NC0038377_J17010665report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17010665
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:2/27/2017
Customer Address:Mayo Steam Plant
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, Kim Witt
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 89
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2017003078 MAYO STEAM 30-Jan-17 2:30 PM Alex Lefitz SW-REF1
2017003086 MAYO STEAM 30-Jan-17 1:35 PM Alex Lefitz SW-CBT1
2017003087 MAYO STEAM 30-Jan-17 12:35 PM Alex Lefitz SW-CB1
2017003088 MAYO STEAM 30-Jan-17 1:14 PM Alex Lefitz BG-2
2017003089 MAYO STEAM 30-Jan-17 1:14 PM Alex Lefitz BG-2 DUP
2017003090 MAYO STEAM 30-Jan-17 2:43 PM Alex Lefitz ABMW-4BR
2017003091 MAYO STEAM 30-Jan-17 4:25 PM Alex Lefitz Filter Blank
2017003092 MAYO STEAM 30-Jan-17 4:25 PM Alex Lefitz Equipment Blank
8 Total Samples
Duke Energy Analytical Lab
Page 2 of 89
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:2/27/2017
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003078
Collection Date:30-Jan-17 2:30 PM
Site:SW-REF1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.030 mg-N/L EPA 353.2 02/03/2017 12:26 TLINN0.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.9 mg/L EPA 300.0 01/31/2017 10:38 BGN90340.1 1
Sulfate 7.6 mg/L EPA 300.0 01/31/2017 10:38 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/11/2017 12:06 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/09/2017 13:44 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.010 mg/L EPA 200.7 02/15/2017 14:45 MHALL30.005 1
Barium (Ba)0.025 mg/L EPA 200.7 02/15/2017 14:45 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 14:45 MHALL30.05 1
Iron (Fe)0.177 mg/L EPA 200.7 02/15/2017 14:45 MHALL30.01 1
Manganese (Mn)0.085 mg/L EPA 200.7 02/15/2017 14:45 MHALL30.005 1
Strontium (Sr)0.044 mg/L EPA 200.7 02/15/2017 14:45 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 14:45 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.13 mg/L EPA 200.7 02/17/2017 15:27B2 JJMACKE0.01 1
Magnesium (Mg)2.62 mg/L EPA 200.7 02/17/2017 15:27 JJMACKE0.005 1
Potassium (K)1.39 mg/L EPA 200.7 02/17/2017 15:27 JJMACKE0.1 1
Sodium (Na)7.51 mg/L EPA 200.7 02/17/2017 15:27B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.429 mg/L EPA 200.7 02/06/2017 13:25 MHH71310.005 1
Barium (Ba)0.028 mg/L EPA 200.7 02/06/2017 13:25 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/06/2017 13:25 MHH71310.05 1
Iron (Fe)1.03 mg/L EPA 200.7 02/06/2017 13:25 MHH71310.01 1
Manganese (Mn)0.092 mg/L EPA 200.7 02/06/2017 13:25 MHH71310.005 1
Strontium (Sr)0.046 mg/L EPA 200.7 02/06/2017 13:25 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/06/2017 13:25 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003078
Collection Date:30-Jan-17 2:30 PM
Site:SW-REF1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 18:21 PARMSTR0.2 1
Vanadium (V) Low Level 0.396 ug/L EPA 200.8 02/17/2017 18:21B2 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 20:55 PARMSTR0.2 1
Vanadium (V) Low Level 1.08 ug/L EPA 200.8 02/17/2017 20:55B2 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 82 mg/L SM2540C 02/01/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 5 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003078
Collection Date:30-Jan-17 2:30 PM
Site:SW-REF1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 3.5 mg/L SM5310C/EPA9060A 02/01/2017 14:17 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/01/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 6 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003086
Collection Date:30-Jan-17 1:35 PM
Site:SW-CBT1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/03/2017 12:27 TLINN0.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 300.0 01/31/2017 09:47 BGN90340.5 5
Sulfate 17 mg/L EPA 300.0 01/31/2017 09:47 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/11/2017 12:08 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/09/2017 13:47 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 15:04 MHALL30.005 1
Barium (Ba)0.022 mg/L EPA 200.7 02/15/2017 15:04 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 15:04 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/15/2017 15:04 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/15/2017 15:04 MHALL30.005 1
Strontium (Sr)0.069 mg/L EPA 200.7 02/15/2017 15:04 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 15:04 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.15 mg/L EPA 200.7 02/17/2017 15:41B2 JJMACKE0.01 1
Magnesium (Mg)4.30 mg/L EPA 200.7 02/17/2017 15:41 JJMACKE0.005 1
Potassium (K)1.60 mg/L EPA 200.7 02/17/2017 15:41 JJMACKE0.1 1
Sodium (Na)10.5 mg/L EPA 200.7 02/17/2017 15:41B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.139 mg/L EPA 200.7 02/06/2017 13:37 MHH71310.005 1
Barium (Ba)0.023 mg/L EPA 200.7 02/06/2017 13:37 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/06/2017 13:37 MHH71310.05 1
Iron (Fe)0.096 mg/L EPA 200.7 02/06/2017 13:37 MHH71310.01 1
Manganese (Mn)0.010 mg/L EPA 200.7 02/06/2017 13:37 MHH71310.005 1
Strontium (Sr)0.069 mg/L EPA 200.7 02/06/2017 13:37 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/06/2017 13:37 MHH71310.005 1
Duke Energy Analytical Lab
Page 7 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003086
Collection Date:30-Jan-17 1:35 PM
Site:SW-CBT1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 18:29 PARMSTR0.2 1
Vanadium (V) Low Level 0.325 ug/L EPA 200.8 02/17/2017 18:29B2 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 20:24 PARMSTR0.2 1
Vanadium (V) Low Level 0.347 ug/L EPA 200.8 02/17/2017 20:24B2 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 81 mg/L SM2540C 02/01/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 8 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003086
Collection Date:30-Jan-17 1:35 PM
Site:SW-CBT1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 2.6 mg/L SM5310C/EPA9060A 02/01/2017 14:17 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/01/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 9 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003087
Collection Date:30-Jan-17 12:35 PM
Site:SW-CB1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/03/2017 12:28 TLINN0.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 51 mg/L EPA 300.0 01/31/2017 10:55 BGN9034110
Sulfate 28 mg/L EPA 300.0 01/31/2017 10:55 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/11/2017 12:11 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/09/2017 13:49 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 15:08 MHALL30.005 1
Barium (Ba)0.054 mg/L EPA 200.7 02/15/2017 15:08 MHALL30.005 1
Boron (B)1.05 mg/L EPA 200.7 02/15/2017 15:08 MHALL30.05 1
Iron (Fe)1.06 mg/L EPA 200.7 02/15/2017 15:08 MHALL30.01 1
Manganese (Mn)1.00 mg/L EPA 200.7 02/15/2017 15:08 MHALL30.005 1
Strontium (Sr)0.365 mg/L EPA 200.7 02/15/2017 15:08 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 15:08 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.2 mg/L EPA 200.7 02/17/2017 15:45B2 JJMACKE0.01 1
Magnesium (Mg)9.59 mg/L EPA 200.7 02/17/2017 15:45 JJMACKE0.005 1
Potassium (K)1.83 mg/L EPA 200.7 02/17/2017 15:45 JJMACKE0.1 1
Sodium (Na)19.6 mg/L EPA 200.7 02/17/2017 15:45B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.065 mg/L EPA 200.7 02/06/2017 13:41 MHH71310.005 1
Barium (Ba)0.053 mg/L EPA 200.7 02/06/2017 13:41 MHH71310.005 1
Boron (B)1.06 mg/L EPA 200.7 02/06/2017 13:41 MHH71310.05 1
Iron (Fe)1.47 mg/L EPA 200.7 02/06/2017 13:41 MHH71310.01 1
Manganese (Mn)1.06 mg/L EPA 200.7 02/06/2017 13:41 MHH71310.005 1
Strontium (Sr)0.367 mg/L EPA 200.7 02/06/2017 13:41 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/06/2017 13:41 MHH71310.005 1
Duke Energy Analytical Lab
Page 10 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003087
Collection Date:30-Jan-17 12:35 PM
Site:SW-CB1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Cobalt (Co)1.01 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 18:37 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/17/2017 18:37B2 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Cobalt (Co)1.04 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 21:03 PARMSTR0.2 1
Vanadium (V) Low Level 0.357 ug/L EPA 200.8 02/17/2017 21:03B2 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 180 mg/L SM2540C 02/01/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 11 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003087
Collection Date:30-Jan-17 12:35 PM
Site:SW-CB1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.9 mg/L SM5310C/EPA9060A 02/01/2017 14:17 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7 mg/L SM2540D 02/01/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 12 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003088
Collection Date:30-Jan-17 1:14 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/03/2017 12:34 TLINN0.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 01/31/2017 12:36 BGN90340.5 5
Sulfate 5.6 mg/L EPA 300.0 01/31/2017 12:36 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/11/2017 12:13 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/09/2017 13:52 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 15:12 MHALL30.005 1
Barium (Ba)0.043 mg/L EPA 200.7 02/15/2017 15:12 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 15:12 MHALL30.05 1
Iron (Fe)0.071 mg/L EPA 200.7 02/15/2017 15:12 MHALL30.01 1
Manganese (Mn)0.104 mg/L EPA 200.7 02/15/2017 15:12 MHALL30.005 1
Strontium (Sr)0.278 mg/L EPA 200.7 02/15/2017 15:12 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 15:12 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)50.0 mg/L EPA 200.7 02/17/2017 15:49B2 JJMACKE0.01 1
Magnesium (Mg)10.6 mg/L EPA 200.7 02/17/2017 15:49 JJMACKE0.005 1
Potassium (K)3.48 mg/L EPA 200.7 02/17/2017 15:49 JJMACKE0.1 1
Sodium (Na)44.0 mg/L EPA 200.7 02/17/2017 15:49B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.082 mg/L EPA 200.7 02/06/2017 13:45 MHH71310.005 1
Barium (Ba)0.043 mg/L EPA 200.7 02/06/2017 13:45 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/06/2017 13:45 MHH71310.05 1
Iron (Fe)0.184 mg/L EPA 200.7 02/06/2017 13:45 MHH71310.01 1
Manganese (Mn)0.104 mg/L EPA 200.7 02/06/2017 13:45 MHH71310.005 1
Strontium (Sr)0.287 mg/L EPA 200.7 02/06/2017 13:45 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/06/2017 13:45 MHH71310.005 1
Duke Energy Analytical Lab
Page 13 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003088
Collection Date:30-Jan-17 1:14 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 17:51 PARMSTR0.2 1
Vanadium (V) Low Level 3.33 ug/L EPA 200.8 02/17/2017 17:51B2 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 21:10 PARMSTR0.2 1
Vanadium (V) Low Level 4.14 ug/L EPA 200.8 02/17/2017 21:10B2 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 02/01/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 14 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003088
Collection Date:30-Jan-17 1:14 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.4 mg/L SM5310C/EPA9060A 02/01/2017 14:17 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/01/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 15 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003089
Collection Date:30-Jan-17 1:14 PM
Site:BG-2 DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/03/2017 12:38 TLINN0.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 01/31/2017 12:53 BGN90340.5 5
Sulfate 5.6 mg/L EPA 300.0 01/31/2017 12:53 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/11/2017 12:15 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/09/2017 13:54 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 15:16 MHALL30.005 1
Barium (Ba)0.044 mg/L EPA 200.7 02/15/2017 15:16 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 15:16 MHALL30.05 1
Iron (Fe)0.078 mg/L EPA 200.7 02/15/2017 15:16 MHALL30.01 1
Manganese (Mn)0.105 mg/L EPA 200.7 02/15/2017 15:16 MHALL30.005 1
Strontium (Sr)0.281 mg/L EPA 200.7 02/15/2017 15:16 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 15:16 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)48.4 mg/L EPA 200.7 02/17/2017 15:53B2 JJMACKE0.01 1
Magnesium (Mg)10.3 mg/L EPA 200.7 02/17/2017 15:53 JJMACKE0.005 1
Potassium (K)3.39 mg/L EPA 200.7 02/17/2017 15:53 JJMACKE0.1 1
Sodium (Na)42.8 mg/L EPA 200.7 02/17/2017 15:53B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.089 mg/L EPA 200.7 02/06/2017 13:49 MHH71310.005 1
Barium (Ba)0.043 mg/L EPA 200.7 02/06/2017 13:49 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/06/2017 13:49 MHH71310.05 1
Iron (Fe)0.189 mg/L EPA 200.7 02/06/2017 13:49 MHH71310.01 1
Manganese (Mn)0.102 mg/L EPA 200.7 02/06/2017 13:49 MHH71310.005 1
Strontium (Sr)0.284 mg/L EPA 200.7 02/06/2017 13:49 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/06/2017 13:49 MHH71310.005 1
Duke Energy Analytical Lab
Page 16 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003089
Collection Date:30-Jan-17 1:14 PM
Site:BG-2 DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 18:44 PARMSTR0.2 1
Vanadium (V) Low Level 3.45 ug/L EPA 200.8 02/17/2017 18:44B2 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 21:18 PARMSTR0.2 1
Vanadium (V) Low Level 4.20 ug/L EPA 200.8 02/17/2017 21:18B2 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 330 mg/L SM2540C 02/01/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 17 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003089
Collection Date:30-Jan-17 1:14 PM
Site:BG-2 DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.4 mg/L SM5310C/EPA9060A 02/01/2017 14:17 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6 mg/L SM2540D 02/01/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 18 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003090
Collection Date:30-Jan-17 2:43 PM
Site:ABMW-4BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/03/2017 12:39 TLINN0.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 5.1 mg/L EPA 300.0 01/31/2017 11:45 BGN90340.5 5
Sulfate 36 mg/L EPA 300.0 01/31/2017 11:45 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/11/2017 12:18 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/09/2017 13:57 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 02/15/2017 15:20 MHALL30.005 1
Barium (Ba)0.125 mg/L EPA 200.7 02/15/2017 15:20 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 15:20 MHALL30.05 1
Iron (Fe)0.640 mg/L EPA 200.7 02/15/2017 15:20 MHALL30.01 1
Manganese (Mn)0.382 mg/L EPA 200.7 02/15/2017 15:20 MHALL30.005 1
Strontium (Sr)1.88 mg/L EPA 200.7 02/15/2017 15:20 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 15:20 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)75.2 mg/L EPA 200.7 02/17/2017 15:57B2 JJMACKE0.01 1
Magnesium (Mg)5.64 mg/L EPA 200.7 02/17/2017 15:57 JJMACKE0.005 1
Potassium (K)7.06 mg/L EPA 200.7 02/17/2017 15:57 JJMACKE0.1 1
Sodium (Na)21.2 mg/L EPA 200.7 02/17/2017 15:57B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.056 mg/L EPA 200.7 02/06/2017 13:53 MHH71310.005 1
Barium (Ba)0.126 mg/L EPA 200.7 02/06/2017 13:53 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/06/2017 13:53 MHH71310.05 1
Iron (Fe)0.822 mg/L EPA 200.7 02/06/2017 13:53 MHH71310.01 1
Manganese (Mn)0.394 mg/L EPA 200.7 02/06/2017 13:53 MHH71310.005 1
Strontium (Sr)1.96 mg/L EPA 200.7 02/06/2017 13:53 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/06/2017 13:53 MHH71310.005 1
Duke Energy Analytical Lab
Page 19 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003090
Collection Date:30-Jan-17 2:43 PM
Site:ABMW-4BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Molybdenum (Mo)5.16 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 19:15 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/17/2017 19:15B2 PARMSTR0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Copper (Cu)1.73 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Molybdenum (Mo)7.28 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 21:49 PARMSTR0.2 1
Vanadium (V) Low Level 0.423 ug/L EPA 200.8 02/17/2017 21:49B2 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 02/01/2017 14:30 MGIGANT251
Duke Energy Analytical Lab
Page 20 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003090
Collection Date:30-Jan-17 2:43 PM
Site:ABMW-4BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.786 mg/L SM5310C/EPA9060A 02/01/2017 14:17 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/01/2017 10:00 MGIGANT51
Duke Energy Analytical Lab
Page 21 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003091
Collection Date:30-Jan-17 4:25 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/09/2017 13:59 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/15/2017 15:24 MHALL30.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/15/2017 15:24 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2017 15:24 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/15/2017 15:24 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/15/2017 15:24 MHALL30.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 02/15/2017 15:24 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2017 15:24 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 19:23 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/17/2017 19:23B2 PARMSTR0.3 1
Duke Energy Analytical Lab
Page 22 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003092
Collection Date:30-Jan-17 4:25 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/03/2017 12:40 TLINN0.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/31/2017 12:02 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/31/2017 12:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/11/2017 12:47 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 02/17/2017 16:00B2 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 02/17/2017 16:00 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 02/17/2017 16:00 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 02/17/2017 16:00B2 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/06/2017 13:57 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/06/2017 13:57 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/06/2017 13:57 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/06/2017 13:57 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/06/2017 13:57 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 02/06/2017 13:57 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/06/2017 13:57 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/17/2017 21:57 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/17/2017 21:57B2 PARMSTR0.3 1
Duke Energy Analytical Lab
Page 23 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
2017003092
Collection Date:30-Jan-17 4:25 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.197 mg/L SM5310C/EPA9060A 02/01/2017 14:17 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/01/2017 10:00 MGIGANT51
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Duke Energy Analytical Lab
Page 24 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020097 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0023 mg-N/L -1-0.0023 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0042 mg-N/L -10.0042 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0024 mg-N/L -10.0024 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0006 mg-N/L -10.0006 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.322 3.01 107mg-N/L -11090103.22
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.322 3.01 107mg-N/L -11090103.22
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.321 3.01 107mg-N/L -11090103.21
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.322 3.01 107mg-N/L -11090103.22
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010218 -- 2017000878
Nitrite + Nitrate
(Colorimetric)
0.213 0.25 93.6mg-N/L -1109010.213
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010218 -- 2017000878
Nitrite + Nitrate
(Colorimetric)
0.219 0.25 96 2.49mg-N/L -1109010.219
Duke Energy Analytical Lab
Page 25 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020097 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17010504 -- 2017002237
Nitrite + Nitrate
(Colorimetric)
0.755 0.25 99.7mg-N/L -1109010.755
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17010504 -- 2017002237
Nitrite + Nitrate
(Colorimetric)
0.758 0.25 101 1.39mg-N/L -1109010.758
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17010567 -- 2017002552
Nitrite + Nitrate
(Colorimetric)
0.401 0.25 101mg-N/L -1109010.401
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17010567 -- 2017002552
Nitrite + Nitrate
(Colorimetric)
0.4 0.25 101 0.355mg-N/L -1109010.4
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003088
Nitrite + Nitrate
(Colorimetric)
0.253 0.25 99.2mg-N/L -1109010.253
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003088
Nitrite + Nitrate
(Colorimetric)
0.259 0.25 101 2.27mg-N/L -1109010.259
Duke Energy Analytical Lab
Page 26 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17010653 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0399 mg/L -10.0399 0.1 < 1/2 RDL
Sulfate -0.0141 mg/L -1-0.0141 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.9 25 98.1mg/L -12080534.5
Sulfate 8.22 25 97mg/L -12080541.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.93 25 98.8 0.711mg/L -12080534.7
Sulfate 8.25 25 97.7 0.688mg/L -12080541.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.84 5 96.8mg/L -1109014.84
Sulfate 4.83 5 96.7mg/L -1109014.83
Duke Energy Analytical Lab
Page 27 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020315 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.007 ug/L -10.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.819 100 81.9ug/L -1307010081.9
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.822 100 82.2 0.378ug/L -1307010082.2
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.04 2 102ug/L -1158512.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.4ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010632 -- 2017002934
Mercury (Hg) 0.983 1 97.7ug/L -1307010.983
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010632 -- 2017002934
Mercury (Hg) 1 1 99.6 1.93ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003288
Mercury (Hg) 0.916 1 90.3ug/L -1307010.916
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003288
Mercury (Hg) 0.953 1 94 4.02ug/L -1307010.953
Duke Energy Analytical Lab
Page 28 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020267 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.009 ug/L -10.009 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.02 2 101ug/L -1158512.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2.05 2 102ug/L -1158512.05
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010611 -- 2017002793
Mercury (Hg) 0.951 1 94.5ug/L -1307010.951
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010611 -- 2017002793
Mercury (Hg) 0.949 1 94.3 0.212ug/L -1307010.949
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17010639 -- 2017002971
Mercury (Hg) 0.986 1 98.4ug/L -1307010.986
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17010639 -- 2017002971
Mercury (Hg) 0.986 1 98.4 0ug/L -1307010.986
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17010641 -- 2017002976
Mercury (Hg) 0.9 1 89.2ug/L -1307010.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17010641 -- 2017002976
Mercury (Hg) 0.898 1 89 0.224ug/L -1307010.898
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17010664 -- 2017003083
Mercury (Hg) 0.905 1 89.7ug/L -1307010.905
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17010664 -- 2017003083
Mercury (Hg) 0.892 1 88.4 1.46ug/L -1307010.892
Duke Energy Analytical Lab
Page 29 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020427 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000076 mg/L -1-0.000076 0.005 < 1/2 RDL
Barium (Ba) -0.000032 mg/L -1-0.000032 0.005 < 1/2 RDL
Boron (B) -0.00607 mg/L -1-0.00607 0.05 < 1/2 RDL
Iron (Fe) -0.000516 mg/L -1-0.000516 0.01 < 1/2 RDL
Manganese (Mn) 0.000066 mg/L -10.000066 0.005 < 1/2 RDL
Strontium (Sr) 0.000076 mg/L -10.000076 0.005 < 1/2 RDL
Zinc (Zn) -0.00228 mg/L -1-0.00228 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) -0.000064 mg/L -1-0.000064 0.005 < 1/2 RDL
Barium (Ba) 0.000003 mg/L -10.000003 0.005 < 1/2 RDL
Boron (B) -0.00694 mg/L -1-0.00694 0.05 < 1/2 RDL
Iron (Fe) 0.000037 mg/L -10.000037 0.01 < 1/2 RDL
Manganese (Mn) 0.000203 mg/L -10.000203 0.005 < 1/2 RDL
Strontium (Sr) 0.000076 mg/L -10.000076 0.005 < 1/2 RDL
Zinc (Zn) -0.00175 mg/L -1-0.00175 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2 2 99.8mg/L -1158512
Barium (Ba) 0.956 1 95.6mg/L -1158510.956
Boron (B) 1.95 2 97.3mg/L -1158511.95
Iron (Fe) 1.96 2 97.9mg/L -1158511.96
Manganese (Mn) 0.938 1 93.8mg/L -1158510.938
Strontium (Sr) 1.81 2 90.6mg/L -1158511.81
Zinc (Zn) 0.987 1 98.7mg/L -1158510.987
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.05 2 103mg/L -1158512.05
Barium (Ba) 0.972 1 97.2mg/L -1158510.972
Boron (B) 1.99 2 99.7mg/L -1158511.99
Iron (Fe) 2.01 2 100mg/L -1158512.01
Manganese (Mn) 0.963 1 96.3mg/L -1158510.963
Strontium (Sr) 1.83 2 91.8mg/L -1158511.83
Zinc (Zn) 1.02 1 102mg/L -1158511.02
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Aluminum (Al) 5.57 5 111mg/L -1307015.57
Duke Energy Analytical Lab
Page 30 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020427 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Barium (Ba) 5.69 5 113mg/L -1307015.69
Boron (B) 5.32 5 106mg/L -1307015.32
Iron (Fe) 5.53 5 107mg/L -1307015.53
Manganese (Mn) 5.72 5 113mg/L -1307015.72
Strontium (Sr) 5.47 5 108mg/L -1307015.47
Zinc (Zn) 5.6 5 112mg/L -1307015.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Aluminum (Al) 5.63 5 112 1.09mg/L -1307015.63
Barium (Ba) 5.73 5 114 0.739mg/L -1307015.73
Boron (B) 5.39 5 108 1.21mg/L -1307015.39
Iron (Fe) 5.59 5 108 1.13mg/L -1307015.59
Manganese (Mn) 5.79 5 114 1.2mg/L -1307015.79
Strontium (Sr) 5.47 5 109 0.0737mg/L -1307015.47
Zinc (Zn) 5.64 5 113 0.836mg/L -1307015.64
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003264
Aluminum (Al) 5.75 5 115mg/L -1307015.75
Barium (Ba) 5.84 5 116mg/L -1307015.84
Boron (B) 6.05 5 108mg/L -1307016.05
Iron (Fe) 16.2 5 109mg/L -13070116.2
Manganese (Mn) 12.6 5 104mg/L -13070112.6
Strontium (Sr) 5.7 5 107mg/L -1307015.7
Zinc (Zn) 5.63 5 112mg/L -1307015.63
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003264
Aluminum (Al) 5.71 5 114 0.578mg/L -1307015.71
Barium (Ba) 5.79 5 115 0.903mg/L -1307015.79
Boron (B) 5.97 5 107 1.4mg/L -1307015.97
Iron (Fe) 16 5 105 3.89mg/L -13070116
Manganese (Mn) 12.6 5 103 1.24mg/L -13070112.6
Strontium (Sr) 5.63 5 106 1.33mg/L -1307015.63
Zinc (Zn) 5.59 5 112 0.696mg/L -1307015.59
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Aluminum (Al) 5.75 5 115mg/L -1307015.75
Barium (Ba) 5.86 5 116mg/L -1307015.86
Duke Energy Analytical Lab
Page 31 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020427 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Boron (B) 5.44 5 109mg/L -1307015.44
Iron (Fe) 6.7 5 109mg/L -1307016.7
Manganese (Mn) 6.79 5 114mg/L -1307016.79
Strontium (Sr) 5.75 5 107mg/L -1307015.75
Zinc (Zn) 5.53 5 111mg/L -1307015.53
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020009 -- 2017003292
Aluminum (Al) 5.61 5 112 2.48mg/L -1307015.61
Barium (Ba) 5.68 5 112 3.08mg/L -1307015.68
Boron (B) 5.33 5 107 2.06mg/L -1307015.33
Iron (Fe) 6.55 5 106 2.73mg/L -1307016.55
Manganese (Mn) 6.63 5 111 2.71mg/L -1307016.63
Strontium (Sr) 5.61 5 105 2.74mg/L -1307015.61
Zinc (Zn) 5.4 5 108 2.29mg/L -1307015.4
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Aluminum (Al) 5.82 5 116mg/L -1307015.82
Barium (Ba) 5.8 5 116mg/L -1307015.8
Boron (B) 5.4 5 107mg/L -1307015.4
Iron (Fe) 5.79 5 111mg/L -1307015.79
Manganese (Mn) 5.93 5 117mg/L -1307015.93
Strontium (Sr) 5.47 5 108mg/L -1307015.47
Zinc (Zn) 5.8 5 116mg/L -1307015.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003487
Aluminum (Al) 5.78 5 115 0.691mg/L -1307015.78
Barium (Ba) 5.79 5 116 0.121mg/L -1307015.79
Boron (B) 5.39 5 107 0.168mg/L -1307015.39
Iron (Fe) 5.76 5 110 0.417mg/L -1307015.76
Manganese (Mn) 5.92 5 116 0.223mg/L -1307015.92
Strontium (Sr) 5.44 5 107 0.503mg/L -1307015.44
Zinc (Zn) 5.78 5 116 0.362mg/L -1307015.78
Duke Energy Analytical Lab
Page 32 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020504 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00757 mg/L -10.00757 0.01 > 1/2 RDL
Magnesium (Mg) 0.000896 mg/L -10.000896 0.005 < 1/2 RDL
Potassium (K) 0.0154 mg/L -10.0154 0.1 < 1/2 RDL
Sodium (Na) 0.0356 mg/L -10.0356 0.05 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.00206 mg/L -10.00206 0.01 < 1/2 RDL
Magnesium (Mg) 0.000226 mg/L -10.000226 0.005 < 1/2 RDL
Potassium (K) -0.00613 mg/L -1-0.00613 0.1 < 1/2 RDL
Sodium (Na) 0.00629 mg/L -10.00629 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Calcium (Ca) 0.00194 mg/L -10.00194 0.01 < 1/2 RDL
Magnesium (Mg) 0.000174 mg/L -10.000174 0.005 < 1/2 RDL
Potassium (K) -0.012 mg/L -1-0.012 0.1 < 1/2 RDL
Sodium (Na) 0.00633 mg/L -10.00633 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 1.97 2 98.5mg/L -1158511.97
Magnesium (Mg) 1.93 2 96.5mg/L -1158511.93
Potassium (K) 3.86 4 96.5mg/L -1158513.86
Sodium (Na) 7.99 8.1 98.6mg/L -1158517.99
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 1.96 2 97.8mg/L -1158511.96
Magnesium (Mg) 1.93 2 96.3mg/L -1158511.93
Potassium (K) 3.83 4 95.8mg/L -1158513.83
Sodium (Na) 7.99 8.1 98.7mg/L -1158517.99
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Calcium (Ca) 1.96 2 97.9mg/L -1158511.96
Magnesium (Mg) 1.91 2 95.7mg/L -1158511.91
Potassium (K) 3.83 4 95.8mg/L -1158513.83
Sodium (Na) 7.99 8.1 98.7mg/L -1158517.99
Duke Energy Analytical Lab
Page 33 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020504 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Calcium (Ca) 10.1 5 99.4mg/L -13070110.1
Magnesium (Mg) 7.75 5 103mg/L -1307017.75
Potassium (K) 6.45 5 101mg/L -1307016.45
Sodium (Na) 11.9 5 87.5mg/L -13070111.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Calcium (Ca) 10.4 5 105 5.96mg/L -13070110.4
Magnesium (Mg) 7.92 5 106 3.31mg/L -1307017.92
Potassium (K) 6.58 5 104 2.62mg/L -1307016.58
Sodium (Na) 12.1 5 92.4 5.51mg/L -13070112.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003266
Calcium (Ca) 12.3 5 180mg/L -130701200
Magnesium (Mg) 7.25 5 0mg/L -13070155.1
Potassium (K) 6.58 5 105mg/L -1307018.85
Sodium (Na) 10.8 5 102mg/L -13070118.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020005 -- 2017003266
Calcium (Ca) 200 5 461 87.9mg/L -130701214
Magnesium (Mg) 55.1 5 34.1 200mg/L -13070158.6
Potassium (K) 8.85 5 116 10.1mg/L -1307019.41
Sodium (Na) 18.8 5 128 21.8mg/L -13070120.1
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17020040 -- 2017003472
Calcium (Ca) 29.2 5 99.6mg/L -13070112.3
Magnesium (Mg) 9.9 5 101mg/L -1307017.25
Potassium (K) 6.9 5 101mg/L -1307016.58
Sodium (Na) 14.1 5 97.5mg/L -13070110.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17020040 -- 2017003472
Calcium (Ca) 214 5 103 3.74mg/L -13070112.5
Magnesium (Mg) 58.6 5 102 1.04mg/L -1307017.3
Potassium (K) 9.41 5 103 2.14mg/L -1307016.69
Sodium (Na) 20.1 5 101 3.69mg/L -13070111
Duke Energy Analytical Lab
Page 34 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020504 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003489
Calcium (Ca) 29.2 5 121mg/L -13070129.2
Magnesium (Mg) 9.9 5 107mg/L -1307019.9
Potassium (K) 6.9 5 105mg/L -1307016.9
Sodium (Na) 14.1 5 104mg/L -13070114.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17020042 -- 2017003489
Calcium (Ca) 12.5 5 120 0.936mg/L -13070129.1
Magnesium (Mg) 7.3 5 107 0.468mg/L -1307019.87
Potassium (K) 6.69 5 105 0.341mg/L -1307016.91
Sodium (Na) 11 5 102 1.77mg/L -13070114
Duke Energy Analytical Lab
Page 35 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020082 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.0004 mg/L -10.0004 0.005 < 1/2 RDL
Barium (Ba) -0.000108 mg/L -1-0.000108 0.005 < 1/2 RDL
Boron (B) -0.00219 mg/L -1-0.00219 0.05 < 1/2 RDL
Iron (Fe) 0.000327 mg/L -10.000327 0.01 < 1/2 RDL
Manganese (Mn) 0.000125 mg/L -10.000125 0.005 < 1/2 RDL
Strontium (Sr) -0.000005 mg/L -1-0.000005 0.005 < 1/2 RDL
Zinc (Zn) 0.000653 mg/L -10.000653 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.86 5 97.1mg/L -1158514.86
Barium (Ba) 4.92 5 98.5mg/L -1158514.92
Boron (B) 4.8 5 96mg/L -1158514.8
Iron (Fe) 4.94 5 98.8mg/L -1158514.94
Manganese (Mn) 4.95 5 99mg/L -1158514.95
Strontium (Sr) 4.76 5 95.2mg/L -1158514.76
Zinc (Zn) 4.93 5 98.7mg/L -1158514.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Aluminum (Al) 5.64 5 104mg/L -1307015.64
Barium (Ba) 4.89 5 97.2mg/L -1307014.89
Boron (B) 4.79 5 95.5mg/L -1307014.79
Iron (Fe) 5.92 5 97.9mg/L -1307015.92
Manganese (Mn) 4.97 5 97.7mg/L -1307014.97
Strontium (Sr) 4.74 5 93.9mg/L -1307014.74
Zinc (Zn) 4.84 5 96.8mg/L -1307014.84
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003078
Aluminum (Al) 5.63 5 104 0.0384mg/L -1307015.63
Barium (Ba) 4.91 5 97.7 0.492mg/L -1307014.91
Boron (B) 4.81 5 96 0.501mg/L -1307014.81
Iron (Fe) 5.95 5 98.3 0.449mg/L -1307015.95
Manganese (Mn) 5 5 98.2 0.592mg/L -1307015
Strontium (Sr) 4.77 5 94.5 0.679mg/L -1307014.77
Zinc (Zn) 4.86 5 97.2 0.351mg/L -1307014.86
Duke Energy Analytical Lab
Page 36 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020134 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.041 ug/L -1-0.041 1 < 1/2 RDL
Arsenic (As) 0.059 ug/L -10.059 1 < 1/2 RDL
Beryllium (Be) 0.04 ug/L -10.04 1 < 1/2 RDL
Cadmium (Cd) 0 ug/L -10 1 < 1/2 RDL
Chromium (Cr) 0.025 ug/L -10.025 1 < 1/2 RDL
Cobalt (Co) 0 ug/L -10 1 < 1/2 RDL
Copper (Cu) 0.029 ug/L -10.029 1 < 1/2 RDL
Lead (Pb) 0 ug/L -10 1 < 1/2 RDL
Molybdenum (Mo) 0.01 ug/L -10.01 1 < 1/2 RDL
Nickel (Ni) -0.013 ug/L -1-0.013 1 < 1/2 RDL
Selenium (Se) 0.032 ug/L -10.032 1 < 1/2 RDL
Thallium (Tl) Low Level 0.012 ug/L -10.012 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.174 ug/L -10.174 0.3 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 48.8 50 97.5ug/L -11585148.8
Arsenic (As) 48.7 50 97.4ug/L -11585148.7
Beryllium (Be) 52.9 50 106ug/L -11585152.9
Cadmium (Cd) 50.1 50 100ug/L -11585150.1
Chromium (Cr) 50.2 50 100ug/L -11585150.2
Cobalt (Co) 48.9 50 97.9ug/L -11585148.9
Copper (Cu) 49.4 50 98.8ug/L -11585149.4
Lead (Pb) 49.6 50 99.3ug/L -11585149.6
Molybdenum (Mo) 50.1 50 100ug/L -11585150.1
Nickel (Ni) 49.6 50 99.1ug/L -11585149.6
Selenium (Se) 48.3 50 96.6ug/L -11585148.3
Thallium (Tl) Low Level 45.5 50 91.1ug/L -11585145.5
Vanadium (V) Low Level 49.6 50 99.3ug/L -11585149.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003088
Antimony (Sb) 50 50 100ug/L -13070150
Arsenic (As) 49.1 50 98ug/L -13070149.1
Beryllium (Be) 53.6 50 107ug/L -13070153.6
Cadmium (Cd) 50.3 50 101ug/L -13070150.3
Chromium (Cr) 50.9 50 101ug/L -13070150.9
Cobalt (Co) 48.5 50 96.8ug/L -13070148.5
Copper (Cu) 48.8 50 97ug/L -13070148.8
Lead (Pb) 50.5 50 101ug/L -13070150.5
Duke Energy Analytical Lab
Page 37 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020134 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003088
Molybdenum (Mo) 51.8 50 102ug/L -13070151.8
Nickel (Ni) 49.4 50 97.2ug/L -13070149.4
Selenium (Se) 47.9 50 95.7ug/L -13070147.9
Thallium (Tl) Low Level 39.1 50 78.2ug/L -13070139.1
Vanadium (V) Low Level 54.6 50 103ug/L -13070154.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003088
Antimony (Sb) 50.2 50 101 0.427ug/L -13070150.2
Arsenic (As) 49.5 50 98.8 0.775ug/L -13070149.5
Beryllium (Be) 54.4 50 109 1.47ug/L -13070154.4
Cadmium (Cd) 50.3 50 101 0.0378ug/L -13070150.3
Chromium (Cr) 50.7 50 101 0.381ug/L -13070150.7
Cobalt (Co) 48.2 50 96.2 0.595ug/L -13070148.2
Copper (Cu) 48.7 50 96.9 0.126ug/L -13070148.7
Lead (Pb) 50.3 50 100 0.512ug/L -13070150.3
Molybdenum (Mo) 51.5 50 102 0.606ug/L -13070151.5
Nickel (Ni) 49.2 50 96.8 0.458ug/L -13070149.2
Selenium (Se) 47.8 50 95.6 0.0837ug/L -13070147.8
Thallium (Tl) Low Level 38.7 50 77.3 1.23ug/L -13070138.7
Vanadium (V) Low Level 54.5 50 102 0.148ug/L -13070154.5
Duke Energy Analytical Lab
Page 38 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020094 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.029 ug/L -1-0.029 1 < 1/2 RDL
Arsenic (As) 0.045 ug/L -10.045 1 < 1/2 RDL
Beryllium (Be) -0.001 ug/L -1-0.001 1 < 1/2 RDL
Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL
Chromium (Cr) 0.013 ug/L -10.013 1 < 1/2 RDL
Cobalt (Co) 0.001 ug/L -10.001 1 < 1/2 RDL
Copper (Cu) -0.037 ug/L -1-0.037 1 < 1/2 RDL
Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL
Molybdenum (Mo) 0.008 ug/L -10.008 1 < 1/2 RDL
Nickel (Ni) -0.006 ug/L -1-0.006 1 < 1/2 RDL
Selenium (Se) 0.035 ug/L -10.035 1 < 1/2 RDL
Thallium (Tl) Low Level 0.007 ug/L -10.007 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.164 ug/L -10.164 0.3 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 47.8 50 95.6ug/L -11585147.8
Arsenic (As) 46.9 50 93.7ug/L -11585146.9
Beryllium (Be) 50.3 50 101ug/L -11585150.3
Cadmium (Cd) 48.9 50 97.8ug/L -11585148.9
Chromium (Cr) 48.8 50 97.5ug/L -11585148.8
Cobalt (Co) 47.4 50 94.7ug/L -11585147.4
Copper (Cu) 47.5 50 95ug/L -11585147.5
Lead (Pb) 48.2 50 96.4ug/L -11585148.2
Molybdenum (Mo) 48.4 50 96.8ug/L -11585148.4
Nickel (Ni) 47.8 50 95.5ug/L -11585147.8
Selenium (Se) 46.8 50 93.5ug/L -11585146.8
Thallium (Tl) Low Level 43.5 50 87ug/L -11585143.5
Vanadium (V) Low Level 48.5 50 97.1ug/L -11585148.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003086
Antimony (Sb) 46.7 50 93.3ug/L -13070146.7
Arsenic (As) 45.4 50 90.5ug/L -13070145.4
Beryllium (Be) 51.3 50 103ug/L -13070151.3
Cadmium (Cd) 47.4 50 94.8ug/L -13070147.4
Chromium (Cr) 47.7 50 95ug/L -13070147.7
Cobalt (Co) 45.7 50 91.2ug/L -13070145.7
Copper (Cu) 46.6 50 91.9ug/L -13070146.6
Lead (Pb) 47.5 50 95ug/L -13070147.5
Duke Energy Analytical Lab
Page 39 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020094 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003086
Molybdenum (Mo) 47.4 50 94.6ug/L -13070147.4
Nickel (Ni) 47.2 50 92.9ug/L -13070147.2
Selenium (Se) 45.6 50 91ug/L -13070145.6
Thallium (Tl) Low Level 42.6 50 85.2ug/L -13070142.6
Vanadium (V) Low Level 48 50 95.3ug/L -13070148
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010665 -- 2017003086
Antimony (Sb) 47.5 50 94.9 1.69ug/L -13070147.5
Arsenic (As) 46.5 50 92.9 2.51ug/L -13070146.5
Beryllium (Be) 51.8 50 104 0.98ug/L -13070151.8
Cadmium (Cd) 48.6 50 97.2 2.56ug/L -13070148.6
Chromium (Cr) 49 50 97.5 2.58ug/L -13070149
Cobalt (Co) 46.6 50 93 1.93ug/L -13070146.6
Copper (Cu) 47.6 50 94.1 2.31ug/L -13070147.6
Lead (Pb) 48.5 50 96.9 2.08ug/L -13070148.5
Molybdenum (Mo) 48.2 50 96.3 1.71ug/L -13070148.2
Nickel (Ni) 47.8 50 94.1 1.22ug/L -13070147.8
Selenium (Se) 46.3 50 92.5 1.67ug/L -13070146.3
Thallium (Tl) Low Level 44.2 50 88.4 3.64ug/L -13070144.2
Vanadium (V) Low Level 49.1 50 97.4 2.17ug/L -13070149.1
Duke Energy Analytical Lab
Page 40 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020008 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16120339 -- 2016039777
TDS 205 0.971mg/L -1205
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17010568 -- 2017002557
TDS 325 0.927mg/L -1325
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 100 100mg/L -110901100
Duke Energy Analytical Lab
Page 41 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020034 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.031 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.032 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 109mg/L -1208012.36
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 106 3.49mg/L -1208012.28
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 104mg/L -1208014.05
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 102 1.75mg/L -1208014.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 98.1mg/L -1158512.82
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 99.3mg/L -1158512.85
Duke Energy Analytical Lab
Page 42 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17010665
Q17020002 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS 0 mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16120339 -- 2016039777
TSS 0 200mg/L -10
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 47.6 50 95.2mg/L -11090147.6
Final QualifierDilMeasuredUnits:Parameter
LCSD # 1
RPD% Recovery LCL UCLSpike
TSS 48.4 50 96.8 1.67mg/L -148.4
Duke Energy Analytical Lab
Page 43 of 89
#=CL#
February 09, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92328208
92328208
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17010665
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 31, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
Duke Energy Analytical Lab
Page 44 of 89
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92328208
J17010665
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
Duke Energy Analytical Lab
Page 45 of 89
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92328208
J17010665
Lab ID Sample ID Matrix Date Collected Date Received
92328208001 2017003078 Water 01/30/17 14:30 01/31/17 13:50
92328208002 2017003086 Water 01/30/17 13:35 01/31/17 13:50
92328208003 2017003087 Water 01/30/17 12:35 01/31/17 13:50
92328208004 2017003088 Water 01/30/17 13:14 01/31/17 13:50
92328208005 2017003089 Water 01/30/17 13:14 01/31/17 13:50
92328208006 2017003090 Water 01/30/17 14:43 01/31/17 13:50
92328208007 2017003092 Water 01/30/17 16:25 01/31/17 13:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 27
Duke Energy Analytical Lab
Page 46 of 89
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92328208
J17010665
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92328208001 2017003078 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328208002 2017003086 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328208003 2017003087 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328208004 2017003088 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328208005 2017003089 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328208006 2017003090 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92328208007 2017003092 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
Duke Energy Analytical Lab
Page 47 of 89
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92328208
J17010665
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92328208001 2017003078
Methane 28.4 ug/L 02/04/17 17:18 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)22.2 mg/L 02/06/17 17:285.0SM 2320B
Alkalinity, Total as CaCO3 22.2 mg/L 02/06/17 17:285.0SM 2320B
Chromium, Hexavalent 0.47 ug/L 02/08/17 17:240.12EPA 218.7
92328208002 2017003086
Alkalinity,Bicarbonate (CaCO3)29.8 mg/L 02/06/17 17:385.0SM 2320B
Alkalinity, Total as CaCO3 29.8 mg/L 02/06/17 17:385.0SM 2320B
Chromium, Hexavalent 0.35 ug/L 02/08/17 17:370.12EPA 218.7
92328208003 2017003087
Methane 56.0 ug/L 02/04/17 17:49 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)51.9 mg/L 02/06/17 17:475.0SM 2320B
Alkalinity, Total as CaCO3 51.9 mg/L 02/06/17 17:475.0SM 2320B
Chromium, Hexavalent 0.36 ug/L 02/08/17 17:500.12EPA 218.7
92328208004 2017003088
Methane 801 ug/L 02/04/17 18:04 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)228 mg/L 02/06/17 18:165.0SM 2320B
Alkalinity, Total as CaCO3 228 mg/L 02/06/17 18:165.0SM 2320B
Chromium, Hexavalent 0.055 ug/L 02/08/17 18:030.025EPA 218.7
92328208005 2017003089
Methane 845 ug/L 02/04/17 18:19 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)227 mg/L 02/06/17 18:315.0SM 2320B
Alkalinity, Total as CaCO3 227 mg/L 02/06/17 18:315.0SM 2320B
Chromium, Hexavalent 0.056 ug/L 02/08/17 18:160.025EPA 218.7
92328208006 2017003090
Methane 7450 ug/L 02/04/17 18:34 N210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)234 mg/L 02/06/17 18:455.0SM 2320B
Alkalinity, Total as CaCO3 234 mg/L 02/06/17 18:455.0SM 2320B
Sulfide 0.22 mg/L 02/01/17 17:110.10SM 4500-S2D
Chromium, Hexavalent 0.47 ug/L 02/08/17 18:290.12EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 27
Duke Energy Analytical Lab
Page 48 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328208
J17010665
Method:
Client:Duke Energy
RSK 175 Modified
Date:February 09, 2017
Description:RSK 175 Headspace
General Information:
7 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
Duke Energy Analytical Lab
Page 49 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328208
J17010665
Method:
Client:Duke Energy
SM 2320B
Date:February 09, 2017
Description:2320B Alkalinity
General Information:
7 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
Duke Energy Analytical Lab
Page 50 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328208
J17010665
Method:
Client:Duke Energy
SM 4500-S2D
Date:February 09, 2017
Description:4500S2D Sulfide Water
General Information:
7 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 346541
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92328208001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1922359)
• Sulfide
• MSD (Lab ID: 1922360)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
Duke Energy Analytical Lab
Page 51 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92328208
J17010665
Method:
Client:Duke Energy
EPA 218.7
Date:February 09, 2017
Description:Hexavalent Chromium by IC
General Information:
6 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 349119
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92328053002,92328212005
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1875322)
• Chromium, Hexavalent
• MS (Lab ID: 1875324)
• Chromium, Hexavalent
• MSD (Lab ID: 1875323)
• Chromium, Hexavalent
• MSD (Lab ID: 1875325)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
Duke Energy Analytical Lab
Page 52 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328208
J17010665
Sample:2017003078 Lab ID:92328208001 Collected:01/30/17 14:30 Received:01/31/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 28.4 ug/L 02/04/17 17:18 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)22.2 mg/L 02/06/17 17:285.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/06/17 17:285.0 1
Alkalinity, Total as CaCO3 22.2 mg/L 02/06/17 17:285.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/01/17 17:11 18496-25-8 M10.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.47 ug/L 02/08/17 17:24 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
Duke Energy Analytical Lab
Page 53 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328208
J17010665
Sample:2017003086 Lab ID:92328208002 Collected:01/30/17 13:35 Received:01/31/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/04/17 17:33 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)29.8 mg/L 02/06/17 17:385.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/06/17 17:385.0 1
Alkalinity, Total as CaCO3 29.8 mg/L 02/06/17 17:385.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/01/17 17:11 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.35 ug/L 02/08/17 17:37 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
Duke Energy Analytical Lab
Page 54 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328208
J17010665
Sample:2017003087 Lab ID:92328208003 Collected:01/30/17 12:35 Received:01/31/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 56.0 ug/L 02/04/17 17:49 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)51.9 mg/L 02/06/17 17:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/06/17 17:475.0 1
Alkalinity, Total as CaCO3 51.9 mg/L 02/06/17 17:475.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/01/17 17:11 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.36 ug/L 02/08/17 17:50 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
Duke Energy Analytical Lab
Page 55 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328208
J17010665
Sample:2017003088 Lab ID:92328208004 Collected:01/30/17 13:14 Received:01/31/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 801 ug/L 02/04/17 18:04 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)228 mg/L 02/06/17 18:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/06/17 18:165.0 1
Alkalinity, Total as CaCO3 228 mg/L 02/06/17 18:165.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/01/17 17:11 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.055 ug/L 02/08/17 18:03 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
Duke Energy Analytical Lab
Page 56 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328208
J17010665
Sample:2017003089 Lab ID:92328208005 Collected:01/30/17 13:14 Received:01/31/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 845 ug/L 02/04/17 18:19 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)227 mg/L 02/06/17 18:315.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/06/17 18:315.0 1
Alkalinity, Total as CaCO3 227 mg/L 02/06/17 18:315.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/01/17 17:11 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.056 ug/L 02/08/17 18:16 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
Duke Energy Analytical Lab
Page 57 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328208
J17010665
Sample:2017003090 Lab ID:92328208006 Collected:01/30/17 14:43 Received:01/31/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 7450 ug/L 02/04/17 18:34 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)234 mg/L 02/06/17 18:455.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/06/17 18:455.0 1
Alkalinity, Total as CaCO3 234 mg/L 02/06/17 18:455.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide 0.22 mg/L 02/01/17 17:11 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.47 ug/L 02/08/17 18:29 18540-29-90.12 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 27
Duke Energy Analytical Lab
Page 58 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92328208
J17010665
Sample:2017003092 Lab ID:92328208007 Collected:01/30/17 16:25 Received:01/31/17 13:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 02/04/17 18:50 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 02/06/17 18:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/06/17 18:585.0 1
Alkalinity, Total as CaCO3 ND mg/L 02/06/17 18:585.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/01/17 17:11 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
Duke Energy Analytical Lab
Page 59 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328208
J17010665
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347060
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006, 92328208007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1925160
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006, 92328208007
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N202/04/17 13:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1925161LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 473 N239611970-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1925163MATRIX SPIKE SAMPLE:
MSSpike
Result
92328212001
Methane ug/L 509 N239612970-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92328166011
1925162SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 27
Duke Energy Analytical Lab
Page 60 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328208
J17010665
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
347007
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006, 92328208007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1924995
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006, 92328208007
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 02/06/17 14:23
Alkalinity, Total as CaCO3 mg/L ND 5.0 02/06/17 14:23
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 02/06/17 14:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1924996LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 45.450 91 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924997MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328166011
1924998
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 99 80-12098 0 255015.5 65.0 64.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1924999MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328166023
1925000
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-12098 0 25509.5 58.4 58.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
Duke Energy Analytical Lab
Page 61 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328208
J17010665
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
346541
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006, 92328208007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1922357
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006, 92328208007
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 02/01/17 17:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1922358LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1922359MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328208001
1922360
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 73 80-12073 0 10.5ND 0.37 0.37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 27
Duke Energy Analytical Lab
Page 62 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92328208
J17010665
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349119
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1875320
Associated Lab Samples:92328208001, 92328208002, 92328208003, 92328208004, 92328208005, 92328208006
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 02/08/17 12:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1875321LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.071.075 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1875322MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328053002
1875323
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.38 125 85-115149 18 20.38ND 0.47 0.56
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1875324MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92328212005
1875325
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 123 85-115137 5 20.0750.092 0.18 0.19
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 27
Duke Energy Analytical Lab
Page 63 of 89
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92328208
J17010665
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 27
Duke Energy Analytical Lab
Page 64 of 89
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92328208
J17010665
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92328208001 3470602017003078RSK 175 Modified
92328208002 3470602017003086RSK 175 Modified
92328208003 3470602017003087RSK 175 Modified
92328208004 3470602017003088RSK 175 Modified
92328208005 3470602017003089RSK 175 Modified
92328208006 3470602017003090RSK 175 Modified
92328208007 3470602017003092RSK 175 Modified
92328208001 3470072017003078SM 2320B
92328208002 3470072017003086SM 2320B
92328208003 3470072017003087SM 2320B
92328208004 3470072017003088SM 2320B
92328208005 3470072017003089SM 2320B
92328208006 3470072017003090SM 2320B
92328208007 3470072017003092SM 2320B
92328208001 3465412017003078SM 4500-S2D
92328208002 3465412017003086SM 4500-S2D
92328208003 3465412017003087SM 4500-S2D
92328208004 3465412017003088SM 4500-S2D
92328208005 3465412017003089SM 4500-S2D
92328208006 3465412017003090SM 4500-S2D
92328208007 3465412017003092SM 4500-S2D
92328208001 3491192017003078EPA 218.7
92328208002 3491192017003086EPA 218.7
92328208003 3491192017003087EPA 218.7
92328208004 3491192017003088EPA 218.7
92328208005 3491192017003089EPA 218.7
92328208006 3491192017003090EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/09/2017 11:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 27
Duke Energy Analytical Lab
Page 65 of 89
Page 23 of 27
Duke Energy Analytical Lab
Page 66 of 89
Page 24 of 27
Duke Energy Analytical Lab
Page 67 of 89
Page 25 of 27
Duke Energy Analytical Lab
Page 68 of 89
Page 26 of 27
Duke Energy Analytical Lab
Page 69 of 89
Page 27 of 27
Duke Energy Analytical Lab
Page 70 of 89

February 17, 2017

Anne Pridgeon
Duke Energy
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment
Work Order: 415381
SDG: J17010665

Dear Anne Pridgeon:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on January 31, 2017. This original data report has been prepared and reviewed in
accordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 5015714
Enclosures
Page 1 of 18
Chelsea Seagle for
Duke Energy Analytical Lab
Page 71 of 89
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO004 Duke Energy Carolinas, LLC <BR> (PO 5015714)
Client SDG: J17010665 GEL Work Order: 415381
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for but not detected above the Lc
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 18
Duke Energy Analytical Lab
Page 72 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1635755
1635755
1637568
1636180
1114
0926
1204
0450
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/06/17
02/08/17
02/14/17
02/17/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415381001
Ground Water
30-JAN-17 14:30
31-JAN-17
2017003078 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.839
0.796
1
2
3
4
U
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"62 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/01/17 16357540512SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 18
Duke Energy Analytical Lab
Page 73 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1635755
1635755
1637568
1636180
1123
0932
1204
0525
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/06/17
02/08/17
02/14/17
02/17/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415381002
Ground Water
30-JAN-17 13:35
31-JAN-17
2017003086 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.613
0.674
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
2.24
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"84.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/01/17 16357540512SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 18
Duke Energy Analytical Lab
Page 74 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1635755
1635755
1637568
1636180
1125
0937
1204
0525
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/06/17
02/08/17
02/14/17
02/17/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415381003
Ground Water
30-JAN-17 12:35
31-JAN-17
2017003087 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.688
0.568
1
2
3
4
J
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000813
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"84.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/01/17 16357540512SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 18
Duke Energy Analytical Lab
Page 75 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1635755
1635755
1637568
1636180
1126
0938
1204
0525
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/06/17
02/08/17
02/14/17
02/17/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415381004
Ground Water
30-JAN-17 13:14
31-JAN-17
2017003088 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.498
0.668
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000926
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"86.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/01/17 16357540512SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 18
Duke Energy Analytical Lab
Page 76 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1635755
1635755
1637568
1636180
1128
0940
1204
0525
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/06/17
02/08/17
02/14/17
02/17/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415381005
Ground Water
30-JAN-17 13:14
31-JAN-17
2017003089 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.495
0.811
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000808
ND
ND
ND
ND
1.30
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"83 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/01/17 16357540512SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 7 of 18
Duke Energy Analytical Lab
Page 77 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: February 17, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1635755
1635755
1637568
1636180
1129
0941
1204
0525
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
02/06/17
02/08/17
02/14/17
02/17/17
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment Project:
415381006
Ground Water
30-JAN-17 14:43
31-JAN-17
2017003090 DUKE00401Project:
DUPO004Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.429
0.602
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00039
ND
ND
ND
3.72
0.746
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"78.5 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 02/01/17 16357540512SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 8 of 18
Duke Energy Analytical Lab
Page 78 of 89
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1635755Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Parmname
Anne PridgeonContact:
Duke Energy
13339 Hagers Ferry Road
Huntersville, North Carolina
February 17, 2017Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
Anlst Date Time
SKJ 02/08/17 09:27
02/06/17 11:16
02/06/17 11:02
02/08/17 09:12
02/08/17 09:10
02/06/17 11:01
QC
ND
ND
ND
ND
0.0514
0.000527
0.000652
0.00503
ND
ND
ND
ND
NOM Sample
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
U
U
U
U
U
U
U
U
QC1203719370 415381001
QC1203719369
QC1203719373
QC1203719368
N/A
N/A
N/A
N/A
REC%
103
105
119
101
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
415381Workorder:
Mail Code: MGO3A2
U
U
U
U
RPD%
Page 1 of 4
Page 9 of 18
Duke Energy Analytical Lab
Page 79 of 89
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
1635755
1637568
Batch
Batch
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Parmname Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
02/06/17 11:17
02/08/17 09:29
02/08/17 09:30
02/06/17 11:19
02/14/17 12:04
02/14/17 12:04
02/14/17 12:04
QC
0.051
0.000491
0.000623
0.00478
ND
ND
ND
ND
0.410
7.24
0.841
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
0.483
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-10%)
(0%-10%)
N/A
(75%-125%)
Qual
U
U
U
U
U
QC1203719371 415381001
QC1203719374 415381001
QC1203719372 415381001
QC1203723897 415291008
QC1203723898
QC1203723896
N/A
N/A
N/A
N/A
N/A
REC%
103
98.2
113
95.6
103
0.0496
0.0005
0.00055
0.005
7.01
MS
MS
SDILT
DUP
LCS
MB
415381Workorder:
U
U
U
U
U
U
U
U
U
RPD%
Page 2 of 4
Page 10 of 18
Duke Energy Analytical Lab
Page 80 of 89
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Rad Ra-226
1636180Batch
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
LXP1 02/17/17 06:00
02/17/17 07:30
02/17/17 06:00
02/17/17 07:30
QC
1.06
25.4
-0.112
134
NOM Sample
1.46
1.46
Range
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
QC1203720441 415379001
QC1203720443
QC1203720440
QC1203720442 415379001
The Qualifiers in this report are defined as follows:
32.2
REC%
98
102
26.0
130
DUP
LCS
MB
MS
415381Workorder:
**
<
>
BD
E
FA
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
RPD%
Notes:
Page 3 of 4
Page 11 of 18
Duke Energy Analytical Lab
Page 81 of 89
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 4 of 4
Units Anlst Date TimeQCNOMSampleRangeQualREC%
415381Workorder:
U
U
UI
UJ
UL
X
Y
^
h
Analyte was analyzed for but not detected above the Lc
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 12 of 18
Duke Energy Analytical Lab
Page 82 of 89
Page 13 of 18
Duke Energy Analytical Lab
Page 83 of 89
Page 14 of 18
Duke Energy Analytical Lab
Page 84 of 89

Technical Case Narrative
Duke Energy Carolinas, LLC
(DUPC)
SDG #: J17010665
Work Order #: 415381

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1635755

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1635754
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415381001 2017003078
415381002 2017003086
415381003 2017003087
415381004 2017003088
415381005 2017003089
415381006 2017003090
1203719368 Method Blank (MB)ICP-MS
1203719369 Laboratory Control Sample (LCS)
1203719373 Laboratory Control Sample (LCS)
1203719372 415381001(2017003078L) Serial Dilution (SD)
1203719370 415381001(2017003078D) Sample Duplicate (DUP)
1203719371 415381001(2017003078S) Matrix Spike (MS)
1203719374 415381001(2017003078S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1637568
Page 15 of 18
Duke Energy Analytical Lab
Page 85 of 89
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415381001 2017003078
415381002 2017003086
415381003 2017003087
415381004 2017003088
415381005 2017003089
415381006 2017003090
1203723896 Method Blank (MB)
1203723897 415291008(2017002804) Sample Duplicate (DUP)
1203723898 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The blank result
1203723896 (MB) is greater than the MDC but less than the required detection limit.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1636180
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
415381001 2017003078
415381002 2017003086
415381003 2017003087
415381004 2017003088
415381005 2017003089
415381006 2017003090
1203720440 Method Blank (MB)
1203720441 415379001(2017003079) Sample Duplicate (DUP)
1203720442 415379001(2017003079) Matrix Spike (MS)
1203720443 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Page 16 of 18
Duke Energy Analytical Lab
Page 86 of 89
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203720442 (2017003079MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 17 of 18
Duke Energy Analytical Lab
Page 87 of 89
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA170010
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-21
VT87156
460202
C780
997404
List of current GEL Certifications as of 17 February 2017
Page 18 of 18
Duke Energy Analytical Lab
Page 88 of 89
Duke Energy Analytical Lab
Page 89 of 89