NC0038377_J15120113 Final Report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15120113
Project Name:MAYO STEAM - AB GW ASSESSMENT VEND-SYNTERRA
Lab Contact:Anne Pifer
Date:12/18/2015
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Brandon Russo, Kathy Webb, John Toepfer
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
1 of 100
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015037995 MAYO STEAM 05-Dec-15 5:53 PM Erin Black BG-1
1 Total Samples
2 of 100
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:12/12/2015
Electronic Data Deliverable (EDD) Sent Separately
3 of 100
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120113
2015037995
Collection Date:05-Dec-15 5:53 PM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
4 of 100
#=CL#
December 11, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278723
92278723
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
AB GW MAYO J15120113
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 08, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 41
5 of 100
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
Greenwood Certification IDs
816 Durst Avenue East, Greenwood, SC 29649
South Carolina Laboratory ID #: 24562North Carolina Divison of Water Resources Certification
number 25
Florida Certification number E87633
Virginia VELAP ID: 460250
Asbestos NVLAP accreditation: 101410-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 41
6 of 100
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Lab ID Sample ID Matrix Date Collected Date Received
92278723001 BG-1 Water 12/05/15 17:53 12/08/15 09:00
92278723002 BG-1 0.1 Water 12/05/15 17:53 12/08/15 09:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 41
7 of 100
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278723001 BG-1 EPA 300.0 2 PASI-GCDC
EPA 300.0 2 PASI-WCDC
EPA 200.7 7 PASI-AJMW
EPA 200.7 7 PASI-AJMW
EPA 200.7 4 PASI-ACDF
EPA 200.8 13 PASI-MTT3
EPA 200.8 13 PASI-MTT3
EPA 245.1 1 PASI-ASH1
EPA 245.1 1 PASI-ASH1
SM 2540C 1 PASI-ASAM
SM 2540D 1 PASI-ASAM
EPA 353.2 1 PASI-ADMN
SM 5310B 1 PASI-AMDW
92278723002 BG-1 0.1 EPA 200.7 7 PASI-AJMW
EPA 200.8 13 PASI-MTT3
EPA 245.1 1 PASI-ASH1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 41
8 of 100
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278723001 BG-1
Chloride 10.1 mg/L 12/10/15 03:021.0EPA 300.0
Aluminum 0.25 mg/L 12/11/15 11:530.10EPA 200.7
Barium 0.094 mg/L 12/11/15 11:530.0050EPA 200.7
Iron 0.35 mg/L 12/11/15 11:530.050EPA 200.7
Manganese 0.018 mg/L 12/11/15 11:530.0050EPA 200.7
Strontium 0.18 mg/L 12/11/15 11:530.0050EPA 200.7
Zinc 0.014 mg/L 12/11/15 11:530.010EPA 200.7
Barium, Dissolved 0.087 mg/L 12/08/15 21:500.0050EPA 200.7
Manganese, Dissolved 0.0076 mg/L 12/08/15 21:500.0050EPA 200.7
Strontium, Dissolved 0.17 mg/L 12/08/15 21:500.0050EPA 200.7
Zinc, Dissolved 0.015 mg/L 12/08/15 21:500.010EPA 200.7
Calcium 12600 ug/L 12/08/15 20:56100EPA 200.7
Magnesium 3280 ug/L 12/08/15 20:56100EPA 200.7
Sodium 12200 ug/L 12/08/15 20:565000EPA 200.7
Cadmium 0.13 ug/L 12/09/15 10:380.080EPA 200.8
Chromium 1.0 ug/L 12/09/15 10:380.50EPA 200.8
Lead 0.13 ug/L 12/09/15 10:380.10EPA 200.8
Nickel 1.9 ug/L 12/09/15 10:380.50EPA 200.8
Vanadium 4.2 ug/L 12/09/15 10:381.0EPA 200.8
Total Dissolved Solids 118 mg/L 12/08/15 16:1825.0SM 2540C
Nitrogen, NO2 plus NO3 0.66 mg/L 12/09/15 14:160.020EPA 353.2
Total Organic Carbon 1.0 mg/L 12/09/15 16:501.0SM 5310B
92278723002 BG-1 0.1
Barium, Dissolved 0.086 mg/L 12/08/15 21:540.0050EPA 200.7
Manganese, Dissolved 0.0075 mg/L 12/08/15 21:540.0050EPA 200.7
Strontium, Dissolved 0.17 mg/L 12/08/15 21:540.0050EPA 200.7
Zinc, Dissolved 0.014 mg/L 12/08/15 21:540.010EPA 200.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 41
9 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 300.0
Date:December 11, 2015
Description:3000 IC Anions 28 Days, GWD
General Information:
1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 41
10 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 200.7
Date:December 11, 2015
Description:200.7 MET ICP
General Information:
1 sample was analyzed for EPA 200.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 200.7 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 41
11 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 200.7
Date:December 11, 2015
Description:200.7 MET ICP, Dissolved
General Information:
2 samples were analyzed for EPA 200.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 200.7 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 41
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 200.7
Date:December 11, 2015
Description:200.7 MET ICP, No Prep
General Information:
1 sample was analyzed for EPA 200.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: ICP/18224
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92278722004,92278726001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1622722)
• Calcium
• MSD (Lab ID: 1622723)
• Calcium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 41
13 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 200.8
Date:December 11, 2015
Description:200.8 MET ICPMS
General Information:
1 sample was analyzed for EPA 200.8. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 200.8 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 41
14 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 200.8
Date:December 11, 2015
Description:200.8 MET ICPMS, Dissolved
General Information:
2 samples were analyzed for EPA 200.8. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 200.8 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 41
15 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 245.1
Date:December 11, 2015
Description:245.1 Mercury
General Information:
1 sample was analyzed for EPA 245.1. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 245.1 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 41
16 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 245.1
Date:December 11, 2015
Description:245.1 Mercury, Dissolved
General Information:
2 samples were analyzed for EPA 245.1. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 245.1 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 41
17 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
SM 2540C
Date:December 11, 2015
Description:2540C Total Dissolved Solids
General Information:
1 sample was analyzed for SM 2540C. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 41
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
SM 2540D
Date:December 11, 2015
Description:2540D Total Suspended Solids
General Information:
1 sample was analyzed for SM 2540D. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 41
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
EPA 353.2
Date:December 11, 2015
Description:353.2 Nitrogen, NO2/NO3 pres.
General Information:
1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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20 of 100
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Method:
Client:Duke Energy
SM 5310B
Date:December 11, 2015
Description:5310B TOC
General Information:
1 sample was analyzed for SM 5310B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/25689
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92278368001,92278368002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1623370)
• Total Organic Carbon
• MSD (Lab ID: 1623371)
• Total Organic Carbon
R1: RPD value was outside control limits.
• MSD (Lab ID: 1623371)
• Total Organic Carbon
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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21 of 100
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Sample:BG-1 Lab ID:92278723001 Collected:12/05/15 17:53 Received:12/08/15 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 300.03000 IC Anions 28 Days, GWD
Chloride 10.1 mg/L 12/10/15 03:02 16887-00-61.0 1
Sulfate ND mg/L 12/10/15 03:02 14808-79-81.0 1
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP
Aluminum 0.25 mg/L 12/11/15 11:53 7429-90-512/10/15 19:000.10 1
Barium 0.094 mg/L 12/11/15 11:53 7440-39-312/10/15 19:000.0050 1
Boron ND mg/L 12/11/15 11:53 7440-42-812/10/15 19:000.050 1
Iron 0.35 mg/L 12/11/15 11:53 7439-89-612/10/15 19:000.050 1
Manganese 0.018 mg/L 12/11/15 11:53 7439-96-512/10/15 19:000.0050 1
Strontium 0.18 mg/L 12/11/15 11:53 7440-24-612/10/15 19:000.0050 1
Zinc 0.014 mg/L 12/11/15 11:53 7440-66-612/10/15 19:000.010 1
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP, Dissolved
Aluminum, Dissolved ND mg/L 12/08/15 21:50 7429-90-512/08/15 15:350.10 1
Barium, Dissolved 0.087 mg/L 12/08/15 21:50 7440-39-312/08/15 15:350.0050 1
Boron, Dissolved ND mg/L 12/08/15 21:50 7440-42-812/08/15 15:350.050 1
Iron, Dissolved ND mg/L 12/08/15 21:50 7439-89-612/08/15 15:350.050 1
Manganese, Dissolved 0.0076 mg/L 12/08/15 21:50 7439-96-512/08/15 15:350.0050 1
Strontium, Dissolved 0.17 mg/L 12/08/15 21:50 7440-24-612/08/15 15:350.0050 1
Zinc, Dissolved 0.015 mg/L 12/08/15 21:50 7440-66-612/08/15 15:350.010 1
Analytical Method: EPA 200.7200.7 MET ICP, No Prep
Calcium 12600 ug/L 12/08/15 20:56 7440-70-21001
Magnesium 3280 ug/L 12/08/15 20:56 7439-95-41001
Potassium ND ug/L 12/08/15 20:56 7440-09-750001
Sodium 12200 ug/L 12/08/15 20:56 7440-23-550001
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8200.8 MET ICPMS
Antimony ND ug/L 12/09/15 10:38 7440-36-012/09/15 00:030.50 1
Arsenic ND ug/L 12/09/15 10:38 7440-38-212/09/15 00:030.50 1
Beryllium ND ug/L 12/09/15 10:38 7440-41-712/09/15 00:030.20 1
Cadmium 0.13 ug/L 12/09/15 10:38 7440-43-912/09/15 00:030.080 1
Chromium 1.0 ug/L 12/09/15 10:38 7440-47-312/09/15 00:030.50 1
Cobalt ND ug/L 12/09/15 10:38 7440-48-412/09/15 00:030.50 1
Copper ND ug/L 12/09/15 10:38 7440-50-812/09/15 00:031.0 1
Lead 0.13 ug/L 12/09/15 10:38 7439-92-112/09/15 00:030.10 1
Molybdenum ND ug/L 12/09/15 10:38 7439-98-712/09/15 00:030.50 1
Nickel 1.9 ug/L 12/09/15 10:38 7440-02-012/09/15 00:030.50 1
Selenium ND ug/L 12/09/15 10:38 7782-49-212/09/15 00:030.50 1
Thallium ND ug/L 12/09/15 10:38 7440-28-012/09/15 00:030.10 1
Vanadium 4.2 ug/L 12/09/15 10:38 7440-62-212/09/15 00:031.0 1
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8200.8 MET ICPMS, Dissolved
Antimony, Dissolved ND ug/L 12/09/15 10:10 7440-36-012/08/15 23:562.5 1
Arsenic, Dissolved ND ug/L 12/09/15 10:10 7440-38-212/08/15 23:562.5 1
Beryllium, Dissolved ND ug/L 12/09/15 10:10 7440-41-712/08/15 23:561.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
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Huntersville, NC 28078
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22 of 100
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Sample:BG-1 Lab ID:92278723001 Collected:12/05/15 17:53 Received:12/08/15 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8200.8 MET ICPMS, Dissolved
Cadmium, Dissolved ND ug/L 12/09/15 10:10 7440-43-912/08/15 23:560.40 1
Chromium, Dissolved ND ug/L 12/09/15 10:10 7440-47-312/08/15 23:562.5 1
Cobalt, Dissolved ND ug/L 12/09/15 10:10 7440-48-412/08/15 23:562.5 1
Copper, Dissolved ND ug/L 12/09/15 10:10 7440-50-812/08/15 23:565.0 1
Lead, Dissolved ND ug/L 12/09/15 10:10 7439-92-112/08/15 23:560.50 1
Molybdenum, Dissolved ND ug/L 12/09/15 10:10 7439-98-712/08/15 23:562.5 1
Nickel, Dissolved ND ug/L 12/09/15 10:10 7440-02-012/08/15 23:562.5 1
Selenium, Dissolved ND ug/L 12/09/15 10:10 7782-49-212/08/15 23:562.5 1
Thallium, Dissolved ND ug/L 12/09/15 10:10 7440-28-012/08/15 23:560.50 1
Vanadium, Dissolved ND ug/L 12/09/15 10:10 7440-62-212/08/15 23:565.0 1
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury
Mercury ND ug/L 12/09/15 14:24 7439-97-612/09/15 09:500.20 1
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury, Dissolved
Mercury, Dissolved ND ug/L 12/09/15 17:39 7439-97-612/09/15 12:150.20 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 118 mg/L 12/08/15 16:1825.0 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids ND mg/L 12/08/15 15:513.2 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3 0.66 mg/L 12/09/15 14:160.020 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 1.0 mg/L 12/09/15 16:50 7440-44-01.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
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23 of 100
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Sample:BG-1 0.1 Lab ID:92278723002 Collected:12/05/15 17:53 Received:12/08/15 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP, Dissolved
Aluminum, Dissolved ND mg/L 12/08/15 21:54 7429-90-512/08/15 15:350.10 1
Barium, Dissolved 0.086 mg/L 12/08/15 21:54 7440-39-312/08/15 15:350.0050 1
Boron, Dissolved ND mg/L 12/08/15 21:54 7440-42-812/08/15 15:350.050 1
Iron, Dissolved ND mg/L 12/08/15 21:54 7439-89-612/08/15 15:350.050 1
Manganese, Dissolved 0.0075 mg/L 12/08/15 21:54 7439-96-512/08/15 15:350.0050 1
Strontium, Dissolved 0.17 mg/L 12/08/15 21:54 7440-24-612/08/15 15:350.0050 1
Zinc, Dissolved 0.014 mg/L 12/08/15 21:54 7440-66-612/08/15 15:350.010 1
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8200.8 MET ICPMS, Dissolved
Antimony, Dissolved ND ug/L 12/09/15 08:17 7440-36-012/09/15 00:362.5 1
Arsenic, Dissolved ND ug/L 12/09/15 08:17 7440-38-212/09/15 00:362.5 1
Beryllium, Dissolved ND ug/L 12/09/15 08:17 7440-41-712/09/15 00:361.0 1
Cadmium, Dissolved ND ug/L 12/09/15 08:17 7440-43-912/09/15 00:360.40 1
Chromium, Dissolved ND ug/L 12/09/15 08:17 7440-47-312/09/15 00:362.5 1
Cobalt, Dissolved ND ug/L 12/09/15 08:17 7440-48-412/09/15 00:362.5 1
Copper, Dissolved ND ug/L 12/09/15 08:17 7440-50-812/09/15 00:365.0 1
Lead, Dissolved ND ug/L 12/09/15 08:17 7439-92-112/09/15 00:360.50 1
Molybdenum, Dissolved ND ug/L 12/09/15 08:17 7439-98-712/09/15 00:362.5 1
Nickel, Dissolved ND ug/L 12/09/15 08:17 7440-02-012/09/15 00:362.5 1
Selenium, Dissolved ND ug/L 12/09/15 08:17 7782-49-212/09/15 00:362.5 1
Thallium, Dissolved ND ug/L 12/09/15 08:17 7440-28-012/09/15 00:360.50 1
Vanadium, Dissolved ND ug/L 12/09/15 08:17 7440-62-212/09/15 00:365.0 1
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury, Dissolved
Mercury, Dissolved ND ug/L 12/09/15 17:41 7439-97-612/09/15 12:150.20 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
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24 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GWD/2722
EPA 300.0
EPA 300.0
3000 IC Anions, GWD
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1623390
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Chloride mg/L ND 1.0 12/09/15 22:11
Sulfate mg/L ND 1.0 12/09/15 22:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1623391LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/L 49.950 100 90-110
Sulfate mg/L 47.650 95 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623392MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722004
1623393
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride mg/L 50 95 90-11094 1 205011.9 59.4 58.9
Sulfate mg/L 50 92 90-11091 1 205023.5 69.7 68.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623394MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92277988002
1623395
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride mg/L 50 95 90-11098 3 20504.3 51.7 53.3
Sulfate mg/L 50 93 90-11097 3 205023.8 70.1 72.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 41
25 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
ICP/18224
EPA 200.7
EPA 200.7
ICP Metals, Trace, No Prep
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1622720
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Calcium ug/L ND 100 12/08/15 20:13
Magnesium ug/L ND 100 12/08/15 20:13
Potassium ug/L ND 5000 12/08/15 20:13
Sodium ug/L ND 5000 12/08/15 20:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1622721LABORATORY CONTROL SAMPLE:
LCSSpike
Calcium ug/L 49105000 98 85-115
Magnesium ug/L 49005000 98 85-115
Potassium ug/L 4910J5000 98 85-115
Sodium ug/L 4960J5000 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622722MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722004
1622723
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Calcium ug/L M150005870-13057 0 205000540005680056800
Magnesium ug/L 5000 92 70-13092 0 205000238002850028400
Potassium ug/L 5000 93 70-13094 0 205000ND88008840
Sodium ug/L 5000 84 70-13083 0 205000192002340023300
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622724MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278726001
1622725
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Calcium ug/L 5000 85 70-13085 0 205000118001600016100
Magnesium ug/L 5000 88 70-13090 1 205000418085808680
Potassium ug/L 5000 92 70-13095 2 2050004000J86108740
Sodium ug/L 5000 74 70-13079 1 205000284003200032300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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Page 22 of 41
26 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8744
EPA 245.1
EPA 245.1
245.1 Mercury
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1622819
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Mercury ug/L ND 0.20 12/09/15 13:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1622820LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.22.5 89 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622821MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722004
1622822
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 102 70-130102 0 202.5ND 2.6 2.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622823MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278726001
1622824
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 97 70-13095 1 202.5ND 2.5 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 41
27 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8746
EPA 245.1
EPA 245.1
245.1 Mercury - Dissolved
Associated Lab Samples:92278723001, 92278723002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1622833
Associated Lab Samples:92278723001, 92278723002
Matrix:Water
Analyzed
Mercury, Dissolved ug/L ND 0.20 12/09/15 16:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1622834LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury, Dissolved ug/L 2.52.5 101 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622835MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722001
1622836
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury, Dissolved ug/L 2.5 92 70-13092 0 252.5ND 2.4 2.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622837MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722013
1622838
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury, Dissolved ug/L 2.5 97 70-13094 3 252.5ND 2.5 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 41
28 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20247
EPA 200.7
EPA 200.7
200.7 MET
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1625842
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Aluminum mg/L ND 0.10 12/11/15 11:45
Barium mg/L ND 0.0050 12/11/15 11:45
Boron mg/L ND 0.050 12/11/15 11:45
Iron mg/L ND 0.050 12/11/15 11:45
Manganese mg/L ND 0.0050 12/11/15 11:45
Strontium mg/L ND 0.0050 12/11/15 11:45
Zinc mg/L ND 0.010 12/11/15 11:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1625843LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum mg/L 4.85 95 85-115
Barium mg/L 0.47.5 95 85-115
Boron mg/L 0.50.5 100 85-115
Iron mg/L 4.95 97 85-115
Manganese mg/L 0.48.5 95 85-115
Strontium mg/L 0.47.5 94 85-115
Zinc mg/L 0.47.5 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1625844MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278723001
1625845
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum mg/L 5 99 70-13094 6 2050.25 5.2 4.9
Barium mg/L .5 91 70-13086 4 20.50.094 0.55 0.52
Boron mg/L .5 96 70-13091 6 20.5ND 0.48 0.45
Iron mg/L 5 95 70-13090 5 2050.35 5.1 4.9
Manganese mg/L .5 92 70-13088 5 20.50.018 0.48 0.46
Strontium mg/L .5 89 70-13084 4 20.50.18 0.62 0.60
Zinc mg/L .5 92 70-13087 5 20.50.014 0.48 0.45
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 25 of 41
29 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20204
EPA 200.7
EPA 200.7
200.7 MET Dissolved
Associated Lab Samples:92278723001, 92278723002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1622755
Associated Lab Samples:92278723001, 92278723002
Matrix:Water
Analyzed
Aluminum, Dissolved mg/L ND 0.10 12/08/15 20:10
Barium, Dissolved mg/L ND 0.0050 12/08/15 20:10
Boron, Dissolved mg/L ND 0.050 12/08/15 20:10
Iron, Dissolved mg/L ND 0.050 12/08/15 20:10
Manganese, Dissolved mg/L ND 0.0050 12/08/15 20:10
Strontium, Dissolved mg/L ND 0.0050 12/08/15 20:10
Zinc, Dissolved mg/L ND 0.010 12/08/15 20:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1622756LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum, Dissolved mg/L 5.05 100 85-115
Barium, Dissolved mg/L 0.49.5 99 85-115
Boron, Dissolved mg/L 0.50.5 100 85-115
Iron, Dissolved mg/L 5.05 100 85-115
Manganese, Dissolved mg/L 0.49.5 98 85-115
Strontium, Dissolved mg/L 0.49.5 98 85-115
Zinc, Dissolved mg/L 0.49.5 98 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622757MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278720008
1622758
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum, Dissolved mg/L 5 106 70-130106 0 205ND5.3 5.4
Barium, Dissolved mg/L .5 101 70-130101 0 20.50.0061 0.51 0.51
Boron, Dissolved mg/L .5 108 70-130109 1 20.5ND 0.56 0.57
Iron, Dissolved mg/L 5 97 70-13097 0 205ND4.9 4.9
Manganese, Dissolved mg/L .5 99 70-13099 0 20.50.016 0.51 0.51
Strontium, Dissolved mg/L .5 100 70-130101 0 20.50.070 0.57 0.57
Zinc, Dissolved mg/L .5 114 70-130114 0 20.5ND 0.57 0.57
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622759MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722012
1622760
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum, Dissolved mg/L 5 105 70-130108 3 205ND5.3 5.4
Barium, Dissolved mg/L .5 96 70-13099 1 20.50.32 0.80 0.82
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 41
30 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1622759MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722012
1622760
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Boron, Dissolved mg/L .5 104 70-130105 1 20.5ND 0.55 0.56
Iron, Dissolved mg/L 5 92 70-13095 1 2055.8 10.4 10.5
Manganese, Dissolved mg/L .5 89 70-13092 1 20.51.3 1.7 1.7
Strontium, Dissolved mg/L .5 95 70-13097 1 20.50.41 0.88 0.89
Zinc, Dissolved mg/L .5 110 70-130113 3 20.5ND 0.55 0.56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 41
31 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/60193
EPA 200.8
EPA 200.8
200.8 MET
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2152519
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Antimony ug/L ND 0.50 12/09/15 10:35
Arsenic ug/L ND 0.50 12/09/15 10:35
Beryllium ug/L ND 0.20 12/09/15 10:35
Cadmium ug/L ND 0.080 12/09/15 10:35
Chromium ug/L ND 0.50 12/09/15 10:35
Cobalt ug/L ND 0.50 12/09/15 10:35
Copper ug/L ND 1.0 12/09/15 10:35
Lead ug/L ND 0.10 12/09/15 10:35
Molybdenum ug/L ND 0.50 12/09/15 10:35
Nickel ug/L ND 0.50 12/09/15 10:35
Selenium ug/L ND 0.50 12/09/15 10:35
Thallium ug/L ND 0.10 12/09/15 10:35
Vanadium ug/L ND 1.0 12/09/15 10:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2152520LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 85.180 106 85-115
Arsenic ug/L 83.780 105 85-115
Beryllium ug/L 82.980 104 85-115
Cadmium ug/L 89.680 112 85-115
Chromium ug/L 89.780 112 85-115
Cobalt ug/L 87.080 109 85-115
Copper ug/L 89.580 112 85-115
Lead ug/L 88.180 110 85-115
Molybdenum ug/L 87.980 110 85-115
Nickel ug/L 88.780 111 85-115
Selenium ug/L 85.880 107 85-115
Thallium ug/L 89.780 112 85-115
Vanadium ug/L 90.180 113 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2152521MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722010
2152522
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 80 106 70-130106 0 20804.3 89.1 89.5
Arsenic ug/L 80 89 70-130107 2 2080551622636
Beryllium ug/L 80 99 70-130101 2 2080ND79.4 80.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 41
32 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2152521MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722010
2152522
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cadmium ug/L 80 102 70-130104 1 2080ND82.0 83.1
Chromium ug/L 80 110 70-130110 0 2080ND87.8 88.2
Cobalt ug/L 80 100 70-130102 2 2080ND80.0 81.4
Copper ug/L 80 104 70-130105 1 2080ND83.3 84.4
Lead ug/L 80 107 70-130107 0 2080ND85.7 85.6
Molybdenum ug/L 80 76 70-130107 3 2080829890915
Nickel ug/L 80 103 70-130104 0 20802.1 84.8 85.1
Selenium ug/L 80 97 70-13098 1 20804.2 82.2 82.9
Thallium ug/L 80 110 70-130110 1 2080ND87.8 88.3
Vanadium ug/L 80 110 70-130111 1 20809.9 98.2 99.0
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2152523MATRIX SPIKE SAMPLE:
MSSpike
Result
92278719009
Antimony ug/L 82.280 103 70-130ND
Arsenic ug/L 81.680 102 70-130ND
Beryllium ug/L 77.880 97 70-130ND
Cadmium ug/L 85.280 107 70-130ND
Chromium ug/L 85.280 106 70-130ND
Cobalt ug/L 82.280 103 70-130ND
Copper ug/L 88.480 110 70-130ND
Lead ug/L 82.980 104 70-130ND
Molybdenum ug/L 85.180 106 70-130ND
Nickel ug/L 85.280 106 70-130ND
Selenium ug/L 79.480 99 70-130ND
Thallium ug/L 85.080 106 70-130ND
Vanadium ug/L 85.680 107 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 41
33 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/60196
EPA 200.8
EPA 200.8
200.8 MET Dissolved
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2152533
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Antimony, Dissolved ug/L ND 0.50 12/09/15 09:02
Arsenic, Dissolved ug/L ND 0.50 12/09/15 09:02
Beryllium, Dissolved ug/L ND 0.20 12/09/15 09:02
Cadmium, Dissolved ug/L ND 0.080 12/09/15 09:02
Chromium, Dissolved ug/L ND 0.50 12/09/15 09:02
Cobalt, Dissolved ug/L ND 0.50 12/09/15 09:02
Copper, Dissolved ug/L ND 1.0 12/09/15 09:02
Lead, Dissolved ug/L ND 0.10 12/09/15 09:02
Molybdenum, Dissolved ug/L ND 0.50 12/09/15 09:02
Nickel, Dissolved ug/L ND 0.50 12/09/15 09:02
Selenium, Dissolved ug/L ND 0.50 12/09/15 09:02
Thallium, Dissolved ug/L ND 0.10 12/09/15 09:02
Vanadium, Dissolved ug/L ND 1.0 12/09/15 09:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2152534LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony, Dissolved ug/L 85.980 107 85-115
Arsenic, Dissolved ug/L 85.080 106 85-115
Beryllium, Dissolved ug/L 83.580 104 85-115
Cadmium, Dissolved ug/L 89.280 112 85-115
Chromium, Dissolved ug/L 88.580 111 85-115
Cobalt, Dissolved ug/L 88.180 110 85-115
Copper, Dissolved ug/L 90.180 113 85-115
Lead, Dissolved ug/L 88.280 110 85-115
Molybdenum, Dissolved ug/L 87.380 109 85-115
Nickel, Dissolved ug/L 89.880 112 85-115
Selenium, Dissolved ug/L 85.480 107 85-115
Thallium, Dissolved ug/L 89.180 111 85-115
Vanadium, Dissolved ug/L 88.980 111 85-115
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2152537MATRIX SPIKE SAMPLE:
MSSpike
Result
92278723001
Antimony, Dissolved ug/L 431400 108 70-130ND
Arsenic, Dissolved ug/L 429400 107 70-130ND
Beryllium, Dissolved ug/L 417400 104 70-130ND
Cadmium, Dissolved ug/L 456400 114 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 41
34 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2152537MATRIX SPIKE SAMPLE:
MSSpike
Result
92278723001
Chromium, Dissolved ug/L 451400 113 70-130ND
Cobalt, Dissolved ug/L 441400 110 70-130ND
Copper, Dissolved ug/L 465400 116 70-130ND
Lead, Dissolved ug/L 445400 111 70-130ND
Molybdenum, Dissolved ug/L 442400 111 70-130ND
Nickel, Dissolved ug/L 455400 113 70-130ND
Selenium, Dissolved ug/L 430400 107 70-130ND
Thallium, Dissolved ug/L 452400 113 70-130ND
Vanadium, Dissolved ug/L 454400 113 70-130ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2152557MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722001
2152558
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony, Dissolved ug/L 400 107 70-130110 3 20400ND428439
Arsenic, Dissolved ug/L 400 107 70-130108 1 20400ND429432
Beryllium, Dissolved ug/L 400 103 70-130105 3 20400ND411422
Cadmium, Dissolved ug/L 400 112 70-130110 2 20400ND448441
Chromium, Dissolved ug/L 400 112 70-130111 1 20400ND449445
Cobalt, Dissolved ug/L 400 108 70-130109 0 20400ND434435
Copper, Dissolved ug/L 400 114 70-130114 0 20400ND457455
Lead, Dissolved ug/L 400 110 70-130111 0 204000.90 443 443
Molybdenum, Dissolved ug/L 400 112 70-130110 2 2040015.5 464 455
Nickel, Dissolved ug/L 400 112 70-130112 0 20400ND447448
Selenium, Dissolved ug/L 400 106 70-130106 0 20400ND424426
Thallium, Dissolved ug/L 400 113 70-130113 0 20400ND452451
Vanadium, Dissolved ug/L 400 113 70-130113 0 20400ND453453
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 41
35 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/60197
EPA 200.8
EPA 200.8
200.8 MET Dissolved
Associated Lab Samples:92278723002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2152538
Associated Lab Samples:92278723002
Matrix:Water
Analyzed
Antimony, Dissolved ug/L ND 0.50 12/09/15 07:59
Arsenic, Dissolved ug/L ND 0.50 12/09/15 07:59
Beryllium, Dissolved ug/L ND 0.20 12/09/15 07:59
Cadmium, Dissolved ug/L ND 0.080 12/09/15 07:59
Chromium, Dissolved ug/L ND 0.50 12/09/15 07:59
Cobalt, Dissolved ug/L ND 0.50 12/09/15 07:59
Copper, Dissolved ug/L ND 1.0 12/09/15 07:59
Lead, Dissolved ug/L ND 0.10 12/09/15 07:59
Molybdenum, Dissolved ug/L ND 0.50 12/09/15 07:59
Nickel, Dissolved ug/L ND 0.50 12/09/15 07:59
Selenium, Dissolved ug/L ND 0.50 12/09/15 07:59
Thallium, Dissolved ug/L ND 0.10 12/09/15 07:59
Vanadium, Dissolved ug/L ND 1.0 12/09/15 07:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2152539LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony, Dissolved ug/L 85.180 106 85-115
Arsenic, Dissolved ug/L 85.080 106 85-115
Beryllium, Dissolved ug/L 85.380 107 85-115
Cadmium, Dissolved ug/L 88.180 110 85-115
Chromium, Dissolved ug/L 88.680 111 85-115
Cobalt, Dissolved ug/L 88.480 110 85-115
Copper, Dissolved ug/L 91.080 114 85-115
Lead, Dissolved ug/L 88.880 111 85-115
Molybdenum, Dissolved ug/L 86.880 108 85-115
Nickel, Dissolved ug/L 90.480 113 85-115
Selenium, Dissolved ug/L 86.880 108 85-115
Thallium, Dissolved ug/L 89.880 112 85-115
Vanadium, Dissolved ug/L 89.380 112 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2152540MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278723002
2152541
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony, Dissolved ug/L 400 105 70-130109 4 20400ND419437
Arsenic, Dissolved ug/L 400 104 70-130108 4 20400ND414432
Beryllium, Dissolved ug/L 400 103 70-130106 2 20400ND414422
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 41
36 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2152540MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278723002
2152541
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cadmium, Dissolved ug/L 400 109 70-130112 3 20400ND435447
Chromium, Dissolved ug/L 400 108 70-130114 6 20400ND433458
Cobalt, Dissolved ug/L 400 107 70-130111 3 20400ND429442
Copper, Dissolved ug/L 400 114 70-130121 7 20400ND455486
Lead, Dissolved ug/L 400 108 70-130112 3 20400ND434447
Molybdenum, Dissolved ug/L 400 105 70-130110 4 20400ND421439
Nickel, Dissolved ug/L 400 111 70-130115 4 20400ND445462
Selenium, Dissolved ug/L 400 106 70-130110 4 20400ND426442
Thallium, Dissolved ug/L 400 110 70-130113 2 20400ND440451
Vanadium, Dissolved ug/L 400 110 70-130114 3 20400ND444459
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2152542MATRIX SPIKE SAMPLE:
MSSpike
Result
92278719006
Antimony, Dissolved ug/L 430400 108 70-130ND
Arsenic, Dissolved ug/L 426400 107 70-130ND
Beryllium, Dissolved ug/L 417400 104 70-130ND
Cadmium, Dissolved ug/L 439400 110 70-130ND
Chromium, Dissolved ug/L 443400 111 70-130ND
Cobalt, Dissolved ug/L 432400 108 70-130ND
Copper, Dissolved ug/L 471400 117 70-130ND
Lead, Dissolved ug/L 440400 110 70-130ND
Molybdenum, Dissolved ug/L 430400 107 70-130ND
Nickel, Dissolved ug/L 448400 112 70-130ND
Selenium, Dissolved ug/L 424400 106 70-130ND
Thallium, Dissolved ug/L 447400 112 70-130ND
Vanadium, Dissolved ug/L 444400 111 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 41
37 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41822
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1622877
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 12/08/15 16:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1622878LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 244250 98 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278722004
1622879SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 303 3 5293
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278726001
1622880SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 129 2 5126
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 41
38 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41817
SM 2540D
SM 2540D
2540D Total Suspended Solids
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1622677
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Total Suspended Solids mg/L ND 2.5 12/08/15 15:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1622678LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids mg/L 262250 105 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278722004
1622679SAMPLE DUPLICATE:
Total Suspended Solids mg/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278726001
1622680SAMPLE DUPLICATE:
Total Suspended Solids mg/L ND 5ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 41
39 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25681
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, preserved
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1623279
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Nitrogen, NO2 plus NO3 mg/L ND 0.020 12/09/15 13:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1623280LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, NO2 plus NO3 mg/L 2.42.5 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623281MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278720004
1623282
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, NO2 plus NO3 mg/L 2.5 98 75-12598 0 102.5ND 2.5 2.5
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623283MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278722001
1623284
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, NO2 plus NO3 mg/L 2.5 97 75-12597 0 102.5ND 2.4 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 41
40 of 100
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25689
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples:92278723001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1623366
Associated Lab Samples:92278723001
Matrix:Water
Analyzed
Total Organic Carbon mg/L ND 1.0 12/09/15 10:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1623367LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon mg/L 24.725 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623368MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278368001
1623369
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon mg/L 25 107 90-110109 2 5254.9 31.6 32.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623370MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278368002
1623371
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon mg/L M6,R125-2120 90-110-880 9 525383033003610
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
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[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - GreenwoodPASI-G
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - GreenwoodPASI-W
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
Pace Analytical Services, Inc.
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[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278723
AB GW MAYO J15120113
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278723001 GWD/2722BG-1 EPA 300.0
92278723001 MPRP/20247 ICP/18267BG-1 EPA 200.7 EPA 200.7
92278723001 MPRP/20204 ICP/18226BG-1 EPA 200.7 EPA 200.7
92278723002 MPRP/20204 ICP/18226BG-1 0.1 EPA 200.7 EPA 200.7
92278723001 ICP/18224BG-1 EPA 200.7
92278723001 MPRP/60193 ICPM/27800BG-1 EPA 200.8 EPA 200.8
92278723001 MPRP/60196 ICPM/27795BG-1 EPA 200.8 EPA 200.8
92278723002 MPRP/60197 ICPM/27794BG-1 0.1 EPA 200.8 EPA 200.8
92278723001 MERP/8744 MERC/8399BG-1 EPA 245.1 EPA 245.1
92278723001 MERP/8746 MERC/8401BG-1 EPA 245.1 EPA 245.1
92278723002 MERP/8746 MERC/8401BG-1 0.1 EPA 245.1 EPA 245.1
92278723001 WET/41822BG-1 SM 2540C
92278723001 WET/41817BG-1 SM 2540D
92278723001 WETA/25681BG-1 EPA 353.2
92278723001 WETA/25689BG-1 SM 5310B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 04:39 PM
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[phone]
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#=CL#
December 11, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278980
92278980
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120113 REV
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 09, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Bishop for
[e-mail]
HORIZON Database Administrator
Kevin Herring
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
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[phone]
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278980
J15120113 REV
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278980
J15120113 REV
Lab ID Sample ID Matrix Date Collected Date Received
92278980001 2015037995 Water 12/05/15 17:53 12/09/15 09:38
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278980
J15120113 REV
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278980001 2015037995 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ASER
REPORT OF LABORATORY ANALYSIS
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278980
J15120113 REV
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278980001 2015037995
Alkalinity,Bicarbonate (CaCO3)52.8 mg/L 12/10/15 15:375.0SM 2320B
Alkalinity, Total as CaCO3 52.8 mg/L 12/10/15 15:375.0SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278980
J15120113 REV
Method:
Client:Duke Energy
RSK 175
Date:December 11, 2015
Description:RSK 175 AIR Headspace
General Information:
1 sample was analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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[phone]
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278980
J15120113 REV
Method:
Client:Duke Energy
SM 2320B
Date:December 11, 2015
Description:2320B Alkalinity
General Information:
1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/41869
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92278978001,92278980001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1624766)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1624767)
• Alkalinity, Total as CaCO3
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278980
J15120113 REV
Sample:2015037995 Lab ID:92278980001 Collected:12/05/15 17:53 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 13:12 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)52.8 mg/L 12/10/15 15:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 15:375.0 1
Alkalinity, Total as CaCO3 52.8 mg/L 12/10/15 15:375.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 15
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278980
J15120113 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24812
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92278980001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2154496
Associated Lab Samples:92278980001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 12/10/15 10:19
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2154497LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2154498
Methane ug/L 52.260.7 86 85-1159054.9 5 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278948018
2154499SAMPLE DUPLICATE:
Methane ug/L 3.2J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278965005
2154500SAMPLE DUPLICATE:
Methane ug/L 19.4 5 2020.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:18 PM
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[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278980
J15120113 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41869
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92278980001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1624764
Associated Lab Samples:92278980001
Matrix:Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 12/10/15 11:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1624765LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 51.050 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624766MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278978001
1624767
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1507790-11075 1 45090.2 129 128
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624768MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278980001
1624769
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 96 90-11098 1 45052.8 101 102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278980
J15120113 REV
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:18 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 11 of 15
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278980
J15120113 REV
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278980001 AIR/248122015037995RSK 175
92278980001 WET/418692015037995SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:18 PM
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[phone]
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#=CL#
December 14, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278697
92278697
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120113
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 07, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278697
J15120113
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278697
J15120113
Lab ID Sample ID Matrix Date Collected Date Received
92278697001 2015037995 Water 12/05/15 17:53 12/07/15 15:05
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278697
J15120113
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278697001 2015037995 EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278697
J15120113
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278697001 2015037995
Chromium, Hexavalent 0.31 ug/L 12/14/15 20:050.060EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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#=NA#
PROJECT NARRATIVE
Project:
92278697
J15120113
Date:December 14, 2015
Pace Project No.:
This report has been revised.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278697
J15120113
Method:
Client:Duke Energy
EPA 218.7
Date:December 14, 2015
Description:Hexavalent Chromium by IC
General Information:
1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278697
J15120113
Sample:2015037995 Lab ID:92278697001 Collected:12/05/15 17:53 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.31 ug/L 12/14/15 20:05 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/14/2015 09:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278697
J15120113
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52896
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92278697001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1416198
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/11/15 13:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1416199LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.076.075 101 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1416200MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278695010
1416201
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 120 85-115128 6 20.025ND 0.030 0.032
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1416202MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278672007
1416203
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 99 85-11591 9 20.075ND 0.074 0.068
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/14/2015 09:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278697
J15120113
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/14/2015 09:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278697
J15120113
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278697001 WETA/528962015037995EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/14/2015 09:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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