NC0038377_J15090289report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15090289
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:9/21/2015
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Brandon Russo, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 73
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015030194 MAYO STEAM 11-Sep-15 12:26 PM Erin Black MW-07D
2015030195 MAYO STEAM 11-Sep-15 1:43 PM Erin Black MW-07BR
2015030196 MAYO STEAM 11-Sep-15 10:23 AM Erin Black MW-08BR
2015030197 MAYO STEAM 11-Sep-15 9:41 AM Erin Black MW-09BR
2015030198 MAYO STEAM 11-Sep-15 12:25 PM Erin Black MW-10BR
2015030199 MAYO STEAM 11-Sep-15 4:22 PM Erin Black MW-11BR
2015030200 MAYO STEAM 11-Sep-15 12:03 PM Erin Black CW-1
2015030201 MAYO STEAM 11-Sep-15 10:31 AM Erin Black CW-1D
2015030202 MAYO STEAM 11-Sep-15 10:30 AM Erin Black BG-2
2015030203 MAYO STEAM 11-Sep-15 3:20 PM Erin Black Filter Blank
2015030204 MAYO STEAM 11-Sep-15 3:20 PM Erin Black Equipment Blank
11 Total Samples
Page 2 of 73
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:9/21/2015
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030194
Collection Date:11-Sep-15 12:26 PM
Site:MW-07D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.031 mg-N/L EPA 353.2 09/14/2015 14:22 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 78 mg/L EPA 300.0 09/14/2015 14:40 BGN9034110
Sulfate 7.9 mg/L EPA 300.0 09/14/2015 14:40 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 11:35 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2015 14:21 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/15/2015 11:42 FCJORDA0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 09/15/2015 11:42 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 11:42 FCJORDA0.05 1
Iron (Fe)0.051 mg/L EPA 200.7 09/15/2015 11:42 FCJORDA0.01 1
Manganese (Mn)0.162 mg/L EPA 200.7 09/15/2015 11:42 FCJORDA0.005 1
Strontium (Sr)0.412 mg/L EPA 200.7 09/15/2015 11:42 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 09/15/2015 11:42 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.05 mg/L EPA 200.7 09/16/2015 09:54 FCJORDA0.01 1
Magnesium (Mg)2.56 mg/L EPA 200.7 09/16/2015 09:54 FCJORDA0.005 1
Potassium (K)0.272 mg/L EPA 200.7 09/16/2015 09:54 FCJORDA0.1 1
Sodium (Na)2.79 mg/L EPA 200.7 09/16/2015 09:54 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.164 mg/L EPA 200.7 09/15/2015 11:48 MHH71310.005 1
Barium (Ba)0.024 mg/L EPA 200.7 09/15/2015 11:48 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 11:48 MHH71310.05 1
Iron (Fe)0.161 mg/L EPA 200.7 09/15/2015 11:48 MHH71310.01 1
Manganese (Mn)0.166 mg/L EPA 200.7 09/15/2015 11:48 MHH71310.005 1
Strontium (Sr)0.418 mg/L EPA 200.7 09/15/2015 11:48 MHH71310.005 1
Zinc (Zn)0.034 mg/L EPA 200.7 09/15/2015 11:48 MHH71310.005 1
Page 4 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030194
Collection Date:11-Sep-15 12:26 PM
Site:MW-07D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Copper (Cu)1.10 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Molybdenum (Mo)1.24 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA0.2 1
Vanadium (V) Low Level 0.695 ug/L EPA 200.8 09/16/2015 01:16 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Molybdenum (Mo)1.37 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA0.2 1
Vanadium (V) Low Level 0.843 ug/L EPA 200.8 09/16/2015 17:06 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 5 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030195
Collection Date:11-Sep-15 1:43 PM
Site:MW-07BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.017 mg-N/L EPA 353.2 09/14/2015 14:23 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 09/14/2015 14:57 BGN9034110
Sulfate 1.9 mg/L EPA 300.0 09/14/2015 14:57 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 11:37 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2015 12:47 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.005 mg/L EPA 200.7 09/15/2015 11:46 FCJORDA0.005 1
Barium (Ba)0.139 mg/L EPA 200.7 09/15/2015 11:46 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 11:46 FCJORDA0.05 1
Iron (Fe)0.491 mg/L EPA 200.7 09/15/2015 11:46 FCJORDA0.01 1
Manganese (Mn)0.224 mg/L EPA 200.7 09/15/2015 11:46 FCJORDA0.005 1
Strontium (Sr)1.00 mg/L EPA 200.7 09/15/2015 11:46 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 11:46 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)56.2 mg/L EPA 200.7 09/16/2015 10:13M4 FCJORDA0.01 1
Magnesium (Mg)12.9 mg/L EPA 200.7 09/16/2015 10:13M4 FCJORDA0.005 1
Potassium (K)4.53 mg/L EPA 200.7 09/16/2015 10:13 FCJORDA0.1 1
Sodium (Na)17.0 mg/L EPA 200.7 09/16/2015 10:13M4 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 09/15/2015 12:49 MHH71310.005 1
Barium (Ba)0.140 mg/L EPA 200.7 09/15/2015 12:49 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:49 MHH71310.05 1
Iron (Fe)0.618 mg/L EPA 200.7 09/15/2015 12:49 MHH71310.01 1
Manganese (Mn)0.227 mg/L EPA 200.7 09/15/2015 12:49 MHH71310.005 1
Strontium (Sr)0.985 mg/L EPA 200.7 09/15/2015 12:49 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 12:49 MHH71310.005 1
Page 6 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030195
Collection Date:11-Sep-15 1:43 PM
Site:MW-07BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Molybdenum (Mo)3.17 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/16/2015 00:56 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Molybdenum (Mo)3.09 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/16/2015 16:46 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 7 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030196
Collection Date:11-Sep-15 10:23 AM
Site:MW-08BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.090 mg-N/L EPA 353.2 09/14/2015 14:24 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 120 mg/L EPA 300.0 09/14/2015 15:14 BGN90342.5 25
Sulfate 36 mg/L EPA 300.0 09/14/2015 15:14 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 11:39 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 13:41 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.005 mg/L EPA 200.7 09/15/2015 11:58 FCJORDA0.005 1
Barium (Ba)0.042 mg/L EPA 200.7 09/15/2015 11:58 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 11:58 FCJORDA0.05 1
Iron (Fe)1.36 mg/L EPA 200.7 09/15/2015 11:58 FCJORDA0.01 1
Manganese (Mn)1.35 mg/L EPA 200.7 09/15/2015 11:58 FCJORDA0.005 1
Strontium (Sr)0.382 mg/L EPA 200.7 09/15/2015 11:58 FCJORDA0.005 1
Zinc (Zn)0.041 mg/L EPA 200.7 09/15/2015 11:58 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.99 mg/L EPA 200.7 09/16/2015 10:17 FCJORDA0.01 1
Magnesium (Mg)2.27 mg/L EPA 200.7 09/16/2015 10:17 FCJORDA0.005 1
Potassium (K)0.590 mg/L EPA 200.7 09/16/2015 10:17 FCJORDA0.1 1
Sodium (Na)3.60 mg/L EPA 200.7 09/16/2015 10:17 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.092 mg/L EPA 200.7 09/15/2015 12:05 MHH71310.005 1
Barium (Ba)0.042 mg/L EPA 200.7 09/15/2015 12:05 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:05 MHH71310.05 1
Iron (Fe)1.53 mg/L EPA 200.7 09/15/2015 12:05 MHH71310.01 1
Manganese (Mn)1.39 mg/L EPA 200.7 09/15/2015 12:05 MHH71310.005 1
Strontium (Sr)0.393 mg/L EPA 200.7 09/15/2015 12:05 MHH71310.005 1
Zinc (Zn)0.036 mg/L EPA 200.7 09/15/2015 12:05 MHH71310.005 1
Page 8 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030196
Collection Date:11-Sep-15 10:23 AM
Site:MW-08BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Copper (Cu)6.01 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Molybdenum (Mo)3.97 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Nickel (Ni)10.4 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/16/2015 01:23 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Chromium (Cr)14.1 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Cobalt (Co)1.08 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Copper (Cu)2.00 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Lead (Pb)1.00 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Molybdenum (Mo)4.65 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Nickel (Ni)12.0 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA0.2 1
Vanadium (V) Low Level 0.512 ug/L EPA 200.8 09/16/2015 17:13 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 540 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 2.4 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 9 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030197
Collection Date:11-Sep-15 9:41 AM
Site:MW-09BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 09/14/2015 14:26 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 25 mg/L EPA 300.0 09/14/2015 15:31 BGN9034110
Sulfate 8.1 mg/L EPA 300.0 09/14/2015 15:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 11:42 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 13:49 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 09/15/2015 12:17 FCJORDA0.005 1
Barium (Ba)0.013 mg/L EPA 200.7 09/15/2015 12:17 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:17 FCJORDA0.05 1
Iron (Fe)0.367 mg/L EPA 200.7 09/15/2015 12:17 FCJORDA0.01 1
Manganese (Mn)0.677 mg/L EPA 200.7 09/15/2015 12:17 FCJORDA0.005 1
Strontium (Sr)0.079 mg/L EPA 200.7 09/15/2015 12:17 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 09/15/2015 12:17 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)18.3 mg/L EPA 200.7 09/16/2015 10:21 FCJORDA0.01 1
Magnesium (Mg)3.55 mg/L EPA 200.7 09/16/2015 10:21 FCJORDA0.005 1
Potassium (K)2.01 mg/L EPA 200.7 09/16/2015 10:21 FCJORDA0.1 1
Sodium (Na)17.1 mg/L EPA 200.7 09/16/2015 10:21 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.44 mg/L EPA 200.7 09/15/2015 12:53 MHH71310.005 1
Barium (Ba)0.016 mg/L EPA 200.7 09/15/2015 12:53 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:53 MHH71310.05 1
Iron (Fe)1.40 mg/L EPA 200.7 09/15/2015 12:53 MHH71310.01 1
Manganese (Mn)0.694 mg/L EPA 200.7 09/15/2015 12:53 MHH71310.005 1
Strontium (Sr)0.076 mg/L EPA 200.7 09/15/2015 12:53 MHH71310.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 09/15/2015 12:53 MHH71310.005 1
Page 10 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030197
Collection Date:11-Sep-15 9:41 AM
Site:MW-09BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Copper (Cu)5.57 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Nickel (Ni)1.36 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA0.2 1
Vanadium (V) Low Level 0.764 ug/L EPA 200.8 09/16/2015 01:29 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Copper (Cu)3.02 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Nickel (Ni)1.51 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA0.2 1
Vanadium (V) Low Level 1.94 ug/L EPA 200.8 09/16/2015 17:19 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 1.9 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 11 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030198
Collection Date:11-Sep-15 12:25 PM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 09/14/2015 14:27 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 19 mg/L EPA 300.0 09/14/2015 12:42 BGN9034110
Sulfate 81 mg/L EPA 300.0 09/14/2015 12:42 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 11:44 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 13:51 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/15/2015 12:20 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/15/2015 12:20 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:20 FCJORDA0.05 1
Iron (Fe)0.022 mg/L EPA 200.7 09/15/2015 12:20 FCJORDA0.01 1
Manganese (Mn)0.135 mg/L EPA 200.7 09/15/2015 12:20 FCJORDA0.005 1
Strontium (Sr)0.193 mg/L EPA 200.7 09/15/2015 12:20 FCJORDA0.005 1
Zinc (Zn)0.016 mg/L EPA 200.7 09/15/2015 12:20 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)29.1 mg/L EPA 200.7 09/16/2015 10:24 FCJORDA0.01 1
Magnesium (Mg)13.7 mg/L EPA 200.7 09/16/2015 10:24 FCJORDA0.005 1
Potassium (K)4.28 mg/L EPA 200.7 09/16/2015 10:24 FCJORDA0.1 1
Sodium (Na)39.7 mg/L EPA 200.7 09/16/2015 10:24 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.017 mg/L EPA 200.7 09/15/2015 12:13 MHH71310.005 1
Barium (Ba)0.005 mg/L EPA 200.7 09/15/2015 12:13 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:13 MHH71310.05 1
Iron (Fe)0.037 mg/L EPA 200.7 09/15/2015 12:13 MHH71310.01 1
Manganese (Mn)0.135 mg/L EPA 200.7 09/15/2015 12:13 MHH71310.005 1
Strontium (Sr)0.198 mg/L EPA 200.7 09/15/2015 12:13 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 12:13 MHH71310.005 1
Page 12 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030198
Collection Date:11-Sep-15 12:25 PM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Copper (Cu)9.78 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Nickel (Ni)2.13 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA0.2 1
Vanadium (V) Low Level 1.68 ug/L EPA 200.8 09/16/2015 01:36 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Molybdenum (Mo)1.00 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Nickel (Ni)1.83 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA0.2 1
Vanadium (V) Low Level 1.73 ug/L EPA 200.8 09/16/2015 17:26 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 2.1 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 13 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030199
Collection Date:11-Sep-15 4:22 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.165 mg-N/L EPA 353.2 09/14/2015 14:33 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 09/14/2015 12:59 BGN9034110
Sulfate 16 mg/L EPA 300.0 09/14/2015 12:59 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 11:46 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 13:53 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.056 mg/L EPA 200.7 09/15/2015 12:24 FCJORDA0.005 1
Barium (Ba)0.031 mg/L EPA 200.7 09/15/2015 12:24 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:24 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/15/2015 12:24 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/15/2015 12:24 FCJORDA0.005 1
Strontium (Sr)0.287 mg/L EPA 200.7 09/15/2015 12:24 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 12:24 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)30.6 mg/L EPA 200.7 09/16/2015 10:28 FCJORDA0.01 1
Magnesium (Mg)4.96 mg/L EPA 200.7 09/16/2015 10:28 FCJORDA0.005 1
Potassium (K)7.29 mg/L EPA 200.7 09/16/2015 10:28 FCJORDA0.1 1
Sodium (Na)15.6 mg/L EPA 200.7 09/16/2015 10:28 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.195 mg/L EPA 200.7 09/15/2015 12:17 MHH71310.005 1
Barium (Ba)0.032 mg/L EPA 200.7 09/15/2015 12:17 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:17 MHH71310.05 1
Iron (Fe)0.153 mg/L EPA 200.7 09/15/2015 12:17 MHH71310.01 1
Manganese (Mn)0.011 mg/L EPA 200.7 09/15/2015 12:17 MHH71310.005 1
Strontium (Sr)0.318 mg/L EPA 200.7 09/15/2015 12:17 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 12:17 MHH71310.005 1
Page 14 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030199
Collection Date:11-Sep-15 4:22 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.73 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Arsenic (As)1.09 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Chromium (Cr)14.5 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Copper (Cu)1.65 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Molybdenum (Mo)7.40 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Selenium (Se)1.07 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA0.2 1
Vanadium (V) Low Level 8.79 ug/L EPA 200.8 09/16/2015 01:42 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.74 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Arsenic (As)1.06 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Chromium (Cr)15.6 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Copper (Cu)1.44 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Molybdenum (Mo)7.76 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Selenium (Se)1.16 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA0.2 1
Vanadium (V) Low Level 9.15 ug/L EPA 200.8 09/16/2015 17:32 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 180 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 1.2 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 15 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030200
Collection Date:11-Sep-15 12:03 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.4 mg-N/L EPA 353.2 09/14/2015 14:38 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 22 mg/L EPA 300.0 09/14/2015 13:16 BGN90340.5 5
Sulfate 9.0 mg/L EPA 300.0 09/14/2015 13:16 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 11:49 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 13:56 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/15/2015 12:28 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/15/2015 12:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:28 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/15/2015 12:28 FCJORDA0.01 1
Manganese (Mn)0.005 mg/L EPA 200.7 09/15/2015 12:28 FCJORDA0.005 1
Strontium (Sr)0.076 mg/L EPA 200.7 09/15/2015 12:28 FCJORDA0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 09/15/2015 12:28 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.0 mg/L EPA 200.7 09/16/2015 10:32 FCJORDA0.01 1
Magnesium (Mg)4.33 mg/L EPA 200.7 09/16/2015 10:32 FCJORDA0.005 1
Potassium (K)1.09 mg/L EPA 200.7 09/16/2015 10:32 FCJORDA0.1 1
Sodium (Na)17.1 mg/L EPA 200.7 09/16/2015 10:32 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.107 mg/L EPA 200.7 09/15/2015 12:21 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/15/2015 12:21 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:21 MHH71310.05 1
Iron (Fe)0.093 mg/L EPA 200.7 09/15/2015 12:21 MHH71310.01 1
Manganese (Mn)0.010 mg/L EPA 200.7 09/15/2015 12:21 MHH71310.005 1
Strontium (Sr)0.071 mg/L EPA 200.7 09/15/2015 12:21 MHH71310.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 09/15/2015 12:21 MHH71310.005 1
Page 16 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030200
Collection Date:11-Sep-15 12:03 PM
Site:CW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Copper (Cu)2.01 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA0.2 1
Vanadium (V) Low Level 0.510 ug/L EPA 200.8 09/16/2015 01:49 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Copper (Cu)5.06 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA0.2 1
Vanadium (V) Low Level 0.687 ug/L EPA 200.8 09/16/2015 17:39 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 0.720 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 17 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030201
Collection Date:11-Sep-15 10:31 AM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.261 mg-N/L EPA 353.2 09/14/2015 14:39 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 8.3 mg/L EPA 300.0 09/14/2015 14:06 BGN90340.1 1
Sulfate 2.4 mg/L EPA 300.0 09/14/2015 14:06 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 12:26 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 13:58 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/15/2015 12:32 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/15/2015 12:32 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:32 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/15/2015 12:32 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/15/2015 12:32 FCJORDA0.005 1
Strontium (Sr)0.163 mg/L EPA 200.7 09/15/2015 12:32 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 12:32 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)42.9 mg/L EPA 200.7 09/16/2015 10:36 FCJORDA0.01 1
Magnesium (Mg)9.28 mg/L EPA 200.7 09/16/2015 10:36 FCJORDA0.005 1
Potassium (K)2.11 mg/L EPA 200.7 09/16/2015 10:36 FCJORDA0.1 1
Sodium (Na)12.7 mg/L EPA 200.7 09/16/2015 10:36 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.010 mg/L EPA 200.7 09/15/2015 12:25 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/15/2015 12:25 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:25 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/15/2015 12:25 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/15/2015 12:25 MHH71310.005 1
Strontium (Sr)0.166 mg/L EPA 200.7 09/15/2015 12:25 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 12:25 MHH71310.005 1
Page 18 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030201
Collection Date:11-Sep-15 10:31 AM
Site:CW-1D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Molybdenum (Mo)21.5 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA0.2 1
Vanadium (V) Low Level 1.24 ug/L EPA 200.8 09/16/2015 01:56 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Molybdenum (Mo)21.0 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA0.2 1
Vanadium (V) Low Level 1.25 ug/L EPA 200.8 09/16/2015 17:45 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 0.485 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 19 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030202
Collection Date:11-Sep-15 10:30 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.019 mg-N/L EPA 353.2 09/14/2015 14:40 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 32 mg/L EPA 300.0 09/14/2015 14:23 BGN90340.5 5
Sulfate 5.4 mg/L EPA 300.0 09/14/2015 14:23 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 12:33 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 14:00 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/16/2015 14:59 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/15/2015 12:36 FCJORDA0.005 1
Barium (Ba)0.050 mg/L EPA 200.7 09/15/2015 12:36 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:36 FCJORDA0.05 1
Iron (Fe)0.135 mg/L EPA 200.7 09/15/2015 12:36 FCJORDA0.01 1
Manganese (Mn)0.127 mg/L EPA 200.7 09/15/2015 12:36 FCJORDA0.005 1
Strontium (Sr)0.283 mg/L EPA 200.7 09/15/2015 12:36 FCJORDA0.005 1
Zinc (Zn)0.033 mg/L EPA 200.7 09/15/2015 12:36 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/15/2015 15:28 FCJORDA0.005 1
Barium (Ba)0.049 mg/L EPA 200.7 09/15/2015 15:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 15:28 FCJORDA0.05 1
Iron (Fe)0.132 mg/L EPA 200.7 09/15/2015 15:28 FCJORDA0.01 1
Manganese (Mn)0.125 mg/L EPA 200.7 09/15/2015 15:28 FCJORDA0.005 1
Strontium (Sr)0.279 mg/L EPA 200.7 09/15/2015 15:28 FCJORDA0.005 1
Zinc (Zn)0.022 mg/L EPA 200.7 09/15/2015 15:28 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)50.6 mg/L EPA 200.7 09/16/2015 10:40 FCJORDA0.01 1
Magnesium (Mg)10.6 mg/L EPA 200.7 09/16/2015 10:40 FCJORDA0.005 1
Potassium (K)3.56 mg/L EPA 200.7 09/16/2015 10:40 FCJORDA0.1 1
Sodium (Na)44.6 mg/L EPA 200.7 09/16/2015 10:40 FCJORDA0.05 1
Page 20 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030202
Collection Date:11-Sep-15 10:30 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.082 mg/L EPA 200.7 09/15/2015 12:29 MHH71310.005 1
Barium (Ba)0.050 mg/L EPA 200.7 09/15/2015 12:29 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:29 MHH71310.05 1
Iron (Fe)0.244 mg/L EPA 200.7 09/15/2015 12:29 MHH71310.01 1
Manganese (Mn)0.130 mg/L EPA 200.7 09/15/2015 12:29 MHH71310.005 1
Strontium (Sr)0.291 mg/L EPA 200.7 09/15/2015 12:29 MHH71310.005 1
Zinc (Zn)0.023 mg/L EPA 200.7 09/15/2015 12:29 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Copper (Cu)6.39 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Nickel (Ni)1.48 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA0.2 1
Vanadium (V) Low Level 3.61 ug/L EPA 200.8 09/16/2015 02:02 JAHERMA0.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Nickel (Ni)1.37 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 16:16 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 16:16 MHALL30.2 1
Vanadium (V) Low Level 3.22 ug/L EPA 200.8 09/15/2015 16:16 MHALL30.3 1
Page 21 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030202
Collection Date:11-Sep-15 10:30 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Chromium (Cr)4.05 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Nickel (Ni)2.87 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA0.2 1
Vanadium (V) Low Level 4.00 ug/L EPA 200.8 09/16/2015 17:52 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 330 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 1.4 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Page 22 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030203
Collection Date:11-Sep-15 3:20 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 14:03 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/15/2015 12:39 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/15/2015 12:39 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:39 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/15/2015 12:39 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/15/2015 12:39 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 09/15/2015 12:39 FCJORDA0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 09/15/2015 12:39 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Copper (Cu)4.41 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/16/2015 02:09 JAHERMA0.3 1
Page 23 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030204
Collection Date:11-Sep-15 3:20 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 09/14/2015 14:41 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 09/14/2015 15:48 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 09/14/2015 15:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/15/2015 12:35 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.032 mg/L EPA 200.7 09/16/2015 10:43 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 09/16/2015 10:43 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 09/16/2015 10:43 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 09/16/2015 10:43 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 09/15/2015 12:34 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/15/2015 12:34 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/15/2015 12:34 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/15/2015 12:34 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/15/2015 12:34 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 09/15/2015 12:34 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/15/2015 12:34 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/16/2015 17:59 JAHERMA0.3 1
Page 24 of 73
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090289
2015030204
Collection Date:11-Sep-15 3:20 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 09/14/2015 13:45 CJELLIO251
Total Carbon
TOC 0.508 mg/L SM5310C/EPA9060A 09/17/2015 15:16 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/14/2015 08:26 CJELLIO51
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
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SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QI14036Lot Number:
J15090289Project Number:
AB GW Assessment Water - MayoProject Name:
09/17/2015Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QI14036
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Mayo
Project Number: J15090289
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QI14036

Project Name: AB GW Assessment Water - Mayo
Project Number: J15090289
Sample Number Sample ID Matrix Date Sampled Date Received
001 09/11/2015 12262015030194Aqueous 09/14/2015
002 09/11/2015 13432015030195Aqueous 09/14/2015
003 09/11/2015 10232015030196Aqueous 09/14/2015
004 09/11/2015 09412015030197Aqueous 09/14/2015
005 09/11/2015 12252015030198Aqueous 09/14/2015
006 09/11/2015 16222015030199Aqueous 09/14/2015
007 09/11/2015 12032015030200Aqueous 09/14/2015
008 09/11/2015 10312015030201Aqueous 09/14/2015
009 09/11/2015 10302015030202Aqueous 09/14/2015
010 09/11/2015 15202015030204Aqueous 09/14/2015
(10 samples)
Page: 3 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QI14036

Project Name: AB GW Assessment Water - Mayo
Project Number: J15090289
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015030194 Aqueous Alkalinity SM 2320B-200 mg/L 5
001 2015030194 Aqueous Bicarbonate Alkalinity SM 2320B-200 mg/L 5
002 2015030195 Aqueous Alkalinity SM 2320B-220 mg/L 7
002 2015030195 Aqueous Bicarbonate Alkalinity SM 2320B-220 mg/L 7
002 2015030195 Aqueous Methane RSK - 175 25 ug/L 8
003 2015030196 Aqueous Alkalinity SM 2320B-190 mg/L 9
003 2015030196 Aqueous Bicarbonate Alkalinity SM 2320B-190 mg/L 9
003 2015030196 Aqueous Methane RSK - 175 13 ug/L 10
004 2015030197 Aqueous Alkalinity SM 2320B-55 mg/L 11
004 2015030197 Aqueous Bicarbonate Alkalinity SM 2320B-55 mg/L 11
004 2015030197 Aqueous Methane RSK - 175 10 ug/L 12
005 2015030198 Aqueous Alkalinity SM 2320B-110 mg/L 13
005 2015030198 Aqueous Bicarbonate Alkalinity SM 2320B-110 mg/L 13
006 2015030199 Aqueous Alkalinity SM 2320B-100 mg/L 15
006 2015030199 Aqueous Bicarbonate Alkalinity SM 2320B-88 mg/L 15
006 2015030199 Aqueous Carbonate Alkalinity SM 2320B-15 mg/L 15
007 2015030200 Aqueous Alkalinity SM 2320B-37 mg/L 17
007 2015030200 Aqueous Bicarbonate Alkalinity SM 2320B-37 mg/L 17
008 2015030201 Aqueous Alkalinity SM 2320B-170 mg/L 19
008 2015030201 Aqueous Bicarbonate Alkalinity SM 2320B-160 mg/L 19
009 2015030202 Aqueous Alkalinity SM 2320B-220 mg/L 21
009 2015030202 Aqueous Bicarbonate Alkalinity SM 2320B-220 mg/L 21
009 2015030202 Aqueous Methane RSK - 175 400 ug/L 22
(23 detections)
Page: 4 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030194
QI14036-001
09/11/2015 1226
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2214 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2214 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2214 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 200 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 200 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030194
QI14036-001
09/11/2015 1226
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1358 DCS 85044
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030195
QI14036-002
09/11/2015 1343
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2221 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2221 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2221 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 220 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 220 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030195
QI14036-002
09/11/2015 1343
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1408 DCS 85044
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 25 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030196
QI14036-003
09/11/2015 1023
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2228 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2228 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2228 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 190 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 190 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030196
QI14036-003
09/11/2015 1023
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1420 DCS 85044
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 13 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030197
QI14036-004
09/11/2015 0941
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2233 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2233 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2233 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 55 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 55 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 11 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030197
QI14036-004
09/11/2015 0941
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1641 DCS 85087
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 10 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 12 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030198
QI14036-005
09/11/2015 1225
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2239 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2239 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2239 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 110 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 110 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 13 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030198
QI14036-005
09/11/2015 1225
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1651 DCS 85087
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 14 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030199
QI14036-006
09/11/2015 1622
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2245 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2245 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2245 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 100 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 88 1mg/L10
Carbonate Alkalinity SM 2320B-20 15 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 15 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030199
QI14036-006
09/11/2015 1622
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1728 DCS 85087
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 16 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030200
QI14036-007
09/11/2015 1203
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2250 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2250 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2250 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 37 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 37 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 17 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030200
QI14036-007
09/11/2015 1203
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1739 DCS 85087
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 18 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030201
QI14036-008
09/11/2015 1031
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2256 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2256 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2256 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 170 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 160 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 19 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030201
QI14036-008
09/11/2015 1031
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 1749 DCS 85087
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 20 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030202
QI14036-009
09/11/2015 1030
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2315 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2315 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2315 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 220 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 220 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 21 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030202
QI14036-009
09/11/2015 1030
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 2150 JJG 85110
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 400 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 22 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030204
QI14036-010
09/11/2015 1520
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/15/2015 2320 BWS 84973
1 (Bicarbonate ) SM 2320B-2011 1 09/15/2015 2320 HMA
1 (Carbonate Al) SM 2320B-2011 1 09/15/2015 2320 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 23 of 24
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015030204
QI14036-010
09/11/2015 1520
09/14/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090289
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/16/2015 2200 JJG 85110
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 24 of 24
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Shealy Environmental Services, Inc.

QC Summary
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:QQ84973-001
84973
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 09/15/2015 215310mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:QQ84973-002
84973
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 100 09/15/2015 215910310090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ85044-001
85044
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 09/16/2015 092810ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ85044-002
85044
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 140 09/16/2015 09039215070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ85044-003
85044
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 140 09/16/2015 09189115070-1300.84 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ85087-001
85087
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 09/16/2015 152910ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ85087-002
85087
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 130 09/16/2015 15058815070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ85087-003
85087
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 130 09/16/2015 15188715070-1300.98 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ85110-001
85110
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 09/16/2015 212110ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ85110-002
85110
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 140 09/16/2015 20299115070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ85110-003
85110
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 140 09/16/2015 20449015070-1300.77 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI14036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Chain of Custody
and
Miscellaneous Documents
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

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