NC0038377_J15090363F_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15090363
Project Name:MAYO STEAM - AB GW ASSESSMENT SPECIATION
Lab Contact:Peggy Kendall
Date:10/8/2015
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Brandon Russo, Kathy Webb, John Toepfer
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 45
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015030450 MAYO STEAM 10-Sep-15 9:50 AM Synterra ABMW-02BR
2015030451 MAYO STEAM 10-Sep-15 2:22 PM Synterra ABMW-03
2015030452 MAYO STEAM 10-Sep-15 9:22 AM Synterra ABMW-01
2015030453 MAYO STEAM 10-Sep-15 2:40 PM Synterra ABMW-03S
2015030454 MAYO STEAM 10-Sep-15 10:20 AM Synterra ABMW-02
2015030455 MAYO STEAM 10-Sep-15 2:15 PM Synterra MW-12D
2015030456 MAYO STEAM 10-Sep-15 12:45 PM Synterra EB-1
7 Total Samples
Page 2 of 45
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Peggy Kendall Date:10/8/2015
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 45
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090363
2015030450
Collection Date: 10-Sep-15 9:50 AM
Site: ABMW-02BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete Vendor Method V_BRAND
Page 4 of 45
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090363
2015030451
Collection Date: 10-Sep-15 2:22 PM
Site: ABMW-03
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete Vendor Method V_BRAND
Page 5 of 45
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090363
2015030452
Collection Date: 10-Sep-15 9:22 AM
Site: ABMW-01
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete Vendor Method V_BRAND
Page 6 of 45
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090363
2015030453
Collection Date: 10-Sep-15 2:40 PM
Site: ABMW-03S
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete Vendor Method V_BRAND
Page 7 of 45
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090363
2015030454
Collection Date: 10-Sep-15 10:20 AM
Site: ABMW-02
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete Vendor Method V_BRAND
Page 8 of 45
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090363
2015030455
Collection Date: 10-Sep-15 2:15 PM
Site: MW-12D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete Vendor Method V_BRAND
Page 9 of 45
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090363
2015030456
Collection Date: 10-Sep-15 12:45 PM
Site: EB-1
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete Vendor Method V_BRAND
Page 10 of 45

18804 North Creek Parkway, Suite 100, Bothell, WA 98011 • T: 206-632-6206• F: 206-632-6017 • www.brooksapplied.com

October 7, 2015

Peggy Kendall
Duke Energy Analytical Laboratory
Mail Code MGO3A2 (Building 7405)
13339 Hagers Ferry Rd.
Huntersville, NC 28078
980-875-5848

Project: Duke Energy Progress Mayo (LIMS# J15090363)

Ms. Kendall,

Attached is the report associated with seven (7) aqueous samples submitted for hexavalent
chromium, arsenic speciation, iron speciation, and manganese speciation analyses. The samples
were received in a sealed cooler at 2.1°C on September 11, 2015. Hexavalent chromium analysis
was performed by ion chromatography inductively coupled plasma dynamic reaction cell mass
spectrometry (IC-ICP-DRC-MS). Arsenic speciation analyses were performed by IC-ICP-DRC-
MS. All samples requesting iron speciation analysis were analyzed by spectrophotometry.
Mn(II) analysis was performed via IC-ICP-DRC-MS. Mn(IV) analysis were performed via
digestion and subsequent analysis by inductively coupled plasma triple quadrupole mass
spectrometry (ICP-QQQ-MS). Any issues associated with the analyses are addressed in the
following report.

If you have any questions, please feel free to contact me at your convenience.

Sincerely,
Jeremy Maute
Project Manager
Brooks Applied Labs, LLC

Page 11 of 45
Brooks Applied Labs, LLC

Report prepared for:

Peggy Kendall
Duke Energy Analytical Laboratory
Mail Code MGO3A2 (Building 7405)
13339 Hagers Ferry Rd.
Huntersville, NC 28078

Project: Duke Energy Progress Mayo (LIMS# J15090363)

October 7, 2015

1. Sample Reception

Seven (7) aqueous samples were submitted for hexavalent chromium, arsenic speciation, iron
speciation, and manganese speciation analyses. The samples were received in acceptable
condition on September 11, 2015 in a sealed container at a temperature of 2.1°C.

All samples were received in a laminar flow clean hood, void of trace metals contamination
and ultra-violet radiation, and were designated discrete sample identifiers. Sample fractions
requesting hexavalent chromium, arsenic speciation, and iron speciation analyses were field
filtered by the client. Two containers were submitted for each client sample requesting
manganese speciation, one field filtered fraction and one unfiltered fraction.

Upon receipt the pH of each aqueous sample submitted for hexavalent chromium analysis
was checked to confirm the adequacy of the field-preservation with the buffer solution
provided by Brooks Applied Labs (BAL). An aliquot of each sample submitted for
hexavalent chromium analysis was decanted into a clean polypropylene tube. All hexavalent
chromium sample fractions were stored in a secure refrigerator maintained at a temperature
of 4oC, until the analyses could be performed.

An aliquot of each sample submitted for arsenic speciation analysis was decanted into a clean
polypropylene centrifuge tube; all filtrates and original bottles were then stored in a secure,
monitored refrigerator (maintained at a temperature of ≤6oC) until the analyses could be
performed.

The sample fractions requesting iron speciation analysis were stored in a secure, monitored
refrigerator (maintained at a temperature of ≤6oC) until the analyses could be performed.

An aliquot of each filtered sample submitted for manganese speciation analysis was decanted
into a polypropylene centrifuge tube for Mn(II) analysis. These fractions were stored in a
secure, monitored refrigerator (maintained at a temperature of ≤6oC) until the analyses could
be performed. Subsequently, the original bottles (filtered and unfiltered fractions) intended
Page 12 of 45
for Mn speciation were preserved to pH < 2 with concentrated HNO3 and then stored in a
secure polyethylene container, known to be free from trace metals contamination, until the
digestion could be performed.

2. Sample Preparation

All sample preparation is performed in laminar flow clean hoods known to be free from trace
metals contamination. All applied water for dilutions and sample preservatives are
monitored for contamination to account for any biases associated with the sample results.

Hexavalent Chromium Analysis by IC-ICP-DRC-MS Prior to analysis, an aliquot of each
sample was filtered with a syringe filter (0.45µm) and injected directly into a sealed
autosampler vial. No further sample preparation was performed as any chemical alteration of
a sample may shift the equilibrium of the system, resulting in changes in speciation ratios.

Arsenic Speciation Analysis by IC-ICP-DRC-MS An aliquot of each sample was filtered
directly into a sealed autosampler vial. No further sample preparation was performed as a
buffered EDTA solution was provided by Brooks Applied Labs for field-preservation of the
submitted samples.

Iron Speciation Analysis by Spectrophotometry No sample preparation was required as a de-
gassed HCL solution was provided by Brooks Applied Labs for field-preservation of the
submitted samples.

Manganese Mn(II) Analysis by IC-ICP-DRC-MS An aliquot of each sample was filtered
(0.45µm) directly into an autosampler vial for Mn(II) analysis. No additional sample
preparation was performed as any chemical alteration of the samples may shift the
equilibrium of the system resulting in changes in speciation ratios.

Manganese Mn(IV) Analysis by ICP-QQQ-MS Each filtered and unfiltered sample submitted
for Mn speciation analysis was preserved with 1% HNO3 (v/v) upon sample receipt. Each
sample fraction was then further digested on a hotblock apparatus with aliquots of 50%
HNO3 (v/v) and 50% HCl (v/v), in accordance with the digestion procedure specified in EPA
Method 200.8. All resulting sample digests were analyzed for total manganese via
inductively coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS).

3. Sample Analysis

All sample analysis is preceded by a minimum of a five-point calibration curve spanning the
entire concentration range of interest. Calibration curves are performed at the beginning of
each analytical day. All calibration curves, associated with each species of interest, are
standardized by linear regression resulting in a response factor. All sample results are
instrument blank corrected to account for any operational biases associated with the
analytical platform.

Page 13 of 45
Prior to sample analysis, all calibration curves are verified using second source standards
which are identified as initial calibration verification standards (ICV).

Ongoing instrument performance is identified by the analysis of continuing calibration
verification standards (CCV) and continuing calibration blanks (CCB) at a minimum interval
of every ten analytical runs.

Hexavalent Chromium Analysis by IC-ICP-DRC-MS Each sample for hexavalent chromium
analysis was analyzed by ion chromatography inductively coupled plasma dynamic reaction
cell mass spectrometry (IC-ICP-DRC-MS). An aliquot of each sample is injected onto an
anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting chromium
species are then introduced into a radio frequency (RF) plasma where energy-transfer
processes cause desolvation, atomization, and ionization. The ions are extracted from the
plasma through a differentially-pumped vacuum interface and travel through a pressurized
chamber (DRC) containing a reaction gas which preferentially reacts with interfering ions of
the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted
through the mass analyzer and the resulting current is processed by a data handling system.

Retention times for each eluting species are compared to known standards for species
identification.

Arsenic Speciation Analysis by IC-ICP-DRC-MS Each sample was analyzed for arsenic
speciation via ion chromatography inductively coupled plasma dynamic reaction cell mass
spectrometry (IC-ICP-DRC-MS). Aliquots of each sample are injected onto an anion
exchange column and eluted isocratically. The eluting chromium species are then introduced
into a radio frequency (RF) plasma where energy-transfer processes cause desolvation,
atomization, and ionization. The ions are extracted from the plasma through a differentially-
pumped vacuum interface and travel through a pressurized chamber (DRC) containing a
reaction gas which preferentially reacts with interfering ions of the same target mass to
charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer
and the resulting current is processed by a data handling system.

Retention times for each eluting species are compared to known standards for species
identification.

Iron Speciation Analysis by Spectrophotometry All samples submitted for Fe speciation
quantification were analyzed in accordance with the scientifically accepted method outlined
by:

Stookey, L.L., (1970). “Ferrozine - A new spectrophotometric reagent for iron”,
Anal.Chem., 42:779-81.

Manganese Mn(II) Analysis by IC-ICP-DRC-MS All samples for Mn(II) analysis were
analyzed by ion chromatography inductively coupled plasma dynamic reaction cell mass
spectrometry (IC-ICP-DRC-MS). Aliquots of each sample are injected onto an anion
exchange column and mobilized by an acidic (pH < 7) gradient. An ion pairing agent
Page 14 of 45
provides a dynamic ion exchange mechanism for the cationic manganese species on the
chromatographic column. The differences in the affinity of manganese species towards the
ion pair agent and the column results in separation. The eluting selenium species are then
introduced into a radio frequency (RF) plasma where energy-transfer processes cause
desolvation, atomization, and ionization. The ions are extracted from the plasma through a
differentially-pumped vacuum interface and travel through a pressurized chamber (DRC)
containing a reaction gas which preferentially reacts with interfering ions of the same target
mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass
analyzer and the resulting current is processed by a data handling system.

Retention times for each eluting species are compared to known standards for species
identification.

Manganese Mn(IV) Analysis by ICP-QQQ-MS All samples submitted for Mn speciation
quantitation were analyzed by inductively coupled plasma triple quadrupole mass
spectrometry (ICP-QQQ-MS). Aliquots of each sample digest are introduced into a radio
frequency (RF) plasma where energy-transfer processes cause desolvation, atomization, and
ionization. The ions are extracted from the plasma through a differentially-pumped vacuum
interface and travel through an initial quadrupole (Q1), which filters the target masses prior
to their entrance into a second chamber. The second chamber contains specific reactive
gasses or collision gasses that preferentially react either with interfering ions of the same
target mass to charge ratios (m/z) or with the target analyte, producing an entirely different
mass to charge ratio (m/z) which can then be differentiated from the initial interferences.
The ions then exit the collision/reaction cell into and additional quadrupole (Q2). A solid-
state detector detects ions transmitted through the mass analyzer, on the basis of their mass-
to-charge ratio (m/z), and the resulting current is processed by a data handling system.

4. Analytical Issues

No significant analytical issues were encountered. With the exception noted below, all
quality control parameters associated with the samples were within acceptance limits.

The monomethylarsonic acid spike recovery for the laboratory fortified blank (LFB) sample
was greater than the upper control limit of 120% (at 127%). All monomethylarsonic acid
results in the batch were non-detects. An LFB recovery for monomethylarsonic acid that is
biased high should have no impact on associated results that are below the detection limit.
Consequently, no corrective actions were required and no qualification of data was
necessary.

Unknown arsenic species were present in various samples associated with the arsenic
speciation analysis resulting in late elution into following sample injections. The late eluting
peaks did not affect the target arsenic species; however, differentiation between late eluting
peaks and other unknown arsenic species for a given sample could not be accomplished.
Consequently, unknown arsenic species are not reported.

Page 15 of 45

Mn(IV) is quantified by analyzing the water samples for total Mn and dissolved Mn. Mn(IV)
is operationally defined as the difference between the filtered and unfiltered total Mn
concentrations, since it is thermodynamically favored to be in the form of a precipitate.

The estimated method detection limit (eMDL) for hexavalent chromium is generated from
replicate analyses of the lowest standard in the calibration curve.

The eMDL values for arsenite, arsenate, monomethylarsonic acid, and dimethylarsinic acid
are generated using the standard deviation of replicate analyses of the lowest standard in the
calibration curve.

The eMDL values for Fe speciation were set at 5.0 based on the sensitivity of the instrument.

The eMDL for Mn(II) generated from replicate analyses of the lowest standard in the
calibration curve yielded a detection limit value less than 10% the level of the associated
method reporting limit (MRL) . The MDL may not be less than 10% the level of the MRL so
the Mn(II) eMDL was raised to a value 10% the magnitude of the MRL.

The eMDL values for Mn(IV) been calculated using the standard deviation of the method
blanks prepared and analyzed concurrently with the submitted samples.

If you have any questions or concerns regarding this report, please feel free to contact me.

Sincerely,
Jeremy Maute
Project Manager
Brooks Applied Labs, LLC

Page 16 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Definition of Data Qualifiers
(Effective 9/23/09)
Laboratory Accreditation
BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida
Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is
also certified by many other states to perform environmental analyses. For a current list of our accreditations /certifications,
please visit our website at <http://www.brooksrand.com/about/accreditations-certifications/>. Results reported relate only to
the samples listed in the report.
Report Information
BLK
BRL
BS
CAL
CCV
D
DUP
ICV
MSD
ND
NR
PS
REC
RPD
RSD
SCV
SOP
method blank
Brooks Rand Labs
laboratory fortified blank
calibration standard
continuing calibration verification
dissolved fraction
duplicate
initial calibration verification
matrix spike duplicate
non-detect
non-reportable
post preparation spike
percent recovery
relative percent difference
relative standard deviation
secondary calibration verification
standard operating procedure
MDL
MRL
MS
method detection limit
method reporting limit
matrix spike
SRM
T
COC
standard reference material
total recoverable fraction
chain of custody record
Common Abbreviations
These qualifiers are based on those previously utilized by Brooks Rand Labs, those found in the EPA SOW ILM03.0,
Exhibit B, Section III, pg. B-18, and the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic
Superfund Data Review; USEPA; January 2010. These supersede all previous qualifiers ever employed by BRL.
Detected by the instrument, the result is > the MDL but ≤ the MRL. Result is reported and considered an estimate.J
E An estimated value due to the presence of interferences. A full explanation is presented in the narrative.
H Holding time and/or preservation requirements not met. Result is estimated.
J-1 Estimated value. A full explanation is presented in the narrative.
J-M Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated.
J-N Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated.
M Duplicate precision (RPD) was not within acceptance criteria. Result is estimated.
N Spike recovery was not within acceptance criteria. Result is estimated.
R Rejected, unusable value. A full explanation is presented in the narrative.
U Result is ≤ the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL.
X Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch.
Result is estimated.
Field Quality Control Samples
Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type
and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be
done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field
quality control samples.
IBL instrument blank
continuing calibration blankCCB not calculatedN/C
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 17 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Sample Information
Report Matrix Type ReceivedSampledSampleLab IDAlias
N15I048-01ABMW-02BR 09/09/2015 09/11/2015Samplewater2015030450
N15I048-02ABMW-03 09/10/2015 09/11/2015Samplewater2015030451
N15I048-03ABMW-01 09/10/2015 09/11/2015Samplewater2015030452
N15I048-04ABMW-01 09/10/2015 09/11/2015SampleWater2015030452
N15I048-05ABMW-03S 09/10/2015 09/11/2015Samplewater2015030453
N15I048-06ABMW-02 09/10/2015 09/11/2015Samplewater2015030454
N15I048-07MW-12D 09/10/2015 09/11/2015Samplewater2015030455
N15I048-08EB-1 09/10/2015 09/11/2015Samplewater2015030456
Batch Summary
Analyte Prepared Analyzed SequenceBatchLab Matrix Method
NC0004709/11/2015 09/12/2015 S150023IC-ICP-MSAs(III)Water
NC0004709/11/2015 09/12/2015 S150023IC-ICP-MSAs(V)Water
NC0010009/16/2015 09/17/2015 S150033EPA 7199 ModCr(VI)Water
NC0004709/11/2015 09/12/2015 S150023IC-ICP-MSDMAsWater
NC0008909/11/2015 09/11/2015 S150028SM 3500-Fe B mod.Fe(II)Water
NC0009209/11/2015 09/11/2015 S150026SM 3500-Fe B mod.Fe(Reduc) Water
NC0004709/11/2015 09/12/2015 S150023IC-ICP-MSMMAsWater
NC0011709/18/2015 09/22/2015 S150040EPA 6800 ModMn(II)Water
NC0009309/17/2015 09/22/2015 S150038EPA 200.8MnWater
NC0012709/23/2015 09/23/2015 S150050EPA 200.8MnWater
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 18 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Sample Results
Sample Sequence Result MDL MRL Unit BatchQualifierAnalyte BasisReport Matrix
ABMW-01, 2015030452
123D S150023NC00047water2.160.551N15I048-03 As(III)µg/L
72.0D S150023NC00047water2.160.406N15I048-03 As(V)µg/L
0.007D U S150033NC00100water0.0510.007N15I048-03 Cr(VI)µg/L
0.498D U S150023NC00047water2.250.498N15I048-03 DMAs µg/L
3950D S150028NC00089water1000250N15I048-03 Fe(II)µg/L
359D N/A[CALC]water 1000250N15I048-03 Fe(III)µg/L
4310D S150026NC00092water1000250N15I048-03 Fe(Reduc)µg/L
0.310D U S150023NC00047water2.280.310N15I048-03 MMAs µg/L
3140T S150038NC00093Water1.000.09N15I048-04 Mn µg/L
3090D S150050NC00127Water1.000.13N15I048-04 Mn µg/L
3340D S150040NC00117water25025.0N15I048-03 Mn(II)µg/L
48.1T N/A[CALC]Water 1.000.13N15I048-04 Mn(IV)µg/L
ABMW-02, 2015030454
402D S150023NC00047water2.160.551N15I048-06 As(III)µg/L
3.86D S150023NC00047water2.160.406N15I048-06 As(V)µg/L
0.498D U S150023NC00047water2.250.498N15I048-06 DMAs µg/L
0.310D U S150023NC00047water2.280.310N15I048-06 MMAs µg/L
ABMW-02BR, 2015030450
0.560D J S150023NC00047water2.160.551N15I048-01 As(III)µg/L
0.406D U S150023NC00047water2.160.406N15I048-01 As(V)µg/L
0.498D U S150023NC00047water2.250.498N15I048-01 DMAs µg/L
0.310D U S150023NC00047water2.280.310N15I048-01 MMAs µg/L
ABMW-03, 2015030451
45.0D S150023NC00047water2.160.551N15I048-02 As(III)µg/L
4.80D S150023NC00047water2.160.406N15I048-02 As(V)µg/L
0.498D U S150023NC00047water2.250.498N15I048-02 DMAs µg/L
0.310D U S150023NC00047water2.280.310N15I048-02 MMAs µg/L
ABMW-03S, 2015030453
1.58D J S150023NC00047water2.160.551N15I048-05 As(III)µg/L
0.406D U S150023NC00047water2.160.406N15I048-05 As(V)µg/L
0.498D U S150023NC00047water2.250.498N15I048-05 DMAs µg/L
0.310D U S150023NC00047water2.280.310N15I048-05 MMAs µg/L
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 19 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Sample Results
Sample Sequence Result MDL MRL Unit BatchQualifierAnalyte BasisReport Matrix
EB-1, 2015030456
0.551D U S150023NC00047water2.160.551N15I048-08 As(III)µg/L
0.406D U S150023NC00047water2.160.406N15I048-08 As(V)µg/L
0.011D J S150033NC00100water0.0510.007N15I048-08 Cr(VI)µg/L
0.498D U S150023NC00047water2.250.498N15I048-08 DMAs µg/L
0.310D U S150023NC00047water2.280.310N15I048-08 MMAs µg/L
MW-12D, 2015030455
0.551D U S150023NC00047water2.160.551N15I048-07 As(III)µg/L
0.406D U S150023NC00047water2.160.406N15I048-07 As(V)µg/L
0.357D S150033NC00100water0.0510.007N15I048-07 Cr(VI)µg/L
0.498D U S150023NC00047water2.250.498N15I048-07 DMAs µg/L
0.310D U S150023NC00047water2.280.310N15I048-07 MMAs µg/L
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 20 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Accuracy & Precision Summary
Batch: NC00047
Analyte Result UnitsNative Spike REC & Limits RPD & Limits
Method: IC-ICP-MS
Lab Matrix: Water
Sample
Laboratory Fortified Blank (NC00024)NC00047-BS1
5.000 103%µg/L 80-120As(III)5.173
5.000 101%µg/L 80-120As(V)5.039
3.198 104%µg/L 80-120DMAs3.340
Laboratory Fortified Blank (NC00025)NC00047-BS2
5.924 127%µg/L 80-120MMAs7.513
Duplicate (N15I014-05)NC00047-DUP1
µg/L 253%As(III)123.0126.8
µg/L 254%As(V)143.4148.9
µg/L 25N/CDMAsNDND
µg/L 25N/CMMAsNDND
Matrix Spike (N15I014-05)NC00047-MS1
216.0 93%µg/L 75-125As(III)328.3126.8
216.0 103%µg/L 75-125As(V)371.4148.9
225.1 98%µg/L 75-125DMAs219.9ND
227.7 109%µg/L 75-125MMAs248.0ND
Matrix Spike Duplicate (N15I014-05)NC00047-MSD1
216.0 96%µg/L 75-125 252%As(III)335.0126.8
216.0 102%µg/L 75-125 250.3%As(V)370.2148.9
225.1 98%µg/L 75-125 250.6%DMAs 221.3ND
227.7 111%µg/L 75-125 252%MMAs 252.8ND
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 21 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Accuracy & Precision Summary
Batch: NC00089
Analyte Result UnitsNative Spike REC & Limits RPD & Limits
Method: SM 3500-Fe B mod.
Lab Matrix: Water
Sample
Duplicate (N15I048-03)NC00089-DUP1
µg/L 250%Fe(II)39483948
Matrix Spike (N15I048-03)NC00089-MS1
25000 97%µg/L 75-125Fe(II)281103948
Matrix Spike Duplicate (N15I048-03)NC00089-MSD1
25000 94%µg/L 75-125 252%Fe(II)275203948
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 22 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Accuracy & Precision Summary
Batch: NC00092
Analyte Result UnitsNative Spike REC & Limits RPD & Limits
Method: SM 3500-Fe B mod.
Lab Matrix: Water
Sample
Laboratory Fortified Blank (NC00155)NC00092-BS1
500.0 109%µg/L 80-120Fe(Reduc)543.1
Certified Reference Material (NC00046, TMDA 70.2 Reference Standard)NC00092-SRM1
376.0 113%µg/L 75-125Fe(Reduc)423.5
Duplicate (N15I048-03)NC00092-DUP1
µg/L 253%Fe(Reduc)44264307
Matrix Spike (N15I048-03)NC00092-MS1
25000 107%µg/L 75-125Fe(Reduc)309804307
Matrix Spike Duplicate (N15I048-03)NC00092-MSD1
25000 102%µg/L 75-125 254%Fe(Reduc)297904307
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 23 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Accuracy & Precision Summary
Batch: NC00093
Analyte Result UnitsNative Spike REC & Limits RPD & Limits
Method: EPA 200.8
Lab Matrix: Water
Sample
Laboratory Fortified Blank (NC00407)NC00093-BS1
500.0 106%µg/L 75-125Mn531.0
Certified Reference Material (NC00143, TMDA 70.2 Reference Standard - Bottle1)NC00093-SRM1
312.0 106%µg/L 75-125Mn329.3
Duplicate (N15I048-04)NC00093-DUP2
µg/L 252%Mn 30783136
Matrix Spike (N15I048-04)NC00093-MS2
1000 105%µg/L 75-125Mn41903136
Matrix Spike Duplicate (N15I048-04)NC00093-MSD2
1000 119%µg/L 75-125 253%Mn 43253136
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 24 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Accuracy & Precision Summary
Batch: NC00100
Analyte Result UnitsNative Spike REC & Limits RPD & Limits
Method: EPA 7199 Mod
Lab Matrix: Water
Sample
Laboratory Fortified Blank (NC00338)NC00100-BS1
2.002 97%µg/L 80-120Cr(VI)1.950
Duplicate (N15I036-03)NC00100-DUP1
µg/L 259%Cr(VI)0.0200.021
Matrix Spike (N15I036-03)NC00100-MS1
5.102 98%µg/L 75-125Cr(VI)5.0380.021
Matrix Spike Duplicate (N15I036-03)NC00100-MSD1
5.102 99%µg/L 75-125 250.7%Cr(VI)5.0730.021
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 25 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Accuracy & Precision Summary
Batch: NC00117
Analyte Result UnitsNative Spike REC & Limits RPD & Limits
Method: EPA 6800 Mod
Lab Matrix: Water
Sample
Laboratory Fortified Blank (NC00387)NC00117-BS1
10.00 109%µg/L 80-120Mn(II)10.91
Duplicate (N15I048-03)NC00117-DUP1
µg/L 254%Mn(II)34783337
Matrix Spike (N15I048-03)NC00117-MS1
2500 110%µg/L 75-125Mn(II)60923337
Matrix Spike Duplicate (N15I048-03)NC00117-MSD1
2500 108%µg/L 75-125 251%Mn(II)60283337
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 26 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Accuracy & Precision Summary
Batch: NC00127
Analyte Result UnitsNative Spike REC & Limits RPD & Limits
Method: EPA 200.8
Lab Matrix: Water
Sample
Laboratory Fortified Blank (NC00466)NC00127-BS1
1000 100%µg/L 75-125Mn995.1
Certified Reference Material (NC00143, TMDA 70.2 Reference Standard - Bottle1)NC00127-SRM1
312.0 96%µg/L 75-125Mn298.9
Duplicate (N15I048-04)NC00127-DUP1
µg/L 250.4%Mn 30993088
Matrix Spike (N15I048-04)NC00127-MS1
1000 96%µg/L 75-125Mn40473088
Matrix Spike Duplicate (N15I048-04)NC00127-MSD1
1000 93%µg/L 75-125 250.6%Mn 40233088
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 27 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Batch: NC00047
Method: IC-ICP-MS
Matrix: Water
Analyte: As(III)
Result UnitsSample
NC00047-BLK1 µg/L0.00
NC00047-BLK2 µg/L0.00
NC00047-BLK3 µg/L0.00
NC00047-BLK4 µg/L0.00
MDL: 0.551Average: 0.000 Standard Deviation: 0.000
Limit: 0.551Limit: 2.160 MRL: 2.16
Analyte: As(V)
Result UnitsSample
NC00047-BLK1 µg/L0.00
NC00047-BLK2 µg/L0.00
NC00047-BLK3 µg/L0.00
NC00047-BLK4 µg/L0.00
MDL: 0.406Average: 0.000 Standard Deviation: 0.000
Limit: 0.406Limit: 2.160 MRL: 2.16
Analyte: DMAs
Result UnitsSample
NC00047-BLK1 µg/L0.00
NC00047-BLK2 µg/L0.423
NC00047-BLK3 µg/L0.00
NC00047-BLK4 µg/L0.00
MDL: 0.498Average: 0.106 Standard Deviation: 0.211
Limit: 0.498Limit: 2.251 MRL: 2.25
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 28 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Analyte: MMAs
Result UnitsSample
NC00047-BLK1 µg/L0.00
NC00047-BLK2 µg/L0.00
NC00047-BLK3 µg/L0.00
NC00047-BLK4 µg/L0.00
MDL: 0.310Average: 0.000 Standard Deviation: 0.000
Limit: 0.310Limit: 2.277 MRL: 2.28
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 29 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Batch: NC00089
Method: SM 3500-Fe B mod.
Matrix: Water
Analyte: Fe(II)
Result UnitsSample
NC00089-BLK1 µg/L2.4
NC00089-BLK2 µg/L0.0
NC00089-BLK3 µg/L0.0
NC00089-BLK4 µg/L0.0
MDL: 5.0Average: 0.6
Limit: 5.0Limit: 20.0 MRL: 20.0
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 30 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Batch: NC00092
Method: SM 3500-Fe B mod.
Matrix: Water
Analyte: Fe(Reduc)
Result UnitsSample
NC00092-BLK1 µg/L0.0
NC00092-BLK2 µg/L2.4
NC00092-BLK3 µg/L0.0
NC00092-BLK4 µg/L0.0
MDL: 5.0Average: 0.6 Standard Deviation: 1.2
Limit: 5.0Limit: 20.0 MRL: 20.0
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 31 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Batch: NC00093
Method: EPA 200.8
Matrix: Water
Analyte: Total Mn
Result UnitsSample
NC00093-BLK1 µg/L0.06
NC00093-BLK2 µg/L0.03
NC00093-BLK3 µg/L0.03
NC00093-BLK4 µg/L0.02
MDL: 0.09Average: 0.04 Standard Deviation: 0.02
Limit: 0.06Limit: 0.20 MRL: 1.00
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 32 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Batch: NC00100
Method: EPA 7199 Mod
Matrix: Water
Analyte: Cr(VI)
Result UnitsSample
NC00100-BLK1 µg/L-0.001
NC00100-BLK2 µg/L0.002
NC00100-BLK3 µg/L-0.0003
NC00100-BLK4 µg/L-0.001
MDL: 0.007Average: 0.000 Standard Deviation: 0.001
Limit: 0.007Limit: 0.051 MRL: 0.051
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 33 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Batch: NC00117
Method: EPA 6800 Mod
Matrix: Water
Analyte: Mn(II)
Result UnitsSample
NC00117-BLK1 µg/L0.074
NC00117-BLK2 µg/L0.041
NC00117-BLK3 µg/L0.025
NC00117-BLK4 µg/L0.064
MDL: 0.500Average: 0.051 Standard Deviation: 0.022
Limit: 0.333Limit: 1.000 MRL: 5.00
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 34 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Method Blanks & Reporting Limits
Batch: NC00127
Method: EPA 200.8
Matrix: Water
Analyte: Dissolved Mn
Result UnitsSample
NC00127-BLK1 µg/L0.11
NC00127-BLK2 µg/L0.11
NC00127-BLK3 µg/L0.11
NC00127-BLK4 µg/L0.10
MDL: 0.13Average: 0.11 Standard Deviation: 0.01
Limit: 0.09Limit: 0.29 MRL: 1.00
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 35 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Sample Containers
Lab ID: N15I048-01 Report Matrix: water
Sample Type: Sample Received: 09/11/2015Sample: ABMW-02BR
Collected: 09/09/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler10ml EDTA 8/13/15 >4<6125mlBottle HDPE As-SP
Lab ID: N15I048-02 Report Matrix: water
Sample Type: Sample Received: 09/11/2015Sample: ABMW-03
Collected: 09/10/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler10ml EDTA 8/13/15 >4<6125mlBottle HDPE As-SP
Lab ID: N15I048-03 Report Matrix: water
Sample Type: Sample Received: 09/11/2015Sample: ABMW-01
Collected: 09/10/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler10ml EDTA 8/13/15 >4<6125mlBottle HDPE As-SP
B not
provided
coolernonenone15mlCent Tube 15mL Mn-SP
C not
provided
cooler2.7ml CrVI Preservative none 9-9.5125mlBottle Cr-SP
D not
provided
cooler2.5ml degassed HCL none <2125mlBottle HDPE - White Label
Lab ID: N15I048-04 Report Matrix: Water
Sample Type: Sample Received: 09/11/2015Sample: ABMW-01
Collected: 09/10/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler1% HNO3 (BRL) not provided <2125mlBottle HDPE - White Label
B not
provided
cooler1% HNO3 (BRL) not provided <2125mlBottle HDPE - White Label-D
Lab ID: N15I048-05 Report Matrix: water
Sample Type: Sample Received: 09/11/2015Sample: ABMW-03S
Collected: 09/10/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler10ml EDTA 8/13/15 >4<6125mlBottle HDPE As-SP
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 36 of 45
Project ID: DUK-HV1503Z
PM: Jeremy Maute
Client PM: Peggy Kendall
Client PO: 1217608
Sample Containers
Lab ID: N15I048-06 Report Matrix: water
Sample Type: Sample Received: 09/11/2015Sample: ABMW-02
Collected: 09/10/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler10ml EDTA 8/13/15 >4<6125mlBottle HDPE As-SP
Lab ID: N15I048-07 Report Matrix: water
Sample Type: Sample Received: 09/11/2015Sample: MW-12D
Collected: 09/10/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler10ml EDTA 8/13/15 >4<6125mlBottle HDPE As-SP
B not
provided
cooler2.7ml CrVI Preservative 9-9.5125mlBottle Cr-SP
Lab ID: N15I048-08 Report Matrix: water
Sample Type: Sample Received: 09/11/2015Sample: EB-1
Collected: 09/10/2015
Ship. Cont.pHP-LotPreservationLotSizeContainerDes
A not
provided
cooler10ml EDTA 8/13/15 >4<6125mlBottle HDPE As-SP
B not
provided
cooler2.7ml CrVI Preservative 9-9.5125mlBottle Cr-SP
Shipping Containers
cooler
Tracking No: 808184554892 via FedEx
Temperature: 2.1 °C
Coolant Type: Ice
Description: cooler
Damaged in transit? No
Returned to client? No
Custody seals present? No
Custody seals intact? No
COC present? Yes
Received: September 11, 2015 10:00
18804 North Creek Parkway, Suite 100, Bothell, WA 98011 · P(206) 632-6206 · F(206) 632-6017 · [e-mail] · www.brooksapplied.com
Page 37 of 45
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