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Home My WebLink AboutNC0038377_J15060885report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060885 Project Name:MAYO STEAM - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:7/7/2015 Customer Address: Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 36 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015021167 MAYO STEAM 25-Jun-15 12:00 PM Erin Black MW-11BR 2015021168 MAYO STEAM 25-Jun-15 3:45 PM Erin Black ABMW-1 2015021169 MAYO STEAM 25-Jun-15 10:40 AM Erin Black Filter Blank 2015021170 MAYO STEAM 25-Jun-15 10:40 AM Erin Black Equipment Blank 4 Total Samples Analytical Lab Page 2 of 36 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:7/7/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060885 2015021167 Collection Date: 25-Jun-15 12:00 PM Site: MW-11BR Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 14:08 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 16 mg/L EPA 300.0 06/26/2015 16:42 BGN9034110 Sulfate 14 mg/L EPA 300.0 06/26/2015 16:42 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:59 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:35 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.016 mg/L EPA 200.7 07/01/2015 09:52 MHH71310.005 1 Barium (Ba)0.046 mg/L EPA 200.7 07/01/2015 09:52 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 07/01/2015 09:52 MHH71310.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 07/01/2015 09:52 MHH71310.01 1 Manganese (Mn)0.073 mg/L EPA 200.7 07/01/2015 09:52 MHH71310.005 1 Strontium (Sr)0.225 mg/L EPA 200.7 07/01/2015 09:52 MHH71310.005 1 Zinc (Zn)0.012 mg/L EPA 200.7 07/01/2015 09:52 MHH71310.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)49.6 mg/L EPA 200.7 07/01/2015 09:26 MHH71310.01 1 Magnesium (Mg)11.1 mg/L EPA 200.7 07/01/2015 09:26 MHH71310.005 1 Potassium (K)5.03 mg/L EPA 200.7 07/01/2015 09:26 MHH71310.1 1 Sodium (Na)14.3 mg/L EPA 200.7 07/01/2015 09:26 MHH71310.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.080 mg/L EPA 200.7 07/02/2015 10:00 MHH71310.005 1 Barium (Ba)0.044 mg/L EPA 200.7 07/02/2015 10:00 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 07/02/2015 10:00 MHH71310.05 1 Iron (Fe)0.115 mg/L EPA 200.7 07/02/2015 10:00 MHH71310.01 1 Manganese (Mn)0.067 mg/L EPA 200.7 07/02/2015 10:00 MHH71310.005 1 Strontium (Sr)0.200 mg/L EPA 200.7 07/02/2015 10:00 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 07/02/2015 10:00 MHH71310.005 1 Analytical Lab Page 4 of 36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060885 2015021167 Collection Date: 25-Jun-15 12:00 PM Site: MW-11BR Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)1.61 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Chromium (Cr)1.59 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Copper (Cu)7.72 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Molybdenum (Mo)5.04 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA0.2 1 Vanadium (V) Low Level 2.39 ug/L EPA 200.8 07/01/2015 14:49 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)1.32 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Chromium (Cr)1.73 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Molybdenum (Mo)5.41 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA11 Thallium (Tl) Low Level 0.323 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA0.2 1 Vanadium (V) Low Level 2.69 ug/L EPA 200.8 07/02/2015 12:38 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 250 mg/L SM2540C 06/29/2015 14:38 AGIBBS5251 Total Carbon TOC 1.1 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/29/2015 07:23 AGIBBS551 Analytical Lab Page 5 of 36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060885 2015021168 Collection Date: 25-Jun-15 3:45 PM Site: ABMW-1 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 14:04M2 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 16 mg/L EPA 300.0 06/26/2015 18:37 BGN9034110 Sulfate 5.8 mg/L EPA 300.0 06/26/2015 18:37 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 11:01 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:37 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.146 mg/L EPA 200.7 07/01/2015 09:57 MHH71310.005 1 Barium (Ba)0.850 mg/L EPA 200.7 07/01/2015 09:57 MHH71310.005 1 Boron (B)4.53 mg/L EPA 200.7 07/01/2015 09:57 MHH71310.05 1 Iron (Fe)0.483 mg/L EPA 200.7 07/01/2015 09:57 MHH71310.01 1 Manganese (Mn)2.12 mg/L EPA 200.7 07/01/2015 09:57 MHH71310.005 1 Strontium (Sr)3.36 mg/L EPA 200.7 07/01/2015 09:57 MHH71310.005 1 Zinc (Zn)0.014 mg/L EPA 200.7 07/01/2015 09:57 MHH71310.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)100 mg/L EPA 200.7 07/01/2015 09:39 MHH71310.1 10 Magnesium (Mg)51.9 mg/L EPA 200.7 07/01/2015 09:39 MHH71310.005 1 Potassium (K)24.6 mg/L EPA 200.7 07/01/2015 09:39 MHH7131110 Sodium (Na)18.7 mg/L EPA 200.7 07/01/2015 09:39 MHH71310.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.179 mg/L EPA 200.7 07/02/2015 10:04 MHH71310.005 1 Barium (Ba)0.925 mg/L EPA 200.7 07/02/2015 10:04 MHH71310.005 1 Boron (B)4.56 mg/L EPA 200.7 07/02/2015 10:04 MHH71310.05 1 Iron (Fe)1.37 mg/L EPA 200.7 07/02/2015 10:04 MHH71310.01 1 Manganese (Mn)2.28 mg/L EPA 200.7 07/02/2015 10:04 MHH71310.005 1 Strontium (Sr)3.49 mg/L EPA 200.7 07/02/2015 10:04 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 07/02/2015 10:04 MHH71310.005 1 Analytical Lab Page 6 of 36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060885 2015021168 Collection Date: 25-Jun-15 3:45 PM Site: ABMW-1 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)43.0 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Arsenic (As)369 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Cobalt (Co)5.55 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Copper (Cu)10.6 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Molybdenum (Mo)205 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Nickel (Ni)4.77 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA11 Thallium (Tl) Low Level 2.13 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA0.2 1 Vanadium (V) Low Level 290 ug/L EPA 200.8 07/01/2015 14:57 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)38.0 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Arsenic (As)518 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA55 Beryllium (Be)< 1 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Cobalt (Co)6.09 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Molybdenum (Mo)213 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Nickel (Ni)5.45 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA11 Thallium (Tl) Low Level 2.47 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA0.2 1 Vanadium (V) Low Level 314 ug/L EPA 200.8 07/02/2015 12:45 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 540 mg/L SM2540C 06/29/2015 14:38 AGIBBS5251 Total Carbon TOC 2.8 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L SM2540D 06/29/2015 07:23 AGIBBS551 Analytical Lab Page 7 of 36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060885 2015021169 Collection Date: 25-Jun-15 10:40 AM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:39 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 07/01/2015 10:06 MHH71310.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 07/01/2015 10:06 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 07/01/2015 10:06 MHH71310.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 07/01/2015 10:06 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 07/01/2015 10:06 MHH71310.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 07/01/2015 10:06 MHH71310.005 1 Zinc (Zn)0.027 mg/L EPA 200.7 07/01/2015 10:06 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/01/2015 15:04 JAHERMA0.3 1 Analytical Lab Page 8 of 36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060885 2015021170 Collection Date: 25-Jun-15 10:40 AM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.012 mg-N/L EPA 353.2 06/26/2015 14:09 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 06/26/2015 15:53 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 06/26/2015 15:53 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 11:04 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.030 mg/L EPA 200.7 07/01/2015 09:48 MHH71310.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 07/01/2015 09:48 MHH71310.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 07/01/2015 09:48 MHH71310.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 07/01/2015 09:48 MHH71310.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.007 mg/L EPA 200.7 07/02/2015 10:07 MHH71310.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 07/02/2015 10:07 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 07/02/2015 10:07 MHH71310.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 07/02/2015 10:07 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 07/02/2015 10:07 MHH71310.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 07/02/2015 10:07 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 07/02/2015 10:07 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/02/2015 12:52 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 9 of 36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060885 2015021170 Collection Date: 25-Jun-15 10:40 AM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/29/2015 14:38 AGIBBS5251 Total Carbon TOC 0.268 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/29/2015 07:23 AGIBBS551 Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. Analytical Lab Page 10 of 36 Analytical Lab Page 11 of 36 Analytical Lab Page 12 of 36 Analytical Lab Page 13 of 36 Analytical Lab Page 14 of 36 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QF30012Lot Number: J15060885Project Number: AB GW Assessment Water - MayoProject Name: 07/02/2015Date Completed: Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QF30012 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Mayo Project Number: J15060885 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF30012 Project Name: AB GW Assessment Water - Mayo Project Number: J15060885 Sample Number Sample ID Matrix Date Sampled Date Received 001 06/25/2015 12002015021167Aqueous 06/30/2015 002 06/25/2015 15452015021168Aqueous 06/30/2015 003 06/25/2015 10402015021170Aqueous 06/30/2015 (3 samples) Page: 3 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF30012 Project Name: AB GW Assessment Water - Mayo Project Number: J15060885 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015021167 Aqueous Alkalinity SM 2320B-160 mg/L 5 001 2015021167 Aqueous Bicarbonate Alkalinity SM 2320B-160 mg/L 5 002 2015021168 Aqueous Alkalinity SM 2320B-450 mg/L 7 002 2015021168 Aqueous Bicarbonate Alkalinity SM 2320B-450 mg/L 7 (4 detections) Page: 4 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015021167 QF30012-001 06/25/2015 1200 06/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060885 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2256 HMA 78533 1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2256 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2256 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 160 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 160 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015021167 QF30012-001 06/25/2015 1200 06/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060885 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 07/01/2015 1737 JJG 78641 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015021168 QF30012-002 06/25/2015 1545 06/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060885 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2305 HMA 78533 1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2305 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2305 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 450 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 450 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015021168 QF30012-002 06/25/2015 1545 06/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060885 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/30/2015 1657 DCS 78512 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015021170 QF30012-003 06/25/2015 1040 06/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060885 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2309 HMA 78533 1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2316 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2309 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015021170 QF30012-003 06/25/2015 1040 06/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060885 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/30/2015 1716 DCS 78512 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. QC Summary Page: 11 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:QQ78533-001 78533 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/30/2015 220510mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 12 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:QQ78533-002 78533 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 99 06/30/2015 22119910090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 13 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - MB Batch: Sample ID:QQ78512-001 78512 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/30/2015 125510ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 14 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCS Batch: Sample ID:QQ78512-002 78512 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 120 06/30/2015 12338215070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 15 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCSD Batch: Sample ID:QQ78512-003 78512 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 120 06/30/2015 12448015070-1302.7 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 16 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - MB Batch: Sample ID:QQ78641-001 78641 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 07/01/2015 172710ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 17 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCS Batch: Sample ID:QQ78641-002 78641 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 110 07/01/2015 16497615070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 18 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCSD Batch: Sample ID:QQ78641-003 78641 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 110 07/01/2015 17117415070-1302.0 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 19 of 19 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Analytical Lab Page 36 of 36