NC0038377_J15120036report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15120036
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:12/10/2015
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Brandon Russo, Kathy Webb, John Toepfer
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 119
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015037569 MAYO STEAM 01-Dec-15 10:05 AM Erin Black ABMW-02
2015037571 MAYO STEAM 01-Dec-15 10:50 AM Erin Black ABMW-02BR
2015037572 MAYO STEAM 01-Dec-15 9:22 AM Erin Black ABMW-03
2015037573 MAYO STEAM 01-Dec-15 11:20 AM Erin Black ABMW-03S
2015037574 MAYO STEAM 01-Dec-15 12:15 PM Erin Black ABMW-04
2015037575 MAYO STEAM 01-Dec-15 4:16 PM Erin Black ABMW-04D
2015037576 MAYO STEAM 01-Dec-15 1:25 PM Erin Black ABMW-04BR
2015037577 MAYO STEAM 01-Dec-15 3:10 PM Erin Black MW-2
2015037578 MAYO STEAM 01-Dec-15 1:45 PM Erin Black MW-4
2015037579 MAYO STEAM 01-Dec-15 Erin Black FB-Peri-1
2015037580 MAYO STEAM 01-Dec-15 Erin Black EB-Peri-1
11 Total Samples
Page 2 of 119
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:12/10/2015
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037569
Collection Date:01-Dec-15 10:05 AM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/04/2015 09:05 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 12/02/2015 11:01 BGN90340.5 5
Sulfate 17 mg/L EPA 300.0 12/02/2015 11:01 BGN90340.5 5
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/02/2015 16:08 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:34 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/05/2015 13:12 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 12/02/2015 14:45 FCJORDA0.005 1
Barium (Ba)0.165 mg/L EPA 200.7 12/02/2015 14:45 FCJORDA0.005 1
Boron (B)8.12 mg/L EPA 200.7 12/02/2015 14:45 FCJORDA0.05 1
Iron (Fe)0.297 mg/L EPA 200.7 12/02/2015 14:45 FCJORDA0.01 1
Manganese (Mn)1.06 mg/L EPA 200.7 12/02/2015 14:45 FCJORDA0.005 1
Strontium (Sr)1.59 mg/L EPA 200.7 12/02/2015 14:45 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 14:45 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.019 mg/L EPA 200.7 12/02/2015 15:45 FCJORDA0.005 1
Barium (Ba)0.162 mg/L EPA 200.7 12/02/2015 15:45 FCJORDA0.005 1
Boron (B)7.96 mg/L EPA 200.7 12/02/2015 15:45 FCJORDA0.05 1
Iron (Fe)0.215 mg/L EPA 200.7 12/02/2015 15:45 FCJORDA0.01 1
Manganese (Mn)1.05 mg/L EPA 200.7 12/02/2015 15:45 FCJORDA0.005 1
Strontium (Sr)1.56 mg/L EPA 200.7 12/02/2015 15:45 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 15:45 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)70.2 mg/L EPA 200.7 12/02/2015 16:39 FCJORDA0.01 1
Magnesium (Mg)20.4 mg/L EPA 200.7 12/02/2015 16:39 FCJORDA0.05 10
Potassium (K)17.6 mg/L EPA 200.7 12/02/2015 16:39 FCJORDA0.1 1
Sodium (Na)31.0 mg/L EPA 200.7 12/02/2015 16:39 FCJORDA0.05 1
Page 4 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037569
Collection Date:01-Dec-15 10:05 AM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.026 mg/L EPA 200.7 12/03/2015 16:21 FCJORDA0.005 1
Barium (Ba)0.168 mg/L EPA 200.7 12/03/2015 16:21 FCJORDA0.005 1
Boron (B)8.16 mg/L EPA 200.7 12/03/2015 16:21 FCJORDA0.05 1
Iron (Fe)0.208 mg/L EPA 200.7 12/03/2015 16:21 FCJORDA0.01 1
Manganese (Mn)1.10 mg/L EPA 200.7 12/03/2015 16:21 FCJORDA0.005 1
Strontium (Sr)1.59 mg/L EPA 200.7 12/03/2015 16:21 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:21 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Arsenic (As)329 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Molybdenum (Mo)1010 ug/L EPA 200.8 12/03/2015 15:40 MHALL31010
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 15:40 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 15:40 MHALL30.2 1
Vanadium (V) Low Level 1.52 ug/L EPA 200.8 12/03/2015 15:40 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Arsenic (As)342 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Molybdenum (Mo)992 ug/L EPA 200.8 12/03/2015 14:59 MHALL31010
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 14:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 14:59 MHALL30.2 1
Vanadium (V) Low Level 1.55 ug/L EPA 200.8 12/03/2015 14:59 MHALL30.3 1
Page 5 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037569
Collection Date:01-Dec-15 10:05 AM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Arsenic (As)290 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Molybdenum (Mo)1080 ug/L EPA 200.8 12/03/2015 17:53M4 MHALL31010
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 17:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 17:53 MHALL30.2 1
Vanadium (V) Low Level 1.79 ug/L EPA 200.8 12/03/2015 17:53 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 410 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 8.9 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 6 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037571
Collection Date:01-Dec-15 10:50 AM
Site:ABMW-02BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/04/2015 09:06 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 26 mg/L EPA 300.0 12/03/2015 08:46 BGN90340.5 5
Sulfate 3.2 mg/L EPA 300.0 12/03/2015 08:46 BGN90340.1 1
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/02/2015 16:10 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:36 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/05/2015 13:14 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/02/2015 14:57 FCJORDA0.005 1
Barium (Ba)0.124 mg/L EPA 200.7 12/02/2015 14:57 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/02/2015 14:57 FCJORDA0.05 1
Iron (Fe)0.590 mg/L EPA 200.7 12/02/2015 14:57 FCJORDA0.01 1
Manganese (Mn)0.192 mg/L EPA 200.7 12/02/2015 14:57 FCJORDA0.005 1
Strontium (Sr)1.07 mg/L EPA 200.7 12/02/2015 14:57 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 14:57 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/02/2015 15:57 FCJORDA0.005 1
Barium (Ba)0.122 mg/L EPA 200.7 12/02/2015 15:57 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/02/2015 15:57 FCJORDA0.05 1
Iron (Fe)0.476 mg/L EPA 200.7 12/02/2015 15:57 FCJORDA0.01 1
Manganese (Mn)0.192 mg/L EPA 200.7 12/02/2015 15:57 FCJORDA0.005 1
Strontium (Sr)1.07 mg/L EPA 200.7 12/02/2015 15:57 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 15:57 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)72.6 mg/L EPA 200.7 12/02/2015 16:50 FCJORDA0.01 1
Magnesium (Mg)12.4 mg/L EPA 200.7 12/02/2015 16:50 FCJORDA0.005 1
Potassium (K)5.81 mg/L EPA 200.7 12/02/2015 16:50 FCJORDA0.1 1
Sodium (Na)29.7 mg/L EPA 200.7 12/02/2015 16:50 FCJORDA0.05 1
Page 7 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037571
Collection Date:01-Dec-15 10:50 AM
Site:ABMW-02BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.017 mg/L EPA 200.7 12/03/2015 16:10 FCJORDA0.005 1
Barium (Ba)0.122 mg/L EPA 200.7 12/03/2015 16:10 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/03/2015 16:10 FCJORDA0.05 1
Iron (Fe)0.672 mg/L EPA 200.7 12/03/2015 16:10 FCJORDA0.01 1
Manganese (Mn)0.198 mg/L EPA 200.7 12/03/2015 16:10 FCJORDA0.005 1
Strontium (Sr)1.06 mg/L EPA 200.7 12/03/2015 16:10 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:10 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Arsenic (As)1.92 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Molybdenum (Mo)3.47 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 16:34 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 16:34 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 16:34 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Arsenic (As)1.72 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Molybdenum (Mo)3.61 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 14:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 14:37 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 14:37 MHALL30.3 1
Page 8 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037571
Collection Date:01-Dec-15 10:50 AM
Site:ABMW-02BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Arsenic (As)1.88 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Molybdenum (Mo)4.40 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 18:21 MHALL311
Thallium (Tl) Low Level 0.210 ug/L EPA 200.8 12/03/2015 18:21 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 18:21 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 0.948 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 9 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037572
Collection Date:01-Dec-15 9:22 AM
Site:ABMW-03
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/04/2015 09:07 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 59 mg/L EPA 300.0 12/03/2015 09:03 BGN9034110
Sulfate 3.4 mg/L EPA 300.0 12/03/2015 09:03 BGN90340.1 1
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/02/2015 16:12 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:39 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/05/2015 13:16 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.029 mg/L EPA 200.7 12/02/2015 15:01 FCJORDA0.005 1
Barium (Ba)0.265 mg/L EPA 200.7 12/02/2015 15:01 FCJORDA0.005 1
Boron (B)1.77 mg/L EPA 200.7 12/02/2015 15:01 FCJORDA0.05 1
Iron (Fe)18.1 mg/L EPA 200.7 12/02/2015 15:01 FCJORDA0.01 1
Manganese (Mn)1.00 mg/L EPA 200.7 12/02/2015 15:01 FCJORDA0.005 1
Strontium (Sr)1.58 mg/L EPA 200.7 12/02/2015 15:01 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 15:01 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.028 mg/L EPA 200.7 12/02/2015 16:00 FCJORDA0.005 1
Barium (Ba)0.264 mg/L EPA 200.7 12/02/2015 16:00 FCJORDA0.005 1
Boron (B)1.79 mg/L EPA 200.7 12/02/2015 16:00 FCJORDA0.05 1
Iron (Fe)18.0 mg/L EPA 200.7 12/02/2015 16:00 FCJORDA0.01 1
Manganese (Mn)1.01 mg/L EPA 200.7 12/02/2015 16:00 FCJORDA0.005 1
Strontium (Sr)1.58 mg/L EPA 200.7 12/02/2015 16:00 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 16:00 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)60.8 mg/L EPA 200.7 12/02/2015 16:54 FCJORDA0.01 1
Magnesium (Mg)13.6 mg/L EPA 200.7 12/02/2015 16:54 FCJORDA0.005 1
Potassium (K)12.1 mg/L EPA 200.7 12/02/2015 16:54 FCJORDA0.1 1
Sodium (Na)10.2 mg/L EPA 200.7 12/02/2015 16:54 FCJORDA0.05 1
Page 10 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037572
Collection Date:01-Dec-15 9:22 AM
Site:ABMW-03
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.062 mg/L EPA 200.7 12/03/2015 16:25 FCJORDA0.005 1
Barium (Ba)0.279 mg/L EPA 200.7 12/03/2015 16:25 FCJORDA0.005 1
Boron (B)1.74 mg/L EPA 200.7 12/03/2015 16:25 FCJORDA0.05 1
Iron (Fe)21.5 mg/L EPA 200.7 12/03/2015 16:25 FCJORDA0.01 1
Manganese (Mn)1.12 mg/L EPA 200.7 12/03/2015 16:25 FCJORDA0.005 1
Strontium (Sr)1.62 mg/L EPA 200.7 12/03/2015 16:25 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:25 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Arsenic (As)79.8 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Molybdenum (Mo)12.8 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 12:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 12:59 MHALL30.2 1
Vanadium (V) Low Level 0.316 ug/L EPA 200.8 12/03/2015 12:59 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Arsenic (As)83.7 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Molybdenum (Mo)13.3 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA0.2 1
Vanadium (V) Low Level 0.305 ug/L EPA 200.8 12/02/2015 14:52 JAHERMA0.3 1
Page 11 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037572
Collection Date:01-Dec-15 9:22 AM
Site:ABMW-03
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Arsenic (As)77.7 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Molybdenum (Mo)9.98 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 18:28 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 18:28 MHALL30.2 1
Vanadium (V) Low Level 0.471 ug/L EPA 200.8 12/03/2015 18:28 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 330 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 3.0 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 28 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 12 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037573
Collection Date:01-Dec-15 11:20 AM
Site:ABMW-03S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.012 mg-N/L EPA 353.2 12/04/2015 09:08 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.8 mg/L EPA 300.0 12/02/2015 11:52 BGN90340.1 1
Sulfate 0.61 mg/L EPA 300.0 12/02/2015 11:52 BGN90340.1 1
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/02/2015 16:15 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:41 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/05/2015 13:19 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 12/02/2015 15:05 FCJORDA0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 12/02/2015 15:05 FCJORDA0.005 1
Boron (B)1.16 mg/L EPA 200.7 12/02/2015 15:05 FCJORDA0.05 1
Iron (Fe)4.56 mg/L EPA 200.7 12/02/2015 15:05 FCJORDA0.01 1
Manganese (Mn)0.563 mg/L EPA 200.7 12/02/2015 15:05 FCJORDA0.005 1
Strontium (Sr)0.074 mg/L EPA 200.7 12/02/2015 15:05 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 12/02/2015 15:05 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.006 mg/L EPA 200.7 12/02/2015 16:04 FCJORDA0.005 1
Barium (Ba)0.021 mg/L EPA 200.7 12/02/2015 16:04 FCJORDA0.005 1
Boron (B)0.953 mg/L EPA 200.7 12/02/2015 16:04 FCJORDA0.05 1
Iron (Fe)2.81 mg/L EPA 200.7 12/02/2015 16:04 FCJORDA0.01 1
Manganese (Mn)0.460 mg/L EPA 200.7 12/02/2015 16:04 FCJORDA0.005 1
Strontium (Sr)0.067 mg/L EPA 200.7 12/02/2015 16:04 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 12/02/2015 16:04 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.15 mg/L EPA 200.7 12/02/2015 16:58 FCJORDA0.01 1
Magnesium (Mg)0.403 mg/L EPA 200.7 12/02/2015 16:58 FCJORDA0.005 1
Potassium (K)0.583 mg/L EPA 200.7 12/02/2015 16:58 FCJORDA0.1 1
Sodium (Na)13.5 mg/L EPA 200.7 12/02/2015 16:58 FCJORDA0.05 1
Page 13 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037573
Collection Date:01-Dec-15 11:20 AM
Site:ABMW-03S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.025 mg/L EPA 200.7 12/03/2015 16:29 FCJORDA0.005 1
Barium (Ba)0.027 mg/L EPA 200.7 12/03/2015 16:29 FCJORDA0.005 1
Boron (B)0.635 mg/L EPA 200.7 12/03/2015 16:29 FCJORDA0.05 1
Iron (Fe)0.465 mg/L EPA 200.7 12/03/2015 16:29 FCJORDA0.01 1
Manganese (Mn)0.282 mg/L EPA 200.7 12/03/2015 16:29 FCJORDA0.005 1
Strontium (Sr)0.055 mg/L EPA 200.7 12/03/2015 16:29 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 12/03/2015 16:29 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Arsenic (As)1.55 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Cobalt (Co)3.79 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 16:56 MHALL311
Thallium (Tl) Low Level 0.227 ug/L EPA 200.8 12/03/2015 16:56 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 16:56 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Arsenic (As)1.01 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Cobalt (Co)3.40 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/02/2015 14:59 JAHERMA0.3 1
Page 14 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037573
Collection Date:01-Dec-15 11:20 AM
Site:ABMW-03S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Cobalt (Co)1.82 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Copper (Cu)1.32 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Nickel (Ni)1.06 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 18:35 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 18:35 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 18:35 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 0.561 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 15 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037574
Collection Date:01-Dec-15 12:15 PM
Site:ABMW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/04/2015 09:10 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 12/02/2015 12:08 BGN9034110
Sulfate 41 mg/L EPA 300.0 12/02/2015 12:08 BGN9034110
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 14:54 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:43 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/05/2015 13:21 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 12/02/2015 15:08 FCJORDA0.005 1
Barium (Ba)0.513 mg/L EPA 200.7 12/02/2015 15:08 FCJORDA0.005 1
Boron (B)5.76 mg/L EPA 200.7 12/02/2015 15:08 FCJORDA0.05 1
Iron (Fe)2.49 mg/L EPA 200.7 12/02/2015 15:08 FCJORDA0.01 1
Manganese (Mn)1.02 mg/L EPA 200.7 12/02/2015 15:08 FCJORDA0.005 1
Strontium (Sr)2.80 mg/L EPA 200.7 12/02/2015 15:08 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 15:08 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.033 mg/L EPA 200.7 12/02/2015 16:08 FCJORDA0.005 1
Barium (Ba)0.452 mg/L EPA 200.7 12/02/2015 16:08 FCJORDA0.005 1
Boron (B)5.20 mg/L EPA 200.7 12/02/2015 16:08 FCJORDA0.05 1
Iron (Fe)2.02 mg/L EPA 200.7 12/02/2015 16:08 FCJORDA0.01 1
Manganese (Mn)0.919 mg/L EPA 200.7 12/02/2015 16:08 FCJORDA0.005 1
Strontium (Sr)2.46 mg/L EPA 200.7 12/02/2015 16:08 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 16:08 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)119 mg/L EPA 200.7 12/02/2015 17:44 FCJORDA0.1 10
Magnesium (Mg)32.4 mg/L EPA 200.7 12/02/2015 17:44 FCJORDA0.05 10
Potassium (K)22.4 mg/L EPA 200.7 12/02/2015 17:44 FCJORDA110
Sodium (Na)11.2 mg/L EPA 200.7 12/02/2015 17:44 FCJORDA0.5 10
Page 16 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037574
Collection Date:01-Dec-15 12:15 PM
Site:ABMW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.162 mg/L EPA 200.7 12/03/2015 16:33 FCJORDA0.005 1
Barium (Ba)0.437 mg/L EPA 200.7 12/03/2015 16:33 FCJORDA0.005 1
Boron (B)5.08 mg/L EPA 200.7 12/03/2015 16:33 FCJORDA0.05 1
Iron (Fe)2.28 mg/L EPA 200.7 12/03/2015 16:33 FCJORDA0.01 1
Manganese (Mn)0.894 mg/L EPA 200.7 12/03/2015 16:33 FCJORDA0.005 1
Strontium (Sr)2.42 mg/L EPA 200.7 12/03/2015 16:33 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:33 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Arsenic (As)800 ug/L EPA 200.8 12/03/2015 17:03 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Cobalt (Co)1.27 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Molybdenum (Mo)444 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 17:03 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 17:03 MHALL30.2 1
Vanadium (V) Low Level 1.75 ug/L EPA 200.8 12/03/2015 17:03 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Arsenic (As)772 ug/L EPA 200.8 12/03/2015 15:06 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Cobalt (Co)1.39 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Molybdenum (Mo)434 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 15:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 15:06 MHALL30.2 1
Vanadium (V) Low Level 1.60 ug/L EPA 200.8 12/03/2015 15:06 MHALL30.3 1
Page 17 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037574
Collection Date:01-Dec-15 12:15 PM
Site:ABMW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Arsenic (As)774 ug/L EPA 200.8 12/03/2015 18:42 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Cobalt (Co)1.29 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Molybdenum (Mo)448 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 18:42 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 18:42 MHALL30.2 1
Vanadium (V) Low Level 2.16 ug/L EPA 200.8 12/03/2015 18:42 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 52 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 2.8 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 10 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 18 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037575
Collection Date:01-Dec-15 4:16 PM
Site:ABMW-04D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/04/2015 09:11 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 12/03/2015 09:20 BGN90340.5 5
Sulfate 3.1 mg/L EPA 300.0 12/03/2015 09:20 BGN90340.1 1
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 14:56 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:46 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/05/2015 13:23 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.092 mg/L EPA 200.7 12/02/2015 15:12 FCJORDA0.005 1
Barium (Ba)1.02 mg/L EPA 200.7 12/02/2015 15:12 FCJORDA0.005 1
Boron (B)4.09 mg/L EPA 200.7 12/02/2015 15:12 FCJORDA0.05 1
Iron (Fe)57.6 mg/L EPA 200.7 12/02/2015 15:12 FCJORDA0.1 10
Manganese (Mn)5.28 mg/L EPA 200.7 12/02/2015 15:12 FCJORDA0.005 1
Strontium (Sr)2.17 mg/L EPA 200.7 12/02/2015 15:12 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 12/02/2015 15:12 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.085 mg/L EPA 200.7 12/02/2015 16:12 FCJORDA0.005 1
Barium (Ba)1.00 mg/L EPA 200.7 12/02/2015 16:12 FCJORDA0.005 1
Boron (B)4.17 mg/L EPA 200.7 12/02/2015 16:12 FCJORDA0.05 1
Iron (Fe)52.3 mg/L EPA 200.7 12/02/2015 16:12 FCJORDA0.1 10
Manganese (Mn)5.24 mg/L EPA 200.7 12/02/2015 16:12 FCJORDA0.005 1
Strontium (Sr)2.20 mg/L EPA 200.7 12/02/2015 16:12 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 16:12 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)139 mg/L EPA 200.7 12/02/2015 17:48 FCJORDA0.1 10
Magnesium (Mg)38.3 mg/L EPA 200.7 12/02/2015 17:48 FCJORDA0.05 10
Potassium (K)20.6 mg/L EPA 200.7 12/02/2015 17:48 FCJORDA110
Sodium (Na)17.6 mg/L EPA 200.7 12/02/2015 17:48 FCJORDA0.5 10
Page 19 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037575
Collection Date:01-Dec-15 4:16 PM
Site:ABMW-04D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.643 mg/L EPA 200.7 12/03/2015 16:37 FCJORDA0.005 1
Barium (Ba)0.990 mg/L EPA 200.7 12/03/2015 16:37 FCJORDA0.005 1
Boron (B)3.95 mg/L EPA 200.7 12/03/2015 16:37 FCJORDA0.05 1
Iron (Fe)60.3 mg/L EPA 200.7 12/03/2015 16:37 FCJORDA0.1 10
Manganese (Mn)5.25 mg/L EPA 200.7 12/03/2015 16:37 FCJORDA0.005 1
Strontium (Sr)2.14 mg/L EPA 200.7 12/03/2015 16:37 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:37 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Arsenic (As)81.6 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Cobalt (Co)3.17 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Molybdenum (Mo)42.0 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 17:11 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 17:11 MHALL30.2 1
Vanadium (V) Low Level 8.07 ug/L EPA 200.8 12/03/2015 17:11 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Arsenic (As)80.9 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Cobalt (Co)3.35 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Molybdenum (Mo)48.6 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 15:13 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 15:13 MHALL30.2 1
Vanadium (V) Low Level 7.54 ug/L EPA 200.8 12/03/2015 15:13 MHALL30.3 1
Page 20 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037575
Collection Date:01-Dec-15 4:16 PM
Site:ABMW-04D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Arsenic (As)84.2 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Chromium (Cr)1.49 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Cobalt (Co)3.82 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Molybdenum (Mo)56.1 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Nickel (Ni)1.13 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/04/2015 12:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/04/2015 12:59 MHALL30.2 1
Vanadium (V) Low Level 12.1 ug/L EPA 200.8 12/04/2015 12:59 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 540 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 6.3 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS 88 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 21 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037576
Collection Date:01-Dec-15 1:25 PM
Site:ABMW-04BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/04/2015 09:12 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 5.1 mg/L EPA 300.0 12/02/2015 13:33 BGN90340.1 1
Sulfate 28 mg/L EPA 300.0 12/02/2015 13:33 BGN9034110
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 14:59 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:48 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/05/2015 13:26 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 12/02/2015 15:16 FCJORDA0.005 1
Barium (Ba)0.103 mg/L EPA 200.7 12/02/2015 15:16 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/02/2015 15:16 FCJORDA0.05 1
Iron (Fe)0.016 mg/L EPA 200.7 12/02/2015 15:16 FCJORDA0.01 1
Manganese (Mn)0.328 mg/L EPA 200.7 12/02/2015 15:16 FCJORDA0.005 1
Strontium (Sr)1.81 mg/L EPA 200.7 12/02/2015 15:16 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 15:16 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.015 mg/L EPA 200.7 12/02/2015 16:16 FCJORDA0.005 1
Barium (Ba)0.102 mg/L EPA 200.7 12/02/2015 16:16 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/02/2015 16:16 FCJORDA0.05 1
Iron (Fe)0.016 mg/L EPA 200.7 12/02/2015 16:16 FCJORDA0.01 1
Manganese (Mn)0.329 mg/L EPA 200.7 12/02/2015 16:16 FCJORDA0.005 1
Strontium (Sr)1.80 mg/L EPA 200.7 12/02/2015 16:16 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 16:16 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)72.3 mg/L EPA 200.7 12/02/2015 17:09 FCJORDA0.01 1
Magnesium (Mg)5.26 mg/L EPA 200.7 12/02/2015 17:09 FCJORDA0.005 1
Potassium (K)8.84 mg/L EPA 200.7 12/02/2015 17:09 FCJORDA0.1 1
Sodium (Na)20.9 mg/L EPA 200.7 12/02/2015 17:09 FCJORDA0.05 1
Page 22 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037576
Collection Date:01-Dec-15 1:25 PM
Site:ABMW-04BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.109 mg/L EPA 200.7 12/03/2015 16:41 FCJORDA0.005 1
Barium (Ba)0.102 mg/L EPA 200.7 12/03/2015 16:41 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/03/2015 16:41 FCJORDA0.05 1
Iron (Fe)0.318 mg/L EPA 200.7 12/03/2015 16:41 FCJORDA0.01 1
Manganese (Mn)0.330 mg/L EPA 200.7 12/03/2015 16:41 FCJORDA0.005 1
Strontium (Sr)1.73 mg/L EPA 200.7 12/03/2015 16:41 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:41 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Molybdenum (Mo)1.02 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 13:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 13:06 MHALL30.2 1
Vanadium (V) Low Level 0.336 ug/L EPA 200.8 12/03/2015 13:06 MHALL30.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Molybdenum (Mo)1.07 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA0.2 1
Vanadium (V) Low Level 0.354 ug/L EPA 200.8 12/02/2015 15:06 JAHERMA0.3 1
Page 23 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037576
Collection Date:01-Dec-15 1:25 PM
Site:ABMW-04BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Copper (Cu)6.58 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Molybdenum (Mo)5.65 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 18:49 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 18:49 MHALL30.2 1
Vanadium (V) Low Level 0.594 ug/L EPA 200.8 12/03/2015 18:49 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 640 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 0.138 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 24 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037577
Collection Date:01-Dec-15 3:10 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 12/04/2015 09:13 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 300.0 12/02/2015 12:59 BGN9034110
Sulfate 16 mg/L EPA 300.0 12/02/2015 12:59 BGN9034110
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 14:47 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:27 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 12/02/2015 15:20 FCJORDA0.005 1
Barium (Ba)0.066 mg/L EPA 200.7 12/02/2015 15:20 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/02/2015 15:20 FCJORDA0.05 1
Iron (Fe)0.876 mg/L EPA 200.7 12/02/2015 15:20 FCJORDA0.01 1
Manganese (Mn)1.27 mg/L EPA 200.7 12/02/2015 15:20 FCJORDA0.005 1
Strontium (Sr)0.201 mg/L EPA 200.7 12/02/2015 15:20 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 12/02/2015 15:20 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)19.8 mg/L EPA 200.7 12/02/2015 17:13 FCJORDA0.01 1
Magnesium (Mg)7.82 mg/L EPA 200.7 12/02/2015 17:13 FCJORDA0.005 1
Potassium (K)5.84 mg/L EPA 200.7 12/02/2015 17:13 FCJORDA0.1 1
Sodium (Na)24.6 mg/L EPA 200.7 12/02/2015 17:13 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.907 mg/L EPA 200.7 12/03/2015 16:44 FCJORDA0.005 1
Barium (Ba)0.074 mg/L EPA 200.7 12/03/2015 16:44 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/03/2015 16:44 FCJORDA0.05 1
Iron (Fe)1.35 mg/L EPA 200.7 12/03/2015 16:44 FCJORDA0.01 1
Manganese (Mn)1.61 mg/L EPA 200.7 12/03/2015 16:44 FCJORDA0.005 1
Strontium (Sr)0.212 mg/L EPA 200.7 12/03/2015 16:44 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:44 FCJORDA0.005 1
Page 25 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037577
Collection Date:01-Dec-15 3:10 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Cobalt (Co)4.23 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Nickel (Ni)3.14 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 13:13 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 13:13 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 13:13 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Cobalt (Co)5.20 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Molybdenum (Mo)1.00 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Nickel (Ni)4.69 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 18:56 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 18:56 MHALL30.2 1
Vanadium (V) Low Level 0.747 ug/L EPA 200.8 12/03/2015 18:56 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 2.1 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 26 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037578
Collection Date:01-Dec-15 1:45 PM
Site:MW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.325 mg-N/L EPA 353.2 12/04/2015 09:20 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.3 mg/L EPA 300.0 12/03/2015 09:36 BGN90340.1 1
Sulfate 36 mg/L EPA 300.0 12/03/2015 09:36 BGN9034220
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:01 ACPAYNE0.05 1
M ercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:50 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/02/2015 15:24 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 12/02/2015 15:24 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/02/2015 15:24 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/02/2015 15:24 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/02/2015 15:24 FCJORDA0.005 1
Strontium (Sr)0.088 mg/L EPA 200.7 12/02/2015 15:24 FCJORDA0.005 1
Zinc (Zn)0.013 mg/L EPA 200.7 12/02/2015 15:24 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)24.0 mg/L EPA 200.7 12/02/2015 17:17 FCJORDA0.01 1
Magnesium (Mg)7.37 mg/L EPA 200.7 12/02/2015 17:17 FCJORDA0.005 1
Potassium (K)5.84 mg/L EPA 200.7 12/02/2015 17:17 FCJORDA0.1 1
Sodium (Na)18.4 mg/L EPA 200.7 12/02/2015 17:17 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 12/03/2015 16:48 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 12/03/2015 16:48 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/03/2015 16:48 FCJORDA0.05 1
Iron (Fe)0.022 mg/L EPA 200.7 12/03/2015 16:48 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/03/2015 16:48 FCJORDA0.005 1
Strontium (Sr)0.087 mg/L EPA 200.7 12/03/2015 16:48 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 12/03/2015 16:48 FCJORDA0.005 1
Page 27 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037578
Collection Date:01-Dec-15 1:45 PM
Site:MW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Molybdenum (Mo)2.18 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Nickel (Ni)1.51 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 13:20 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 13:20 MHALL30.2 1
Vanadium (V) Low Level 0.521 ug/L EPA 200.8 12/03/2015 13:20 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Molybdenum (Mo)2.29 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Nickel (Ni)1.71 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 19:03 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 19:03 MHALL30.2 1
Vanadium (V) Low Level 0.664 ug/L EPA 200.8 12/03/2015 19:03 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 0.605 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
Page 28 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037579
Collection Date:01-Dec-15
Site:FB-Peri-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:53 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/02/2015 15:28 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/02/2015 15:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/02/2015 15:28 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/02/2015 15:28 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/02/2015 15:28 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/02/2015 15:28 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/02/2015 15:28 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 13:27 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 13:27 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 13:27 MHALL30.3 1
Page 29 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037580
Collection Date:01-Dec-15
Site:EB-Peri-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/04/2015 09:24 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 12/02/2015 09:53 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 12/02/2015 09:53 BGN90340.1 1
M ERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/03/2015 15:10 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 12/02/2015 17:21 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 12/02/2015 17:21 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 12/02/2015 17:21 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 12/02/2015 17:21 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/03/2015 16:52 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/03/2015 16:52 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/03/2015 16:52 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/03/2015 16:52 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/03/2015 16:52 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/03/2015 16:52 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/03/2015 16:52 FCJORDA0.005 1
Page 30 of 119
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120036
2015037580
Collection Date:01-Dec-15
Site:EB-Peri-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/03/2015 19:10 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/03/2015 19:10 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/03/2015 19:10 MHALL30.3 1
M ETHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 12/03/2015 16:05 CJELLIO251
Total Carbon
TOC 0.332 mg/L SM5310C/EPA9060A 12/02/2015 13:37 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/02/2015 10:37 CJELLIO51
For sample 2015037573 (ABMW-03S), the total metals concentrations were generally lower than the dissolved of the
same sample. The total metals bottle was re-analyzed undigested, and the results matched the original analyses. No
further action was taken.
-- Additional Information --
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
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#=CL#
December 07, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278078
92278078
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120036
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 02, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 22
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278078
J15120036
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 22
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278078
J15120036
Lab ID Sample ID Matrix Date Collected Date Received
92278078001 2015037569 Water 12/01/15 10:05 12/02/15 14:15
92278078002 2015037571 Water 12/01/15 10:50 12/02/15 14:15
92278078003 2015037572 Water 12/01/15 09:22 12/02/15 14:15
92278078004 2015037573 Water 12/01/15 11:20 12/02/15 14:15
92278078005 2015037574 Water 12/01/15 12:15 12/02/15 14:15
92278078006 2015037575 Water 12/01/15 16:16 12/02/15 14:15
92278078007 2015037576 Water 12/01/15 13:25 12/02/15 14:15
92278078008 2015037577 Water 12/01/15 15:10 12/02/15 14:15
92278078009 2015037578 Water 12/01/15 13:45 12/02/15 14:15
92278078010 2015037580 Water 12/01/15 00:00 12/02/15 14:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 22
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278078
J15120036
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278078001 2015037569 EPA 218.7 1 PASI-OTK1
92278078002 2015037571 EPA 218.7 1 PASI-OTK1
92278078003 2015037572 EPA 218.7 1 PASI-OTK1
92278078004 2015037573 EPA 218.7 1 PASI-OTK1
92278078005 2015037574 EPA 218.7 1 PASI-OTK1
92278078006 2015037575 EPA 218.7 1 PASI-OTK1
92278078007 2015037576 EPA 218.7 1 PASI-OTK1
92278078008 2015037577 EPA 218.7 1 PASI-OTK1
92278078009 2015037578 EPA 218.7 1 PASI-OTK1
92278078010 2015037580 EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 22
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278078
J15120036
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278078007 2015037576
Chromium, Hexavalent 0.043 ug/L 12/05/15 01:120.030EPA 218.7
92278078009 2015037578
Chromium, Hexavalent 0.038 ug/L 12/05/15 01:380.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 22
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278078
J15120036
Method:
Client:Duke Energy
EPA 218.7
Date:December 07, 2015
Description:Hexavalent Chromium by IC
General Information:
10 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037569 Lab ID: 92278078001 Collected: 12/01/15 10:05 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/04/15 22:36 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037571 Lab ID: 92278078002 Collected: 12/01/15 10:50 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/04/15 23:41 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037572 Lab ID: 92278078003 Collected: 12/01/15 09:22 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/05/15 00:20 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037573 Lab ID: 92278078004 Collected: 12/01/15 11:20 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/05/15 00:33 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037574 Lab ID: 92278078005 Collected: 12/01/15 12:15 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/05/15 00:46 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037575 Lab ID: 92278078006 Collected: 12/01/15 16:16 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/05/15 00:59 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037576 Lab ID: 92278078007 Collected: 12/01/15 13:25 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.043 ug/L 12/05/15 01:12 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037577 Lab ID: 92278078008 Collected: 12/01/15 15:10 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/05/15 01:25 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037578 Lab ID: 92278078009 Collected: 12/01/15 13:45 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.038 ug/L 12/05/15 01:38 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 22
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278078
J15120036
Sample: 2015037580 Lab ID: 92278078010 Collected: 12/01/15 00:00 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/05/15 01:51 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 22
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278078
J15120036
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52722
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples: 92278078001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1410260
Associated Lab Samples:
Matrix: Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/04/15 16:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1410261LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.075.075 100 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1410262MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278080008
1410263
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 134 85-115134 0 20.025ND 0.034 0.033
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1410264MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278080018
1410265
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 100 85-11592 9 20.075ND 0.075 0.069
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 22
Page 68 of 119
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278078
J15120036
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52727
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92278078002, 92278078003, 92278078004, 92278078005, 92278078006, 92278078007, 92278078008,
92278078009, 92278078010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1410802
Associated Lab Samples:
Matrix: Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/04/15 23:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1410803LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.072.075 96 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1410804MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278078002
1410805
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 108 85-115116 6 20.075ND 0.097 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 22
Page 69 of 119
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278078
J15120036
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 22
Page 70 of 119
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278078
J15120036
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278078001 WETA/527222015037569EPA 218.7
92278078002 WETA/527272015037571EPA 218.7
92278078003 WETA/527272015037572EPA 218.7
92278078004 WETA/527272015037573EPA 218.7
92278078005 WETA/527272015037574EPA 218.7
92278078006 WETA/527272015037575EPA 218.7
92278078007 WETA/527272015037576EPA 218.7
92278078008 WETA/527272015037577EPA 218.7
92278078009 WETA/527272015037578EPA 218.7
92278078010 WETA/527272015037580EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 04:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 22
Page 71 of 119
Page 21 of 22
Page 72 of 119
Page 22 of 22
Page 73 of 119
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QL03068Lot Number:
J15120036Project Number:
AB GW Assessment Water - MayoProject Name:
12/09/2015Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 24
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QL03068
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Mayo
Project Number: J15120036
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QL03068

Project Name: AB GW Assessment Water - Mayo
Project Number: J15120036
Sample Number Sample ID Matrix Date Sampled Date Received
001 12/01/2015 10052015037569Aqueous 12/03/2015
002 12/01/2015 10502015037571Aqueous 12/03/2015
003 12/01/2015 09222015037572Aqueous 12/03/2015
004 12/01/2015 11202015037573Aqueous 12/03/2015
005 12/01/2015 12152015037574Aqueous 12/03/2015
006 12/01/2015 16162015037575Aqueous 12/03/2015
007 12/01/2015 13252015037576Aqueous 12/03/2015
008 12/01/2015 15102015037577Aqueous 12/03/2015
009 12/01/2015 13452015037578Aqueous 12/03/2015
010 12/01/20152015037580Aqueous 12/03/2015
(10 samples)
Page: 3 of 24
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QL03068

Project Name: AB GW Assessment Water - Mayo
Project Number: J15120036
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015037569 Aqueous Alkalinity SM 2320B-310 mg/L 5
001 2015037569 Aqueous Bicarbonate Alkalinity SM 2320B-310 mg/L 5
001 2015037569 Aqueous Methane RSK - 175 12000 ug/L 6
002 2015037571 Aqueous Alkalinity SM 2320B-250 mg/L 7
002 2015037571 Aqueous Bicarbonate Alkalinity SM 2320B-250 mg/L 7
002 2015037571 Aqueous Methane RSK - 175 82 ug/L 8
003 2015037572 Aqueous Alkalinity SM 2320B-170 mg/L 9
003 2015037572 Aqueous Bicarbonate Alkalinity SM 2320B-170 mg/L 9
003 2015037572 Aqueous Methane RSK - 175 7700 ug/L 10
004 2015037573 Aqueous Alkalinity SM 2320B-36 mg/L 11
004 2015037573 Aqueous Bicarbonate Alkalinity SM 2320B-36 mg/L 11
005 2015037574 Aqueous Alkalinity SM 2320B-400 mg/L 13
005 2015037574 Aqueous Bicarbonate Alkalinity SM 2320B-400 mg/L 13
005 2015037574 Aqueous Methane RSK - 175 4300 ug/L 14
006 2015037575 Aqueous Alkalinity SM 2320B-550 mg/L 15
006 2015037575 Aqueous Bicarbonate Alkalinity SM 2320B-550 mg/L 15
006 2015037575 Aqueous Methane RSK - 175 12000 ug/L 16
007 2015037576 Aqueous Alkalinity SM 2320B-220 mg/L 17
007 2015037576 Aqueous Bicarbonate Alkalinity SM 2320B-220 mg/L 17
007 2015037576 Aqueous Methane RSK - 175 260 ug/L 18
008 2015037577 Aqueous Alkalinity SM 2320B-100 mg/L 19
008 2015037577 Aqueous Bicarbonate Alkalinity SM 2320B-100 mg/L 19
008 2015037577 Aqueous Methane RSK - 175 620 ug/L 20
009 2015037578 Aqueous Alkalinity SM 2320B-88 mg/L 21
009 2015037578 Aqueous Bicarbonate Alkalinity SM 2320B-88 mg/L 21
(25 detections)
Page: 4 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037569
QL03068-001
12/01/2015 1005
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2116 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2116 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2116 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 310 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 310 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 24
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037569
QL03068-001
12/01/2015 1005
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 5 12/08/2015 2152 JJG 91669
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 12000 2ug/L50
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037571
QL03068-002
12/01/2015 1050
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0035 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0035 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0035 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 250 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 250 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 24
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037571
QL03068-002
12/01/2015 1050
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1902 JJG 91655
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 82 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037572
QL03068-003
12/01/2015 0922
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0042 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0042 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0042 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 170 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 170 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 24
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037572
QL03068-003
12/01/2015 0922
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 5 12/08/2015 2218 JJG 91669
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 7700 2ug/L50
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037573
QL03068-004
12/01/2015 1120
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0046 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0046 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0046 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 36 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 36 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 11 of 24
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037573
QL03068-004
12/01/2015 1120
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1935 JJG 91655
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 12 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037574
QL03068-005
12/01/2015 1215
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0059 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0059 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0059 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 400 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 400 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 13 of 24
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037574
QL03068-005
12/01/2015 1215
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 4 12/08/2015 2235 JJG 91669
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 4300 2ug/L40
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 14 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037575
QL03068-006
12/01/2015 1616
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0133 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0133 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0133 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 550 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 550 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 15 of 24
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037575
QL03068-006
12/01/2015 1616
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 5 12/09/2015 1210 JJG 91762
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 12000 2ug/L50
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 16 of 24
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037576
QL03068-007
12/01/2015 1325
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0141 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0141 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0141 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 220 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 220 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 17 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037576
QL03068-007
12/01/2015 1325
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 2316 JJG 91669
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 260 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 18 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037577
QL03068-008
12/01/2015 1510
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0146 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0146 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0146 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 100 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 100 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 19 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037577
QL03068-008
12/01/2015 1510
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 2333 JJG 91669
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 620 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 20 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037578
QL03068-009
12/01/2015 1345
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0205 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0205 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0205 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 88 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 88 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 21 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037578
QL03068-009
12/01/2015 1345
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/09/2015 0008 JJG 91669
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 22 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037580
QL03068-010
12/01/2015
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0209 MJI 91406
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0209 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0209 MJI
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 23 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015037580
QL03068-010
12/01/2015
12/03/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15120036
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/09/2015 1237 JJG 91762
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 24 of 24
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Shealy Environmental Services, Inc.

QC Summary
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:QQ91396-001
91396
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 12/04/2015 182810mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:QQ91396-002
91396
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 92 12/04/2015 18349210090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MS
Batch:
Sample ID:QL03068-001MS
91396
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(mg/L)(mg/L)(mg/L)
Alkalinity 390 12/04/2015 21247710070-1303101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MSD
Batch:
Sample ID:QL03068-001MD
91396
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
Limit
Sample
Amount
Dil(mg/L)(mg/L)(mg/L)
Alkalinity 390 12/04/2015 21327410070-1300.83 203101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:QQ91406-001
91406
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 12/05/2015 002110mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:QQ91406-002
91406
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 95 12/05/2015 00289510090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MS
Batch:
Sample ID:QL03068-005MS
91406
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(mg/L)(mg/L)(mg/L)
Alkalinity 470 12/05/2015 0108N6610070-1304001
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MSD
Batch:
Sample ID:QL03068-005MD
91406
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
Limit
Sample
Amount
Dil(mg/L)(mg/L)(mg/L)
Alkalinity 460 12/05/2015 0122N6510070-1300.20 204001
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ91655-001
91655
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 12/08/2015 114910ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ91655-002
91655
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 310 12/08/2015 111710530070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ91655-003
91655
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 320 12/08/2015 121611030070-1304.8 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ91669-001
91669
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 12/08/2015 211710ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ91669-002
91669
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 310 12/08/2015 204610530070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ91669-003
91669
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 310 12/08/2015 210110430070-1301.7 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ91762-001
91762
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 12/09/2015 114410ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ91762-002
91762
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 260 12/09/2015 11088730070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ91762-003
91762
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 260 12/09/2015 11278830070-1300.14 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QL03068
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Chain of Custody
and
Miscellaneous Documents
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Page 119 of 119