NC0038377_J16030157-F_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16030157
Project Name:MAYO STEAM - ABGW
Lab Contact:Peggy Kendall
Date:4/15/2016
Customer Address:Mayo Steam Plant
Customer Name(s):J. TOEPFER, T. HUNSUCKER
10660 Boston Road
Roxboro,North Carolina 27574
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 78
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016006339 MAYO STEAM 04-Apr-16 5:05 PM Synterra CW-1
2016006340 MAYO STEAM 04-Apr-16 5:08 PM Synterra CW-1D
2016006341 MAYO STEAM 04-Apr-16 3:24 PM Synterra CW-2
2016006342 MAYO STEAM 04-Apr-16 3:03 PM Synterra CW-2D
2016006343 MAYO STEAM 05-Apr-16 9:15 AM Synterra CW-3
2016006344 MAYO STEAM 05-Apr-16 10:13 AM Synterra CW-4
2016006345 MAYO STEAM 05-Apr-16 9:38 AM Synterra CW-5
2016006346 MAYO STEAM 04-Apr-16 4:07 PM Synterra CW-6
2016006347 MAYO STEAM 04-Apr-16 2:07 PM Synterra BG-1
2016006348 MAYO STEAM 04-Apr-16 3:32 PM Synterra BG-2
2016006349 MAYO STEAM 04-Apr-16 4:07 PM Synterra DUP CW-6
2016006350 MAYO STEAM 05-Apr-16 4:36 PM Synterra FIELD BLANK
12 Total Samples
Page 2 of 78
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/14/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006339
Collection Date:04-Apr-16 5:05 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 24 mg/L EPA 300.0 04/05/2016 19:15 BGN90340.5 5
Nitrate 7.3 mg/L EPA 300.0 04/05/2016 19:15 BGN90340.1 1
Nitrate as N 1.7 mg-N/L EPA 300.0 04/05/2016 19:15 BGN90340.023 1
Sulfate 12 mg/L EPA 300.0 04/05/2016 19:15 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:20 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.995 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.05 1
Calcium (Ca)11.1 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Iron (Fe)0.366 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.01 1
Magnesium (Mg)5.63 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Manganese (Mn)0.013 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Potassium (K)1.18 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.1 1
Sodium (Na)18.2 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.05 1
Strontium (Sr)0.089 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 04/06/2016 13:15 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 20:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 20:31 MHALL30.2 1
Vanadium (V) Low Level 1.10 ug/L EPA 200.8 04/06/2016 20:31 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 4 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006339
Collection Date:04-Apr-16 5:05 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 5 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006340
Collection Date:04-Apr-16 5:08 PM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 04/05/2016 18:41 BGN90340.2 2
Nitrate 2.6 mg/L EPA 300.0 04/05/2016 18:41 BGN90340.1 1
Nitrate as N 0.58 mg-N/L EPA 300.0 04/05/2016 18:41 BGN90340.023 1
Sulfate 5.0 mg/L EPA 300.0 04/05/2016 18:41 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:23 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.071 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.05 1
Calcium (Ca)41.1 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Iron (Fe)0.040 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.01 1
Magnesium (Mg)9.12 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Manganese (Mn)0.013 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Potassium (K)2.00 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.1 1
Sodium (Na)12.3 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.05 1
Strontium (Sr)0.167 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/06/2016 13:19 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Molybdenum (Mo)21.6 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 20:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 20:37 MHALL30.2 1
Vanadium (V) Low Level 1.10 ug/L EPA 200.8 04/06/2016 20:37 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 6 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006340
Collection Date:04-Apr-16 5:08 PM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 7 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006341
Collection Date:04-Apr-16 3:24 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 40 mg/L EPA 300.0 04/05/2016 19:50 BGN9034110
Nitrate < 0.1 mg/L EPA 300.0 04/05/2016 19:50 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/05/2016 19:50 BGN90340.023 1
Sulfate 33 mg/L EPA 300.0 04/05/2016 19:50 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:25 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Barium (Ba)0.102 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Boron (B)0.562 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.05 1
Calcium (Ca)12.9 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.01 1
Magnesium (Mg)6.80 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Manganese (Mn)0.127 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Potassium (K)1.72 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.1 1
Sodium (Na)12.9 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.05 1
Strontium (Sr)0.178 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 04/06/2016 13:23 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 20:42 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 20:42 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2016 20:42 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 8 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006341
Collection Date:04-Apr-16 3:24 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 9 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006342
Collection Date:04-Apr-16 3:03 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 53 mg/L EPA 300.0 04/05/2016 20:08 BGN9034110
Nitrate 0.11 mg/L EPA 300.0 04/05/2016 20:08 BGN90340.1 1
Nitrate as N 0.02 mg-N/L EPA 300.0 04/05/2016 20:08 BGN90340.023 1
Sulfate 46 mg/L EPA 300.0 04/05/2016 20:08 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:28 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.390 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Barium (Ba)0.048 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Boron (B)0.428 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.05 1
Calcium (Ca)28.7 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Iron (Fe)0.191 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.01 1
Magnesium (Mg)7.80 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Manganese (Mn)0.092 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Potassium (K)2.67 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.1 1
Sodium (Na)19.0 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.05 1
Strontium (Sr)0.263 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 04/06/2016 13:26 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 20:47 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 20:47 MHALL30.2 1
Vanadium (V) Low Level 0.377 ug/L EPA 200.8 04/06/2016 20:47 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 240 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 10 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006342
Collection Date:04-Apr-16 3:03 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 7.6 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 11 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006343
Collection Date:05-Apr-16 9:15 AM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 100 mg/L EPA 300.0 04/06/2016 13:45 BGN9034220
Nitrate 1.3 mg/L EPA 300.0 04/06/2016 13:45 BGN90340.1 1
Nitrate as N 0.29 mg-N/L EPA 300.0 04/06/2016 13:45 BGN90340.023 1
Sulfate 16 mg/L EPA 300.0 04/06/2016 13:45 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:30 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Barium (Ba)0.018 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.05 1
Calcium (Ca)64.2 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.01 1
Magnesium (Mg)7.81 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Manganese (Mn)0.034 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Potassium (K)4.38 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.1 1
Sodium (Na)42.1 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.05 1
Strontium (Sr)0.321 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/08/2016 13:10 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 19:50 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 19:50 MHALL30.2 1
Vanadium (V) Low Level 1.23 ug/L EPA 200.8 04/10/2016 19:50 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 390 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
Page 12 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006343
Collection Date:05-Apr-16 9:15 AM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/07/2016 10:48 PARMSTR51
Page 13 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006344
Collection Date:05-Apr-16 10:13 AM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.6 mg/L EPA 300.0 04/06/2016 14:19 BGN90340.5 5
Nitrate 0.59 mg/L EPA 300.0 04/06/2016 14:19 BGN90340.1 1
Nitrate as N 0.13 mg-N/L EPA 300.0 04/06/2016 14:19 BGN90340.023 1
Sulfate 20 mg/L EPA 300.0 04/06/2016 14:19 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:33 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.121 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.05 1
Calcium (Ca)10.8 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Iron (Fe)0.058 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.01 1
Magnesium (Mg)3.00 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Manganese (Mn)0.007 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Potassium (K)1.18 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.1 1
Sodium (Na)15.6 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.05 1
Strontium (Sr)0.116 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/08/2016 13:14 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 19:56 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 19:56 MHALL30.2 1
Vanadium (V) Low Level 0.888 ug/L EPA 200.8 04/10/2016 19:56 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
Page 14 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006344
Collection Date:05-Apr-16 10:13 AM
Site:CW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/07/2016 10:48 PARMSTR51
Page 15 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006345
Collection Date:05-Apr-16 9:38 AM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 39 mg/L EPA 300.0 04/06/2016 14:36 BGN90340.5 5
Nitrate 0.13 mg/L EPA 300.0 04/06/2016 14:36 BGN90340.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 04/06/2016 14:36 BGN90340.023 1
Sulfate 7.0 mg/L EPA 300.0 04/06/2016 14:36 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:35 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Barium (Ba)0.047 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.05 1
Calcium (Ca)55.5 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Iron (Fe)0.513 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.01 1
Magnesium (Mg)7.46 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Manganese (Mn)0.380 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Potassium (K)5.76 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.1 1
Sodium (Na)18.4 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.05 1
Strontium (Sr)0.161 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/08/2016 13:18 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 20:01 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 20:01 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 20:01 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 270 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
Page 16 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006345
Collection Date:05-Apr-16 9:38 AM
Site:CW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 04/07/2016 10:48 PARMSTR51
Page 17 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006346
Collection Date:04-Apr-16 4:07 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 97 mg/L EPA 300.0 04/05/2016 20:25 BGN9034220
Nitrate < 0.1 mg/L EPA 300.0 04/05/2016 20:25 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/05/2016 20:25 BGN90340.023 1
Sulfate 41 mg/L EPA 300.0 04/05/2016 20:25 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:37 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Barium (Ba)0.045 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.05 1
Calcium (Ca)102 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Iron (Fe)1.86 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.01 1
Magnesium (Mg)20.1 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Manganese (Mn)1.42 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Potassium (K)10.7 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.1 1
Sodium (Na)38.4 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.05 1
Strontium (Sr)0.338 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/06/2016 13:30 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Molybdenum (Mo)3.69 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 20:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 20:53 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2016 20:53 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 540 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 18 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006346
Collection Date:04-Apr-16 4:07 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 19 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006347
Collection Date:04-Apr-16 2:07 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 04/05/2016 18:58 BGN90340.2 2
Nitrate 3.3 mg/L EPA 300.0 04/05/2016 18:58 BGN90340.1 1
Nitrate as N 0.75 mg-N/L EPA 300.0 04/05/2016 18:58 BGN90340.023 1
Sulfate 0.25 mg/L EPA 300.0 04/05/2016 18:58 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:40 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.177 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Barium (Ba)0.088 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.05 1
Calcium (Ca)12.1 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Iron (Fe)0.190 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.01 1
Magnesium (Mg)3.20 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Manganese (Mn)0.012 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Potassium (K)1.36 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.1 1
Sodium (Na)11.5 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.05 1
Strontium (Sr)0.167 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 04/06/2016 13:34 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 20:58 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 20:58 MHALL30.2 1
Vanadium (V) Low Level 3.94 ug/L EPA 200.8 04/06/2016 20:58 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 20 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006347
Collection Date:04-Apr-16 2:07 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 21 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006348
Collection Date:04-Apr-16 3:32 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 30 mg/L EPA 300.0 04/05/2016 19:33 BGN90340.5 5
Nitrate < 0.1 mg/L EPA 300.0 04/05/2016 19:33 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/05/2016 19:33 BGN90340.023 1
Sulfate 4.9 mg/L EPA 300.0 04/05/2016 19:33 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:54 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.065 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Barium (Ba)0.065 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.05 1
Calcium (Ca)59.2 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Iron (Fe)0.585 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.01 1
Magnesium (Mg)13.9 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Manganese (Mn)0.237 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Potassium (K)3.34 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.1 1
Sodium (Na)56.0 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.05 1
Strontium (Sr)0.391 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/06/2016 13:03 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 21:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 21:04 MHALL30.2 1
Vanadium (V) Low Level 5.00 ug/L EPA 200.8 04/06/2016 21:04 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 360 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 22 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006348
Collection Date:04-Apr-16 3:32 PM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 24 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 23 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006349
Collection Date:04-Apr-16 4:07 PM
Site:DUP CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 98 mg/L EPA 300.0 04/05/2016 20:42 BGN9034220
Nitrate < 0.1 mg/L EPA 300.0 04/05/2016 20:42 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/05/2016 20:42 BGN90340.023 1
Sulfate 41 mg/L EPA 300.0 04/05/2016 20:42 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:57 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.019 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Barium (Ba)0.046 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.05 1
Calcium (Ca)104 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Iron (Fe)1.90 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.01 1
Magnesium (Mg)20.4 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Manganese (Mn)1.45 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Potassium (K)10.9 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.1 1
Sodium (Na)39.0 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.05 1
Strontium (Sr)0.344 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/06/2016 13:38 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Molybdenum (Mo)3.59 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/06/2016 21:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/06/2016 21:09 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/06/2016 21:09 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS 560 mg/L SM2540C 04/06/2016 14:30 PARMSTR251
Page 24 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006349
Collection Date:04-Apr-16 4:07 PM
Site:DUP CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/06/2015 10:53 PARMSTR51
Page 25 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006350
Collection Date:05-Apr-16 4:36 PM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/06/2016 12:35 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 04/06/2016 12:35 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 04/06/2016 12:35 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 04/06/2016 12:35 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2016 09:59 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.05 1
Calcium (Ca)< 0.01 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.05 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/08/2016 13:22 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 20:07 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 20:07 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 20:07 MHALL30.3 1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/07/2016 14:22 PARMSTR251
Page 26 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
2016006350
Collection Date:05-Apr-16 4:36 PM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/07/2016 10:48 PARMSTR51
Page 27 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040052 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0291 mg/L -10.0291 0.1 < 1/2 RDL
Nitrate 0.0068 mg/L -10.0068 0.1 < 1/2 RDL
Sulfate 0.016 mg/L -10.016 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 9.87 5 102mg/L -1208019.87
Nitrate 6.56 5 103mg/L -1208016.56
Sulfate 7.48 5 102mg/L -1208017.48
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 9.81 5 101 1.15mg/L -1208019.81
Nitrate 6.55 5 103 0.221mg/L -1208016.55
Sulfate 7.47 5 102 0.116mg/L -1208017.47
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.03 5 101mg/L -1109015.03
Nitrate 4.97 5 99.4mg/L -1109014.97
Sulfate 4.96 5 99.1mg/L -1109014.96
Page 28 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040072 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0261 mg/L -10.0261 0.1 < 1/2 RDL
Nitrate 0.0117 mg/L -10.0117 0.1 < 1/2 RDL
Sulfate 0.0026 mg/L -10.0026 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.3 5 103mg/L -1208015.3
Nitrate 9.14 5 103mg/L -1208019.14
Sulfate 7.01 5 102mg/L -1208017.01
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.27 5 102 0.588mg/L -1208015.27
Nitrate 9.14 5 103 0.0117mg/L -1208019.14
Sulfate 7.01 5 102 0.0666mg/L -1208017.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.04 5 101mg/L -1109015.04
Nitrate 5.02 5 100mg/L -1109015.02
Sulfate 5.04 5 101mg/L -1109015.04
Page 29 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040114 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.018 ug/L -1-0.018 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.012 ug/L -1-0.012 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.815 20 83.6ug/L -130702016.3
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.807 20 82.9 0.841ug/L -130702016.1
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.951 100 96.6ug/L -1307010095.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.955 100 97 0.403ug/L -1307010095.5
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.02 2 101ug/L -1158512.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2.01 2 101ug/L -1158512.01
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030482 -- 2016007816
Mercury (Hg) 0.988 1 100ug/L -1307010.988
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030482 -- 2016007816
Mercury (Hg) 0.972 1 98.6 1.61ug/L -1307010.972
Page 30 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040068 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00168 mg/L -10.00168 0.005 < 1/2 RDL
Barium (Ba) 0.000103 mg/L -10.000103 0.005 < 1/2 RDL
Boron (B) -0.00136 mg/L -1-0.00136 0.05 < 1/2 RDL
Calcium (Ca) 0.0098 mg/L -10.0098 0.01 > 1/2 RDL
Chromium (Cr) -0.000258 mg/L -1-0.000258 0.005 < 1/2 RDL
Copper (Cu) 0.000159 mg/L -10.000159 0.005 < 1/2 RDL
Iron (Fe) 0.000324 mg/L -10.000324 0.01 < 1/2 RDL
Magnesium (Mg) 0.000341 mg/L -10.000341 0.005 < 1/2 RDL
Manganese (Mn) -0.000399 mg/L -1-0.000399 0.005 < 1/2 RDL
Nickel (Ni) -0.0013 mg/L -1-0.0013 0.005 < 1/2 RDL
Potassium (K) 0.000378 mg/L -10.000378 0.1 < 1/2 RDL
Sodium (Na) -0.0108 mg/L -1-0.0108 0.05 < 1/2 RDL
Strontium (Sr) 0.00005 mg/L -10.00005 0.005 < 1/2 RDL
Zinc (Zn) -0.000863 mg/L -1-0.000863 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.13 5 103mg/L -1158515.13
Barium (Ba) 5.1 5 102mg/L -1158515.1
Boron (B) 4.96 5 99.1mg/L -1158514.96
Calcium (Ca) 4.82 5 96.4mg/L -1158514.82
Chromium (Cr) 4.91 5 98.2mg/L -1158514.91
Copper (Cu) 4.96 5 99.1mg/L -1158514.96
Iron (Fe) 4.89 5 97.9mg/L -1158514.89
Magnesium (Mg) 5.13 5 103mg/L -1158515.13
Manganese (Mn) 5.12 5 102mg/L -1158515.12
Nickel (Ni) 4.95 5 99mg/L -1158514.95
Potassium (K) 4.99 5 99.7mg/L -1158514.99
Sodium (Na) 4.89 5 97.9mg/L -1158514.89
Strontium (Sr) 5.01 5 100mg/L -1158515.01
Zinc (Zn) 4.99 5 99.8mg/L -1158514.99
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030157 -- 2016006348
Aluminum (Al) 5.11 5 101mg/L -1307015.11
Barium (Ba) 5.12 5 101mg/L -1307015.12
Boron (B) 4.99 5 99.8mg/L -1307014.99
Calcium (Ca) 64.9 5 113mg/L -13070164.9
Chromium (Cr) 4.86 5 97.1mg/L -1307014.86
Copper (Cu) 4.89 5 97.9mg/L -1307014.89
Page 31 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040068 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16030157 -- 2016006348
Iron (Fe) 5.36 5 95.5mg/L -1307015.36
Magnesium (Mg) 18.5 5 93.5mg/L -13070118.5
Manganese (Mn) 5.22 5 99.6mg/L -1307015.22
Nickel (Ni) 4.75 5 95mg/L -1307014.75
Potassium (K) 8.39 5 101mg/L -1307018.39
Sodium (Na) 61.8 5 115mg/L -13070161.8
Strontium (Sr) 5.36 5 99.4mg/L -1307015.36
Zinc (Zn) 4.83 5 96.6mg/L -1307014.83
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16030157 -- 2016006348
Aluminum (Al) 5.13 5 101 0.356mg/L -1307015.13
Barium (Ba) 5.14 5 101 0.474mg/L -1307015.14
Boron (B) 5.06 5 101 1.27mg/L -1307015.06
Calcium (Ca) 65.9 5 133 16mg/L -13070165.9
Chromium (Cr) 4.89 5 97.8 0.636mg/L -1307014.89
Copper (Cu) 4.92 5 98.3 0.489mg/L -1307014.92
Iron (Fe) 5.39 5 96.2 0.73mg/L -1307015.39
Magnesium (Mg) 18.8 5 99.5 6.28mg/L -13070118.8
Manganese (Mn) 5.25 5 100 0.661mg/L -1307015.25
Nickel (Ni) 4.78 5 95.5 0.525mg/L -1307014.78
Potassium (K) 8.46 5 103 1.49mg/L -1307018.46
Sodium (Na) 62.7 5 133 14.7mg/L -13070162.7
Strontium (Sr) 5.41 5 100 0.981mg/L -1307015.41
Zinc (Zn) 4.87 5 97.4 0.784mg/L -1307014.87
Page 32 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040130 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.0025 mg/L -10.0025 0.005 = 1/2 RDL
Barium (Ba) -0.000134 mg/L -1-0.000134 0.005 < 1/2 RDL
Boron (B) 0.00152 mg/L -10.00152 0.05 < 1/2 RDL
Calcium (Ca) 0.00443 mg/L -10.00443 0.01 < 1/2 RDL
Chromium (Cr) -0.000317 mg/L -1-0.000317 0.005 < 1/2 RDL
Copper (Cu) 0.000007 mg/L -10.000007 0.005 < 1/2 RDL
Iron (Fe) -0.000078 mg/L -1-0.000078 0.01 < 1/2 RDL
Magnesium (Mg) 0.000202 mg/L -10.000202 0.005 < 1/2 RDL
Manganese (Mn) -0.000039 mg/L -1-0.000039 0.005 < 1/2 RDL
Nickel (Ni) -0.000048 mg/L -1-0.000048 0.005 < 1/2 RDL
Potassium (K) -0.00267 mg/L -1-0.00267 0.1 < 1/2 RDL
Sodium (Na) 0.00245 mg/L -10.00245 0.05 < 1/2 RDL
Strontium (Sr) 0.000032 mg/L -10.000032 0.005 < 1/2 RDL
Zinc (Zn) 0.000263 mg/L -10.000263 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.92 5 98.5mg/L -1158514.92
Barium (Ba) 4.95 5 98.9mg/L -1158514.95
Boron (B) 4.92 5 98.3mg/L -1158514.92
Calcium (Ca) 4.96 5 99.2mg/L -1158514.96
Chromium (Cr) 4.93 5 98.5mg/L -1158514.93
Copper (Cu) 4.9 5 98.1mg/L -1158514.9
Iron (Fe) 4.92 5 98.5mg/L -1158514.92
Magnesium (Mg) 5.06 5 101mg/L -1158515.06
Manganese (Mn) 4.94 5 98.8mg/L -1158514.94
Nickel (Ni) 4.99 5 99.7mg/L -1158514.99
Potassium (K) 4.86 5 97.1mg/L -1158514.86
Sodium (Na) 4.88 5 97.5mg/L -1158514.88
Strontium (Sr) 4.9 5 98.1mg/L -1158514.9
Zinc (Zn) 4.98 5 99.5mg/L -1158514.98
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040142 -- 2016009748
Aluminum (Al) 5.6 5 101mg/L -1307015.6
Barium (Ba) 4.94 5 98.6mg/L -1307014.94
Boron (B) 4.93 5 98.4mg/L -1307014.93
Calcium (Ca) 6.1 5 98.1mg/L -1307016.1
Chromium (Cr) 4.94 5 98.7mg/L -1307014.94
Copper (Cu) 4.89 5 97.8mg/L -1307014.89
Page 33 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040130 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040142 -- 2016009748
Iron (Fe) 5.25 5 98.3mg/L -1307015.25
Magnesium (Mg) 5.79 5 100mg/L -1307015.79
Manganese (Mn) 4.95 5 98.4mg/L -1307014.95
Nickel (Ni) 4.98 5 99.5mg/L -1307014.98
Potassium (K) 6.07 5 96.5mg/L -1307016.07
Sodium (Na) 10.2 5 96.2mg/L -13070110.2
Strontium (Sr) 4.95 5 98.6mg/L -1307014.95
Zinc (Zn) 5.01 5 99.3mg/L -1307015.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040142 -- 2016009748
Aluminum (Al) 5.55 5 99.8 0.978mg/L -1307015.55
Barium (Ba) 4.93 5 98.3 0.305mg/L -1307014.93
Boron (B) 4.87 5 97.3 1.21mg/L -1307014.87
Calcium (Ca) 6.07 5 97.4 0.757mg/L -1307016.07
Chromium (Cr) 4.9 5 98.1 0.651mg/L -1307014.9
Copper (Cu) 4.87 5 97.3 0.554mg/L -1307014.87
Iron (Fe) 5.22 5 97.7 0.673mg/L -1307015.22
Magnesium (Mg) 5.77 5 99.8 0.5mg/L -1307015.77
Manganese (Mn) 4.92 5 98 0.448mg/L -1307014.92
Nickel (Ni) 4.95 5 99 0.524mg/L -1307014.95
Potassium (K) 6.02 5 95.5 1.02mg/L -1307016.02
Sodium (Na) 10.2 5 95.4 0.835mg/L -13070110.2
Strontium (Sr) 4.89 5 97.5 1.14mg/L -1307014.89
Zinc (Zn) 4.98 5 98.8 0.465mg/L -1307014.98
Page 34 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.013 ug/L -1-0.013 1 < 1/2 RDL
Arsenic (As) 0.0075 ug/L -10.0075 1 < 1/2 RDL
Beryllium (Be) -0.026 ug/L -1-0.026 1 < 1/2 RDL
Cadmium (Cd) 0.0004 ug/L -10.0004 1 < 1/2 RDL
Cobalt (Co) 0.0007 ug/L -10.0007 1 < 1/2 RDL
Lead (Pb) 0.0002 ug/L -10.0002 1 < 1/2 RDL
Molybdenum (Mo) 0.016 ug/L -10.016 1 < 1/2 RDL
Selenium (Se) 0.0406 ug/L -10.0406 1 < 1/2 RDL
Thallium (Tl) Low Level -0.004 ug/L -1-0.004 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.0241 ug/L -1-0.0241 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 52 50 104ug/L -11585152
Arsenic (As) 48.9 50 97.8ug/L -11585148.9
Beryllium (Be) 51.2 50 102ug/L -11585151.2
Cadmium (Cd) 50.3 50 101ug/L -11585150.3
Cobalt (Co) 48.4 50 96.8ug/L -11585148.4
Lead (Pb) 50.4 50 101ug/L -11585150.4
Molybdenum (Mo) 49.5 50 99.1ug/L -11585149.5
Selenium (Se) 49.2 50 98.3ug/L -11585149.2
Thallium (Tl) Low Level 51.1 50 102ug/L -11585151.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040059 -- 2016009371
Antimony (Sb) 55 50 109ug/L -13070155
Arsenic (As) 49 50 98ug/L -13070149
Beryllium (Be) 50.1 50 100ug/L -13070150.1
Cadmium (Cd) 50 50 100ug/L -13070150
Cobalt (Co) 47.4 50 94.8ug/L -13070147.4
Lead (Pb) 50.1 50 100ug/L -13070150.1
Molybdenum (Mo) 50.6 50 101ug/L -13070150.6
Selenium (Se) 49.3 50 98.5ug/L -13070149.3
Thallium (Tl) Low Level 49.4 50 98.8ug/L -13070149.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040059 -- 2016009371
Antimony (Sb) 54.8 50 108 0.279ug/L -13070154.8
Arsenic (As) 49 50 98 0.0337ug/L -13070149
Beryllium (Be) 51 50 102 1.7ug/L -13070151
Page 35 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040070 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040059 -- 2016009371
Cadmium (Cd) 50.1 50 100 0.223ug/L -13070150.1
Cobalt (Co) 47.4 50 94.7 0.077ug/L -13070147.4
Lead (Pb) 50 50 100 0.183ug/L -13070150
Molybdenum (Mo) 50.5 50 101 0.146ug/L -13070150.5
Selenium (Se) 49.2 50 98.3 0.211ug/L -13070149.2
Thallium (Tl) Low Level 50 50 100 1.22ug/L -13070150
Page 36 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040135 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0489 ug/L -1-0.0489 1 < 1/2 RDL
Arsenic (As) -0.0027 ug/L -1-0.0027 1 < 1/2 RDL
Beryllium (Be) -0.0141 ug/L -1-0.0141 1 < 1/2 RDL
Cadmium (Cd) 0.0006 ug/L -10.0006 1 < 1/2 RDL
Cobalt (Co) -0.0006 ug/L -1-0.0006 1 < 1/2 RDL
Lead (Pb) 0.0001 ug/L -10.0001 1 < 1/2 RDL
Molybdenum (Mo) 0.0014 ug/L -10.0014 1 < 1/2 RDL
Selenium (Se) -0.0056 ug/L -1-0.0056 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0188 ug/L -1-0.0188 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.0348 ug/L -1-0.0348 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.2 50 98.3ug/L -11585149.2
Arsenic (As) 49.9 50 99.8ug/L -11585149.9
Beryllium (Be) 49.3 50 98.5ug/L -11585149.3
Cadmium (Cd) 50 50 99.9ug/L -11585150
Cobalt (Co) 49.6 50 99.2ug/L -11585149.6
Lead (Pb) 48.5 50 97.1ug/L -11585148.5
Molybdenum (Mo) 50.4 50 101ug/L -11585150.4
Selenium (Se) 49.3 50 98.7ug/L -11585149.3
Thallium (Tl) Low Level 46.9 50 93.8ug/L -11585146.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16040142 -- 2016009748
Antimony (Sb) 48.5 50 97ug/L -13070148.5
Arsenic (As) 50.3 50 100ug/L -13070150.3
Beryllium (Be) 50.5 50 101ug/L -13070150.5
Cadmium (Cd) 50.9 50 102ug/L -13070150.9
Cobalt (Co) 50 50 99.7ug/L -13070150
Lead (Pb) 49.4 50 98.3ug/L -13070149.4
Molybdenum (Mo) 49.9 50 99.5ug/L -13070149.9
Selenium (Se) 49.9 50 99.8ug/L -13070149.9
Thallium (Tl) Low Level 48 50 96.1ug/L -13070148
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040142 -- 2016009748
Antimony (Sb) 47.4 50 94.8 2.35ug/L -13070147.4
Arsenic (As) 49.7 50 99.3 1.09ug/L -13070149.7
Beryllium (Be) 49.1 50 98.1 2.89ug/L -13070149.1
Page 37 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040135 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16040142 -- 2016009748
Cadmium (Cd) 50.4 50 101 1.13ug/L -13070150.4
Cobalt (Co) 49.8 50 99.3 0.409ug/L -13070149.8
Lead (Pb) 49 50 97.6 0.74ug/L -13070149
Molybdenum (Mo) 49.4 50 98.6 0.916ug/L -13070149.4
Selenium (Se) 50.8 50 101 1.68ug/L -13070150.8
Thallium (Tl) Low Level 48.2 50 96.3 0.231ug/L -13070148.2
Page 38 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040081 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16040081 -- 2016009483
TDS 0.414mg/L -1723
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16040081 -- 2016009484
TDS 0.138mg/L -1725
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 101mg/L -110901101
Page 39 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040115 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030638 -- 2016008499
TDS 3.28mg/L -1120
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030638 -- 2016008502
TDS 0.708mg/L -1425
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16030638 -- 2016008503
TDS 2.17mg/L -1140
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 98mg/L -11090198
Page 40 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040066 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030316 -- 2016007139
TSS 0mg/L -17.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 93.6mg/L -146.8
Page 41 of 78
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16030157
Q16040101 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16030291 -- 2016007021
TSS 0mg/L -13
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16030291 -- 2016007023
TSS 3.28mg/L -16.2
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16030306 -- 2016007102
TSS 8.7mg/L -12.4
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 102mg/L -151.2
Page 42 of 78
#=CL#
April 11, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92292562
92292562
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16030157
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 05, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 19
Page 43 of 78
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92292562
J16030157
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 19
Page 44 of 78
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92292562
J16030157
Lab ID Sample ID Matrix Date Collected Date Received
92292562001 2016006339 Water 04/04/16 17:05 04/05/16 14:40
92292562002 2016006340 Water 04/04/16 17:08 04/05/16 14:40
92292562003 2016006341 Water 04/04/16 15:24 04/05/16 14:40
92292562004 2016006342 Water 04/04/16 15:03 04/05/16 14:40
92292562005 2016006346 Water 04/04/16 16:07 04/05/16 14:40
92292562006 2016006347 Water 04/04/16 14:07 04/05/16 14:40
92292562007 2016006348 Water 04/04/16 15:32 04/05/16 14:40
92292562008 2016006349 Water 04/04/16 16:07 04/05/16 14:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 19
Page 45 of 78
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92292562
J16030157
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92292562001 2016006339 SM 2320B 3 PASI-ATEP
92292562002 2016006340 SM 2320B 3 PASI-ATEP
92292562003 2016006341 SM 2320B 3 PASI-ATEP
92292562004 2016006342 SM 2320B 3 PASI-ATEP
92292562005 2016006346 SM 2320B 3 PASI-ATEP
92292562006 2016006347 SM 2320B 3 PASI-ATEP
92292562007 2016006348 SM 2320B 3 PASI-ATEP
92292562008 2016006349 SM 2320B 3 PASI-ATEP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 19
Page 46 of 78
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92292562
J16030157
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92292562001 2016006339
Alkalinity,Bicarbonate (CaCO3)38.0 mg/L 04/08/16 19:445.0SM 2320B
Alkalinity, Total as CaCO3 38.0 mg/L 04/08/16 19:445.0SM 2320B
92292562002 2016006340
Alkalinity,Bicarbonate (CaCO3)166 mg/L 04/08/16 20:215.0SM 2320B
Alkalinity, Total as CaCO3 166 mg/L 04/08/16 20:215.0SM 2320B
92292562004 2016006342
Alkalinity,Bicarbonate (CaCO3)35.6 mg/L 04/08/16 20:425.0SM 2320B
Alkalinity, Total as CaCO3 35.6 mg/L 04/08/16 20:425.0SM 2320B
92292562005 2016006346
Alkalinity,Bicarbonate (CaCO3)290 mg/L 04/08/16 20:545.0SM 2320B
Alkalinity, Total as CaCO3 290 mg/L 04/08/16 20:545.0SM 2320B
92292562006 2016006347
Alkalinity,Bicarbonate (CaCO3)53.0 mg/L 04/08/16 21:095.0SM 2320B
Alkalinity, Total as CaCO3 53.0 mg/L 04/08/16 21:095.0SM 2320B
92292562007 2016006348
Alkalinity,Bicarbonate (CaCO3)303 mg/L 04/08/16 21:405.0SM 2320B
Alkalinity, Total as CaCO3 303 mg/L 04/08/16 21:405.0SM 2320B
92292562008 2016006349
Alkalinity,Bicarbonate (CaCO3)281 mg/L 04/08/16 21:565.0SM 2320B
Alkalinity, Total as CaCO3 281 mg/L 04/08/16 21:565.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 19
Page 47 of 78
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292562
J16030157
Method:
Client:Duke Energy
SM 2320B
Date:April 11, 2016
Description:2320B Alkalinity
General Information:
8 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 19
Page 48 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006339 Lab ID:92292562001 Collected:04/04/16 17:05 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)38.0 mg/L 04/08/16 19:445.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 19:445.0 1
Alkalinity, Total as CaCO3 38.0 mg/L 04/08/16 19:445.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 19
Page 49 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006340 Lab ID:92292562002 Collected:04/04/16 17:08 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)166 mg/L 04/08/16 20:215.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 20:215.0 1
Alkalinity, Total as CaCO3 166 mg/L 04/08/16 20:215.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 19
Page 50 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006341 Lab ID:92292562003 Collected:04/04/16 15:24 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/08/16 20:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 20:345.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/08/16 20:345.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 19
Page 51 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006342 Lab ID:92292562004 Collected:04/04/16 15:03 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)35.6 mg/L 04/08/16 20:425.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 20:425.0 1
Alkalinity, Total as CaCO3 35.6 mg/L 04/08/16 20:425.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 19
Page 52 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006346 Lab ID:92292562005 Collected:04/04/16 16:07 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)290 mg/L 04/08/16 20:545.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 20:545.0 1
Alkalinity, Total as CaCO3 290 mg/L 04/08/16 20:545.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 19
Page 53 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006347 Lab ID:92292562006 Collected:04/04/16 14:07 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)53.0 mg/L 04/08/16 21:095.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 21:095.0 1
Alkalinity, Total as CaCO3 53.0 mg/L 04/08/16 21:095.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 19
Page 54 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006348 Lab ID:92292562007 Collected:04/04/16 15:32 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)303 mg/L 04/08/16 21:405.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 21:405.0 1
Alkalinity, Total as CaCO3 303 mg/L 04/08/16 21:405.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 19
Page 55 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292562
J16030157
Sample:2016006349 Lab ID:92292562008 Collected:04/04/16 16:07 Received:04/05/16 14:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)281 mg/L 04/08/16 21:565.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 21:565.0 1
Alkalinity, Total as CaCO3 281 mg/L 04/08/16 21:565.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 19
Page 56 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292562
J16030157
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44113
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92292562001, 92292562002, 92292562003, 92292562004, 92292562005, 92292562006, 92292562007,
92292562008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1705260
Associated Lab Samples:92292562001, 92292562002, 92292562003, 92292562004, 92292562005, 92292562006, 92292562007,
92292562008
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/08/16 19:25
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/08/16 19:25
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/08/16 19:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1705261LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.450 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1705262MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92292562001
1705263
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120100 0 255038.0 88.0 87.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1705264MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92292612008
1705265
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 2550ND48.3 48.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 19
Page 57 of 78
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92292562
J16030157
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 19
Page 58 of 78
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92292562
J16030157
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92292562001 WET/441132016006339SM 2320B
92292562002 WET/441132016006340SM 2320B
92292562003 WET/441132016006341SM 2320B
92292562004 WET/441132016006342SM 2320B
92292562005 WET/441132016006346SM 2320B
92292562006 WET/441132016006347SM 2320B
92292562007 WET/441132016006348SM 2320B
92292562008 WET/441132016006349SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 19
Page 59 of 78
Page 18 of 19
Page 60 of 78
Page 19 of 19
Page 61 of 78
#=CL#
April 11, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92292689
92292689
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16030157
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 06, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 15
Page 62 of 78
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92292689
J16030157
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 15
Page 63 of 78
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92292689
J16030157
Lab ID Sample ID Matrix Date Collected Date Received
92292689001 2016006343 Water 04/05/16 09:15 04/06/16 13:25
92292689002 2016006344 Water 04/05/16 10:13 04/06/16 13:25
92292689003 2016006345 Water 04/05/16 09:38 04/06/16 13:25
92292689004 2016006350 Water 04/05/16 16:36 04/06/16 13:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 15
Page 64 of 78
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92292689
J16030157
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92292689001 2016006343 SM 2320B 3 PASI-ATEP
92292689002 2016006344 SM 2320B 3 PASI-ATEP
92292689003 2016006345 SM 2320B 3 PASI-ATEP
92292689004 2016006350 SM 2320B 3 PASI-ATEP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 15
Page 65 of 78
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92292689
J16030157
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92292689001 2016006343
Alkalinity,Bicarbonate (CaCO3)135 mg/L 04/08/16 23:495.0SM 2320B
Alkalinity, Total as CaCO3 135 mg/L 04/08/16 23:495.0SM 2320B
92292689002 2016006344
Alkalinity,Bicarbonate (CaCO3)46.8 mg/L 04/09/16 00:005.0SM 2320B
Alkalinity, Total as CaCO3 46.8 mg/L 04/09/16 00:005.0SM 2320B
92292689003 2016006345
Alkalinity,Bicarbonate (CaCO3)148 mg/L 04/09/16 00:125.0SM 2320B
Alkalinity, Total as CaCO3 148 mg/L 04/09/16 00:125.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 15
Page 66 of 78
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292689
J16030157
Method:
Client:Duke Energy
SM 2320B
Date:April 11, 2016
Description:2320B Alkalinity
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 15
Page 67 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292689
J16030157
Sample:2016006343 Lab ID:92292689001 Collected:04/05/16 09:15 Received:04/06/16 13:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)135 mg/L 04/08/16 23:495.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/08/16 23:495.0 1
Alkalinity, Total as CaCO3 135 mg/L 04/08/16 23:495.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292689
J16030157
Sample:2016006344 Lab ID:92292689002 Collected:04/05/16 10:13 Received:04/06/16 13:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)46.8 mg/L 04/09/16 00:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/09/16 00:005.0 1
Alkalinity, Total as CaCO3 46.8 mg/L 04/09/16 00:005.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292689
J16030157
Sample:2016006345 Lab ID:92292689003 Collected:04/05/16 09:38 Received:04/06/16 13:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)148 mg/L 04/09/16 00:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/09/16 00:125.0 1
Alkalinity, Total as CaCO3 148 mg/L 04/09/16 00:125.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292689
J16030157
Sample:2016006350 Lab ID:92292689004 Collected:04/05/16 16:36 Received:04/06/16 13:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/09/16 00:245.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/09/16 00:245.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/09/16 00:245.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292689
J16030157
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44113
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92292689001, 92292689002, 92292689003, 92292689004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1705260
Associated Lab Samples:92292689001, 92292689002, 92292689003, 92292689004
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/08/16 19:25
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/08/16 19:25
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/08/16 19:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1705261LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.450 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1705262MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92292562001
1705263
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120100 0 255038.0 88.0 87.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1705264MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92292612008
1705265
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 2550ND48.3 48.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92292689
J16030157
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92292689
J16030157
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92292689001 WET/441132016006343SM 2320B
92292689002 WET/441132016006344SM 2320B
92292689003 WET/441132016006345SM 2320B
92292689004 WET/441132016006350SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/11/2016 01:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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