NC0038377_J16110328report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16110328
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:12/9/2016
Customer Address:Mayo Steam Plant
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 66
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016036486 MAYO STEAM 09-Nov-16 8:35 AM illegible MW-3
1 Total Samples
Duke Energy Analytical Lab
Page 2 of 66
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:12/9/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
2016036486
Collection Date:09-Nov-16 8:35 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.065 mg-N/L EPA 353.2 11/21/2016 13:01 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 47 mg/L EPA 300.0 11/16/2016 11:32 BGN9034110
Sulfate 22 mg/L EPA 300.0 11/16/2016 11:32 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2016 12:20 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2016 14:27 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 11/29/2016 09:09 JJMACKE0.005 1
Barium (Ba)0.065 mg/L EPA 200.7 11/29/2016 09:09 JJMACKE0.005 1
Boron (B)1.17 mg/L EPA 200.7 11/29/2016 09:09 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 11/29/2016 09:09 JJMACKE0.01 1
Manganese (Mn)0.808 mg/L EPA 200.7 11/29/2016 09:09 JJMACKE0.005 1
Strontium (Sr)0.346 mg/L EPA 200.7 11/29/2016 09:09 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/29/2016 09:09 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.9 mg/L EPA 200.7 12/05/2016 15:52 JJMACKE0.01 1
Magnesium (Mg)8.68 mg/L EPA 200.7 12/05/2016 15:52 JJMACKE0.005 1
Potassium (K)2.17 mg/L EPA 200.7 12/05/2016 15:52 JJMACKE0.1 1
Sodium (Na)22.4 mg/L EPA 200.7 12/05/2016 15:52 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 11/19/2016 12:15 JJMACKE0.005 1
Barium (Ba)0.056 mg/L EPA 200.7 11/19/2016 12:15 JJMACKE0.005 1
Boron (B)1.04 mg/L EPA 200.7 11/19/2016 12:15 JJMACKE0.05 1
Iron (Fe)0.023 mg/L EPA 200.7 11/19/2016 12:15 JJMACKE0.01 1
Manganese (Mn)0.932 mg/L EPA 200.7 11/19/2016 12:15 JJMACKE0.005 1
Strontium (Sr)0.314 mg/L EPA 200.7 11/19/2016 12:15 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/19/2016 12:15 JJMACKE0.005 1
Duke Energy Analytical Lab
Page 4 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
2016036486
Collection Date:09-Nov-16 8:35 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Molybdenum (Mo)1.48 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Nickel (Ni)2.90 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/29/2016 19:09B2 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 11/29/2016 19:09 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Molybdenum (Mo)4.03 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Nickel (Ni)3.79 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN30.2 1
Vanadium (V) Low Level 0.447 ug/L EPA 200.8 11/22/2016 13:23 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 11/14/2016 13:58 HGRUVER251
Duke Energy Analytical Lab
Page 5 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
2016036486
Collection Date:09-Nov-16 8:35 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.999 mg/L SM5310C/EPA9060A 11/22/2016 16:070.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/14/2016 11:18 HGRUVER51
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Duke Energy Analytical Lab
Page 6 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110605 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0018 mg-N/L -10.0018 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0022 mg-N/L -10.0022 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0013 mg-N/L -10.0013 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.002 mg-N/L -10.002 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 5
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0011 mg-N/L -10.0011 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 6
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0001 mg-N/L -10.0001 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 7
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.001 mg-N/L -10.001 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 8
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.001 mg-N/L -1-0.001 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 9
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0002 mg-N/L -10.0002 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.306 3.01 102mg-N/L -11090103.06
Duke Energy Analytical Lab
Page 7 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110605 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.307 3.01 102mg-N/L -11090103.07
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.305 3.01 101mg-N/L -11090103.05
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.308 3.01 102mg-N/L -11090103.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 5
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.307 3.01 102mg-N/L -11090103.07
Final QualifierDilMeasuredUnits:Parameter
LCS # 6
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.308 3.01 102mg-N/L -11090103.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 7
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.304 3.01 101mg-N/L -11090103.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 8
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.306 3.01 102mg-N/L -11090103.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 9
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.304 3.01 101mg-N/L -11090103.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100204 -- 2016032553
Nitrite + Nitrate
(Colorimetric)
0.72 50 97.5mg-N/L -11090200144
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100204 -- 2016032553
Nitrite + Nitrate
(Colorimetric)
0.721 50 97.8 0.287mg-N/L -11090200144
Duke Energy Analytical Lab
Page 8 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110605 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110199 -- 2016035890
Nitrite + Nitrate
(Colorimetric)
0.412 0.25 98.2mg-N/L -1109010.412
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110199 -- 2016035890
Nitrite + Nitrate
(Colorimetric)
0.408 0.25 97 1.31mg-N/L -1109010.408
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16110287 -- 2016036244
Nitrite + Nitrate
(Colorimetric)
0.327 0.25 99.2mg-N/L -1109010.327
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16110287 -- 2016036244
Nitrite + Nitrate
(Colorimetric)
0.328 0.25 99.5 0.282mg-N/L -1109010.328
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16110287 -- 2016036246
Nitrite + Nitrate
(Colorimetric)
0.348 0.25 98.3mg-N/L -1109010.348
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16110287 -- 2016036246
Nitrite + Nitrate
(Colorimetric)
0.35 0.25 99.2 0.891mg-N/L -1109010.35
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J16110227 -- 2016036015
Nitrite + Nitrate
(Colorimetric)
0.23 0.25 99.2mg-N/L -1109010.23
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J16110227 -- 2016036015
Nitrite + Nitrate
(Colorimetric)
0.23 0.25 99.2 0mg-N/L -1109010.23
Final QualifierDilMeasuredUnits:Parameter
MS # 6
% Recovery LCL UCLSpike
Parent Sample: J16110348 -- 2016036576
Nitrite + Nitrate
(Colorimetric)
0.3 0.25 96.2mg-N/L -1109010.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 6
RPD% Recovery LCL UCLSpike
Parent Sample: J16110348 -- 2016036576
Nitrite + Nitrate
(Colorimetric)
0.301 0.25 96.6 0.332mg-N/L -1109010.301
Duke Energy Analytical Lab
Page 9 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110605 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 7
% Recovery LCL UCLSpike
Parent Sample: J16110348 -- 2016036579
Nitrite + Nitrate
(Colorimetric)
0.389 0.25 96.4mg-N/L -1109010.389
Final QualifierDilMeasuredUnits:Parameter
MSD # 7
RPD% Recovery LCL UCLSpike
Parent Sample: J16110348 -- 2016036579
Nitrite + Nitrate
(Colorimetric)
0.389 0.25 96.5 0.124mg-N/L -1109010.389
Final QualifierDilMeasuredUnits:Parameter
MS # 8
% Recovery LCL UCLSpike
Parent Sample: J16110328 -- 2016036486
Nitrite + Nitrate
(Colorimetric)
0.31 0.25 97.9mg-N/L -1109010.31
Final QualifierDilMeasuredUnits:Parameter
MSD # 8
RPD% Recovery LCL UCLSpike
Parent Sample: J16110328 -- 2016036486
Nitrite + Nitrate
(Colorimetric)
0.308 0.25 97.2 0.697mg-N/L -1109010.308
Duke Energy Analytical Lab
Page 10 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110483 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0167 mg/L -10.0167 0.1 < 1/2 RDL
Sulfate -0.0448 mg/L -1-0.0448 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.53 5 96.6mg/L -1208015.53
Sulfate 6.33 5 95.4mg/L -1208016.33
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.52 5 96.3 0.301mg/L -1208015.52
Sulfate 6.31 5 95 0.441mg/L -1208016.31
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 7.65 5 117mg/L -1208017.65
Sulfate 7.73 5 117mg/L -1208017.73
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 7.67 5 117 0.24mg/L -1208017.67
Sulfate 7.74 5 117 0.0807mg/L -1208017.74
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.79 5 95.8mg/L -1109014.79
Sulfate 4.84 5 96.7mg/L -1109014.84
Duke Energy Analytical Lab
Page 11 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16120051 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.22 2 111ug/L -1158512.22
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110348 -- 2016036576
Mercury (Hg) 1.13 1 113ug/L -1307011.13
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110348 -- 2016036576
Mercury (Hg) 1.15 1 115 1.84ug/L -1307011.15
Duke Energy Analytical Lab
Page 12 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16120052 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.13 1 113ug/L -1307011.13
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.15 1 115 1.84ug/L -1307011.15
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.22 2 111ug/L -1158512.22
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2.06 2 103ug/L -1158512.06
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036128
Mercury (Hg) 1.1 1 110ug/L -1307011.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036128
Mercury (Hg) 1.09 1 109 0.917ug/L -1307011.09
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036320
Mercury (Hg) 1.04 1 105ug/L -1307011.04
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036320
Mercury (Hg) 1.03 1 104 1.15ug/L -1307011.03
Duke Energy Analytical Lab
Page 13 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110732 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000159 mg/L -1-0.000159 0.005 < 1/2 RDL
Barium (Ba) 0.000001 mg/L -10.000001 0.005 < 1/2 RDL
Boron (B) -0.00372 mg/L -1-0.00372 0.05 < 1/2 RDL
Iron (Fe) 0.000414 mg/L -10.000414 0.01 < 1/2 RDL
Manganese (Mn) -0.000239 mg/L -1-0.000239 0.005 < 1/2 RDL
Strontium (Sr) -0.000016 mg/L -1-0.000016 0.005 < 1/2 RDL
Zinc (Zn) 0.00102 mg/L -10.00102 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) -0.000138 mg/L -1-0.000138 0.005 < 1/2 RDL
Barium (Ba) 0.00194 mg/L -10.00194 0.005 < 1/2 RDL
Boron (B) -0.00216 mg/L -1-0.00216 0.05 < 1/2 RDL
Iron (Fe) 0.000859 mg/L -10.000859 0.01 < 1/2 RDL
Manganese (Mn) -0.000153 mg/L -1-0.000153 0.005 < 1/2 RDL
Strontium (Sr) -0.000015 mg/L -1-0.000015 0.005 < 1/2 RDL
Zinc (Zn) 0.00137 mg/L -10.00137 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Aluminum (Al) -0.000069 mg/L -1-0.000069 0.005 < 1/2 RDL
Barium (Ba) 0.000254 mg/L -10.000254 0.005 < 1/2 RDL
Boron (B) -0.00196 mg/L -1-0.00196 0.05 < 1/2 RDL
Iron (Fe) 0.00205 mg/L -10.00205 0.01 < 1/2 RDL
Manganese (Mn) -0.000006 mg/L -1-0.000006 0.005 < 1/2 RDL
Strontium (Sr) -0.000019 mg/L -1-0.000019 0.005 < 1/2 RDL
Zinc (Zn) 0.00151 mg/L -10.00151 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.17 2 108mg/L -1158512.17
Barium (Ba) 0.983 1 98.3mg/L -1158510.983
Boron (B) 2.01 2 101mg/L -1158512.01
Iron (Fe) 2.02 2 101mg/L -1158512.02
Manganese (Mn) 0.983 1 98.3mg/L -1158510.983
Strontium (Sr) 1.89 2 94.7mg/L -1158511.89
Zinc (Zn) 1.04 1 104mg/L -1158511.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.17 2 109mg/L -1158512.17
Duke Energy Analytical Lab
Page 14 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110732 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Barium (Ba) 0.984 1 98.4mg/L -1158510.984
Boron (B) 2.03 2 101mg/L -1158512.03
Iron (Fe) 2.02 2 101mg/L -1158512.02
Manganese (Mn) 0.982 1 98.2mg/L -1158510.982
Strontium (Sr) 1.89 2 94.5mg/L -1158511.89
Zinc (Zn) 1.04 1 104mg/L -1158511.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Aluminum (Al) 2.24 2 112mg/L -1158512.24
Barium (Ba) 1.01 1 102mg/L -1158511.01
Boron (B) 2.09 2 104mg/L -1158512.09
Iron (Fe) 2.08 2 104mg/L -1158512.08
Manganese (Mn) 1.01 1 101mg/L -1158511.01
Strontium (Sr) 1.95 2 97.3mg/L -1158511.95
Zinc (Zn) 1.07 1 107mg/L -1158511.07
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Aluminum (Al)2 111mg/L -1158512.23
Barium (Ba)1 100mg/L -1158511
Boron (B)2 104mg/L -1158512.07
Iron (Fe)2 103mg/L -1158512.07
Manganese (Mn)1 100mg/L -1158511
Strontium (Sr)2 96.5mg/L -1158511.93
Zinc (Zn)1 106mg/L -1158511.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 5
% Recovery LCL UCLSpike
Aluminum (Al)2 111mg/L -1158512.23
Barium (Ba)1 104mg/L -1158511.04
Boron (B)2 102mg/L -1158512.05
Iron (Fe)2 101mg/L -1158512.03
Manganese (Mn)1 105mg/L -1158511.05
Strontium (Sr)2 99.5mg/L -1158511.99
Zinc (Zn)1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 6
% Recovery LCL UCLSpike
Aluminum (Al)2 113mg/L -1158512.27
Barium (Ba)1 104mg/L -1158511.04
Duke Energy Analytical Lab
Page 15 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110732 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 6
% Recovery LCL UCLSpike
Boron (B)2 104mg/L -1158512.08
Iron (Fe)2 103mg/L -1158512.07
Manganese (Mn)1 100mg/L -1158511
Strontium (Sr)2 99.2mg/L -1158511.98
Zinc (Zn)1 104mg/L -1158511.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110145 -- 2016035692
Aluminum (Al) 5.7 5 114mg/L -1307015.7
Barium (Ba) 5.54 5 111mg/L -1307015.54
Boron (B) 5.48 5 109mg/L -1307015.48
Iron (Fe) 5.38 5 105mg/L -1307015.38
Manganese (Mn) 5.65 5 112mg/L -1307015.65
Strontium (Sr) 5.36 5 106mg/L -1307015.36
Zinc (Zn) 5.58 5 112mg/L -1307015.58
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110145 -- 2016035692
Aluminum (Al) 5.63 5 112 1.19mg/L -1307015.63
Barium (Ba) 5.5 5 110 0.599mg/L -1307015.5
Boron (B) 5.43 5 108 0.94mg/L -1307015.43
Iron (Fe) 5.34 5 105 0.762mg/L -1307015.34
Manganese (Mn) 5.61 5 111 0.7mg/L -1307015.61
Strontium (Sr) 5.32 5 105 0.836mg/L -1307015.32
Zinc (Zn) 5.54 5 111 0.773mg/L -1307015.54
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110145 -- 2016035701
Aluminum (Al) 5.71 5 114mg/L -1307015.71
Barium (Ba) 5.62 5 111mg/L -1307015.62
Boron (B) 6.68 5 107mg/L -1307016.68
Iron (Fe) 6.47 5 105mg/L -1307016.47
Manganese (Mn) 6.66 5 108mg/L -1307016.66
Strontium (Sr) 5.74 5 106mg/L -1307015.74
Zinc (Zn) 5.55 5 111mg/L -1307015.55
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110145 -- 2016035701
Aluminum (Al) 5.71 5 114 0.035mg/L -1307015.71
Barium (Ba) 5.62 5 111 0.018mg/L -1307015.62
Boron (B) 6.69 5 107 0.0187mg/L -1307016.69
Duke Energy Analytical Lab
Page 16 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110732 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110145 -- 2016035701
Iron (Fe) 6.49 5 105 0.267mg/L -1307016.49
Manganese (Mn) 6.67 5 109 0.147mg/L -1307016.67
Strontium (Sr) 5.76 5 107 0.432mg/L -1307015.76
Zinc (Zn) 5.56 5 111 0.216mg/L -1307015.56
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16110154 -- 2016035734
Aluminum (Al) 5.91 5 114mg/L -1307015.91
Barium (Ba) 5.73 5 111mg/L -1307015.73
Boron (B) 5.73 5 109mg/L -1307015.73
Iron (Fe) 5.34 5 106mg/L -1307015.34
Manganese (Mn) 6.04 5 112mg/L -1307016.04
Strontium (Sr) 5.36 5 104mg/L -1307015.36
Zinc (Zn) 5.6 5 112mg/L -1307015.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16110154 -- 2016035734
Aluminum (Al) 5.96 5 115 0.961mg/L -1307015.96
Barium (Ba) 5.77 5 112 0.738mg/L -1307015.77
Boron (B) 5.82 5 111 1.6mg/L -1307015.82
Iron (Fe) 5.39 5 107 0.902mg/L -1307015.39
Manganese (Mn) 6.08 5 113 0.854mg/L -1307016.08
Strontium (Sr) 5.39 5 105 0.592mg/L -1307015.39
Zinc (Zn) 5.65 5 113 0.889mg/L -1307015.65
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16110191 -- 2016035863
Aluminum (Al) 5.78 5 115mg/L -1307015.78
Barium (Ba) 5.57 5 111mg/L -1307015.57
Boron (B) 5.7 5 113mg/L -1307015.7
Iron (Fe) 5.56 5 107mg/L -1307015.56
Manganese (Mn) 6.06 5 113mg/L -1307016.06
Strontium (Sr) 5.75 5 109mg/L -1307015.75
Zinc (Zn) 5.54 5 111mg/L -1307015.54
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16110191 -- 2016035863
Aluminum (Al) 5.71 5 114 1.22mg/L -1307015.71
Barium (Ba) 5.55 5 111 0.397mg/L -1307015.55
Boron (B) 5.62 5 111 1.39mg/L -1307015.62
Iron (Fe) 5.48 5 105 1.6mg/L -1307015.48
Duke Energy Analytical Lab
Page 17 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110732 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16110191 -- 2016035863
Manganese (Mn) 5.96 5 111 1.75mg/L -1307015.96
Strontium (Sr) 5.69 5 108 1.01mg/L -1307015.69
Zinc (Zn) 5.41 5 108 2.38mg/L -1307015.41
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J16110227 -- 2016036010
Aluminum (Al) 5.47 5 109mg/L -1307015.47
Barium (Ba) 5.05 5 100mg/L -1307015.05
Boron (B) 10.3 5 97.6mg/L -13070110.3
Iron (Fe) 4.86 5 96.8mg/L -1307014.86
Manganese (Mn) 6.47 5 103mg/L -1307016.47
Strontium (Sr) 6.07 5 104mg/L -1307016.07
Zinc (Zn) 5.15 5 95.4mg/L -1307015.15
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J16110227 -- 2016036010
Aluminum (Al) 5.42 5 108 0.864mg/L -1307015.42
Barium (Ba) 5.01 5 99.6 0.8mg/L -1307015.01
Boron (B) 10.3 5 97.2 0.411mg/L -13070110.3
Iron (Fe) 4.85 5 96.7 0.165mg/L -1307014.85
Manganese (Mn) 6.44 5 103 0.582mg/L -1307016.44
Strontium (Sr) 6.08 5 104 0.193mg/L -1307016.08
Zinc (Zn) 5.13 5 95.1 0.357mg/L -1307015.13
Final QualifierDilMeasuredUnits:Parameter
MS # 6
% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036125
Aluminum (Al)5 110mg/L -1307015.69
Barium (Ba)5 104mg/L -1307015.21
Boron (B)5 104mg/L -1307015.21
Iron (Fe)5 99.7mg/L -1307014.99
Manganese (Mn)5 106mg/L -1307015.28
Strontium (Sr)5 102mg/L -1307015.33
Zinc (Zn)5 105mg/L -1307015.26
Final QualifierDilMeasuredUnits:Parameter
MSD # 6
RPD% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036125
Aluminum (Al)5 110 0.241mg/L -1307015.68
Barium (Ba)5 104 0.114mg/L -1307015.2
Boron (B)5 104 0.355mg/L -1307015.22
Iron (Fe)5 99.7 0.012mg/L -1307014.99
Manganese (Mn)5 105 0.171mg/L -1307015.27
Duke Energy Analytical Lab
Page 18 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110732 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 6
RPD% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036125
Strontium (Sr)5 101 0.262mg/L -1307015.31
Zinc (Zn)5 105 0.0723mg/L -1307015.25
Final QualifierDilMeasuredUnits:Parameter
MS # 7
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036318
Aluminum (Al)5 112mg/L -1307015.6
Barium (Ba)5 110mg/L -1307015.51
Boron (B)5 104mg/L -1307015.19
Iron (Fe)5 101mg/L -1307015.05
Manganese (Mn)5 105mg/L -1307015.59
Strontium (Sr)5 108mg/L -1307015.58
Zinc (Zn)5 103mg/L -1307015.15
Final QualifierDilMeasuredUnits:Parameter
MSD # 7
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036318
Aluminum (Al)5 110 1.31mg/L -1307015.52
Barium (Ba)5 107 2.13mg/L -1307015.4
Boron (B)5 107 2.9mg/L -1307015.34
Iron (Fe)5 98.8 1.89mg/L -1307014.95
Manganese (Mn)5 103 2.13mg/L -1307015.48
Strontium (Sr)5 106 1.62mg/L -1307015.49
Zinc (Zn)5 101 1.72mg/L -1307015.06
Final QualifierDilMeasuredUnits:Parameter
MS # 8
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Aluminum (Al)5 113mg/L -1307015.66
Barium (Ba)5 109mg/L -1307015.5
Boron (B)5 102mg/L -1307015.09
Iron (Fe)5 98.1mg/L -1307016.68
Manganese (Mn)5 104mg/L -1307016.11
Strontium (Sr)5 107mg/L -1307015.6
Zinc (Zn)5 101mg/L -1307015.05
Final QualifierDilMeasuredUnits:Parameter
MSD # 8
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Aluminum (Al)5 115 1.36mg/L -1307015.74
Barium (Ba)5 110 0.821mg/L -1307015.54
Boron (B)5 109 6.76mg/L -1307015.44
Iron (Fe)5 101 2.46mg/L -1307016.8
Manganese (Mn)5 106 2.22mg/L -1307016.22
Strontium (Sr)5 108 0.851mg/L -1307015.64
Duke Energy Analytical Lab
Page 19 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110732 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 8
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Zinc (Zn)5 103 2.18mg/L -1307015.16
Final QualifierDilMeasuredUnits:Parameter
MS # 9
% Recovery LCL UCLSpike
Parent Sample: J16110329 -- 2016036493
Aluminum (Al)5 114mg/L -1307015.72
Barium (Ba)5 108mg/L -1307015.52
Boron (B)5 108mg/L -1307015.42
Iron (Fe)5 101mg/L -1307015.33
Manganese (Mn)5mg/L -130701Not Tested
Strontium (Sr)5 106mg/L -1307016.23
Zinc (Zn)5 103mg/L -1307015.14
Final QualifierDilMeasuredUnits:Parameter
MSD # 9
RPD% Recovery LCL UCLSpike
Parent Sample: J16110329 -- 2016036493
Aluminum (Al)5 114 0.651mg/L -1307015.68
Barium (Ba)5 108 0.344mg/L -1307015.5
Boron (B)5 108 0.155mg/L -1307015.41
Iron (Fe)5 101 0.648mg/L -1307015.3
Manganese (Mn)5 105mg/L -1307015.52
Strontium (Sr)5 106 0.229mg/L -1307016.24
Zinc (Zn)5 102 1.01mg/L -1307015.09
Final QualifierDilMeasuredUnits:Parameter
MS # 10
% Recovery LCL UCLSpike
Parent Sample: J16110398 -- 2016036763
Aluminum (Al)5 112mg/L -1307015.6
Barium (Ba)5 105mg/L -1307015.31
Boron (B)5 109mg/L -1307015.44
Iron (Fe)5 100mg/L -1307016.67
Manganese (Mn)5 106mg/L -1307016.02
Strontium (Sr)5 106mg/L -1307015.49
Zinc (Zn)5 103mg/L -1307015.14
Final QualifierDilMeasuredUnits:Parameter
MSD # 10
RPD% Recovery LCL UCLSpike
Parent Sample: J16110398 -- 2016036763
Aluminum (Al)5 113mg/L -1307015.65
Barium (Ba)5 108mg/L -1307015.43
Boron (B)5 109mg/L -1307015.45
Iron (Fe)5 101mg/L -1307016.69
Manganese (Mn)5 107mg/L -1307016.05
Strontium (Sr)5 106mg/L -1307015.51
Zinc (Zn)5 103mg/L -1307015.15
Duke Energy Analytical Lab
Page 20 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16120085 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00419 mg/L -10.00419 0.01 < 1/2 RDL
Magnesium (Mg) 0.000036 mg/L -10.000036 0.005 < 1/2 RDL
Potassium (K) 0.0121 mg/L -10.0121 0.1 < 1/2 RDL
Sodium (Na) -0.00874 mg/L -1-0.00874 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.00328 mg/L -10.00328 0.01 < 1/2 RDL
Magnesium (Mg) 0.00125 mg/L -10.00125 0.005 < 1/2 RDL
Potassium (K) 0.0153 mg/L -10.0153 0.1 < 1/2 RDL
Sodium (Na) 0.00281 mg/L -10.00281 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Calcium (Ca) 0.0116 mg/L -10.0116 0.01 > RDL
Magnesium (Mg) 0.00336 mg/L -10.00336 0.005 > 1/2 RDL
Potassium (K) 0.039 mg/L -10.039 0.1 < 1/2 RDL
Sodium (Na) 0.0202 mg/L -10.0202 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 1.96 2 98.2mg/L -1158511.96
Magnesium (Mg) 1.93 2 96.5mg/L -1158511.93
Potassium (K) 3.85 4 96.3mg/L -1158513.85
Sodium (Na) 7.94 8.1 98.1mg/L -1158517.94
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 1.95 2 97.5mg/L -1158511.95
Magnesium (Mg) 1.93 2 96.3mg/L -1158511.93
Potassium (K) 3.82 4 95.5mg/L -1158513.82
Sodium (Na) 7.92 8.1 97.8mg/L -1158517.92
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Calcium (Ca) 1.96 2 97.8mg/L -1158511.96
Magnesium (Mg) 1.93 2 96.7mg/L -1158511.93
Potassium (K) 3.83 4 95.8mg/L -1158513.83
Sodium (Na) 7.94 8.1 98mg/L -1158517.94
Duke Energy Analytical Lab
Page 21 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16120085 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036125
Calcium (Ca) 22.4 5 87.2mg/L -13070122.4
Magnesium (Mg) 5.98 5 98.5mg/L -1307015.98
Potassium (K) 11.2 5 88.1mg/L -13070111.2
Sodium (Na) 20.2 5 90.4mg/L -13070120.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036125
Calcium (Ca) 22.7 5 91.6 4.97mg/L -13070122.7
Magnesium (Mg) 6.05 5 99.8 1.29mg/L -1307016.05
Potassium (K) 11.3 5 89.2 1.22mg/L -13070111.3
Sodium (Na) 20.4 5 94.5 4.5mg/L -13070120.4
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036133
Calcium (Ca) 21.6 5 90.6mg/L -13070121.6
Magnesium (Mg) 11.4 5 84.6mg/L -13070111.4
Potassium (K) 8.03 5 98.1mg/L -1307018.03
Sodium (Na) 32.4 5 88.6mg/L -13070132.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110262 -- 2016036133
Calcium (Ca) 21.7 5 91.6 1.19mg/L -13070121.7
Magnesium (Mg) 11.4 5 84.5 0.0473mg/L -13070111.4
Potassium (K) 8.08 5 99 0.893mg/L -1307018.08
Sodium (Na) 32.5 5 91.5 3.22mg/L -13070132.5
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036326
Calcium (Ca) 74.1 5 65.9mg/L -13070174.1
Magnesium (Mg) 20.7 5 82.2mg/L -13070120.7
Potassium (K) 9.39 5 96mg/L -1307019.39
Sodium (Na) 29.3 5 87.4mg/L -13070129.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036326
Calcium (Ca) 73.2 5 49.1 29.2mg/L -13070173.2
Magnesium (Mg) 20.4 5 77.3 6.22mg/L -13070120.4
Potassium (K) 9.28 5 93.9 2.23mg/L -1307019.28
Sodium (Na) 28.9 5 79.7 9.24mg/L -13070128.9
Duke Energy Analytical Lab
Page 22 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16120085 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16110329 -- 2016036493
Calcium (Ca) 91.4 5 72.6mg/L -13070191.4
Magnesium (Mg) 23.4 5 80.1mg/L -13070123.4
Potassium (K) 9.22 5 97.1mg/L -1307019.22
Sodium (Na) 22.3 5 91.4mg/L -13070122.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16110329 -- 2016036493
Calcium (Ca) 90.6 5 56.4 25mg/L -13070190.6
Magnesium (Mg) 23.3 5 77.5 3.33mg/L -13070123.3
Potassium (K) 9.16 5 95.9 1.24mg/L -1307019.16
Sodium (Na) 22.1 5 88 3.7mg/L -13070122.1
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J16110398 -- 2016036763
Calcium (Ca) 72.5 5 70.1mg/L -13070172.5
Magnesium (Mg) 24.3 5 58mg/L -13070124.3
Potassium (K) 9.74 5 95.5mg/L -1307019.74
Sodium (Na) 24.7 5 89.7mg/L -13070124.7
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J16110398 -- 2016036763
Calcium (Ca) 72.9 5 77.6 10mg/L -13070172.9
Magnesium (Mg) 24.5 5 61.8 6.27mg/L -13070124.5
Potassium (K) 9.8 5 96.5 1.1mg/L -1307019.8
Sodium (Na) 24.8 5 92 2.44mg/L -13070124.8
Final QualifierDilMeasuredUnits:Parameter
MS # 6
% Recovery LCL UCLSpike
Parent Sample: J16110448 -- 2016037004
Calcium (Ca) 65.7 5 92.4mg/L -13070165.7
Magnesium (Mg) 23.6 5 88.3mg/L -13070123.6
Potassium (K) 10.7 5 99mg/L -13070110.7
Sodium (Na) 23.4 5 96.9mg/L -13070123.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 6
RPD% Recovery LCL UCLSpike
Parent Sample: J16110448 -- 2016037004
Calcium (Ca) 64.5 5 68.2 30mg/L -13070164.5
Magnesium (Mg) 23.3 5 81.8 7.67mg/L -13070123.3
Potassium (K) 10.4 5 93.7 5.48mg/L -13070110.4
Sodium (Na) 23 5 88.3 9.31mg/L -13070123
Duke Energy Analytical Lab
Page 23 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110486 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.0015 mg/L -10.0015 0.005 < 1/2 RDL
Barium (Ba) -0.000226 mg/L -1-0.000226 0.005 < 1/2 RDL
Boron (B) 0.00123 mg/L -10.00123 0.05 < 1/2 RDL
Iron (Fe) 0.0024 mg/L -10.0024 0.01 < 1/2 RDL
Manganese (Mn) 0.000177 mg/L -10.000177 0.005 < 1/2 RDL
Strontium (Sr) 0.000166 mg/L -10.000166 0.005 < 1/2 RDL
Zinc (Zn) 0.00254 mg/L -10.00254 0.005 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.62 5 92.3mg/L -1158514.62
Barium (Ba) 4.8 5 96.1mg/L -1158514.8
Boron (B) 4.73 5 94.7mg/L -1158514.73
Iron (Fe) 4.74 5 94.9mg/L -1158514.74
Manganese (Mn) 4.62 5 92.3mg/L -1158514.62
Strontium (Sr) 4.72 5 94.5mg/L -1158514.72
Zinc (Zn) 4.66 5 93.3mg/L -1158514.66
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036318
Aluminum (Al) 4.47 5 89.1mg/L -1307014.47
Barium (Ba) 4.76 5 94.7mg/L -1307014.76
Boron (B) 4.73 5 94.3mg/L -1307014.73
Iron (Fe) 4.74 5 93.7mg/L -1307014.74
Manganese (Mn) 4.9 5 91.2mg/L -1307014.9
Strontium (Sr) 4.82 5 93mg/L -1307014.82
Zinc (Zn) 4.51 5 90mg/L -1307014.51
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036318
Aluminum (Al) 4.44 5 88.5 0.698mg/L -1307014.44
Barium (Ba) 4.73 5 94 0.721mg/L -1307014.73
Boron (B) 4.7 5 93.8 0.595mg/L -1307014.7
Iron (Fe) 4.7 5 92.9 0.9mg/L -1307014.7
Manganese (Mn) 4.85 5 90.2 1.1mg/L -1307014.85
Strontium (Sr) 4.78 5 92.1 0.994mg/L -1307014.78
Zinc (Zn) 4.46 5 89.2 0.982mg/L -1307014.46
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Aluminum (Al) 4.53 5 90.5mg/L -1307014.53
Duke Energy Analytical Lab
Page 24 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110486 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Barium (Ba) 4.78 5 94.6mg/L -1307014.78
Boron (B) 4.74 5 94.7mg/L -1307014.74
Iron (Fe) 6.08 5 91.4mg/L -1307016.08
Manganese (Mn) 5.4 5 90.5mg/L -1307015.4
Strontium (Sr) 4.85 5 92.1mg/L -1307014.85
Zinc (Zn) 4.51 5 90.3mg/L -1307014.51
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Aluminum (Al) 4.6 5 91.9 1.6mg/L -1307014.6
Barium (Ba) 4.84 5 95.9 1.45mg/L -1307014.84
Boron (B) 4.81 5 96.2 1.53mg/L -1307014.81
Iron (Fe) 6.12 5 92.3 0.937mg/L -1307016.12
Manganese (Mn) 5.43 5 91.3 0.792mg/L -1307015.43
Strontium (Sr) 4.94 5 93.7 1.76mg/L -1307014.94
Zinc (Zn) 4.6 5 92 1.89mg/L -1307014.6
Duke Energy Analytical Lab
Page 25 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110701 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.002 ug/L -1-0.002 1 < 1/2 RDL
Arsenic (As) 0.012 ug/L -10.012 1 < 1/2 RDL
Beryllium (Be) 0.047 ug/L -10.047 1 < 1/2 RDL
Cadmium (Cd) 0.001 ug/L -10.001 1 < 1/2 RDL
Chromium (Cr) 0.025 ug/L -10.025 1 < 1/2 RDL
Cobalt (Co) 0.005 ug/L -10.005 1 < 1/2 RDL
Copper (Cu) 0.003 ug/L -10.003 1 < 1/2 RDL
Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL
Molybdenum (Mo) 0.261 ug/L -10.261 1 < 1/2 RDL
Nickel (Ni) -0.042 ug/L -1-0.042 1 < 1/2 RDL
Selenium (Se) 0.003 ug/L -10.003 1 < 1/2 RDL
Thallium (Tl) Low Level 0.034 ug/L B210.034 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.001 ug/L -10.001 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.9 50 99.7ug/L -11585149.9
Arsenic (As) 49.8 50 99.5ug/L -11585149.8
Beryllium (Be) 50.3 50 101ug/L -11585150.3
Cadmium (Cd) 50.3 50 101ug/L -11585150.3
Chromium (Cr) 50.2 50 100ug/L -11585150.2
Cobalt (Co) 49.2 50 98.4ug/L -11585149.2
Copper (Cu) 50.9 50 102ug/L -11585150.9
Lead (Pb) 49.3 50 98.7ug/L -11585149.3
Molybdenum (Mo) 49.9 50 99.7ug/L -11585149.9
Nickel (Ni) 51.2 50 102ug/L -11585151.2
Selenium (Se) 47.8 50 95.6ug/L -11585147.8
Thallium (Tl) Low Level 44.9 50 89.9ug/L -11585144.9
Vanadium (V) Low Level 49.5 50 98.9ug/L -11585149.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036318
Antimony (Sb) 50.2 50 100ug/L -13070150.2
Arsenic (As) 50.2 50 99.9ug/L -13070150.2
Beryllium (Be) 55 50 110ug/L -13070155
Cadmium (Cd) 50.2 50 100ug/L -13070150.2
Chromium (Cr) 50.9 50 100ug/L -13070150.9
Cobalt (Co) 49.4 50 97.5ug/L -13070149.4
Copper (Cu) 50.8 50 100ug/L -13070150.8
Lead (Pb) 49.6 50 99ug/L -13070149.6
Duke Energy Analytical Lab
Page 26 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110701 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036318
Molybdenum (Mo) 55.6 50 101ug/L -13070155.6
Nickel (Ni) 51.5 50 99.9ug/L -13070151.5
Selenium (Se) 48.5 50 96.5ug/L -13070148.5
Thallium (Tl) Low Level 43.9 50 87.6ug/L -13070143.9
Vanadium (V) Low Level 51.6 50 100ug/L -13070151.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036318
Antimony (Sb) 50.1 50 99.8 0.208ug/L -13070150.1
Arsenic (As) 50.1 50 99.6 0.323ug/L -13070150.1
Beryllium (Be) 52.3 50 105 4.94ug/L -13070152.3
Cadmium (Cd) 50.4 50 101 0.34ug/L -13070150.4
Chromium (Cr) 51.1 50 101 0.432ug/L -13070151.1
Cobalt (Co) 49.3 50 97.4 0.0349ug/L -13070149.3
Copper (Cu) 50.8 50 101 0.125ug/L -13070150.8
Lead (Pb) 49.4 50 98.7 0.338ug/L -13070149.4
Molybdenum (Mo) 55.5 50 101 0.181ug/L -13070155.5
Nickel (Ni) 51.8 50 101 0.681ug/L -13070151.8
Selenium (Se) 47.4 50 94.4 2.2ug/L -13070147.4
Thallium (Tl) Low Level 43.7 50 87.2 0.552ug/L -13070143.7
Vanadium (V) Low Level 51.3 50 99.3 0.664ug/L -13070151.3
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Antimony (Sb) 52 50 104ug/L -13070152
Arsenic (As) 52.3 50 104ug/L -13070152.3
Beryllium (Be) 55.3 50 111ug/L -13070155.3
Cadmium (Cd) 51.7 50 103ug/L -13070151.7
Chromium (Cr) 52.7 50 105ug/L -13070152.7
Cobalt (Co) 50.8 50 101ug/L -13070150.8
Copper (Cu) 51.7 50 103ug/L -13070151.7
Lead (Pb) 51.1 50 102ug/L -13070151.1
Molybdenum (Mo) 55.8 50 106ug/L -13070155.8
Nickel (Ni) 53 50 106ug/L -13070153
Selenium (Se) 48.8 50 97.6ug/L -13070148.8
Thallium (Tl) Low Level 45.6 50 91.1ug/L -13070145.6
Vanadium (V) Low Level 52.2 50 104ug/L -13070152.2
Duke Energy Analytical Lab
Page 27 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110701 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036327
Antimony (Sb) 50.4 50 101 2.97ug/L -13070150.4
Arsenic (As) 50.6 50 101 3.38ug/L -13070150.6
Beryllium (Be) 54.6 50 109 1.19ug/L -13070154.6
Cadmium (Cd) 50.3 50 101 2.72ug/L -13070150.3
Chromium (Cr) 51.1 50 102 3.14ug/L -13070151.1
Cobalt (Co) 49.4 50 98.1 2.92ug/L -13070149.4
Copper (Cu) 50.3 50 101 2.59ug/L -13070150.3
Lead (Pb) 50.1 50 100 2.1ug/L -13070150.1
Molybdenum (Mo) 54.2 50 103 3.02ug/L -13070154.2
Nickel (Ni) 51.2 50 102 3.58ug/L -13070151.2
Selenium (Se) 48 50 96 1.68ug/L -13070148
Thallium (Tl) Low Level 45 50 90 1.19ug/L -13070145
Vanadium (V) Low Level 50.8 50 101 2.67ug/L -13070150.8
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Duke Energy Analytical Lab
Page 28 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110490 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.044 ug/L -1-0.044 1 < 1/2 RDL
Arsenic (As) -0.015 ug/L -1-0.015 1 < 1/2 RDL
Beryllium (Be) 0.051 ug/L -10.051 1 < 1/2 RDL
Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL
Chromium (Cr) 1.37 ug/L -11.37 1 > RDL
Cobalt (Co) 0.008 ug/L -10.008 1 < 1/2 RDL
Copper (Cu) 0.044 ug/L -10.044 1 < 1/2 RDL
Lead (Pb) -0.009 ug/L -1-0.009 1 < 1/2 RDL
Molybdenum (Mo) 0.032 ug/L -10.032 1 < 1/2 RDL
Nickel (Ni) -0.055 ug/L -1-0.055 1 < 1/2 RDL
Selenium (Se) -0.029 ug/L -1-0.029 1 < 1/2 RDL
Thallium (Tl) Low Level 0.002 ug/L -10.002 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.025 ug/L -10.025 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.9 50 99.9ug/L -11585149.9
Arsenic (As) 49.1 50 98.3ug/L -11585149.1
Beryllium (Be) 49.7 50 99.4ug/L -11585149.7
Cadmium (Cd) 50.6 50 101ug/L -11585150.6
Chromium (Cr) 50.1 50 100ug/L -11585150.1
Cobalt (Co) 49.5 50 99.1ug/L -11585149.5
Copper (Cu) 50.1 50 100ug/L -11585150.1
Lead (Pb) 49.4 50 98.8ug/L -11585149.4
Molybdenum (Mo) 49.6 50 99.3ug/L -11585149.6
Nickel (Ni) 50.9 50 102ug/L -11585150.9
Selenium (Se) 45.3 50 90.6ug/L -11585145.3
Thallium (Tl) Low Level 43.8 50 87.6ug/L -11585143.8
Vanadium (V) Low Level 50 50 100ug/L -11585150
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036319
Antimony (Sb) 51.6 50 103ug/L -13070151.6
Arsenic (As) 50.7 50 101ug/L -13070150.7
Beryllium (Be) 52.5 50 105ug/L -13070152.5
Cadmium (Cd) 51.1 50 102ug/L -13070151.1
Chromium (Cr) 60.2 50 104ug/L -13070160.2
Cobalt (Co) 49.2 50 97.7ug/L -13070149.2
Copper (Cu) 49.3 50 98ug/L -13070149.3
Lead (Pb) 50.9 50 102ug/L -13070150.9
Duke Energy Analytical Lab
Page 29 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110490 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036319
Molybdenum (Mo) 67 50 104ug/L -13070167
Nickel (Ni) 51.6 50 100ug/L -13070151.6
Selenium (Se) 46.5 50 91.5ug/L -13070146.5
Thallium (Tl) Low Level 44.7 50 89ug/L -13070144.7
Vanadium (V) Low Level 53.6 50 105ug/L -13070153.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110300 -- 2016036319
Antimony (Sb) 49.7 50 98.8 3.83ug/L -13070149.7
Arsenic (As) 48.3 50 96.1 4.8ug/L -13070148.3
Beryllium (Be) 48.8 50 97.5 7.41ug/L -13070148.8
Cadmium (Cd) 48.7 50 97.4 4.86ug/L -13070148.7
Chromium (Cr) 56.9 50 97.1 6.67ug/L -13070156.9
Cobalt (Co) 46.9 50 92.9 5ug/L -13070146.9
Copper (Cu) 47.2 50 93.8 4.42ug/L -13070147.2
Lead (Pb) 48.8 50 97.6 4.23ug/L -13070148.8
Molybdenum (Mo) 63.9 50 97.3 6.17ug/L -13070163.9
Nickel (Ni) 49.5 50 95.9 4.13ug/L -13070149.5
Selenium (Se) 45.3 50 89 2.76ug/L -13070145.3
Thallium (Tl) Low Level 43.5 50 86.6 2.79ug/L -13070143.5
Vanadium (V) Low Level 50.4 50 98.6 6.28ug/L -13070150.4
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110328 -- 2016036486
Antimony (Sb) 50.6 50 101ug/L -13070150.6
Arsenic (As) 49.4 50 98.8ug/L -13070149.4
Beryllium (Be) 52.5 50 105ug/L -13070152.5
Cadmium (Cd) 50.7 50 101ug/L -13070150.7
Chromium (Cr) 50.9 50 101ug/L -13070150.9
Cobalt (Co) 48.3 50 96.5ug/L -13070148.3
Copper (Cu) 49.7 50 98.3ug/L -13070149.7
Lead (Pb) 49.7 50 99.4ug/L -13070149.7
Molybdenum (Mo) 54 50 99.9ug/L -13070154
Nickel (Ni) 53.9 50 100ug/L -13070153.9
Selenium (Se) 43.7 50 87.4ug/L -13070143.7
Thallium (Tl) Low Level 46.1 50 92.3ug/L -13070146.1
Vanadium (V) Low Level 51.6 50 102ug/L -13070151.6
Duke Energy Analytical Lab
Page 30 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110490 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110328 -- 2016036486
Antimony (Sb) 50.6 50 101 0.0732ug/L -13070150.6
Arsenic (As) 50 50 99.9 1.16ug/L -13070150
Beryllium (Be) 55 50 110 4.73ug/L -13070155
Cadmium (Cd) 50.9 50 102 0.406ug/L -13070150.9
Chromium (Cr) 51.2 50 102 0.558ug/L -13070151.2
Cobalt (Co) 48.5 50 96.9 0.403ug/L -13070148.5
Copper (Cu) 49.8 50 98.4 0.0956ug/L -13070149.8
Lead (Pb) 50.1 50 100 0.816ug/L -13070150.1
Molybdenum (Mo) 54.5 50 101 0.946ug/L -13070154.5
Nickel (Ni) 53.7 50 99.8 0.316ug/L -13070153.7
Selenium (Se) 43.5 50 87 0.472ug/L -13070143.5
Thallium (Tl) Low Level 46.4 50 92.9 0.633ug/L -13070146.4
Vanadium (V) Low Level 51.7 50 103 0.27ug/L -13070151.7
Duke Energy Analytical Lab
Page 31 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110398 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16100290 -- 2016032881
TDS 3.17mg/L -1653
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16100290 -- 2016032884
TDS 0.236mg/L -1424
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 95mg/L -11090195
Duke Energy Analytical Lab
Page 32 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110676 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.004 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.003 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
TOC mg/L -10.08 0.1 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 98.3mg/L -1208013.54
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 94.3 4.1mg/L -1208013.46
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 97mg/L -1208012.94
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 100 3.15mg/L -1208013
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 99.8mg/L -1208014.14
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 95.5 4.41mg/L -1208014.05
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 101mg/L -1158512.89
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.93
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.93
Duke Energy Analytical Lab
Page 33 of 66
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110328
Q16110400 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10.2 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16110173 -- 2016035790
TSS 3.64mg/L -15.6
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16110173 -- 2016035791
TSS 0mg/L -15.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 102mg/L -11090151.2
Duke Energy Analytical Lab
Page 34 of 66
#=CL#
November 21, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92319474
92319474
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16110328
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 11, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 19
Duke Energy Analytical Lab
Page 35 of 66
#=CP#
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Pace Project No.:
Project:
92319474
J16110328
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Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Duke Energy Analytical Lab
Page 36 of 66
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92319474
J16110328
Lab ID Sample ID Matrix Date Collected Date Received
92319474001 2016036486 Water 11/09/16 08:35 11/11/16 13:15
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Duke Energy Analytical Lab
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92319474
J16110328
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92319474001 2016036486 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 38 of 66
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92319474
J16110328
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92319474001 2016036486
Alkalinity,Bicarbonate (CaCO3)66.4 mg/L 11/14/16 16:115.0SM 2320B
Alkalinity, Total as CaCO3 66.4 mg/L 11/14/16 16:115.0SM 2320B
Chromium, Hexavalent 0.22 ug/L 11/19/16 15:020.025EPA 218.7
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 39 of 66
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92319474
J16110328
Method:
Client:Duke Energy
RSK 175 Modified
Date:November 21, 2016
Description:RSK 175 Headspace
General Information:
1 sample was analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Duke Energy Analytical Lab
Page 40 of 66
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92319474
J16110328
Method:
Client:Duke Energy
SM 2320B
Date:November 21, 2016
Description:2320B Alkalinity
General Information:
1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
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Duke Energy Analytical Lab
Page 41 of 66
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92319474
J16110328
Method:
Client:Duke Energy
SM 4500-S2D
Date:November 21, 2016
Description:4500S2D Sulfide Water
General Information:
1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 336797
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92319243006,92319243007
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1867597)
• Sulfide
• MSD (Lab ID: 1867598)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
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Duke Energy Analytical Lab
Page 42 of 66
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92319474
J16110328
Method:
Client:Duke Energy
EPA 218.7
Date:November 21, 2016
Description:Hexavalent Chromium by IC
General Information:
1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 333512
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92319496005,92319499001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1785702)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
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Duke Energy Analytical Lab
Page 43 of 66
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92319474
J16110328
Sample:2016036486 Lab ID:92319474001 Collected:11/09/16 08:35 Received:11/11/16 13:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 11/16/16 12:34 74-82-8 N210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)66.4 mg/L 11/14/16 16:115.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/14/16 16:115.0 1
Alkalinity, Total as CaCO3 66.4 mg/L 11/14/16 16:115.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 11/14/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.22 ug/L 11/19/16 15:02 18540-29-90.025 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/21/2016 02:08 PM
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[phone]
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Duke Energy Analytical Lab
Page 44 of 66
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92319474
J16110328
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
337194
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92319474001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1869891
Associated Lab Samples:92319474001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N211/16/16 11:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1869892LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 322 N23968170-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1869893MATRIX SPIKE SAMPLE:
MSSpike
Result
92319499001
Methane ug/L 466 N239611570-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92319499002
1869894SAMPLE DUPLICATE:
Methane ug/L ND N22014.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/21/2016 02:08 PM
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[phone]
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Duke Energy Analytical Lab
Page 45 of 66
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92319474
J16110328
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
336744
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92319474001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1867364
Associated Lab Samples:92319474001
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 11/14/16 10:15
Alkalinity, Total as CaCO3 mg/L ND 5.0 11/14/16 10:15
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 11/14/16 10:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1867365LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.250 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1867366MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92319351021
1867367
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-12098 1 255083.0 134 132
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1867368MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92319473006
1867369
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 106 80-120105 0 2550235287287
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/21/2016 02:08 PM
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Huntersville, NC 28078
[phone]
Page 12 of 19
Duke Energy Analytical Lab
Page 46 of 66
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92319474
J16110328
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
336797
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92319474001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1867593
Associated Lab Samples:92319474001
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 11/14/16 15:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1867594LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.45.5 90 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1867595MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92319243006
1867596
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 89 80-12089 0 10.5ND 0.45 0.44
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1867597MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92319243007
1867598
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 52 80-12052 0 10.5ND 0.33 0.33
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/21/2016 02:08 PM
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Duke Energy Analytical Lab
Page 47 of 66
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92319474
J16110328
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
333512
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92319474001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1785698
Associated Lab Samples:92319474001
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.025 11/18/16 20:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1785699LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.075.075 100 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1785700MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92319496005
1785701
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .75 99 85-11593 6 20.75ND 0.74 0.70
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1785702MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92319499001
1785703
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 125 85-115109 3 20.0250.085 0.12 0.11
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/21/2016 02:08 PM
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Duke Energy Analytical Lab
Page 48 of 66
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92319474
J16110328
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 49 of 66
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92319474
J16110328
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92319474001 3371942016036486RSK 175 Modified
92319474001 3367442016036486SM 2320B
92319474001 3367972016036486SM 4500-S2D
92319474001 3335122016036486EPA 218.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/21/2016 02:08 PM
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Duke Energy Analytical Lab
Page 50 of 66
Page 17 of 19
Duke Energy Analytical Lab
Page 51 of 66
Page 18 of 19
Duke Energy Analytical Lab
Page 52 of 66
Page 19 of 19
Duke Energy Analytical Lab
Page 53 of 66

December 01, 2016

Anne Pridgeon
Duke Energy
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 410503
SDG: J16110328

Dear Anne Pridgeon:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on November 11, 2016. This original data report has been prepared and reviewed in
accordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944
Enclosures
Page 1 of 12
Chelsea Seagle for
Duke Energy Analytical Lab
Page 54 of 66
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16110328 GEL Work Order: 410503
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for but not detected above the Lc
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 12
Duke Energy Analytical Lab
Page 55 of 66
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: December 1, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1616051
1616051
1618292
1616416
1142
0852
1133
0825
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
11/28/16
11/29/16
11/30/16
12/01/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Anne PridgeonContact:
Duke EnergyCompany :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
410503001
Water
09-NOV-16 08:35
11-NOV-16
2016036486 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.975
0.704
1
2
3
4
U
U
U
J
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
0.00002
ND
0.915
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"72.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 11/15/16 16160500845SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 12
Duke Energy Analytical Lab
Page 56 of 66
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1616051Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Anne PridgeonContact:
Duke Energy
13339 Hagers Ferry Road
Huntersville, North Carolina
December 1, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 11/29/16 08:53
11/28/16 11:44
11/28/16 11:41
11/29/16 08:50
11/29/16 08:49
11/28/16 11:39
11/28/16 11:45
11/29/16 08:55
11/29/16 08:57
QC
ND
ND
ND
ND
0.0486
0.000522
0.000622
0.00499
ND
ND
ND
ND
0.0485
0.000534
0.000631
0.00501
ND
NOM Sample
ND
ND
0.00002
ND
ND
ND
ND
0.00002
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203669785 410503001
QC1203669784
QC1203669788
QC1203669783
QC1203669786 410503001
QC1203669789 410503001
QC1203669787 410503001
N/A
N/A
200
N/A
N/A
REC%
97.9
104
113
99.8
97.6
107
114
99.7
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
410503Workorder:
Mail Code: MGO3A2
U
U
J
U
U
U
U
J
U
^
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1616051
1618292
1616416
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
11/29/16 08:57
11/28/16 11:46
11/30/16 11:33
11/30/16 10:13
11/30/16 10:13
12/01/16 08:55
12/01/16 09:25
12/01/16 08:55
12/01/16 08:55
QC
ND
ND
ND
1.33
7.92
0.0831
0.189
26.4
0.617
139
NOM Sample
ND
0.020
ND
0.476
0.0432
0.0432
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
N/A
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203675344 410509014
QC1203675345
QC1203675343
QC1203670615 410504010
QC1203670617
QC1203670614
QC1203670616 410504010
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
94.6
N/A
REC%
110
108
114
7.19
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
410503Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
J
U
U
U
U
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
410503Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for but not detected above the Lc
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16110328
Work Order #: 410503

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1616051

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1616050
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
410503001 2016036486
1203669783 Method Blank (MB)ICP-MS
1203669784 Laboratory Control Sample (LCS)
1203669788 Laboratory Control Sample (LCS)
1203669787 410503001(2016036486L) Serial Dilution (SD)
1203669785 410503001(2016036486D) Sample Duplicate (DUP)
1203669786 410503001(2016036486S) Matrix Spike (MS)
1203669789 410503001(2016036486S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1618292
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
410503001 2016036486
1203675343 Method Blank (MB)
1203675344 410509014(NonSDG) Sample Duplicate (DUP)
1203675345 Laboratory Control Sample (LCS)
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The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Recounts
Sample 410503001 (2016036486) was recounted to verify sample result. The second count is reported. Sample
1203675344 (Non SDG 410509014DUP) was recounted due to high relative percent difference/relative error
ratio. The recount is reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1616416
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
410503001 2016036486
1203670614 Method Blank (MB)
1203670615 410504010(2016036498) Sample Duplicate (DUP)
1203670616 410504010(2016036498) Matrix Spike (MS)
1203670617 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203670616 (2016036498MS), aliquot was reduced to conserve sample volume.

Certification Statement

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Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA170010
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-21
VT87156
460202
C780
997404
List of current GEL Certifications as of 01 December 2016
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Duke Energy Analytical Lab
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