NC0038377_J15060802report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15060802
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:7/3/2015
Customer Address:
Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 69
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015020818 MAYO STEAM 23-Jun-15 2:15 PM Erin Black MW-16S
2015020821 MAYO STEAM 23-Jun-15 12:30 PM Erin Black MW-16D
2015020822 MAYO STEAM 23-Jun-15 9:57 AM Erin Black MW-16BR
2015020823 MAYO STEAM 23-Jun-15 9:20 AM Erin Black ABMW-4BR
2015020824 MAYO STEAM 23-Jun-15 2:20 PM Erin Black MW-13BR
2015020837 MAYO STEAM 23-Jun-15 12:30 PM Erin Black MW-16D-Dup
2015020838 MAYO STEAM 23-Jun-15 9:24 AM Erin Black MW-3
2015020839 MAYO STEAM 23-Jun-15 4:30 PM Erin Black Filter Blank
2015020840 MAYO STEAM 23-Jun-15 4:30 PM Erin Black Equipment Blank
9 Total Samples
Analytical Lab
Page 2 of 69
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:7/3/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020818
Collection Date: 23-Jun-15 2:15 PM
Site: MW-16S
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.144 mg-N/L EPA 353.2 06/26/2015 11:28 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 06/25/2015 15:57 BGN9034110
Sulfate 5.3 mg/L EPA 300.0 06/25/2015 15:57 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:21 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 11:59 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/26/2015 10:03 FCJORDA0.005 1
Barium (Ba)0.046 mg/L EPA 200.7 06/26/2015 10:03 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 10:03 FCJORDA0.05 1
Iron (Fe)0.470 mg/L EPA 200.7 06/26/2015 10:03 FCJORDA0.01 1
Manganese (Mn)0.276 mg/L EPA 200.7 06/26/2015 10:03 FCJORDA0.005 1
Strontium (Sr)0.111 mg/L EPA 200.7 06/26/2015 10:03 FCJORDA0.005 1
Zinc (Zn)0.065 mg/L EPA 200.7 06/26/2015 10:03 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.57 mg/L EPA 200.7 06/26/2015 11:54 FCJORDA0.01 1
Magnesium (Mg)4.01 mg/L EPA 200.7 06/26/2015 11:54 FCJORDA0.005 1
Potassium (K)2.06 mg/L EPA 200.7 06/26/2015 11:54 FCJORDA0.1 1
Sodium (Na)11.2 mg/L EPA 200.7 06/26/2015 11:54 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.017 mg/L EPA 200.7 06/26/2015 13:53 FCJORDA0.005 1
Barium (Ba)0.046 mg/L EPA 200.7 06/26/2015 13:53 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 13:53 FCJORDA0.05 1
Iron (Fe)0.860 mg/L EPA 200.7 06/26/2015 13:53 FCJORDA0.01 1
Manganese (Mn)0.260 mg/L EPA 200.7 06/26/2015 13:53 FCJORDA0.005 1
Strontium (Sr)0.109 mg/L EPA 200.7 06/26/2015 13:53 FCJORDA0.005 1
Zinc (Zn)0.039 mg/L EPA 200.7 06/26/2015 13:53 FCJORDA0.005 1
Analytical Lab
Page 4 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020818
Collection Date: 23-Jun-15 2:15 PM
Site: MW-16S
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Cobalt (Co)4.35 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Copper (Cu)4.18 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Molybdenum (Mo)1.23 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Nickel (Ni)1.63 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 16:19 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 16:19 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/27/2015 16:19 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Cobalt (Co)4.32 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Copper (Cu)1.02 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Molybdenum (Mo)1.24 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Nickel (Ni)1.57 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 05:51 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 05:51 SLS25600.2 1
Vanadium (V) Low Level 0.303 ug/L EPA 200.8 06/27/2015 05:51 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 0.508 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/25/2015 09:00 AGIBBS551
Analytical Lab
Page 5 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020821
Collection Date: 23-Jun-15 12:30 PM
Site: MW-16D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)2.9 mg-N/L EPA 353.2 06/26/2015 11:37 LSTARL10.05 5
INORGANIC IONS BY IC
Chloride 8.8 mg/L EPA 300.0 06/25/2015 16:15 BGN90340.1 1
Sulfate 7.7 mg/L EPA 300.0 06/25/2015 16:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:23 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 11:52 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/26/2015 10:07 FCJORDA0.005 1
Barium (Ba)0.012 mg/L EPA 200.7 06/26/2015 10:07 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 10:07 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/26/2015 10:07 FCJORDA0.01 1
Manganese (Mn)0.260 mg/L EPA 200.7 06/26/2015 10:07 FCJORDA0.005 1
Strontium (Sr)0.163 mg/L EPA 200.7 06/26/2015 10:07 FCJORDA0.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 06/26/2015 10:07 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.6 mg/L EPA 200.7 06/26/2015 11:58 FCJORDA0.01 1
Magnesium (Mg)5.16 mg/L EPA 200.7 06/26/2015 11:58 FCJORDA0.005 1
Potassium (K)2.32 mg/L EPA 200.7 06/26/2015 11:58 FCJORDA0.1 1
Sodium (Na)9.77 mg/L EPA 200.7 06/26/2015 11:58 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.102 mg/L EPA 200.7 06/26/2015 13:57 FCJORDA0.005 1
Barium (Ba)0.013 mg/L EPA 200.7 06/26/2015 13:57 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 13:57 FCJORDA0.05 1
Iron (Fe)0.087 mg/L EPA 200.7 06/26/2015 13:57 FCJORDA0.01 1
Manganese (Mn)0.269 mg/L EPA 200.7 06/26/2015 13:57 FCJORDA0.005 1
Strontium (Sr)0.163 mg/L EPA 200.7 06/26/2015 13:57 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/26/2015 13:57 FCJORDA0.005 1
Analytical Lab
Page 6 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020821
Collection Date: 23-Jun-15 12:30 PM
Site: MW-16D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Molybdenum (Mo)10.9 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 16:40 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 16:40 SLS25600.2 1
Vanadium (V) Low Level 0.530 ug/L EPA 200.8 06/27/2015 16:40 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Molybdenum (Mo)10.1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 05:58 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 05:58 SLS25600.2 1
Vanadium (V) Low Level 0.617 ug/L EPA 200.8 06/27/2015 05:58 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 0.208 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/25/2015 09:00 AGIBBS551
Analytical Lab
Page 7 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020822
Collection Date: 23-Jun-15 9:57 AM
Site: MW-16BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 11:32 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 7.0 mg/L EPA 300.0 06/25/2015 16:33 BGN90340.1 1
Sulfate 12 mg/L EPA 300.0 06/25/2015 16:33 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:26 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:02 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 06/26/2015 11:02 FCJORDA0.005 1
Barium (Ba)0.009 mg/L EPA 200.7 06/26/2015 11:02 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 11:02 FCJORDA0.05 1
Iron (Fe)0.012 mg/L EPA 200.7 06/26/2015 11:02 FCJORDA0.01 1
Manganese (Mn)0.025 mg/L EPA 200.7 06/26/2015 11:02 FCJORDA0.005 1
Strontium (Sr)0.112 mg/L EPA 200.7 06/26/2015 11:02 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/26/2015 11:02 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)22.5 mg/L EPA 200.7 06/26/2015 12:01 FCJORDA0.01 1
Magnesium (Mg)3.89 mg/L EPA 200.7 06/26/2015 12:01 FCJORDA0.005 1
Potassium (K)1.70 mg/L EPA 200.7 06/26/2015 12:01 FCJORDA0.1 1
Sodium (Na)23.9 mg/L EPA 200.7 06/26/2015 12:01 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.088 mg/L EPA 200.7 06/29/2015 09:33 MHH71310.005 1
Barium (Ba)0.011 mg/L EPA 200.7 06/29/2015 09:33 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/29/2015 09:33 MHH71310.05 1
Iron (Fe)0.080 mg/L EPA 200.7 06/29/2015 09:33 MHH71310.01 1
Manganese (Mn)0.030 mg/L EPA 200.7 06/29/2015 09:33 MHH71310.005 1
Strontium (Sr)0.112 mg/L EPA 200.7 06/29/2015 09:33 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/29/2015 09:33 MHH71310.005 1
Analytical Lab
Page 8 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020822
Collection Date: 23-Jun-15 9:57 AM
Site: MW-16BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Arsenic (As)2.07 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Molybdenum (Mo)21.8 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 16:48 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 16:48 SLS25600.2 1
Vanadium (V) Low Level 2.68 ug/L EPA 200.8 06/27/2015 16:48 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Arsenic (As)2.05 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Molybdenum (Mo)23.4 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 14:31 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 14:31 SLS25600.2 1
Vanadium (V) Low Level 2.79 ug/L EPA 200.8 06/27/2015 14:31 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 3.7 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 06/25/2015 09:00 AGIBBS551
Analytical Lab
Page 9 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020823
Collection Date: 23-Jun-15 9:20 AM
Site: ABMW-4BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 11:35 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 4.8 mg/L EPA 300.0 06/25/2015 16:50 BGN90340.1 1
Sulfate 80 mg/L EPA 300.0 06/25/2015 16:50 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:28 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:04 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 06/26/2015 10:22 FCJORDA0.005 1
Barium (Ba)0.113 mg/L EPA 200.7 06/26/2015 10:22 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 10:22 FCJORDA0.05 1
Iron (Fe)1.42 mg/L EPA 200.7 06/26/2015 10:22 FCJORDA0.01 1
Manganese (Mn)0.410 mg/L EPA 200.7 06/26/2015 10:22 FCJORDA0.005 1
Strontium (Sr)2.02 mg/L EPA 200.7 06/26/2015 10:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/26/2015 10:22 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)85.3 mg/L EPA 200.7 06/26/2015 12:05 FCJORDA0.01 1
Magnesium (Mg)5.97 mg/L EPA 200.7 06/26/2015 12:05 FCJORDA0.005 1
Potassium (K)6.23 mg/L EPA 200.7 06/26/2015 12:05 FCJORDA0.1 1
Sodium (Na)21.2 mg/L EPA 200.7 06/26/2015 12:05 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 06/29/2015 09:45 MHH71310.005 1
Barium (Ba)0.115 mg/L EPA 200.7 06/29/2015 09:45 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/29/2015 09:45 MHH71310.05 1
Iron (Fe)1.59 mg/L EPA 200.7 06/29/2015 09:45 MHH71310.01 1
Manganese (Mn)0.407 mg/L EPA 200.7 06/29/2015 09:45 MHH71310.005 1
Strontium (Sr)2.02 mg/L EPA 200.7 06/29/2015 09:45 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/29/2015 09:45 MHH71310.005 1
Analytical Lab
Page 10 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020823
Collection Date: 23-Jun-15 9:20 AM
Site: ABMW-4BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Molybdenum (Mo)6.10 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 16:55 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 16:55 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/27/2015 16:55 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Arsenic (As)1.08 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Molybdenum (Mo)6.12 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 14:08 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 14:08 SLS25600.2 1
Vanadium (V) Low Level 0.382 ug/L EPA 200.8 06/27/2015 14:08 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/25/2015 09:00 AGIBBS551
Analytical Lab
Page 11 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020824
Collection Date: 23-Jun-15 2:20 PM
Site: MW-13BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 11:36 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 46 mg/L EPA 300.0 06/25/2015 15:21 BGN9034110
Sulfate 18 mg/L EPA 300.0 06/25/2015 15:21 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:30 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:06 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.027 mg/L EPA 200.7 06/26/2015 10:26 FCJORDA0.005 1
Barium (Ba)0.041 mg/L EPA 200.7 06/26/2015 10:26 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 10:26 FCJORDA0.05 1
Iron (Fe)1.16 mg/L EPA 200.7 06/26/2015 10:26 FCJORDA0.01 1
Manganese (Mn)0.486 mg/L EPA 200.7 06/26/2015 10:26 FCJORDA0.005 1
Strontium (Sr)0.423 mg/L EPA 200.7 06/26/2015 10:26 FCJORDA0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 06/26/2015 10:26 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)75.2 mg/L EPA 200.7 06/26/2015 12:09 FCJORDA0.01 1
Magnesium (Mg)13.1 mg/L EPA 200.7 06/26/2015 12:09 FCJORDA0.005 1
Potassium (K)5.49 mg/L EPA 200.7 06/26/2015 12:09 FCJORDA0.1 1
Sodium (Na)25.7 mg/L EPA 200.7 06/26/2015 12:09 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.037 mg/L EPA 200.7 06/29/2015 09:48 MHH71310.005 1
Barium (Ba)0.040 mg/L EPA 200.7 06/29/2015 09:48 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/29/2015 09:48 MHH71310.05 1
Iron (Fe)1.13 mg/L EPA 200.7 06/29/2015 09:48 MHH71310.01 1
Manganese (Mn)0.474 mg/L EPA 200.7 06/29/2015 09:48 MHH71310.005 1
Strontium (Sr)0.418 mg/L EPA 200.7 06/29/2015 09:48 MHH71310.005 1
Zinc (Zn)0.036 mg/L EPA 200.7 06/29/2015 09:48 MHH71310.005 1
Analytical Lab
Page 12 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020824
Collection Date: 23-Jun-15 2:20 PM
Site: MW-13BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Molybdenum (Mo)7.20 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 17:02 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 17:02 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/27/2015 17:02 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Cobalt (Co)1.19 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Molybdenum (Mo)8.28 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 14:38 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 14:38 SLS25600.2 1
Vanadium (V) Low Level 0.381 ug/L EPA 200.8 06/27/2015 14:38 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 0.900 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
Analytical Lab
Page 13 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020824
Collection Date: 23-Jun-15 2:20 PM
Site: MW-13BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 06/25/2015 09:00 AGIBBS551
Analytical Lab
Page 14 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020837
Collection Date: 23-Jun-15 12:30 PM
Site: MW-16D-Dup
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)2.9 mg-N/L EPA 353.2 06/26/2015 11:43 LSTARL10.05 5
INORGANIC IONS BY IC
Chloride 8.9 mg/L EPA 300.0 06/25/2015 17:26 BGN90340.1 1
Sulfate 7.8 mg/L EPA 300.0 06/25/2015 17:26 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:33 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:09 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/26/2015 11:06 FCJORDA0.005 1
Barium (Ba)0.013 mg/L EPA 200.7 06/26/2015 11:06 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 11:06 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/26/2015 11:06 FCJORDA0.01 1
Manganese (Mn)0.250 mg/L EPA 200.7 06/26/2015 11:06 FCJORDA0.005 1
Strontium (Sr)0.179 mg/L EPA 200.7 06/26/2015 11:06 FCJORDA0.005 1
Zinc (Zn)0.093 mg/L EPA 200.7 06/26/2015 11:06 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.4 mg/L EPA 200.7 06/26/2015 12:13 FCJORDA0.01 1
Magnesium (Mg)5.10 mg/L EPA 200.7 06/26/2015 12:13 FCJORDA0.005 1
Potassium (K)2.31 mg/L EPA 200.7 06/26/2015 12:13 FCJORDA0.1 1
Sodium (Na)9.72 mg/L EPA 200.7 06/26/2015 12:13 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.086 mg/L EPA 200.7 06/29/2015 09:52 MHH71310.005 1
Barium (Ba)0.013 mg/L EPA 200.7 06/29/2015 09:52 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/29/2015 09:52 MHH71310.05 1
Iron (Fe)0.085 mg/L EPA 200.7 06/29/2015 09:52 MHH71310.01 1
Manganese (Mn)0.261 mg/L EPA 200.7 06/29/2015 09:52 MHH71310.005 1
Strontium (Sr)0.163 mg/L EPA 200.7 06/29/2015 09:52 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/29/2015 09:52 MHH71310.005 1
Analytical Lab
Page 15 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020837
Collection Date: 23-Jun-15 12:30 PM
Site: MW-16D-Dup
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Molybdenum (Mo)10.6 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 17:09 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 17:09 SLS25600.2 1
Vanadium (V) Low Level 0.537 ug/L EPA 200.8 06/27/2015 17:09 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Molybdenum (Mo)11.3 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 14:45 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 14:45 SLS25600.2 1
Vanadium (V) Low Level 0.729 ug/L EPA 200.8 06/27/2015 14:45 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 0.214 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/25/2015 09:00 AGIBBS551
Analytical Lab
Page 16 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020838
Collection Date: 23-Jun-15 9:24 AM
Site: MW-3
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
Analytical Lab
Page 17 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020839
Collection Date: 23-Jun-15 4:30 PM
Site: Filter Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 12:11 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/26/2015 10:34 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/26/2015 10:34 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 10:34 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/26/2015 10:34 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/26/2015 10:34 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/26/2015 10:34 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 06/26/2015 10:34 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Copper (Cu)6.05 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 17:16 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 17:16 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/27/2015 17:16 MHALL30.3 1
Analytical Lab
Page 18 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020840
Collection Date: 23-Jun-15 4:30 PM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 11:39 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 06/25/2015 13:51 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 06/25/2015 13:51 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/30/2015 10:35 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.036 mg/L EPA 200.7 06/26/2015 12:17 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/26/2015 12:17 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 06/26/2015 12:17 FCJORDA0.1 1
Sodium (Na)0.052 mg/L EPA 200.7 06/26/2015 12:17 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 06/29/2015 09:56 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/29/2015 09:56 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/29/2015 09:56 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/29/2015 09:56 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/29/2015 09:56 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/29/2015 09:56 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/29/2015 09:56 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/27/2015 14:52 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/27/2015 14:52 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/27/2015 14:52 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
Analytical Lab
Page 19 of 69
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060802
2015020840
Collection Date: 23-Jun-15 4:30 PM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 06/25/2015 15:24 AGIBBS5251
Total Carbon
TOC 0.204 mg/L SM5310C/EPA9060A 06/29/2015 13:32 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/25/2015 09:00 AGIBBS551
Analytical Lab
Page 20 of 69
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Page 25 of 69

July 02, 2015

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 375757
SDG: J15060802

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on June 25, 2015. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Analytical Lab
Page 26 of 69
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J15060802 GEL Work Order: 375757
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
for
Analytical Lab
Page 27 of 69
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 2, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1488554
1488554
1488665
1488667
1547
1911
1137
0920
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/01/15
07/01/15
07/01/15
07/01/15
SKJ
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
375757001
Water
23-JUN-15 14:20
25-JUN-15
2015020824 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"83.6 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.41
0.400
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/26/15 14885530800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000047
0.00
0.00
0.00
-0.618
1.22
NominalResult
RLDL
Notes:
Analytical Lab
Page 28 of 69
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 2, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1488554
1488554
1488665
1488667
1549
1913
1137
0920
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/01/15
07/01/15
07/01/15
07/01/15
SKJ
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
375757002
Water
23-JUN-15 09:24
25-JUN-15
2015020838 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"75.7 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.37
0.261
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/26/15 14885530800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.00173
0.00
0.00
0.00
0.238
3.13
NominalResult
RLDL
Notes:
Analytical Lab
Page 29 of 69
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1488554Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 2, 2015Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/01/15 19:03
07/01/15 17:08
07/01/15 17:01
07/01/15 19:01
07/01/15 18:59
07/01/15 17:00
07/01/15 17:09
07/01/15 19:05
07/01/15 19:06
QC
ND
ND
ND
0.000209
0.0552
0.00054
0.000575
0.00601
ND
ND
ND
ND
0.0553
0.00054
0.000577
0.00601
ND
NOM Sample
ND
ND
ND
0.000232
0.000232
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
QC1203344242 375756001
QC1203344241
QC1203344250
QC1203344240
QC1203344243 375756001
QC1203344251 375756001
QC1203344244 375756001
N/A
N/A
N/A
10.4
N/A
REC%
111
108
105
120
111
108
105
120
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
375757Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^
RPD%
Page 1 of 3
Analytical Lab
Page 30 of 69
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1488554
1488665
1488667
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
CXP3
07/01/15 19:06
07/01/15 17:10
07/01/15 11:38
07/01/15 11:38
07/01/15 11:35
07/01/15 09:55
07/01/15 09:55
07/01/15 09:20
07/01/15 09:55
QC
ND
ND
ND
1.32
29.1
1.05
1.99
25.2
0.431
113
NOM Sample
ND
ND
0.232
-0.618
1.22
1.22
Range
(0%-10%)
(0%-10%)
N/A
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203344535 375757001
QC1203344536
QC1203344534
QC1203344538 375757001
QC1203344540
QC1203344537
QC1203344539 375757001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
N/A
47.6
REC%
95
102
90.8
30.7
24.7
124
DUP
LCS
MB
DUP
LCS
MB
MS
375757Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
RPD%
Notes:
Page 2 of 3
Analytical Lab
Page 31 of 69
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
375757Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Analytical Lab
Page 32 of 69
Analytical Lab
Page 33 of 69
Analytical Lab
Page 34 of 69
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
Oklahoma
Pennsylvania NELAP
Plant Material Permit
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-110
88-0651
42D0904046
2940 Interim
SC00012
PH-0169
SC000122013-10
2567.01
E87156
P330-12-00283, P330-12-00284
SC00012
967
SC000122013-10
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA150001
270
M-SC012
9976
SC000122013-10
NE-OS-26-13
SC000122014-1
2054
SC002
SC00012
11501
233
45709
9904
68-00485
PDEP-12-00260
10120002
10120001
TN 02934
T104704235-15-10
SC000122015-17
VT87156
460202
C780
997404
List of current GEL Certifications as of 02 July 2015
Analytical Lab
Page 35 of 69
There are no "Data Exception Reports" associated with this analytical report.
Analytical Lab
Page 36 of 69
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QF26039Lot Number:
J15060802Project Number:
AB GW Assessment Water - MayoProject Name:
07/01/2015Date Completed:
Grant Wilton
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QF26039
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Mayo
Project Number: J15060802
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 18
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF26039

Project Name: AB GW Assessment Water - Mayo
Project Number: J15060802
Sample Number Sample ID Matrix Date Sampled Date Received
001 06/23/2015 141520150201818Aqueous 06/26/2015
002 06/23/2015 123020150201821Aqueous 06/26/2015
003 06/23/2015 095720150201822Aqueous 06/26/2015
004 06/23/2015 092020150201823Aqueous 06/26/2015
005 06/23/2015 142020150201824Aqueous 06/26/2015
006 06/23/2015 123020150201837Aqueous 06/26/2015
007 06/23/2015 163020150201840Aqueous 06/26/2015
(7 samples)
Page: 3 of 18
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Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF26039

Project Name: AB GW Assessment Water - Mayo
Project Number: J15060802
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 20150201818 Aqueous Alkalinity SM 2320B-43 mg/L 5
001 20150201818 Aqueous Bicarbonate Alkalinity SM 2320B-43 mg/L 5
002 20150201821 Aqueous Alkalinity SM 2320B-76 mg/L 7
002 20150201821 Aqueous Bicarbonate Alkalinity SM 2320B-75 mg/L 7
003 20150201822 Aqueous Alkalinity SM 2320B-97 mg/L 9
003 20150201822 Aqueous Bicarbonate Alkalinity SM 2320B-96 mg/L 9
004 20150201823 Aqueous Alkalinity SM 2320B-190 mg/L 11
004 20150201823 Aqueous Bicarbonate Alkalinity SM 2320B-190 mg/L 11
005 20150201824 Aqueous Alkalinity SM 2320B-210 mg/L 13
005 20150201824 Aqueous Bicarbonate Alkalinity SM 2320B-210 mg/L 13
006 20150201837 Aqueous Alkalinity SM 2320B-76 mg/L 15
006 20150201837 Aqueous Bicarbonate Alkalinity SM 2320B-76 mg/L 15
(12 detections)
Page: 4 of 18
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201818
QF26039-001
06/23/2015 1415
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2036 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2036 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2036 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 43 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 43 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 18
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201818
QF26039-001
06/23/2015 1415
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/29/2015 2154 JJG 78405
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 18
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201821
QF26039-002
06/23/2015 1230
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2042 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2042 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2042 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 76 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 75 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 18
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201821
QF26039-002
06/23/2015 1230
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/29/2015 1434 DCS 78365
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 18
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201822
QF26039-003
06/23/2015 0957
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2048 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2048 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2048 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 97 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 96 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 18
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201822
QF26039-003
06/23/2015 0957
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/29/2015 2207 JJG 78405
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 18
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Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201823
QF26039-004
06/23/2015 0920
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2055 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2055 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2055 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 190 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 190 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 11 of 18
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Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201823
QF26039-004
06/23/2015 0920
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/29/2015 2231 JJG 78405
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 12 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201824
QF26039-005
06/23/2015 1420
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2102 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2102 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2102 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 210 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 210 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 13 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201824
QF26039-005
06/23/2015 1420
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/30/2015 1348 DCS 78512
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 14 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201837
QF26039-006
06/23/2015 1230
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2108 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2108 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2108 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 76 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 76 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 15 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201837
QF26039-006
06/23/2015 1230
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/30/2015 1358 DCS 78512
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 16 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201840
QF26039-007
06/23/2015 1630
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/30/2015 2113 HMA 78532
1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 2113 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 2113 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 17 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
20150201840
QF26039-007
06/23/2015 1630
06/26/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060802
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/30/2015 1410 DCS 78512
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 18 of 18
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

QC Summary
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:QQ78532-001
78532
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 06/30/2015 182910mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:QQ78532-002
78532
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 97 06/30/2015 18349710090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ78365-001
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/29/2015 101510ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ78365-002
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 130 06/29/2015 09498315070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ78365-003
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 110 06/29/2015 10027515070-13010 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ78405-001
78405
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/29/2015 161510ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ78405-002
78405
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 120 06/29/2015 15448015070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ78405-003
78405
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 110 06/29/2015 15547315070-1308.9 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - MB
Batch:
Sample ID:QQ78512-001
78512
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/30/2015 125510ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCS
Batch:
Sample ID:QQ78512-002
78512
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 120 06/30/2015 12338215070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Methane - LCSD
Batch:
Sample ID:QQ78512-003
78512
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 120 06/30/2015 12448015070-1302.7 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF26039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Analytical Lab
Page 69 of 69