NC0038377_J15120100 Final Report (12-21-15)_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15120100
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:12/18/2015
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Brandon Russo, Kathy Webb, John Toepfer
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
1 of 83
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015037873 MAYO STEAM 03-Dec-15 9:30 AM Erin Black MW-3
2015037874 MAYO STEAM 03-Dec-15 12:35 PM Erin Black ABMW-1
2015037875 MAYO STEAM 03-Dec-15 9:11 AM Erin Black MW-10BR
2015037876 MAYO STEAM 03-Dec-15 2:21 PM Erin Black MW-11BR
2015037877 MAYO STEAM 03-Dec-15 3:30 PM Erin Black Filter Blank
2015037878 MAYO STEAM 03-Dec-15 3:30 PM Erin Black Equipment Blank
6 Total Samples
2 of 83
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:12/11/2015
Electronic Data Deliverable (EDD) Sent Separately
3 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037873
Collection Date:03-Dec-15 9:30 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.062 mg-N/L EPA 353.2 12/08/2015 15:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 45 mg/L EPA 300.0 12/05/2015 12:55 BGN9034110
Sulfate 22 mg/L EPA 300.0 12/05/2015 12:55 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 11:40M2 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 16:34 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:49 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/06/2015 19:19 FCJORDA0.005 1
Barium (Ba)0.056 mg/L EPA 200.7 12/06/2015 19:19 FCJORDA0.005 1
Boron (B)0.934 mg/L EPA 200.7 12/06/2015 19:19 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/06/2015 19:19 FCJORDA0.01 1
Manganese (Mn)1.22 mg/L EPA 200.7 12/06/2015 19:19 FCJORDA0.005 1
Strontium (Sr)0.321 mg/L EPA 200.7 12/06/2015 19:19 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 12/06/2015 19:19 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/08/2015 16:17 FCJORDA0.005 1
Barium (Ba)0.058 mg/L EPA 200.7 12/08/2015 16:17 FCJORDA0.005 1
Boron (B)0.943 mg/L EPA 200.7 12/08/2015 16:17 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 16:17 FCJORDA0.01 1
Manganese (Mn)1.27 mg/L EPA 200.7 12/08/2015 16:17 FCJORDA0.005 1
Strontium (Sr)0.342 mg/L EPA 200.7 12/08/2015 16:17 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 16:17 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)27.9 mg/L EPA 200.7 12/07/2015 15:35 FCJORDA0.01 1
Magnesium (Mg)8.52 mg/L EPA 200.7 12/07/2015 15:35 FCJORDA0.005 1
Potassium (K)2.13 mg/L EPA 200.7 12/07/2015 15:35 FCJORDA0.1 1
Sodium (Na)22.9 mg/L EPA 200.7 12/07/2015 15:35 FCJORDA0.05 1
4 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037873
Collection Date:03-Dec-15 9:30 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 12/08/2015 14:36 MHH71310.005 1
Barium (Ba)0.057 mg/L EPA 200.7 12/08/2015 14:36 MHH71310.005 1
Boron (B)0.930 mg/L EPA 200.7 12/08/2015 14:36 MHH71310.05 1
Iron (Fe)0.010 mg/L EPA 200.7 12/08/2015 14:36 MHH71310.01 1
Manganese (Mn)1.31 mg/L EPA 200.7 12/08/2015 14:36 MHH71310.005 1
Strontium (Sr)0.328 mg/L EPA 200.7 12/08/2015 14:36 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 14:36 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Nickel (Ni)2.89 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 03:24 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 03:24 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 03:24 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Nickel (Ni)2.47 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 01:48 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 01:48 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 01:48 MHALL30.3 1
5 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037873
Collection Date:03-Dec-15 9:30 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Nickel (Ni)2.72 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 23:15 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 23:15 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 23:15 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 12/05/2015 13:50 CJELLIO251
Total Carbon
TOC 0.990 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/05/2015 10:34 CJELLIO51
6 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037874
Collection Date:03-Dec-15 12:35 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 15:31 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 12/05/2015 13:49 BGN90340.5 5
Sulfate 19 mg/L EPA 300.0 12/05/2015 13:49 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 11:58 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 16:36 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:51 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.185 mg/L EPA 200.7 12/06/2015 19:22 FCJORDA0.005 1
Barium (Ba)0.536 mg/L EPA 200.7 12/06/2015 19:22 FCJORDA0.005 1
Boron (B)5.71 mg/L EPA 200.7 12/06/2015 19:22 FCJORDA0.05 1
Iron (Fe)0.262 mg/L EPA 200.7 12/06/2015 19:22 FCJORDA0.01 1
Manganese (Mn)0.930 mg/L EPA 200.7 12/06/2015 19:22 FCJORDA0.005 1
Strontium (Sr)2.03 mg/L EPA 200.7 12/06/2015 19:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/06/2015 19:22 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.176 mg/L EPA 200.7 12/08/2015 16:28 FCJORDA0.005 1
Barium (Ba)0.550 mg/L EPA 200.7 12/08/2015 16:28 FCJORDA0.005 1
Boron (B)5.85 mg/L EPA 200.7 12/08/2015 16:28 FCJORDA0.05 1
Iron (Fe)0.022 mg/L EPA 200.7 12/08/2015 16:28 FCJORDA0.01 1
Manganese (Mn)0.914 mg/L EPA 200.7 12/08/2015 16:28 FCJORDA0.005 1
Strontium (Sr)2.06 mg/L EPA 200.7 12/08/2015 16:28 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 16:28 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)66.9 mg/L EPA 200.7 12/07/2015 15:47 FCJORDA0.01 1
Magnesium (Mg)37.7 mg/L EPA 200.7 12/07/2015 15:47 FCJORDA0.005 1
Potassium (K)22.0 mg/L EPA 200.7 12/07/2015 15:47 FCJORDA110
Sodium (Na)17.3 mg/L EPA 200.7 12/07/2015 15:47 FCJORDA0.05 1
7 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037874
Collection Date:03-Dec-15 12:35 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.229 mg/L EPA 200.7 12/08/2015 14:49 MHH71310.005 1
Barium (Ba)0.661 mg/L EPA 200.7 12/08/2015 14:49 MHH71310.005 1
Boron (B)5.48 mg/L EPA 200.7 12/08/2015 14:49 MHH71310.05 1
Iron (Fe)1.11 mg/L EPA 200.7 12/08/2015 14:49 MHH71310.01 1
Manganese (Mn)1.23 mg/L EPA 200.7 12/08/2015 14:49 MHH71310.005 1
Strontium (Sr)2.42 mg/L EPA 200.7 12/08/2015 14:49 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 14:49 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)14.6 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Arsenic (As)422 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Cobalt (Co)2.06 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Molybdenum (Mo)275 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Nickel (Ni)1.80 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 03:31 MHALL311
Thallium (Tl) Low Level 0.654 ug/L EPA 200.8 12/09/2015 03:31 MHALL30.2 1
Vanadium (V) Low Level 75.9 ug/L EPA 200.8 12/09/2015 03:31 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)15.9 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Arsenic (As)376 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Cobalt (Co)1.84 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Molybdenum (Mo)276 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Nickel (Ni)1.51 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 02:36 MHALL311
Thallium (Tl) Low Level 0.731 ug/L EPA 200.8 12/08/2015 02:36 MHALL30.2 1
Vanadium (V) Low Level 65.3 ug/L EPA 200.8 12/08/2015 02:36 MHALL30.3 1
8 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037874
Collection Date:03-Dec-15 12:35 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)17.2 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Arsenic (As)574 ug/L EPA 200.8 12/08/2015 22:01 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Cobalt (Co)2.98 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Copper (Cu)1.34 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Molybdenum (Mo)271 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Nickel (Ni)2.17 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 22:01 MHALL311
Thallium (Tl) Low Level 0.931 ug/L EPA 200.8 12/08/2015 22:01 MHALL30.2 1
Vanadium (V) Low Level 167 ug/L EPA 200.8 12/08/2015 22:01 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 410 mg/L SM2540C 12/05/2015 13:50 CJELLIO251
Total Carbon
TOC 4.2 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 12/05/2015 10:34 CJELLIO51
9 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037875
Collection Date:03-Dec-15 9:11 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 15:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 300.0 12/05/2015 14:07 BGN9034110
Sulfate 83 mg/L EPA 300.0 12/05/2015 14:07 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 12:01 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 16:38 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 12/06/2015 19:26 FCJORDA0.005 1
Barium (Ba)0.005 mg/L EPA 200.7 12/06/2015 19:26 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/06/2015 19:26 FCJORDA0.05 1
Iron (Fe)0.088 mg/L EPA 200.7 12/06/2015 19:26 FCJORDA0.01 1
Manganese (Mn)0.099 mg/L EPA 200.7 12/06/2015 19:26 FCJORDA0.005 1
Strontium (Sr)0.191 mg/L EPA 200.7 12/06/2015 19:26 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/06/2015 19:26 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)30.0 mg/L EPA 200.7 12/08/2015 08:16 FCJORDA0.01 1
Magnesium (Mg)12.9 mg/L EPA 200.7 12/08/2015 08:16 FCJORDA0.005 1
Potassium (K)3.95 mg/L EPA 200.7 12/08/2015 08:16 FCJORDA0.1 1
Sodium (Na)37.7 mg/L EPA 200.7 12/08/2015 08:16 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.034 mg/L EPA 200.7 12/08/2015 14:53 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/08/2015 14:53 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 14:53 MHH71310.05 1
Iron (Fe)0.193 mg/L EPA 200.7 12/08/2015 14:53 MHH71310.01 1
Manganese (Mn)0.084 mg/L EPA 200.7 12/08/2015 14:53 MHH71310.005 1
Strontium (Sr)0.198 mg/L EPA 200.7 12/08/2015 14:53 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 14:53 MHH71310.005 1
10 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037875
Collection Date:03-Dec-15 9:11 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Nickel (Ni)1.93 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 03:39 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 03:39 MHALL30.2 1
Vanadium (V) Low Level 1.67 ug/L EPA 200.8 12/09/2015 03:39 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Nickel (Ni)2.02 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 23:23 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 23:23 MHALL30.2 1
Vanadium (V) Low Level 1.50 ug/L EPA 200.8 12/08/2015 23:23 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 12/05/2015 13:50 CJELLIO251
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/05/2015 10:34 CJELLIO51
11 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037875
Collection Date:03-Dec-15 9:11 AM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
12 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037876
Collection Date:03-Dec-15 2:21 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.249 mg-N/L EPA 353.2 12/08/2015 15:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 12/05/2015 14:25 BGN90340.5 5
Sulfate 15 mg/L EPA 300.0 12/05/2015 14:25 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 12:03 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 16:40 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:54 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.094 mg/L EPA 200.7 12/06/2015 19:42 FCJORDA0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 12/06/2015 19:42 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/06/2015 19:42 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/06/2015 19:42 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/06/2015 19:42 FCJORDA0.005 1
Strontium (Sr)0.242 mg/L EPA 200.7 12/06/2015 19:42 FCJORDA0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 12/06/2015 19:42 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.089 mg/L EPA 200.7 12/08/2015 16:32 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 12/08/2015 16:32 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 16:32 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 16:32 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 16:32 FCJORDA0.005 1
Strontium (Sr)0.257 mg/L EPA 200.7 12/08/2015 16:32 FCJORDA0.005 1
Zinc (Zn)0.013 mg/L EPA 200.7 12/08/2015 16:32 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)23.3 mg/L EPA 200.7 12/07/2015 16:14 FCJORDA0.01 1
Magnesium (Mg)8.95 mg/L EPA 200.7 12/07/2015 16:14 FCJORDA0.005 1
Potassium (K)12.1 mg/L EPA 200.7 12/07/2015 16:14 FCJORDA0.1 1
Sodium (Na)20.7 mg/L EPA 200.7 12/07/2015 16:14 FCJORDA0.05 1
13 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037876
Collection Date:03-Dec-15 2:21 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.207 mg/L EPA 200.7 12/08/2015 14:57 MHH71310.005 1
Barium (Ba)0.022 mg/L EPA 200.7 12/08/2015 14:57 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 14:57 MHH71310.05 1
Iron (Fe)0.304 mg/L EPA 200.7 12/08/2015 14:57 MHH71310.01 1
Manganese (Mn)0.029 mg/L EPA 200.7 12/08/2015 14:57 MHH71310.005 1
Strontium (Sr)0.250 mg/L EPA 200.7 12/08/2015 14:57 MHH71310.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 12/08/2015 14:57 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.68 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Arsenic (As)1.03 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Chromium (Cr)13.8 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Copper (Cu)1.08 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Molybdenum (Mo)7.39 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Selenium (Se)1.35 ug/L EPA 200.8 12/09/2015 04:03 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 04:03 MHALL30.2 1
Vanadium (V) Low Level 11.5 ug/L EPA 200.8 12/09/2015 04:03 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)1.82 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Arsenic (As)1.03 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Chromium (Cr)13.3 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Copper (Cu)1.05 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Molybdenum (Mo)7.62 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Selenium (Se)1.15 ug/L EPA 200.8 12/08/2015 02:58 MHALL311
Thallium (Tl) Low Level 0.442 ug/L EPA 200.8 12/08/2015 02:58 MHALL30.2 1
Vanadium (V) Low Level 10.8 ug/L EPA 200.8 12/08/2015 02:58 MHALL30.3 1
14 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037876
Collection Date:03-Dec-15 2:21 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.57 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Arsenic (As)1.05 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Chromium (Cr)24.1 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Copper (Cu)1.99 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Molybdenum (Mo)7.69 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Nickel (Ni)7.20 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Selenium (Se)1.04 ug/L EPA 200.8 12/09/2015 00:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 00:09 MHALL30.2 1
Vanadium (V) Low Level 12.1 ug/L EPA 200.8 12/09/2015 00:09 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 12/05/2015 13:50 CJELLIO251
Total Carbon
TOC 1.0 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 12/05/2015 10:34 CJELLIO51
15 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037877
Collection Date:03-Dec-15 3:30 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 16:43 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:56 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/06/2015 19:45 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/06/2015 19:45 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/06/2015 19:45 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/06/2015 19:45 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/06/2015 19:45 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/06/2015 19:45 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/06/2015 19:45 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/08/2015 16:36 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/08/2015 16:36 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 16:36 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 16:36 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 16:36 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/08/2015 16:36 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 16:36 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 04:21 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 04:21 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 04:21 MHALL30.3 1
16 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037877
Collection Date:03-Dec-15 3:30 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 03:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 03:06 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 03:06 MHALL30.3 1
17 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037878
Collection Date:03-Dec-15 3:30 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 15:53 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 12/05/2015 14:43 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 12/05/2015 14:43 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 12:05 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 12/07/2015 16:18 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 12/07/2015 16:18 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 12/07/2015 16:18 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 12/07/2015 16:18 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/08/2015 15:01 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/08/2015 15:01 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 15:01 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 15:01 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 15:01 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/08/2015 15:01 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 15:01 MHH71310.005 1
18 of 83
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120100
2015037878
Collection Date:03-Dec-15 3:30 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 00:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 00:31 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 00:31 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/05/2015 13:50 CJELLIO251
Total Carbon
TOC 0.202 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/05/2015 10:34 CJELLIO51
M2 - Hg MS/MSD recovery at 41% . The sample was diluted and reanalyzed at a10x dilution which produced 87%
recovery. Matrix interference is suspected.
-- Additional Information --
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
19 of 83
#=CL#
December 10, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278491
92278491
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120100
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 04, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 16
20 of 83
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278491
J15120100
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
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Virginia Environmental Certification #: 460165
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Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 16
21 of 83
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278491
J15120100
Lab ID Sample ID Matrix Date Collected Date Received
92278491001 2015037873 Water 12/03/15 09:30 12/04/15 11:20
92278491002 2015037874 Water 12/03/15 12:35 12/04/15 11:20
92278491003 2015037875 Water 12/03/15 09:11 12/04/15 11:20
92278491004 2015037876 Water 12/03/15 14:21 12/04/15 11:20
92278491005 2015037878 Water 12/03/15 15:30 12/04/15 11:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 16
22 of 83
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278491
J15120100
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278491001 2015037873 EPA 218.7 1 PASI-OTK1
92278491002 2015037874 EPA 218.7 1 PASI-OTK1
92278491003 2015037875 EPA 218.7 1 PASI-OTK1
92278491004 2015037876 EPA 218.7 1 PASI-OTK1
92278491005 2015037878 EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 16
23 of 83
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278491
J15120100
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278491001 2015037873
Chromium, Hexavalent 0.20 ug/L 12/10/15 09:370.030EPA 218.7
92278491004 2015037876
Chromium, Hexavalent 13.6 ug/L 12/10/15 10:163.0EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 16
24 of 83
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278491
J15120100
Method:
Client:Duke Energy
EPA 218.7
Date:December 10, 2015
Description:Hexavalent Chromium by IC
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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25 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278491
J15120100
Sample:2015037873 Lab ID:92278491001 Collected:12/03/15 09:30 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.20 ug/L 12/10/15 09:37 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278491
J15120100
Sample:2015037874 Lab ID:92278491002 Collected:12/03/15 12:35 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 09:50 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278491
J15120100
Sample:2015037875 Lab ID:92278491003 Collected:12/03/15 09:11 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 10:03 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278491
J15120100
Sample:2015037876 Lab ID:92278491004 Collected:12/03/15 14:21 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 13.6 ug/L 12/10/15 10:16 18540-29-93.0 100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278491
J15120100
Sample:2015037878 Lab ID:92278491005 Collected:12/03/15 15:30 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 10:29 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278491
J15120100
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52816
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92278491001, 92278491002, 92278491003, 92278491004, 92278491005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1413840
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/10/15 00:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1413841LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.069.075 92 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1413842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278480007
1413843
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .025 91 85-11598 3 20.0250.035 0.058 0.060
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1413844MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278480017
1413845
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 99 85-115108 7 20.075ND 0.091 0.097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278491
J15120100
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278491
J15120100
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278491001 WETA/528162015037873EPA 218.7
92278491002 WETA/528162015037874EPA 218.7
92278491003 WETA/528162015037875EPA 218.7
92278491004 WETA/528162015037876EPA 218.7
92278491005 WETA/528162015037878EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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[phone]
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Page 15 of 16
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Page 16 of 16
35 of 83
#=CL#
December 21, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278985
92278985
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120100 REV
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 09, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Revised report for conformation of analysis
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278985
J15120100 REV
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278985
J15120100 REV
Lab ID Sample ID Matrix Date Collected Date Received
92278985001 2015037873 Water 12/03/15 09:30 12/09/15 09:38
92278985002 2015037874 Water 12/03/15 12:35 12/09/15 09:38
92278985003 2015037875 Water 12/03/15 09:11 12/09/15 09:38
92278985004 2015037876 Water 12/03/15 14:21 12/09/15 09:38
92278985005 2015037878 Water 12/03/15 15:30 12/09/15 09:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
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38 of 83
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278985
J15120100 REV
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278985001 2015037873 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ASER
92278985002 2015037874 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ASER
92278985003 2015037875 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ASER
92278985004 2015037876 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ASER
92278985005 2015037878 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ASER
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278985
J15120100 REV
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278985001 2015037873
Alkalinity,Bicarbonate (CaCO3)74.9 mg/L 12/10/15 17:375.0SM 2320B
Alkalinity, Total as CaCO3 74.9 mg/L 12/10/15 17:375.0SM 2320B
92278985002 2015037874
Methane 3340 ug/L 12/10/15 15:31 1g,CL10.0RSK 175
Alkalinity,Bicarbonate (CaCO3)280 mg/L 12/10/15 17:485.0SM 2320B
Alkalinity, Carbonate (CaCO3)86.5 mg/L 12/10/15 17:485.0SM 2320B
Alkalinity, Total as CaCO3 366 mg/L 12/10/15 17:485.0SM 2320B
92278985003 2015037875
Alkalinity,Bicarbonate (CaCO3)103 mg/L 12/10/15 18:525.0SM 2320B
Alkalinity, Total as CaCO3 103 mg/L 12/10/15 18:525.0SM 2320B
92278985004 2015037876
Alkalinity,Bicarbonate (CaCO3)69.6 mg/L 12/10/15 19:235.0SM 2320B
Alkalinity, Total as CaCO3 70.7 mg/L 12/10/15 19:235.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278985
J15120100 REV
Method:
Client:Duke Energy
RSK 175
Date:December 21, 2015
Description:RSK 175 AIR Headspace
General Information:
5 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: AIR/24818
CL: The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased low.
• 2015037873 (Lab ID: 92278985001)
• Methane
• 2015037874 (Lab ID: 92278985002)
• Methane
• 2015037875 (Lab ID: 92278985003)
• Methane
• 2015037876 (Lab ID: 92278985004)
• Methane
• 2015037878 (Lab ID: 92278985005)
• Methane
• BLANK (Lab ID: 2154687)
• Methane
• DUP (Lab ID: 2154690)
• Methane
• DUP (Lab ID: 2154691)
• Methane
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278985
J15120100 REV
Method:
Client:Duke Energy
RSK 175
Date:December 21, 2015
Description:RSK 175 AIR Headspace
Additional Comments:
Analyte Comments:
QC Batch: AIR/24818
1g: Result confirmed by second analysis performed out of hold.
• 2015037873 (Lab ID: 92278985001)
• Methane
• 2015037874 (Lab ID: 92278985002)
• Methane
• 2015037875 (Lab ID: 92278985003)
• Methane
• 2015037876 (Lab ID: 92278985004)
• Methane
• 2015037878 (Lab ID: 92278985005)
• Methane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278985
J15120100 REV
Method:
Client:Duke Energy
SM 2320B
Date:December 21, 2015
Description:2320B Alkalinity
General Information:
5 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/41869
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92278978001,92278980001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1624766)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1624767)
• Alkalinity, Total as CaCO3
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278985
J15120100 REV
Sample:2015037873 Lab ID:92278985001 Collected:12/03/15 09:30 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 15:00 74-82-8 1g,CL10.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)74.9 mg/L 12/10/15 17:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 17:375.0 1
Alkalinity, Total as CaCO3 74.9 mg/L 12/10/15 17:375.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278985
J15120100 REV
Sample:2015037874 Lab ID:92278985002 Collected:12/03/15 12:35 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 3340 ug/L 12/10/15 15:31 74-82-8 1g,CL10.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)280 mg/L 12/10/15 17:485.0 1
Alkalinity, Carbonate (CaCO3)86.5 mg/L 12/10/15 17:485.0 1
Alkalinity, Total as CaCO3 366 mg/L 12/10/15 17:485.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278985
J15120100 REV
Sample:2015037875 Lab ID:92278985003 Collected:12/03/15 09:11 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 15:47 74-82-8 1g,CL10.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)103 mg/L 12/10/15 18:525.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 18:525.0 1
Alkalinity, Total as CaCO3 103 mg/L 12/10/15 18:525.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
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[phone]
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46 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278985
J15120100 REV
Sample:2015037876 Lab ID:92278985004 Collected:12/03/15 14:21 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 15:56 74-82-8 1g,CL10.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)69.6 mg/L 12/10/15 19:235.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 19:235.0 1
Alkalinity, Total as CaCO3 70.7 mg/L 12/10/15 19:235.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278985
J15120100 REV
Sample:2015037878 Lab ID:92278985005 Collected:12/03/15 15:30 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 16:04 74-82-8 1g,CL10.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 20:175.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 20:175.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 20:175.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278985
J15120100 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24818
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92278985001, 92278985002, 92278985003, 92278985004, 92278985005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2154687
Associated Lab Samples:92278985001, 92278985002, 92278985003, 92278985004, 92278985005
Matrix:Water
Analyzed
Methane ug/L ND 10.0 CL12/10/15 13:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2154688LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2154689
Methane ug/L 54.960.7 90 85-1158853.4 3 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278975001
2154690SAMPLE DUPLICATE:
Methane ug/L 4.9J CL20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278985002
2154691SAMPLE DUPLICATE:
Methane ug/L 3270 CL2203340
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 21
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278985
J15120100 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41869
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92278985001, 92278985002, 92278985003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1624764
Associated Lab Samples:92278985001, 92278985002, 92278985003
Matrix:Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 12/10/15 11:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1624765LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 51.050 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624766MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278978001
1624767
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1507780-12075 1 255090.2 129 128
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624768MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278980001
1624769
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 96 80-12098 1 255052.8 101 102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 21
50 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278985
J15120100 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41870
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92278985004, 92278985005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1624770
Associated Lab Samples:92278985004, 92278985005
Matrix:Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 12/10/15 19:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1624771LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.450 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624772MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278985004
1624773
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 255070.7 119 119
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624774MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278988009
1624775
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120101 1 2550ND52.5 53.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 21
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278985
J15120100 REV
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Result confirmed by second analysis performed out of hold.1g
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased
low.CL
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278985
J15120100 REV
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278985001 AIR/248182015037873RSK 175
92278985002 AIR/248182015037874RSK 175
92278985003 AIR/248182015037875RSK 175
92278985004 AIR/248182015037876RSK 175
92278985005 AIR/248182015037878RSK 175
92278985001 WET/418692015037873SM 2320B
92278985002 WET/418692015037874SM 2320B
92278985003 WET/418692015037875SM 2320B
92278985004 WET/418702015037876SM 2320B
92278985005 WET/418702015037878SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/21/2015 02:31 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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