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Home My WebLink AboutNC0038377_J16050271report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J16050271 Project Name:MAYO STEAM - NPDES - AOW Lab Contact:Mary Ann Ogle Date:5/25/2016 Customer Address:Mayo Steam Plant Customer Name(s):Ross Hartfield, Jerry Wylie, Tim Hunsucker, Kathy Webb, Brandon Russo 10660 Boston Road Roxboro,North Carolina 27574 Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Page 1 of 23 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016013289 MAYO STEAM 10-May-16 4:03 PM Kyle Donovan S-10 1 Total Samples Page 2 of 23 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:5/25/2016 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16050271 2016013289 Collection Date:10-May-16 4:03 PM Site:S-10 Matrix:NPDES Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L EPA 1664B 05/12/2016 08:30 CJELLIO51 ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.01 mg-N/L EPA 353.2 05/16/2016 11:15 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 31 mg/L EPA 300.0 05/13/2016 12:24 BGN9034110 Fluoride < 0.1 mg/L EPA 300.0 05/13/2016 12:24 BGN90340.1 1 Sulfate 32 mg/L EPA 300.0 05/13/2016 12:24 BGN9034110 TOTAL DISSOLVED SOLIDS TDS 100 mg/L SM2540C 05/16/2016 14:36 PARMSTR251 TOTAL SUSPENDED SOLIDS TSS 18 mg/L SM2540D 05/16/2016 10:00 PARMSTR51 Page 4 of 23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16050271 Q16050232 1664_SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Oil and Grease mg/L -10 5 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Oil and Grease 36.4 81.2mg/L -11480129.5 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16050155 -- 2016012838 Oil and Grease 32.3 85mg/L -11480128 Page 5 of 23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16050271 Q16050328 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Nitrite + Nitrate (Colorimetric) 0.0003 mg-N/L -10.0003 0.01 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Nitrite + Nitrate (Colorimetric) 0.0001 mg-N/L -10.0001 0.01 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Nitrite + Nitrate (Colorimetric) 0.0014 mg-N/L -10.0014 0.01 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 4 RDL Relative Concentration Nitrite + Nitrate (Colorimetric) 0.0022 mg-N/L -10.0022 0.01 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Nitrite + Nitrate (Colorimetric) 0.301 3.01 100mg-N/L -11090103.01 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Nitrite + Nitrate (Colorimetric) 0.3 3.01 99.6mg-N/L -11090103 Final QualifierDilMeasuredUnits:Parameter LCS # 3 % Recovery LCL UCLSpike Nitrite + Nitrate (Colorimetric) 0.3 3.01 99.5mg-N/L -11090103 Final QualifierDilMeasuredUnits:Parameter LCS # 4 % Recovery LCL UCLSpike Nitrite + Nitrate (Colorimetric) 0.295 3.01 98.1mg-N/L -11090102.95 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16050334 -- 2016013552 Nitrite + Nitrate (Colorimetric) 0.546 0.25 92mg-N/L -1109010.546 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16050334 -- 2016013552 Nitrite + Nitrate (Colorimetric) 0.546 0.25 91.7 0.261mg-N/L -1109010.546 Page 6 of 23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16050271 Q16050328 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J16050334 -- 2016013562 Nitrite + Nitrate (Colorimetric) 0.246 0.25 96.8mg-N/L -1109010.246 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J16050334 -- 2016013562 Nitrite + Nitrate (Colorimetric) 0.244 0.25 96 0.788mg-N/L -1109010.244 Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J16050034 -- 2016012324 Nitrite + Nitrate (Colorimetric) 0.508 0.25 98.2mg-N/L -1109010.508 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J16050034 -- 2016012324 Nitrite + Nitrate (Colorimetric) 0.504 0.25 96.5 1.81mg-N/L -1109010.504 Final QualifierDilMeasuredUnits:Parameter MS # 4 % Recovery LCL UCLSpike Parent Sample: J16050158 -- 2016012847 Nitrite + Nitrate (Colorimetric) 0.248 0.25 95.7mg-N/L -1109010.248 Final QualifierDilMeasuredUnits:Parameter MSD # 4 RPD% Recovery LCL UCLSpike Parent Sample: J16050158 -- 2016012847 Nitrite + Nitrate (Colorimetric) 0.248 0.25 95.4 0.293mg-N/L -1109010.248 Page 7 of 23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16050271 Q16050258 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0125 mg/L -10.0125 0.1 < 1/2 RDL Fluoride 0.0359 mg/L -10.0359 0.1 < 1/2 RDL Sulfate 0.0024 mg/L -10.0024 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 7.62 5 101mg/L -1208017.62 Fluoride 5.09 5 101mg/L -1208015.09 Sulfate 6.74 5 98.2mg/L -1208016.74 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 7.64 5 101 0.307mg/L -1208017.64 Fluoride 5.1 5 101 0.216mg/L -1208015.1 Sulfate 6.75 5 98.4 0.224mg/L -1208016.75 Final QualifierDilMeasuredUnits:Parameter IS # 2 % Recovery LCL UCLSpike Chloride 9.86 5 100mg/L -1208019.86 Fluoride 5.08 5 101mg/L -1208015.08 Sulfate 6.83 5 102mg/L -1208016.83 Final QualifierDilMeasuredUnits:Parameter ISD # 2 RPD% Recovery LCL UCLSpike Chloride 9.83 5 99.3 0.62mg/L -1208019.83 Fluoride 5.09 5 101 0.156mg/L -1208015.09 Sulfate 6.8 5 101 0.547mg/L -1208016.8 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 4.98 5 99.5mg/L -1109014.98 Fluoride 5.09 5 102mg/L -1109015.09 Sulfate 4.99 5 99.9mg/L -1109014.99 Page 8 of 23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16050271 Q16050310 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS mg/L -1-1 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration TDS mg/L -1-1 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J16050324 -- 2016013488 TDS 0.834mg/L -1716 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J16050324 -- 2016013489 TDS 1.64mg/L -1921 Final QualifierDilMeasuredUnits:Parameter Duplicate # 3 RPD Parent Sample: J16050324 -- 2016013490 TDS 1.74mg/L -1399 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 100 96mg/L -11090196 Page 9 of 23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16050271 Q16050303 TSS TOTAL SUSPENDED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TSS mg/L -10 5 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J16050158 -- 2016012847 TSS 7.69mg/L -15.4 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J16050158 -- 2016012848 TSS 0mg/L -10.6 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TSS 50 103mg/L -11090151.6 Page 10 of 23 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle RE13042Lot Number: J16050271Project Number: Mayo NPDES AOWProject Name: 05/18/2016Date Completed: Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 5 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: RE13042 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: Mayo NPDES AOW Project Number: J16050271 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 5 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: RE13042 Project Name: Mayo NPDES AOW Project Number: J16050271 Sample Number Sample ID Matrix Date Sampled Date Received 001 05/10/2016 16032016013289Aqueous 05/12/2016 (1 sample) Page: 3 of 5 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: RE13042 Project Name: Mayo NPDES AOW Project Number: J16050271 Sample Sample ID Matrix Parameter Method Result Q Units Page (0 detections) Page: 4 of 5 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2016013289 RE13042-001 05/10/2016 1603 05/12/2016 Aqueous Project Name: Mayo NPDES AOW Project Number: J16050271 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/17/2016 1845 MJI 13423 1 (Bicarbonate ) SM 2320B-2011 1 05/17/2016 1845 MJI 1 (Carbonate Al) SM 2320B-2011 1 05/17/2016 1845 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page: 5 of 5 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. QC Summary QC Data for Lot Number: RE13042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:RQ13423-001 13423 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 05/17/2016 182710mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RE13042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:RQ13423-002 13423 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 99 05/17/2016 18339910090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RE13042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - Duplicate Batch: Sample ID:RE13042-001DU 13423 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q Analysis Date% RPD % RPD Limit Sample Amount Dil(mg/L)(mg/L) Alkalinity ND 05/17/2016 18490.00 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: RE13042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Chain of Custody and Miscellaneous Documents 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 23 of 23