NC0038377_J16070378report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070378
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:8/1/2016
Customer Address:Mayo Steam Plant
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Page 1 of 83
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016021704 MAYO STEAM 13-Jul-16 9:32 AM Kaitlyn Fox MW-11BR
2016021705 MAYO STEAM 13-Jul-16 11:46 AM Kaitlyn Fox MW-10BR
2016021706 MAYO STEAM 13-Jul-16 1:44 PM Kaitlyn Fox ABMW-02
2016021707 MAYO STEAM 13-Jul-16 3:41 PM Kaitlyn Fox BG-2
2016021708 MAYO STEAM 13-Jul-16 4:40 PM Kaitlyn Fox BG-1
2016021709 MAYO STEAM 13-Jul-16 9:45 AM Kaitlyn Fox Filter Blank
2016021710 MAYO STEAM 13-Jul-16 9:45 AM Kaitlyn Fox Equipment Blank
7 Total Samples
Page 2 of 83
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:8/1/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021704
Collection Date:13-Jul-16 9:32 AM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.354 mg-N/L EPA 353.2 07/18/2016 13:25 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 07/19/2016 14:48B2 BGN90340.5 5
Sulfate 12 mg/L EPA 300.0 07/19/2016 14:48 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:36 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 12:01 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.242 mg/L EPA 200.7 07/18/2016 12:03 JJMACKE0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 07/18/2016 12:03 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 12:03 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/18/2016 12:03 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/18/2016 12:03 JJMACKE0.005 1
Strontium (Sr)0.249 mg/L EPA 200.7 07/18/2016 12:03 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 07/18/2016 12:03 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)20.8 mg/L EPA 200.7 07/19/2016 14:11 JJMACKE0.01 1
Magnesium (Mg)1.70 mg/L EPA 200.7 07/19/2016 14:11 JJMACKE0.005 1
Potassium (K)7.78 mg/L EPA 200.7 07/19/2016 14:11 JJMACKE0.1 1
Sodium (Na)17.3 mg/L EPA 200.7 07/19/2016 14:11 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.451 mg/L EPA 200.7 07/23/2016 11:31 JJMACKE0.005 1
Barium (Ba)0.027 mg/L EPA 200.7 07/23/2016 11:31 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/23/2016 11:31 JJMACKE0.05 1
Iron (Fe)0.104 mg/L EPA 200.7 07/23/2016 11:31 JJMACKE0.01 1
Manganese (Mn)0.015 mg/L EPA 200.7 07/23/2016 11:31 JJMACKE0.005 1
Strontium (Sr)0.278 mg/L EPA 200.7 07/23/2016 11:31 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 11:31 JJMACKE0.005 1
Page 4 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021704
Collection Date:13-Jul-16 9:32 AM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.36 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Chromium (Cr)16.2 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Copper (Cu)6.55 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Lead (Pb)1.00 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Molybdenum (Mo)7.96 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA0.2 1
Vanadium (V) Low Level 14.5 ug/L EPA 200.8 07/19/2016 20:12 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.48 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Chromium (Cr)14.5 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Copper (Cu)1.99 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Molybdenum (Mo)9.15 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Selenium (Se)1.02 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA0.2 1
Vanadium (V) Low Level 15.6 ug/L EPA 200.8 07/19/2016 18:19 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Page 5 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021704
Collection Date:13-Jul-16 9:32 AM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.878 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.4 mg/L SM2540D 07/19/2016 10:12 PARMSTR51
Page 6 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021705
Collection Date:13-Jul-16 11:46 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.026 mg-N/L EPA 353.2 07/18/2016 13:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 300.0 07/19/2016 15:59B2 BGN9034110
Sulfate 84 mg/L EPA 300.0 07/19/2016 15:59 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 12:03 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 12:17M2 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/18/2016 12:14 JJMACKE0.005 1
Barium (Ba)0.006 mg/L EPA 200.7 07/18/2016 12:14 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 12:14 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/18/2016 12:14 JJMACKE0.01 1
Manganese (Mn)0.074 mg/L EPA 200.7 07/18/2016 12:14 JJMACKE0.005 1
Strontium (Sr)0.191 mg/L EPA 200.7 07/18/2016 12:14 JJMACKE0.005 1
Zinc (Zn)0.028 mg/L EPA 200.7 07/18/2016 12:14 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)30.9 mg/L EPA 200.7 07/19/2016 14:35 JJMACKE0.01 1
Magnesium (Mg)13.7 mg/L EPA 200.7 07/19/2016 14:35 JJMACKE0.005 1
Potassium (K)4.62 mg/L EPA 200.7 07/19/2016 14:35 JJMACKE0.1 1
Sodium (Na)41.7 mg/L EPA 200.7 07/19/2016 14:35 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.018 mg/L EPA 200.7 07/23/2016 11:05 JJMACKE0.005 1
Barium (Ba)0.006 mg/L EPA 200.7 07/23/2016 11:05 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/23/2016 11:05 JJMACKE0.05 1
Iron (Fe)0.024 mg/L EPA 200.7 07/23/2016 11:05 JJMACKE0.01 1
Manganese (Mn)0.074 mg/L EPA 200.7 07/23/2016 11:05 JJMACKE0.005 1
Strontium (Sr)0.198 mg/L EPA 200.7 07/23/2016 11:05 JJMACKE0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 07/23/2016 11:05 JJMACKE0.005 1
Page 7 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021705
Collection Date:13-Jul-16 11:46 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Copper (Cu)10.8 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Lead (Pb)1.53 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Nickel (Ni)1.71 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA0.2 1
Vanadium (V) Low Level 2.02 ug/L EPA 200.8 07/19/2016 20:20 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Nickel (Ni)1.82 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA0.2 1
Vanadium (V) Low Level 2.01 ug/L EPA 200.8 07/19/2016 18:27 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Page 8 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021705
Collection Date:13-Jul-16 11:46 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/19/2016 10:12 PARMSTR51
Page 9 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021706
Collection Date:13-Jul-16 1:44 PM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/18/2016 13:28 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 22 mg/L EPA 300.0 07/19/2016 16:17B2 BGN90340.5 5
Sulfate 5.4 mg/L EPA 300.0 07/19/2016 16:17 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:43 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 10:13 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 07/18/2016 12:18 JJMACKE0.005 1
Barium (Ba)0.063 mg/L EPA 200.7 07/18/2016 12:18 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 12:18 JJMACKE0.05 1
Iron (Fe)1.22 mg/L EPA 200.7 07/18/2016 12:18 JJMACKE0.01 1
Manganese (Mn)0.285 mg/L EPA 200.7 07/18/2016 12:18 JJMACKE0.005 1
Strontium (Sr)2.16 mg/L EPA 200.7 07/18/2016 12:18 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 12:18 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)72.8 mg/L EPA 200.7 07/19/2016 14:39 JJMACKE0.01 1
Magnesium (Mg)11.8 mg/L EPA 200.7 07/19/2016 14:39 JJMACKE0.005 1
Potassium (K)6.98 mg/L EPA 200.7 07/19/2016 14:39 JJMACKE0.1 1
Sodium (Na)17.7 mg/L EPA 200.7 07/19/2016 14:39 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 07/23/2016 11:35 JJMACKE0.005 1
Barium (Ba)0.064 mg/L EPA 200.7 07/23/2016 11:35 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/23/2016 11:35 JJMACKE0.05 1
Iron (Fe)1.12 mg/L EPA 200.7 07/23/2016 11:35 JJMACKE0.01 1
Manganese (Mn)0.275 mg/L EPA 200.7 07/23/2016 11:35 JJMACKE0.005 1
Strontium (Sr)2.22 mg/L EPA 200.7 07/23/2016 11:35 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 11:35 JJMACKE0.005 1
Page 10 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021706
Collection Date:13-Jul-16 1:44 PM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Molybdenum (Mo)3.71 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA0.2 1
Vanadium (V) Low Level 0.322 ug/L EPA 200.8 07/19/2016 20:27 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Molybdenum (Mo)3.64 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA0.2 1
Vanadium (V) Low Level 0.331 ug/L EPA 200.8 07/19/2016 17:30 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Page 11 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021706
Collection Date:13-Jul-16 1:44 PM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.1 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/19/2016 10:12 PARMSTR51
Page 12 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021707
Collection Date:13-Jul-16 3:41 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/18/2016 13:29 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 10:49 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/18/2016 12:22 JJMACKE0.005 1
Barium (Ba)0.051 mg/L EPA 200.7 07/18/2016 12:22 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 12:22 JJMACKE0.05 1
Iron (Fe)0.275 mg/L EPA 200.7 07/18/2016 12:22 JJMACKE0.01 1
Manganese (Mn)0.170 mg/L EPA 200.7 07/18/2016 12:22 JJMACKE0.005 1
Strontium (Sr)0.312 mg/L EPA 200.7 07/18/2016 12:22 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 07/18/2016 12:22 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Copper (Cu)1.86 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA0.2 1
Vanadium (V) Low Level 4.11 ug/L EPA 200.8 07/19/2016 20:34 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Page 13 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021707
Collection Date:13-Jul-16 3:41 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
Page 14 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021708
Collection Date:13-Jul-16 4:40 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.827 mg-N/L EPA 353.2 07/18/2016 13:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 12:24 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/18/2016 12:26 JJMACKE0.005 1
Barium (Ba)0.084 mg/L EPA 200.7 07/18/2016 12:26 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 12:26 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/18/2016 12:26 JJMACKE0.01 1
Manganese (Mn)0.007 mg/L EPA 200.7 07/18/2016 12:26 JJMACKE0.005 1
Strontium (Sr)0.168 mg/L EPA 200.7 07/18/2016 12:26 JJMACKE0.005 1
Zinc (Zn)0.021 mg/L EPA 200.7 07/18/2016 12:26 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Copper (Cu)10.5 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Lead (Pb)1.66 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA0.2 1
Vanadium (V) Low Level 3.54 ug/L EPA 200.8 07/19/2016 20:41 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Page 15 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021708
Collection Date:13-Jul-16 4:40 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.723 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
Page 16 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021709
Collection Date:13-Jul-16 9:45 AM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:15 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/18/2016 12:30 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/18/2016 12:30 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 12:30 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/18/2016 12:30 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/18/2016 12:30 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/18/2016 12:30 JJMACKE0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 07/18/2016 12:30 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Copper (Cu)8.43 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/19/2016 20:48 JAHERMA0.3 1
Page 17 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021710
Collection Date:13-Jul-16 9:45 AM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.028 mg-N/L EPA 353.2 07/18/2016 13:31 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 07/19/2016 15:42B2 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 07/19/2016 15:42 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:58 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.393 mg/L EPA 200.7 07/19/2016 14:43 JJMACKE0.01 1
Magnesium (Mg)0.053 mg/L EPA 200.7 07/19/2016 14:43 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 07/19/2016 14:43 JJMACKE0.1 1
Sodium (Na)0.249 mg/L EPA 200.7 07/19/2016 14:43 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/23/2016 11:39 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/23/2016 11:39 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/23/2016 11:39 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/23/2016 11:39 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/23/2016 11:39 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/23/2016 11:39 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 11:39 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/19/2016 18:34 JAHERMA0.3 1
Page 18 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
2016021710
Collection Date:13-Jul-16 9:45 AM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.622 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/19/2016 10:12 PARMSTR51
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Page 19 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0016 mg-N/L -1-0.0016 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0007 mg-N/L -1-0.0007 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0005 mg-N/L -10.0005 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0009 mg-N/L -10.0009 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 99.9mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 99.9mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 99mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.296 3.01 98.2mg-N/L -11090102.96
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060271 -- 2016016749
Nitrite + Nitrate
(Colorimetric)
0.253 0.25 101mg-N/L -1109010.253
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060271 -- 2016016749
Nitrite + Nitrate
(Colorimetric)
0.253 0.25 101 0.278mg-N/L -1109010.253
Page 20 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070367 -- 2016021651
Nitrite + Nitrate
(Colorimetric)
0.258 0.25 102mg-N/L -1109010.258
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070367 -- 2016021651
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101 0.709mg-N/L -1109010.256
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Nitrite + Nitrate
(Colorimetric)
0.364 0.25 93.4mg-N/L -1109010.364
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Nitrite + Nitrate
(Colorimetric)
0.366 0.25 94.2 0.853mg-N/L -1109010.366
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070132 -- 2016021202
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101mg-N/L -1109010.256
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070132 -- 2016021202
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101 0.0395mg-N/L -1109010.256
Page 21 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070432 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0634 mg/L -10.0634 0.1 > 1/2 RDL
Sulfate 0.0127 mg/L -10.0127 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Chloride 2.96 mg/L -12.96 0.1
Sulfate 2.43 mg/L -12.43 0.1
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 7.98 5 100mg/L -1208017.98
Sulfate 7.37 5 98.8mg/L -1208017.37
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 7.99 5 101 0.245mg/L -1208017.99
Sulfate 7.37 5 98.9 0.0243mg/L -1208017.37
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.97 5 99.4mg/L -1109014.97
Sulfate 4.97 5 99.4mg/L -1109014.97
Page 22 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070592 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.021 ug/L -10.021 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.024 ug/L -10.024 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.025 ug/L -10.025 0.05 = 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Mercury (Hg) 0.038 ug/L -10.038 0.05
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 2
Mercury (Hg) 0.017 ug/L -10.017 0.05
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.07 1 104ug/L -1307011.07
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.1 1 106 2.38ug/L -1307011.1
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.888 1 87.1ug/L -1307010.888
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.886 1 86.9 0.23ug/L -1307010.886
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 97.8ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.9 2 95ug/L -1158511.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Mercury (Hg) 0.987 1 96.2ug/L -1307010.987
Page 23 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070592 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Mercury (Hg) 0.973 1 94.8 1.47ug/L -1307010.973
Page 24 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070593 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.021 ug/L -10.021 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.024 ug/L -10.024 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.025 ug/L -10.025 0.05 = 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Mercury (Hg) 0.025 ug/L -10.025 0.05
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.987 1 96.2ug/L -1307010.987
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.973 1 94.8 1.47ug/L -1307010.973
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 97.8ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.9 2 95ug/L -1158511.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021706
Mercury (Hg) 1.07 1 104ug/L -1307011.07
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021706
Mercury (Hg) 1.1 1 106 2.38ug/L -1307011.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021707
Mercury (Hg) 0.888 1 87.1ug/L -1307010.888
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021707
Mercury (Hg) 0.886 1 86.9 0.23ug/L -1307010.886
Page 25 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070593 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021705
Mercury (Hg) 0.662 1 64.8ug/L -1307010.662
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021705
Mercury (Hg) 0.669 1 65.5 1.07ug/L -1307010.669
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021708
Mercury (Hg) 0.937 1 91.8ug/L -1307010.937
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021708
Mercury (Hg) 0.938 1 91.9 0.109ug/L -1307010.938
Page 26 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070618 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.003 ug/L -10.003 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.01 ug/L -10.01 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.5ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 93.9ug/L -1158511.88
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Mercury (Hg) 0.983 1 97.2ug/L -1307010.983
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Mercury (Hg) 1.01 1 99.5 2.34ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Mercury (Hg) 1.01 1 100ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Mercury (Hg) 0.991 1 98.2 1.92ug/L -1307010.991
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020920
Mercury (Hg) 0.994 1 97.3ug/L -1307010.994
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020920
Mercury (Hg) 1 1 97.9 0.615ug/L -1307011
Page 27 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070433 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000125 mg/L -10.000125 0.005 < 1/2 RDL
Barium (Ba) 0.000057 mg/L -10.000057 0.005 < 1/2 RDL
Boron (B) 0.000109 mg/L -10.000109 0.05 < 1/2 RDL
Iron (Fe) -0.000832 mg/L -1-0.000832 0.01 < 1/2 RDL
Manganese (Mn) -0.000161 mg/L -1-0.000161 0.005 < 1/2 RDL
Strontium (Sr) 0.000063 mg/L -10.000063 0.005 < 1/2 RDL
Zinc (Zn) -0.00052 mg/L -1-0.00052 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.06 2 103mg/L -1158512.06
Barium (Ba) 0.99 1 99mg/L -1158510.99
Boron (B) 1.99 2 99.4mg/L -1158511.99
Iron (Fe) 2.03 2 102mg/L -1158512.03
Manganese (Mn) 0.979 1 97.9mg/L -1158510.979
Strontium (Sr) 1.9 2 94.8mg/L -1158511.9
Zinc (Zn) 1.02 1 102mg/L -1158511.02
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Aluminum (Al) 5.75 5 110mg/L -1307015.75
Barium (Ba) 5.33 5 106mg/L -1307015.33
Boron (B) 5.16 5 103mg/L -1307015.16
Iron (Fe) 5.15 5 103mg/L -1307015.15
Manganese (Mn) 5.4 5 108mg/L -1307015.4
Strontium (Sr) 5.33 5 102mg/L -1307015.33
Zinc (Zn) 5.33 5 106mg/L -1307015.33
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Aluminum (Al) 5.8 5 111 0.903mg/L -1307015.8
Barium (Ba) 5.38 5 107 0.993mg/L -1307015.38
Boron (B) 5.2 5 104 0.696mg/L -1307015.2
Iron (Fe) 5.2 5 104 0.909mg/L -1307015.2
Manganese (Mn) 5.43 5 109 0.628mg/L -1307015.43
Strontium (Sr) 5.37 5 102 0.666mg/L -1307015.37
Zinc (Zn) 5.37 5 107 0.637mg/L -1307015.37
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021855
Aluminum (Al) 5.23 5 105mg/L -1307015.23
Page 28 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070433 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021855
Barium (Ba) 5.13 5 101mg/L -1307015.13
Boron (B) 4.95 5 98.8mg/L -1307014.95
Iron (Fe) 5.25 5 97.3mg/L -1307015.25
Manganese (Mn) 5.36 5 102mg/L -1307015.36
Strontium (Sr) 5.67 5 95.5mg/L -1307015.67
Zinc (Zn) 4.99 5 99.7mg/L -1307014.99
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021855
Aluminum (Al) 5.47 5 109 4.5mg/L -1307015.47
Barium (Ba) 5.36 5 105 4.29mg/L -1307015.36
Boron (B) 5.17 5 103 4.46mg/L -1307015.17
Iron (Fe) 5.49 5 102 4.91mg/L -1307015.49
Manganese (Mn) 5.63 5 107 5.24mg/L -1307015.63
Strontium (Sr) 5.91 5 100 4.92mg/L -1307015.91
Zinc (Zn) 5.24 5 105 4.8mg/L -1307015.24
Page 29 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00129 mg/L -10.00129 0.01 < 1/2 RDL
Magnesium (Mg) 0.000115 mg/L -10.000115 0.005 < 1/2 RDL
Potassium (K) -0.00152 mg/L -1-0.00152 0.1 < 1/2 RDL
Sodium (Na) -0.00992 mg/L -1-0.00992 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.00148 mg/L -10.00148 0.01 < 1/2 RDL
Magnesium (Mg) 0.000217 mg/L -10.000217 0.005 < 1/2 RDL
Potassium (K) 0.00492 mg/L -10.00492 0.1 < 1/2 RDL
Sodium (Na) -0.0117 mg/L -1-0.0117 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.04 2 102mg/L -1158512.04
Magnesium (Mg) 1.99 2 99.3mg/L -1158511.99
Potassium (K) 3.98 4 99.6mg/L -1158513.98
Sodium (Na) 8.38 8.1 103mg/L -1158518.38
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 2.14 2 107mg/L -1158512.14
Magnesium (Mg) 2.08 2 104mg/L -1158512.08
Potassium (K) 4.21 4 105mg/L -1158514.21
Sodium (Na) 8.85 8.1 109mg/L -1158518.85
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Calcium (Ca) 104 5 0mg/L -130701104
Magnesium (Mg) 21.2 5 88.2mg/L -13070121.2
Potassium (K) 15.9 5 93.2mg/L -13070115.9
Sodium (Na) 38.3 5 106mg/L -13070138.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Calcium (Ca) 104 5 204 200mg/L -130701104
Magnesium (Mg) 21.1 5 88 0.25mg/L -13070121.1
Potassium (K) 16 5 94 0.876mg/L -13070116
Sodium (Na) 38.3 5 107 0.981mg/L -13070138.3
Page 30 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Calcium (Ca) 19.1 5 93.9mg/L -13070119.1
Magnesium (Mg) 7.69 5 104mg/L -1307017.69
Potassium (K) 10.1 5 98.1mg/L -13070110.1
Sodium (Na) 51.5 5 71.7mg/L -13070151.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Calcium (Ca) 19.3 5 97.7 3.97mg/L -13070119.3
Magnesium (Mg) 7.78 5 105 1.66mg/L -1307017.78
Potassium (K) 10.2 5 101 3.07mg/L -13070110.2
Sodium (Na) 52.1 5 83.3 14.9mg/L -13070152.1
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Calcium (Ca) 25.9 5 102mg/L -13070125.9
Magnesium (Mg) 7.35 5 113mg/L -1307017.35
Potassium (K) 12.9 5 102mg/L -13070112.9
Sodium (Na) 22.6 5 107mg/L -13070122.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Calcium (Ca) 26 5 104 1.61mg/L -13070126
Magnesium (Mg) 7.39 5 114 0.671mg/L -1307017.39
Potassium (K) 13 5 104 1.83mg/L -13070113
Sodium (Na) 22.8 5 110 2.73mg/L -13070122.8
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Calcium (Ca) 65.4 5 83.2mg/L -13070165.4
Magnesium (Mg) 18.6 5 95.7mg/L -13070118.6
Potassium (K) 11 5 110mg/L -13070111
Sodium (Na) 25.6 5 103mg/L -13070125.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Calcium (Ca) 65.8 5 91 8.91mg/L -13070165.8
Magnesium (Mg) 18.6 5 96.6 1.02mg/L -13070118.6
Potassium (K) 11 5 110 0.4mg/L -13070111
Sodium (Na) 25.7 5 105 1.9mg/L -13070125.7
Page 31 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070564 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000923 mg/L -10.000923 0.005 < 1/2 RDL
Barium (Ba) 0.000045 mg/L -10.000045 0.005 < 1/2 RDL
Boron (B) -0.00015 mg/L -1-0.00015 0.05 < 1/2 RDL
Iron (Fe) 0.000595 mg/L -10.000595 0.01 < 1/2 RDL
Manganese (Mn) -0.000252 mg/L -1-0.000252 0.005 < 1/2 RDL
Strontium (Sr) 0.000108 mg/L -10.000108 0.005 < 1/2 RDL
Zinc (Zn) 0.000146 mg/L -10.000146 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.57 5 111mg/L -1158515.57
Barium (Ba) 5.09 5 102mg/L -1158515.09
Boron (B) 5.02 5 100mg/L -1158515.02
Iron (Fe) 5.06 5 101mg/L -1158515.06
Manganese (Mn) 5.27 5 105mg/L -1158515.27
Strontium (Sr) 4.97 5 99.3mg/L -1158514.97
Zinc (Zn) 5.16 5 103mg/L -1158515.16
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021705
Aluminum (Al) 5.42 5 108mg/L -1307015.42
Barium (Ba) 4.96 5 99mg/L -1307014.96
Boron (B) 4.98 5 99.5mg/L -1307014.98
Iron (Fe) 4.95 5 98.4mg/L -1307014.95
Manganese (Mn) 5.17 5 102mg/L -1307015.17
Strontium (Sr) 5.05 5 97.1mg/L -1307015.05
Zinc (Zn) 4.98 5 99.3mg/L -1307014.98
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021705
Aluminum (Al) 5.45 5 109 0.572mg/L -1307015.45
Barium (Ba) 5.02 5 100 1.18mg/L -1307015.02
Boron (B) 5.05 5 101 1.5mg/L -1307015.05
Iron (Fe) 4.98 5 99.1 0.729mg/L -1307014.98
Manganese (Mn) 5.21 5 103 0.841mg/L -1307015.21
Strontium (Sr) 5.1 5 98.1 1.07mg/L -1307015.1
Zinc (Zn) 5.03 5 100 0.963mg/L -1307015.03
Page 32 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070350 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.058 ug/L -10.058 1 < 1/2 RDL
Arsenic (As) 0.036 ug/L -10.036 1 < 1/2 RDL
Beryllium (Be) 0.0261 ug/L -10.0261 1 < 1/2 RDL
Cadmium (Cd) -0.0072 ug/L -1-0.0072 1 < 1/2 RDL
Chromium (Cr) -0.015 ug/L -1-0.015 1 < 1/2 RDL
Cobalt (Co) -0.0129 ug/L -1-0.0129 1 < 1/2 RDL
Copper (Cu) 0.0286 ug/L -10.0286 1 < 1/2 RDL
Lead (Pb) -0.004 ug/L -1-0.004 1 < 1/2 RDL
Molybdenum (Mo) 0 ug/L -10 1 < 1/2 RDL
Nickel (Ni) -0.376 ug/L -1-0.376 1 < 1/2 RDL
Selenium (Se) 0.0244 ug/L -10.0244 1 < 1/2 RDL
Thallium (Tl) Low Level 0.0061 ug/L -10.0061 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0235 ug/L -10.0235 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.4 50 98.8ug/L -11585149.4
Arsenic (As) 51.7 50 103ug/L -11585151.7
Beryllium (Be) 52.3 50 105ug/L -11585152.3
Cadmium (Cd) 48.4 50 96.9ug/L -11585148.4
Chromium (Cr) 51.6 50 103ug/L -11585151.6
Cobalt (Co) 52.2 50 104ug/L -11585152.2
Copper (Cu) 50 50 100ug/L -11585150
Lead (Pb) 49 50 98.1ug/L -11585149
Molybdenum (Mo) 48.1 50 96.1ug/L -11585148.1
Nickel (Ni) 51.4 50 103ug/L -11585151.4
Selenium (Se) 52.3 50 105ug/L -11585152.3
Thallium (Tl) Low Level 44.9 50 89.8ug/L -11585144.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021267
Antimony (Sb) 51.7 50 103ug/L -13070151.7
Arsenic (As) 54.3 50 108ug/L -13070154.3
Beryllium (Be) 52.7 50 105ug/L -13070152.7
Cadmium (Cd) 48.8 50 97.6ug/L -13070148.8
Chromium (Cr) 53.4 50 106ug/L -13070153.4
Cobalt (Co) 51.8 50 103ug/L -13070151.8
Copper (Cu) 51 50 102ug/L -13070151
Lead (Pb) 48.9 50 97.8ug/L -13070148.9
Molybdenum (Mo) 62.4 50 97.9ug/L -13070162.4
Page 33 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070350 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021267
Nickel (Ni) 51.8 50 101ug/L -13070151.8
Selenium (Se) 51.6 50 103ug/L -13070151.6
Thallium (Tl) Low Level 43.9 50 87.8ug/L -13070143.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021267
Antimony (Sb) 50.1 50 99.8 3.21ug/L -13070150.1
Arsenic (As) 53.5 50 106 1.36ug/L -13070153.5
Beryllium (Be) 51.6 50 103 1.97ug/L -13070151.6
Cadmium (Cd) 48 50 96 1.69ug/L -13070148
Chromium (Cr) 52.2 50 104 2.23ug/L -13070152.2
Cobalt (Co) 50.2 50 100 3.06ug/L -13070150.2
Copper (Cu) 50.7 50 101 0.513ug/L -13070150.7
Lead (Pb) 48.6 50 97.2 0.656ug/L -13070148.6
Molybdenum (Mo) 61.8 50 96.6 1.36ug/L -13070161.8
Nickel (Ni) 53 50 104 2.46ug/L -13070153
Selenium (Se) 52.9 50 106 2.53ug/L -13070152.9
Thallium (Tl) Low Level 43.8 50 87.6 0.182ug/L -13070143.8
Page 34 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070356 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.0677 ug/L -10.0677 1 < 1/2 RDL
Arsenic (As) -0.0151 ug/L -1-0.0151 1 < 1/2 RDL
Beryllium (Be) 0.0535 ug/L -10.0535 1 < 1/2 RDL
Cadmium (Cd) -0.0072 ug/L -1-0.0072 1 < 1/2 RDL
Chromium (Cr) -0.0182 ug/L -1-0.0182 1 < 1/2 RDL
Cobalt (Co) -0.0096 ug/L -1-0.0096 1 < 1/2 RDL
Copper (Cu) 0.0148 ug/L -10.0148 1 < 1/2 RDL
Lead (Pb) -0.0098 ug/L -1-0.0098 1 < 1/2 RDL
Molybdenum (Mo) 0.0104 ug/L -10.0104 1 < 1/2 RDL
Nickel (Ni) -0.522 ug/L -1-0.522 1 < 1/2 RDL
Selenium (Se) 0.0161 ug/L -10.0161 1 < 1/2 RDL
Thallium (Tl) Low Level 0.0164 ug/L -10.0164 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.036 ug/L -10.036 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.2 50 100ug/L -11585150.2
Arsenic (As) 52.6 50 105ug/L -11585152.6
Beryllium (Be) 53.4 50 107ug/L -11585153.4
Cadmium (Cd) 50 50 99.9ug/L -11585150
Chromium (Cr) 53.3 50 107ug/L -11585153.3
Cobalt (Co) 53.9 50 108ug/L -11585153.9
Copper (Cu) 50.5 50 101ug/L -11585150.5
Lead (Pb) 49.4 50 98.9ug/L -11585149.4
Molybdenum (Mo) 48.7 50 97.4ug/L -11585148.7
Nickel (Ni) 52.7 50 105ug/L -11585152.7
Selenium (Se) 51.9 50 104ug/L -11585151.9
Thallium (Tl) Low Level 45 50 90.1ug/L -11585145
Vanadium (V) Low Level 54.4 50 109ug/L -11585154.4
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021706
Antimony (Sb) 51.1 50 102ug/L -13070151.1
Arsenic (As) 54 50 106ug/L -13070154
Beryllium (Be) 57 50 114ug/L -13070157
Cadmium (Cd) 48 50 96.1ug/L -13070148
Chromium (Cr) 53.6 50 106ug/L -13070153.6
Cobalt (Co) 52.2 50 104ug/L -13070152.2
Copper (Cu) 51.9 50 103ug/L -13070151.9
Lead (Pb) 50 50 100ug/L -13070150
Page 35 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070356 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021706
Molybdenum (Mo) 53 50 98.7ug/L -13070153
Nickel (Ni) 50.9 50 102ug/L -13070150.9
Selenium (Se) 53.5 50 107ug/L -13070153.5
Thallium (Tl) Low Level 45.1 50 90.1ug/L -13070145.1
Vanadium (V) Low Level 53.9 50 107ug/L -13070153.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021706
Antimony (Sb) 50.8 50 101 0.61ug/L -13070150.8
Arsenic (As) 54.8 50 108 1.57ug/L -13070154.8
Beryllium (Be) 55.6 50 111 2.58ug/L -13070155.6
Cadmium (Cd) 48.8 50 97.5 1.45ug/L -13070148.8
Chromium (Cr) 54 50 107 0.674ug/L -13070154
Cobalt (Co) 51.8 50 103 0.828ug/L -13070151.8
Copper (Cu) 51.1 50 102 1.58ug/L -13070151.1
Lead (Pb) 49.3 50 98.5 1.57ug/L -13070149.3
Molybdenum (Mo) 52.8 50 98.3 0.305ug/L -13070152.8
Nickel (Ni) 52.2 50 105 2.48ug/L -13070152.2
Selenium (Se) 52.7 50 105 1.56ug/L -13070152.7
Thallium (Tl) Low Level 45.6 50 91.2 1.17ug/L -13070145.6
Vanadium (V) Low Level 55 50 109 2.2ug/L -13070155
Page 36 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070446 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060373 -- 2016017136
TDS 1.34mg/L -1375
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060373 -- 2016017137
TDS 4.69mg/L -1218
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16060373 -- 2016017138
TDS 0mg/L -11
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 103mg/L -110901103
Page 37 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070374 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.023 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.04 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
TOC mg/L -10.363 0.1
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 2
TOC mg/L -12.81 0.1
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 3
TOC mg/L -11.97 0.1
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 105mg/L -1208012.46
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 102 3.1mg/L -1208012.39
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 89.7mg/L -1208014.61
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 92.3 2.8mg/L -1208014.66
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 95.8mg/L -1208013.89
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 99.5 3.84mg/L -1208013.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 101mg/L -1158512.91
Page 38 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070374 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 104mg/L -1158512.98
Page 39 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070378
Q16070435 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070378 -- 2016021704
TSS 3.17mg/L -16.2
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070378 -- 2016021705
TSS 0mg/L -11
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 108mg/L -11090154
Page 40 of 83

July 29, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 401635
SDG: J16070378

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 14, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944
Enclosures
Page 1 of 16
Chelsea Seagle for
Page 41 of 83
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16070378 GEL Work Order: 401635
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 16
Page 42 of 83
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0907
0821
1530
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401635001
Water
13-JUL-16 09:32
14-JUL-16
2016021704 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.434
0.198
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00025
ND
ND
ND
ND
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"95.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 16
Page 43 of 83
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0908
0823
1530
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401635002
Water
13-JUL-16 11:46
14-JUL-16
2016021705 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.493
0.502
1
2
3
4
J
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000755
ND
ND
ND
0.518
0.900
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"90.4 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 16
Page 44 of 83
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0910
0824
1531
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401635003
Water
13-JUL-16 13:44
14-JUL-16
2016021706 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.522
0.427
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000729
ND
ND
ND
ND
2.05
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"90.2 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 16
Page 45 of 83
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0911
0826
1531
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401635004
Water
13-JUL-16 15:41
14-JUL-16
2016021707 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.514
0.522
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000918
ND
ND
ND
3.12
4.40
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 16
Page 46 of 83
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0913
0827
1531
0935
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401635005
Water
13-JUL-16 16:40
14-JUL-16
2016021708 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.756
0.417
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.29
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"52 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 7 of 16
Page 47 of 83
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1581994Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 29, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/29/16 09:21
07/28/16 09:20
07/28/16 09:05
07/29/16 08:20
07/29/16 08:18
07/28/16 09:04
07/28/16 09:22
07/29/16 09:23
07/29/16 09:24
QC
ND
ND
ND
0.000177
0.0535
0.00055
0.000545
0.00518
ND
ND
ND
ND
0.0526
0.000536
0.000547
0.00533
ND
NOM Sample
ND
ND
ND
0.000158
0.000158
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
J
U
U
U
U
U
QC1203585489 401636001
QC1203585487
QC1203585488
QC1203585486
QC1203585490 401636001
QC1203585491 401636001
QC1203585492 401636001
N/A
N/A
N/A
10.9
N/A
REC%
108
110
99.1
104
106
107
99.5
107
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
401635Workorder:
Mail Code: MGO3A2
U
U
U
J
J
U
U
U
U
^
RPD%
Page 1 of 3
Page 8 of 16
Page 48 of 83
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1581994
1582445
1583317
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
07/29/16 09:24
07/28/16 09:23
07/28/16 15:34
07/28/16 15:34
07/28/16 15:34
07/27/16 11:20
07/27/16 11:55
07/27/16 10:35
07/27/16 11:20
QC
ND
ND
ND
0.148
11.7
0.0413
0.957
24.9
0.387
113
NOM Sample
ND
ND
0.158
0.111
0.719
0.719
Range
(0%-10%)
(0%-10%)
N/A
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203586579 401638004
QC1203586580
QC1203586578
QC1203588597 401821001
QC1203588599
QC1203588596
QC1203588598 401821001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
N/A
28.4
REC%
78.3
102
92.4
15.0
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
401635Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
J
U
RPD%
Notes:
Page 2 of 3
Page 9 of 16
Page 49 of 83
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
401635Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 10 of 16
Page 50 of 83
Page 11 of 16
Page 51 of 83
Page 12 of 16
Page 52 of 83

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16070378
Work Order #: 401635

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1581994

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1581993
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401635001 2016021704
401635002 2016021705
401635003 2016021706
401635004 2016021707
401635005 2016021708
1203585486 Method Blank (MB)ICP-MS
1203585487 Laboratory Control Sample (LCS)
1203585488 Laboratory Control Sample (LCS)
1203585492 401636001(2016021471L) Serial Dilution (SD)
1203585489 401636001(2016021471D) Sample Duplicate (DUP)
1203585490 401636001(2016021471S) Matrix Spike (MS)
1203585491 401636001(2016021471S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1582445
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
Page 13 of 16
Page 53 of 83
401635001 2016021704
401635002 2016021705
401635003 2016021706
401635004 2016021707
401635005 2016021708
1203586578 Method Blank (MB)
1203586579 401638004(2016021448) Sample Duplicate (DUP)
1203586580 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1583317
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401635001 2016021704
401635002 2016021705
401635003 2016021706
401635004 2016021707
401635005 2016021708
1203588596 Method Blank (MB)
1203588597 401821001(NonSDG) Sample Duplicate (DUP)
1203588598 401821001(NonSDG) Matrix Spike (MS)
1203588599 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203588598 (Non SDG 401821001MS), aliquot was reduced to conserve sample volume.

Page 14 of 16
Page 54 of 83

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 15 of 16
Page 55 of 83
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 29 July 2016
Page 16 of 16
Page 56 of 83
#=CL#
July 25, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92305199
92305199
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16070378
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 14, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 26
Page 57 of 83
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92305199
J16070378
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 26
Page 58 of 83
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92305199
J16070378
Lab ID Sample ID Matrix Date Collected Date Received
92305199001 2016021704 Water 07/13/16 09:32 07/14/16 14:55
92305199002 2016021705 Water 07/13/16 11:46 07/14/16 14:55
92305199003 2016021706 Water 07/13/16 13:44 07/14/16 14:55
92305199004 2016021707 Water 07/13/16 15:41 07/14/16 14:55
92305199005 2016021708 Water 07/13/16 16:40 07/14/16 14:55
92305199006 2016021710 Water 07/13/16 09:45 07/14/16 14:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 26
Page 59 of 83
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92305199
J16070378
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92305199001 2016021704 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92305199002 2016021705 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92305199003 2016021706 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92305199004 2016021707 RSK 175 Modified 1 PASI-CZDO
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92305199005 2016021708 RSK 175 Modified 1 PASI-CZDO
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92305199006 2016021710 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 26
Page 60 of 83
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92305199
J16070378
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92305199001 2016021704
Alkalinity,Bicarbonate (CaCO3)5.8 mg/L 07/17/16 19:465.0SM 2320B
Alkalinity, Carbonate (CaCO3)63.6 mg/L 07/17/16 19:465.0SM 2320B
Alkalinity, Total as CaCO3 69.4 mg/L 07/17/16 19:465.0SM 2320B
Chromium, Hexavalent 12.5 ug/L 07/19/16 17:393.0EPA 218.7
92305199002 2016021705
Alkalinity,Bicarbonate (CaCO3)112 mg/L 07/17/16 19:575.0SM 2320B
Alkalinity, Total as CaCO3 112 mg/L 07/17/16 19:575.0SM 2320B
Chromium, Hexavalent 0.041 ug/L 07/19/16 13:420.030EPA 218.7
92305199003 2016021706
Methane 31.5 ug/L 07/20/16 23:5410.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)251 mg/L 07/17/16 20:095.0SM 2320B
Alkalinity, Total as CaCO3 251 mg/L 07/17/16 20:095.0SM 2320B
92305199004 2016021707
Methane 2260 ug/L 07/21/16 00:1010.0RSK 175 Modified
92305199005 2016021708
Chromium, Hexavalent 0.23 ug/L 07/19/16 14:210.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 26
Page 61 of 83
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92305199
J16070378
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 25, 2016
Description:RSK 175 Headspace
General Information:
6 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 322053
CL: The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased low.
• 2016021704 (Lab ID: 92305199001)
• Methane
• 2016021705 (Lab ID: 92305199002)
• Methane
• 2016021708 (Lab ID: 92305199005)
• Methane
• 2016021710 (Lab ID: 92305199006)
• Methane
• BLANK (Lab ID: 1784702)
• Methane
• LCS (Lab ID: 1784703)
• Methane
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321523
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304131002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1784357)
• Methane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 26
Page 62 of 83
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92305199
J16070378
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 25, 2016
Description:RSK 175 Headspace
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 322053
P2: Re-extraction or re-analysis could not be performed due to insufficient sample amount.
• 2016021704 (Lab ID: 92305199001)
• Methane
• 2016021705 (Lab ID: 92305199002)
• Methane
• 2016021708 (Lab ID: 92305199005)
• Methane
• 2016021710 (Lab ID: 92305199006)
• Methane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 26
Page 63 of 83
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92305199
J16070378
Method:
Client:Duke Energy
SM 2320B
Date:July 25, 2016
Description:2320B Alkalinity
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 26
Page 64 of 83
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92305199
J16070378
Method:
Client:Duke Energy
SM 4500-S2D
Date:July 25, 2016
Description:4500S2D Sulfide Water
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321606
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304968001,92304968002
M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences.
• MS (Lab ID: 1782276)
• Sulfide
• MSD (Lab ID: 1782277)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 26
Page 65 of 83
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92305199
J16070378
Method:
Client:Duke Energy
EPA 218.7
Date:July 25, 2016
Description:Hexavalent Chromium by IC
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 309644
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• MS (Lab ID: 1641532)
• Chromium, Hexavalent
• MSD (Lab ID: 1641533)
• Chromium, Hexavalent
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 26
Page 66 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305199
J16070378
Sample:2016021704 Lab ID:92305199001 Collected:07/13/16 09:32 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/18/16 21:59 74-82-8 CL,P210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)5.8 mg/L 07/17/16 19:465.0 1
Alkalinity, Carbonate (CaCO3)63.6 mg/L 07/17/16 19:465.0 1
Alkalinity, Total as CaCO3 69.4 mg/L 07/17/16 19:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/18/16 21:20 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 12.5 ug/L 07/19/16 17:39 18540-29-93.0 100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 26
Page 67 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305199
J16070378
Sample:2016021705 Lab ID:92305199002 Collected:07/13/16 11:46 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/18/16 22:14 74-82-8 CL,P210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)112 mg/L 07/17/16 19:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 19:575.0 1
Alkalinity, Total as CaCO3 112 mg/L 07/17/16 19:575.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/18/16 21:20 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.041 ug/L 07/19/16 13:42 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 26
Page 68 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305199
J16070378
Sample:2016021706 Lab ID:92305199003 Collected:07/13/16 13:44 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 31.5 ug/L 07/20/16 23:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)251 mg/L 07/17/16 20:095.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 20:095.0 1
Alkalinity, Total as CaCO3 251 mg/L 07/17/16 20:095.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/20/16 19:15 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/19/16 13:55 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 26
Page 69 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305199
J16070378
Sample:2016021707 Lab ID:92305199004 Collected:07/13/16 15:41 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 2260 ug/L 07/21/16 00:10 74-82-810.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/20/16 19:15 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/19/16 14:08 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 26
Page 70 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305199
J16070378
Sample:2016021708 Lab ID:92305199005 Collected:07/13/16 16:40 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/18/16 23:00 74-82-8 CL,P210.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/20/16 19:15 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.23 ug/L 07/19/16 14:21 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 26
Page 71 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305199
J16070378
Sample:2016021710 Lab ID:92305199006 Collected:07/13/16 09:45 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/18/16 23:16 74-82-8 CL,P210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/17/16 20:235.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 20:235.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/17/16 20:235.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/20/16 19:15 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 26
Page 72 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305199
J16070378
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321523
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92305199003, 92305199004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781824
Associated Lab Samples:92305199003, 92305199004
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/20/16 21:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781825LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 472 N239611970-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1784357MATRIX SPIKE SAMPLE:
MSSpike
Result
92304131002
Methane ug/L 3370 H5,M1,N239619370-1302610
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92304131003
1784358SAMPLE DUPLICATE:
Methane ug/L ND H5,N220ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 26
Page 73 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305199
J16070378
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322053
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92305199001, 92305199002, 92305199005, 92305199006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1784702
Associated Lab Samples:92305199001, 92305199002, 92305199005, 92305199006
Matrix:Water
Analyzed
Methane ug/L ND 10.0 CL,N207/18/16 11:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1784703LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 350 CL,N23968870-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 26
Page 74 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305199
J16070378
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321478
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92305199001, 92305199002, 92305199003, 92305199006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781661
Associated Lab Samples:92305199001, 92305199002, 92305199003, 92305199006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/17/16 17:45
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/17/16 17:45
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/17/16 17:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781662LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 52.850 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781663MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305067001
1781664
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 109 80-120114 2 2550113167170
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781665MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305202001
1781666
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 109 80-120106 1 2550133187186
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 26
Page 75 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305199
J16070378
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321606
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92305199001, 92305199002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1782272
Associated Lab Samples:92305199001, 92305199002
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/18/16 21:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1782273LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1782274MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304968001
1782275
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 97 90-11097 0 10.5ND 0.49 0.49
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1782276MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304968002
1782277
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M3.5 26 90-11026 0 10.5ND 0.22 0.22
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 26
Page 76 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305199
J16070378
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321930
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92305199003, 92305199004, 92305199005, 92305199006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1784223
Associated Lab Samples:92305199003, 92305199004, 92305199005, 92305199006
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/20/16 19:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1784224LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.52.5 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1784225MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305199003
1784226
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 101 90-110101 0 10.5ND 0.51 0.51
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1784227MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305199004
1784228
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 107 90-110107 0 10.5ND 0.54 0.54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 26
Page 77 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305199
J16070378
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
309644
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92305199001, 92305199002, 92305199003, 92305199004, 92305199005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1641530
Associated Lab Samples:92305199001, 92305199002, 92305199003, 92305199004, 92305199005
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 07/19/16 12:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1641531LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.075.075 100 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1641532MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305461001
1641533
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L E.075 98 85-115109 2 20.075ND 0.37 0.37
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1641534MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305339003
1641535
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .025 113 85-115110 20.025ND .028J .028J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 26
Page 78 of 83
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92305199
J16070378
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased
low.CL
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.H5
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3
The lab does not hold TNI accreditation for this parameter.N2
Re-extraction or re-analysis could not be performed due to insufficient sample amount.P2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 26
Page 79 of 83
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92305199
J16070378
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92305199001 3220532016021704RSK 175 Modified
92305199002 3220532016021705RSK 175 Modified
92305199003 3215232016021706RSK 175 Modified
92305199004 3215232016021707RSK 175 Modified
92305199005 3220532016021708RSK 175 Modified
92305199006 3220532016021710RSK 175 Modified
92305199001 3214782016021704SM 2320B
92305199002 3214782016021705SM 2320B
92305199003 3214782016021706SM 2320B
92305199006 3214782016021710SM 2320B
92305199001 3216062016021704SM 4500-S2D
92305199002 3216062016021705SM 4500-S2D
92305199003 3219302016021706SM 4500-S2D
92305199004 3219302016021707SM 4500-S2D
92305199005 3219302016021708SM 4500-S2D
92305199006 3219302016021710SM 4500-S2D
92305199001 3096442016021704EPA 218.7
92305199002 3096442016021705EPA 218.7
92305199003 3096442016021706EPA 218.7
92305199004 3096442016021707EPA 218.7
92305199005 3096442016021708EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:06 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 26
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