NC0038377_J16100110report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16100110
Project Name:MAYO STEAM - NPDES - AOW
Lab Contact:Mary Ann Ogle
Date:10/18/2016
Customer Address:Mayo Steam Plant
Customer Name(s):Ross Hartfield, Jerry Wylie, Tim Hunsucker, Kathy Webb, Brandon Russo
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 70
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016032167 MAYO STEAM 05-Oct-16 10:05 AM Kaitlyn Fox S-03
2016032168 MAYO STEAM 05-Oct-16 11:25 AM Kaitlyn Fox S-02
2016032169 MAYO STEAM 05-Oct-16 10:55 AM Kaitlyn Fox S-02B
2016032170 MAYO STEAM 05-Oct-16 12:20 PM Kaitlyn Fox S-08
2016032171 MAYO STEAM 05-Oct-16 1:25 PM Kaitlyn Fox S-05
2016032172 MAYO STEAM 05-Oct-16 2:35 PM Kaitlyn Fox S-01
2016032173 MAYO STEAM 05-Oct-16 2:35 PM Kaitlyn Fox S-01 Dup
2016032174 MAYO STEAM 05-Oct-16 3:45 PM Kaitlyn Fox S-09
2016032175 MAYO STEAM 05-Oct-16 4:10 PM Kaitlyn Fox S-06
2016032176 MAYO STEAM 05-Oct-16 2:00 PM Kaitlyn Fox FIELD BLANK
2016032177 MAYO STEAM 05-Oct-16 2:02 PM Kaitlyn Fox Trip Blank
11 Total Samples
Page 2 of 70
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:10/18/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032167
Collection Date:05-Oct-16 10:05 AM
Site:S-03
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.10 mg-N/L EPA 353.2 10/10/2016 08:57 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 63 mg/L EPA 300.0 10/07/2016 14:35 BGN9034110
Fluoride 0.12 mg/L EPA 300.0 10/07/2016 14:35 BGN90340.1 1
Sulfate 33 mg/L EPA 300.0 10/07/2016 14:35 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.034 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.005 1
Boron (B)1.51 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.05 1
Calcium (Ca)33.0 mg/L EPA 200.7 10/12/2016 15:32B1 JJMACKE0.01 1
Iron (Fe)0.251 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.01 1
Magnesium (Mg)11.3 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.005 1
Manganese (Mn)1.23 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.005 1
Potassium (K)2.46 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.1 1
Sodium (Na)26.0 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.05 1
Total Hardness (Ca and Mg)129 mg/L
(CaCO3)
EPA 200.7 10/12/2016 15:32 JJMACKE0.19 1
Zinc (Zn)0.007 mg/L EPA 200.7 10/12/2016 15:32 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 19:24 JAHERMA0.2 1
Page 4 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032167
Collection Date:05-Oct-16 10:05 AM
Site:S-03
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 7.30 SI Units Field WorkF1
Temperature 17.0 °C Field WorkF1
Specific Conductance 408 uS/cm Field WorkF1
Turbidity 1.31 NTU Field WorkF1
Flow 0.0510 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 240 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 5 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032168
Collection Date:05-Oct-16 11:25 AM
Site:S-02
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 10/10/2016 09:01 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 78 mg/L EPA 300.0 10/07/2016 14:51 BGN9034110
Fluoride < 0.1 mg/L EPA 300.0 10/07/2016 14:51 BGN90340.1 1
Sulfate 42 mg/L EPA 300.0 10/07/2016 14:51 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.036 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.005 1
Barium (Ba)0.150 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.005 1
Boron (B)1.86 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.05 1
Calcium (Ca)28.5 mg/L EPA 200.7 10/12/2016 15:45B1 JJMACKE0.01 1
Iron (Fe)5.66 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.01 1
Magnesium (Mg)13.4 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.005 1
Manganese (Mn)2.36 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.005 1
Potassium (K)2.90 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.1 1
Sodium (Na)20.9 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.05 1
Total Hardness (Ca and Mg)126 mg/L
(CaCO3)
EPA 200.7 10/12/2016 15:45 JJMACKE0.19 1
Zinc (Zn)0.018 mg/L EPA 200.7 10/12/2016 15:45 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Arsenic (As)1.96 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Nickel (Ni)1.62 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 19:31 JAHERMA0.2 1
Page 6 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032168
Collection Date:05-Oct-16 11:25 AM
Site:S-02
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.80 SI Units Field WorkF1
Temperature 16.8 °C Field WorkF1
Specific Conductance 228 uS/cm Field WorkF1
Turbidity 33.8 NTU Field WorkF1
Flow 0.0050 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS 10 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 7 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032169
Collection Date:05-Oct-16 10:55 AM
Site:S-02B
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.23 mg-N/L EPA 353.2 10/10/2016 09:02 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 65 mg/L EPA 300.0 10/07/2016 15:07 BGN9034110
Fluoride < 0.1 mg/L EPA 300.0 10/07/2016 15:07 BGN90340.1 1
Sulfate 28 mg/L EPA 300.0 10/07/2016 15:07 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.108 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.005 1
Barium (Ba)0.032 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.005 1
Boron (B)1.78 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.05 1
Calcium (Ca)35.3 mg/L EPA 200.7 10/12/2016 15:49B1 JJMACKE0.01 1
Iron (Fe)0.334 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.01 1
Magnesium (Mg)13.8 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.005 1
Manganese (Mn)3.07 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.005 1
Potassium (K)2.32 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.1 1
Sodium (Na)17.8 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.05 1
Total Hardness (Ca and Mg)145 mg/L
(CaCO3)
EPA 200.7 10/12/2016 15:49 JJMACKE0.19 1
Zinc (Zn)0.005 mg/L EPA 200.7 10/12/2016 15:49 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 18:34 JAHERMA0.2 1
Page 8 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032169
Collection Date:05-Oct-16 10:55 AM
Site:S-02B
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 7.30 SI Units Field WorkF1
Temperature 17.0 °C Field WorkF1
Specific Conductance 396 uS/cm Field WorkF1
Turbidity 0.9 NTU Field WorkF1
Flow 0.0010 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 9 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032170
Collection Date:05-Oct-16 12:20 PM
Site:S-08
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.08 mg-N/L EPA 353.2 10/10/2016 09:03 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 80 mg/L EPA 300.0 10/07/2016 15:22 BGN9034110
Fluoride < 0.1 mg/L EPA 300.0 10/07/2016 15:22 BGN90340.1 1
Sulfate 62 mg/L EPA 300.0 10/07/2016 15:22 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.141 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.005 1
Barium (Ba)0.081 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.005 1
Boron (B)1.83 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.05 1
Calcium (Ca)28.6 mg/L EPA 200.7 10/12/2016 15:54B1 JJMACKE0.01 1
Iron (Fe)1.19 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.01 1
Magnesium (Mg)18.2 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.005 1
Manganese (Mn)2.26 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.005 1
Potassium (K)3.94 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.1 1
Sodium (Na)21.0 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.05 1
Total Hardness (Ca and Mg)146 mg/L
(CaCO3)
EPA 200.7 10/12/2016 15:54 JJMACKE0.19 1
Zinc (Zn)0.005 mg/L EPA 200.7 10/12/2016 15:54 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 19:38 JAHERMA0.2 1
Page 10 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032170
Collection Date:05-Oct-16 12:20 PM
Site:S-08
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 7.00 SI Units Field WorkF1
Temperature 18.2 °C Field WorkF1
Specific Conductance 434 uS/cm Field WorkF1
Turbidity 7.15 NTU Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS 9.0 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 11 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032171
Collection Date:05-Oct-16 1:25 PM
Site:S-05
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 10/10/2016 09:04 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 47 mg/L EPA 300.0 10/07/2016 15:38 BGN9034110
Fluoride 0.20 mg/L EPA 300.0 10/07/2016 15:38 BGN90340.1 1
Sulfate 47 mg/L EPA 300.0 10/07/2016 15:38 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.050 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.005 1
Barium (Ba)0.035 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.005 1
Boron (B)1.10 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.05 1
Calcium (Ca)31.5 mg/L EPA 200.7 10/12/2016 15:58B1 JJMACKE0.01 1
Iron (Fe)0.038 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.01 1
Magnesium (Mg)11.4 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.005 1
Manganese (Mn)0.052 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.005 1
Potassium (K)4.96 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.1 1
Sodium (Na)11.9 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.05 1
Total Hardness (Ca and Mg)126 mg/L
(CaCO3)
EPA 200.7 10/12/2016 15:58 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/12/2016 15:58 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Arsenic (As)3.05 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Copper (Cu)1.29 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Molybdenum (Mo)13.1 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 19:45 JAHERMA0.2 1
Page 12 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032171
Collection Date:05-Oct-16 1:25 PM
Site:S-05
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 8.70 SI Units Field WorkF1
Temperature 24.0 °C Field WorkF1
Specific Conductance 319 uS/cm Field WorkF1
Turbidity 4.78 NTU Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 13 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032172
Collection Date:05-Oct-16 2:35 PM
Site:S-01
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 10/10/2016 09:05 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 63 mg/L EPA 300.0 10/07/2016 19:53 BGN9034110
Fluoride 0.13 mg/L EPA 300.0 10/07/2016 19:53 BGN90340.1 1
Sulfate 43 mg/L EPA 300.0 10/07/2016 19:53 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.005 1
Barium (Ba)0.154 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.005 1
Boron (B)1.90 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.05 1
Calcium (Ca)25.7 mg/L EPA 200.7 10/12/2016 16:02B1 JJMACKE0.01 1
Iron (Fe)13.9 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.01 1
Magnesium (Mg)9.54 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.005 1
Manganese (Mn)3.14 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.005 1
Potassium (K)1.85 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.1 1
Sodium (Na)38.5 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.05 1
Total Hardness (Ca and Mg)104 mg/L
(CaCO3)
EPA 200.7 10/12/2016 16:02 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/12/2016 16:02 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Arsenic (As)2.46 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 19:52 JAHERMA0.2 1
Page 14 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032172
Collection Date:05-Oct-16 2:35 PM
Site:S-01
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.90 SI Units Field WorkF1
Temperature 18.8 °C Field WorkF1
Specific Conductance 436 uS/cm Field WorkF1
Turbidity 4.57 NTU Field WorkF1
Flow 0.0080 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 270 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS 13 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 15 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032173
Collection Date:05-Oct-16 2:35 PM
Site:S-01 Dup
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 10/10/2016 09:07 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 63 mg/L EPA 300.0 10/07/2016 20:09 BGN9034110
Fluoride 0.13 mg/L EPA 300.0 10/07/2016 20:09 BGN90340.1 1
Sulfate 44 mg/L EPA 300.0 10/07/2016 20:09 BGN9034110
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.023 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.005 1
Barium (Ba)0.147 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.005 1
Boron (B)1.82 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.05 1
Calcium (Ca)24.8 mg/L EPA 200.7 10/12/2016 16:07B1 JJMACKE0.01 1
Iron (Fe)13.4 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.01 1
Magnesium (Mg)9.10 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.005 1
Manganese (Mn)3.01 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.005 1
Potassium (K)1.78 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.1 1
Sodium (Na)36.6 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.05 1
Total Hardness (Ca and Mg)99.4 mg/L
(CaCO3)
EPA 200.7 10/12/2016 16:07 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/12/2016 16:07 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Arsenic (As)2.46 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 19:59 JAHERMA0.2 1
Page 16 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032173
Collection Date:05-Oct-16 2:35 PM
Site:S-01 Dup
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.90 SI Units Field WorkF1
Temperature 18.8 °C Field WorkF1
Specific Conductance 436 uS/cm Field WorkF1
Turbidity 4.57 NTU Field WorkF1
Flow 0.0080 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS 11 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 17 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032174
Collection Date:05-Oct-16 3:45 PM
Site:S-09
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 10/10/2016 09:08 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 22 mg/L EPA 300.0 10/07/2016 20:25 BGN90340.5 5
Fluoride 0.16 mg/L EPA 300.0 10/07/2016 20:25 BGN90340.1 1
Sulfate 9.2 mg/L EPA 300.0 10/07/2016 20:25 BGN90340.5 5
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.026 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.005 1
Barium (Ba)0.070 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.05 1
Calcium (Ca)27.1 mg/L EPA 200.7 10/12/2016 16:28B1 JJMACKE0.01 1
Iron (Fe)12.1 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.01 1
Magnesium (Mg)10.2 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.005 1
Manganese (Mn)2.19 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.005 1
Potassium (K)1.08 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.1 1
Sodium (Na)27.1 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.05 1
Total Hardness (Ca and Mg)110 mg/L
(CaCO3)
EPA 200.7 10/12/2016 16:28 JJMACKE0.19 1
Zinc (Zn)0.006 mg/L EPA 200.7 10/12/2016 16:28 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Nickel (Ni)3.24 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 20:06 JAHERMA0.2 1
Page 18 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032174
Collection Date:05-Oct-16 3:45 PM
Site:S-09
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.60 SI Units Field WorkF1
Temperature 17.0 °C Field WorkF1
Specific Conductance 341 uS/cm Field WorkF1
Turbidity 4.33 NTU Field WorkF1
Flow 0.0050 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS 16 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 19 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032175
Collection Date:05-Oct-16 4:10 PM
Site:S-06
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease < 5 mg/L EPA 1664B 10/10/2016 08:30 CJELLIO51
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.03 mg-N/L EPA 353.2 10/10/2016 09:09 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 24 mg/L EPA 300.0 10/08/2016 09:14 BGN90340.5 5
Fluoride 0.12 mg/L EPA 300.0 10/08/2016 09:14 BGN90340.1 1
Sulfate 14 mg/L EPA 300.0 10/08/2016 09:14 BGN90340.5 5
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.126 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.005 1
Boron (B)0.520 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.05 1
Calcium (Ca)12.9 mg/L EPA 200.7 10/12/2016 16:32B1 JJMACKE0.01 1
Iron (Fe)0.196 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.01 1
Magnesium (Mg)5.85 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.005 1
Manganese (Mn)0.054 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.005 1
Potassium (K)2.59 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.1 1
Sodium (Na)7.52 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.05 1
Total Hardness (Ca and Mg)56.3 mg/L
(CaCO3)
EPA 200.7 10/12/2016 16:32 JJMACKE0.19 1
Zinc (Zn)0.007 mg/L EPA 200.7 10/12/2016 16:32 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Copper (Cu)1.14 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Molybdenum (Mo)2.10 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 10/12/2016 20:13 JAHERMA0.2 1
Page 20 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032175
Collection Date:05-Oct-16 4:10 PM
Site:S-06
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 7.40 SI Units Field WorkF1
Temperature 22.0 °C Field WorkF1
Specific Conductance 154 uS/cm Field WorkF1
Turbidity 2.93 NTU Field WorkF1
Flow 0.3710 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 10/11/2016 17:36 CJELLIO251
TOTAL SUSPENDED SOLIDS
TSS 21 mg/L SM2540D 10/11/2016 15:14 HGRUVER51
Page 21 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032176
Collection Date:05-Oct-16 2:00 PM
Site:FIELD BLANK
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
Page 22 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
2016032177
Collection Date:05-Oct-16 2:02 PM
Site:Trip Blank
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
Qualifiers:
B1 Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in
sample was greater than 10X the concentration of the target analyte detected in the method blank. Analyte
concentration in sample is not affected by contamination.
F Field Parameters are not covered under the DPAL certification. If certification is required for these
parameters please request field certificates from the samplers. This data is provided at the request of the
client.
Page 23 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100187 1664_SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Oil and Grease mg/L -10.0994 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Oil and Grease 39.8971 92.7mg/L -118.57044429269167.6610156707391137
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16080747 -- 2016027441
Oil and Grease 32.5156 86.2mg/L -11480128.5
Page 24 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100192 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0005 mg-N/L -10.0005 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0003 mg-N/L -1-0.0003 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0008 mg-N/L -1-0.0008 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0012 mg-N/L -10.0012 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 5
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0005 mg-N/L -10.0005 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 6
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0009 mg-N/L -10.0009 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.7mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.6mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 98.9mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.296 3.01 98.5mg-N/L -11090102.96
Page 25 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100192 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 5
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.299 3.01 99.5mg-N/L -11090103
Final QualifierDilMeasuredUnits:Parameter
LCS # 6
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.295 3.01 98.1mg-N/L -11090102.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090215 -- 2016029141
Nitrite + Nitrate
(Colorimetric)
0.549 50 95.2mg-N/L -11090200110
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090215 -- 2016029141
Nitrite + Nitrate
(Colorimetric)
0.549 50 95.4 0.21mg-N/L -11090200110
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032167
Nitrite + Nitrate
(Colorimetric)
0.337 0.25 93.6mg-N/L -1109010.337
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032167
Nitrite + Nitrate
(Colorimetric)
0.338 0.25 93.8 0.256mg-N/L -1109010.338
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16100028 -- 2016031806
Nitrite + Nitrate
(Colorimetric)
0.136 0.25 57.6mg-N/L -1109010.136
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16100028 -- 2016031806
Nitrite + Nitrate
(Colorimetric)
0.135 0.25 57.1 0.906mg-N/L -1109010.135
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16100028 -- 2016031808
Nitrite + Nitrate
(Colorimetric)
0.817 1.25 102mg-N/L -1109054.09
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16100028 -- 2016031808
Nitrite + Nitrate
(Colorimetric)
0.818 1.25 102 0.275mg-N/L -1109054.09
Page 26 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100192 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J16100038 -- 2016031851
Nitrite + Nitrate
(Colorimetric)
0.238 0.25 95.3mg-N/L -1109010.238
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J16100038 -- 2016031851
Nitrite + Nitrate
(Colorimetric)
0.236 0.25 94.4 1.01mg-N/L -1109010.236
Final QualifierDilMeasuredUnits:Parameter
MS # 6
% Recovery LCL UCLSpike
Parent Sample: J16100058 -- 2016031924
Nitrite + Nitrate
(Colorimetric)
0.242 0.25 93.8mg-N/L -1109010.242
Final QualifierDilMeasuredUnits:Parameter
MSD # 6
RPD% Recovery LCL UCLSpike
Parent Sample: J16100058 -- 2016031924
Nitrite + Nitrate
(Colorimetric)
0.247 0.25 95.8 2.07mg-N/L -1109010.247
Final QualifierDilMeasuredUnits:Parameter
MS # 7
% Recovery LCL UCLSpike
Parent Sample: J16100132 -- 2016032265
Nitrite + Nitrate
(Colorimetric)
0.006 0.25 14.3mg-N/L -1109010.006
Final QualifierDilMeasuredUnits:Parameter
MSD # 7
RPD% Recovery LCL UCLSpike
Parent Sample: J16100132 -- 2016032265
Nitrite + Nitrate
(Colorimetric)
0.0057 0.25 14.2 0.842mg-N/L -1109010.0057
Final QualifierDilMeasuredUnits:Parameter
MS # 8
% Recovery LCL UCLSpike
Parent Sample: J16100132 -- 2016032268
Nitrite + Nitrate
(Colorimetric)
0.234 0.25 91.1mg-N/L -1109010.234
Final QualifierDilMeasuredUnits:Parameter
MSD # 8
RPD% Recovery LCL UCLSpike
Parent Sample: J16100132 -- 2016032268
Nitrite + Nitrate
(Colorimetric)
0.24 0.25 93.8 2.94mg-N/L -1109010.24
Page 27 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100154 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0486 mg/L -10.0486 0.1 < 1/2 RDL
Fluoride 0.0222 mg/L -10.0222 0.1 < 1/2 RDL
Sulfate -0.0097 mg/L -1-0.0097 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.84 5 102mg/L -1208015.84
Fluoride 4.9 5 97mg/L -1208014.9
Sulfate 6.65 5 102mg/L -1208016.65
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.84 5 102 0.0945mg/L -1208015.84
Fluoride 4.9 5 96.9 0.122mg/L -1208014.9
Sulfate 6.65 5 102 0.063mg/L -1208016.65
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 9.33 5 99.5mg/L -1208019.33
Fluoride 5.01 5 99.1mg/L -1208015.01
Sulfate 6.94 5 102mg/L -1208016.94
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 9.45 5 102 2.33mg/L -1208019.45
Fluoride 5.06 5 100 0.86mg/L -1208015.06
Sulfate 7.03 5 104 1.6mg/L -1208017.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.03 5 101mg/L -1109015.03
Fluoride 5.2 5 104mg/L -1109015.2
Sulfate 5.04 5 101mg/L -1109015.04
Page 28 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100202 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00236 mg/L -10.00236 0.005 < 1/2 RDL
Barium (Ba) 0.00017 mg/L -10.00017 0.005 < 1/2 RDL
Boron (B) 0.00149 mg/L -10.00149 0.05 < 1/2 RDL
Calcium (Ca) 0.013 mg/L B110.013 0.01 > RDL
Iron (Fe) 0.000827 mg/L -10.000827 0.01 < 1/2 RDL
Magnesium (Mg) 0.0016 mg/L -10.0016 0.005 < 1/2 RDL
Manganese (Mn) 0.000189 mg/L -10.000189 0.005 < 1/2 RDL
Potassium (K) 0.0189 mg/L -10.0189 0.1 < 1/2 RDL
Sodium (Na) 0.00422 mg/L -10.00422 0.05 < 1/2 RDL
Zinc (Zn) 0.000863 mg/L -10.000863 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.61 5 112mg/L -1158515.61
Barium (Ba) 5.39 5 108mg/L -1158515.39
Boron (B) 5.27 5 105mg/L -1158515.27
Calcium (Ca) 5.32 5 106mg/L B11158515.32
Iron (Fe) 5.28 5 106mg/L -1158515.28
Magnesium (Mg) 5.4 5 108mg/L -1158515.4
Manganese (Mn) 5.5 5 110mg/L -1158515.5
Potassium (K) 5.35 5 107mg/L -1158515.35
Sodium (Na) 5.28 5 106mg/L -1158515.28
Zinc (Zn) 5.37 5 107mg/L -1158515.37
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032167
Aluminum (Al) 5.61 5 112mg/L -1307015.61
Barium (Ba) 5.41 5 107mg/L -1307015.41
Boron (B) 6.73 5 104mg/L -1307016.73
Calcium (Ca) 38 5 98.7mg/L B113070138
Iron (Fe) 5.45 5 104mg/L -1307015.45
Magnesium (Mg) 15.8 5 89.9mg/L -13070115.8
Manganese (Mn) 6.74 5 110mg/L -1307016.74
Potassium (K) 7.77 5 106mg/L -1307017.77
Sodium (Na) 31.5 5 110mg/L -13070131.5
Zinc (Zn) 5.19 5 104mg/L -1307015.19
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032167
Aluminum (Al) 5.53 5 110 1.41mg/L -1307015.53
Page 29 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100202 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032167
Barium (Ba) 5.38 5 106 0.619mg/L -1307015.38
Boron (B) 6.72 5 104 0.192mg/L -1307016.72
Calcium (Ca) 37.8 5 94.9 3.99mg/L B113070137.8
Iron (Fe) 5.39 5 103 1.18mg/L -1307015.39
Magnesium (Mg) 15.9 5 92.6 2.89mg/L -13070115.9
Manganese (Mn) 6.7 5 109 0.746mg/L -1307016.7
Potassium (K) 7.79 5 107 0.376mg/L -1307017.79
Sodium (Na) 31.7 5 113 2.76mg/L -13070131.7
Zinc (Zn) 5.16 5 103 0.658mg/L -1307015.16
Qualifiers:
B1 Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in
sample was greater than 10X the concentration of the target analyte detected in the method blank. Analyte
concentration in sample is not affected by contamination.
Page 30 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100207 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.057 ug/L -1-0.057 1 < 1/2 RDL
Arsenic (As) 0.04 ug/L -10.04 1 < 1/2 RDL
Cadmium (Cd) 0.008 ug/L -10.008 1 < 1/2 RDL
Chromium (Cr) 0.01 ug/L -10.01 1 < 1/2 RDL
Copper (Cu) -0.271 ug/L -1-0.271 1 < 1/2 RDL
Lead (Pb) 0.004 ug/L -10.004 1 < 1/2 RDL
Molybdenum (Mo) 0.016 ug/L -10.016 1 < 1/2 RDL
Nickel (Ni) -0.43 ug/L -1-0.43 1 < 1/2 RDL
Selenium (Se) 0.11 ug/L -10.11 1 < 1/2 RDL
Thallium (Tl) Low Level -0.037 ug/L -1-0.037 0.2 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.9 50 102ug/L -11585150.9
Arsenic (As) 51.6 50 103ug/L -11585151.6
Cadmium (Cd) 51.4 50 103ug/L -11585151.4
Chromium (Cr) 49.5 50 98.9ug/L -11585149.5
Copper (Cu) 51.2 50 102ug/L -11585151.2
Lead (Pb) 50.6 50 101ug/L -11585150.6
Molybdenum (Mo) 50.6 50 101ug/L -11585150.6
Nickel (Ni) 52.4 50 105ug/L -11585152.4
Selenium (Se) 48 50 96.1ug/L -11585148
Thallium (Tl) Low Level 44.3 50 88.5ug/L -11585144.3
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032169
Antimony (Sb) 50.9 50 102ug/L -13070150.9
Arsenic (As) 51.2 50 102ug/L -13070151.2
Cadmium (Cd) 50.5 50 101ug/L -13070150.5
Chromium (Cr) 49.4 50 98.7ug/L -13070149.4
Copper (Cu) 49.6 50 98.8ug/L -13070149.6
Lead (Pb) 50 50 99.9ug/L -13070150
Molybdenum (Mo) 50.4 50 101ug/L -13070150.4
Nickel (Ni) 50.9 50 101ug/L -13070150.9
Selenium (Se) 46.8 50 93.4ug/L -13070146.8
Thallium (Tl) Low Level 44 50 88ug/L -13070144
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032169
Antimony (Sb) 50.6 50 101 0.538ug/L -13070150.6
Page 31 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100207 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100110 -- 2016032169
Arsenic (As) 50.8 50 101 0.901ug/L -13070150.8
Cadmium (Cd) 50.7 50 101 0.518ug/L -13070150.7
Chromium (Cr) 49.2 50 98.1 0.573ug/L -13070149.2
Copper (Cu) 49.4 50 98.4 0.438ug/L -13070149.4
Lead (Pb) 49.9 50 99.8 0.144ug/L -13070149.9
Molybdenum (Mo) 50.2 50 100 0.527ug/L -13070150.2
Nickel (Ni) 51.1 50 102 0.514ug/L -13070151.1
Selenium (Se) 47.5 50 94.9 1.57ug/L -13070147.5
Thallium (Tl) Low Level 44.4 50 88.8 0.907ug/L -13070144.4
Page 32 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100227 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16100110 -- 2016032167
TDS 4.41mg/L -1255
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16100110 -- 2016032168
TDS 1.17mg/L -1255
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16100110 -- 2016032169
TDS 2.74mg/L -1252
Page 33 of 70
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100110
Q16100228 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -1-0.2 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16080747 -- 2016027441
TSS 9.52mg/L -12.2
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16100110 -- 2016032167
TSS 9.52mg/L -12.2
Page 34 of 70
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
RJ06081Lot Number:
J16100110Project Number:
Mayo NPDES AOWProject Name:
10/13/2016Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 24
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: RJ06081
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: Mayo NPDES AOW
Project Number: J16100110
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 24
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: RJ06081

Project Name: Mayo NPDES AOW
Project Number: J16100110
Sample Number Sample ID Matrix Date Sampled Date Received
001 10/05/2016 10052016032167Aqueous 10/06/2016
002 10/05/2016 11252016032168Aqueous 10/06/2016
003 10/05/2016 10552016032169Aqueous 10/06/2016
004 10/05/2016 12202016032170Aqueous 10/06/2016
005 10/05/2016 13252016032171Aqueous 10/06/2016
006 10/05/2016 14352016032172Aqueous 10/06/2016
007 10/05/2016 14352016032173Aqueous 10/06/2016
008 10/05/2016 15452016032174Aqueous 10/06/2016
009 10/05/2016 16102016032175Aqueous 10/06/2016
010 10/05/2016 14002016032176Aqueous 10/06/2016
011 10/05/2016 14022016032177Aqueous 10/06/2016
(11 samples)
Page: 3 of 24
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: RJ06081

Project Name: Mayo NPDES AOW
Project Number: J16100110
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2016032167 Aqueous Alkalinity SM 2320B-69 mg/L 5
001 2016032167 Aqueous Bicarbonate Alkalinity SM 2320B-69 mg/L 5
001 2016032167 Aqueous Mercury (CVAFS)1631E 3.68 ng/L 6
002 2016032168 Aqueous Alkalinity SM 2320B-32 mg/L 7
002 2016032168 Aqueous Bicarbonate Alkalinity SM 2320B-32 mg/L 7
003 2016032169 Aqueous Alkalinity SM 2320B-73 mg/L 9
003 2016032169 Aqueous Bicarbonate Alkalinity SM 2320B-73 mg/L 9
003 2016032169 Aqueous Mercury (CVAFS)1631E 1.49 ng/L 10
004 2016032170 Aqueous Alkalinity SM 2320B-25 mg/L 11
004 2016032170 Aqueous Bicarbonate Alkalinity SM 2320B-25 mg/L 11
004 2016032170 Aqueous Mercury (CVAFS)1631E 0.560 ng/L 12
005 2016032171 Aqueous Alkalinity SM 2320B-36 mg/L 13
005 2016032171 Aqueous Bicarbonate Alkalinity SM 2320B-36 mg/L 13
006 2016032172 Aqueous Alkalinity SM 2320B-73 mg/L 15
006 2016032172 Aqueous Bicarbonate Alkalinity SM 2320B-73 mg/L 15
007 2016032173 Aqueous Alkalinity SM 2320B-72 mg/L 17
007 2016032173 Aqueous Bicarbonate Alkalinity SM 2320B-72 mg/L 17
008 2016032174 Aqueous Alkalinity SM 2320B-140 mg/L 19
008 2016032174 Aqueous Bicarbonate Alkalinity SM 2320B-140 mg/L 19
009 2016032175 Aqueous Alkalinity SM 2320B-21 mg/L 21
009 2016032175 Aqueous Bicarbonate Alkalinity SM 2320B-21 mg/L 21
009 2016032175 Aqueous Mercury (CVAFS)1631E 2.48 ng/L 22
(22 detections)
Page: 4 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032167
RJ06081-001
10/05/2016 1005
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1549 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1549 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1549 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 69 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 69 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 5 of 24
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032167
RJ06081-001
10/05/2016 1005
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1523 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 3.68 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 6 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032168
RJ06081-002
10/05/2016 1125
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1554 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1554 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1554 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 32 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 32 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 7 of 24
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032168
RJ06081-002
10/05/2016 1125
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1528 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 8 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032169
RJ06081-003
10/05/2016 1055
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1600 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1600 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1600 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 73 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 73 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 9 of 24
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032169
RJ06081-003
10/05/2016 1055
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1330 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 1.49 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 10 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032170
RJ06081-004
10/05/2016 1220
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1604 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1604 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1604 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 25 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 25 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 11 of 24
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032170
RJ06081-004
10/05/2016 1220
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1335 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 0.560 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 12 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032171
RJ06081-005
10/05/2016 1325
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1623 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1623 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1623 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 36 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 36 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 13 of 24
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032171
RJ06081-005
10/05/2016 1325
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1315 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 14 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032172
RJ06081-006
10/05/2016 1435
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1633 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1633 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1633 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 73 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 73 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 15 of 24
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032172
RJ06081-006
10/05/2016 1435
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1350 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 16 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032173
RJ06081-007
10/05/2016 1435
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1638 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1638 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1638 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 72 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 72 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 17 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032173
RJ06081-007
10/05/2016 1435
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1355 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 18 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032174
RJ06081-008
10/05/2016 1545
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1644 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1644 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1644 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 140 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 140 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 19 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032174
RJ06081-008
10/05/2016 1545
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1401 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 20 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032175
RJ06081-009
10/05/2016 1610
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 10/07/2016 1648 MJI 24071
1 (Bicarbonate ) SM 2320B-2011 1 10/07/2016 1648 MJI
1 (Carbonate Al) SM 2320B-2011 1 10/07/2016 1648 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 21 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 21 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 21 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032175
RJ06081-009
10/05/2016 1610
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1406 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 2.48 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 22 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032176
RJ06081-010
10/05/2016 1400
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1411 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 23 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016032177
RJ06081-011
10/05/2016 1402
10/06/2016
Aqueous
Project Name: Mayo NPDES AOW
Project Number: J16100110
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 10/12/2016 1416 BNW 10/11/2016 0949 23921
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page: 24 of 24
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Shealy Environmental Services, Inc.

QC Summary
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:RQ24071-001
24071
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 10/07/2016 153910mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:RQ24071-002
24071
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 100 10/07/2016 154510210090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - Duplicate
Batch:
Sample ID:RJ06081-005DU
24071
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q Analysis Date% RPD
% RPD
Limit
Sample
Amount
Dil(mg/L)(mg/L)
Alkalinity 35 10/07/2016 16283.9 20361
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - MB
Batch:Prep Method:
Prep Date:
Sample ID:RQ23921-001
23921 1631E
10/11/2016 949Analytical Method:1631E
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Mercury (CVAFS)ND 10/12/2016 16050.500 ng/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - LCS
Batch:Prep Method:
Prep Date:
Sample ID:RQ23921-002
23921 1631E
10/11/2016 949Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ng/L)(ng/L)
Mercury (CVAFS)5.16 10/12/2016 16101035.00 75-1251
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - MS
Batch:Prep Method:
Prep Date:
Sample ID:RJ06081-005MS
23921 1631E
10/11/2016 949Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(ng/L)(ng/L)(ng/L)
Mercury (CVAFS)4.96 10/12/2016 1320995.00 71-125ND1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - MSD
Batch:Prep Method:
Prep Date:
Sample ID:RJ06081-005MD
23921 1631E
10/11/2016 949Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
Limit
Sample
Amount
Dil(ng/L)(ng/L)(ng/L)
Mercury (CVAFS)4.98 10/12/2016 13251005.00 71-1250.40 24ND1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RJ06081
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Chain of Custody
and
Miscellaneous Documents
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Page 70 of 70