NC0038377_J15070341report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15070341
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:7/18/2015
Customer Address:
Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 17
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015022933 MAYO STEAM 07-Jul-15 10:05 AM illegible CW-2
2015022934 MAYO STEAM 07-Jul-15 9:47 AM illegible CW-2D
2 Total Samples
Analytical Lab
Page 2 of 17
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:7/18/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 17
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070341
2015022933
Collection Date: 07-Jul-15 10:05 AM
Site: CW-2
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
Analytical Lab
Page 4 of 17
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070341
2015022934
Collection Date: 07-Jul-15 9:47 AM
Site: CW-2D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
Analytical Lab
Page 5 of 17

July 17, 2015

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 376975
SDG: J15070341

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 10, 2015. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 11
Erin Trent for
Analytical Lab
Page 6 of 17
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J15070341 GEL Work Order: 376975
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
for
Page 2 of 11
Analytical Lab
Page 7 of 17
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 17, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1491995
1491995
1491968
1492045
1019
0846
1125
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/17/15
07/17/15
07/16/15
07/16/15
PRB
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
376975001
Water
07-JUL-15 10:05
10-JUL-15
2015022933 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.7 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.37
0.868
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/14/15 14919941710JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000257
0.00
0.00
1.00E-06
1.06
1.61
NominalResult
RLDL
Notes:
Page 3 of 11
Analytical Lab
Page 8 of 17
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 17, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1491995
1491995
1491968
1492045
1021
0847
1248
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/17/15
07/17/15
07/16/15
07/16/15
PRB
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
376975002
Water
07-JUL-15 09:47
10-JUL-15
2015022934 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"95.3 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.72
0.640
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/14/15 14919941710JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000354
0.00
0.00
1.00E-06
1.57
0.792
NominalResult
RLDL
Notes:
Page 4 of 11
Analytical Lab
Page 9 of 17
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1491995Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 17, 2015Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ
PRB
SKJ
PRB
SKJ
07/17/15 08:38
07/17/15 10:10
07/17/15 09:56
07/17/15 08:35
07/17/15 08:34
07/17/15 09:54
07/17/15 10:15
07/17/15 08:39
07/17/15 08:41
QC
ND
ND
ND
0.00144
0.0446
0.000509
0.000534
0.00555
ND
ND
ND
ND
0.0486
0.000486
0.000521
0.00542
ND
NOM Sample
ND
ND
ND
0.000504
0.000504
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
QC1203352380 376974001
QC1203352378
QC1203352379
QC1203352377
QC1203352381 376974001
QC1203352382 376974001
QC1203352383 376974001
N/A
N/A
N/A
96.0
N/A
REC%
89.8
102
97.1
111
96.8
97.2
94.7
108
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
376975Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^*
RPD%
Page 1 of 3
Page 5 of 11
Analytical Lab
Page 10 of 17
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1491995
1491968
1492045
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
PRB
AXM6
CXP3
07/17/15 08:41
07/17/15 10:16
07/16/15 11:27
07/16/15 11:25
07/16/15 11:27
07/16/15 08:00
07/16/15 08:00
07/16/15 08:00
07/16/15 08:00
QC
ND
ND
0.117
-0.336
33.5
0.638
1.27
23.6
0.489
129
NOM Sample
ND
ND
0.504
1.41
0.719
0.719
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
J
U
U
QC1203352289 376974002
QC1203352290
QC1203352288
QC1203352518 376974001
QC1203352520
QC1203352517
QC1203352519 376974001
The Qualifiers in this report are defined as follows:
N/A
N/A
16.1
325
55.1
REC%
110
95.5
103
30.5
24.7
124
DUP
LCS
MB
DUP
LCS
MB
MS
376975Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
*
RPD%
Notes:
Page 2 of 3
Page 6 of 11
Analytical Lab
Page 11 of 17
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
376975Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Analytical Lab
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Page 8 of 11
Analytical Lab
Page 13 of 17
Page 9 of 11
Analytical Lab
Page 14 of 17
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
Oklahoma
Pennsylvania NELAP
Plant Material Permit
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-110
88-0651
42D0904046
2940 Interim
SC00012
PH-0169
SC000122013-10
2567.01
E87156
P330-12-00283, P330-12-00284
SC00012
967
SC000122013-10
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA150001
270
M-SC012
9976
SC000122013-10
NE-OS-26-13
SC000122014-1
2054
SC002
SC00012
11501
233
45709
9904
68-00485
PDEP-12-00260
10120002
10120001
TN 02934
T104704235-15-10
SC000122015-17
VT87156
460202
C780
997404
List of current GEL Certifications as of 17 July 2015
Page 10 of 11
Analytical Lab
Page 15 of 17
1430817DER Report No.:
1Revision No.:
Samantha Jacobs
Originator’s Name:
17-JUL-15 Paul Boyd
Data Validator/Group Leader:
17-JUL-15
Instrument Type:Client Code:
Quality Criteria:
ICP/MS
Specifications
DUKE
Type:
Process
Division:
Industrial
Mo.Day Yr.
17-JUL-15
GEL Laboratories LLC
Form GEL-DER
DATA EXCEPTION REPORT
DER Disposition:
1. Not all the applicable analyte RPD values were within the acceptance
criteria.
1203352380 (2015022931DUP) Uranium-238 [96.0* (0.0%-20.0%)].
Specification and Requirements
Exception Description:
1. Failed RPD for DUP:
QC 1203352380DUP
Application Issues:
Failed RPD for DUP
Batch ID:
1491995
Test / Method:
SW846 3010A/6020A Liquid
Matrix Type:
See Below
Sample Numbers:
Potentially affected work order(s)(SDG):376974(J15070340),376975(J15070341),376977(J15070278)
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Analytical Lab
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Analytical Lab
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