NC0038377_J16070300report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070300
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:7/29/2016
Customer Address:Mayo Steam Plant
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please note that the matrix spike and spike duplicate associated with alkalinity sample MW14BR were outside method limits.
Batch quality however including MB/LCS were acceptable.
For IMS metals, the relationship for dissolved Copper between the parent MW-12D and duplicate sample, MW-12D dup has
been confirmed by reanalysis of raw volume.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 64
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016021339 MAYO STEAM 11-Jul-16 2:23 PM Kaitlyn Fox MW-13BR
2016021340 MAYO STEAM 11-Jul-16 4:11 PM Kaitlyn Fox MW-14BR
2016021341 MAYO STEAM 11-Jul-16 1:56 PM Kaitlyn Fox MW-12S
2016021342 MAYO STEAM 11-Jul-16 4:17 PM Kaitlyn Fox MW-12D
2016021343 MAYO STEAM 11-Jul-16 4:17 PM Kaitlyn Fox MW-12D DUP
2016021344 MAYO STEAM 11-Jul-16 4:25 PM Kaitlyn Fox Filter Blank
2016021345 MAYO STEAM 11-Jul-16 4:25 PM Kaitlyn Fox Equipment Blank
7 Total Samples
Duke Energy Analytical Lab
Page 2 of 64
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:7/28/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021339
Collection Date:11-Jul-16 2:23 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/18/2016 13:46 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 40 mg/L EPA 300.0 07/14/2016 20:38 BGN9034110
Sulfate 18 mg/L EPA 300.0 07/14/2016 20:38 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:43 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/20/2016 15:06 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 12:50 JJMACKE0.005 1
Barium (Ba)0.021 mg/L EPA 200.7 07/14/2016 12:50 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 12:50 JJMACKE0.05 1
Iron (Fe)0.717 mg/L EPA 200.7 07/14/2016 12:50 JJMACKE0.01 1
Manganese (Mn)0.321 mg/L EPA 200.7 07/14/2016 12:50 JJMACKE0.005 1
Strontium (Sr)0.351 mg/L EPA 200.7 07/14/2016 12:50 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/14/2016 12:50 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)70.2 mg/L EPA 200.7 07/19/2016 12:35 JJMACKE0.01 1
Magnesium (Mg)13.0 mg/L EPA 200.7 07/19/2016 12:35 JJMACKE0.005 1
Potassium (K)4.72 mg/L EPA 200.7 07/19/2016 12:35 JJMACKE0.1 1
Sodium (Na)19.4 mg/L EPA 200.7 07/19/2016 12:35 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.407 mg/L EPA 200.7 07/14/2016 09:52 MHH71310.005 1
Barium (Ba)0.029 mg/L EPA 200.7 07/14/2016 09:52 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 09:52 MHH71310.05 1
Iron (Fe)1.33 mg/L EPA 200.7 07/14/2016 09:52 MHH71310.01 1
Manganese (Mn)0.348 mg/L EPA 200.7 07/14/2016 09:52 MHH71310.005 1
Strontium (Sr)0.380 mg/L EPA 200.7 07/14/2016 09:52 MHH71310.005 1
Zinc (Zn)0.023 mg/L EPA 200.7 07/14/2016 09:52 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021339
Collection Date:11-Jul-16 2:23 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Cobalt (Co)1.43 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Molybdenum (Mo)3.17 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Nickel (Ni)4.48 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN30.2 1
Vanadium (V) Low Level 0.320 ug/L EPA 200.8 07/14/2016 19:47 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Chromium (Cr)4.51 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Cobalt (Co)1.92 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Copper (Cu)1.95 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Molybdenum (Mo)3.20 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Nickel (Ni)2.82 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA0.2 1
Vanadium (V) Low Level 0.871 ug/L EPA 200.8 07/14/2016 16:30 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 330 mg/L SM2540C 07/15/2016 14:24 JASTOWE251
Duke Energy Analytical Lab
Page 5 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021339
Collection Date:11-Jul-16 2:23 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.594 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 15 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 6 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021340
Collection Date:11-Jul-16 4:11 PM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.157 mg-N/L EPA 353.2 07/18/2016 13:47 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 07/14/2016 20:56 BGN90340.2 2
Sulfate 11 mg/L EPA 300.0 07/14/2016 20:56 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:45 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/20/2016 14:57 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 13:02 JJMACKE0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 07/14/2016 13:02 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 13:02 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 13:02 JJMACKE0.01 1
Manganese (Mn)0.211 mg/L EPA 200.7 07/14/2016 13:02 JJMACKE0.005 1
Strontium (Sr)0.142 mg/L EPA 200.7 07/14/2016 13:02 JJMACKE0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 07/14/2016 13:02 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)14.4 mg/L EPA 200.7 07/19/2016 12:39 JJMACKE0.01 1
Magnesium (Mg)2.51 mg/L EPA 200.7 07/19/2016 12:39 JJMACKE0.005 1
Potassium (K)5.18 mg/L EPA 200.7 07/19/2016 12:39 JJMACKE0.1 1
Sodium (Na)47.9 mg/L EPA 200.7 07/19/2016 12:39 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.058 mg/L EPA 200.7 07/14/2016 10:04 MHH71310.005 1
Barium (Ba)0.022 mg/L EPA 200.7 07/14/2016 10:04 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 10:04 MHH71310.05 1
Iron (Fe)0.037 mg/L EPA 200.7 07/14/2016 10:04 MHH71310.01 1
Manganese (Mn)0.247 mg/L EPA 200.7 07/14/2016 10:04 MHH71310.005 1
Strontium (Sr)0.140 mg/L EPA 200.7 07/14/2016 10:04 MHH71310.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 07/14/2016 10:04 MHH71310.005 1
Duke Energy Analytical Lab
Page 7 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021340
Collection Date:11-Jul-16 4:11 PM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Copper (Cu)8.91 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Lead (Pb)1.21 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Molybdenum (Mo)5.25 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN30.2 1
Vanadium (V) Low Level 2.50 ug/L EPA 200.8 07/15/2016 12:09 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Copper (Cu)1.58 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Molybdenum (Mo)8.07 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA0.2 1
Vanadium (V) Low Level 2.48 ug/L EPA 200.8 07/14/2016 16:02 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 07/15/2016 14:24 JASTOWE251
Duke Energy Analytical Lab
Page 8 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021340
Collection Date:11-Jul-16 4:11 PM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.840 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 9 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021341
Collection Date:11-Jul-16 1:56 PM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.566 mg-N/L EPA 353.2 07/18/2016 13:48 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 300.0 07/14/2016 21:14 BGN90340.1 1
Sulfate 1.6 mg/L EPA 300.0 07/14/2016 21:14 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:26 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/20/2016 15:04 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.031 mg/L EPA 200.7 07/14/2016 13:05 JJMACKE0.005 1
Barium (Ba)0.010 mg/L EPA 200.7 07/14/2016 13:05 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 13:05 JJMACKE0.05 1
Iron (Fe)0.069 mg/L EPA 200.7 07/14/2016 13:05 JJMACKE0.01 1
Manganese (Mn)0.041 mg/L EPA 200.7 07/14/2016 13:05 JJMACKE0.005 1
Strontium (Sr)0.018 mg/L EPA 200.7 07/14/2016 13:05 JJMACKE0.005 1
Zinc (Zn)0.219 mg/L EPA 200.7 07/14/2016 13:05 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)2.89 mg/L EPA 200.7 07/19/2016 12:52 JJMACKE0.01 1
Magnesium (Mg)0.694 mg/L EPA 200.7 07/19/2016 12:52 JJMACKE0.005 1
Potassium (K)1.89 mg/L EPA 200.7 07/19/2016 12:52 JJMACKE0.1 1
Sodium (Na)4.34 mg/L EPA 200.7 07/19/2016 12:52 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.392 mg/L EPA 200.7 07/14/2016 10:08 MHH71310.005 1
Barium (Ba)0.013 mg/L EPA 200.7 07/14/2016 10:08 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 10:08 MHH71310.05 1
Iron (Fe)0.385 mg/L EPA 200.7 07/14/2016 10:08 MHH71310.01 1
Manganese (Mn)0.034 mg/L EPA 200.7 07/14/2016 10:08 MHH71310.005 1
Strontium (Sr)0.021 mg/L EPA 200.7 07/14/2016 10:08 MHH71310.005 1
Zinc (Zn)0.227 mg/L EPA 200.7 07/14/2016 10:08 MHH71310.005 1
Duke Energy Analytical Lab
Page 10 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021341
Collection Date:11-Jul-16 1:56 PM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Copper (Cu)8.07 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Lead (Pb)1.08 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN30.2 1
Vanadium (V) Low Level 0.502 ug/L EPA 200.8 07/14/2016 20:19 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Copper (Cu)1.90 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Nickel (Ni)1.16 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA0.2 1
Vanadium (V) Low Level 0.974 ug/L EPA 200.8 07/14/2016 16:37 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 43 mg/L SM2540C 07/15/2016 14:24 JASTOWE251
Duke Energy Analytical Lab
Page 11 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021341
Collection Date:11-Jul-16 1:56 PM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 12 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021342
Collection Date:11-Jul-16 4:17 PM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.176 mg-N/L EPA 353.2 07/18/2016 13:49 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.4 mg/L EPA 300.0 07/14/2016 21:31 BGN90340.1 1
Sulfate 1.1 mg/L EPA 300.0 07/14/2016 21:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:48 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/20/2016 15:09 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 13:09 JJMACKE0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 07/14/2016 13:09 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 13:09 JJMACKE0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 07/14/2016 13:09 JJMACKE0.01 1
Manganese (Mn)0.070 mg/L EPA 200.7 07/14/2016 13:09 JJMACKE0.005 1
Strontium (Sr)0.088 mg/L EPA 200.7 07/14/2016 13:09 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/14/2016 13:09 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)11.5 mg/L EPA 200.7 07/19/2016 12:56 JJMACKE0.01 1
Magnesium (Mg)3.16 mg/L EPA 200.7 07/19/2016 12:56 JJMACKE0.005 1
Potassium (K)1.36 mg/L EPA 200.7 07/19/2016 12:56 JJMACKE0.1 1
Sodium (Na)9.26 mg/L EPA 200.7 07/19/2016 12:56 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.155 mg/L EPA 200.7 07/14/2016 10:12 MHH71310.005 1
Barium (Ba)0.017 mg/L EPA 200.7 07/14/2016 10:12 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 10:12 MHH71310.05 1
Iron (Fe)0.223 mg/L EPA 200.7 07/14/2016 10:12 MHH71310.01 1
Manganese (Mn)0.081 mg/L EPA 200.7 07/14/2016 10:12 MHH71310.005 1
Strontium (Sr)0.088 mg/L EPA 200.7 07/14/2016 10:12 MHH71310.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 07/14/2016 10:12 MHH71310.005 1
Duke Energy Analytical Lab
Page 13 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021342
Collection Date:11-Jul-16 4:17 PM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Copper (Cu)1.17 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Nickel (Ni)1.09 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN30.2 1
Vanadium (V) Low Level 0.667 ug/L EPA 200.8 07/15/2016 12:15 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Chromium (Cr)1.19 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Nickel (Ni)1.23 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA0.2 1
Vanadium (V) Low Level 0.898 ug/L EPA 200.8 07/14/2016 16:44 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 98 mg/L SM2540C 07/15/2016 14:24 JASTOWE251
Duke Energy Analytical Lab
Page 14 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021342
Collection Date:11-Jul-16 4:17 PM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.276 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 15 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021343
Collection Date:11-Jul-16 4:17 PM
Site:MW-12D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.170 mg-N/L EPA 353.2 07/18/2016 13:50 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.4 mg/L EPA 300.0 07/14/2016 21:49 BGN90340.1 1
Sulfate 1.1 mg/L EPA 300.0 07/14/2016 21:49 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:50 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/20/2016 15:11 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 13:13 JJMACKE0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 07/14/2016 13:13 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 13:13 JJMACKE0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 07/14/2016 13:13 JJMACKE0.01 1
Manganese (Mn)0.070 mg/L EPA 200.7 07/14/2016 13:13 JJMACKE0.005 1
Strontium (Sr)0.087 mg/L EPA 200.7 07/14/2016 13:13 JJMACKE0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 07/14/2016 13:13 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)11.0 mg/L EPA 200.7 07/19/2016 13:00 JJMACKE0.01 1
Magnesium (Mg)3.02 mg/L EPA 200.7 07/19/2016 13:00 JJMACKE0.005 1
Potassium (K)1.31 mg/L EPA 200.7 07/19/2016 13:00 JJMACKE0.1 1
Sodium (Na)8.88 mg/L EPA 200.7 07/19/2016 13:00 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.154 mg/L EPA 200.7 07/14/2016 10:16 MHH71310.005 1
Barium (Ba)0.017 mg/L EPA 200.7 07/14/2016 10:16 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 10:16 MHH71310.05 1
Iron (Fe)0.235 mg/L EPA 200.7 07/14/2016 10:16 MHH71310.01 1
Manganese (Mn)0.084 mg/L EPA 200.7 07/14/2016 10:16 MHH71310.005 1
Strontium (Sr)0.090 mg/L EPA 200.7 07/14/2016 10:16 MHH71310.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 07/14/2016 10:16 MHH71310.005 1
Duke Energy Analytical Lab
Page 16 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021343
Collection Date:11-Jul-16 4:17 PM
Site:MW-12D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Copper (Cu)7.54 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Lead (Pb)1.09 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Nickel (Ni)1.23 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN30.2 1
Vanadium (V) Low Level 0.691 ug/L EPA 200.8 07/14/2016 20:32 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Chromium (Cr)1.17 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Nickel (Ni)1.16 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA0.2 1
Vanadium (V) Low Level 1.04 ug/L EPA 200.8 07/14/2016 16:51 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 07/15/2016 14:24 JASTOWE251
Duke Energy Analytical Lab
Page 17 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021343
Collection Date:11-Jul-16 4:17 PM
Site:MW-12D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.271 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 18 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021344
Collection Date:11-Jul-16 4:25 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/20/2016 15:14 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 13:36 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/14/2016 13:36 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 13:36 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 13:36 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/14/2016 13:36 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/14/2016 13:36 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/14/2016 13:36 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Copper (Cu)4.58 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 12:22 CWSPEN30.3 1
Duke Energy Analytical Lab
Page 19 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021345
Collection Date:11-Jul-16 4:25 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/18/2016 13:52 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 07/14/2016 13:46 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 07/14/2016 13:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:53 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 07/19/2016 13:28 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 07/19/2016 13:28 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 07/19/2016 13:28 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 07/19/2016 13:28 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 10:20 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/14/2016 10:20 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 10:20 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 10:20 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/14/2016 10:20 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/14/2016 10:20 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/14/2016 10:20 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/14/2016 16:58 JAHERMA0.3 1
Duke Energy Analytical Lab
Page 20 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
2016021345
Collection Date:11-Jul-16 4:25 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.364 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 21 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0016 mg-N/L -1-0.0016 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0007 mg-N/L -1-0.0007 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0005 mg-N/L -10.0005 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0009 mg-N/L -10.0009 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 99.9mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 99.9mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 99mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.296 3.01 98.2mg-N/L -11090102.96
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060271 -- 2016016749
Nitrite + Nitrate
(Colorimetric)
0.253 0.25 101mg-N/L -1109010.253
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060271 -- 2016016749
Nitrite + Nitrate
(Colorimetric)
0.253 0.25 101 0.278mg-N/L -1109010.253
Duke Energy Analytical Lab
Page 22 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070367 -- 2016021651
Nitrite + Nitrate
(Colorimetric)
0.258 0.25 102mg-N/L -1109010.258
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070367 -- 2016021651
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101 0.709mg-N/L -1109010.256
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Nitrite + Nitrate
(Colorimetric)
0.364 0.25 93.4mg-N/L -1109010.364
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Nitrite + Nitrate
(Colorimetric)
0.366 0.25 94.2 0.853mg-N/L -1109010.366
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070132 -- 2016021202
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101mg-N/L -1109010.256
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070132 -- 2016021202
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101 0.0395mg-N/L -1109010.256
Duke Energy Analytical Lab
Page 23 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070323 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0191 mg/L -10.0191 0.1 < 1/2 RDL
Sulfate 0.0202 mg/L -10.0202 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 7.28 5 101mg/L -1208017.28
Sulfate 6.73 5 99.6mg/L -1208016.73
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 7.26 5 101 0.344mg/L -1208017.26
Sulfate 6.71 5 99.4 0.247mg/L -1208016.71
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 6.9 5 103mg/L -1208016.9
Sulfate 6.45 5 102mg/L -1208016.45
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 6.91 5 104 0.141mg/L -1208016.91
Sulfate 6.44 5 102 0.223mg/L -1208016.44
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.18 5 104mg/L -1208015.18
Sulfate 5.15 5 103mg/L -1208015.15
Duke Energy Analytical Lab
Page 24 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070324 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.016 ug/L -10.016 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.019 ug/L -10.019 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.926 100 91.2ug/L -1307010092.6
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.898 100 88.4 3.12ug/L -1307010089.8
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 97.8ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.89 2 94.7ug/L -1158511.89
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021490
Mercury (Hg) 0.734 1 71.7ug/L -1307010.734
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021490
Mercury (Hg) 0.734 1 71.7 0ug/L -1307010.734
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021341
Mercury (Hg) 0.869 1 85.2ug/L -1307010.869
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021341
Mercury (Hg) 0.855 1 83.8 1.66ug/L -1307010.855
Duke Energy Analytical Lab
Page 25 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070512 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.004 ug/L -10.004 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.3ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Mercury (Hg) 1.04 1 102ug/L -1307011.04
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Mercury (Hg) 1.02 1 101 1.29ug/L -1307011.02
Duke Energy Analytical Lab
Page 26 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000029 mg/L -10.000029 0.005 < 1/2 RDL
Barium (Ba) 0.00006 mg/L -10.00006 0.005 < 1/2 RDL
Boron (B) 0.000281 mg/L -10.000281 0.05 < 1/2 RDL
Iron (Fe) -0.000508 mg/L -1-0.000508 0.01 < 1/2 RDL
Manganese (Mn) -0.000329 mg/L -1-0.000329 0.005 < 1/2 RDL
Strontium (Sr) 0.000134 mg/L -10.000134 0.005 < 1/2 RDL
Zinc (Zn) -0.000785 mg/L -1-0.000785 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) -0.000007 mg/L -1-0.000007 0.005 < 1/2 RDL
Barium (Ba) 0.000039 mg/L -10.000039 0.005 < 1/2 RDL
Boron (B) 0.00088 mg/L -10.00088 0.05 < 1/2 RDL
Iron (Fe) -0.000931 mg/L -1-0.000931 0.01 < 1/2 RDL
Manganese (Mn) -0.000163 mg/L -1-0.000163 0.005 < 1/2 RDL
Strontium (Sr) 0.000104 mg/L -10.000104 0.005 < 1/2 RDL
Zinc (Zn) -0.000664 mg/L -1-0.000664 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.09 2 105mg/L -1158512.09
Barium (Ba) 0.985 1 98.5mg/L -1158510.985
Boron (B) 1.98 2 99.2mg/L -1158511.98
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.982 1 98.2mg/L -1158510.982
Strontium (Sr) 1.91 2 95.5mg/L -1158511.91
Zinc (Zn) 1.03 1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.1 2 105mg/L -1158512.1
Barium (Ba) 0.991 1 99.1mg/L -1158510.991
Boron (B) 2.01 2 100mg/L -1158512.01
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.989 1 98.9mg/L -1158510.989
Strontium (Sr) 1.92 2 96.2mg/L -1158511.92
Zinc (Zn) 1.03 1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Aluminum (Al) 5.53 5 109mg/L -1307015.53
Duke Energy Analytical Lab
Page 27 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Barium (Ba) 5.26 5 104mg/L -1307015.26
Boron (B) 10.7 5 93.7mg/L -13070110.7
Iron (Fe) 5.3 5 101mg/L -1307015.3
Manganese (Mn) 7.89 5 96.8mg/L -1307017.89
Strontium (Sr) 7.3 5 102mg/L -1307017.3
Zinc (Zn) 5.21 5 104mg/L -1307015.21
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Aluminum (Al) 5.63 5 111 1.83mg/L -1307015.63
Barium (Ba) 5.35 5 105 1.65mg/L -1307015.35
Boron (B) 10.9 5 97.5 4mg/L -13070110.9
Iron (Fe) 5.39 5 103 1.86mg/L -1307015.39
Manganese (Mn) 8.03 5 99.5 2.77mg/L -1307018.03
Strontium (Sr) 7.37 5 104 1.32mg/L -1307017.37
Zinc (Zn) 5.29 5 106 1.64mg/L -1307015.29
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.43 5 108mg/L -1307015.43
Barium (Ba) 5.17 5 103mg/L -1307015.17
Boron (B) 5.11 5 102mg/L -1307015.11
Iron (Fe) 5.69 5 99.5mg/L -1307015.69
Manganese (Mn) 5.57 5 105mg/L -1307015.57
Strontium (Sr) 5.35 5 99.9mg/L -1307015.35
Zinc (Zn) 5.13 5 103mg/L -1307015.13
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.52 5 110 1.74mg/L -1307015.52
Barium (Ba) 5.27 5 105 2.02mg/L -1307015.27
Boron (B) 5.22 5 104 2.23mg/L -1307015.22
Iron (Fe) 5.81 5 102 2.32mg/L -1307015.81
Manganese (Mn) 5.67 5 107 1.98mg/L -1307015.67
Strontium (Sr) 5.43 5 102 1.71mg/L -1307015.43
Zinc (Zn) 5.24 5 105 2.04mg/L -1307015.24
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Aluminum (Al) 5.52 5 110mg/L -1307015.52
Barium (Ba) 5.23 5 104mg/L -1307015.23
Duke Energy Analytical Lab
Page 28 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Boron (B) 5.09 5 102mg/L -1307015.09
Iron (Fe) 5.09 5 102mg/L -1307015.09
Manganese (Mn) 5.4 5 107mg/L -1307015.4
Strontium (Sr) 5.08 5 100mg/L -1307015.08
Zinc (Zn) 5.29 5 106mg/L -1307015.29
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Aluminum (Al) 5.52 5 110 0.0725mg/L -1307015.52
Barium (Ba) 5.24 5 104 0.211mg/L -1307015.24
Boron (B) 5.11 5 102 0.294mg/L -1307015.11
Iron (Fe) 5.12 5 102 0.431mg/L -1307015.12
Manganese (Mn) 5.42 5 108 0.41mg/L -1307015.42
Strontium (Sr) 5.09 5 101 0.139mg/L -1307015.09
Zinc (Zn) 5.31 5 106 0.246mg/L -1307015.31
Duke Energy Analytical Lab
Page 29 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00129 mg/L -10.00129 0.01 < 1/2 RDL
Magnesium (Mg) 0.000115 mg/L -10.000115 0.005 < 1/2 RDL
Potassium (K) -0.00152 mg/L -1-0.00152 0.1 < 1/2 RDL
Sodium (Na) -0.00992 mg/L -1-0.00992 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.00148 mg/L -10.00148 0.01 < 1/2 RDL
Magnesium (Mg) 0.000217 mg/L -10.000217 0.005 < 1/2 RDL
Potassium (K) 0.00492 mg/L -10.00492 0.1 < 1/2 RDL
Sodium (Na) -0.0117 mg/L -1-0.0117 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.04 2 102mg/L -1158512.04
Magnesium (Mg) 1.99 2 99.3mg/L -1158511.99
Potassium (K) 3.98 4 99.6mg/L -1158513.98
Sodium (Na) 8.38 8.1 103mg/L -1158518.38
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 2.14 2 107mg/L -1158512.14
Magnesium (Mg) 2.08 2 104mg/L -1158512.08
Potassium (K) 4.21 4 105mg/L -1158514.21
Sodium (Na) 8.85 8.1 109mg/L -1158518.85
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Calcium (Ca) 104 5 0mg/L -130701104
Magnesium (Mg) 21.2 5 88.2mg/L -13070121.2
Potassium (K) 15.9 5 93.2mg/L -13070115.9
Sodium (Na) 38.3 5 106mg/L -13070138.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Calcium (Ca) 104 5 204 200mg/L -130701104
Magnesium (Mg) 21.1 5 88 0.25mg/L -13070121.1
Potassium (K) 16 5 94 0.876mg/L -13070116
Sodium (Na) 38.3 5 107 0.981mg/L -13070138.3
Duke Energy Analytical Lab
Page 30 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Calcium (Ca) 19.1 5 93.9mg/L -13070119.1
Magnesium (Mg) 7.69 5 104mg/L -1307017.69
Potassium (K) 10.1 5 98.1mg/L -13070110.1
Sodium (Na) 51.5 5 71.7mg/L -13070151.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Calcium (Ca) 19.3 5 97.7 3.97mg/L -13070119.3
Magnesium (Mg) 7.78 5 105 1.66mg/L -1307017.78
Potassium (K) 10.2 5 101 3.07mg/L -13070110.2
Sodium (Na) 52.1 5 83.3 14.9mg/L -13070152.1
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Calcium (Ca) 25.9 5 102mg/L -13070125.9
Magnesium (Mg) 7.35 5 113mg/L -1307017.35
Potassium (K) 12.9 5 102mg/L -13070112.9
Sodium (Na) 22.6 5 107mg/L -13070122.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Calcium (Ca) 26 5 104 1.61mg/L -13070126
Magnesium (Mg) 7.39 5 114 0.671mg/L -1307017.39
Potassium (K) 13 5 104 1.83mg/L -13070113
Sodium (Na) 22.8 5 110 2.73mg/L -13070122.8
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Calcium (Ca) 65.4 5 83.2mg/L -13070165.4
Magnesium (Mg) 18.6 5 95.7mg/L -13070118.6
Potassium (K) 11 5 110mg/L -13070111
Sodium (Na) 25.6 5 103mg/L -13070125.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Calcium (Ca) 65.8 5 91 8.91mg/L -13070165.8
Magnesium (Mg) 18.6 5 96.6 1.02mg/L -13070118.6
Potassium (K) 11 5 110 0.4mg/L -13070111
Sodium (Na) 25.7 5 105 1.9mg/L -13070125.7
Duke Energy Analytical Lab
Page 31 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070257 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00146 mg/L -10.00146 0.005 < 1/2 RDL
Barium (Ba) 0.0002 mg/L -10.0002 0.005 < 1/2 RDL
Boron (B) 0.00202 mg/L -10.00202 0.05 < 1/2 RDL
Iron (Fe) 0.000737 mg/L -10.000737 0.01 < 1/2 RDL
Manganese (Mn) 0.000264 mg/L -10.000264 0.005 < 1/2 RDL
Strontium (Sr) 0.000363 mg/L -10.000363 0.005 < 1/2 RDL
Zinc (Zn) 0.00213 mg/L -10.00213 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.78 5 95.7mg/L -1158514.78
Barium (Ba) 5.05 5 101mg/L -1158515.05
Boron (B) 5.13 5 103mg/L -1158515.13
Iron (Fe) 5.08 5 102mg/L -1158515.08
Manganese (Mn) 5.02 5 100mg/L -1158515.02
Strontium (Sr) 4.99 5 99.8mg/L -1158514.99
Zinc (Zn) 5.02 5 100mg/L -1158515.02
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.47 5 101mg/L -1307015.47
Barium (Ba) 5.1 5 101mg/L -1307015.1
Boron (B) 5.19 5 104mg/L -1307015.19
Iron (Fe) 6.34 5 100mg/L -1307016.34
Manganese (Mn) 5.31 5 99.2mg/L -1307015.31
Strontium (Sr) 5.38 5 100mg/L -1307015.38
Zinc (Zn) 4.91 5 97.8mg/L -1307014.91
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.39 5 99.7 1.55mg/L -1307015.39
Barium (Ba) 5.06 5 101 0.811mg/L -1307015.06
Boron (B) 5.17 5 103 0.329mg/L -1307015.17
Iron (Fe) 6.28 5 99 1.24mg/L -1307016.28
Manganese (Mn) 5.27 5 98.5 0.749mg/L -1307015.27
Strontium (Sr) 5.32 5 98.8 1.31mg/L -1307015.32
Zinc (Zn) 4.9 5 97.5 0.328mg/L -1307014.9
Duke Energy Analytical Lab
Page 32 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070304 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.091 ug/L -1-0.091 1 < 1/2 RDL
Arsenic (As) 0.0151 ug/L -10.0151 1 < 1/2 RDL
Beryllium (Be) 0.0675 ug/L -10.0675 1 < 1/2 RDL
Cadmium (Cd) 0.0121 ug/L -10.0121 1 < 1/2 RDL
Chromium (Cr) -0.0814 ug/L -1-0.0814 1 < 1/2 RDL
Cobalt (Co) 0.0099 ug/L -10.0099 1 < 1/2 RDL
Copper (Cu) -0.11 ug/L -1-0.11 1 < 1/2 RDL
Lead (Pb) 0.0068 ug/L -10.0068 1 < 1/2 RDL
Molybdenum (Mo) 0.0034 ug/L -10.0034 1 < 1/2 RDL
Nickel (Ni) -0.0029 ug/L -1-0.0029 1 < 1/2 RDL
Selenium (Se) -0.081 ug/L -1-0.081 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0346 ug/L -1-0.0346 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0426 ug/L -10.0426 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 52.3 50 105ug/L -11585152.3
Arsenic (As) 51.1 50 102ug/L -11585151.1
Beryllium (Be) 50 50 100ug/L -11585150
Cadmium (Cd) 51.4 50 103ug/L -11585151.4
Chromium (Cr) 51.8 50 104ug/L -11585151.8
Cobalt (Co) 50.7 50 101ug/L -11585150.7
Copper (Cu) 50.7 50 101ug/L -11585150.7
Lead (Pb) 52 50 104ug/L -11585152
Molybdenum (Mo) 51.7 50 103ug/L -11585151.7
Nickel (Ni) 51.4 50 103ug/L -11585151.4
Selenium (Se) 49.1 50 98.1ug/L -11585149.1
Thallium (Tl) Low Level 49.6 50 99.1ug/L -11585149.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Antimony (Sb) 51.8 50 103ug/L -13070151.8
Arsenic (As) 50.6 50 101ug/L -13070150.6
Beryllium (Be) 55.5 50 111ug/L -13070155.5
Cadmium (Cd) 50 50 100ug/L -13070150
Chromium (Cr) 51.6 50 102ug/L -13070151.6
Cobalt (Co) 49.8 50 96.7ug/L -13070149.8
Copper (Cu) 48.9 50 97.5ug/L -13070148.9
Lead (Pb) 50.8 50 101ug/L -13070150.8
Molybdenum (Mo) 54.2 50 102ug/L -13070154.2
Duke Energy Analytical Lab
Page 33 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070304 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Nickel (Ni) 53.3 50 97.7ug/L -13070153.3
Selenium (Se) 48.2 50 96.5ug/L -13070148.2
Thallium (Tl) Low Level 48.4 50 96.8ug/L -13070148.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Antimony (Sb) 52.5 50 104 1.42ug/L -13070152.5
Arsenic (As) 51.2 50 102 1.23ug/L -13070151.2
Beryllium (Be) 54.1 50 108 2.64ug/L -13070154.1
Cadmium (Cd) 50.8 50 102 1.66ug/L -13070150.8
Chromium (Cr) 52 50 103 0.773ug/L -13070152
Cobalt (Co) 50.4 50 98 1.33ug/L -13070150.4
Copper (Cu) 49.4 50 98.5 1.04ug/L -13070149.4
Lead (Pb) 51.1 50 102 0.572ug/L -13070151.1
Molybdenum (Mo) 54.4 50 102 0.412ug/L -13070154.4
Nickel (Ni) 54.5 50 100 2.42ug/L -13070154.5
Selenium (Se) 48.8 50 97.8 1.3ug/L -13070148.8
Thallium (Tl) Low Level 49.5 50 99 2.25ug/L -13070149.5
Duke Energy Analytical Lab
Page 34 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070260 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0002 ug/L -1-0.0002 1 < 1/2 RDL
Arsenic (As) 0.0408 ug/L -10.0408 1 < 1/2 RDL
Beryllium (Be) 0 ug/L -10 1 < 1/2 RDL
Cadmium (Cd) -0.0007 ug/L -1-0.0007 1 < 1/2 RDL
Chromium (Cr) -0.0137 ug/L -1-0.0137 1 < 1/2 RDL
Cobalt (Co) -0.0142 ug/L -1-0.0142 1 < 1/2 RDL
Copper (Cu) -0.172 ug/L -1-0.172 1 < 1/2 RDL
Lead (Pb) -0.0041 ug/L -1-0.0041 1 < 1/2 RDL
Molybdenum (Mo) 0.0178 ug/L -10.0178 1 < 1/2 RDL
Nickel (Ni) -0.012 ug/L -1-0.012 1 < 1/2 RDL
Selenium (Se) -0.0014 ug/L -1-0.0014 1 < 1/2 RDL
Thallium (Tl) Low Level 0.0743 ug/L -10.0743 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.161 ug/L -10.161 0.3 > 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.3 50 101ug/L -11585150.3
Arsenic (As) 52.7 50 105ug/L -11585152.7
Beryllium (Be) 52.5 50 105ug/L -11585152.5
Cadmium (Cd) 49.6 50 99.2ug/L -11585149.6
Chromium (Cr) 51.7 50 103ug/L -11585151.7
Cobalt (Co) 52.8 50 106ug/L -11585152.8
Copper (Cu) 52.7 50 105ug/L -11585152.7
Lead (Pb) 48.6 50 97.2ug/L -11585148.6
Molybdenum (Mo) 51 50 102ug/L -11585151
Nickel (Ni) 50.8 50 102ug/L -11585150.8
Selenium (Se) 49.1 50 98.3ug/L -11585149.1
Thallium (Tl) Low Level 48 50 95.9ug/L -11585148
Vanadium (V) Low Level 51.6 50 103ug/L -11585151.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Antimony (Sb) 50.8 50 101ug/L -13070150.8
Arsenic (As) 51.5 50 102ug/L -13070151.5
Beryllium (Be) 52.9 50 106ug/L -13070152.9
Cadmium (Cd) 49.2 50 98.3ug/L -13070149.2
Chromium (Cr) 49.3 50 98.4ug/L -13070149.3
Cobalt (Co) 49.9 50 98.2ug/L -13070149.9
Copper (Cu) 51.1 50 99.1ug/L -13070151.1
Lead (Pb) 49.3 50 98.5ug/L -13070149.3
Duke Energy Analytical Lab
Page 35 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070260 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Molybdenum (Mo) 57.2 50 98.3ug/L -13070157.2
Nickel (Ni) 50.1 50 99.1ug/L -13070150.1
Selenium (Se) 48.2 50 96.5ug/L -13070148.2
Thallium (Tl) Low Level 49.1 50 98.1ug/L -13070149.1
Vanadium (V) Low Level 53.3 50 102ug/L -13070153.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Antimony (Sb) 49.2 50 97.9 3.22ug/L -13070149.2
Arsenic (As) 51.6 50 102 0.157ug/L -13070151.6
Beryllium (Be) 51 50 102 3.74ug/L -13070151
Cadmium (Cd) 49.1 50 98.3 0.061ug/L -13070149.1
Chromium (Cr) 49.3 50 98.4 0.0203ug/L -13070149.3
Cobalt (Co) 50.1 50 98.5 0.346ug/L -13070150.1
Copper (Cu) 51.4 50 99.7 0.604ug/L -13070151.4
Lead (Pb) 48.5 50 97 1.56ug/L -13070148.5
Molybdenum (Mo) 57.5 50 98.8 0.508ug/L -13070157.5
Nickel (Ni) 50.2 50 99.4 0.222ug/L -13070150.2
Selenium (Se) 48.9 50 97.8 1.36ug/L -13070148.9
Thallium (Tl) Low Level 48.5 50 96.7 1.4ug/L -13070148.5
Vanadium (V) Low Level 52.5 50 100 1.55ug/L -13070152.5
Duke Energy Analytical Lab
Page 36 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070360 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060345 -- 2016017027
TDS 0.221mg/L -1453
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060345 -- 2016017028
TDS 66.7mg/L -12
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 99mg/L -11090199
Duke Energy Analytical Lab
Page 37 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070294 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.025 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.049 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 96.6mg/L -1208013.68
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 103 6.85mg/L -1208013.82
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 105mg/L -1208012.39
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 103 2.69mg/L -1208012.33
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 98.8mg/L -1208012.82
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 103 4.31mg/L -1208012.9
Final QualifierDilMeasuredUnits:Parameter
IS # 4
% Recovery LCL UCLSpike
TOC 2 102mg/L -1208013.46
Final QualifierDilMeasuredUnits:Parameter
ISD # 4
RPD% Recovery LCL UCLSpike
TOC 2 99.3 2.29mg/L -1208013.41
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.92
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.93
Duke Energy Analytical Lab
Page 38 of 64
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070300
Q16070249 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060233 -- 2016016599
TSS 10.5mg/L -15.4
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070200 -- 2016020916
TSS 0mg/L -11.2
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 102mg/L -11090151.2
Duke Energy Analytical Lab
Page 39 of 64
#=CL#
July 19, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92304785
92304785
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16070300
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Bishop for
[e-mail]
HORIZON Database Administrator
Kevin Herring
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
Duke Energy Analytical Lab
Page 40 of 64
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92304785
J16070300
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 24
Duke Energy Analytical Lab
Page 41 of 64
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92304785
J16070300
Lab ID Sample ID Matrix Date Collected Date Received
92304785001 2016021339 Water 07/11/16 14:23 07/12/16 14:06
92304785002 2016021340 Water 07/11/16 16:11 07/12/16 14:06
92304785003 2016021341 Water 07/11/16 13:56 07/12/16 14:06
92304785004 2016021342 Water 07/11/16 16:17 07/12/16 14:06
92304785005 2016021343 Water 07/11/16 16:17 07/12/16 14:06
92304785006 2016021345 Water 07/11/16 16:25 07/12/16 14:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 24
Duke Energy Analytical Lab
Page 42 of 64
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92304785
J16070300
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92304785001 2016021339 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304785002 2016021340 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304785003 2016021341 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304785004 2016021342 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304785005 2016021343 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304785006 2016021345 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 24
Duke Energy Analytical Lab
Page 43 of 64
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92304785
J16070300
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92304785001 2016021339
Methane 54.6 ug/L 07/15/16 20:2010.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)211 mg/L 07/15/16 22:365.0SM 2320B
Alkalinity, Total as CaCO3 211 mg/L 07/15/16 22:365.0SM 2320B
92304785002 2016021340
Alkalinity,Bicarbonate (CaCO3)130 mg/L 07/15/16 23:095.0SM 2320B
Alkalinity, Total as CaCO3 130 mg/L 07/15/16 23:095.0SM 2320B
92304785003 2016021341
Alkalinity,Bicarbonate (CaCO3)12.8 mg/L 07/15/16 23:475.0SM 2320B
Alkalinity, Total as CaCO3 12.8 mg/L 07/15/16 23:475.0SM 2320B
Chromium, Hexavalent 0.045 ug/L 07/15/16 14:380.030EPA 218.7
92304785004 2016021342
Methane 17.9 ug/L 07/15/16 21:0610.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)56.3 mg/L 07/15/16 23:585.0SM 2320B
Alkalinity, Total as CaCO3 56.3 mg/L 07/15/16 23:585.0SM 2320B
Chromium, Hexavalent 0.73 ug/L 07/15/16 15:170.090EPA 218.7
92304785005 2016021343
Methane 21.7 ug/L 07/15/16 21:2110.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)56.4 mg/L 07/16/16 00:105.0SM 2320B
Alkalinity, Total as CaCO3 56.4 mg/L 07/16/16 00:105.0SM 2320B
Chromium, Hexavalent 0.65 ug/L 07/15/16 15:310.090EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 24
Duke Energy Analytical Lab
Page 44 of 64
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304785
J16070300
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 19, 2016
Description:RSK 175 Headspace
General Information:
6 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 24
Duke Energy Analytical Lab
Page 45 of 64
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304785
J16070300
Method:
Client:Duke Energy
SM 2320B
Date:July 19, 2016
Description:2320B Alkalinity
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321357
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304615003,92304785002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1780860)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1780861)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 24
Duke Energy Analytical Lab
Page 46 of 64
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304785
J16070300
Method:
Client:Duke Energy
SM 4500-S2D
Date:July 19, 2016
Description:4500S2D Sulfide Water
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321058
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304497002,92304520001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1779226)
• Sulfide
• MS (Lab ID: 1779228)
• Sulfide
• MSD (Lab ID: 1779227)
• Sulfide
• MSD (Lab ID: 1779229)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 24
Duke Energy Analytical Lab
Page 47 of 64
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304785
J16070300
Method:
Client:Duke Energy
EPA 218.7
Date:July 19, 2016
Description:Hexavalent Chromium by IC
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 24
Duke Energy Analytical Lab
Page 48 of 64
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304785
J16070300
Sample:2016021339 Lab ID:92304785001 Collected:07/11/16 14:23 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 54.6 ug/L 07/15/16 20:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)211 mg/L 07/15/16 22:365.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 22:365.0 1
Alkalinity, Total as CaCO3 211 mg/L 07/15/16 22:365.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/15/16 14:12 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 24
Duke Energy Analytical Lab
Page 49 of 64
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304785
J16070300
Sample:2016021340 Lab ID:92304785002 Collected:07/11/16 16:11 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 20:35 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)130 mg/L 07/15/16 23:095.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 23:095.0 1
Alkalinity, Total as CaCO3 130 mg/L 07/15/16 23:095.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/15/16 14:25 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 24
Duke Energy Analytical Lab
Page 50 of 64
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304785
J16070300
Sample:2016021341 Lab ID:92304785003 Collected:07/11/16 13:56 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 20:51 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)12.8 mg/L 07/15/16 23:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 23:475.0 1
Alkalinity, Total as CaCO3 12.8 mg/L 07/15/16 23:475.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.045 ug/L 07/15/16 14:38 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 24
Duke Energy Analytical Lab
Page 51 of 64
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304785
J16070300
Sample:2016021342 Lab ID:92304785004 Collected:07/11/16 16:17 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 17.9 ug/L 07/15/16 21:06 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)56.3 mg/L 07/15/16 23:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 23:585.0 1
Alkalinity, Total as CaCO3 56.3 mg/L 07/15/16 23:585.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.73 ug/L 07/15/16 15:17 18540-29-90.090 3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 24
Duke Energy Analytical Lab
Page 52 of 64
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304785
J16070300
Sample:2016021343 Lab ID:92304785005 Collected:07/11/16 16:17 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 21.7 ug/L 07/15/16 21:21 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)56.4 mg/L 07/16/16 00:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 00:105.0 1
Alkalinity, Total as CaCO3 56.4 mg/L 07/16/16 00:105.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.65 ug/L 07/15/16 15:31 18540-29-90.090 3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 24
Duke Energy Analytical Lab
Page 53 of 64
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304785
J16070300
Sample:2016021345 Lab ID:92304785006 Collected:07/11/16 16:25 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 21:37 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/16/16 12:055.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 12:055.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/16/16 12:055.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 24
Duke Energy Analytical Lab
Page 54 of 64
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304785
J16070300
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321404
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005, 92304785006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781373
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005, 92304785006
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/15/16 16:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781374LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1781376
Methane ug/L 369 N23969370-13093367 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 24
Duke Energy Analytical Lab
Page 55 of 64
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304785
J16070300
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321357
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1780858
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/15/16 20:02
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/15/16 20:02
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/15/16 20:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1780859LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.550 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1780860MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304615003
1780861
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M15013080-120130 0 255012.6 77.6 77.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1780862MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304785002
1780863
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 118 80-12087 8 2550130189174
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 24
Duke Energy Analytical Lab
Page 56 of 64
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304785
J16070300
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321461
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304785006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781594
Associated Lab Samples:92304785006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/16/16 11:44
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/16/16 11:44
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/16/16 11:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781595LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 52.050 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781596MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304785006
1781597
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 2550ND48.3 48.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781598MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304863002
1781599
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 255037.1 85.7 85.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 24
Duke Energy Analytical Lab
Page 57 of 64
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304785
J16070300
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321058
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005, 92304785006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779224
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005, 92304785006
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/13/16 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779225LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779226MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304497002
1779227
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 125 90-110125 0 10.5ND 0.63 0.63
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779228MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304520001
1779229
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 113 90-110113 0 10.5ND 0.59 0.59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 24
Duke Energy Analytical Lab
Page 58 of 64
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304785
J16070300
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
309009
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1638251
Associated Lab Samples:92304785001, 92304785002, 92304785003, 92304785004, 92304785005
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 07/15/16 10:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638252LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1638253MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304787001
1638254
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 106 85-115105 1 20.075ND 0.11 0.11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 24
Duke Energy Analytical Lab
Page 59 of 64
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92304785
J16070300
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 24
Duke Energy Analytical Lab
Page 60 of 64
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92304785
J16070300
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92304785001 3214042016021339RSK 175 Modified
92304785002 3214042016021340RSK 175 Modified
92304785003 3214042016021341RSK 175 Modified
92304785004 3214042016021342RSK 175 Modified
92304785005 3214042016021343RSK 175 Modified
92304785006 3214042016021345RSK 175 Modified
92304785001 3213572016021339SM 2320B
92304785002 3213572016021340SM 2320B
92304785003 3213572016021341SM 2320B
92304785004 3213572016021342SM 2320B
92304785005 3213572016021343SM 2320B
92304785006 3214612016021345SM 2320B
92304785001 3210582016021339SM 4500-S2D
92304785002 3210582016021340SM 4500-S2D
92304785003 3210582016021341SM 4500-S2D
92304785004 3210582016021342SM 4500-S2D
92304785005 3210582016021343SM 4500-S2D
92304785006 3210582016021345SM 4500-S2D
92304785001 3090092016021339EPA 218.7
92304785002 3090092016021340EPA 218.7
92304785003 3090092016021341EPA 218.7
92304785004 3090092016021342EPA 218.7
92304785005 3090092016021343EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 24
Duke Energy Analytical Lab
Page 61 of 64
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Duke Energy Analytical Lab
Page 62 of 64
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Duke Energy Analytical Lab
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Duke Energy Analytical Lab
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