NC0038377_J16040064report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J16040064
Project Name:MAYO STEAM - NPDES - AOW
Lab Contact:Mary Ann Ogle
Date:4/19/2016
Customer Address:Mayo Steam Plant
Customer Name(s):Ross Hartfield, Tim Hunsucker, Kathy Webb, Brandon Russo
10660 Boston Road
Roxboro,North Carolina 27574
Phone:[phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 55
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016009380 MAYO STEAM 04-Apr-16 3:10 PM Kaitlyn Fox S-05
2016009381 MAYO STEAM 04-Apr-16 1:55 PM Kaitlyn Fox S-08
2016009382 MAYO STEAM 04-Apr-16 12:20 PM Kaitlyn Fox S-01
2016009383 MAYO STEAM 04-Apr-16 11:00 AM Kaitlyn Fox S-02 Dup
2016009384 MAYO STEAM 04-Apr-16 11:00 AM Kaitlyn Fox S-02
2016009385 MAYO STEAM 04-Apr-16 10:20 AM Kaitlyn Fox S-03
2016009386 MAYO STEAM 04-Apr-16 4:50 PM Kaitlyn Fox S-06
2016009387 MAYO STEAM 04-Apr-16 4:05 PM Kaitlyn Fox S-09
2016009388 MAYO STEAM 04-Apr-16 6:20 PM Kaitlyn Fox FIELD BLANK
9 Total Samples
Analytical Lab
Page 2 of 55
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:4/19/2016
Electronic Data Deliverable (EDD) Sent Separatel
Analytical Lab
Page 3 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009380
Collection Date:04-Apr-16 3:10 PM
Site:S-05
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2016 13:41 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 52 mg/L EPA 300.0 04/06/2016 19:31 BGN90342.5 25
Fluoride < 0.5 mg/L EPA 300.0 04/06/2016 19:31 BGN90340.5 5
Sulfate 68 mg/L EPA 300.0 04/06/2016 19:31 BGN90342.5 25
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.080 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.005 1
Barium (Ba)0.053 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.005 1
Boron (B)1.20 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.05 1
Calcium (Ca)34.6 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.01 1
Iron (Fe)0.059 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.01 1
Magnesium (Mg)11.6 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.005 1
Manganese (Mn)0.112 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.005 1
Potassium (K)4.83 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.1 1
Sodium (Na)10.9 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.05 1
Total Hardness (Ca and Mg)134 mg/L
(CaCO3)
EPA 200.7 04/07/2016 15:33 JJMACKE0.19 1
Zinc (Zn)0.005 mg/L EPA 200.7 04/07/2016 15:33 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Arsenic (As)1.97 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Copper (Cu)1.76 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Molybdenum (Mo)15.0 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Nickel (Ni)3.43 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 15:58 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 15:58 MHALL30.2 1
Analytical Lab
Page 4 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009380
Collection Date:04-Apr-16 3:10 PM
Site:S-05
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 7.30 SI Units Field WorkF1
Flow NR cfs Field WorkF1
Specific Conductance 364 uS/cm Field WorkF1
Temperature 17.0 °C Field WorkF1
Turbidity 4.77 NTU Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 5 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009381
Collection Date:04-Apr-16 1:55 PM
Site:S-08
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2016 13:42 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 78 mg/L EPA 300.0 04/06/2016 19:48 BGN9034220
Fluoride < 0.5 mg/L EPA 300.0 04/06/2016 19:48 BGN90340.5 5
Sulfate 55 mg/L EPA 300.0 04/06/2016 19:48 BGN9034220
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.067 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.005 1
Barium (Ba)0.091 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.005 1
Boron (B)1.44 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.05 1
Calcium (Ca)23.6 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.01 1
Iron (Fe)2.25 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.01 1
Magnesium (Mg)16.0 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.005 1
Manganese (Mn)2.26 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.005 1
Potassium (K)2.84 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.1 1
Sodium (Na)21.2 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.05 1
Total Hardness (Ca and Mg)125 mg/L
(CaCO3)
EPA 200.7 04/07/2016 15:45 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2016 15:45 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Nickel (Ni)3.05 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 15:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 15:37 MHALL30.2 1
Analytical Lab
Page 6 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009381
Collection Date:04-Apr-16 1:55 PM
Site:S-08
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
Specific Conductance 419 uS/cm Field WorkF1
pH 6.50 SI Units Field WorkF1
Flow NR cfs Field WorkF1
Turbidity 5.73 NTU Field WorkF1
Temperature 16.0 °C Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS 76 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 7 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009382
Collection Date:04-Apr-16 12:20 PM
Site:S-01
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2016 13:43 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 60 mg/L EPA 300.0 04/06/2016 20:06 BGN90342.5 25
Fluoride < 0.5 mg/L EPA 300.0 04/06/2016 20:06 BGN90340.5 5
Sulfate 44 mg/L EPA 300.0 04/06/2016 20:06 BGN90342.5 25
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.005 1
Barium (Ba)0.137 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.005 1
Boron (B)1.60 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.05 1
Calcium (Ca)23.1 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.01 1
Iron (Fe)13.4 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.01 1
Magnesium (Mg)8.93 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.005 1
Manganese (Mn)3.15 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.005 1
Potassium (K)1.60 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.1 1
Sodium (Na)35.8 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.05 1
Total Hardness (Ca and Mg)94.4 mg/L
(CaCO3)
EPA 200.7 04/07/2016 15:49 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2016 15:49 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Arsenic (As)1.90 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Nickel (Ni)1.08 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 16:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 16:04 MHALL30.2 1
Analytical Lab
Page 8 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009382
Collection Date:04-Apr-16 12:20 PM
Site:S-01
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.30 SI Units Field WorkF1
Turbidity 3.71 NTU Field WorkF1
Flow 1.0 cfs Field WorkF1
Specific Conductance 416 uS/cm Field WorkF1
Temperature 15.0 °C Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 240 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS 6.8 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 9 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009383
Collection Date:04-Apr-16 11:00 AM
Site:S-02 Dup
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.05 mg-N/L EPA 353.2 04/07/2016 13:56 LSTARL10.05 5
INORGANIC IONS BY IC
Chloride 84 mg/L EPA 300.0 04/06/2016 20:23 BGN90342.5 25
Fluoride < 0.5 mg/L EPA 300.0 04/06/2016 20:23 BGN90340.5 5
Sulfate 43 mg/L EPA 300.0 04/06/2016 20:23 BGN90342.5 25
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.005 1
Barium (Ba)0.144 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.005 1
Boron (B)1.64 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.05 1
Calcium (Ca)26.5 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.01 1
Iron (Fe)3.72 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.01 1
Magnesium (Mg)13.1 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.005 1
Manganese (Mn)2.41 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.005 1
Potassium (K)2.57 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.1 1
Sodium (Na)20.6 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.05 1
Total Hardness (Ca and Mg)120 mg/L
(CaCO3)
EPA 200.7 04/07/2016 15:52 JJMACKE0.19 1
Zinc (Zn)0.011 mg/L EPA 200.7 04/07/2016 15:52 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Nickel (Ni)1.81 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 16:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 16:09 MHALL30.2 1
Analytical Lab
Page 10 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009383
Collection Date:04-Apr-16 11:00 AM
Site:S-02 Dup
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
Specific Conductance 414 uS/cm Field WorkF1
pH 6.40 SI Units Field WorkF1
Flow 1.0 cfs Field WorkF1
Turbidity 1.19 NTU Field WorkF1
Temperature 13.0 °C Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 11 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009384
Collection Date:04-Apr-16 11:00 AM
Site:S-02
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.05 mg-N/L EPA 353.2 04/07/2016 14:00 LSTARL10.05 5
INORGANIC IONS BY IC
Chloride 85 mg/L EPA 300.0 04/06/2016 20:41 BGN90342.5 25
Fluoride < 0.5 mg/L EPA 300.0 04/06/2016 20:41 BGN90340.5 5
Sulfate 45 mg/L EPA 300.0 04/06/2016 20:41 BGN90342.5 25
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.005 1
Barium (Ba)0.146 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.005 1
Boron (B)1.66 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.05 1
Calcium (Ca)27.0 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.01 1
Iron (Fe)3.76 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.01 1
Magnesium (Mg)13.2 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.005 1
Manganese (Mn)2.44 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.005 1
Potassium (K)2.62 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.1 1
Sodium (Na)21.1 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.05 1
Total Hardness (Ca and Mg)122 mg/L
(CaCO3)
EPA 200.7 04/07/2016 15:56 JJMACKE0.19 1
Zinc (Zn)0.011 mg/L EPA 200.7 04/07/2016 15:56 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Nickel (Ni)1.84 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 16:14 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 16:14 MHALL30.2 1
Analytical Lab
Page 12 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009384
Collection Date:04-Apr-16 11:00 AM
Site:S-02
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
Specific Conductance 414 uS/cm Field WorkF1
pH 6.40 SI Units Field WorkF1
Flow 1.0 cfs Field WorkF1
Temperature 13.0 °C Field WorkF1
Turbidity 1.19 NTU Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 13 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009385
Collection Date:04-Apr-16 10:20 AM
Site:S-03
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2016 14:01 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 62 mg/L EPA 300.0 04/06/2016 20:58 BGN90342.5 25
Fluoride < 0.5 mg/L EPA 300.0 04/06/2016 20:58 BGN90340.5 5
Sulfate 33 mg/L EPA 300.0 04/06/2016 20:58 BGN90342.5 25
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.046 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.005 1
Barium (Ba)0.054 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.005 1
Boron (B)1.17 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.05 1
Calcium (Ca)25.9 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.01 1
Iron (Fe)0.346 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.01 1
Magnesium (Mg)10.0 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.005 1
Manganese (Mn)0.956 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.005 1
Potassium (K)1.91 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.1 1
Sodium (Na)23.3 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.05 1
Total Hardness (Ca and Mg)106 mg/L
(CaCO3)
EPA 200.7 04/07/2016 16:00 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2016 16:00 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 16:20 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 16:20 MHALL30.2 1
Analytical Lab
Page 14 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009385
Collection Date:04-Apr-16 10:20 AM
Site:S-03
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
Turbidity 4.13 NTU Field WorkF1
Specific Conductance 360 uS/cm Field WorkF1
pH 6.90 SI Units Field WorkF1
Temperature 13.0 °C Field WorkF1
Flow 0.37000 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 15 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009386
Collection Date:04-Apr-16 4:50 PM
Site:S-06
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2016 14:02 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 8.3 mg/L EPA 300.0 04/06/2016 21:16 BGN90340.1 1
Fluoride 0.12 mg/L EPA 300.0 04/06/2016 21:16 BGN90340.1 1
Sulfate 6.9 mg/L EPA 300.0 04/06/2016 21:16 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.267 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.005 1
Barium (Ba)0.024 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.05 1
Calcium (Ca)8.72 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.01 1
Iron (Fe)0.627 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.01 1
Magnesium (Mg)3.59 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.005 1
Manganese (Mn)0.151 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.005 1
Potassium (K)1.40 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.1 1
Sodium (Na)10.2 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.05 1
Total Hardness (Ca and Mg)36.6 mg/L
(CaCO3)
EPA 200.7 04/07/2016 16:04 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2016 16:04 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 16:25 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 16:25 MHALL30.2 1
Analytical Lab
Page 16 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009386
Collection Date:04-Apr-16 4:50 PM
Site:S-06
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
Temperature 19.0 °C Field WorkF1
Turbidity 6.60 NTU Field WorkF1
Flow 0.40000 cfs Field WorkF1
pH 7.10 SI Units Field WorkF1
Specific Conductance 124 uS/cm Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 96 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 17 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009387
Collection Date:04-Apr-16 4:05 PM
Site:S-09
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2016 14:03 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 21 mg/L EPA 300.0 04/06/2016 21:33 BGN90340.5 5
Fluoride 0.16 mg/L EPA 300.0 04/06/2016 21:33 BGN90340.1 1
Sulfate 9.2 mg/L EPA 300.0 04/06/2016 21:33 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.023 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.005 1
Barium (Ba)0.065 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.05 1
Calcium (Ca)24.3 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.01 1
Iron (Fe)11.1 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.01 1
Magnesium (Mg)9.23 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.005 1
Manganese (Mn)2.14 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.005 1
Potassium (K)1.04 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.1 1
Sodium (Na)25.2 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.05 1
Total Hardness (Ca and Mg)98.7 mg/L
(CaCO3)
EPA 200.7 04/07/2016 16:08 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2016 16:08 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Nickel (Ni)3.25 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 16:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 16:31 MHALL30.2 1
Analytical Lab
Page 18 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009387
Collection Date:04-Apr-16 4:05 PM
Site:S-09
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Field Parameters (certification not covered under DPAL certification)
pH 6.00 SI Units Field WorkF1
Turbidity 1.54 NTU Field WorkF1
Specific Conductance 339 uS/cm Field WorkF1
Temperature 18.0 °C Field WorkF1
Flow 0.13000 cfs Field WorkF1
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Analytical Lab
Page 19 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009388
Collection Date:04-Apr-16 6:20 PM
Site:FIELD BLANK
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2016 14:05 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/06/2016 16:02 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 04/06/2016 16:02 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 04/06/2016 16:02 BGN90340.1 1
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.05 1
Calcium (Ca)0.018 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.01 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.05 1
Total Hardness (Ca and Mg)< 0.19 mg/L
(CaCO3)
EPA 200.7 04/07/2016 16:13 JJMACKE0.19 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2016 16:13 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/07/2016 16:36 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/07/2016 16:36 MHALL30.2 1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
Analytical Lab
Page 20 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
2016009388
Collection Date:04-Apr-16 6:20 PM
Site:FIELD BLANK
Matrix:NPDES
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Qualifiers:
F Field Parameters are not covered under the DPAL certification. If certification is required for these parameters
please request field certificates from the samplers. This data is provided at the request of the client.
Analytical Lab
Page 21 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040116 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.242 1.25 99.6mg-N/L -51.21
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.248 1.25 102 2.42mg-N/L -51.24
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.221 1.25 92mg-N/L -51.11
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.219 1.25 91.2 0.917mg-N/L -51.1
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.314 3.01 104mg-N/L -11090103.14
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.302 3.01 100mg-N/L -11090103.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.304 3.01 101mg-N/L -11090103.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.303 3.01 101mg-N/L -11090103.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040092 -- 2016009555
Nitrite + Nitrate
(Colorimetric)
0.301 0.25 100mg-N/L -1109010.301
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040092 -- 2016009555
Nitrite + Nitrate
(Colorimetric)
0.295 0.25 97.9 2.46mg-N/L -1109010.295
Analytical Lab
Page 22 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040116 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16030630 -- 2016008442
Nitrite + Nitrate
(Colorimetric)
0.536 0.25 95.1mg-N/L -1109010.536
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16030630 -- 2016008442
Nitrite + Nitrate
(Colorimetric)
0.542 0.25 97.6 2.66mg-N/L -1109010.542
Analytical Lab
Page 23 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040087 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0261 mg/L -10.0261 0.1 < 1/2 RDL
Fluoride 0.041 mg/L -10.041 0.1 < 1/2 RDL
Sulfate 0.0026 mg/L -10.0026 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.7 5 104mg/L -1208015.7
Fluoride 5.45 5 108mg/L -1208015.45
Sulfate 8.63 5 106mg/L -1208018.63
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.68 5 103 0.358mg/L -1208015.68
Fluoride 5.46 5 108 0.206mg/L -1208015.46
Sulfate 8.63 5 106 0.0885mg/L -1208018.63
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.98 5 101mg/L -1208018.98
Fluoride 5.38 5 106mg/L -1208015.38
Sulfate 7.11 5 100mg/L -1208017.11
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.89 5 99.3 1.71mg/L -1208018.89
Fluoride 5.39 5 107 0.298mg/L -1208015.39
Sulfate 7.12 5 100 0.176mg/L -1208017.12
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.04 5 101mg/L -1109015.04
Fluoride 5.35 5 107mg/L -1109015.35
Sulfate 5.04 5 101mg/L -1109015.04
Analytical Lab
Page 24 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040108 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00242 mg/L -10.00242 0.005 < 1/2 RDL
Barium (Ba) 0.000123 mg/L -10.000123 0.005 < 1/2 RDL
Boron (B) 0.00325 mg/L -10.00325 0.05 < 1/2 RDL
Calcium (Ca) 0.00572 mg/L -10.00572 0.01 > 1/2 RDL
Iron (Fe) 0.000105 mg/L -10.000105 0.01 < 1/2 RDL
Magnesium (Mg) 0.000197 mg/L -10.000197 0.005 < 1/2 RDL
Manganese (Mn) -0.000318 mg/L -1-0.000318 0.005 < 1/2 RDL
Potassium (K) -0.00765 mg/L -1-0.00765 0.1 < 1/2 RDL
Sodium (Na) -0.0051 mg/L -1-0.0051 0.05 < 1/2 RDL
Zinc (Zn) 0.000332 mg/L -10.000332 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.12 5 102mg/L -1158515.12
Barium (Ba) 5.02 5 100mg/L -1158515.02
Boron (B) 4.79 5 95.9mg/L -1158514.79
Calcium (Ca) 4.68 5 93.6mg/L -1158514.68
Iron (Fe) 4.8 5 96.1mg/L -1158514.8
Magnesium (Mg) 4.99 5 99.8mg/L -1158514.99
Manganese (Mn) 5.06 5 101mg/L -1158515.06
Potassium (K) 4.95 5 99.1mg/L -1158514.95
Sodium (Na) 4.98 5 99.6mg/L -1158514.98
Zinc (Zn) 4.88 5 97.6mg/L -1158514.88
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040064 -- 2016009380
Aluminum (Al) 5.28 5 104mg/L -1307015.28
Barium (Ba) 5.17 5 102mg/L -1307015.17
Boron (B) 5.89 5 93.8mg/L -1307015.89
Calcium (Ca) 38.5 5 77.6mg/L -13070138.5
Iron (Fe) 4.9 5 96.9mg/L -1307014.9
Magnesium (Mg) 15.8 5 83.8mg/L -13070115.8
Manganese (Mn) 5.21 5 102mg/L -1307015.21
Potassium (K) 9.64 5 96.2mg/L -1307019.64
Sodium (Na) 15.9 5 102mg/L -13070115.9
Zinc (Zn) 4.85 5 96.9mg/L -1307014.85
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040064 -- 2016009380
Aluminum (Al) 5.21 5 103 1.34mg/L -1307015.21
Analytical Lab
Page 25 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040108 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040064 -- 2016009380
Barium (Ba) 5.11 5 101 1.22mg/L -1307015.11
Boron (B) 5.9 5 94.1 0.298mg/L -1307015.9
Calcium (Ca) 38.7 5 82.4 6.03mg/L -13070138.7
Iron (Fe) 4.88 5 96.3 0.559mg/L -1307014.88
Magnesium (Mg) 15.8 5 85.4 1.82mg/L -13070115.8
Manganese (Mn) 5.15 5 101 1.26mg/L -1307015.15
Potassium (K) 9.6 5 95.3 0.94mg/L -1307019.6
Sodium (Na) 15.8 5 99.3 2.25mg/L -13070115.8
Zinc (Zn) 4.84 5 96.6 0.248mg/L -1307014.84
Analytical Lab
Page 26 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040111 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0328 ug/L -1-0.0328 1 < 1/2 RDL
Arsenic (As) -0.0009 ug/L -1-0.0009 1 < 1/2 RDL
Cadmium (Cd) -0.0007 ug/L -1-0.0007 1 < 1/2 RDL
Chromium (Cr) -0.0289 ug/L -1-0.0289 1 < 1/2 RDL
Copper (Cu) -0.0141 ug/L -1-0.0141 1 < 1/2 RDL
Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL
Molybdenum (Mo) 0.0012 ug/L -10.0012 1 < 1/2 RDL
Nickel (Ni) 0.0079 ug/L -10.0079 1 < 1/2 RDL
Selenium (Se) 0.155 ug/L -10.155 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0484 ug/L -1-0.0484 0.2 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 52.6 50 105ug/L -11585152.6
Arsenic (As) 48.3 50 96.6ug/L -11585148.3
Cadmium (Cd) 50.5 50 101ug/L -11585150.5
Chromium (Cr) 52.3 50 105ug/L -11585152.3
Copper (Cu) 49.3 50 98.5ug/L -11585149.3
Lead (Pb) 49.8 50 99.7ug/L -11585149.8
Molybdenum (Mo) 49.4 50 98.7ug/L -11585149.4
Nickel (Ni) 48.6 50 97.1ug/L -11585148.6
Selenium (Se) 49.3 50 98.7ug/L -11585149.3
Thallium (Tl) Low Level 52.1 50 104ug/L -11585152.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040064 -- 2016009381
Antimony (Sb) 55.4 50 111ug/L -13070155.4
Arsenic (As) 49.7 50 98.7ug/L -13070149.7
Cadmium (Cd) 50.7 50 101ug/L -13070150.7
Chromium (Cr) 51.4 50 103ug/L -13070151.4
Copper (Cu) 48.2 50 96.1ug/L -13070148.2
Lead (Pb) 50.7 50 101ug/L -13070150.7
Molybdenum (Mo) 50.9 50 101ug/L -13070150.9
Nickel (Ni) 50.8 50 95.5ug/L -13070150.8
Selenium (Se) 49.2 50 97.9ug/L -13070149.2
Thallium (Tl) Low Level 51.1 50 102ug/L -13070151.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040064 -- 2016009381
Antimony (Sb) 54.5 50 109 1.5ug/L -13070154.5
Analytical Lab
Page 27 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040111 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040064 -- 2016009381
Arsenic (As) 49.4 50 98.2 0.507ug/L -13070149.4
Cadmium (Cd) 50.6 50 101 0.132ug/L -13070150.6
Chromium (Cr) 51.5 50 103 0.148ug/L -13070151.5
Copper (Cu) 47.7 50 95.2 0.95ug/L -13070147.7
Lead (Pb) 50.7 50 101 0.0484ug/L -13070150.7
Molybdenum (Mo) 50.7 50 101 0.308ug/L -13070150.7
Nickel (Ni) 49.8 50 93.6 2.02ug/L -13070149.8
Selenium (Se) 49.7 50 98.9 1.05ug/L -13070149.7
Thallium (Tl) Low Level 50.7 50 101 0.852ug/L -13070150.7
Analytical Lab
Page 28 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040115 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030638 -- 2016008499
TDS 3.28mg/L -1120
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030638 -- 2016008502
TDS 0.708mg/L -1425
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16030638 -- 2016008503
TDS 2.17mg/L -1140
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 98mg/L -11090198
Analytical Lab
Page 29 of 55
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040064
Q16040066 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030316 -- 2016007139
TSS 0mg/L -17.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 93.6mg/L -146.8
Analytical Lab
Page 30 of 55
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
RD08039Lot Number:
J16040064Project Number:
NPDES - AOWProject Name:
04/14/2016Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: RD08039
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: NPDES - AOW
Project Number: J16040064
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 14
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: RD08039

Project Name: NPDES - AOW
Project Number: J16040064
Sample Number Sample ID Matrix Date Sampled Date Received
001 04/04/2016 15102016009380Aqueous 04/08/2016
002 04/04/2016 13552016009381Aqueous 04/08/2016
003 04/04/2016 12202016009382Aqueous 04/08/2016
004 04/04/2016 11002016009383Aqueous 04/08/2016
005 04/04/2016 11002016009384Aqueous 04/08/2016
006 04/04/2016 10202016009385Aqueous 04/08/2016
007 04/04/2016 16502016009386Aqueous 04/08/2016
008 04/04/2016 16052016009387Aqueous 04/08/2016
009 04/04/2016 18202016009388Aqueous 04/08/2016
(9 samples)
Page: 3 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: RD08039

Project Name: NPDES - AOW
Project Number: J16040064
Sample Sample ID Matrix Parameter Method Result Q Units Page
006 2016009385 Aqueous Mercury (CVAFS)1631E 2.79 ng/L 10
007 2016009386 Aqueous Mercury (CVAFS)1631E 1.75 ng/L 11
(2 detections)
Page: 4 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009380
RD08039-001
04/04/2016 1510
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 1959 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009381
RD08039-002
04/04/2016 1355
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2014 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009382
RD08039-003
04/04/2016 1220
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2020 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 14
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009383
RD08039-004
04/04/2016 1100
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2025 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 14
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009384
RD08039-005
04/04/2016 1100
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2030 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009385
RD08039-006
04/04/2016 1020
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2036 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 2.79 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 14
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009386
RD08039-007
04/04/2016 1650
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2041 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E 1.75 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 11 of 14
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009387
RD08039-008
04/04/2016 1605
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2046 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 12 of 14
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009388
RD08039-009
04/04/2016 1820
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 04/12/2016 1858 MJI 10764
1 (Bicarbonate ) SM 2320B-2011 1 04/12/2016 1858 MJI
1 (Carbonate Al) SM 2320B-2011 1 04/12/2016 1858 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 13 of 14
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Shealy Environmental Services, Inc.

Mercury (CVAFS)
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2016009388
RD08039-009
04/04/2016 1820
04/08/2016
Aqueous
Project Name: NPDES - AOW
Project Number: J16040064
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 04/13/2016 2101 COH 04/11/2016 1103 10535
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 14 of 14
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Shealy Environmental Services, Inc.

QC Summary
QC Data for Lot Number: RD08039
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Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:RQ10764-001
10764
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 04/12/2016 175910mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RD08039
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Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:RQ10764-002
10764
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 100 04/12/2016 180510110090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RD08039
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Shealy Environmental Services, Inc.

Mercury (CVAFS) - MB
Batch:Prep Method:
Prep Date:
Sample ID:RQ10535-001
10535 1631E
04/11/2016 1103Analytical Method:1631E
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Mercury (CVAFS)ND 04/13/2016 19390.500 ng/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RD08039
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Shealy Environmental Services, Inc.

Mercury (CVAFS) - LCS
Batch:Prep Method:
Prep Date:
Sample ID:RQ10535-002
10535 1631E
04/11/2016 1103Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ng/L)(ng/L)
Mercury (CVAFS)5.07 04/13/2016 19441015.00 75-1251
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RD08039
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Shealy Environmental Services, Inc.

Mercury (CVAFS) - MS
Batch:Prep Method:
Prep Date:
Sample ID:RD08039-001MS
10535 1631E
04/11/2016 1103Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(ng/L)(ng/L)(ng/L)
Mercury (CVAFS)4.75 04/13/2016 2004955.00 71-125ND1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RD08039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Mercury (CVAFS) - MSD
Batch:Prep Method:
Prep Date:
Sample ID:RD08039-001MD
10535 1631E
04/11/2016 1103Analytical Method:1631E
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
Limit
Sample
Amount
Dil(ng/L)(ng/L)(ng/L)
Mercury (CVAFS)4.44 04/13/2016 2009895.00 71-1256.7 24ND1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: RD08039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Chain of Custody
and
Miscellaneous Documents
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Analytical Lab
Page 55 of 55