The URL can be used to link to this page

Home My WebLink AboutNC0038377_J15060701report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060701 Project Name:MAYO STEAM - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:7/2/2015 Customer Address: Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 38 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015020447 MAYO STEAM 19-Jun-15 12:25 PM Erin Black MW-7D 2015020448 MAYO STEAM 19-Jun-15 1:05 PM Erin Black MW-7BR 2015020449 MAYO STEAM 19-Jun-15 Filter Blank 2015020450 MAYO STEAM 19-Jun-15 Equipment Blank 4 Total Samples Analytical Lab Page 2 of 38 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:7/2/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 38 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060701 2015020447 Collection Date: 19-Jun-15 12:25 PM Site: MW-7D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 10:58 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 78 mg/L EPA 300.0 06/23/2015 20:16 BGN9034110 Sulfate 9.0 mg/L EPA 300.0 06/23/2015 20:16 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/24/2015 15:14 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/24/2015 16:18 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/22/2015 10:48 FCJORDA0.005 1 Barium (Ba)0.023 mg/L EPA 200.7 06/22/2015 10:48 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/22/2015 10:48 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/22/2015 10:48 FCJORDA0.01 1 Manganese (Mn)0.176 mg/L EPA 200.7 06/22/2015 10:48 FCJORDA0.005 1 Strontium (Sr)0.430 mg/L EPA 200.7 06/22/2015 10:48 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/22/2015 10:48 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)59.5 mg/L EPA 200.7 06/22/2015 13:00M4 FCJORDA0.01 1 Magnesium (Mg)26.4 mg/L EPA 200.7 06/22/2015 13:00M4 FCJORDA0.05 10 Potassium (K)2.66 mg/L EPA 200.7 06/22/2015 13:00 FCJORDA0.1 1 Sodium (Na)30.7 mg/L EPA 200.7 06/22/2015 13:00M4 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.147 mg/L EPA 200.7 06/24/2015 12:13 MHH71310.005 1 Barium (Ba)0.024 mg/L EPA 200.7 06/24/2015 12:13 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/24/2015 12:13 MHH71310.05 1 Iron (Fe)0.069 mg/L EPA 200.7 06/24/2015 12:13 MHH71310.01 1 Manganese (Mn)0.188 mg/L EPA 200.7 06/24/2015 12:13 MHH71310.005 1 Strontium (Sr)0.442 mg/L EPA 200.7 06/24/2015 12:13 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/24/2015 12:13 MHH71310.005 1 Analytical Lab Page 4 of 38 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060701 2015020447 Collection Date: 19-Jun-15 12:25 PM Site: MW-7D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Molybdenum (Mo)1.46 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Nickel (Ni)1.01 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 19:48 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 19:48 SLS25600.2 1 Vanadium (V) Low Level 0.680 ug/L EPA 200.8 06/26/2015 19:48 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Molybdenum (Mo)1.35 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 17:59 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 17:59 SLS25600.2 1 Vanadium (V) Low Level 0.798 ug/L EPA 200.8 06/26/2015 17:59 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 390 mg/L SM2540C 06/23/2015 14:39 AGIBBS5251 Total Carbon TOC 1.2 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/22/2015 07:54 AGIBBS551 Analytical Lab Page 5 of 38 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060701 2015020448 Collection Date: 19-Jun-15 1:05 PM Site: MW-7BR Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 11:04M2 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 15 mg/L EPA 300.0 06/23/2015 20:32 BGN9034110 Sulfate 1.6 mg/L EPA 300.0 06/23/2015 20:32 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/24/2015 15:16 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/24/2015 16:20 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.007 mg/L EPA 200.7 06/22/2015 10:52 FCJORDA0.005 1 Barium (Ba)0.138 mg/L EPA 200.7 06/22/2015 10:52 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/22/2015 10:52 FCJORDA0.05 1 Iron (Fe)0.223 mg/L EPA 200.7 06/22/2015 10:52 FCJORDA0.01 1 Manganese (Mn)0.263 mg/L EPA 200.7 06/22/2015 10:52 FCJORDA0.005 1 Strontium (Sr)0.986 mg/L EPA 200.7 06/22/2015 10:52 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/22/2015 10:52 FCJORDA0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)57.3 mg/L EPA 200.7 06/22/2015 13:11 FCJORDA0.01 1 Magnesium (Mg)12.1 mg/L EPA 200.7 06/22/2015 13:11 FCJORDA0.005 1 Potassium (K)4.92 mg/L EPA 200.7 06/22/2015 13:11 FCJORDA0.1 1 Sodium (Na)18.2 mg/L EPA 200.7 06/22/2015 13:11 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.015 mg/L EPA 200.7 06/26/2015 13:34 FCJORDA0.005 1 Barium (Ba)0.140 mg/L EPA 200.7 06/26/2015 13:34 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 13:34 FCJORDA0.05 1 Iron (Fe)0.339 mg/L EPA 200.7 06/26/2015 13:34 FCJORDA0.01 1 Manganese (Mn)0.263 mg/L EPA 200.7 06/26/2015 13:34 FCJORDA0.005 1 Strontium (Sr)0.988 mg/L EPA 200.7 06/26/2015 13:34 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/26/2015 13:34 FCJORDA0.005 1 Analytical Lab Page 6 of 38 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060701 2015020448 Collection Date: 19-Jun-15 1:05 PM Site: MW-7BR Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Molybdenum (Mo)3.57 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 19:55 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 19:55 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 19:55 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Molybdenum (Mo)3.72 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 21:44 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 21:44 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 21:44 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 270 mg/L SM2540C 06/23/2015 14:39 AGIBBS5251 Total Carbon TOC 1.9 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/22/2015 07:54 AGIBBS551 Analytical Lab Page 7 of 38 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060701 2015020449 Collection Date: 19-Jun-15 Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/24/2015 16:22 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/22/2015 10:56 FCJORDA0.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/22/2015 10:56 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/22/2015 10:56 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/22/2015 10:56 FCJORDA0.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/22/2015 10:56 FCJORDA0.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/22/2015 10:56 FCJORDA0.005 1 Zinc (Zn)0.008 mg/L EPA 200.7 06/22/2015 10:56 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 20:02 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 20:02 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 20:02 SLS25600.3 1 Analytical Lab Page 8 of 38 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060701 2015020450 Collection Date: 19-Jun-15 Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 11:07 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 06/23/2015 18:21 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 06/23/2015 18:21 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/24/2015 15:19 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)< 0.01 mg/L EPA 200.7 06/22/2015 13:15 FCJORDA0.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/22/2015 13:15 FCJORDA0.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 06/22/2015 13:15 FCJORDA0.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 06/22/2015 13:15 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/26/2015 13:38 FCJORDA0.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/26/2015 13:38 FCJORDA0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/26/2015 13:38 FCJORDA0.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/26/2015 13:38 FCJORDA0.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/26/2015 13:38 FCJORDA0.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/26/2015 13:38 FCJORDA0.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/26/2015 13:38 FCJORDA0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 21:51 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 21:51 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 21:51 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 9 of 38 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060701 2015020450 Collection Date: 19-Jun-15 Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/23/2015 14:39 AGIBBS5251 Total Carbon TOC 0.271 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/22/2015 07:54 AGIBBS551 Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. Analytical Lab Page 10 of 38 Analytical Lab Page 11 of 38 Analytical Lab Page 12 of 38 Analytical Lab Page 13 of 38 Analytical Lab Page 14 of 38 Analytical Lab Page 15 of 38 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QF24068Lot Number: J15060701Project Number: AB GW Assessment Water - MayoProject Name: 07/01/2015Date Completed: Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QF24068 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Mayo Project Number: J15060701 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF24068 Project Name: AB GW Assessment Water - Mayo Project Number: J15060701 Sample Number Sample ID Matrix Date Sampled Date Received 001 06/19/2015 12252015020447Aqueous 06/24/2015 002 06/19/2015 13052015020448Aqueous 06/24/2015 003 06/19/2015 12002015020450Aqueous 06/24/2015 (3 samples) Page: 3 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF24068 Project Name: AB GW Assessment Water - Mayo Project Number: J15060701 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015020447 Aqueous Alkalinity SM 2320B-180 mg/L 5 001 2015020447 Aqueous Bicarbonate Alkalinity SM 2320B-180 mg/L 5 002 2015020448 Aqueous Alkalinity SM 2320B-210 mg/L 7 002 2015020448 Aqueous Bicarbonate Alkalinity SM 2320B-200 mg/L 7 003 2015020450 Aqueous Methane RSK - 175 11 ug/L 10 (5 detections) Page: 4 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015020447 QF24068-001 06/19/2015 1225 06/24/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060701 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/26/2015 2217 HMA 78168 1 (Bicarbonate ) SM 2320B-2011 1 06/26/2015 2217 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/26/2015 2217 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 180 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 180 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015020447 QF24068-001 06/19/2015 1225 06/24/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060701 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/29/2015 1213 DCS 78365 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015020448 QF24068-002 06/19/2015 1305 06/24/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060701 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/26/2015 2224 HMA 78168 1 (Bicarbonate ) SM 2320B-2011 1 06/26/2015 2224 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/26/2015 2224 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 210 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 200 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015020448 QF24068-002 06/19/2015 1305 06/24/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060701 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/29/2015 1352 DCS 78365 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015020450 QF24068-003 06/19/2015 1200 06/24/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060701 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/30/2015 1840 HMA 78532 1 (Bicarbonate ) SM 2320B-2011 1 06/30/2015 1840 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/30/2015 1840 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015020450 QF24068-003 06/19/2015 1200 06/24/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060701 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/29/2015 1403 DCS 78365 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 11 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. QC Summary QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:QQ78168-001 78168 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/26/2015 193510mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:QQ78168-002 78168 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 98 06/26/2015 19419810090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MS Batch: Sample ID:QF24068-002MS 78168 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 220 06/26/2015 2231N9.6100 70-1302101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MSD Batch: Sample ID:QF24068-002MD 78168 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 220 06/26/2015 2238N9.8100 70-1300.079 202101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - MB Batch: Sample ID:QQ78532-001 78532 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/30/2015 182910mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Inorganic non-metals - LCS Batch: Sample ID:QQ78532-002 78532 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 97 06/30/2015 18349710090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - MB Batch: Sample ID:QQ78365-001 78365 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/29/2015 101510ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCS Batch: Sample ID:QQ78365-002 78365 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 130 06/29/2015 09498315070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Methane - LCSD Batch: Sample ID:QQ78365-003 78365 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 110 06/29/2015 10027515070-13010 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF24068 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Analytical Lab Page 38 of 38