 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003729
Collection Date:02-Feb-17 10:16 AM
Site:MW-8BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Molybdenum (Mo)2.67 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Nickel (Ni)2.28 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 22:37N1 CWSPEN30.2 1
Vanadium (V) Low Level 0.607 ug/L EPA 200.8 02/22/2017 22:37 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Chromium (Cr)3.32 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Molybdenum (Mo)2.69 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Nickel (Ni)3.61 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR0.2 1
Vanadium (V) Low Level 1.22 ug/L EPA 200.8 02/22/2017 17:13 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 480 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 20 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003729
Collection Date:02-Feb-17 10:16 AM
Site:MW-8BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.7 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 21 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003730
Collection Date:02-Feb-17 11:46 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 14:54 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 300.0 02/06/2017 21:42 GHUTCHI220
Sulfate 86 mg/L EPA 300.0 02/06/2017 21:42 GHUTCHI220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:16 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 14:02 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 12:33 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/16/2017 12:33 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 12:33 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/16/2017 12:33 JJMACKE0.01 1
Manganese (Mn)0.059 mg/L EPA 200.7 02/16/2017 12:33 JJMACKE0.005 1
Strontium (Sr)0.194 mg/L EPA 200.7 02/16/2017 12:33 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 02/16/2017 12:33 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)69.7 mg/L EPA 200.7 02/20/2017 13:15 JJMACKE0.01 1
Magnesium (Mg)13.5 mg/L EPA 200.7 02/20/2017 13:15 JJMACKE0.05 10
Potassium (K)5.52 mg/L EPA 200.7 02/20/2017 13:15 JJMACKE0.1 1
Sodium (Na)27.1 mg/L EPA 200.7 02/20/2017 13:15 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.049 mg/L EPA 200.7 02/20/2017 14:31 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/20/2017 14:31 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:31 MHH71310.05 1
Iron (Fe)0.078 mg/L EPA 200.7 02/20/2017 14:31 MHH71310.01 1
Manganese (Mn)0.072 mg/L EPA 200.7 02/20/2017 14:31 MHH71310.005 1
Strontium (Sr)0.203 mg/L EPA 200.7 02/20/2017 14:31 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 14:31 MHH71310.005 1
Duke Energy Analytical Lab
Page 22 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003730
Collection Date:02-Feb-17 11:46 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Nickel (Ni)1.76 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 22:44N1 CWSPEN30.2 1
Vanadium (V) Low Level 1.83 ug/L EPA 200.8 02/22/2017 22:44 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Nickel (Ni)1.91 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR0.2 1
Vanadium (V) Low Level 1.99 ug/L EPA 200.8 02/22/2017 17:21 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 23 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003730
Collection Date:02-Feb-17 11:46 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.9 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 24 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003731
Collection Date:02-Feb-17 9:01 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.291 mg-N/L EPA 353.2 02/14/2017 14:55 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 02/06/2017 22:05 GHUTCHI0.5 5
Sulfate 8.6 mg/L EPA 300.0 02/06/2017 22:05 GHUTCHI0.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:18 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 14:05 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 12:36 JJMACKE0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 02/16/2017 12:36 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 12:36 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/16/2017 12:36 JJMACKE0.01 1
Manganese (Mn)0.108 mg/L EPA 200.7 02/16/2017 12:36 JJMACKE0.005 1
Strontium (Sr)0.151 mg/L EPA 200.7 02/16/2017 12:36 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 12:36 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)28.9 mg/L EPA 200.7 02/20/2017 12:00 JJMACKE0.01 1
Magnesium (Mg)13.1 mg/L EPA 200.7 02/20/2017 12:00 JJMACKE0.005 1
Potassium (K)4.04 mg/L EPA 200.7 02/20/2017 12:00 JJMACKE0.1 1
Sodium (Na)38.4 mg/L EPA 200.7 02/20/2017 12:00 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.063 mg/L EPA 200.7 02/20/2017 14:35 MHH71310.005 1
Barium (Ba)0.019 mg/L EPA 200.7 02/20/2017 14:35 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:35 MHH71310.05 1
Iron (Fe)0.037 mg/L EPA 200.7 02/20/2017 14:35 MHH71310.01 1
Manganese (Mn)0.096 mg/L EPA 200.7 02/20/2017 14:35 MHH71310.005 1
Strontium (Sr)0.150 mg/L EPA 200.7 02/20/2017 14:35 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 14:35 MHH71310.005 1
Duke Energy Analytical Lab
Page 25 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003731
Collection Date:02-Feb-17 9:01 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Molybdenum (Mo)4.70 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 22:51N1 CWSPEN30.2 1
Vanadium (V) Low Level 1.98 ug/L EPA 200.8 02/22/2017 22:51 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Copper (Cu)1.36 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Molybdenum (Mo)5.04 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR0.2 1
Vanadium (V) Low Level 2.07 ug/L EPA 200.8 02/22/2017 17:28 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 26 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003731
Collection Date:02-Feb-17 9:01 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.832 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 27 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003732
Collection Date:02-Feb-17 1:34 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:20 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)14.1 mg/L EPA 200.7 02/20/2017 12:03 JJMACKE0.01 1
Magnesium (Mg)2.49 mg/L EPA 200.7 02/20/2017 12:03 JJMACKE0.005 1
Potassium (K)6.28 mg/L EPA 200.7 02/20/2017 12:03 JJMACKE0.1 1
Sodium (Na)41.1 mg/L EPA 200.7 02/20/2017 12:03 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.34 mg/L EPA 200.7 02/20/2017 14:52M1 MHH71310.005 1
Barium (Ba)0.071 mg/L EPA 200.7 02/20/2017 14:52 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:52 MHH71310.05 1
Iron (Fe)1.84 mg/L EPA 200.7 02/20/2017 14:52 MHH71310.01 1
Manganese (Mn)1.33 mg/L EPA 200.7 02/20/2017 14:52 MHH71310.005 1
Strontium (Sr)0.226 mg/L EPA 200.7 02/20/2017 14:52 MHH71310.005 1
Zinc (Zn)0.023 mg/L EPA 200.7 02/20/2017 14:52 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Chromium (Cr)1.64 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Cobalt (Co)5.04 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Copper (Cu)17.1 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Molybdenum (Mo)9.32 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Nickel (Ni)14.3 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR0.2 1
Vanadium (V) Low Level 2.74 ug/L EPA 200.8 02/22/2017 17:36 PARMSTR0.3 1
TOTAL SUSPENDED SOLIDS
TSS 17 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 28 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003733
Collection Date:02-Feb-17 3:26 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 14:56 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 34 mg/L EPA 300.0 02/06/2017 22:27 GHUTCHI110
Sulfate 15 mg/L EPA 300.0 02/06/2017 22:27 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:40 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 14:07 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 12:40 JJMACKE0.005 1
Barium (Ba)0.033 mg/L EPA 200.7 02/16/2017 12:40 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 12:40 JJMACKE0.05 1
Iron (Fe)2.73 mg/L EPA 200.7 02/16/2017 12:40 JJMACKE0.01 1
Manganese (Mn)0.412 mg/L EPA 200.7 02/16/2017 12:40 JJMACKE0.005 1
Strontium (Sr)0.341 mg/L EPA 200.7 02/16/2017 12:40 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 12:40 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)65.0 mg/L EPA 200.7 02/20/2017 12:07 JJMACKE0.01 1
Magnesium (Mg)12.0 mg/L EPA 200.7 02/20/2017 12:07 JJMACKE0.005 1
Potassium (K)4.43 mg/L EPA 200.7 02/20/2017 12:07 JJMACKE0.1 1
Sodium (Na)16.8 mg/L EPA 200.7 02/20/2017 12:07 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.091 mg/L EPA 200.7 02/20/2017 14:39 MHH71310.005 1
Barium (Ba)0.031 mg/L EPA 200.7 02/20/2017 14:39 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 14:39 MHH71310.05 1
Iron (Fe)2.92 mg/L EPA 200.7 02/20/2017 14:39 MHH71310.01 1
Manganese (Mn)0.421 mg/L EPA 200.7 02/20/2017 14:39 MHH71310.005 1
Strontium (Sr)0.353 mg/L EPA 200.7 02/20/2017 14:39 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 14:39 MHH71310.005 1
Duke Energy Analytical Lab
Page 29 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003733
Collection Date:02-Feb-17 3:26 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Cobalt (Co)2.68 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Molybdenum (Mo)2.24 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 23:06N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 23:06 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Chromium (Cr)2.70 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Cobalt (Co)2.91 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Molybdenum (Mo)2.35 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Nickel (Ni)1.39 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR0.2 1
Vanadium (V) Low Level 0.406 ug/L EPA 200.8 02/22/2017 17:44 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 30 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003733
Collection Date:02-Feb-17 3:26 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.458 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 10 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 31 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003734
Collection Date:02-Feb-17 1:46 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.299 mg-N/L EPA 353.2 02/14/2017 15:35 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 02/06/2017 22:50 GHUTCHI0.5 5
Sulfate 9.5 mg/L EPA 300.0 02/06/2017 22:50 GHUTCHI0.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:42 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 13:41 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.192 mg/L EPA 200.7 02/16/2017 12:44 JJMACKE0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 02/16/2017 12:44 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 12:44 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/16/2017 12:44 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/16/2017 12:44 JJMACKE0.005 1
Strontium (Sr)0.248 mg/L EPA 200.7 02/16/2017 12:44 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 12:44 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)17.8 mg/L EPA 200.7 02/20/2017 12:19 JJMACKE0.01 1
Magnesium (Mg)1.20 mg/L EPA 200.7 02/20/2017 12:19 JJMACKE0.005 1
Potassium (K)6.52 mg/L EPA 200.7 02/20/2017 12:19 JJMACKE0.1 1
Sodium (Na)15.4 mg/L EPA 200.7 02/20/2017 12:19 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.240 mg/L EPA 200.7 02/20/2017 15:04 MHH71310.005 1
Barium (Ba)0.024 mg/L EPA 200.7 02/20/2017 15:04 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 15:04 MHH71310.05 1
Iron (Fe)0.037 mg/L EPA 200.7 02/20/2017 15:04 MHH71310.01 1
Manganese (Mn)0.005 mg/L EPA 200.7 02/20/2017 15:04 MHH71310.005 1
Strontium (Sr)0.280 mg/L EPA 200.7 02/20/2017 15:04 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 15:04 MHH71310.005 1
Duke Energy Analytical Lab
Page 32 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003734
Collection Date:02-Feb-17 1:46 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.52 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Chromium (Cr)10.9 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Copper (Cu)1.03 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Molybdenum (Mo)9.11 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 22:58N1 CWSPEN30.2 1
Vanadium (V) Low Level 11.7 ug/L EPA 200.8 02/22/2017 22:58 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.51 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Chromium (Cr)10.5 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Copper (Cu)1.19 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Molybdenum (Mo)9.30 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR0.2 1
Vanadium (V) Low Level 12.0 ug/L EPA 200.8 02/22/2017 18:14 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 02/07/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 33 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003734
Collection Date:02-Feb-17 1:46 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.3 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/07/2017 09:00 MGIGANT51
Duke Energy Analytical Lab
Page 34 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003735
Collection Date:02-Feb-17 2:45 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/20/2017 15:01 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 12:49 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/16/2017 12:49 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 12:49 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/16/2017 12:49 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/16/2017 12:49 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 02/16/2017 12:49 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 12:49 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 23:34N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 23:34 CWSPEN30.3 1
Duke Energy Analytical Lab
Page 35 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003736
Collection Date:02-Feb-17 2:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:36 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 02/06/2017 23:13 GHUTCHI0.1 1
Sulfate < 0.1 mg/L EPA 300.0 02/06/2017 23:13 GHUTCHI0.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 13:45 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.039 mg/L EPA 200.7 02/20/2017 12:22 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 02/20/2017 12:22 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 02/20/2017 12:22 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 02/20/2017 12:22 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/20/2017 15:08 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/20/2017 15:08 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 15:08 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/20/2017 15:08 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/20/2017 15:08 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 02/20/2017 15:08 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 15:08 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 18:22 PARMSTR0.3 1
Duke Energy Analytical Lab
Page 36 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
2017003736
Collection Date:02-Feb-17 2:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.226 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5.4 mg/L SM2540D 02/07/2017 09:00 MGIGANT5.4 1
N1-Target analyte was detected in continuing calibration blank(s) at a concentration greater than ½ the reporting limit
but less than the reporting limit.
Qualifiers:
M1 Matrix spike recovery was High: the associated Laboratory Control Spike (LCS) was acceptable.
N1 See additional information listed below.
Duke Energy Analytical Lab
Page 37 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020381 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0006 mg-N/L -1-0.0006 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0007 mg-N/L -1-0.0007 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0011 mg-N/L -10.0011 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0007 mg-N/L -1-0.0007 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.303 3.01 101mg-N/L -11090103.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.3 3.01 99.7mg-N/L -11090103
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.6mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 98.9mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010203 -- 2017000828
Nitrite + Nitrate
(Colorimetric)
0.993 50 96.4mg-N/L -11090200199
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010203 -- 2017000828
Nitrite + Nitrate
(Colorimetric)
0.987 50 94 2.52mg-N/L -11090200197
Duke Energy Analytical Lab
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Certificate of Laboratory Analysis
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Order # J17020082
Q17020381 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Nitrite + Nitrate
(Colorimetric)
0.24 0.25 99.1mg-N/L -1109010.24
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Nitrite + Nitrate
(Colorimetric)
0.234 0.25 97 2.16mg-N/L -1109010.234
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Nitrite + Nitrate
(Colorimetric)
0.306 0.25 98.1mg-N/L -1109010.306
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Nitrite + Nitrate
(Colorimetric)
0.309 0.25 99.2 1.18mg-N/L -1109010.309
Duke Energy Analytical Lab
Page 39 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020118 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0 mg/L -10 0.1 < 1/2 RDL
Sulfate 0 mg/L -10 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 3.45 10 108mg/L -12080517.2
Sulfate 2.99 10 113mg/L -12080514.9
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 3.45 10 108 0.139mg/L -12080517.3
Sulfate 2.99 10 113 0.0444mg/L -12080514.9
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 2.92 20 109mg/L -120801029.2
Sulfate 4.41 20 104mg/L -120801044.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 2.9 20 109 0.55mg/L -120801029
Sulfate 4.38 20 102 1.8mg/L -120801043.8
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 2.08 2 104mg/L -1109012.08
Sulfate 2.1 2 105mg/L -1109012.1
Duke Energy Analytical Lab
Page 40 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020456 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.014 ug/L -10.014 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.02 ug/L -10.02 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.903 20 88.2ug/L -130702018.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.914 20 89.2 1.18ug/L -130702018.3
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.861 100 83.6ug/L -1307010086.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.843 100 81.8 2.2ug/L -1307010084.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.98 2 98.8ug/L -1158511.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.86 2 93.2ug/L -1158511.86
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020436 -- 2017005386
Mercury (Hg) 1.01 1 98.1ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020436 -- 2017005386
Mercury (Hg) 1.03 1 99.7 1.62ug/L -1307011.03
Duke Energy Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020536 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.012 ug/L -10.012 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.015 ug/L -10.015 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.01 2 100ug/L -1158512.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.94 2 96.8ug/L -1158511.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003734
Mercury (Hg) 1.04 1 102ug/L -1307011.04
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003734
Mercury (Hg) 1.06 1 105 2.03ug/L -1307011.06
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020223 -- 2017004412
Mercury (Hg) 1 1 98.8ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020223 -- 2017004412
Mercury (Hg) 0.975 1 96.3 2.56ug/L -1307010.975
Duke Energy Analytical Lab
Page 42 of 113
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Order # J17020082
Q17020465 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000078 mg/L -10.000078 0.005 < 1/2 RDL
Barium (Ba) 0.000042 mg/L -10.000042 0.005 < 1/2 RDL
Boron (B) 0.000248 mg/L -10.000248 0.05 < 1/2 RDL
Iron (Fe) -0.000187 mg/L -1-0.000187 0.01 < 1/2 RDL
Manganese (Mn) 0.000006 mg/L -10.000006 0.005 < 1/2 RDL
Strontium (Sr) 0.000105 mg/L -10.000105 0.005 < 1/2 RDL
Zinc (Zn) 0.00191 mg/L -10.00191 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) 0.000585 mg/L -10.000585 0.005 < 1/2 RDL
Barium (Ba) -0.00015 mg/L -1-0.00015 0.005 < 1/2 RDL
Boron (B) 0.000013 mg/L -10.000013 0.05 < 1/2 RDL
Iron (Fe) 0.0047 mg/L -10.0047 0.01 < 1/2 RDL
Manganese (Mn) 0.000108 mg/L -10.000108 0.005 < 1/2 RDL
Strontium (Sr) 0.000116 mg/L -10.000116 0.005 < 1/2 RDL
Zinc (Zn) 0.000335 mg/L -10.000335 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.04 2 102mg/L -1158512.04
Barium (Ba) 0.991 1 99.1mg/L -1158510.991
Boron (B) 2.01 2 101mg/L -1158512.01
Iron (Fe) 2.03 2 102mg/L -1158512.03
Manganese (Mn) 0.97 1 97mg/L -1158510.97
Strontium (Sr) 1.9 2 94.8mg/L -1158511.9
Zinc (Zn) 1.02 1 102mg/L -1158511.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.04 2 102mg/L -1158512.04
Barium (Ba) 0.989 1 98.9mg/L -1158510.989
Boron (B) 2 2 100mg/L -1158512
Iron (Fe) 2.02 2 101mg/L -1158512.02
Manganese (Mn) 0.97 1 97mg/L -1158510.97
Strontium (Sr) 1.9 2 94.8mg/L -1158511.9
Zinc (Zn) 1 1 100mg/L -1158511
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Aluminum (Al) 5.69 5 114mg/L -1307015.69
Duke Energy Analytical Lab
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Order # J17020082
Q17020465 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Barium (Ba) 5.85 5 116mg/L -1307015.85
Boron (B) 6.25 5 104mg/L -1307016.25
Iron (Fe) 5.5 5 110mg/L -1307015.5
Manganese (Mn) 6.84 5 113mg/L -1307016.84
Strontium (Sr) 5.8 5 109mg/L -1307015.8
Zinc (Zn) 5.67 5 113mg/L -1307015.67
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Aluminum (Al) 5.64 5 113 0.812mg/L -1307015.64
Barium (Ba) 5.81 5 115 0.694mg/L -1307015.81
Boron (B) 6.17 5 102 1.42mg/L -1307016.17
Iron (Fe) 5.44 5 109 0.97mg/L -1307015.44
Manganese (Mn) 6.78 5 112 1.18mg/L -1307016.78
Strontium (Sr) 5.73 5 108 1.33mg/L -1307015.73
Zinc (Zn) 5.63 5 113 0.638mg/L -1307015.63
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003726
Aluminum (Al) 5.65 5 113mg/L -1307015.65
Barium (Ba) 5.89 5 117mg/L -1307015.89
Boron (B) 5.3 5 106mg/L -1307015.3
Iron (Fe) 5.85 5 110mg/L -1307015.85
Manganese (Mn) 6.46 5 115mg/L -1307016.46
Strontium (Sr) 5.64 5 110mg/L -1307015.64
Zinc (Zn) 5.69 5 114mg/L -1307015.69
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003726
Aluminum (Al) 5.64 5 113 0.124mg/L -1307015.64
Barium (Ba) 5.88 5 117 0.206mg/L -1307015.88
Boron (B) 5.27 5 105 0.643mg/L -1307015.27
Iron (Fe) 5.82 5 109 0.494mg/L -1307015.82
Manganese (Mn) 6.43 5 114 0.523mg/L -1307016.43
Strontium (Sr) 5.63 5 109 0.311mg/L -1307015.63
Zinc (Zn) 5.67 5 113 0.229mg/L -1307015.67
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020342 -- 2017004969
Aluminum (Al) 5.63 5 113mg/L -1307015.63
Barium (Ba) 5.38 5 107mg/L -1307015.38
Duke Energy Analytical Lab
Page 44 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020465 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020342 -- 2017004969
Boron (B) 7.42 5 99.6mg/L -1307017.42
Iron (Fe) 5.42 5 108mg/L -1307015.42
Manganese (Mn) 5.69 5 114mg/L -1307015.69
Strontium (Sr) 6.41 5 108mg/L -1307016.41
Zinc (Zn) 5.33 5 107mg/L -1307015.33
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020342 -- 2017004969
Aluminum (Al) 5.59 5 112 0.73mg/L -1307015.59
Barium (Ba) 4.92 5 97.7 9.1mg/L -1307014.92
Boron (B) 7.32 5 97.5 2.09mg/L -1307017.32
Iron (Fe) 5.37 5 107 0.945mg/L -1307015.37
Manganese (Mn) 5.65 5 113 0.6mg/L -1307015.65
Strontium (Sr) 6.38 5 107 0.614mg/L -1307016.38
Zinc (Zn) 5.32 5 106 0.169mg/L -1307015.32
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17020345 -- 2017004981
Aluminum (Al) 5.68 5 113mg/L -1307015.68
Barium (Ba) 5.82 5 115mg/L -1307015.82
Boron (B) 5.47 5 104mg/L -1307015.47
Iron (Fe) 15.1 5 106mg/L -13070115.1
Manganese (Mn) 9.7 5 99.1mg/L -1307019.7
Strontium (Sr) 5.59 5 109mg/L -1307015.59
Zinc (Zn) 5.64 5 112mg/L -1307015.64
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17020345 -- 2017004981
Aluminum (Al) 5.7 5 114 0.317mg/L -1307015.7
Barium (Ba) 5.83 5 115 0.261mg/L -1307015.83
Boron (B) 5.53 5 105 1.15mg/L -1307015.53
Iron (Fe) 15.2 5 108 1.53mg/L -13070115.2
Manganese (Mn) 9.73 5 99.7 0.523mg/L -1307019.73
Strontium (Sr) 5.61 5 109 0.349mg/L -1307015.61
Zinc (Zn) 5.64 5 112 0.143mg/L -1307015.64
Duke Energy Analytical Lab
Page 45 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020530 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) -0.00008 mg/L -1-0.00008 0.01 < 1/2 RDL
Magnesium (Mg) 0.000244 mg/L -10.000244 0.005 < 1/2 RDL
Potassium (K) 0.0178 mg/L -10.0178 0.1 < 1/2 RDL
Sodium (Na) 0.000083 mg/L -10.000083 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 1.99 2 99.4mg/L -1158511.99
Magnesium (Mg) 1.96 2 98.2mg/L -1158511.96
Potassium (K) 3.88 4 97.1mg/L -1158513.88
Sodium (Na) 7.94 8.1 98mg/L -1158517.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003712
Calcium (Ca) 63.8 5 84.2mg/L -13070163.8
Magnesium (Mg) 12.7 5 103mg/L -13070112.7
Potassium (K) 10.2 5 118mg/L -13070110.2
Sodium (Na) 46.1 5 104mg/L -13070146.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003712
Calcium (Ca) 63.1 5 71.1 16.9mg/L -13070163.1
Magnesium (Mg) 12.6 5 102 0.956mg/L -13070112.6
Potassium (K) 10.1 5 116 1.64mg/L -13070110.1
Sodium (Na) 45.9 5 100 3.64mg/L -13070145.9
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003733
Calcium (Ca) 69.1 5 81.6mg/L -13070169.1
Magnesium (Mg) 17.4 5 109mg/L -13070117.4
Potassium (K) 10.2 5 115mg/L -13070110.2
Sodium (Na) 21.9 5 103mg/L -13070121.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003733
Calcium (Ca) 69.7 5 93.2 13.3mg/L -13070169.7
Magnesium (Mg) 17.5 5 110 0.898mg/L -13070117.5
Potassium (K) 10.2 5 116 0.897mg/L -13070110.2
Sodium (Na) 22.1 5 107 4.21mg/L -13070122.1
Duke Energy Analytical Lab
Page 46 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020484 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.0009 mg/L -10.0009 0.005 < 1/2 RDL
Barium (Ba) 0.00004 mg/L -10.00004 0.005 < 1/2 RDL
Boron (B) 0.000893 mg/L -10.000893 0.05 < 1/2 RDL
Iron (Fe) 0.00115 mg/L -10.00115 0.01 < 1/2 RDL
Manganese (Mn) 0.000144 mg/L -10.000144 0.005 < 1/2 RDL
Strontium (Sr) 0.000194 mg/L -10.000194 0.005 < 1/2 RDL
Zinc (Zn) 0.00159 mg/L -10.00159 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.66 5 93.2mg/L -1158514.66
Barium (Ba) 4.7 5 94mg/L -1158514.7
Boron (B) 4.86 5 97.3mg/L -1158514.86
Iron (Fe) 4.92 5 98.4mg/L -1158514.92
Manganese (Mn) 4.87 5 97.4mg/L -1158514.87
Strontium (Sr) 4.78 5 95.6mg/L -1158514.78
Zinc (Zn) 4.78 5 95.6mg/L -1158514.78
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003712
Aluminum (Al) 5.01 5 96mg/L -1307015.01
Barium (Ba) 4.75 5 94.7mg/L -1307014.75
Boron (B) 4.96 5 99.1mg/L -1307014.96
Iron (Fe) 5.09 5 98.4mg/L -1307015.09
Manganese (Mn) 4.85 5 96.9mg/L -1307014.85
Strontium (Sr) 5.13 5 96.5mg/L -1307015.13
Zinc (Zn) 4.68 5 93.6mg/L -1307014.68
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003712
Aluminum (Al) 5.03 5 96.5 0.457mg/L -1307015.03
Barium (Ba) 4.79 5 95.5 0.799mg/L -1307014.79
Boron (B) 4.99 5 99.6 0.564mg/L -1307014.99
Iron (Fe) 5.13 5 99.1 0.689mg/L -1307015.13
Manganese (Mn) 4.89 5 97.6 0.741mg/L -1307014.89
Strontium (Sr) 5.14 5 96.5 0.0622mg/L -1307015.14
Zinc (Zn) 4.69 5 93.8 0.277mg/L -1307014.69
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003732
Aluminum (Al) 7.9 5 131mg/L -1307017.9
Duke Energy Analytical Lab
Page 47 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020484 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003732
Barium (Ba) 4.81 5 94.9mg/L -1307014.81
Boron (B) 4.99 5 99.8mg/L -1307014.99
Iron (Fe) 7.03 5 104mg/L -1307017.03
Manganese (Mn) 6.32 5 99.6mg/L -1307016.32
Strontium (Sr) 5.01 5 95.6mg/L -1307015.01
Zinc (Zn) 4.89 5 97.3mg/L -1307014.89
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003732
Aluminum (Al) 7.88 5 131 0.244mg/L -1307017.88
Barium (Ba) 4.8 5 94.6 0.253mg/L -1307014.8
Boron (B) 4.98 5 99.5 0.321mg/L -1307014.98
Iron (Fe) 7.03 5 104 0.0193mg/L -1307017.03
Manganese (Mn) 6.3 5 99.4 0.261mg/L -1307016.3
Strontium (Sr) 5.09 5 97.4 1.82mg/L -1307015.09
Zinc (Zn) 4.84 5 96.3 0.971mg/L -1307014.84
Duke Energy Analytical Lab
Page 48 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020527 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.052 ug/L -1-0.052 1 < 1/2 RDL
Arsenic (As) 0.002 ug/L -10.002 1 < 1/2 RDL
Beryllium (Be) -0.021 ug/L -1-0.021 1 < 1/2 RDL
Cadmium (Cd) 0.004 ug/L -10.004 1 < 1/2 RDL
Chromium (Cr) -0.027 ug/L -1-0.027 1 < 1/2 RDL
Cobalt (Co) 0.003 ug/L -10.003 1 < 1/2 RDL
Copper (Cu) -0.059 ug/L -1-0.059 1 < 1/2 RDL
Lead (Pb) 0.005 ug/L -10.005 1 < 1/2 RDL
Molybdenum (Mo) 0.008 ug/L -10.008 1 < 1/2 RDL
Nickel (Ni) -0.17 ug/L -1-0.17 1 < 1/2 RDL
Selenium (Se) 0.01 ug/L -10.01 1 < 1/2 RDL
Thallium (Tl) Low Level 0.058 ug/L -10.058 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.005 ug/L -1-0.005 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.1 50 100ug/L -11585150.1
Arsenic (As) 50 50 100ug/L -11585150
Beryllium (Be) 52.2 50 104ug/L -11585152.2
Cadmium (Cd) 50.9 50 102ug/L -11585150.9
Chromium (Cr) 51 50 102ug/L -11585151
Cobalt (Co) 50.6 50 101ug/L -11585150.6
Copper (Cu) 50.5 50 101ug/L -11585150.5
Lead (Pb) 51.1 50 102ug/L -11585151.1
Molybdenum (Mo) 51.8 50 104ug/L -11585151.8
Nickel (Ni) 51.1 50 102ug/L -11585151.1
Selenium (Se) 49.7 50 99.4ug/L -11585149.7
Thallium (Tl) Low Level 52.3 50 105ug/L -11585152.3
Vanadium (V) Low Level 50.6 50 101ug/L -11585150.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003712
Antimony (Sb) 51.9 50 104ug/L -13070151.9
Arsenic (As) 51.2 50 102ug/L -13070151.2
Beryllium (Be) 53.4 50 107ug/L -13070153.4
Cadmium (Cd) 51.1 50 102ug/L -13070151.1
Chromium (Cr) 51.3 50 103ug/L -13070151.3
Cobalt (Co) 50.2 50 100ug/L -13070150.2
Copper (Cu) 50.9 50 102ug/L -13070150.9
Lead (Pb) 51.3 50 102ug/L -13070151.3
Duke Energy Analytical Lab
Page 49 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020527 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003712
Molybdenum (Mo) 52.6 50 105ug/L -13070152.6
Nickel (Ni) 50.4 50 101ug/L -13070150.4
Selenium (Se) 50.1 50 100ug/L -13070150.1
Thallium (Tl) Low Level 35.9 50 71.7ug/L -13070135.9
Vanadium (V) Low Level 52.7 50 103ug/L -13070152.7
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003712
Antimony (Sb) 51.8 50 104 0.199ug/L -13070151.8
Arsenic (As) 51.2 50 102 0.0822ug/L -13070151.2
Beryllium (Be) 55.8 50 112 4.46ug/L -13070155.8
Cadmium (Cd) 51 50 102 0.129ug/L -13070151
Chromium (Cr) 51.3 50 103 0.0956ug/L -13070151.3
Cobalt (Co) 50.2 50 100 0.0279ug/L -13070150.2
Copper (Cu) 50.5 50 101 0.785ug/L -13070150.5
Lead (Pb) 51.3 50 103 0.0624ug/L -13070151.3
Molybdenum (Mo) 53.1 50 105 0.853ug/L -13070153.1
Nickel (Ni) 50.7 50 101 0.491ug/L -13070150.7
Selenium (Se) 50.5 50 101 0.797ug/L -13070150.5
Thallium (Tl) Low Level 41.2 50 82.3 13.7ug/L -13070141.2
Vanadium (V) Low Level 52.8 50 103 0.216ug/L -13070152.8
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003733
Antimony (Sb) 51.3 50 102ug/L -13070151.3
Arsenic (As) 50.9 50 101ug/L -13070150.9
Beryllium (Be) 54.4 50 109ug/L -13070154.4
Cadmium (Cd) 50.4 50 101ug/L -13070150.4
Chromium (Cr) 51 50 102ug/L -13070151
Cobalt (Co) 52.6 50 99.9ug/L -13070152.6
Copper (Cu) 50.4 50 101ug/L -13070150.4
Lead (Pb) 50.9 50 102ug/L -13070150.9
Molybdenum (Mo) 54.6 50 105ug/L -13070154.6
Nickel (Ni) 51 50 101ug/L -13070151
Selenium (Se) 50 50 100ug/L -13070150
Thallium (Tl) Low Level 45.6 50 91.1ug/L -13070145.6
Vanadium (V) Low Level 51 50 102ug/L -13070151
Duke Energy Analytical Lab
Page 50 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020527 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003733
Antimony (Sb) 51.9 50 104 1.18ug/L -13070151.9
Arsenic (As) 51.5 50 103 1.21ug/L -13070151.5
Beryllium (Be) 52.7 50 105 3.2ug/L -13070152.7
Cadmium (Cd) 50.9 50 102 0.948ug/L -13070150.9
Chromium (Cr) 51.6 50 103 1.08ug/L -13070151.6
Cobalt (Co) 53.1 50 101 0.853ug/L -13070153.1
Copper (Cu) 50.4 50 101 0.0119ug/L -13070150.4
Lead (Pb) 51.3 50 103 0.852ug/L -13070151.3
Molybdenum (Mo) 54.7 50 105 0.235ug/L -13070154.7
Nickel (Ni) 51.5 50 102 1.06ug/L -13070151.5
Selenium (Se) 50.2 50 100 0.301ug/L -13070150.2
Thallium (Tl) Low Level 45.9 50 91.7 0.645ug/L -13070145.9
Vanadium (V) Low Level 51.6 50 103 1.29ug/L -13070151.6
Duke Energy Analytical Lab
Page 51 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020491 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.051 ug/L -1-0.051 1 < 1/2 RDL
Arsenic (As) 0.035 ug/L -10.035 1 < 1/2 RDL
Beryllium (Be) 0.06 ug/L -10.06 1 < 1/2 RDL
Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL
Chromium (Cr) 0.028 ug/L -10.028 1 < 1/2 RDL
Cobalt (Co) -0.001 ug/L -1-0.001 1 < 1/2 RDL
Copper (Cu) 0.05 ug/L -10.05 1 < 1/2 RDL
Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL
Molybdenum (Mo) 0.037 ug/L -10.037 1 < 1/2 RDL
Nickel (Ni) 0.008 ug/L -10.008 1 < 1/2 RDL
Selenium (Se) 0.095 ug/L -10.095 1 < 1/2 RDL
Thallium (Tl) Low Level -0.008 ug/L -1-0.008 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.13 ug/L -10.13 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 51.3 50 103ug/L -11585151.3
Arsenic (As) 51.8 50 104ug/L -11585151.8
Beryllium (Be) 53.1 50 106ug/L -11585153.1
Cadmium (Cd) 52.2 50 104ug/L -11585152.2
Chromium (Cr) 51.9 50 104ug/L -11585151.9
Cobalt (Co) 51.9 50 104ug/L -11585151.9
Copper (Cu) 52 50 104ug/L -11585152
Lead (Pb) 51.5 50 103ug/L -11585151.5
Molybdenum (Mo) 52.8 50 106ug/L -11585152.8
Nickel (Ni) 52.1 50 104ug/L -11585152.1
Selenium (Se) 52.1 50 104ug/L -11585152.1
Thallium (Tl) Low Level 51.1 50 102ug/L -11585151.1
Vanadium (V) Low Level 51.7 50 103ug/L -11585151.7
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003725
Antimony (Sb) 48.7 50 97.4ug/L -13070148.7
Arsenic (As) 50.3 50 100ug/L -13070150.3
Beryllium (Be) 53.7 50 107ug/L -13070153.7
Cadmium (Cd) 51.3 50 103ug/L -13070151.3
Chromium (Cr) 51.5 50 102ug/L -13070151.5
Cobalt (Co) 50.6 50 101ug/L -13070150.6
Copper (Cu) 50.9 50 101ug/L -13070150.9
Lead (Pb) 50.4 50 101ug/L -13070150.4
Duke Energy Analytical Lab
Page 52 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020491 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003725
Molybdenum (Mo) 51.2 50 102ug/L -13070151.2
Nickel (Ni) 51.7 50 102ug/L -13070151.7
Selenium (Se) 51.8 50 103ug/L -13070151.8
Thallium (Tl) Low Level 48.8 50 97.7ug/L -13070148.8
Vanadium (V) Low Level 53.5 50 103ug/L -13070153.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003725
Antimony (Sb) 47.9 50 95.8 1.59ug/L -13070147.9
Arsenic (As) 50.1 50 100 0.453ug/L -13070150.1
Beryllium (Be) 51.8 50 104 3.6ug/L -13070151.8
Cadmium (Cd) 51 50 102 0.639ug/L -13070151
Chromium (Cr) 50.4 50 100 2.15ug/L -13070150.4
Cobalt (Co) 50.4 50 101 0.35ug/L -13070150.4
Copper (Cu) 50.7 50 101 0.349ug/L -13070150.7
Lead (Pb) 50 50 99.9 0.774ug/L -13070150
Molybdenum (Mo) 50.7 50 101 0.969ug/L -13070150.7
Nickel (Ni) 51.2 50 101 0.919ug/L -13070151.2
Selenium (Se) 53 50 105 2.36ug/L -13070153
Thallium (Tl) Low Level 48.9 50 97.9 0.186ug/L -13070148.9
Vanadium (V) Low Level 52.5 50 101 2.01ug/L -13070152.5
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003733
Antimony (Sb) 50.3 50 100ug/L -13070150.3
Arsenic (As) 50.4 50 100ug/L -13070150.4
Beryllium (Be) 53.6 50 107ug/L -13070153.6
Cadmium (Cd) 50.3 50 101ug/L -13070150.3
Chromium (Cr) 53.1 50 101ug/L -13070153.1
Cobalt (Co) 52.1 50 98.4ug/L -13070152.1
Copper (Cu) 50 50 98.4ug/L -13070150
Lead (Pb) 50.3 50 100ug/L -13070150.3
Molybdenum (Mo) 54.4 50 104ug/L -13070154.4
Nickel (Ni) 51 50 99.2ug/L -13070151
Selenium (Se) 53.2 50 106ug/L -13070153.2
Thallium (Tl) Low Level 45.9 50 92ug/L -13070145.9
Vanadium (V) Low Level 51.1 50 101ug/L -13070151.1
Duke Energy Analytical Lab
Page 53 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020491 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003733
Antimony (Sb) 50 50 99.7 0.496ug/L -13070150
Arsenic (As) 50.5 50 100 0.26ug/L -13070150.5
Beryllium (Be) 52.2 50 104 2.68ug/L -13070152.2
Cadmium (Cd) 50.1 50 100 0.265ug/L -13070150.1
Chromium (Cr) 53.4 50 101 0.742ug/L -13070153.4
Cobalt (Co) 52.4 50 99 0.622ug/L -13070152.4
Copper (Cu) 50 50 98.5 0.102ug/L -13070150
Lead (Pb) 50.3 50 100 0ug/L -13070150.3
Molybdenum (Mo) 54.4 50 104 0.0576ug/L -13070154.4
Nickel (Ni) 51.3 50 99.8 0.659ug/L -13070151.3
Selenium (Se) 53.6 50 107 0.763ug/L -13070153.6
Thallium (Tl) Low Level 47.8 50 95.7 4.03ug/L -13070147.8
Vanadium (V) Low Level 51.2 50 102 0.211ug/L -13070151.2
Duke Energy Analytical Lab
Page 54 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020157 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17010238 -- 2017000970
TDS 287 1.05mg/L -1287
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17010238 -- 2017000973
TDS 795 0.378mg/L -1795
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17010567 -- 2017002546
TDS 44 4.44mg/L -144
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 92 100 92mg/L -11090192
Duke Energy Analytical Lab
Page 55 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020421 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.01 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
TOC mg/L -10.021 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 101mg/L -1208014.2
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 91.3 10.2mg/L -1208014.01
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 104mg/L -1208013.13
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 97.5 6.5mg/L -1208013
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 97.8mg/L -1208013.06
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 97.2 0.666mg/L -1208013.05
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 98.9mg/L -1158512.84
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 96.8mg/L -1158512.78
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
TOC 2.87 96.9mg/L -1158512.78
Duke Energy Analytical Lab
Page 56 of 113
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020082
Q17020149 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17010567 -- 2017002546
TSS 0.8 40mg/L -10.8
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17010567 -- 2017002547
TSS 9.4 8.16mg/L -19.4
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 46.4 50 92.8mg/L -11090146.4
Duke Energy Analytical Lab
Page 57 of 113
#=CL#
February 14, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92328680
92328680
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17020082
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on February 03, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 33
Duke Energy Analytical Lab
Page 58 of 113
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92328680
J17020082
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Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 33
Duke Energy Analytical Lab
Page 59 of 113
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92328680
J17020082
Lab ID Sample ID Matrix Date Collected Date Received
92328680001 2017003712 Water 02/02/17 13:45 02/03/17 13:30
92328680002 2017003725 Water 02/02/17 14:35 02/03/17 13:30
92328680003 2017003726 Water 02/02/17 11:40 02/03/17 13:30
92328680004 2017003727 Water 02/02/17 14:06 02/03/17 13:30
92328680005 2017003728 Water 02/02/17 12:03 02/03/17 13:30
92328680006 2017003729 Water 02/02/17 10:16 02/03/17 13:30
92328680007 2017003730 Water 02/02/17 11:46 02/03/17 13:30
92328680008 2017003731 Water 02/02/17 09:01 02/03/17 13:30
92328680009 2017003733 Water 02/02/17 15:20 02/03/17 13:30
92328680010 2017003734 Water 02/02/17 13:46 02/03/17 13:30
92328680011 2017003736 Water 02/02/17 14:45 02/03/17 13:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 33
Duke Energy Analytical Lab
Page 60 of 113
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92328680
J17020082
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92328680001 2017003712 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680002 2017003725 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680003 2017003726 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680004 2017003727 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680005 2017003728 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680006 2017003729 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680007 2017003730 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680008 2017003731 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680009 2017003733 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680010 2017003734 RSK 175 Modified 1 PASI-CWDV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 33
Duke Energy Analytical Lab
Page 61 of 113
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92328680
J17020082
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
92328680011 2017003736 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 33
Duke Energy Analytical Lab
Page 62 of 113
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92328680
J17020082
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92328680001 2017003712
Alkalinity,Bicarbonate (CaCO3)142 mg/L 02/09/17 13:205.0SM 2320B
Alkalinity, Total as CaCO3 142 mg/L 02/09/17 13:205.0SM 2320B
Chromium, Hexavalent 0.35 ug/L 02/09/17 12:080.12EPA 218.7
92328680002 2017003725
Alkalinity,Bicarbonate (CaCO3)49.1 mg/L 02/09/17 14:005.0SM 2320B
Alkalinity, Total as CaCO3 49.1 mg/L 02/09/17 14:005.0SM 2320B
Chromium, Hexavalent 0.48 ug/L 02/09/17 12:210.12EPA 218.7
92328680003 2017003726
Methane 10.6 ug/L 02/08/17 14:01 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)165 mg/L 02/09/17 14:125.0SM 2320B
Alkalinity, Total as CaCO3 165 mg/L 02/09/17 14:125.0SM 2320B
Chromium, Hexavalent 0.27 ug/L 02/09/17 12:340.12EPA 218.7
92328680004 2017003727
Alkalinity,Bicarbonate (CaCO3)236 mg/L 02/09/17 14:255.0SM 2320B
Alkalinity, Total as CaCO3 236 mg/L 02/09/17 14:255.0SM 2320B
92328680005 2017003728
Methane 3350 ug/L 02/08/17 14:31 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)228 mg/L 02/09/17 14:375.0SM 2320B
Alkalinity, Total as CaCO3 228 mg/L 02/09/17 14:375.0SM 2320B
Chromium, Hexavalent 1.8 ug/L 02/10/17 12:050.50EPA 218.7
92328680006 2017003729
Alkalinity,Bicarbonate (CaCO3)150 mg/L 02/09/17 14:525.0SM 2320B
Alkalinity, Total as CaCO3 150 mg/L 02/09/17 14:525.0SM 2320B
Chromium, Hexavalent 0.27 ug/L 02/10/17 12:180.12EPA 218.7
92328680007 2017003730
Alkalinity,Bicarbonate (CaCO3)107 mg/L 02/09/17 15:235.0SM 2320B
Alkalinity, Total as CaCO3 107 mg/L 02/09/17 15:235.0SM 2320B
Chromium, Hexavalent 0.070 ug/L 02/10/17 12:310.025EPA 218.7
92328680008 2017003731
Alkalinity,Bicarbonate (CaCO3)121 mg/L 02/09/17 15:355.0SM 2320B
Alkalinity, Total as CaCO3 121 mg/L 02/09/17 15:355.0SM 2320B
Chromium, Hexavalent 0.067 ug/L 02/10/17 12:440.025EPA 218.7
92328680009 2017003733
Methane 55.0 ug/L 02/08/17 15:32 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)213 mg/L 02/09/17 15:485.0SM 2320B
Alkalinity, Total as CaCO3 213 mg/L 02/09/17 15:485.0SM 2320B
Chromium, Hexavalent 0.26 ug/L 02/10/17 12:570.12EPA 218.7
92328680010 2017003734
Methane 198 ug/L 02/08/17 16:48 N210.0RSK 175 Modified
Alkalinity, Carbonate (CaCO3)59.7 mg/L 02/09/17 16:035.0SM 2320B
Alkalinity, Total as CaCO3 62.9 mg/L 02/09/17 16:035.0SM 2320B
Chromium, Hexavalent 11.1 ug/L 02/13/17 15:282.5EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 33
Duke Energy Analytical Lab
Page 63 of 113
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328680
J17020082
Method:
Client:Duke Energy
RSK 175 Modified
Date:February 14, 2017
Description:RSK 175 Headspace
General Information:
11 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below
or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
Page 7 of 33
Duke Energy Analytical Lab
Page 64 of 113
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328680
J17020082
Method:
Client:Duke Energy
SM 2320B
Date:February 14, 2017
Description:2320B Alkalinity
General Information:
11 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 8 of 33
Duke Energy Analytical Lab
Page 65 of 113
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328680
J17020082
Method:
Client:Duke Energy
SM 4500-S2D
Date:February 14, 2017
Description:4500S2D Sulfide Water
General Information:
11 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 33
Duke Energy Analytical Lab
Page 66 of 113
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328680
J17020082
Method:
Client:Duke Energy
EPA 218.7
Date:February 14, 2017
Description:Hexavalent Chromium by IC
General Information:
10 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 33
Duke Energy Analytical Lab
Page 67 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003712 Lab ID:92328680001 Collected:02/02/17 13:45 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/08/17 13:30 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)142 mg/L 02/09/17 13:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 13:205.0 1
Alkalinity, Total as CaCO3 142 mg/L 02/09/17 13:205.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.35 ug/L 02/09/17 12:08 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 33
Duke Energy Analytical Lab
Page 68 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003725 Lab ID:92328680002 Collected:02/02/17 14:35 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/08/17 13:45 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)49.1 mg/L 02/09/17 14:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 14:005.0 1
Alkalinity, Total as CaCO3 49.1 mg/L 02/09/17 14:005.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.48 ug/L 02/09/17 12:21 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 33
Duke Energy Analytical Lab
Page 69 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003726 Lab ID:92328680003 Collected:02/02/17 11:40 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 10.6 ug/L 02/08/17 14:01 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)165 mg/L 02/09/17 14:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 14:125.0 1
Alkalinity, Total as CaCO3 165 mg/L 02/09/17 14:125.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.27 ug/L 02/09/17 12:34 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 33
Duke Energy Analytical Lab
Page 70 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003727 Lab ID:92328680004 Collected:02/02/17 14:06 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/08/17 14:16 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)236 mg/L 02/09/17 14:255.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 14:255.0 1
Alkalinity, Total as CaCO3 236 mg/L 02/09/17 14:255.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/10/17 11:52 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 33
Duke Energy Analytical Lab
Page 71 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003728 Lab ID:92328680005 Collected:02/02/17 12:03 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 3350 ug/L 02/08/17 14:31 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)228 mg/L 02/09/17 14:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 14:375.0 1
Alkalinity, Total as CaCO3 228 mg/L 02/09/17 14:375.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 1.8 ug/L 02/10/17 12:05 18540-29-90.50 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 33
Duke Energy Analytical Lab
Page 72 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003729 Lab ID:92328680006 Collected:02/02/17 10:16 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/08/17 14:46 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)150 mg/L 02/09/17 14:525.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 14:525.0 1
Alkalinity, Total as CaCO3 150 mg/L 02/09/17 14:525.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.27 ug/L 02/10/17 12:18 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 33
Duke Energy Analytical Lab
Page 73 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003730 Lab ID:92328680007 Collected:02/02/17 11:46 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/08/17 15:02 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)107 mg/L 02/09/17 15:235.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 15:235.0 1
Alkalinity, Total as CaCO3 107 mg/L 02/09/17 15:235.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.070 ug/L 02/10/17 12:31 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 33
Duke Energy Analytical Lab
Page 74 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003731 Lab ID:92328680008 Collected:02/02/17 09:01 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/08/17 15:17 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)121 mg/L 02/09/17 15:355.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 15:355.0 1
Alkalinity, Total as CaCO3 121 mg/L 02/09/17 15:355.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.067 ug/L 02/10/17 12:44 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 33
Duke Energy Analytical Lab
Page 75 of 113
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003733 Lab ID:92328680009 Collected:02/02/17 15:20 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 55.0 ug/L 02/08/17 15:32 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)213 mg/L 02/09/17 15:485.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 15:485.0 1
Alkalinity, Total as CaCO3 213 mg/L 02/09/17 15:485.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.26 ug/L 02/10/17 12:57 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003734 Lab ID:92328680010 Collected:02/02/17 13:46 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 198 ug/L 02/08/17 16:48 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 02/09/17 16:035.0 1
Alkalinity, Carbonate (CaCO3)59.7 mg/L 02/09/17 16:035.0 1
Alkalinity, Total as CaCO3 62.9 mg/L 02/09/17 16:035.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 11.1 ug/L 02/13/17 15:28 18540-29-92.5 100
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328680
J17020082
Sample:2017003736 Lab ID:92328680011 Collected:02/02/17 14:45 Received:02/03/17 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/08/17 17:03 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 02/09/17 16:145.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/09/17 16:145.0 1
Alkalinity, Total as CaCO3 ND mg/L 02/09/17 16:145.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/07/17 15:30 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 78 of 113
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328680
J17020082
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347390
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92328680010, 92328680011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1927040
Associated Lab Samples:92328680010, 92328680011
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N202/08/17 16:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1927041LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 460 N239611670-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1928308MATRIX SPIKE SAMPLE:
MSSpike
Result
92328823001
Methane ug/L 510 N239612970-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92328823002
1928309SAMPLE DUPLICATE:
Methane ug/L 31.8 N272029.6
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 79 of 113
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328680
J17020082
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347601
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92328680001, 92328680002, 92328680003, 92328680004, 92328680005, 92328680006, 92328680007,
92328680008, 92328680009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1928291
Associated Lab Samples:92328680001, 92328680002, 92328680003, 92328680004, 92328680005, 92328680006, 92328680007,
92328680008, 92328680009
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N202/08/17 15:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1928292LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1928293
Methane ug/L 412 N239610470-130120475 14 20
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 80 of 113
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328680
J17020082
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347527
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92328680001, 92328680002, 92328680003, 92328680004, 92328680005, 92328680006, 92328680007,
92328680008, 92328680009, 92328680010, 92328680011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1928026
Associated Lab Samples:92328680001, 92328680002, 92328680003, 92328680004, 92328680005, 92328680006, 92328680007,
92328680008, 92328680009, 92328680010, 92328680011
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 02/09/17 13:02
Alkalinity, Total as CaCO3 mg/L ND 5.0 02/09/17 13:02
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 02/09/17 13:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1928027LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.150 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1928028MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328680001
1928029
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 102 80-120107 1 2550142193196
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1928030MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328680011
1928031
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120100 0 2550ND50.2 50.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
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Huntersville, NC 28078
[phone]
Page 24 of 33
Duke Energy Analytical Lab
Page 81 of 113
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328680
J17020082
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347195
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92328680001, 92328680002, 92328680003, 92328680004, 92328680005, 92328680006, 92328680007,
92328680008, 92328680009, 92328680010, 92328680011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1925825
Associated Lab Samples:92328680001, 92328680002, 92328680003, 92328680004, 92328680005, 92328680006, 92328680007,
92328680008, 92328680009, 92328680010, 92328680011
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 02/07/17 15:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1925826LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1925827MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328584002
1925828
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 104 80-120103 0 10.5ND 0.54 0.54
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1925829MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328680001
1925830
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 94 80-12094 0 10.5ND 0.48 0.49
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 25 of 33
Duke Energy Analytical Lab
Page 82 of 113
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328680
J17020082
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349403
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92328680001, 92328680002, 92328680003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1877133
Associated Lab Samples:92328680001, 92328680002, 92328680003
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 02/08/17 19:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1877134LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1877135MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521002
1877136
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L 1.5 111 85-115115 3 201.5ND 1.8 1.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1877137MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521012
1877138
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .5 101 85-115111 9 20.5ND 0.51 0.56
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
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Huntersville, NC 28078
[phone]
Page 26 of 33
Duke Energy Analytical Lab
Page 83 of 113
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328680
J17020082
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349682
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92328680004, 92328680005, 92328680006, 92328680007, 92328680008, 92328680009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1879103
Associated Lab Samples:92328680004, 92328680005, 92328680006, 92328680007, 92328680008, 92328680009
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 02/10/17 10:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1879104LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.071.075 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1879105MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521008
1879106
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .38 105 85-115103 1 20.380.69 1.1 1.1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/14/2017 05:44 PM
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Huntersville, NC 28078
[phone]
Page 27 of 33
Duke Energy Analytical Lab
Page 84 of 113
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328680
J17020082
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349683
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92328680010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1879109
Associated Lab Samples:92328680010
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 02/13/17 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1879110LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.081.075 108 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1879111MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328828010
1879112
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .75 114 85-115110 1 20.754.2 5.0 5.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1883427MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328680010
1883428
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L 7.5 103 85-115100 1 207.511.1 18.9 18.6
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 85 of 113
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92328680
J17020082
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92328680
J17020082
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92328680001 3476012017003712RSK 175 Modified
92328680002 3476012017003725RSK 175 Modified
92328680003 3476012017003726RSK 175 Modified
92328680004 3476012017003727RSK 175 Modified
92328680005 3476012017003728RSK 175 Modified
92328680006 3476012017003729RSK 175 Modified
92328680007 3476012017003730RSK 175 Modified
92328680008 3476012017003731RSK 175 Modified
92328680009 3476012017003733RSK 175 Modified
92328680010 3473902017003734RSK 175 Modified
92328680011 3473902017003736RSK 175 Modified
92328680001 3475272017003712SM 2320B
92328680002 3475272017003725SM 2320B
92328680003 3475272017003726SM 2320B
92328680004 3475272017003727SM 2320B
92328680005 3475272017003728SM 2320B
92328680006 3475272017003729SM 2320B
92328680007 3475272017003730SM 2320B
92328680008 3475272017003731SM 2320B
92328680009 3475272017003733SM 2320B
92328680010 3475272017003734SM 2320B
92328680011 3475272017003736SM 2320B
92328680001 3471952017003712SM 4500-S2D
92328680002 3471952017003725SM 4500-S2D
92328680003 3471952017003726SM 4500-S2D
92328680004 3471952017003727SM 4500-S2D
92328680005 3471952017003728SM 4500-S2D
92328680006 3471952017003729SM 4500-S2D
92328680007 3471952017003730SM 4500-S2D
92328680008 3471952017003731SM 4500-S2D
92328680009 3471952017003733SM 4500-S2D
92328680010 3471952017003734SM 4500-S2D
92328680011 3471952017003736SM 4500-S2D
92328680001 3494032017003712EPA 218.7
92328680002 3494032017003725EPA 218.7
92328680003 3494032017003726EPA 218.7
92328680004 3496822017003727EPA 218.7
92328680005 3496822017003728EPA 218.7
92328680006 3496822017003729EPA 218.7
92328680007 3496822017003730EPA 218.7
92328680008 3496822017003731EPA 218.7
92328680009 3496822017003733EPA 218.7
92328680010 3496832017003734EPA 218.7
REPORT OF LABORATORY ANALYSIS
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Page 87 of 113
Page 31 of 33
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Page 88 of 113
Page 32 of 33
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Page 89 of 113
Page 33 of 33
Duke Energy Analytical Lab
Page 90 of 113

February 24, 2017

Anne Pridgeon
Duke Energy
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment
Work Order: 415729
SDG: J17020082

Dear Anne Pridgeon:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on February 06, 2017. This original data report has been prepared and reviewed in
accordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 5015714
Enclosures
Page 1 of 22
Chelsea Seagle for
Duke Energy Analytical Lab
Page 91 of 113
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO004 Duke Energy Carolinas, LLC <BR> (PO 5015714)
Client SDG: J17020082 GEL Work Order: 415729
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for but not detected above the Lc
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 22
Duke Energy Analytical Lab
Page 92 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1110
1045
1407
0715
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729001
Ground Water
02-FEB-17 13:45
06-FEB-17
2017003712 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.596
0.631
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00136
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"91.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 22
Duke Energy Analytical Lab
Page 93 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1119
1054
1407
0715
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729002
Ground Water
02-FEB-17 14:35
06-FEB-17
2017003725 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.429
0.568
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00033
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"91.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 22
Duke Energy Analytical Lab
Page 94 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1121
1056
1407
0715
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729003
Ground Water
02-FEB-17 11:40
06-FEB-17
2017003726 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.490
0.688
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000459
ND
ND
ND
1.61
1.36
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"84 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 22
Duke Energy Analytical Lab
Page 95 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1122
1057
1407
0715
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729004
Ground Water
02-FEB-17 14:06
06-FEB-17
2017003727 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.488
0.393
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00334
ND
ND
ND
0.535
1.89
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"80.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 22
Duke Energy Analytical Lab
Page 96 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1124
1059
1408
0715
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729005
Ground Water
02-FEB-17 12:03
06-FEB-17
2017003728 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.595
0.360
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000147
ND
ND
ND
ND
1.35
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"77.1 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 7 of 22
Duke Energy Analytical Lab
Page 97 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1125
1104
1408
0715
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729006
Ground Water
02-FEB-17 10:16
06-FEB-17
2017003729 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.521
0.767
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00149
ND
ND
ND
ND
1.14
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"90.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 8 of 22
Duke Energy Analytical Lab
Page 98 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1130
1105
1411
0750
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729007
Ground Water
02-FEB-17 11:46
06-FEB-17
2017003730 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.512
0.616
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000927
ND
ND
ND
ND
0.690
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"91.1 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 9 of 22
Duke Energy Analytical Lab
Page 99 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1131
1107
1408
0750
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729008
Ground Water
02-FEB-17 09:01
06-FEB-17
2017003731 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.721
0.485
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000205
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"89.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 10 of 22
Duke Energy Analytical Lab
Page 100 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1133
1108
1413
0750
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729009
Ground Water
02-FEB-17 15:26
06-FEB-17
2017003733 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.891
0.388
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000467
ND
ND
ND
ND
1.01
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"63.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 11 of 22
Duke Energy Analytical Lab
Page 101 of 113
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 24, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1637100
1637100
1638127
1637843
1134
1110
1413
0750
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/21/17
02/24/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415729010
Ground Water
02-FEB-17 13:46
06-FEB-17
2017003734 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.570
0.806
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000699
ND
ND
ND
ND
0.897
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"83.1 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16370991645CXW4
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 12 of 22
Duke Energy Analytical Lab
Page 102 of 113
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1637100Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Parmname
Anne PridgeonContact:
Duke Energy
13339 Hagers Ferry Road
Huntersville, North Carolina
February 24, 2017Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
Anlst Date Time
SKJ 02/16/17 10:47
02/17/17 11:12
02/17/17 11:09
02/16/17 10:44
02/16/17 10:42
02/17/17 11:07
QC
ND
ND
ND
0.00133
0.0569
0.000489
0.000625
0.00491
ND
ND
ND
ND
NOM Sample
ND
ND
ND
0.00136
Range
(0%-20%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
U
U
U
U
U
U
U
QC1203722868 415729001
QC1203722867
QC1203722871
QC1203722866
N/A
N/A
N/A
1.97
REC%
115
97.8
114
98.3
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
415729Workorder:
Mail Code: MGO3A2
U
U
U
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
1637100
1638127
Batch
Batch
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Parmname Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
02/17/17 11:13
02/16/17 10:48
02/16/17 10:50
02/17/17 11:15
02/21/17 14:12
02/21/17 14:13
02/21/17 14:12
QC
0.0577
0.000549
0.000674
0.00474
ND
ND
ND
0.297
0.569
7.25
0.286
NOM Sample
0.00136
ND
ND
ND
ND
ND
ND
1.36
0.00343
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-10%)
(0%-10%)
N/A
(75%-125%)
Qual
U
U
U
U
U
QC1203722869 415729001
QC1203722872 415729001
QC1203722870 415729001
QC1203725358 415729010
QC1203725359
QC1203725357
N/A
N/A
N/A
9.43
N/A
REC%
114
110
122
94.7
104
0.0496
0.0005
0.00055
0.005
7.00
MS
MS
SDILT
DUP
LCS
MB
415729Workorder:
U
U
U
U
U
U
U
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Rad Ra-226
1637843Batch
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
LXP1 02/24/17 08:55
02/24/17 08:55
02/24/17 08:20
02/24/17 08:55
QC
0.239
20.4
0.241
122
NOM Sample
0.390
0.390
Range
N/A
(75%-125%)
(75%-125%)
Qual
U
U
QC1203724559 415729001
QC1203724561
QC1203724558
QC1203724560 415729001
The Qualifiers in this report are defined as follows:
N/A
REC%
78.6
94.2
26.0
130
DUP
LCS
MB
MS
415729Workorder:
**
<
>
BD
E
FA
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
U
U
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 4 of 4
Units Anlst Date TimeQCNOMSampleRangeQualREC%
415729Workorder:
U
U
UI
UJ
UL
X
Y
^
h
Analyte was analyzed for but not detected above the Lc
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy Carolinas, LLC
(DUPC)
SDG #: J17020082
Work Order #: 415729

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1637100

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1637099
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415729001 2017003712
415729002 2017003725
415729003 2017003726
415729004 2017003727
415729005 2017003728
415729006 2017003729
415729007 2017003730
415729008 2017003731
415729009 2017003733
415729010 2017003734
1203722866 Method Blank (MB)ICP-MS
1203722867 Laboratory Control Sample (LCS)
1203722871 Laboratory Control Sample (LCS)
1203722870 415729001(2017003712L) Serial Dilution (SD)
1203722868 415729001(2017003712D) Sample Duplicate (DUP)
1203722869 415729001(2017003712S) Matrix Spike (MS)
1203722872 415729001(2017003712S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
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Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1638127
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415729001 2017003712
415729002 2017003725
415729003 2017003726
415729004 2017003727
415729005 2017003728
415729006 2017003729
415729007 2017003730
415729008 2017003731
415729009 2017003733
415729010 2017003734
1203725357 Method Blank (MB)
1203725358 415729010(2017003734) Sample Duplicate (DUP)
1203725359 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1637843
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415729001 2017003712
415729002 2017003725
415729003 2017003726
415729004 2017003727
415729005 2017003728
415729006 2017003729
415729007 2017003730
415729008 2017003731
415729009 2017003733
415729010 2017003734
1203724558 Method Blank (MB)
1203724559 415729001(2017003712) Sample Duplicate (DUP)
1203724560 415729001(2017003712) Matrix Spike (MS)
1203724561 Laboratory Control Sample (LCS)
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The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203724560 (2017003712MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA170010
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-17-12
SC000122016-21
VT87156
460202
C780
997404
List of current GEL Certifications as of 24 February 2017
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Duke Energy Analytical Lab
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