NC0038377_J16060373report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16060373
Project Name:MAYO STEAM - ABGW
Lab Contact:Anne Pridgeon
Date:8/2/2016
Customer Address:Mayo Steam Plant
Customer Name(s):J. TOEPFER, T. HUNSUCKER
10660 Boston Road
Roxboro,North Carolina 27574
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
LIMS number for CW-5 and CW-6 provided on pregenerated COC was changed during sampling. Historical data for the dionex
parameter indicated that sample volumes were not in fact switched in field as previously communicated. Results are consistent
with historical information as reported.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 61
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016017127 MAYO STEAM 13-Jul-16 11:46 AM Kaitlyn Fox CW-1
2016017128 MAYO STEAM 13-Jul-16 11:28 AM Kaitlyn Fox CW-1D
2016017129 MAYO STEAM 13-Jul-16 1:29 PM Kaitlyn Fox CW-2
2016017130 MAYO STEAM 13-Jul-16 1:09 PM Kaitlyn Fox CW-2D
2016017131 MAYO STEAM 13-Jul-16 5:35 PM Kaitlyn Fox CW-3
2016017132 MAYO STEAM 13-Jul-16 4:38 PM Kaitlyn Fox CW-4
2016017133 MAYO STEAM 13-Jul-16 3:23 PM Kaitlyn Fox CW-6
2016017134 MAYO STEAM 13-Jul-16 2:22 PM Kaitlyn Fox CW-5
2016017135 MAYO STEAM 13-Jul-16 4:40 PM Kaitlyn Fox BG-1
2016017136 MAYO STEAM 13-Jul-16 3:41 PM Kaitlyn Fox BG-2
2016017137 MAYO STEAM 13-Jul-16 11:28 AM Kaitlyn Fox DUP CW-1D
2016017138 MAYO STEAM 13-Jul-16 11:15 AM Kaitlyn Fox FIELD BLANK
12 Total Samples
Duke Energy Analytical Lab
Page 2 of 61
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By: Date:
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017127
Collection Date:13-Jul-16 11:46 AM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 23 mg/L EPA 300.0 07/14/2016 13:29 BGN90340.5 5
Nitrate 6.6 mg/L EPA 300.0 07/14/2016 13:29 BGN90340.1 1
Nitrate as N 1.5 mg-N/L EPA 300.0 07/14/2016 13:29 BGN90340.023 1
Sulfate 15 mg/L EPA 300.0 07/14/2016 13:29 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 10:20 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.029 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.05 1
Calcium (Ca)10.0 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Iron (Fe)0.020 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.01 1
Magnesium (Mg)4.34 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Potassium (K)1.37 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.1 1
Sodium (Na)16.9 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.05 1
Strontium (Sr)0.074 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 07/26/2016 09:41 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA0.2 1
Vanadium (V) Low Level 0.637 ug/L EPA 200.8 07/27/2016 15:27 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 4 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017127
Collection Date:13-Jul-16 11:46 AM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 5 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017128
Collection Date:13-Jul-16 11:28 AM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 07/14/2016 13:47 BGN90340.2 2
Nitrate 2.3 mg/L EPA 300.0 07/14/2016 13:47 BGN90340.1 1
Nitrate as N 0.52 mg-N/L EPA 300.0 07/14/2016 13:47 BGN90340.023 1
Sulfate 4.5 mg/L EPA 300.0 07/14/2016 13:47 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:11 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.05 1
Calcium (Ca)45.7 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.01 1
Magnesium (Mg)9.31 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Potassium (K)2.05 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.1 1
Sodium (Na)13.1 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.05 1
Strontium (Sr)0.179 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 09:53 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Molybdenum (Mo)21.5 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA0.2 1
Vanadium (V) Low Level 1.40 ug/L EPA 200.8 07/27/2016 15:00 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 6 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017128
Collection Date:13-Jul-16 11:28 AM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 7 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017129
Collection Date:13-Jul-16 1:29 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 43 mg/L EPA 300.0 07/14/2016 14:05 BGN9034110
Nitrate < 0.1 mg/L EPA 300.0 07/14/2016 14:05 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 07/14/2016 14:05 BGN90340.023 1
Sulfate 36 mg/L EPA 300.0 07/14/2016 14:05 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 10:56 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Barium (Ba)0.103 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Boron (B)0.742 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.05 1
Calcium (Ca)14.2 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Iron (Fe)0.011 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.01 1
Magnesium (Mg)6.73 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Manganese (Mn)0.298 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Potassium (K)1.80 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.1 1
Sodium (Na)14.8 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.05 1
Strontium (Sr)0.204 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 07/26/2016 09:57 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/27/2016 15:34 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 8 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017129
Collection Date:13-Jul-16 1:29 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 9 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017130
Collection Date:13-Jul-16 1:09 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 49 mg/L EPA 300.0 07/14/2016 14:23 BGN9034110
Nitrate < 0.1 mg/L EPA 300.0 07/14/2016 14:23 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 07/14/2016 14:23 BGN90340.023 1
Sulfate 47 mg/L EPA 300.0 07/14/2016 14:23 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:13 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.338 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Barium (Ba)0.029 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Boron (B)0.412 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.05 1
Calcium (Ca)76.7 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Iron (Fe)0.213 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.01 1
Magnesium (Mg)7.04 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Manganese (Mn)0.198 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Potassium (K)4.16 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.1 1
Sodium (Na)20.6 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.05 1
Strontium (Sr)0.405 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:14 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA0.2 1
Vanadium (V) Low Level 1.28 ug/L EPA 200.8 07/27/2016 15:41 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 10 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017130
Collection Date:13-Jul-16 1:09 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 22 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 11 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017131
Collection Date:13-Jul-16 5:35 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 96 mg/L EPA 300.0 07/14/2016 14:40 BGN9034220
Nitrate 1.3 mg/L EPA 300.0 07/14/2016 14:40 BGN90340.1 1
Nitrate as N 0.28 mg-N/L EPA 300.0 07/14/2016 14:40 BGN90340.023 1
Sulfate 16 mg/L EPA 300.0 07/14/2016 14:40 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:16 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.166 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Barium (Ba)0.017 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.05 1
Calcium (Ca)64.8 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Iron (Fe)0.136 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.01 1
Magnesium (Mg)7.63 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Manganese (Mn)0.010 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Potassium (K)4.40 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.1 1
Sodium (Na)43.0 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.05 1
Strontium (Sr)0.330 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:05 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA0.2 1
Vanadium (V) Low Level 1.74 ug/L EPA 200.8 07/27/2016 15:48 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 390 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 12 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017131
Collection Date:13-Jul-16 5:35 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 13 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017132
Collection Date:13-Jul-16 4:38 PM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.8 mg/L EPA 300.0 07/14/2016 14:58 BGN90340.1 1
Nitrate 0.48 mg/L EPA 300.0 07/14/2016 14:58 BGN90340.1 1
Nitrate as N 0.11 mg-N/L EPA 300.0 07/14/2016 14:58 BGN90340.023 1
Sulfate 22 mg/L EPA 300.0 07/14/2016 14:58 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:18 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.101 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Barium (Ba)0.024 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.05 1
Calcium (Ca)11.5 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Iron (Fe)0.056 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.01 1
Magnesium (Mg)3.02 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Manganese (Mn)0.009 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Potassium (K)1.18 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.1 1
Sodium (Na)15.4 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.05 1
Strontium (Sr)0.126 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:09 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA0.2 1
Vanadium (V) Low Level 1.11 ug/L EPA 200.8 07/27/2016 15:55 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 14 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017132
Collection Date:13-Jul-16 4:38 PM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 15 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017133
Collection Date:13-Jul-16 3:23 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 94 mg/L EPA 300.0 07/15/2016 10:52 BGN9034220
Nitrate 0.12 mg/L EPA 300.0 07/15/2016 10:52 BGN90340.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 07/15/2016 10:52 BGN90340.023 1
Sulfate 39 mg/L EPA 300.0 07/15/2016 10:52 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:21 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.105 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Barium (Ba)0.044 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.05 1
Calcium (Ca)110 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Iron (Fe)2.27 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.01 1
Magnesium (Mg)21.0 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Manganese (Mn)1.51 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Potassium (K)10.4 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.1 1
Sodium (Na)41.3 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.05 1
Strontium (Sr)0.346 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 07/26/2016 10:18 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Molybdenum (Mo)3.57 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/27/2016 16:02 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 550 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 16 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017133
Collection Date:13-Jul-16 3:23 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 18 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 17 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017134
Collection Date:13-Jul-16 2:22 PM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 40 mg/L EPA 300.0 07/15/2016 11:08 BGN9034110
Nitrate < 0.1 mg/L EPA 300.0 07/15/2016 11:08 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 07/15/2016 11:08 BGN90340.023 1
Sulfate 6.0 mg/L EPA 300.0 07/15/2016 11:08 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:46 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.032 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Barium (Ba)0.054 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.05 1
Calcium (Ca)55.3 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Iron (Fe)0.865 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.01 1
Magnesium (Mg)7.38 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Manganese (Mn)0.854 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Potassium (K)5.66 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.1 1
Sodium (Na)18.2 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.05 1
Strontium (Sr)0.167 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:38 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Cobalt (Co)1.04 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/27/2016 16:09 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 18 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017134
Collection Date:13-Jul-16 2:22 PM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 19 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017135
Collection Date:13-Jul-16 4:40 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 07/14/2016 15:52 BGN90340.5 5
Nitrate 3.6 mg/L EPA 300.0 07/14/2016 15:52 BGN90340.1 1
Nitrate as N 0.81 mg-N/L EPA 300.0 07/14/2016 15:52 BGN90340.023 1
Sulfate 0.23 mg/L EPA 300.0 07/14/2016 15:52 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:48 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.066 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Barium (Ba)0.086 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.05 1
Calcium (Ca)12.3 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Iron (Fe)0.089 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.01 1
Magnesium (Mg)3.09 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Manganese (Mn)0.007 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Potassium (K)1.28 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.1 1
Sodium (Na)11.9 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.05 1
Strontium (Sr)0.177 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:22 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA0.2 1
Vanadium (V) Low Level 3.58 ug/L EPA 200.8 07/27/2016 16:43 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 20 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017135
Collection Date:13-Jul-16 4:40 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 21 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017136
Collection Date:13-Jul-16 3:41 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 30 mg/L EPA 300.0 07/14/2016 16:10 BGN90340.5 5
Nitrate < 0.1 mg/L EPA 300.0 07/14/2016 16:10 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 07/14/2016 16:10 BGN90340.023 1
Sulfate 4.9 mg/L EPA 300.0 07/14/2016 16:10 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:51 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.058 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Barium (Ba)0.059 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.05 1
Calcium (Ca)59.9 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Iron (Fe)0.484 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.01 1
Magnesium (Mg)13.5 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Manganese (Mn)0.207 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Potassium (K)3.23 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.1 1
Sodium (Na)53.3 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.05 1
Strontium (Sr)0.374 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:26 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA0.2 1
Vanadium (V) Low Level 4.79 ug/L EPA 200.8 07/27/2016 16:36 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 22 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017136
Collection Date:13-Jul-16 3:41 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 23 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017137
Collection Date:13-Jul-16 11:28 AM
Site:DUP CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 07/14/2016 18:51 BGN90340.2 2
Nitrate 2.4 mg/L EPA 300.0 07/14/2016 18:51 BGN90340.1 1
Nitrate as N 0.54 mg-N/L EPA 300.0 07/14/2016 18:51 BGN90340.023 1
Sulfate 4.6 mg/L EPA 300.0 07/14/2016 18:51 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:53 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.026 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.05 1
Calcium (Ca)45.8 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Iron (Fe)0.016 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.01 1
Magnesium (Mg)9.34 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Manganese (Mn)0.005 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Potassium (K)2.04 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.1 1
Sodium (Na)13.0 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.05 1
Strontium (Sr)0.179 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:50 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Molybdenum (Mo)21.1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA0.2 1
Vanadium (V) Low Level 1.27 ug/L EPA 200.8 07/27/2016 17:11 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 24 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017137
Collection Date:13-Jul-16 11:28 AM
Site:DUP CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 25 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017138
Collection Date:13-Jul-16 11:15 AM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 07/14/2016 18:33 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 07/14/2016 18:33 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 07/14/2016 18:33 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 07/14/2016 18:33 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/23/2016 11:56 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.05 1
Calcium (Ca)0.029 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.05 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/26/2016 10:54 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/27/2016 17:18 JAHERMA0.3 1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 07/19/2016 14:50 PARMSTR251
Duke Energy Analytical Lab
Page 26 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
2016017138
Collection Date:13-Jul-16 11:15 AM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Duke Energy Analytical Lab
Page 27 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070299 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride -0.0034 mg/L -1-0.0034 0.1 < 1/2 RDL
Nitrate 0.0497 mg/L -10.0497 0.1 < 1/2 RDL
Sulfate -0.0384 mg/L -1-0.0384 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.8 5 91.2mg/L -1208016.8
Nitrate 4.63 5 91.7mg/L -1208014.63
Sulfate 5.32 5 92.1mg/L -1208015.32
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.89 5 93 1.9mg/L -1208016.89
Nitrate 4.66 5 92.3 0.644mg/L -1208014.66
Sulfate 5.4 5 93.6 1.69mg/L -1208015.4
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 9.2 5 94mg/L -1208019.2
Nitrate 6.18 5 99.2mg/L -1208016.18
Sulfate 7.69 5 95.4mg/L -1208017.69
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 9.2 5 93.9 0.0937mg/L -1208019.2
Nitrate 6.18 5 99.2 0.0484mg/L -1208016.18
Sulfate 7.68 5 95.4 0.0273mg/L -1208017.68
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.25 5 105mg/L -1109015.25
Nitrate 5.24 5 105mg/L -1109015.24
Sulfate 5.23 5 105mg/L -1109015.23
Duke Energy Analytical Lab
Page 28 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070592 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.021 ug/L -10.021 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.024 ug/L -10.024 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.025 ug/L -10.025 0.05 = 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.07 1 104ug/L -1307011.07
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.1 1 106 2.38ug/L -1307011.1
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.888 1 87.1ug/L -1307010.888
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.886 1 86.9 0.23ug/L -1307010.886
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 97.8ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.9 2 95ug/L -1158511.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Mercury (Hg) 0.987 1 96.2ug/L -1307010.987
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Mercury (Hg) 0.973 1 94.8 1.47ug/L -1307010.973
Duke Energy Analytical Lab
Page 29 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070602 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000623 mg/L -10.000623 0.005 < 1/2 RDL
Barium (Ba) 0.000029 mg/L -10.000029 0.005 < 1/2 RDL
Boron (B) 0.00227 mg/L -10.00227 0.05 < 1/2 RDL
Calcium (Ca) 0.00233 mg/L -10.00233 0.01 < 1/2 RDL
Chromium (Cr) -0.000022 mg/L -1-0.000022 0.005 < 1/2 RDL
Copper (Cu) 0.000409 mg/L -10.000409 0.005 < 1/2 RDL
Iron (Fe) 0.000433 mg/L -10.000433 0.01 < 1/2 RDL
Magnesium (Mg) -0.00193 mg/L -1-0.00193 0.005 < 1/2 RDL
Manganese (Mn) 0.00008 mg/L -10.00008 0.005 < 1/2 RDL
Nickel (Ni) -0.000225 mg/L -1-0.000225 0.005 < 1/2 RDL
Potassium (K) 0.00667 mg/L -10.00667 0.1 < 1/2 RDL
Sodium (Na) 0.00663 mg/L -10.00663 0.05 < 1/2 RDL
Strontium (Sr) 0.000131 mg/L -10.000131 0.005 < 1/2 RDL
Zinc (Zn) 0.000523 mg/L -10.000523 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.73 5 94.6mg/L -1158514.73
Barium (Ba) 5.05 5 101mg/L -1158515.05
Boron (B) 4.86 5 97.3mg/L -1158514.86
Calcium (Ca) 5 5 100mg/L -1158515
Chromium (Cr) 4.93 5 98.6mg/L -1158514.93
Copper (Cu) 4.91 5 98.2mg/L -1158514.91
Iron (Fe) 5.04 5 101mg/L -1158515.04
Magnesium (Mg) 4.95 5 99.1mg/L -1158514.95
Manganese (Mn) 4.98 5 99.6mg/L -1158514.98
Nickel (Ni) 4.98 5 99.5mg/L -1158514.98
Potassium (K) 4.88 5 97.5mg/L -1158514.88
Sodium (Na) 4.93 5 98.7mg/L -1158514.93
Strontium (Sr) 4.98 5 99.5mg/L -1158514.98
Zinc (Zn) 4.97 5 99.4mg/L -1158514.97
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017127
Aluminum (Al) 4.67 5 92.7mg/L -1307014.67
Barium (Ba) 4.98 5 99.6mg/L -1307014.98
Boron (B) 4.78 5 95.4mg/L -1307014.78
Calcium (Ca) 14.9 5 97.6mg/L -13070114.9
Chromium (Cr) 4.86 5 97.3mg/L -1307014.86
Copper (Cu) 4.85 5 96.9mg/L -1307014.85
Duke Energy Analytical Lab
Page 30 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070602 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017127
Iron (Fe) 5.01 5 99.9mg/L -1307015.01
Magnesium (Mg) 9.13 5 95.6mg/L -1307019.13
Manganese (Mn) 4.9 5 97.9mg/L -1307014.9
Nickel (Ni) 4.88 5 97.5mg/L -1307014.88
Potassium (K) 6.19 5 96.4mg/L -1307016.19
Sodium (Na) 21.9 5 101mg/L -13070121.9
Strontium (Sr) 4.95 5 97.4mg/L -1307014.95
Zinc (Zn) 4.88 5 97.2mg/L -1307014.88
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017127
Aluminum (Al) 4.75 5 94.4 1.77mg/L -1307014.75
Barium (Ba) 5.05 5 101 1.46mg/L -1307015.05
Boron (B) 4.89 5 97.6 2.32mg/L -1307014.89
Calcium (Ca) 15.2 5 104 6.23mg/L -13070115.2
Chromium (Cr) 4.96 5 99.1 1.89mg/L -1307014.96
Copper (Cu) 4.93 5 98.6 1.72mg/L -1307014.93
Iron (Fe) 5.11 5 102 1.9mg/L -1307015.11
Magnesium (Mg) 9.31 5 99.3 3.76mg/L -1307019.31
Manganese (Mn) 4.99 5 99.7 1.82mg/L -1307014.99
Nickel (Ni) 4.97 5 99.4 1.89mg/L -1307014.97
Potassium (K) 6.31 5 98.8 2.42mg/L -1307016.31
Sodium (Na) 22.3 5 108 6.76mg/L -13070122.3
Strontium (Sr) 5.04 5 99.3 1.91mg/L -1307015.04
Zinc (Zn) 4.98 5 99.3 2.08mg/L -1307014.98
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017134
Aluminum (Al) 4.6 5 91.4mg/L -1307014.6
Barium (Ba) 5.04 5 99.7mg/L -1307015.04
Boron (B) 4.85 5 97mg/L -1307014.85
Calcium (Ca) 60.7 5 109mg/L -13070160.7
Chromium (Cr) 4.87 5 97.3mg/L -1307014.87
Copper (Cu) 4.86 5 97.2mg/L -1307014.86
Iron (Fe) 5.77 5 98mg/L -1307015.77
Magnesium (Mg) 12.3 5 98.8mg/L -13070112.3
Manganese (Mn) 5.74 5 97.7mg/L -1307015.74
Nickel (Ni) 4.85 5 96.9mg/L -1307014.85
Potassium (K) 10.6 5 98.5mg/L -13070110.6
Sodium (Na) 23.1 5 97.9mg/L -13070123.1
Duke Energy Analytical Lab
Page 31 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070602 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017134
Strontium (Sr) 5.06 5 97.9mg/L -1307015.06
Zinc (Zn) 4.86 5 97.1mg/L -1307014.86
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017134
Aluminum (Al) 4.63 5 92 0.698mg/L -1307014.63
Barium (Ba) 5.06 5 100 0.48mg/L -1307015.06
Boron (B) 4.86 5 97.1 0.103mg/L -1307014.86
Calcium (Ca) 61.3 5 120 9.27mg/L -13070161.3
Chromium (Cr) 4.91 5 98.1 0.778mg/L -1307014.91
Copper (Cu) 4.87 5 97.5 0.308mg/L -1307014.87
Iron (Fe) 5.8 5 98.8 0.752mg/L -1307015.8
Magnesium (Mg) 12.4 5 101 2.46mg/L -13070112.4
Manganese (Mn) 5.78 5 98.5 0.836mg/L -1307015.78
Nickel (Ni) 4.87 5 97.4 0.453mg/L -1307014.87
Potassium (K) 10.7 5 100 1.61mg/L -13070110.7
Sodium (Na) 23.4 5 103 5.52mg/L -13070123.4
Strontium (Sr) 5.03 5 97.2 0.677mg/L -1307015.03
Zinc (Zn) 4.89 5 97.8 0.739mg/L -1307014.89
Duke Energy Analytical Lab
Page 32 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070608 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.016 ug/L -10.016 1 < 1/2 RDL
Arsenic (As) 0.012 ug/L -10.012 1 < 1/2 RDL
Beryllium (Be) -0.046 ug/L -1-0.046 1 < 1/2 RDL
Cadmium (Cd) 0.003 ug/L -10.003 1 < 1/2 RDL
Cobalt (Co) 0.005 ug/L -10.005 1 < 1/2 RDL
Lead (Pb) 0.005 ug/L -10.005 1 < 1/2 RDL
Molybdenum (Mo) 0.02 ug/L -10.02 1 < 1/2 RDL
Selenium (Se) 0.001 ug/L -10.001 1 < 1/2 RDL
Thallium (Tl) Low Level 0.075 ug/L -10.075 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.021 ug/L -10.021 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 54.9 50 110ug/L -11585154.9
Arsenic (As) 51.3 50 103ug/L -11585151.3
Beryllium (Be) 52.1 50 104ug/L -11585152.1
Cadmium (Cd) 50.4 50 101ug/L -11585150.4
Cobalt (Co) 50.9 50 102ug/L -11585150.9
Lead (Pb) 50.4 50 101ug/L -11585150.4
Molybdenum (Mo) 50.2 50 100ug/L -11585150.2
Selenium (Se) 49.6 50 99.2ug/L -11585149.6
Thallium (Tl) Low Level 49 50 98ug/L -11585149
Vanadium (V) Low Level 49 50 98ug/L -11585149
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017128
Antimony (Sb) 55.9 50 112ug/L -13070155.9
Arsenic (As) 51.6 50 103ug/L -13070151.6
Beryllium (Be) 51.1 50 102ug/L -13070151.1
Cadmium (Cd) 50.4 50 101ug/L -13070150.4
Cobalt (Co) 49.6 50 99.1ug/L -13070149.6
Lead (Pb) 50.7 50 101ug/L -13070150.7
Molybdenum (Mo) 72.5 50 102ug/L -13070172.5
Selenium (Se) 49.5 50 98.7ug/L -13070149.5
Thallium (Tl) Low Level 47.8 50 95.6ug/L -13070147.8
Vanadium (V) Low Level 51.3 50 99.8ug/L -13070151.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017128
Antimony (Sb) 55.3 50 110 1.05ug/L -13070155.3
Duke Energy Analytical Lab
Page 33 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070608 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017128
Arsenic (As) 51 50 102 1.21ug/L -13070151
Beryllium (Be) 53.8 50 108 5.21ug/L -13070153.8
Cadmium (Cd) 50.1 50 100 0.653ug/L -13070150.1
Cobalt (Co) 49.4 50 98.7 0.398ug/L -13070149.4
Lead (Pb) 50.2 50 100 0.94ug/L -13070150.2
Molybdenum (Mo) 71.9 50 101 1.26ug/L -13070171.9
Selenium (Se) 49.1 50 97.9 0.763ug/L -13070149.1
Thallium (Tl) Low Level 49.3 50 98.5 3.02ug/L -13070149.3
Vanadium (V) Low Level 51 50 99.1 0.702ug/L -13070151
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017135
Antimony (Sb) 54.1 50 108ug/L -13070154.1
Arsenic (As) 49.9 50 99.7ug/L -13070149.9
Beryllium (Be) 50.9 50 102ug/L -13070150.9
Cadmium (Cd) 49.6 50 98.9ug/L -13070149.6
Cobalt (Co) 48.9 50 97.7ug/L -13070148.9
Lead (Pb) 49.4 50 98.8ug/L -13070149.4
Molybdenum (Mo) 49.5 50 98.8ug/L -13070149.5
Selenium (Se) 49 50 97.6ug/L -13070149
Thallium (Tl) Low Level 49.8 50 99.6ug/L -13070149.8
Vanadium (V) Low Level 52.8 50 98.4ug/L -13070152.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16060373 -- 2016017135
Antimony (Sb) 54.3 50 108 0.322ug/L -13070154.3
Arsenic (As) 50.1 50 100 0.42ug/L -13070150.1
Beryllium (Be) 52.5 50 105 2.95ug/L -13070152.5
Cadmium (Cd) 49.9 50 99.6 0.683ug/L -13070149.9
Cobalt (Co) 49.2 50 98.2 0.541ug/L -13070149.2
Lead (Pb) 49.7 50 99.4 0.621ug/L -13070149.7
Molybdenum (Mo) 49.8 50 99.5 0.688ug/L -13070149.8
Selenium (Se) 49.1 50 97.9 0.331ug/L -13070149.1
Thallium (Tl) Low Level 50.8 50 102 2.06ug/L -13070150.8
Vanadium (V) Low Level 53.1 50 99 0.669ug/L -13070153.1
Duke Energy Analytical Lab
Page 34 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070446 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060373 -- 2016017136
TDS 1.34mg/L -1375
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060373 -- 2016017137
TDS 4.69mg/L -1218
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16060373 -- 2016017138
TDS 0mg/L -11
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 103mg/L -110901103
Duke Energy Analytical Lab
Page 35 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060373
Q16070396 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060373 -- 2016017127
TSS 10.5mg/L -12
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060373 -- 2016017128
TSS 0mg/L -10
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 102mg/L -11090151.2
Duke Energy Analytical Lab
Page 36 of 61
#=CL#
July 25, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92305207
92305207
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16060373
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 14, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
Duke Energy Analytical Lab
Page 37 of 61
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92305207
J16060373
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 24
Duke Energy Analytical Lab
Page 38 of 61
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92305207
J16060373
Lab ID Sample ID Matrix Date Collected Date Received
92305207001 2016017127 Water 07/13/16 11:46 07/14/16 14:55
92305207002 2016017128 Water 07/13/16 11:28 07/14/16 14:55
92305207003 2016017129 Water 07/13/16 13:29 07/14/16 14:55
92305207004 2016017130 Water 07/13/16 13:09 07/14/16 14:55
92305207005 2016017131 Water 07/13/16 17:35 07/14/16 14:55
92305207006 2016017132 Water 07/13/16 16:38 07/14/16 14:55
92305207007 2016017134 Water 07/13/16 15:23 07/14/16 14:55
92305207008 2016017133 Water 07/13/16 14:22 07/14/16 14:55
92305207009 2016017135 Water 07/13/16 16:40 07/14/16 14:55
92305207010 2016017136 Water 07/13/16 15:41 07/14/16 14:55
92305207011 2016017137 Water 07/13/16 11:28 07/14/16 14:55
92305207012 2016017138 Water 07/13/16 11:15 07/14/16 14:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 24
Duke Energy Analytical Lab
Page 39 of 61
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92305207
J16060373
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92305207001 2016017127 SM 2320B 3 PASI-AKDF
92305207002 2016017128 SM 2320B 3 PASI-AKDF
92305207003 2016017129 SM 2320B 3 PASI-AKDF
92305207004 2016017130 SM 2320B 3 PASI-AKDF
92305207005 2016017131 SM 2320B 3 PASI-AKDF
92305207006 2016017132 SM 2320B 3 PASI-AKDF
92305207007 2016017134 SM 2320B 3 PASI-AKDF
92305207008 2016017133 SM 2320B 3 PASI-AKDF
92305207009 2016017135 SM 2320B 3 PASI-AKDF
92305207010 2016017136 SM 2320B 3 PASI-AKDF
92305207011 2016017137 SM 2320B 3 PASI-AKDF
92305207012 2016017138 SM 2320B 3 PASI-AKDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 24
Duke Energy Analytical Lab
Page 40 of 61
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92305207
J16060373
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92305207001 2016017127
Alkalinity,Bicarbonate (CaCO3)46.0 mg/L 07/17/16 21:355.0SM 2320B
Alkalinity, Total as CaCO3 46.0 mg/L 07/17/16 21:355.0SM 2320B
92305207002 2016017128
Alkalinity,Bicarbonate (CaCO3)169 mg/L 07/17/16 21:475.0SM 2320B
Alkalinity, Total as CaCO3 169 mg/L 07/17/16 21:475.0SM 2320B
92305207003 2016017129
Alkalinity,Bicarbonate (CaCO3)7.2 mg/L 07/17/16 22:005.0SM 2320B
Alkalinity, Total as CaCO3 7.2 mg/L 07/17/16 22:005.0SM 2320B
92305207004 2016017130
Alkalinity,Bicarbonate (CaCO3)112 mg/L 07/17/16 22:115.0SM 2320B
Alkalinity, Total as CaCO3 112 mg/L 07/17/16 22:115.0SM 2320B
92305207005 2016017131
Alkalinity,Bicarbonate (CaCO3)148 mg/L 07/17/16 22:245.0SM 2320B
Alkalinity, Total as CaCO3 148 mg/L 07/17/16 22:245.0SM 2320B
92305207006 2016017132
Alkalinity,Bicarbonate (CaCO3)48.8 mg/L 07/17/16 22:375.0SM 2320B
Alkalinity, Total as CaCO3 48.8 mg/L 07/17/16 22:375.0SM 2320B
92305207007 2016017134
Alkalinity,Bicarbonate (CaCO3)163 mg/L 07/17/16 23:085.0SM 2320B
Alkalinity, Total as CaCO3 163 mg/L 07/17/16 23:085.0SM 2320B
92305207008 2016017133
Alkalinity,Bicarbonate (CaCO3)312 mg/L 07/17/16 23:225.0SM 2320B
Alkalinity, Total as CaCO3 312 mg/L 07/17/16 23:225.0SM 2320B
92305207009 2016017135
Alkalinity,Bicarbonate (CaCO3)53.1 mg/L 07/18/16 12:145.0SM 2320B
Alkalinity, Total as CaCO3 53.1 mg/L 07/18/16 12:145.0SM 2320B
92305207010 2016017136
Alkalinity,Bicarbonate (CaCO3)302 mg/L 07/18/16 12:515.0SM 2320B
Alkalinity, Total as CaCO3 302 mg/L 07/18/16 12:515.0SM 2320B
92305207011 2016017137
Alkalinity,Bicarbonate (CaCO3)172 mg/L 07/18/16 13:085.0SM 2320B
Alkalinity, Total as CaCO3 172 mg/L 07/18/16 13:085.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Duke Energy Analytical Lab
Page 41 of 61
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92305207
J16060373
Method:
Client:Duke Energy
SM 2320B
Date:July 25, 2016
Description:2320B Alkalinity
General Information:
12 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
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Duke Energy Analytical Lab
Page 42 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017127 Lab ID:92305207001 Collected:07/13/16 11:46 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)46.0 mg/L 07/17/16 21:355.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 21:355.0 1
Alkalinity, Total as CaCO3 46.0 mg/L 07/17/16 21:355.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
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Duke Energy Analytical Lab
Page 43 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017128 Lab ID:92305207002 Collected:07/13/16 11:28 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)169 mg/L 07/17/16 21:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 21:475.0 1
Alkalinity, Total as CaCO3 169 mg/L 07/17/16 21:475.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 8 of 24
Duke Energy Analytical Lab
Page 44 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017129 Lab ID:92305207003 Collected:07/13/16 13:29 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.2 mg/L 07/17/16 22:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 22:005.0 1
Alkalinity, Total as CaCO3 7.2 mg/L 07/17/16 22:005.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 9 of 24
Duke Energy Analytical Lab
Page 45 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017130 Lab ID:92305207004 Collected:07/13/16 13:09 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)112 mg/L 07/17/16 22:115.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 22:115.0 1
Alkalinity, Total as CaCO3 112 mg/L 07/17/16 22:115.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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Huntersville, NC 28078
[phone]
Page 10 of 24
Duke Energy Analytical Lab
Page 46 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017131 Lab ID:92305207005 Collected:07/13/16 17:35 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)148 mg/L 07/17/16 22:245.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 22:245.0 1
Alkalinity, Total as CaCO3 148 mg/L 07/17/16 22:245.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 11 of 24
Duke Energy Analytical Lab
Page 47 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017132 Lab ID:92305207006 Collected:07/13/16 16:38 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)48.8 mg/L 07/17/16 22:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 22:375.0 1
Alkalinity, Total as CaCO3 48.8 mg/L 07/17/16 22:375.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 12 of 24
Duke Energy Analytical Lab
Page 48 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017134 Lab ID:92305207007 Collected:07/13/16 15:23 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)163 mg/L 07/17/16 23:085.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 23:085.0 1
Alkalinity, Total as CaCO3 163 mg/L 07/17/16 23:085.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 13 of 24
Duke Energy Analytical Lab
Page 49 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017133 Lab ID:92305207008 Collected:07/13/16 14:22 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)312 mg/L 07/17/16 23:225.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 23:225.0 1
Alkalinity, Total as CaCO3 312 mg/L 07/17/16 23:225.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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Huntersville, NC 28078
[phone]
Page 14 of 24
Duke Energy Analytical Lab
Page 50 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017135 Lab ID:92305207009 Collected:07/13/16 16:40 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)53.1 mg/L 07/18/16 12:145.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/18/16 12:145.0 1
Alkalinity, Total as CaCO3 53.1 mg/L 07/18/16 12:145.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 24
Duke Energy Analytical Lab
Page 51 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017136 Lab ID:92305207010 Collected:07/13/16 15:41 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)302 mg/L 07/18/16 12:515.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/18/16 12:515.0 1
Alkalinity, Total as CaCO3 302 mg/L 07/18/16 12:515.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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Huntersville, NC 28078
[phone]
Page 16 of 24
Duke Energy Analytical Lab
Page 52 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017137 Lab ID:92305207011 Collected:07/13/16 11:28 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)172 mg/L 07/18/16 13:085.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/18/16 13:085.0 1
Alkalinity, Total as CaCO3 172 mg/L 07/18/16 13:085.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 17 of 24
Duke Energy Analytical Lab
Page 53 of 61
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305207
J16060373
Sample:2016017138 Lab ID:92305207012 Collected:07/13/16 11:15 Received:07/14/16 14:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/18/16 13:225.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/18/16 13:225.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/18/16 13:225.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 18 of 24
Duke Energy Analytical Lab
Page 54 of 61
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305207
J16060373
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321478
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92305207001, 92305207002, 92305207003, 92305207004, 92305207005, 92305207006, 92305207007,
92305207008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781661
Associated Lab Samples:92305207001, 92305207002, 92305207003, 92305207004, 92305207005, 92305207006, 92305207007,
92305207008
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/17/16 17:45
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/17/16 17:45
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/17/16 17:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781662LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 52.850 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781663MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305067001
1781664
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 109 80-120114 2 2550113167170
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781665MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305202001
1781666
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 109 80-120106 1 2550133187186
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 19 of 24
Duke Energy Analytical Lab
Page 55 of 61
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305207
J16060373
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321520
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92305207009, 92305207010, 92305207011, 92305207012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781808
Associated Lab Samples:92305207009, 92305207010, 92305207011, 92305207012
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/18/16 11:53
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/18/16 11:53
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/18/16 11:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781809LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.150 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781810MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305207009
1781811
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 93 80-12098 3 255053.1 99.8 102
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781812MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305339005
1781813
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 96 80-120101 1 2550308356358
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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[phone]
Page 20 of 24
Duke Energy Analytical Lab
Page 56 of 61
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92305207
J16060373
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
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[phone]
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Duke Energy Analytical Lab
Page 57 of 61
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92305207
J16060373
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92305207001 3214782016017127SM 2320B
92305207002 3214782016017128SM 2320B
92305207003 3214782016017129SM 2320B
92305207004 3214782016017130SM 2320B
92305207005 3214782016017131SM 2320B
92305207006 3214782016017132SM 2320B
92305207007 3214782016017134SM 2320B
92305207008 3214782016017133SM 2320B
92305207009 3215202016017135SM 2320B
92305207010 3215202016017136SM 2320B
92305207011 3215202016017137SM 2320B
92305207012 3215202016017138SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 04:04 PM
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Duke Energy Analytical Lab
Page 58 of 61
Page 23 of 24
Duke Energy Analytical Lab
Page 59 of 61
Page 24 of 24
Duke Energy Analytical Lab
Page 60 of 61
Duke Energy Analytical Lab
Page 61 of 61