NC0038377_J16100368report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16100368
Project Name:MAYO STEAM - ABGW
Lab Contact:Anne Pridgeon
Date:11/17/2016
Customer Address:Mayo Steam Plant
Customer Name(s):J. TOEPFER, T. HUNSUCKER
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 75
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016033268 MAYO STEAM 02-Nov-16 2:03 PM Kaitlyn Fox CW-1
2016033269 MAYO STEAM 02-Nov-16 1:43 PM Kaitlyn Fox CW-1D
2016033270 MAYO STEAM 03-Nov-16 1:51 PM Kaitlyn Fox CW-2
2016033271 MAYO STEAM 03-Nov-16 1:32 PM Kaitlyn Fox CW-2D
2016033272 MAYO STEAM 02-Nov-16 2:50 PM Kaitlyn Fox CW-3
2016033273 MAYO STEAM 03-Nov-16 9:25 AM Kaitlyn Fox CW-4
2016033274 MAYO STEAM 02-Nov-16 3:48 PM Kaitlyn Fox CW-5
2016033275 MAYO STEAM 03-Nov-16 1:35 PM Kaitlyn Fox CW-6
2016033276 MAYO STEAM 02-Nov-16 11:43 AM Kaitlyn Fox BG-1
2016033277 MAYO STEAM 02-Nov-16 9:55 AM Kaitlyn Fox BG-2
2016033278 MAYO STEAM 02-Nov-16 9:55 AM Kaitlyn Fox DUP BG-2
2016033279 MAYO STEAM 02-Nov-16 10:20 AM Kaitlyn Fox FIELD BLANK
12 Total Samples
Duke Energy Analytical Lab
Page 2 of 75
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:11/17/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033268
Collection Date:02-Nov-16 2:03 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 300.0 11/03/2016 15:14 GHUTCHI110
Nitrate 6.2 mg/L EPA 300.0 11/03/2016 15:14 GHUTCHI110
Nitrate as N 1.4 mg-N/L EPA 300.0 11/03/2016 15:14 GHUTCHI0.023 1
Sulfate 9.4 mg/L EPA 300.0 11/03/2016 15:14 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:09 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.103 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.05 1
Calcium (Ca)9.58 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Iron (Fe)0.105 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.01 1
Magnesium (Mg)4.07 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Manganese (Mn)0.010 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Potassium (K)1.11 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.1 1
Sodium (Na)16.7 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.05 1
Strontium (Sr)0.070 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 11/13/2016 17:35 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR0.2 1
Vanadium (V) Low Level 0.698 ug/L EPA 200.8 11/08/2016 01:44 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 4 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033268
Collection Date:02-Nov-16 2:03 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 5 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033269
Collection Date:02-Nov-16 1:43 PM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.5 mg/L EPA 300.0 11/03/2016 16:46 GHUTCHI0.2 2
Nitrate 1.1 mg/L EPA 300.0 11/03/2016 16:46 GHUTCHI0.2 2
Nitrate as N 0.25 mg-N/L EPA 300.0 11/03/2016 16:46 GHUTCHI0.023 1
Sulfate 2.6 mg/L EPA 300.0 11/03/2016 16:46 GHUTCHI0.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:17 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.05 1
Calcium (Ca)47.7 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Iron (Fe)0.014 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.01 1
Magnesium (Mg)9.16 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Manganese (Mn)0.019 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Potassium (K)2.16 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.1 1
Sodium (Na)13.0 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.05 1
Strontium (Sr)0.177 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 17:23 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Molybdenum (Mo)22.3 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR0.2 1
Vanadium (V) Low Level 1.19 ug/L EPA 200.8 11/08/2016 01:51 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 6 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033269
Collection Date:02-Nov-16 1:43 PM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 7 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033270
Collection Date:03-Nov-16 1:51 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 58 mg/L EPA 300.0 11/04/2016 14:18 GHUTCHI220
Nitrate 0.13 mg/L EPA 300.0 11/04/2016 14:18 GHUTCHI0.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 11/04/2016 14:18 GHUTCHI0.023 1
Sulfate 37 mg/L EPA 300.0 11/04/2016 14:18 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:19 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Barium (Ba)0.131 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Boron (B)0.902 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.05 1
Calcium (Ca)19.2 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.01 1
Magnesium (Mg)8.58 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Manganese (Mn)0.367 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Potassium (K)2.13 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.1 1
Sodium (Na)18.3 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.05 1
Strontium (Sr)0.269 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 11/13/2016 17:39 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 11/08/2016 01:59 CWSPEN30.3 1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 8 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033270
Collection Date:03-Nov-16 1:51 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 9 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033271
Collection Date:03-Nov-16 1:32 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 44 mg/L EPA 300.0 11/04/2016 13:09 GHUTCHI220
Nitrate 0.13 mg/L EPA 300.0 11/04/2016 13:09 GHUTCHI0.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 11/04/2016 13:09 GHUTCHI0.023 1
Sulfate 45 mg/L EPA 300.0 11/04/2016 13:09 GHUTCHI220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:22 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.562 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Barium (Ba)0.035 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Boron (B)0.440 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.05 1
Calcium (Ca)47.1 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Iron (Fe)0.303 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.01 1
Magnesium (Mg)7.27 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Manganese (Mn)0.077 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Potassium (K)3.10 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.1 1
Sodium (Na)18.8 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.05 1
Strontium (Sr)0.295 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 11/13/2016 17:43 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR0.2 1
Vanadium (V) Low Level 0.808 ug/L EPA 200.8 11/08/2016 01:13 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 10 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033271
Collection Date:03-Nov-16 1:32 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 15 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 11 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033272
Collection Date:02-Nov-16 2:50 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 92 mg/L EPA 300.0 11/03/2016 17:09 GHUTCHI550
Nitrate 1.5 mg/L EPA 300.0 11/03/2016 17:09 GHUTCHI110
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/03/2016 17:09 GHUTCHI0.023 1
Sulfate 16 mg/L EPA 300.0 11/03/2016 17:09 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:24 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.080 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Barium (Ba)0.013 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.05 1
Calcium (Ca)62.7 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Iron (Fe)0.074 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.01 1
Magnesium (Mg)7.45 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Manganese (Mn)0.006 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Potassium (K)4.18 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.1 1
Sodium (Na)40.7 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.05 1
Strontium (Sr)0.314 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 17:47 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR0.2 1
Vanadium (V) Low Level 1.59 ug/L EPA 200.8 11/08/2016 02:07 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 400 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 12 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033272
Collection Date:02-Nov-16 2:50 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 13 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033273
Collection Date:03-Nov-16 9:25 AM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.4 mg/L EPA 300.0 11/04/2016 11:37 GHUTCHI110
Nitrate 0.50 mg/L EPA 300.0 11/04/2016 11:37 GHUTCHI0.1 1
Nitrate as N 0.11 mg-N/L EPA 300.0 11/04/2016 11:37 GHUTCHI0.023 1
Sulfate 27 mg/L EPA 300.0 11/04/2016 11:37 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:26 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.183 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Barium (Ba)0.031 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.05 1
Calcium (Ca)12.5 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Iron (Fe)0.128 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.01 1
Magnesium (Mg)3.61 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Manganese (Mn)0.010 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Potassium (K)1.15 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.1 1
Sodium (Na)16.8 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.05 1
Strontium (Sr)0.159 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 17:51 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR0.2 1
Vanadium (V) Low Level 1.24 ug/L EPA 200.8 11/08/2016 02:14 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 14 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033273
Collection Date:03-Nov-16 9:25 AM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 15 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033274
Collection Date:02-Nov-16 3:48 PM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 38 mg/L EPA 300.0 11/03/2016 17:55 GHUTCHI110
Nitrate < 1 mg/L EPA 300.0 11/03/2016 17:55 GHUTCHI110
Nitrate as N 0.10 mg-N/L EPA 300.0 11/03/2016 17:55 GHUTCHI0.023 1
Sulfate 5.4 mg/L EPA 300.0 11/03/2016 17:55 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:29 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Barium (Ba)0.055 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.05 1
Calcium (Ca)54.0 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Iron (Fe)0.609 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.01 1
Magnesium (Mg)7.68 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Manganese (Mn)0.776 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Potassium (K)5.86 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.1 1
Sodium (Na)18.6 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.05 1
Strontium (Sr)0.167 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 17:55 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 11/08/2016 03:08 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 290 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 16 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033274
Collection Date:02-Nov-16 3:48 PM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 17 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033275
Collection Date:03-Nov-16 1:35 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 85 mg/L EPA 300.0 11/04/2016 13:55 GHUTCHI220
Nitrate 0.13 mg/L EPA 300.0 11/04/2016 13:55 GHUTCHI0.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 11/04/2016 13:55 GHUTCHI0.023 1
Sulfate 39 mg/L EPA 300.0 11/04/2016 13:55 GHUTCHI220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:31 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.125 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Barium (Ba)0.034 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.05 1
Calcium (Ca)97.2 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Iron (Fe)0.371 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.01 1
Magnesium (Mg)18.7 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Manganese (Mn)0.988 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Potassium (K)10.4 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.1 1
Sodium (Na)37.5 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.05 1
Strontium (Sr)0.321 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 11/13/2016 17:59 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Molybdenum (Mo)4.15 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 11/08/2016 02:45 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 530 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 18 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033275
Collection Date:03-Nov-16 1:35 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 15 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 19 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033276
Collection Date:02-Nov-16 11:43 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 300.0 11/03/2016 18:41 GHUTCHI110
Nitrate 3.7 mg/L EPA 300.0 11/03/2016 18:41 GHUTCHI0.1 1
Nitrate as N 0.82 mg-N/L EPA 300.0 11/03/2016 18:41 GHUTCHI0.023 1
Sulfate 0.27 mg/L EPA 300.0 11/03/2016 18:41 GHUTCHI0.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:39 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.032 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Barium (Ba)0.085 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.05 1
Calcium (Ca)12.1 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Iron (Fe)0.032 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.01 1
Magnesium (Mg)3.17 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Manganese (Mn)0.007 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Potassium (K)1.28 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.1 1
Sodium (Na)11.5 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.05 1
Strontium (Sr)0.172 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 18:03 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR0.2 1
Vanadium (V) Low Level 3.62 ug/L EPA 200.8 11/08/2016 02:53 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 20 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033276
Collection Date:02-Nov-16 11:43 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 21 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033277
Collection Date:02-Nov-16 9:55 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 11/03/2016 19:04 GHUTCHI110
Nitrate < 1 mg/L EPA 300.0 11/03/2016 19:04 GHUTCHI110
Nitrate as N 0.11 mg-N/L EPA 300.0 11/03/2016 19:04 GHUTCHI0.023 1
Sulfate 5.1 mg/L EPA 300.0 11/03/2016 19:04 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:46 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Barium (Ba)0.046 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.05 1
Calcium (Ca)53.2 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Iron (Fe)0.186 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.01 1
Magnesium (Mg)10.8 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Manganese (Mn)0.124 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Potassium (K)3.37 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.1 1
Sodium (Na)43.6 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.05 1
Strontium (Sr)0.302 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 18:31 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR0.2 1
Vanadium (V) Low Level 3.45 ug/L EPA 200.8 11/08/2016 03:01 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS 350 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 22 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033277
Collection Date:02-Nov-16 9:55 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 23 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033278
Collection Date:02-Nov-16 9:55 AM
Site:DUP BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 11/03/2016 19:27 GHUTCHI110
Nitrate < 1 mg/L EPA 300.0 11/03/2016 19:27 GHUTCHI110
Nitrate as N 0.12 mg-N/L EPA 300.0 11/03/2016 19:27 GHUTCHI0.023 1
Sulfate 5.2 mg/L EPA 300.0 11/03/2016 19:27 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:49 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.046 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Barium (Ba)0.047 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.05 1
Calcium (Ca)55.1 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Iron (Fe)0.185 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.01 1
Magnesium (Mg)11.0 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Manganese (Mn)0.129 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Potassium (K)3.47 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.1 1
Sodium (Na)45.1 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.05 1
Strontium (Sr)0.312 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 18:35 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN30.2 1
Vanadium (V) Low Level 3.45 ug/L EPA 200.8 11/08/2016 03:39 CWSPEN30.3 1
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 24 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033278
Collection Date:02-Nov-16 9:55 AM
Site:DUP BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 25 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033279
Collection Date:02-Nov-16 10:20 AM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 11/03/2016 19:50 GHUTCHI0.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/03/2016 19:50 GHUTCHI0.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/03/2016 19:50 GHUTCHI0.023 1
Sulfate < 0.1 mg/L EPA 300.0 11/03/2016 19:50 GHUTCHI0.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/14/2016 14:51 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.05 1
Calcium (Ca)< 0.01 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.05 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/13/2016 18:39 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 11/08/2016 03:47 PARMSTR0.3 1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 11/08/2016 16:33251
Duke Energy Analytical Lab
Page 26 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
2016033279
Collection Date:02-Nov-16 10:20 AM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 11/07/2016 12:36 HGRUVER51
Duke Energy Analytical Lab
Page 27 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110111 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0 mg/L -10 0.1 < 1/2 RDL
Nitrate 0 mg/L -10 0.1 < 1/2 RDL
Sulfate 0.027 mg/L -10.027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 4.14 2 106mg/L -1208014.14
Nitrate 2.79 2 109mg/L -1208012.79
Sulfate 3.13 2 110mg/L -1208013.13
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 4.1 2 104 2.19mg/L -1208014.1
Nitrate 2.74 2 106 2.19mg/L -1208012.74
Sulfate 3.09 2 107 2.16mg/L -1208013.09
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 2.01 2 101mg/L -1208012.01
Nitrate 2.02 2 101mg/L -1208012.02
Sulfate 2.03 2 101mg/L -1208012.03
Duke Energy Analytical Lab
Page 28 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110139 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0 mg/L -10 0.1 < 1/2 RDL
Nitrate 0 mg/L -10 0.1 < 1/2 RDL
Sulfate 0.027 mg/L -10.027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 2.94 2 105mg/L -1208012.94
Nitrate 2.13 2 102mg/L -1208012.13
Sulfate 4.76 2 101mg/L -1208014.76
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 2.92 2 104 1mg/L -1208012.92
Nitrate 2.11 2 101 0.981mg/L -1208012.11
Sulfate 4.73 2 99.3 1.3mg/L -1208014.73
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 2.01 2 101mg/L -1109012.01
Nitrate 2.02 2 101mg/L -1109012.02
Sulfate 2.03 2 101mg/L -1109012.03
Duke Energy Analytical Lab
Page 29 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110428 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.006 ug/L -1-0.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.03 2 101ug/L -1158512.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033268
Mercury (Hg) 0.988 1 100ug/L -1307010.988
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033268
Mercury (Hg) 0.99 1 100 0.2ug/L -1307010.99
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033276
Mercury (Hg) 0.977 1 97.3ug/L -1307010.977
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033276
Mercury (Hg) 0.965 1 96.1 1.24ug/L -1307010.965
Duke Energy Analytical Lab
Page 30 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110198 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000757 mg/L -10.000757 0.005 < 1/2 RDL
Barium (Ba) -0.000429 mg/L -1-0.000429 0.005 < 1/2 RDL
Boron (B) -0.000703 mg/L -1-0.000703 0.05 < 1/2 RDL
Calcium (Ca) 0.000659 mg/L -10.000659 0.01 < 1/2 RDL
Chromium (Cr) -0.000365 mg/L -1-0.000365 0.005 < 1/2 RDL
Copper (Cu) -0.00265 mg/L -1-0.00265 0.005 < 1/2 RDL
Iron (Fe) 0.000162 mg/L -10.000162 0.01 < 1/2 RDL
Magnesium (Mg) -0.000198 mg/L -1-0.000198 0.005 < 1/2 RDL
Manganese (Mn) -0.000036 mg/L -1-0.000036 0.005 < 1/2 RDL
Nickel (Ni) -0.000263 mg/L -1-0.000263 0.005 < 1/2 RDL
Potassium (K) -0.00743 mg/L -1-0.00743 0.1 < 1/2 RDL
Sodium (Na) -0.000454 mg/L -1-0.000454 0.05 < 1/2 RDL
Strontium (Sr) -0.000128 mg/L -1-0.000128 0.005 < 1/2 RDL
Zinc (Zn) 0.000317 mg/L -10.000317 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.03 5 101mg/L -1158515.03
Barium (Ba) 5.09 5 102mg/L -1158515.09
Boron (B) 5.09 5 102mg/L -1158515.09
Calcium (Ca) 5.06 5 101mg/L -1158515.06
Chromium (Cr) 4.94 5 98.7mg/L -1158514.94
Copper (Cu) 5 5 100mg/L -1158515
Iron (Fe) 5.13 5 103mg/L -1158515.13
Magnesium (Mg) 5.02 5 100mg/L -1158515.02
Manganese (Mn) 5.01 5 100mg/L -1158515.01
Nickel (Ni) 5.03 5 101mg/L -1158515.03
Potassium (K) 5 5 100mg/L -1158515
Sodium (Na) 4.89 5 97.9mg/L -1158514.89
Strontium (Sr) 5.12 5 102mg/L -1158515.12
Zinc (Zn) 4.97 5 99.3mg/L -1158514.97
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033269
Aluminum (Al) 4.93 5 98.4mg/L -1307014.93
Barium (Ba) 5.01 5 100mg/L -1307015.01
Boron (B) 5.11 5 102mg/L -1307015.11
Calcium (Ca) 53 5 105mg/L -13070153
Chromium (Cr) 4.86 5 97.2mg/L -1307014.86
Copper (Cu) 4.94 5 98.8mg/L -1307014.94
Duke Energy Analytical Lab
Page 31 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110198 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033269
Iron (Fe) 5.06 5 101mg/L -1307015.06
Magnesium (Mg) 13.9 5 94.1mg/L -13070113.9
Manganese (Mn) 4.94 5 98.4mg/L -1307014.94
Nickel (Ni) 4.92 5 98.3mg/L -1307014.92
Potassium (K) 7.16 5 100mg/L -1307017.16
Sodium (Na) 17.6 5 92.2mg/L -13070117.6
Strontium (Sr) 5.3 5 102mg/L -1307015.3
Zinc (Zn) 4.84 5 96.7mg/L -1307014.84
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033269
Aluminum (Al) 5 5 99.6 1.27mg/L -1307015
Barium (Ba) 5.08 5 102 1.39mg/L -1307015.08
Boron (B) 5.11 5 102 0.0979mg/L -1307015.11
Calcium (Ca) 53.5 5 115 8.91mg/L -13070153.5
Chromium (Cr) 4.94 5 98.8 1.63mg/L -1307014.94
Copper (Cu) 5 5 100 1.25mg/L -1307015
Iron (Fe) 5.12 5 102 1.1mg/L -1307015.12
Magnesium (Mg) 14 5 97.2 3.22mg/L -13070114
Manganese (Mn) 4.99 5 99.4 1.03mg/L -1307014.99
Nickel (Ni) 4.97 5 99.5 1.17mg/L -1307014.97
Potassium (K) 7.27 5 102 2.12mg/L -1307017.27
Sodium (Na) 17.9 5 96.4 4.39mg/L -13070117.9
Strontium (Sr) 5.24 5 101 1.08mg/L -1307015.24
Zinc (Zn) 4.92 5 98.3 1.7mg/L -1307014.92
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110107 -- 2016035510
Aluminum (Al) 4.79 5 95.7mg/L -1307014.79
Barium (Ba) 5.02 5 99.8mg/L -1307015.02
Boron (B) 6.01 5 102mg/L -1307016.01
Calcium (Ca) 122 5 0mg/L -130701122
Chromium (Cr) 4.78 5 95.5mg/L -1307014.78
Copper (Cu) 4.87 5 97.6mg/L -1307014.87
Iron (Fe) 7.78 5 98.1mg/L -1307017.78
Magnesium (Mg) 21 5 0mg/L -13070121
Manganese (Mn) 5.85 5 96.9mg/L -1307015.85
Nickel (Ni) 4.72 5 94.5mg/L -1307014.72
Potassium (K) 12.6 5 102mg/L -13070112.6
Sodium (Na) 18.9 5 93.9mg/L -13070118.9
Duke Energy Analytical Lab
Page 32 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110198 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16110107 -- 2016035510
Strontium (Sr) 5.33 5 101mg/L -1307015.33
Zinc (Zn) 4.68 5 93.5mg/L -1307014.68
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16110107 -- 2016035510
Aluminum (Al) 4.89 5 97.5 1.91mg/L -1307014.89
Barium (Ba) 5.12 5 102 1.94mg/L -1307015.12
Boron (B) 5.98 5 102 0.489mg/L -1307015.98
Calcium (Ca) 121 5 26.1 200mg/L -130701121
Chromium (Cr) 4.87 5 97.5 2.03mg/L -1307014.87
Copper (Cu) 4.97 5 99.5 1.91mg/L -1307014.97
Iron (Fe) 7.83 5 99.1 1.03mg/L -1307017.83
Magnesium (Mg) 20.9 5 183 200mg/L -13070120.9
Manganese (Mn) 5.92 5 98.4 1.6mg/L -1307015.92
Nickel (Ni) 4.82 5 96.4 2.01mg/L -1307014.82
Potassium (K) 12.5 5 102 0.275mg/L -13070112.5
Sodium (Na) 18.8 5 93 0.899mg/L -13070118.8
Strontium (Sr) 5.34 5 101 0.258mg/L -1307015.34
Zinc (Zn) 4.78 5 95.5 2.03mg/L -1307014.78
Duke Energy Analytical Lab
Page 33 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110204 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0124 ug/L -1-0.0124 1 < 1/2 RDL
Arsenic (As) -0.0056 ug/L -1-0.0056 1 < 1/2 RDL
Beryllium (Be) -0.0075 ug/L -1-0.0075 1 < 1/2 RDL
Cadmium (Cd) 0.0008 ug/L -10.0008 1 < 1/2 RDL
Cobalt (Co) 0.0006 ug/L -10.0006 1 < 1/2 RDL
Lead (Pb) 0.0041 ug/L -10.0041 1 < 1/2 RDL
Molybdenum (Mo) 0.011 ug/L -10.011 1 < 1/2 RDL
Selenium (Se) 0.0043 ug/L -10.0043 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0213 ug/L -1-0.0213 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.0217 ug/L -1-0.0217 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 54.2 50 108ug/L -11585154.2
Arsenic (As) 50.4 50 101ug/L -11585150.4
Beryllium (Be) 51.2 50 102ug/L -11585151.2
Cadmium (Cd) 50.3 50 101ug/L -11585150.3
Cobalt (Co) 50.5 50 101ug/L -11585150.5
Lead (Pb) 50.8 50 102ug/L -11585150.8
Molybdenum (Mo) 49.8 50 99.6ug/L -11585149.8
Selenium (Se) 49.9 50 99.7ug/L -11585149.9
Thallium (Tl) Low Level 46.6 50 93.1ug/L -11585146.6
Vanadium (V) Low Level 50.2 50 100ug/L -11585150.2
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033271
Antimony (Sb) 51.1 50 102ug/L -13070151.1
Arsenic (As) 51.6 50 103ug/L -13070151.6
Beryllium (Be) 54.1 50 108ug/L -13070154.1
Cadmium (Cd) 50.8 50 102ug/L -13070150.8
Cobalt (Co) 50 50 99.8ug/L -13070150
Lead (Pb) 52 50 103ug/L -13070152
Molybdenum (Mo) 50 50 99.6ug/L -13070150
Selenium (Se) 50.4 50 101ug/L -13070150.4
Thallium (Tl) Low Level 47.6 50 95.2ug/L -13070147.6
Vanadium (V) Low Level 52.1 50 103ug/L -13070152.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033271
Antimony (Sb) 50.4 50 101 1.32ug/L -13070150.4
Duke Energy Analytical Lab
Page 34 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110204 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033271
Arsenic (As) 50.4 50 101 2.31ug/L -13070150.4
Beryllium (Be) 51 50 102 5.81ug/L -13070151
Cadmium (Cd) 49.7 50 99.3 2.27ug/L -13070149.7
Cobalt (Co) 49 50 97.7 2.11ug/L -13070149
Lead (Pb) 50.5 50 100 2.9ug/L -13070150.5
Molybdenum (Mo) 48.9 50 97.5 2.2ug/L -13070148.9
Selenium (Se) 49.1 50 98 2.54ug/L -13070149.1
Thallium (Tl) Low Level 47.7 50 95.4 0.214ug/L -13070147.7
Vanadium (V) Low Level 50.6 50 99.7 2.96ug/L -13070150.6
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033274
Antimony (Sb) 54.3 50 109ug/L -13070154.3
Arsenic (As) 50.3 50 100ug/L -13070150.3
Beryllium (Be) 51.5 50 103ug/L -13070151.5
Cadmium (Cd) 49.6 50 99.1ug/L -13070149.6
Cobalt (Co) 49.8 50 97.6ug/L -13070149.8
Lead (Pb) 49.7 50 99.5ug/L -13070149.7
Molybdenum (Mo) 50.2 50 98.7ug/L -13070150.2
Selenium (Se) 48.9 50 97.9ug/L -13070148.9
Thallium (Tl) Low Level 47.8 50 95.5ug/L -13070147.8
Vanadium (V) Low Level 50 50 99.6ug/L -13070150
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16100368 -- 2016033274
Antimony (Sb) 54.7 50 109 0.757ug/L -13070154.7
Arsenic (As) 50.4 50 101 0.208ug/L -13070150.4
Beryllium (Be) 50.4 50 101 2.01ug/L -13070150.4
Cadmium (Cd) 49.6 50 99.3 0.148ug/L -13070149.6
Cobalt (Co) 49.8 50 97.5 0.0209ug/L -13070149.8
Lead (Pb) 49.8 50 99.6 0.121ug/L -13070149.8
Molybdenum (Mo) 50.7 50 99.7 1.03ug/L -13070150.7
Selenium (Se) 49.5 50 98.9 1.06ug/L -13070149.5
Thallium (Tl) Low Level 48.2 50 96.3 0.807ug/L -13070148.2
Vanadium (V) Low Level 50.2 50 100 0.406ug/L -13070150.2
Duke Energy Analytical Lab
Page 35 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110260 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -11 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -11 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16100368 -- 2016033268
TDS 1.28mg/L -1157
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16100368 -- 2016033269
TDS 0.917mg/L -1217
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16100368 -- 2016033270
TDS 3.33mg/L -1214
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J16100368 -- 2016033271
TDS 0.775mg/L -1259
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 105mg/L -110901105
Duke Energy Analytical Lab
Page 36 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100368
Q16110214 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16100368 -- 2016033268
TSS 0mg/L -13.2
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16100368 -- 2016033269
TSS 0mg/L -10.4
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16100368 -- 2016033270
TSS 0mg/L -10
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 95.2mg/L -11090147.6
Duke Energy Analytical Lab
Page 37 of 75
#=CL#
November 11, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92318466
92318466
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16100368
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 03, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 20
Duke Energy Analytical Lab
Page 38 of 75
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92318466
J16100368
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20
Duke Energy Analytical Lab
Page 39 of 75
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92318466
J16100368
Lab ID Sample ID Matrix Date Collected Date Received
92318466001 2016033268 Water 11/02/16 14:03 11/03/16 15:02
92318466002 2016033269 Water 11/02/16 13:43 11/03/16 15:02
92318466003 2016033272 Water 11/02/16 14:50 11/03/16 15:02
92318466004 2016033274 Water 11/02/16 15:48 11/03/16 15:02
92318466005 2016033276 Water 11/02/16 11:43 11/03/16 15:02
92318466006 2016033277 Water 11/02/16 09:55 11/03/16 15:02
92318466007 2016033278 Water 11/02/16 09:55 11/03/16 15:02
92318466008 2016033279 Water 11/02/16 10:20 11/03/16 15:02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
Duke Energy Analytical Lab
Page 40 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92318466
J16100368
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92318466001 2016033268 SM 2320B 3 PASI-AKDF
92318466002 2016033269 SM 2320B 3 PASI-AKDF
92318466003 2016033272 SM 2320B 3 PASI-AKDF
92318466004 2016033274 SM 2320B 3 PASI-AKDF
92318466005 2016033276 SM 2320B 3 PASI-AKDF
92318466006 2016033277 SM 2320B 3 PASI-AKDF
92318466007 2016033278 SM 2320B 3 PASI-AKDF
92318466008 2016033279 SM 2320B 3 PASI-AKDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 20
Duke Energy Analytical Lab
Page 41 of 75
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92318466
J16100368
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92318466001 2016033268
Alkalinity,Bicarbonate (CaCO3)35.8 mg/L 11/07/16 12:135.0SM 2320B
Alkalinity, Total as CaCO3 35.8 mg/L 11/07/16 12:135.0SM 2320B
92318466002 2016033269
Alkalinity,Bicarbonate (CaCO3)175 mg/L 11/07/16 12:255.0SM 2320B
Alkalinity, Total as CaCO3 175 mg/L 11/07/16 12:255.0SM 2320B
92318466003 2016033272
Alkalinity,Bicarbonate (CaCO3)141 mg/L 11/07/16 12:385.0SM 2320B
Alkalinity, Total as CaCO3 141 mg/L 11/07/16 12:385.0SM 2320B
92318466004 2016033274
Alkalinity,Bicarbonate (CaCO3)155 mg/L 11/07/16 12:515.0SM 2320B
Alkalinity, Total as CaCO3 155 mg/L 11/07/16 12:515.0SM 2320B
92318466005 2016033276
Alkalinity,Bicarbonate (CaCO3)53.5 mg/L 11/07/16 13:045.0SM 2320B
Alkalinity, Total as CaCO3 53.5 mg/L 11/07/16 13:045.0SM 2320B
92318466006 2016033277
Alkalinity,Bicarbonate (CaCO3)235 mg/L 11/07/16 13:415.0SM 2320B
Alkalinity, Total as CaCO3 235 mg/L 11/07/16 13:415.0SM 2320B
92318466007 2016033278
Alkalinity,Bicarbonate (CaCO3)233 mg/L 11/07/16 13:565.0SM 2320B
Alkalinity, Total as CaCO3 233 mg/L 11/07/16 13:565.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 20
Duke Energy Analytical Lab
Page 42 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92318466
J16100368
Method:
Client:Duke Energy
SM 2320B
Date:November 11, 2016
Description:2320B Alkalinity
General Information:
8 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 335798
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92318463004,92318466005
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1861987)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1861988)
• Alkalinity, Total as CaCO3
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 20
Duke Energy Analytical Lab
Page 43 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033268 Lab ID:92318466001 Collected:11/02/16 14:03 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)35.8 mg/L 11/07/16 12:135.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 12:135.0 1
Alkalinity, Total as CaCO3 35.8 mg/L 11/07/16 12:135.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 20
Duke Energy Analytical Lab
Page 44 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033269 Lab ID:92318466002 Collected:11/02/16 13:43 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)175 mg/L 11/07/16 12:255.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 12:255.0 1
Alkalinity, Total as CaCO3 175 mg/L 11/07/16 12:255.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 20
Duke Energy Analytical Lab
Page 45 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033272 Lab ID:92318466003 Collected:11/02/16 14:50 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)141 mg/L 11/07/16 12:385.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 12:385.0 1
Alkalinity, Total as CaCO3 141 mg/L 11/07/16 12:385.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 20
Duke Energy Analytical Lab
Page 46 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033274 Lab ID:92318466004 Collected:11/02/16 15:48 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)155 mg/L 11/07/16 12:515.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 12:515.0 1
Alkalinity, Total as CaCO3 155 mg/L 11/07/16 12:515.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 20
Duke Energy Analytical Lab
Page 47 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033276 Lab ID:92318466005 Collected:11/02/16 11:43 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)53.5 mg/L 11/07/16 13:045.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 13:045.0 1
Alkalinity, Total as CaCO3 53.5 mg/L 11/07/16 13:045.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 20
Duke Energy Analytical Lab
Page 48 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033277 Lab ID:92318466006 Collected:11/02/16 09:55 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)235 mg/L 11/07/16 13:415.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 13:415.0 1
Alkalinity, Total as CaCO3 235 mg/L 11/07/16 13:415.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 20
Duke Energy Analytical Lab
Page 49 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033278 Lab ID:92318466007 Collected:11/02/16 09:55 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)233 mg/L 11/07/16 13:565.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 13:565.0 1
Alkalinity, Total as CaCO3 233 mg/L 11/07/16 13:565.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 20
Duke Energy Analytical Lab
Page 50 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318466
J16100368
Sample:2016033279 Lab ID:92318466008 Collected:11/02/16 10:20 Received:11/03/16 15:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 11/07/16 14:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/07/16 14:105.0 1
Alkalinity, Total as CaCO3 ND mg/L 11/07/16 14:105.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
Duke Energy Analytical Lab
Page 51 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92318466
J16100368
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
335798
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92318466001, 92318466002, 92318466003, 92318466004, 92318466005, 92318466006, 92318466007,
92318466008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1861985
Associated Lab Samples:92318466001, 92318466002, 92318466003, 92318466004, 92318466005, 92318466006, 92318466007,
92318466008
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 11/07/16 10:08
Alkalinity, Total as CaCO3 mg/L ND 5.0 11/07/16 10:08
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 11/07/16 10:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1861986LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.850 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1861987MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92318463004
1861988
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1506880-12063 4 255036.6 70.9 68.3
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1861989MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92318466005
1861990
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-120103 1 255053.5 104 105
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
Duke Energy Analytical Lab
Page 52 of 75
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92318466
J16100368
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 20
Duke Energy Analytical Lab
Page 53 of 75
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92318466
J16100368
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92318466001 3357982016033268SM 2320B
92318466002 3357982016033269SM 2320B
92318466003 3357982016033272SM 2320B
92318466004 3357982016033274SM 2320B
92318466005 3357982016033276SM 2320B
92318466006 3357982016033277SM 2320B
92318466007 3357982016033278SM 2320B
92318466008 3357982016033279SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 20
Duke Energy Analytical Lab
Page 54 of 75
Page 18 of 20
Duke Energy Analytical Lab
Page 55 of 75
Page 19 of 20
Duke Energy Analytical Lab
Page 56 of 75
Page 20 of 20
Duke Energy Analytical Lab
Page 57 of 75
#=CL#
November 11, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92318635
92318635
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16100368
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 04, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 16
Duke Energy Analytical Lab
Page 58 of 75
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92318635
J16100368
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 16
Duke Energy Analytical Lab
Page 59 of 75
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92318635
J16100368
Lab ID Sample ID Matrix Date Collected Date Received
92318635001 2016033270 Water 11/03/16 13:51 11/04/16 14:55
92318635002 2016033271 Water 11/03/16 13:32 11/04/16 14:55
92318635003 2016033273 Water 11/03/16 09:25 11/04/16 14:55
92318635004 2016033275 Water 11/03/16 13:35 11/04/16 14:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 16
Duke Energy Analytical Lab
Page 60 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92318635
J16100368
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92318635001 2016033270 SM 2320B 3 PASI-AKDF
92318635002 2016033271 SM 2320B 3 PASI-AKDF
92318635003 2016033273 SM 2320B 3 PASI-AKDF
92318635004 2016033275 SM 2320B 3 PASI-AKDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 16
Duke Energy Analytical Lab
Page 61 of 75
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92318635
J16100368
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92318635001 2016033270
Alkalinity,Bicarbonate (CaCO3)7.8 mg/L 11/08/16 02:545.0SM 2320B
Alkalinity, Total as CaCO3 7.8 mg/L 11/08/16 02:545.0SM 2320B
92318635002 2016033271
Alkalinity,Bicarbonate (CaCO3)52.1 mg/L 11/08/16 03:035.0SM 2320B
Alkalinity, Total as CaCO3 52.1 mg/L 11/08/16 03:035.0SM 2320B
92318635003 2016033273
Alkalinity,Bicarbonate (CaCO3)44.4 mg/L 11/08/16 03:135.0SM 2320B
Alkalinity, Total as CaCO3 44.4 mg/L 11/08/16 03:135.0SM 2320B
92318635004 2016033275
Alkalinity,Bicarbonate (CaCO3)278 mg/L 11/08/16 03:245.0SM 2320B
Alkalinity, Total as CaCO3 278 mg/L 11/08/16 03:245.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 16
Duke Energy Analytical Lab
Page 62 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92318635
J16100368
Method:
Client:Duke Energy
SM 2320B
Date:November 11, 2016
Description:2320B Alkalinity
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 16
Duke Energy Analytical Lab
Page 63 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318635
J16100368
Sample:2016033270 Lab ID:92318635001 Collected:11/03/16 13:51 Received:11/04/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.8 mg/L 11/08/16 02:545.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/08/16 02:545.0 1
Alkalinity, Total as CaCO3 7.8 mg/L 11/08/16 02:545.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:28 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 16
Duke Energy Analytical Lab
Page 64 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318635
J16100368
Sample:2016033271 Lab ID:92318635002 Collected:11/03/16 13:32 Received:11/04/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)52.1 mg/L 11/08/16 03:035.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/08/16 03:035.0 1
Alkalinity, Total as CaCO3 52.1 mg/L 11/08/16 03:035.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:28 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 16
Duke Energy Analytical Lab
Page 65 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318635
J16100368
Sample:2016033273 Lab ID:92318635003 Collected:11/03/16 09:25 Received:11/04/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)44.4 mg/L 11/08/16 03:135.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/08/16 03:135.0 1
Alkalinity, Total as CaCO3 44.4 mg/L 11/08/16 03:135.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:28 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 16
Duke Energy Analytical Lab
Page 66 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92318635
J16100368
Sample:2016033275 Lab ID:92318635004 Collected:11/03/16 13:35 Received:11/04/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)278 mg/L 11/08/16 03:245.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 11/08/16 03:245.0 1
Alkalinity, Total as CaCO3 278 mg/L 11/08/16 03:245.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:28 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 16
Duke Energy Analytical Lab
Page 67 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92318635
J16100368
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
335800
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92318635001, 92318635002, 92318635003, 92318635004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1861997
Associated Lab Samples:92318635001, 92318635002, 92318635003, 92318635004
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 11/08/16 00:50
Alkalinity, Total as CaCO3 mg/L ND 5.0 11/08/16 00:50
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 11/08/16 00:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1861998LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.450 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1861999MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92318622008
1862000
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-120100 1 2550ND51.4 51.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1862001MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92318635004
1862002
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-12096 0 2550278327326
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:28 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 16
Duke Energy Analytical Lab
Page 68 of 75
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92318635
J16100368
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:28 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 16
Duke Energy Analytical Lab
Page 69 of 75
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92318635
J16100368
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92318635001 3358002016033270SM 2320B
92318635002 3358002016033271SM 2320B
92318635003 3358002016033273SM 2320B
92318635004 3358002016033275SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/11/2016 01:28 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 16
Duke Energy Analytical Lab
Page 70 of 75
Page 14 of 16
Duke Energy Analytical Lab
Page 71 of 75
Page 15 of 16
Duke Energy Analytical Lab
Page 72 of 75
Page 16 of 16
Duke Energy Analytical Lab
Page 73 of 75
Duke Energy Analytical Lab
Page 74 of 75
Duke Energy Analytical Lab
Page 75 of 75