NC0038377_J16090155report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16090155
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:9/29/2016
Customer Address:Mayo Steam Plant
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 89
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016028877 MAYO STEAM 07-Sep-16 8:01 AM illegible MW-14BR
2016028878 MAYO STEAM 07-Sep-16 10:53 AM illegible MW-12D
2016028879 MAYO STEAM 07-Sep-16 10:54 AM illegible MW-12S
2016028880 MAYO STEAM 07-Sep-16 12:50 PM illegible MW-10BR
2016028881 MAYO STEAM 07-Sep-16 2:25 PM illegible ABMW-02BRL
2016028882 MAYO STEAM 07-Sep-16 3:56 PM illegible BG-02
2016028883 MAYO STEAM 07-Sep-16 3:56 PM illegible BG-02 Dup
2016028887 MAYO STEAM 07-Sep-16 4:25 PM illegible Filter Blank
2016028888 MAYO STEAM 07-Sep-16 4:25 PM illegible Equipment Blank
9 Total Samples
Duke Energy Analytical Lab
Page 2 of 89
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:9/29/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028877
Collection Date:07-Sep-16 8:01 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.191 mg-N/L EPA 353.2 09/12/2016 11:14 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 09/20/2016 13:12 BGN90340.5 5
Sulfate 12 mg/L EPA 300.0 09/20/2016 13:12 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:38 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 13:51 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/09/2016 14:55 JJMACKE0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 09/09/2016 14:55 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 14:55 JJMACKE0.05 1
Iron (Fe)0.015 mg/L EPA 200.7 09/09/2016 14:55 JJMACKE0.01 1
Manganese (Mn)0.252 mg/L EPA 200.7 09/09/2016 14:55 JJMACKE0.005 1
Strontium (Sr)0.155 mg/L EPA 200.7 09/09/2016 14:55 JJMACKE0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 09/09/2016 14:55 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)15.3 mg/L EPA 200.7 09/12/2016 15:43M4 JJMACKE0.01 1
Magnesium (Mg)2.57 mg/L EPA 200.7 09/12/2016 15:43 JJMACKE0.005 1
Potassium (K)7.13 mg/L EPA 200.7 09/12/2016 15:43 JJMACKE0.1 1
Sodium (Na)46.3 mg/L EPA 200.7 09/12/2016 15:43M4 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.059 mg/L EPA 200.7 09/12/2016 12:12 MHH71310.005 1
Barium (Ba)0.028 mg/L EPA 200.7 09/12/2016 12:12 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:12 MHH71310.05 1
Iron (Fe)0.056 mg/L EPA 200.7 09/12/2016 12:12 MHH71310.01 1
Manganese (Mn)0.322 mg/L EPA 200.7 09/12/2016 12:12 MHH71310.005 1
Strontium (Sr)0.168 mg/L EPA 200.7 09/12/2016 12:12 MHH71310.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 09/12/2016 12:12 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028877
Collection Date:07-Sep-16 8:01 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Copper (Cu)3.83 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Molybdenum (Mo)6.78 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN30.2 1
Vanadium (V) Low Level 1.75 ug/L EPA 200.8 09/28/2016 00:56 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Copper (Cu)1.43 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Molybdenum (Mo)9.57 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR0.2 1
Vanadium (V) Low Level 2.07 ug/L EPA 200.8 09/12/2016 20:22 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 09/08/2016 14:04 HGRUVER251
Duke Energy Analytical Lab
Page 5 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028877
Collection Date:07-Sep-16 8:01 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.887 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Duke Energy Analytical Lab
Page 6 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028878
Collection Date:07-Sep-16 10:53 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.180 mg-N/L EPA 353.2 09/12/2016 11:15 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.8 mg/L EPA 300.0 09/20/2016 16:22 BGN90340.5 5
Sulfate 1.1 mg/L EPA 300.0 09/20/2016 16:22 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:41 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 13:53 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/09/2016 15:06 JJMACKE0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 09/09/2016 15:06 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 15:06 JJMACKE0.05 1
Iron (Fe)0.014 mg/L EPA 200.7 09/09/2016 15:06 JJMACKE0.01 1
Manganese (Mn)0.060 mg/L EPA 200.7 09/09/2016 15:06 JJMACKE0.005 1
Strontium (Sr)0.088 mg/L EPA 200.7 09/09/2016 15:06 JJMACKE0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 09/09/2016 15:06 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.9 mg/L EPA 200.7 09/12/2016 15:54 JJMACKE0.01 1
Magnesium (Mg)3.02 mg/L EPA 200.7 09/12/2016 15:54 JJMACKE0.005 1
Potassium (K)1.34 mg/L EPA 200.7 09/12/2016 15:54 JJMACKE0.1 1
Sodium (Na)9.05 mg/L EPA 200.7 09/12/2016 15:54 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.257 mg/L EPA 200.7 09/12/2016 12:24 MHH71310.005 1
Barium (Ba)0.016 mg/L EPA 200.7 09/12/2016 12:24 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:24 MHH71310.05 1
Iron (Fe)0.409 mg/L EPA 200.7 09/12/2016 12:24 MHH71310.01 1
Manganese (Mn)0.064 mg/L EPA 200.7 09/12/2016 12:24 MHH71310.005 1
Strontium (Sr)0.083 mg/L EPA 200.7 09/12/2016 12:24 MHH71310.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 09/12/2016 12:24 MHH71310.005 1
Duke Energy Analytical Lab
Page 7 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028878
Collection Date:07-Sep-16 10:53 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Copper (Cu)7.25 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN30.2 1
Vanadium (V) Low Level 0.302 ug/L EPA 200.8 09/28/2016 01:03 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Chromium (Cr)2.99 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Nickel (Ni)2.02 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR0.2 1
Vanadium (V) Low Level 1.13 ug/L EPA 200.8 09/12/2016 19:37 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 09/08/2016 14:04 HGRUVER251
Duke Energy Analytical Lab
Page 8 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028878
Collection Date:07-Sep-16 10:53 AM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.289 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 8.2 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Duke Energy Analytical Lab
Page 9 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028879
Collection Date:07-Sep-16 10:54 AM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.756 mg-N/L EPA 353.2 09/12/2016 11:17 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.2 mg/L EPA 300.0 09/20/2016 16:37 BGN90340.1 1
Sulfate 1.1 mg/L EPA 300.0 09/20/2016 16:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:26 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 13:56 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.019 mg/L EPA 200.7 09/09/2016 15:10 JJMACKE0.005 1
Barium (Ba)0.011 mg/L EPA 200.7 09/09/2016 15:10 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 15:10 JJMACKE0.05 1
Iron (Fe)0.017 mg/L EPA 200.7 09/09/2016 15:10 JJMACKE0.01 1
Manganese (Mn)0.016 mg/L EPA 200.7 09/09/2016 15:10 JJMACKE0.005 1
Strontium (Sr)0.015 mg/L EPA 200.7 09/09/2016 15:10 JJMACKE0.005 1
Zinc (Zn)0.134 mg/L EPA 200.7 09/09/2016 15:10 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)1.56 mg/L EPA 200.7 09/12/2016 15:58 JJMACKE0.01 1
Magnesium (Mg)0.640 mg/L EPA 200.7 09/12/2016 15:58 JJMACKE0.005 1
Potassium (K)1.36 mg/L EPA 200.7 09/12/2016 15:58 JJMACKE0.1 1
Sodium (Na)4.78 mg/L EPA 200.7 09/12/2016 15:58 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.284 mg/L EPA 200.7 09/12/2016 12:28 MHH71310.005 1
Barium (Ba)0.012 mg/L EPA 200.7 09/12/2016 12:28 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:28 MHH71310.05 1
Iron (Fe)0.270 mg/L EPA 200.7 09/12/2016 12:28 MHH71310.01 1
Manganese (Mn)0.011 mg/L EPA 200.7 09/12/2016 12:28 MHH71310.005 1
Strontium (Sr)0.016 mg/L EPA 200.7 09/12/2016 12:28 MHH71310.005 1
Zinc (Zn)0.140 mg/L EPA 200.7 09/12/2016 12:28 MHH71310.005 1
Duke Energy Analytical Lab
Page 10 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028879
Collection Date:07-Sep-16 10:54 AM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Copper (Cu)2.86 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/28/2016 01:10 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR0.2 1
Vanadium (V) Low Level 0.711 ug/L EPA 200.8 09/12/2016 20:29 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 52 mg/L SM2540C 09/08/2016 14:04 HGRUVER251
Duke Energy Analytical Lab
Page 11 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028879
Collection Date:07-Sep-16 10:54 AM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.763 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Duke Energy Analytical Lab
Page 12 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028880
Collection Date:07-Sep-16 12:50 PM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.029 mg-N/L EPA 353.2 09/12/2016 11:24 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 22 mg/L EPA 300.0 09/20/2016 14:36 BGN9034110
Sulfate 90 mg/L EPA 300.0 09/20/2016 14:36 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:43 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 13:58 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/09/2016 15:14 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/09/2016 15:14 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 15:14 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/09/2016 15:14 JJMACKE0.01 1
Manganese (Mn)0.064 mg/L EPA 200.7 09/09/2016 15:14 JJMACKE0.005 1
Strontium (Sr)0.198 mg/L EPA 200.7 09/09/2016 15:14 JJMACKE0.005 1
Zinc (Zn)0.016 mg/L EPA 200.7 09/09/2016 15:14 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)28.5 mg/L EPA 200.7 09/12/2016 16:02 JJMACKE0.01 1
Magnesium (Mg)12.7 mg/L EPA 200.7 09/12/2016 16:02 JJMACKE0.005 1
Potassium (K)3.94 mg/L EPA 200.7 09/12/2016 16:02 JJMACKE0.1 1
Sodium (Na)38.2 mg/L EPA 200.7 09/12/2016 16:02 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.021 mg/L EPA 200.7 09/12/2016 12:32 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/12/2016 12:32 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:32 MHH71310.05 1
Iron (Fe)0.035 mg/L EPA 200.7 09/12/2016 12:32 MHH71310.01 1
Manganese (Mn)0.072 mg/L EPA 200.7 09/12/2016 12:32 MHH71310.005 1
Strontium (Sr)0.208 mg/L EPA 200.7 09/12/2016 12:32 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/12/2016 12:32 MHH71310.005 1
Duke Energy Analytical Lab
Page 13 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028880
Collection Date:07-Sep-16 12:50 PM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Copper (Cu)5.41 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Nickel (Ni)1.73 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN30.2 1
Vanadium (V) Low Level 1.54 ug/L EPA 200.8 09/28/2016 00:07 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Nickel (Ni)1.79 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR0.2 1
Vanadium (V) Low Level 1.91 ug/L EPA 200.8 09/12/2016 20:35 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 09/08/2016 14:04 HGRUVER251
Duke Energy Analytical Lab
Page 14 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028880
Collection Date:07-Sep-16 12:50 PM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Duke Energy Analytical Lab
Page 15 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028881
Collection Date:07-Sep-16 2:25 PM
Site:ABMW-02BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 09/12/2016 11:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 23 mg/L EPA 300.0 09/20/2016 16:52 BGN90340.5 5
Sulfate 3.2 mg/L EPA 300.0 09/20/2016 16:52 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:46 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 14:01 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 09/09/2016 15:18 JJMACKE0.005 1
Barium (Ba)0.065 mg/L EPA 200.7 09/09/2016 15:18 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 15:18 JJMACKE0.05 1
Iron (Fe)1.18 mg/L EPA 200.7 09/09/2016 15:18 JJMACKE0.01 1
Manganese (Mn)0.308 mg/L EPA 200.7 09/09/2016 15:18 JJMACKE0.005 1
Strontium (Sr)2.26 mg/L EPA 200.7 09/09/2016 15:18 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/09/2016 15:18 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)68.1 mg/L EPA 200.7 09/12/2016 16:06 JJMACKE0.01 1
Magnesium (Mg)11.1 mg/L EPA 200.7 09/12/2016 16:06 JJMACKE0.005 1
Potassium (K)6.43 mg/L EPA 200.7 09/12/2016 16:06 JJMACKE0.1 1
Sodium (Na)16.5 mg/L EPA 200.7 09/12/2016 16:06 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.030 mg/L EPA 200.7 09/12/2016 12:36 MHH71310.005 1
Barium (Ba)0.064 mg/L EPA 200.7 09/12/2016 12:36 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:36 MHH71310.05 1
Iron (Fe)1.22 mg/L EPA 200.7 09/12/2016 12:36 MHH71310.01 1
Manganese (Mn)0.291 mg/L EPA 200.7 09/12/2016 12:36 MHH71310.005 1
Strontium (Sr)2.30 mg/L EPA 200.7 09/12/2016 12:36 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/12/2016 12:36 MHH71310.005 1
Duke Energy Analytical Lab
Page 16 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028881
Collection Date:07-Sep-16 2:25 PM
Site:ABMW-02BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Molybdenum (Mo)2.19 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/28/2016 01:17 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Molybdenum (Mo)3.02 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR0.2 1
Vanadium (V) Low Level 0.308 ug/L EPA 200.8 09/12/2016 20:41 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 09/08/2016 14:04 HGRUVER251
Duke Energy Analytical Lab
Page 17 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028881
Collection Date:07-Sep-16 2:25 PM
Site:ABMW-02BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.0 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Duke Energy Analytical Lab
Page 18 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028882
Collection Date:07-Sep-16 3:56 PM
Site:BG-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 09/12/2016 11:29 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 09/20/2016 17:08 BGN90340.5 5
Sulfate 5.6 mg/L EPA 300.0 09/20/2016 17:08 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:48 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 14:03 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/09/2016 15:22 JJMACKE0.005 1
Barium (Ba)0.049 mg/L EPA 200.7 09/09/2016 15:22 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 15:22 JJMACKE0.05 1
Iron (Fe)0.164 mg/L EPA 200.7 09/09/2016 15:22 JJMACKE0.01 1
Manganese (Mn)0.139 mg/L EPA 200.7 09/09/2016 15:22 JJMACKE0.005 1
Strontium (Sr)0.316 mg/L EPA 200.7 09/09/2016 15:22 JJMACKE0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 09/09/2016 15:22 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)56.4 mg/L EPA 200.7 09/12/2016 16:09 JJMACKE0.01 1
Magnesium (Mg)13.1 mg/L EPA 200.7 09/12/2016 16:09 JJMACKE0.005 1
Potassium (K)3.31 mg/L EPA 200.7 09/12/2016 16:09 JJMACKE0.1 1
Sodium (Na)53.5 mg/L EPA 200.7 09/12/2016 16:09 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.151 mg/L EPA 200.7 09/12/2016 12:40 MHH71310.005 1
Barium (Ba)0.059 mg/L EPA 200.7 09/12/2016 12:40 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:40 MHH71310.05 1
Iron (Fe)0.553 mg/L EPA 200.7 09/12/2016 12:40 MHH71310.01 1
Manganese (Mn)0.194 mg/L EPA 200.7 09/12/2016 12:40 MHH71310.005 1
Strontium (Sr)0.378 mg/L EPA 200.7 09/12/2016 12:40 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/12/2016 12:40 MHH71310.005 1
Duke Energy Analytical Lab
Page 19 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028882
Collection Date:07-Sep-16 3:56 PM
Site:BG-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Copper (Cu)2.15 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN30.2 1
Vanadium (V) Low Level 2.98 ug/L EPA 200.8 09/28/2016 01:24 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR0.2 1
Vanadium (V) Low Level 5.34 ug/L EPA 200.8 09/12/2016 20:48 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 09/08/2016 14:04 HGRUVER251
Duke Energy Analytical Lab
Page 20 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028882
Collection Date:07-Sep-16 3:56 PM
Site:BG-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Duke Energy Analytical Lab
Page 21 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028883
Collection Date:07-Sep-16 3:56 PM
Site:BG-02 Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.011 mg-N/L EPA 353.2 09/12/2016 11:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 09/20/2016 17:23 BGN90340.5 5
Sulfate 5.6 mg/L EPA 300.0 09/20/2016 17:23 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:50 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 14:06 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/09/2016 15:25 JJMACKE0.005 1
Barium (Ba)0.052 mg/L EPA 200.7 09/09/2016 15:25 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 15:25 JJMACKE0.05 1
Iron (Fe)0.157 mg/L EPA 200.7 09/09/2016 15:25 JJMACKE0.01 1
Manganese (Mn)0.133 mg/L EPA 200.7 09/09/2016 15:25 JJMACKE0.005 1
Strontium (Sr)0.301 mg/L EPA 200.7 09/09/2016 15:25 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/09/2016 15:25 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)56.6 mg/L EPA 200.7 09/12/2016 16:30 JJMACKE0.01 1
Magnesium (Mg)13.0 mg/L EPA 200.7 09/12/2016 16:30 JJMACKE0.005 1
Potassium (K)3.28 mg/L EPA 200.7 09/12/2016 16:30 JJMACKE0.1 1
Sodium (Na)53.5 mg/L EPA 200.7 09/12/2016 16:30 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.118 mg/L EPA 200.7 09/12/2016 12:44 MHH71310.005 1
Barium (Ba)0.058 mg/L EPA 200.7 09/12/2016 12:44 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:44 MHH71310.05 1
Iron (Fe)0.506 mg/L EPA 200.7 09/12/2016 12:44 MHH71310.01 1
Manganese (Mn)0.192 mg/L EPA 200.7 09/12/2016 12:44 MHH71310.005 1
Strontium (Sr)0.374 mg/L EPA 200.7 09/12/2016 12:44 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/12/2016 12:44 MHH71310.005 1
Duke Energy Analytical Lab
Page 22 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028883
Collection Date:07-Sep-16 3:56 PM
Site:BG-02 Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN30.2 1
Vanadium (V) Low Level 3.02 ug/L EPA 200.8 09/28/2016 01:31 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR0.2 1
Vanadium (V) Low Level 5.29 ug/L EPA 200.8 09/12/2016 20:54 PARMSTR0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 360 mg/L SM2540C 09/08/2016 14:04 HGRUVER251
Duke Energy Analytical Lab
Page 23 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028883
Collection Date:07-Sep-16 3:56 PM
Site:BG-02 Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.7 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Duke Energy Analytical Lab
Page 24 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028887
Collection Date:07-Sep-16 4:25 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/19/2016 12:05 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/09/2016 15:29 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/09/2016 15:29 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/09/2016 15:29 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/09/2016 15:29 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/09/2016 15:29 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 09/09/2016 15:29 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 09/09/2016 15:29 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Copper (Cu)5.40 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/28/2016 01:38 CWSPEN30.3 1
Duke Energy Analytical Lab
Page 25 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028888
Collection Date:07-Sep-16 4:25 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 09/12/2016 11:31 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 09/20/2016 12:08 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 09/20/2016 12:08 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2016 12:53 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.017 mg/L EPA 200.7 09/12/2016 16:34 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 09/12/2016 16:34 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 09/12/2016 16:34 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 09/12/2016 16:34 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/12/2016 12:48 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/12/2016 12:48 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/12/2016 12:48 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/12/2016 12:48 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/12/2016 12:48 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 09/12/2016 12:48 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/12/2016 12:48 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Arsenic (As)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Beryllium (Be)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Chromium (Cr)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Cobalt (Co)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Copper (Cu)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Lead (Pb)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Nickel (Ni)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Selenium (Se)< 1 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/12/2016 21:01 PARMSTR0.3 1
Duke Energy Analytical Lab
Page 26 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
2016028888
Collection Date:07-Sep-16 4:25 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.618 mg/L SM5310C/EPA9060A 09/09/2016 09:54 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2016 11:03 HGRUVER51
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Duke Energy Analytical Lab
Page 27 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090240 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0008 mg-N/L -10.0008 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0008 mg-N/L -10.0008 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0013 mg-N/L -10.0013 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0002 mg-N/L -10.0002 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.31 3.01 103mg-N/L -11090103.1
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.308 3.01 102mg-N/L -11090103.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.308 3.01 102mg-N/L -11090103.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.308 3.01 102mg-N/L -11090103.08
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16080026 -- 2016023918
Nitrite + Nitrate
(Colorimetric)
1.24 0.25 106mg-N/L -1109011.24
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16080026 -- 2016023918
Nitrite + Nitrate
(Colorimetric)
1.25 0.25 110 3.79mg-N/L -1109011.25
Duke Energy Analytical Lab
Page 28 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090240 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090004 -- 2016027978
Nitrite + Nitrate
(Colorimetric)
0.23 0.25 91mg-N/L -1109010.23
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16090004 -- 2016027978
Nitrite + Nitrate
(Colorimetric)
0.213 0.25 84.4 7.52mg-N/L -1109010.213
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16090004 -- 2016027979
Nitrite + Nitrate
(Colorimetric)
0.342 0.25 93.1mg-N/L -1109010.342
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16090004 -- 2016027979
Nitrite + Nitrate
(Colorimetric)
0.38 0.25 108 14.8mg-N/L -1109010.38
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028880
Nitrite + Nitrate
(Colorimetric)
0.296 0.25 107mg-N/L -1109010.296
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028880
Nitrite + Nitrate
(Colorimetric)
0.279 0.25 99.9 6.81mg-N/L -1109010.279
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J16090011 -- 2016027994
Nitrite + Nitrate
(Colorimetric)
0.264 0.25 104mg-N/L -1109010.264
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J16090011 -- 2016027994
Nitrite + Nitrate
(Colorimetric)
0.26 0.25 103 1.47mg-N/L -1109010.26
Duke Energy Analytical Lab
Page 29 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090486 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0368 mg/L -10.0368 0.1 < 1/2 RDL
Sulfate -0.0003 mg/L -1-0.0003 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 8.09 5 105mg/L -1208018.09
Sulfate 7.64 5 105mg/L -1208017.64
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 8.09 5 105 0.0589mg/L -1208018.09
Sulfate 7.63 5 104 0.241mg/L -1208017.63
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.77 5 103mg/L -1208018.77
Sulfate 5.92 5 105mg/L -1208015.92
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.83 5 104 1.02mg/L -1208018.83
Sulfate 5.94 5 105 0.251mg/L -1208015.94
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.16 5 103mg/L -1208015.16
Sulfate 5.19 5 104mg/L -1208015.19
Duke Energy Analytical Lab
Page 30 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090384 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.968 1 97.1ug/L -1307010.968
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.985 1 98.8 1.74ug/L -1307010.985
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.99 2 99.5ug/L -1158511.99
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.94 2 97.2ug/L -1158511.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028879
Mercury (Hg) 0.987 1 97.3ug/L -1307010.987
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028879
Mercury (Hg) 0.994 1 98 0.717ug/L -1307010.994
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090185 -- 2016029039
Mercury (Hg) 0.994 1 100ug/L -1307010.994
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16090185 -- 2016029039
Mercury (Hg) 0.992 1 99.9 0.2ug/L -1307010.992
Duke Energy Analytical Lab
Page 31 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090385 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.94 2 97.2ug/L -1158511.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090113 -- 2016028672
Mercury (Hg) 0.968 1 97.1ug/L -1307010.968
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090113 -- 2016028672
Mercury (Hg) 0.985 1 98.8 1.74ug/L -1307010.985
Duke Energy Analytical Lab
Page 32 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090429 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.004 ug/L -1-0.004 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.01 2 101ug/L -1158512.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 97.9ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090269 -- 2016029352
Mercury (Hg) 1.02 1 102ug/L -1307011.02
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090269 -- 2016029352
Mercury (Hg) 1.01 1 101 1.28ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090303 -- 2016029524
Mercury (Hg) 1.01 1 102ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16090303 -- 2016029524
Mercury (Hg) 1.02 1 102 0.0978ug/L -1307011.02
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16090303 -- 2016029525
Mercury (Hg) 1.01 1 102ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16090303 -- 2016029525
Mercury (Hg) 1.01 1 102 0.295ug/L -1307011.01
Duke Energy Analytical Lab
Page 33 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090222 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000022 mg/L -1-0.000022 0.005 < 1/2 RDL
Barium (Ba) 0.000091 mg/L -10.000091 0.005 < 1/2 RDL
Boron (B) -0.000493 mg/L -1-0.000493 0.05 < 1/2 RDL
Iron (Fe) -0.000036 mg/L -1-0.000036 0.01 < 1/2 RDL
Manganese (Mn) -0.000099 mg/L -1-0.000099 0.005 < 1/2 RDL
Strontium (Sr) 0.000018 mg/L -10.000018 0.005 < 1/2 RDL
Zinc (Zn) -0.000358 mg/L -1-0.000358 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.06 2 103mg/L -1158512.06
Barium (Ba) 0.988 1 98.8mg/L -1158510.988
Boron (B) 2.02 2 101mg/L -1158512.02
Iron (Fe) 2.06 2 103mg/L -1158512.06
Manganese (Mn) 0.983 1 98.3mg/L -1158510.983
Strontium (Sr) 1.91 2 95.7mg/L -1158511.91
Zinc (Zn) 1.05 1 105mg/L -1158511.05
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028877
Aluminum (Al) 5.95 5 119mg/L -1307015.95
Barium (Ba) 5.75 5 115mg/L -1307015.75
Boron (B) 5.7 5 114mg/L -1307015.7
Iron (Fe) 5.56 5 111mg/L -1307015.56
Manganese (Mn) 6.07 5 116mg/L -1307016.07
Strontium (Sr) 5.82 5 113mg/L -1307015.82
Zinc (Zn) 5.76 5 115mg/L -1307015.76
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028877
Aluminum (Al) 5.92 5 118 0.438mg/L -1307015.92
Barium (Ba) 5.73 5 114 0.455mg/L -1307015.73
Boron (B) 5.68 5 113 0.353mg/L -1307015.68
Iron (Fe) 5.56 5 111 0.018mg/L -1307015.56
Manganese (Mn) 6.08 5 116 0.0343mg/L -1307016.08
Strontium (Sr) 5.82 5 113 0.053mg/L -1307015.82
Zinc (Zn) 5.76 5 115 0.104mg/L -1307015.76
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090185 -- 2016029038
Aluminum (Al) 5.93 5 119mg/L -1307015.93
Duke Energy Analytical Lab
Page 34 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090222 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090185 -- 2016029038
Barium (Ba) 5.82 5 116mg/L -1307015.82
Boron (B) 5.8 5 116mg/L -1307015.8
Iron (Fe) 5.54 5 110mg/L -1307015.54
Manganese (Mn) 5.84 5 110mg/L -1307015.84
Strontium (Sr) 6.13 5 119mg/L -1307016.13
Zinc (Zn) 5.73 5 114mg/L -1307015.73
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16090185 -- 2016029038
Aluminum (Al) 5.9 5 118 0.642mg/L -1307015.9
Barium (Ba) 5.77 5 115 0.78mg/L -1307015.77
Boron (B) 5.72 5 114 1.32mg/L -1307015.72
Iron (Fe) 5.52 5 109 0.456mg/L -1307015.52
Manganese (Mn) 5.82 5 110 0.491mg/L -1307015.82
Strontium (Sr) 6.08 5 118 0.86mg/L -1307016.08
Zinc (Zn) 5.7 5 114 0.543mg/L -1307015.7
Duke Energy Analytical Lab
Page 35 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090255 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00275 mg/L -10.00275 0.01 < 1/2 RDL
Magnesium (Mg) -0.000036 mg/L -1-0.000036 0.005 < 1/2 RDL
Potassium (K) -0.0138 mg/L -1-0.0138 0.1 < 1/2 RDL
Sodium (Na) -0.00325 mg/L -1-0.00325 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 1.99 2 99.7mg/L -1158511.99
Magnesium (Mg) 1.93 2 96.5mg/L -1158511.93
Potassium (K) 3.86 4 96.4mg/L -1158513.86
Sodium (Na) 8.09 8.1 99.9mg/L -1158518.09
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028877
Calcium (Ca) 21.4 5 123mg/L -13070121.4
Magnesium (Mg) 8.28 5 114mg/L -1307018.28
Potassium (K) 12.4 5 105mg/L -13070112.4
Sodium (Na) 53.7 5 148mg/L -13070153.7
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028877
Calcium (Ca) 21.6 5 126 2.56mg/L -13070121.6
Magnesium (Mg) 8.46 5 118 3.02mg/L -1307018.46
Potassium (K) 12.6 5 108 3.39mg/L -13070112.6
Sodium (Na) 54.8 5 169 13.4mg/L -13070154.8
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090185 -- 2016029038
Calcium (Ca) 62 5 47.6mg/L -13070162
Magnesium (Mg) 18.6 5 85.4mg/L -13070118.6
Potassium (K) 10.4 5 103mg/L -13070110.4
Sodium (Na) 26.8 5 87.9mg/L -13070126.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16090185 -- 2016029038
Calcium (Ca) 61.9 5 45.6 4.33mg/L -13070161.9
Magnesium (Mg) 18.6 5 85.6 0.234mg/L -13070118.6
Potassium (K) 10.4 5 103 0.854mg/L -13070110.4
Sodium (Na) 26.8 5 88 0.091mg/L -13070126.8
Duke Energy Analytical Lab
Page 36 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090201 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00178 mg/L -10.00178 0.005 < 1/2 RDL
Barium (Ba) -0.000019 mg/L -1-0.000019 0.005 < 1/2 RDL
Boron (B) -0.00104 mg/L -1-0.00104 0.05 < 1/2 RDL
Iron (Fe) 0.00471 mg/L -10.00471 0.01 < 1/2 RDL
Manganese (Mn) -0.000125 mg/L -1-0.000125 0.005 < 1/2 RDL
Strontium (Sr) 0.00002 mg/L -10.00002 0.005 < 1/2 RDL
Zinc (Zn) -0.000605 mg/L -1-0.000605 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.52 5 90.5mg/L -1158514.52
Barium (Ba) 4.89 5 97.8mg/L -1158514.89
Boron (B) 4.77 5 95.4mg/L -1158514.77
Iron (Fe) 4.93 5 98.7mg/L -1158514.93
Manganese (Mn) 4.86 5 97.2mg/L -1158514.86
Strontium (Sr) 4.81 5 96.2mg/L -1158514.81
Zinc (Zn) 4.85 5 97.1mg/L -1158514.85
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028877
Aluminum (Al) 4.75 5 93.8mg/L -1307014.75
Barium (Ba) 5.07 5 101mg/L -1307015.07
Boron (B) 4.99 5 99.2mg/L -1307014.99
Iron (Fe) 5.15 5 102mg/L -1307015.15
Manganese (Mn) 5.3 5 99.5mg/L -1307015.3
Strontium (Sr) 5.16 5 99.8mg/L -1307015.16
Zinc (Zn) 4.97 5 99.2mg/L -1307014.97
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028877
Aluminum (Al) 4.76 5 94 0.234mg/L -1307014.76
Barium (Ba) 5.07 5 101 0.0198mg/L -1307015.07
Boron (B) 4.97 5 98.7 0.566mg/L -1307014.97
Iron (Fe) 5.14 5 102 0.0983mg/L -1307015.14
Manganese (Mn) 5.29 5 99.4 0.121mg/L -1307015.29
Strontium (Sr) 5.13 5 99.2 0.523mg/L -1307015.13
Zinc (Zn) 4.96 5 99.1 0.121mg/L -1307014.96
Duke Energy Analytical Lab
Page 37 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090621 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.029 ug/L -1-0.029 1 < 1/2 RDL
Arsenic (As) -0.024 ug/L -1-0.024 1 < 1/2 RDL
Beryllium (Be) 0.046 ug/L -10.046 1 < 1/2 RDL
Cadmium (Cd) 0.001 ug/L -10.001 1 < 1/2 RDL
Chromium (Cr) 0 ug/L -10 1 < 1/2 RDL
Cobalt (Co) 0.004 ug/L -10.004 1 < 1/2 RDL
Copper (Cu) -0.339 ug/L -1-0.339 1 < 1/2 RDL
Lead (Pb) -0.003 ug/L -1-0.003 1 < 1/2 RDL
Molybdenum (Mo) 0.023 ug/L -10.023 1 < 1/2 RDL
Nickel (Ni) -0.221 ug/L -1-0.221 1 < 1/2 RDL
Selenium (Se) -0.106 ug/L -1-0.106 1 < 1/2 RDL
Thallium (Tl) Low Level -0.003 ug/L -1-0.003 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.255 ug/L -1-0.255 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.6 50 99.3ug/L -11585149.6
Arsenic (As) 50.2 50 100ug/L -11585150.2
Beryllium (Be) 50.6 50 101ug/L -11585150.6
Cadmium (Cd) 52.2 50 104ug/L -11585152.2
Chromium (Cr) 51.9 50 104ug/L -11585151.9
Cobalt (Co) 51.2 50 102ug/L -11585151.2
Copper (Cu) 51.6 50 103ug/L -11585151.6
Lead (Pb) 48.9 50 97.8ug/L -11585148.9
Molybdenum (Mo) 50.8 50 102ug/L -11585150.8
Nickel (Ni) 53.4 50 107ug/L -11585153.4
Selenium (Se) 47 50 93.9ug/L -11585147
Thallium (Tl) Low Level 49 50 98ug/L -11585149
Vanadium (V) Low Level 50.2 50 100ug/L -11585150.2
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028880
Antimony (Sb) 47.6 50 95.3ug/L -13070147.6
Arsenic (As) 48.3 50 96.4ug/L -13070148.3
Beryllium (Be) 51.8 50 104ug/L -13070151.8
Cadmium (Cd) 49.4 50 98.8ug/L -13070149.4
Chromium (Cr) 50.1 50 99.9ug/L -13070150.1
Cobalt (Co) 48.6 50 97.2ug/L -13070148.6
Copper (Cu) 54.5 50 98.1ug/L -13070154.5
Lead (Pb) 48.6 50 95.8ug/L -13070148.6
Duke Energy Analytical Lab
Page 38 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090621 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028880
Molybdenum (Mo) 49.3 50 97.2ug/L -13070149.3
Nickel (Ni) 51.7 50 100ug/L -13070151.7
Selenium (Se) 46.1 50 92.4ug/L -13070146.1
Thallium (Tl) Low Level 37.7 50 75.3ug/L -13070137.7
Vanadium (V) Low Level 51.1 50 99.2ug/L -13070151.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028880
Antimony (Sb) 47.3 50 94.5 0.763ug/L -13070147.3
Arsenic (As) 48 50 95.7 0.673ug/L -13070148
Beryllium (Be) 53.3 50 107 2.89ug/L -13070153.3
Cadmium (Cd) 49.3 50 98.5 0.229ug/L -13070149.3
Chromium (Cr) 50.2 50 100 0.286ug/L -13070150.2
Cobalt (Co) 48.4 50 96.6 0.572ug/L -13070148.4
Copper (Cu) 54.1 50 97.4 0.751ug/L -13070154.1
Lead (Pb) 48.9 50 96.5 0.687ug/L -13070148.9
Molybdenum (Mo) 49.1 50 96.9 0.392ug/L -13070149.1
Nickel (Ni) 51.9 50 100 0.421ug/L -13070151.9
Selenium (Se) 46.3 50 92.7 0.395ug/L -13070146.3
Thallium (Tl) Low Level 38.2 50 76.4 1.48ug/L -13070138.2
Vanadium (V) Low Level 51.4 50 99.7 0.563ug/L -13070151.4
Duke Energy Analytical Lab
Page 39 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090207 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0175 ug/L -1-0.0175 1 < 1/2 RDL
Arsenic (As) -0.0066 ug/L -1-0.0066 1 < 1/2 RDL
Beryllium (Be) 0.0272 ug/L -10.0272 1 < 1/2 RDL
Cadmium (Cd) 0.0015 ug/L -10.0015 1 < 1/2 RDL
Chromium (Cr) 0.0029 ug/L -10.0029 1 < 1/2 RDL
Cobalt (Co) 0.0035 ug/L -10.0035 1 < 1/2 RDL
Copper (Cu) -0.0239 ug/L -1-0.0239 1 < 1/2 RDL
Lead (Pb) 0.0023 ug/L -10.0023 1 < 1/2 RDL
Molybdenum (Mo) -0.0009 ug/L -1-0.0009 1 < 1/2 RDL
Nickel (Ni) -0.0475 ug/L -1-0.0475 1 < 1/2 RDL
Selenium (Se) -0.009 ug/L -1-0.009 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0168 ug/L -1-0.0168 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.0077 ug/L -1-0.0077 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 52.3 50 105ug/L -11585152.3
Arsenic (As) 49.5 50 99.1ug/L -11585149.5
Beryllium (Be) 49.9 50 99.8ug/L -11585149.9
Cadmium (Cd) 49.9 50 99.9ug/L -11585149.9
Chromium (Cr) 49.4 50 98.9ug/L -11585149.4
Cobalt (Co) 49.3 50 98.7ug/L -11585149.3
Copper (Cu) 49.4 50 98.9ug/L -11585149.4
Lead (Pb) 50 50 100ug/L -11585150
Molybdenum (Mo) 49.3 50 98.6ug/L -11585149.3
Nickel (Ni) 50.2 50 100ug/L -11585150.2
Selenium (Se) 48.7 50 97.4ug/L -11585148.7
Thallium (Tl) Low Level 48.8 50 97.5ug/L -11585148.8
Vanadium (V) Low Level 49 50 97.9ug/L -11585149
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028878
Antimony (Sb) 51.9 50 104ug/L -13070151.9
Arsenic (As) 49 50 97.9ug/L -13070149
Beryllium (Be) 50.2 50 100ug/L -13070150.2
Cadmium (Cd) 49.3 50 98.6ug/L -13070149.3
Chromium (Cr) 51.4 50 96.7ug/L -13070151.4
Cobalt (Co) 48.8 50 97.2ug/L -13070148.8
Copper (Cu) 49.7 50 98.1ug/L -13070149.7
Lead (Pb) 49.6 50 98.9ug/L -13070149.6
Duke Energy Analytical Lab
Page 40 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090207 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028878
Molybdenum (Mo) 49.5 50 98ug/L -13070149.5
Nickel (Ni) 51.6 50 99.1ug/L -13070151.6
Selenium (Se) 47.5 50 95ug/L -13070147.5
Thallium (Tl) Low Level 48.4 50 96.7ug/L -13070148.4
Vanadium (V) Low Level 50.4 50 98.6ug/L -13070150.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090155 -- 2016028878
Antimony (Sb) 51.9 50 104 0.0368ug/L -13070151.9
Arsenic (As) 49.2 50 98.3 0.466ug/L -13070149.2
Beryllium (Be) 51.5 50 103 2.54ug/L -13070151.5
Cadmium (Cd) 49.6 50 99.2 0.615ug/L -13070149.6
Chromium (Cr) 51.2 50 96.4 0.363ug/L -13070151.2
Cobalt (Co) 49.1 50 97.8 0.635ug/L -13070149.1
Copper (Cu) 49.8 50 98.3 0.229ug/L -13070149.8
Lead (Pb) 49.7 50 99.2 0.33ug/L -13070149.7
Molybdenum (Mo) 49.8 50 98.5 0.507ug/L -13070149.8
Nickel (Ni) 51.8 50 99.5 0.472ug/L -13070151.8
Selenium (Se) 48 50 96 1.12ug/L -13070148
Thallium (Tl) Low Level 48.7 50 97.2 0.469ug/L -13070148.7
Vanadium (V) Low Level 50.3 50 98.3 0.34ug/L -13070150.3
Duke Energy Analytical Lab
Page 41 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090158 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -11 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16090155 -- 2016028877
TDS 1.73mg/L -1229
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16090155 -- 2016028878
TDS 2mg/L -199
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 104mg/L -110901104
Duke Energy Analytical Lab
Page 42 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090223 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 78mg/L -1208016.09
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 87.8 11.8mg/L -1208016.29
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 101mg/L -1208013.03
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 95.2 6.16mg/L -1208012.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 97.6mg/L -1158512.8
Duke Energy Analytical Lab
Page 43 of 89
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090155
Q16090187 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16080026 -- 2016023918
TSS 15.4mg/L -11.4
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16090155 -- 2016028877
TSS 0mg/L -11.2
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 92.8mg/L -11090146.4
Duke Energy Analytical Lab
Page 44 of 89
#=CL#
September 14, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92311601
92311601
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16090155
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on September 08, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 26
Duke Energy Analytical Lab
Page 45 of 89
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92311601
J16090155
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
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Missouri Certification #: 236
Montana Certification #: Cert 0074
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Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
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2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
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North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 26
Duke Energy Analytical Lab
Page 46 of 89
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92311601
J16090155
Lab ID Sample ID Matrix Date Collected Date Received
92311601001 2016028877 Water 09/07/16 08:21 09/08/16 11:51
92311601002 2016028878 Water 09/07/16 10:53 09/08/16 11:51
92311601003 2016028879 Water 09/07/16 10:54 09/08/16 11:51
92311601004 2016028880 Water 09/07/16 12:50 09/08/16 11:51
92311601005 2016028881 Water 09/07/16 14:25 09/08/16 11:51
92311601006 2016028882 Water 09/07/16 15:56 09/08/16 11:51
92311601007 2016028883 Water 09/07/16 15:56 09/08/16 11:51
92311601008 2016028888 Water 09/07/16 16:25 09/08/16 11:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 26
Duke Energy Analytical Lab
Page 47 of 89
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92311601
J16090155
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92311601001 2016028877 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92311601002 2016028878 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92311601003 2016028879 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92311601004 2016028880 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92311601005 2016028881 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92311601006 2016028882 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92311601007 2016028883 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
EPA 218.7 1 PASI-OAEM
92311601008 2016028888 RSK 175 Modified 1 PASI-CWDV
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AMDW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 26
Duke Energy Analytical Lab
Page 48 of 89
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92311601
J16090155
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92311601001 2016028877
Alkalinity,Bicarbonate (CaCO3)130 mg/L 09/09/16 17:465.0SM 2320B
Alkalinity, Total as CaCO3 130 mg/L 09/09/16 17:465.0SM 2320B
92311601002 2016028878
Methane 19.4 ug/L 09/09/16 14:2910.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)53.5 mg/L 09/09/16 17:585.0SM 2320B
Alkalinity, Total as CaCO3 53.5 mg/L 09/09/16 17:585.0SM 2320B
Chromium, Hexavalent 0.75 ug/L 09/13/16 10:070.090EPA 218.7
92311601003 2016028879
Alkalinity,Bicarbonate (CaCO3)9.5 mg/L 09/09/16 18:105.0SM 2320B
Alkalinity, Total as CaCO3 9.5 mg/L 09/09/16 18:105.0SM 2320B
Chromium, Hexavalent 0.16 ug/L 09/12/16 18:220.030EPA 218.7
92311601004 2016028880
Alkalinity,Bicarbonate (CaCO3)103 mg/L 09/09/16 18:195.0SM 2320B
Alkalinity, Total as CaCO3 103 mg/L 09/09/16 18:195.0SM 2320B
Chromium, Hexavalent 0.070 ug/L 09/12/16 18:350.030EPA 218.7
92311601005 2016028881
Methane 69.8 ug/L 09/12/16 10:3610.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)237 mg/L 09/09/16 18:315.0SM 2320B
Alkalinity, Total as CaCO3 237 mg/L 09/09/16 18:315.0SM 2320B
Sulfide 0.46 mg/L 09/14/16 01:500.10SM 4500-S2D
92311601006 2016028882
Methane 1670 ug/L 09/12/16 10:5210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)257 mg/L 09/09/16 18:435.0SM 2320B
Alkalinity, Total as CaCO3 257 mg/L 09/09/16 18:435.0SM 2320B
92311601007 2016028883
Methane 1570 ug/L 09/12/16 11:0710.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)258 mg/L 09/09/16 18:585.0SM 2320B
Alkalinity, Total as CaCO3 258 mg/L 09/09/16 18:585.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 5 of 26
Duke Energy Analytical Lab
Page 49 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92311601
J16090155
Method:
Client:Duke Energy
RSK 175 Modified
Date:September 14, 2016
Description:RSK 175 Headspace
General Information:
8 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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[phone]
Page 6 of 26
Duke Energy Analytical Lab
Page 50 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92311601
J16090155
Method:
Client:Duke Energy
SM 2320B
Date:September 14, 2016
Description:2320B Alkalinity
General Information:
8 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 26
Duke Energy Analytical Lab
Page 51 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92311601
J16090155
Method:
Client:Duke Energy
SM 4500-S2D
Date:September 14, 2016
Description:4500S2D Sulfide Water
General Information:
8 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 26
Duke Energy Analytical Lab
Page 52 of 89
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92311601
J16090155
Method:
Client:Duke Energy
EPA 218.7
Date:September 14, 2016
Description:Hexavalent Chromium by IC
General Information:
7 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 320078
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92311374001,92311814001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1702046)
• Chromium, Hexavalent
• MSD (Lab ID: 1702047)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 26
Duke Energy Analytical Lab
Page 53 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028877 Lab ID:92311601001 Collected:09/07/16 08:21 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 09/09/16 14:14 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)130 mg/L 09/09/16 17:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 17:465.0 1
Alkalinity, Total as CaCO3 130 mg/L 09/09/16 17:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 09/14/16 01:50 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 09/12/16 17:56 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 26
Duke Energy Analytical Lab
Page 54 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028878 Lab ID:92311601002 Collected:09/07/16 10:53 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 19.4 ug/L 09/09/16 14:29 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)53.5 mg/L 09/09/16 17:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 17:585.0 1
Alkalinity, Total as CaCO3 53.5 mg/L 09/09/16 17:585.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 09/14/16 01:50 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.75 ug/L 09/13/16 10:07 18540-29-90.090 3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 26
Duke Energy Analytical Lab
Page 55 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028879 Lab ID:92311601003 Collected:09/07/16 10:54 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 09/09/16 14:44 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)9.5 mg/L 09/09/16 18:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 18:105.0 1
Alkalinity, Total as CaCO3 9.5 mg/L 09/09/16 18:105.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 09/14/16 01:50 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.16 ug/L 09/12/16 18:22 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 26
Duke Energy Analytical Lab
Page 56 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028880 Lab ID:92311601004 Collected:09/07/16 12:50 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 09/09/16 15:00 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)103 mg/L 09/09/16 18:195.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 18:195.0 1
Alkalinity, Total as CaCO3 103 mg/L 09/09/16 18:195.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 09/14/16 01:50 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.070 ug/L 09/12/16 18:35 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 26
Duke Energy Analytical Lab
Page 57 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028881 Lab ID:92311601005 Collected:09/07/16 14:25 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 69.8 ug/L 09/12/16 10:36 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)237 mg/L 09/09/16 18:315.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 18:315.0 1
Alkalinity, Total as CaCO3 237 mg/L 09/09/16 18:315.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide 0.46 mg/L 09/14/16 01:50 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 09/12/16 18:48 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 26
Duke Energy Analytical Lab
Page 58 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028882 Lab ID:92311601006 Collected:09/07/16 15:56 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 1670 ug/L 09/12/16 10:52 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)257 mg/L 09/09/16 18:435.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 18:435.0 1
Alkalinity, Total as CaCO3 257 mg/L 09/09/16 18:435.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 09/14/16 01:50 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 09/12/16 19:01 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 26
Duke Energy Analytical Lab
Page 59 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028883 Lab ID:92311601007 Collected:09/07/16 15:56 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 1570 ug/L 09/12/16 11:07 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)258 mg/L 09/09/16 18:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 18:585.0 1
Alkalinity, Total as CaCO3 258 mg/L 09/09/16 18:585.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 09/14/16 01:50 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 09/12/16 19:14 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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Huntersville, NC 28078
[phone]
Page 16 of 26
Duke Energy Analytical Lab
Page 60 of 89
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92311601
J16090155
Sample:2016028888 Lab ID:92311601008 Collected:09/07/16 16:25 Received:09/08/16 11:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 09/12/16 11:22 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 09/09/16 19:325.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 09/09/16 19:325.0 1
Alkalinity, Total as CaCO3 ND mg/L 09/09/16 19:325.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 09/14/16 01:50 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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[phone]
Page 17 of 26
Duke Energy Analytical Lab
Page 61 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92311601
J16090155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
327972
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1817339
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N209/09/16 09:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1817340LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 396 N239610070-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1817341MATRIX SPIKE SAMPLE:
MSSpike
Result
92310972002
Methane ug/L 386 N23969870-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92310972003
1817343SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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Page 18 of 26
Duke Energy Analytical Lab
Page 62 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92311601
J16090155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328132
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92311601005, 92311601006, 92311601007, 92311601008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1818353
Associated Lab Samples:92311601005, 92311601006, 92311601007, 92311601008
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N209/12/16 10:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1818354LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1818355
Methane ug/L 412 N239610470-13098389 6 20
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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Huntersville, NC 28078
[phone]
Page 19 of 26
Duke Energy Analytical Lab
Page 63 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92311601
J16090155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
327926
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004, 92311601005, 92311601006, 92311601007,
92311601008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1817131
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004, 92311601005, 92311601006, 92311601007,
92311601008
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 09/09/16 16:05
Alkalinity, Total as CaCO3 mg/L ND 5.0 09/09/16 16:05
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 09/09/16 16:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1817132LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.750 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1817133MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92311515003
1817134
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 99 80-12092 3 255096.1 146 142
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1817135MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92311601008
1817136
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12096 1 2550ND48.4 48.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 20 of 26
Duke Energy Analytical Lab
Page 64 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92311601
J16090155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328347
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004, 92311601005, 92311601006, 92311601007,
92311601008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1819792
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004, 92311601005, 92311601006, 92311601007,
92311601008
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 09/14/16 01:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1819793LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.52.5 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1819794MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92311515001
1819795
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 98 80-12099 1 10.5ND 0.49 0.50
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1819796MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92311601006
1819797
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 97 80-12099 1 10.5ND 0.49 0.50
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
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[phone]
Page 21 of 26
Duke Energy Analytical Lab
Page 65 of 89
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92311601
J16090155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
320078
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004, 92311601005, 92311601006, 92311601007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1702044
Associated Lab Samples:92311601001, 92311601002, 92311601003, 92311601004, 92311601005, 92311601006, 92311601007
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 09/12/16 16:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1702045LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.079.075 105 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1702046MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92311374001
1702047
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M67.5 82 85-11569 4 207.519.4 25.6 24.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1702048MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92311814001
1702049
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .025 93 85-11590 0 20.0250.19 0.21 0.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 26
Duke Energy Analytical Lab
Page 66 of 89
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92311601
J16090155
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
The lab does not hold TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 26
Duke Energy Analytical Lab
Page 67 of 89
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92311601
J16090155
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92311601001 3279722016028877RSK 175 Modified
92311601002 3279722016028878RSK 175 Modified
92311601003 3279722016028879RSK 175 Modified
92311601004 3279722016028880RSK 175 Modified
92311601005 3281322016028881RSK 175 Modified
92311601006 3281322016028882RSK 175 Modified
92311601007 3281322016028883RSK 175 Modified
92311601008 3281322016028888RSK 175 Modified
92311601001 3279262016028877SM 2320B
92311601002 3279262016028878SM 2320B
92311601003 3279262016028879SM 2320B
92311601004 3279262016028880SM 2320B
92311601005 3279262016028881SM 2320B
92311601006 3279262016028882SM 2320B
92311601007 3279262016028883SM 2320B
92311601008 3279262016028888SM 2320B
92311601001 3283472016028877SM 4500-S2D
92311601002 3283472016028878SM 4500-S2D
92311601003 3283472016028879SM 4500-S2D
92311601004 3283472016028880SM 4500-S2D
92311601005 3283472016028881SM 4500-S2D
92311601006 3283472016028882SM 4500-S2D
92311601007 3283472016028883SM 4500-S2D
92311601008 3283472016028888SM 4500-S2D
92311601001 3200782016028877EPA 218.7
92311601002 3200782016028878EPA 218.7
92311601003 3200782016028879EPA 218.7
92311601004 3200782016028880EPA 218.7
92311601005 3200782016028881EPA 218.7
92311601006 3200782016028882EPA 218.7
92311601007 3200782016028883EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/14/2016 04:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 26
Duke Energy Analytical Lab
Page 68 of 89
Page 25 of 26
Duke Energy Analytical Lab
Page 69 of 89
Page 26 of 26
Duke Energy Analytical Lab
Page 70 of 89

September 28, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 405456
SDG: J16090155

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on September 08, 2016. This original data report has been prepared and reviewed in
accordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944
Enclosures
Page 1 of 18
Chelsea Seagle for
Duke Energy Analytical Lab
Page 71 of 89
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16090155 GEL Work Order: 405456
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 18
Duke Energy Analytical Lab
Page 72 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: September 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1597119
1597119
1601517
1597779
1598005
1401
1722
0833
1157
0850
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
09/22/16
09/22/16
09/27/16
09/27/16
09/22/16
SKJ
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
405456001
Water
07-SEP-16 08:21
08-SEP-16
2016028877 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.662
0.491
1
2
3
4
5
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000314
ND
ND
ND
ND
2.00
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"93.6 (15%-125%)
The following Prep Methods were performed:
SW846 3010A
SW846 3010A
SW 846 3010 Acid Digestion
SW 846 3010 Acid Digestion
09/23/16
09/09/16
1601516
1597117
1922
0805
JP1
SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 18
Duke Energy Analytical Lab
Page 73 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: September 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1597119
1597119
1601517
1597779
1598005
1407
1731
0839
1157
0850
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
09/22/16
09/22/16
09/27/16
09/27/16
09/22/16
SKJ
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
405456002
Water
07-SEP-16 10:53
08-SEP-16
2016028878 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.458
0.656
1
2
3
4
5
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000105
ND
ND
ND
ND
2.19
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"99.6 (15%-125%)
The following Prep Methods were performed:
SW846 3010A
SW846 3010A
SW 846 3010 Acid Digestion
SW 846 3010 Acid Digestion
09/23/16
09/09/16
1601516
1597117
1922
0805
JP1
SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 18
Duke Energy Analytical Lab
Page 74 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: September 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1597119
1597119
1601517
1597779
1598005
1411
1733
0841
1157
0850
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
09/22/16
09/22/16
09/27/16
09/27/16
09/22/16
SKJ
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
405456003
Water
07-SEP-16 10:54
08-SEP-16
2016028879 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.586
0.765
1
2
3
4
5
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.56
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"80.5 (15%-125%)
The following Prep Methods were performed:
SW846 3010A
SW846 3010A
SW 846 3010 Acid Digestion
SW 846 3010 Acid Digestion
09/23/16
09/09/16
1601516
1597117
1922
0805
JP1
SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 18
Duke Energy Analytical Lab
Page 75 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: September 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1597119
1597119
1601517
1597779
1598005
1413
1734
0842
1157
0850
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
09/22/16
09/22/16
09/27/16
09/27/16
09/22/16
SKJ
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
405456004
Water
07-SEP-16 12:50
08-SEP-16
2016028880 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.531
0.715
1
2
3
4
5
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.64
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"88.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A
SW846 3010A
SW 846 3010 Acid Digestion
SW 846 3010 Acid Digestion
09/23/16
09/09/16
1601516
1597117
1922
0805
JP1
SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 18
Duke Energy Analytical Lab
Page 76 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: September 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1597119
1597119
1601517
1597779
1598005
1414
1736
0844
1157
0850
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
09/22/16
09/22/16
09/27/16
09/27/16
09/22/16
SKJ
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
405456005
Water
07-SEP-16 14:25
08-SEP-16
2016028881 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.732
0.758
1
2
3
4
5
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000525
ND
ND
ND
1.00
3.94
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"90 (15%-125%)
The following Prep Methods were performed:
SW846 3010A
SW846 3010A
SW 846 3010 Acid Digestion
SW 846 3010 Acid Digestion
09/23/16
09/09/16
1601516
1597117
1922
0805
JP1
SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 7 of 18
Duke Energy Analytical Lab
Page 77 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: September 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1597119
1597119
1601517
1597779
1598005
1416
1738
1427
1157
0920
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
09/22/16
09/22/16
09/27/16
09/27/16
09/22/16
SKJ
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
405456006
Water
07-SEP-16 15:56
08-SEP-16
2016028882 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.829
0.620
1
2
3
4
5
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000791
ND
ND
ND
ND
0.997
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"68.2 (15%-125%)
The following Prep Methods were performed:
SW846 3010A
SW846 3010A
SW 846 3010 Acid Digestion
SW 846 3010 Acid Digestion
09/23/16
09/09/16
1601516
1597117
1922
0805
JP1
SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 8 of 18
Duke Energy Analytical Lab
Page 78 of 89
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: September 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1597119
1597119
1601517
1597779
1598005
1417
1739
1428
1157
0920
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
09/22/16
09/22/16
09/27/16
09/27/16
09/22/16
SKJ
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
405456007
Water
07-SEP-16 15:56
08-SEP-16
2016028883 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.507
0.296
1
2
3
4
5
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000827
ND
ND
ND
ND
1.28
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"94.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A
SW846 3010A
SW 846 3010 Acid Digestion
SW 846 3010 Acid Digestion
09/23/16
09/09/16
1601516
1597117
1922
0805
JP1
SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1597119
1601517
Batch
Batch
Uranium-233
Uranium-234
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-233
Uranium-234
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-233
Uranium-234
Uranium-238
Uranium-236
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
September 28, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
ug/L
ug/L
ug/mL
Anlst Date Time
SKJ
SKJ
09/22/16 17:24
09/22/16 14:02
09/22/16 13:59
09/22/16 17:21
09/22/16 17:19
09/22/16 13:58
09/22/16 14:04
09/22/16 17:25
09/22/16 17:27
09/22/16 14:05
09/27/16 08:34
QC
ND
ND
0.000308
0.0525
0.000602
0.000577
ND
ND
ND
0.0519
0.00057
0.000568
ND
ND
0.073
ND
NOM Sample
ND
ND
0.000314
0.000314
ND
ND
ND
ND
0.314
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-10%)
Qual
U
U
U
U
U
U
U
J
U
QC1203623511 405456001
QC1203623509
QC1203623510
QC1203623508
QC1203623512 405456001
QC1203623513 405456001
QC1203623514 405456001
QC1203634243 405456001
QC1203634242
N/A
N/A
2.09
N/A
N/A
16.1
N/A
REC%
106
120
105
104
114
103
0.0496
0.0005
0.00055
0.0496
0.0005
0.00055
DUP
LCS
LCS
MB
MS
MS
SDILT
DUP
LCS
405456Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^
RPD%
Page 1 of 3
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1601517
1597779
1598005
Batch
Batch
Batch
Uranium-236
Uranium-236
Uranium-236
Uranium-236
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/mL
ug/mL
ug/mL
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
09/27/16 08:31
09/27/16 08:30
09/27/16 08:36
09/27/16 08:37
09/27/16 12:05
09/27/16 12:05
09/27/16 12:05
09/22/16 11:00
09/22/16 11:00
09/22/16 10:25
09/22/16 11:00
QC
0.00407
0.000025
0.0042
ND
0.158
7.68
0.230
5.20
21.1
0.189
115
NOM Sample
ND
ND
0.0147
4.37
4.37
Range
(80%-120%)
(75%-125%)
(0%-10%)
N/A
(75%-125%)
(0%-20%)
(75%-125%)
(75%-125%)
Qual
J
U
U
U
U
QC1203634241
QC1203634244 405456001
QC1203634245 405456001
QC1203625319 405457008
QC1203625320
QC1203625318
QC1203625903 405457012
QC1203625905
QC1203625902
QC1203625904 405457012
The Qualifiers in this report are defined as follows:
N/A
N/A
17.5
REC%
81.5
84
104
86.6
90.3
0.005
0.005
7.36
24.4
122
MB
MS
SDILT
DUP
LCS
MB
DUP
LCS
MB
MS
405456Workorder:
**
<
>
BD
E
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
U
U
U
RPD%
Notes:
Page 2 of 3
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
405456Workorder:
FA
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16090155
Work Order #: 405456

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1597119

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1597117
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
405456001 2016028877
405456002 2016028878
405456003 2016028879
405456004 2016028880
405456005 2016028881
405456006 2016028882
405456007 2016028883
1203623508 Method Blank (MB)ICP-MS
1203623509 Laboratory Control Sample (LCS)
1203623510 Laboratory Control Sample (LCS)
1203623514 405456001(2016028877L) Serial Dilution (SD)
1203623511 405456001(2016028877D) Sample Duplicate (DUP)
1203623512 405456001(2016028877S) Matrix Spike (MS)
1203623513 405456001(2016028877S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1601517

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1601516
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The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
405456001 2016028877
405456002 2016028878
405456003 2016028879
405456004 2016028880
405456005 2016028881
405456006 2016028882
405456007 2016028883
1203634241 Method Blank (MB)ICP-MS
1203634242 Laboratory Control Sample (LCS)
1203634245 405456001(2016028877L) Serial Dilution (SD)
1203634243 405456001(2016028877D) Sample Duplicate (DUP)
1203634244 405456001(2016028877S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1597779
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
405456001 2016028877
405456002 2016028878
405456003 2016028879
405456004 2016028880
405456005 2016028881
405456006 2016028882
405456007 2016028883
1203625318 Method Blank (MB)
1203625319 405457008(NonSDG) Sample Duplicate (DUP)
1203625320 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

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Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1598005
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
405456001 2016028877
405456002 2016028878
405456003 2016028879
405456004 2016028880
405456005 2016028881
405456006 2016028882
405456007 2016028883
1203625902 Method Blank (MB)
1203625903 405457012(NonSDG) Sample Duplicate (DUP)
1203625904 405457012(NonSDG) Matrix Spike (MS)
1203625905 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203625904 (Non SDG 405457012MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 28 September 2016
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Duke Energy Analytical Lab
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