NC0038377_J15060849report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15060849
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:7/8/2015
Customer Address:
Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 41
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015021048 MAYO STEAM 24-Jun-15 2:20 PM illegible MW-12S
2015021049 MAYO STEAM 24-Jun-15 11:50 AM illegible MW-12D
2015021050 MAYO STEAM 24-Jun-15 9:45 AM illegible Filter Blank
2015021051 MAYO STEAM 24-Jun-15 9:45 AM illegible Equipment Blank
4 Total Samples
Analytical Lab
Page 2 of 41
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:7/8/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060849
2015021048
Collection Date: 24-Jun-15 2:20 PM
Site: MW-12S
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
Analytical Lab
Page 4 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060849
2015021049
Collection Date: 24-Jun-15 11:50 AM
Site: MW-12D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.080 mg-N/L EPA 353.2 06/26/2015 11:41 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 4.0 mg/L EPA 300.0 06/26/2015 17:48 BGN90340.1 1
Sulfate 0.96 mg/L EPA 300.0 06/26/2015 17:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:54 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:25 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/26/2015 10:38 FCJORDA0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 06/26/2015 10:38 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 10:38 FCJORDA0.05 1
Iron (Fe)0.095 mg/L EPA 200.7 06/26/2015 10:38 FCJORDA0.01 1
Manganese (Mn)0.674 mg/L EPA 200.7 06/26/2015 10:38 FCJORDA0.005 1
Strontium (Sr)0.094 mg/L EPA 200.7 06/26/2015 10:38 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 06/26/2015 10:38 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)12.6 mg/L EPA 200.7 06/26/2015 12:32 FCJORDA0.01 1
Magnesium (Mg)3.44 mg/L EPA 200.7 06/26/2015 12:32 FCJORDA0.005 1
Potassium (K)1.60 mg/L EPA 200.7 06/26/2015 12:32 FCJORDA0.1 1
Sodium (Na)8.98 mg/L EPA 200.7 06/26/2015 12:32 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.184 mg/L EPA 200.7 06/29/2015 10:11 MHH71310.005 1
Barium (Ba)0.026 mg/L EPA 200.7 06/29/2015 10:11 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/29/2015 10:11 MHH71310.05 1
Iron (Fe)0.326 mg/L EPA 200.7 06/29/2015 10:11 MHH71310.01 1
Manganese (Mn)0.683 mg/L EPA 200.7 06/29/2015 10:11 MHH71310.005 1
Strontium (Sr)0.095 mg/L EPA 200.7 06/29/2015 10:11 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/29/2015 10:11 MHH71310.005 1
Analytical Lab
Page 5 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060849
2015021049
Collection Date: 24-Jun-15 11:50 AM
Site: MW-12D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.66 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Cobalt (Co)1.28 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Molybdenum (Mo)1.63 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Nickel (Ni)1.82 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA0.2 1
Vanadium (V) Low Level 0.642 ug/L EPA 200.8 07/01/2015 13:37 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.63 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Cobalt (Co)1.37 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Molybdenum (Mo)1.75 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Nickel (Ni)2.50 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 15:21 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 15:21 SLS25600.2 1
Vanadium (V) Low Level 0.719 ug/L EPA 200.8 06/27/2015 15:21 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 0.396 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/26/2015 07:22 AGIBBS551
Analytical Lab
Page 6 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060849
2015021050
Collection Date: 24-Jun-15 9:45 AM
Site: Filter Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:32 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/26/2015 10:49 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/26/2015 10:49 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 10:49 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/26/2015 10:49 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/26/2015 10:49 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/26/2015 10:49 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/26/2015 10:49 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.08 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/01/2015 14:42 JAHERMA0.3 1
Analytical Lab
Page 7 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060849
2015021051
Collection Date: 24-Jun-15 9:45 AM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 11:42 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 06/26/2015 15:37 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 06/26/2015 15:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:56 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.051 mg/L EPA 200.7 06/26/2015 12:43 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/26/2015 12:43 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 06/26/2015 12:43 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 06/26/2015 12:43 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.010 mg/L EPA 200.7 06/29/2015 10:15 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/29/2015 10:15 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/29/2015 10:15 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/29/2015 10:15 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/29/2015 10:15 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/29/2015 10:15 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/29/2015 10:15 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 15:28 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 15:28 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/27/2015 15:28 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
Analytical Lab
Page 8 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060849
2015021051
Collection Date: 24-Jun-15 9:45 AM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 0.199 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/26/2015 07:22 AGIBBS551
Analytical Lab
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Analytical Lab
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Analytical Lab
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July 07, 2015

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 375817
SDG: J15060849

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on June 26, 2015. This revised data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures. Rev01: This data package is revised to report the correct sample
number.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 10
Analytical Lab
Page 15 of 41
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J15060849 GEL Work Order: 375817
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
for
Page 2 of 10
Analytical Lab
Page 16 of 41
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 7, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1488950
1488950
1489005
1488987
1556
1921
1104
0930
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/01/15
07/01/15
07/02/15
07/02/15
SKJ
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
375817001
Water
24-JUN-15 14:20
26-JUN-15
2015021048 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"85.3 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.53
0.647
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/29/15 14889490800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000602
0.00
0.00
1.00E-06
0.583
0.840
NominalResult
RLDL
Notes:
Page 3 of 10
Analytical Lab
Page 17 of 41
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1488950Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 7, 2015Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/01/15 19:22
07/01/15 15:58
07/01/15 15:55
07/01/15 19:20
07/01/15 19:18
07/01/15 15:54
07/01/15 15:59
07/01/15 19:24
07/01/15 19:25
QC
ND
ND
ND
0.0000701
0.0546
0.000532
0.000568
0.00599
ND
ND
ND
ND
0.056
0.000544
0.000568
0.00596
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
J
U
U
U
U
U
QC1203345331 375817001
QC1203345330
QC1203345334
QC1203345329
QC1203345332 375817001
QC1203345335 375817001
QC1203345333 375817001
N/A
N/A
N/A
200
N/A
REC%
110
106
103
120
113
109
103
119
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
375817Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
Page 1 of 3
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Analytical Lab
Page 18 of 41
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1488950
1489005
1488987
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
CXP3
07/01/15 19:25
07/01/15 16:00
07/02/15 11:04
07/02/15 11:05
07/02/15 11:04
07/02/15 10:05
07/02/15 10:05
07/02/15 10:05
07/02/15 10:05
QC
ND
ND
ND
-0.0978
23.9
0.0154
0.793
26.1
0.456
142
NOM Sample
ND
ND
ND
0.583
0.840
0.840
Range
(0%-10%)
(0%-10%)
N/A
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203345449 375817001
QC1203345450
QC1203345448
QC1203345397 375817001
QC1203345399
QC1203345396
QC1203345398 375817001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
N/A
5.78
REC%
78
106
114
30.6
24.7
124
DUP
LCS
MB
DUP
LCS
MB
MS
375817Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
U
RPD%
Notes:
Page 2 of 3
Page 5 of 10
Analytical Lab
Page 19 of 41
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
375817Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 6 of 10
Analytical Lab
Page 20 of 41
Page 7 of 10
Analytical Lab
Page 21 of 41
Page 8 of 10
Analytical Lab
Page 22 of 41
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
Oklahoma
Pennsylvania NELAP
Plant Material Permit
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-110
88-0651
42D0904046
2940 Interim
SC00012
PH-0169
SC000122013-10
2567.01
E87156
P330-12-00283, P330-12-00284
SC00012
967
SC000122013-10
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA150001
270
M-SC012
9976
SC000122013-10
NE-OS-26-13
SC000122014-1
2054
SC002
SC00012
11501
233
45709
9904
68-00485
PDEP-12-00260
10120002
10120001
TN 02934
T104704235-15-10
SC000122015-17
VT87156
460202
C780
997404
List of current GEL Certifications as of 07 July 2015
Page 9 of 10
Analytical Lab
Page 23 of 41
There are no "Data Exception Reports" associated with this analytical report.
Page 10 of 10
Analytical Lab
Page 24 of 41
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QF26038Lot Number:
J15060849Project Number:
AB GW Assessment Water - MayoProject Name:
07/01/2015Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QF26038
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Mayo
Project Number: J15060849
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF26038

Project Name: AB GW Assessment Water - Mayo
Project Number: J15060849
Sample Number Sample ID Matrix Date Sampled Date Received
001 06/24/2015 14202015021048Aqueous
002 06/24/2015 11502015021049Aqueous 06/26/2015
003 06/24/2015 09452015021051Aqueous 06/26/2015
(3 samples)
Page: 3 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF26038

Project Name: AB GW Assessment Water - Mayo
Project Number: J15060849
Sample Sample ID Matrix Parameter Method Result Q Units Page
002 2015021049 Aqueous Alkalinity SM 2320B-53 mg/L 5
002 2015021049 Aqueous Bicarbonate Alkalinity SM 2320B-53 mg/L 5
(2 detections)
Page: 4 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015021049
QF26038-002
06/24/2015 1150
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060849
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2026 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2026 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2026 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 53 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 53 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015021049
QF26038-002
06/24/2015 1150
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060849
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/29/2015 1414 DCS 78365
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015021051
QF26038-003
06/24/2015 0945
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060849
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2031 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2031 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2031 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015021051
QF26038-003
06/24/2015 0945
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060849
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/29/2015 1424 DCS 78365
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

QC Summary
QC Data for Lot Number: QF26038
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:QQ78532-001
78532
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 06/30/2015 182910mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26038
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:QQ78532-002
78532
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 97 06/30/2015 18349710090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26038
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ78365-001
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/29/2015 101510ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26038
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ78365-002
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 130 06/29/2015 09498315070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26038
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ78365-003
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 110 06/29/2015 10027515070-13010 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26038
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Analytical Lab
Page 41 of 41