NC0038377_J15090168report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15090168
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:9/17/2015
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Brandon Russo, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 61
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015029708 MAYO STEAM 08-Sep-15 3:55 PM Erin Black MW-13BR
2015029709 MAYO STEAM 08-Sep-15 1:40 PM Erin Black MW-03BR
2015029710 MAYO STEAM 08-Sep-15 1:58 PM Erin Black CW-3
2015029711 MAYO STEAM 08-Sep-15 4:02 PM Erin Black MW-2
2015029712 MAYO STEAM 08-Sep-15 2:40 PM Erin Black CW-2
2015029713 MAYO STEAM 08-Sep-15 4:05 PM Erin Black CW-2D
2015029714 MAYO STEAM 08-Sep-15 5:36 PM Erin Black MW-3
2015029715 MAYO STEAM 08-Sep-15 3:30 PM Filter Blank
2015029716 MAYO STEAM 08-Sep-15 3:30 PM Equipment Blank
9 Total Samples
Page 2 of 61
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:9/17/2015
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029708
Collection Date:08-Sep-15 3:55 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 09/09/2015 11:19M2 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 43 mg/L EPA 300.0 09/09/2015 17:33 BGN9034110
Sulfate 12 mg/L EPA 300.0 09/09/2015 17:33 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/09/2015 16:17 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 12:43 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 09/10/2015 10:00 FCJORDA0.005 1
Barium (Ba)0.048 mg/L EPA 200.7 09/10/2015 10:00 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/10/2015 10:00 FCJORDA0.05 1
Iron (Fe)2.04 mg/L EPA 200.7 09/10/2015 10:00 FCJORDA0.01 1
Manganese (Mn)0.614 mg/L EPA 200.7 09/10/2015 10:00 FCJORDA0.005 1
Strontium (Sr)0.421 mg/L EPA 200.7 09/10/2015 10:00 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/10/2015 10:00 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)73.0 mg/L EPA 200.7 09/10/2015 10:48 FCJORDA0.01 1
Magnesium (Mg)12.9 mg/L EPA 200.7 09/10/2015 10:48 FCJORDA0.005 1
Potassium (K)5.31 mg/L EPA 200.7 09/10/2015 10:48 FCJORDA0.1 1
Sodium (Na)24.8 mg/L EPA 200.7 09/10/2015 10:48 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.143 mg/L EPA 200.7 09/11/2015 09:39B1 FCJORDA0.005 1
Barium (Ba)0.051 mg/L EPA 200.7 09/11/2015 09:39 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/11/2015 09:39 FCJORDA0.05 1
Iron (Fe)2.40 mg/L EPA 200.7 09/11/2015 09:39 FCJORDA0.01 1
Manganese (Mn)0.630 mg/L EPA 200.7 09/11/2015 09:39 FCJORDA0.005 1
Strontium (Sr)0.430 mg/L EPA 200.7 09/11/2015 09:39 FCJORDA0.005 1
Zinc (Zn)0.099 mg/L EPA 200.7 09/11/2015 09:39 FCJORDA0.005 1
Page 4 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029708
Collection Date:08-Sep-15 3:55 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Molybdenum (Mo)4.24 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA11
Thallium (Tl) Low Level 0.243 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/15/2015 11:42 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Molybdenum (Mo)5.17 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA11
Thallium (Tl) Low Level 0.538 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA0.2 1
Vanadium (V) Low Level 0.465 ug/L EPA 200.8 09/15/2015 13:34 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 360 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 0.859 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS 10 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Page 5 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029709
Collection Date:08-Sep-15 1:40 PM
Site:MW-03BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.028 mg-N/L EPA 353.2 09/09/2015 11:20 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 150 mg/L EPA 300.0 09/09/2015 20:05 BGN9034220
Sulfate 9.3 mg/L EPA 300.0 09/09/2015 20:05 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/09/2015 16:19 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 12:50 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/10/2015 10:11 FCJORDA0.005 1
Barium (Ba)0.043 mg/L EPA 200.7 09/10/2015 10:11 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/10/2015 10:11 FCJORDA0.05 1
Iron (Fe)0.400 mg/L EPA 200.7 09/10/2015 10:11 FCJORDA0.01 1
Manganese (Mn)0.618 mg/L EPA 200.7 09/10/2015 10:11 FCJORDA0.005 1
Strontium (Sr)0.410 mg/L EPA 200.7 09/10/2015 10:11 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 09/10/2015 10:11 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)142 mg/L EPA 200.7 09/10/2015 11:00 FCJORDA0.1 10
Magnesium (Mg)11.0 mg/L EPA 200.7 09/10/2015 11:00 FCJORDA0.005 1
Potassium (K)8.16 mg/L EPA 200.7 09/10/2015 11:00 FCJORDA0.1 1
Sodium (Na)21.8 mg/L EPA 200.7 09/10/2015 11:00 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.059 mg/L EPA 200.7 09/11/2015 09:51B1 FCJORDA0.005 1
Barium (Ba)0.048 mg/L EPA 200.7 09/11/2015 09:51 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/11/2015 09:51 FCJORDA0.05 1
Iron (Fe)0.729 mg/L EPA 200.7 09/11/2015 09:51 FCJORDA0.01 1
Manganese (Mn)0.694 mg/L EPA 200.7 09/11/2015 09:51 FCJORDA0.005 1
Strontium (Sr)0.414 mg/L EPA 200.7 09/11/2015 09:51 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/11/2015 09:51 FCJORDA0.005 1
Page 6 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029709
Collection Date:08-Sep-15 1:40 PM
Site:MW-03BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Copper (Cu)1.25 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Molybdenum (Mo)1.09 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/15/2015 11:48 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Molybdenum (Mo)1.37 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA0.2 1
Vanadium (V) Low Level 0.494 ug/L EPA 200.8 09/15/2015 13:14 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 780 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Page 7 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029710
Collection Date:08-Sep-15 1:58 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.312 mg-N/L EPA 353.2 09/09/2015 11:21 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 97 mg/L EPA 300.0 09/09/2015 20:22 BGN9034220
Sulfate 15 mg/L EPA 300.0 09/09/2015 20:22 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/09/2015 16:22 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 12:52 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/10/2015 10:15 FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 09/10/2015 10:15 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/10/2015 10:15 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 10:15 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/10/2015 10:15 FCJORDA0.005 1
Strontium (Sr)0.332 mg/L EPA 200.7 09/10/2015 10:15 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 09/10/2015 10:15 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)63.5 mg/L EPA 200.7 09/10/2015 11:04 FCJORDA0.01 1
Magnesium (Mg)8.11 mg/L EPA 200.7 09/10/2015 11:04 FCJORDA0.005 1
Potassium (K)4.48 mg/L EPA 200.7 09/10/2015 11:04 FCJORDA0.1 1
Sodium (Na)43.5 mg/L EPA 200.7 09/10/2015 11:04 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.016 mg/L EPA 200.7 09/11/2015 09:55B FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 09/11/2015 09:55 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/11/2015 09:55 FCJORDA0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 09/11/2015 09:55 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/11/2015 09:55 FCJORDA0.005 1
Strontium (Sr)0.338 mg/L EPA 200.7 09/11/2015 09:55 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/11/2015 09:55 FCJORDA0.005 1
Page 8 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029710
Collection Date:08-Sep-15 1:58 PM
Site:CW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Copper (Cu)5.88 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA0.2 1
Vanadium (V) Low Level 1.36 ug/L EPA 200.8 09/15/2015 11:55 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA0.2 1
Vanadium (V) Low Level 1.52 ug/L EPA 200.8 09/15/2015 13:40 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 430 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Page 9 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029711
Collection Date:08-Sep-15 4:02 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.087 mg-N/L EPA 353.2 09/09/2015 11:22 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 09/09/2015 18:57 BGN9034110
Sulfate 17 mg/L EPA 300.0 09/09/2015 18:57 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/09/2015 16:24 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 12:55 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 09/10/2015 10:19 FCJORDA0.005 1
Barium (Ba)0.064 mg/L EPA 200.7 09/10/2015 10:19 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/10/2015 10:19 FCJORDA0.05 1
Iron (Fe)0.763 mg/L EPA 200.7 09/10/2015 10:19 FCJORDA0.01 1
Manganese (Mn)1.32 mg/L EPA 200.7 09/10/2015 10:19 FCJORDA0.005 1
Strontium (Sr)0.190 mg/L EPA 200.7 09/10/2015 10:19 FCJORDA0.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 09/10/2015 10:19 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)18.9 mg/L EPA 200.7 09/10/2015 11:07 FCJORDA0.01 1
Magnesium (Mg)7.71 mg/L EPA 200.7 09/10/2015 11:07 FCJORDA0.005 1
Potassium (K)5.87 mg/L EPA 200.7 09/10/2015 11:07 FCJORDA0.1 1
Sodium (Na)25.7 mg/L EPA 200.7 09/10/2015 11:07 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.495 mg/L EPA 200.7 09/11/2015 09:58B1 FCJORDA0.005 1
Barium (Ba)0.079 mg/L EPA 200.7 09/11/2015 09:58 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/11/2015 09:58 FCJORDA0.05 1
Iron (Fe)1.19 mg/L EPA 200.7 09/11/2015 09:58 FCJORDA0.01 1
Manganese (Mn)1.73 mg/L EPA 200.7 09/11/2015 09:58 FCJORDA0.005 1
Strontium (Sr)0.210 mg/L EPA 200.7 09/11/2015 09:58 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/11/2015 09:58 FCJORDA0.005 1
Page 10 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029711
Collection Date:08-Sep-15 4:02 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Cobalt (Co)3.85 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Copper (Cu)6.51 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Nickel (Ni)3.25 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA0.2 1
Vanadium (V) Low Level 0.421 ug/L EPA 200.8 09/15/2015 11:22 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Cobalt (Co)4.86 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Nickel (Ni)3.63 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA0.2 1
Vanadium (V) Low Level 0.741 ug/L EPA 200.8 09/15/2015 13:47 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Page 11 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029712
Collection Date:08-Sep-15 2:40 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.040 mg-N/L EPA 353.2 09/09/2015 11:29 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 62 mg/L EPA 300.0 09/09/2015 19:14 BGN9034110
Sulfate 36 mg/L EPA 300.0 09/09/2015 19:14 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/09/2015 16:27 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 12:57 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 13:54 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 09/10/2015 10:23 FCJORDA0.005 1
Barium (Ba)0.124 mg/L EPA 200.7 09/10/2015 10:23 FCJORDA0.005 1
Boron (B)0.815 mg/L EPA 200.7 09/10/2015 10:23 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 10:23 FCJORDA0.01 1
Manganese (Mn)0.451 mg/L EPA 200.7 09/10/2015 10:23 FCJORDA0.005 1
Strontium (Sr)0.280 mg/L EPA 200.7 09/10/2015 10:23 FCJORDA0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 09/10/2015 10:23 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)0.012 mg/L EPA 200.7 09/10/2015 14:24 FCJORDA0.005 1
Barium (Ba)0.125 mg/L EPA 200.7 09/10/2015 14:24 FCJORDA0.005 1
Boron (B)0.805 mg/L EPA 200.7 09/10/2015 14:24 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 14:24 FCJORDA0.01 1
Manganese (Mn)0.442 mg/L EPA 200.7 09/10/2015 14:24 FCJORDA0.005 1
Strontium (Sr)0.280 mg/L EPA 200.7 09/10/2015 14:24 FCJORDA0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 09/10/2015 14:24 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)20.9 mg/L EPA 200.7 09/10/2015 11:11 FCJORDA0.01 1
Magnesium (Mg)8.90 mg/L EPA 200.7 09/10/2015 11:11 FCJORDA0.005 1
Potassium (K)2.11 mg/L EPA 200.7 09/10/2015 11:11 FCJORDA0.1 1
Sodium (Na)20.4 mg/L EPA 200.7 09/10/2015 11:11 FCJORDA0.05 1
Page 12 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029712
Collection Date:08-Sep-15 2:40 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.025 mg/L EPA 200.7 09/11/2015 10:02B FCJORDA0.005 1
Barium (Ba)0.130 mg/L EPA 200.7 09/11/2015 10:02 FCJORDA0.005 1
Boron (B)0.848 mg/L EPA 200.7 09/11/2015 10:02 FCJORDA0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 09/11/2015 10:02 FCJORDA0.01 1
Manganese (Mn)0.465 mg/L EPA 200.7 09/11/2015 10:02 FCJORDA0.005 1
Strontium (Sr)0.291 mg/L EPA 200.7 09/11/2015 10:02 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 09/11/2015 10:02 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Copper (Cu)6.70 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Nickel (Ni)2.60 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/15/2015 12:01 JAHERMA0.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Copper (Cu)1.27 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Nickel (Ni)2.28 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA0.2 1
Vanadium (V) Low Level 0.402 ug/L EPA 200.8 09/10/2015 19:42 JAHERMA0.3 1
Page 13 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029712
Collection Date:08-Sep-15 2:40 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Nickel (Ni)2.45 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA0.2 1
Vanadium (V) Low Level 0.358 ug/L EPA 200.8 09/15/2015 14:04 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 0.726 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Page 14 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029713
Collection Date:08-Sep-15 4:05 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.098 mg-N/L EPA 353.2 09/09/2015 11:32 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 41 mg/L EPA 300.0 09/09/2015 19:31 BGN9034110
Sulfate 49 mg/L EPA 300.0 09/09/2015 19:31 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 11:23 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 12:59 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 14:01 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/10/2015 10:26 FCJORDA0.005 1
Barium (Ba)0.035 mg/L EPA 200.7 09/10/2015 10:26 FCJORDA0.005 1
Boron (B)0.351 mg/L EPA 200.7 09/10/2015 10:26 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 10:26 FCJORDA0.01 1
Manganese (Mn)0.011 mg/L EPA 200.7 09/10/2015 10:26 FCJORDA0.005 1
Strontium (Sr)0.276 mg/L EPA 200.7 09/10/2015 10:26 FCJORDA0.005 1
Zinc (Zn)0.020 mg/L EPA 200.7 09/10/2015 10:26 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/10/2015 14:33 FCJORDA0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 09/10/2015 14:33 FCJORDA0.005 1
Boron (B)0.358 mg/L EPA 200.7 09/10/2015 14:33 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 14:33 FCJORDA0.01 1
Manganese (Mn)0.017 mg/L EPA 200.7 09/10/2015 14:33 FCJORDA0.005 1
Strontium (Sr)0.276 mg/L EPA 200.7 09/10/2015 14:33 FCJORDA0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 09/10/2015 14:33 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)38.6 mg/L EPA 200.7 09/10/2015 11:15 FCJORDA0.01 1
Magnesium (Mg)8.08 mg/L EPA 200.7 09/10/2015 11:15 FCJORDA0.005 1
Potassium (K)3.45 mg/L EPA 200.7 09/10/2015 11:15 FCJORDA0.1 1
Sodium (Na)18.3 mg/L EPA 200.7 09/10/2015 11:15 FCJORDA0.05 1
Page 15 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029713
Collection Date:08-Sep-15 4:05 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.517 mg/L EPA 200.7 09/11/2015 10:06B1 FCJORDA0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 09/11/2015 10:06 FCJORDA0.005 1
Boron (B)0.358 mg/L EPA 200.7 09/11/2015 10:06 FCJORDA0.05 1
Iron (Fe)0.267 mg/L EPA 200.7 09/11/2015 10:06 FCJORDA0.01 1
Manganese (Mn)0.079 mg/L EPA 200.7 09/11/2015 10:06 FCJORDA0.005 1
Strontium (Sr)0.286 mg/L EPA 200.7 09/11/2015 10:06 FCJORDA0.005 1
Zinc (Zn)0.039 mg/L EPA 200.7 09/11/2015 10:06 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Copper (Cu)7.19 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA0.2 1
Vanadium (V) Low Level 0.470 ug/L EPA 200.8 09/15/2015 12:08 JAHERMA0.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Copper (Cu)1.13 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA0.2 1
Vanadium (V) Low Level 0.664 ug/L EPA 200.8 09/10/2015 19:21 JAHERMA0.3 1
Page 16 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029713
Collection Date:08-Sep-15 4:05 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA0.2 1
Vanadium (V) Low Level 0.689 ug/L EPA 200.8 09/15/2015 14:11 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 270 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 0.640 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS 22 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Page 17 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029714
Collection Date:08-Sep-15 5:36 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.082 mg-N/L EPA 353.2 09/09/2015 11:09 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 45 mg/L EPA 300.0 09/09/2015 19:48 BGN9034110
Sulfate 21 mg/L EPA 300.0 09/09/2015 19:48 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 11:30 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 13:02 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 14:03 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 09/10/2015 10:30 FCJORDA0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 09/10/2015 10:30 FCJORDA0.005 1
Boron (B)1.04 mg/L EPA 200.7 09/10/2015 10:30 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 10:30 FCJORDA0.01 1
Manganese (Mn)1.07 mg/L EPA 200.7 09/10/2015 10:30 FCJORDA0.005 1
Strontium (Sr)0.329 mg/L EPA 200.7 09/10/2015 10:30 FCJORDA0.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 09/10/2015 10:30 FCJORDA0.005 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/10/2015 14:13 FCJORDA0.005 1
Barium (Ba)0.058 mg/L EPA 200.7 09/10/2015 14:13 FCJORDA0.005 1
Boron (B)1.04 mg/L EPA 200.7 09/10/2015 14:13 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 14:13 FCJORDA0.01 1
Manganese (Mn)1.01 mg/L EPA 200.7 09/10/2015 14:13 FCJORDA0.005 1
Strontium (Sr)0.333 mg/L EPA 200.7 09/10/2015 14:13 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 09/10/2015 14:13 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)26.5 mg/L EPA 200.7 09/10/2015 11:19 FCJORDA0.01 1
Magnesium (Mg)8.85 mg/L EPA 200.7 09/10/2015 11:19 FCJORDA0.005 1
Potassium (K)2.36 mg/L EPA 200.7 09/10/2015 11:19 FCJORDA0.1 1
Sodium (Na)23.7 mg/L EPA 200.7 09/10/2015 11:19 FCJORDA0.05 1
Page 18 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029714
Collection Date:08-Sep-15 5:36 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 09/11/2015 10:10B FCJORDA0.005 1
Barium (Ba)0.060 mg/L EPA 200.7 09/11/2015 10:10 FCJORDA0.005 1
Boron (B)1.05 mg/L EPA 200.7 09/11/2015 10:10 FCJORDA0.05 1
Iron (Fe)0.021 mg/L EPA 200.7 09/11/2015 10:10 FCJORDA0.01 1
Manganese (Mn)1.21 mg/L EPA 200.7 09/11/2015 10:10 FCJORDA0.005 1
Strontium (Sr)0.342 mg/L EPA 200.7 09/11/2015 10:10 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/11/2015 10:10 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Copper (Cu)5.76 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Nickel (Ni)2.81 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/15/2015 12:15 JAHERMA0.3 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Copper (Cu)1.02 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Nickel (Ni)2.81 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA0.2 1
Vanadium (V) Low Level 0.497 ug/L EPA 200.8 09/10/2015 19:49 JAHERMA0.3 1
Page 19 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029714
Collection Date:08-Sep-15 5:36 PM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Nickel (Ni)2.81 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA0.2 1
Vanadium (V) Low Level 0.384 ug/L EPA 200.8 09/15/2015 14:17 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 0.921 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Page 20 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029715
Collection Date:08-Sep-15 3:30 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 14:05 ACPAYNE0.05 1
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (Al)< 0.005 mg/L EPA 200.7 09/10/2015 14:17 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/10/2015 14:17 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/10/2015 14:17 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/10/2015 14:17 FCJORDA0.01 1
Manganese (Mn)0.008 mg/L EPA 200.7 09/10/2015 14:17 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 09/10/2015 14:17 FCJORDA0.005 1
Zinc (Zn)0.013 mg/L EPA 200.7 09/10/2015 14:17 FCJORDA0.005 1
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Copper (Cu)3.70 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/10/2015 19:56 JAHERMA0.3 1
Page 21 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029716
Collection Date:08-Sep-15 3:30 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 09/09/2015 11:13 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 09/09/2015 17:16 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 09/09/2015 17:16 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 09/11/2015 11:32 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.020 mg/L EPA 200.7 09/10/2015 11:23 FCJORDA0.01 1
Magnesium (Mg)0.008 mg/L EPA 200.7 09/10/2015 11:23 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 09/10/2015 11:23 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 09/10/2015 11:23 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.010 mg/L EPA 200.7 09/11/2015 10:14B FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 09/11/2015 10:14 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 09/11/2015 10:14 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 09/11/2015 10:14 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 09/11/2015 10:14 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 09/11/2015 10:14 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 09/11/2015 10:14 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 09/15/2015 14:24 JAHERMA0.3 1
Page 22 of 61
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15090168
2015029716
Collection Date:08-Sep-15 3:30 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 09/09/2015 14:23 CJELLIO251
Total Carbon
TOC 0.113 mg/L SM5310C/EPA9060A 09/10/2015 12:35 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 09/09/2015 10:54 GHUTCHI51
Qualifiers:
B Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in
sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be
due to contamination.
B1 Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in
sample was greater than 10X the concentration of the target analyte detected in the method blank. Analyte
concentration in sample is not affected by contamination.
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
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SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QI09075Lot Number:
J15090168Project Number:
AB GW Assessment Water - MayoProject Name:
09/14/2015Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 20
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QI09075
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Mayo
Project Number: J15090168
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 20
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QI09075

Project Name: AB GW Assessment Water - Mayo
Project Number: J15090168
Sample Number Sample ID Matrix Date Sampled Date Received
001 09/08/2015 15552015029708Aqueous 09/09/2015
002 09/08/2015 13402015029709Aqueous 09/09/2015
003 09/08/2015 13582015029710Aqueous 09/09/2015
004 09/08/2015 16022015029711Aqueous 09/09/2015
005 09/08/2015 14402015029712Aqueous 09/09/2015
006 09/08/2015 16052015029713Aqueous 09/09/2015
007 09/08/2015 17362015029714Aqueous 09/09/2015
008 09/08/2015 15302015029716Aqueous 09/09/2015
(8 samples)
Page: 3 of 20
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QI09075

Project Name: AB GW Assessment Water - Mayo
Project Number: J15090168
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015029708 Aqueous Alkalinity SM 2320B-230 mg/L 5
001 2015029708 Aqueous Bicarbonate Alkalinity SM 2320B-230 mg/L 5
002 2015029709 Aqueous Alkalinity SM 2320B-230 mg/L 7
002 2015029709 Aqueous Bicarbonate Alkalinity SM 2320B-230 mg/L 7
003 2015029710 Aqueous Alkalinity SM 2320B-140 mg/L 9
003 2015029710 Aqueous Bicarbonate Alkalinity SM 2320B-140 mg/L 9
004 2015029711 Aqueous Alkalinity SM 2320B-110 mg/L 11
004 2015029711 Aqueous Bicarbonate Alkalinity SM 2320B-110 mg/L 11
004 2015029711 Aqueous Methane RSK - 175 1700 ug/L 12
005 2015029712 Aqueous Alkalinity SM 2320B-11 mg/L 13
005 2015029712 Aqueous Bicarbonate Alkalinity SM 2320B-11 mg/L 13
006 2015029713 Aqueous Alkalinity SM 2320B-70 mg/L 15
006 2015029713 Aqueous Bicarbonate Alkalinity SM 2320B-70 mg/L 15
007 2015029714 Aqueous Alkalinity SM 2320B-76 mg/L 17
007 2015029714 Aqueous Bicarbonate Alkalinity SM 2320B-76 mg/L 17
(15 detections)
Page: 4 of 20
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029708
QI09075-001
09/08/2015 1555
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1524 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1524 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 230 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 230 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 20
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029708
QI09075-001
09/08/2015 1555
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/10/2015 1052 DCS 84578
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029709
QI09075-002
09/08/2015 1340
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1532 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1532 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 230 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 230 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 20
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029709
QI09075-002
09/08/2015 1340
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/10/2015 1107 DCS 84578
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029710
QI09075-003
09/08/2015 1358
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1539 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1539 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 140 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 140 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 20
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029710
QI09075-003
09/08/2015 1358
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/10/2015 1122 DCS 84578
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029711
QI09075-004
09/08/2015 1602
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1544 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1544 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 110 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 110 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 11 of 20
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029711
QI09075-004
09/08/2015 1602
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 5 09/11/2015 1411 DCS 84693
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 1700 2ug/L50
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 12 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029712
QI09075-005
09/08/2015 1440
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1549 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1549 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 11 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 11 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 13 of 20
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029712
QI09075-005
09/08/2015 1440
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/10/2015 1146 DCS 84578
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 14 of 20
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029713
QI09075-006
09/08/2015 1605
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1555 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1555 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 70 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 70 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 15 of 20
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029713
QI09075-006
09/08/2015 1605
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/10/2015 1204 DCS 84578
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 16 of 20
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029714
QI09075-007
09/08/2015 1736
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1601 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1601 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 76 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 76 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 17 of 20
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029714
QI09075-007
09/08/2015 1736
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/10/2015 1218 DCS 84578
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 18 of 20
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029716
QI09075-008
09/08/2015 1530
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 09/10/2015 1607 BWS 84565
1 (Bicarbonate ) SM 2320B-2011 1 09/10/2015 1607 BWS
1 (Carbonate Al) SM 2320B-2011 1 09/10/2015 0000 BWS
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 19 of 20
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015029716
QI09075-008
09/08/2015 1530
09/09/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15090168
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 09/10/2015 1315 DCS 84578
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 20 of 20
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Shealy Environmental Services, Inc.

QC Summary
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:QQ84565-001
84565
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 09/10/2015 134710mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:QQ84565-002
84565
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 100 09/10/2015 135310110090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ84578-001
84578
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 09/10/2015 102110ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ84578-002
84578
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 140 09/10/2015 09489215070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ84578-003
84578
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 130 09/10/2015 10028715070-1305.2 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ84693-001
84693
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 09/11/2015 133510ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ84693-002
84693
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 140 09/11/2015 13109415070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ84693-003
84693
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 140 09/11/2015 13229415070-1300.078 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QI09075
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Chain of Custody
and
Miscellaneous Documents
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Page 61 of 61