NC0038377_J17020042report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17020042
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:2/28/2017
Customer Address:Mayo Steam Plant
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, Kim Witt
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Method 200.8: It should be noted that several analytes including Cr, Cu, Pb, Mo, Ni are trending upward when compared to
historical data for MW2 and MW12S.
Method 200.8: The instrument calibration blank recovered above the detection limit for low level thallium however the
concentration was less than the reporting limit. Data impacted has been flagged accordingly.
Method 200.8: Low level thallium was present in blank(s) above the method detection limit but less than the reporting limit. Data
is valid for compliance purposes.
Method 5310C: The current reported result is above historical limits however based upon prior results, this is consistent with
upward trends for total carbon for MW12S.
Method 218.7: The matrix spike and spike duplicate associated with ABMW-4 recovered outside method limits for hexavalent
chromium. Respective batch quality checks including LCS were acceptable therefore there is no adverse impact to data.
Method 2320: The matrix spike and spike duplicate associated with MW16D and ABMW-4D recovered outside method limits for
alkalinity. Respective batch quality checks including LCS were acceptable therefore there is no adverse impact to data.
Method 218.7: Please note that the preservation was not consistent with method requirements (>8) for the stabilization of
hexavalent chromium over a 24hr period for following samples: ABMW-4D, ABMW-3S, MW16BR. Data may be flagged with a
P4 or HT flag due to this finding.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 166
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Duke Energy Analytical Lab
Page 2 of 166
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2017003487 MAYO STEAM 01-Feb-17 10:10 AM Alex Lefitz MW-16BR
2017003488 MAYO STEAM 01-Feb-17 1:15 PM Alex Lefitz SW-CB2
2017003489 MAYO STEAM 01-Feb-17 12:10 PM Alex Lefitz MW-16D
2017003490 MAYO STEAM 01-Feb-17 3:30 PM Alex Lefitz ABMW-1
2017003491 MAYO STEAM 01-Feb-17 9:40 AM Alex Lefitz MW-16S
2017003492 MAYO STEAM 01-Feb-17 5:26 PM Alex Lefitz MW-2
2017003493 MAYO STEAM 01-Feb-17 10:36 AM Alex Lefitz MW-12S
2017003494 MAYO STEAM 01-Feb-17 10:40 AM Alex Lefitz MW-12D
2017003495 MAYO STEAM 01-Feb-17 10:40 AM Alex Lefitz MW-12D DUP
2017003496 MAYO STEAM 01-Feb-17 1:44 PM Alex Lefitz BG-1
2017003497 MAYO STEAM 01-Feb-17 3:21 PM Alex Lefitz MW-3
2017003498 MAYO STEAM 01-Feb-17 9:36 AM Alex Lefitz ABMW-4
2017003499 MAYO STEAM 01-Feb-17 11:07 AM Alex Lefitz ABMW-2
2017003500 MAYO STEAM 01-Feb-17 11:25 AM Alex Lefitz ABMW-4D
2017003501 MAYO STEAM 01-Feb-17 12:51 PM Alex Lefitz ABMW-2BR
2017003502 MAYO STEAM 01-Feb-17 2:06 PM Alex Lefitz ABMW-2BRL
2017003503 MAYO STEAM 01-Feb-17 3:30 PM Alex Lefitz ABMW-3
2017003504 MAYO STEAM 01-Feb-17 4:06 PM Alex Lefitz ABMW-3S
18 Total Samples
Duke Energy Analytical Lab
Page 3 of 166
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:2/28/2017
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 4 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003487
Collection Date:01-Feb-17 10:10 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:02 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.7 mg/L EPA 300.0 02/07/2017 10:44 BGN90340.1 1
Sulfate 0.65 mg/L EPA 300.0 02/07/2017 10:44 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:11 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 13:55 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 02/15/2017 17:50 MHALL30.005 1
Barium (Ba)0.010 mg/L EPA 200.7 02/15/2017 17:50 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 17:50 MHALL30.05 1
Iron (Fe)0.253 mg/L EPA 200.7 02/15/2017 17:50 MHALL30.01 1
Manganese (Mn)0.104 mg/L EPA 200.7 02/15/2017 17:50 MHALL30.005 1
Strontium (Sr)0.087 mg/L EPA 200.7 02/15/2017 17:50 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 17:50 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)24.4 mg/L EPA 200.7 02/17/2017 18:44B2 JJMACKE0.01 1
Magnesium (Mg)2.08 mg/L EPA 200.7 02/17/2017 18:44 JJMACKE0.005 1
Potassium (K)2.80 mg/L EPA 200.7 02/17/2017 18:44 JJMACKE0.1 1
Sodium (Na)30.9 mg/L EPA 200.7 02/17/2017 18:44B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.018 mg/L EPA 200.7 02/20/2017 11:57 MHH71310.005 1
Barium (Ba)0.010 mg/L EPA 200.7 02/20/2017 11:57 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 11:57 MHH71310.05 1
Iron (Fe)0.278 mg/L EPA 200.7 02/20/2017 11:57 MHH71310.01 1
Manganese (Mn)0.093 mg/L EPA 200.7 02/20/2017 11:57 MHH71310.005 1
Strontium (Sr)0.088 mg/L EPA 200.7 02/20/2017 11:57 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 11:57 MHH71310.005 1
Duke Energy Analytical Lab
Page 5 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003487
Collection Date:01-Feb-17 10:10 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Molybdenum (Mo)57.9 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 22:40N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/21/2017 22:40 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Molybdenum (Mo)59.2 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 02:23N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.422 ug/L EPA 200.8 02/21/2017 02:23 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 6 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003487
Collection Date:01-Feb-17 10:10 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 22 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 7 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003488
Collection Date:01-Feb-17 1:15 PM
Site:SW-CB2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:06 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 29 mg/L EPA 300.0 02/07/2017 11:01 BGN90340.5 5
Sulfate 15 mg/L EPA 300.0 02/07/2017 11:01 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:18 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:05 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 18:01 MHALL30.005 1
Barium (Ba)0.032 mg/L EPA 200.7 02/15/2017 18:01 MHALL30.005 1
Boron (B)0.465 mg/L EPA 200.7 02/15/2017 18:01 MHALL30.05 1
Iron (Fe)0.066 mg/L EPA 200.7 02/15/2017 18:01 MHALL30.01 1
Manganese (Mn)1.86 mg/L EPA 200.7 02/15/2017 18:01 MHALL30.005 1
Strontium (Sr)0.176 mg/L EPA 200.7 02/15/2017 18:01 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 18:01 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)15.8 mg/L EPA 200.7 02/17/2017 18:48B2 JJMACKE0.01 1
Magnesium (Mg)5.97 mg/L EPA 200.7 02/17/2017 18:48 JJMACKE0.005 1
Potassium (K)2.00 mg/L EPA 200.7 02/17/2017 18:48 JJMACKE0.1 1
Sodium (Na)12.1 mg/L EPA 200.7 02/17/2017 18:48B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.121 mg/L EPA 200.7 02/20/2017 12:09 MHH71310.005 1
Barium (Ba)0.034 mg/L EPA 200.7 02/20/2017 12:09 MHH71310.005 1
Boron (B)0.486 mg/L EPA 200.7 02/20/2017 12:09 MHH71310.05 1
Iron (Fe)2.07 mg/L EPA 200.7 02/20/2017 12:09 MHH71310.01 1
Manganese (Mn)1.97 mg/L EPA 200.7 02/20/2017 12:09 MHH71310.005 1
Strontium (Sr)0.192 mg/L EPA 200.7 02/20/2017 12:09 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 12:09 MHH71310.005 1
Duke Energy Analytical Lab
Page 8 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003488
Collection Date:01-Feb-17 1:15 PM
Site:SW-CB2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Cobalt (Co)1.01 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 23:09N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/21/2017 23:09 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Cobalt (Co)1.01 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 01:52N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.473 ug/L EPA 200.8 02/21/2017 01:52 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 9 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003488
Collection Date:01-Feb-17 1:15 PM
Site:SW-CB2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 4.2 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 10 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003489
Collection Date:01-Feb-17 12:10 PM
Site:MW-16D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)3.3 mg-N/L EPA 353.2 02/14/2017 15:17 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.8 mg/L EPA 300.0 02/07/2017 11:18 BGN90340.1 1
Sulfate 6.9 mg/L EPA 300.0 02/07/2017 11:18 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:26 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:07 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 18:05 MHALL30.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/15/2017 18:05 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 18:05 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/15/2017 18:05 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/15/2017 18:05 MHALL30.005 1
Strontium (Sr)0.157 mg/L EPA 200.7 02/15/2017 18:05 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 18:05 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)23.1 mg/L EPA 200.7 02/17/2017 19:11B2 JJMACKE0.01 1
Magnesium (Mg)4.53 mg/L EPA 200.7 02/17/2017 19:11 JJMACKE0.005 1
Potassium (K)1.66 mg/L EPA 200.7 02/17/2017 19:11 JJMACKE0.1 1
Sodium (Na)8.86 mg/L EPA 200.7 02/17/2017 19:11B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.099 mg/L EPA 200.7 02/20/2017 12:13 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/20/2017 12:13 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 12:13 MHH71310.05 1
Iron (Fe)0.140 mg/L EPA 200.7 02/20/2017 12:13 MHH71310.01 1
Manganese (Mn)0.120 mg/L EPA 200.7 02/20/2017 12:13 MHH71310.005 1
Strontium (Sr)0.165 mg/L EPA 200.7 02/20/2017 12:13 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 12:13 MHH71310.005 1
Duke Energy Analytical Lab
Page 11 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003489
Collection Date:01-Feb-17 12:10 PM
Site:MW-16D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Molybdenum (Mo)6.02 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 23:17N1 CWSPEN30.2 1
Vanadium (V) Low Level 0.544 ug/L EPA 200.8 02/21/2017 23:17 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Molybdenum (Mo)6.28 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 02:30N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.882 ug/L EPA 200.8 02/21/2017 02:30 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 12 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003489
Collection Date:01-Feb-17 12:10 PM
Site:MW-16D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.274 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 13 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003490
Collection Date:01-Feb-17 3:30 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:08 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 02/07/2017 11:34 BGN90340.5 5
Sulfate 21 mg/L EPA 300.0 02/07/2017 11:34 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:28 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:10 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.263 mg/L EPA 200.7 02/15/2017 18:09 MHALL30.005 1
Barium (Ba)0.489 mg/L EPA 200.7 02/15/2017 18:09 MHALL30.005 1
Boron (B)5.67 mg/L EPA 200.7 02/15/2017 18:09 MHALL30.05 1
Iron (Fe)0.858 mg/L EPA 200.7 02/15/2017 18:09 MHALL30.01 1
Manganese (Mn)0.867 mg/L EPA 200.7 02/15/2017 18:09 MHALL30.005 1
Strontium (Sr)1.72 mg/L EPA 200.7 02/15/2017 18:09 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 18:09 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)50.6 mg/L EPA 200.7 02/18/2017 08:45B2 JJMACKE0.01 1
Magnesium (Mg)28.7 mg/L EPA 200.7 02/18/2017 08:45 JJMACKE0.05 10
Potassium (K)21.0 mg/L EPA 200.7 02/18/2017 08:45 JJMACKE0.1 1
Sodium (Na)16.5 mg/L EPA 200.7 02/18/2017 08:45B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.233 mg/L EPA 200.7 02/20/2017 12:17 MHH71310.005 1
Barium (Ba)0.520 mg/L EPA 200.7 02/20/2017 12:17 MHH71310.005 1
Boron (B)5.82 mg/L EPA 200.7 02/20/2017 12:17 MHH71310.05 1
Iron (Fe)1.45 mg/L EPA 200.7 02/20/2017 12:17 MHH71310.01 1
Manganese (Mn)0.982 mg/L EPA 200.7 02/20/2017 12:17 MHH71310.005 1
Strontium (Sr)1.89 mg/L EPA 200.7 02/20/2017 12:17 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 12:17 MHH71310.005 1
Duke Energy Analytical Lab
Page 14 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003490
Collection Date:01-Feb-17 3:30 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)15.8 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Arsenic (As)298 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Cobalt (Co)3.68 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Molybdenum (Mo)314 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Nickel (Ni)2.97 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN311
Thallium (Tl) Low Level 0.481 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN30.2 1
Vanadium (V) Low Level 58.6 ug/L EPA 200.8 02/22/2017 12:07 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)14.7 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Arsenic (As)323 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Cobalt (Co)3.87 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Molybdenum (Mo)304 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Nickel (Ni)3.00 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR11
Thallium (Tl) Low Level 0.581 ug/L EPA 200.8 02/21/2017 02:38N1 PARMSTR0.2 1
Vanadium (V) Low Level 56.7 ug/L EPA 200.8 02/21/2017 02:38 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 15 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003490
Collection Date:01-Feb-17 3:30 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 3.7 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 16 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003491
Collection Date:01-Feb-17 9:40 AM
Site:MW-16S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.035 mg-N/L EPA 353.2 02/14/2017 15:09 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 42 mg/L EPA 300.0 02/08/2017 15:21 BGN90340.5 5
Sulfate 11 mg/L EPA 300.0 02/08/2017 15:21 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:30 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:12 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 18:13 MHALL30.005 1
Barium (Ba)0.075 mg/L EPA 200.7 02/15/2017 18:13 MHALL30.005 1
Boron (B)0.235 mg/L EPA 200.7 02/15/2017 18:13 MHALL30.05 1
Iron (Fe)0.424 mg/L EPA 200.7 02/15/2017 18:13 MHALL30.01 1
Manganese (Mn)0.542 mg/L EPA 200.7 02/15/2017 18:13 MHALL30.005 1
Strontium (Sr)0.179 mg/L EPA 200.7 02/15/2017 18:13 MHALL30.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 02/15/2017 18:13 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)15.2 mg/L EPA 200.7 02/17/2017 19:26B2 JJMACKE0.01 1
Magnesium (Mg)4.87 mg/L EPA 200.7 02/17/2017 19:26 JJMACKE0.005 1
Potassium (K)1.65 mg/L EPA 200.7 02/17/2017 19:26 JJMACKE0.1 1
Sodium (Na)18.1 mg/L EPA 200.7 02/17/2017 19:26B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 02/20/2017 12:21 MHH71310.005 1
Barium (Ba)0.075 mg/L EPA 200.7 02/20/2017 12:21 MHH71310.005 1
Boron (B)0.255 mg/L EPA 200.7 02/20/2017 12:21 MHH71310.05 1
Iron (Fe)0.393 mg/L EPA 200.7 02/20/2017 12:21 MHH71310.01 1
Manganese (Mn)0.562 mg/L EPA 200.7 02/20/2017 12:21 MHH71310.005 1
Strontium (Sr)0.199 mg/L EPA 200.7 02/20/2017 12:21 MHH71310.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 02/20/2017 12:21 MHH71310.005 1
Duke Energy Analytical Lab
Page 17 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003491
Collection Date:01-Feb-17 9:40 AM
Site:MW-16S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Cobalt (Co)6.60 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Nickel (Ni)2.45 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 23:31N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/21/2017 23:31 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Cobalt (Co)6.22 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Nickel (Ni)2.29 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 02:46N1 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/21/2017 02:46 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 18 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003491
Collection Date:01-Feb-17 9:40 AM
Site:MW-16S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.787 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 19 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003492
Collection Date:01-Feb-17 5:26 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.198 mg-N/L EPA 353.2 02/14/2017 15:11 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 02/07/2017 12:08 BGN90340.5 5
Sulfate 18 mg/L EPA 300.0 02/07/2017 12:08 BGN90340.5 5
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:15 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 18:16 MHALL30.005 1
Barium (Ba)0.038 mg/L EPA 200.7 02/15/2017 18:16 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 18:16 MHALL30.05 1
Iron (Fe)0.170 mg/L EPA 200.7 02/15/2017 18:16 MHALL30.01 1
Manganese (Mn)0.264 mg/L EPA 200.7 02/15/2017 18:16 MHALL30.005 1
Strontium (Sr)0.161 mg/L EPA 200.7 02/15/2017 18:16 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 18:16 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Molybdenum (Mo)1.22 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Nickel (Ni)2.23 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 22:11N1 CWSPEN30.2 1
Vanadium (V) Low Level 0.875 ug/L EPA 200.8 02/21/2017 22:11 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Duke Energy Analytical Lab
Page 20 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003492
Collection Date:01-Feb-17 5:26 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
Duke Energy Analytical Lab
Page 21 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003493
Collection Date:01-Feb-17 10:36 AM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:12 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 0.36 mg/L EPA 300.0 02/07/2017 12:25 BGN90340.1 1
Sulfate 1.6 mg/L EPA 300.0 02/07/2017 12:25 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:33 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:17 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.132 mg/L EPA 200.7 02/15/2017 18:20 MHALL30.005 1
Barium (Ba)0.010 mg/L EPA 200.7 02/15/2017 18:20 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 18:20 MHALL30.05 1
Iron (Fe)3.01 mg/L EPA 200.7 02/15/2017 18:20 MHALL30.01 1
Manganese (Mn)0.223 mg/L EPA 200.7 02/15/2017 18:20 MHALL30.005 1
Strontium (Sr)0.024 mg/L EPA 200.7 02/15/2017 18:20 MHALL30.005 1
Zinc (Zn)0.065 mg/L EPA 200.7 02/15/2017 18:20 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.07 mg/L EPA 200.7 02/17/2017 19:30B2 JJMACKE0.01 1
Magnesium (Mg)1.11 mg/L EPA 200.7 02/17/2017 19:30 JJMACKE0.005 1
Potassium (K)3.78 mg/L EPA 200.7 02/17/2017 19:30 JJMACKE0.1 1
Sodium (Na)0.566 mg/L EPA 200.7 02/17/2017 19:30B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.361 mg/L EPA 200.7 02/20/2017 12:25 MHH71310.005 1
Barium (Ba)0.011 mg/L EPA 200.7 02/20/2017 12:25 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 12:25 MHH71310.05 1
Iron (Fe)3.24 mg/L EPA 200.7 02/20/2017 12:25 MHH71310.01 1
Manganese (Mn)0.211 mg/L EPA 200.7 02/20/2017 12:25 MHH71310.005 1
Strontium (Sr)0.025 mg/L EPA 200.7 02/20/2017 12:25 MHH71310.005 1
Zinc (Zn)0.090 mg/L EPA 200.7 02/20/2017 12:25 MHH71310.005 1
Duke Energy Analytical Lab
Page 22 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003493
Collection Date:01-Feb-17 10:36 AM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Arsenic (As)1.86 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Chromium (Cr)1.08 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Cobalt (Co)1.56 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Copper (Cu)3.70 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Molybdenum (Mo)2.89 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Nickel (Ni)2.58 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 23:38N1 CWSPEN30.2 1
Vanadium (V) Low Level 4.70 ug/L EPA 200.8 02/21/2017 23:38 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Arsenic (As)1.79 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Chromium (Cr)1.61 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Cobalt (Co)1.65 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Copper (Cu)9.46 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Lead (Pb)2.41 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Molybdenum (Mo)3.15 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Nickel (Ni)3.03 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 03:16N1 PARMSTR0.2 1
Vanadium (V) Low Level 5.90 ug/L EPA 200.8 02/21/2017 03:16 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 85 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 23 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003493
Collection Date:01-Feb-17 10:36 AM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 14 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.5 5
TOTAL SUSPENDED SOLIDS
TSS 20 mg/L SM2540D 02/06/2017 08:30 MGIGANT171
Duke Energy Analytical Lab
Page 24 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003494
Collection Date:01-Feb-17 10:40 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.190 mg-N/L EPA 353.2 02/14/2017 15:13 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.8 mg/L EPA 300.0 02/07/2017 12:42 BGN90340.1 1
Sulfate 1.0 mg/L EPA 300.0 02/07/2017 12:42 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:35 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:20 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 18:24 MHALL30.005 1
Barium (Ba)0.014 mg/L EPA 200.7 02/15/2017 18:24 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 18:24 MHALL30.05 1
Iron (Fe)0.019 mg/L EPA 200.7 02/15/2017 18:24 MHALL30.01 1
Manganese (Mn)0.085 mg/L EPA 200.7 02/15/2017 18:24 MHALL30.005 1
Strontium (Sr)0.084 mg/L EPA 200.7 02/15/2017 18:24 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 18:24 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.3 mg/L EPA 200.7 02/17/2017 19:34B2 JJMACKE0.01 1
Magnesium (Mg)2.80 mg/L EPA 200.7 02/17/2017 19:34 JJMACKE0.005 1
Potassium (K)1.22 mg/L EPA 200.7 02/17/2017 19:34 JJMACKE0.1 1
Sodium (Na)8.18 mg/L EPA 200.7 02/17/2017 19:34B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.115 mg/L EPA 200.7 02/20/2017 12:29 MHH71310.005 1
Barium (Ba)0.014 mg/L EPA 200.7 02/20/2017 12:29 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 12:29 MHH71310.05 1
Iron (Fe)0.243 mg/L EPA 200.7 02/20/2017 12:29 MHH71310.01 1
Manganese (Mn)0.096 mg/L EPA 200.7 02/20/2017 12:29 MHH71310.005 1
Strontium (Sr)0.083 mg/L EPA 200.7 02/20/2017 12:29 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 12:29 MHH71310.005 1
Duke Energy Analytical Lab
Page 25 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003494
Collection Date:01-Feb-17 10:40 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Nickel (Ni)1.23 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 23:45N1 CWSPEN30.2 1
Vanadium (V) Low Level 0.470 ug/L EPA 200.8 02/21/2017 23:45 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Chromium (Cr)1.39 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Nickel (Ni)1.62 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 03:24N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.874 ug/L EPA 200.8 02/21/2017 03:24 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 26 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003494
Collection Date:01-Feb-17 10:40 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.366 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 27 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003495
Collection Date:01-Feb-17 10:40 AM
Site:MW-12D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.185 mg-N/L EPA 353.2 02/14/2017 15:14 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 300.0 02/07/2017 12:59 BGN90340.1 1
Sulfate 1.0 mg/L EPA 300.0 02/07/2017 12:59 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:38 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:22 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 18:28 MHALL30.005 1
Barium (Ba)0.014 mg/L EPA 200.7 02/15/2017 18:28 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 18:28 MHALL30.05 1
Iron (Fe)0.018 mg/L EPA 200.7 02/15/2017 18:28 MHALL30.01 1
Manganese (Mn)0.081 mg/L EPA 200.7 02/15/2017 18:28 MHALL30.005 1
Strontium (Sr)0.082 mg/L EPA 200.7 02/15/2017 18:28 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 18:28 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)11.2 mg/L EPA 200.7 02/17/2017 19:38B2 JJMACKE0.01 1
Magnesium (Mg)3.04 mg/L EPA 200.7 02/17/2017 19:38 JJMACKE0.005 1
Potassium (K)1.34 mg/L EPA 200.7 02/17/2017 19:38 JJMACKE0.1 1
Sodium (Na)8.83 mg/L EPA 200.7 02/17/2017 19:38B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.121 mg/L EPA 200.7 02/20/2017 12:33 MHH71310.005 1
Barium (Ba)0.015 mg/L EPA 200.7 02/20/2017 12:33 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 12:33 MHH71310.05 1
Iron (Fe)0.253 mg/L EPA 200.7 02/20/2017 12:33 MHH71310.01 1
Manganese (Mn)0.101 mg/L EPA 200.7 02/20/2017 12:33 MHH71310.005 1
Strontium (Sr)0.084 mg/L EPA 200.7 02/20/2017 12:33 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 12:33 MHH71310.005 1
Duke Energy Analytical Lab
Page 28 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003495
Collection Date:01-Feb-17 10:40 AM
Site:MW-12D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Nickel (Ni)1.28 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 23:53N1 CWSPEN30.2 1
Vanadium (V) Low Level 0.480 ug/L EPA 200.8 02/21/2017 23:53 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Chromium (Cr)1.17 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Nickel (Ni)1.54 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 13:53N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.921 ug/L EPA 200.8 02/22/2017 13:53 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 29 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003495
Collection Date:01-Feb-17 10:40 AM
Site:MW-12D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.375 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 30 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003496
Collection Date:01-Feb-17 1:44 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.809 mg-N/L EPA 353.2 02/14/2017 15:15 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.5 mg/L EPA 300.0 02/07/2017 15:48 BGN90340.2 2
Sulfate 0.26 mg/L EPA 300.0 02/07/2017 15:48 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:40 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:29 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 18:32 MHALL30.005 1
Barium (Ba)0.085 mg/L EPA 200.7 02/15/2017 18:32 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 18:32 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/15/2017 18:32 MHALL30.01 1
Manganese (Mn)0.005 mg/L EPA 200.7 02/15/2017 18:32 MHALL30.005 1
Strontium (Sr)0.159 mg/L EPA 200.7 02/15/2017 18:32 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 18:32 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)12.2 mg/L EPA 200.7 02/20/2017 10:19 JJMACKE0.01 1
Magnesium (Mg)3.19 mg/L EPA 200.7 02/20/2017 10:19 JJMACKE0.005 1
Potassium (K)1.33 mg/L EPA 200.7 02/20/2017 10:19 JJMACKE0.1 1
Sodium (Na)11.2 mg/L EPA 200.7 02/20/2017 10:19 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.231 mg/L EPA 200.7 02/20/2017 12:37 MHH71310.005 1
Barium (Ba)0.087 mg/L EPA 200.7 02/20/2017 12:37 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 12:37 MHH71310.05 1
Iron (Fe)0.200 mg/L EPA 200.7 02/20/2017 12:37 MHH71310.01 1
Manganese (Mn)0.013 mg/L EPA 200.7 02/20/2017 12:37 MHH71310.005 1
Strontium (Sr)0.174 mg/L EPA 200.7 02/20/2017 12:37 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 12:37 MHH71310.005 1
Duke Energy Analytical Lab
Page 31 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003496
Collection Date:01-Feb-17 1:44 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Nickel (Ni)1.55 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 00:00N1 CWSPEN30.2 1
Vanadium (V) Low Level 3.65 ug/L EPA 200.8 02/22/2017 00:00 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Copper (Cu)1.22 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Nickel (Ni)1.60 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 14:00 PARMSTR0.2 1
Vanadium (V) Low Level 4.34 ug/L EPA 200.8 02/22/2017 14:00N1 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 32 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003496
Collection Date:01-Feb-17 1:44 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.703 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 33 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003497
Collection Date:01-Feb-17 3:21 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.061 mg-N/L EPA 353.2 02/14/2017 15:23 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 52 mg/L EPA 300.0 02/07/2017 16:05 BGN9034110
Sulfate 21 mg/L EPA 300.0 02/07/2017 16:05 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:43 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:37 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 10:08 JJMACKE0.005 1
Barium (Ba)0.062 mg/L EPA 200.7 02/16/2017 10:08 JJMACKE0.005 1
Boron (B)1.06 mg/L EPA 200.7 02/16/2017 10:08 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/16/2017 10:08 JJMACKE0.01 1
Manganese (Mn)1.20 mg/L EPA 200.7 02/16/2017 10:08 JJMACKE0.005 1
Strontium (Sr)0.348 mg/L EPA 200.7 02/16/2017 10:08 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 10:08 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)26.5 mg/L EPA 200.7 02/17/2017 19:49B2 JJMACKE0.01 1
Magnesium (Mg)9.04 mg/L EPA 200.7 02/17/2017 19:49 JJMACKE0.005 1
Potassium (K)2.02 mg/L EPA 200.7 02/17/2017 19:49 JJMACKE0.1 1
Sodium (Na)21.7 mg/L EPA 200.7 02/17/2017 19:49B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/20/2017 12:53 MHH71310.005 1
Barium (Ba)0.055 mg/L EPA 200.7 02/20/2017 12:53 MHH71310.005 1
Boron (B)0.989 mg/L EPA 200.7 02/20/2017 12:53 MHH71310.05 1
Iron (Fe)0.013 mg/L EPA 200.7 02/20/2017 12:53 MHH71310.01 1
Manganese (Mn)1.31 mg/L EPA 200.7 02/20/2017 12:53 MHH71310.005 1
Strontium (Sr)0.338 mg/L EPA 200.7 02/20/2017 12:53 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 12:53 MHH71310.005 1
Duke Energy Analytical Lab
Page 34 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003497
Collection Date:01-Feb-17 3:21 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Copper (Cu)1.11 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Nickel (Ni)3.85 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 00:58N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 00:58 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Chromium (Cr)1.23 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Copper (Cu)1.12 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Nickel (Ni)4.00 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 03:47N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.309 ug/L EPA 200.8 02/21/2017 03:47 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 35 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003497
Collection Date:01-Feb-17 3:21 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.0 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 36 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003498
Collection Date:01-Feb-17 9:36 AM
Site:ABMW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:26 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 02/07/2017 16:22 BGN90340.5 5
Sulfate 53 mg/L EPA 300.0 02/07/2017 16:22 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/15/2017 14:45 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:39 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.018 mg/L EPA 200.7 02/16/2017 10:20 JJMACKE0.005 1
Barium (Ba)0.570 mg/L EPA 200.7 02/16/2017 10:20 JJMACKE0.005 1
Boron (B)5.89 mg/L EPA 200.7 02/16/2017 10:20 JJMACKE0.05 1
Iron (Fe)5.44 mg/L EPA 200.7 02/16/2017 10:20 JJMACKE0.01 1
Manganese (Mn)2.41 mg/L EPA 200.7 02/16/2017 10:20 JJMACKE0.005 1
Strontium (Sr)2.89 mg/L EPA 200.7 02/16/2017 10:20 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 10:20 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)119 mg/L EPA 200.7 02/18/2017 08:49B2 JJMACKE0.1 10
Magnesium (Mg)32.4 mg/L EPA 200.7 02/18/2017 08:49 JJMACKE0.05 10
Potassium (K)24.3 mg/L EPA 200.7 02/18/2017 08:49 JJMACKE110
Sodium (Na)13.1 mg/L EPA 200.7 02/18/2017 08:49B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.093 mg/L EPA 200.7 02/20/2017 13:05 MHH71310.005 1
Barium (Ba)0.542 mg/L EPA 200.7 02/20/2017 13:05 MHH71310.005 1
Boron (B)6.02 mg/L EPA 200.7 02/20/2017 13:05 MHH71310.05 1
Iron (Fe)5.68 mg/L EPA 200.7 02/20/2017 13:05 MHH71310.01 1
Manganese (Mn)2.43 mg/L EPA 200.7 02/20/2017 13:05 MHH71310.005 1
Strontium (Sr)2.93 mg/L EPA 200.7 02/20/2017 13:05 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 13:05 MHH71310.005 1
Duke Energy Analytical Lab
Page 37 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003498
Collection Date:01-Feb-17 9:36 AM
Site:ABMW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Arsenic (As)668 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR22
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Cobalt (Co)2.57 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Molybdenum (Mo)516 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR22
Nickel (Ni)1.16 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 15:48N1 PARMSTR0.2 1
Vanadium (V) Low Level 3.30 ug/L EPA 200.8 02/21/2017 15:48 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Arsenic (As)718 ug/L EPA 200.8 02/22/2017 14:08M4 PARMSTR22
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Cobalt (Co)2.60 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Molybdenum (Mo)521 ug/L EPA 200.8 02/22/2017 14:08M4 PARMSTR22
Nickel (Ni)1.22 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 14:08N1 PARMSTR0.2 1
Vanadium (V) Low Level 3.94 ug/L EPA 200.8 02/22/2017 14:08 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 550 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 38 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003498
Collection Date:01-Feb-17 9:36 AM
Site:ABMW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 2.5 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 24 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 39 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003499
Collection Date:01-Feb-17 11:07 AM
Site:ABMW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 02/07/2017 16:39 BGN90340.5 5
Sulfate 32 mg/L EPA 300.0 02/07/2017 16:39 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 12:34 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:42 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.062 mg/L EPA 200.7 02/16/2017 10:24 JJMACKE0.005 1
Barium (Ba)0.112 mg/L EPA 200.7 02/16/2017 10:24 JJMACKE0.005 1
Boron (B)8.39 mg/L EPA 200.7 02/16/2017 10:24 JJMACKE0.05 1
Iron (Fe)0.065 mg/L EPA 200.7 02/16/2017 10:24 JJMACKE0.01 1
Manganese (Mn)0.457 mg/L EPA 200.7 02/16/2017 10:24 JJMACKE0.005 1
Strontium (Sr)1.27 mg/L EPA 200.7 02/16/2017 10:24 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 10:24 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)32.9 mg/L EPA 200.7 02/17/2017 19:57B2 JJMACKE0.01 1
Magnesium (Mg)18.1 mg/L EPA 200.7 02/17/2017 19:57 JJMACKE0.005 1
Potassium (K)51.0 mg/L EPA 200.7 02/17/2017 19:57 JJMACKE110
Sodium (Na)50.9 mg/L EPA 200.7 02/17/2017 19:57B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.113 mg/L EPA 200.7 02/20/2017 13:09 MHH71310.005 1
Barium (Ba)0.087 mg/L EPA 200.7 02/20/2017 13:09 MHH71310.005 1
Boron (B)8.90 mg/L EPA 200.7 02/20/2017 13:09 MHH71310.05 1
Iron (Fe)0.094 mg/L EPA 200.7 02/20/2017 13:09 MHH71310.01 1
Manganese (Mn)0.270 mg/L EPA 200.7 02/20/2017 13:09 MHH71310.005 1
Strontium (Sr)1.08 mg/L EPA 200.7 02/20/2017 13:09 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 13:09 MHH71310.005 1
Duke Energy Analytical Lab
Page 40 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003499
Collection Date:01-Feb-17 11:07 AM
Site:ABMW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Arsenic (As)928 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR55
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Molybdenum (Mo)1510 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR55
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 15:56N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.864 ug/L EPA 200.8 02/21/2017 15:56 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Arsenic (As)933 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR55
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Molybdenum (Mo)1420 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR55
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 14:16N1 PARMSTR0.2 1
Vanadium (V) Low Level 1.11 ug/L EPA 200.8 02/22/2017 14:16 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 450 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 41 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003499
Collection Date:01-Feb-17 11:07 AM
Site:ABMW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 8.3 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.5 5
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 42 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003500
Collection Date:01-Feb-17 11:25 AM
Site:ABMW-4D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:29 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 02/08/2017 15:38 BGN90340.5 5
Sulfate 2.6 mg/L EPA 300.0 02/08/2017 15:38 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 12:37 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:44 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.062 mg/L EPA 200.7 02/16/2017 14:59 JJMACKE0.005 1
Barium (Ba)0.882 mg/L EPA 200.7 02/16/2017 14:59 JJMACKE0.005 1
Boron (B)4.06 mg/L EPA 200.7 02/16/2017 14:59 JJMACKE0.05 1
Iron (Fe)51.4 mg/L EPA 200.7 02/16/2017 14:59 JJMACKE0.1 10
Manganese (Mn)5.78 mg/L EPA 200.7 02/16/2017 14:59 JJMACKE0.005 1
Strontium (Sr)1.97 mg/L EPA 200.7 02/16/2017 14:59 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 14:59 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)120 mg/L EPA 200.7 02/18/2017 08:53B2 JJMACKE0.1 10
Magnesium (Mg)36.3 mg/L EPA 200.7 02/18/2017 08:53 JJMACKE0.05 10
Potassium (K)17.0 mg/L EPA 200.7 02/18/2017 08:53 JJMACKE0.1 1
Sodium (Na)16.9 mg/L EPA 200.7 02/18/2017 08:53B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.430 mg/L EPA 200.7 02/20/2017 13:13 MHH71310.005 1
Barium (Ba)0.835 mg/L EPA 200.7 02/20/2017 13:13 MHH71310.005 1
Boron (B)3.94 mg/L EPA 200.7 02/20/2017 13:13 MHH71310.05 1
Iron (Fe)53.0 mg/L EPA 200.7 02/20/2017 13:13 MHH71310.1 10
Manganese (Mn)5.66 mg/L EPA 200.7 02/20/2017 13:13 MHH71310.005 1
Strontium (Sr)1.94 mg/L EPA 200.7 02/20/2017 13:13 MHH71310.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 02/20/2017 13:13 MHH71310.005 1
Duke Energy Analytical Lab
Page 43 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003500
Collection Date:01-Feb-17 11:25 AM
Site:ABMW-4D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Arsenic (As)34.3 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Cobalt (Co)5.00 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Molybdenum (Mo)43.6 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 01:20N1 CWSPEN30.2 1
Vanadium (V) Low Level 8.37 ug/L EPA 200.8 02/22/2017 01:20 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Arsenic (As)32.8 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Chromium (Cr)1.39 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Cobalt (Co)5.16 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Molybdenum (Mo)38.7 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Nickel (Ni)1.57 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 04:33N1 PARMSTR0.2 1
Vanadium (V) Low Level 11.3 ug/L EPA 200.8 02/21/2017 04:33 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 600 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 44 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003500
Collection Date:01-Feb-17 11:25 AM
Site:ABMW-4D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 7.0 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.5 5
TOTAL SUSPENDED SOLIDS
TSS 71 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 45 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003501
Collection Date:01-Feb-17 12:51 PM
Site:ABMW-2BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 26 mg/L EPA 300.0 02/07/2017 18:21 BGN90340.5 5
Sulfate 5.6 mg/L EPA 300.0 02/07/2017 18:21 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 12:39 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:47 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/16/2017 10:35 JJMACKE0.005 1
Barium (Ba)0.111 mg/L EPA 200.7 02/16/2017 10:35 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 10:35 JJMACKE0.05 1
Iron (Fe)0.377 mg/L EPA 200.7 02/16/2017 10:35 JJMACKE0.01 1
Manganese (Mn)0.237 mg/L EPA 200.7 02/16/2017 10:35 JJMACKE0.005 1
Strontium (Sr)1.04 mg/L EPA 200.7 02/16/2017 10:35 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 10:35 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)73.5 mg/L EPA 200.7 02/20/2017 10:23 JJMACKE0.01 1
Magnesium (Mg)12.4 mg/L EPA 200.7 02/20/2017 10:23 JJMACKE0.005 1
Potassium (K)6.05 mg/L EPA 200.7 02/20/2017 10:23 JJMACKE0.1 1
Sodium (Na)27.1 mg/L EPA 200.7 02/20/2017 10:23 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.018 mg/L EPA 200.7 02/20/2017 13:17 MHH71310.005 1
Barium (Ba)0.109 mg/L EPA 200.7 02/20/2017 13:17 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 13:17 MHH71310.05 1
Iron (Fe)1.09 mg/L EPA 200.7 02/20/2017 13:17 MHH71310.01 1
Manganese (Mn)0.236 mg/L EPA 200.7 02/20/2017 13:17 MHH71310.005 1
Strontium (Sr)1.04 mg/L EPA 200.7 02/20/2017 13:17 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 13:17 MHH71310.005 1
Duke Energy Analytical Lab
Page 46 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003501
Collection Date:01-Feb-17 12:51 PM
Site:ABMW-2BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Arsenic (As)2.26 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Molybdenum (Mo)8.50 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 00:07N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 00:07 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Arsenic (As)3.50 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Molybdenum (Mo)8.93 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 05:04N1 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/21/2017 05:04 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 350 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 47 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003501
Collection Date:01-Feb-17 12:51 PM
Site:ABMW-2BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.963 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 48 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003502
Collection Date:01-Feb-17 2:06 PM
Site:ABMW-2BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:31 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 21 mg/L EPA 300.0 02/07/2017 18:38 BGN90340.5 5
Sulfate 1.6 mg/L EPA 300.0 02/07/2017 18:38 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 12:42 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:49 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 02/16/2017 10:39 JJMACKE0.005 1
Barium (Ba)0.067 mg/L EPA 200.7 02/16/2017 10:39 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/16/2017 10:39 JJMACKE0.05 1
Iron (Fe)1.05 mg/L EPA 200.7 02/16/2017 10:39 JJMACKE0.01 1
Manganese (Mn)0.316 mg/L EPA 200.7 02/16/2017 10:39 JJMACKE0.005 1
Strontium (Sr)2.20 mg/L EPA 200.7 02/16/2017 10:39 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 10:39 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)67.5 mg/L EPA 200.7 02/20/2017 10:27 JJMACKE0.01 1
Magnesium (Mg)11.0 mg/L EPA 200.7 02/20/2017 10:27 JJMACKE0.005 1
Potassium (K)6.30 mg/L EPA 200.7 02/20/2017 10:27 JJMACKE0.1 1
Sodium (Na)16.4 mg/L EPA 200.7 02/20/2017 10:27 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 02/20/2017 13:21 MHH71310.005 1
Barium (Ba)0.063 mg/L EPA 200.7 02/20/2017 13:21 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/20/2017 13:21 MHH71310.05 1
Iron (Fe)1.08 mg/L EPA 200.7 02/20/2017 13:21 MHH71310.01 1
Manganese (Mn)0.312 mg/L EPA 200.7 02/20/2017 13:21 MHH71310.005 1
Strontium (Sr)2.23 mg/L EPA 200.7 02/20/2017 13:21 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 13:21 MHH71310.005 1
Duke Energy Analytical Lab
Page 49 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003502
Collection Date:01-Feb-17 2:06 PM
Site:ABMW-2BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Arsenic (As)1.33 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Molybdenum (Mo)1.27 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 01:27N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 01:27 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Arsenic (As)1.53 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Molybdenum (Mo)1.29 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 05:12N1 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/21/2017 05:12 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 50 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003502
Collection Date:01-Feb-17 2:06 PM
Site:ABMW-2BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.4 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 51 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003503
Collection Date:01-Feb-17 3:30 PM
Site:ABMW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 68 mg/L EPA 300.0 02/07/2017 17:47 BGN9034110
Sulfate 34 mg/L EPA 300.0 02/07/2017 17:47 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 12:44 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:52 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.021 mg/L EPA 200.7 02/16/2017 11:00 JJMACKE0.005 1
Barium (Ba)0.227 mg/L EPA 200.7 02/16/2017 11:00 JJMACKE0.005 1
Boron (B)1.92 mg/L EPA 200.7 02/16/2017 11:00 JJMACKE0.05 1
Iron (Fe)11.0 mg/L EPA 200.7 02/16/2017 11:00 JJMACKE0.01 1
Manganese (Mn)0.700 mg/L EPA 200.7 02/16/2017 11:00 JJMACKE0.005 1
Strontium (Sr)1.44 mg/L EPA 200.7 02/16/2017 11:00 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 11:00 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)57.5 mg/L EPA 200.7 02/20/2017 10:31 JJMACKE0.01 1
Magnesium (Mg)12.7 mg/L EPA 200.7 02/20/2017 10:31 JJMACKE0.005 1
Potassium (K)12.3 mg/L EPA 200.7 02/20/2017 10:31 JJMACKE0.1 1
Sodium (Na)13.3 mg/L EPA 200.7 02/20/2017 10:31 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.039 mg/L EPA 200.7 02/20/2017 13:25 MHH71310.005 1
Barium (Ba)0.226 mg/L EPA 200.7 02/20/2017 13:25 MHH71310.005 1
Boron (B)1.94 mg/L EPA 200.7 02/20/2017 13:25 MHH71310.05 1
Iron (Fe)13.0 mg/L EPA 200.7 02/20/2017 13:25 MHH71310.01 1
Manganese (Mn)0.746 mg/L EPA 200.7 02/20/2017 13:25 MHH71310.005 1
Strontium (Sr)1.43 mg/L EPA 200.7 02/20/2017 13:25 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 13:25 MHH71310.005 1
Duke Energy Analytical Lab
Page 52 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003503
Collection Date:01-Feb-17 3:30 PM
Site:ABMW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Arsenic (As)194 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Molybdenum (Mo)51.1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 01:34N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 01:34 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Arsenic (As)185 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Molybdenum (Mo)44.3 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 05:19N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.485 ug/L EPA 200.8 02/21/2017 05:19 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 360 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 53 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003503
Collection Date:01-Feb-17 3:30 PM
Site:ABMW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 2.5 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 22 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Duke Energy Analytical Lab
Page 54 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003504
Collection Date:01-Feb-17 4:06 PM
Site:ABMW-3S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/14/2017 15:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 02/07/2017 18:04 BGN90340.2 2
Sulfate 0.53 mg/L EPA 300.0 02/07/2017 18:04 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2017 12:46 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/17/2017 14:54 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 02/16/2017 11:04 JJMACKE0.005 1
Barium (Ba)0.021 mg/L EPA 200.7 02/16/2017 11:04 JJMACKE0.005 1
Boron (B)1.26 mg/L EPA 200.7 02/16/2017 11:04 JJMACKE0.05 1
Iron (Fe)1.75 mg/L EPA 200.7 02/16/2017 11:04 JJMACKE0.01 1
Manganese (Mn)0.369 mg/L EPA 200.7 02/16/2017 11:04 JJMACKE0.005 1
Strontium (Sr)0.074 mg/L EPA 200.7 02/16/2017 11:04 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/16/2017 11:04 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.75 mg/L EPA 200.7 02/20/2017 10:35 JJMACKE0.01 1
Magnesium (Mg)0.781 mg/L EPA 200.7 02/20/2017 10:35 JJMACKE0.005 1
Potassium (K)1.05 mg/L EPA 200.7 02/20/2017 10:35 JJMACKE0.1 1
Sodium (Na)16.1 mg/L EPA 200.7 02/20/2017 10:35 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 02/20/2017 13:29 MHH71310.005 1
Barium (Ba)0.023 mg/L EPA 200.7 02/20/2017 13:29 MHH71310.005 1
Boron (B)1.26 mg/L EPA 200.7 02/20/2017 13:29 MHH71310.05 1
Iron (Fe)2.57 mg/L EPA 200.7 02/20/2017 13:29 MHH71310.01 1
Manganese (Mn)0.377 mg/L EPA 200.7 02/20/2017 13:29 MHH71310.005 1
Strontium (Sr)0.079 mg/L EPA 200.7 02/20/2017 13:29 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/20/2017 13:29 MHH71310.005 1
Duke Energy Analytical Lab
Page 55 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003504
Collection Date:01-Feb-17 4:06 PM
Site:ABMW-3S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Cobalt (Co)2.41 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/22/2017 01:41N1 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/22/2017 01:41 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Arsenic (As)1.22 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Cobalt (Co)2.32 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/21/2017 05:27N1 PARMSTR0.2 1
Vanadium (V) Low Level 0.479 ug/L EPA 200.8 02/21/2017 05:27 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 02/06/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 56 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
2017003504
Collection Date:01-Feb-17 4:06 PM
Site:ABMW-3S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.663 mg/L SM5310C/EPA9060A 02/14/2017 13:11 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/06/2017 08:30 MGIGANT51
Low level thallium was present in blank(s) above the method detection limit but less than the reporting limit. Data is
valid for compliance purposes.
Qualifiers:
B2 Target analyte was detected in Method Blank(s) at a concentration greater than ½ the reporting limit but less
than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
N1 See additional information listed below.
Duke Energy Analytical Lab
Page 57 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020381 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0006 mg-N/L -1-0.0006 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0007 mg-N/L -1-0.0007 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0011 mg-N/L -10.0011 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0007 mg-N/L -1-0.0007 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.303 3.01 101mg-N/L -11090103.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.3 3.01 99.7mg-N/L -11090103
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.6mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 98.9mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010203 -- 2017000828
Nitrite + Nitrate
(Colorimetric)
0.993 50 96.4mg-N/L -11090200199
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010203 -- 2017000828
Nitrite + Nitrate
(Colorimetric)
0.987 50 94 2.52mg-N/L -11090200197
Duke Energy Analytical Lab
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Order # J17020042
Q17020381 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Nitrite + Nitrate
(Colorimetric)
0.24 0.25 99.1mg-N/L -1109010.24
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Nitrite + Nitrate
(Colorimetric)
0.234 0.25 97 2.16mg-N/L -1109010.234
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Nitrite + Nitrate
(Colorimetric)
0.306 0.25 98.1mg-N/L -1109010.306
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Nitrite + Nitrate
(Colorimetric)
0.309 0.25 99.2 1.18mg-N/L -1109010.309
Duke Energy Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020153 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0407 mg/L -10.0407 0.1 < 1/2 RDL
Sulfate 0.0027 mg/L -10.0027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Chloride 0.03 mg/L -10.03 0.1 < 1/2 RDL
Sulfate -0.0339 mg/L -1-0.0339 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 9.57 250 96.7mg/L -1208050479
Sulfate 7.11 250 86.9mg/L -1208050355
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 9.59 250 97 0.25mg/L -1208050479
Sulfate 7.11 250 87 0.0552mg/L -1208050355
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 7.21 25 102mg/L -12080536.1
Sulfate 5.36 25 107mg/L -12080526.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 7.14 25 101 1.47mg/L -12080535.7
Sulfate 5.29 25 105 1.29mg/L -12080526.5
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.88 5 97.6mg/L -1109014.88
Sulfate 4.79 5 95.7mg/L -1109014.79
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Chloride 5.15 5 103mg/L -1109015.15
Sulfate 5.18 5 104mg/L -1109015.18
Duke Energy Analytical Lab
Page 60 of 166
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This report shall not be reproduced, except in full.
Order # J17020042
Q17020411 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.003 ug/L -10.003 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.004 ug/L -10.004 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.753 20 71.1ug/L -130702015.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.749 20 70.6 0.705ug/L -130702015
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.795 20 74.6ug/L -130702015.9
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.796 20 74.7 0.067ug/L -130702015.9
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.74 2 87.2ug/L -1158511.74
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.74 2 87ug/L -1158511.74
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010657 -- 2017003049
Mercury (Hg) 0.976 1 97ug/L -1307010.976
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010657 -- 2017003049
Mercury (Hg) 0.965 1 95.9 1.14ug/L -1307010.965
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003488
Mercury (Hg) 0.874 1 87.1ug/L -1307010.874
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003488
Mercury (Hg) 0.861 1 85.8 1.5ug/L -1307010.861
Duke Energy Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020456 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.014 ug/L -10.014 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.02 ug/L -10.02 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.903 20 88.2ug/L -130702018.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.914 20 89.2 1.18ug/L -130702018.3
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.861 100 83.6ug/L -1307010086.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.843 100 81.8 2.2ug/L -1307010084.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.98 2 98.8ug/L -1158511.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.86 2 93.2ug/L -1158511.86
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020436 -- 2017005386
Mercury (Hg) 1.01 1 98.1ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020436 -- 2017005386
Mercury (Hg) 1.03 1 99.7 1.62ug/L -1307011.03
Duke Energy Analytical Lab
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Order # J17020042
Q17020503 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.014 ug/L -10.014 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.24 2 112ug/L -1158512.24
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.95 2 97.3ug/L -1158511.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Mercury (Hg) 0.968 1 94.8ug/L -1307010.968
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Mercury (Hg) 0.971 1 95.1 0.316ug/L -1307010.971
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Mercury (Hg) 1 1 97.7ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Mercury (Hg) 0.973 1 94.9 2.91ug/L -1307010.973
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003496
Mercury (Hg) 1.04 1 102ug/L -1307011.04
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003496
Mercury (Hg) 1.02 1 100 1.29ug/L -1307011.02
Duke Energy Analytical Lab
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Order # J17020042
Q17020427 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000076 mg/L -1-0.000076 0.005 < 1/2 RDL
Barium (Ba) -0.000032 mg/L -1-0.000032 0.005 < 1/2 RDL
Boron (B) -0.00607 mg/L -1-0.00607 0.05 < 1/2 RDL
Iron (Fe) -0.000516 mg/L -1-0.000516 0.01 < 1/2 RDL
Manganese (Mn) 0.000066 mg/L -10.000066 0.005 < 1/2 RDL
Strontium (Sr) 0.000076 mg/L -10.000076 0.005 < 1/2 RDL
Zinc (Zn) -0.00228 mg/L -1-0.00228 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) -0.000064 mg/L -1-0.000064 0.005 < 1/2 RDL
Barium (Ba) 0.000003 mg/L -10.000003 0.005 < 1/2 RDL
Boron (B) -0.00694 mg/L -1-0.00694 0.05 < 1/2 RDL
Iron (Fe) 0.000037 mg/L -10.000037 0.01 < 1/2 RDL
Manganese (Mn) 0.000203 mg/L -10.000203 0.005 < 1/2 RDL
Strontium (Sr) 0.000076 mg/L -10.000076 0.005 < 1/2 RDL
Zinc (Zn) -0.00175 mg/L -1-0.00175 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2 2 99.8mg/L -1158512
Barium (Ba) 0.956 1 95.6mg/L -1158510.956
Boron (B) 1.95 2 97.3mg/L -1158511.95
Iron (Fe) 1.96 2 97.9mg/L -1158511.96
Manganese (Mn) 0.938 1 93.8mg/L -1158510.938
Strontium (Sr) 1.81 2 90.6mg/L -1158511.81
Zinc (Zn) 0.987 1 98.7mg/L -1158510.987
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.05 2 103mg/L -1158512.05
Barium (Ba) 0.972 1 97.2mg/L -1158510.972
Boron (B) 1.99 2 99.7mg/L -1158511.99
Iron (Fe) 2.01 2 100mg/L -1158512.01
Manganese (Mn) 0.963 1 96.3mg/L -1158510.963
Strontium (Sr) 1.83 2 91.8mg/L -1158511.83
Zinc (Zn) 1.02 1 102mg/L -1158511.02
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Aluminum (Al) 5.57 5 111mg/L -1307015.57
Duke Energy Analytical Lab
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Order # J17020042
Q17020427 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Barium (Ba) 5.69 5 113mg/L -1307015.69
Boron (B) 5.32 5 106mg/L -1307015.32
Iron (Fe) 5.53 5 107mg/L -1307015.53
Manganese (Mn) 5.72 5 113mg/L -1307015.72
Strontium (Sr) 5.47 5 108mg/L -1307015.47
Zinc (Zn) 5.6 5 112mg/L -1307015.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Aluminum (Al) 5.63 5 112 1.09mg/L -1307015.63
Barium (Ba) 5.73 5 114 0.739mg/L -1307015.73
Boron (B) 5.39 5 108 1.21mg/L -1307015.39
Iron (Fe) 5.59 5 108 1.13mg/L -1307015.59
Manganese (Mn) 5.79 5 114 1.2mg/L -1307015.79
Strontium (Sr) 5.47 5 109 0.0737mg/L -1307015.47
Zinc (Zn) 5.64 5 113 0.836mg/L -1307015.64
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003264
Aluminum (Al) 5.75 5 115mg/L -1307015.75
Barium (Ba) 5.84 5 116mg/L -1307015.84
Boron (B) 6.05 5 108mg/L -1307016.05
Iron (Fe) 16.2 5 109mg/L -13070116.2
Manganese (Mn) 12.6 5 104mg/L -13070112.6
Strontium (Sr) 5.7 5 107mg/L -1307015.7
Zinc (Zn) 5.63 5 112mg/L -1307015.63
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003264
Aluminum (Al) 5.71 5 114 0.578mg/L -1307015.71
Barium (Ba) 5.79 5 115 0.903mg/L -1307015.79
Boron (B) 5.97 5 107 1.4mg/L -1307015.97
Iron (Fe) 16 5 105 3.89mg/L -13070116
Manganese (Mn) 12.6 5 103 1.24mg/L -13070112.6
Strontium (Sr) 5.63 5 106 1.33mg/L -1307015.63
Zinc (Zn) 5.59 5 112 0.696mg/L -1307015.59
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Aluminum (Al) 5.75 5 115mg/L -1307015.75
Barium (Ba) 5.86 5 116mg/L -1307015.86
Duke Energy Analytical Lab
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This report shall not be reproduced, except in full.
Order # J17020042
Q17020427 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Boron (B) 5.44 5 109mg/L -1307015.44
Iron (Fe) 6.7 5 109mg/L -1307016.7
Manganese (Mn) 6.79 5 114mg/L -1307016.79
Strontium (Sr) 5.75 5 107mg/L -1307015.75
Zinc (Zn) 5.53 5 111mg/L -1307015.53
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Aluminum (Al) 5.61 5 112 2.48mg/L -1307015.61
Barium (Ba) 5.68 5 112 3.08mg/L -1307015.68
Boron (B) 5.33 5 107 2.06mg/L -1307015.33
Iron (Fe) 6.55 5 106 2.73mg/L -1307016.55
Manganese (Mn) 6.63 5 111 2.71mg/L -1307016.63
Strontium (Sr) 5.61 5 105 2.74mg/L -1307015.61
Zinc (Zn) 5.4 5 108 2.29mg/L -1307015.4
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Aluminum (Al) 5.82 5 116mg/L -1307015.82
Barium (Ba) 5.8 5 116mg/L -1307015.8
Boron (B) 5.4 5 107mg/L -1307015.4
Iron (Fe) 5.79 5 111mg/L -1307015.79
Manganese (Mn) 5.93 5 117mg/L -1307015.93
Strontium (Sr) 5.47 5 108mg/L -1307015.47
Zinc (Zn) 5.8 5 116mg/L -1307015.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Aluminum (Al) 5.78 5 115 0.691mg/L -1307015.78
Barium (Ba) 5.79 5 116 0.121mg/L -1307015.79
Boron (B) 5.39 5 107 0.168mg/L -1307015.39
Iron (Fe) 5.76 5 110 0.417mg/L -1307015.76
Manganese (Mn) 5.92 5 116 0.223mg/L -1307015.92
Strontium (Sr) 5.44 5 107 0.503mg/L -1307015.44
Zinc (Zn) 5.78 5 116 0.362mg/L -1307015.78
Duke Energy Analytical Lab
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Certificate of Laboratory Analysis
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Order # J17020042
Q17020465 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000078 mg/L -10.000078 0.005 < 1/2 RDL
Barium (Ba) 0.000042 mg/L -10.000042 0.005 < 1/2 RDL
Boron (B) 0.000248 mg/L -10.000248 0.05 < 1/2 RDL
Iron (Fe) -0.000187 mg/L -1-0.000187 0.01 < 1/2 RDL
Manganese (Mn) 0.000006 mg/L -10.000006 0.005 < 1/2 RDL
Strontium (Sr) 0.000105 mg/L -10.000105 0.005 < 1/2 RDL
Zinc (Zn) 0.00191 mg/L -10.00191 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) 0.000585 mg/L -10.000585 0.005 < 1/2 RDL
Barium (Ba) -0.00015 mg/L -1-0.00015 0.005 < 1/2 RDL
Boron (B) 0.000013 mg/L -10.000013 0.05 < 1/2 RDL
Iron (Fe) 0.0047 mg/L -10.0047 0.01 < 1/2 RDL
Manganese (Mn) 0.000108 mg/L -10.000108 0.005 < 1/2 RDL
Strontium (Sr) 0.000116 mg/L -10.000116 0.005 < 1/2 RDL
Zinc (Zn) 0.000335 mg/L -10.000335 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.04 2 102mg/L -1158512.04
Barium (Ba) 0.991 1 99.1mg/L -1158510.991
Boron (B) 2.01 2 101mg/L -1158512.01
Iron (Fe) 2.03 2 102mg/L -1158512.03
Manganese (Mn) 0.97 1 97mg/L -1158510.97
Strontium (Sr) 1.9 2 94.8mg/L -1158511.9
Zinc (Zn) 1.02 1 102mg/L -1158511.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.04 2 102mg/L -1158512.04
Barium (Ba) 0.989 1 98.9mg/L -1158510.989
Boron (B) 2 2 100mg/L -1158512
Iron (Fe) 2.02 2 101mg/L -1158512.02
Manganese (Mn) 0.97 1 97mg/L -1158510.97
Strontium (Sr) 1.9 2 94.8mg/L -1158511.9
Zinc (Zn) 1 1 100mg/L -1158511
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Aluminum (Al) 5.69 5 114mg/L -1307015.69
Duke Energy Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020465 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Barium (Ba) 5.85 5 116mg/L -1307015.85
Boron (B) 6.25 5 104mg/L -1307016.25
Iron (Fe) 5.5 5 110mg/L -1307015.5
Manganese (Mn) 6.84 5 113mg/L -1307016.84
Strontium (Sr) 5.8 5 109mg/L -1307015.8
Zinc (Zn) 5.67 5 113mg/L -1307015.67
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Aluminum (Al) 5.64 5 113 0.812mg/L -1307015.64
Barium (Ba) 5.81 5 115 0.694mg/L -1307015.81
Boron (B) 6.17 5 102 1.42mg/L -1307016.17
Iron (Fe) 5.44 5 109 0.97mg/L -1307015.44
Manganese (Mn) 6.78 5 112 1.18mg/L -1307016.78
Strontium (Sr) 5.73 5 108 1.33mg/L -1307015.73
Zinc (Zn) 5.63 5 113 0.638mg/L -1307015.63
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003726
Aluminum (Al) 5.65 5 113mg/L -1307015.65
Barium (Ba) 5.89 5 117mg/L -1307015.89
Boron (B) 5.3 5 106mg/L -1307015.3
Iron (Fe) 5.85 5 110mg/L -1307015.85
Manganese (Mn) 6.46 5 115mg/L -1307016.46
Strontium (Sr) 5.64 5 110mg/L -1307015.64
Zinc (Zn) 5.69 5 114mg/L -1307015.69
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020082 -- 2017003726
Aluminum (Al) 5.64 5 113 0.124mg/L -1307015.64
Barium (Ba) 5.88 5 117 0.206mg/L -1307015.88
Boron (B) 5.27 5 105 0.643mg/L -1307015.27
Iron (Fe) 5.82 5 109 0.494mg/L -1307015.82
Manganese (Mn) 6.43 5 114 0.523mg/L -1307016.43
Strontium (Sr) 5.63 5 109 0.311mg/L -1307015.63
Zinc (Zn) 5.67 5 113 0.229mg/L -1307015.67
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020342 -- 2017004969
Aluminum (Al) 5.63 5 113mg/L -1307015.63
Barium (Ba) 5.38 5 107mg/L -1307015.38
Duke Energy Analytical Lab
Page 68 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020465 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020342 -- 2017004969
Boron (B) 7.42 5 99.6mg/L -1307017.42
Iron (Fe) 5.42 5 108mg/L -1307015.42
Manganese (Mn) 5.69 5 114mg/L -1307015.69
Strontium (Sr) 6.41 5 108mg/L -1307016.41
Zinc (Zn) 5.33 5 107mg/L -1307015.33
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020342 -- 2017004969
Aluminum (Al) 5.59 5 112 0.73mg/L -1307015.59
Barium (Ba) 4.92 5 97.7 9.1mg/L -1307014.92
Boron (B) 7.32 5 97.5 2.09mg/L -1307017.32
Iron (Fe) 5.37 5 107 0.945mg/L -1307015.37
Manganese (Mn) 5.65 5 113 0.6mg/L -1307015.65
Strontium (Sr) 6.38 5 107 0.614mg/L -1307016.38
Zinc (Zn) 5.32 5 106 0.169mg/L -1307015.32
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17020345 -- 2017004981
Aluminum (Al) 5.68 5 113mg/L -1307015.68
Barium (Ba) 5.82 5 115mg/L -1307015.82
Boron (B) 5.47 5 104mg/L -1307015.47
Iron (Fe) 15.1 5 106mg/L -13070115.1
Manganese (Mn) 9.7 5 99.1mg/L -1307019.7
Strontium (Sr) 5.59 5 109mg/L -1307015.59
Zinc (Zn) 5.64 5 112mg/L -1307015.64
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17020345 -- 2017004981
Aluminum (Al) 5.7 5 114 0.317mg/L -1307015.7
Barium (Ba) 5.83 5 115 0.261mg/L -1307015.83
Boron (B) 5.53 5 105 1.15mg/L -1307015.53
Iron (Fe) 15.2 5 108 1.53mg/L -13070115.2
Manganese (Mn) 9.73 5 99.7 0.523mg/L -1307019.73
Strontium (Sr) 5.61 5 109 0.349mg/L -1307015.61
Zinc (Zn) 5.64 5 112 0.143mg/L -1307015.64
Duke Energy Analytical Lab
Page 69 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020504 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00757 mg/L -10.00757 0.01 > 1/2 RDL
Magnesium (Mg) 0.000896 mg/L -10.000896 0.005 < 1/2 RDL
Potassium (K) 0.0154 mg/L -10.0154 0.1 < 1/2 RDL
Sodium (Na) 0.0356 mg/L -10.0356 0.05 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.00206 mg/L -10.00206 0.01 < 1/2 RDL
Magnesium (Mg) 0.000226 mg/L -10.000226 0.005 < 1/2 RDL
Potassium (K) -0.00613 mg/L -1-0.00613 0.1 < 1/2 RDL
Sodium (Na) 0.00629 mg/L -10.00629 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Calcium (Ca) 0.00194 mg/L -10.00194 0.01 < 1/2 RDL
Magnesium (Mg) 0.000174 mg/L -10.000174 0.005 < 1/2 RDL
Potassium (K) -0.012 mg/L -1-0.012 0.1 < 1/2 RDL
Sodium (Na) 0.00633 mg/L -10.00633 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 1.97 2 98.5mg/L -1158511.97
Magnesium (Mg) 1.93 2 96.5mg/L -1158511.93
Potassium (K) 3.86 4 96.5mg/L -1158513.86
Sodium (Na) 7.99 8.1 98.6mg/L -1158517.99
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 1.96 2 97.8mg/L -1158511.96
Magnesium (Mg) 1.93 2 96.3mg/L -1158511.93
Potassium (K) 3.83 4 95.8mg/L -1158513.83
Sodium (Na) 7.99 8.1 98.7mg/L -1158517.99
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Calcium (Ca) 1.96 2 97.9mg/L -1158511.96
Magnesium (Mg) 1.91 2 95.7mg/L -1158511.91
Potassium (K) 3.83 4 95.8mg/L -1158513.83
Sodium (Na) 7.99 8.1 98.7mg/L -1158517.99
Duke Energy Analytical Lab
Page 70 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020504 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Calcium (Ca) 10.1 5 99.4mg/L -13070110.1
Magnesium (Mg) 7.75 5 103mg/L -1307017.75
Potassium (K) 6.45 5 101mg/L -1307016.45
Sodium (Na) 11.9 5 87.5mg/L -13070111.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Calcium (Ca) 10.4 5 105 5.96mg/L -13070110.4
Magnesium (Mg) 7.92 5 106 3.31mg/L -1307017.92
Potassium (K) 6.58 5 104 2.62mg/L -1307016.58
Sodium (Na) 12.1 5 92.4 5.51mg/L -13070112.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003266
Calcium (Ca) 12.3 5 180mg/L -130701200
Magnesium (Mg) 7.25 5 0mg/L -13070155.1
Potassium (K) 6.58 5 105mg/L -1307018.85
Sodium (Na) 10.8 5 102mg/L -13070118.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003266
Calcium (Ca) 200 5 461 87.9mg/L -130701214
Magnesium (Mg) 55.1 5 34.1 200mg/L -13070158.6
Potassium (K) 8.85 5 116 10.1mg/L -1307019.41
Sodium (Na) 18.8 5 128 21.8mg/L -13070120.1
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020040 -- 2017003472
Calcium (Ca) 29.2 5 99.6mg/L -13070112.3
Magnesium (Mg) 9.9 5 101mg/L -1307017.25
Potassium (K) 6.9 5 101mg/L -1307016.58
Sodium (Na) 14.1 5 97.5mg/L -13070110.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020040 -- 2017003472
Calcium (Ca) 214 5 103 3.74mg/L -13070112.5
Magnesium (Mg) 58.6 5 102 1.04mg/L -1307017.3
Potassium (K) 9.41 5 103 2.14mg/L -1307016.69
Sodium (Na) 20.1 5 101 3.69mg/L -13070111
Duke Energy Analytical Lab
Page 71 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020504 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003489
Calcium (Ca) 29.2 5 121mg/L -13070129.2
Magnesium (Mg) 9.9 5 107mg/L -1307019.9
Potassium (K) 6.9 5 105mg/L -1307016.9
Sodium (Na) 14.1 5 104mg/L -13070114.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003489
Calcium (Ca) 12.5 5 120 0.936mg/L -13070129.1
Magnesium (Mg) 7.3 5 107 0.468mg/L -1307019.87
Potassium (K) 6.69 5 105 0.341mg/L -1307016.91
Sodium (Na) 11 5 102 1.77mg/L -13070114
Duke Energy Analytical Lab
Page 72 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020520 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00303 mg/L -10.00303 0.01 < 1/2 RDL
Magnesium (Mg) 0.00208 mg/L -10.00208 0.005 < 1/2 RDL
Potassium (K) 0.00394 mg/L -10.00394 0.1 < 1/2 RDL
Sodium (Na) 0.00167 mg/L -10.00167 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2 2 100mg/L -1158512
Magnesium (Mg) 1.97 2 98.5mg/L -1158511.97
Potassium (K) 3.88 4 97mg/L -1158513.88
Sodium (Na) 7.97 8.1 98.5mg/L -1158517.97
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020211 -- 2017004362
Calcium (Ca) 10.7 5 125mg/L -13070110.7
Magnesium (Mg) 7.43 5 122mg/L -1307017.43
Potassium (K) 8.51 5 122mg/L -1307018.51
Sodium (Na) 13.6 5 113mg/L -13070113.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020211 -- 2017004362
Calcium (Ca) 10.6 5 123 1.28mg/L -13070110.6
Magnesium (Mg) 7.44 5 122 0.0164mg/L -1307017.44
Potassium (K) 8.46 5 121 0.822mg/L -1307018.46
Sodium (Na) 13.6 5 113 0.106mg/L -13070113.6
Duke Energy Analytical Lab
Page 73 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020483 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00239 mg/L -10.00239 0.005 < 1/2 RDL
Barium (Ba) 0.0002 mg/L -10.0002 0.005 < 1/2 RDL
Boron (B) 0.00217 mg/L -10.00217 0.05 < 1/2 RDL
Iron (Fe) 0.00213 mg/L -10.00213 0.01 < 1/2 RDL
Manganese (Mn) 0.00106 mg/L -10.00106 0.005 < 1/2 RDL
Strontium (Sr) 0.000843 mg/L -10.000843 0.005 < 1/2 RDL
Zinc (Zn) 0.00119 mg/L -10.00119 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.62 5 92.4mg/L -1158514.62
Barium (Ba) 4.85 5 97mg/L -1158514.85
Boron (B) 4.83 5 96.7mg/L -1158514.83
Iron (Fe) 4.84 5 96.8mg/L -1158514.84
Manganese (Mn) 4.83 5 96.5mg/L -1158514.83
Strontium (Sr) 4.84 5 96.7mg/L -1158514.84
Zinc (Zn) 4.75 5 94.9mg/L -1158514.75
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Aluminum (Al) 4.64 5 92.4mg/L -1307014.64
Barium (Ba) 4.83 5 96.5mg/L -1307014.83
Boron (B) 4.88 5 96.9mg/L -1307014.88
Iron (Fe) 5.09 5 96.3mg/L -1307015.09
Manganese (Mn) 4.88 5 95.7mg/L -1307014.88
Strontium (Sr) 4.92 5 96.6mg/L -1307014.92
Zinc (Zn) 4.71 5 94.1mg/L -1307014.71
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Aluminum (Al) 4.7 5 93.6 1.29mg/L -1307014.7
Barium (Ba) 4.88 5 97.4 0.949mg/L -1307014.88
Boron (B) 4.91 5 97.4 0.576mg/L -1307014.91
Iron (Fe) 5.17 5 97.8 1.55mg/L -1307015.17
Manganese (Mn) 4.95 5 97.2 1.53mg/L -1307014.95
Strontium (Sr) 4.94 5 97 0.434mg/L -1307014.94
Zinc (Zn) 4.78 5 95.5 1.46mg/L -1307014.78
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Aluminum (Al) 4.58 5 91.5mg/L -1307014.58
Duke Energy Analytical Lab
Page 74 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020483 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Barium (Ba) 4.79 5 94.6mg/L -1307014.79
Boron (B) 5.82 5 96.6mg/L -1307015.82
Iron (Fe) 4.83 5 96.3mg/L -1307014.83
Manganese (Mn) 6.07 5 95.2mg/L -1307016.07
Strontium (Sr) 5.09 5 95mg/L -1307015.09
Zinc (Zn) 4.68 5 93.5mg/L -1307014.68
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003497
Aluminum (Al) 4.5 5 89.9 1.83mg/L -1307014.5
Barium (Ba) 4.69 5 92.6 2.12mg/L -1307014.69
Boron (B) 5.8 5 96.2 0.374mg/L -1307015.8
Iron (Fe) 4.79 5 95.5 0.897mg/L -1307014.79
Manganese (Mn) 5.98 5 93.5 1.74mg/L -1307015.98
Strontium (Sr) 5.04 5 94 1.06mg/L -1307015.04
Zinc (Zn) 4.62 5 92.4 1.12mg/L -1307014.62
Duke Energy Analytical Lab
Page 75 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020488 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.053 ug/L -1-0.053 1 < 1/2 RDL
Arsenic (As) 0.012 ug/L -10.012 1 < 1/2 RDL
Beryllium (Be) 0.014 ug/L -10.014 1 < 1/2 RDL
Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL
Chromium (Cr) 0.055 ug/L -10.055 1 < 1/2 RDL
Cobalt (Co) 0.002 ug/L -10.002 1 < 1/2 RDL
Copper (Cu) 0.049 ug/L -10.049 1 < 1/2 RDL
Lead (Pb) 0.006 ug/L -10.006 1 < 1/2 RDL
Molybdenum (Mo) 0.01 ug/L -10.01 1 < 1/2 RDL
Nickel (Ni) 0.143 ug/L -10.143 1 < 1/2 RDL
Selenium (Se) 0.027 ug/L -10.027 1 < 1/2 RDL
Thallium (Tl) Low Level -0.009 ug/L -1-0.009 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.015 ug/L -10.015 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 51 50 102ug/L -11585151
Arsenic (As) 50.8 50 102ug/L -11585150.8
Beryllium (Be) 51.7 50 103ug/L -11585151.7
Cadmium (Cd) 50.8 50 102ug/L -11585150.8
Chromium (Cr) 51 50 102ug/L -11585151
Cobalt (Co) 52 50 104ug/L -11585152
Copper (Cu) 52.3 50 105ug/L -11585152.3
Lead (Pb) 50.5 50 101ug/L -11585150.5
Molybdenum (Mo) 52.6 50 105ug/L -11585152.6
Nickel (Ni) 52.1 50 104ug/L -11585152.1
Selenium (Se) 48.2 50 96.3ug/L -11585148.2
Thallium (Tl) Low Level 50.4 50 101ug/L -11585150.4
Vanadium (V) Low Level 50.9 50 102ug/L -11585150.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003492
Antimony (Sb) 50.9 50 102ug/L -13070150.9
Arsenic (As) 51 50 102ug/L -13070151
Beryllium (Be) 51 50 102ug/L -13070151
Cadmium (Cd) 50.3 50 101ug/L -13070150.3
Chromium (Cr) 50.9 50 101ug/L -13070150.9
Cobalt (Co) 51.6 50 101ug/L -13070151.6
Copper (Cu) 52.2 50 104ug/L -13070152.2
Lead (Pb) 50.4 50 101ug/L -13070150.4
Duke Energy Analytical Lab
Page 76 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020488 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003492
Molybdenum (Mo) 53.5 50 105ug/L -13070153.5
Nickel (Ni) 53.5 50 102ug/L -13070153.5
Selenium (Se) 47.3 50 94.4ug/L -13070147.3
Thallium (Tl) Low Level 36.5 50 72.8ug/L -13070136.5
Vanadium (V) Low Level 51.9 50 102ug/L -13070151.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003492
Antimony (Sb) 50.7 50 101 0.528ug/L -13070150.7
Arsenic (As) 50.9 50 101 0.197ug/L -13070150.9
Beryllium (Be) 52.7 50 105 3.27ug/L -13070152.7
Cadmium (Cd) 50.4 50 101 0.363ug/L -13070150.4
Chromium (Cr) 51.1 50 101 0.328ug/L -13070151.1
Cobalt (Co) 51.6 50 101 0.156ug/L -13070151.6
Copper (Cu) 52 50 103 0.398ug/L -13070152
Lead (Pb) 50 50 100 0.747ug/L -13070150
Molybdenum (Mo) 53.2 50 104 0.652ug/L -13070153.2
Nickel (Ni) 53.9 50 103 0.758ug/L -13070153.9
Selenium (Se) 47.2 50 94.3 0.0572ug/L -13070147.2
Thallium (Tl) Low Level 37.3 50 74.6 2.41ug/L -13070137.3
Vanadium (V) Low Level 51.7 50 102 0.371ug/L -13070151.7
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003501
Antimony (Sb) 51 50 102ug/L -13070151
Arsenic (As) 53.5 50 103ug/L -13070153.5
Beryllium (Be) 54.2 50 109ug/L -13070154.2
Cadmium (Cd) 50.4 50 101ug/L -13070150.4
Chromium (Cr) 51.1 50 102ug/L -13070151.1
Cobalt (Co) 51.1 50 102ug/L -13070151.1
Copper (Cu) 51.8 50 103ug/L -13070151.8
Lead (Pb) 51 50 102ug/L -13070151
Molybdenum (Mo) 61.6 50 106ug/L -13070161.6
Nickel (Ni) 51.2 50 102ug/L -13070151.2
Selenium (Se) 47.6 50 95.2ug/L -13070147.6
Thallium (Tl) Low Level 35.1 50 70.3ug/L -13070135.1
Vanadium (V) Low Level 51.3 50 102ug/L -13070151.3
Duke Energy Analytical Lab
Page 77 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020488 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003501
Antimony (Sb) 51 50 102 0.0589ug/L -13070151
Arsenic (As) 53.9 50 103 0.746ug/L -13070153.9
Beryllium (Be) 52 50 104 4.13ug/L -13070152
Cadmium (Cd) 50.6 50 101 0.394ug/L -13070150.6
Chromium (Cr) 51 50 102 0.198ug/L -13070151
Cobalt (Co) 51.2 50 102 0.343ug/L -13070151.2
Copper (Cu) 51.8 50 103 0.0484ug/L -13070151.8
Lead (Pb) 50.5 50 101 1.05ug/L -13070150.5
Molybdenum (Mo) 61.5 50 106 0.192ug/L -13070161.5
Nickel (Ni) 51.7 50 103 0.902ug/L -13070151.7
Selenium (Se) 46.4 50 92.9 2.48ug/L -13070146.4
Thallium (Tl) Low Level 35.1 50 70.3 0.0825ug/L -13070135.1
Vanadium (V) Low Level 51.6 50 103 0.506ug/L -13070151.6
Duke Energy Analytical Lab
Page 78 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020490 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.028 ug/L -1-0.028 1 < 1/2 RDL
Arsenic (As) 0.067 ug/L -10.067 1 < 1/2 RDL
Beryllium (Be) -0.011 ug/L -1-0.011 1 < 1/2 RDL
Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL
Chromium (Cr) -0.006 ug/L -1-0.006 1 < 1/2 RDL
Cobalt (Co) 0.001 ug/L -10.001 1 < 1/2 RDL
Copper (Cu) -0.107 ug/L -1-0.107 1 < 1/2 RDL
Lead (Pb) 0.004 ug/L -10.004 1 < 1/2 RDL
Molybdenum (Mo) 0.024 ug/L -10.024 1 < 1/2 RDL
Nickel (Ni) 0.017 ug/L -10.017 1 < 1/2 RDL
Selenium (Se) 0.022 ug/L -10.022 1 < 1/2 RDL
Thallium (Tl) Low Level 0.053 ug/L -10.053 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.119 ug/L -10.119 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 53 50 106ug/L -11585153
Arsenic (As) 52 50 104ug/L -11585152
Beryllium (Be) 55.4 50 111ug/L -11585155.4
Cadmium (Cd) 53.4 50 107ug/L -11585153.4
Chromium (Cr) 53.7 50 107ug/L -11585153.7
Cobalt (Co) 51.5 50 103ug/L -11585151.5
Copper (Cu) 52.3 50 105ug/L -11585152.3
Lead (Pb) 52.7 50 105ug/L -11585152.7
Molybdenum (Mo) 53.8 50 108ug/L -11585153.8
Nickel (Ni) 53.1 50 106ug/L -11585153.1
Selenium (Se) 47.3 50 94.7ug/L -11585147.3
Thallium (Tl) Low Level 51.7 50 103ug/L -11585151.7
Vanadium (V) Low Level 53.7 50 107ug/L -11585153.7
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003488
Antimony (Sb) 51.9 50 104ug/L -13070151.9
Arsenic (As) 51.1 50 102ug/L -13070151.1
Beryllium (Be) 56.1 50 112ug/L -13070156.1
Cadmium (Cd) 51.3 50 103ug/L -13070151.3
Chromium (Cr) 51.5 50 103ug/L -13070151.5
Cobalt (Co) 50.1 50 98.1ug/L -13070150.1
Copper (Cu) 50.4 50 100ug/L -13070150.4
Lead (Pb) 51.3 50 102ug/L -13070151.3
Duke Energy Analytical Lab
Page 79 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020490 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003488
Molybdenum (Mo) 52 50 104ug/L -13070152
Nickel (Ni) 50.8 50 101ug/L -13070150.8
Selenium (Se) 48.5 50 96.6ug/L -13070148.5
Thallium (Tl) Low Level 48.1 50 96.1ug/L -13070148.1
Vanadium (V) Low Level 52.2 50 104ug/L -13070152.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003488
Antimony (Sb) 51.2 50 102 1.28ug/L -13070151.2
Arsenic (As) 50.1 50 99.5 2.01ug/L -13070150.1
Beryllium (Be) 54.6 50 109 2.78ug/L -13070154.6
Cadmium (Cd) 50.8 50 102 0.958ug/L -13070150.8
Chromium (Cr) 51.6 50 103 0.144ug/L -13070151.6
Cobalt (Co) 49.5 50 96.9 1.22ug/L -13070149.5
Copper (Cu) 49.9 50 99 1.07ug/L -13070149.9
Lead (Pb) 50.9 50 102 0.691ug/L -13070150.9
Molybdenum (Mo) 51.9 50 104 0.152ug/L -13070151.9
Nickel (Ni) 50.2 50 99.6 1.24ug/L -13070150.2
Selenium (Se) 47.9 50 95.5 1.14ug/L -13070147.9
Thallium (Tl) Low Level 49.9 50 99.8 3.69ug/L -13070149.9
Vanadium (V) Low Level 52.1 50 103 0.18ug/L -13070152.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003498
Antimony (Sb) 52.7 50 105ug/L -13070152.7
Arsenic (As) 738 50 39.7ug/L -130701738
Beryllium (Be) 55.2 50 110ug/L -13070155.2
Cadmium (Cd) 51.1 50 102ug/L -13070151.1
Chromium (Cr) 51.9 50 103ug/L -13070151.9
Cobalt (Co) 51.2 50 97.1ug/L -13070151.2
Copper (Cu) 48.9 50 97.6ug/L -13070148.9
Lead (Pb) 51.6 50 103ug/L -13070151.6
Molybdenum (Mo) 617 50 193ug/L -130701617
Nickel (Ni) 50.5 50 98.7ug/L -13070150.5
Selenium (Se) 49.4 50 98.2ug/L -13070149.4
Thallium (Tl) Low Level 50.3 50 100ug/L -13070150.3
Vanadium (V) Low Level 56.6 50 105ug/L -13070156.6
Duke Energy Analytical Lab
Page 80 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020490 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003498
Antimony (Sb) 53 50 106 0.567ug/L -13070153
Arsenic (As) 741 50 45.4 13.5ug/L -130701741
Beryllium (Be) 55.9 50 111 1.16ug/L -13070155.9
Cadmium (Cd) 51.8 50 103 1.21ug/L -13070151.8
Chromium (Cr) 52.3 50 104 0.738ug/L -13070152.3
Cobalt (Co) 51.3 50 97.3 0.187ug/L -13070151.3
Copper (Cu) 49.2 50 98.1 0.54ug/L -13070149.2
Lead (Pb) 51.6 50 103 0.00777ug/L -13070151.6
Molybdenum (Mo) 615 50 188 2.22ug/L -130701615
Nickel (Ni) 50.6 50 98.8 0.122ug/L -13070150.6
Selenium (Se) 49 50 97.5 0.744ug/L -13070149
Thallium (Tl) Low Level 51.1 50 102 1.54ug/L -13070151.1
Vanadium (V) Low Level 56.8 50 106 0.404ug/L -13070156.8
Duke Energy Analytical Lab
Page 81 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020125 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17020042 -- 2017003487
TDS 192 1.55mg/L -1192
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17020042 -- 2017003488
TDS 153 2.58mg/L -1153
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17020042 -- 2017003489
TDS 168 1.18mg/L -1168
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 105 100 105mg/L -110901105
Duke Energy Analytical Lab
Page 82 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020421 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.01 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
TOC mg/L -10.021 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 101mg/L -1208014.2
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 91.3 10.2mg/L -1208014.01
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 104mg/L -1208013.13
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 97.5 6.5mg/L -1208013
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 97.8mg/L -1208013.06
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 97.2 0.666mg/L -1208013.05
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 98.9mg/L -1158512.84
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 96.8mg/L -1158512.78
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
TOC 2.87 96.9mg/L -1158512.78
Duke Energy Analytical Lab
Page 83 of 166
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020042
Q17020119 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17010238 -- 2017000970
TSS 8.2 0mg/L -18.2
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17010238 -- 2017000973
TSS 0.6 0mg/L -10.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50.8 50 102mg/L -11090150.8
Duke Energy Analytical Lab
Page 84 of 166
#=CL#
February 10, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92328521
92328521
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17020042
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on February 02, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 47
Duke Energy Analytical Lab
Page 85 of 166
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92328521
J17020042
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 47
Duke Energy Analytical Lab
Page 86 of 166
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92328521
J17020042
Lab ID Sample ID Matrix Date Collected Date Received
92328521001 2017003487 Water 02/01/17 10:10 02/02/17 12:10
92328521002 2017003488 Water 02/01/17 13:15 02/02/17 12:10
92328521003 2017003489 Water 02/01/17 12:10 02/02/17 12:10
92328521004 2017003490 Water 02/01/17 15:30 02/02/17 12:10
92328521005 2017003491 Water 02/01/17 09:40 02/02/17 12:10
92328521006 2017003492 Water 01/31/17 17:26 02/02/17 12:10
92328521007 2017003493 Water 02/01/17 10:36 02/02/17 12:10
92328521008 2017003494 Water 02/01/17 10:40 02/02/17 12:10
92328521009 2017003495 Water 02/01/17 10:40 02/02/17 12:10
92328521010 2017003496 Water 02/01/17 13:44 02/02/17 12:10
92328521011 2017003497 Water 02/01/17 15:21 02/02/17 12:10
92328521012 2017003498 Water 02/01/17 09:36 02/02/17 12:10
92328521013 2017003499 Water 02/01/17 11:07 02/02/17 12:10
92328521014 2017003500 Water 02/01/17 11:25 02/02/17 12:10
92328521015 2017003501 Water 02/01/17 12:51 02/02/17 12:10
92328521016 2017003502 Water 02/01/17 14:06 02/02/17 12:10
92328521017 2017003503 Water 02/01/17 15:30 02/02/17 12:10
92328521018 2017003504 Water 02/01/17 16:06 02/02/17 12:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 47
Duke Energy Analytical Lab
Page 87 of 166
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92328521
J17020042
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92328521001 2017003487 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521002 2017003488 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521003 2017003489 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521004 2017003490 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521005 2017003491 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521006 2017003492 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-ADMN
EPA 218.7 1 PASI-OAEM
92328521007 2017003493 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521008 2017003494 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521009 2017003495 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521010 2017003496 RSK 175 Modified 1 PASI-CWDV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 47
Duke Energy Analytical Lab
Page 88 of 166
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92328521
J17020042
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521011 2017003497 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521012 2017003498 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521013 2017003499 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521014 2017003500 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521015 2017003501 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521016 2017003502 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521017 2017003503 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328521018 2017003504 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 47
Duke Energy Analytical Lab
Page 89 of 166
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92328521
J17020042
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92328521001 2017003487
Methane 4230 ug/L 02/07/17 15:37 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)122 mg/L 02/08/17 14:195.0SM 2320B
Alkalinity, Total as CaCO3 122 mg/L 02/08/17 14:195.0SM 2320B
Sulfide 0.20 mg/L 02/04/17 01:290.10SM 4500-S2D
Chromium, Hexavalent 0.36 ug/L 02/08/17 02:55 H30.12EPA 218.7
92328521002 2017003488
Methane 90.4 ug/L 02/07/17 15:52 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)39.0 mg/L 02/08/17 14:345.0SM 2320B
Alkalinity, Total as CaCO3 39.0 mg/L 02/08/17 14:345.0SM 2320B
92328521003 2017003489
Alkalinity,Bicarbonate (CaCO3)76.9 mg/L 02/08/17 15:155.0SM 2320B
Alkalinity, Total as CaCO3 76.9 mg/L 02/08/17 15:155.0SM 2320B
Chromium, Hexavalent 0.29 ug/L 02/08/17 21:000.12EPA 218.7
92328521004 2017003490
Methane 12400 ug/L 02/07/17 17:39 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)301 mg/L 02/08/17 16:125.0SM 2320B
Alkalinity, Total as CaCO3 301 mg/L 02/08/17 16:125.0SM 2320B
Chromium, Hexavalent 0.83 ug/L 02/08/17 21:130.25EPA 218.7
92328521005 2017003491
Methane 85.9 ug/L 02/07/17 17:54 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)32.3 mg/L 02/08/17 16:265.0SM 2320B
Alkalinity, Total as CaCO3 32.3 mg/L 02/08/17 16:265.0SM 2320B
92328521006 2017003492
Methane 342 ug/L 02/07/17 18:10 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)103 mg/L 02/08/17 14:445.0SM 2320B
Alkalinity, Total as CaCO3 103 mg/L 02/08/17 14:445.0SM 2320B
92328521007 2017003493
Methane 36.0 ug/L 02/07/17 18:25 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)23.8 mg/L 02/08/17 16:375.0SM 2320B
Alkalinity, Total as CaCO3 23.8 mg/L 02/08/17 16:375.0SM 2320B
Chromium, Hexavalent 5.7 ug/L 02/08/17 21:521.2EPA 218.7
92328521008 2017003494
Methane 71.0 ug/L 02/07/17 18:40 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)54.9 mg/L 02/08/17 16:475.0SM 2320B
Alkalinity, Total as CaCO3 54.9 mg/L 02/08/17 16:475.0SM 2320B
Chromium, Hexavalent 0.69 ug/L 02/10/17 10:340.12EPA 218.7
92328521009 2017003495
Methane 72.4 ug/L 02/07/17 18:56 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)54.3 mg/L 02/08/17 16:595.0SM 2320B
Alkalinity, Total as CaCO3 54.3 mg/L 02/08/17 16:595.0SM 2320B
Chromium, Hexavalent 0.89 ug/L 02/10/17 11:130.12EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 47
Duke Energy Analytical Lab
Page 90 of 166
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92328521
J17020042
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92328521010 2017003496
Alkalinity,Bicarbonate (CaCO3)52.8 mg/L 02/08/17 17:105.0SM 2320B
Alkalinity, Total as CaCO3 52.8 mg/L 02/08/17 17:105.0SM 2320B
Chromium, Hexavalent 0.29 ug/L 02/10/17 11:260.12EPA 218.7
92328521011 2017003497
Alkalinity,Bicarbonate (CaCO3)70.5 mg/L 02/08/17 17:225.0SM 2320B
Alkalinity, Total as CaCO3 70.5 mg/L 02/08/17 17:225.0SM 2320B
Chromium, Hexavalent 0.62 ug/L 02/10/17 11:390.12EPA 218.7
92328521012 2017003498
Methane 16600 ug/L 02/07/17 19:42 M1,N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)449 mg/L 02/08/17 17:345.0SM 2320B
Alkalinity, Total as CaCO3 449 mg/L 02/08/17 17:345.0SM 2320B
92328521013 2017003499
Methane 6970 ug/L 02/07/17 20:12 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)294 mg/L 02/08/17 18:035.0SM 2320B
Alkalinity, Carbonate (CaCO3)20.3 mg/L 02/08/17 18:035.0SM 2320B
Alkalinity, Total as CaCO3 315 mg/L 02/08/17 18:035.0SM 2320B
92328521014 2017003500
Methane 53600 ug/L 02/09/17 07:36 N2100RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)552 mg/L 02/08/17 18:405.0SM 2320B
Alkalinity, Total as CaCO3 552 mg/L 02/08/17 18:40 M15.0SM 2320B
Chromium, Hexavalent 3.8 ug/L 02/09/17 11:03 P41.2EPA 218.7
92328521015 2017003501
Methane 847 ug/L 02/07/17 20:58 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)269 mg/L 02/08/17 20:005.0SM 2320B
Alkalinity, Total as CaCO3 269 mg/L 02/08/17 20:005.0SM 2320B
Chromium, Hexavalent 0.94 ug/L 02/09/17 11:160.25EPA 218.7
92328521016 2017003502
Methane 535 ug/L 02/07/17 21:13 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)243 mg/L 02/08/17 20:135.0SM 2320B
Alkalinity, Total as CaCO3 243 mg/L 02/08/17 20:135.0SM 2320B
Sulfide 0.17 mg/L 02/04/17 01:510.10SM 4500-S2D
Chromium, Hexavalent 0.26 ug/L 02/09/17 11:290.12EPA 218.7
92328521017 2017003503
Methane 10700 ug/L 02/07/17 21:29 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)135 mg/L 02/08/17 20:275.0SM 2320B
Alkalinity, Total as CaCO3 135 mg/L 02/08/17 20:275.0SM 2320B
Chromium, Hexavalent 6.0 ug/L 02/09/17 11:421.2EPA 218.7
92328521018 2017003504
Methane 140 ug/L 02/07/17 21:44 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)34.4 mg/L 02/08/17 20:405.0SM 2320B
Alkalinity, Total as CaCO3 34.4 mg/L 02/08/17 20:405.0SM 2320B
Chromium, Hexavalent 0.27 ug/L 02/09/17 11:55 P40.12EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 47
Duke Energy Analytical Lab
Page 91 of 166
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328521
J17020042
Method:
Client:Duke Energy
RSK 175 Modified
Date:February 10, 2017
Description:RSK 175 Headspace
General Information:
18 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below
or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 347229
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92328521012
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1926060)
• Methane
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 47
Duke Energy Analytical Lab
Page 92 of 166
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328521
J17020042
Method:
Client:Duke Energy
SM 2320B
Date:February 10, 2017
Description:2320B Alkalinity
General Information:
18 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 347333
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92328521003,92328521014
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1926728)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 47
Duke Energy Analytical Lab
Page 93 of 166
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328521
J17020042
Method:
Client:Duke Energy
SM 4500-S2D
Date:February 10, 2017
Description:4500S2D Sulfide Water
General Information:
18 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 47
Duke Energy Analytical Lab
Page 94 of 166
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328521
J17020042
Method:
Client:Duke Energy
EPA 218.7
Date:February 10, 2017
Description:Hexavalent Chromium by IC
General Information:
18 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
P4: Sample field preservation does not meet EPA or method recommendations for this analysis.
• 2017003500 (Lab ID: 92328521014)
• 2017003504 (Lab ID: 92328521018)
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H3: Sample was received or analysis requested beyond the recognized method holding time.
• 2017003487 (Lab ID: 92328521001)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 349403
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2017003488 (Lab ID: 92328521002)
• Chromium, Hexavalent
• 2017003491 (Lab ID: 92328521005)
• Chromium, Hexavalent
• 2017003492 (Lab ID: 92328521006)
• Chromium, Hexavalent
• 2017003498 (Lab ID: 92328521012)
• Chromium, Hexavalent
• 2017003499 (Lab ID: 92328521013)
• Chromium, Hexavalent
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 47
Duke Energy Analytical Lab
Page 95 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003487 Lab ID:92328521001 Collected:02/01/17 10:10 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 4230 ug/L 02/07/17 15:37 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)122 mg/L 02/08/17 14:195.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 14:195.0 1
Alkalinity, Total as CaCO3 122 mg/L 02/08/17 14:195.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide 0.20 mg/L 02/04/17 01:29 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.36 ug/L 02/08/17 02:55 18540-29-9 H30.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 47
Duke Energy Analytical Lab
Page 96 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003488 Lab ID:92328521002 Collected:02/01/17 13:15 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 90.4 ug/L 02/07/17 15:52 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)39.0 mg/L 02/08/17 14:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 14:345.0 1
Alkalinity, Total as CaCO3 39.0 mg/L 02/08/17 14:345.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:29 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/08/17 20:21 18540-29-9 D30.50 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 47
Duke Energy Analytical Lab
Page 97 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003489 Lab ID:92328521003 Collected:02/01/17 12:10 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/07/17 16:08 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)76.9 mg/L 02/08/17 15:155.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 15:155.0 1
Alkalinity, Total as CaCO3 76.9 mg/L 02/08/17 15:155.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:29 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.29 ug/L 02/08/17 21:00 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 47
Duke Energy Analytical Lab
Page 98 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003490 Lab ID:92328521004 Collected:02/01/17 15:30 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 12400 ug/L 02/07/17 17:39 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)301 mg/L 02/08/17 16:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 16:125.0 1
Alkalinity, Total as CaCO3 301 mg/L 02/08/17 16:125.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:29 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.83 ug/L 02/08/17 21:13 18540-29-90.25 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 47
Duke Energy Analytical Lab
Page 99 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003491 Lab ID:92328521005 Collected:02/01/17 09:40 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 85.9 ug/L 02/07/17 17:54 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)32.3 mg/L 02/08/17 16:265.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 16:265.0 1
Alkalinity, Total as CaCO3 32.3 mg/L 02/08/17 16:265.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:29 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/08/17 21:26 18540-29-9 D30.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 47
Duke Energy Analytical Lab
Page 100 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003492 Lab ID:92328521006 Collected:01/31/17 17:26 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 342 ug/L 02/07/17 18:10 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)103 mg/L 02/08/17 14:445.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 14:445.0 1
Alkalinity, Total as CaCO3 103 mg/L 02/08/17 14:445.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/03/17 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/08/17 21:39 18540-29-9 D30.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 47
Duke Energy Analytical Lab
Page 101 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003493 Lab ID:92328521007 Collected:02/01/17 10:36 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 36.0 ug/L 02/07/17 18:25 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)23.8 mg/L 02/08/17 16:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 16:375.0 1
Alkalinity, Total as CaCO3 23.8 mg/L 02/08/17 16:375.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:29 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 5.7 ug/L 02/08/17 21:52 18540-29-91.2 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 47
Duke Energy Analytical Lab
Page 102 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003494 Lab ID:92328521008 Collected:02/01/17 10:40 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 71.0 ug/L 02/07/17 18:40 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)54.9 mg/L 02/08/17 16:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 16:475.0 1
Alkalinity, Total as CaCO3 54.9 mg/L 02/08/17 16:475.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:29 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.69 ug/L 02/10/17 10:34 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 47
Duke Energy Analytical Lab
Page 103 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003495 Lab ID:92328521009 Collected:02/01/17 10:40 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 72.4 ug/L 02/07/17 18:56 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)54.3 mg/L 02/08/17 16:595.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 16:595.0 1
Alkalinity, Total as CaCO3 54.3 mg/L 02/08/17 16:595.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.89 ug/L 02/10/17 11:13 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 47
Duke Energy Analytical Lab
Page 104 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003496 Lab ID:92328521010 Collected:02/01/17 13:44 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/07/17 19:11 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)52.8 mg/L 02/08/17 17:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 17:105.0 1
Alkalinity, Total as CaCO3 52.8 mg/L 02/08/17 17:105.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.29 ug/L 02/10/17 11:26 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 47
Duke Energy Analytical Lab
Page 105 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003497 Lab ID:92328521011 Collected:02/01/17 15:21 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/07/17 19:26 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)70.5 mg/L 02/08/17 17:225.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 17:225.0 1
Alkalinity, Total as CaCO3 70.5 mg/L 02/08/17 17:225.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.62 ug/L 02/10/17 11:39 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 47
Duke Energy Analytical Lab
Page 106 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003498 Lab ID:92328521012 Collected:02/01/17 09:36 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 16600 ug/L 02/07/17 19:42 74-82-8 M1,N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)449 mg/L 02/08/17 17:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 17:345.0 1
Alkalinity, Total as CaCO3 449 mg/L 02/08/17 17:345.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/09/17 10:11 18540-29-9 D30.50 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 47
Duke Energy Analytical Lab
Page 107 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003499 Lab ID:92328521013 Collected:02/01/17 11:07 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 6970 ug/L 02/07/17 20:12 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)294 mg/L 02/08/17 18:035.0 1
Alkalinity, Carbonate (CaCO3)20.3 mg/L 02/08/17 18:035.0 1
Alkalinity, Total as CaCO3 315 mg/L 02/08/17 18:035.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/09/17 10:50 18540-29-9 D30.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 47
Duke Energy Analytical Lab
Page 108 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003500 Lab ID:92328521014 Collected:02/01/17 11:25 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 53600 ug/L 02/09/17 07:36 74-82-8 N210010
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)552 mg/L 02/08/17 18:405.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 18:405.0 1
Alkalinity, Total as CaCO3 552 mg/L 02/08/17 18:40 M15.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 3.8 ug/L 02/09/17 11:03 18540-29-9 P41.2 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 47
Duke Energy Analytical Lab
Page 109 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003501 Lab ID:92328521015 Collected:02/01/17 12:51 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 847 ug/L 02/07/17 20:58 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)269 mg/L 02/08/17 20:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 20:005.0 1
Alkalinity, Total as CaCO3 269 mg/L 02/08/17 20:005.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.94 ug/L 02/09/17 11:16 18540-29-90.25 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 47
Duke Energy Analytical Lab
Page 110 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003502 Lab ID:92328521016 Collected:02/01/17 14:06 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 535 ug/L 02/07/17 21:13 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)243 mg/L 02/08/17 20:135.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 20:135.0 1
Alkalinity, Total as CaCO3 243 mg/L 02/08/17 20:135.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide 0.17 mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.26 ug/L 02/09/17 11:29 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 47
Duke Energy Analytical Lab
Page 111 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003503 Lab ID:92328521017 Collected:02/01/17 15:30 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 10700 ug/L 02/07/17 21:29 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)135 mg/L 02/08/17 20:275.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 20:275.0 1
Alkalinity, Total as CaCO3 135 mg/L 02/08/17 20:275.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 6.0 ug/L 02/09/17 11:42 18540-29-91.2 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 47
Duke Energy Analytical Lab
Page 112 of 166
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328521
J17020042
Sample:2017003504 Lab ID:92328521018 Collected:02/01/17 16:06 Received:02/02/17 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 140 ug/L 02/07/17 21:44 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)34.4 mg/L 02/08/17 20:405.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/08/17 20:405.0 1
Alkalinity, Total as CaCO3 34.4 mg/L 02/08/17 20:405.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/04/17 01:51 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.27 ug/L 02/09/17 11:55 18540-29-9 P40.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 47
Duke Energy Analytical Lab
Page 113 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347228
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92328521001, 92328521002, 92328521003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1926054
Associated Lab Samples:92328521001, 92328521002, 92328521003
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N202/07/17 11:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1926055LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 361 N23969170-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1926056MATRIX SPIKE SAMPLE:
MSSpike
Result
92328411018
Methane ug/L 426 N239610870-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92328411020
1926057SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 47
Duke Energy Analytical Lab
Page 114 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347229
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92328521004, 92328521005, 92328521006, 92328521007, 92328521008, 92328521009, 92328521010,
92328521011, 92328521012, 92328521013, 92328521014, 92328521015, 92328521016, 92328521017,
92328521018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1926058
Associated Lab Samples:92328521004, 92328521005, 92328521006, 92328521007, 92328521008, 92328521009, 92328521010,
92328521011, 92328521012, 92328521013, 92328521014, 92328521015, 92328521016, 92328521017,
92328521018
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N202/07/17 17:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1926059LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 367 N23969370-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1926060MATRIX SPIKE SAMPLE:
MSSpike
Result
92328521012
Methane ug/L 16100 M1,N2396-143 70-13016600
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92328521013
1926061SAMPLE DUPLICATE:
Methane ug/L 6610 N25206970
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 47
Duke Energy Analytical Lab
Page 115 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347332
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92328521001, 92328521002, 92328521006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1926718
Associated Lab Samples:92328521001, 92328521002, 92328521006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 02/08/17 09:44
Alkalinity, Total as CaCO3 mg/L ND 5.0 02/08/17 09:44
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 02/08/17 09:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1926719LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.950 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1926720MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328411010
1926721
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 93 80-12090 2 255014.0 60.4 59.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1926722MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328411020
1926723
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120100 0 25509.8 59.7 59.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 47
Duke Energy Analytical Lab
Page 116 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347333
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92328521003, 92328521004, 92328521005, 92328521007, 92328521008, 92328521009, 92328521010,
92328521011, 92328521012, 92328521013, 92328521014, 92328521015, 92328521016, 92328521017,
92328521018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1926724
Associated Lab Samples:92328521003, 92328521004, 92328521005, 92328521007, 92328521008, 92328521009, 92328521010,
92328521011, 92328521012, 92328521013, 92328521014, 92328521015, 92328521016, 92328521017,
92328521018
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 02/08/17 14:57
Alkalinity, Total as CaCO3 mg/L ND 5.0 02/08/17 14:57
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 02/08/17 14:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1926725LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.850 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1926726MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521003
1926727
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120100 0 255076.9 127 127
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1926728MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521014
1926729
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M15012380-120104 2 2550552614604
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 47
Duke Energy Analytical Lab
Page 117 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
346896
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92328521006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1924239
Associated Lab Samples:92328521006
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 02/03/17 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1924240LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.53.5 107 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924241MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328387008
1924242
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 100 80-120100 0 10.5ND 0.50 0.50
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924243MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328387009
1924244
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 101 80-120101 0 10.5ND 0.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 47
Duke Energy Analytical Lab
Page 118 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
346947
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92328521001, 92328521002, 92328521003, 92328521004, 92328521005, 92328521007, 92328521008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1924773
Associated Lab Samples:92328521001, 92328521002, 92328521003, 92328521004, 92328521005, 92328521007, 92328521008
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 02/04/17 01:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1924774LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.53.5 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924775MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328339028
1924776
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 94 80-12095 0 10.5ND 0.47 0.48
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924777MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328411024
1924778
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 97 80-12097 0 10.5ND 0.49 0.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 47
Duke Energy Analytical Lab
Page 119 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
346948
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92328521009, 92328521010, 92328521011, 92328521012, 92328521013, 92328521014, 92328521015,
92328521016, 92328521017, 92328521018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1924779
Associated Lab Samples:92328521009, 92328521010, 92328521011, 92328521012, 92328521013, 92328521014, 92328521015,
92328521016, 92328521017, 92328521018
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 02/04/17 01:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1924780LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.53.5 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924781MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521009
1924782
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 99 80-12099 0 10.5ND 0.50 0.50
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924783MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328553001
1924784
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 92 80-12092 0 10.5ND 0.47 0.47
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 47
Duke Energy Analytical Lab
Page 120 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349143
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92328521001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1875595
Associated Lab Samples:92328521001
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 02/08/17 12:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1875596LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.079.075 105 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1875597MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328387006
1875598
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 98 85-115104 5 20.075ND 0.085 0.089
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 47
Duke Energy Analytical Lab
Page 121 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349403
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92328521002, 92328521003, 92328521004, 92328521005, 92328521006, 92328521007, 92328521012,
92328521013, 92328521014, 92328521015, 92328521016, 92328521017, 92328521018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1877133
Associated Lab Samples:92328521002, 92328521003, 92328521004, 92328521005, 92328521006, 92328521007, 92328521012,
92328521013, 92328521014, 92328521015, 92328521016, 92328521017, 92328521018
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 02/08/17 19:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1877134LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1877135MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521002
1877136
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L 1.5 111 85-115115 3 201.5ND 1.8 1.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1877137MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521012
1877138
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .5 101 85-115111 9 20.5ND 0.51 0.56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 47
Duke Energy Analytical Lab
Page 122 of 166
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328521
J17020042
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349682
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92328521008, 92328521009, 92328521010, 92328521011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1879103
Associated Lab Samples:92328521008, 92328521009, 92328521010, 92328521011
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 02/10/17 10:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1879104LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.071.075 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1879105MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328521008
1879106
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .38 105 85-115103 1 20.380.69 1.1 1.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 47
Duke Energy Analytical Lab
Page 123 of 166
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92328521
J17020042
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter.N2
Sample field preservation does not meet EPA or method recommendations for this analysis.P4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 47
Duke Energy Analytical Lab
Page 124 of 166
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92328521
J17020042
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92328521001 3472282017003487RSK 175 Modified
92328521002 3472282017003488RSK 175 Modified
92328521003 3472282017003489RSK 175 Modified
92328521004 3472292017003490RSK 175 Modified
92328521005 3472292017003491RSK 175 Modified
92328521006 3472292017003492RSK 175 Modified
92328521007 3472292017003493RSK 175 Modified
92328521008 3472292017003494RSK 175 Modified
92328521009 3472292017003495RSK 175 Modified
92328521010 3472292017003496RSK 175 Modified
92328521011 3472292017003497RSK 175 Modified
92328521012 3472292017003498RSK 175 Modified
92328521013 3472292017003499RSK 175 Modified
92328521014 3472292017003500RSK 175 Modified
92328521015 3472292017003501RSK 175 Modified
92328521016 3472292017003502RSK 175 Modified
92328521017 3472292017003503RSK 175 Modified
92328521018 3472292017003504RSK 175 Modified
92328521001 3473322017003487SM 2320B
92328521002 3473322017003488SM 2320B
92328521003 3473332017003489SM 2320B
92328521004 3473332017003490SM 2320B
92328521005 3473332017003491SM 2320B
92328521006 3473322017003492SM 2320B
92328521007 3473332017003493SM 2320B
92328521008 3473332017003494SM 2320B
92328521009 3473332017003495SM 2320B
92328521010 3473332017003496SM 2320B
92328521011 3473332017003497SM 2320B
92328521012 3473332017003498SM 2320B
92328521013 3473332017003499SM 2320B
92328521014 3473332017003500SM 2320B
92328521015 3473332017003501SM 2320B
92328521016 3473332017003502SM 2320B
92328521017 3473332017003503SM 2320B
92328521018 3473332017003504SM 2320B
92328521001 3469472017003487SM 4500-S2D
92328521002 3469472017003488SM 4500-S2D
92328521003 3469472017003489SM 4500-S2D
92328521004 3469472017003490SM 4500-S2D
92328521005 3469472017003491SM 4500-S2D
92328521006 3468962017003492SM 4500-S2D
92328521007 3469472017003493SM 4500-S2D
92328521008 3469472017003494SM 4500-S2D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 47
Duke Energy Analytical Lab
Page 125 of 166
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92328521
J17020042
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92328521009 3469482017003495SM 4500-S2D
92328521010 3469482017003496SM 4500-S2D
92328521011 3469482017003497SM 4500-S2D
92328521012 3469482017003498SM 4500-S2D
92328521013 3469482017003499SM 4500-S2D
92328521014 3469482017003500SM 4500-S2D
92328521015 3469482017003501SM 4500-S2D
92328521016 3469482017003502SM 4500-S2D
92328521017 3469482017003503SM 4500-S2D
92328521018 3469482017003504SM 4500-S2D
92328521001 3491432017003487EPA 218.7
92328521002 3494032017003488EPA 218.7
92328521003 3494032017003489EPA 218.7
92328521004 3494032017003490EPA 218.7
92328521005 3494032017003491EPA 218.7
92328521006 3494032017003492EPA 218.7
92328521007 3494032017003493EPA 218.7
92328521008 3496822017003494EPA 218.7
92328521009 3496822017003495EPA 218.7
92328521010 3496822017003496EPA 218.7
92328521011 3496822017003497EPA 218.7
92328521012 3494032017003498EPA 218.7
92328521013 3494032017003499EPA 218.7
92328521014 3494032017003500EPA 218.7
92328521015 3494032017003501EPA 218.7
92328521016 3494032017003502EPA 218.7
92328521017 3494032017003503EPA 218.7
92328521018 3494032017003504EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/10/2017 05:26 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 47
Duke Energy Analytical Lab
Page 126 of 166
Page 43 of 47
Duke Energy Analytical Lab
Page 127 of 166
Page 44 of 47
Duke Energy Analytical Lab
Page 128 of 166
Page 45 of 47
Duke Energy Analytical Lab
Page 129 of 166
Page 46 of 47
Duke Energy Analytical Lab
Page 130 of 166
Page 47 of 47
Duke Energy Analytical Lab
Page 131 of 166

February 28, 2017

Anne Pridgeon
Duke Energy
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment
Work Order: 415701
SDG: J17020042

Dear Anne Pridgeon:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on February 03, 2017. This original data report has been prepared and reviewed in
accordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 5015714
Enclosures
Page 1 of 33
Chelsea Seagle for
Duke Energy Analytical Lab
Page 132 of 166
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO004 Duke Energy Carolinas, LLC <BR> (PO 5015714)
Client SDG: J17020042 GEL Work Order: 415701
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 33
Duke Energy Analytical Lab
Page 133 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636784
1636784
1638008
1637831
0819
0852
1034
0700
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/15/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701001
Ground Water
01-FEB-17 10:10
03-FEB-17
2017003487 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.751
0.691
1
2
3
4
U
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.5 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367811148SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 33
Duke Energy Analytical Lab
Page 134 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636784
1636784
1638008
1637831
0821
0853
1034
0700
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/15/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701002
Ground Water
01-FEB-17 13:15
03-FEB-17
2017003488 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.683
0.306
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
0.719
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"94.2 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367811148SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 33
Duke Energy Analytical Lab
Page 135 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636784
1636784
1638008
1637831
1430
0858
1034
0700
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/16/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701003
Ground Water
01-FEB-17 12:10
03-FEB-17
2017003489 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.547
0.613
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000357
ND
ND
ND
ND
0.894
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"88.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367811148SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 33
Duke Energy Analytical Lab
Page 136 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636784
1636784
1638008
1637831
0828
0859
1034
0700
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/15/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.001
0.00005
0.00005
0.00005
1.00
1.00
5
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701004
Ground Water
01-FEB-17 15:30
03-FEB-17
2017003490 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000335
0.00001
0.00001
0.00001
0.492
0.810
1
2
3
4
U
J
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.134
ND
0.00001
ND
1.00
0.953
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"88.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367811148SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 33
Duke Energy Analytical Lab
Page 137 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636784
1636784
1638008
1637831
0830
0901
1034
0700
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/15/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701005
Ground Water
01-FEB-17 09:40
03-FEB-17
2017003491 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.524
0.595
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
0.525
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"93.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367811148SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 7 of 33
Duke Energy Analytical Lab
Page 138 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636784
1636784
1638008
1637831
0831
0902
1034
0700
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/15/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701006
Ground Water
31-JAN-17 17:26
03-FEB-17
2017003492 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.563
0.791
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00041
ND
ND
ND
1.59
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"83.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367811148SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 8 of 33
Duke Energy Analytical Lab
Page 139 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636784
1636784
1638008
1637831
1431
0904
1034
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/16/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701007
Ground Water
01-FEB-17 10:36
03-FEB-17
2017003493 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.654
0.496
1
2
3
4
J
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000112
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"95.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367811148SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 9 of 33
Duke Energy Analytical Lab
Page 140 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1036
1008
1039
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701008
Ground Water
01-FEB-17 10:40
03-FEB-17
2017003494 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.586
0.444
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000146
ND
ND
ND
ND
0.835
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 10 of 33
Duke Energy Analytical Lab
Page 141 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1045
1014
1039
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701009
Ground Water
01-FEB-17 10:40
03-FEB-17
2017003495 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.570
0.621
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000167
ND
ND
ND
ND
1.22
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"95 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 11 of 33
Duke Energy Analytical Lab
Page 142 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1047
1019
1039
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701010
Ground Water
01-FEB-17 13:44
03-FEB-17
2017003496 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.658
0.753
1
2
3
4
U
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.5 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 12 of 33
Duke Energy Analytical Lab
Page 143 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1048
1020
1039
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701011
Ground Water
01-FEB-17 15:21
03-FEB-17
2017003497 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.468
0.456
1
2
3
4
J
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000948
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"96.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 13 of 33
Duke Energy Analytical Lab
Page 144 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1050
1022
1039
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701012
Ground Water
01-FEB-17 09:36
03-FEB-17
2017003498 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.480
0.651
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00214
ND
ND
ND
ND
1.07
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"89.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 14 of 33
Duke Energy Analytical Lab
Page 145 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1051
1023
1039
0825
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701013
Ground Water
01-FEB-17 11:07
03-FEB-17
2017003499 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.525
0.505
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00347
ND
ND
ND
ND
0.615
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"91.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 15 of 33
Duke Energy Analytical Lab
Page 146 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1055
1028
1039
0825
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701014
Ground Water
01-FEB-17 11:25
03-FEB-17
2017003500 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.614
0.559
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000469
ND
ND
ND
1.19
0.776
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"89.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 16 of 33
Duke Energy Analytical Lab
Page 147 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1057
1030
1039
0825
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701015
Ground Water
01-FEB-17 12:51
03-FEB-17
2017003501 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.386
0.766
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00256
ND
ND
ND
0.593
1.56
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"89 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 17 of 33
Duke Energy Analytical Lab
Page 148 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1058
1031
1042
0825
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701016
Ground Water
01-FEB-17 14:06
03-FEB-17
2017003502 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.378
0.387
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00027
ND
ND
ND
1.72
2.55
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"99.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 18 of 33
Duke Energy Analytical Lab
Page 149 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1100
1033
1042
0825
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701017
Ground Water
01-FEB-17 15:30
03-FEB-17
2017003503 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.734
0.350
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000734
ND
ND
ND
ND
0.511
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"81.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 19 of 33
Duke Energy Analytical Lab
Page 150 of 166
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 28, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1636788
1636788
1638008
1637831
1101
1034
1042
0825
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/17/17
02/16/17
02/17/17
02/23/17
SKJ
SKJ
AXM6
MXH8
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415701018
Ground Water
01-FEB-17 16:06
03-FEB-17
2017003504 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.473
0.741
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.21
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"82.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/06/17 16367871151SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 20 of 33
Duke Energy Analytical Lab
Page 151 of 166
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1636784Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Parmname
Anne PridgeonContact:
Duke Energy
13339 Hagers Ferry Road
Huntersville, North Carolina
February 28, 2017Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
Anlst Date Time
SKJ 02/16/17 08:39
02/14/17 08:50
02/14/17 08:47
02/16/17 08:36
02/16/17 08:35
02/14/17 08:46
QC
ND
ND
ND
ND
0.0492
0.00053
0.000646
0.00512
ND
ND
ND
ND
NOM Sample
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
U
U
U
U
U
U
U
U
QC1203721966 415703001
QC1203721965
QC1203721972
QC1203721964
N/A
N/A
N/A
N/A
REC%
99
106
117
102
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
415701Workorder:
Mail Code: MGO3A2
U
U
U
U
RPD%
Page 1 of 5
Page 21 of 33
Duke Energy Analytical Lab
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1636784
1636788
Batch
Batch
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Parmname Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
ug/L
ug/L
ug/L
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
Anlst Date Time
SKJ
SKJ
02/14/17 08:52
02/16/17 08:41
02/16/17 08:42
02/14/17 08:53
02/16/17 10:10
02/17/17 10:38
02/17/17 10:35
QC
0.0479
0.000543
0.000638
0.0052
ND
ND
ND
ND
ND
ND
ND
0.000116
0.0547
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.000146
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-10%)
(0%-10%)
(+/-0.0002)
(80%-120%)
Qual
U
U
U
U
U
U
U
J
QC1203721967 415703001
QC1203721973 415703001
QC1203721968 415703001
QC1203721979 415701008
QC1203721978
N/A
N/A
N/A
N/A
N/A
N/A
N/A
23
REC%
96.5
109
116
104
110
0.0496
0.0005
0.00055
0.005
0.0496
MS
MS
SDILT
DUP
LCS
415701Workorder:
U
U
U
U
U
U
U
U
U
U
U
J ^
RPD%
Page 2 of 5
Page 22 of 33
Duke Energy Analytical Lab
Page 153 of 166
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1636788Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Parmname Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
ug/L
ug/L
Anlst Date Time
SKJ 02/16/17 10:06
02/16/17 10:05
02/17/17 10:33
02/17/17 10:39
02/16/17 10:11
02/16/17 10:13
QC
0.000535
0.000646
0.00509
ND
ND
ND
0.0000928
0.055
0.000512
0.000634
0.00504
ND
ND
ND
NOM Sample
0.000146
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-10%)
Qual
U
U
U
J
U
U
U
QC1203721982
QC1203721977
QC1203721980 415701008
QC1203721983 415701008
QC1203721981 415701008
N/A
N/A
N/A
REC%
107
117
102
111
102
115
101
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
LCS
MB
MS
MS
SDILT
415701Workorder:
J
U
U
U
U
U
U
RPD%
Page 3 of 5
Page 23 of 33
Duke Energy Analytical Lab
Page 154 of 166
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1636788
1638008
1637831
Batch
Batch
Batch
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
MXH8
02/17/17 10:41
02/17/17 10:42
02/17/17 10:42
02/17/17 10:42
02/23/17 09:05
02/23/17 09:05
02/23/17 09:05
02/23/17 09:05
QC
0.0794
0.164
5.53
0.145
0.697
30.3
0.305
121
NOM Sample
0.146
0.297
0.684
0.684
Range
(0%-10%)
N/A
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
J
U
U
U
QC1203725029 415701018
QC1203725030
QC1203725028
QC1203724508 415701001
QC1203724510
QC1203724507
QC1203724509 415701001
The Qualifiers in this report are defined as follows:
173
N/A
1.96
REC%
79
117
92.8
7.00
26.0
130
DUP
LCS
MB
DUP
LCS
MB
MS
415701Workorder:
**
<
>
BD
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
J
U
U
U
RPD%
Notes:
Page 4 of 5
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Duke Energy Analytical Lab
Page 155 of 166
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 5 of 5
Units Anlst Date TimeQCNOMSampleRangeQualREC%
415701Workorder:
E
FA
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Page 26 of 33
Duke Energy Analytical Lab
Page 157 of 166
Page 27 of 33
Duke Energy Analytical Lab
Page 158 of 166
Page 28 of 33
Duke Energy Analytical Lab
Page 159 of 166

Technical Case Narrative
Duke Energy Carolinas, LLC
(DUPC)
SDG #: J17020042
Work Order #: 415701

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1636784

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1636781
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415701001 2017003487
415701002 2017003488
415701003 2017003489
415701004 2017003490
415701005 2017003491
415701006 2017003492
415701007 2017003493
1203721964 Method Blank (MB)ICP-MS
1203721965 Laboratory Control Sample (LCS)
1203721972 Laboratory Control Sample (LCS)
1203721968 415703001(2017003472L) Serial Dilution (SD)
1203721966 415703001(2017003472D) Sample Duplicate (DUP)
1203721967 415703001(2017003472S) Matrix Spike (MS)
1203721973 415703001(2017003472S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Calibration Information

CRDL/PQL Requirements
The CRDL standard recoveries for SW846 6020A/6020B met the advisory control limits with the exception of
uranium-238. Client sample concentrations were less than the MDL or greater than two times the PQL; therefore
the data were not adversely affected. 415701001 (2017003487), 415701002 (2017003488), 415701004
(2017003490), 415701005 (2017003491) and 415701006 (2017003492).

Technical Information

Page 29 of 33
Duke Energy Analytical Lab
Page 160 of 166
Sample Dilutions
Dilutions may be required for many reasons, including to minimize matrix interferences or to bring over range
target analyte concentrations into the linear calibration range. Sample 415701004 (2017003490) was diluted to
ensure that the analyte concentration was within the linear calibration range of the instrument.
Analyte
415701
004
Uranium-238 5X

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1636788

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1636787
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415701008 2017003494
415701009 2017003495
415701010 2017003496
415701011 2017003497
415701012 2017003498
415701013 2017003499
415701014 2017003500
415701015 2017003501
415701016 2017003502
415701017 2017003503
415701018 2017003504
1203721977 Method Blank (MB)ICP-MS
1203721978 Laboratory Control Sample (LCS)
1203721982 Laboratory Control Sample (LCS)
1203721981 415701008(2017003494L) Serial Dilution (SD)
1203721979 415701008(2017003494D) Sample Duplicate (DUP)
1203721980 415701008(2017003494S) Matrix Spike (MS)
1203721983 415701008(2017003494S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry
Page 30 of 33
Duke Energy Analytical Lab
Page 161 of 166

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1638008
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415701001 2017003487
415701002 2017003488
415701003 2017003489
415701004 2017003490
415701005 2017003491
415701006 2017003492
415701007 2017003493
415701008 2017003494
415701009 2017003495
415701010 2017003496
415701011 2017003497
415701012 2017003498
415701013 2017003499
415701014 2017003500
415701015 2017003501
415701016 2017003502
415701017 2017003503
415701018 2017003504
1203725028 Method Blank (MB)
1203725029 415701018(2017003504) Sample Duplicate (DUP)
1203725030 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1637831
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415701001 2017003487
415701002 2017003488
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Duke Energy Analytical Lab
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415701003 2017003489
415701004 2017003490
415701005 2017003491
415701006 2017003492
415701007 2017003493
415701008 2017003494
415701009 2017003495
415701010 2017003496
415701011 2017003497
415701012 2017003498
415701013 2017003499
415701014 2017003500
415701015 2017003501
415701016 2017003502
415701017 2017003503
415701018 2017003504
1203724507 Method Blank (MB)
1203724508 415701001(2017003487) Sample Duplicate (DUP)
1203724509 415701001(2017003487) Matrix Spike (MS)
1203724510 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203724509 (2017003487MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 32 of 33
Duke Energy Analytical Lab
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA170010
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-17-12
SC000122016-21
VT87156
460202
C780
997404
List of current GEL Certifications as of 28 February 2017
Page 33 of 33
Duke Energy Analytical Lab
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Duke Energy Analytical Lab
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Duke Energy Analytical Lab
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