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Home My WebLink AboutNC0038377_J15120069-F_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15120069 Project Name:MAYO STEAM - AB GW ASSESSMENT WATER Lab Contact:Anne Pifer Date:12/10/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie,Brandon Russo, Kathy Webb, John Toepfer Phone: Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Anne Pifer) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Anne Pifer Page 1 of 133 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015037738 MAYO STEAM 02-Dec-15 10:15 AM Erin Black MW-7D 2015037739 MAYO STEAM 02-Dec-15 9:30 AM Erin Black MW-7BR 2015037740 MAYO STEAM 02-Dec-15 2:20 PM Erin Black MW-9BR 2015037741 MAYO STEAM 02-Dec-15 9:41 AM Erin Black MW-8BR 2015037742 MAYO STEAM 02-Dec-15 5:01 PM Erin Black MW-12S 2015037743 MAYO STEAM 02-Dec-15 3:41 PM Erin Black MW-12D 2015037744 MAYO STEAM 02-Dec-15 3:41 PM Erin Black MW-12D DUP 2015037745 MAYO STEAM 02-Dec-15 12:11 PM Erin Black MW-13BR 2015037746 MAYO STEAM 02-Dec-15 10:55 AM Erin Black MW-14BR 2015037747 MAYO STEAM 02-Dec-15 2:05 PM Erin Black MW-3BR 2015037748 MAYO STEAM 02-Dec-15 8:45 AM Erin Black MW-5BR 2015037749 MAYO STEAM 02-Dec-15 10:45 AM Erin Black Filter Blank 2015037750 MAYO STEAM 02-Dec-15 10:45 AM Erin Black Equipment Blank 2015037751 MAYO STEAM 02-Dec-15 4:45 PM Erin Black CW-2 2015037752 MAYO STEAM 02-Dec-15 3:40 PM Erin Black CW-2D 15 Total Samples Page 2 of 133 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:12/10/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037738 Collection Date:02-Dec-15 10:15 AM Site:MW-7D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 08:16M2 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 71 mg/L EPA 300.0 12/03/2015 13:00 BGN9034110 Sulfate 9.9 mg/L EPA 300.0 12/03/2015 13:00 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 09:43 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 14:50 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 10:58 FCJORDA0.005 1 Barium (Ba)0.021 mg/L EPA 200.7 12/04/2015 10:58 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 10:58 FCJORDA0.05 1 Iron (Fe)0.098 mg/L EPA 200.7 12/04/2015 10:58 FCJORDA0.01 1 Manganese (Mn)0.101 mg/L EPA 200.7 12/04/2015 10:58 FCJORDA0.005 1 Strontium (Sr)0.429 mg/L EPA 200.7 12/04/2015 10:58 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 10:58 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)56.2 mg/L EPA 200.7 12/06/2015 12:10 FCJORDA0.01 1 Magnesium (Mg)22.5 mg/L EPA 200.7 12/06/2015 12:10 FCJORDA0.05 10 Potassium (K)2.12 mg/L EPA 200.7 12/06/2015 12:10 FCJORDA0.1 1 Sodium (Na)33.4 mg/L EPA 200.7 12/06/2015 12:10 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.034 mg/L EPA 200.7 12/08/2015 13:05B2 FCJORDA0.005 1 Barium (Ba)0.021 mg/L EPA 200.7 12/08/2015 13:05 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:05 FCJORDA0.05 1 Iron (Fe)0.348 mg/L EPA 200.7 12/08/2015 13:05 FCJORDA0.01 1 Manganese (Mn)0.093 mg/L EPA 200.7 12/08/2015 13:05 FCJORDA0.005 1 Strontium (Sr)0.448 mg/L EPA 200.7 12/08/2015 13:05 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 13:05 FCJORDA0.005 1 Page 4 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037738 Collection Date:02-Dec-15 10:15 AM Site:MW-7D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 12:37 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 12:37 MHALL30.2 1 Vanadium (V) Low Level 0.705 ug/L EPA 200.8 12/08/2015 12:37 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 05:16 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 05:16 MHALL30.2 1 Vanadium (V) Low Level 0.779 ug/L EPA 200.8 12/08/2015 05:16 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 370 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 1.4 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 5 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037739 Collection Date:02-Dec-15 9:30 AM Site:MW-7BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 08:20 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 12 mg/L EPA 300.0 12/03/2015 16:06 BGN90340.2 2 Sulfate 2.6 mg/L EPA 300.0 12/03/2015 16:06 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 09:52 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 14:52 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 11:09 FCJORDA0.005 1 Barium (Ba)0.153 mg/L EPA 200.7 12/04/2015 11:09 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:09 FCJORDA0.05 1 Iron (Fe)0.446 mg/L EPA 200.7 12/04/2015 11:09 FCJORDA0.01 1 Manganese (Mn)0.221 mg/L EPA 200.7 12/04/2015 11:09 FCJORDA0.005 1 Strontium (Sr)1.05 mg/L EPA 200.7 12/04/2015 11:09 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 11:09 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)56.5 mg/L EPA 200.7 12/06/2015 12:21 FCJORDA0.01 1 Magnesium (Mg)13.0 mg/L EPA 200.7 12/06/2015 12:21 FCJORDA0.005 1 Potassium (K)4.31 mg/L EPA 200.7 12/06/2015 12:21 FCJORDA0.1 1 Sodium (Na)16.5 mg/L EPA 200.7 12/06/2015 12:21 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.017 mg/L EPA 200.7 12/08/2015 13:16B2 FCJORDA0.005 1 Barium (Ba)0.156 mg/L EPA 200.7 12/08/2015 13:16 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:16 FCJORDA0.05 1 Iron (Fe)0.551 mg/L EPA 200.7 12/08/2015 13:16 FCJORDA0.01 1 Manganese (Mn)0.224 mg/L EPA 200.7 12/08/2015 13:16 FCJORDA0.005 1 Strontium (Sr)1.10 mg/L EPA 200.7 12/08/2015 13:16 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 13:16 FCJORDA0.005 1 Page 6 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037739 Collection Date:02-Dec-15 9:30 AM Site:MW-7BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Molybdenum (Mo)2.45 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 13:17 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 13:17 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 13:17 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Molybdenum (Mo)2.92 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 04:40 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 04:40 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 04:40 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 250 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 1.0 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 7 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037740 Collection Date:02-Dec-15 2:20 PM Site:MW-9BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.183 mg-N/L EPA 353.2 12/08/2015 08:21 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 24 mg/L EPA 300.0 12/03/2015 16:23 BGN90340.5 5 Sulfate 8.9 mg/L EPA 300.0 12/03/2015 16:23 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 09:55 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 14:54 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.013 mg/L EPA 200.7 12/04/2015 11:21 FCJORDA0.005 1 Barium (Ba)0.009 mg/L EPA 200.7 12/04/2015 11:21 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:21 FCJORDA0.05 1 Iron (Fe)0.165 mg/L EPA 200.7 12/04/2015 11:21 FCJORDA0.01 1 Manganese (Mn)0.902 mg/L EPA 200.7 12/04/2015 11:21 FCJORDA0.005 1 Strontium (Sr)0.104 mg/L EPA 200.7 12/04/2015 11:21 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 11:21 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)9.98 mg/L EPA 200.7 12/06/2015 12:32 FCJORDA0.01 1 Magnesium (Mg)2.91 mg/L EPA 200.7 12/06/2015 12:32 FCJORDA0.005 1 Potassium (K)1.90 mg/L EPA 200.7 12/06/2015 12:32 FCJORDA0.1 1 Sodium (Na)12.9 mg/L EPA 200.7 12/06/2015 12:32 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)3.79 mg/L EPA 200.7 12/08/2015 13:20B2 FCJORDA0.005 1 Barium (Ba)0.009 mg/L EPA 200.7 12/08/2015 13:20 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:20 FCJORDA0.05 1 Iron (Fe)3.69 mg/L EPA 200.7 12/08/2015 13:20 FCJORDA0.01 1 Manganese (Mn)0.451 mg/L EPA 200.7 12/08/2015 13:20 FCJORDA0.005 1 Strontium (Sr)0.048 mg/L EPA 200.7 12/08/2015 13:20 FCJORDA0.005 1 Zinc (Zn)0.007 mg/L EPA 200.7 12/08/2015 13:20 FCJORDA0.005 1 Page 8 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037740 Collection Date:02-Dec-15 2:20 PM Site:MW-9BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Copper (Cu)9.00 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Nickel (Ni)2.41 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 13:23 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 13:23 MHALL30.2 1 Vanadium (V) Low Level 1.03 ug/L EPA 200.8 12/08/2015 13:23 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Chromium (Cr)3.72 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Copper (Cu)15.5 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Nickel (Ni)1.62 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 05:23 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 05:23 MHALL30.2 1 Vanadium (V) Low Level 5.41 ug/L EPA 200.8 12/08/2015 05:23 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 220 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 3.6 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI110 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 9 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037741 Collection Date:02-Dec-15 9:41 AM Site:MW-8BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.110 mg-N/L EPA 353.2 12/08/2015 08:22 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 120 mg/L EPA 300.0 12/03/2015 16:40 BGN90342.5 25 Sulfate 34 mg/L EPA 300.0 12/03/2015 16:40 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 09:57 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 14:57 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 11:33 FCJORDA0.005 1 Barium (Ba)0.039 mg/L EPA 200.7 12/04/2015 11:33 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:33 FCJORDA0.05 1 Iron (Fe)0.332 mg/L EPA 200.7 12/04/2015 11:33 FCJORDA0.01 1 Manganese (Mn)0.913 mg/L EPA 200.7 12/04/2015 11:33 FCJORDA0.005 1 Strontium (Sr)0.380 mg/L EPA 200.7 12/04/2015 11:33 FCJORDA0.005 1 Zinc (Zn)0.028 mg/L EPA 200.7 12/04/2015 11:33 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)80.8 mg/L EPA 200.7 12/06/2015 12:44 FCJORDA0.01 1 Magnesium (Mg)21.8 mg/L EPA 200.7 12/06/2015 12:44 FCJORDA0.05 10 Potassium (K)5.98 mg/L EPA 200.7 12/06/2015 12:44 FCJORDA0.1 1 Sodium (Na)34.1 mg/L EPA 200.7 12/06/2015 12:44 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.083 mg/L EPA 200.7 12/08/2015 13:24B2 FCJORDA0.005 1 Barium (Ba)0.039 mg/L EPA 200.7 12/08/2015 13:24 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:24 FCJORDA0.05 1 Iron (Fe)0.468 mg/L EPA 200.7 12/08/2015 13:24 FCJORDA0.01 1 Manganese (Mn)0.911 mg/L EPA 200.7 12/08/2015 13:24 FCJORDA0.005 1 Strontium (Sr)0.400 mg/L EPA 200.7 12/08/2015 13:24 FCJORDA0.005 1 Zinc (Zn)0.030 mg/L EPA 200.7 12/08/2015 13:24 FCJORDA0.005 1 Page 10 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037741 Collection Date:02-Dec-15 9:41 AM Site:MW-8BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Cobalt (Co)1.13 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Molybdenum (Mo)3.60 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Nickel (Ni)3.26 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 13:28 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 13:28 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 13:28 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Molybdenum (Mo)3.62 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Nickel (Ni)3.92 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 05:30 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 05:30 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 05:30 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 500 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 1.5 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 11 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037742 Collection Date:02-Dec-15 5:01 PM Site:MW-12S Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.638 mg-N/L EPA 353.2 12/08/2015 08:23 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 3.3 mg/L EPA 300.0 12/03/2015 14:08 BGN90340.1 1 Sulfate 1.3 mg/L EPA 300.0 12/03/2015 14:08 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 09:59 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 14:59 TLINN0.05 1 Mercury Dissolved (cold vapor) in Water (0.1mm FILTER) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:02 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.015 mg/L EPA 200.7 12/04/2015 11:39 FCJORDA0.005 1 Barium (Ba)0.012 mg/L EPA 200.7 12/04/2015 11:39 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:39 FCJORDA0.05 1 Iron (Fe)0.087 mg/L EPA 200.7 12/04/2015 11:39 FCJORDA0.01 1 Manganese (Mn)0.137 mg/L EPA 200.7 12/04/2015 11:39 FCJORDA0.005 1 Strontium (Sr)0.019 mg/L EPA 200.7 12/04/2015 11:39 FCJORDA0.005 1 Zinc (Zn)0.078 mg/L EPA 200.7 12/04/2015 11:39 FCJORDA0.005 1 DISSOLVED METALS BY ICP (0.1mm FILTER) Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 13:47 FCJORDA0.005 1 Barium (Ba)0.012 mg/L EPA 200.7 12/04/2015 13:47 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 13:47 FCJORDA0.05 1 Iron (Fe)0.066 mg/L EPA 200.7 12/04/2015 13:47 FCJORDA0.01 1 Manganese (Mn)0.142 mg/L EPA 200.7 12/04/2015 13:47 FCJORDA0.005 1 Strontium (Sr)0.020 mg/L EPA 200.7 12/04/2015 13:47 FCJORDA0.005 1 Zinc (Zn)0.084 mg/L EPA 200.7 12/04/2015 13:47 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)1.56 mg/L EPA 200.7 12/06/2015 12:48 FCJORDA0.01 1 Magnesium (Mg)0.792 mg/L EPA 200.7 12/06/2015 12:48 FCJORDA0.005 1 Potassium (K)1.40 mg/L EPA 200.7 12/06/2015 12:48 FCJORDA0.1 1 Sodium (Na)5.08 mg/L EPA 200.7 12/06/2015 12:48 FCJORDA0.05 1 Page 12 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037742 Collection Date:02-Dec-15 5:01 PM Site:MW-12S Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.164 mg/L EPA 200.7 12/08/2015 13:28B2 FCJORDA0.005 1 Barium (Ba)0.016 mg/L EPA 200.7 12/08/2015 13:28 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:28 FCJORDA0.05 1 Iron (Fe)0.336 mg/L EPA 200.7 12/08/2015 13:28 FCJORDA0.01 1 Manganese (Mn)0.152 mg/L EPA 200.7 12/08/2015 13:28 FCJORDA0.005 1 Strontium (Sr)0.021 mg/L EPA 200.7 12/08/2015 13:28 FCJORDA0.005 1 Zinc (Zn)0.079 mg/L EPA 200.7 12/08/2015 13:28 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Chromium (Cr)2.01 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Nickel (Ni)2.71 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 13:34 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 13:34 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 13:34 MHALL30.3 1 Total Recoverable Metals Dissolved 0.1mm Filter Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Nickel (Ni)2.48 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 23:00 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 23:00 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 23:00 MHALL30.3 1 Page 13 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037742 Collection Date:02-Dec-15 5:01 PM Site:MW-12S Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Chromium (Cr)7.17 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Nickel (Ni)5.41 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 05:38 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 05:38 MHALL30.2 1 Vanadium (V) Low Level 0.313 ug/L EPA 200.8 12/08/2015 05:38 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 26 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 0.519 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 14 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037743 Collection Date:02-Dec-15 3:41 PM Site:MW-12D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.132 mg-N/L EPA 353.2 12/08/2015 08:27 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 4.5 mg/L EPA 300.0 12/03/2015 14:25 BGN90340.1 1 Sulfate 1.0 mg/L EPA 300.0 12/03/2015 14:25 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:02 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:01 TLINN0.05 1 Mercury Dissolved (cold vapor) in Water (0.1mm FILTER) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 16:55 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 11:44 FCJORDA0.005 1 Barium (Ba)0.018 mg/L EPA 200.7 12/04/2015 11:44 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:44 FCJORDA0.05 1 Iron (Fe)0.032 mg/L EPA 200.7 12/04/2015 11:44 FCJORDA0.01 1 Manganese (Mn)0.185 mg/L EPA 200.7 12/04/2015 11:44 FCJORDA0.005 1 Strontium (Sr)0.087 mg/L EPA 200.7 12/04/2015 11:44 FCJORDA0.005 1 Zinc (Zn)0.015 mg/L EPA 200.7 12/04/2015 11:44 FCJORDA0.005 1 DISSOLVED METALS BY ICP (0.1mm FILTER) Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 13:59 FCJORDA0.005 1 Barium (Ba)0.019 mg/L EPA 200.7 12/04/2015 13:59 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 13:59 FCJORDA0.05 1 Iron (Fe)0.029 mg/L EPA 200.7 12/04/2015 13:59 FCJORDA0.01 1 Manganese (Mn)0.187 mg/L EPA 200.7 12/04/2015 13:59 FCJORDA0.005 1 Strontium (Sr)0.088 mg/L EPA 200.7 12/04/2015 13:59 FCJORDA0.005 1 Zinc (Zn)0.014 mg/L EPA 200.7 12/04/2015 13:59 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)11.3 mg/L EPA 200.7 12/06/2015 12:51 FCJORDA0.01 1 Magnesium (Mg)3.22 mg/L EPA 200.7 12/06/2015 12:51 FCJORDA0.005 1 Potassium (K)1.46 mg/L EPA 200.7 12/06/2015 12:51 FCJORDA0.1 1 Sodium (Na)9.18 mg/L EPA 200.7 12/06/2015 12:51 FCJORDA0.05 1 Page 15 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037743 Collection Date:02-Dec-15 3:41 PM Site:MW-12D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.306 mg/L EPA 200.7 12/08/2015 13:32B2 FCJORDA0.005 1 Barium (Ba)0.021 mg/L EPA 200.7 12/08/2015 13:32 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:32 FCJORDA0.05 1 Iron (Fe)0.504 mg/L EPA 200.7 12/08/2015 13:32 FCJORDA0.01 1 Manganese (Mn)0.193 mg/L EPA 200.7 12/08/2015 13:32 FCJORDA0.005 1 Strontium (Sr)0.090 mg/L EPA 200.7 12/08/2015 13:32 FCJORDA0.005 1 Zinc (Zn)0.016 mg/L EPA 200.7 12/08/2015 13:32 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Nickel (Ni)1.76 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 13:41 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 13:41 MHALL30.2 1 Vanadium (V) Low Level 0.366 ug/L EPA 200.8 12/08/2015 13:41 MHALL30.3 1 Total Recoverable Metals Dissolved 0.1mm Filter Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Nickel (Ni)1.80 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 23:18 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 23:18 MHALL30.2 1 Vanadium (V) Low Level 0.398 ug/L EPA 200.8 12/07/2015 23:18 MHALL30.3 1 Page 16 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037743 Collection Date:02-Dec-15 3:41 PM Site:MW-12D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)1.44 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Chromium (Cr)3.43 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Nickel (Ni)3.01 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 05:45 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 05:45 MHALL30.2 1 Vanadium (V) Low Level 1.01 ug/L EPA 200.8 12/08/2015 05:45 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 97 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 0.266 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 17 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037744 Collection Date:02-Dec-15 3:41 PM Site:MW-12D DUP Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.143 mg-N/L EPA 353.2 12/08/2015 08:28 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 4.5 mg/L EPA 300.0 12/03/2015 14:42 BGN90340.1 1 Sulfate 1.1 mg/L EPA 300.0 12/03/2015 14:42 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:04 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:04 TLINN0.05 1 Mercury Dissolved (cold vapor) in Water (0.1mm FILTER) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:04 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 11:48 FCJORDA0.005 1 Barium (Ba)0.018 mg/L EPA 200.7 12/04/2015 11:48 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:48 FCJORDA0.05 1 Iron (Fe)0.032 mg/L EPA 200.7 12/04/2015 11:48 FCJORDA0.01 1 Manganese (Mn)0.187 mg/L EPA 200.7 12/04/2015 11:48 FCJORDA0.005 1 Strontium (Sr)0.088 mg/L EPA 200.7 12/04/2015 11:48 FCJORDA0.005 1 Zinc (Zn)0.014 mg/L EPA 200.7 12/04/2015 11:48 FCJORDA0.005 1 DISSOLVED METALS BY ICP (0.1mm FILTER) Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 14:11 FCJORDA0.005 1 Barium (Ba)0.018 mg/L EPA 200.7 12/04/2015 14:11 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 14:11 FCJORDA0.05 1 Iron (Fe)0.030 mg/L EPA 200.7 12/04/2015 14:11 FCJORDA0.01 1 Manganese (Mn)0.188 mg/L EPA 200.7 12/04/2015 14:11 FCJORDA0.005 1 Strontium (Sr)0.088 mg/L EPA 200.7 12/04/2015 14:11 FCJORDA0.005 1 Zinc (Zn)0.017 mg/L EPA 200.7 12/04/2015 14:11 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)11.3 mg/L EPA 200.7 12/06/2015 12:55 FCJORDA0.01 1 Magnesium (Mg)3.20 mg/L EPA 200.7 12/06/2015 12:55 FCJORDA0.005 1 Potassium (K)1.44 mg/L EPA 200.7 12/06/2015 12:55 FCJORDA0.1 1 Sodium (Na)9.24 mg/L EPA 200.7 12/06/2015 12:55 FCJORDA0.05 1 Page 18 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037744 Collection Date:02-Dec-15 3:41 PM Site:MW-12D DUP Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.239 mg/L EPA 200.7 12/08/2015 13:36B2 FCJORDA0.005 1 Barium (Ba)0.020 mg/L EPA 200.7 12/08/2015 13:36 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:36 FCJORDA0.05 1 Iron (Fe)0.393 mg/L EPA 200.7 12/08/2015 13:36 FCJORDA0.01 1 Manganese (Mn)0.193 mg/L EPA 200.7 12/08/2015 13:36 FCJORDA0.005 1 Strontium (Sr)0.091 mg/L EPA 200.7 12/08/2015 13:36 FCJORDA0.005 1 Zinc (Zn)0.017 mg/L EPA 200.7 12/08/2015 13:36 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Nickel (Ni)1.54 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 13:49 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 13:49 MHALL30.2 1 Vanadium (V) Low Level 0.414 ug/L EPA 200.8 12/08/2015 13:49 MHALL30.3 1 Total Recoverable Metals Dissolved 0.1mm Filter Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Nickel (Ni)1.65 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 23:24 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 23:24 MHALL30.2 1 Vanadium (V) Low Level 0.401 ug/L EPA 200.8 12/07/2015 23:24 MHALL30.3 1 Page 19 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037744 Collection Date:02-Dec-15 3:41 PM Site:MW-12D DUP Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Chromium (Cr)3.13 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Nickel (Ni)2.52 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 05:53 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 05:53 MHALL30.2 1 Vanadium (V) Low Level 0.768 ug/L EPA 200.8 12/08/2015 05:53 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 69 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 0.251 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 20 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037745 Collection Date:02-Dec-15 12:11 PM Site:MW-13BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 08:29 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 41 mg/L EPA 300.0 12/03/2015 14:58 BGN9034110 Sulfate 14 mg/L EPA 300.0 12/03/2015 14:58 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:07 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:06 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 11:52 FCJORDA0.005 1 Barium (Ba)0.041 mg/L EPA 200.7 12/04/2015 11:52 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:52 FCJORDA0.05 1 Iron (Fe)1.98 mg/L EPA 200.7 12/04/2015 11:52 FCJORDA0.01 1 Manganese (Mn)0.520 mg/L EPA 200.7 12/04/2015 11:52 FCJORDA0.005 1 Strontium (Sr)0.398 mg/L EPA 200.7 12/04/2015 11:52 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 11:52 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)72.7 mg/L EPA 200.7 12/06/2015 13:03 FCJORDA0.01 1 Magnesium (Mg)13.5 mg/L EPA 200.7 12/06/2015 13:03 FCJORDA0.005 1 Potassium (K)5.09 mg/L EPA 200.7 12/06/2015 13:03 FCJORDA0.1 1 Sodium (Na)23.3 mg/L EPA 200.7 12/06/2015 13:03 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.171 mg/L EPA 200.7 12/08/2015 13:40B2 FCJORDA0.005 1 Barium (Ba)0.045 mg/L EPA 200.7 12/08/2015 13:40 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:40 FCJORDA0.05 1 Iron (Fe)2.49 mg/L EPA 200.7 12/08/2015 13:40 FCJORDA0.01 1 Manganese (Mn)0.548 mg/L EPA 200.7 12/08/2015 13:40 FCJORDA0.005 1 Strontium (Sr)0.416 mg/L EPA 200.7 12/08/2015 13:40 FCJORDA0.005 1 Zinc (Zn)0.054 mg/L EPA 200.7 12/08/2015 13:40 FCJORDA0.005 1 Page 21 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037745 Collection Date:02-Dec-15 12:11 PM Site:MW-13BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Molybdenum (Mo)4.38 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 17:13 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 17:13 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 17:13 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Chromium (Cr)16.3 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Copper (Cu)1.20 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Molybdenum (Mo)5.86 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Nickel (Ni)7.97 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 06:00 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 06:00 MHALL30.2 1 Vanadium (V) Low Level 0.429 ug/L EPA 200.8 12/08/2015 06:00 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 330 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 0.761 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 9.0 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 22 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037746 Collection Date:02-Dec-15 10:55 AM Site:MW-14BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.112 mg-N/L EPA 353.2 12/08/2015 08:31 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 11 mg/L EPA 300.0 12/03/2015 15:15 BGN9034110 Sulfate 10 mg/L EPA 300.0 12/03/2015 15:15 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:09 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (0.1mm FILTER) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:06 TLINN0.05 1 DISSOLVED METALS BY ICP (0.1mm FILTER) Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 14:14 FCJORDA0.005 1 Barium (Ba)0.021 mg/L EPA 200.7 12/04/2015 14:14 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 14:14 FCJORDA0.05 1 Iron (Fe)0.271 mg/L EPA 200.7 12/04/2015 14:14 FCJORDA0.01 1 Manganese (Mn)0.312 mg/L EPA 200.7 12/04/2015 14:14 FCJORDA0.005 1 Strontium (Sr)0.136 mg/L EPA 200.7 12/04/2015 14:14 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 14:14 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)13.4 mg/L EPA 200.7 12/06/2015 13:12 FCJORDA0.01 1 Magnesium (Mg)2.29 mg/L EPA 200.7 12/06/2015 13:12 FCJORDA0.005 1 Potassium (K)5.75 mg/L EPA 200.7 12/06/2015 13:12 FCJORDA0.1 1 Sodium (Na)41.6 mg/L EPA 200.7 12/06/2015 13:12 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.077 mg/L EPA 200.7 12/08/2015 13:43B2 FCJORDA0.005 1 Barium (Ba)0.022 mg/L EPA 200.7 12/08/2015 13:43 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:43 FCJORDA0.05 1 Iron (Fe)0.396 mg/L EPA 200.7 12/08/2015 13:43 FCJORDA0.01 1 Manganese (Mn)0.304 mg/L EPA 200.7 12/08/2015 13:43 FCJORDA0.005 1 Strontium (Sr)0.141 mg/L EPA 200.7 12/08/2015 13:43 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 13:43 FCJORDA0.005 1 Page 23 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037746 Collection Date:02-Dec-15 10:55 AM Site:MW-14BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Total Recoverable Metals Dissolved 0.1mm Filter Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Molybdenum (Mo)6.34 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Nickel (Ni)1.03 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 23:29 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 23:29 MHALL30.2 1 Vanadium (V) Low Level 1.44 ug/L EPA 200.8 12/07/2015 23:29 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Molybdenum (Mo)6.62 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 16:37 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 16:37 MHALL30.2 1 Vanadium (V) Low Level 1.82 ug/L EPA 200.8 12/08/2015 16:37 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 210 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 0.822 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 24 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037747 Collection Date:02-Dec-15 2:05 PM Site:MW-3BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 08:32 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 140 mg/L EPA 300.0 12/03/2015 16:57 BGN9034220 Sulfate 8.9 mg/L EPA 300.0 12/03/2015 16:57 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:11 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:13 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 11:56 FCJORDA0.005 1 Barium (Ba)0.046 mg/L EPA 200.7 12/04/2015 11:56 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 11:56 FCJORDA0.05 1 Iron (Fe)0.147 mg/L EPA 200.7 12/04/2015 11:56 FCJORDA0.01 1 Manganese (Mn)0.729 mg/L EPA 200.7 12/04/2015 11:56 FCJORDA0.005 1 Strontium (Sr)0.378 mg/L EPA 200.7 12/04/2015 11:56 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 11:56 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)135 mg/L EPA 200.7 12/06/2015 13:16 FCJORDA0.1 10 Magnesium (Mg)10.6 mg/L EPA 200.7 12/06/2015 13:16 FCJORDA0.005 1 Potassium (K)8.09 mg/L EPA 200.7 12/06/2015 13:16 FCJORDA0.1 1 Sodium (Na)24.0 mg/L EPA 200.7 12/06/2015 13:16 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.020 mg/L EPA 200.7 12/08/2015 13:47B2 FCJORDA0.005 1 Barium (Ba)0.046 mg/L EPA 200.7 12/08/2015 13:47 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:47 FCJORDA0.05 1 Iron (Fe)0.171 mg/L EPA 200.7 12/08/2015 13:47 FCJORDA0.01 1 Manganese (Mn)0.737 mg/L EPA 200.7 12/08/2015 13:47 FCJORDA0.005 1 Strontium (Sr)0.396 mg/L EPA 200.7 12/08/2015 13:47 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 13:47 FCJORDA0.005 1 Page 25 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037747 Collection Date:02-Dec-15 2:05 PM Site:MW-3BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Molybdenum (Mo)2.40 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 17:36 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 17:36 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 17:36 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Molybdenum (Mo)2.57 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 16:54 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 16:54 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 16:54 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 590 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 1.9 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 26 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037748 Collection Date:02-Dec-15 8:45 AM Site:MW-5BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 08:38M2 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 65 mg/L EPA 300.0 12/03/2015 21:44 BGN9034110 Sulfate 0.31 mg/L EPA 300.0 12/03/2015 21:44 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:18 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:20 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.010 mg/L EPA 200.7 12/04/2015 12:00 FCJORDA0.005 1 Barium (Ba)0.039 mg/L EPA 200.7 12/04/2015 12:00 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 12:00 FCJORDA0.05 1 Iron (Fe)8.60 mg/L EPA 200.7 12/04/2015 12:00 FCJORDA0.01 1 Manganese (Mn)1.75 mg/L EPA 200.7 12/04/2015 12:00 FCJORDA0.005 1 Strontium (Sr)0.207 mg/L EPA 200.7 12/04/2015 12:00 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 12:00 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)88.2 mg/L EPA 200.7 12/06/2015 13:27 FCJORDA0.01 1 Magnesium (Mg)6.84 mg/L EPA 200.7 12/06/2015 13:27 FCJORDA0.005 1 Potassium (K)6.54 mg/L EPA 200.7 12/06/2015 13:27 FCJORDA0.1 1 Sodium (Na)17.3 mg/L EPA 200.7 12/06/2015 13:27 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.043 mg/L EPA 200.7 12/08/2015 13:59B2 FCJORDA0.005 1 Barium (Ba)0.039 mg/L EPA 200.7 12/08/2015 13:59 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 13:59 FCJORDA0.05 1 Iron (Fe)8.23 mg/L EPA 200.7 12/08/2015 13:59 FCJORDA0.01 1 Manganese (Mn)1.86 mg/L EPA 200.7 12/08/2015 13:59 FCJORDA0.005 1 Strontium (Sr)0.219 mg/L EPA 200.7 12/08/2015 13:59 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 13:59 FCJORDA0.005 1 Page 27 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037748 Collection Date:02-Dec-15 8:45 AM Site:MW-5BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Molybdenum (Mo)1.48 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 17:43 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 17:43 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 17:43 MHALL30.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Arsenic (As)1.39 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Molybdenum (Mo)2.26 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:01 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:01 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 17:01 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 370 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 2.6 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 24 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 28 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037749 Collection Date:02-Dec-15 10:45 AM Site:Filter Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:23 TLINN0.05 1 Mercury Dissolved (cold vapor) in Water (0.1mm FILTER) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:09 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 12:11 FCJORDA0.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 12/04/2015 12:11 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 12:11 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 12/04/2015 12:11 FCJORDA0.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 12/04/2015 12:11 FCJORDA0.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 12/04/2015 12:11 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 12:11 FCJORDA0.005 1 DISSOLVED METALS BY ICP (0.1mm FILTER) Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 14:18 FCJORDA0.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 12/04/2015 14:18 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/04/2015 14:18 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 12/04/2015 14:18 FCJORDA0.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 12/04/2015 14:18 FCJORDA0.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 12/04/2015 14:18 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/04/2015 14:18 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 17:50 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 17:50 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 17:50 MHALL30.3 1 Page 29 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037749 Collection Date:02-Dec-15 10:45 AM Site:Filter Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Total Recoverable Metals Dissolved 0.1mm Filter Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 23:35 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 23:35 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 23:35 MHALL30.3 1 Page 30 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037750 Collection Date:02-Dec-15 10:45 AM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 08:41 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 12/03/2015 19:12 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 12/03/2015 19:12 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:33 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.011 mg/L EPA 200.7 12/06/2015 13:31 FCJORDA0.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 12/06/2015 13:31 FCJORDA0.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 12/06/2015 13:31 FCJORDA0.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 12/06/2015 13:31 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/08/2015 14:10 FCJORDA0.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 12/08/2015 14:10 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 14:10 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 14:10 FCJORDA0.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 14:10 FCJORDA0.005 1 Strontium (Sr)0.006 mg/L EPA 200.7 12/08/2015 14:10 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 14:10 FCJORDA0.005 1 Page 31 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037750 Collection Date:02-Dec-15 10:45 AM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:07 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:07 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 17:07 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 0.178 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 32 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037751 Collection Date:02-Dec-15 4:45 PM Site:CW-2 Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.045 mg-N/L EPA 353.2 12/08/2015 08:43 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 57 mg/L EPA 300.0 12/03/2015 19:29 BGN9034220 Sulfate 35 mg/L EPA 300.0 12/03/2015 19:29 BGN9034220 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:35 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:25 TLINN0.05 1 Mercury Dissolved (cold vapor) in Water (0.1mm FILTER) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:11 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.014 mg/L EPA 200.7 12/04/2015 12:15 FCJORDA0.005 1 Barium (Ba)0.136 mg/L EPA 200.7 12/04/2015 12:15 FCJORDA0.005 1 Boron (B)0.659 mg/L EPA 200.7 12/04/2015 12:15 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 12/04/2015 12:15 FCJORDA0.01 1 Manganese (Mn)0.286 mg/L EPA 200.7 12/04/2015 12:15 FCJORDA0.005 1 Strontium (Sr)0.236 mg/L EPA 200.7 12/04/2015 12:15 FCJORDA0.005 1 Zinc (Zn)0.008 mg/L EPA 200.7 12/04/2015 12:15 FCJORDA0.005 1 DISSOLVED METALS BY ICP (0.1mm FILTER) Aluminum (Al)0.016 mg/L EPA 200.7 12/04/2015 14:22 FCJORDA0.005 1 Barium (Ba)0.147 mg/L EPA 200.7 12/04/2015 14:22 FCJORDA0.005 1 Boron (B)0.706 mg/L EPA 200.7 12/04/2015 14:22 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 12/04/2015 14:22 FCJORDA0.01 1 Manganese (Mn)0.309 mg/L EPA 200.7 12/04/2015 14:22 FCJORDA0.005 1 Strontium (Sr)0.248 mg/L EPA 200.7 12/04/2015 14:22 FCJORDA0.005 1 Zinc (Zn)0.007 mg/L EPA 200.7 12/04/2015 14:22 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)17.6 mg/L EPA 200.7 12/06/2015 13:35 FCJORDA0.01 1 Magnesium (Mg)8.98 mg/L EPA 200.7 12/06/2015 13:35 FCJORDA0.005 1 Potassium (K)2.12 mg/L EPA 200.7 12/06/2015 13:35 FCJORDA0.1 1 Sodium (Na)16.2 mg/L EPA 200.7 12/06/2015 13:35 FCJORDA0.05 1 Page 33 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037751 Collection Date:02-Dec-15 4:45 PM Site:CW-2 Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.172 mg/L EPA 200.7 12/08/2015 14:14B2 FCJORDA0.005 1 Barium (Ba)0.143 mg/L EPA 200.7 12/08/2015 14:14 FCJORDA0.005 1 Boron (B)0.665 mg/L EPA 200.7 12/08/2015 14:14 FCJORDA0.05 1 Iron (Fe)0.162 mg/L EPA 200.7 12/08/2015 14:14 FCJORDA0.01 1 Manganese (Mn)0.294 mg/L EPA 200.7 12/08/2015 14:14 FCJORDA0.005 1 Strontium (Sr)0.250 mg/L EPA 200.7 12/08/2015 14:14 FCJORDA0.005 1 Zinc (Zn)0.008 mg/L EPA 200.7 12/08/2015 14:14 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Nickel (Ni)1.85 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 17:56 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 17:56 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 17:56 MHALL30.3 1 Total Recoverable Metals Dissolved 0.1mm Filter Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Nickel (Ni)1.75 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 23:40 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 23:40 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 23:40 MHALL30.3 1 Page 34 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037751 Collection Date:02-Dec-15 4:45 PM Site:CW-2 Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Nickel (Ni)1.92 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:14 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:14 MHALL30.2 1 Vanadium (V) Low Level 0.326 ug/L EPA 200.8 12/08/2015 17:14 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 170 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 1.4 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Page 35 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037752 Collection Date:02-Dec-15 3:40 PM Site:CW-2D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.034 mg-N/L EPA 353.2 12/08/2015 08:44 LSTARL10.01 1 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 44 mg/L EPA 300.0 12/03/2015 19:46 BGN9034110 Sulfate 50 mg/L EPA 300.0 12/03/2015 19:46 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 10:37 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 15:27 TLINN0.05 1 Mercury Dissolved (cold vapor) in Water (0.1mm FILTER) Mercury (Hg)< 0.05 ug/L EPA 245.1 12/08/2015 17:13 TLINN0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 12:19 FCJORDA0.005 1 Barium (Ba)0.041 mg/L EPA 200.7 12/04/2015 12:19 FCJORDA0.005 1 Boron (B)0.397 mg/L EPA 200.7 12/04/2015 12:19 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 12/04/2015 12:19 FCJORDA0.01 1 Manganese (Mn)0.031 mg/L EPA 200.7 12/04/2015 12:19 FCJORDA0.005 1 Strontium (Sr)0.244 mg/L EPA 200.7 12/04/2015 12:19 FCJORDA0.005 1 Zinc (Zn)0.026 mg/L EPA 200.7 12/04/2015 12:19 FCJORDA0.005 1 DISSOLVED METALS BY ICP (0.1mm FILTER) Aluminum (Al)< 0.005 mg/L EPA 200.7 12/04/2015 14:26 FCJORDA0.005 1 Barium (Ba)0.041 mg/L EPA 200.7 12/04/2015 14:26 FCJORDA0.005 1 Boron (B)0.395 mg/L EPA 200.7 12/04/2015 14:26 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 12/04/2015 14:26 FCJORDA0.01 1 Manganese (Mn)0.033 mg/L EPA 200.7 12/04/2015 14:26 FCJORDA0.005 1 Strontium (Sr)0.247 mg/L EPA 200.7 12/04/2015 14:26 FCJORDA0.005 1 Zinc (Zn)0.024 mg/L EPA 200.7 12/04/2015 14:26 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)37.9 mg/L EPA 200.7 12/06/2015 13:39 FCJORDA0.01 1 Magnesium (Mg)7.58 mg/L EPA 200.7 12/06/2015 13:39 FCJORDA0.005 1 Potassium (K)3.30 mg/L EPA 200.7 12/06/2015 13:39 FCJORDA0.1 1 Sodium (Na)19.3 mg/L EPA 200.7 12/06/2015 13:39 FCJORDA0.05 1 Page 36 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037752 Collection Date:02-Dec-15 3:40 PM Site:CW-2D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.340 mg/L EPA 200.7 12/08/2015 14:18B2 FCJORDA0.005 1 Barium (Ba)0.042 mg/L EPA 200.7 12/08/2015 14:18 FCJORDA0.005 1 Boron (B)0.393 mg/L EPA 200.7 12/08/2015 14:18 FCJORDA0.05 1 Iron (Fe)0.231 mg/L EPA 200.7 12/08/2015 14:18 FCJORDA0.01 1 Manganese (Mn)0.117 mg/L EPA 200.7 12/08/2015 14:18 FCJORDA0.005 1 Strontium (Sr)0.293 mg/L EPA 200.7 12/08/2015 14:18 FCJORDA0.005 1 Zinc (Zn)0.024 mg/L EPA 200.7 12/08/2015 14:18 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 18:01 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 18:01 MHALL30.2 1 Vanadium (V) Low Level 0.352 ug/L EPA 200.8 12/07/2015 18:01 MHALL30.3 1 Total Recoverable Metals Dissolved 0.1mm Filter Antimony (Sb)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/07/2015 23:46 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/07/2015 23:46 MHALL30.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/07/2015 23:46 MHALL30.3 1 Page 37 of 133 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15120069 2015037752 Collection Date:02-Dec-15 3:40 PM Site:CW-2D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:20 MHALL311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:20 MHALL30.2 1 Vanadium (V) Low Level 0.478 ug/L EPA 200.8 12/08/2015 17:20 MHALL30.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 200 mg/L SM2540C 12/06/2015 11:19 CJELLIO251 Total Carbon TOC 0.618 mg/L SM5310C/EPA9060A 12/06/2015 12:48 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 18 mg/L SM2540D 12/06/2015 08:31 CJELLIO51 Qualifiers: B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. Page 38 of 133 Page 39 of 133 Page 40 of 133 Page 41 of 133 Page 42 of 133 Page 43 of 133 Page 44 of 133 Page 45 of 133 Page 46 of 133 Page 47 of 133 Page 48 of 133 Page 49 of 133 Page 50 of 133 Page 51 of 133 Page 52 of 133 Page 53 of 133 Page 54 of 133 Page 55 of 133 Page 56 of 133 Page 57 of 133 Page 58 of 133 Page 59 of 133 #=CL# December 08, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92278329 92278329 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15120069 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on December 03, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 26 Page 60 of 133 #=CP# CERTIFICATIONS Pace Project No.: Project: 92278329 J15120069 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 26 Page 61 of 133 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92278329 J15120069 Lab ID Sample ID Matrix Date Collected Date Received 92278329001 2015037738 Water 12/02/15 10:15 12/03/15 14:25 92278329002 2015037739 Water 12/02/15 09:30 12/03/15 14:25 92278329003 2015037740 Water 12/02/15 14:20 12/03/15 14:25 92278329004 2015037741 Water 12/02/15 09:41 12/03/15 14:25 92278329005 2015037742 Water 12/02/15 17:01 12/03/15 14:25 92278329006 2015037743 Water 12/02/15 15:41 12/03/15 14:25 92278329007 2015037744 Water 12/02/15 15:41 12/03/15 14:25 92278329008 2015037745 Water 12/02/15 12:11 12/03/15 14:25 92278329009 2015037746 Water 12/02/15 10:55 12/03/15 14:25 92278329010 2015037747 Water 12/02/15 14:05 12/03/15 14:25 92278329011 2015037748 Water 12/02/15 08:45 12/03/15 14:25 92278329012 2015037750 Water 12/02/15 10:45 12/03/15 14:25 92278329013 2015037751 Water 12/02/15 16:45 12/03/15 14:25 92278329014 2015037752 Water 12/02/15 15:40 12/03/15 14:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 26 Page 62 of 133 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92278329 J15120069 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92278329001 2015037738 EPA 218.7 1 PASI-OTK1 92278329002 2015037739 EPA 218.7 1 PASI-OTK1 92278329003 2015037740 EPA 218.7 1 PASI-OTK1 92278329004 2015037741 EPA 218.7 1 PASI-OTK1 92278329005 2015037742 EPA 218.7 1 PASI-OTK1 92278329006 2015037743 EPA 218.7 1 PASI-OTK1 92278329007 2015037744 EPA 218.7 1 PASI-OTK1 92278329008 2015037745 EPA 218.7 1 PASI-OTK1 92278329009 2015037746 EPA 218.7 1 PASI-OTK1 92278329010 2015037747 EPA 218.7 1 PASI-OTK1 92278329011 2015037748 EPA 218.7 1 PASI-OTK1 92278329012 2015037750 EPA 218.7 1 PASI-OTK1 92278329013 2015037751 EPA 218.7 1 PASI-OTK1 92278329014 2015037752 EPA 218.7 1 PASI-OTK1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 26 Page 63 of 133 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92278329 J15120069 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92278329003 2015037740 Chromium, Hexavalent 0.045 ug/L 12/07/15 14:100.030EPA 218.7 92278329005 2015037742 Chromium, Hexavalent 0.043 ug/L 12/07/15 14:360.030EPA 218.7 92278329006 2015037743 Chromium, Hexavalent 0.55 ug/L 12/07/15 14:490.30EPA 218.7 92278329007 2015037744 Chromium, Hexavalent 0.64 ug/L 12/07/15 15:020.30EPA 218.7 92278329013 2015037751 Chromium, Hexavalent 0.12 ug/L 12/07/15 17:120.030EPA 218.7 92278329014 2015037752 Chromium, Hexavalent 0.061 ug/L 12/07/15 17:280.030EPA 218.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 26 Page 64 of 133 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92278329 J15120069 Method: Client:Duke Energy EPA 218.7 Date:December 08, 2015 Description:Hexavalent Chromium by IC General Information: 14 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 26 Page 65 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037738 Lab ID:92278329001 Collected:12/02/15 10:15 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 13:44 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 26 Page 66 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037739 Lab ID:92278329002 Collected:12/02/15 09:30 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 13:57 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 26 Page 67 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037740 Lab ID:92278329003 Collected:12/02/15 14:20 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent 0.045 ug/L 12/07/15 14:10 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 26 Page 68 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037741 Lab ID:92278329004 Collected:12/02/15 09:41 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 14:23 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 26 Page 69 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037742 Lab ID:92278329005 Collected:12/02/15 17:01 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent 0.043 ug/L 12/07/15 14:36 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 26 Page 70 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037743 Lab ID:92278329006 Collected:12/02/15 15:41 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent 0.55 ug/L 12/07/15 14:49 18540-29-90.30 10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 26 Page 71 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037744 Lab ID:92278329007 Collected:12/02/15 15:41 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent 0.64 ug/L 12/07/15 15:02 18540-29-90.30 10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 26 Page 72 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037745 Lab ID:92278329008 Collected:12/02/15 12:11 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 15:15 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 26 Page 73 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037746 Lab ID:92278329009 Collected:12/02/15 10:55 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 15:54 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 26 Page 74 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037747 Lab ID:92278329010 Collected:12/02/15 14:05 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 16:33 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 26 Page 75 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037748 Lab ID:92278329011 Collected:12/02/15 08:45 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 16:46 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 26 Page 76 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037750 Lab ID:92278329012 Collected:12/02/15 10:45 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 12/07/15 16:59 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 26 Page 77 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037751 Lab ID:92278329013 Collected:12/02/15 16:45 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent 0.12 ug/L 12/07/15 17:12 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 26 Page 78 of 133 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92278329 J15120069 Sample:2015037752 Lab ID:92278329014 Collected:12/02/15 15:40 Received:12/03/15 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent 0.061 ug/L 12/07/15 17:28 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 26 Page 79 of 133 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92278329 J15120069 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/52762 EPA 218.7 EPA 218.7 Chromium, Hexavalent IC Associated Lab Samples:92278329001, 92278329002, 92278329003, 92278329004, 92278329005, 92278329006, 92278329007, 92278329008, 92278329009, 92278329010, 92278329011, 92278329012, 92278329013, 92278329014 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1412102 Associated Lab Samples: Matrix:Water Analyzed Chromium, Hexavalent ug/L ND 0.030 12/07/15 12:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1412103LABORATORY CONTROL SAMPLE: LCSSpike Chromium, Hexavalent ug/L 0.077.075 103 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1412104MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92278325021 1412105 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chromium, Hexavalent ug/L M6.5 39 85-11555 3 20.52.7 2.9 3.0 Parameter Units MS Result % Rec Limits Qual% RecConc. 1412106MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92278329009 1412107 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chromium, Hexavalent ug/L .075 112 85-115115 3 20.075ND 0.084 0.086 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 26 Page 80 of 133 #=QL# QUALIFIERS Pace Project No.: Project: 92278329 J15120069 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 26 Page 81 of 133 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92278329 J15120069 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92278329001 WETA/527622015037738EPA 218.7 92278329002 WETA/527622015037739EPA 218.7 92278329003 WETA/527622015037740EPA 218.7 92278329004 WETA/527622015037741EPA 218.7 92278329005 WETA/527622015037742EPA 218.7 92278329006 WETA/527622015037743EPA 218.7 92278329007 WETA/527622015037744EPA 218.7 92278329008 WETA/527622015037745EPA 218.7 92278329009 WETA/527622015037746EPA 218.7 92278329010 WETA/527622015037747EPA 218.7 92278329011 WETA/527622015037748EPA 218.7 92278329012 WETA/527622015037750EPA 218.7 92278329013 WETA/527622015037751EPA 218.7 92278329014 WETA/527622015037752EPA 218.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/08/2015 04:01 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 26 Page 82 of 133 Page 24 of 26 Page 83 of 133 Page 25 of 26 Page 84 of 133 Page 26 of 26 Page 85 of 133 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QL03069Lot Number: J15120069Project Number: AB GW Assessment Water - MayoProject Name: 12/09/2015Date Completed: Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QL03069 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Mayo Project Number: J15120069 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QL03069 Project Name: AB GW Assessment Water - Mayo Project Number: J15120069 Sample Number Sample ID Matrix Date Sampled Date Received 001 12/02/2015 10152015037738Aqueous 12/03/2015 002 12/02/2015 09302015037739Aqueous 12/03/2015 003 12/02/2015 14202015037740Aqueous 12/03/2015 004 12/02/2015 09412015037741Aqueous 12/03/2015 005 12/02/2015 17012015037742Aqueous 12/03/2015 006 12/02/2015 15412015037743Aqueous 12/03/2015 007 12/02/2015 15412015037744Aqueous 12/03/2015 008 12/02/2015 12112015037745Aqueous 12/03/2015 009 12/02/2015 10552015037746Aqueous 12/03/2015 010 12/02/2015 14052015037747Aqueous 12/03/2015 011 12/02/2015 08452015037748Aqueous 12/03/2015 012 12/02/2015 10452015037750Aqueous 12/03/2015 013 12/02/2015 16452015037751Aqueous 12/03/2015 014 12/02/2015 15402015037752Aqueous 12/03/2015 (14 samples) Page: 3 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QL03069 Project Name: AB GW Assessment Water - Mayo Project Number: J15120069 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015037738 Aqueous Alkalinity SM 2320B-190 mg/L 5 001 2015037738 Aqueous Bicarbonate Alkalinity SM 2320B-190 mg/L 5 002 2015037739 Aqueous Alkalinity SM 2320B-210 mg/L 7 002 2015037739 Aqueous Bicarbonate Alkalinity SM 2320B-210 mg/L 7 002 2015037739 Aqueous Methane RSK - 175 23 ug/L 8 003 2015037740 Aqueous Alkalinity SM 2320B-44 mg/L 9 003 2015037740 Aqueous Bicarbonate Alkalinity SM 2320B-44 mg/L 9 003 2015037740 Aqueous Methane RSK - 175 14 ug/L 10 004 2015037741 Aqueous Alkalinity SM 2320B-160 mg/L 11 004 2015037741 Aqueous Bicarbonate Alkalinity SM 2320B-160 mg/L 11 004 2015037741 Aqueous Methane RSK - 175 16 ug/L 12 005 2015037742 Aqueous Alkalinity SM 2320B-12 mg/L 13 005 2015037742 Aqueous Bicarbonate Alkalinity SM 2320B-12 mg/L 13 006 2015037743 Aqueous Alkalinity SM 2320B-54 mg/L 15 006 2015037743 Aqueous Bicarbonate Alkalinity SM 2320B-54 mg/L 15 007 2015037744 Aqueous Alkalinity SM 2320B-55 mg/L 17 007 2015037744 Aqueous Bicarbonate Alkalinity SM 2320B-55 mg/L 17 008 2015037745 Aqueous Alkalinity SM 2320B-210 mg/L 19 008 2015037745 Aqueous Bicarbonate Alkalinity SM 2320B-210 mg/L 19 009 2015037746 Aqueous Alkalinity SM 2320B-100 mg/L 21 009 2015037746 Aqueous Bicarbonate Alkalinity SM 2320B-100 mg/L 21 010 2015037747 Aqueous Alkalinity SM 2320B-210 mg/L 23 010 2015037747 Aqueous Bicarbonate Alkalinity SM 2320B-210 mg/L 23 011 2015037748 Aqueous Alkalinity SM 2320B-200 mg/L 25 011 2015037748 Aqueous Bicarbonate Alkalinity SM 2320B-200 mg/L 25 011 2015037748 Aqueous Methane RSK - 175 640 ug/L 26 014 2015037752 Aqueous Alkalinity SM 2320B-120 mg/L 31 014 2015037752 Aqueous Bicarbonate Alkalinity SM 2320B-120 mg/L 31 (28 detections) Page: 4 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037738 QL03069-001 12/02/2015 1015 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0216 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0216 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0216 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 190 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 190 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037738 QL03069-001 12/02/2015 1015 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1254 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037739 QL03069-002 12/02/2015 0930 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0224 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0224 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0224 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 210 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 210 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037739 QL03069-002 12/02/2015 0930 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1310 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 23 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037740 QL03069-003 12/02/2015 1420 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0229 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0229 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0229 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 44 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 44 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037740 QL03069-003 12/02/2015 1420 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1327 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 14 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037741 QL03069-004 12/02/2015 0941 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0236 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0236 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0236 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 160 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 160 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037741 QL03069-004 12/02/2015 0941 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1344 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 16 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037742 QL03069-005 12/02/2015 1701 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0241 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0241 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0241 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 12 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 12 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037742 QL03069-005 12/02/2015 1701 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1401 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037743 QL03069-006 12/02/2015 1541 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0257 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0257 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0257 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 54 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 54 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037743 QL03069-006 12/02/2015 1541 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1417 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037744 QL03069-007 12/02/2015 1541 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0316 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0316 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0316 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 55 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 55 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037744 QL03069-007 12/02/2015 1541 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1434 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037745 QL03069-008 12/02/2015 1211 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0323 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0323 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0323 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 210 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 210 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037745 QL03069-008 12/02/2015 1211 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1451 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037746 QL03069-009 12/02/2015 1055 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0329 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0329 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0329 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 100 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 100 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037746 QL03069-009 12/02/2015 1055 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1508 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037747 QL03069-010 12/02/2015 1405 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0337 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0337 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0337 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 210 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 210 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037747 QL03069-010 12/02/2015 1405 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1525 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037748 QL03069-011 12/02/2015 0845 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0345 MJI 91406 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0345 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0345 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 200 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 200 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 25 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037748 QL03069-011 12/02/2015 0845 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1541 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 640 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 26 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037750 QL03069-012 12/02/2015 1045 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0400 MJI 91407 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0400 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0400 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 27 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037750 QL03069-012 12/02/2015 1045 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1558 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 28 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037751 QL03069-013 12/02/2015 1645 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0405 MJI 91407 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0405 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0405 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 29 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037751 QL03069-013 12/02/2015 1645 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1615 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 30 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037752 QL03069-014 12/02/2015 1540 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0412 MJI 91407 1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0412 MJI 1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0412 MJI AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 120 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 120 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 31 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015037752 QL03069-014 12/02/2015 1540 12/03/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15120069 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 12/09/2015 1632 JJG 91762 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 32 of 32 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. QC Summary QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:QQ91406-001 91406 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 12/05/2015 002110mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:QQ91406-002 91406 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 95 12/05/2015 00289510090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MS Batch: Sample ID:QL03069-005MS 91406 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 110 12/05/2015 02469510070-130121 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MSD Batch: Sample ID:QL03069-005MD 91406 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 110 12/05/2015 02519510070-1300.047 20121 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:QQ91407-001 91407 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 12/05/2015 035010mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:QQ91407-002 91407 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 90 12/05/2015 03559010090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - MB Batch: Sample ID:QQ91762-001 91762 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 12/09/2015 114410ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCS Batch: Sample ID:QQ91762-002 91762 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 260 12/09/2015 11088730070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCSD Batch: Sample ID:QQ91762-003 91762 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 260 12/09/2015 11278830070-1300.14 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QL03069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Chain of Custody and Miscellaneous Documents 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 132 of 133 Page 133 of 133